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  • 04. Solid Earth::04.08. Volcanology::04.08.01. Gases  (22)
  • 01. Atmosphere::01.02. Ionosphere::01.02.99. General or miscellaneous  (19)
  • 01. Atmosphere::01.02. Ionosphere::01.02.05. Wave propagation  (12)
  • Physics
  • INGV  (52)
  • 2005-2009  (52)
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  • 1
    Publication Date: 2019-11-04
    Description: This paper focuses on the problem of invalid O/X polarization tagging of an ionogram and how this can affect ionogram autoscaling methods. To illustrate this problem, 623 ionograms recorded in March and April 2004 (days 080-105) by the digisonde 256 installed at Learmonth (22.3° S, 114.1° E) were considered. These ionograms, often characterized by very unreliable O/X polarization tagging of the echoes because of unresolved antenna issues, have been autoscaled by both ARTIST 4.2 and Autoscala. Results of comparisons between automatically and manually scaled foF2 data are shown for both programs, considering as acceptable an autoscaled value that lies within 0.5 MHz of the manual value. Autoscala values of foF2 agree with the manually-scaled values for ~99% of ionograms, while ARTIST values of foF2 agree with the manually-scaled values for ~75% of ionograms. While ARTIST was coded on the assumption of valid polarization tagging, the fact remains that it produces invalid results when equipment issues cause invalid tagging. Autoscaling procedures that do not use the polarization tagging will generally work better than ARTIST in such cases. However, these other procedures are susceptible to failure in other situations.
    Description: Published
    Description: 597-607
    Description: 1.7. Osservazioni di alta e media atmosfera
    Description: 3.9. Fisica della magnetosfera, ionosfera e meteorologia spaziale
    Description: JCR Journal
    Description: open
    Keywords: Ionospheric Monitoring ; Ionograms ; ARTIST ; Autoscala ; 01. Atmosphere::01.02. Ionosphere::01.02.05. Wave propagation ; 01. Atmosphere::01.02. Ionosphere::01.02.06. Instruments and techniques
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
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  • 2
    Publication Date: 2021-05-17
    Description: A comparison between two of the most used scintillation models and experimental data is presented. The experimental data have been derived from a GPS scintillation monitor developed at Cornell University and placed in Tucuman (Argentina), under the peak of the anomaly. The models used (GISM and WBMOD) have been run for the geophysical conditions corresponding to the measurements. The comparison is done by subdividing the information on the basis of an ionospheric grid of 5°×5° surface square boxes. The comparison has been performed for several local times, from 18 LT until 04 LT. Here, only a few cases of particular interest are shown. The goal is to understand if the models are able to forecast actual scintillation morphology (from the satellite navigation systems point of view) and if they could be used to yield an estimate of scintillation effects on satellite navigation systems.
    Description: Published
    Description: JCR Journal
    Description: open
    Keywords: ionospheric scintillations ; scintillation models ; GPS ; SBAS ; 01. Atmosphere::01.02. Ionosphere::01.02.99. General or miscellaneous ; 04. Solid Earth::04.03. Geodesy::04.03.99. General or miscellaneous
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
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  • 3
    Publication Date: 2020-11-12
    Description: Fluid geochemistry monitoring in the Azores involves the regular sampling and analysis of gas discharges from fumaroles and measurements of CO2 diffuse soil gas emissions. Main degassing areas under monitoring are associated with hydrothermal systems of active central volcanoes in S. Miguel, Terceira and Graciosa islands. Fumarole discharge analysis since 1991 show that apart from steam these gas emissions are CO2 dominated with H2S, H2, CH4 and N2 in minor amounts. Mapping of CO2 diffuse soil emissions in S. Miguel Island lead to the conclusion that some inhabited areas are located within hazard-zones. At Furnas village, inside Furnas volcano caldera, about 62% of the 896 houses are within the CO2 anomaly, 5% being in areas of moderate to high risk. At Ribeira Seca, on the north flank of Fogo volcano, few family houses were evacuated when CO2 concentrations in the air reached 8 mol%. To assess and analyse the CO2 soil flux emissions, continuous monitoring stations were installed in S. Miguel (2), Terceira and Graciosa islands. The statistical analysis of the data showed that some meteorological parameters influence the CO2 flux. The average of CO2 flux in S. Miguel stations ranges from 250 g/m2/d at Furnas volcano to 530 g/m2/d at Fogo volcano. At Terceira Island it is about 330 g/m2/d and at Graciosa 4400 g/m2/d.
    Description: Published
    Description: JCR Journal
    Description: open
    Keywords: volcanology ; geochemistry ; soil degassing ; monitoring ; risk ; 04. Solid Earth::04.08. Volcanology::04.08.01. Gases ; 04. Solid Earth::04.08. Volcanology::04.08.06. Volcano monitoring
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
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  • 4
    Publication Date: 2019-11-04
    Description: Various modern applications of empirical electron density models need realistic structures of the electron density distribution with smaller scales than the model background. Travelling Ionospheric Disturbances (TIDs) produce three dimensional and time dependent disturbances of the background ionization. We present a TID model suitable to «modulate» large scale electron density distributions by multiplication. A model TID takes into account the forward tilt of the disturbance wave front, a distinct vertical structure, a fan type horizontal radiation characteristic, geometric dilution and attenuation. More complicated radiation patterns can be constructed by means of superposition. The model TIDs originate from source regions which can be chosen arbitrarily. We show examples for TID modulations of the background model family developed at Trieste and Graz (NeQuick, COSTprof and NeUoG-plas).
    Description: Published
    Description: JCR Journal
    Description: open
    Keywords: ionosphere ; electron density models ; Travelling Ionospheric Disturbances ; TID model ; 01. Atmosphere::01.02. Ionosphere::01.02.99. General or miscellaneous ; 01. Atmosphere::01.02. Ionosphere::01.02.05. Wave propagation
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  • 5
    Publication Date: 2019-11-04
    Description: Noble gas solubility in silicate melts and glasses has gained a crucial role in Earth Sciences investigations and in the studies of non-crystalline materials on a micro to a macro-scale. Due to their special geochemical features, noble gases are in fact ideal tracers of magma degassing. Their inert nature also allows them to be used to probe the structure of silicate melts. Owing to the development of modern high pressure and temperature technologies, a large number of experimental investigations have been performed on this subject in recent times. This paper reviews the related literature, and tries to define our present state of knowledge, the problems encountered in the experimental procedures and the theoretical questions which remain unresolved. Throughout the manuscript I will also try to show how the thermodynamic and structural interpretations of the growing experimental dataset are greatly improving our understanding of the dissolution mechanisms, although there are still several points under discussion. Our improved capability of predicting noble gas solubilities in conditions closer to those found in magma has allowed scientists to develop quantitative models of magma degassing, which provide constraints on a number of questions of geological impact. Despite these recent improvements, noble gas solubility in more complex systems involving the main volatiles in magmas, is poorly known and a lot of work must be done. Expertise from other fields would be extremely valuable to upcoming research, thus focus should be placed on the structural aspects and the practical and commercial interests of the study of noble gas solubility.
