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  • 04. Solid Earth::04.04. Geology::04.04.12. Fluid Geochemistry  (31)
  • 04. Solid Earth::04.07. Tectonophysics::04.07.07. Tectonics  (29)
  • 04. Solid Earth::04.08. Volcanology::04.08.05. Volcanic rocks  (28)
  • Elsevier  (82)
  • Chinese Geoscience Union  (2)
  • Essen : Verl. Glückauf
  • Krefeld : Geologischer Dienst Nordhein-Westfalen
  • Oxford University Press
  • Seismological Society of America
  • 2005-2009  (86)
Collection
Keywords
Publisher
Years
Year
  • 1
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    The Afragola settlement near Vesuvius, Italy: The destruction and abandonment of a Bronze Age village revealed by archaeology, volcanology and rock-magnetism (2009)
    Elsevier
    Details
    Publication Date: 2021-06-15
    Description: Public works in progress in the Campanian plain north of Somma-Vesuvius recently encountered the remains of a prehistoric settlement close to the town of Afragola. Rescue excavations brought to light a Bronze Age village partially destroyed and buried by pyroclastic density currents (PDCs) of the Vesuvian Pomici di Avellino eruption (3.8 14C ka BP) and subsequently sealed by alluvial deposits. Volcanological and rockmagnetic investigations supplemented the excavations. Careful comparison between volcanological and archaeological stratigraphies led to an understanding of the timing of the damage the buildings suffered when they were struck by a series of PDCs. The first engulfed the village, located some 14 km to the north of the inferred vent, and penetrated into the dwellings without causing major damage. The buildings were able to withstand the weak dynamic pressure of the currents and deviate their path, as shown by the magnetic fabric analyses. Some later collapsed under the load of the deposits piled up by successive currents. Stepwise demagnetization of the thermal remanent magnetization (TRM) carried by potsherds embedded in the deposits yields deposition temperatures in the order of 260– 320 °C, fully consistent with those derived from pottery and lithic fragments from other distal and proximal sites. The fairly uniform temperature of the deposits is here ascribed to the lack of pervasive air entrainment into the currents. This, in turn, resulted from the lack of major topographical obstacles along the flat plain. The coupling of structural damage and sedimentological analyses indicates that the currents were not destructive in the Afragola area, but TRM data indicate they were still hot enough to cause death or severe injury to humans and animals. The successful escape of the entire population is apparent from the lack of human remains and from thousands of human footprints on the surface of the deposits left by the first PDCs. People were thus able to walk barefoot across the already emplaced deposits and escape the subsequent PDCs. The rapid cooling of the deposits was probably due to both their thinness and heat dissipation due to condensation of water vapour released in the mixture by magma–water interaction.
    Description: Published
    Description: 408–421
    Description: 2.3. TTC - Laboratori di chimica e fisica delle rocce
    Description: 3.5. Geologia e storia dei vulcani ed evoluzione dei magmi
    Description: 3.6. Fisica del vulcanismo
    Description: JCR Journal
    Description: reserved
    Keywords: pyroclastic density current ; Bronze Age ; magnetic fabric ; deposition temperature ; 04. Solid Earth::04.04. Geology::04.04.10. Stratigraphy ; 04. Solid Earth::04.05. Geomagnetism::04.05.07. Rock magnetism ; 04. Solid Earth::04.08. Volcanology::04.08.05. Volcanic rocks
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
    Type: article
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  • 2
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    Helium isotopes in hydrothermal volcanic fluids of the Azores Archipelago (2009)
    Elsevier
    Details
    Publication Date: 2021-06-25
    Description: We present the first helium isotope data for thermal waters and gas emissions on the islands of Terceira, Graciosa, Faial, Pico and Flores, as well as new data for Sao Miguel. The results allow us to track current mantle degassing associated with the Azores hot spot, to delineate its spatial distribution and to discuss its possible origin. As a general rule, we find that free gases tend to display somewhat higher 3He/4He ratio than groundwaters.We argue that this difference is likely due to radiogenic helium inputs to aquifers duringwater– rock interactions and, therefore, that gas phases are the fluid carriers with the most representative of mantle source signature. The measured 3He/4He ratios (normalized to the air ratio, Ra) range from lower-than-MORB values (5.23–6.07 Ra) on central Sao Miguel, to MORB values on Faial (8.53 Ra) and Flores (8.04 Ra) – located on either side of the Mid-Atlantic Ridge – and to plume-type values on Graciosa (11.2 Ra) and Terceira (13.5 Ra) where free gases also display ten times higher-than-MORB CO2/3He ratios (1.8–2.6×1010). Such a wide He isotopic range and its spatial distribution corroborate with available data for volcanic rocks, indicating that plume's head presently underlies the central part of the archipelago. The plume-type 3He/4He ratios on Terceira and Graciosa agree with geochemical and seismic evidence of a deep-rooted mantle plume feeding the Azores hot spot. Our finding that high 3He/4He ratios correspond to low 3He concentrations and high (arctype) CO2/3He values exclude a simple plume supply of 3He-rich primitive mantle. Instead, the simultaneity of both elevated CO2/3He and 3He/4He ratios is best explained by a 3He-rich contribution from the lower mantle diluted in a CO2-rich feeding plume that contains a recycled altered oceanic plate component. The alternative possibility of an enhanced time-integrated 3He/(U+Th) ratio in the Azores plume due to a greater compatibility of helium relative to U and Th during melting events is difficult to reconcile with the enriched pattern of volcanic rocks from the central islands. In any case, the Azores plume should derive from a mantle reservoir that could escape convective homogenization for a very long period of time, in agreement with subchondritic osmium isotopic ratios in volcanic rocks from the central islands of the archipelago.
    Description: Published
    Description: 70−80
    Description: 1.2. TTC - Sorveglianza geochimica delle aree vulcaniche attive
    Description: JCR Journal
    Description: reserved
    Keywords: hydrothemal fluids ; helium isotopes ; 04. Solid Earth::04.04. Geology::04.04.12. Fluid Geochemistry
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
    Type: article
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  • 3
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    Present-day stress-field modelling of southern Italy constrained by stress and GPS data (2009)
    Elsevier
    Details
    Publication Date: 2020-11-16
    Description: The present-day tectonic setting of the Italian peninsula is very complex and involves competing geodynamic processes. In this context, southern peninsular Italy is characterised by extension along the Apenninic belt and in the Tyrrhenian margin and by transpression in the Apulia-Gargano region. The extension is well defined by means of geological, seismological, and contemporary stress data. For the latter only few data are available in the Apulia-Gargano region, leaving the state of stress in that area unresolved. Here we develop a finite-element model of the southern Italian region in order to predict the contemporary stress field. Our model predictions are constrained by model-independent observations of the orientation of maximum horizontal stress (SHmax), the tectonic regime, and the horizontal velocities derived from GPS observations. We performed a blind test with 31 newly acquired SHmax orientations in the Southern Apennines. These new data come from the analysis of borehole breakouts performed in 46 deep oil exploration wells ranging in depth from 1300 to 5500 m. The model results agree with the stress data that define a prevailing NW-SE SHmax orientation along the Apenninic belt and foredeep and thus are capable to predict the stress field where no stress information is available. We first analyse how much model predictions, based on older data, deviate from present-day stress data and then recalibrate the models based on our new stress data, giving insight into the resolution of both models and data. In the studied region, which is affected by low deformation rates, we find that geodetic data alone cannot resolve such low levels of deformation due to the high relative measurement errors. We conclude that both GPS and stress data are required to constrain model results.
    Description: This research was supported by the Italian Presidenza del Consiglio dei Ministri - Dipartimento della Protezione Civile (DPC) through the INGV-DPC project S1.
    Description: Published
    Description: 193-204
    Description: 2T. Deformazione crostale attiva
    Description: JCR Journal
    Description: open
    Keywords: Neotectonics ; Borehole-breakouts ; Southern Apennines ; Finite-element models ; 04. Solid Earth::04.03. Geodesy::04.03.01. Crustal deformations ; 04. Solid Earth::04.03. Geodesy::04.03.08. Theory and Models ; 04. Solid Earth::04.07. Tectonophysics::04.07.05. Stress ; 04. Solid Earth::04.07. Tectonophysics::04.07.07. Tectonics
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
    Type: article
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  • 4
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    Mercury concentration, speciation and budget in volcanic aquifers: Italy and Guadeloupe (Lesser Antilles) (2009)
    Elsevier
    Details
    Publication Date: 2017-04-04
    Description: Quantifying the contribution of volcanism to global mercury (Hg) emissions is important to understand the pathways and the mechanisms of Hg cycling through the Earth's geochemical reservoirs and to assess its environmental impacts. While previous studies have suggested that degassing volcanoes might contribute importantly to the atmospheric budget of mercury, little is known about the amount and behaviour of Hg in volcanic aquifers. Here we report on detailed investigations of both the content and the speciation of mercury in aquifers of active volcanoes in Italy and Guadeloupe Island (Lesser Antilles). In the studied groundwaters, total Hg (THg) concentrations range from 10 to 500 ng/l and are lower than the 1000 ng/l threshold value for human health protection fixed by the World Health Organization [WHO (1993): WHO Guidelines for Drinking Water Quality- http://www.who.int/water_sanitation_health/GDWQ/index.htlm]. Positive co-variations of (THg) with sulphate indicate that Hg-SO4-rich acid groundwaters receive a direct input of magmatic/hydrothermal gases carrying mercury as Hg0 (gas). Increasing THg in a volcanic aquifer could thus be a sensitive tracer of magmatic gas input prior to an eruption. Since the complex behaviour and toxicity of mercury in waters depend on its chemical speciation, we carefully determined the different aqueous forms of this element in our samples.We find that dissolved elemental Hg0 (aq) and particulate-bound Hg (HgP) widely prevail in volcanic aquifers, in proportions that highlight the efficiency of Hg adsorption onto colloidal particles. Moreover, we observe that dissolved Hg0 aq and Hg(II) forms coexist in comparable amount in most of the waters, in stark contrast to the results of thermodynamic equilibrium modelling. Therefore, chemical equilibrium between dissolved mercury species in volcanic waters is either prevented by natural kinetic effects or not preserved in collected waters due to sampling/storage artefacts. Finally, we provide a first quantitative comparison of the relative intensity of aqueous transport and atmospheric emissions of mercury at Mount Etna, a very active basaltic volcano.
    Description: Published
    Description: 96-106
    Description: 4.5. Studi sul degassamento naturale e sui gas petroliferi
    Description: JCR Journal
    Description: reserved
    Keywords: speciation ; volcanic aquifers ; total and dissolved mercury ; mercury cycling ; volatile budget ; 04. Solid Earth::04.04. Geology::04.04.12. Fluid Geochemistry
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
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  • 5
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    Chronology of the 2007 eruption of Stromboli and the activity of the Scientific Synthesis Group (2009)
    Elsevier
    Details
    Publication Date: 2017-04-04
    Description: On 27 February 2007, at 12.49 GMT, a new eruption of Stromboli took place with the effusion of a lava flow from a fracture cutting the flank of the NE cone, which rapidly reached the sea. The eruption had been heralded by an increase in the amplitude of tremor and flank movement since at least the 14th of February. Short-term precursors were an increase in the rate of occurrence of small landslides within the “Sciara del Fuoco” scar on the North-western flank of the volcano. A new effusive vent opened at 18.30 GMT on the Sciara del Fuoco at an height of 400 m asl. The new lava emission caused the sudden termination of the summit flow and initiated a period of non-stationary lava outpouring which ended on 2 April, 2007. The eruption has been characterized by a rapid decrease in the eruption rate after the first days and subsequently by episodic pulse increases. On the 15th of March, the increase in lava outpouring, monitored by a thermal camera, heralded by 9 min the occurrence of a violent paroxysmal explosion with the formation of an impulsive eruption column and the emission of small pumices mingled with black scoriae. The pumice had a bulk composition similar to that of the lava and of the black scoriae, but with a distinct lower content of phenocrysts. A similar feature has been repeatedly observed during the major explosive paroxysms of Stromboli. Short term precursors of the paroxysm were recorded by strainmeter and tiltmeter stations. The volcano monitoring activity has been made by a joint team of researchers from the INGV sections of Catania, Napoli, Palermo and Rome, along with researchers from the Universities of Florence, Pisa, Roma Tre, and Palermo. The scientific activity was coordinated by a Synthesis Group made up by scientists responsible for the different monitoring techniques of INGV and Universities and by the volcanic experts of Commissione Nazionale Grandi Rischi of the Prime Minister Office (Civil Protection Department). The group made a daily evaluation of the state of the volcano and transmitted its recommendations to the Civil Protection Department (DPC). Several prevention measures were adopted by DPC, the main of which were the evacuation of the coast zone when strong acceleration of the Sciara del Fuoco slope motion (occurred twice) could led to a dangerous tsunami by flank collapse (as last occurred on 30 December 2002) and four days before the 15 March paroxysm when access was prohibited to the part of the volcano above 290 m asl.
    Description: Published
    Description: 123–130
    Description: 2.3. TTC - Laboratori di chimica e fisica delle rocce
    Description: JCR Journal
    Description: reserved
    Keywords: Stromboli volcano ; 2007 eruption ; scientific emergency management ; 04. Solid Earth::04.08. Volcanology::04.08.03. Magmas ; 04. Solid Earth::04.08. Volcanology::04.08.05. Volcanic rocks
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
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  • 6
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    Geochemical Monitoring of Cold Waters during Seismicity: Implications for Earthquake-induced Modification in Shallow Aquifers (2009)
    Chinese Geoscience Union
    Details
    Publication Date: 2017-04-04
    Description: The geochemical monitoring carried out on fluids released in the Central Apennines (Umbria region) evidenced seismically-induced modifications of the physic-chemical parameters in all the released fluids, including some cold waters circulating in certain carbonate rocks that are exploited for drinking purposes. The results allowed us to recognize the presence of components of diverse origin that changed the chemical composition of the water. These components, potentially dangerous for human consumption, can be considered as being “secondary effects” on local aquifers, induced by crustal deformation. We would also stress the relationship between the circulating fluids and active tectonic structures, as we detected modifications in some springs that were apparently not located anywhere near the local faults. The temporal variations in the geochemical features of the investigated cold waters are related to the local faulting activity that occurs during seismogenesis. The geochemical monitoring that provided information on fault movements during the seismic crisis, is also able to give us information regarding faulting activity in its earlier stages.
    Description: Published
    Description: 709-729
    Description: 3.2. Tettonica attiva
    Description: N/A or not JCR
    Description: reserved
    Keywords: cold waters ; earthquakes ; 04. Solid Earth::04.04. Geology::04.04.12. Fluid Geochemistry
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
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  • 7
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    Effects of soil gas permeability and recirculation flux on soil CO2 flux measurements performed using a closed dynamic accumulation chamber (2009)
    Elsevier
    Details
    Publication Date: 2017-04-04
    Description: Dynamic accumulation chamber methods have been extensively used to estimate the total output of CO2 released from active volcanic area. In order to asses the performance and reliability of a closed dynamic system several tests were carried out with different soil permeabilities and soil CO2 fluxes. A special device was used to create a constant one-dimensional CO2 flux through a soil column with a known permeability. Three permeabilities were investigated, ranging between 3.6 × 10− 2 and 3.5 × 10 μm2, as were several CO2 fluxes (ranging between 1.1 × 10− 6 and 6.3 × 10− 5 kg m− 2 s− 1). The results highlight that the accuracy of soil CO2 flux measurements strictly depends on the soil gas permeability and the soil CO2 flux regimen. Generally chamber measurements underestimate CO2 fluxes at low soil permeability and low soil CO2 fluxes, whereas appreciable overestimations occur for high permeability soil, especially for high soil CO2 fluxes. Other tests carried out with different settings for the measurement device, such as the chamber volume and the flux of the pump used to recirculate air through the chamber and the gas analyzer (recirculation flux), revealed a strong dependence of the closed dynamic chamber measurements on the recirculation flux. Low recirculation fluxes (0.2–0.4 l min− 1) decreased the performance of the measurement system, causing underestimations of the actual soil CO2 flux, whereas higher values (0.6–1.0 l min− 1) resulted in overestimations, especially for elevated soil CO2 fluxes. An empirical equation was deduced to allow accumulation chamber fluxes to be calculated very accurately based on soil gas permeabilities measured in the field.
    Description: Published
    Description: 387-393
    Description: 1.2. TTC - Sorveglianza geochimica delle aree vulcaniche attive
    Description: 4.5. Studi sul degassamento naturale e sui gas petroliferi
    Description: JCR Journal
    Description: reserved
    Keywords: Soil CO2 flux measuraments ; Closed dynamic chamber ; soil gas permeability ; 04. Solid Earth::04.02. Exploration geophysics::04.02.01. Geochemical exploration ; 04. Solid Earth::04.04. Geology::04.04.12. Fluid Geochemistry ; 04. Solid Earth::04.08. Volcanology::04.08.01. Gases ; 04. Solid Earth::04.08. Volcanology::04.08.06. Volcano monitoring ; 04. Solid Earth::04.08. Volcanology::04.08.07. Instruments and techniques
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
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  • 8
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    Time-dependent deformation of the eastern flank of Mt. Etna: after-slip or viscoelastic relaxation? (2009)
    Elsevier
    Details
    Publication Date: 2017-04-04
    Description: Major results of post-intrusive GPS monitoring of the five months encompassing and following the onset of 2002-03 Mt. Etna eruption are presented and discussed here. The overall ground deformation pattern is characterized by a time-dependent relaxation function. We evaluated two different parameterizations of relaxation functions, each one linked to a different relaxation process: i) viscoelastic relaxation and ii) after-slip mechanism. The former indicated that the process occurred within a weak layer characterized by viscosity values ranging between 7.1 • 1014 Pa s and 1.3 • 1015 Pa s. The latter evidenced that frictional processes occurred beneath a layer of velocity-strengthening having a thickness with values ranging between 0.4 km and 1.7 km. Either model may explain the observed time-dependent deformation, both from the statistical point of view and the comparison with geologic and seismic information. Although we are unable to favour one model rather than the other, these results indicate that the mechanism, responsible for the observed post-intrusive deformation, occurs within a sliding “zone” located inside the clayey sedimentary basement.
    Description: This study was undertaken with financial support from the FLANK project (DPC-INGV 2008 - 2010 contract)
    Description: Published
    Description: 300-311
    Description: 1.3. TTC - Sorveglianza geodetica delle aree vulcaniche attive
    Description: JCR Journal
    Description: reserved
    Keywords: 2002-03 Mt. Etna eruption ; Post-intrusive relaxation ; Viscoelastic ; After-slip ; Rheology ; 04. Solid Earth::04.08. Volcanology::04.08.05. Volcanic rocks ; 04. Solid Earth::04.08. Volcanology::04.08.06. Volcano monitoring
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
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  • 9
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    Methane fluxes from the soils in active volcanic areas: the case of Pantelleria Island (Italy) (2009)
    Elsevier
    Details
    Publication Date: 2017-04-04
    Description: Methane, the most abundant hydrocarbon in the atmosphere, plays an important role in the Earth’s atmospheric chemistry and radiative balance being the second most important greenhouse gas after CO2. Methane is released to the atmosphere by a wide number of sources, both natural and anthropogenic, with the latter being twice as large as the former (Kvenvolden and Rogers, 2005). It has recently been established that significant amounts of geological methane, produced within the Earth’s crust, are currently released naturally into the atmosphere (Etiope, 2004). Among natural sources the volcanic/geothermal emissions are probably the least constrained. Recent estimations for volcanic and geothermal systems in Europe (Etiope et al. 2007) gave a rather large provisional range (4-16 kt/a) that claims for much more field measurements in order to widen the current database and decrease the present uncertainties. Pantelleria is an active volcanic complex, at present in quiescent status, hosting a high enthalpy geothermal system. Explorative geothermal wells tapped an exploitable water-dominated reservoir at 600-800 m depth with maximum measured temperatures of 250 °C. While some data are available on diffuse CO2 fluxes, data on CH4 are available only for fumarolic fluids. In the present study we measured CH4 fluxes in the area of Favara Grande characterized by intense diffuse degassing and widespread signs of geothermal activity (fumaroles, steaming grounds and large zones devoid of vegetation). Values range from negative (-43 to 0 mgCH4 m2 day), typical of soils with methanotrophic activity, up to 3500 mgCH4 m2 day in the most thermalized area. The preliminary estimate of the methane release from the area of Favara Grande is about 2.5 t/a. Extrapolation to the whole volcanic/geothermal system of Pantelleria gives about 10 t/a.
    Description: Published
    Description: Davos, Switzerland
    Description: 1.2. TTC - Sorveglianza geochimica delle aree vulcaniche attive
    Description: 4.5. Studi sul degassamento naturale e sui gas petroliferi
    Description: open
    Keywords: soil gases ; methane output ; 04. Solid Earth::04.04. Geology::04.04.12. Fluid Geochemistry ; 04. Solid Earth::04.08. Volcanology::04.08.01. Gases
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
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  • 10
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    The evolution of a dynamic geological system: the support of a GIS for geochemicd measurements at the fumarole field of Vulcano, Italy (2009)
    Elsevier
    Details
    Publication Date: 2017-04-04
    Description: The island of Vulcano (Aeolian arc, Southern Italy) has displayed several periods of volcanic unrest since the end of the last eruption (1890). We report here results obtained from a long-term survey concerning variations of both the steam output and the exhaling surface area at the sun~mit crater fumarolic field of La Fossa. The field measurements analysed in a Geographiciil Information System (GIS: show a highly dynamic volcanic system in which deep variations in the geochemishy and the temperature of the released fluids were accompanied by fluctuations in the mass output of steam and the topography of the crater field. The use of a GIS facilitated digitized reconstructions of maps of the crater field in addition to analysis (of the steam flux data. The furnarolic field expanded its surface area from 50 m2 in 1983 to more than 2400 m* in 1995, accompanied by an increase in steam output from 152 to about 1400 tonnes per day. The possibility that the observed phenomena are related to volcano-tectonic activity and to magma uprising is taken into consideration.
    Description: Published
    Description: 253-263
    Description: 1.2. TTC - Sorveglianza geochimica delle aree vulcaniche attive
    Description: JCR Journal
    Description: reserved
    Keywords: volcanic surveillance ; Steam output ; tectonic lines ; flux ; 04. Solid Earth::04.04. Geology::04.04.12. Fluid Geochemistry
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
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  • 11
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    Geochemical evaluation of observed changes in volcanic activity during the 2007 eruption at Stromboli (Italy) (2009)
    Elsevier
    Details
    Publication Date: 2017-04-04
    Description: On February 27, 2007 a new eruption started at Stromboli that lasted until April 2 and included a paroxysmal explosion on March 15. Geochemical monitoring carried out over several years revealed some appreciable variations that preceded both the eruption onset and the explosion. The carbon dioxide (CO2) flux from the soil at Pizzo Sopra La Fossa markedly increased a few days before the eruption onset, and continued during lava effusion to reach its maximum value (at 90,000 g m−2 d−1) a few days before the paroxysm. Almost contemporarily, the δ13CCO2 of the SC5 fumarole located in the summit area increased markedly, peaking just before the explosion (δ13CCO2~−1.8‰). Following the paroxysm, helium (He) isotopes measured in the gases dissolved in the basal thermal aquifer sharply increased. Almost contemporarily, the automatic station of CO2 flux recorded an anomalous degassing rate. Also temperatures and the vertical thermal gradient, which had been measured since November 2006 in the soil at Pizzo Sopra La Fossa, showed appreciable variabilities that lasted until the end of the eruption. The geochemical variations indicated the degassing of a new batch of volatile-rich magma that preceded and probably fed the paroxysm. The anomalous 3He/4He ratio suggested that the ascent of a second batch of volatile-rich magma toward the surface was probably responsible of the resumption of the ordinary activity. A comparison with the geochemical variations observed during the 2002–2003 eruption indicated that the 2007 eruption was less energetic.
    Description: Published
    Description: 246-254
    Description: 1.2. TTC - Sorveglianza geochimica delle aree vulcaniche attive
    Description: JCR Journal
    Description: reserved
    Keywords: geochemistry ; eruption ; dissolved gases ; Stromboli ; volcanic activity ; 03. Hydrosphere::03.02. Hydrology::03.02.03. Groundwater processes ; 03. Hydrosphere::03.04. Chemical and biological::03.04.03. Chemistry of waters ; 03. Hydrosphere::03.04. Chemical and biological::03.04.05. Gases ; 03. Hydrosphere::03.04. Chemical and biological::03.04.06. Hydrothermal systems ; 04. Solid Earth::04.04. Geology::04.04.12. Fluid Geochemistry ; 04. Solid Earth::04.08. Volcanology::04.08.01. Gases ; 04. Solid Earth::04.08. Volcanology::04.08.06. Volcano monitoring ; 05. General::05.02. Data dissemination::05.02.01. Geochemical data ; 05. General::05.02. Data dissemination::05.02.03. Volcanic eruptions
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
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  • 12
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    Dike propagation in volcanic edifices: Overview and possible developments (2009)
    Elsevier
    Details
    Publication Date: 2017-04-04
    Description: Eruptions are fed by dikes; therefore, better knowledge of dike propagation is necessary to improve our understanding of how magma is transferred and extruded at volcanoes. This study presents an overview of dike patterns and the factors controlling dike propagation within volcanic edifices. Largely based on published data, three main types of dikes (regional, circumferential and radial) are illustrated and discussed. Dike pattern data from 25 volcanic edifices in different settings are compared to derive semi-quantitative relationships between the topography (relief, shape, height, and presence of sector collapses) of the volcano, tectonic setting (presence of a regional stress field), and mean composition (SiO2 content). The overview demonstrates how dike propagation in a volcano is not a random process; rather, it depends from the following factors (listed in order of importance): the presence of relief, the shape of the edifice and regional tectonic control. We find that taller volcanoes develop longer radial dikes, whose (mainly lateral) propagation is independent of the composition of magma or the aspect ratio of the edifice. Future research, starting from these preliminary evaluations, should be devoted to identifying dike propagation paths and likely locations of vent formation at specific volcanoes, to better aid hazards assessment.
