ALBERT

Description: Gas hydrates dissociation could induce or trigger submarine landslides, especially in upper continental slopes where hydrates are vulnerable to natural and artificial perturbations. This work investigates destabilization mechanisms of an upper continental slope undergoing hydrate dissociation and identifies spatiotemporal failure modes influenced by characteristics of the overburden above the hydrate-bearing layer (i.e. the hydrate reservoir). A Thermo-Hydro-Chemical coupled numerical model of transient pore pressure induced by hydrate dissociation is coupled with the limit equilibrium slope analysis method to study the spatiotemporal evolution of the potential sliding plane and to calculate the corresponding factor of safety. The results suggest that overpressure generated by the liberated fluid from hydrate dissociation is the primary reason for instability in a gentle marine slope. The study identifies three sliding modes, namely co-melting non-interface sliding, co-melting interface sliding, and post-melting non-interface sliding, depending on the overburden's characteristics, including overburden thickness, permeability, and cohesion. Co-melting non-interface sliding takes place during hydrate dissociation if the hydrate reservoir underlies a thin, pervious and low-cohesion overburden cover. For less permeable and more cohesive overburdens, the potential sliding plane is deeper and co-melting interface sliding could be triggered due to overpressure developed at the reservoir-overburden interface. If the hydrate reservoir is covered by a thick, low-permeability and slightly cohesive overburden, post-melting non-interface sliding could occur after the hydrates are completely dissociated. This failure is delayed, because the gas/water trapped at the interface during hydrate dissociation is insufficient to trigger instability due to very high overburden stresses. However, as the gas migrates upwards over time and encounters a weak zone in the overburden deposits, failure could happen within the overburden deposits even after hydrate dissociation stops. The findings help to improve our fundamental understanding about the destabilization mechanism and failure modes of the continental slopes undergoing hydrate dissociation, and to delineate the vulnerable configurations of the slopes.

Description: n our daily lives, we consume foods that have been transported, stored, prepared, cooked, or otherwise processed by ourselves or others. Food storage and preparation have drastic effects on the chemical composition of foods. Untargeted mass spectrometry analysis of food samples has the potential to increase our chemical understanding of these processes by detecting a broad spectrum of chemicals. We performed a time-based analysis of the chemical changes in foods during common preparations, such as fermentation, brewing, and ripening, using untargeted mass spectrometry and molecular networking. The data analysis workflow presented implements an approach to study changes in food chemistry that can reveal global alterations in chemical profiles, identify changes in abundance, as well as identify specific chemicals and their transformation products. The data generated in this study are publicly available, enabling the replication and re-analysis of these data in isolation, and serve as a baseline dataset for future investigations.

Description: Deepwater spills pose a unique challenge for reliable predictions of oil transport and fate, since live oil spewing under very high hydrostatic pressure has characteristics remarkably distinct from oil spilling in shallow water. It is thus important to describe in detail the complex thermodynamic processes occurring in the near-field, meters above the wellhead, and the hydrodynamic processes in the far-field, up to kilometers away. However, these processes are typically modeled separately since they occur at different scales. Here we directly couple two oil prediction applications developed during the Deepwater Horizon blowout operating at different scales: the near-field Texas A&M Oilspill Calculator (TAMOC) and the far-field oil application of the Connectivity Modeling System (oil-CMS). To achieve this coupling, new oil-CMS modules were developed to read TAMOC output, which consists of the description of distinct oil droplet “types,” each of specific size and pseudo-component mixture that enters at a given mass flow rate, time, and position into the far field. These variables are transformed for use in the individual-based framework of CMS, where each droplet type fits into a droplet size distribution (DSD). Here we used 19 pseudo-components representing a large range of hydrocarbon compounds and their respective thermodynamic properties. Simulation results show that the dispersion pathway of the different droplet types varies significantly. Indeed, some droplet types remain suspended in the subsea over months, while others accumulate in the surface layers. In addition, the decay rate of oil pseudo-components significantly alters the dispersion, denoting the importance of more biodegradation and dissolution studies of chemically and naturally dispersed live oil at high pressure. This new modeling tool shows the potential for improved accuracy in predictions of oil partition in the water column and of advancing impact assessment and response during a deepwater spill.

Description: Petroleum is one of the most complex naturally occurring organic mixtures. The physical and chemical properties of petroleum in a reservoir depend on its molecular composition and the reservoir conditions (temperature, pressure). The composition of petroleum varies greatly, ranging from the simplest gas (methane), condensates, conventional crude oil to heavy oil and oil sands bitumen with complex molecules having molecular weights in excess of 1000 daltons (Da). The distribution of petroleum constituents in a reservoir largely depends on source facies (original organic material buried), age (evolution of organisms), depositional environment (dysoxic versus anoxic), maturity of the source rock (kerogen) at time of expulsion, primary/secondary migration, and in-reservoir alteration such as biodegradation, gas washing, water washing, segregation, and/or mixing from different oil charges. These geochemical aspects define the physical characteristics of a petroleum in the reservoir, including its density and viscosity. When the petroleum is released from the reservoir through an oil exploration accident like in the case of the Deepwater Horizon event, several processes are affecting the physical and chemical properties of the petroleum from the well head into the deep sea. A better understanding of these properties is crucial for the development of near-field oil spill models, oil droplet and gas bubble calculations, and partitioning behavior of oil components in the water. Section 3.1 introduces general aspects of the origin of petroleum, the impact of geochemical processes on the composition of a petroleum, and some molecular compositional and physicochemical background information of the Macondo well oil. Section 3.2 gives an overview over experimental determination of all relevant physicochemical properties of petroleum, especially of petroleum under reservoir conditions. Based on the phase equilibrium modeling using equations of state (EOS), a number of these properties can be predicted which is presented in Sect. 3.3 along with a comparison to experimental data obtained with methods described in Sect. 3.2.

Description: Deutschland wird im Juli 2020 den Vorsitz im Sicherheitsrat der Vereinten Nationen übernehmen und den Blick der Staatengemeinschaft erneut auf die sicherheits­relevanten Folgen des Klimawandels lenken. Besorgniserregend ist besonders, dass der Meeresspiegel mit zunehmender Geschwindigkeit ansteigt. Dies birgt die Gefahr einer dauerhaften Überflutung niedrig gelegener Küstengebiete und kleinerer Inseln. Dar­aus ergeben sich auch schwierige völkerrechtliche Fragen, auf die das geltende Recht nur zum Teil Antworten liefert. Daher müssen einzelne Regelungsmaterien wie etwa das Seerecht oder der Individualschutz weiterentwickelt werden. Denkbar ist zum einen, dass etablierte Normen und Prinzipien im Lichte neuer Herausforderungen progressiv ausgelegt werden. Zum anderen ließen sich Lücken durch zusätzliche ver­tragliche Regelungen schließen. Damit politische Spielräume für eine Fortentwicklung des völkerrechtlichen Instrumentariums entstehen können, ist ein breiterer Dia­log unter den Staaten nötig. Der Sicherheitsrat könnte maßgebliche Anstöße liefern, um einen solchen Austausch in Gang zu bringen.

