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  • 1
    ISSN: 1573-0956
    Schlagwort(e): (AGI) ; heat flow ; lithosphere ; thermal conductivity ; thermal diffusivity ; models ; uncertainty
    Quelle: Springer Online Journal Archives 1860-2000
    Thema: Geologie und Paläontologie , Physik
    Notizen: Abstract Measurements on thermal conductivity and diffusivity as functions of temperature (up to 1150 K) and pressure (up to 1000 MPa) are presented for Archaean and Proterozoic mafic high-grade rocks metamorphosed in middle and lower crustal pressures, and situated in eastern Finland, central Fennoscandian Shield. Decrease of 12–20% in conductivity and 40–55% in diffusivity was recorded between room temperature and 1150 K, which can be considered as typical of phonon conductivity. Radiative heat transfer effects were not detected in these samples. Pressure dependencies of the samples are weak if compared to crystalline rocks in general, but relatively typical for mafic rocks. The temperature and pressure dependencies of thermal transport properties (data from literature and the present study) were applied in an uncertainty analysis of lithospheric conductive thermal modellings with random (Monte Carlo) simulations using a 4-layer model representative of shield lithosphere. Model parameters were varied according to predetermined probability functions and standard deviations were calculated for lithospheric temperature and heat flow density after 1500 independent simulations. The results suggest that the variations (uncertainties) in calculated temperature and heat flow density values due to variations in the temperature and pressure dependencies of conductivity are minor in comparison to the effects produced by typical variations in the room temperature value of conductivity, heat production rate or lower boundary condition values.
    Materialart: Digitale Medien
    Standort Signatur Erwartet Verfügbarkeit
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  • 2
    Digitale Medien
    Digitale Medien
    Springer
    International journal of thermophysics 16 (1995), S. 1-9 
    ISSN: 1572-9567
    Schlagwort(e): hydrothermal ; laser-induced grating ; speed of sound ; thermal diffusivity ; transient grating
    Quelle: Springer Online Journal Archives 1860-2000
    Thema: Physik
    Notizen: Abstract We use the laser-induced grating technique to measure the thermal difusivity and speed of sound of hydrothermal solutions. In this noninvasive optical technique, a transient grating is produced in the hydrothermal solution by optical absorption from two crossed, time-coincident nanosecond laser pulses. The grating is probed by measuring the diffraction efficiency of a third laser beam. The grating relaxes via thermal diffusion, and the thermal diffusivity is determined by measuring the decay of the grating diffraction efficiency as a function of of the pump-probe delay time. In addition, intense pump pulses produce counterpropagating acoustic waves that appear as large undulations in the transient grating decay spectrum. The speed of sound in the sample is simply the grating fringe spacing divided by the undulation period. The cell is made from a commercial high-pressure fitting and is equipped with two diamond windows for optical access. Results are presented for dilute dye/water solutions withT=400° and pressures between 20 and 70 MPa.
    Materialart: Digitale Medien
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  • 3
    Digitale Medien
    Digitale Medien
    Springer
    International journal of thermophysics 20 (1999), S. 665-676 
    ISSN: 1572-9567
    Schlagwort(e): density ; myocardium ; swine ; thermal conductivity ; thermal diffusivity
    Quelle: Springer Online Journal Archives 1860-2000
    Thema: Physik
    Notizen: Abstract This paper presents the experimental technique and results for the thermal conductivity, thermal diffusivity, and density of swine myocardial tissue. These properties were measured for freshly excised tissue. Thermal properties were measured using a self-heated thermistor probe, while the density was measured using a water displacement method. Thermistor probes were inserted into the tissue of interest and were used to supply heat within the tissue as well as to monitor the temperature rise in the tissue. An empirical calibration procedure was used to measure the properties of the tissue at different temperatures. The measurement instrument was first calibrated against agar-gelled water and glycerol at each temperature. The measurements were made at temperatures of 25, 37, 50, 62, and 76°C. The uncertainty in the measurement ranges from 2% at lower temperatures to about 5% at higher temperatures (T 〉 50°C). The properties of the tissue depend significantly on the water content. At temperatures higher than 50°C, there is significant water loss from the tissue during the procedure. The water loss is found to vary exponentially with the increase in temperature relative to ambient. Consequently, there is a decrease in the thermal conductivity values with increasing temperature. This decrease, however, is not as much as one would expect from the water loss data. A hypothesis to explain the relationships among water loss, cell damage, and thermal properties is proposed.
    Materialart: Digitale Medien
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  • 4
    Digitale Medien
    Digitale Medien
    Springer
    International journal of thermophysics 20 (1999), S. 1237-1246 
    ISSN: 1572-9567
    Schlagwort(e): electrical resistivity ; enthalpy ; high temperature ; liquid alloys ; rhenium alloys ; specific heat ; thermal conductivity ; thermal diffusivity ; tungsten alloys
    Quelle: Springer Online Journal Archives 1860-2000
    Thema: Physik
    Notizen: Abstract Results are reported for the thermal conductivity and thermal diffusivity as a function of temperature for four W–Re alloys (4.0, 21.24, 24.07, and 31.09 mass% of Re) over a wide temperature range covering the solid and liquid states. The measurements allow the determination of specific heat and dependences among electrical resistivity, temperature, and density of the alloys into the liquid phase. The thermal conductivity is calculated using the Wiedeman–Franz law. Additionally, data for thermal conductivity and thermal diffusivity of the constituent elements, tungsten and rhenium, are presented for the first time. Both metals have been previously studied with the same experimental technique.
    Materialart: Digitale Medien
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  • 5
    Digitale Medien
    Digitale Medien
    Springer
    International journal of thermophysics 17 (1996), S. 695-703 
    ISSN: 1572-9567
    Schlagwort(e): AC calorimetry ; CVD diamond film ; Debye phonon model ; grain boundary ; thermal conductivity ; thermal diffusivity ; U-process
    Quelle: Springer Online Journal Archives 1860-2000
    Thema: Physik
    Notizen: Abstract Diamond films 60 and 170 µm in thickness were grown by PACVD (plasma-assisted chemical vapor deposition) under similar conditions. The thermal diffusivity of these freestanding films was measured between 100 and 300 K using AC calorimetry. Radiation heat loss from the surface was estimated by analyzing both the amplitude and the phase shift of a lock-in amplifier signal. Thermal conductivity was calculated using the specific heat data of natural diamond. At room temperature, the thermal conductivity of the 60 and 170 υm films is 9 and 16 W-cm−1. K−1 respectively, which is 40–70% that of natural diamond, The temperature dependence of thermal conductivity of the CVD diamond films is similar to that of natural diamond, Phonon scattering processes are considered using the Debye model, The microsize of the grain boundary has a significant effect on the mean free path of phonons at low temperatures. The grain in CVD diamond film is grown as a columnar structure, Thus, the thicker film has the larger mean grain size and the higher thermal conductivity. Scanning electron microscopy (SEM) and Raman spectroscopy were used to study the microstructure of the CVD diamond films. In this experiment, we evaluated the quality of CVD diamond film of the whole sample by measuring the thermal conductivity.
