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  • 03. Hydrosphere::03.04. Chemical and biological::03.04.06. Hydrothermal systems  (18)
  • 04. Solid Earth::04.06. Seismology::04.06.03. Earthquake source and dynamics  (18)
  • Elsevier  (30)
  • Agu  (6)
  • 2005-2009  (36)
Collection
Keywords
Publisher
Years
Year
  • 1
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    A seismic sequence from Northern Apennines (Italy) provides new insight on the role of fluids in the active tectonics of accretionary wedges (2009)
    Elsevier
    Details
    Publication Date: 2017-04-04
    Description: We analyze a seismic sequence which occurred in 2000 along the Northern Apennines accretionary wedge (Italy). The sequence developed within the Cretaceous–Triassic limestones of the tectonic wedge, where methane-rich and oil reservoirs are stored. Ruptures mainly developed on WNW–ESE striking thrusts. The compressive stress field is consistent with that acting at regional scale in Northern Apennines. Seismic parameters indicate that fluids are involved in the seismogenic process. The amplitudes of the P and S phases and data from some stations evidence a P to S conversion within Vp/Vs=2.1 layer. The attenuation properties of crust show a higher attenuation zone located west of the epicentral cloud. Eight hundred aftershocks delineate a sub-vertical cloud of events between 7 and 14 km depth. The space–time evolution of the aftershocks is consistent with a diffusive spreading (diffusivity=1.9 m2/s) along vertically superimposed thrusts. Diffusion also controls the time evolution of the sequence. Fluid pressure is estimated to be roughly equal to the vertical, lithostatic stress. The overpressure within reservoirs develops by tectonic compaction processes. The fluids upraise along sub-vertical fractures related to the shortening of the wedge. The 2000 sequence occurred in an area that separates a thermal and deeper petroleum system from a shallower biogenic system. The divider of these systems controls the attenuation properties of the crust. The fluid–rock interaction at seismogenetic depth is related to hydrothermal processes more than to compaction. In accretionary wedges, seismicity activating superimposed thrusts may drive methane and oil upraising from the upper crust.
    Description: Published
    Description: 99-109
    Description: 3.1. Fisica dei terremoti
    Description: 3.2. Tettonica attiva
    Description: JCR Journal
    Description: partially_open
    Keywords: seismicity ; fluids ; accretionary wedge ; thrust ; geodynamics ; Northern Apennines ; 04. Solid Earth::04.04. Geology::04.04.01. Earthquake geology and paleoseismology ; 04. Solid Earth::04.06. Seismology::04.06.01. Earthquake faults: properties and evolution ; 04. Solid Earth::04.06. Seismology::04.06.03. Earthquake source and dynamics ; 04. Solid Earth::04.06. Seismology::04.06.09. Waves and wave analysis
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
    Type: article
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  • 2
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    Geochemical evaluation of observed changes in volcanic activity during the 2007 eruption at Stromboli (Italy) (2009)
    Elsevier
    Details
    Publication Date: 2017-04-04
    Description: On February 27, 2007 a new eruption started at Stromboli that lasted until April 2 and included a paroxysmal explosion on March 15. Geochemical monitoring carried out over several years revealed some appreciable variations that preceded both the eruption onset and the explosion. The carbon dioxide (CO2) flux from the soil at Pizzo Sopra La Fossa markedly increased a few days before the eruption onset, and continued during lava effusion to reach its maximum value (at 90,000 g m−2 d−1) a few days before the paroxysm. Almost contemporarily, the δ13CCO2 of the SC5 fumarole located in the summit area increased markedly, peaking just before the explosion (δ13CCO2~−1.8‰). Following the paroxysm, helium (He) isotopes measured in the gases dissolved in the basal thermal aquifer sharply increased. Almost contemporarily, the automatic station of CO2 flux recorded an anomalous degassing rate. Also temperatures and the vertical thermal gradient, which had been measured since November 2006 in the soil at Pizzo Sopra La Fossa, showed appreciable variabilities that lasted until the end of the eruption. The geochemical variations indicated the degassing of a new batch of volatile-rich magma that preceded and probably fed the paroxysm. The anomalous 3He/4He ratio suggested that the ascent of a second batch of volatile-rich magma toward the surface was probably responsible of the resumption of the ordinary activity. A comparison with the geochemical variations observed during the 2002–2003 eruption indicated that the 2007 eruption was less energetic.
    Description: Published
    Description: 246-254
    Description: 1.2. TTC - Sorveglianza geochimica delle aree vulcaniche attive
    Description: JCR Journal
    Description: reserved
    Keywords: geochemistry ; eruption ; dissolved gases ; Stromboli ; volcanic activity ; 03. Hydrosphere::03.02. Hydrology::03.02.03. Groundwater processes ; 03. Hydrosphere::03.04. Chemical and biological::03.04.03. Chemistry of waters ; 03. Hydrosphere::03.04. Chemical and biological::03.04.05. Gases ; 03. Hydrosphere::03.04. Chemical and biological::03.04.06. Hydrothermal systems ; 04. Solid Earth::04.04. Geology::04.04.12. Fluid Geochemistry ; 04. Solid Earth::04.08. Volcanology::04.08.01. Gases ; 04. Solid Earth::04.08. Volcanology::04.08.06. Volcano monitoring ; 05. General::05.02. Data dissemination::05.02.01. Geochemical data ; 05. General::05.02. Data dissemination::05.02.03. Volcanic eruptions
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
    Type: article
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  • 3
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    Attenuation of body waves in Southeastern Sicily (Italy) (2009)
    Elsevier
    Details
    Publication Date: 2017-04-04
    Description: The attenuation of P- and S-waves in Southeastern Sicily was estimated by applying two different methods in time and frequency domains. We analyzed waveforms from about 290 local events (0.6 ≤ ML ≤ 4.6) recorded at a three-component digital network. By applying the pulse broadeningmethod to the first P-wave pulse,we found an averageQp value of ca. 140. The application of the frequency decay method provided a Qp value of ca. 120, in the low-frequency band (3–9Hz). Conversely, in the high frequency range (16–27Hz) the average Qp is significantly larger (ca. 640). The frequency decay method was also applied to S-waves spectra. In the low frequency range (2–5Hz) the estimated average Qs is ca. 190. As for Qp, also Qs, in the high frequency range (16–27Hz), is larger (ca. 700). These results evidenced a frequency dependence of both the quality factors Qp and Qs, as commonly observed in tectonically active zones characterized by high degree of heterogeneity
    Description: Published
    Description: 267-279
    Description: JCR Journal
    Description: reserved
    Keywords: attenuation ; body waves ; 04. Solid Earth::04.06. Seismology::04.06.03. Earthquake source and dynamics
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
    Type: article
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  • 4
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    Seismicity, seismotectonics and crustal velocity structure of the Messina Strait (Italy) (2009)
    Elsevier
    Details
    Publication Date: 2017-04-04
    Description: The Messina Strait is the most important structural element interrupting the southernmost part of the Alpine-Apenninic orogenic belt, known as the Calabro-Peloritan Arc. It is being a narrow fan-shaped basin linking the Ionian Sea to the Tyrrhenian Sea. This region is affected by considerable seismic activity which mirrors the geodynamic processes due to the convergence between the African and the Eurasian plates. In the last four centuries, a significant number of disastrous earthquakes originated along the Arc. Among these, the most noteworthy event occurred on December 28, 1908 (known as the Reggio Calabria-Messina earthquake), in the Messina Strait area and caused a large tsunami and more than 100,000 casualties. In this research we focus on the relationships between the general tectonic setting, which characterize the Messina Strait and adjacent areas, seismicity patterns and the crustal structure. We analyzed a data set consisting of more than 300 events occurring in the years from 1999 to 2007, having a magnitude range from 1.0 to 3.8. This data set was exploited in a local earthquake tomography, by carrying out a simultaneous inversion of both the three-dimensional velocity structure and the distribution of seismic foci. We applied the “tomoADD” algorithm, which uses a combination of absolute and differential arrival times and a concept of self-adapting grid geometry, accounting for ray density encountered across the volume. With this method the accuracy of event locations is improved and velocity structure near the source region is resolved in more detail than standard tomography. Fault plane solutions were obtained for the major and best-recorded earthquakes. The obtained velocity images highlight vertical and lateral heterogeneities that can be associated with structural features striking from NNE-SSW to NE-SW. These results are consistent with important tectonic elements visible at the surface and the pattern delineated by earthquake locations and focal mechanisms.