Description: The sheared-passive margin offshore Durban (South Africa) is characterised by a narrow continental shelf and steep slope hosting numerous submarine canyons. Supply of sediment to the margin is predominantly terrigenous, dominated by discharge from several short but fast-flowing rivers. IODP Expedition 361 provides a unique opportunity to investigate the role of sea level fluctuations on the sedimentation patterns and slope instability along the South African margin. We analysed 〉300 sediment samples and downcore variations in P-wave, magnetic susceptibility, bioturbation intensity, and bulk density from site U1474, as well as regional seismic reflection profiles to: (i) document an increase in sand input since the mid-Pliocene; (ii) associate this change to a drop in sea level and extension of subaerial drainage systems towards the shelf-edge; (iii) demonstrate that slope instability has played a key role in the evolution of the South Africa margin facing the Natal Valley. Furthermore, we highlight how the widespread occurrence of failure events reflects the tectonic control on the morphology of the shelf and slope, as well as bottom current scour and instability of fan complexes. This information in important to improve hazard assessment in a populated coastal region with growing offshore hydrocarbon activities.

Description: A comparison of gouge and hammer coring techniques in intertidal wetland soils highlights a significant effect of soil compaction of up to 28% associated with the widely applied hammer coring method employed in Blue Carbon research. Hammer coring reduces the thickness of the soil profile and increases the dry bulk density, which results in an overestimation of the soil OC stock of up to 22%. In saltmarshes with multiple different soil units, we show that hammer coring is unsuitable for the calculation of OC stocks and should be avoided in favour of Russian or gouge cores. Compaction changes both soil dry bulk density and porosity and we show that resultant radiometric chronologies are compromised, almost doubling mass accumulation rates. While we show that the OC (%) content of these sediments is largely unchanged by coring method, the implication for OC burial rates are profound because of the significant effect of hammer coring on the calculation of soil mass accumlation rates.

Description: Areas of Research: Biological oceanography, Plankton Ecology and Evolution (this was a teaching cruise within the BMARSYS programme at Hamburg University. The main goal was for students to familiarize themselves with the methods associated with the areas of research stated above).

Description: Marine fungi are part of the huge and understudied biodiversity hosted in the sea. To broaden the knowledge on fungi inhabiting the Mediterranean Sea and their role in sponge holobiont, three sponges namely Aplysina cavernicola, Crambe crambe and Phorbas tenacior were collected in Villefranche sur Mer, (France) at about 25 m depth. The fungal communities associated with the sponges were isolated using different techniques to increase the numbers of fungi isolated. All fungi were identified to species level giving rise to 19, 13 and 3 species for P. tenacior, A. cavernicola and C. crambe, respectively. Of note, 35.7% and 50.0% of the species detected were either reported for the first time in the marine environment or in association with sponges. The mini-satellite analysis confirmed the uniqueness of the mycobiota of each sponge, leading to think that the sponge, with its metabolome, may shape the microbial community.

Description: Seagrasses provide multiple ‘ecosystem services' in coastal waters, including carbon sequestration. However, this ‘Blue Carbon’ potential has been only evaluated for certain species from some areas of the world. In this study, we provide initial estimates on the magnitude and local variability of carbon sequestration, as organic carbon stocks, for seagrass meadows of Cymodocea nodosa (Ucria) Ascherson in the oceanic island of Gran Canaria (Canary Islands, Spain, central-eastern Atlantic). Six seagrass meadows were selected; at each meadow, cores inserted up to 30 cm in the seabed were collected in the ‘interior’, ‘edge’ and ‘unvegetated’ bottoms immediately adjacent to seagrass patches. We estimated organic carbon (Corg) pools by means of the Loss of Ignition (LOI) procedure. Overall, larger Corg pools were observed in the ‘interior’ and 'edges' of meadow patches than in adjacent ‘unvegetated’ bottoms. At the meadow-level, Corg pools were not predicted neither by the meadow area, nor by the mean shoot density, or sediment grain fractions. Overall, the total estimated stock was 86.20 ± 19.06 Mg C ha−1. By considering the total potential extension of seagrass meadows across the entire island perimeter, we estimated a total stock of 60.34 Gg of C, for a mean estimated financial value of 919,432.249 € (1313.47 € ha−1), which ranges between 351,631.35 € (502.33 € ha−1) and 1,498,954.45 € (2141.36 € ha−1), according to varying market prices in the last 5 years. This work highlights, therefore, the importance of meadows underpinned by C. nodosa not only at an ecological, but also at an economic level, in particular from the perspective of regional climate change adaptation strategies.

Description: JAGO-AUV-FieldTrials, Äolische Inseln Wochenbericht 05.-18.02.2020

Description: Western Boundary Currents, such as the Gulf Stream, are regions of vivid air-sea interaction. Mesoscale features of these currents play a fundamental role in global ocean heat transport and exchange with the atmosphere. Related processes and their interactions across scales have gained increasing attention in the last years, since high-resolution, mesoscale-resolving modeling became computationally feasible on climate time scales. Here, we show the impact of explicitly resolving the oceanic mesoscale in the coupled global climate model FOCI on North Atlantic and European climate. For this purpose, we use the ocean nesting capability in FOCI, which facilitates regional ocean grid refinement. We explore and compare pre-industrial simulations each extending over at least 150 years: a reference run without any grid refinement and an experiment with a nest in the North Atlantic. Technically, the regional ocean nest maintains frequent two-way exchange with the global host grid, which in turn is fully coupled to the atmosphere model. The ocean model NEMO has a global resolution of 1/2˚ model with 46 vertical levels and 1/10˚ refinement in the nest region, while the atmosphere model ECHAM6 has a 1.8˚ horizontal resolution (T63) and 95 vertical levels, including the strato- and mesosphere. Within the nest region, the increased resolution leads to a more eddy-rich simulation and an improved mean state. The North Atlantic Current is considerably better represented, which reduces the typical North Atlantic cold bias from -8˚C in the reference run without nest to -2˚C. Beyond local bias correction of the mean state, we will also discuss the impact of explicitly modeling ocean mesoscale dynamics on atmospheric variability on different time scales, such as the North Atlantic Oscillation or the Atlantic Multidecadal Variability.

Description: Nitrous oxide (N2O) is one of the most important long-lived greenhouse gases (GHG) responsible for the overall warming of the Earth system, and the strongest ozone-depleting compound in the stratosphere. While the ocean is thought to be a net source of N2O to the atmosphere, at regional and basin-scales there is a large range of variability in terms of its mid-depth water production and consumption, as well as a wide range of physical processes which impact the pool of this GHG in surface waters, posing a significant challenge to both observational and model-based estimates of the annual emissions. Furthermore, although environmental changes such as warming, eutrophication and decrease in sea ice coverage are expected to affect the cycling of N2O, the particular direction of the projected trends is highly uncertain, mostly due to the paucity of measurements in strong source regions and areas of difficult access due to their remote location or extreme weather conditions. In this talk I will present an overview of the current state of knowledge with respect to the exchanges of N2O across the sea-air-ice interfaces, and discuss their relevance in the context of ongoing climate change. To this end, I will use examples from ship-based observations in Eastern Boundary Upwelling Systems (EBUS), the subpolar North Atlantic and the Arctic Ocean. By looking at the contrasting features of these ecosystems and how they affect the marine budget of N2O, I aim to highlight the need of new approaches and priority areas for research on GHGs such as N2O.