    Description: Partly fundedwith DPC-INGVfunds (LAVAProject).
    Description: Published
    Description: 67–77
    Description: 1.5. TTC - Sorveglianza dell'attività eruttiva dei vulcani
    Description: 3.2. Tettonica attiva
    Description: 3.6. Fisica del vulcanismo
    Description: JCR Journal
    Description: reserved
    Keywords: dikes ; volcanoes ; topography ; tectonic setting ; eruptions ; 03. Hydrosphere::03.04. Chemical and biological::03.04.02. Carbon cycling ; 04. Solid Earth::04.01. Earth Interior::04.01.99. General or miscellaneous ; 04. Solid Earth::04.04. Geology::04.04.99. General or miscellaneous ; 04. Solid Earth::04.04. Geology::04.04.09. Structural geology ; 04. Solid Earth::04.07. Tectonophysics::04.07.99. General or miscellaneous ; 04. Solid Earth::04.07. Tectonophysics::04.07.05. Stress ; 04. Solid Earth::04.07. Tectonophysics::04.07.07. Tectonics ; 04. Solid Earth::04.08. Volcanology::04.08.99. General or miscellaneous ; 04. Solid Earth::04.08. Volcanology::04.08.03. Magmas ; 04. Solid Earth::04.08. Volcanology::04.08.06. Volcano monitoring ; 04. Solid Earth::04.08. Volcanology::04.08.08. Volcanic risk ; 05. General::05.02. Data dissemination::05.02.99. General or miscellaneous ; 05. General::05.02. Data dissemination::05.02.03. Volcanic eruptions ; 05. General::05.08. Risk::05.08.99. General or miscellaneous
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
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  • 13
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    Intrusion of eccentric dikes: The case of the 2001 eruption and its role in the dynamics of Mt. Etna volcano (2009)
    Elsevier
    Details
    Publication Date: 2017-04-04
    Description: The 2001 eruption represents one of the most studied events both from volcanological and geophysical point of view on Mt. Etna. This eruption was a crucial event in the recent dynamics of the volcano, marking the passage from a period (March 1993–June 2001) of moderate stability with slow, continuous flank sliding and contemporaneous summit eruptions, to a period (July 2001 to present) of dramatically increased flank deformations and flank eruptions. We show new GPS data and high precision relocation of seismicity in order to demonstrate the role of the 2001 intrusive phase in this change of the dynamic regime of the volcano. GPS data consist of two kinematic surveys carried out on 12 July, a few hours before the beginning of the seismic swarm, and on 17 July, just after the onset of eruptive activity. A picture of the spatial distribution of the sin-eruptive seismicity has been obtained using the HypoDD relocation algorithm based on the double-difference (DD) technique. Modeling of GPS measurements reveals a southward motion of the upper southern part of the volcano, driven by a NNW–SSE structure showing mainly left-lateral kinematics. Precise hypocenter location evidences an aseismic zone at about sea level, where the magma upraise was characterized by a much higher velocity and an abrupt westward shift, revealing the existence of a weakened or ductile zone. These results reveal how an intrusion of a dike can severely modify the shallow stress field, triggering significant flank failure. In 2001, the intrusion was driven by a weakened surface, which might correspond to a decollement plane of the portion of the volcano affected by flank instability, inducing an additional stress testified by GPS measurements and seismic data, which led to an acceleration of the sliding flanks.
    Description: This work was funded by the Istituto Nazionale di Geofisica e Vulcanologia and by the Dipartimento per la Protezione Civile (Italy).
    Description: Published
    Description: 78–86
    Description: 1.3. TTC - Sorveglianza geodetica delle aree vulcaniche attive
    Description: 1.4. TTC - Sorveglianza sismologica delle aree vulcaniche attive
    Description: 1.5. TTC - Sorveglianza dell'attività eruttiva dei vulcani
    Description: 3.2. Tettonica attiva
    Description: 3.6. Fisica del vulcanismo
    Description: 4.3. TTC - Scenari di pericolosità vulcanica
    Description: JCR Journal
    Description: reserved
    Keywords: stress release ; dike ; volcano-tectonics ; flank instability ; Mt. Etna ; instrumental monitoring ; 04. Solid Earth::04.01. Earth Interior::04.01.99. General or miscellaneous ; 04. Solid Earth::04.01. Earth Interior::04.01.02. Geological and geophysical evidences of deep processes ; 04. Solid Earth::04.02. Exploration geophysics::04.02.99. General or miscellaneous ; 04. Solid Earth::04.03. Geodesy::04.03.99. General or miscellaneous ; 04. Solid Earth::04.03. Geodesy::04.03.07. Satellite geodesy ; 04. Solid Earth::04.04. Geology::04.04.99. General or miscellaneous ; 04. Solid Earth::04.04. Geology::04.04.09. Structural geology ; 04. Solid Earth::04.06. Seismology::04.06.99. General or miscellaneous ; 04. Solid Earth::04.06. Seismology::04.06.08. Volcano seismology ; 04. Solid Earth::04.07. Tectonophysics::04.07.99. General or miscellaneous ; 04. Solid Earth::04.07. Tectonophysics::04.07.05. Stress ; 04. Solid Earth::04.07. Tectonophysics::04.07.07. Tectonics ; 04. Solid Earth::04.08. Volcanology::04.08.99. General or miscellaneous ; 04. Solid Earth::04.08. Volcanology::04.08.03. Magmas ; 04. Solid Earth::04.08. Volcanology::04.08.06. Volcano monitoring ; 04. Solid Earth::04.08. Volcanology::04.08.08. Volcanic risk ; 05. General::05.02. Data dissemination::05.02.99. General or miscellaneous ; 05. General::05.02. Data dissemination::05.02.02. Seismological data ; 05. General::05.02. Data dissemination::05.02.03. Volcanic eruptions
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  • 14
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    Long-term forecast of eruption style and size at Campi Flegrei caldera (Italy) (2009)
    Elsevier
    Details
    Publication Date: 2017-04-04
    Description: The Campi Flegrei caldera is an active and restless volcano in the densely inhabited Neapolitan area of southern Italy. Because of the very high value (lives, properties, infrastructures, etc.) exposed to potential volcanic hazards, it is one of the areas at highest volcanic risk on Earth. In such a situation we have made an attempt to contribute to assessment of its volcanic hazards by providing a quantitative probabilistic longterm forecast of style and size of the next eruption. We have evaluated the most relevant physical parameters of the 22 explosive eruptions of the Campi Flegrei caldera over the past 5 ka. This time span has been taken as the reference period for volcanic hazards assessment on the basis of the volcanic and deformation history of the caldera. The evaluated parameters include dispersal, volume and density of the pyroclastic deposits, volume of erupted magma, total erupted mass, and eruption magnitude. The obtained results permit a size classification of the explosive eruptions, which are grouped into three sizes: small, medium, and large. On the basis of the reconstructed eruption dynamics, we have considered a type event(s) representative of each size class and hypothesized the style of the next event. An effusive eruption will likely generate a dome or very small lava flows, while an explosive event of any size very probably will produce particles fallout and flowage of pyroclastic density currents. Using a Bayesian inference procedure, we have assigned a conditional probability of occurrence to each of the eruption size classes. A small-size explosive eruption is the most likely event with a probability of about 60%; a large-size explosive eruption is the least likely event with a probability of about 4%; a medium-size explosive eruption has a probability of occurrence of about 25%; an effusive eruption has about 11% probability of occurrence.
    Description: Published
    Description: 265–276
    Description: 3.5. Geologia e storia dei vulcani ed evoluzione dei magmi
    Description: 4.3. TTC - Scenari di pericolosità vulcanica
    Description: JCR Journal
    Description: reserved
    Keywords: volcanic hazards assessment ; eruption size ; eruption style ; Campi Flegrei caldera ; 04. Solid Earth::04.08. Volcanology::04.08.05. Volcanic rocks ; 04. Solid Earth::04.08. Volcanology::04.08.08. Volcanic risk
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  • 15
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    Nitrogen Isotopes in Volcanic Fluids of Different Geodynamic Settings (2009)
    Elsevier
    Details
    Publication Date: 2017-04-04
    Description: Nitrogen isotopes , N2/36Ar and 3He/4He were measured in volcanic fluids within different geodynamic settings. Subduction zones are represented by Aeolian archipelago, Mexican volcanic belt and Hellenic arc, spreading zones – by Socorro island in Mexico and Iceland and hot spots by Iceland and Islands of Cabo Verde. The δ15N values, corrected for air contamination of volcanic fluids, discharged from Vulcano Island (Italy), highlighted the presence of heavy nitrogen (around +4.3 ±0.5‰). Similar 15N values (around +5‰), have been measured for the fluids collected in the Jalisco Block, that is a geologically and tectonically complex forearc zone of the northwestern Mexico [1]. Positive values (15N around +3‰) have been also measured in the volcanic fluids discharged from Nysiros island located in the Ellenic Arc characterized by subduction processes. All uncorrected data for the Socorro island are in the range of -1 to -2‰. The results of raw nitrogen isotope data of Iceland samples reveal more negative isotope composition (about -4.4‰). On the basis of the non-atmospheric N2 fraction (around 50%) the corrected data of 15N for Iceland are around -16‰, very close to the values proposed by [2]. In a volcanic gas sample from Fogo volcano (Cabo Verde islands) we found a very negative value: -9.9‰ and -15‰ for raw and corrected values, respectively.
    Description: Geochimica et Cosmochimica Acta
    Description: Published
    Description: Davos, Switzerland
    Description: 2.4. TTC - Laboratori di geochimica dei fluidi
    Description: open
    Keywords: Nitrogen Isotopes ; Helium Isotopes ; Volcanic fluids ; 04. Solid Earth::04.07. Tectonophysics::04.07.02. Geodynamics ; 04. Solid Earth::04.07. Tectonophysics::04.07.07. Tectonics ; 04. Solid Earth::04.08. Volcanology::04.08.01. Gases ; 04. Solid Earth::04.08. Volcanology::04.08.07. Instruments and techniques ; 05. General::05.02. Data dissemination::05.02.01. Geochemical data
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
    Type: Poster session
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  • 16
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    Hydrothermal methane fluxes from the soil at Pantelleria island (Italy) (2009)
    Elsevier
    Details
    Publication Date: 2017-04-04
    Description: Chemical and isotopic analyses of the main gas manifestations of the island of Pantelleria (Italy) were used to gain insight on the origin of the released methane. Results indicate that the most probable origin is through abiogenic reactions within the hydrothermal system. Methane and CO2 flux measurements from the soils were made with the accumulation chamber method in an area of about 0.015 km2 within the main fumarolic area of the island (Favara Grande). The 23 measurements range from –34 to 3550 mg m-2 d-1 for CH4 and from 0.6 to 379 g m-2 d-1 for CO2. The relationships between CH4 and CO2 fluxes and the CH4/CO2 ratios in the gases collected between 25 and 100 cm depth provide evidence for methanotrophic processes within the soils. Methane output for the surveyed area was calculated in 2.5 t a-1 and extrapolated to about 5-10 t a-1 for the entire volcanic/hydrothermal system of the island. Previous higher estimates of the CH4 output at Pantelleria (Etiope et al., 2007 - J. Volcanol. Geotherm. Res., 165, 76 – 86) were based on soil CO2 output and CH4/CO2 ratios in fumarolic gases; the present work provides the first direct CH4 flux data and it suggests that methanotrophic activity in the soil could be substantial in reducing the CH4 emission to the atmosphere.
    Description: Published
    Description: 147-157
    Description: 1.2. TTC - Sorveglianza geochimica delle aree vulcaniche attive
    Description: 4.5. Studi sul degassamento naturale e sui gas petroliferi
    Description: JCR Journal
    Description: reserved
    Keywords: hydrothermal systems ; gas geochemistry ; isotope composition ; methane output ; methanotrophic consumption ; 01. Atmosphere::01.01. Atmosphere::01.01.07. Volcanic effects ; 04. Solid Earth::04.04. Geology::04.04.12. Fluid Geochemistry ; 04. Solid Earth::04.08. Volcanology::04.08.01. Gases
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  • 17
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    Geochemical and B–Sr–Nd isotopic evidence for mingling and mixing processes in the magmatic system that fed the Astroni volcano (4.1–3.8 ka) within the Campi Flegrei caldera (southern Italy) (2009)
    Elsevier
    Details
    Publication Date: 2017-04-04
    Description: The Astroni volcano was built through seven eruptions that generated pyroclastic deposits and lava domes within the Campi Flegrei caldera (southern Italy) 4.1–3.8 ka BP. Whole-rock geochemical and B–Sr–Nd isotopic investigations were carried out on representative samples of all seven eruptions. The products vary from tephriphonolites to phonolites, and from latites to trachytes. They show textural, mineralogical and isotopic evidence of disequilibrium, including distinct clinopyroxene populations, rounded and/or resorbed plagioclase and alkali-feldspar, and reverse-zoned phenocrysts of all these mineral phases. The Sr, Nd and B isotopic composition of whole rocks is variable and correlated with the degree of chemical evolution, suggesting open-system processes in addition to fractional crystallisation. Moreover, significant Sr-isotopic disequilibrium between the phenocrysts and glass has been documented for one sample. The chemostratigraphy of the products indicates that Astroni eruptions 1 through 5 were fed by magmas of trachytic to phonolitic composition that were less enriched in radiogenic Sr and 11B up-section. This variability has been interpreted as the result of mingling between at least two distinct magmatic endmembers, one more evolved and the other less evolved. Another heterogeneous batch of magma, resulting from almost complete mixing between the same two end-members, was drained during eruptions 6 and 7. The more evolved end-member, characterised by 87Sr/86Sr≥0.7075, 143Nd/144Nd≤0.51247 and δ11B≥−8‰, was very similar to the magma that fed the final phases of the Agnano–Monte Spina eruption, which occurred a few centuries earlier in the Astroni vent area. The less evolved end-member had 87Sr/ 86Sr≤0.70726, 143Nd/144Nd≥0.51251 and δ11B≤10‰, and was likely derived by fractional crystallisation of a mantle-derived magma. An abrupt decrease in both the Sr isotope ratio and the Th content, detected at the transition between Unit 4 and 5, suggests that another magma with a 87Sr/86Sr ratio intermediate between those of the two identified end-members may have been involved in Astroni activity. The more evolved endmember is interpreted as a residue of the Agnano–Monte Spina eruption that was invaded by either the intermediate or the less evolved magmatic end-member, promoting mingling and triggering Astroni activity. This study of Astroni provides insights for both short- and long-term volcanic hazard assessment, as the Astroni volcano is the best example of a very close sequence of eruptions from the same vent area in the Campi Flegrei caldera.
    Description: Published
    Description: 135–151
    Description: 2.3. TTC - Laboratori di chimica e fisica delle rocce
    Description: 3.5. Geologia e storia dei vulcani ed evoluzione dei magmi
    Description: JCR Journal
    Description: reserved
    Keywords: Campi Flegrei caldera ; B–Sr–Nd isotope geochemistry ; Magma mingling/mixing ; Chemostratigraphy ; 04. Solid Earth::04.08. Volcanology::04.08.03. Magmas ; 04. Solid Earth::04.08. Volcanology::04.08.05. Volcanic rocks
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  • 18
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    The Paganica Fault and surface coseismic ruptures caused by the 6 april 2009 earthquake (L’Aquila, central Italy) (2009)
    Seismological Society of America
    Details
    Publication Date: 2022-06-14
    Description: On 6 April 2009, at 01:32 GMT, an Mw 6.3 seismic event hit the central Apennines, severely damaging the town of L’Aquila and dozens of neighboring villages and resulting in approximately 300 casualties (Istituto Nazionale di Geofisica e Vulcanologia, http://www.ingv.it; MedNet, http://mednet.rm.ingv.it/proce- dure/events/QRCMT/090406_013322/qrcmt.html). This earth- quake was the strongest in central Italy since the devastating 1915 Fucino event (Mw 7.0). The INGV national seismic net- work located the hypocenter 5 km southwest of L’Aquila, 8–9 km deep. Based on this information and on the seismotectonic framework of the region, earthquake geologists traveled to the field to identify possible surface faulting (Emergeo Working Group 2009a, 2009b). The most convincing evidence of pri- mary surface rupture is along the Paganica fault, the geometry of which is consistent with seismological, synthetic aperture radar (SAR) and GPS data. Investigation of other known nor- mal faults of the area, i.e., the Mt. Pettino, Mt. San Franco, and Mt. Stabiata normal faults suggested that these structures were not activated during the April 6 shock (Emergeo Working Group 2009a, 2009b). In this report, we first describe the seismotectonic frame- work of the area, and then we present the field information that supports the occurrence of surficial displacement on the Paganica fault.
    Description: Published
    Description: 940-950
    Description: 3.2. Tettonica attiva
    Description: JCR Journal
    Description: open
    Keywords: Surface coseismic ruptures ; Paganica Fault ; earthquake ; 04. Solid Earth::04.04. Geology::04.04.01. Earthquake geology and paleoseismology ; 04. Solid Earth::04.04. Geology::04.04.09. Structural geology ; 04. Solid Earth::04.06. Seismology::04.06.01. Earthquake faults: properties and evolution ; 04. Solid Earth::04.06. Seismology::04.06.03. Earthquake source and dynamics ; 04. Solid Earth::04.06. Seismology::04.06.06. Surveys, measurements, and monitoring ; 04. Solid Earth::04.07. Tectonophysics::04.07.07. Tectonics
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  • 19
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    Experimental solidification of anhydrous latitic and trachytic melts at different cooling rates: the role of nucleation kinetics (2008)
    Elsevier
    Details
    Publication Date: 2020-10-29
    Description: Two sets of cooling experiments were run at atmospheric conditions for two anhydrous starting latitic and trachytic melts: 1) five cooling rates (25, 12.5, 3, 0.5, and 0.125 °C/min) between 1300° and 800 °C, and 2) a 11 0.5 °C/min cooling rate from 1300 °C with quench temperatures at 1200°, 1100°, 1000° and 900 °C. Trachytic run-products are invariably glassy. Nucleation is also suppressed in the latitic run-products at the three highest 13 cooling rates. Conversely, in the 0.5 and 0.125 °C/min runs, latites have a crystal content of 90 vol.%. The 14 phases are: plagioclase, clinopyroxene, glass and iron-bearing oxide (in order of abundance). The variable 15 quench temperatures, investigated by coupling experiments with Pt-wire and Pt- capsule sample containers inset 2,again did not produce crystallization of trachyte, whereas latitic samples are characterized by 10 vol.% of oxides, pyroxenes and plagioclase (in order of appearance), at temperature b1000 °C. Effects of (preferential) heterogeneous nucleation on sample holders, of superheating degree, and chemical species loss during cooling are absent for both melt compositions. The difference of solidification paths between these two silicate melts can be ascribed only to their small chemical differences. In comparison with calculated equilibrium conditions all the experimental latitic and trachytic run-products revealed strong kinetic effects, interpretable in the light of the nucleation theory. The glass- forming ability (GFA) of trachyte is higher, whereas their critical cooling rate (Rc) is lower (b0.125 °C/min), in comparison to latitic melts (RcN0.5 °C/min). The experimental results carried out in this study can be applied to lava flows and domes; trachytic lavas are able to flow for longer period with respect to latitic ones in a metastable condition. Glass-rich terrestrial lavas, i.e. obsidians, can be the result of sluggish nucleation kinetics due to the relative high polymerisation of evolved silicate melts.
    Description: Published
    Description: 91-101
    Description: 2.3. TTC - Laboratori di chimica e fisica delle rocce
    Description: 3.6. Fisica del vulcanismo
    Description: JCR Journal
    Description: reserved
    Keywords: crystallization ; lava flows ; 04. Solid Earth::04.08. Volcanology::04.08.02. Experimental volcanism ; 04. Solid Earth::04.08. Volcanology::04.08.03. Magmas ; 04. Solid Earth::04.08. Volcanology::04.08.05. Volcanic rocks ; 04. Solid Earth::04.08. Volcanology::04.08.07. Instruments and techniques ; 05. General::05.02. Data dissemination::05.02.02. Seismological data
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  • 20
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    Mechanisms for ground-surface fracturing and incipient slope failure associated with the 2001 eruption of Mt. Etna, Italy: analysis of ephemeral field data (2008)
    Elsevier
    Details
    Publication Date: 2020-11-26
    Description: During the July^August 2001 eruption of Mt. Etna development of extensional fractures/faults and grabens accompanied magma intrusion and subsequent volcanic activity. During the first days of the eruption, we performed an analysis of attitude, displacement and propagation of fractures and faults exposed on the ground surface in two sites, Torre del Filosofo and Valle del Leone, located along the same fracture system in the region surrounding the Valle del Bove depression on the eastern flank of Mt. Etna. Fractures and faults formed as the consequence of a shallow intruding dyke system that fed the several volcanic centres developed along the fracture system. The investigated sites differ in slope attitude and in geometrical relationships between fractures and slopes. In particular, the fracture system propagated parallel to the gentle slope (67‡ dip) in the Torre del Filosofo area, and perpendicular to the steep slope (V25‡ dip) in the Valle del Leone area. In the Torre del Filosofo area, slight graben subsidence and horizontal extension of the ground surface by about 3 m were recorded. In the Valle del Leone area, extensional faulting forming a larger and deeper graben with horizontal extension of the ground surface by about 10 m was recorded. For the Valle del Leone area, we assessed a downhill dip of 14‡ for the graben master fault at the structural level beneath the graben where the fault dip shallows. These results suggest that dyke intrusion at Mount Etna, and particularly in the region surrounding the Valle del Bove depression, may be at the origin of slope failure and subsequent slumps where boundary conditions, i.e. geometry of dyke, slope dip and initial shear stress, amongst others, favour incipient failures.
    Description: Published
    Description: 281-294
    Description: 1.5. TTC - Sorveglianza dell'attività eruttiva dei vulcani
    Description: 3.2. Tettonica attiva
    Description: 3.5. Geologia e storia dei sistemi vulcanici
    Description: 3.6. Fisica del vulcanismo
    Description: JCR Journal
    Description: reserved
    Keywords: dykes ; extensional fractures ; grabens ; slope failures ; 04. Solid Earth::04.04. Geology::04.04.99. General or miscellaneous ; 04. Solid Earth::04.04. Geology::04.04.09. Structural geology ; 04. Solid Earth::04.07. Tectonophysics::04.07.02. Geodynamics ; 04. Solid Earth::04.07. Tectonophysics::04.07.05. Stress ; 04. Solid Earth::04.07. Tectonophysics::04.07.07. Tectonics ; 04. Solid Earth::04.08. Volcanology::04.08.99. General or miscellaneous ; 04. Solid Earth::04.08. Volcanology::04.08.03. Magmas ; 04. Solid Earth::04.08. Volcanology::04.08.05. Volcanic rocks ; 04. Solid Earth::04.08. Volcanology::04.08.06. Volcano monitoring ; 04. Solid Earth::04.08. Volcanology::04.08.08. Volcanic risk ; 05. General::05.02. Data dissemination::05.02.03. Volcanic eruptions
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  • 21
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    Carbon dioxide degassing from Tuscany and Northern Latium (Italy) (2008)
    Elsevier
    Details
    Publication Date: 2021-01-07
    Description: The CO2 degassing process from a large area on the Tyrrhenian side of central Italy, probably related to the input into the upper crust of mantle fluids, was investigated in detail through the geochemical study of gas emissions and groundwater. Mass-balance calculations and carbon isotopes show that over 50% of the inorganic carbon in regional groundwater is derived from a deep source highlighting gas−liquid separation processes at depth. The deep carbonate−evaporite regional aquifer acts as the main CO2 reservoir and when total pressure of the reservoir fluid exceeds hydrostatic pressure, a free gas phase separates from the parent liquid and escapes toward the surface generating gas emissions which characterise the study area. The distribution of the CO2 flux anomalies and the location of high PCO2 springs and gas emissions suggest that the storage and the expulsion of the CO2 toward the atmosphere are controlled by the geological and structural setting of the shallow crust. The average CO2 flux and the total amount of CO2 discharged by the study area were computed using surface heat flow, enthalpy and CO2 molality of the liquid phase circulating in the deep carbonate−evaporite aquifer. The results show that the CO2 flux varies from 1×104 mol y−1 km−2 to 5×107 mol y−1 km−2, with an average value of 4.8×106 mol y−1 km−2, about five times higher than the value of 1×106 mol y−1 derived by Kerrick et al. [Kerrick, D.M., McKibben, M.A., Seward, T.M., Caldeira, K., 1995. Convective hydrothermal CO2 emission from high heat flow regions. Chem. Geol. 121, 285–293] as baseline for terrestrial CO2 emissions. The total CO2 discharged from the study area is 0.9×1011 mol y−1, confirming that Earth degassing from Tyrrhenian central Italy is a globally relevant carbon source
    Description: Published
    Description: 89–102
    Description: 2.4. TTC - Laboratori di geochimica dei fluidi
    Description: 4.5. Degassamento naturale
    Description: JCR Journal
    Description: reserved
    Keywords: Earth degassing ; carbon dioxide ; CO2 flux ; groundwater ; 04. Solid Earth::04.02. Exploration geophysics::04.02.01. Geochemical exploration ; 04. Solid Earth::04.04. Geology::04.04.12. Fluid Geochemistry ; 04. Solid Earth::04.08. Volcanology::04.08.01. Gases ; 04. Solid Earth::04.08. Volcanology::04.08.06. Volcano monitoring
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  • 22
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    Chemical evolution of thermal waters and changes in the hydrothermal system of Papandayan volcano (West Java, Indonesia) after the November 2002 eruption (2008)
    Elsevier
    Details
    Publication Date: 2021-05-17
    Description: Papandayan is a stratovolcano situated in West Java, Indonesia. Since the last magmatic eruption in 1772,only few hydrothermal explosions have occurred. An explosive eruption occurred in November 2002 and ejected ash and altered rocks. The altered rocks show that an advanced argillic alteration took place in the hydrothermal system by interaction between acid fluids and rocks. Four zones of alteration have been defined and are limited in extension and shape along faults or across permeable structures at different levels beneath the active crater of the volcano. At the present time, the activity is centered in the northeast crater with discharge of low temperature fumaroles and acid hot springs. Two types of acid fluids are emitted in the crater of Papandayan volcano: (1) acid sulfate-chloride waters with pH between 1.6 and 4.6 and (2) acid sulfate waters with pH between 1.2 and 2.5. The water samples collected after the eruption on January 2003 reveal an increase in the SO4/Cl and Mg/Cl ratios. This evolution is likely explained by an increase in the neutralization of acid fluids and tends to show that water–rock interactions were more significant after the eruption. The evolution in the chemistry observed since 2003 is the consequence of the opening of new fractures at depth where unaltered (or less altered) volcanic rocks were in contact with the ascending acid waters. The high δ34S values (9–17‰) observed in acid sulfatechloride waters before the November 2002 eruption suggest that a significant fraction of dissolved sulfates was formed by the disproportionation of magmatic SO2. On the other hand, the low δ34S (−0.3–7‰) observed in hot spring waters sampled after the eruption suggest that the hydrothermal contribution (i.e. the surficial oxidation of hydrogen sulfide) has increased.