    Description: Published
    Description: 65-78
    Description: 3.2. Tettonica attiva
    Description: JCR Journal
    Description: open
    Keywords: Crustal structure ; Focal mechanism ; Seismicity ; Seismotectonics ; Tomography ; 04. Solid Earth::04.06. Seismology::04.06.03. Earthquake source and dynamics
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
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  • 5
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    The Albano Maar Lake high resolution bathymetry and dissolved CO2 budget (Colli Albani volcano, Italy): Constrains to hazard evaluation (2008)
    Elsevier
    Details
    Publication Date: 2017-04-04
    Description: The Albano Lake is the deepest volcanic lake in Italy (−167 m) and fills the youngest maar of the quiescent Colli Albani volcano. The lake has undergone significant level changes and lahar generating overflows occurred about 5800 yrs B.P. and likely in 398 b.C., when Romans excavated a tunnel drain through the maar wall. Hazardous lake rollovers and CO2 release are still possible because the Albano volcano shows active ground deformation, gas emission and periodic seismic swarms. On November 2005, the first high resolution bathymetric survey of the Albano Lake was performed. Here we present the results provided by a Digital Elevation Model and 2-D and 3-D images of the crater lake floor, which is made by coalescent and partly overlapping craters and wide flat surfaces separated by some evident scarps. Submerged shorelines are identified at depths between −20 m and −41 m and indicate the occurrence of significant lake level changes, likely between 7.1 and 4.1 ka. The current lake volume is ~447.5×106 m3 and the total quantity of dissolved CO2 is 6850 t estimated by chemical analyses of samples collected on May 2006. A decrease of nearly one order of magnitude of the CO2 dissolved in the lake water below −120 m, observed from December 1997 to May 2006 (from 4190 to 465 t respectively), has been attributed to lake water overturn. The observed oscillations of the dissolved CO2 concentrations justify the efforts of monitoring the chemical and physical characteristics of the lake. At present the quantity of dissolved CO2 is very far from saturation and Nyostype events cannot presently occur.
    Description: DPC-INGV Project V3_1
    Description: Published
    Description: 258–268
    Description: 1.2. TTC - Sorveglianza geochimica delle aree vulcaniche attive
    Description: 1.3. TTC - Sorveglianza geodetica delle aree vulcaniche attive
    Description: JCR Journal
    Description: reserved
    Keywords: Albano maar ; lake bathymetry ; geochemistry ; crater lake hazard ; 03. Hydrosphere::03.04. Chemical and biological::03.04.05. Gases ; 03. Hydrosphere::03.04. Chemical and biological::03.04.06. Hydrothermal systems ; 04. Solid Earth::04.06. Seismology::04.06.04. Ground motion ; 04. Solid Earth::04.08. Volcanology::04.08.06. Volcano monitoring
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
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  • 6
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    A seismic source zone model for the seismic hazard assessment of the Italian territory (2008)
    Elsevier
    Details
    Publication Date: 2017-04-04
    Description: We designed a new seismic source model for Italy to be used as an input for country-wide probabilistic seismic hazard assessment (PSHA) in the frame of the compilation of a new national reference map. We started off by reviewing existing models available for Italy and for other European countries, then discussed the main open issues in the current practice of seismogenic zoning. The new model, termed ZS9, is largely based on data collected in the past 10 years, including historical earthquakes and instrumental seismicity, active faults and their seismogenic potential, and seismotectonic evidence from recent earthquakes. This information allowed us to propose new interpretations for poorly understood areas where the new data are in conflict with assumptions made in designing the previous and widely used model ZS4. ZS9 is made out of 36 zones where earthquakes with Mw 〉= 5 are expected. It also assumes that earthquakes with Mw up to 5 may occur anywhere outside the seismogenic zones, although the associated probability is rather low. Special care was taken to ensure that each zone sampled a large enough number of earthquakes so that we could compute reliable earthquake production rates. Although it was drawn following criteria that are standard practice in PSHA, ZS9 is also innovative in that every zone is characterised also by its mean seismogenic depth (the depth of the crustal volume that will presumably release future earthquakes) and predominant focal mechanism (their most likely rupture mechanism). These properties were determined using instrumental data, and only in a limited number of cases we resorted to geologic constraints and expert judgment to cope with lack of data or conflicting indications. These attributes allow ZS9 to be used with more accurate regionalized depth-dependent attenuation relations, and are ultimately expected to increase significantly the reliability of seismic hazard estimates.
    Description: Published
    Description: 85-108
    Description: 3.2. Tettonica attiva
    Description: 4.2. TTC - Scenari e mappe di pericolosità sismica
    Description: JCR Journal
    Description: reserved
    Keywords: Seismotectonics ; Seismic source zone model ; Seismic hazard ; Italy ; 04. Solid Earth::04.06. Seismology::04.06.03. Earthquake source and dynamics ; 04. Solid Earth::04.06. Seismology::04.06.11. Seismic risk ; 04. Solid Earth::04.07. Tectonophysics::04.07.04. Plate boundaries, motion, and tectonics
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
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  • 7
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    Intrusion of eccentric dikes: The case of the 2001 eruption and its role in the dynamics of Mt. Etna volcano (2008)
    Elsevier
    Details
    Publication Date: 2017-04-04
    Description: The 2001 eruption represents one of the most studied events both from volcanological and geophysical point of view on Mt. Etna. This eruption was a crucial event in the recent dynamic of the volcano, marking the passage from a period (March 1993 – June 2001) of moderate stability with slow, continuous flank sliding and contemporaneous summit eruptions, to a period (July 2001 to present) of dramatically increased flank deformations and flank eruptions. We show new GPS data and high precision relocation of seismicity in order to demonstrate the role of the 2001 intrusive phase in this change of the dynamic regime of the volcano. GPS data consist of two kinematic surveys carried out on 12 July, a few hours before the beginning of the seismic swarm, and on 17 July, just after the onset of eruptive activity. A picture of the spatial distribution of the sin-eruptive seismicity has been obtained using the HypoDD relocation algorithm based on the double-difference (DD) technique. Modeling of GPS measurements reveal a southward motion of the upper southern part of the volcano, driven by a NNW-SSE structure showing mainly left-lateral kinematics. Precise hypocenter location evidences an aseismic zone at about sea level, where the magma upraise was characterized by a much higher velocity and an abrupt westward shift, revealing the existence of a weakened or ductile zone. These results reveal how an intrusion of a dike can severely modify the shallow stress field, triggering significant flank failure. In 2001, the intrusion was driven by a weakened surface, which might correspond to a decollement plane of the portion of the volcano affected by flank instability, inducing an additional stress testified by GPS measurements and seismic data, which led to an acceleration of the sliding flanks.