Description: The Arctic Ocean is particularly sensitive to climate change. Its ecosystem structure and function are prone to be disturbed by fast warming and massive retreat of sea-ice, which in turn, might result in feedbacks on climate. Moreover, such drastic changes are expected to influence the meridional fluxes of heat, freshwater and biogeochemical tracers between subpolar areas and the Arctic. As the third most important greenhouse gas and major ozone-depleting substance in the stratosphere, nitrous oxide (N2O) is a crucial gas to study in order to assess the ocean’s role in the production and exchange of climate-relevant compounds to the atmosphere. Between 2018 and 2019 we conducted ship-based surveys to elucidate the source-sink dynamics of N2O in the subpolar-polar North Atlantic. Based on results from those campaigns, we show the distribution and spatial variability of surface N2O, which ranged from moderate supersaturation (positive sea-air fluxes) in ice-free subpolar areas to unusually strong undersaturation (negative sea-air fluxes) in partially or fully ice-covered areas. We also present a comprehensive overview of the water column distribution of N2O in the region, and by combining this data with hydrographic and chemical (O2 and inorganic nutrients) information, we trace back the origin of the dominant water masses so as to illustrate the connectivity between the Fram Strait and the Nordic Seas off southeast Greenland. This analysis is used to discuss how the meridional water mass exchange in the region influences the balance of local vs. remote N2O production and its spatial variability. Furthermore, we use the results from collocated molecular analyses (functional gene markers) to infer the occurrence and abundances of the main microbial communities responsible for the cycling of N2O. This contribution is relevant for assessments of expected changes in trace gas emissions with further climate-driven changes in the Arctic Ocean.

Description: The development of overpressure in continental margins is typically evaluated with hydrogeological models. Such approaches are used to both identify fluid flow patterns and to evaluate the development of high pore pressures within layers with particular physical properties that may promote slope instability. In some instances, these models are defined with sediment properties based on facies characterization and proxy values of porosity, permeability or compressibility are derived from the existing literature as direct measurements are rarely available. This study uses finite-element models to quantify the differences in computed overpressure generated by fine-grained hemipelagic sediments from Gulf of Cadiz, offshore Martinique and Gulf of Mexico, and their consequences in terms of submarine slope stability. By comparing our simulation results with in-situ pore pressure data measured in the Gulf of Mexico, we demonstrated that physical properties measured on volcanic-influenced hemipelagic sediments underestimate the computed stability of a submarine slope. Physical properties measured on sediments from the study area are key to improving the reliability and accuracy of overpressure models, and when that information is not available literature data from samples with similar lithologies, composition and depositional settings enable better assessment of the overpressure role as a pre-conditioning factor in submarine landslide initiation.

Description: 21.2.2020 – 2.3.2020, La-Seyne-sur-Mer(Frankreich) - Malaga (Spanien)

Description: Vermessung des Meeresbodens - ein deutscher Beitragzur Vervollständigung der Weltkarte bis2030 / Bathymetric mapping of the seafloor - a German contribution to completing the map by 2030. 19.12.2019 - 14.01.2020 von Mindelo (Cabo Verde) - nach Bridgetown (Barbados)

Description: Submarine slope failures pose a direct threat to seafloor installations and coastal communities. Here, we evaluate the influence of free gas on the soil’s shear strength and submarine slope failures in areas with gassy soils based on an extensive literature review. We identify two potential destabilization mechanisms: gas bubbles in the pore space lead to a reduced shear strength of the soil and/or gas induces excess pore pressures that consequently reduce the effective stress in the soil. Our evaluation of the reported mechanical and hydraulic behaviour of gassy sediments indicates that the unfavourable impact of entrapped gas on a soil’s shearing resistance is not sufficient to trigger large scale slope failures. Liquefaction failure due to high gas pressures is, however, a viable scenario in coarse-grained soils. Transferring the gas influence on the soil mechanical behaviour to constitutive models is identified as the most important prerequisite for a successful future analysis of slope stability.

Description: Ponta Delgada - Las Palmas, 06.03. - 09.03.2020

Description: Ciona intestinalis is within the group of taxa that are spreading globally and is one of the most thriving invasive marine species, known to depress both species richness and abundance at a local scale in distinct geographic areas. It is a dominant biofouling agent, associated with the decreasing economic incomes from aquaculture operations around the world. Ciona intestinalis was first observed in 2007 at Straumsvík in Southwest Iceland. The present study was designed to provide general information on its current distribution across Icelandic harbours. The species was found only on the SW coast of Iceland, in dense aggregations reaching up to 876 ind/m2 in all harbours from Grindavík to Akranes. The current work provides information that can be used to track the dispersal of C. intestinalis populations along the Icelandic coast and for the development of effective management decisions.

Description: The Tuaheni Landslide Complex (TLC) is characterised by areas of compression upslope and extension downslope. It has been thought to consist of a stack of two genetically linked landslide units identified on seismic data. We use 3D seismic reflection, bathymetry data, and IODP core U1517C (Expedition 372), to understand the internal structures, deformation mechanisms and depositional processes of the TLC deposits. Unit II and Unit III of U1517C correspond to the two chaotic units in 3D seismic data. In the core, Unit II shows deformation whereas Unit III appears more like an in situ sequence. Variance attribute analysis shows that Unit II is split in lobes around a coherent stratified central ridge and is bounded by scarps. By contrast, we find that Unit III is continuous beneath the central ridge and has an upslope geometry that we interpret as a channellevee system. Both units show evidence of lateral spreading due to the presence of the Tuaheni Canyon removing support from the toe. Our results suggest that Unit II and Unit III are not genetically linked, that they are separated substantially in time and they had different emplacement mechanisms, but fail under similar circumstances.

Description: The marine environment encompasses a huge biological diversity and can be considered as an underexplored location for prospecting bioactive molecules. In this review, the current state of art about antimicrobial molecules from marine bacteria has been summarized considering the main phylum and sources evolved in a marine environment. Considering the last two decades, we have found as most studied group of bacteria producers of substances with antimicrobial activity is the Firmicutes phylum, in particular strains of the Bacillus genus. The reason for that can be attributed to the difficult cultivation of typical Actinobacteria from a marine sediment, whose members are the major producers of antimicrobial substances in land environments. However, a reversed trend has been observed in recent years with an increasing number of reports settling on Actinobacteria. Great diversity of chemical structures have been identified, such as fijimicyns and lynamicyns from Actinomycetes and macrolactins produced by Bacillus.

Description: Ponta Delgada - Las Palmas, 10.03. - 16.03.2020

Description: 09.03.-15.03.2020

Description: This contribution presents the detailed responses to the peer-review of Froese et al. (2019) “Estimating stock status from relative abundance and resilience” (ICES J. Mar. Sci. 2019) which outlined a method called “AMSY” for inferring biomass trends for stocks for which only catch-per-unit-effort and limited ancillary (‘priors’) data are available. The responses emphasize that the required priors are legitimate and straightforward to obtain, thus, making AMSY a method of choice in data-sparse situations. This is also a good example of the role of peer-review in validating and improving science.

Description: Ponta Delgada - Las Palmas, 17.03. - 23.03.2020

Description: Submarine landslides occur on continental margins globally and can have devastating consequences for marine habitats, offshore infrastructure and coastal communities due to potential tsunamigenesis. Therefore, understanding landslide magnitude and distribution is central to marine and coastal hazard planning. We present the first submarine landslide database for the eastern margin of New Zealand comprising 〉2200 landslides occurring in water depths from c. 300–4000 m. Landslides are more prevalent and, on average, larger on the active margin compared with the passive margin. We attribute higher concentrations of landslides on the active margin to tectonic processes including uplift and oversteepening, faulting and seamount subduction. Submarine landslide scars are concentrated around canyon systems and close to canyon thalwegs. This suggests that not only does mass wasting play a major role in canyon evolution, but also that canyon-forming processes may provide preconditioning factors for slope failure. Results of this study offer unique insights into the spatial distribution, magnitude and morphology of submarine landslides across different geological settings, providing a better understanding of the causative factors for mass wasting in New Zealand and around the world.