    Description: Published
    Description: JCR Journal
    Description: open
    Keywords: noble gases ; solubility ; degassing ; silicate melts ; 04. Solid Earth::04.08. Volcanology::04.08.01. Gases
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  • 6
    Publication Date: 2019-11-04
    Description: We present an empirical model of sulphur solubility that allows us to calculate f S2 if P, T, fO2 and the melt composition, including H2O and S, are known. The model is calibrated against three main experimental data bases consisting in both dry and hydrous silicate melts. Its prime goal is to calculate the f S2 of hydrous basalts that currently lack experimental constraints of their sulphur solubility behaviour. Application of the model to Stromboli, Vesuvius, Vulcano and Etna eruptive products shows that the primitive magmas found at these volcanoes record f S2 in the range 0.1-1 bar. In contrast, at all volcanoes the magmatic evolution is marked by dramatic variations in f S2 that spreads over up to 9 orders of magnitude. The f S2 can either increase during differentiation or decrease during decompression to shallow reservoirs, and seems to be related to closed versus open conduit conditions, respectively. The calculated f S2 shows that the Italian magmas are undersaturated in a FeS melt, except during closed conduit conditions, in which case differentiation may eventually reach conditions of sulphide melt saturation. The knowledge of f S2, fO2 and fH2O allows us to calculate the fluid phase composition coexisting with magmas at depth in the C-O-H-S system. Calculated fluids show a wide range in composition, with CO2 mole fractions of up to 0.97. Except at shallow levels, the fluid phase is generally dominated by CO2 and H2O species, the mole fractions of SO2 and H2S rarely exceeding 0.05 each. The comparison between calculated fluid compositions and volcanic gases shows that such an approach should provide constraints on both the depth and mode of degassing, as well as on the amount of free fluid in magma reservoirs. Under the assumption of a single step separation of the gas phase in a closed-system condition, the application to Stromboli and Etna suggests that the main reservoirs feeding the eruptions and persistent volcanic plumes at these volcanoes might contain as much as 5 wt% of a free fluid phase. Consideration of the magma budget needed to balance the amounts of volatiles emitted in the light of these results shows that the amount of nonerupted magma could be overestimated by as much as one order of magnitude.
    Description: Published
    Description: JCR Journal
    Description: open
    Keywords: sulphur ; hydrous basalts ; volcanic gas ; 04. Solid Earth::04.08. Volcanology::04.08.01. Gases ; 04. Solid Earth::04.08. Volcanology::04.08.03. Magmas ; 04. Solid Earth::04.08. Volcanology::04.08.07. Instruments and techniques
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  • 7
    Publication Date: 2019-11-04
    Description: A compendium of diffusion measurements and their Arrhenius equations for water, carbon dioxide, sulfur, fluorine, and chlorine in silicate melts similar in composition to natural igneous rocks is presented. Water diffusion in silicic melts is well studied and understood, however little data exists for melts of intermediate to basic compositions. The data demonstrate that both the water concentration and the anhydrous melt composition affect the diffusion coefficient of water. Carbon dioxide diffusion appears only weakly dependent, at most, on the volatilefree melt composition and no effect of carbon dioxide concentration has been observed, although few experiments have been performed. Based upon one study, the addition of water to rhyolitic melts increases carbon dioxide diffusion by orders of magnitude to values similar to that of 6 wt% water. Sulfur diffusion in intermediate to silicic melts depends upon the anhydrous melt composition and the water concentration. In water-bearing silicic melts sulfur diffuses 2 to 3 orders of magnitude slower than water. Chlorine diffusion is affected by both water concentration and anhydrous melt composition; its values are typically between those of water and sulfur. Information on fluorine diffusion is rare, but the volatile-free melt composition exerts a strong control on its diffusion. At the present time the diffusion of water, carbon dioxide, sulfur and chlorine can be estimated in silicic melts at magmatic temperatures. The diffusion of water and carbon dioxide in basic to intermediate melts is only known at a limited set of temperatures and compositions. The diffusion data for rhyolitic melts at 800°C together with a standard model for the enrichment of incompatible elements in front of growing crystals demonstrate that rapid crystal growth, greater than 10-10 ms-1, can significantly increase the volatile concentrations at the crystal-melt interface and that any of that melt trapped by the formation of melt inclusions may not be representative of the bulk melt. However, basaltic melt inclusions trapped at 1300°C are more likely to contain bulk melt concentrations of water and carbon dioxide.
    Description: Published
    Description: JCR Journal
    Description: open
    Keywords: diffusion ; silicate melts ; volatiles ; water ; carbon dioxide ; sulfur ; fluorine ; igneous processes ; chlorine ; melt inclusion ; 04. Solid Earth::04.08. Volcanology::04.08.01. Gases ; 04. Solid Earth::04.08. Volcanology::04.08.03. Magmas
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  • 8
    Publication Date: 2019-11-04
    Description: We have characterized the textures of pumice clasts from Phlegraean Fields to gain insights into the conduit flow-dynamics of alkaline explosive eruptions. Vesicularities, vesicle number densities, and vesicle sizes and shapes were measured to obtain the bulk and groundmass properties of the juvenile fraction of Campanian Ignimbrite (CI) and Agnano Monte Spina (AMS) eruptions. The results report the coexistence of three end-member pumice types in the deposits of both eruptions, 1) microvesicular, 2) tube and 3) expanded, which differ according to clast morphology and the macro- to microscopic vesicle texture. Vesicularities (0.85-0.94 for CI, 0.51-0.91 for AMS) and vesicle number densities (2-4×105 cm-2 in CI, 3×105-106 cm-2 in AMS) span quite a wide range in all the three pumice types. Overall, tube pumices exhibit the highest bulk (0.89) and groundmass (CI 0.85, AMS 0.82) average vesicle volume fractions but the lowest average vesicle number densities (CI 2×105, AMS 4×105 cm-2). Comparison with textures of calc-alkaline pumices has revealed many similarities and points to a common origin and distribution of the products from both magma compositions within the volcanic conduit. In addition, the results of the textural analysis were interpreted in the light of the conduit flow modeling of Phlegraean Fields eruptions. The comparison of textural observations with results from simulations of conduit magma ascent has exhibited a good agreement between measured and numerically calculated vesicularities for both compositions, helping to constrain the overall dynamics of alkaline versus calc-alkaline eruptions.
    Description: Published
    Description: JCR Journal
    Description: open
    Keywords: Phlegraean Fields ; Plinian eruptions ; vesicle textures ; magma ascent dynamics ; 04. Solid Earth::04.08. Volcanology::04.08.01. Gases ; 04. Solid Earth::04.08. Volcanology::04.08.05. Volcanic rocks ; 04. Solid Earth::04.08. Volcanology::04.08.07. Instruments and techniques
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  • 9
    Publication Date: 2019-11-04
    Description: Volatile components in magma strongly influence many physical properties of melts and minerals. The temperature resolved degassing analysis of volcanic crystalline and vitreous rocks gives detailed information about volatile compounds in the melt. Aspecial high-temperature mass-spectrometry device in combination with a thermo-balance allows a quantitative determination of different volatile species. It enables a differentiation between the primary gas content in the magma and the gas released from decomposition of secondary alteration products. The gas release profiles give the following indications: i) during the littoral explosions of Pahoehoe lava the content of volatiles is not changed by interaction with air or sea water; ii) the degassing profiles of vitreous black sand verify the primary content of volatiles in the erupted melt, only CO2 was detected; iii) the oxygen release profile gives significant indications for oxygen undersaturation of the erupted magma; iv) remelting of black sand in air at 1450°C for 0.45 h causes an oxygen saturation of the basaltic melt; v) remelting of black sand in argon atmosphere confirms the oxygen undersaturation of the melt; vi) remelting of black sand-black shale mixtures affects a significant change in the degassing profiles, especially in CO2-release. With the first investigations we can demonstrate that gas release curves of volcanic rocks are qualified for a) detection of the primary gas content of erupted magma; b) detection of alteration processes of the igneous glass; c) detection of contamination of the magma with adjacent rocks.
    Description: Published
    Description: JCR Journal
    Description: open
    Keywords: volatiles ; magmatic rocks ; basaltic glass ; degassing ; Hawaiian lava ; remelting ; blacksand ; 04. Solid Earth::04.08. Volcanology::04.08.01. Gases ; 04. Solid Earth::04.08. Volcanology::04.08.03. Magmas
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  • 10
    Publication Date: 2019-11-04
    Description: The EQ3/6 software package, version 7.2 was successfully used to model scrubbing of magmatic gas by pure water at 0.1 MPa, in the liquid and liquid-plus-gas regions. Some post-calculations were necessary to account for gas separation effects. In these post-calculations, redox potential was considered to be fixed by precipitation of crystalline a-sulfur, a ubiquitous and precocious process. As geochemical modeling is constrained by conservation of enthalpy upon water-gas mixing, the enthalpies of the gas species of interest were reviewed, adopting as reference state the liquid phase at the triple point. Our results confirm that significant emissions of highly acidic gas species (SO2(g), HCl(g), and HF(g)) are prevented by scrubbing, until dry conditions are established, at least locally. Nevertheless important outgassing of HCl(g) can take place from acid, HCl-rich brines. Moreover, these findings support the rule of thumb which is generally used to distinguish SO2-, HCl-, and HF-bearing magmatic gases from SO2-, HCl-, and HF-free hydrothermal gases.