    Materialart: Digitale Medien
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  • 6
    Digitale Medien
    Digitale Medien
    Springer
    International journal of thermophysics 19 (1998), S. 579-593 
    ISSN: 1572-9567
    Schlagwort(e): gasoline ; hydrocarbons ; kinetic measurements ; resonance ; sensor ; standing waves ; thermal diffusivity ; thermal wave
    Quelle: Springer Online Journal Archives 1860-2000
    Thema: Physik
    Notizen: Abstract A novel thermal-wave resonant cavity (TWRC) was constructed and used for thermophysical measurements of gases and vapors, with an AC current-heated thin-film resistive element acting as a thermal-wave source. A thin-film pyroelectric element was used both as a cavity wall and as a signal transducer. A theoretical model of the cavity length-scanned thermal-wave field was developed to quantify the standing-wave resonance antinode patterns in the demodulated lock-in signal output in-phase and quadrature channels. These resonance extrema were used to measure precisely the thermal diffusivity of the intracavity gas or vapor. Seven high-purity gases (nitrogen, dry air, oxygen, methane, hydrogen in nitrogen, pure hydrogen, and helium) were measured using the cavity. Fourth-significant-figure precision was obtained for this parameter, with standard deviations less than 0.32% for the five measurements performed with each gas. Furthermore, three grades of gasoline vapors from Imperial Oil were studied with the cavity. The measured thermal diffusivities showed that the TWRC can monitor fundamental evaporation kinetics as an analytical quality-control instrument. These results, together with the simplicity of TWRC sensor fabrication, are indicative of its potential to become a new standard measurement instrument for the determination of gas thermal diffusivity with improved precision, and a new in situ monitor of chemical evaporation kinetics over conventional methodologies, such as gas chromatography and mass spectrometry.
    Materialart: Digitale Medien
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  • 7
    Digitale Medien
    Digitale Medien
    Springer
    International journal of thermophysics 21 (2000), S. 207-215 
    ISSN: 1572-9567
    Schlagwort(e): calorific intensity ; hot probe ; organ or tissue of a living body ; specific heat ; thermal conductivity ; thermal diffusivity
    Quelle: Springer Online Journal Archives 1860-2000
    Thema: Physik
    Notizen: Abstract A new method was developed to determine simultaneously the thermal conductivity, thermal diffusivity, specific heat, and calorific intensity of the organ or tissue of a living body either in vivo or in vitro with a thin hot probe. By using the method, the thermophysical properties and calorific intensities of a human palm and in vivo liver and a kidney, heart, brain, and foreleg and hindleg muscles of an anesthetized canine were measured. It is concluded that there are no significant differences in the thermophysical properties of organ or tissue of a living body either in vivo or in vitro. The measured thermophysical properties are in good agreement with those reported in the literature.
    Materialart: Digitale Medien
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  • 8
    Digitale Medien
    Digitale Medien
    Springer
    International journal of thermophysics 16 (1995), S. 23-31 
    ISSN: 1572-9567
    Schlagwort(e): diffusion coefficient ; fluctuations ; n-hexane ; nonequilibrium ; Rayleigh scattering ; Soret coefficient ; thermal diffusivity ; toluene
    Quelle: Springer Online Journal Archives 1860-2000
    Thema: Physik
    Notizen: Abstract We have developed an experimental arrangement for measuring Rayleigh scattering in liquids and liquid mixtures that are either in thermal equilibrium or in thermal nonequilibrium states. As an illustrative example we report experimental values for the thermal dilfusivity, the mass diffusion coefficient, the Rayleigh-factor ratio, and the Suret coefficient of an equimolar mixture of liquid toluene andn-hexane.
    Materialart: Digitale Medien
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  • 9
    Digitale Medien
    Digitale Medien
    Springer
    International journal of thermophysics 16 (1995), S. 821-829 
    ISSN: 1572-9567
    Schlagwort(e): a.c. calorimetry ; fluctuation effects ; specific heat ; superconductors ; thermal conductivity ; thermal diffusivity
    Quelle: Springer Online Journal Archives 1860-2000
    Thema: Physik
    Notizen: Abstract The specific heat and thermal conductivity measurements of YBa2Cu3O7−δ high-T c superconductors were performed by an a.c. calorimetry method. Investigations of the specific heat of YBa2Cu3O7−δ ceramics in magnetic fields show that an increase in the magnetic field reduces the jump in the specific heat, broadens the transition region, and shifts the transition temperature downward by about 0.5 K, Temperature dependence of the specific heat of a YBa2Cu3O7−σ high-T c superconducting ceramic reveals that fluctuation affect the specific heat near the superconducting transition, Critical exponentsα =α′ = 0.5, the critical amplitudesC + =C − = 0.5 J · mol−1 K−1, the space dimensionalityd = 3, and the number of components in the order parametern = 3 is calculated, The specific heat and the along-c-axis thermal conductivity of YBa2Cu,3O7−δ single crystal were simultaneously measured.
    Materialart: Digitale Medien
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  • 10
    Digitale Medien
    Digitale Medien
    Springer
    International journal of thermophysics 16 (1995), S. 973-995 
    ISSN: 1572-9567
    Schlagwort(e): heat transfer ; optical diagnostics ; photothermal methods ; thermal diffusivity
    Quelle: Springer Online Journal Archives 1860-2000
    Thema: Physik
    Notizen: Abstract The measurement of thermal diffusivity of a material (in particular, a thin film) is important for various reasons, e.g., to predict the heat transfer in the solid subjected to a thermal process, to monitor surface composition or morphology, or to detect invisible subsurface defects like delaminations. This measurement can be done in a noncontact manner using various photothermal methods. Such methods typically involve pulsed heating of the surface by small amounts using a laser source; the decay of the surface temperature after this pulsed photothermal heating is then probed to provide the thermal diffusivity. Various probing methods have been developed in the literature, including the probing of reflection, refraction, and diffraction from the pulsed heated area, infrared thermal radiometry, and surface deformation. This paper provides an overview of such techniques and some examples of their applications.
    Materialart: Digitale Medien
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  • 11
    Digitale Medien
    Digitale Medien
    Springer
    International journal of thermophysics 16 (1995), S. 1069-1086 
    ISSN: 1572-9567
    Schlagwort(e): flow anisotropy ; forced Rayleigh scattering ; molten salts ; optical method ; polymers ; shear anisotropy ; thermal conductivity ; thermal diffusivity
    Quelle: Springer Online Journal Archives 1860-2000
    Thema: Physik
    Notizen: Abstract The experimental determination of thermophysical properties has been greatly improved by the introduction of laser technology. The laser beam is used for sensing and also for heating (or exciting) the specimen. The advantage of using a laser beam is most strongly felt in the measurement of the thermal conductivity or the thermal diffusivity, which are some of the most difficult properties to measure. Interesting features of new techniques for investigating various aspects of thermal conductivity in fluids and solids are reviewed. An optical method, the so-called forced Rayleigh scattering method, or the laser-induced optical-grating method, has been developed and used extensively by the present author's group. The method is a high-speed remote-sensing method which can also quantitatively detect anisotropy, namely, direction dependence of heat conduction in the material. It was used for determination of the thermal diffusivity and its anisotropic behavior for high-temperature materials such as molten salts, liquid crystals, extended polymer samples, and flowing polymer melts under shear. Interesting applications of the method were demonstrated also for thermal diffusivity “mapping” and microscale measurement.
    Materialart: Digitale Medien
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  • 12
    Digitale Medien
    Digitale Medien
    Springer
    International journal of thermophysics 16 (1995), S. 1353-1361 
    ISSN: 1572-9567
    Schlagwort(e): aqueous solutions ; diffraction ; ethanol ; laser-induced thermal grating ; methanol ; scattering ; thermal conductivity ; thermal diffusivity ; water
    Quelle: Springer Online Journal Archives 1860-2000
    Thema: Physik
    Notizen: Abstract The thermal diffusivity of methanol, ethanol, and their aqueous solutions was measured at atmospheric pressure and temperature. The measurements were performed with a laser-induced thermal grating technique. The aqueous solutions have weight fractions of 20, 40, 60, and 80%. Systematic errors were taken into consideration, and corrections were made to the measured values. Focused laser beams were used, which notably intensify the diffracted signal, reduce the background to zero, and justify neglecting the heterodyne term of the diffracted signal, thus simplifying the data evaluation. Hence, the accuracy of the measurements was improved significantly. The overall accuracy of the measurements is estimated to be better than 1.5%.