Description: Nitrogen fixers, or diazotrophs, play a key role in the carbon and nitrogen cycle of the world oceans, but the controlling mechanisms are not comprehensively understood yet. The present study compares two paradigms on the ecological niche of diazotrophs in an Earth System Model (ESM). In our standard model configuration, which is representative for most of the state-of-the-art pelagic ecosystem models, diazotrophs take advantage of zooplankton featuring a lower food preference for diazotrophs than for ordinary phytoplankton. We compare this paradigm with the idea that diazotrophs are more competitive under oligotrophic conditions, characterized by low (dissolved, particulate, organic and inorganic) phosphorous availability. Both paradigms are supported by observational evidence and lead to a similar good agreement to the most recent and advanced observation-based nitrogen fixation estimate in our ESM framework. Further, we illustrate that the similarity between the two paradigms breaks in a RCP 8.5 anthropogenic emission scenario. We conclude that a more advanced understanding of the ecological niche of diazotrophs is mandatory for assessing the cycling of essential nutrients, especially under changing environmental conditions. Our results call for more in-situ measurements of cyanobacteria biomass if major controls of nitrogen fixation in the oceans are to be dissected.

Description: 23.03.-26.03.2020

Description: Ponta Delgada - Las Palmas, 24. - 30.03.2020

Description: Interest in microalgae-derived products is growing, mostly due to their unique characteristics and range of industrial applications. To obtain different products, one must employ specific pretreatments that retain the properties of the biologically active compounds extracted from microalgae biomass; thus, new extraction techniques require frequent upgrades. Due to increased interest in economically viable and ecologically friendly processes, new extraction methods that can be incorporated into microalgae biorefinery systems have become the main focus of research. Therefore, this review aims to address the potential applications, future prospects, and economic scenario of the new physicochemical treatments used in the extraction of bioactive microalgae compounds.

Description: Long-chain polyunsaturated fatty acids (LC-PUFAs) especially ω-3 fatty acids provide significant health benefits for human beings. However, ω-3 LC-PUFAs cannot be synthesized de novo in mammals. Traditionally, ω-3 LC-PUFAs are extracted from marine fish, and their production depends on sea fishing, which has not met ever-increasing global demand. To address the challenges, innovative cellular engineering strategies need to be developed. In nature, many fungi and microalgae are rich in ω-3 LC-PUFAs, representing promising sources of ω-3 LC-PUFAs. The latest progress in developing new cellular engineering strategies toward sustainable ω-3 LC-PUFAs production using fungi and microalga has demonstrated that they can to some extent address the supply shortage. In this review, we critically summarize the recent progress in enhancing the productivity in various ω-3 LC-PUFAs-producing organisms, as well as the latest efforts of biosynthesizing PUFAs in heterogenous biosystems. In addition, we also provide future perspectives in developing genetic toolkits for LC-PUFAs producing microbes so that cut-edging biotechnology such as gene stacking and genome editing can be further applied to increase the productivity of ω-3 LC-PUFAs.

Description: Factors affecting carotenoid extraction with edible oils were examined using edible brown seaweed, Sargassum horneri, as main sample. The results indicate that drying was essential to extract fucoxanthin (Fx) from S. horneri and physical (boiling) and chemical (acid/alkali) pretreatment of the wet sample increased the extraction rate of Fx. Additionally, more Fx was found from the dried S. horneri powder with a smaller particle size. The extraction rate of Fx is affected by the extraction temperature and time, showing that the effective extraction would be obtained at 50 °C within 12 hr extraction. Among the oils used, short-chain (C4 and C6) triacylglycerol (TAG) (SCT) and medium-chain (C8) TAG (MCT) could extract more Fx from S. horneri and more β-carotene and lutein from spinach and olive leaves. The relatively lower viscosity of SCT and MCT would be the most likely reason for the higher extraction rates of both TAGs.

Description: Sargassum fusiforme polysaccharides, acidic water-soluble polysaccharides extract from Sargassum fusiforme, are mainly composed of alginic acid, fucoidan and laminaran. Alginic acid is carboxyl-containing polysaccharide formed by joining β-D-mannuronic acid and α-L-guluronic acid through β-(1→4)/α-(1→4) glycosidic bond. Fucoidan, a natural water-soluble sulfated heteropolysaccharide with fucose and sulfuric acid groups as the core structure, is mainly linked by L-fucose through α-(1→3) glycosidic bond and has the strongest biological activity. Laminaran is mainly composed of β-D-glucose through β-(1→3) glycosidic bond linkage. Sargassum fusiforme polysaccharides have a variety of pharmacological activities, including antioxidant, anti-tumor, promoting immunity, anti-aging, prompting bone growth, lowering blood glucose, anti-coagulation, anti-virus, anti-bacteria, anti-fatigue, promoting growth and development, and skin protection. These activities are closely related to the functions of fucoidan in Sargassum fusiforme polysaccharides, which fucoidan is able to strengthen immune system and antioxidation in human body. In this review, the composition, the isolation and purification, and the biological activities of Sargassum fusiforme polysaccharides are discussed and can bereference for further study.

Description: The 2010 Deepwater Horizon disaster remains the largest single accidental release of oil and gas into the ocean. During the 87-day release, scientists used oceanographic tools to collect wellhead oil and gas samples, interrogate microbial community shifts and activities, and track the chemical composition of dissolved oil in the ocean’s interior. In the decade since the disaster, field and laboratory investigations studied the physics and chemistry of irrupted oil and gas at high pressure and low temperature, the role of chemical dispersants in oil composition and microbial hydrocarbon degradation, and the impact of combined oil, gas and dispersants on the flora and fauna of coastal and deep-sea environments. The multi-faceted, multidisciplinary scientific response to the released oil, gas and dispersants culminated in a better understanding of the environmental factors that influence the short-term and long-term fate and transport of oil in marine settings. In this Review, we summarize the unique aspects of the Deepwater Horizon release and highlight the advances in oil chemistry and microbiology that resulted from novel applications of emerging technologies. We end with an outlook on the applicability of these findings to possible oil releases in future deep-sea drilling locations and newly-opened high-latitude shipping lanes.

Description: The interseismic slip distribution in the Marmara fault system represents both observational and modelling challenges. The observational challenge is obvious: the faults are under water and to understand their interseismic behavior (creeping versus locked) requires expensive and logistically difficult underwater geodetic measurements, alongside those on land. Up to now, two such underwater studies have been conducted and they suggest that the segment to the south of Istanbul zone (so-called Central segment) is locked while some creep is probably going on along the neighboring segment to the west. Given these two important findings, the slip distribution problem is still non-trivial due to the fact that our experiments so far demonstrate that the block-based slip inversions and those that only consider a single fault (with the same geometry as one of the boundaries of the blocks) give significantly different results. In this study we approach the problem using three methodologies: block models with spatially non-varying strains within individual blocks, a boundary element approach and a continuum kinematic approach. Although the block model does not give spatially varying strains, the inversion results from the block model can be used as an input to model strain field in the vicinity of the fault. We construct a formulation to correlate the results from these with the strain rates obtained using focal mechanism summations.