    Description: In press
    Description: 1.1. TTC - Monitoraggio sismico del territorio nazionale
    Description: 1.3. TTC - Sorveglianza geodetica delle aree vulcaniche attive
    Description: 1.4. TTC - Sorveglianza sismologica delle aree vulcaniche attive
    Description: 1.5. TTC - Sorveglianza dell'attività eruttiva dei vulcani
    Description: 3.2. Tettonica attiva
    Description: 3.5. Geologia e storia dei sistemi vulcanici
    Description: 3.6. Fisica del vulcanismo
    Description: 4.2. TTC - Scenari e mappe di pericolosità sismica
    Description: 4.3. TTC - Scenari di pericolosità vulcanica
    Description: 4.4. Scenari e mitigazione del rischio ambientale
    Description: JCR Journal
    Description: reserved
    Keywords: Stress release ; Dike ; Volcano-tectonics ; Flank instability ; Mount Etna ; Instrumental monitoring ; 04. Solid Earth::04.01. Earth Interior::04.01.99. General or miscellaneous ; 04. Solid Earth::04.01. Earth Interior::04.01.02. Geological and geophysical evidences of deep processes ; 04. Solid Earth::04.02. Exploration geophysics::04.02.99. General or miscellaneous ; 04. Solid Earth::04.03. Geodesy::04.03.99. General or miscellaneous ; 04. Solid Earth::04.03. Geodesy::04.03.06. Measurements and monitoring ; 04. Solid Earth::04.03. Geodesy::04.03.07. Satellite geodesy ; 04. Solid Earth::04.04. Geology::04.04.99. General or miscellaneous ; 04. Solid Earth::04.04. Geology::04.04.01. Earthquake geology and paleoseismology ; 04. Solid Earth::04.04. Geology::04.04.09. Structural geology ; 04. Solid Earth::04.06. Seismology::04.06.99. General or miscellaneous ; 04. Solid Earth::04.06. Seismology::04.06.03. Earthquake source and dynamics ; 04. Solid Earth::04.06. Seismology::04.06.04. Ground motion ; 04. Solid Earth::04.06. Seismology::04.06.08. Volcano seismology ; 04. Solid Earth::04.07. Tectonophysics::04.07.99. General or miscellaneous ; 04. Solid Earth::04.07. Tectonophysics::04.07.02. Geodynamics ; 04. Solid Earth::04.07. Tectonophysics::04.07.05. Stress ; 04. Solid Earth::04.07. Tectonophysics::04.07.07. Tectonics ; 04. Solid Earth::04.08. Volcanology::04.08.99. General or miscellaneous ; 04. Solid Earth::04.08. Volcanology::04.08.06. Volcano monitoring ; 04. Solid Earth::04.08. Volcanology::04.08.07. Instruments and techniques ; 04. Solid Earth::04.08. Volcanology::04.08.08. Volcanic risk ; 05. General::05.02. Data dissemination::05.02.03. Volcanic eruptions
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
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  • 8
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    Hydrothermal Fluid Circulation and its Effect on Caldera Unrest (2008)
    Elsevier
    Details
    Publication Date: 2017-04-04
    Description: This paper focuses on the role that hydrothermal systems may play in caldera unrest. Changes in the fluid chemistry, temperature, and discharge rate of hydrothermal systems are commonly detected at the surface during volcanic unrest, as hydrothermal fluids adjust to changing subsurface conditions. Geochemical monitoring is carried out to observe the evolving system conditions. Circulating fluids can also generate signals that affect geophysical parameters monitored at the surface. Effective hazard evaluation requires a proper understanding of unrest phenomena and correct interpretation of their causes. Physical modeling of fluid circulation allows quantification of the evolution of a hydrothermal system, and hence evaluation of the potential role of hydrothermal fluids during caldera unrest. Modeling results can be compared with monitoring data, and then contribute to the interpretation of the recent caldera evolution. This paper: 1) describes the main features of hydrothermal systems; 2) briefly reviews numerical modeling of heat and fluid flow through porous media; 3) highlight the effects of hydrothermal fluids on unrest processes; and 4) describes some model applications to the Phlegrean Fields caldera. Simultaneous modeling of different independent parameters has proved to be a powerful tool for understanding caldera unrest. The results highlight the importance of comprehensive conceptual models that incorporate all the available geochemical and geophysical information, and they also stress the need for high-quality, multi-parameter monitoring and modeling of volcanic activity.
    Description: Published
    Description: 393-416
    Description: 3.6. Fisica del vulcanismo
    Description: 4.3. TTC - Scenari di pericolosità vulcanica
    Description: reserved
    Keywords: hydrothermal fluids ; unrest ; modeling ; caldera ; monitoring ; volcanic hazard ; 03. Hydrosphere::03.04. Chemical and biological::03.04.06. Hydrothermal systems ; 04. Solid Earth::04.08. Volcanology::04.08.06. Volcano monitoring ; 04. Solid Earth::04.08. Volcanology::04.08.08. Volcanic risk
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
    Type: book chapter
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  • 9
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    Methana, the westernmost active volcanic system of the south Aegean arc (Greece): insight from fluids geochemistry (2008)
    Elsevier
    Details
    Publication Date: 2017-04-04
    Description: An extensive geochemical survey of the fluids released by the volcanic/geothermal system of Methana was undertaken. Gases were characterized based on the chemical and isotopic [helium (He) and carbon (C)] analysis of 27 samples. Carbon dioxide soil gas concentration and fluxes were measured at 179 sampling sites throughout the peninsula. Forty samples of thermal and cold groundwaters were also sampled and analysed to characterize the geochemistry of the aquifers. Gases of hydrothermal origin gave a preliminary geothermometric estimate of about 210 °C. The He-isotope composition indicated mantle contributions of up to 40%, and the C-isotope composition of CO2 indicated that it predominantly (〉90%) originated from limestone decomposition. The groundwater composition was suggestive of mixing between meteoric and hydrothermally modified sea-water endmembers and water–rock interaction processes limited to simple rock dissolution driven by an increased endogenous CO2 content. All of the thermal manifestations and anomalous degassing areas, although of limited extent, were spatially correlated with the main active tectonic system of the area. The total CO2 output of the volcanic system has been preliminary estimated to be less than 0.05 kg s–1. Although this value is very low compared to those of other volcanic systems, anomalous CO2 degassing at Methana – which is currently restricted to limited areas and at present is the only volcanic risk of the peninsula – is a potential gas hazard that warrants further assessment in future studies.
    Description: Published
    Description: 818-828
    Description: 1.2. TTC - Sorveglianza geochimica delle aree vulcaniche attive
    Description: JCR Journal
    Description: reserved
    Keywords: Methana ; south Aegean volcanic arc ; fluids geochemistry ; soil gases ; groundwaters ; 03. Hydrosphere::03.04. Chemical and biological::03.04.03. Chemistry of waters ; 03. Hydrosphere::03.04. Chemical and biological::03.04.05. Gases ; 03. Hydrosphere::03.04. Chemical and biological::03.04.06. Hydrothermal systems ; 04. Solid Earth::04.02. Exploration geophysics::04.02.01. Geochemical exploration ; 04. Solid Earth::04.04. Geology::04.04.12. Fluid Geochemistry ; 04. Solid Earth::04.08. Volcanology::04.08.01. Gases ; 04. Solid Earth::04.08. Volcanology::04.08.06. Volcano monitoring ; 04. Solid Earth::04.08. Volcanology::04.08.08. Volcanic risk
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
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  • 10
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    Carbon isotopic composition of soil CO2 efflux, a powerful method to discriminate different sources feeding soil CO2 degassing in volcanic-hydrothermal areas (2008)
    Elsevier
    Details
    Publication Date: 2017-04-04
    Description: A new method combining measurements of soil CO2 flux and determinations of the carbon isotopic composition of soil CO2 efflux was developed in order to qualitatively and quantitatively characterise the CO2 source feeding the soil CO2 diffuse degassing. The method was tested in March 2007 at the Solfatara of Pozzuoli volcano degassing area (Naples, Italy) where more than 300 measurements of soil CO2 flux and determinations of the carbon isotopic composition of soil CO2 efflux were performed, surveying Solfatara crater and its surroundings. The wide range of CO2 flux and CO2 isotopic composition values (from 8.4 g m−2 d−1 to 28,834 g m−2 d−1, and from 0.73‰ to −33.54‰, respectively), together with their statistical distributions suggests the occurrence of multiple CO2 sources feeding soil degassing. The combined interpretation of flux and isotopic data allows us to identify and characterise two distinct gas sources: a hydrothermal and a biogenic source. The soil CO2 from the hydrothermal source is characterised by a mean δ13CCO2 of −2.3‰±0.9‰, hence close to the isotopic composition of the fumarolic CO2 (δ13CCO2=−1.48‰± 0.22‰) and by a mean CO2 flux of 2875 g m−2 d−1. The CO2 from the biogenic source is characterised by a mean δ13CCO2 of −19.4‰±2.1‰, and by a mean CO2 flux of 26 g m−2 d−1, which are both in the range of the typical values for biologic CO2 soil degassing. This reliable characterisation of the biogenic CO2 flux would not have been possible by solely applying a statistical analysis of the CO2 flux values, which is commonly applied in volcanological studies for the partitioning between background fluxes and anomalous CO2 fluxes. A map of the Solfatara diffuse degassing structure was derived from the estimated threshold for the biogenic CO2 flux, highlighting that soil degassing of hydrothermal CO2 mixed in different proportion with biogenic CO2 occurs over a large area (~0.8 km2), which extends over the inner part of the Solfatara crater as well as the eastern periphery, corresponding with a NW–SE fault system. The presented method and data analysis are important means of surveillance of the volcanic activity.