    Materialart: Digitale Medien
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  • 13
    Digitale Medien
    Digitale Medien
    Springer
    International journal of thermophysics 17 (1996), S. 253-261 
    ISSN: 1572-9567
    Schlagwort(e): flash method ; melts ; radiation correction ; slags ; three-layer analysis ; thermal conductivity ; thermal diffusivity
    Quelle: Springer Online Journal Archives 1860-2000
    Thema: Physik
    Notizen: Abstract A high-temperature measuring system has been developed to undertake measurements of thennal difusivity and specific heat up to 1900 K. The overall design allows measurements on solids to be undertaken using the accepted standard techniques and analytical procedures. The specific design for molten materials and especially slags is based on the differential threelayer technique utilizing a special cell which can be accomodated in the system. In this method, the liquid specimen is sandwiched between an upper inner platinum crucible and a lower outer platinum crucible, to provide a three-layered sandwich. A laser pulse irradiates the surface of the upper platinum crucible and the temperature response of the surface of the lower platinum crucible is observed. For the purpose of accurate measurement of specimen thickness at the measuring temperature, two runs are performed in which the thicknesses arel andl+°Dl, wherel is unknown butΔl can be set accurately with a built-in micrometer. The thermal difusivity is obtained through a curve-fitting method by a personal computer using a three-layer analysis with a correction for the radiative component based on the transparent body assumption. Following verification of the basic performance, using solids of known properties and water and ethanol, a continuous casting mixture has been evaluated. The initial results on the fluids are in good agreement with those in the literature.
    Materialart: Digitale Medien
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  • 14
    Digitale Medien
    Digitale Medien
    Springer
    International journal of thermophysics 17 (1996), S. 293-328 
    ISSN: 1572-9567
    Schlagwort(e): 2,2-dichloro-1,1,1-trifluoroethane ; HCFC-123 ; R123 ; thermal conductivity ; thermal diffusivity ; transport properties ; viscosity
    Quelle: Springer Online Journal Archives 1860-2000
    Thema: Physik
    Notizen: Abstract The thermal conductivity and the viscosity data of CFC alternative refrigerant HCFC-123 (2,2-dichloro-1,1,1-trifluoroethane: CHCI2-CF3) were critically evaluated and correlated on the basis of a comprehensive literature survey. Using the residual transport-property concept, we have developed the three-dimensional surfaces of the thermal conductivity-temperature-density and the viscosity-temperature-density. A dilute-gas function and an excess function of simple form were established for each property. The critical enhancement contribution was taken no account because reliable crossover equations of state and the thermal conductivity data are still missing in the critical region. The correlation for the thermal conductivity is valid at temperatures from 253 to 373 K, pressures up to 30 MPa, and densities up to 1633 kg m−3. The correlation for the viscosity is valid at temperatures from 253 to 423 K, pressures up to 20 MPa. and densities up to 1608 kg·m−3. The uncertainties of the present correlations are estimated to be 50% for both properties, since the experimental data are still scarce and somewhat contradictory in the vapor phase at present.
    Materialart: Digitale Medien
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  • 15
    Digitale Medien
    Digitale Medien
    Springer
    International journal of thermophysics 17 (1996), S. 329-345 
    ISSN: 1572-9567
    Schlagwort(e): diffraction ; forced Rayleigh scattering ; laser-induced thermal grating ; numerical simulation ; thermal diffusivity ; toluene
    Quelle: Springer Online Journal Archives 1860-2000
    Thema: Physik
    Notizen: Abstract The laser-induced thermal grating technique has been used to determine the thermal diffusivity of liquids and liquid mixtures. But the dynamic behaviour of the transient thermal grating has not yet been thoroughly investigated, and the systematic errors, which result from the departures from one-dimensional heat conduction, have scarcely been studied quantitatively. In this paper. a three-dimensional numerical simulation and results of the transient thermal grating technique are presented, which enable a good understanding of the dynamic behaviour of the transient thermal grating. The results of this simulation are important for the proper design of the experimental setup to keep the systematic errors for the diffusivity measurement small. Based on the simulation method, the systematic errors were analyzed quantitatively. Here, the following effects were studied: (I) sample thickness, (2) intersection angle, (3) absorption, (4) Gaussian beam intensity distribution and focusing of heating laser beam, and (5) heating pulse duration and laser power. This error analysis makes it possible to specify the criteria for optimum measuring conditions, to correct the measured thermal-diffusivity values for systematic errors, and to estimate the accuracy of the measurements.
    Materialart: Digitale Medien
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  • 16
    Digitale Medien
    Digitale Medien
    Springer
    International journal of thermophysics 20 (1999), S. 977-986 
    ISSN: 1572-9567
    Schlagwort(e): ac calorimetry ; CVD diamond ; modified Angstrom method ; reference materials ; thermal conductivity ; thermal diffusivity
    Quelle: Springer Online Journal Archives 1860-2000
    Thema: Physik
    Notizen: Abstract Modified ac calorimetry, a variation of the Angstrom method, has been shown to be a precise tool for measuring the in-plane thermal diffusivity of thin films (thickness less than 300 μm) of a wide variety of materials and layered composites. The property is determined from an analysis of the decay curve of the ac temperature waves generated by irradiation of a specimen using uniform chopped light (at frequencies from 1 to 20 Hz) from a halogen lamp source. To address certain limiting factors, especially to improve the signal-to-noise ratio and to eliminate heat losses, an improved form of measurement instrument has been developed. It is based on the use of a modulated laser beam heating to provide a higher intensity energy source plus a special optical system to ensure that one-dimensional ac temperature wave propagation is obtained. Measurements can now be made using frequencies in the range of 0.01 to 10 Hz, i.e., 10 times lower than in the traditional method. The performance of the improved measurement instrument will be illustrated by results on various materials of known thermal properties such as nickel and stainless steel, proposed reference materials such as a glassy carbon and alumina, plus a comparison of results obtained on CVD diamond films used in an international round-robin series with those obtained by the traditional technique.
    Materialart: Digitale Medien
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  • 17
    Digitale Medien
    Digitale Medien
    Springer
    International journal of thermophysics 20 (1999), S. 1051-1060 
    ISSN: 1572-9567
    Schlagwort(e): copper ; liquid metals ; liquid alloys ; Lorenz relation ; resistivity ; thermal conductivity ; thermal diffusivity ; tin
    Quelle: Springer Online Journal Archives 1860-2000
    Thema: Physik
    Notizen: Abstract The thermal properties (heat capacity, thermal diffusivity, and electrical resistivity) of a Cu + 10 wt% Sn alloy in both solid and liquid phases have been reported. Using these values it was confirmed that the Lorenz relation is suitable for obtaining thermal conductivity from electrical resistivity in the liquid phase of this alloy. Also, the temperature differential (dλ/dT) obtained from such an approach was in excellent agreement with the thermal conductivity values calculated from thermal diffusivity.