    Description: Published
    Description: JCR Journal
    Description: open
    Keywords: magmatic gas ; magma degassing ; hydrothermalsystem ; crater lake ; meteoric water ; scrubbing ; reaction path modeling ; 04. Solid Earth::04.08. Volcanology::04.08.01. Gases
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  • 11
    Publication Date: 2019-11-04
    Description: An overview of novel laser techniques suitable for volcanic monitoring, based on different kinds of infrared laser sources, is presented. Their main advantages and drawbacks are discussed focusing on the achievable sensitivity and precision levels in analysis of gaseous species. Some of the most recent experimental results obtained in laboratory development as well as in field tests of home-built laser spectrometers are reported. New perspectives in optical devices aimed at geochemical and geophysical applications are also considered.
    Description: Published
    Description: JCR Journal
    Description: open
    Keywords: diode laser ; absorption spectroscopy ; optical fiber ; 04. Solid Earth::04.08. Volcanology::04.08.01. Gases ; 04. Solid Earth::04.08. Volcanology::04.08.07. Instruments and techniques
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  • 12
    Publication Date: 2019-11-04
    Description: Thermodynamic modelling of magmatic gases shows that SiF4 may be an important F-bearing species at the high pressures typical of magma reservoirs. Upon decompression during degassing, SiF4 will react with water vapour to form HF and silica. Common magmatic gases of high-T fumaroles seem to contain too little SiF4 to be a significant source of silica, except if extremely large amounts of gas percolate through a small volume of rock, as is the case in lava domes. Only if fluorine contents of the gases exceed 1 mol% detectable amounts of silica may be formed, but such high fluorine contents have not yet been observed in natural gases. Alternatively, silica may be formed by heating of cool SiF4-rich gases circulating in cooling lava bodies. We suggest that these mechanisms may be responsible for the deposition of crystalline silica, most probably cristobalite, observed in vesicles in lavas from Lewotolo volcano (Eastern Sunda Arc, Indonesia). Silica occurs as vapour-crystallised patches in vesicles, and is sometimes associated with F-phlogopite, which further supports F-rich conditions during deposition. Because of the connection between F-rich conditions and high-K volcanism, we propose that late-stage gaseous transport and deposition of silica may be more widespread in K-rich volcanoes than elsewhere, and long-term exposure to ash from eruptions of such volcanoes could therefore carry an increased risk for respiratory diseases. The dependence of SiF4/HF on temperature reported here differs from the current calibration used for temperature measurements of fumarolic gases by remote sensing techniques, and we suggest an updated calibration.
    Description: Published
    Description: JCR Journal
    Description: open
    Keywords: SiF4 ; vapour crystallisation ; silica ; degassing ; 04. Solid Earth::04.08. Volcanology::04.08.01. Gases ; 04. Solid Earth::04.08. Volcanology::04.08.04. Thermodynamics
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  • 13
    Publication Date: 2019-11-04
    Description: An Eulerian model for passive gas dispersion based on the K-theory for turbulent diffusion, coupled with a mass consistent wind model is presented. The procedure can be used to forecast gas concentration over large and complex terrains. The input to the model includes the topography, wind measurements from meteorological stations, atmospheric stability information and gas flow rate from the ground sources. Here, this model is applied to study the distribution of the CO2 discharged from the hot sources of the Solfatara Volcano, Naples, Italy, where the input data were measured during a 15 day campaign in June 2001 carried out to test an Eddy Covariance (EC) station by Osservatorio Vesuviano-INGV, Naples.
    Description: Published
    Description: JCR Journal
    Description: open
    Keywords: gas dispersion ; volcanic gas ; K-theory ; computer model ; 04. Solid Earth::04.08. Volcanology::04.08.01. Gases
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  • 14
    Publication Date: 2019-11-04
    Description: The paper addresses some fundamental aspects of the dynamics of dense granular flows down inclines relevant to pyroclastic density currents. A simple mechanistic framework is presented to analyze the dynamics of the frontal zone, with a focus on the establishment of conditions that promote air entrainment at the head of the current and motion-induced self-fluidization of the flow. The one-dimensional momentum balance on the current along the incline is considered under the hypothesis of strongly turbulent flow and pseudo-homogeneous behaviour of the two-phase gas-solid flow. Departures from one-dimensional flow in the frontal region are also analyzed and provide the key to the assessment of air cross-flow and fluidization of the solids in the head of the current. The conditions for the establishment of steady motion of pyroclastic flows down an incline, in either the fluidized or «dry» granular states, are examined.
    Description: Published
    Description: JCR Journal
    Description: open
    Keywords: pyroclastic flow ; fluidization ; gravity current ; 04. Solid Earth::04.08. Volcanology::04.08.01. Gases
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  • 15
    Publication Date: 2019-11-04
    Description: Large deviations in the direction of arrival of ionospherically propagating radio signals from the Great Circle Path (GCP) have serious implications for the planning and operation of communications and radiolocation systems operating within the HF-band. Very large deviations are particularly prevalent in the polar and sub-auroral regions where signals often arrive at the receiver with bearings displaced from the great circle direction by up to ±100° or more. Measurements made over several paths are presented in this paper, and the principle causes of off-great circle propagation outlined. Significant progress has been made in modelling the propagation effects and work is now in hand to incorporate the results into tools to aid the planning and operation of HF radio systems operating at northerly latitudes.
    Description: Published
    Description: JCR Journal
    Description: open
    Keywords: 01. Atmosphere::01.02. Ionosphere::01.02.05. Wave propagation
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  • 16
    Publication Date: 2019-11-04
    Description: The aim of this work within the WP 3.1 of the COST 271 Action is the characterization of the variability introduced in the F-region ionosphere by -Planetary Wave Signatures- (PWS) and -Gravity Wave Signatures- (GWS). Typical patterns of percentage of time occurrence and time duration of PWS, their climatology and main drivers, as well as their vertical and longitudinal structure have been obtained. Despite the above characterization, the spectral distribution of event duration is too broad to allow for a reasonable prediction of PWS from ionospheric measurements themselves. GWS with a regular morning/evening wave bursts and specific GWS events whose arising can be predicted have been evaluated. As above, their typical pattern of occurrence and time duration, and their vertical structure have been obtained. The latter events remain in the ionospheric variability during disturbed days while additional wave enhancements of auroral origin occur. However, both types of disturbances can be distinguished.
    Description: Published
    Description: JCR Journal
    Description: open
    Keywords: 01. Atmosphere::01.02. Ionosphere::01.02.05. Wave propagation
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  • 17
    Publication Date: 2019-11-04
    Description: Investigation of the relationship between TEC and (foF2)2 shows that although they are highly correlated, a «hysteresis» effect exists between them. The slab thickness is greater before than after mid-day for equal cos ?values. Moreover, a comparison of the calculated upper and lower quartiles of variability in TEC, foF2 and Nmax, respectively shows that the variability of TEC lies between those of foF2 and Nmax depending on the level of solar activity.
    Description: Published
    Description: JCR Journal
    Description: open
    Keywords: ionospheric variability ; radio wave propagation ; space and satellite communications ; 01. Atmosphere::01.02. Ionosphere::01.02.05. Wave propagation
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  • 18
    Publication Date: 2019-11-04
    Description: The paper reviews the work done in the course of the COST 271 Action concerned with the development of tools and methods for forecasting, nowcasting and warning of ionospheric propagation conditions. Three broad categories of work are covered. First, the maintenance and enhancement of existing operational services that provide forecast or nowcast data products to end users; brief descriptions of RWC Warsaw and the STIF service are given. Second, the development of prototype or experimental services; descriptions are given of a multi-datasource system for reconstruction of electron density profiles, and a new technique using real-time IMF data to forecast ionospheric storms. The third category is the most wide-ranging, and deals with work that has presented new or improved tools or methods that future operational forecasting or nowcasting system will rely on. This work covers two areas - methods for updating models with prompt data, and improvements in modelling or our understanding of various ionospheric-magnetospheric features - and ranges over updating models of ionospheric characteristics and electron density, modelling geomagnetic storms, describing the spatial evolution of the mid-latitude trough, and validating a recently-proposed technique for deriving TEC from ionosonde observations.