    Description: Published
    Description: 276-286
    Description: 1.2. TTC - Sorveglianza geochimica delle aree vulcaniche attive
    Description: 2.4. TTC - Laboratori di geochimica dei fluidi
    Description: JCR Journal
    Description: reserved
    Keywords: Papandayan volcano ; Indonesia ; phreatic eruption ; hydrothermal system ; fluid geochemistry ; advanced argillic alteration ; gas geochemistry ; 04. Solid Earth::04.08. Volcanology::04.08.01. Gases ; 04. Solid Earth::04.08. Volcanology::04.08.05. Volcanic rocks ; 04. Solid Earth::04.08. Volcanology::04.08.06. Volcano monitoring ; 05. General::05.02. Data dissemination::05.02.01. Geochemical data ; 05. General::05.02. Data dissemination::05.02.03. Volcanic eruptions
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  • 23
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    Physical properties of tuffs from a scientific borehole at Alban hills volcanic district (central Italy) (2008)
    Elsevier
    Details
    Publication Date: 2020-11-17
    Description: Recent seismic swarms and hydrothermal activity suggest that the Quaternary volcanic complex of the Alban Hills may pose a threat to the city of Rome. A 350m scientific borehole was therefore drilled into this volcanic area to elucidate its inner structure for the first time. Wire-line logs were run in the borehole in order to characterize the physical properties of the rocks and their variations with depth. In particular, a detailed sonic log was run to measure the P-wave velocity from the well-head down to 110 m. To further investigate velocity changes, we carried out laboratory measurements of P and S elastic wave velocities and fluid permeability at effective pressures up to 70 MPa during both increasing and decreasing pressure cycles on selected core samples representative of the main volcanic units. Specifically, we studied samples from two pyroclastic units representative of two classes of volcanic deposits that are representative of the whole succession: (i) a coarse-grained, well-lithified facies (Pozzolane Rosse unit), containing abundant mm-to-cm lava clasts and crystals; and (ii) a fine-grained, matrix-supported pyroclastic deposit (Tufo Pisolitico di Trigoria unit), with rare lithic lava clasts and sparse pumice. Elastic wave velocities reveal significant differences between units and indicate how, within the same lithology, the different degree of lithification and presence of clasts can affect significantly physical property values. The mean laboratory value of the Pwave velocity for Pozzolane Rosse and Tufo Pisolitico di Trigoria units is respectively of 3.75 and 3.2 km/s at an effective pressure equivalent to that at the depth at which the sonic velocity was measured. Under increasing effective pressure a profound influence on the transport properties is observed. Permeability ranges from the order of 10−18 m2 for the Pozzolane Rosse unit to the order of 10−15 m2 for the Tufo Pisolitico di Trigoria unit, in good agreement with the shallow aquifer circulating in the shallower units.
    Description: Published
    Description: 161-169
    Description: 3V. Proprietà chimico-fisiche dei magmi e dei prodotti vulcanici
    Description: JCR Journal
    Description: reserved
    Keywords: Scientific borehole ; Volcanic rocks ; Physical properties ; 04. Solid Earth::04.08. Volcanology::04.08.05. Volcanic rocks
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  • 24
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    The evolution of elastic moduli with increasing crack damage during cyclic stressing of a basalt from Mt. Etna volcano (2008)
    Elsevier
    Details
    Publication Date: 2020-11-16
    Description: Volcanic edifices, such as Mt. Etna (Italy), are commonly subject to repeated cycles of stress over time due to the combination of magma emplacement from deep reservoirs to shallow depths and superimposed tectonic stresses. Such repeated stress cycles lead to anisotropic deformation and an increase in the level of crack damage within the rocks of the edifice and hence changes to their elastic moduli, which are a key parameter for reliable modelling of deformation sources. We therefore report results of changes in elastic moduli measured during increasing amplitude cyclic stressing experiments on dry and water-saturated samples of Etna basalt. In all experiments, the Young’s modulus decreased by approximately 30% over the total sequence of loading cycles, and the Poisson’s ratio increased by a factor of approximately 3 ± 0.5. Microseismicity, in terms of acoustic emission (AE) output, was also recorded throughout each experiment. Our results demonstrate that AE output only re-commences during any loading cycle when the level of stress where AE ceased during the unloading portion of the previous cycle is exceeded; a manifestation of the Kaiser stress-memory effect. In cycles where no AE output is generated, we also observe no change in elastic moduli. This result is observed for both mechanical and thermal stressing. Our results are interpreted in relation to measurements of volcano-tectonic seismicity and deformation at Mt. Etna volcano.
    Description: Published
    Description: 153-160
    Description: 3V. Proprietà chimico-fisiche dei magmi e dei prodotti vulcanici
    Description: JCR Journal
    Description: reserved
    Keywords: rock mechanics, elastic moduli, Etna basalt ; 04. Solid Earth::04.08. Volcanology::04.08.05. Volcanic rocks
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  • 25
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    Volumetric observations during paroxysmal eruptions at Mount Etna: pressurized drainage of a shallow chamber or pulsed supply? (2008)
    Elsevier
    Details
    Publication Date: 2017-04-04
    Description: The October 17 to November 5, 1999, eruption of Mount Etna’s Bocca Nuova crater emplaced a V15U106 m3 flow field. The eruption was characterized by 11 paroxysmal events during which intense Strombolian and lava fountain activity fed vigorous channelized PaPa flows at eruption rates of up to 120 m3 s31. Each paroxysm lasted between 75 and 450 min, and was separated by periods of less intense Strombolian activity and less vigorous (610 m3 s31) effusion. Ground-based, satellite- and model-derived volumetric data show that the eruption was characterized by two periods during which eruption rates and cumulative volume showed exponential decay. This is consistent with a scenario whereby the system was depressurized during the first eruptive period (October 17^23), repressurized during an October 24 pause, and then depressurized again during the second period (October 25^28). The imbalance between the erupted and supplied volumes mean that the two periods involved the collection of 1.5^5.7U106 m3 and 1.2^ 3.6U106 m3, respectively, or an increase in the time-averaged supply to 11.6^13.6 m3 s31 and 12.5^14.9 m3 s31. Two models are consistent with the observed episodic fountaining, derived volumetric trends and calculated volume imbalance: a magma collection model and a pulsed supply model. In the former case, depressurization of a shallow reservoir cause the observed volumetric trends and foam collapse at the reservoir roof powers fountaining. In the pulsing case, variations in magma flux account for pressurization^depressurization and supply the excess volume. Increases in rise rate and volatile flux, coupled with rapid exsolution during ascent, trigger fountaining. Limiting equations that define critical foam layer volumes and magma rise rates necessary for Hawaiian-style fountaining favor the latter model.
    Description: Published
    Description: 79-95
    Description: 1.5. TTC - Sorveglianza dell'attività eruttiva dei vulcani
    Description: 3.5. Geologia e storia dei sistemi vulcanici
    Description: 3.6. Fisica del vulcanismo
    Description: 4.3. TTC - Scenari di pericolosità vulcanica
    Description: JCR Journal
    Description: reserved
    Keywords: Etna ; lava fountaining ; eruption rates ; lava channel ; foam layers ; rise rates ; 04. Solid Earth::04.01. Earth Interior::04.01.99. General or miscellaneous ; 04. Solid Earth::04.01. Earth Interior::04.01.05. Rheology ; 04. Solid Earth::04.02. Exploration geophysics::04.02.99. General or miscellaneous ; 04. Solid Earth::04.02. Exploration geophysics::04.02.05. Downhole, radioactivity, remote sensing, and other methods ; 04. Solid Earth::04.02. Exploration geophysics::04.02.07. Instruments and techniques ; 04. Solid Earth::04.04. Geology::04.04.99. General or miscellaneous ; 04. Solid Earth::04.04. Geology::04.04.11. Instruments and techniques ; 04. Solid Earth::04.08. Volcanology::04.08.99. General or miscellaneous ; 04. Solid Earth::04.08. Volcanology::04.08.01. Gases ; 04. Solid Earth::04.08. Volcanology::04.08.02. Experimental volcanism ; 04. Solid Earth::04.08. Volcanology::04.08.03. Magmas ; 04. Solid Earth::04.08. Volcanology::04.08.04. Thermodynamics ; 04. Solid Earth::04.08. Volcanology::04.08.05. Volcanic rocks ; 04. Solid Earth::04.08. Volcanology::04.08.06. Volcano monitoring ; 04. Solid Earth::04.08. Volcanology::04.08.07. Instruments and techniques ; 04. Solid Earth::04.08. Volcanology::04.08.08. Volcanic risk ; 05. General::05.02. Data dissemination::05.02.03. Volcanic eruptions
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  • 26
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    Hydrochemical dynamics of the “lake–spring” system in the crater of El Chichón volcano (Chiapas, Mexico) (2008)
    Elsevier
    Details
    Publication Date: 2017-04-04
    Description: El Chichón volcano (Chiapas, Mexico) erupted violently in March–April 1982, breaching through the former volcano–hydrothermal system. Since then, the 1982 crater has hosted a shallow (1–3.3 m, acidic (pH ∼ 2.2) and warm (∼ 30 °C) crater lake with a strongly varying chemistry (Cl/SO4=0–79 molar ratio). The changes in crater lake chemistry and volume are not systematically related to the seasonal variation of rainfall, but rather to the activity of near-neutral geyser-like springs in the crater (Soap Pool). These Soap Pool springs are the only sources of Cl for the lake. Their geyser-like behaviour with a long-term (months to years) periodicity is due to a specific geometry of the shallow boiling aquifer beneath the lake, which is the remnant of the 1983 Cl-rich (24,000 mg/l) crater lake water. The Soap Pool springs decreased in Cl content over time. The zero-time extrapolation (1982, year of the eruption) approaches the Cl content in the initial crater lake,meanwhile the extrapolation towards the future indicates a zero-Cl content by 2009±1. This particular situation offers the opportunity to calculate mass balance and Cl budget to quantify the lake–spring system in the El Chichón crater. These calculations show that the water balance without the input of SP springs is negative, implying that the lake should disappear during the dry season. The isotopic composition of lake waters (δD and δ18O) coincide with this crater lake-SP dynamics, reflecting evaporation processes and mixing with SP geyser and meteoric water. Future dome growth, not observed yet in the post-1982 El Chichón crater, may be anticipated by changes in lake chemistry and dynamics.
    Description: Published
    Description: 237–248
    Description: 1.2. TTC - Sorveglianza geochimica delle aree vulcaniche attive
    Description: 2.4. TTC - Laboratori di geochimica dei fluidi
    Description: JCR Journal
    Description: reserved
    Keywords: El Chichón volcano ; crater lake–Spring dynamics ; fluid geochemistry ; stable isotopes ; monitoring ; 04. Solid Earth::04.04. Geology::04.04.12. Fluid Geochemistry ; 04. Solid Earth::04.08. Volcanology::04.08.01. Gases ; 04. Solid Earth::04.08. Volcanology::04.08.06. Volcano monitoring ; 05. General::05.02. Data dissemination::05.02.01. Geochemical data
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  • 27
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    Estimating thermal inflow to El Chichón crater lake using the energy-budget, chemical and isotope balance approaches (2008)
    Elsevier
    Details
    Publication Date: 2017-04-04
    Description: El Chichón crater lake appeared immediately after the 1982 catastrophic eruption in a newly formed, 1-km wide, explosive crater. During the first 2 years after the eruption the lake transformed from hot and ultraacidic caused by dissolution of magmatic gases, to a warm and less acidic lake due to a rapid “magmatic-tohydrothermal transition” — input of hydrothermal fluids and oxidation of H2S to sulfate. Chemical composition of the lake water and other thermal fluids discharging in the crater, stable isotope composition (δD and δ18O) of lake water, gas condensates and thermal waters collected in 1995–2006 were used for the mass-balance calculations (Cl, SO4 and isotopic composition) of the thermal flux from the crater floor. The calculated fluxes of thermal fluid by different mass-balance approaches become of the same order of magnitude as those derived from the energy-budget model if values of 1.9 and 2 mmol/mol are taken for the catchment coefficient and the average H2S concentration in the hydrothermal vapors, respectively. The total heat power from the crater is estimated to be between 35 and 60 MW and the CO2 flux is not higher than 150 t/day or ~200 gm−2 day−1.
    Description: Published
    Description: 472-481
    Description: 1.2. TTC - Sorveglianza geochimica delle aree vulcaniche attive
    Description: 2.4. TTC - Laboratori di geochimica dei fluidi
    Description: JCR Journal
    Description: reserved
    Keywords: El Chichón ; crater lake ; mass-energy budget ; CO2 flux ; 04. Solid Earth::04.04. Geology::04.04.12. Fluid Geochemistry ; 05. General::05.02. Data dissemination::05.02.01. Geochemical data ; 05. General::05.02. Data dissemination::05.02.04. Hydrogeological data
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  • 28
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    Belt bending driven by lateral bending of subducting lithospheric slab: geophysical evidences from the northern Apennines (Italy) (2008)
    Elsevier
    Details
    Publication Date: 2017-04-04
    Description: Many of the mountain belts displaying a curved shape are "oroclines", i.e. are produced after progressive bending of an originally straight fold and thrust belt. The bending process was previously explained as a consequence of several possible events taking place in the crustal orogenic wedge, such as occurrence of obstacles, non-coaxial deformation, and mouvements on wrench faults. Recent paleomagnetic results from the northern Apenninic Arc document that this belt is properly an orocline and results from Late Messinian-Early Pliocene bending of a Messinian straight belt-foredeep system. Tomographic images in turn show the presence of a high-velocity body, interpreted as subducted slab, in the upper mantle beneath the northern Apennines, between 35 and 670 km depth. Down to 100 km, this body displays an arcuate shape which closely mirrors the geological outlines, while it appears to be straight (and parallel to the Messinian pre-rotated belt) at depth. We explore here the possibility that the arcuate shape of the northern Apennines is a consequence, closely following in time, on much deeper processes than previously suggested, i.e. the lateral bending of the subducting Adriatic plate.
    Description: Published
    Description: 53-64
    Description: JCR Journal
    Description: reserved
    Keywords: paleomagnetism ; seismic tomography ; Northern Apennines ; orocline ; 04. Solid Earth::04.05. Geomagnetism::04.05.06. Paleomagnetism ; 04. Solid Earth::04.06. Seismology::04.06.07. Tomography and anisotropy ; 04. Solid Earth::04.07. Tectonophysics::04.07.02. Geodynamics ; 04. Solid Earth::04.07. Tectonophysics::04.07.07. Tectonics
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  • 29
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    Transpressive strain on the Lipari–Vulcano volcanic complex and dynamics of the “La Fossa” cone (Aeolian Islands, Sicily) revealed by GPS surveys on a dense network (2008)
    Elsevier
    Details
    Publication Date: 2017-04-04
    Description: Ground deformation resulting from the last two GPS surveys carried out in March 2006 and September 2007 on the Lipari–Vulcano volcanic complex are analyzed. Data inversion was performed by Genetic Algorithms approach, using the horizontal strain measured on 258 GPS baselines, in order to avoid bias due to the ambiguity in fixing the reference system and to disregard the vertical deformation of the “La Fossa” cone. There are two networks in this area: the main Lipari–Vulcano network and the denser Vulcano–Nord one. Surveying strategies adopted for the main network during the latest surveys allowed long baselines, from Lipari and Vulcano to the surrounding permanent stations in the southern Tyrrhenian, to be processed with reliable accuracy. The fast-static strategy was instead adopted to survey the Vulcano–Nord network. Data from the main Lipari–Vulcano network has been processed in the ITRF05 frame and also in a local reference frame together with the Vulcano–Nord data. A significant Northward motion of Vulcano island with respect to the ITRF05 has been detected. This motion abruptly decreases in the northern part of Vulcano, suggesting a decoupling of the main Vulcano island from the rest of the volcanic complex. The analysis in the local reference frame evidenced a relative SSE-ward motion of Lipari and Northern part of Vulcano, with respect to the central and southern Vulcano. This comparison also highlights a local uplift of the “La Fossa” cone. In addition, a strain tensor analysis was performed, which highlighted a main NNE–SSW contraction and a minor ESE–WNW extension detected only on the southern part of Vulcano. This results are in agreement with a transpressive kinematics of the Lipari–Vulcano volcanic complex, with a main dextral component of displacement along a NW–SE striking structure.
    Description: Published
    Description: 64-70
    Description: 1.3. TTC - Sorveglianza geodetica delle aree vulcaniche attive
    Description: JCR Journal
    Description: reserved
    Keywords: Volcano-tectonics ; Modeling ; ground deformation ; Tyrrhenian sea ; 04. Solid Earth::04.03. Geodesy::04.03.06. Measurements and monitoring ; 04. Solid Earth::04.03. Geodesy::04.03.07. Satellite geodesy ; 04. Solid Earth::04.03. Geodesy::04.03.08. Theory and Models ; 04. Solid Earth::04.03. Geodesy::04.03.09. Instruments and techniques ; 04. Solid Earth::04.07. Tectonophysics::04.07.07. Tectonics ; 04. Solid Earth::04.07. Tectonophysics::04.07.08. Volcanic arcs
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  • 30
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    Middle Pleistocene to Holocene activity of the Gondola Fault Zone (Southern Adriatic Foreland): deformation of a regional shear zone and seismotectonic implications (2008)
    Elsevier
    Details
    Publication Date: 2017-04-04
    Description: Recent seismicity in and around the Gargano Promontory, an uplifted portion of the Southern Adriatic Foreland domain, indicates active E–W strike-slip faulting in a region that has also been struck by large historical earthquakes, particularly along the Mattinata Fault. Seismic profiles published in the past two decades show that the pattern of tectonic deformation along the E–W-trending segment of the Gondola Fault Zone, the offshore counterpart of the Mattinata Fault, is strikingly similar to that observed onshore during the Eocene–Pliocene interval. Based on the lack of instrumental seismicity in the south Adriatic offshore, however, and on standard seismic reflection data showing an undisturbed Quaternary succession above the Gondola Fault Zone, this fault zone has been interpreted as essentially inactive since the Pliocene. Nevertheless, many investigators emphasised the genetic relationships and physical continuity between the Mattinata Fault, a positively active tectonic feature, and the Gondola Fault Zone. The seismotectonic potential of the system formed by these two faults has never been investigated in detail. Recent investigations of Quaternary sedimentary successions on the Adriatic shelf, by means of very high-resolution seismic–stratigraphic data, have led to the identification of fold growth and fault propagation in Middle–Upper Pleistocene and Holocene units. The inferred pattern of gentle folding and shallow faulting indicates that sediments deposited during the past ca. 450 ka were recurrently deformed along the E–W branch of the Gondola Fault Zone. We performed a detailed reconstruction and kinematic interpretation of the most recent deformation observed along the Gondola Fault Zone and interpret it in the broader context of the seismotectonic setting of the Southern Apennines-foreland region. We hypothesise that the entire 180 km-long Molise–Gondola Shear Zone is presently active and speculate that also its offshore portion, the Gondola Fault Zone, has a seismogenic behaviour.
    Description: Study supported by ISMAR-CNR projects EUROSTRATAFORM (EVK3-CT-2002-00079) and “Rischi Sottomarini”(GNDT 2000–2004) and by the Project S2 funded in the framework of the 2004–2006 agreement between the Italian Department of Civil Protection and INGV (Research Unit 2.4). This is ISMAR-CNR (Bologna) contribution n. 1570.
    Description: Published
    Description: 110-121
    Description: 3.2. Tettonica attiva
    Description: JCR Journal
    Description: reserved
    Keywords: Quaternary ; Foreland deformation ; Active fault ; Adriatic Sea ; 04. Solid Earth::04.02. Exploration geophysics::04.02.06. Seismic methods ; 04. Solid Earth::04.04. Geology::04.04.04. Marine geology ; 04. Solid Earth::04.04. Geology::04.04.10. Stratigraphy ; 04. Solid Earth::04.07. Tectonophysics::04.07.07. Tectonics
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  • 31
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    Intrusion of eccentric dikes: The case of the 2001 eruption and its role in the dynamics of Mt. Etna volcano (2008)
    Elsevier
    Details
    Publication Date: 2017-04-04
    Description: The 2001 eruption represents one of the most studied events both from volcanological and geophysical point of view on Mt. Etna. This eruption was a crucial event in the recent dynamic of the volcano, marking the passage from a period (March 1993 – June 2001) of moderate stability with slow, continuous flank sliding and contemporaneous summit eruptions, to a period (July 2001 to present) of dramatically increased flank deformations and flank eruptions. We show new GPS data and high precision relocation of seismicity in order to demonstrate the role of the 2001 intrusive phase in this change of the dynamic regime of the volcano. GPS data consist of two kinematic surveys carried out on 12 July, a few hours before the beginning of the seismic swarm, and on 17 July, just after the onset of eruptive activity. A picture of the spatial distribution of the sin-eruptive seismicity has been obtained using the HypoDD relocation algorithm based on the double-difference (DD) technique. Modeling of GPS measurements reveal a southward motion of the upper southern part of the volcano, driven by a NNW-SSE structure showing mainly left-lateral kinematics. Precise hypocenter location evidences an aseismic zone at about sea level, where the magma upraise was characterized by a much higher velocity and an abrupt westward shift, revealing the existence of a weakened or ductile zone. These results reveal how an intrusion of a dike can severely modify the shallow stress field, triggering significant flank failure. In 2001, the intrusion was driven by a weakened surface, which might correspond to a decollement plane of the portion of the volcano affected by flank instability, inducing an additional stress testified by GPS measurements and seismic data, which led to an acceleration of the sliding flanks.