    Description: Published
    Description: 372–379
    Description: 1.2. TTC - Sorveglianza geochimica delle aree vulcaniche attive
    Description: 2.4. TTC - Laboratori di geochimica dei fluidi
    Description: 4.5. Degassamento naturale
    Description: JCR Journal
    Description: reserved
    Keywords: CO2 soil degassing ; CO2 flux ; carbon dioxide ; carbon isotopes ; 03. Hydrosphere::03.04. Chemical and biological::03.04.05. Gases ; 03. Hydrosphere::03.04. Chemical and biological::03.04.06. Hydrothermal systems ; 04. Solid Earth::04.04. Geology::04.04.12. Fluid Geochemistry ; 04. Solid Earth::04.08. Volcanology::04.08.01. Gases
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
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  • 11
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    Geochemical and biochemical evidence of lake overturn and fish kill at Lake Averno, Italy (2008)
    Elsevier
    Details
    Publication Date: 2017-04-04
    Description: Lake Averno is situated in the homonymous crater in the northwestern sector of the Campi Flegrei active volcanic system in Campania region, Italy. In February 2005 a fish kill event was observed in the lake, prompting a geochemical survey to ascertain the possible cause. In February 2005 a geochemical survey revealed that the lake water was unstratified chemically and isotopically, presumably, as a result of lake overturn. This fish kill phenomenon was recorded at least two other times in the past. In contrast to the February 2005 results, data collected in October 2005, shows the Lake Averno to be stratified, with an oxic epilimnion (surface to 6 m) and an anoxic hypolimnion (6 m to lake bottom at about 33 m). Chemical and isotopic compositions of Lake Averno waters suggest an origin by mixing of shallow waters with a Na–Cl hydrothermal component coupled with an active evaporation process. The isotopic composition of Dissolved Inorganic Carbon, as well as the composition of the non-reactive dissolved gas species again supports the occurrence of this mixing process. Decreasing levels of SO4 and increasing levels of H2S and CH4 contents in lake water with depth, strongly suggests anaerobic bacterial processes are occurring through decomposition of organic matter under anoxic conditions in the sediment and in the water column. Sulfate reduction and methanogenesis processes coexist and play a pivotal role in the anaerobic environment of the Lake Averno. The sulfate reducing bacterial activity has been estimated in the range of 14–22 μmol m−2 day−1. Total gas pressure of dissolved gases ranges between 800 and 1400 mbar, well below the hydrostatic pressure throughout the water column, excluding the possibility, at least at the survey time, of a limnic eruption. Vertical changes in the density of lake waters indicate that overturn may be triggered by cooling of epilimnetic waters below 7 °C. This is a possible phenomenon in winter periods if atmospheric temperatures remain frosty for enough time, as occurred in February 2005. The bulk of these results strongly support the hypothesis that fish kill was caused by a series of events that began with the cooling of the epilimnetic waters with breaking of the thermal stratification, followed by lake overturn and the rise of toxic levels of H2S from the reduced waters near the lake bottom.
    Description: Published
    Description: 305–316
    Description: 1.2. TTC - Sorveglianza geochimica delle aree vulcaniche attive
    Description: 2.4. TTC - Laboratori di geochimica dei fluidi
    Description: 4.5. Degassamento naturale
    Description: JCR Journal
    Description: reserved
    Keywords: lake Averno ; dissolved gases ; stable isotopes ; stable isotopes ; 03. Hydrosphere::03.04. Chemical and biological::03.04.05. Gases ; 03. Hydrosphere::03.04. Chemical and biological::03.04.06. Hydrothermal systems ; 04. Solid Earth::04.04. Geology::04.04.12. Fluid Geochemistry ; 04. Solid Earth::04.08. Volcanology::04.08.06. Volcano monitoring
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
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  • 12
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    Shear-Wave Velocity Models and Seismic Sources in Campanian volcanic areas:Vesuvio and Campi Flegrei (2007)
    Elsevier
    Details
    Publication Date: 2020-09-29
    Description: This chapter summarizes a comparative study of shear-wave velocity models and seismic sources in the Campanian volcanic areas of Vesuvius and Phlegraean Fields. These velocity models were obtained through the nonlinear inversion of surfacewave tomography data, using as a priori constraints the relevant information available in the literature. Local group velocity data were obtained by means of the frequency–time analysis for the time period between 0.3 and 2 s and were combined with the group velocity data for the time period between 10 and 35 s from the regional events located in the Italian peninsula and bordering areas and two station phase velocity data corresponding to the time period between 25 and 100 s. In order to invert Rayleigh wave dispersion curves, we applied the nonlinear inversion method called hedgehog and retrieved average models for the first 30–35km of the lithosphere, with the lower part of the upper mantle being kept fixed on the basis of existing regional models. A feature that is common to the two volcanic areas is a low shear velocity layer which is centered at the depth of about 10 km, while on the outside of the cone and along a path in the northeastern part of the Vesuvius area this layer is absent. This low velocity can be associated with the presence of partial melting and, therefore, may represent a quite diffused crustal magma reservoir which is fed by a deeper one that is regional in character and located in the uppermost mantle. The study of seismic source in terms of the moment tensor is suitable for an investigation of physical processes within a volcano; indeed, its components, double couple, compensated linear vector dipole, and volumetric, can be related to the movements of magma and fluids within the volcanic system. Although for many recent earthquake events the percentage of double couple component is high, our results also show the presence of significant non-double couple components in both volcanic areas.