Description: Compound-specific radiocarbon (14C) dating often requires working with small samples of 〈 100 µg carbon (µgC). This makes the radiocarbon dates of biomarker compounds very sensitive to biases caused by extraneous carbon of unknown composition, a procedural blank, which is introduced to the samples during the steps necessary to prepare a sample for radiocarbon analysis by accelerator mass spectrometry (i.e., isolating single compounds from a heterogeneous mixture, combustion, gas purification and graphitization). Reporting accurate radiocarbon dates thus requires a correction for the procedural blank. We present our approach to assess the fraction modern carbon (F14C) and the mass of the procedural blanks introduced during the preparation procedures of lipid biomarkers (i.e. n-alkanoic acids) and lignin phenols. We isolated differently sized aliquots (6–151 µgC) of n-alkanoic acids and lignin phenols obtained from standard materials with known F14C values. Each compound class was extracted from two standard materials (one fossil, one modern) and purified using the same procedures as for natural samples of unknown F14C. There is an inverse linear relationship between the measured F14C values of the processed aliquots and their mass, which suggests constant contamination during processing of individual samples. We use Bayesian methods to fit linear regression lines between F14C and 1/mass for the fossil and modern standards. The intersection points of these lines are used to infer F14Cblank and mblank and their associated uncertainties. We estimate 4.88 ± 0.69 μgC of procedural blank with F14C of 0.714 ± 0.077 for n-alkanoic acids, and 0.90 ± 0.23 μgC of procedural blank with F14C of 0.813 ± 0.155 for lignin phenols. These F14Cblank and mblank can be used to correct AMS results of lipid and lignin samples by isotopic mass balance. This method may serve as a standardized procedure for blank assessment in small-scale radiocarbon analysis.

Description: Numerical simulation is important for practical and efficient assessment of hydrate reservoir formation stability and gas production potential. The history-matching simulation of hydrate gas production tests is complex due to coupled THM (thermo-hydro-mechanical) phenomena. The well log data from the Eastern Nankai Trough methane gas production site suggest vertically heterogeneous field properties. In the previous numerical simulation research of this site, the heterogeneous geological data were homogenized by adopting the standard mean-field theory, which can potentially lead to inaccurate simulation results due to the mesh size effect. By introducing new upscaling techniques for the permeability profiles and mechanical responses, a revised homogenization approach is proposed to improve the coupled THM simulation accuracy. In this study, seven gas production simulations of a hypothetical reservoir, six simulations of the Eastern Nankai Trough gas production test, and four simulations of the randomly generated site formation production test with different mesh sizes and different homogenization approaches were carried out to demonstrate that the proposed upscaling techniques can improve the accuracy of the simulation results with a coarse mesh model. This work, in turn, provides researchers and field engineers a much quicker way to assess the complex geomechanical behaviors of hydrate gas production site.

Description: Die Geowissenschaft betrachtet die Erde und damit auch die Entstehung von Tiefsee-Ebenen und untermeerischen Hochgebirgen aus einem anderen Blickwinkel. Um diese Herangehensweise nachzuvollziehen, hilft es, sich die Erde ohne Wasser vorzustellen. Wie die übrigen inneren Planeten unseres Sonnensystems, Merkur, Venus und Mars, ist auch die Erde von einer festen äußeren Schale, der sogenannten Erdkruste, umgeben. Dabei ist unsere Erde jedoch einzigartig darin, dass hier nicht nur eine, sondern zwei unterschiedliche Krustentypen auftreten, die kontinentale Kruste auf der einen und die ozeanische Kruste auf der anderen Seite.

Description: Nitrous oxide is an important greenhouse gas and there is a need for sensitive techniques to study its distribution in the environment at concentrations near equilibrium with the atmosphere (9.6 nM in water at 20 °C). Here we present an electrochemical sensor that can quantify N2O in the nanomolar range. The sensor principle relies on a front guard cathode placed in front of the measuring cathode. This cathode is used to periodically block the flux of N2O towards the measuring cathode, thereby creating an amplitude in the signal. This signal amplitude is unaffected by drift in the baseline current and can be read at very high resolution, resulting in a sensitivity of 2 nM N2O for newly constructed sensors. Interference from oxygen is prevented by placing the front guard cathode in oxygen-consuming electrolyte. The sensor was field tested by measuring an N2O profile to a depth of 120 m in the oxygen minimum zone of the Eastern Tropical North Pacific Ocean (ETNP) off the coast of Mexico.

Description: Wave-Glider-Nutzlast-Modul (1) mit- einem Grundträger (11), wobei dieser Grundträger (11) in eine Wave-Glider-Nutzlast-Modul-Aufnahme in einem Wave-Glider einsetzbar ist;- wenigstens einer Geräte-Aufnahme (12) für wissenschaftliche Geräte und/oder Messgeräte und/oder Sensoren befestigt in dem Grundträger (11), wobei die wissenschaftlichen Geräte und/oder Messgeräte und/oder Sensoren auf der Geräte-Aufnahme (12) wenigstens teilweise oder vollständig innerhalb des Grundträgers (11) anordenbar sind; wobei- der Grundträger (11) U-förmig ausgebildet ist und- die Geräte-Aufnahme (12) als Platte mit Rasterbohrungen zur Aufnahme von Adaptern und/oder Schraubverbindungen und/oder Schrauben und/oder Kopplungsmitteln ausgebildet ist.

Description: It is generally assumed that seismic activity at volcanoes is closely connected to degassing processes. Intuitively, one would therefore expect a good correlation between degassing rates and seismic amplitude. However, both examples and counterexamples of such a correlation exist. In this study on Villarrica volcano (Chile), we pursued a different approach to relate gas flux and volcanic seismicity using 3 months of SO$_2$ flux rate measurements and 12 days of seismic recordings from early 2012.〈br /> We analyzed the statistical distributions of interevent times between transient seismic waveforms commonly associated with explosions and between peaks in the degassing time series.〈br /> Both event types showed a periodic recurrence with a mode of 20-25 s and around 1 h for transients and degassing, respectively. The normalized interevent times were fitted by almost identical log-normal distributions. Given the actually very different time scales, this similarity potentially indicates a scale-invariant phenomenon. We could reproduce these empirical findings by modelling the occurrence of transients as a renewal process from which the degassing events were derived recursively with increasing probability since the previous degassing event. In this model, the seismic transients could be either produced by degassing processes within the conduit or by gas release at the lava lake surface while the longer intervals of the degassing events may be explained by accumulation of gas either in the magma column or in the juvenile gas plume.〈br /> Additionally, we analyzed volcano-tectonic events, which behaved very differently from the transients. They showed the clustered occurrence of tectonic earthquakes.