    Description: In press
    Description: 1.1. TTC - Monitoraggio sismico del territorio nazionale
    Description: 1.3. TTC - Sorveglianza geodetica delle aree vulcaniche attive
    Description: 1.4. TTC - Sorveglianza sismologica delle aree vulcaniche attive
    Description: 1.5. TTC - Sorveglianza dell'attività eruttiva dei vulcani
    Description: 3.2. Tettonica attiva
    Description: 3.5. Geologia e storia dei sistemi vulcanici
    Description: 3.6. Fisica del vulcanismo
    Description: 4.2. TTC - Scenari e mappe di pericolosità sismica
    Description: 4.3. TTC - Scenari di pericolosità vulcanica
    Description: 4.4. Scenari e mitigazione del rischio ambientale
    Description: JCR Journal
    Description: reserved
    Keywords: Stress release ; Dike ; Volcano-tectonics ; Flank instability ; Mount Etna ; Instrumental monitoring ; 04. Solid Earth::04.01. Earth Interior::04.01.99. General or miscellaneous ; 04. Solid Earth::04.01. Earth Interior::04.01.02. Geological and geophysical evidences of deep processes ; 04. Solid Earth::04.02. Exploration geophysics::04.02.99. General or miscellaneous ; 04. Solid Earth::04.03. Geodesy::04.03.99. General or miscellaneous ; 04. Solid Earth::04.03. Geodesy::04.03.06. Measurements and monitoring ; 04. Solid Earth::04.03. Geodesy::04.03.07. Satellite geodesy ; 04. Solid Earth::04.04. Geology::04.04.99. General or miscellaneous ; 04. Solid Earth::04.04. Geology::04.04.01. Earthquake geology and paleoseismology ; 04. Solid Earth::04.04. Geology::04.04.09. Structural geology ; 04. Solid Earth::04.06. Seismology::04.06.99. General or miscellaneous ; 04. Solid Earth::04.06. Seismology::04.06.03. Earthquake source and dynamics ; 04. Solid Earth::04.06. Seismology::04.06.04. Ground motion ; 04. Solid Earth::04.06. Seismology::04.06.08. Volcano seismology ; 04. Solid Earth::04.07. Tectonophysics::04.07.99. General or miscellaneous ; 04. Solid Earth::04.07. Tectonophysics::04.07.02. Geodynamics ; 04. Solid Earth::04.07. Tectonophysics::04.07.05. Stress ; 04. Solid Earth::04.07. Tectonophysics::04.07.07. Tectonics ; 04. Solid Earth::04.08. Volcanology::04.08.99. General or miscellaneous ; 04. Solid Earth::04.08. Volcanology::04.08.06. Volcano monitoring ; 04. Solid Earth::04.08. Volcanology::04.08.07. Instruments and techniques ; 04. Solid Earth::04.08. Volcanology::04.08.08. Volcanic risk ; 05. General::05.02. Data dissemination::05.02.03. Volcanic eruptions
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  • 32
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    Structural features of the 2007 Stromboli eruption (2008)
    Elsevier
    Details
    Publication Date: 2017-04-04
    Description: On 27 February 2007, two NE–SW and NNW–SSE dike-fed effusive vents opened to the North (at 650 and 400 m above sea level, asl) of the summit craters at Stromboli, forming a fissure parallel to the inner walls of the Sciara del Fuoco (SdF) sector collapse depression. The formation of these vents was soon followed by rapid subsidence of the summit crater area. This partly obstructed the central conduit, temporarily choking the fissure and increasing the deformation of the upper part of SdF. The reactivation of the NNW–SSE vent and the opening of a new vent located at 500 m asl, fed by a second dike, released the internal pressure and surface deformation ceased. The eruption then continued again from the 400 m vent, after a summit explosion on 15 March, until ending in early April after a progressive decrease of magma output. Repeated NE–SW dike intrusions have occurred in recent years, close to the upper SE limit of the SdF. In that zone, named Bastimento, the eruptive fractures traced the discontinuities that borders the SdF, increasing the risk of triggering new sector collapse. Whereas the NE–SW trending structures lie along the regional volcanostructural trend of the Aeolian arc through Stromboli, the NNW–SSE vents are oblique to this trend and may be controlled by the anomalous stress field within the unstable flank of the SdF. Another fundamental aspect of the 2007 eruption is the collapse of the central conduit, due to the rapid and deep magma drainage linked to the opening of the 400 m vent. The intrusion of dikes and development of flank vents during the 2007 eruption could possibly have triggered catastrophic landslides and related tsunami or eruptive paroxysms, but the opening of new effusive vents released the internal pressures, diminishing the hazard.
    Description: In press
    Description: 1.5. TTC - Sorveglianza dell'attività eruttiva dei vulcani
    Description: 3.2. Tettonica attiva
    Description: 3.5. Geologia e storia dei sistemi vulcanici
    Description: 3.6. Fisica del vulcanismo
    Description: 4.3. TTC - Scenari di pericolosità vulcanica
    Description: JCR Journal
    Description: reserved
    Keywords: 2007 Stromboli eruption ; Dike-fed vent ; Volcano-Tectonics ; Conduit collapse ; Flank instability ; 04. Solid Earth::04.04. Geology::04.04.99. General or miscellaneous ; 04. Solid Earth::04.04. Geology::04.04.09. Structural geology ; 04. Solid Earth::04.07. Tectonophysics::04.07.99. General or miscellaneous ; 04. Solid Earth::04.07. Tectonophysics::04.07.07. Tectonics ; 04. Solid Earth::04.07. Tectonophysics::04.07.08. Volcanic arcs ; 04. Solid Earth::04.08. Volcanology::04.08.99. General or miscellaneous ; 04. Solid Earth::04.08. Volcanology::04.08.06. Volcano monitoring ; 04. Solid Earth::04.08. Volcanology::04.08.08. Volcanic risk ; 05. General::05.08. Risk::05.08.99. General or miscellaneous
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  • 33
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    Comparison between different methodologies for detecting Radon in soil along an active fault: the case of the Pernicana fault system, Mt. Etna (Italy) (2008)
    Elsevier
    Details
    Publication Date: 2017-04-04
    Description: Three different methodologies were used to measure Radon (222Rn) in soil, based on both passive and active detection system. The first technique consisted of Solid State Nuclear Track Detectors (SSNTD), CR-39 type, and allowed integrated measurements. The second one consisted of a portable device for short time measurements. The last consisted of a continuous measurement device for extended monitoring, placed in selected sites. Soil 222Rn activity was measured together with soil Thoron (220Rn) and soil carbon dioxide (CO2) efflux, and it was compared with the content of radionuclides in the rocks. Two different soil gas horizontal transects were investigated across the Pernicana fault system (NE flank of Mount Etna), from November 2006 to April 2007. The results obtained with the three methodologies are in a general agreement with each other and reflect the tectonic settings of the investigated study area. The lowest 222Rn values were recorded just on the fault plane, and relatively higher values were recorded a few tens of meters from the fault axis on both of its sides. This pattern could be explained as a dilution effect resulting from high rates of soil CO2 efflux. Time variations of 222Rn activity were mostly linked to atmospheric influences, whereas no significant correlation with the volcanic activity was observed. In order to further investigate regional radon distributions, spot measurements were made to identify sites having high Rn emissions that could subsequently be monitored for temporal radon variations.. SSNTD measurements allow for extended-duration monitoring of a relatively large number of sites, although with some loss of temporal resolution due to their long integration time. Continuous monitoring probes are optimal for detailed time monitoring, but because of their expense, they can best be used to complement the information acquired with SSNTD in a network of monitored sites.
    Description: In press
    Description: 1.2. TTC - Sorveglianza geochimica delle aree vulcaniche attive
    Description: 1.5. TTC - Sorveglianza dell'attività eruttiva dei vulcani
    Description: 3.2. Tettonica attiva
    Description: 4.4. Scenari e mitigazione del rischio ambientale
    Description: 4.5. Degassamento naturale
    Description: JCR Journal
    Description: reserved
    Keywords: Soil Radon and Thoron activity ; soil CO2 efflux ; Pernicana fault system ; Mount Etna ; volcano-tectonic monitoring ; 03. Hydrosphere::03.04. Chemical and biological::03.04.07. Radioactivity and isotopes ; 03. Hydrosphere::03.04. Chemical and biological::03.04.08. Instruments and techniques ; 04. Solid Earth::04.01. Earth Interior::04.01.99. General or miscellaneous ; 04. Solid Earth::04.02. Exploration geophysics::04.02.01. Geochemical exploration ; 04. Solid Earth::04.02. Exploration geophysics::04.02.05. Downhole, radioactivity, remote sensing, and other methods ; 04. Solid Earth::04.04. Geology::04.04.99. General or miscellaneous ; 04. Solid Earth::04.04. Geology::04.04.06. Rheology, friction, and structure of fault zones ; 04. Solid Earth::04.04. Geology::04.04.09. Structural geology ; 04. Solid Earth::04.06. Seismology::04.06.99. General or miscellaneous ; 04. Solid Earth::04.07. Tectonophysics::04.07.99. General or miscellaneous ; 04. Solid Earth::04.07. Tectonophysics::04.07.07. Tectonics ; 04. Solid Earth::04.08. Volcanology::04.08.99. General or miscellaneous ; 04. Solid Earth::04.08. Volcanology::04.08.06. Volcano monitoring ; 04. Solid Earth::04.08. Volcanology::04.08.07. Instruments and techniques
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  • 34
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    Major and trace element geochemistry of neutral and acidic thermal springs at El Chichón volcano, Mexico Implications for monitoring of the volcanic activity (2008)
    Elsevier
    Details
    Publication Date: 2017-04-04
    Description: Four groups of thermal springs with temperatures from 50 to 80 °C are located on the S–SW–W slopes of El Chichón volcano, a composite dome-tephra edifice, which exploded in 1982 with a 1 km wide, 160 m deep crater left. Very dynamic thermal activity inside the crater (variations in chemistry and migration of pools and fumaroles, drastic changes in the crater lake volume and chemistry) contrasts with the stable behavior of the flank hot springs during the time of observations (1974–2005). All known groups of hot springs are located on the contact of the basement and volcanic edifice, and only on the W–SW–S slopes of the volcano at almost same elevations 600–650 m asl and less than 3 km of direct distance from the crater. Three groups of near-neutral (pH≈6) springs at SW–S slopes have the total thermal water outflow rate higher than 300 l/s and are similar in composition. The fourth and farthest group on the western slope discharges acidic (pH≈2) saline (10 g/kg of Cl) water with a much lower outflow rate (b10 l/s). Water–rock interaction modeling of main types of the El Chichón thermal waters using regular log Q/K graphs (saturation indices vs temperature) showed maximum equilibrium temperature slightly higher than 200 °C. Acidic waters are equilibrated with some clay minerals at about 120 °C. Three main sources of the salinity of thermal water are suggested on the basis of mixing plots and isotopic data: a magmatic source for CO2, boron, sulfur and a limited part of Cl; volcanic rock source for the major cations and trace elements; the oil-bearing evaporitic basement source (oil-field brine?) for NaCl, Br, a part of Ca and some trace elements. All flank thermal springs end up in the river Rio Magdalena that has a variable seasonal flow rates from 4 to 20 m3/s. Any changes in the chemistry of springs must notably change the composition of the streams draining hot springs and eventually, Rio Magdalena. A monthly geochemical monitoring of Rio Magdalena and streams draining main hot springs would be a useful tool for surveying the activity of the volcano.
    Description: Published
    Description: 224–236
    Description: 2.4. TTC - Laboratori di geochimica dei fluidi
    Description: JCR Journal
    Description: reserved
    Keywords: volcano–hydrothermal system ; crater lake ; acidic water ; trace elements ; thermochemical modeling ; El Chichón volcano ; 04. Solid Earth::04.04. Geology::04.04.12. Fluid Geochemistry ; 04. Solid Earth::04.08. Volcanology::04.08.06. Volcano monitoring ; 05. General::05.02. Data dissemination::05.02.01. Geochemical data
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  • 35
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    Modeling the interplay of fO2 and fS2 along the FeS-silicate melt equilibrium (2008)
    Elsevier
    Details
    Publication Date: 2017-04-04
    Description: In this paper we will discuss a simplified thermodynamic description for the saturation of FeS, either liquid or solid, in magmatic melts. The Conjugated-Toop–Samis–Flood–Grjotheim model [Moretti R. and Ottonello G., 2005. Solubility and speciation of sulfur in silicate melts, the Conjugated-Toop–Samis–Flood–Grjotheim (CTSFG) model. Geochimica et Cosmochimica Acta, 69, 801–823] has furnished the theoretical reference frame, since it already accounts for the solubility of gaseous sulfur and the speciation and oxidation state of sulfur in silicate melts. We provide a new model to predict the saturation of magmatic silicate melts with an FeS phase that is internally consistent with these previous parameterizations. The derived model provides an effective sulfogeobarometer, which is superior with respect to previous models. For magmas rising from depth to surface, our appraisal of molar volumes of sulfur-bearing species in silicate melts allows us to model oxidation–reduction processes at different pressures, and sulfur concentrations for saturationwith either liquid or solid phases. In this respect, the nature of the oxygen fugacity buffer is critical. On the basis of model results on some typical compositions of volcanological interest, the sulfur contents at sulfide saturation (SCSS) have been calculated and the results duplicate the experimental observations that the SCSS is positively correlatedwith pressure forwatersaturated acidic melts and negatively correlated with pressure for water-poor basaltic melts. This new model provides fO2–fS2 pairs of FeS saturation of natural silicatemelts. In caseswhere the redox constraint is lacking, the model can be used to investigate whether the dissolved sulfur content approaches SCSS or not, and if so, to estimate at which fO2 value the silicate melt is saturated with a sulfide phase
    Description: Published
    Description: 286–298
    Description: 2.3. TTC - Laboratori di chimica e fisica delle rocce
    Description: 3.6. Fisica del vulcanismo
    Description: JCR Journal
    Description: reserved
    Keywords: Sulfur ; Silicate melt ; Iron sulfide ; Chemical thermodynamics ; 04. Solid Earth::04.08. Volcanology::04.08.01. Gases ; 04. Solid Earth::04.08. Volcanology::04.08.03. Magmas ; 04. Solid Earth::04.08. Volcanology::04.08.04. Thermodynamics ; 04. Solid Earth::04.08. Volcanology::04.08.05. Volcanic rocks
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  • 36
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    Fingerprinting ash deposits of small scale eruptions by their physical and textural features (2008)
    Elsevier
    Details
    Publication Date: 2017-04-04
    Description: Correlation of distal ash deposits with their proximal counterparts mainly relies on chemical and mineralogical characterization of bulk rock and matrix glasses. However, the study of juvenile fragments often reveals the heterogeneity in terms of clast shape, external surface, groundmass texture and composition. This is particularly evident in small scale eruptions, characterized by a strong variability in texture and relative abundance of juvenile fragments. This heterogeneity introduces an inherent uncertainty, that makes the compositional data alone inadequate to unequivocally characterize the tephra bed. Pyroclast characteristics, if described and quantified, can represent an additional clue for the correct identification of the tephra. The paper presents morphological, textural and compositional data on the products of an ash eruption from Middle Age activity of Vesuvius, to demonstrate the information that can be extracted from the proposed type of analysis. Juvenile fragments from five ash layers throughout the studied products were randomly hand-picked and fully characterized in terms of external morphology, particle outline parameterization, groundmass texture and glass composition. Statistical analysis of shape parameters characterized groups of fragments that can be compared with the other textural and physical parameters. The main result is that the data do not show important cross-correlation so suggesting that all of these parameters, together with accurate field data are needed for the complete fingerprinting of a tephra bed. We suggest that this approach is especially important for characterizing the products of small scale, compositionally undistinguishable, eruptions and represents the necessary step to deal with before going into more detailed compositional analyses.
    Description: Published
    Description: 277-287
    Description: 3.5. Geologia e storia dei sistemi vulcanici
    Description: JCR Journal
    Description: reserved
    Keywords: tephrostratigraphic methods ; shape parameters ; groundmass texture ; mid-intensity eruptions ; ash deposits ; 04. Solid Earth::04.08. Volcanology::04.08.05. Volcanic rocks ; 04. Solid Earth::04.08. Volcanology::04.08.06. Volcano monitoring
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  • 37
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    Deep water gravity core from the Marsili Basin (Tyrrhenian Sea) records Pleistocenic–Holocenic explosive events and instability of the Aeolian Archipelago (2008)
    Elsevier
    Details
    Publication Date: 2017-04-04
    Description: A 4.8 m long gravity core was recovered on a relative topographic high in the northern part of the Marsili Basin (southern Tyrrhenian Sea) at a water depth of 3200 m. The core was taken in order to decipher the sedimentary record of the past volcanic events of the nearby Aeolian arc. A succession of thin (2 cm to 5 cm thick) fine-grained turbidites, mainly of volcaniclastic origin, topped by hemipelagic mud layers and a number of primary tephra layers were recovered by the core. The most prominent turbidite occurs in the lower part of the core at 385 cm. It consists of a 20 cm-thick, thinning-upward, pebble to sand-sized bed. Grain-size analysis and component compositions in the 0.063–0.250 mm size fractions were determined on thirty samples taken from primary tephra beds and the silty–sandy basal part of the volcaniclastic turbidite units. SEM scans and glass fraction chemical analyses were successively carried out on a selection of 17 samples. To aid source correlation and comparison, sub-aerial tephras of the Lower Pollara (Salina, 24 ± 3.6 ka), Gabellotto-Fiumebianco (Lipari, 8.5 or 11.5 ka), Monte Pilato (Lipari, 749 or 580 AD) and Secche di Lazzaro (Stromboli, ~ 5 ka) eruptions were also analyzed with the same procedure. Primary tephra respectively belonging to the eruptions of Lower Pollara, Gabellotto-Fiumebianco and Vesuvius (AP eruptions 3.5 ka–79 AD) were identified in the core at the expected relative stratigraphic depths. Two turbidite beds composed of monogenic glass shards were also identified and interpreted as the remobilisation of primary tephras of Secche di Lazzaro (Stromboli, 5 ka) and Pilato (Lipari, 580 or 749 AD). Tephrochronology results indicate that the cored sequence formed in the last 30 ka suggesting an average sedimentation rate of 0.15–0.17 mm/y. The thick pebbly sandy turbidite unit in the lower part of the core has component and glass composition compatible with the Lower Pollara volcanic sequence of Salina Island. In view of the grain-size and thickness of the turbidite unit, we suggest that it represents the deposit of a large failure event. The tephra corresponding to the Lower Pollara event lies below the turbidite unit, separated by 16 cm of hemipelagic mud, indicating that the collapse took place sometime after the eruption.
    Description: Published
    Description: 133-144
    Description: 2.3. TTC - Laboratori di chimica e fisica delle rocce
    Description: 3.5. Geologia e storia dei sistemi vulcanici
    Description: 3.6. Fisica del vulcanismo
    Description: JCR Journal
    Description: reserved
    Keywords: tephrochronology ; turbidity current ; flank collapse ; Marsili Basin ; gravity core ; 04. Solid Earth::04.04. Geology::04.04.04. Marine geology ; 04. Solid Earth::04.04. Geology::04.04.08. Sediments: dating, processes, transport ; 04. Solid Earth::04.08. Volcanology::04.08.05. Volcanic rocks
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  • 38
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    Seismotectonics of strike–slip earthquakes within the deep crust of southern Italy: Geometry, kinematics, stress field and crustal rheology of the Potenza 1990–1991 seismic sequences (Mmax 5.7) (2008)
    Elsevier
    Details
    Publication Date: 2017-04-04
    Description: We present a revision and a seismotectonic interpretation of deep crust strike–slip earthquake sequences that occurred in 1990– 1991 in the Southern Apennines (Potenza area). The revision is motivated by: i) the striking similarity to a seismic sequence that occurred in 2002 ∼140 km NNW, in an analogous tectonic context (Molise area), suggesting a common seismotectonic environment of regional importance; ii) the close proximity of such deep strike–slip seismicity with shallow extensional seismicity (Apennine area); and iii) the lack of knowledge about the mechanical properties of the crust that might justify the observed crustal seismicity. A comparison between the revised 1990–1991 earthquakes and the 2002 earthquakes, as well as the integration of seismological data with a rheological analysis offer new constraints on the regional seismotectonic context of crustal seismicity in the Southern Apennines. The seismological revision consists of a relocation of the aftershock sequences based on newly constrained velocity models. New focal mechanisms of the aftershocks are computed and the active state of stress is constrained via the use of a stress inversion technique. The relationships among the observed seismicity, the crustal structure of the Southern Apennines, and the rheological layering are analysed along a crustal section crossing southern Italy, by computing geotherms and two-mechanism (brittle frictional vs. ductile plastic strength) rheological profiles. The 1990–1991 seismicity is concentrated in a well-defined depth range (mostly between 15 and 23 km depths). This depth range corresponds to the upper pat of the middle crust underlying the Apulian sedimentary cover, in the footwall of the easternmost Apennine thrust system. The 3D distribution of the aftershocks, the fault kinematics, and the stress inversion indicate the activation of a right-lateral strike–slip fault striking N100°E under a stress field characterized by a sub-horizontal N142°-trending σ1 and a sub-horizontal N232°-trending σ3, very similar to the known stress field of the Gargano seismic zone in the Apulian foreland. The apparent anomalous depths of the earthquakes (N15 km) and the confinement within a relatively narrow depth range are explained by the crustal rheology, which consists of a strong brittle layer at mid crustal depths sandwiched between two plastic horizons. This articulated rheological stratification is typical of the central part of the Southern Apennine crust, where the Apulian crust is overthrusted by Apennine units. Both the Potenza 1990–1991 and the Molise 2002 seismic sequences can be interpreted to be due to crustal E–W fault zones within the Apulian crust inherited from previous tectonic phases and overthrusted by Apennine units during the Late Pliocene–Middle Pleistocene. The present strike–slip tectonic regime reactivated these fault zones and caused them to move with an uneven mechanical behaviour; brittle seismogenic faulting is confined to the strong brittle part of the middle crust. This strong brittle layer might also act as a stress guide able to laterally transmit the deviatoric stresses responsible for the strike–slip regime in the Apulian crust and may explain the close proximity (nearly overlapping) of the strike–slip and normal faulting regimes in the Southern Apennines. From a methodological point of view, it seems that rather simple two-mechanism rheological profiles, though affected by uncertainties, are still a useful tool for estimating the rheological properties and likely seismogenic behaviour of the crust.
    Description: Published
    Description: 281–300
    Description: 3.2. Tettonica attiva
    Description: JCR Journal
    Description: reserved
    Keywords: Strike–slip seismicity; ; Deep crust; ; Active stress; ; Crustal rheology; ; Seismotectonics; ; Southern Apennines ; 04. Solid Earth::04.07. Tectonophysics::04.07.07. Tectonics
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  • 39
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    The role of pre-existing thrust faults and topography on the styles of extension in the Gran Sasso range (central Italy) (2008)
    Elsevier
    Details
    Publication Date: 2017-04-04
    Description: Structural analysis and field mapping together with simple geometrical and flexural elastic models, document that two styles of Quaternary extensional tectonics characterized the Gran Sasso range (central Apennines, Italy). In the western part of the range, extension took place on 10–15-km-long range-front normal faults with associated 600–1000-m-high escarpments showing evidence of Late Glacial–Holocene activity. This topography has been reproduced with a thin elastic plate subjected to the isostatic forces induced by the movement along high-angle (55°–65°) planar normal faults. In the eastern part of the belt extension occurred on shallow-dipping normal faults (30°–35°) which reactivated progressively deeper pre-existing thrusts. In this area antithetic "domino" faults formed to accommodate the mechanical adjustment of the hanging-wall over a variably dipping major fault surface. The eastward increase in shortening, due to the earlier compressional phase, documented in the Gran Sasso belt by previous authors, accounts for the more developed zones of weakness and high topographic relief in the eastern sector. This setting could explain the different styles of extension and the more advanced northeastern limit of normal faulting in the eastern sector. This work suggests that normal faults can originate either with low- or high-angle geometry in the upper crust according to the pre-existing tectonic setting and that topography could be important in controlling the geometry and pattern of migrating normal faulting.
    Description: Published
    Description: 229-254
    Description: JCR Journal
    Description: reserved
    Keywords: extensional tectonics ; Quaternary ; thrust faults ; topography ; Apennines ; 04. Solid Earth::04.04. Geology::04.04.09. Structural geology ; 04. Solid Earth::04.07. Tectonophysics::04.07.07. Tectonics
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  • 40
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    Dike propagation in volcanic edifices: Overview and possible developments (2008)
    Elsevier
    Details
    Publication Date: 2017-04-04
    Description: Eruptions are often fed by dikes; therefore, better knowledge of dike propagation is necessary to improve our understanding of how magma is transferred and extruded at volcanoes. This study presents an overview of dike patterns and the factors controlling dike propagation within volcanic edifices. Largely based on published data, three main types of dikes (regional, circumferential and radial) are illustrated and discussed. Dike pattern data from 25 volcanic edifices in different settings are compared to derive semi-quantitative relationships between the topography (relief, shape, height, and presence of sector collapses) of the volcano, tectonic setting (presence of a regional stress field), and mean composition (SiO2 content). The overview demonstrates how dike propagation in a volcano is not a random process; rather, it depends from the following factors (listed in order of importance): the presence of relief, the shape of the edifice and regional tectonic control. We find that taller volcanoes develop longer radial dikes, whose (mainly lateral) propagation is independent of the composition of magma or the aspect ratio of the edifice. Future research, starting from these preliminary evaluations, should be devoted to identifying dike propagation paths and likely locations of vent formation at specific volcanoes, to better aid hazards assessment.
    Description: In press
    Description: 1.5. TTC - Sorveglianza dell'attività eruttiva dei vulcani
    Description: 3.2. Tettonica attiva
    Description: 3.5. Geologia e storia dei sistemi vulcanici
    Description: 3.6. Fisica del vulcanismo
    Description: 4.3. TTC - Scenari di pericolosità vulcanica
    Description: JCR Journal
    Description: open
    Keywords: dikes ; volcanoes ; topography ; tectonic setting ; eruptions ; 04. Solid Earth::04.04. Geology::04.04.99. General or miscellaneous ; 04. Solid Earth::04.04. Geology::04.04.09. Structural geology ; 04. Solid Earth::04.07. Tectonophysics::04.07.99. General or miscellaneous ; 04. Solid Earth::04.07. Tectonophysics::04.07.05. Stress ; 04. Solid Earth::04.07. Tectonophysics::04.07.07. Tectonics ; 04. Solid Earth::04.08. Volcanology::04.08.99. General or miscellaneous ; 04. Solid Earth::04.08. Volcanology::04.08.06. Volcano monitoring ; 04. Solid Earth::04.08. Volcanology::04.08.08. Volcanic risk ; 05. General::05.02. Data dissemination::05.02.03. Volcanic eruptions
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  • 41
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    Elemental and isotope covariation of noble gases in mineral phases from Etnean volcanics erupted during 2001–2005, and genetic relation with peripheral gas discharges (2008)
    Elsevier
    Details
    Publication Date: 2017-04-04
    Description: During 2001–2005, Mount Etna was characterized by intense eruptive activity involving the emission of petrologically different products from several vents, which involved at least two types of magma with different degrees of evolution. We investigated the ratios and abundances for noble-gas isotopes in fluid inclusions trapped in olivines and pyroxenes in the erupted products. We confirm that olivine has the most efficient crystalline structure for preserving the pristine composition of entrapped gases, while pyroxene can suffer diffusive He loss. Both the minerals also experience noble gas air contamination after eruption. Helium isotopes of the products genetically linked to the two different magmas fall in the isotopic range typical of the Etnean volcanism. This result is compatible with the metasomatic process that the Etnean mantle is undergoing by fluids from the Ionian slab during the last ten kyr, as previously inferred by isotope and trace element geochemistry. Significant differences were also observed among olivines of the same parental magma that erupted throughout 2001–2005, with 3He/4He ratios moving from about 7.0 Ra in 2001 volcanites, to 6.6 Ra in 2004–2005 products. Changes in He abundances and isotope ratios were attributed to variations in protracted degassing of the same magma bodies from the 2001 to the 2004–2005 events, with the latter lacking any contribution of undegassed magma. The decrease in 3He/4He is similar to that found from measurements carried out every fifteen days during the same period in gases discharged at the periphery of the volcano. To our knowledge this is the first time that such a comparison has been performed so in detail, and provides strong evidence of the real-time feeding of peripheral emissions by magmatic degassing.