    Description: Published
    Description: 287-309
    Description: reserved
    Keywords: NONE ; 04. Solid Earth::04.06. Seismology::04.06.03. Earthquake source and dynamics
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
    Type: book chapter
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  • 13
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    Prediction of response spectra via real-time earthquake measurements (2007)
    Elsevier
    Details
    Publication Date: 2021-06-21
    Description: The development and implementation of an earthquake early warning system (EEWS), both in regional or on-site configurations can help to mitigate the losses due to the occurrence of moderate-to-large earthquakes in densely populated and/or industrialized areas. The capability of an EEWS to provide real-time estimates of source parameters (location and magnitude) can be used to take some countermeasures during the earthquake occurrence and before the arriving of the most destructive waves at the site of interest. However, some critical issues are peculiar of EEWS and need further investigation: (1) the uncertainties on earthquake magnitude and location estimates based on the measurements of some observed quantities in the very early portion of the recorded signals; (2) the selection of the most appropriate parameter to be used to predict the ground motion amplitude both in near-and far-source ranges; (3) the use of the estimates provided by the EEWS for structural engineering and risk mitigation applications. In the present study, the issues above are discussed using the Campania–Lucania region (Southern Apennines) in Italy, as test-site area. In this region a prototype system for earthquake early warning, and more generally for seismic alert management, is under development. The system is based on a dense, wide dynamic accelerometric network deployed in the area where the moderate-to-large earthquake causative fault systems are located. The uncertainty analysis is performed through a real-time probabilistic seismic hazard analysis by using two different approaches. The first is the Bayesian approach that implicitly integrate both the time evolving estimate of earthquake parameters, the probability density functions and the variability of ground motion propagation providing the most complete information. The second is a classical point estimate approach which does not account for the probability density function of the magnitude and only uses the average of the estimates performed at each seismic station. Both the approaches are applied to two main towns located in the area of interest, Napoli and Avellino, for which a missed and false alarm analysis is presented by means of a scenario earthquake: an M 7.0 seismic event located at the centre of the seismic network. Concerning the ground motion prediction, attention is focused on the response spectra as the most appropriate function to characterize the ground motion for earthquake engineering applications of EEWS.
    Description: Published
    Description: On line First
    Description: 4.1. Metodologie sismologiche per l'ingegneria sismica
    Description: JCR Journal
    Description: reserved
    Keywords: Earthquake early-warning ; Real-time seismology ; Bayesian analysis ; Missed and false alarm ; 04. Solid Earth::04.06. Seismology::04.06.03. Earthquake source and dynamics ; 04. Solid Earth::04.06. Seismology::04.06.11. Seismic risk
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  • 14
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    Source parameters and scaling relationships in the Friuli-Venezia Giulia (Northeastern Italy) region (2007)
    Elsevier
    Details
    Publication Date: 2017-04-04
    Description: We estimated the source parameters of 53 local earthquakes (2.0 〈ML 〈 5.7) of the Friuli-Venezia Giulia (Northeastern Italy) area, recorded by the short-period local seismic network of the Istituto Nazionale di Oceanografia e Geofisica Sperimentale (OGS), in the period 1995–2003. Data were selected on the basis of high quality locations and focal mechanisms. Standard H/V spectral ratios (HVRS) of the three-component stations of the network were performed in order to assess local amplifications, and only stations showing HVRS not exceeding two were considered for the source parameters estimation. Both velocity and acceleration data were used to compute the SH-wave spectra. Observed spectra were corrected for attenuation effects using an independent regional estimate of the quality factor Q and a station dependent estimate of the spectral decay parameter k. Only earthquakes withML 〉 3.0 recorded with a sampling rate of 125 cps were used to compute k, thus allowing to visualize a linear trend of the high frequency acceleration spectrum up to 40–50 Hz. SH-wave spectra, corrected for attenuation, showed an ω−2 shape allowing a good fit with the Brune model. Seismic moments and Brune radii ranged between 1.5 × 1012 and 1.1 × 1017 Nm and between 0.1 and 2.7 km respectively.We obtainedMo = 1.1 × 1017 Nm for the seismic moment of the Kobarid (SLO) main shock, in good agreement with the Harvard CMT solution (Mo = 3.5 × 1017 Nm). Brune stress drops were confined to the range from 0.07 to 5.31MPa, with an average value of 0.73MPa and seem to be approximately constant over five orders of magnitude of seismic moment. Radiated seismic energy computed from two nearby stations scales with seismic moment according to logEs = 1.30 logMo − 9.06, and apparent stress values are between 0.02 and 4.26MPa. The observed scatter of Brune stress drop data allowed to hypothesize a scaling relation Mo ∝ f −3.43 c between seismic moment and corner frequency in order to accommodate both Brune stress drop and apparent stress scalings. No systematic differences are evidenced between stress parameters of earthquakes with different focal mechanisms. As a consequence, a relation of the seismic stress release with the strength of rocks can be hypothesized. A high correlation (r 〉 0.9) of Brune stress drop is found with both apparent stress and RMS stress drop, according to σB = 2.0 σa and σrms = 2.26 σB respectively.
    Description: Published
    Description: 148-167
    Description: JCR Journal
    Description: reserved
    Keywords: Earthquakes ; Attenuation ; Seismic spectra ; Seismic moment ; Seismic stress ; 04. Solid Earth::04.06. Seismology::04.06.03. Earthquake source and dynamics
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  • 15
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    A thermal pressurization model for the spontaneous ...: 2. Traction evolution and dynamic parameters (2007)
    Agu
    Details
    Publication Date: 2017-04-04
    Description: We investigate the dynamic traction evolution during the spontaneous propagation of a 3-D earthquake rupture governed by slip-weakening or rate- and state-dependent constitutive laws and accounting for thermal pressurization effects. The analytical solutions as well as temperature and pore pressure evolutions are discussed in the companion paper by Bizzarri and Cocco. Our numerical experiments reveal that frictional heating and thermal pressurization modify traction evolution. The breakdown stress drop, the characteristic slip-weakening distance, and the fracture energy depend on the slipping zone thickness (2w) and hydraulic diffusivity (w). Thermally activated pore pressure changes caused by frictional heating yield temporal variations of the effective normal stress acting on the fault plane. In the framework of rate- and state-dependent friction, these thermal perturbations modify both the effective normal stress and the friction coefficient. Breakdown stress drop, slip-weakening distance, and specific fracture energy (J/m2) increase for decreasing values of hydraulic diffusivity and slipping zone thickness. We propose scaling relations to evaluate the effect of w and w on these physical parameters. We have also investigated the effects of choosing different evolution laws for the state variable. We have performed simulations accounting for the porosity evolution during the breakdown time. Our results point out that thermal pressurization modifies the shape of the slip-weakening curves. For particular configurations, the traction versus slip curves display a gradual and continuous weakening for increasing slip: in these cases, the definitions of a minimum residual stress and the slip-weakening distance become meaningless.
    Description: Published
    Description: B05304
    Description: JCR Journal
    Description: reserved
    Keywords: thermal pressurization ; 04. Solid Earth::04.01. Earth Interior::04.01.05. Rheology ; 04. Solid Earth::04.02. Exploration geophysics::04.02.03. Heat flow ; 04. Solid Earth::04.06. Seismology::04.06.03. Earthquake source and dynamics
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  • 16
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    Repeating earthquakes from rupture of an asperity under an Antarctic outlet glacier (2007)
    Elsevier
    Details
    Publication Date: 2017-04-04
    Description: The inner regions of the Antarctic continent are generally regarded as nearly aseismic, although microseismicity is known to occur beneath some outlet ice streams, related to the interaction between the fast flowing ice and the bedrock. Here we show the occurrence of unusual earthquakes beneath an Antarctic outlet glacier that share almost the same magnitude, pointing to the repeated rupture of a single asperity. These seismic events produce waveforms with very high similarity and uncommon spectrum and are tightly clustered in space but, unlike other reported instances of repeating earthquakes on a patch of the San Andreas Fault, they occur in frequent irregular swarms. Evidence locates these events at the rock–ice interface under the glacier, and shows the existence of stick–slip motion on a smaller scale than the large slow slip events detected by global seismographs. Seismic behaviour of large glaciers can presumably be connected to surges in ice motion. This study determines a little known environment for fracture dynamics studies, while also contributing to the understanding of the coupling processes between fast flowing glaciers and bedrock that influence ice stream evolution and stability.