    Materialart: Digitale Medien
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  • 18
    Digitale Medien
    Digitale Medien
    Springer
    International journal of thermophysics 17 (1996), S. 713-721 
    ISSN: 1572-9567
    Schlagwort(e): impulse transducer ; laser heating ; laser-produced plasma ; molten metal ; RF levitator-heater ; thermal diffusivity
    Quelle: Springer Online Journal Archives 1860-2000
    Thema: Physik
    Notizen: Abstract A high-power pulsed laser excitation of a material surface generates a well-separated sequence of plasma, fluid flow, and acoustic events. When the movement of the surface due to evaporation by laser heating is kept in pace with the thermal diffusion front, the ablative mass loss from a solid surface becomes strongly correlated with the thermal diffusivity of the target matter. The other thermophysiocal properties which figure in this correlation are the mass density, heat of formation, and molecular weight. The functional relationship, which is given in this text for the first time, can be exploited to measure the thertnophysical properties. We have now extended such an approach to measurement of the thermal diffusivity of molten specimens by developing a new instrumentation for determining the ablative mass loss due to a single laser pulse. This has been accomplished by combining a facility for controlled generation of a molten specimen and a novel transducer for real-time measurement of the impulse imparted to the molten target by a laser-produced plasma plume, The transducer design, calibration, signal recovery, and method of extracting the mass loss per laser excitation are detailed by comparing the results for metallic specimens in the solid and molten state.
    Materialart: Digitale Medien
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  • 19
    Digitale Medien
    Digitale Medien
    Springer
    International journal of thermophysics 20 (1999), S. 1587-1602 
    ISSN: 1572-9567
    Schlagwort(e): photothermal radiometry ; roughness effects ; thermal-sprayed coatings ; thermal diffusivity ; thermal conductivity
    Quelle: Springer Online Journal Archives 1860-2000
    Thema: Physik
    Notizen: Abstract Laser infrared photothermal radiometry (PTR) was used to measure the thermophysical properties (thermal diffusivity and conductivity) of various thermal sprayed coatings on carbon steel. A one-dimensional photothermal model of a three-layered system in the backscattered mode was introduced and compared with experimental measurements. The uppermost layer was used to represent a roughness-equivalent layer, a second layer represented the thermal sprayed coating, and the third layer represented the substrate. The thermophysical parameters of thermal sprayed coatings examined in this work were obtained when a multiparameter-fit optimization algorithm was used with the backscattered PTR experimental results. The results also suggested a good method to determine the thickness of tungsten carbide and stainless-steel thermal spray coatings once the thermophysical properties are known. The ability of PTR to measure the thermophysical properties and the coating thickness has a strong potential as a method for in situ characterization of thermal spray coatings.
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  • 20
    Digitale Medien
    Digitale Medien
    Springer
    International journal of thermophysics 21 (2000), S. 495-502 
    ISSN: 1572-9567
    Schlagwort(e): flash method ; response delay ; thermal diffusivity ; time constant
    Quelle: Springer Online Journal Archives 1860-2000
    Thema: Physik
    Notizen: Abstract This work investigates the effect of the response delay of a measuring system on a thermal diffusivity measurement. A model of an m th-order delay in the measuring system is introduced, and a general expression for the output of the system with temperature response as input is derived. The effect on the temperature response caused by such a system is discussed. As a practical example, a third-order measuring system is considered. The measured temperature responses of stainless steel foils are compared with those calculated with the model of a third-order delay system. Good agreement between the two results is shown.
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  • 21
    Digitale Medien
    Digitale Medien
    Springer
    International journal of thermophysics 21 (2000), S. 535-542 
    ISSN: 1572-9567
    Schlagwort(e): flash method ; thermal contact resistance ; thermal control coatings ; thermal diffusivity ; two-layer composite sample
    Quelle: Springer Online Journal Archives 1860-2000
    Thema: Physik
    Notizen: Abstract The thermal diffusivity of brittle coatings cannot be measured by the flash method directly because of the difficulty of preparing free-standing samples. Adopting the flash method using a two-layer composite sample, it is possible to measure thermal diffusivity if the radiant pulse is well defined and good thermal contact on the interface of the composite sample can be ensured. Using an equilateral trapezoidal pulse of an Nd-glass laser measuring the dimensionless temperature history of the rear face of the sample, we determined the thermal diffusivity of thermal control coatings in the temperature range of 80 to 200°C. The results for different thicknesses of substrate showed that the thermal contact resistance of the interface can be neglected.
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  • 22
    Digitale Medien
    Digitale Medien
    Springer
    International journal of thermophysics 21 (2000), S. 479-485 
    ISSN: 1572-9567
    Schlagwort(e): diamond ; film ; flash method ; thermal diffusivity
    Quelle: Springer Online Journal Archives 1860-2000
    Thema: Physik
    Notizen: Abstract This paper discusses the short-pulse-flash method developed for thermal diffusivity measurements on thin films. Two kinds of CVD diamond film have been prepared, and their thermal diffusivity in the perpendicular direction has been measured with this method. The measurement errors caused by the surface coating are discussed.
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  • 23
    Digitale Medien
    Digitale Medien
    Springer
    International journal of thermophysics 21 (2000), S. 513-524 
    ISSN: 1572-9567
    Schlagwort(e): metal ; microscopic structure ; phase lag ; photoacoustic effect ; thermal diffusivity ; thin layer
    Quelle: Springer Online Journal Archives 1860-2000
    Thema: Physik
    Notizen: Abstract The thermal diffusivities of four kinds of metallic foils from 20 to 200μμm in thickness were measured by a photoacoustic method on the basis of the Rosencwaig and Gersho theory. The measured data for continuous foils of uniform microscopic structure almost agreed with the literature values. Measurements were also carried out on two kinds of metallic thin films with of 10μμm thickness produced by sputtering. The difference in thermal diffusivity between the foils and the sputtered films depended on the uniformity of the microscopic structure.
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  • 24
    Digitale Medien
    Digitale Medien
    Springer
    International journal of thermophysics 21 (2000), S. 553-561 
    ISSN: 1572-9567
    Schlagwort(e): inverse analysis ; Levenberg–Marquardt algorithm ; pulse heating ; relaxation parameters ; thermal diffusivity ; universal heat conduction model
    Quelle: Springer Online Journal Archives 1860-2000
    Thema: Physik
    Notizen: Abstract This paper presents an inverse analysis for simultaneous estimation of relaxation parameters and thermal diffusivity with a universal heat conduction model by using temperature responses measured at the surface of a finite medium subjected to pulse heat fluxes. In the direct analysis, the temperature responses in a finite medium subjected to a pulse heat flux are derived by solving the universal heat conduction equation. The inverse analysis is performed by a nonlinear least-squares method for determining the two relaxation parameters and thermal diffusivity. Here, the nonlinear system of algebraic equations resulting from the sensitivity matrix is solved by the Levenberg–Marquardt iterative algorithm. The inverse analysis is utilized to estimate the relaxation parameters and the thermal diffusivity from the simulated experimental non-Fourier temperature response obtained by direct calculation.
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  • 25
    Digitale Medien
    Digitale Medien
    Springer
    International journal of thermophysics 21 (2000), S. 571-583 
    ISSN: 1572-9567
    Schlagwort(e): CsPbCl3 single crystal ; heat of transition ; phase transition ; pulse transient method ; specific heat ; thermal conductivity ; thermal diffusivity
    Quelle: Springer Online Journal Archives 1860-2000
    Thema: Physik
    Notizen: Abstract The main features of the pulse transient method are presented. The method gives the specific heat c and thermal diffusivity a for a single measurement, while thermal conductivity λ is calculated according to λ=caρ, where ρ is the density. The pulse transient method is a dynamic method based on the measurement of the temperature response to a heat pulse produced within a specimen. An apparatus operating in the temperature range from −40 to 100°C is described. Errors are discussed. The thermophysical properties of a CsPbCl3 single crystal are determined using the pulse transient method for a temperature range between 10 and 65°C in the controlled heating and cooling regimes. The data show anomalies in the thermophysical properties around the phase transition temperature at 47°C. Discrepancies in comparison with previously published data are discussed.