    Description: Published
    Description: 683-690
    Description: 1.2. TTC - Sorveglianza geochimica delle aree vulcaniche attive
    Description: JCR Journal
    Description: open
    Keywords: fluid inclusions ; noble gases ; helium isotopes ; magma degassing ; olivine ; pyroxene ; 04. Solid Earth::04.08. Volcanology::04.08.01. Gases ; 04. Solid Earth::04.08. Volcanology::04.08.03. Magmas ; 04. Solid Earth::04.08. Volcanology::04.08.05. Volcanic rocks ; 04. Solid Earth::04.08. Volcanology::04.08.06. Volcano monitoring ; 05. General::05.02. Data dissemination::05.02.01. Geochemical data
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  • 42
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    Methana, the westernmost active volcanic system of the south Aegean arc (Greece): insight from fluids geochemistry (2008)
    Elsevier
    Details
    Publication Date: 2017-04-04
    Description: An extensive geochemical survey of the fluids released by the volcanic/geothermal system of Methana was undertaken. Gases were characterized based on the chemical and isotopic [helium (He) and carbon (C)] analysis of 27 samples. Carbon dioxide soil gas concentration and fluxes were measured at 179 sampling sites throughout the peninsula. Forty samples of thermal and cold groundwaters were also sampled and analysed to characterize the geochemistry of the aquifers. Gases of hydrothermal origin gave a preliminary geothermometric estimate of about 210 °C. The He-isotope composition indicated mantle contributions of up to 40%, and the C-isotope composition of CO2 indicated that it predominantly (〉90%) originated from limestone decomposition. The groundwater composition was suggestive of mixing between meteoric and hydrothermally modified sea-water endmembers and water–rock interaction processes limited to simple rock dissolution driven by an increased endogenous CO2 content. All of the thermal manifestations and anomalous degassing areas, although of limited extent, were spatially correlated with the main active tectonic system of the area. The total CO2 output of the volcanic system has been preliminary estimated to be less than 0.05 kg s–1. Although this value is very low compared to those of other volcanic systems, anomalous CO2 degassing at Methana – which is currently restricted to limited areas and at present is the only volcanic risk of the peninsula – is a potential gas hazard that warrants further assessment in future studies.
    Description: Published
    Description: 818-828
    Description: 1.2. TTC - Sorveglianza geochimica delle aree vulcaniche attive
    Description: JCR Journal
    Description: reserved
    Keywords: Methana ; south Aegean volcanic arc ; fluids geochemistry ; soil gases ; groundwaters ; 03. Hydrosphere::03.04. Chemical and biological::03.04.03. Chemistry of waters ; 03. Hydrosphere::03.04. Chemical and biological::03.04.05. Gases ; 03. Hydrosphere::03.04. Chemical and biological::03.04.06. Hydrothermal systems ; 04. Solid Earth::04.02. Exploration geophysics::04.02.01. Geochemical exploration ; 04. Solid Earth::04.04. Geology::04.04.12. Fluid Geochemistry ; 04. Solid Earth::04.08. Volcanology::04.08.01. Gases ; 04. Solid Earth::04.08. Volcanology::04.08.06. Volcano monitoring ; 04. Solid Earth::04.08. Volcanology::04.08.08. Volcanic risk
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  • 43
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    Mercury concentration, speciation and budget in volcanic aquifers: Italy and Guadeloupe (Lesser Antilles) (2008)
    Elsevier
    Details
    Publication Date: 2017-04-04
    Description: Research article
    Description: Quantifying the contribution of volcanism to global mercury (Hg) emissions is important to understand the pathways and the mechanisms of Hg cycling through the Earth's geochemical reservoirs and to assess its environmental impacts. While previous studies have suggested that degassing volcanoes might contribute importantly to the atmospheric budget of mercury, little is known about the amount and behaviour of Hg in volcanic aquifers. Here we report on detailed investigations of both the content and the speciation of mercury in aquifers of active volcanoes in Italy and Guadeloupe Island (Lesser Antilles). In the studied groundwaters, total Hg (THg) concentrations range from 10 to 500 ng/l and are lower than the 1000 ng/l threshold value for human health protection fixed by the World Health Organization [WHO (1993): WHO Guidelines for Drinking Water Quality- http://www.who.int/water_sanitation_health/GDWQ/index.htlm]. Positive co-variations of (THg) with sulphate indicate that Hg-SO4-rich acid groundwaters receive a direct input of magmatic/hydrothermal gases carrying mercury as Hg0 (gas). Increasing THg in a volcanic aquifer could thus be a sensitive tracer of magmatic gas input prior to an eruption. Since the complex behaviour and toxicity of mercury in waters depend on its chemical speciation, we carefully determined the different aqueous forms of this element in our samples.We find that dissolved elemental Hg0 (aq) and particulate-bound Hg (HgP) widely prevail in volcanic aquifers, in proportions that highlight the efficiency of Hg adsorption onto colloidal particles. Moreover, we observe that dissolved Hg0 aq and Hg(II) forms coexist in comparable amount in most of the waters, in stark contrast to the results of thermodynamic equilibrium modelling. Therefore, chemical equilibrium between dissolved mercury species in volcanic waters is either prevented by natural kinetic effects or not preserved in collected waters due to sampling/storage artefacts. Finally, we provide a first quantitative comparison of the relative intensity of aqueous transport and atmospheric emissions of mercury at Mount Etna, a very active basaltic volcano.
    Description: In press
    Description: 4.5. Degassamento naturale
    Description: JCR Journal
    Description: open
    Keywords: Fluid geochemistry ; volcanic mercury ; 04. Solid Earth::04.04. Geology::04.04.12. Fluid Geochemistry
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  • 44
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    The Tortonian salinity crisis in the Fortuna Basin (southeastern Spain): Stratigraphic record, tectonic scenario and chronostratigraphy (2008)
    Elsevier
    Details
    Publication Date: 2017-04-04
    Description: The Neogene Fortuna and Bajo Segura basins are located on the northeastern end of the Trans-Alborán Shear Zone (TASZ), on the eastern Betic cordillera. The stratigraphic study of the infilling of these basins has shown two major sedimentary discontinuities. The first one, represented by an erosive surface separating open marine marls from an overlying coastal conglomeratic unit, is linked to the onset of the activity along the TASZ, which in this area indicates the beginning of the Abanilla Thrust emplacement. In the Fortuna Basin, the Tortonian salinity crisis, registered over this older first discontinuity, was therefore related to tectonic processes of the eastern portion of the cordillera and consequently would not have an expression in the western basins. The age of the Tortonian Salinity Crisis has been established with nannofossil biostratigraphy as Latest Tortonian at a somewhat lower stratigraphic position than previously recognized. The second sedimentary discontinuity was developed in relation with the known Mediterranean-wide Messinian salinity crisis.
    Description: Published
    Description: 474-481
    Description: 2.2. Laboratorio di paleomagnetismo
    Description: JCR Journal
    Description: reserved
    Keywords: Betic Cordillera ; Tortonian Salinity Crisis ; Messinian Salinity Crisis ; Trans-Alboran Shear Zone ; Fortuna Basin ; Spain ; 04. Solid Earth::04.04. Geology::04.04.10. Stratigraphy ; 04. Solid Earth::04.05. Geomagnetism::04.05.06. Paleomagnetism ; 04. Solid Earth::04.07. Tectonophysics::04.07.07. Tectonics
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  • 45
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    Vertical-axis rotation of a foreland fold and implications for orogenic curvature: an example from the Southern Pyrenees, Spain (2008)
    Elsevier
    Details
    Publication Date: 2017-04-04
    Description: In curved orogenic systems where thrusting and vertical-axis rotations have been documented, it is possible to determine whether the curvature is secondary or progressive based on the timing between the two motions. The South-Central Unit of the Southern Pyrenees provides an opportunity to investigate relationships between thrusting, folding, and vertical-axis rotation because of unusual preservation of Tertiary synorogenic sedimentary strata. Paleomagnetic samples were collected from 51 sites in the upper Eocene-lower Oligocene continental synorogenic strata of the Oliana anticline, a foreland fold along the eastern margin of the South-Central Unit. Site-mean characteristic remanent magnetization directions were determined from 17 sites through thermal demagnetization and principal component analysis. In addition, 72 samples were collected from 39 stratigraphic levels spanning the Upper Eocene marine marls and treated with thermal and alternating field demagnetization techniques. Of these, 53 samples yielded demagnetization trajectories that further constrained the rotation. Comparison of the observed mean paleomagnetic direction from the Oliana anticline with the expected direction indicates a counterclockwise rotation (R ± ΔR) of 20.3° ± 10.9°. Based on the stratigraphic horizons recording the rotation, the age of the rotation is younger than ~34 Ma (after deposition of Unit 3). Data covering the Upper Eocene-Lower Oligocene time interval indicate a similar magnitude of rotation, suggesting that late stage emplacement of thrust sheets hinterlandward of the Oliana anticline controlled the rotation, with rotation accommodated along regionally extensive evaporites. The well-constrained timing relationships between thrusting and rotation and the regional and local transport directions, suggest that the South-Central Unit is a progressive curve that formed through distributed shortening.
    Description: Published
    Description: 435-449
    Description: 2.2. Laboratorio di paleomagnetismo
    Description: JCR Journal
    Description: reserved
    Keywords: Pyrenees ; Oliana anticline ; synorogenic strata ; paleomagnetism ; salients ; 04. Solid Earth::04.05. Geomagnetism::04.05.06. Paleomagnetism ; 04. Solid Earth::04.07. Tectonophysics::04.07.02. Geodynamics ; 04. Solid Earth::04.07. Tectonophysics::04.07.07. Tectonics
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  • 46
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    Paleo-environmental and volcano-tectonic evolution of the southeastern £ank of Mt. Etna during the last 225 ka inferred from the volcanic succession of the ‘Timpe’, Acireale, Sicily (2008)
    Elsevier
    Details
    Publication Date: 2017-04-04
    Description: The tectonic escarpments locally known as ‘Timpe’ cut a large sector of the eastern flank of Etna, and allow an ancient volcanic succession dating back to 225 ka to be exposed. Geological and volcanological investigations carried out on this succession have allowed us to recognize relevant angular unconformities and volcanic features which are the remnants of eruptive fissures, as well as important changes in the nature, composition and magmatic affinity of the exposed volcanics. In particular, the recognition in the lower part of the succession of important and unequivocal evidence of ancient eruptive fissures led us to propose a local origin for these volcanics and to revise previous interpretations which attributed their westward-dipping to the progressive tectonic tilting of strata. These elements led us to reinterpret the main features of the volcanic activity occurring since 250 ka BP and their relationship with tectonic structures active in the eastern flank of Etna. We propose a complex paleo-environmental and volcanotectonic evolution of the southeastern flank of Mt. Etna, in which the Timpe fault system played the role of the crustal structure that allowed the rise and eruption of magmas in the above considered time span.
    Description: Published
    Description: 289-306
    Description: 1.5. TTC - Sorveglianza dell'attività eruttiva dei vulcani
    Description: 3.5. Geologia e storia dei sistemi vulcanici
    Description: 3.6. Fisica del vulcanismo
    Description: JCR Journal
    Description: reserved
    Keywords: Mount Etna ; tectonics ; fisssure eruptions ; columnar basalt ; fault escarpment ; xenoliths ; 04. Solid Earth::04.04. Geology::04.04.99. General or miscellaneous ; 04. Solid Earth::04.04. Geology::04.04.03. Geomorphology ; 04. Solid Earth::04.04. Geology::04.04.05. Mineralogy and petrology ; 04. Solid Earth::04.04. Geology::04.04.06. Rheology, friction, and structure of fault zones ; 04. Solid Earth::04.04. Geology::04.04.07. Rock geochemistry ; 04. Solid Earth::04.04. Geology::04.04.09. Structural geology ; 04. Solid Earth::04.04. Geology::04.04.10. Stratigraphy ; 04. Solid Earth::04.04. Geology::04.04.11. Instruments and techniques ; 04. Solid Earth::04.07. Tectonophysics::04.07.99. General or miscellaneous ; 04. Solid Earth::04.07. Tectonophysics::04.07.02. Geodynamics ; 04. Solid Earth::04.07. Tectonophysics::04.07.04. Plate boundaries, motion, and tectonics ; 04. Solid Earth::04.07. Tectonophysics::04.07.05. Stress ; 04. Solid Earth::04.07. Tectonophysics::04.07.07. Tectonics ; 04. Solid Earth::04.08. Volcanology::04.08.99. General or miscellaneous ; 04. Solid Earth::04.08. Volcanology::04.08.01. Gases ; 04. Solid Earth::04.08. Volcanology::04.08.03. Magmas ; 04. Solid Earth::04.08. Volcanology::04.08.05. Volcanic rocks ; 04. Solid Earth::04.08. Volcanology::04.08.06. Volcano monitoring ; 04. Solid Earth::04.08. Volcanology::04.08.07. Instruments and techniques ; 04. Solid Earth::04.08. Volcanology::04.08.08. Volcanic risk ; 05. General::05.02. Data dissemination::05.02.03. Volcanic eruptions
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  • 47
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    The Database of Individual Seismogenic Sources (DISS), version 3: summarizing 20 years of research on Italy’s earthquake geology (2008)
    Elsevier
    Details
    Publication Date: 2017-04-04
    Description: This paper describes the main characteristics, the evolution, and the structure of the Database of Individual Seismogenic Sources (DISS) and particularly of its release of early 2007. The Database contains the results of the investigations of the active tectonics in Italy during the past 20 years. The first two sections of this paper document the recent evolution in mapping and archiving Italian active fault data in relation to important achievements in the understanding of Italian tectonics, some of which were spurred by significant earthquakes. The central sections describe the current structure of the Database, the reasons for its assumptions and data categories, its current contents, its evolution through several years of improvements. The last section describes how the current contents of the Database correspond with the existing strain and stress data available from focal mechanism, borehole breakout, and GPS data for the whole of Italy. The Database supplies a fresh and unified view of active and seismogenic processes in Italy by building on basic physical constraints concerning rates of crustal deformation, on the continuity of deformation belts and on the spatial relationships between adjacent faults, both at the surface and at depth.
    Description: INGVDPC grant to R. Basili (Project S2, Research Unit 1.1).
    Description: Published
    Description: 20-43
    Description: 3.2. Tettonica attiva
    Description: JCR Journal
    Description: reserved
    Keywords: Earthquake geology ; Active fault ; Active tectonics ; Seismic source ; Seismic hazard ; 04. Solid Earth::04.06. Seismology::04.06.05. Historical seismology ; 04. Solid Earth::04.07. Tectonophysics::04.07.04. Plate boundaries, motion, and tectonics ; 04. Solid Earth::04.07. Tectonophysics::04.07.07. Tectonics
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  • 48
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    Carbon isotopic composition of soil CO2 efflux, a powerful method to discriminate different sources feeding soil CO2 degassing in volcanic-hydrothermal areas (2008)
    Elsevier
    Details
    Publication Date: 2017-04-04
    Description: A new method combining measurements of soil CO2 flux and determinations of the carbon isotopic composition of soil CO2 efflux was developed in order to qualitatively and quantitatively characterise the CO2 source feeding the soil CO2 diffuse degassing. The method was tested in March 2007 at the Solfatara of Pozzuoli volcano degassing area (Naples, Italy) where more than 300 measurements of soil CO2 flux and determinations of the carbon isotopic composition of soil CO2 efflux were performed, surveying Solfatara crater and its surroundings. The wide range of CO2 flux and CO2 isotopic composition values (from 8.4 g m−2 d−1 to 28,834 g m−2 d−1, and from 0.73‰ to −33.54‰, respectively), together with their statistical distributions suggests the occurrence of multiple CO2 sources feeding soil degassing. The combined interpretation of flux and isotopic data allows us to identify and characterise two distinct gas sources: a hydrothermal and a biogenic source. The soil CO2 from the hydrothermal source is characterised by a mean δ13CCO2 of −2.3‰±0.9‰, hence close to the isotopic composition of the fumarolic CO2 (δ13CCO2=−1.48‰± 0.22‰) and by a mean CO2 flux of 2875 g m−2 d−1. The CO2 from the biogenic source is characterised by a mean δ13CCO2 of −19.4‰±2.1‰, and by a mean CO2 flux of 26 g m−2 d−1, which are both in the range of the typical values for biologic CO2 soil degassing. This reliable characterisation of the biogenic CO2 flux would not have been possible by solely applying a statistical analysis of the CO2 flux values, which is commonly applied in volcanological studies for the partitioning between background fluxes and anomalous CO2 fluxes. A map of the Solfatara diffuse degassing structure was derived from the estimated threshold for the biogenic CO2 flux, highlighting that soil degassing of hydrothermal CO2 mixed in different proportion with biogenic CO2 occurs over a large area (~0.8 km2), which extends over the inner part of the Solfatara crater as well as the eastern periphery, corresponding with a NW–SE fault system. The presented method and data analysis are important means of surveillance of the volcanic activity.
    Description: Published
    Description: 372–379
    Description: 1.2. TTC - Sorveglianza geochimica delle aree vulcaniche attive
    Description: 2.4. TTC - Laboratori di geochimica dei fluidi
    Description: 4.5. Degassamento naturale
    Description: JCR Journal
    Description: reserved
    Keywords: CO2 soil degassing ; CO2 flux ; carbon dioxide ; carbon isotopes ; 03. Hydrosphere::03.04. Chemical and biological::03.04.05. Gases ; 03. Hydrosphere::03.04. Chemical and biological::03.04.06. Hydrothermal systems ; 04. Solid Earth::04.04. Geology::04.04.12. Fluid Geochemistry ; 04. Solid Earth::04.08. Volcanology::04.08.01. Gases
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  • 49
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    Geochemical and biochemical evidence of lake overturn and fish kill at Lake Averno, Italy (2008)
    Elsevier
    Details
    Publication Date: 2017-04-04
    Description: Lake Averno is situated in the homonymous crater in the northwestern sector of the Campi Flegrei active volcanic system in Campania region, Italy. In February 2005 a fish kill event was observed in the lake, prompting a geochemical survey to ascertain the possible cause. In February 2005 a geochemical survey revealed that the lake water was unstratified chemically and isotopically, presumably, as a result of lake overturn. This fish kill phenomenon was recorded at least two other times in the past. In contrast to the February 2005 results, data collected in October 2005, shows the Lake Averno to be stratified, with an oxic epilimnion (surface to 6 m) and an anoxic hypolimnion (6 m to lake bottom at about 33 m). Chemical and isotopic compositions of Lake Averno waters suggest an origin by mixing of shallow waters with a Na–Cl hydrothermal component coupled with an active evaporation process. The isotopic composition of Dissolved Inorganic Carbon, as well as the composition of the non-reactive dissolved gas species again supports the occurrence of this mixing process. Decreasing levels of SO4 and increasing levels of H2S and CH4 contents in lake water with depth, strongly suggests anaerobic bacterial processes are occurring through decomposition of organic matter under anoxic conditions in the sediment and in the water column. Sulfate reduction and methanogenesis processes coexist and play a pivotal role in the anaerobic environment of the Lake Averno. The sulfate reducing bacterial activity has been estimated in the range of 14–22 μmol m−2 day−1. Total gas pressure of dissolved gases ranges between 800 and 1400 mbar, well below the hydrostatic pressure throughout the water column, excluding the possibility, at least at the survey time, of a limnic eruption. Vertical changes in the density of lake waters indicate that overturn may be triggered by cooling of epilimnetic waters below 7 °C. This is a possible phenomenon in winter periods if atmospheric temperatures remain frosty for enough time, as occurred in February 2005. The bulk of these results strongly support the hypothesis that fish kill was caused by a series of events that began with the cooling of the epilimnetic waters with breaking of the thermal stratification, followed by lake overturn and the rise of toxic levels of H2S from the reduced waters near the lake bottom.
    Description: Published
    Description: 305–316
    Description: 1.2. TTC - Sorveglianza geochimica delle aree vulcaniche attive
    Description: 2.4. TTC - Laboratori di geochimica dei fluidi
    Description: 4.5. Degassamento naturale
    Description: JCR Journal
    Description: reserved
    Keywords: lake Averno ; dissolved gases ; stable isotopes ; stable isotopes ; 03. Hydrosphere::03.04. Chemical and biological::03.04.05. Gases ; 03. Hydrosphere::03.04. Chemical and biological::03.04.06. Hydrothermal systems ; 04. Solid Earth::04.04. Geology::04.04.12. Fluid Geochemistry ; 04. Solid Earth::04.08. Volcanology::04.08.06. Volcano monitoring
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  • 50
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    Explosive activity and eruption scenarios at Somma-Vesuvius (Italy): Towards a new classification scheme (2008)
    Elsevier
    Details
    Publication Date: 2017-04-04
    Description: A new proposal for the classification of Somma-Vesuvius (SV) explosive activity is presented, based on a critical revision of a large set of published and unpublished stratigraphic, compositional, and physical volcanology data on the products of the past 20,000 years of activity. The new database is used to discuss the general behaviour of the volcano in terms of frequency, magnitude and intensity of the events, as well as of the length of the repose time which preceded each eruption. Several different types of eruption are recognized, each characterised by specific physical eruptive parameters: plinian, subplinian (further subdivided in subplinian I and subplinian II), violent strombolian, ash emission events. For each eruption type, a complex scenario is described, with phases of different style, duration, magnitude and intensity occurring during the course of the eruption itself. The name given to each eruption type is derived from the style of the most representative part of the eruption (in terms of duration or volume). On the whole, the magnitude (expressed as the volume of erupted magma) of the past SV eruptions has been roughly decreasing with time while, starting from 3900 years BP, their frequency has been increasing. The eruption intensity, expressed as the estimated magma discharge rate (MDR) continuously increases with increasing magnitude from strombolian to plinian eruptions, the most voluminous plinian events being, however, characterised by a lower MDR than the smaller ones. The length of the “apparent” repose preceding an eruption (the difference in age between one deposit and that immediately on top of it) appears clearly correlated with magnitude for the most intense eruptions (plinian and subplinian I), while this correlation is poorer for eruptions of intermediate size (from violent strombolian to subplinian II). These exhibit a large variability in magnitude, intensity and eruption style for a range of repose time varying from dozens to hundreds of years, then including the current duration of Vesuvius quiescence. By reckoning with the whole range of possibilities that a next unrest at Vesuvius implies, the set of presented eruption scenarios can be useful both for developing a probabilistic approach to hazard assessment and depicting a range of impact scenarios. The scenario for high-intensity events had been already well defined since 1995, in order to redact the emergency plan of the National Department of Civil Defence. Conversely, it is now clear that the impact on the territory of long-lasting, although low-intensity, eruptions (subplinian II, violent strombolian, ash emission activity) can be relevant especially in terms of economic costs. A larger consideration of this type of activity at Vesuvius can be important especially for the aspects of emergency planning and risk reduction.
    Description: Published
    Description: 331-346
    Description: 3.5. Geologia e storia dei sistemi vulcanici
    Description: 4.3. TTC - Scenari di pericolosità vulcanica
    Description: JCR Journal
    Description: reserved
    Keywords: Explosive eruption ; Eruption scenario ; Volcanic history ; Somma-Vesuvius ; Volcanic hazard ; 04. Solid Earth::04.08. Volcanology::04.08.05. Volcanic rocks ; 04. Solid Earth::04.08. Volcanology::04.08.08. Volcanic risk
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  • 51
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    Miocene-Quaternary structural evolution of the Uyuni-Atacama region, Andes of Chile and Bolivia (2008)
    Elsevier
    Details
    Publication Date: 2017-04-04
    Description: We describe the Miocene-Quaternary geological-structural evolution of the region between the Salar de Uyuni and de Atacama, Andes of Chile and Bolivia. We recognised four main tectonic events based on fold geometry, fault kinematics and stratigraphic data. The oldest event, of Miocene age, is characterized by folding and reverse faulting of the sedimentary successions with an E-W direction of shortening in the northern part of the studied area and a WNW-ESE shortening in the southern part. The following two events, of Pliocene age, are characterized by lower shortening amounts; they occurred first by reverse faulting with a NW-SE-trending greatest principal stress (1, computed with striated fault planes) and a vertical least principal stress (3), followed by pervasive strike-slip faulting with the same NW-SE-trending 1 and a horizontal NE-SW 3. The fourth event, dating to the late Pliocene-Quaternary is characterised by normal faulting: the 3 still trends NE-SW, whereas the intermediate principal stress 2 exchanged with 1. Volcanism accompanied both the contractional, transcurrent and extensional tectonic phases. The Mio-Pliocene compression appears directly linked to a rapid convergence and an apparently important coupling between the continental and oceanic plates. The E-W to WNW-ESE direction of shortening of the Miocene structures and the NW-SE 1 of the Pliocene structures seem to be more linked to an intra-Andean re-orientation of structures following the WNW-directed absolute motion of the South-American Plate. The extensional deformations can be interpreted as related to gravity forces affecting the highest parts of the volcanic belt in a sort of asymmetrical (SW-ward) collapse of the belt.