    Description: Progetto Nazionale di Ricerca in Antartide (PNRA) Antarctica New Zealand (ANZ)
    Description: Published
    Description: 151–158
    Description: 3.3. Geodinamica e struttura dell'interno della Terra
    Description: JCR Journal
    Description: reserved
    Keywords: Glacial earthquakes ; Glacial dynamics ; Gutenberg-Richter relationship ; Double-difference hypocentre location ; Repeating earthquake ; 04. Solid Earth::04.06. Seismology::04.06.03. Earthquake source and dynamics
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  • 17
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    Coseismic deformation induced by the Sumatra earthquake (2007)
    Elsevier
    Details
    Publication Date: 2017-04-04
    Description: The giant Sumatra-Andaman earthquake of December 26, 2004 caused permanent deformations effects in a region of previously never observed extension. The GPS data from the worldwide network of permanent IGS sites show significant coseismic displacements in an area exceeding 107 km2, reaching most of South-East Asia, besides Indonesia and India. We have analyzed long GPS time series histories in order to characterize the noise type of each site and, consequently, to precisely assess the formal errors of the coseismic offset estimates. The synthetic simulations of the coseismic displacement field obtained by means of a spherical model using different rupture histories indicate that a major part of the energy release took place in a fault plane similar to that obtained by Ammon et al. (2005) and Vigny et al. (2005) but with a larger amount of compressional slip on the northern segment of the fault area. © 2006 Elsevier Ltd. All rights reserved.
    Description: Published
    Description: 52-62
    Description: JCR Journal
    Description: reserved
    Keywords: Coseismic ; deformation ; 04. Solid Earth::04.06. Seismology::04.06.03. Earthquake source and dynamics
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  • 18
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    Mineral control of arsenic content in thermal waters from volcano-hosted hydrothermal systems: insights from island of Ischia and Phlegrean Fields (Campanian Volcanic Province, Italy) (2007)
    Elsevier
    Details
    Publication Date: 2017-04-04
    Description: This paper documents arsenic concentrations in 157 groundwater samples from the island of Ischia and the Phlegrean Fields, two of the most active volcano-hosted hydrothermal systems from the Campanian Volcanic Province (Southern Italy), in an attempt to identify the environmental conditions and mineral-solution reactions governing arsenic aqueous cycling. On Ischia and in the Phlegrean Fields, groundwaters range in composition from NaCl brines, which we interpret as the surface discharge of deep reservoir fluids, to shallow-depth circulating fluids, the latter ranging from acid-sulphate steam-heated to hypothermal, cold, bicarbonate groundwaters. Arsenic concentrations range from 1.6 to 6900 μg·l−1 and from 2.6 to 3800 μg·l−1 in the Phlegrean Fields and on Ischia, respectively. They increase with increasing water temperature and chlorine contents, and in the sequence bicarbonate groundwatersbsteam-heated groundwatersbNaCl brines. According to thermochemical modeling, we propose that high As concentrations in NaCl brines form after prolonged water–rock interactions at reservoir T, fO2 and fH2S conditions, and under the buffering action of an arsenopyrite+pyrite+pyrrhotite rock assemblage. On their ascent toward the surface, NaCl brines become diluted by As-depleted meteoric-derived bicarbonate groundwaters, giving rise to hybrid water types with intermediate to low As contents. Steam-heated groundwaters give their intermediate to high As concentrations to extensive rock leaching promoted by interaction with As-bearing hydrothermal steam.
    Description: Published
    Description: 313–330
    Description: reserved
    Keywords: Arsenic geochemistry ; Hydrothermal systems ; Water–rock interaction ; Hydrogeochemistry ; Arsenopyrite ; 03. Hydrosphere::03.04. Chemical and biological::03.04.06. Hydrothermal systems
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  • 19
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    Earthquake magnitude estimation from peak amplitudes of very early seismic signals on strong motion records (2007)
    Agu
    Details
    Publication Date: 2017-04-04
    Description: We show that the low-pass filtered, peak amplitudes of initial P- and S-wave seismic signals recorded in the vicinity of an occurring earthquake source correlates with the earthquake magnitude and may be used for real-time estimation of the event size in seismic early warning applications. The earthquake size can be therefore estimated using only a couple of seconds of signal from the P- or S-wave onsets, i.e. while the rupture itself is still propagating and rupture dimension is far from complete. We argue that dynamic stress release and/or slip duration on the fault in the very early stage of seismic fracture, scales both with the observed peak amplitude and with the elastic energy available for fracture propagation. The probability that a fracture grows to a larger size should scale with the energy initially available.
    Description: Published
    Description: L23312
    Description: JCR Journal
    Description: partially_open
    Keywords: Earthquake ; 04. Solid Earth::04.06. Seismology::04.06.03. Earthquake source and dynamics
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  • 20
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    A thermal pressurization model for the spontaneous dynamic rupture propagation on a three-dimensional fault: 1. Methodological approach (2007)
    Agu
    Details
    Publication Date: 2017-04-04
    Description: We investigate the role of frictional heating and thermal pressurization on earthquake ruptures by modeling the spontaneous propagation of a three-dimensional (3-D) crack on a planar fault governed by assigned constitutive laws and allowing the evolution of effective normal stress. We use both slip-weakening and rate- and state-dependent constitutive laws; in this latter case we employ the Linker and Dieterich evolution law for the state variable, and we couple the temporal variations of friction coefficient with those of effective normal stress. In the companion paper we investigate the effects of thermal pressurization on the dynamic traction evolution. We solve the 1-D heat conduction equation coupled with Darcy’s law for fluid flow in porous media. We obtain a relation that couples pore fluid pressure to the temperature evolution on the fault plane. We analytically solve the thermal pressurization problem by considering an appropriate heat source for a fault of finite thickness. Our modeling results show that thermal pressurization reduces the temperature increase caused by frictional heating. However, the effect of the slipping zone thickness on temperature changes is stronger than that of thermal pressurization, at least for a constant porosity model. Pore pressure and effective normal stress evolution affect the dynamic propagation of the earthquake rupture producing a shorter breakdown time and larger breakdown stress drop and rupture velocity. The evolution of the state variable in the framework of rate- and state-dependent friction laws is very different when thermal pressurization is active. In this case the evolution of the friction coefficient differs substantially from that inferred from a slip-weakening law. This implies that the traction evolution and the dynamic parameters are strongly affected by thermal pressurization.
    Description: Published
    Description: B05303
    Description: JCR Journal
    Description: reserved
    Keywords: thermal pressurization ; 04. Solid Earth::04.01. Earth Interior::04.01.05. Rheology ; 04. Solid Earth::04.02. Exploration geophysics::04.02.03. Heat flow ; 04. Solid Earth::04.06. Seismology::04.06.03. Earthquake source and dynamics
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  • 21
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    Physical interpretation of the breakdown process using a rate- and state-dependent friction law (2007)
    Elsevier
    Details
    Publication Date: 2017-04-04
    Description: We study the dynamic traction and the slip velocity evolution within the cohesive zone during the propagation of a dynamic rupture using rate- and state-dependent constitutive laws. We solve the elastodynamic equation for a 2-D in-plane crack using a finite difference algorithm. We show that rate and state constitutive laws allow a quantitative description of the dynamic rupture growth. We confirm the findings of previous studies that slip weakening (SW) is a characteristic behavior of rate and state friction. Our simulations show that the state variable evolution controls the slip acceleration and the slip-weakening behavior. These modeling results help in understanding the physical interpretation of the breakdown process and the weakening mechanisms. We compare the time histories of slip velocity, state variable and total dynamic traction to investigate the temporal evolution of slip acceleration and stress drop during the breakdown time. Because the adopted analytical expression for the state variable evolution controls the slip velocity time histories, we test different evolution laws to investigate slip duration and the healing mechanisms. We show that the classic slowness or slip laws do not yield fast restrengthening or self-healing, although they appropriately describe rupture initiation, propagation and the long-term restrengthening during the interseismic period. Self-healing rupture mode, yielding to short slip durations, has been obtained for homogeneous faults by modifying the evolution law introducing a fast restrengthening of dynamic traction immediately after the weakening phase. In this study, we discuss how the direct effect of friction and the friction behavior at high slip rates affect the weakening and healing mechanisms.