Description: Almost three quarters of known volcanic activity on Earth occurs in underwater locations. The presence of active hydrothermal vent fields in such environments is a potential natural hazard for the environment, the society, and the economy. Despite its importance for risk assessment and risk mitigation, monitoring of the activity is impeded by the remoteness and the extreme conditions of underwater volcanoes. The large difference of population present on Santorini between the winter and summer seasons, all within a partially enclosed system, make the Santorini-Kolumbo volcanic field, an ideal place for detailed exploration. In 2017, GEOMAR in collaboration with the National and Kapodistrian University of Athens (mission: POS-510 ANYDROS), used an Autonomous Underwater Vehicle (AUV) to map the NE–trending Santorini–Kolumbo line, where it also collected CTD data. Here we present the preliminary results from the 15-hour survey held on the 25th March 2017, during the POS-510 expedition targeting the vent field which is located in the North Basin of Santorini Caldera. Detailed CTD 3D profiles have been reconstructed from the raw data of Santorini’s vent field. An anomaly emerges at the depth of 350 m in the Conductivity and Salinity depth profiles, as the CTD sensor is placed directly above the vent sources. Anomalies were evident in the 3D maps reconstructed, showing for the first time a rather weak, but underlying hydrothermal vent activity at various locations. As the present results are the first ones produced from this expedition, further investigation is required incorporating the full dataset. Based on those results, the impact of developing appropriate mechanisms and policies to avoid the associated natural hazard is expected to be immense.

Description: The San Pedro basin (SPB) is located at the south-eastern margin of Hispaniola Island (Dominican Republic and Haiti). It is the largest offshore basin of the Dominican Republic with an extension of 6000 km2. The basin has a maximum water depth of 1600 m and is positioned to the rear of the Muertos Thrust Belt (MTB). The SPB bounds to the West by The Azua basin which has a proven petroleum system and small oil production has been recovered from the Maleno and Higuerito fields. While in the scientific literature the SPB and the Azua basins have been considered as disconnected sedimentary systems, our current study suggests both are shared a common tectonic evolution and therefore the presence of an untested petroleum system in the SPB can be expected. We have carried out a detailed review and synthesis of the onshore systematic geological mapping (SYSMIN I & II Programs) together with the integration of a large volume of sub-surface geophysical data. This includes analysis of 60 exploration wells provided by Banco Nacional de Datos de Hidrocarburos (BNDH) of the Dominican Republic, processing of new 2D multi-channel seismic data from the Spanish Research Project NORCARIBE, re-processing of legacy seismic profiles and interpretation of gravity and magnetic data. Our results led us to propose a new evolution model for the SPB. Basement of both basins consists of Cretaceous sedimentary and volcanic rocks of intra- and back-arc settings. A change in the stress regime in the Campanian led to partial inversion of the basement units favouring the deposition of two main sequences of Campanian to Maastrichtian and Palaeocene? -Eocene age in a submarine foreland setting. Due to collision between the Carbonate Bahamas Province and Hispaniola in middle Eocene, compressional stresses were transferred to the south where Cretaceous and Paleogene sediments were deformed forming the current configuration of MTB and generating a new accommodation space where SPB was developed since Upper Eocene / Oligocene until Present. While the Azua basin was finally exhumed after Miocene/Pliocene, most of SPB continued as an actively subsiding basin. This new model has allowed identification of the main elements of the petroleum system in the SPB basin: a mature Upper Cretaceous source rock and Oligocene to Miocene carbonate and clastic reservoirs interbedded with sealing shales and marls. Main traps (structural and stratigraphic) are of Oligocene to Miocene age and their formation seems to be synchronous to oil generation. While main elements of the petroleum system seem to be present in the basin, timing is a key issue that must be addressed and assessed in any future exploration in the basin.

Description: Geologische Prozesse und dabei entweichende wässrige Lösungen sind in vielen Bereichen der Ozeane für die Entstehung von Oasen in der Tiefsee verantwortlich. Das Leben dort ist an die spezifischen Eigenschaften der auftretenden Gesteine und chemischen Lösungen angepasst und unterscheidet sich daher erheblich von dem der normalen Tiefsee-Ebenen oder Seeberge. Zu den außergewöhnlichen Lebensräumen gehören die sogenannten Schwarzen Raucher, die sich in der Umgebung vulkanisch aktiver Bereiche bilden und an denen heiße (hydrothermale) Lösungen austreten. Dazu gehören aber auch Austrittsstellen von Gasen und Lösungen mit geringerer Temperatur, die sich häufig in den Sehelfgebieten der Kontinente oder in sehr stark sedimentierten Bereichen der Tiefsee finden. Diese werden unter dem Begriff „Cold Seeps" (,.kalte Sickerstellen") zusammengefasst, obwohl diese Stellen sehr unterschiedlich sein können.

Description: Landslide is one of the dangerous types of natural hazards. This phenomenon causes damages in many countries every year. A detailed landslide hazard assessment is necessary to reduce these damages. This research aims to map the landslide susceptibility zoning (LSZ) using the fuzzy logic method and GIS in the Sorkhab basin as a part of the Zagros fold and thrust belt (FTB), northwestern Iran. All slide types were recorded in fieldwork as landslide inventory. Based on the results, four types, i.e., debris slide, earth slide, and rock fall and complex of landslides, was identified in the region. Then, the effect of each landslide contributing factor including topographical elevation heights, slope classes, aspect classes, geological units, proximity to faults, land covers, rainfall classes, and proximity to streams was constructed in GIS and subsequently normalized using fuzzy membership functions. Finally, by combining all standardized layers using the fuzzy gamma operator, a final map of LSZ was produced. The results showed that a 0.9 fuzzy gamma operator has a high accuracy for the LSZ map in the study area. Besides, the accuracy of the LSZ map revealed a strong relationship (R2) between susceptibility classes, and landslide inventory was calculated using a scatter plot equal to 0.79. Hence, the method represented an appropriate accuracy in predicting the landslide susceptibility in the study area.

Description: 05.07.-12.07.2020

Description: We present a new set of global and local sea‐level projections at example tide gauge locations under the RCP2.6, RCP4.5 and RCP8.5 emissions scenarios. Compared to the CMIP5‐based sea‐level projections presented in IPCC AR5, we introduce a number of methodological innovations, including: (i) more comprehensive treatment of uncertainties; (ii) direct traceability between global and local projections; (iii) exploratory extended projections to 2300 based on emulation of individual CMIP5 models. Combining the projections with observed tide gauge records, we explore the contribution to total variance that arises from sea‐level variability, different emissions scenarios and model uncertainty. For the period out to 2300 we further breakdown the model uncertainty by sea‐level component and consider the dependence on geographic location, time horizon and emissions scenario. Our analysis highlights the importance of variability for sea‐level change in the coming decades and the potential value of annual‐to‐decadal predictions of local sea‐level change. Projections to 2300 show a substantial degree of committed sea‐level rise under all emissions scenarios considered and highlights the reduced future risk associated with RCP2.6 and RCP4.5 compared to RCP8.5. Tide gauge locations can show large (〉 50%) departures from the global average, in some cases even reversing the sign of the change. While uncertainty in projections of the future Antarctic ice dynamic response tends to dominate post‐2100, we see a substantial differences in the breakdown of model variance as a function of location, timescale and emissions scenario.

Description: The ability of consumers to convert ingested carbon into growth is critical for secondary production and trophic transfer. We conducted laboratory experiments to investigate the effect of different prey and concentration on the ingestion rate (IR), egg production rate (EPR) and egg production efficiency (EPE) of the ubiquitous copepod, Acartia tonsa. Experiments were run at several prey concentrations, ranging from 11 to 1132 μgC L–1, of the diatom Thalassiosira weissflogii, the autotrophic dinoflagellate Prorocentrum minimum, the heterotrophic dinoflagellate Oxyrrhis sp., the flagellate Dunaliella tertiolecta, and the bacterivorous scuticociliate Uronema sp. IR increased curvilinearly with concentration for all diets. EPR also increased curvilinearly with increasing food concentration similar to IR, with the exception of the flagellate diet, for which EPR decreased linearly with food concentration. EPR ranked as T. weissflogii 〉 P. minimum 〉 Oxyrrhis sp. = Uronema sp. 〉 D. tertiolecta. IR and EPR were linearly related, except for flagellate diet. The slope of the carbon-based relationship between IR and EPR, the egg production efficiency (EPE), was highest for the diatom (77.5%) and lowest for the scuticociliate (4.2%). Egg production was not correlated to ingestion of the flagellate offered to A. tonsa. We conclude that of the five prey species, the diatom T. weissflogii is the best prey to promote A. tonsa reproduction, to optimize trophic transfer efficiency, and to increase mass cultivation of this species.