    Description: In press
    Description: 3.2. Tettonica attiva
    Description: JCR Journal
    Description: reserved
    Keywords: Chile ; Bolivia ; Andes ; tectonic phases ; 04. Solid Earth::04.07. Tectonophysics::04.07.07. Tectonics
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  • 52
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    Seismic strain and seismogenic stress regimes in the crust of the southern Tyrrhenian region (2008)
    Elsevier
    Details
    Publication Date: 2017-04-04
    Description: An investigation has been performed to identify and characterize the seismic deformation zones active over the last decades in the region of Italy that has experienced the strongest seismicity during the last centuries. The study is based on the estimate of hypocenter locations, fault plane solutions, seismogenic stress and seismic strain tensor orientations carried out using the entire dataset of the national and local seismic networks, and the recently improved three-dimensional (3D) crustal velocity model of the study area. A series of simulation tests have been performed to evaluate the significance of the earthquake space distribution obtained and whether it was influenced by network geometry problems related to the sea and the lack of ocean bottom seismometers. In the sectors where hypocentral location was synthetically proved to be reliable, space distributions of earthquakes located with epicenter and focal depth errors less than 3 and 4 km, respectively, have been compared with local geology in order to identify seismogenic faults. The dataset of 32 fault plane solutions estimated with fault parameter errors less than 20° has been used to investigate space variations of seismogenic stress and seismic strain orientations over the study area. Stress was found to be uniform in the Messina Strait and southern Calabria where inversion of the available set of 11 fault plane solutions showed clear evidence of an extensional regime. The different orientations of the minimum compressive stress and strain found in this sector, together with the information available on local geology and tectonics, lead us to propose that the seismicity occurring over the last decades in the Messina Strait and southern Calabria was not in general produced at the main faults, but at minor faults activated by the main tectonic stress field acting in the area. To the west, in the sector including western Etna, the Nebrodi chain and the western Aeolian Islands, analysis of the available set of 16 fault plane solutions revealed a certain degree of stress heterogeneity with an apparent prevalence of north–south compression. This east to west change of stress–strain regimes is evaluated in the light of current hypotheses regarding the geodynamics of the study region.
    Description: Published
    Description: 97-112
    Description: JCR Journal
    Description: open
    Keywords: crustal seismicity ; seismic strain ; seismogenic stress ; Tyrrhenian sea and Italy ; 04. Solid Earth::04.07. Tectonophysics::04.07.05. Stress ; 04. Solid Earth::04.07. Tectonophysics::04.07.07. Tectonics ; 05. General::05.02. Data dissemination::05.02.02. Seismological data
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  • 53
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    The Campanian Ignimbrite and Codola tephra layers: Two temporal/stratigraphic markers for the Early Upper Palaeolithic in southern Italy and eastern Europe (2008)
    Elsevier
    Details
    Publication Date: 2020-02-24
    Description: Tephra layers from archaeological sites in southern Italy and eastern Europe stratigraphically associated with cultural levels containing Early Upper Palaeolithic industry were analysed. The results confirm the occurrence of the Campanian Ignimbrite tephra (CI; ca. 40 cal ka BP) at Castelcivita Cave (southern Italy), Temnata Cave (Bulgaria) and in the Kostenki–Borshchevo area of the Russian Plain. This tephra, originated from the largest eruption of the Phlegrean Field caldera, represents the widest volcanic deposit and one of the most important temporal/stratigraphic markers of western Eurasia. At Paglicci Cave and lesser sites in the Apulia region we recognise a chemically and texturally different tephra, which lithologically, chronologically and chemically matches the physical and chemical characteristics of the Plinian eruption of Codola; a poorly known Late Pleistocene explosive event from the Neapolitan volcanoes, likely Somma–Vesuvius. For this latter, we propose a preliminary age estimate of ca. 33 cal ka BP and a correlation to the widespread C-10 marine tephra of the central Mediterranean. The stratigraphic position of both CI and Codola tephra layers at Castelcivita and Paglicci help date the first and the last documented appearance of Early Upper Palaeolithic industries of southern Italy to ca. 41–40 and 33 cal ka BP, respectively, or between two interstadial oscillations of the Monticchio pollen record – to which the CI and Codola tephras are physically correlated – corresponding to the Greenland interstadials 10–9 and 5. In eastern Europe, the stratigraphic and chronometric data seem to indicate an earlier appearance of the Early Upper Palaeolithic industries, which would predate of two millennia at least the overlying CI tephra. The tephrostratigraphic correlation indicates that in both regions the innovations connected with the so-called Early Upper Palaeolithic – encompassing subsistence strategy and stone tool technology – appeared and evolved during one of the most unstable climatic phases of the Last Glacial period. On this basis, the marked environmental unpredictability characterising this time-span is seen as a potential ecological factor involved in the cultural changes observed.
    Description: Published
    Description: 208–226
    Description: 3.5. Geologia e storia dei sistemi vulcanici
    Description: 3.6. Fisica del vulcanismo
    Description: 4.3. TTC - Scenari di pericolosità vulcanica
    Description: JCR Journal
    Description: reserved
    Keywords: Campanian Ignimbrite ; Early Upper Palaeolithic ; Codola Plinian eruption ; south-eastern Europe ; 04. Solid Earth::04.08. Volcanology::04.08.05. Volcanic rocks ; 04. Solid Earth::04.08. Volcanology::04.08.08. Volcanic risk ; 05. General::05.02. Data dissemination::05.02.03. Volcanic eruptions
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  • 54
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    Neogene–Quaternary evolution of the central Apennine orogenic system (Italy): a structural and palaeomagnetic approach in the Molise region (2008)
    Elsevier
    Details
    Publication Date: 2022-05-30
    Description: We report on new palaeomagnetic and magnetic fabric analyses of mainly Upper Miocene sedimentary sequences from the external central Apennine fold and thrust belt (Molise area), where the principal compressive structures are clearly non-coaxial. The sampling was carried out on the E–W-oriented Matese–Frosolone thrust sheet, that for its geographical position and structural setting (superposition of thrusting, strike-slip and extensional tectonics since Late Miocene to present-day) represents a key structure for the comprehension of the Neogene–Quaternary evolution of the entire Molise area. Palaeomagnetic results suggest that the Matese–Frosolone thrust sheet counterclockwise rotated at least 35° after Messinian times. These data confirm that the present-day trend variability observed in the main compressional structures in the Apennine chain can be related to rotations about vertical axes rather than to changes in the stress field orientation, at least since Late Miocene times. Magnetic fabric analyses indicate that the studied sediments were subjected to very mild deformation, suggesting that the surface emergence of the thrust front of the Matese–Frosolone unit is located farther north, far from the studied area. Well-defined magnetic lineations of tectonic origin were only observed in sites close to localised belts of strike-slip deformation.
    Description: Published
    Description: 143-157
    Description: JCR Journal
    Description: reserved
    Keywords: Apennines ; palaeomagnetism ; anisotropy of magnetic susceptibility ; structural geology ; Neogene ; 04. Solid Earth::04.05. Geomagnetism::04.05.06. Paleomagnetism ; 04. Solid Earth::04.07. Tectonophysics::04.07.07. Tectonics
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  • 55
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    Late Pliocene-Quaternary evolution of outermost hinterland basins of the Northern Apennines (Italy), and their relevance to active tectonics (2008)
    Elsevier
    Details
    Publication Date: 2022-08-25
    Description: We examine the tectonic evolution and structural characteristics of the Quaternary intermontane Mugello, Casentino, and Sansepolcro basins, in the Northern Apennines fold-andthrust belt. These basins have been classically interpreted to have developed under an extensional regime, and to mark the extension-compression transition. The results of our study have instead allowed framing the formation of these basins into a compressive setting tied to the activity of backthrust faults at their northeastern margin. Syndepositional activity of these structures is manifested by consistent architecture of sediments and outcrop-scale deformation. After this phase, the Mugello and Sansepolcro basins experienced a phase of normal faulting extending from the middle Pleistocene until Present. Basin evolution can be thus basically framed into a two-phase history, with extensional tectonics superposed onto compressional structures. Analysis of morphologic features has revealed the occurrence of fresh fault scarps and interaction of faulting with drainage systems, which have been interpreted as evidence for potential ongoing activity of normal faults. Extensional tectonics is also manifested by recent seismicity, and likely caused the strong historical earthquakes affecting the Mugello and Sansepolcro basins. Qualitative comparison of surface information with depth-converted seismic data suggests the basins to represent discrete subsiding areas within the seismic belt extending along the axial zone of the Apennines. The inferred chronology of deformation and the timing of activity of normal faults have an obvious impact on the elaboration of seismic hazard models.
    Description: Published
    Description: 336-356
    Description: 2T. Deformazione crostale attiva
    Description: JCR Journal
    Description: open
    Keywords: Northern Apennines ; Basin evolution ; structural analysis ; active tectonics ; 04. Solid Earth::04.07. Tectonophysics::04.07.07. Tectonics
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  • 56
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    Low-pH waters discharging from submarine vents at Panarea Island (Aeolian Islands, southern Italy) after the 2002 gas blast: origin of hydrothermal fluids and implications for volcanic surveillance (2008)
    Elsevier
    Details
    Publication Date: 2024-05-09
    Description: A geochemical survey of thermal waters collected from submarine vents at Panarea Island (Aeolian Islands, southern Italy) was carried out from December 2002 to March 2007, in order to investigate i) the geochemical processes controlling the chemical composition of the hydrothermal fluids and ii) the possible relations between the chemical features of the hydrothermal reservoir and the activity of the magmatic system. Compositional data of the thermal water samples were integrated in a hydrological conceptual model, which describes the formation of the vent fluid by mixing of seawater, seawater concentrated by boiling, and a deep, highly-saline end-member, whose composition is regulated by water-rock interactions at relatively high temperature and shows clear clues of magmatic-related inputs. The chemical composition of concentrated seawater was assumed to be represented by that of the water sample having the highest Mg content. The composition of the deep end-member was instead calculated by extrapolation assuming a zero-Mg end-member. The Na–K–Ca geothermometer, when applied to the thermal end-member composition, indicated an equilibrium temperature of approximately 300 °C, a temperature in agreement with the results obtained by gas-geothermometry.
    Description: Published
    Description: 246-254
    Description: 3V. Proprietà chimico-fisiche dei magmi e dei prodotti vulcanici
    Description: JCR Journal
    Description: reserved
    Keywords: low-pH waters; shallow submarine hydrothermal springs; Panarea Island ; 04. Solid Earth::04.04. Geology::04.04.12. Fluid Geochemistry
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  • 57
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    Crustal contamination and crystal entrapment during polybaric magma evolution at Mt.Somma-Vesuvius volcano, Italy: Geochemical and Sr isotope evidence (2007)
    Elsevier
    Details
    Publication Date: 2017-04-04
    Description: New major and trace element analyses and Sr-isotope determinations of rocks from Mt. Somma–Vesuvius volcano produced from 25 ky BP to 1944 AD are part of an extensive database documenting the geochemical evolution of this classic region. Volcanic rocks include silica undersaturated, potassic and ultrapotassic lavas and tephras characterized by variable mineralogy and different crystal abundance, as well as by wide ranges of trace element contents and a wide span of initial Sr-isotopic compositions. Both the degree of undersaturation in silica and the crystal content increase through time, being higher in rocks produced after the eruption at 472 AD (Pollena eruption). Compositional variations have been generally thought to reflect contributions from diverse types of mantle and crust. Magma mixing is commonly invoked as a fundamental process affecting the magmas, in addition to crystal fractionation. Our assessment of geochemical and Srisotopic data indicates that compositional variability also reflects the influence of crustal contamination during magma evolution during upward migration to shallow crustal levels and/or by entrapment of crystal mush generated during previous magma storage in the crust. Using a variant of the assimilation fractional crystallization model (Energy Conservation– Assimilation Fractional Crystallization; [Spera and Bohrson, 2001. Energy-constrained open-system magmatic processes I: General model and energy-constrained assimilation and fractional crystallization (EC–AFC) formulation. J. Petrol. 999– 1018]; [Bohrson, W.A. and Spera, F.J., 2001. Energy-constrained open-system magmatic process II: application of energyconstrained assimilation–fractional crystallization (EC–AFC) model to magmatic systems. J. Petrol. 1019–1041]) we estimated the contributions from the crust and suggest that contamination by carbonate rocks that underlie the volcano (2 km down to 9–10 km) is a fundamental process controlling magma compositions at Mt. Somma–Vesuvius in the last 8 ky BP. Contamination in the mid- to upper crust occurred repeatedly, after the magma chamber waxed with influx of new mantle- and crustal-derived magmas and fluids, and waned as a result of magma withdrawal and production of large and energetic plinian and subplinian eruptions.
    Description: Published
    Description: 303– 329
    Description: reserved
    Keywords: Mt. Somma–Vesuvius volcano ; Sr isotopes ; Geochemistry ; Crustal contamination ; Mantle source ; Phenocryst entrapment ; 04. Solid Earth::04.08. Volcanology::04.08.03. Magmas ; 04. Solid Earth::04.08. Volcanology::04.08.05. Volcanic rocks ; 05. General::05.02. Data dissemination::05.02.01. Geochemical data
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  • 58
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    Unveiling the Sources of the Catastrophic 1456 Multiple Earthquake: Hints to an Unexplored Tectonic Mechanism in Southern Italy (2007)
    Seismological Society of America
    Details
    Publication Date: 2017-04-04
    Description: We revisited data related to the 1456 seismic crisis, the largest earthquake to have ever occurred in peninsular Italy, in search of its causative source(s). Data about this earthquake consist solely of historical reports and their intensity assessment. Because of the age of this multiple earthquake, the scarcity and sparseness of the data, and the unusually large damage area, no previous studies have attempted to attribute the 1456 events to specific faults. Existing analytical methods to identify a likely source from intensity data also proved inappropriate for such a sparse dataset, since historical evidence suggests that the cumulative damage pattern contains at least three widely separated events. We subdivided the 1456 damage pattern into three independent mesoseismal areas; each of these areas falls onto east–west tectonic trends previously identified and marked by deep (〉10 km) right-lateral slip earthquakes. Based on this evidence we propose (1) that the 1456 events were generated by individual segments of regional east–west structures and are evidence of a seismogenic style that involves oblique dextral reactivation of east–west lower crustal faults; (2) that each event may have triggered subsequent but relatively distant events in a cascade fashion, as suggested by historical accounts; hence (3) that the 1456 sequence reveals a fundamental but unexplored mechanism of tectonic deformation and seismic release in southern Italy. This style dominates the region that lies between the northwest–southeast system of large extensional faults straddling the crest of the southern Apennines and the buried outer front of the chain. Although the quality of the available information concerning the 1456 earthquake is naturally limited, we show that the overlap of the damage distribution, the orientation and characteristics of regional tectonic structures, the seismicity patterns, and the focal mechanisms all concur with our interpretations and would be difficult to justify otherwise.
    Description: Published
    Description: 725-748
    Description: JCR Journal
    Description: open
    Keywords: historical seismicity ; macroseismic data ; seismogenic faults ; southern Italy ; 04. Solid Earth::04.06. Seismology::04.06.05. Historical seismology ; 04. Solid Earth::04.07. Tectonophysics::04.07.07. Tectonics
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    Type: article
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  • 59
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    Experimental determination of permeability of Neapolitan Yellow Tuff. (2007)
    Elsevier
    Details
    Publication Date: 2017-04-04
    Description: This paper presents and discusses the measurement of permeability of Neapolitan Yellow Tuff (NYT) samples obtained in the framework of a study concerning the phenomenon of bradyseism, i.e. the slow vertical movement of soil, in the Campi Flegrei caldera (Campania—Italy). Measurements have been performed under isothermal, non-isothermal and transient non-isothermal conditions using a specifically designed apparatus. Results of measurements of porosity of different samples are also reported. Experimental results in isothermal conditions show that the volume flux through the samples changes linearly with applied pressure. The values of permeability obtained turn out to be independent of the temperature and pressure gradients applied to the samples. This result is consistent with the fact that the permeability is a characteristic of the porous medium, and as such is not affected by temperature and pressure variation, at least in the range examined. The permeability values measured in our laboratories agree quite well with the ones measured in situ by the Agenzia Generale Italiana Petroli (AGIP) during a geothermal exploration of the Campi Flegrei area in 1980. An interesting, still unexplained phenomenon has been detected during transient phases when both pressure and temperature gradients were applied to the samples. The phenomenon consists in an enhancement of volume flux due to heat flux in the transient phase. The extra volume-flux disappears once the steady temperature gradient is reached.
    Description: Published
    Description: 125-136
    Description: 2.3. TTC - Laboratori di chimica e fisica delle rocce
    Description: 3.5. Geologia e storia dei sistemi vulcanici
    Description: JCR Journal
    Description: reserved
    Keywords: Campi Flegrei ; hydrothermal systems; ; resurgent calderas ; porous media ; hydraulic permeability ; 04. Solid Earth::04.08. Volcanology::04.08.99. General or miscellaneous ; 04. Solid Earth::04.08. Volcanology::04.08.05. Volcanic rocks
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  • 60
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    Environmental impact of magmatic fluorine emission in the Mt. Etna area (2007)
    Elsevier
    Details
    Publication Date: 2017-04-04
    Description: The sustained and uninterrupted plume degassing at Mount Etna volcano, Southern Italy, represents the troposphere’s most prominent natural source of fluorine. Of the ~ 200 Mg of fluorine (as HFg) emitted daily by the volcano, 1.6±2.7 Mg are deposited by wet and dry deposition. Fluorine-deposition via volcanic ash, here characterised for the first time, can be quite significant during volcanic eruptions (i.e. 60 Mg of fluorine were deposited during the 2001 eruption through volcanic ash, corresponding to ~ 85% of the total fluorine deposition). Despite the fact that these depositions are huge, the fate of the deposited fluorine and its impact on the environment are poorly understood. We herein present original data on fluorine abundance in vegetation (Castanea Sativa and Pinus Nigra) and andosoils from the volcano’s flank, in the attempt to reveal the potential impact of volcanogenic fluorine emissions. Fluorine contents in chestnut leaves and pine needles are in the range 1.8-35 µg/g and 2.1-74 µg/g respectively; they exceed the typical background concentrations in plants growing in rural areas, but fall within the lower range of typical concentrations in plants growing near high fluorine anthropogenic emission sources. The rare plume fumigations on the lower flanks of Mt Etna (distance 〉 4 km from summit craters) are probably the cause of the “undisturbed” nature of Etnean vegetation: climatic conditions, which limit the growth of vegetation on the upper regione deserta, are a natural limit to the development of more severe impacts. High fluorine contents, associated with visible symptoms, were only measured in pine needles at three sites, located near recently-active (2001 to 2003) lateral eruptive fractures. Total fluorine contents (FTOT) in the Etnean soils have a range of 112-341 µg/g, and fall within the typical range of undisturbed soils; fluorine extracted with distilled water (FH2O) have a range of 5.1 to 61 µg/g and accounts for 2-40 % of FTOT. FH2O is higher in topsoils from the eastern flank (downwind), while it decreases with depth in soil profiles and on increasing soil grain size (thereby testifying to its association with clay-mineral-rich, fine soil fractions). The fluorine adsorption capacity of the andosoils acts as a natural barrier that protects the groundwater system.
    Description: Published
    Description: 87-101
    Description: 1.2. TTC - Sorveglianza geochimica delle aree vulcaniche attive
    Description: 4.5. Degassamento naturale
    Description: JCR Journal
    Description: reserved
    Keywords: Mt. Etna ; Fluorine ; environmental volcanology ; impact of volcanic F ; soils ; vegetation ; volcanic ash ; 01. Atmosphere::01.01. Atmosphere::01.01.07. Volcanic effects ; 03. Hydrosphere::03.03. Physical::03.03.01. Air/water/earth interactions ; 04. Solid Earth::04.02. Exploration geophysics::04.02.01. Geochemical exploration ; 04. Solid Earth::04.04. Geology::04.04.12. Fluid Geochemistry ; 04. Solid Earth::04.08. Volcanology::04.08.01. Gases ; 05. General::05.08. Risk::05.08.01. Environmental risk
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  • 61
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    Gas geochemistry as a tool to investigate the Earth's degassing through volcanic and seismic areas: The soul of the 8th International Conference on Gas Geochemistry (2007)
    Elsevier
    Details
    Publication Date: 2017-04-04
    Description: Introduction of a special issue of the journal
    Description: no abstract
    Description: Published
    Description: 1-4
    Description: 4.5. Degassamento naturale
    Description: JCR Journal
    Description: reserved
    Keywords: Earth's degassing ; volcanic areas ; seismic areas ; 04. Solid Earth::04.04. Geology::04.04.12. Fluid Geochemistry ; 04. Solid Earth::04.08. Volcanology::04.08.01. Gases
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  • 62
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    REE in skarn systems: A LA-ICP-MS study of garnets from the Crown Jewel gold deposit (2007)
    Elsevier
    Details
    Publication Date: 2017-04-04
    Description: Metamorphic and magmatic garnets are known to fractionate REE, with generally HREE-enriched patterns, and high Lu/ Hf and Sm/Nd ratios, making them very useful as geochemical tracers and in geochronological studies. However, these garnets are typically Al-rich (pyrope, almandine, spessartine, and grossular) and little is known about garnets with a more andraditic (Fe3+) composition, as frequently found in skarn systems. This paper presents LA-ICP-MS data for garnets from the Crown Jewel Au-skarn deposit (USA), discusses the factors controlling incorporation of REE into garnets, and strengthens the potential of garnet REE geochemistry as a tool to help understand the evolution of metasomatic fluids. Garnets from the Crown Jewel deposit range from Adr30Grs70 to almost pure andradite (Adr〉99). Fe-rich garnets (Adr〉90) are isotropic, whereas Al-rich garnets deviate from cubic symmetry and are anisotropic, often showing sectorial dodecahedral twinning. All garnets are extremely LILE-depleted, Ta, Hf, and Th and reveal a positive correlation of RREE3+ with Al content. The Al-rich garnets are relatively enriched in Y, Zr, and Sc and show ‘‘typical’’ HREE-enriched and LREE-depleted patterns with small Eu anomalies. Fe-rich garnets (Adr〉90) have much lower RREE and exhibit LREE-enriched and HREE-depleted patterns, with a strong positive Eu anomaly. Incorporation of REE into garnet is in part controlled by its crystal chemistry, with REE3+ following a coupled, YAG-type substitution mechanism ð½ X2þ VIII 1 ½REE3þ VIII þ1 ½ Si4þ IV 1½Z3þ IV þ1Þ, whereas Eu2+ substitutes for X2+ cations. Thermodynamic data (e.g., Hmixing) in grossular– andradite mixtures suggest preferential incorporation of HREE in grossular and LREE in more andraditic compositions. Variations in textural and optical features and in garnet geochemistry are largely controlled by external factors, such as fluid composition, W/R ratios, mineral growth kinetics, and metasomatism dynamics, suggesting an overall system that shifts dynamically between internally and externally buffered fluid chemistry driven by fracturing. Al-rich garnets formed by diffusive metasomatism, at low W/R ratios, from host-rock buffered metasomatic fluids. Fe-rich garnets grow rapidly by advective metasomatism, at higher W/R ratios, from magmatic-derived fluids, consistent with an increase in porosity by fracturing.
    Description: Published
    Description: 185-205
    Description: 3.6. Fisica del vulcanismo
    Description: 3.8. Geofisica per l'ambiente
    Description: JCR Journal
    Description: reserved
    Keywords: A LA-ICP-MS ; Crown Jewel ; 04. Solid Earth::04.01. Earth Interior::04.01.04. Mineral physics and properties of rocks ; 04. Solid Earth::04.02. Exploration geophysics::04.02.01. Geochemical exploration ; 04. Solid Earth::04.04. Geology::04.04.05. Mineralogy and petrology ; 04. Solid Earth::04.04. Geology::04.04.12. Fluid Geochemistry ; 04. Solid Earth::04.08. Volcanology::04.08.06. Volcano monitoring
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  • 63
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    The Magma feeding system of Somma-Vesuvius (Italy)strato-volcano:new inferences from a review of geochemical and Sr,Nd,Pb and O isotope data. Volcanism in the Campania Plain: Vesuvius, Campi Flegrei and Ignimbrites (2007)
    Elsevier
    Details
    Publication Date: 2017-04-04
    Description: A large database of major, trace and isotope (Sr, Nd, Pb, O) data exists for rocks produced by the volcanic activity of Somma-Vesuvius volcano. Variation diagrams strongly suggest a major role for evolutionary processes such as fractional crystallization, contamination, crystal trapping and magma mixing, occurring after magma genesis in the mantle. Most mafic magmas are enriched in LILE (K, Rb, Ba), REE (Ce, Sm) and Y, show small Nb–Ta negative anomalies, and have values of Nb/Zr at about 0.15. Enrichments in LILE, REE, Nb and Ta do not correlate with Sr isotope values or degree of both K enrichment and silica undersaturation. The results indicate mantle source heterogeneity produced by slab-derived components beneath the volcano. However, the Sr isotope values of Somma-Vesuvius increase from 0.7071 up to 0.7081 with transport through the uppermost 11–12 km of the crust. The Sr isotope variation suggests that the crustal component affected the magmas during ascent through the lithosphere to the surface. Our new geochemical assessment based on chemical, isotopic and fluid inclusion data points to the existence of three main levels of magma storage. Two of the levels are deep and may represent long-lived reservoirs, and an uppermost crustal level that probably coincides with the volcanic conduit. The deeper level of magma storage is deeper than 12 km and fed the 1944 AD eruption. The intermediate level coincides with the seismic discontinuity detected by Zollo et al. (1996) at about 8 km. This intermediate level supplies magmas with 87Sr/86Sr values between 0.7071 and 0.7074, and δO18 8‰ that typically erupted both during interplinian (i.e. 1906 AD) and sub-plinian (472 AD, 1631 AD) events. The shallowest level of magma storage at about 5 km was the site of magma chambers for the Pompei and Avellino eruptions. New investigations are necessary to verify the proposed magma feeding system.