    Description: Published
    Description: JCR Journal
    Description: open
    Keywords: 01. Atmosphere::01.02. Ionosphere::01.02.03. Forecasts ; 01. Atmosphere::01.02. Ionosphere::01.02.05. Wave propagation ; 01. Atmosphere::01.02. Ionosphere::01.02.06. Instruments and techniques
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  • 19
    Publication Date: 2019-11-04
    Description: Results derived from analysing the ionosphere response to faint and bright solar flares are presented. The analysis used technology of a global detection of ionospheric effects from solar flares as developed by the authors, on the basis of phase measurements of the Total Electron Content (TEC) in the ionosphere using an international GPS network. The essence of the method is that use is made of appropriate filtering and a coherent processing of variations in the TEC which is determined from GPS data, simultaneously for the entire set of visible GPS satellites at all stations used in the analysis. This technique is useful for identifying the ionospheric response to faint solar flares (of X-ray class C) when the variation amplitude of the TEC response to separate line-on-sight to GPS satellite is comparable to the level of background fluctuations. The dependence of the TEC variation response amplitude on the bright flares location on the Sun is investigated
    Description: Published
    Description: JCR Journal
    Description: open
    Keywords: ionopshere ; Total Electron Content ; 01. Atmosphere::01.02. Ionosphere::01.02.99. General or miscellaneous
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  • 20
    Publication Date: 2019-11-04
    Description: The purpose of this paper is to review shortly some observational backgrounds for the suggestion of a genuine link between processes in the lower atmosphere and ionospheric response. Attention is concentrated on the waves which are thought to couple the lower atmosphere with the thermosphere/ionosphere system.
    Description: Published
    Description: JCR Journal
    Description: open
    Keywords: Lower atmosphere ; ionospheric response ; waves ; thermosphere ; 01. Atmosphere::01.02. Ionosphere::01.02.05. Wave propagation
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  • 21
    Publication Date: 2019-11-04
    Description: The deviations of hourly f 0 F 2 from monthly medians for 20 stations in Europe during the period 1958-1998 are studied. Spectral analysis is used to show that, both for original data (for each hour) and for the deviations from monthly medians, the deterministic components are the harmonics of 11 years (solar cycle), 1 year and its harmonics, 27 days and 12 h 50.49 m (2nd harmonic of lunar rotation period L 2 ) periodicities. Using histograms for one year samples, it is shown that the deviations from monthly medians are nearly zero mean (mean 〈 0.5) and approximately Gaussian (relative difference range between %10 to %20) and their standard deviations are larger for daylight hours (in the range 5-7). It is shown that the amplitude distribution of the positive and negative deviations is nearly symmetrical at night hours, but asymmetrical for day hours. The positive and negative deviations are then studied separately and it is observed that the positive deviations are nearly independent of R12 except for high latitudes, but negative deviations are modulated by R12 . The 90% confidence interval for negative deviations for each station and each hour is computed as a linear model in terms of R12. After correction for local time, it is shown that for all hours the confidence intervals increase with latitude but decrease above 60N. Long-term trend analysis showed that there is an increase in the amplitude of positive deviations from monthly means irrespective of the solar conditions. Using spectral analysis it is also shown that the seasonal dependency of negative deviations is more accentuated than the seasonal dependency of positive deviations especially at low latitudes. In certain stations, it is also observed that the 4th harmonic of 1 year corresponding to a periodicity of 3 months, which is missing in f 0 F 2 data, appears in the spectra of negative variations.
    Description: Published
    Description: JCR Journal
    Description: open
    Keywords: deviations ; solar cycle ; 01. Atmosphere::01.02. Ionosphere::01.02.99. General or miscellaneous
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  • 22
    Publication Date: 2019-11-04
    Description: In this paper hourly daily F2-layer critical frequency data recorded at Rome and one minute daily TEC data recorded at Florence were used and the relevant variabiles were calculated. It was concluded that there was no clear evidence as to how they correlated. In order to obtain a measure of the f 0 F 2 and TEC variability, the normalised differences df0 F2 and d TEC from the relevant monthly median values were also considered. Since no clear evidence could be obtained as of how df0 F2 and d TEC correlate, a new parameter, the ?Ap /?R ratio was tried. ?Ap was taken as the difference between the maximum value of Ap measured at the relevant disturbance and that corresponding at the beginning of the disturbance. ?R corresponded to the two above mentioned values of Ap. This parameter was compared to the differences of the corresponding df0 F2 values called ?df and d TEC values called ?dT. In wintertime, when ?A p /? R was negative, for the vast majority of the occurrences either ?df or ?dT was negative; ?df and ?dT were never observed to be negative at the same time whereas they were both positive in fewer than 10% of the observations. When ?A p /?R was positive then either ?df or ?dT were negative. In summertime when ?A p /?R was negative both ?df and ?dT were negative. When ?A p /?R was positive, while a positive ?df corresponded almost always to a positive ?dT, a negative ?df would equiprobably indicate either a positive or a negative ?dT.
    Description: Published
    Description: JCR Journal
    Description: open
    Keywords: ionopshere ; ionospheric modelling ; 01. Atmosphere::01.02. Ionosphere::01.02.99. General or miscellaneous
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  • 23
    Publication Date: 2019-11-04
    Description: High-resolution vertical electron density true height profiles from Athens Digisonde are used to calculate the electron content up to the peak of the F 2 layer (bottomside electron content) and also the topside electron content up to 1000 km, using the Huang-Reinisch method, to investigate the relative behavior of these two parameters during storm events. It was shown that the topside electron content represents roughly the 2/3 of the total electron content of the ionosphere and it is strongly affected by the geomagnetic activity, much more than the bottomside electron content. During daylight hours the values of the topside electron content exhibit intense fluctuations, while they become smoother in nature during events of night-time F 2 layer uplifting caused by the auroral activity. All these facts demonstrate that the Huang-Reinisch method provides a realistic tool for monitoring the variations of the ionospheric ionisation at a given location and it could be used in the frames of a world wide effort for the development of realistic models to accurately predict the electron content and to support effectively earth-space communications including navigation systems.
    Description: Published
    Description: JCR Journal
    Description: open
    Keywords: bottom side electron content ; topside electron content ; ionispheric storm effect ; 01. Atmosphere::01.02. Ionosphere::01.02.99. General or miscellaneous
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  • 24
    Publication Date: 2019-11-04
    Description: Much uncertainty currently exists in the use by different workers of the term variability in describing the results of statistical analyses applied to ionospheric measurement data sets and in their relationships with various existing or new ionospheric models. Often it is not clear whether data for different time periods or different geographical areas, and if so which, are being used to formulate results. Terms are presented in the Annex which it is suggested should be used, at least once in every publication addressing this topic, to describe unambiguously what is talked about. The background to the proposed terminology is discussed. Options for variability parameters are also addressed.
    Description: Published
    Description: JCR Journal
    Description: open
    Keywords: ionosphere ; ionospheroc terminology ; space and time variation ; 01. Atmosphere::01.02. Ionosphere::01.02.99. General or miscellaneous
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  • 25
    Publication Date: 2019-11-04
    Description: Proposals are made for Earth-space and space-space paths to apply the term propagation degradation probability, analogous to basic circuit reliability adopted within the Radiocommunication Sector of the International Telecommunication Union (ITU-R) to quantify the performance of HF terrestrial ionospheric radio circuits. The principal elements characterising propagation impairments are described and formulae and a table given by the ITU-R are reproduced relating many of these effects to the path total electron content. Expressions are provided enabling estimates of the probabilities of occurrence of user-specified extreme values to be estimated in terms of their median quantities and day-to-day variabilities. The need is stressed for additional data collection and analyses both to refine the median values and to derive the required reference variability factors.