    Description: Published
    Description: 241-262
    Description: 3.1. Fisica dei terremoti
    Description: JCR Journal
    Description: reserved
    Keywords: fault friction ; earthquake rupture ; rate- ad state dependent constitutive laws ; cohesive zone ; slip weakening ; fracture energy ; 04. Solid Earth::04.06. Seismology::04.06.03. Earthquake source and dynamics
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  • 22
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    Eddy covariance measurements of geothermal heat flux at Solfatara Volcano, Naples, Italy (2007)
    Elsevier
    Details
    Publication Date: 2017-04-04
    Description: The first measurements of volcanic/hydrothermal water vapor and heat flux using eddy covariance (EC) were made at Solfatara crater, Italy, June 8–25, 2001. Deployment at six different locations within the crater allowed areas of focused gas venting to be variably included in the measured flux. Turbulent (EC) fluxes of water vapor varied between 680 and 11200g H2O m−2 d−1. Heat fluxes varied diurnally with the solar input, and the volcanic component of sensible heat ranged from ∼25 to 238W m−2. The highest measurements of both sensible and latent heat flux were made downwind of hot soil regions and degassing pools and during mid-day. The ratio of average volcanic heat (both latent and sensible) to CO2 flux resulted in an equivalent H2O/CO2 flux ratio of 2.2 by weight, which reflects the deep source H2O/CO2 gas ratio. The amount latent heat flux/evaporation was determined to be consistent both with what would be expected from the magnitude of CO2 fluxes and the fumarolic H2O/CO2 ratio, as well as with observed surface temperatures and wind speeds given a moist soil. This suggests that the water vapor that condenses in the shallow subsurface is remobilized at the soil–atmosphere interface through variable evaporation dependent on the deep heat flux and surface temperature. The results suggest that EC provides a quick and easy method to monitor average H2O/CO2 ratios continuously in volcanic regions, providing another important tool for volcanic hazards monitoring.
    Description: Published
    Description: 72–82
    Description: reserved
    Keywords: eddy covariance ; volcanic ; heat flux ; water vapor ; hydrothermal ; degassing ; flux ; emissions ; 03. Hydrosphere::03.04. Chemical and biological::03.04.05. Gases ; 03. Hydrosphere::03.04. Chemical and biological::03.04.06. Hydrothermal systems ; 03. Hydrosphere::03.04. Chemical and biological::03.04.08. Instruments and techniques
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  • 23
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    Evidence of instantaneous dynamic triggering during the seismic sequence of year 2000 in south Iceland (2007)
    Agu
    Details
    Publication Date: 2017-04-04
    Description: We analyze the coseismic stress perturbation during the 17 June 2000 south Iceland seismic sequence; the main shock (Ms 6.6) was followed by three large events within a few tens of seconds (8, 26, and 30 s) located within 80 km. The aim of this paper is to investigate short-term fault interaction and instantaneous triggering. This happens when a fault perturbed by a stress change fails before the end of the transient stress perturbation. We compute the shear, normal, and Coulomb stress changes as functions of time in a stratified elastic half-space by using discrete wave number and reflectivity methods. We calculate dynamic stresses caused by the main shock at the hypocenters of these three subsequent events. Our numerical results show that the onset of the last two events is slightly delayed with respect to the arrival time of the second positive peak of Coulomb stress variation, while the first event occurred after the first positive stress peak. We have also analyzed the response of a spring slider system representing a fault governed by a rate- and state-dependent friction law, perturbed by shear and normal stress variations caused by the main shock. The fault response to the computed stress perturbations is always clock advanced. We have found suitable constitutive parameters of the modeled fault that allow the instantaneous dynamic triggering of these three earthquakes. If the initial sliding velocity is comparable with the tectonic loading velocity, we obtained failure times close to the observed origin times for low values of the initial effective normal stress.
    Description: Published
    Description: B03302
    Description: JCR Journal
    Description: reserved
    Keywords: seismic sequence ; Iceland ; 2000 ; 04. Solid Earth::04.06. Seismology::04.06.01. Earthquake faults: properties and evolution ; 04. Solid Earth::04.06. Seismology::04.06.02. Earthquake interactions and probability ; 04. Solid Earth::04.06. Seismology::04.06.03. Earthquake source and dynamics
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  • 24
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    A critical revision of the seismicity of Northern Apulia (Adriatic microplate - Southern Italy) and implications for the identification of seismogenic structures (2007)
    Elsevier
    Details
    Publication Date: 2017-04-04
    Description: Northern Apulia is an emerged portion of the Adriatic microplate, representing the foreland–foredeep area of a stretch of the Apennine chain in southern Italy. The interaction between the relatively rigid microplate and the contiguous more deformable domains is responsible for the intense seismicity affecting the chain area. However strong, sometimes even disastrous, earthquakes have also hit northern Apulia on several occasions. The identification of the causative faults of such events is still unclear and different hypotheses have been reported in literature. In order to provide guidelines and constraints in the search for these structures, a comprehensive re-examination and reprocessing of all the available seismic data has been carried out taking into consideration 1) the characteristics of historical events, 2) the accurate relocation of events instrumentally recorded in the last 20 years, 3) the determination of focal mechanisms and of the regional stress tensor. The results obtained bring to light a distinction between the foreland and foredeep areas. In the first region there is evidence of a regional stress combining NWcompression and NE extension, thus structures responsible for major earthquakes should be searched for among strike–slip faults, possibly with a slight transpressive character. These structures could be either approximately N–S oriented sinistral or E–Wdextral faults. In the foredeep region there is a transition toward transtensive mechanisms,with strikes similar to those of the previous zone, or maybe also towardsNWoriented normal faults,more similar to those prevailing in the southern Apennine chain in relation to a dominant NE extension; this appears to be the effect of a reduction of the NW compression, probably due to a decrease in efficiency of stress transmission along the more tectonised border of the Adriatic microplate.
    Description: Published
    Description: 9 - 35
    Description: 3.2. Tettonica attiva
    Description: JCR Journal
    Description: reserved
    Keywords: Northern Apulia ; Historical earthquakes ; 04. Solid Earth::04.06. Seismology::04.06.03. Earthquake source and dynamics ; 04. Solid Earth::04.07. Tectonophysics::04.07.02. Geodynamics
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    Diffuse and focused carbon dioxide and methane emissions from the Sousaki geothermal system, Greece (2007)
    Agu
    Details
    Publication Date: 2017-10-06
    Description: We report first data on chemical composition of the gas emitted by the geothermal system of Sousaki, Greece. Gas manifestations display typical geothermal gas composition with CO2 as the main component and CH4 and H2S as minor species. Soil gas composition derives from the mixing of two end-members (atmospheric air and geothermal gas). Soil CO2 fluxes range from〈2 to 33,400 g m 2 d 1. The estimated diffuse output of hydrothermal CO2, estimated for an area of 0.015 km2, is about 630 g s 1, while a tentative estimation of CH4 diffuse output gave a value of about 1.15 g s 1. Point sources accounted for lower flux values of 26 g s 1 of CO2, 0.1 g s 1 of CH4 and 0.02 g s 1 of H2S.