Description: Young extension centers in the proximity of back-rolling subduction zones constitute an ideal natural laboratory to investigate the early evolutional stages of back-arc basins. We present a catalog of 711 microearthquakes recorded during a 32-days deployment of ocean bottom seismometers at the southern part of the Fonualei Rift and Spreading Center in the Lau Basin. The majority of epicenters are concentrated along the central region of the axial valley and about 450 events are associated with an earthquake swarm that is likely linked to magmatic diking in the crust. The earthquake swarm location coincides with several volcanic mounds on the seafloor, covered by fresh lava flows. The spatial distribution of microearthquakes and the maximum depth of brittle faulting is more similar to oceanic spreading centers than to continental rift zones. We interpret our results in conjunction with refraction seismic data and magnetic anomaly data from the same region. In combing all findings, we conclude that the southern Fonualei Rift and Spreading Center is currently in transition from a rifting dominated mode of extension to a seafloor spreading dominated mode of extension. This transition may be associated with fundamental changes in the underlying mechanisms of melt generation leading to a diminishing influence of hydrous flux melting and the growing influence of decompression melting at this back-arc extension zone.

Description: Maria S. Merian - MSM94 - SNAP Westlicher Subpolarer Atlantik 02.08.2020 - 06.09.2020

Description: Introduction: The marine environment is a very promising resource for natural product research, with many of these reaching the market as new drugs, especially in the field of cancer therapy as well as the drug discovery pipeline for new antimicrobials. Exploitation for bioactive marine compounds with unique structures and novel bioactivity such as the isoquinoline alkaloid; trabectedin, the polyether macrolide; halichondrin B, and the peptide; dolastatin 10, requires the use of analytical techniques, which can generate unbiased, quantitative, and qualitative data to benefit the biodiscovery process. Metabolomics has shown to bridge this understanding and facilitate the development of new potential drugs from marine sources and particularly their microbial symbionts. Areas covered: In this review, articles on applied secondary metabolomics ranging from 1990–2018 as well as to the last quarter of 2019 were probed to investigate the impact of metabolomics on drug discovery for new antibiotics and cancer treatment. Expert opinion: The current literature review highlighted the effectiveness of metabolomics in the study of targeting biologically active secondary metabolites from marine sources for optimized discovery of potential new natural products to be made accessible to a R&D pipeline.

Description: 3rd November to 17th November 2020, Kiel - Kiel

Description: Ice flow models of the Antarctic ice sheet are commonly used to simulate its future evolution in response to different climate scenarios and assess the mass loss that would contribute to future sea level rise. However, there is currently no consensus on estimates of the future mass balance of the ice sheet, primarily because of differences in the representation of physical processes, forcings employed and initial states of ice sheet models. This study presents results from ice flow model simulations from 13 international groups focusing on the evolution of the Antarctic ice sheet during the period 2015–2100 as part of the Ice Sheet Model Intercomparison for CMIP6 (ISMIP6). They are forced with outputs from a subset of models from the Coupled Model Intercomparison Project Phase 5 (CMIP5), representative of the spread in climate model results. Simulations of the Antarctic ice sheet contribution to sea level rise in response to increased warming during this period varies between −7.8 and 30.0 cm of sea level equivalent (SLE) under Representative Concentration Pathway (RCP) 8.5 scenario forcing. These numbers are relative to a control experiment with constant climate conditions and should therefore be added to the mass loss contribution under climate conditions similar to present-day conditions over the same period. The simulated evolution of the West Antarctic ice sheet varies widely among models, with an overall mass loss, up to 18.0 cm SLE, in response to changes in oceanic conditions. East Antarctica mass change varies between −6.1 and 8.3 cm SLE in the simulations, with a significant increase in surface mass balance outweighing the increased ice discharge under most RCP 8.5 scenario forcings. The inclusion of ice shelf collapse, here assumed to be caused by large amounts of liquid water ponding at the surface of ice shelves, yields an additional simulated mass loss of 28 mm compared to simulations without ice shelf collapse. The largest sources of uncertainty come from the climate forcing, the ocean-induced melt rates, the calibration of these melt rates based on oceanic conditions taken outside of ice shelf cavities and the ice sheet dynamic response to these oceanic changes. Results under RCP 2.6 scenario based on two CMIP5 climate models show an additional mass loss of 0 and 3 cm of SLE on average compared to simulations done under present-day conditions for the two CMIP5 forcings used and display limited mass gain in East Antarctica.

Description: Due to the remote, seafloor environment in which seafloor massive sulphide deposits form, the assessment of the deposit volume and geometry through methods such as drilling are difficult and expensive. To aid in the evaluation of the resource potential of seafloor massive sulphide deposits, the threedimensional surface geometry inversion of magnetic data collected near the seafloor using autonomous underwater vehicles can further enhance geologic models produced from sparse drilling. This study applies the surface geometry inversion method to magnetic data collected above the active mound at the Trans-Atlantic Geotraverse hydrothermal vent field, creating a 3D wireframe model of the deposit and the hydrothermally altered basalt below it.

Description: Geochemical patterns in the environment are always the result of certain processes. Therefore, it is essential to decipher a process to properly evaluate the environmental role and potential of chemical elements/compounds. This allows the distinction between natural and anthropogenic influence on elemental concentrations. However, if the compositional nature of geochemical data is neglected, erroneous or misleading conclusions regarding the processes involved are probable. In this study the reconstruction of depositional environments and processes through the Holocene in two sediment cores obtained from submerged sinkholes located on the island of Mljet, Croatia, was performed by taking into account the compositional nature of geochemical, mineralogical and grainsize data. Problems involving compositional data are always multivariate; for example, the concentration of a single element does not carry any interpretative information, as only the ratios between elements do. This has led to the discovery of a large number of geochemical proxies based on elemental ratios, which describe certain environmental conditions and processes involved. Nevertheless, some proxies have been found to be restricted to only some specific environments, thus preventing them from being used in general; therefore, some kind of relation between different proxies is necessary to obtain final conclusions. However, when using simple elemental ratios, those correlations cannot be obtained due to the nature of compositional data. With a sequential binary partition of a compositional vector, orthonormal log ratio (olr) coordinates (proxies) can be constructed. When based on expert knowledge, those proxies fully acknowledge the geochemical properties of the chosen elements with one major difference - that the correlation between newly obtained variables is mathematically well grounded. As a result, the final conclusion is more accurate. In this research, geochemical proxies obtained as a representation in olr coordinates of the elements that are enriched compared to the local soil were used to perform principal component analyses. It helped to unravel the evolution of sedimentary environments. Mineralogical (XRD and heavy mineral data) and grain size analyses supported the conclusions obtained based solely on geochemical data. Furthermore, data analysis suggests that the proxies for redox conditions described in the literature should be used with caution, as their use is somewhat limited.