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  • 26
    Digitale Medien
    Digitale Medien
    Springer
    International journal of thermophysics 19 (1998), S. 27-42 
    ISSN: 1572-9567
    Schlagwort(e): carbon dioxide ; ethane ; photothermal ; supercritical fluid ; thermal diffusivity ; thermal lens
    Quelle: Springer Online Journal Archives 1860-2000
    Thema: Physik
    Notizen: Abstract Thermal diffusivities of supercritical CO2 and C2H6 were determined over a wide density range with a photothermal technique. The thermal lens, formed by the degradation of the absorbed light energy as heat by the sample, allows the employment of a nonequilibrium method in the critical region. Controlling the refractive-index gradient, i.e., a density gradient, perturbations can be maintained at levels where convection is negligible. An easy-to-operate setup allowed us to measure thermal diffusivities in the density ranges 5 to 20 mol·dm−3 for CO2 at 308 and 313 K and 2 to 12 mol·dm−3 for C2H6 at 308 K with a standard precision of 15%.
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  • 27
    Digitale Medien
    Digitale Medien
    Springer
    International journal of thermophysics 19 (1998), S. 15-25 
    ISSN: 1572-9567
    Schlagwort(e): aqueous solution ; diffraction ; laser-induced thermal grating ; sodium chloride ; thermal conductivity ; thermal diffusivity
    Quelle: Springer Online Journal Archives 1860-2000
    Thema: Physik
    Notizen: Abstract The laser-induced thermal grating technique was used to determine the thermal diffusivity of aqueous solutions of sodium chloride. In comparison with conventional measurement methods, this noninvasive optical technique has the advantage that no sensors need to be inserted in the sample. Therefore, this technique is especially suitable for the measurement of electrically conducting and corrosive liquids. The aqueous solutions studied have weight fractions of 5, 10, 15, and 20% sodium chloride. Measurement results for the thermal diffusivity are presented for aqueous solutions of sodium chloride in the temperature range 293 to 373 K at atmospheric pressure.
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  • 28
    Digitale Medien
    Digitale Medien
    Springer
    International journal of thermophysics 19 (1998), S. 403-414 
    ISSN: 1572-9567
    Schlagwort(e): dynamic light scattering ; sound velocity ; thermal diffusivity ; toluene
    Quelle: Springer Online Journal Archives 1860-2000
    Thema: Physik
    Notizen: Abstract The thermal diffusivity and the sound velocity of toluene have been determined in a wide temperature range up to the critical point by dynamic light scattering. Measurements were performed for both the liquid and the vapor phase at saturation conditions. The results obtained corroborate the usefulness of the technique for the determination of thermophysical properties. From the lack of reference data for the thermal diffusivity or other properties from which the thermal diffusivity may be derived in the high-temperature range and from deviations of experimental sound velocity data compared to values derived from the currently established equation of state, the need for further experimental investigations on this important reference fluid was established.
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  • 29
    Digitale Medien
    Digitale Medien
    Springer
    International journal of thermophysics 19 (1998), S. 525-535 
    ISSN: 1572-9567
    Schlagwort(e): aluminum oxide ; laser pulse ; molybdenum ; multilayer ; thermal barrier coatings ; thermal diffusion ; thermal diffusivity
    Quelle: Springer Online Journal Archives 1860-2000
    Thema: Physik
    Notizen: Abstract Thermal diffusion through aluminum oxide/molybdenum multilayers (10, 20, and 40 bilayers on molybdenum substrates) was studied through thermal pulse experiments. In these experiments, a thermal pulse (〈50 ns) was delivered by a laser to the front surface of the specimen and the resulting temperature transient on the rear surface, typically several degrees, was recorded. An integral solution for the equations governing heat transfer was used to relate experimental results to the thermal resistance of the interfaces. Experimental studies were conducted at temperatures from 950 to 1150°C, relevant to thermal barrier applications. Significant densification of the oxide layers was observed during the experiments at all but the lowest temperature. As a result of these experiments, an upper bound has been placed on the interface thermal resistance.
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  • 30
    Digitale Medien
    Digitale Medien
    Springer
    International journal of thermophysics 19 (1998), S. 511-523 
    ISSN: 1572-9567
    Schlagwort(e): chemical vapor deposition (CVD) diamond ; phonon scattering ; specific heat ; thermal conductivity ; thermal diffusivity
    Quelle: Springer Online Journal Archives 1860-2000
    Thema: Physik
    Notizen: Abstract The thermal conductivity κ of natural, gem-quality diamond, which can be as high as 2500 Wm−1 K−1 at 25°C, is the highest of any known material. Synthetic diamond grown by chemical vapor deposition (CVD) of films up to 1 mm thick exhibits generally lower values of κ but under optimal growth conditions it can rival gem-quality diamond with values up to 2200 Wm−1 K−1. However, it is polycrystalline and exhibits a columnar microstructure. Measurements on free-standing CVD diamond, with a thickness in the range 25–400 μm, reveal a strong gradient in thermal conductivity as a function of position z from the substrate surface as well as a pronounced anisotropy with respect to z. The temperature dependence of κ in the range 4 to 400 K has been analyzed to determine the types and numbers of phonon scattering centers as a function of z. The defect structure, and therefore the thermal conductivity, are both correlated with the microstructure. Because of the high conductivity of diamond, these samples are thermally thin. For example, laser flash data for a 25-μm-thick diamond sample is expected to be virtually the same as laser flash data for a 1-μm-thick fused silica sample. Several of the techniques described here for diamond are therefore applicable to much thinner samples of more ordinary material.
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  • 31
    Digitale Medien
    Digitale Medien
    Springer
    International journal of thermophysics 19 (1998), S. 969-981 
    ISSN: 1572-9567
    Schlagwort(e): electrical resistivity ; enthalpy ; high temperature ; liquid alloys ; rhenium alloy ; specific heat ; thermal conductivity ; thermal diffusivity ; tungsten alloy
    Quelle: Springer Online Journal Archives 1860-2000
    Thema: Physik
    Notizen: Abstract In earlier experiments we have studied pure elements with a fast pulse heating technique to obtain thermophysical properties of the liquid state. We report here results for thermophysical properties such as specific heat and dependences among enthalpy, electrical resistivity, and temperature, for four W–Re alloys (3.95, 21.03, 23.84, and 30.82 at % of Re) in a wide temperature range covering solid and liquid states. Thermal conductivity is calculated using the Wiedemann–Franz law for the liquid alloy, as.well as data for thermal diffusivity for the beginning of the liquid phase. Additionally, data for the entire temperature range studied have been analyzed in comparison with those of the constituent elements, tungsten and rhenium, since both metals have been studied previously with the same experimental technique. Such information is of interest in the field of metallurgy since W–Re alloys of low Re content in the region of mutual component solubility in the solid state are widely used as thermocouple materials for the purposes of high-temperature thermometry.
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  • 32
    Digitale Medien
    Digitale Medien
    Springer
    International journal of thermophysics 19 (1998), S. 1239-1251 
    ISSN: 1572-9567
    Schlagwort(e): criterion of homogeneity ; dispersed composites ; finite element method (FEM) ; laser flash method ; thermal conductivity ; thermal diffusivity ; steady-state comparison method
    Quelle: Springer Online Journal Archives 1860-2000
    Thema: Physik
    Notizen: Abstract The effective thermal conductivity of dispersed composites with a hot-melt-adhesive matrix, measured using the steady-state method, is compared with the apparent thermal conductivity calculated from the average heat capacity and from the thermal diffusivity measured by the laser-flash method. The transient effect has been observed obviously at higher volume percentages for various dispersed particle sizes and ratios of the thermal conductivity values of dispersed and continuous phases. All of the experimental results are compared with those calculated by existing models and by the finite element method (FEM). An attempt has been made to show how the criterion for the homogeneity of dispersed composites under transient conditions is affected by the percentages of dispersed phase, dispersed particle size, and ratio of the thermal conductivity values of dispersed and continuous phases.