    Description: Published
    Description: 183-204
    Description: open
    Keywords: NONE ; 04. Solid Earth::04.08. Volcanology::04.08.03. Magmas ; 04. Solid Earth::04.08. Volcanology::04.08.05. Volcanic rocks ; 05. General::05.02. Data dissemination::05.02.01. Geochemical data
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    Type: book chapter
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  • 64
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    Evaluation of carbon isotope fractionation of soil CO2 under an advective–diffusive regimen: A tool for computing the isotopic composition of unfractionated deep source (2007)
    Elsevier
    Details
    Publication Date: 2017-04-04
    Description: A physical model based on the advective–diffusion theory was developed in order to describe the mixing between a deep gas source and the atmosphere. The model was used to predict the isotopic fractionation of carbon in soil CO2. Gas samples were collected at different depths in areas characterized by different geological settings and CO2 fluxes. The relative theoretical and experimental isotopic profiles were compared and a good agreement was found. These profiles show how the isotopic composition of CO2 changes through the upper few decimeters of soil and how the amount of the isotopic fractionation is strongly influenced by soil CO2 flux. Finally, the model was used to derive the carbon isotopic composition of unfractioned deep CO2 source for all the investigated sites
    Description: Published
    Description: 3016–3027
    Description: 1.2. TTC - Sorveglianza geochimica delle aree vulcaniche attive
    Description: 2.4. TTC - Laboratori di geochimica dei fluidi
    Description: 4.5. Degassamento naturale
    Description: JCR Journal
    Description: reserved
    Keywords: Carbon isotope fractionation ; soil degassing ; gas transport ; D13C(CO2) ; 04. Solid Earth::04.02. Exploration geophysics::04.02.01. Geochemical exploration ; 04. Solid Earth::04.04. Geology::04.04.12. Fluid Geochemistry ; 04. Solid Earth::04.08. Volcanology::04.08.01. Gases
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  • 65
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    Mapping the Moho of the Western Alps by wide-angle reflection seismics (2007)
    Elsevier
    Details
    Publication Date: 2017-04-04
    Description: In the text
    Description: Published
    Description: 193-202
    Description: 3.3. Geodinamica e struttura dell'interno della Terra
    Description: JCR Journal
    Description: reserved
    Keywords: CROP ; wide-angle ; reflection ; 04. Solid Earth::04.07. Tectonophysics::04.07.07. Tectonics
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  • 66
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    The origin of the fumaroles of La Solfatara (Campi Flegrei, South Italy) (2007)
    Elsevier
    Details
    Publication Date: 2017-04-04
    Description: The analysis of gaseous compositions from Solfatara (Campi Flegrei, South Italy) fumaroles since the early 1980s, clearly reveals a double thermobarometric signature. A first signature at temperatures of about 360 C was inferred by methanebased chemical–isotopic geoindicators and by the H2/Ar geothermometer. These high temperatures, close to the critical point of water, are representative of a deep zone where magmatic gases flash the hydrothermal liquid, forming a gas plume. A second signature was found to be at around 200–240 C. At these temperatures, the kinetically fast reactive species (H2 and CO) re-equilibrate in a pure vapor phase during the rise of the plume. A combination of these observations with an original interpretation of the oxygen isotopic composition of the two dominant species, i.e. H2O and CO2, shed light on the origin of fumarolic fluids by showing that effluents are mixture between fluids degassed from a magma body and the vapor generated at about 360 C by the vaporization of hydrothermal liquids. A typical ‘andesitic’ water type (dD 20&, d18O 10&) and a CO2-rich composition ðXCO2 0:4Þ has been inferred for the magmatic fluids, while for the hydrothermal component a meteoric origin and a CO2 fugacity fixed by fluid-rock reaction at high temperatures have been estimated. In the time the fraction of magmatic fluids in the fumaroles increased (up to 0.5) at each seismic and ground uplift crisis (bradyseism) which occurred at Campi Flegrei, suggesting that bradyseismic crises are triggered by periodic injections of CO2-rich magmatic fluids at the bottom of the hydrothermal system
    Description: Published
    Description: 3040-3055
    Description: 1.2. TTC - Sorveglianza geochimica delle aree vulcaniche attive
    Description: 2.4. TTC - Laboratori di geochimica dei fluidi
    Description: 4.5. Degassamento naturale
    Description: JCR Journal
    Description: reserved
    Keywords: origin of the fumaroles ; 04. Solid Earth::04.04. Geology::04.04.12. Fluid Geochemistry ; 04. Solid Earth::04.08. Volcanology::04.08.06. Volcano monitoring
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  • 67
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    Surface movements in Bologna (Po Plain — Italy) detected by multitemporal DInSAR (2007)
    Elsevier
    Details
    Publication Date: 2019-10-18
    Description: We studied the surface deformations affecting the southeastern sector of the Po Plain sedimentary basin, in particular the area of Bologna. To this aim an advanced DInSAR technique, referred to as DInSAR–SBAS (Small BAseline Subset), has been applied. This technique allows monitoring the temporal evolution of a deformation phenomenon, via the generation of mean deformation velocity maps and displacement time series from a data set of acquired SAR images. In particular, we have processed a set of SAR data acquired by the European Remote Sensing Satellite (ERS) sensors and compared the achieved results with optical levelling measurements, assumed as reference. The surface displacements detected by DInSAR SBAS from 1992 to 2000 are between 10 mm/year in the historical part of Bologna town, and up to 59 mm/year in the NE industrial and agricultural areas. Former measurements from optical levelling referred to 1897 show 2–3 mm/year vertical movements. This trend of displacement increased in the second half of the 20th century and the subsidence rate reached 60 mm/year. We compared the more recent levelling campaigns (in 1992 and late 1999) and DInSAR results from 1992 to 1999. The standard deviation of the difference between levelling data, projected onto the satellite Line Of Sight, and DInSAR results is 2 mm/year. This highlights a good agreement between the measurements provided by two different techniques. The explanation of soil movements based on interferometric results, ground data and geological observations, allowed confirming the anthropogenic cause (surface effect due to the overexploitation of the aquifers) and highlights a natural, tectonic, subsidence.
    Description: Published
    Description: 304-316
    Description: 1.10. TTC - Telerilevamento
    Description: JCR Journal
    Description: partially_open
    Keywords: InSAR ; surface deformation ; SAR interferometry ; 04. Solid Earth::04.03. Geodesy::04.03.99. General or miscellaneous ; 04. Solid Earth::04.03. Geodesy::04.03.06. Measurements and monitoring ; 04. Solid Earth::04.03. Geodesy::04.03.07. Satellite geodesy ; 04. Solid Earth::04.03. Geodesy::04.03.01. Crustal deformations ; 04. Solid Earth::04.07. Tectonophysics::04.07.07. Tectonics ; 04. Solid Earth::04.08. Volcanology::04.08.07. Instruments and techniques
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  • 68
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    A case history of paroxysmal explosion at Stromboli: Timing and dynamics of the April 5, 2003 event (2007)
    Elsevier
    Details
    Publication Date: 2023-01-16
    Description: On April 5, 2003, Stromboli volcano (Italy) produced the most violent explosion of the past 50 years. The event was exceptionally well documented thanks to the presence on the island of several scientists and a large number of instruments deployed over the preceding months to monitor the effusive eruption that began in December 2002. Integration of visual documentation, deposit features and geophysical data allowed an accurate reconstruction of the explosive event and its dynamics. The eruption consisted of a 8-min long explosive event which evolved through four phases whose timing was precisely recorded by an infrared thermometer located about 450 m from the summit crater. Phases 2 and 3 lasted 39 and 42 s, respectively. Both had an impulsive character, were responsible for ejecting almost the entire mass of the pyroclastic products. Phases 1 and 4 represented, respectively, a short-lived precursory event and a waning tale. During Phase 2, meter-sized ballistic blocks were launched with velocities of 170 m/s to altitudes of up to 1400 m above the craters. These fell on the volcano flanks and on the village of Ginostra, about 2 km distant from the vent. A vertical jet rose above the craters which developed to feed a convective plume that reached a height of up to 4 km. The calculated mass of the Phase 2 fallout deposit and mass discharge rate were 1.1–1.4×108 kg and 2.8– 3.6×106 kg/s, respectively. During Phase 3 a scoria flow deposit, with an estimated volume of 0.9–1.1×104 m3, was erupted from the same vent that fed the ongoing sustained lava flow. The average mass discharge rate for this phase was 2.5–3.1×105 kg/s. Products emitted during Phases 2 and 3 consisted of lithic and fresh magmatic material in similar proportions. The juvenile fraction consisted of a deep-originated, almost aphyric, highly vesicular pumice mingled with a shallow-derived, crystal-rich, moderately vesicular scoria. Similarities with the eruption dynamics of other historical paroxysms at Stromboli makes the April 5, 2003 explosion representative of these highly energetic events that constitute the most hazardous volcanic phenomena at Stromboli volcano.
    Description: Published
    Description: 594-606
    Description: JCR Journal
    Description: reserved
    Keywords: stromboli ; Thermal monitoring; paroxysm ; explosive dynamics ; ballistic ejecta ; 04. Solid Earth::04.08. Volcanology::04.08.05. Volcanic rocks ; 04. Solid Earth::04.08. Volcanology::04.08.08. Volcanic risk ; 05. General::05.02. Data dissemination::05.02.03. Volcanic eruptions
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  • 69
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    Evidence of active tectonics on a Roman aqueduct system (II–III century A.D.) near Rome, Italy (2006)
    Elsevier
    Details
    Publication Date: 2017-04-04
    Description: In this paper we describe evidence of strong tectonic deformation affecting two aqueducts of Roman age (II–III century A.D.). The channels are located approximately 20 km northeast of Rome along the ancient Via Tiburtina. Brittle and ductile deformation affects these two structures, including extensional joint systems, NE-oriented faults, and horizontal distortion. This deformation is consistent with rightlateral movement on major N-striking faults, and represents the first evidence that tectonic deformation took place in historical times in the vicinity of Rome, with local strike–slip movement superimposed on a regional extensional fault system.
    Description: Published
    Description: 679–690
    Description: reserved
    Keywords: Strike–slip tectonics ; Active tectonics ; Geo-archaeology ; Rome ; Italy ; 04. Solid Earth::04.07. Tectonophysics::04.07.07. Tectonics
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    Magma dynamics at mid-ocean ridges by noble gas kinetic fractionation: Assessment of magmatic ascent rates (2006)
    Elsevier
    Details
    Publication Date: 2017-04-04
    Description: Despite its impact in understanding oceanic crust formation and eruptive styles of related volcanism, magma dynamics at midocean ridges are poorly known. Here, we propose a new method to assess ascent rates of mid-ocean ridge basalt (MORB) magmas,as well as their pre- and sin-eruptive dynamics. It is based on the idea that a rising magma can reach a variable degree of both CO2 supersaturation in melt and kinetic fractionation among noble gases in vesicles in relation to its ascent rate through the crust. To quantify the relationship, we have used a model of multicomponent bubble growth in MORB melts, developed by extending the single-component model of Proussevitch and Sahagian [A.A. Proussevitch, D.L. Sahagian, Dynamics and energetics of bubble growth in magmas: analytical formulation and numerical modeling, J. Geophys. Res. 103 (1998), 18223–18251.] to CO2–He–Ar gas mixtures. After proper parameterization, we have applied it to published suites of data having the required features (glasses from Pito Seamount and mid-Atlantic ridges). Our results highlight that the investigated MORB magmas display very different ranges of ascent rates: slow rises of popping rock forming-magmas that cross the crust (0.01–0.5 m/s), slightly faster rates of energetic effusions (0.1–1 m/s), up to rates of 1–10 m/s which fall on the edge between lava effusion and Hawaiian activity. Inside a single plumbing system, very dissimilar magma dynamics highlight the large differences in compressive stress of the oceanic crust on a small scale. Constraints on how the systems of ridges work, as well as the characteristics of the magmatic source, can also be obtained. Our model shows how measurements of both the dissolved gas concentration in melt and the volatile composition of vesicles in the same sample are crucial in recognizing the kinetic effects and definitively assessing magma dynamics. An effort should be made to correctly set the studied samples in the sequence of volcanic submarine deposits where they are collected. Enhanced knowledge of a number of physical properties of gas-bearing MOR magmas is also required, mainly noble gas diffusivities, to describe multicomponent bubble growth at a higher confidence level.
    Description: Published
    Description: 138-158
    Description: partially_open
    Keywords: Bubble growth ; MORB ; Noble gas ; Kinetic fractionation ; Modeling ; 04. Solid Earth::04.04. Geology::04.04.07. Rock geochemistry ; 04. Solid Earth::04.04. Geology::04.04.12. Fluid Geochemistry ; 04. Solid Earth::04.08. Volcanology::04.08.01. Gases ; 04. Solid Earth::04.08. Volcanology::04.08.03. Magmas ; 04. Solid Earth::04.08. Volcanology::04.08.04. Thermodynamics
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    The 1980 pressure response and flank failure of Mount St. Helens (USA) inferred from seismic scaling exponents (2006)
    Elsevier
    Details
    Publication Date: 2017-04-04
    Description: The cataclysmic 18 May 1980 eruption at Mount St. Helens was preceded by intense seismic activity marking the mechanical response of the volcanic edifice to interior pressurisation. This seismicity is analysed to yield the temporal change in the seismic scaling exponent, D, inferred from the seismic b-value, that in-turn is related to the seismic moment of an earthquake. Time evolution of D preceding the eruption onset reveals: (1) a major decrease in D occurring over only a few days at the end of March; (2) a steady but stepped decrease in D (steps ~5–10 days) occurring from the end of March to early May; (3) a sharp decrease in D in early May; and (4) steady low values of D occurring 2–3 days before the eruption onset. This response is interpreted as major ruptures, formed at the end of March, arresting and participating in, but not triggering the ultimate failure of the flank. Rather, the rate of interior fracturing slowed in the 2 months preceding the 18 May 1980 major blast, and the triggering of failure is consistent with interior gas overpressurisation. The occurrence of two swarms of low frequency seismic events and the high values of the harmonic tremor indicate the action of interior pressurisation on a cycle of 20–25 days. Solutions are applied to represent the harmonic interior pressurisation of the edifice by gas exsolving from the volcano core. The transient radial migration of overpressured gas may reduce the apparent strength of the edifice, and ultimately trigger failure of the flank. Importantly, this mechanism is capable of triggering flank failure both after multiple core pressurisation cycles have been sustained, and as core pressures are low and diminishing—and may be a minimum. These twin attributes are both apparent in the seismic record for Mount St. Helens, used as a proxy for the unrecorded timing and magnitude of gas pressurisation at the volcano core.
    Description: Published
    Description: 155-168
    Description: partially_open
    Keywords: seismicity ; scaling exponents ; haronic inflation ; pressurisation mechanics ; 04. Solid Earth::04.01. Earth Interior::04.01.04. Mineral physics and properties of rocks ; 04. Solid Earth::04.08. Volcanology::04.08.02. Experimental volcanism ; 04. Solid Earth::04.08. Volcanology::04.08.05. Volcanic rocks
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  • 72
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    Geochemical Characterization and Temporal Changes in Parietal Gas Emissions at Mt. Etna (Italy) During the Period July 2000 - July 2003 (2006)
    Chinese Geoscience Union
    Details
    Publication Date: 2017-04-03
    Description: Several types of natural gas emissions (soil gas, low temperature fumaroles, gas bubbling in mud pools) were collected monthly on Mt. Etna volcano between July 2000 and July 2003 both from its summit and its flanks. Samples were analysed for the determination of the concentrations of CO2, CH4, He, H2, CO as well as the isotopic ratios of 13 14 C/ C of CO2 (δ13C) and He (R/Ra). The analysed gases were chemically divided into two groups: air-contaminated (from sites closer to the summit vents of Mt. Etna) and CO2 - rich. Among the latter, samples from the lower SW flank of the volcano showed high contents of biogenic thermogenic and/or microbial CH4. Isotopic shift in the δ13C values is caused by input of organic CO2 and/or by interaction between magmatic CO2 and shallow ground water as a function of water temperature and CO2 flux from depth. Based on a graphic method applied to δ13 TDIC C of some ground water, the inferred isotopic composition of the pristine magmatic gas at Mt. Etna is characterised by δ13C values ranging from -2 to -1 0 00 . During the period July 2000 - July 2003 significant variations were observed in many of the investigated parameters almost at all monitored sites. Seasonal influences were generally found to be negligible, with only a limited effect of air temperature changes on soil CO2 and ground temperature in only two of the air-contaminated sites. The largest chemical anomalies were observed in the air-contaminated sites, probably because of the strong buffering power of local ground water on gases released through the most peripheral areas where the CO2-rich sites are located. The anomalous changes observed during the study period can be explained in terms of progressive gas release from separate batches of magma that ascend towards the surface in a step-wise manner. Data relevant to the period following the 2002-03 eruption suggest that magma kept accumulating beneath the volcano, thus increasing the probability of a new large eruption at Mt. Etna.
    Description: Istituto Nazionale di Geofisica e Vulcanologia, Sezione di Palermo
    Description: Published
    Description: 805-841
    Description: open
    Keywords: Mt. Etna ; Geochemistry ; Gases ; Eruptive activity ; 04. Solid Earth::04.04. Geology::04.04.12. Fluid Geochemistry
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  • 73
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    Reply to the comment by R.M. Prol-Ledesma on ‘‘Geochemistry of fluids from submarine thermal springs at Punta de Mita, Nayarit, Mexico’’ (2006)
    Elsevier
    In:  Taran Y. A., Inguaggiato S., Marin M., and Yurova L. M. (2002) Geochemistry of fluids from submarine hot springs at Punta de Mita, Nayarit, Mexico. J. Volcanol. Geoth. Res. 115, 329-338.
    Details
    Publication Date: 2017-04-04
    Description: We thank R.M. Prol-Ledesma for her comment on the paper by Taran et al. (2002a) and the new data presented on the water composition of the Punta de Mita (PM) submarine springs. Prol-Ledesma (2003) comments refer to a supposedly wrong citation, superficial description of the geological background, incorrect method of water sampling, wrong approach for the estimation of the end-member composition, irrelevant discussion on the origin of fluids and, lastly, the using of someone else’s ideas and conclusions. In addition, she claims that our data on the fluid chemistry of the springs are not the first (original)ones. The Comment is supported by numerous references to publications by Prol-Ledesma et al. The text below follows the rubrics in the Comment.
    Description: Published
    Description: 319-322
    Description: partially_open
    Keywords: submarine springs ; hydrothermal systems ; geothermometry ; He-isotopes ; formation waters ; Jalisco Block ; 04. Solid Earth::04.04. Geology::04.04.12. Fluid Geochemistry ; 04. Solid Earth::04.08. Volcanology::04.08.01. Gases ; 04. Solid Earth::04.08. Volcanology::04.08.06. Volcano monitoring
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    Helium–strontium isotope constraints on mantle evolution beneath the Roman Comagmatic Province, Italy (2005)
    Elsevier
    Details
    Publication Date: 2020-12-03
    Description: A study of the He isotopic ratios of fluid inclusions in olivine and pyroxene from the Roman Comagmatic Province (RCP),Italy, is presented together with 87Sr/86Sr isotope compositions of the whole rock or pyroxene phenocrysts. A clear covariation in He and Sr isotopes is apparent, with a strong northward increase in radiogenic He and Sr being evident. He and Sr isotopes ratios range from 3He/4He = 5.2 Ra and 87Sr/86Sr = 0.7056 in south Campania, to 3He/4He = 0.44 Ra and 87Sr/86Sr = 0.715905 in the northernmost Latium. Helium isotope ratios are significantly lower than MORB values and are among the lowest yet measured in subduction zone volcanism. The 3He/4He of olivine and pyroxene phenocryst-hosted volatiles appear to be little influenced by posteruptive processes and magma–crust interaction. The 3He/4He–87Sr/86Sr covariation is consistent with binary mixing between an asthenospheric mantle similar to HIMU ocean island basalts, and an enriched (radiogenic) mantle end member generated from subduction of the Ionian/Adriatic plate. The contribution of radiogenic He from metasomatic fluids and postmetasomatism radiogenic ingrowth in the wedge is strongly dependent on the initial He concentration of the mantle. Only when asthenosphere He concentrations are substantially lower than the MORB source mantle, and metasomatism occurred at the beginning of the subduction (f30 Ma), can ingrowth in the mantle wedge account for the 3He/4He of the most radiogenic basalts.
    Description: - European Social Fund - Scottish Universities - Carnegie Trust for the Universities of Scotland.
    Description: Published
    Description: 295–308
    Description: partially_open
    Keywords: Roman Comagmatic Province ; fluid inclusions ; helium ; strontium ; 04. Solid Earth::04.01. Earth Interior::04.01.03. Mantle and Core dynamics ; 04. Solid Earth::04.07. Tectonophysics::04.07.02. Geodynamics ; 04. Solid Earth::04.07. Tectonophysics::04.07.06. Subduction related processes ; 04. Solid Earth::04.07. Tectonophysics::04.07.08. Volcanic arcs ; 04. Solid Earth::04.08. Volcanology::04.08.01. Gases ; 04. Solid Earth::04.08. Volcanology::04.08.05. Volcanic rocks
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    Tectonic control on the eruptive dynamics at Mt. Etna Volcano (Sicily) during the 2001 and 2002–2003 eruptions (2005)
    Elsevier
    Details
    Publication Date: 2020-12-15
    Description: The eruptive events of the July–August 2001 and October 2002–January 2003 at Mt. Etna provide new insights for reconstructing the complex geometry of the feeding system and their relationship to regional tectonics. The 2001 eruption took place mainly on the upper southern sector of the volcano. The eruption was preceded by a large earthquake swarm for a few days before its onset and accompanied by ground deformation and fracturing. The development of surface cracking along with the seismic pattern has allowed us to recognize three distinct eruptive systems (the SW–NE, NNW–SSE and N–S systems) which have been simultaneously active. Such eruptive systems are only the upper portions of a complex feeding system that was fed at the same time by two distinct magmas. The SW–NE and NNW–SSE systems, connected with the SE crater conduit, were fed by magma coming from depth, whereas the N–S system served instead as an ascending pathway for an amphibole-bearing magma residing in a shallow reservoir. The eruptive activity started again on October 2002 on the NE Rift Zone, where about 20 eruptive vents were aligned between 2500 and 1900 m a.s.l., and on the southern flank, from the central crater to the Montagnola. The onset of eruptive activity was accompanied by a seismic swarm. As in the 2001 eruptive event, two independent feeding systems formed, characterized by distinct magmas. The SW–NE system controlled the feeding of the Northeast Rift and was accommodated by left-lateral displacement along the WNW–ESE trending Pernicana Fault. The N–S system fed the eruptions on the southern flank. Moreover, the associated crustal deformation triggered seismic reactivation of tectonic structures in the eastern flank of the volcano and offshore. These two last eruptions indicate that at Mt. Etna the ascent of magma, as well as the accommodation of deformation, is strongly dominated by local extensional structures that are connected to a regional tectonic regime.
    Description: Published
    Description: 211-233
    Description: partially_open
    Keywords: extensional tectonics ; volcanic activity ; seismicity ; Sicily ; Mt. Etna ; 04. Solid Earth::04.06. Seismology::04.06.08. Volcano seismology ; 04. Solid Earth::04.07. Tectonophysics::04.07.07. Tectonics
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    The age of the Neapolitan Yellow Tu caldera-forming eruption (Campi Flegrei caldera-Italy) assessed by 40Ar/39Ar dating method (2005)
    Elsevier
    Details
    Publication Date: 2020-12-17
    Description: The Neapolitan Yellow Tuff (NYT) is the product of the largest known trachytic phreatoplinian eruption. It covered an area larger than 1000 km2 with an estimated volume of about 40 km3 of erupted magma. During the course of the eruption a caldera collapsed within the previously formed Campanian Ignimbrite caldera. The resulting nested structure strongly influenced the following volcanic activity in the Campi Flegrei caldera. As previous dating of the NYT does not converge toward a unique result, a new set of 40Ar/39Ar age determinations has been carried out to better constrain the age of the eruption. Two variants of the 40Ar/39Ar dating method were applied to determine the age of the NYT eruption: (1) single-crystal total fusion (SCTF), on an individual phenocryst of feldspar, and (2) laser incremental heating (LIH), on bulk aliquots of feldspar phenocrysts. The results of the SCTF analyses show that the overall sample weighted mean age, derived from the conventional age calculation, is 15.6 ;0.8 ka. A weighted mean of the isochron age is 15.3 ;1.2 ka (2c), and has been assumed as the best indicator of age to be derived from the SCTF analyses. The LIH analyses results show that plateau ages vary from 15.4; 0.5 to 14.5; 0.5 ka. The overall weighted mean age of the isochron results is 14.9;0.4 ka (2c). This result has been assumed as the reference age for the NYT eruption, and agrees with the SCTF age. The new age obtained for the NYT deposits is of great relevance for the understanding of the evolution and the present state of the Campi Flegrei caldera and collocates the NYT in a crucial stratigraphical position to date the climatic oscillations that occurred between the Late Glacial and the Holocene.