    Description: Published
    Description: JCR Journal
    Description: open
    Keywords: ionosphere ; ionospheric propagation ; 01. Atmosphere::01.02. Ionosphere::01.02.05. Wave propagation
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  • 26
    Publication Date: 2019-11-04
    Description: A critical part of the vertical ionospheric electron concentration profile is the region above its maximum (topside ionosphere) and many attempts have been made to model this region because of the limited experimental data available. Recently, many topside electron concentration profiles obtained with the Intercosmos-19 satellite became accessible through the Internet. The period analyzed corresponds to March 1979 - December 1980, a time interval of high solar activity. The present work describes the comparison of these profiles with the IRI and NeQuick model profiles obtained by driving the models with the values of the maximum electron concentration and its height given by the satellite.
    Description: Published
    Description: JCR Journal
    Description: open
    Keywords: ionospheric electron ; comparison profiles ; 01. Atmosphere::01.02. Ionosphere::01.02.99. General or miscellaneous
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  • 27
    Publication Date: 2019-11-04
    Description: Recently an increasing number of topside electron density profiles has been made available to the scientific community on the Internet. These data are important for ionospheric modeling purposes, since the experimental information on the electron density above the ionosphere maximum of ionization is very scarce. The present work compares NeQuick and IRI models with the topside electron density profiles available in the databases of the ISIS2, IK19 and Cosmos 1809 satellites. Experimental electron content from the F2 peak up to satellite height and electron densities at fixed heights above the peak have been compared under a wide range of different conditions. The analysis performed points out the behavior of the models and the improvements needed to be assessed to have a better reproduction of the experimental results. NeQuick topside is a modified Epstein layer, with thickness parameter determined by an empirical relation. It appears that its performance is strongly affected by this parameter, indicating the need for improvements of its formulation. IRI topside is based on Booker's approach to consider two parts with constant height gradients. It appears that this formulation leads to an overestimation of the electron density in the upper part of the profiles, and overestimation of TEC.
    Description: Published
    Description: JCR Journal
    Description: open
    Keywords: topside ionosphere ; electron density models ; topside soundings ; 01. Atmosphere::01.02. Ionosphere::01.02.99. General or miscellaneous
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  • 28
    Publication Date: 2019-11-04
    Description: The paper reviews recent progress in the development of radio tomographic imaging of the ionized atmosphere, particularly in relation to the use of the technique to assist in the mitigation of propagation effects on practical radio systems.
    Description: Published
    Description: JCR Journal
    Description: open
    Keywords: ionospheric tomography ; total electron content ; ionospheric propagation ; ionospheric modeling ; 01. Atmosphere::01.02. Ionosphere::01.02.05. Wave propagation
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  • 29
    Publication Date: 2019-11-04
    Description: The ionospheric electron density model NeQuick is a «profiler» which uses the peaks of the E-layer, the F1-layer and the F2-layer as anchor points. In the version prepared for and submitted to the International Telecommunication Union (ITU) the model uses the ITU-R (CCIR) maps for foF2 and M(3000)F2 and adapted maps similar to the ITU-R ones for foE and foF1. Since users found problematic behaviour of NeQuick under conditions of strong differences of foE and foF2 map structures, the profiling was adapted by changing the properties of the Epstein layers used for this purpose. The new formulation avoids both strange horizontal structures of the geographic distribution of electron density in fixed heights and unrealistic peculiarities of the height profile which occasionally occurred with the old version of the model. Since the Epstein layer approach allows for 8 parameters only (3 layer amplitudes and 5 semi-thicknesses) the adaptation was no minor task but needed careful planning of suitable strategies.
    Description: Published
    Description: JCR Journal
    Description: open
    Keywords: ionosphere ; electron density models ; profilers ; 01. Atmosphere::01.02. Ionosphere::01.02.99. General or miscellaneous ; 01. Atmosphere::01.02. Ionosphere::01.02.03. Forecasts
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  • 30
    Publication Date: 2019-11-04
    Description: Phase equilibrium relationships in igneous systems can be estimated using empirical mathematical models based on multi-component regular solution formulae. Although these provide useable results within the fitted region, they can give very misleading values outside the compositional range of curve fitting. Moreover, they usually give poor estimates of the well-characterized melting relations of simple systems and do not relate to the large body of thermodynamic activity data available in the metallurgical literature, nor to spectroscopic, diffraction or computational models of silicate melt properties. The aim of this paper is to extend previous acid-base models of silicate melts and to use a quasi-chemical model to calculate the activities of quasi-chemical silicate mixing units, or structons, from combinations of the oxo-species used in quasi-chemical and polymer models to calculate oxide activities in metallurgy.
    Description: Published
    Description: JCR Journal
    Description: open
    Keywords: silicate melt ; acid-base ; oxide melt ; thermodynamic properties ; 04. Solid Earth::04.08. Volcanology::04.08.01. Gases ; 04. Solid Earth::04.08. Volcanology::04.08.04. Thermodynamics
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  • 31
    Publication Date: 2019-11-04
    Description: The Thermodynamics of quasi-chemical and polymeric models are briefly reviewed. It is shown that the two classes are mutually consistent, and that opportune conversion of the existing quasi-chemical parameterization of binary interactions in MO-SiO2 joins to polymeric models may be afforded without substantial loss of precision. It is then shown that polymeric models are extremely useful in deciphering the structural and reactive properties of silicate melts and glasses. They not only allow the Lux-Flood character of the dissolved oxides to be established, but also discriminate subordinate strain energy contributions to the Gibbs free energy of mixing from the dominant chemical interaction terms. This discrimination means that important information on the short-, medium- and long-range periodicity of this class of substances can be retrieved from thermodynamic analysis. Lastly, it is suggested that an important step forward in deciphering the complex topology of the inhomogeneity ranges observed at high SiO2 content can be performed by applying SCMF theory and, particularly, Matsen-Schick spectral analysis, hitherto applied only to rubberlike materials.
    Description: Published
    Description: JCR Journal
    Description: open
    Keywords: silicate melts ; structure ; entropy ; unmixing ; 04. Solid Earth::04.08. Volcanology::04.08.01. Gases ; 04. Solid Earth::04.08. Volcanology::04.08.04. Thermodynamics
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  • 32
    Publication Date: 2019-11-04
    Description: In order to describe and quantify the reactivity of silicate melts, the ionic notation provided by the Temkin formalism has been historically accepted, giving rise to the study of melt chemical equilibria in terms of completely dissociated ionic species. Indeed, ionic modelling of melts works properly as long as the true extension of the anionic matrix is known. This information may be attained in the framework of the Toop-Samis (1962a,b) model, through a parameterisation of the acid-base properties of the dissolved oxides. Moreover, by combining the polymeric model of Toop and Samis with the «group basicity» concept of Duffy and Ingram (1973, 1974a,b, 1976) the bulk optical basicity (Duffy and Ingram, 1971; Duffy, 1992) of molten silicates and glasses can be split into two distinct contributions, i.e. the basicity of the dissolved basic oxides and the basicity of the polymeric units. Application to practical cases, such as the assessment of the oxidation state of iron, require bridging of the energetic gap between the standard state of completely dissociated component (Temkin standard state) and the standard state of pure melt component at P and T of interest. On this basis it is possible to set up a preliminary model for iron speciation in both anhydrous and hydrous aluminosilicate melts. In the case of hydrous melts, I introduce both acidic and basic dissociation of the water component, requiring the combined occurrence of H+ cations, OH- free anions and, to a very minor extent, of T-OH groups. The amphoteric behaviour of water revealed by this study is therefore in line with the earlier prediction of Fraser (1975).