Description: 31.8.-6.9.2020

Description: 7.9.-13.9.2020

Description: 17.-23.8.2020

Description: 14.9.-20.9.2020

Description: An in-depth understanding of dissolution and precipitation of minerals in porous and fractured porous media and the complex feedback on the transport of fluids is essential for various subsurface applications. In this context, we developed a novel non-destructive “lab-on-chip” approach for quantitative in situ assessments of mineralogical changes in porous media. Our experimental approach involves a microfluidic flow-through reactor of reactive homogeneous and heterogeneous (fractured) porous media coupled with high-resolution imaging. Here, the reactive medium consists of compacted celestine grains seeded in a reservoir within the microfluidic chip. This medium reacts with a barium chloride solution injected into the microreactor at a constant flow rate, leading to the dissolution of celestine and growth of barite. Various seeding processes of the mineral grains allow the creation of homogeneous reactive porous media or the introduction of large heterogeneities such as fractures. Hence, our approach enables high-resolution investigations of reactive transport in fractured porous media. The use of confocal Raman spectroscopic techniques enables the spatio-temporal visualization of the mineral transformation at the pore-scale in two- and three-dimensions. Moreover, advanced pore scale modelling correlates the hydrological heterogeneities to the geochemical observations in the micro-reactor, which explains the observed discrepancies between homogeneous and heterogeneous reactive media. Eventually, the proposed methodology can be applied to other chemical systems to provide new insights into hydro-geochemical coupling in porous and fractured porous media as well as high-fidelity datasets to benchmark reactive transport codes that are currently under development.

Description: Current activities at the GEOMAR Helmholtz Centre for Ocean Research in Kiel and the Alfred Wegener Institute, Helmholtz Centre for Polar and Marine Research (AWI) in Bremerhaven, Germany, include developing two new versions of high-resolution coupled climate models. Both climate models successfully use OpenIFS, a portable version of ECMWF’s Integrated Forecasting System (IFS) for use at universities and research institutes. The experience gained in using OpenIFS for climate modelling can in turn provide insights that will help ECMWF to further develop the IFS.

Description: Many climate models strongly underestimate the two most important atmospheric feedbacks operating in El Niño/Southern Oscillation (ENSO), the positive (amplifying) zonal surface wind feedback and negative (damping) surface-heat flux feedback (hereafter ENSO atmospheric feedbacks, EAF), hampering realistic representation of ENSO dynamics in these models. Here we show that the atmospheric components of climate models participating in the 5th phase of the Coupled Model Intercomparison Project (CMIP5) when forced by observed sea surface temperatures (SST), already underestimate EAF on average by 23%, but less than their coupled counterparts (on average by 54%). There is a pronounced tendency of atmosphere models to simulate stronger EAF, when they exhibit a stronger mean deep convection and enhanced cloud cover over the western equatorial Pacific (WEP), indicative of a stronger rising branch of the Pacific Walker Circulation (PWC). Further, differences in the mean deep convection over the WEP between the coupled and uncoupled models explain a large part of the differences in EAF, with the deep convection in the coupled models strongly depending on the equatorial Pacific SST bias. Experiments with a single atmosphere model support the relation between the equatorial Pacific atmospheric mean state, the SST bias and the EAF. An implemented cold SST bias in the observed SST forcing weakens deep convection and reduces cloud cover in the rising branch of the PWC, causing weaker EAF. A warm SST bias has the opposite effect. Our results elucidate how biases in the mean state of the PWC and equatorial SST hamper a realistic simulation of the EAF.

Description: Proteobacteria Alphaproteobacteria Rhizobiales Hyphomicrobiaceae Blas.to.chlo'ris. Gr. masc. n. blastos bud shoot; Gr. masc. adj. chloros green; N.L. fem. n. Blastochloris green bud shoot. Proteobacteria / Alphaproteobacteria / Rhizobiales / Hyphomicrobiaceae / Blastochloris Blastochloris species are anoxygenic phototrophic Alphaproteobacteria that have bacteriochlorophyll b in their photosynthetic reaction centers. Crystals of the photosynthetic reaction centers of Blastochloris viridis were the first that have been studied in high‐resolution structure analysis at 3 Å resolution. Internal photosynthetic membranes are present as lamellae underlying and parallel to the cytoplasmic membrane. Cells are rod shaped to ovoid and exhibit polar growth, budding, and asymmetric cell division and form rosette‐like cell aggregates. They are motile by means of subpolar flagella and stain Gram‐negative. Straight‐chain monounsaturated C18:1 is the predominant component of cellular fatty acids. Ubiquinones and menaquinones are present, and the lipopolysaccharides are characterized by a 2,3‐diamino‐2,3‐deoxy‐d‐glucose (DAG)‐containing, phosphate‐free lipid A with amide‐bound C14:0 3OH. DNA G + C content (mol%): 63.8–68.3. Type species: Blastochloris viridis (Drews and Giesbrecht 1966) Hiraishi 1997 (Rhodopseudomonas viridis Drews and Giesbrecht 1966).

Description: In this decade, the amount of (industrial) Internet of Things devices will increase tremendously. Today, there exist no common standards for interconnection, observation, or the monitoring of these devices. In context of the German "Industrie 4.0"strategy the Reference Architectural Model Industry 4.0 (RAMI 4.0) was introduced to connect different aspects of this rapid development. The idea is to let different stakeholders of these products speak and understand the same terminology. In this paper, we present an approach using Digital Twins to prototype different layers along the axis of the RAMI 4.0, by the example of an autonomous ocean observation system developed in the project ARCHES.

Description: (GPF 20-3_080) 08.11.2020 –08.12.2020, Emden – Emden, King's Trough

Description: The Ligurian Basin is located north-west of Corsica at the transition from the western Alpine orogen to the Apennine system. The Back-arc basin was generated by the southeast trench retreat of the Apennines-Calabrian subduction zone. The opening took place from late Oligocene to Miocene. While the extension led to extreme continental thinning little is known about the style of back-arc rifting. Today, the seismic events indicate the closure of this back-arc basin. To shed light on the present day crustal and lithospheric architecture of the Ligurian Basin, active seismic data have been recorded on short period ocean bottom seismometersin the framework of SPP2017 4D-MB, the German component of AlpArray. An amphibious refraction seismicprofile was shot acrossthe Ligurian Basininan E-W direction from the Gulf of Lion to Corsica. The profile extends onshore Corsica to image the necking zone of continental thinning. Local seismicity was recorded on broad band ocean bottom seismometers over a period of 8 month. The majority of the refraction seismic data show mantle phases at offsets up to 70km. The arrivalsof seismic phases were picked and inverted in a travel time tomography. The results show acrust-mantle boundary in the central basin at ~12km depth below seasurface. The mantle shows rather high velocities 〉7.8 km/s.The crust-mantle boundary deepens from ~12 km to ~18 km within 25 -30 kmtowards Corsica. The results do not map an axial valley as expected for oceanic spreading. However, an extremely thinned continental crust indicates a long lasting rifting process that possibly does not initiated oceanic spreading before the opening of the Ligurian Basin stopped. In the centre of the Ligurian Basin, a cluster of 15 seismic events with magnitudes lower than 2.5 occurred in the upper mantle in a depth of 10-15 kmbelow the seismic Moho. The fault plane solutions indicate reverse faulting and a convergence in NW-SE direction.