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  • 33
    Digitale Medien
    Digitale Medien
    Springer
    International journal of thermophysics 21 (2000), S. 35-44 
    ISSN: 1572-9567
    Schlagwort(e): aqueous solution ; diffraction ; laser-induced thermal grating ; magnesium chloride ; thermal conductivity ; thermal diffusivity
    Quelle: Springer Online Journal Archives 1860-2000
    Thema: Physik
    Notizen: Abstract The thermal diffusivity of aqueous solutions of magnesium chloride was determined in the temperature range 294 to 371 K and at atmospheric pressure. Using a noninvasive optical technique—laser-induced thermal grating (LTG)—the measurements were carried out in aqueous solutions of weight fractions of 5, 10, 15, and 20% magnesium chloride. The measurement results for the aqueous solutions are presented as a function of temperature and weight fraction.
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  • 34
    Digitale Medien
    Digitale Medien
    Springer
    International journal of thermophysics 17 (1996), S. 1113-1124 
    ISSN: 1572-9567
    Schlagwort(e): anisotropy ; forced Rayleigh scattering method ; polymer melt ; thermal diffusivity ; transient behavior
    Quelle: Springer Online Journal Archives 1860-2000
    Thema: Physik
    Notizen: Abstract Molecular orientation of polymer molecules created by shear force due to the flow of the polymer melt in a duct rapidly relaxes after the change in the shear rate. This relaxation causes the changes in anisotropic behavior of mechanical. thermal, and optical properties which have strong effect in precision forming of casted polymer products. Among these properties, thermal diffusivity is one of the most difficult properties to measure by the conventional techniques. The present paper describes and discusses the subsecond measurement of relaxation characteristics in thermal dilfusivity anisotropy of flowing polymer melt in conjunction with measurements of some typical flow characteristics. The method used was the forced Rayleigh scattering method, an optical method which was developed and modified by the authors' group for applying to oriented polymer materials. The measuring lime of I ms can trace the relaxation occurred in the order of several seconds. Measured results of thermal diffusivity anisotropy were compared with transient characteristics of the now and quantitatively showed a good agreement with estimated behavior of oriented polymer molecules.
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  • 35
    Digitale Medien
    Digitale Medien
    Springer
    International journal of thermophysics 17 (1996), S. 1125-1136 
    ISSN: 1572-9567
    Schlagwort(e): impulse transducer ; laser-produced plasmas ; levitation-assisted ; molten metal source ; molten metals ; RF heating ; SS304 ; SS316 ; thermal diffusivity
    Quelle: Springer Online Journal Archives 1860-2000
    Thema: Physik
    Notizen: Abstract We have shown that a laser-produced plasma plume which is representative in elemental composition of the condensed phase target can be reproducibly generated if the movement of the surface due to evaporation is kept in pace with the thermal diffusion front propagating into the bulk. The resulting mass loss is then strongly controlled by the thermal diffusivity of the target matter, and this relationship has been exploited to measure the thermal diffusivity of metallic alloys. We have developed a novel RF Ievitator-heater as a contamination-free molten metal source to be used as a target for LPP plume generation. In order to determine the mass loss due to LPP excitation, a new high-sensitivity transducer has been constructed for measurement of the resulting impulse imparted on the specimen. The impulse transducer is built onto the specimen holder within the levitation-assisted molten metal source. The LPP method has been fully exercised for measurement of the thermal diffusivity of a molten specimen relative to the value for its room temperature solid. The results for SS304 and SS316 are presented, together with a critique of the results. A numerical modeling of the specimen heating in the molten metal source and the physical basis of the new method are also presented.
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  • 36
    Digitale Medien
    Digitale Medien
    Springer
    International journal of thermophysics 17 (1996), S. 1151-1161 
    ISSN: 1572-9567
    Schlagwort(e): alloys ; density ; electrical resistivity ; enthalpy ; heat capacity ; high temperatures ; surface tension ; thermal conductivity ; thermal diffusivity ; viscosity
    Quelle: Springer Online Journal Archives 1860-2000
    Thema: Physik
    Notizen: Abstract Data on the physical properties of alloys at high temperatures are urgently needed for the mathematical modeling of high-temperature processes such as casting, welding, secondary refining, dip melting, spray forming, and metal powder production. Data are required for those properties which are involved in heat and fluid flow in high-temperature processes. Levitated drop methods have been adopted to measure the surface tensions, densities, and enthalpies of commercial alloys, and rapid, transient methods have been developed to measure thermal conductivities to avoid the problem of convection. The results obtained for the properties of commercial alloys for the liquid and “mushy” states are discussed.
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  • 37
    Digitale Medien
    Digitale Medien
    Springer
    International journal of thermophysics 21 (2000), S. 1255-1278 
    ISSN: 1572-9567
    Schlagwort(e): standard uncertainty ; thermal conductivity ; thermal diffusivity ; transient hot strip method ; transient hot wire method
    Quelle: Springer Online Journal Archives 1860-2000
    Thema: Physik
    Notizen: Abstract The standard method for measuring thermal transport properties of dielectric solids such as ceramics and refractories is the transient hot wire (THW) technique. In its simplest arrangement, a thin wire is embedded between two sample halves, where it acts simultaneously as a resistive heat source and a thermometer. From its temperature signal, the thermal conductivity and the thermal diffusivity of the dielectric can be derived. Up to now, there is no uncertainty assessment for this technique strictly following the ISO Guide to the Expression of Uncertainty in Measurement. Here we analyze the ISO standard uncertainty of the THW technique in the same way as in a previous paper on the uncertainty of the closely related transient hot strip (THS) technique. The two papers provide a comprehensive comparison of the most important advantages and disadvantages of these two transient techniques. The results obtained here for the uncertainty (5.8% for the thermal conductivity and 30% for the thermal diffusivity) are nearly the same as those for the THS method. Experiments on a Pyrex standard-reference sample confirm the results.
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  • 38
    Digitale Medien
    Digitale Medien
    Springer
    International journal of thermophysics 19 (1998), S. 259-279 
    ISSN: 1572-9567
    Schlagwort(e): alumel ; chromel ; constantan ; thermal conductivity ; thermal diffusivity ; transient technique
    Quelle: Springer Online Journal Archives 1860-2000
    Thema: Physik
    Notizen: Abstract A transient heating technique, improving the constant-rate-heating technique for the measurements of thermal diffusivities of metals, is proposed. For a physical model of a specimen to be measured, the transient heat-conduction equation was solved with some boundary conditions, and the solution obtained was used as the principle of the present transient heating technique for determining the thermal diffusivity of the specimen. Additionally, a thermal analysis was made to satisfy a boundary condition involved in the principle, that is, the condition of radiative thermal insulation at the two end surfaces of the specimen. To verify the validity of the present technique, the thermal diffusivity of iron, whose thermophysical properties are well-known, was measured with the same apparatus as used in our previous work, and the experimental results are discussed. Moreover, thermal diffusivities of thermocouple materials, namely, constantan, chromel, and alumel, were measured by the technique in the temperature range of 360 to 680 K.