    Description: Published
    Description: JCR Journal
    Description: open
    Keywords: polymerisation ; basicity ; oxidationstate ; water speciation ; Temkin model ; 04. Solid Earth::04.08. Volcanology::04.08.01. Gases ; 04. Solid Earth::04.08. Volcanology::04.08.04. Thermodynamics
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  • 33
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    Publication Date: 2019-11-04
    Description: The strong influence of physical conditions during magma formation on Fe equilibria offers a large variety of possibilities to deduce these conditions from Fe-bearing phases and phase assemblages found in magmatic rocks. Conditions of magma genesis and their evolution are of major interest for the understanding of volcanic eruptions. A brief overview on the most common methods used is given together with potential problems and limitations. Fe equilibria are not only sensitive to changes in intensive parameters (especially T and fO2) and extensive parameters like composition also have major effects, so that direct application of experimentally calibrated equilibria to natural systems is not always possible. Best estimates for pre-eruptive conditions are certainly achieved by studies that relate field observations directly to experimental observations for the composition of interest using as many constraints as possible (phase stability relations, Fe-Ti oxides, Fe partitioning between phases, Fe oxidation state in glass etc.). Local structural environment of Fe in silicate melts is an important parameter that is needed to understand the relationship between melt transport properties and melt structure. Assignment of Fe co-ordination and its relationship to the oxidation state seems not to be straightforward. In addition, there is considerable evidence that the co-ordination of Fe in glass differs from that in the melt, which has to be taken into account when linking melt structure to physical properties of silicate melts at T and P.
    Description: Published
    Description: JCR Journal
    Description: open
    Keywords: iron ; silicate melt ; redox conditions ; 04. Solid Earth::04.08. Volcanology::04.08.01. Gases ; 04. Solid Earth::04.08. Volcanology::04.08.03. Magmas ; 04. Solid Earth::04.08. Volcanology::04.08.04. Thermodynamics
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  • 34
    Publication Date: 2019-11-04
    Description: Experimental studies of Cl solubility in trachytic to phonolitic melts provide insights into the capacity of alkaline magmas to transport Cl from depth to the earths surface and atmosphere, and information on Cl solubility variations with pressure, temperature and melt or fluid composition is crucial for understanding the reasons for variations in Cl emissions at active volcanoes. This paper provides a brief review of Cl solubility experiments conducted on a range of trachytic to phonolitic melt compositions. Depending on the experimental conditions the melts studied were in equilibrium with either a Cl-bearing aqueous fluid or a subcritical assemblage of low- Cl aqueous fluid + Cl-rich brine. The nature of the fluid phase(s) was identified by examination of fluid inclusions present in run product glasses and the fluid bulk composition was calculated by mass balance. Chlorine concentrations in the glass increase with increasing Cl molality in the fluid phase until a plateau in Cl concentration is reached when melt coexists with aqueous fluid + brine. With fluids of similar Cl molality, higher Cl concentrations are observed in peralkaline phonolitic melts compared with peraluminous phonolitic melts; overall the Cl concentrations observed in phonolitic and trachytic melts are approximately twice those found in calcalkaline rhyolitic melts under similar conditions. The observed negative pressure dependence of Cl solubility implies that Cl contents of melts may actually increase during magma decompression if the magma coexists with aqueous fluid and Cl-rich brine (assuming melt-vapor equilibrium is maintained). The high Cl contents (approaching 1 wt% Cl) observed in some melts/glasses from the Vesuvius and Campi Flegrei areas suggest saturation with a Cl-rich brine prior to eruption.
    Description: Published
    Description: JCR Journal
    Description: open
    Keywords: alkaline magmas ; solubility ; chlorine ; supercritical fluid ; 04. Solid Earth::04.08. Volcanology::04.08.01. Gases ; 04. Solid Earth::04.08. Volcanology::04.08.03. Magmas
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  • 35
    Publication Date: 2019-11-04
    Description: Electron density models of the ionosphere use different analytical formulations for the electron density vertical profile in the topside. The present paper compares some single-layer topside analytical descriptions (Chapman, Epstein, modified Epstein used in the NeQuick model) with experimental topside profiles obtained from measurements of IK19 and ISIS2 satellites. The limits of height range and shape for each formulation are described and analyzed and suggestions for the use of multiple layers solution to reproduce experimental results are given.
    Description: Published
    Description: JCR Journal
    Description: open
    Keywords: topside ionosphere ; ionospheric modeling ; ionospheric layer formulation ; top side soundings ; 01. Atmosphere::01.02. Ionosphere::01.02.99. General or miscellaneous
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  • 36
    Publication Date: 2019-11-04
    Description: The effect of pressure, temperature, and melt composition on CO2 and H2O solubilities in aluminosilicate melts, coexisting with CO2-H2O fluids, is discussed on the basis of previously published and new experimental data. The datasets have been chosen so that CO2 and H2O are the main fluid components and the conclusions are only valid for relatively oxidizing conditions. The most important parameters controlling the solubilities of H2O and CO2 are pressure and composition of melt and fluid. On the other hand, the effect of temperature on volatile solubilities is relatively small. At pressures up to 200 MPa, intermediate compositions such as dacite, in which both molecular CO2 and carbonate species can be dissolved, show higher volatile solubilities than rhyolite and basalt. At higher pressures (0.5 to 1 GPa), basaltic melts can incorporate higher amounts of carbon dioxide (by a factor of 2 to 3) than rhyolitic and dacitic melts. Henrian behavior is observed only for CO2 solubility in equilibrium with H2O-CO2 fluids at pressures 〈100 MPa, whereas at higher pressures CO2 solubility varies nonlinearly with CO2 fugacity. The positive deviation from linearity with almost constant CO2 solubility at low water activity indicates that dissolved water strongly enhances the solubility of CO2. Water always shows non-Henrian solubility behavior because of its complex dissolution mechanism (incorporation of OH-groups and H2O molecules in the melt). The model of Newman and Lowenstern (2002), in which ideal mixing between volatiles in both fluid and melt phases is assumed, reproduces adequately the experimental data for rhyolitic and basaltic compositions at pressures below 200 MPa but shows noticeable disagreement at higher pressures, especially for basalt. The empirical model of Liu et al. (2004) is applicable to rhyolitic melts in a wide range of pressure (0-500 MPa) and temperature (700- 1200°C) but cannot be used for other melt compositions. The thermodynamic approach of Papale (1999) allows to calculate the effect of melt composition on volatile solubilities but needs an update to account for more recent experimental data. A disadvantage of this model is that it is not available as a program code. The review indicates a crucial need of new experimental data for scarcely investigated field of pressures and fluid compositions and new models describing evident non-ideality of H-C-O fluid solubility in silicate melts at high pressures.
    Description: Published
    Description: JCR Journal
    Description: open
    Keywords: CO2 ; H2O ; solubility ; mixed fluid ; silicate melt ; experimental data ; 04. Solid Earth::04.08. Volcanology::04.08.01. Gases ; 04. Solid Earth::04.08. Volcanology::04.08.03. Magmas
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  • 37
    Publication Date: 2019-11-04
    Description: Volcanic eruptions are unsteady multiphase phenomena, which encompass many inter-related processes across the whole range of scales from molecular and microscopic to macroscopic, synoptic and global. We provide an overview of recent advances in numerical modelling of volcanic effects, from conduit and eruption column processes to those on the Earth s climate. Conduit flow models examine ascent dynamics and multiphase processes like fragmentation, chemical reactions and mass transfer below the Earth surface. Other models simulate atmospheric dispersal of the erupted gas-particle mixture, focusing on rapid processes occurring in the jet, the lower convective regions, and pyroclastic density currents. The ascending eruption column and intrusive gravity current generated by it, as well as sedimentation and ash dispersal from those flows in the immediate environment of the volcano are examined with modular and generic models. These apply simplifications to the equations describing the system depending on the specific focus of scrutiny. The atmospheric dispersion of volcanic clouds is simulated by ash tracking models. These are inadequate for the first hours of spreading in many cases but focus on long-range prediction of ash location to prevent hazardous aircraft - ash encounters. The climate impact is investigated with global models. All processes and effects of explosive eruptions cannot be simulated by a single model, due to the complexity and hugely contrasting spatial and temporal scales involved. There is now the opportunity to establish a closer integration between different models and to develop the first comprehensive description of explosive eruptions and of their effects on the ground, in the atmosphere, and on the global climate.