    Description: Published
    Description: 157-170
    Description: partially_open
    Keywords: Neapolitan Yellow Tuff ; Campi Flegrei caldera ; 40Ar/39Ar dating method ; Geochronology ; Late Glacial ; Holocene ; 04. Solid Earth::04.04. Geology::04.04.02. Geochronology ; 04. Solid Earth::04.04. Geology::04.04.10. Stratigraphy ; 04. Solid Earth::04.08. Volcanology::04.08.05. Volcanic rocks ; 05. General::05.02. Data dissemination::05.02.03. Volcanic eruptions
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    Water speciation and Sr isotopic exchange during water-melt interaction: a combined NMR-TIMS study on the Cretaio Tephra (Ischia Island,south Italy) (2005)
    Elsevier
    Details
    Publication Date: 2017-04-04
    Description: In order to improve the microscopic understanding of the water-magma interaction process during explosive volcanism,volcanic glasses representative of deposits with sedimentological characteristics suggesting different water/melt ratios were studied by a combination of the nuclear magnetic resonance (NMR) and TIMS methods. The glasses were separated from pumices of two surge layers and one fallout bed of the Cretaio Tephra (Ischia Island,Italy), which is the product of an explosive eruption that occurred at Ischia in the second century BC. The 29Si CP^MAS NMR experiments indicate the occurrence of 1H^29Si dipolar couplings in glasses from the phreatomagmatic activity, suggesting the presence of hydrogen atoms in proximity of silicon atoms. This feature is not detected in the glass from the deposit of the magmatic explosion. 1H MAS NMR spectra reveal different peaks attributed to different hydrous species characterized by different motional properties. These include ‘rigid’ H2O groups isolated in the glass structure, more mobile water species and possibly structural hydroxyl groups. 1H MAS NMR spectra recorded after deuteration experiments of the glass at a temperature up to 300‡C revealed that the exchange reactions of the D2O vapor with hydrogen were limited to the most mobile water species,possibly on vesicle surfaces or in channels. The hydrogen concentration linearly correlates with the 87Sr/86Sr isotope ratio in glasses,suggesting isotopic tracer exchanges between the Sr dissolved in the water vapor and the Sr in the silicon-oxygen network during hydration. It is proposed that the uprising melt interacted with a hydrothermal system of seawater-derived fluids,characterized by relatively high Sr isotopic composition.
    Description: Published
    Description: 311-320
    Description: partially_open
    Keywords: Ischia ; Cretaio Tephra ; Water-melt interaction ; Nuclear magnetic resonance ; Sr isotopes ; 04. Solid Earth::04.08. Volcanology::04.08.05. Volcanic rocks ; 04. Solid Earth::04.08. Volcanology::04.08.07. Instruments and techniques
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    Gas hazard assessment in a densely inhabited area of Colli Albani Volcano (Cava dei Selci, Roma) (2005)
    Elsevier
    Details
    Publication Date: 2017-04-04
    Description: The northwestern flank of the Colli Albani, a Quaternary volcanic complex near Rome, is characterised by high CO2 values and Rn activities in the groundwater and by the presence of zones with strong emission of gas from the soil. The most significant of these zones is Cava dei Selci where many houses are located very near to the gas emission site. The emitted gas consists mainly of CO2 (up to 98 vol) with an appreciable content of H2S (0.8). The He and C isotopic composition indicates, as for all fluids associated with the Quaternary Roman and Tuscany volcanic provinces, the presence of an upper mantle component contaminated by crustal fluids associated with subducted sediments and carbonates. An advective CO2 flux of 37 tons/day has been estimated from the gas bubbles rising to the surface in a small drainage ditch and through a stagnant water pool, present in the rainy season in a topographically low central part of the area. A CO2 soil flux survey with an accumulation chamber, carried out in February-March 2000 over a 12 000 m2 surface with 242 measurement points, gave a total (mostly conductive) flux of 61 tons/day. CO2 soil flux values vary by four orders of magnitude over a 160-m distance and by one order of magnitude over several metres. A fixed network of 114 points over 6350 m2 has been installed in order to investigate temporal flux variations. Six surveys carried out from May 2000 to June 2001 have shown large variations of the total CO2 soil flux (8/25 tons/day). The strong emission of CO2 and H2S, which are gases denser than air, produces dangerous accumulations in low areas which have caused a series of lethal accidents to animals and one to a man. The gas hazard near the houses has been assessed by continuously monitoring the CO2 and H2S concentration in the air at 75 cm from the ground by means of two automatic stations. Certain environmental parameters (wind direction and speed; atm P, T, humidity and rainfall) were also continuously recorded. At both stations, H2S and CO2 exceeded by several times the recommended concentration thresholds. The highest CO2 and H2S values were recorded always with wind speeds less than 1.5 m/s, mostly in the night hours. Our results indicate that there is a severe gas hazard for people living near the gas emission site of Cava dei Selci, and appropriate precautionary and prevention measures have been recommended both to residents and local authorities.
    Description: - GNV funded research project Gas Hazard of Colli Albani
    Description: Published
    Description: 81^94
    Description: partially_open
    Keywords: Colli Albani ; CO2 flux ; H2S ; gas hazard ; 01. Atmosphere::01.01. Atmosphere::01.01.07. Volcanic effects ; 04. Solid Earth::04.01. Earth Interior::04.01.02. Geological and geophysical evidences of deep processes ; 04. Solid Earth::04.03. Geodesy::04.03.06. Measurements and monitoring ; 04. Solid Earth::04.04. Geology::04.04.12. Fluid Geochemistry ; 04. Solid Earth::04.08. Volcanology::04.08.01. Gases ; 04. Solid Earth::04.08. Volcanology::04.08.02. Experimental volcanism ; 04. Solid Earth::04.08. Volcanology::04.08.06. Volcano monitoring ; 05. General::05.02. Data dissemination::05.02.01. Geochemical data ; 04. Solid Earth::04.08. Volcanology::04.08.08. Volcanic risk
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  • 79
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    The buried caldera of Misti volcano, Peru, revealed by combining a self-potential survey with elliptic Fourier function analysis of topography (2005)
    Elsevier
    Details
    Publication Date: 2017-04-04
    Description: This survey proposes a new approach to identify buried caldera boundaries of a volcanic cone, combining (1) a systematic elliptic Fourier functions (EFF) analysis on the contour lines based on the external shape of the edifice with (2) self-potential (SP) measurements on volcano flanks. The methodology of this approach is to investigate the relationships between (1) vertical morphological changes inferred from EFF analysis and (2) lateral lithological transition inside the edifice inferred from SP/elevation gradients. The application of these methods on Misti volcano in southern Peru displays a very good correlation. The three main boundaries evidenced by hierarchical cluster analysis on the contour lines coincide with the two main boundaries characterised by SP signal and with a secondary SP signature related with a summit caldera. In order to explain these results showing a very good correlation between morphologic and lithologic changes as function of elevation, caldera boundaries have been suggested. The latter would be located at an average elevation of (1) 4350–4400 m, (2) 4950–5000 m, and (3) 5500– 5550 m. For the lowest boundary in elevation, the coincidence with the lateral extension of the hydrothermal system inferred from SP measurements suggests that caldera walls act as a barrier for lateral extension of hydrothermal systems. In the summit area, the highest boundary has been related with the summit caldera, inferred by a secondary SP minimum and geological evidence.
    Description: - Institut de Recherche pour le Développement (IRD) - Instituto Geofisico del Peru´ (IGP).
    Description: Published
    Description: 283– 297
    Description: partially_open
    Keywords: caldera ; elliptic Fourier functions ; geomorphology ; self-potential ; Misti volcano ; Peru ; 03. Hydrosphere::03.02. Hydrology::03.02.02. Hydrological processes: interaction, transport, dynamics ; 03. Hydrosphere::03.02. Hydrology::03.02.03. Groundwater processes ; 03. Hydrosphere::03.02. Hydrology::03.02.04. Measurements and monitoring ; 03. Hydrosphere::03.04. Chemical and biological::03.04.05. Gases ; 03. Hydrosphere::03.04. Chemical and biological::03.04.06. Hydrothermal systems ; 04. Solid Earth::04.01. Earth Interior::04.01.02. Geological and geophysical evidences of deep processes ; 04. Solid Earth::04.02. Exploration geophysics::04.02.04. Magnetic and electrical methods ; 04. Solid Earth::04.04. Geology::04.04.03. Geomorphology ; 04. Solid Earth::04.04. Geology::04.04.09. Structural geology ; 04. Solid Earth::04.04. Geology::04.04.11. Instruments and techniques ; 04. Solid Earth::04.08. Volcanology::04.08.05. Volcanic rocks ; 05. General::05.02. Data dissemination::05.02.04. Hydrogeological data ; 05. General::05.05. Mathematical geophysics::05.05.99. General or miscellaneous ; 05. General::05.08. Risk::05.08.99. General or miscellaneous ; 04. Solid Earth::04.08. Volcanology::04.08.08. Volcanic risk
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  • 80
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    Genesis of chlorine and sulphur in fumarolic emissions at Vulcano Island (Italy) : assessment of pH and redox conditions in the hydrothermal system (2005)
    Elsevier
    Details
    Publication Date: 2017-04-04
    Description: Chlorine- and sulphur-bearing compounds in fumarole discharges of the La Fossa crater at Vulcano Island (Italy) can be modelled by a mixing process between magmatic gases and vapour from a boiling hydrothermal system. This allows estimating the compounds in both endmembers. Magma degassing cannot explain the time variation of sulphur and HCl concentrations in the deep endmember, which are more probably linked to reactions of solid phases at depth, before mixing with the hydrothermal vapours. Based on the P^T conditions and speciation of the boiling hydrothermal system below La Fossa, the HCl and Stot contents in the hydrothermal vapours were used to compute the redox conditions and pH of the aqueous solution. The results suggest that the haematite magnetite buffer controls the hydrothermal fO2 values, while the pH has increased since the end of the 1970s. The main processes affecting pH values may be linked to Na^Ca exchanges between evolved seawater, feeding the boiling hydrothermal system, and local rocks. While Na is removed from water, calcium enters the solution, undergoes hydrolysis and produces HCl,lowering the pH of the water. The increasing water^rock ratio within the hydrothermal system lowers the Ca availability, so the aqueous solution becomes less acidic. Seawater flowing towards the boiling hydrothermal brine dissolves a large quantity of pyrite along its path. In the boiling hydrothermal system, dissolved sulphur precipitates as pyrite and anhydrite, and becomes partitioned in vapour phase as H2S and SO2. These results are in agreement with the paragenesis of hydrothermal alteration minerals recovered in drilled wells at Vulcano and are also in agreement with the isotopic composition of sulphur emitted by the crater fumaroles.
    Description: Published
    Description: 137-150
    Description: partially_open
    Keywords: chlorine ; sulphur ; hydrothermal system ; genetic processes ; Vulcano Island ; 04. Solid Earth::04.04. Geology::04.04.12. Fluid Geochemistry ; 04. Solid Earth::04.08. Volcanology::04.08.01. Gases ; 04. Solid Earth::04.08. Volcanology::04.08.04. Thermodynamics ; 04. Solid Earth::04.08. Volcanology::04.08.06. Volcano monitoring ; 05. General::05.02. Data dissemination::05.02.01. Geochemical data
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  • 81
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    Contrasting triggering mechanisms of the 2001 and 2002–2003 eruptions of Mount Etna (Italy) (2005)
    Elsevier
    Details
    Publication Date: 2017-04-04
    Description: Mount Etna produced two significant eruptions in 2001 and 2002–2003, which we have analysed using geological, seismic and deformation data. These eruptions showed some similarities, such as the activating of two magmatic plumbing systems (central–lateral and eccentric), but they differed in their triggering mechanisms. While the 2001 eruption was largely the result of the emplacement of a N–S eccentric dike (independent from the central conduits) consistent with E–W regional extension, the 2002–2003 eruption occurred in response to a major flank slip on the eastern and southeastern sides of the volcano. This is demonstrated by the spatial and temporal distribution of seismicity and deformation preceding and accompanying the two eruptions. During the months prior to the 2001 eruption, most epicenters were concentrated on the southern flank, at depths of 5–15 km below sea level. During the 4 days before the eruption, earthquake hypocenters migrated to shallower levels (from 5 km bsl. upward) indicating the emplacement of the eccentric dike. This is confirmed by the patterns of ground fracturing observed in the field and deformation documented by electronic distance measurements (EDM). In contrast, the months before the 2002–2003 eruption were characterised by shallower seismicity, mainly concentrated along the active faults bordering the slipping flank sector. Flank slip accelerated in September 2002 and a second, more vigorous acceleration of flank slip occurred on 26–27 October 2002, accompanying the opening of eruptive vents. The very short (2 h) seismic crisis preceding the onset of eruptive activity stands in neat contrast with the 4 days of intense seismicity before the 2001 eruption. Subsequently, flank slip-deformation extended all over the eastern and southeastern flanks of the volcano, causing serious damage in this sector. The events of 2001–2003 can be seen as a continuous chain of intimately interacting processes including regional tectonics, magma accumulation and eruption, and flank instability. In this scenario the 2001 eruption led to increased flank instability that subsequently accelerated and culminated with the massive flank slip, which in turn facilitated the 2002–2003 eruption. This sequence of events points to a long-term feedback mechanism between magmatism and flank instability at Etna.
    Description: Published
    Description: 235-255
    Description: partially_open
    Keywords: eruption triggering ; central–lateral vs. eccentric eruptions ; flank instability and slip ; volcano-tectonics ; Mt. Etna ; instrumental monitoring ; 04. Solid Earth::04.07. Tectonophysics::04.07.07. Tectonics ; 04. Solid Earth::04.08. Volcanology::04.08.06. Volcano monitoring ; 05. General::05.02. Data dissemination::05.02.03. Volcanic eruptions ; 04. Solid Earth::04.08. Volcanology::04.08.08. Volcanic risk
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  • 82
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    Fluid circulation at Stromboli volcano (Aeolian Islands, Italy) from self-potential and CO2 surveys (2005)
    Elsevier
    Details
    Publication Date: 2017-04-04
    Description: This work addresses the study of fluid circulation of the Stromboli island using a dense coverage of self-potential (SP) and soil CO2 data. A marked difference exists between the northern flank and the other flanks of the island. The northern flank exhibits (1) a typical negative SP/altitude gradient not observed on the other flanks, and (2) higher levels of CO2. The general SP pattern suggests that the northern flank is composed of porous layers through which vadose water flows down to a basal water table, in contrast to the other flanks where impermeable layers impede the vertical flow of vadose water. In the Sciara del Fuoco and Rina Grande-Le Schicciole landslide complexes, breccias of shallow gliding planes may constitute such impermeable layers whereas elsewhere, poorly permeable, fine-grained pyroclastites or altered lava flows may be present. This general model of the flanks also explains the main CO2 patterns: concentration of CO2 at the surface is high on the porous north flank and lower on the other flanks where impermeable layers can block the upward CO2 flux. The active upper part of the island is underlain by a well-defined hydrothermal system bounded by short-wavelength negative SP anomalies and high peaks of CO2. These boundaries coincide with faults limiting ancient collapses of calderas, craters and flank landslides. The hydrothermal system is not homogeneous but composed of three main subsystems and of a fourth minor one and is not centered on the active craters. The latter are located near its border. This divergence between the location of the active craters and the extent of the hydrothermal system suggests that the internal heat sources may not be limited to sources below the active craters. If the heat source strictly corresponds to intrusions at depth around the active conduits, the geometry of the hydrothermal subsystems must be strongly controlled by heterogeneities within the edifice such as craters, caldera walls or gliding planes of flank collapse, as suggested by the correspondence between SP^CO2 anomalies and structural limits. The inner zone of the hydrothermal subsystems is characterized by positive SP anomalies, indicating upward movements of fluids, and by very low values of CO2 emanation. This pattern suggests that the hydrothermal zone becomes self-sealed at depth, thus creating a barrier to the CO2 flux. In this hypothesis, the observed hydrothermal system is a shallow one and it involves mostly convection of infiltrated meteoric water above the sealed zone. Finally, on the base of CO2 degassing measurements, we present evidence for the presence of two regional faults, oriented N41‡ and N64‡, and decoupled from the volcanic structures.
    Description: Published
    Description: 1^18
    Description: partially_open
    Keywords: Stromboli ; hydrothermal system ; self-potential ; soil gas ; carbon dioxide ; Aeolian islands ; 03. Hydrosphere::03.02. Hydrology::03.02.02. Hydrological processes: interaction, transport, dynamics ; 03. Hydrosphere::03.04. Chemical and biological::03.04.06. Hydrothermal systems ; 04. Solid Earth::04.04. Geology::04.04.12. Fluid Geochemistry ; 04. Solid Earth::04.08. Volcanology::04.08.01. Gases ; 05. General::05.02. Data dissemination::05.02.01. Geochemical data ; 04. Solid Earth::04.08. Volcanology::04.08.08. Volcanic risk
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
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  • 83
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    Isotopic, chemical and dissolved gas constraints on spring water from Popocatepetl volcano (Mexico): evidence of gas–water interaction between magmatic component and shallow fluids (2005)
    Elsevier
    Details
    Publication Date: 2017-04-04
    Description: Geochemical research was carried out on cold and hot springs at Popocatepetl (Popo) volcano (Mexico) in 1999 to identify a possible relationship with magmatic activity. The chemical and isotopic composition of the fluids is compatible with strong gas–water interaction between deep and shallow fluids. In fact, the isotopic composition of He and dissolved carbon species is consistent with a magmatic origin. The presence of a geothermal system having a temperature of 80–1008 C was estimated on the basis of liquid geothermometers. A large amount of dissolved CO2 in the springs was also detected and associated with high CO2 degassing.
    Description: Published
    Description: 91– 108
    Description: partially_open
    Keywords: Popocatepetl volcano ; helium isotope composition ; carbon isotope composition ; dissolved gases ; gas–water interaction ; 03. Hydrosphere::03.02. Hydrology::03.02.03. Groundwater processes ; 03. Hydrosphere::03.04. Chemical and biological::03.04.05. Gases ; 03. Hydrosphere::03.04. Chemical and biological::03.04.06. Hydrothermal systems ; 04. Solid Earth::04.04. Geology::04.04.12. Fluid Geochemistry ; 04. Solid Earth::04.08. Volcanology::04.08.01. Gases
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  • 84
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    Magma dynamics in the shallow plumbing system of Mt. Etna as recorded by compositional variations in volcanics of recent summit activity (1995–1999) (2005)
    Elsevier
    Details
    Publication Date: 2017-04-04
    Description: We describe the reactivation and the successive evolution of the shallow plumbing system of Mt. Etna between the end of the largest flank eruption of the last three centuries (1991–1993) and the subterminal eruption from South-East Crater (SEC), which occurred between February and mid-November 1999. Our analysis is based on observations of the volcanic activity and petrological studies of the erupted volcanics. Bulk rock, mineral and glass compositions have been determined for more than 80 samples erupted from the four summit craters between October 1995 and February 1999. These data allow us to recognise significant compositional variations among the products of different craters. In particular, volcanics produced between 1995 and 1999 by Bocca Nuova (BN), Voragine (VOR) and North-East Crater (NEC) show limited compositional variations and are similar to those observed during recent eruptions (e.g., 1991–93). More primitive magmas have been produced during the more vigorous fire fountains episodes. On the contrary, the South-East Crater produced slightly more differentiated volcanics than those of the other summit craters following its reactivation (November 1996) until the end of 1998. Whole rock compositions of products from this crater show low CaO/Al2O3, whereas interstitial glasses have lower MgO and higher alkali contents than those from the other craters. However, since the beginning of 1999, and just before the start of the subterminal eruption from SEC, the volcanics erupted from this crater progressively changed in composition, becoming similar to those of the other craters. This trend indicates that within the conduits of the summit craters, distinct thermal and fluid-dynamical regimes can evolve, controlling the cooling and crystallisation of Etna magmas.
    Description: Published
    Description: 55-71
    Description: partially_open
    Keywords: Mount Etna ; crystal fractionation ; petrologic monitoring and magmatic process ; 04. Solid Earth::04.04. Geology::04.04.05. Mineralogy and petrology ; 04. Solid Earth::04.08. Volcanology::04.08.03. Magmas ; 04. Solid Earth::04.08. Volcanology::04.08.05. Volcanic rocks
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  • 85
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    Genesis of fumarolic emissions as inferred by isotope mass balances: CO2 and water at Vulcano Island, Italy (2005)
    Elsevier
    Details
    Publication Date: 2017-04-04
    Description: We have developed a quantitative model of CO2 and H2O isotopic mixing between magmatic and hydrothermal gases for the fumarolic emissions of the La Fossa crater (Vulcano Island, Italy). On the basis of isotope balance equations, the model takes into account the isotope equilibrium between H2O and CO2 and extends the recent model of chemical and energy two-end-member mixing by Nuccio et al. (1999). As a result,the H2O and CO2 content and the dD, d18O, and d13C isotope compositions for both magmatic and hydrothermal end-members have been assessed. Low contributions of meteoric steam, added at a shallow depth, have been also recognized and quantified in the fumaroles throughout the period from 1988 to 1998. Nonequilibrium oxygen isotope exchange also seems to be occurring between ascending gases and wall rocks along some fumarolic conduits. The d13CCO2 of the magmatic gases varies around -3 to 1‰ vs. Peedee belemnite (PDB), following a perfect synchronism with the variations of the CO2 concentration in the magmatic gases. This suggests a process of isotope fractionation because of vapor exsolution caused by magma depressurization. The hydrogen isotopes in the magmatic gases (-1 to -35‰ vs. standard mean ocean water [SMOW]), as well as the above d13CCO2 value, are coherent with a convergent tectonic setting of magma generation, where the local mantle is widely contaminated by fluids released from the subducted slab. Magma contamination in the crust probably amplifies this effect. The computed isotope composition of carbon and hydrogen in the hydrothermal vapors has been used to calculate the dD and d13C of the entire hydrothermal system, including mixed H2O-CO2 vapor, liquid water, and dissolved carbon. We have computed values of about 10‰ vs. SMOW for water and -2 to -6.5‰ vs. PDB for CO2. On these grounds, we think that Mediterranean marine water (dDH2O 10‰) feeds the hydrothermal system. It infiltrates at depth throughout the local rocks, reaching oxygen isotope equilibrium at high temperatures. Interaction processes between magmatic gases and the evolving seawater also seem to occur, causing the dissolution of isotopically fractionated aqueous CO2 and providing the source for hydrothermal carbon. These results have important implications concerning fluid circulation beneath Vulcano and address the more convenient routine of geochemical surveillance.
    Description: Published
    Description: 759–772
    Description: partially_open
    Keywords: isotope geochemistry ; volcanic gases ; mixing modeling ; 04. Solid Earth::04.04. Geology::04.04.12. Fluid Geochemistry ; 04. Solid Earth::04.08. Volcanology::04.08.01. Gases ; 04. Solid Earth::04.08. Volcanology::04.08.03. Magmas ; 04. Solid Earth::04.08. Volcanology::04.08.06. Volcano monitoring ; 05. General::05.02. Data dissemination::05.02.01. Geochemical data
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  • 86
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    Influence of volcanic activity on spring water chemistry at Popocatepetl Volcano, Mexico (2005)
    Elsevier
    Details
    Publication Date: 2017-04-04
    Description: The results of the 7 years (1994-2000) of monthly monitoring of spring water before and during eruptions show response to volcanic activity. Low salinity and temperature characterize most of the springs, which are located on the flanks of Popocatepetl Volcano. The pH ranges from 5.8 to 7.8 and temperature from 3 to 36 jC. Oxygen and hydrogen isotopic data show that the water is of meteoric origin, but SO4 2 , Cl , F , HCO3 , B, and SO4 2- /Cl- variations precede main eruptive activity, which is considered linked to influx of magmatic gases and acid fluids that react with sublimates and host rock and mix with the large water system. Na +, Ca2 + , SiO2 and Mg2 + concentrations in the water also increased before eruptive activity. The computed partial pressure of CO2 in equilibrium with spring waters shows values higher than air-saturated water (ASW), with the highest values up to 0.73 bar of pCO2. Boron is detected in the water only preceding the larger eruptions. When present, boron concentration is normally under health standard limits, but in two cases the concentration was slightly above. Other components are within health standard limits, except for F- in one spring.
    Description: Published
    Description: 207– 229
    Description: partially_open
    Keywords: Volcano monitoring ; Spring water chemistry ; Popocatepetl ; Mexico ; 04. Solid Earth::04.04. Geology::04.04.12. Fluid Geochemistry ; 04. Solid Earth::04.08. Volcanology::04.08.06. Volcano monitoring ; 05. General::05.02. Data dissemination::05.02.01. Geochemical data
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