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  • 39
    Digitale Medien
    Digitale Medien
    Springer
    International journal of thermophysics 19 (1998), S. 281-290 
    ISSN: 1572-9567
    Schlagwort(e): GaAs ; impurities ; phonons ; photothermal displacement technique ; semiconductors ; Si ; thermal conductivity ; thermal diffusivity
    Quelle: Springer Online Journal Archives 1860-2000
    Thema: Physik
    Notizen: Abstract Thermal conductivity and thermal diffusivity of Si and GaAs wafers were measured using the photothermal displacement technique, and the temperature dependence of these two quantities was investigated. Thermal diffusivity was obtained from the phase difference between the heating source and the signal, and thermal conductivity was determined from the maximum value of the signal amplitude in the temperature range 80 to 300 K. It was verified that an increase in doping concentration gives rise to a decrease in thermal conductivity at low temperatures. The experimental results obtained on samples with different types and doping concentrations are consistent with those expected from theoretical considerations.
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  • 40
    Digitale Medien
    Digitale Medien
    Springer
    International journal of thermophysics 19 (1998), S. 931-939 
    ISSN: 1572-9567
    Schlagwort(e): adhesives ; coatings ; contact conductance ; thermal barrier coatings ; thermal conductivity ; thermal diffusivity ; thin films
    Quelle: Springer Online Journal Archives 1860-2000
    Thema: Physik
    Notizen: Abstract There is an intense and growing demand for knowledge of the thermal transport properties and contact conductances of coatings, thin films, and interfaces. The laser flash technique is uniquely suited for many of the measurements. The usefulness and limitations of this technique for coatings, greases, and joining techniques are described in some detail. Several alternate techniques, namely, step heating, multiproperty, and photoacoustic techniques, are briefly examined.
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  • 41
    ISSN: 1572-9567
    Schlagwort(e): analytical model ; glass ; laser-flash method ; radiative heat transfer ; thermal conductivity ; thermal diffusivity
    Quelle: Springer Online Journal Archives 1860-2000
    Thema: Physik
    Notizen: Abstract We have developed an analytical model to determine the thermal diffusivity of nonscattering materials from samples with low optical thickness and opaque boundaries with arbitrary emissivities. The paper outlines the new analytical model and describes measurements on two samples: a microscope slide glass and a high-grade fused quartz plate. Results show that the new model applied to measurements on gold- or graphite-coated samples leads to the same results as if a conventional model is used on gold-coated samples.
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  • 42
    Digitale Medien
    Digitale Medien
    Springer
    International journal of thermophysics 20 (1999), S. 691-707 
    ISSN: 1572-9567
    Schlagwort(e): Composites ; flash method ; orthotropic ; thermal conductivity ; thermal diffusivity ; transient technique
    Quelle: Springer Online Journal Archives 1860-2000
    Thema: Physik
    Notizen: Abstract A generalization of the radial flash technique is presented whereby the thermal diffusivity of an orthotropic solid is measured in directions parallel and perpendicular to the flash source. The theoretical formulation is based on a Green's function approach which assumes a general orthotropic solid with three mutually orthogonal thermal diffusivities (or conductivities). Using this approach, a solution to this problem is presented which can be used to develop solutions for arbitrary pulse waveforms and incident geometries. Analytical and numerical results are presented for two-dimensional and three-dimensional cases of finite and semiinfinite solids. Characteristic equations which describe the ratio of the temperatures at two points along a principal axis are given. The equations show excellent agreement with numerical predictions as well as experimental results. A parameter estimation approach is given which improves on the accuracy of the radial flash technique in the determination of thermal diffusivity from experimental data.
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  • 43
    Digitale Medien
    Digitale Medien
    Springer
    International journal of thermophysics 20 (1999), S. 987-996 
    ISSN: 1572-9567
    Schlagwort(e): heat capacity ; high-speed pyrometry ; laser flash ; laser heating, graphite ; thermal conductivity ; thermal diffusivity ; uranium dioxide ; zirconia
    Quelle: Springer Online Journal Archives 1860-2000
    Thema: Physik
    Notizen: Abstract This paper presents a new experimental technique enabling thermophysical measurements to be carried out at very high temperatures in a very simple and small pressurized vessel in which the sample is heated by a continuous wave laser, and subsequently subjected to a short temperature pulse. The adopted method is essentially an extension of the “laser-flash” technique, widely used for thermal diffusivity measurements, whereby, in addition, the heat capacity and, hence, the thermal conductivity, λ, are simultaneously evaluated from the pulse analysis. Results are presented for the thermal diffusivity and heat capacity of graphite, zirconia, and uranium dioxide up to temperatures above 3000 K.
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  • 44
    Digitale Medien
    Digitale Medien
    Springer
    International journal of thermophysics 21 (2000), S. 71-84 
    ISSN: 1572-9567
    Schlagwort(e): molten carbonates ; molten nitrate ; thermal conductivity ; thermal diffusivity ; transient short-hot-wire technique
    Quelle: Springer Online Journal Archives 1860-2000
    Thema: Physik
    Notizen: Abstract A transient short-hot-wire technique has been successfully used to measure the thermal conductivity and thermal diffusivity of molten salts (NaNO3, Li2CO3/K2CO3, and Li2CO3/Na2CO3) which are highly corrosive. This method was developed from the hot-wire technique and is based on two-dimensional numerical solutions of unsteady heat conduction from a short wire with the same length-to-diameter ratio and boundary conditions as those used in the actual experiments. In the present study, the wires are coated with a pure Al2O3 thin film by using a sputtering apparatus. The length and radius of the hot wire and the resistance ratio of the lead terminals and the entire probe are calibrated using water and toluene with known thermophysical properties. Using such a calibrated probe, the thermal conductivity and thermal diffusivity of molten nitrate are measured within errors of 3 and 20%, respectively. Also, the thermal conductivity of the molten carbonates can be measured within an error of 5%, although the thermal diffusivity can be measured within an error of 50%.
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  • 45
    Digitale Medien
    Digitale Medien
    Springer
    International journal of thermophysics 21 (2000), S. 217-248 
    ISSN: 1572-9567
    Schlagwort(e): linear working equation ; nonlinear working equation ; standard uncertainty ; thermal conductivity ; thermal diffusivity ; transient hot strip method
    Quelle: Springer Online Journal Archives 1860-2000
    Thema: Physik
    Notizen: Abstract The transient hot strip (THS) method can be used to measure simultaneously the thermal conductivity λ and diffusivity a of dielectrics within a few minutes. However, although the method has been known for 20 years, there is no complete assessment of its uncertainty. First, the underlying complex mathematical model makes any error analysis a tedious and complicated task. Secondly, the ISO Guide to the Expression of Uncertainty in Measurement does not apply directly because of the classical model's implicit character. In the present paper, the combined standard uncertainty u of the THS method has been determined by applying two different models. First, we start from the classical nonlinear model. The major sources of errors are analyzed, namely, the ideal model errors, the evaluation errors, and the measurement errors. Next, a newly developed numerical procedure combines all the components in a way that the resultant standard uncertainties of the nonlinear model, u(λ)/λ=2.6% and u(a)/a=11%, comply as closely as possible with the principles of the ISO Guide. Second, we start from the recently presented linear expression of the THS mathematical model that is briefly discussed. Since this approximation is explicit in both measurands, the uncertainties, u(λ)/λ=2.5% and u(a)/a=11%, are determined in full accordance with the ISO guide. The uncertainty in thermal conductivity is experimentally assessed against the standard reference CRM 039 (Pyrex). The results obtained are in excellent agreement with the theoretical values.