    Description: Published
    Description: JCR Journal
    Description: open
    Keywords: numerical modeling ; explosive volcanic eruptions ; conduit flow ; multiphase flow simulation ; stratospheric sulfate aerosol ; 01. Atmosphere::01.01. Atmosphere::01.01.07. Volcanic effects ; 04. Solid Earth::04.08. Volcanology::04.08.99. General or miscellaneous ; 04. Solid Earth::04.08. Volcanology::04.08.01. Gases
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  • 38
    Publication Date: 2019-11-04
    Description: A brief summary is given of the major achievements of the COST 271 Action. New challenges have been identified that open the way for a proposal, which is outlined, for a follow-on to the COST 271 Action within the COST Telecommunications, Information Science and Technology framework.
    Description: Published
    Description: JCR Journal
    Description: open
    Keywords: 01. Atmosphere::01.02. Ionosphere::01.02.99. General or miscellaneous
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  • 39
    Publication Date: 2019-11-04
    Description: An important part of the tasks of Working Group 2 of the COST Action 271 «Assessment of space plasma effect for satellites applications» is the assessment of novel data sources for information about the state of ionisation of the ionosphere. This report deals with those aspects which are not represented adequately in the scientific papers in this issue. Here emphasis is given to the product aspect (data and model collections, descriptions of methods and algorithms, availability of products, expected future developments) and the links between the past COST Actions 238 and 251 with the present Action 271 and with possible future cooperations. Working Group 2 was leading in the transionospheric propagation aspects of possible products for the International Telecommunication Unions Radiocommunication (ITU-R) Study Group 3. This report gives a short overview emphasizing future developments.
    Description: Published
    Description: JCR Journal
    Description: open
    Keywords: 01. Atmosphere::01.02. Ionosphere::01.02.99. General or miscellaneous
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  • 40
    Publication Date: 2019-11-04
    Description: Measurements of volcanic gas composition and flux are crucial to probing and understanding a range of magmatic, hydrothermal and atmospheric interactions. The value of optical remote sensing methods has been recognised in this field for more than thirty years but several recent developments promise a new era of volcanic gas surveillance. This could see much higher time- and space-resolved data-sets, sustained at individual volcanoes even during eruptive episodes. We provide here an overview of these optical methods and their application to ground-based volcano monitoring, covering passive and active measurements in the ultraviolet and infrared spectral regions. We hope thereby to promote the use of such devices, and to stimulate development of new optical techniques for volcanological research and monitoring.
    Description: Published
    Description: JCR Journal
    Description: open
    Keywords: volcano monitoring ; volcano plumes ; IR and UV spectoscopy ; 04. Solid Earth::04.08. Volcanology::04.08.01. Gases ; 04. Solid Earth::04.08. Volcanology::04.08.06. Volcano monitoring
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  • 41
    Publication Date: 2019-11-04
    Description: Based on characteristics of the distribution pattern of the western Eger Rift spring gases, a distribution pattern is presented for the gases of the French Massif Central. The central parts of these areas with ascending magmatic CO2 are characterised by high gas fluxes, high CO2 contents of up to 99.99 vol% and isotopially heavy CO2. In the peripheries, the decrease of d13C values of CO2 and CO2 contents in the gas phase is compensated by a rise in N2 contents. It can be demonstrated that gas fractionation in contrary to mixtures with isotopically light biogenic or crustal CO2 controls the distribution pattern of gas composition and isotopic composition of CO2 in these spring gases. Dissolution of CO2 results in formation of HCO3 causing isotope fractionation of CO2 and an enrichment of N2 in the gas phase. With multiple equilibrations, values of about 17 or lower are obtained. The scale of gas alteration depends on the gas flux and the gas-water ratios respectively and can result in N2-rich gases. Essential for the interpretation are gas flux measurements with mass balances derived for most of the springs. Without such mass balances it is not possible to discriminate between mixture and fractionation. The processes of isotopic and chemical solubility fractionations evidently control the gas distribution pattern in other regions as well.
    Description: Published
    Description: JCR Journal
    Description: open
    Keywords: Eger Rift ; French Massif Central ; Eifel ; carbon dioxide ; gas fractionation ; isotope composition ; 04. Solid Earth::04.08. Volcanology::04.08.01. Gases
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
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  • 42
    Publication Date: 2019-11-04
    Description: We report preliminary observations on possible correlations between anomalies of subsoil radon concentration and geodynamical events on Mt. Etna. In recent years several studies have been carried out on radon as a precursor of geophysical events, most of them performed either on tectonic or volcanic areas. The peculiarity of our investigation lies on the choice of the etnean region, in which tectonic and volcanic features are both present. In order to characterize Mt. Etna features by investigating radon gas in soil, two stations were located along the NE-SW direction on Mt. Etna. Each of the two stations is fitted with a radon detector, a 3D seismic station and a meteorological station. Differences in the radon concentration trend in the data from north and south flanks could be linked to different faulting mechanisms and then to different mechanisms of radon uprising. The increase in soil radon concentration could be related to both seismic and volcanic events.
    Description: Published
    Description: JCR Journal
    Description: open
    Keywords: radon ; geodynamical precursor ; Mt. Etna ; 04. Solid Earth::04.08. Volcanology::04.08.01. Gases
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    Type: article
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  • 43
    Publication Date: 2019-11-04
    Description: In winter and equinoctial season nights, the main trough of the F region is an important stable structure of the ionosphere at the border between mid and high latitudes. Therefore it has to be taken into account in modelling and mapping approaches. Werner and Prölss (1995) derived a model for the position of the trough minimum which has found wide acceptance. The model is based on in-situ electron density data measured aboard the low orbiting Dynamic Explorer satellite DE 2 (1981-1986). We present results for other properties of the main trough derived from the same data set. These results are sufficiently good for modelling purposes which need reliable information on the depth, the equatorward and poleward width and the steepness of the walls of the trough. Because of the eccentric orbit of DE 2 (orbit height between about 300-1000 km) it was necessary to «project» observed electron densities to the peak of the F 2 layer. This was done by means of the electron density model COSTprof. The database was restricted to those cases for which the height of DE 2 was below 700 km. Examples are shown for «typical» troughs observed under various conditions.
    Description: Published
    Description: JCR Journal
    Description: open
    Keywords: ionosphere ; on in-situ electron density ; 01. Atmosphere::01.02. Ionosphere::01.02.99. General or miscellaneous
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
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  • 44
    Publication Date: 2019-11-04
    Description: The very strong volcanic eruption of Mt. Pinatubo in June 1991 directly affected the troposphere and lower and middle stratosphere. Here we look at its effects in the mesopause region as revealed by the radio wave absorption measurements in the lower ionosphere over Central Europe and inferred planetary and gravity wave activity. The gravity wave activity inferred from the nighttime LF radio wave absorption displays an evident enhancement for waves of periods of about 2-3 h coinciding with regional measurements of the optical depth of (volcanic) aerosols, while there is no detectable effect for short period waves (T 〈 1 h). There is no detectable effect in the planetary wave activity inferred from the daytime HF radio wave absorption. As for the absorption itself, the results on the impact of the Mt. Pinatubo eruption do not provide an observable effect.
    Description: Published
    Description: JCR Journal
    Description: open
    Keywords: volcanic eruption ; lower ionosphere ; atmospheric waves ; radio wave absorption ; 01. Atmosphere::01.02. Ionosphere::01.02.05. Wave propagation
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  • 45
    Publication Date: 2019-11-04
    Description: The use of data is essential in the context of nowcasting, forecasting and warning of ionospheric propagation conditions, with roles to play in the development, evaluation and operation of models and services. Descriptions are given of three databases that have been established in the course of the COST 271 Action: a database of prompt ionospheric soundings, an extension to a database generated by the EISCAT incoherent scatter radars, and a database intended to facilitate evaluation of TEC estimation methods. Each database includes some background information, a description of the contents and interface, and instructions as to how to gain access to it.