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  • 46
    Digitale Medien
    Digitale Medien
    Springer
    International journal of thermophysics 21 (2000), S. 525-534 
    ISSN: 1572-9567
    Schlagwort(e): ac calorimetric method ; thermal diffusivity ; thin film ; two-dimensional effect
    Quelle: Springer Online Journal Archives 1860-2000
    Thema: Physik
    Notizen: Abstract An ac calorimetric method for measuring the thermal diffusivity of thin-film materials has been widely applied. In the application of this method, the systematic errors caused by the heat loss effect, the edge reflection effect, etc., have been analyzed and corresponding correction methods have been developed. But when measuring films with low thermal diffusivity or with thickness comparable to the thermal diffusion length, a two-dimensional effect which will also result in a systematic error of the measurement is present. In this paper, the mechanism of two-dimensional heat conduction within a thin sample which is supplied a periodic heat flux by a chopped light beam is analyzed. A numerical analysis method is developed to study the effect of the two-dimensional heat conduction on the measured thermal diffusivity values. The relations between the measured thermal diffusivity and independent parameters such as frequency, thickness of sample, width of light spot, etc., are demonstrated to indicate the two-dimensional effect. The experimental precondition for minimizing the systematic error caused by the two-dimensional effect is determined. In addition, the analysis method presented in this paper should be useful for more difficult problems such as error estimation of the thermal diffusivity measurement of coatings or composite films.
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  • 47
    Digitale Medien
    Digitale Medien
    Springer
    International journal of thermophysics 19 (1998), S. 557-567 
    ISSN: 1572-9567
    Schlagwort(e): photothermal method ; scanning laser ; thermal conductivity ; thermal diffusivity ; thermoelectric effect ; thin film
    Quelle: Springer Online Journal Archives 1860-2000
    Thema: Physik
    Notizen: Abstract This work presents a scanning laser-based thermal diffusivity measurement technique for thin films as well as for bulk materials. In this technique, a modulated laser beam is focused through a transparent substrate onto the film–substrate interface. The generated thermal wave is detected using a fast-responding thermocouple formed between the sample surface and the tip of a sharp probe. By scanning the laser beam around the thermocouple, the amplitude and phase distributions of the thermal wave are obtained with micrometer resolution. The thermal diffusivity of the film is determined by fitting the obtained phase signal with a three-dimensional heat conduction model. Experimental results are presented for a 150-nm gold film evaporated on a glass substrate.
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  • 48
    Digitale Medien
    Digitale Medien
    Springer
    International journal of thermophysics 19 (1998), S. 569-577 
    ISSN: 1572-9567
    Schlagwort(e): bulk modulus ; electron-phonon coupling factor ; nonequilibrium heating ; platinum ; thermal diffusivity ; thin films
    Quelle: Springer Online Journal Archives 1860-2000
    Thema: Physik
    Notizen: Abstract Thermophysical and mechanical properties of thin films are investigated using ultrashort laser pulses (200 fs), which upon incidence create a temperature rise and generate an ultrasonic wave at the sample surface. By monitoring the thin film's reflectivity response after the deposition of radiation energy, the bulk modulus and thermal diffusivity normal to the surface can be extrapolated from a single data set. The resulting data show cooling profiles that vary greatly from the well-known Fourier diffusion model and agree favorably with the parabolic two-step heat diffusion model. This method can also be used to characterize electron–lattice energy coupling phenomena. Experimental results from bulk samples of copper and platinum as well as thin-film platinum were utilized to determine the values of the thermal diffusivity, bulk modulus, and electron–phonon coupling factor. In addition, the thin film platinum samples were studied with two substrates, silicon and glass, to gain more knowledge of the substrate's effect on transport properties.
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  • 49
    Digitale Medien
    Digitale Medien
    Springer
    International journal of thermophysics 19 (1998), S. 603-613 
    ISSN: 1572-9567
    Schlagwort(e): air ; interference ; photothermal deflection technique ; thermal diffusivity ; thermal wave
    Quelle: Springer Online Journal Archives 1860-2000
    Thema: Physik
    Notizen: Abstract The photothermal deflection technique applied to a gas thermal wave resonator seems to be one of the most powerful techniques to investigate in situ the thermal diffusivity of the gas. After a brief description of what a thermal wave resonator really is, a discussion is presented of the advantages and disadvantages of its use for measuring the gas thermal diffusivity.
    Materialart: Digitale Medien
    Standort Signatur Erwartet Verfügbarkeit
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  • 50
    Digitale Medien
    Digitale Medien
    Springer
    International journal of thermophysics 19 (1998), S. 1099-1109 
    ISSN: 1572-9567
    Schlagwort(e): photoacoustic detector ; thermal conductivity ; thermal diffusivity
    Quelle: Springer Online Journal Archives 1860-2000
    Thema: Physik
    Notizen: Abstract A resonant and a nonresonant photoacoustic detector were used to determine thermal diffusivities of gases. With a nonresonant detector thermal diffusivities can be determined in a wide range between 10−3 and 10−7 m2·s−1, whereas experiments with the resonant detector deliver thermal diffusivities in a range that is about a factor of 100 smaller. As refrigerants—HFCs, HCFCs, and hydrocarbons—are absorbents in the infrared at a wavelength of 3.39 μm, their thermal diffusivity can be determined without the addition of a trace gas, particularly at pressures below 0.01 MPa. At pressures above 0.1 MPa, the addition of ammonia as a trace gas is recommended. The absorption wavelength is then 1.531 μm. A simulation model for the nonresonant photoacoustic detector is presented for the design of a detector and for an extended error analysis.
    Materialart: Digitale Medien
    Standort Signatur Erwartet Verfügbarkeit
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  • 51
    Digitale Medien
    Digitale Medien
    Springer
    International journal of thermophysics 21 (2000), S. 487-493 
    ISSN: 1572-9567
    Schlagwort(e): ac calorimetric method ; CVD diamond film ; edge effect ; parameter estimation ; thermal diffusivity
    Quelle: Springer Online Journal Archives 1860-2000
    Thema: Physik
    Notizen: Abstract In the thermal diffusivity measurement of a CVD diamond film using an ac calorimetric method, the reflection of an ac temperature wave at the edge of the film sample should be considered due to the limited length of the sample and its high thermal diffusivity, i.e., the edge effect. In this case, the measured thermal diffusivity is given as a function of frequency. The relation between the measured thermal diffusivity and the frequency is represented as an analytical expression. The real thermal diffusivity is obtained by correcting the edge effect by two means. One is an iterative method using the directly measured edge length of the sample to fit the analytical expression. The other is a parameter estimation method by which a simplex method is used to estimate the edge length and the real thermal diffusivity. Thermal diffusivities of two diamond films were measured, and data were analyzed using the above methods. The result shows that the parameter estimation method is relatively accurate and convenient in processing test data.
    Materialart: Digitale Medien
    Standort Signatur Erwartet Verfügbarkeit
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  • 52
    Digitale Medien
    Digitale Medien
    Springer
    International journal of thermophysics 21 (2000), S. 543-552 
    ISSN: 1572-9567
    Schlagwort(e): antireflection coating ; parameter estimation ; photoacoustic effect ; thermal diffusivity ; through-plane
    Quelle: Springer Online Journal Archives 1860-2000
    Thema: Physik
    Notizen: Abstract In this study, we designed and developed two-layer antireflection (AR) optical coating samples on glass substrates, using different evaporation conditions of coating rates and substrate temperatures for two dielectric materials, MgF2 and ZnS, with different refractive indices. The through-plane thermal diffusivity of these systems was measured using the photoacoustic effect. The optical thicknesses of MgF2 and ZnS layers were fixed at 5λ/4 (λ=514.5 nm) and λ, respectively, and the thermal diffusivities of the samples were obtained from the measured amplitude of the photoacoustic signals by changing the chopping frequency of the Ar+ laser beam. The results demonstrated that the thermal diffusivity of the sample fabricated under the conditions of 10μÅ·s−1 and 150°C had the maximum value and that the results were directly related to the microstructure of the film system.
    Materialart: Digitale Medien
    Standort Signatur Erwartet Verfügbarkeit
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