    Description: Published
    Description: JCR Journal
    Description: open
    Keywords: 01. Atmosphere::01.02. Ionosphere::01.02.05. Wave propagation ; 01. Atmosphere::01.02. Ionosphere::01.02.06. Instruments and techniques
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  • 46
    Publication Date: 2019-11-04
    Description: Telecommunications via ionospheric reflection of radio signals of ground-based transmitters are a traditional area. However, this technique is still in use in telecommunications, broadcasting, etc. Various problems have not yet been solved and some of them were studied in Working Group 3 (WG3). Structure of WG 3 and the terms of reference of its four working packages are described in the introductory paper by Zolesi and Cander (2004). Here we describe the main results achieved in COST 271 in the following areas: i) large-scale fluctuations of planetary and gravity waves; ii) development of a new type of HF channel simulator; iii) geomagnetic storm effects on the F1-region ionosphere; iv) the sporadic E-layer and spread-F phenomena; v) the HF radio wave propagation over northerly paths; vi) how to increase the bit rate in ionospheric radio links. In general, substantial progress was achieved but some problems remain open for future investigations.
    Description: Published
    Description: JCR Journal
    Description: open
    Keywords: 01. Atmosphere::01.02. Ionosphere::01.02.99. General or miscellaneous
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
    Type: article
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  • 47
    Publication Date: 2019-11-04
    Description: This paper summarizes the the activities carried out by Working Group 4 of COST 271 Action. The structure of this Working Group included four Working packages that were dealing with different aspects of the same overall problem related to space plasma variability and irregularities effects on advanced satellite systems. General comments about the most relevant achievements and possible future lines of research are given.
    Description: Published
    Description: JCR Journal
    Description: open
    Keywords: 01. Atmosphere::01.02. Ionosphere::01.02.99. General or miscellaneous
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
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  • 48
    Publication Date: 2019-11-04
    Description: The magnetosphere-ionosphere-thermosphere subsystem is strongly coupled via the electric field, particle precipitation, heat flows and small scale interaction. Satellites in situ measurements and ground based complex diagnostics can provide comprehensive coverage of both time and geomagnetic place effects. Human activity also can perturb Earth s environment, but few are connected with controlled experiments in the ionosphere and are transient. Most of them are related to industrial activity and have increased in recent years. The most important power sources are broadcasting transmitters, power stations, power lines and heavy industry. At ionospheric altitude some disturbances and physical processes are related to seismic activity, thunderstorm activity and some global changes in the Earth environment such as ozone holes. Various natural and artificial indicators can affect satellite telecommunication quality. The aim of this presentation is to report progress in understanding the physical processes in the ionosphere described above and to assess the application of these considerations to the study of plasma effects on Earth-space and satellite-to-satellite communication.
    Description: Published
    Description: JCR Journal
    Description: open
    Keywords: 01. Atmosphere::01.02. Ionosphere::01.02.99. General or miscellaneous
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
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  • 49
    Publication Date: 2019-11-04
    Description: The paper presents an overview of the scientific research carried out in the frames of Working Group 1 activities of the COST Action 271. The basic objective of this Working Group was the study of the impact of ionospheric variability on communications. The main achievements and an overall evaluation are reported.
    Description: Published
    Description: JCR Journal
    Description: open
    Keywords: 01. Atmosphere::01.02. Ionosphere::01.02.99. General or miscellaneous
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
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  • 50
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    Publication Date: 2019-11-04
    Description: This article discusses the significance of the achievements of the COST 271 Action on science and technology for space weather and telecommunications in Europe and the world. The Action's work has impacted national and international projects and the decision processes. The key words encompassed in the title of COST 271 are «space weather». But as the reader of this Final Report will appreciate, many more topics were addressed during the Action by the large team of workers from a wide range of countries and organisations than this wording would suggest. Relevant to the performance of telecommunication systems that rely on the presence of the ionosphere for propagation support, or that are affected by transmission through it, there have been investigations among other items of solar and magnetosphere disturbances on the ionosphere, satellite and ground-based measurements of the ionosphere, assembly of near-real-time databases of ionosphere information on the Web, studies of planetary and gravity waves in the ionosphere, ionosphere modelling, mapping and forecasting, long-term changes, ray-path deviations in the presence of irregularities, channel-scattering functions, and scintillations on Earth-space paths. The impact of all this work on the outside communities can be considered within three broad headings as follows.
    Description: Published
    Description: JCR Journal
    Description: open
    Keywords: 01. Atmosphere::01.02. Ionosphere::01.02.99. General or miscellaneous
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
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  • 51
    Publication Date: 2019-11-04
    Description: In the autumn of the year 2000, four radio receivers capable of tracking various beacon satellites were set up along the southwestern coast of Greenland. They are used to reconstruct images of the ionospheric plasma density distribution via the tomographic method. In order to test and validate tomographic imaging under the highly variable conditions often prevailing in the high-latitude ionosphere, a time interval was selected when the Sondrestrom incoherent scatter radar conducted measurements of the ionospheric plasma density while the radio receivers tracked a number of beacon satellites. A comparison between two-dimensional images of the plasma density distribution obtained from the radar and the satellite receivers revealed generally good agreement between radar measurements and tomographic images. Observed discrepancies can be attributed to F region plasma patches moving through the field of view with a speed of several hundred meters per second, thereby smearing out the tomographic image. A notable mismatch occurred around local magnetic midnight when a magnetospheric substorm breakup occurred in the vicinity of southwest Greenland (identified from ground-based magnetometer observations). The breakup was associated with a sudden intensification of the westward auroral electrojet which was centered at about 69 and extended up to some 73 corrected geomagnetic latitude. Ground-based magnetometer data may thus have the potential of indicating when the tomographic method is at risk and may fail. We finally outline the application of tomographic imaging, when combined with magnetic field data, to estimate ionospheric Joule heating rates.
    Description: Published
    Description: JCR Journal
    Description: open
    Keywords: Beacon satellites ; ionospheric plasma ; 01. Atmosphere::01.02. Ionosphere::01.02.04. Plasma Physics ; 01. Atmosphere::01.02. Ionosphere::01.02.05. Wave propagation ; 01. Atmosphere::01.02. Ionosphere::01.02.06. Instruments and techniques
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  • 52
    Publication Date: 2024-05-09
    Description: On 3rd November 2002, at about 3 km off-shore of Panarea Island (Aeolian Islands, Southern Italy), a series of gas vents suddenly and violently opened from the seafloor at the depth of 10-15 m, with an unusually high gas flux and superimposing on the already existing submarine fumarolic field. Starting from the 12th November 2002 a discontinuous geochemical monitoring program was carried out. The emissions consisted in an emulsion whose liquid phase derived from condensation of an uprising vapor phase occurring close to the fluid outlets without significant contamination by seawater. The whole composition of the fluids was basically H2O- and CO2-dominated, with minor amounts of typical «hydrothermal» components (such as H2S, H2, CO and light hydrocarbons), atmospheric-related compounds, and characterized by the occurrence of a significant magmatic gas fraction (mostly represented by SO2, HCl and HF). According to the observed temporal variability of the fluid compositions, between November and December 2002 the hydrothermal feeding system was controlled by oxidizing conditions due to the input of magmatic gases. The magmatic degassing phenomena showed a transient nature, as testified by the almost complete disappearance of the magmatic markers in a couple of months and by the restoration, since January 2003, of the chemical features of the existing hydrothermal system. The most striking feature of the evolution of the «Panarea degassing event» was the relatively rapid restoration of the typical reducing conditions of a stationary hydrothermal system, in which the FeO/Fe1.5O redox pair of the rock mineral phases has turned to be the dominating redox controlling system.
    Description: Published
    Description: JCR Journal
    Description: open
    Keywords: Aeolian Islands ; Panarea ; submarine fumaroles ; gas chemistry ; geochemical monitoring ; 04. Solid Earth::04.08. Volcanology::04.08.01. Gases ; 04. Solid Earth::04.08. Volcanology::04.08.06. Volcano monitoring
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