    Description: Published
    Description: L05307
    Description: JCR Journal
    Description: reserved
    Keywords: carbon dioxide ; methane emissions ; geothermal system, ; 03. Hydrosphere::03.04. Chemical and biological::03.04.06. Hydrothermal systems
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  • 26
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    Long-term seismogenesis in Greece: Comparison of the evolving stress field and precursory scale increase approaches (2007)
    Agu
    Details
    Publication Date: 2024-05-09
    Description: Recent strong (M 6.6) earthquakes in Greece are examined from the point of view of two current, but disparate, approaches to long-term seismogenesis. These are the evolving stress field (ESF) approach, in which earthquakes are considered to be triggered by accumulated stress changes from past earthquakes and tectonic loading on the major faults, and the precursory scale increase (Y) approach, in which a major earthquake is preceded in the long term by an increase in minor earthquake occurrences, with the magnitude of the precursory earthquakes, and the precursor time and area all scaling with the major earthquake magnitude. The strong earthquakes are found to be consistent with both approaches, and it is inferred that both approaches have a relevant role to play in the description of the long-term generation process of major earthquakes. A three-stage faulting model proposed previously to explain the Y phenomenon involves a major crack, which eventually fractures in the major earthquake, being formed before the onset of precursory seismicity. Hence we examine whether ESF can account for the formation of the major crack by examining the accumulated stress changes at the time of the onset of Y for each strong earthquake. In each case, the answer is in the affirmative; there is enhanced stress in the vicinity of the main shock at the time of the onset. The same is true for most, but not all, of the locations of precursory earthquakes.
    Description: Published
    Description: B05318
    Description: reserved
    Keywords: seismogenesis ; Greece: ; 04. Solid Earth::04.06. Seismology::04.06.01. Earthquake faults: properties and evolution ; 04. Solid Earth::04.06. Seismology::04.06.02. Earthquake interactions and probability ; 04. Solid Earth::04.06. Seismology::04.06.03. Earthquake source and dynamics
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
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  • 27
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    Microbial communities near the oxic/anoxic interface in the hydrothermal system of Vulcano Island, Italy (2006)
    Elsevier
    Details
    Publication Date: 2017-04-04
    Description: Hydrothermal fluids and sediments from subaerial and shallow submarine sites at Vulcano Island, Italy were investigated for relations between the thermophilic microbial communities, as analysed by fluorescence in situ hybridization, and their geochemical environment, as assessed by photometry, chromatography, and in situ microsensor measurements. Mixing between hydrothermal fluids and seawater in the sediment pore space was reflected in the chemical composition of the emitted fluids, in depth profiles of pore water oxygen and sulfide concentrations, and in the structure of the benthic microbial community. Organic compounds did not accumulate in the vent fluids (b10 AM fatty acids) or in the sediments (b0.1% Corg), suggesting that efficient utilization supported microbial populations on the order of 104 cells per ml fluid and 108 cells per cm3 sediment. Groups of thermophiles that typically gain metabolic energy from the fermentation of organic matter (Thermococcales, Thermotoga/Thermosipho spp., and Bacillus sp.)were detected in significant abundances at all study sites. Also abundant were thermophiles capable of oxidizing organic acids with oxygen, nitrate, or sulfate. Aerobic thermophiles (Aquificales and Thermus sp.) were more abundant at oxic sites than at anoxic sites. Increasingly oxygenated habitats were associated with decreasing abundance of anaerobic (hyper)thermophiles belonging to the order Archaeoglobales.
    Description: Published
    Description: 169– 182
    Description: partially_open
    Keywords: Biogeochemistry ; Hydrothermal system ; Marine sediment ; Microbial ecology ; Microsensor ; Thermophiles ; 03. Hydrosphere::03.04. Chemical and biological::03.04.04. Ecosystems ; 03. Hydrosphere::03.04. Chemical and biological::03.04.06. Hydrothermal systems
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    Magma-derived gas influx and water-rock interactions in the volcanic aquifer of Mt. Vesuvius, Italy (2005)
    Elsevier
    Details
    Publication Date: 2021-06-25
    Description: We report in this paper a systematic investigation of the chemical and isotopic composition of groundwaters flowing in the volcanic aquifer of Mt. Vesuvius during its current phase of dormancy, including the first data on dissolved helium isotope composition and tritium content. The relevant results on dissolved He and C presented in this paper reveal that an extensive interaction between rising magmatic volatiles and groundwaters currently takes place at Vesuvius. Vesuvius groundwaters are dilute (mean TDS 2800 mg/L) hypothermal fluids (mean T 17.7°C) with a prevalent alkaline-bicarbonate composition. Calcium-bicarbonate groundwaters normally occur on the surrounding Campanian Plain, likely recharged from the Apennines. D and 18O data evidence an essentially meteoric origin of Vesuvius groundwaters, the contribution from either Tyrrhenian seawater or 18O-enriched thermal water appearing to be small or negligible. However, the dissolution of CO2-rich gases at depth promotes acid alteration and isochemical leaching of the permeable volcanic rocks, which explains the generally low pH and high total carbon content of waters. Attainment of chemical equilibrium between the rock and the weathering solutions is prevented by commonly low temperature (10 to 28°C) and acid-reducing conditions. The chemical and isotope (C and He) composition of dissolved gases highlights the magmatic origin of the gas phase feeding the aquifer. We show that although the pristine magmatic composition may vary upon gas ascent because of either dilution by a soil-atmospheric component or fractionation processes during interaction with the aquifer, both 13C/12C and 3He/4He measurements indicate the contribution of a magmatic component with a 13C 0‰ and R/Ra of 2.7, which is consistent with data from Vesuvius fumaroles and phenocryst melt inclusions in olivine phenocrysts. A main control of tectonics on gas ascent is revealed by data presented in this paper. For example, two areas of high CO2 release and enhanced rock leaching are recognized on the western (Torre del Greco) and southwestern (Torre Annunziata–Pompeii) flanks of Vesuvius, where important NE-SW and NW-SE tectonic structures are recognized. In contrast, waters flowing through the northern sector of the volcano are generally colder, less saline, and CO2 depleted, despite in some cases containing significant concentrations of magmaderived helium. The remarkable differences among the various sectors of the volcano are reconciled in a geochemical interpretative model, which is consistent with recent structural and geophysical evidences on the structure of Somma-Vesuvius volcanic complex.
    Description: -European Union, -Ministero dell’Universita’ e della Ricerca Scientifica e Tecnologica; -CNR–Gruppo Nazionale per la Vulcanologia.
    Description: Published
    Description: 963–981
    Description: partially_open
    Keywords: isotopes ; water chemistry ; dissolved gases ; 03. Hydrosphere::03.02. Hydrology::03.02.03. Groundwater processes ; 03. Hydrosphere::03.04. Chemical and biological::03.04.03. Chemistry of waters ; 03. Hydrosphere::03.04. Chemical and biological::03.04.05. Gases ; 03. Hydrosphere::03.04. Chemical and biological::03.04.06. Hydrothermal systems ; 03. Hydrosphere::03.04. Chemical and biological::03.04.07. Radioactivity and isotopes ; 04. Solid Earth::04.08. Volcanology::04.08.01. Gases ; 04. Solid Earth::04.08. Volcanology::04.08.06. Volcano monitoring
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  • 29
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    Geochemical monitoring of groundwaters (1998-2001) at Vesuvius volcano (Italy) (2005)
    Elsevier
    Details
    Publication Date: 2017-04-04
    Description: This work presents the results of hydrogeochemical studies carried out at Vesuvius during the period May 1998 - December 2001, mostly focusing on compositional time variations observed during this time. Based on their chemistry, groundwater samples are distinguished into two groups, 1 and 2, representative of water circulation in the southern and northern sectors of the volcano, respectively. Waters from group 1 are typically more acidic, warmer,and more saline than those of group 2. They also have higher CO2 and CH4 contents, attributed to enhanced input of deep-rising volatiles and prolonged water-rock interactions. Time-series highlight the fairly constant chemical composition of the entire aquifer. Groundwater temperature, pH, bicarbonate content and dissolved CO2 display quite stable values in the study period, particularly in deep wells (piezometric level more than 100 m deep). Shallower water bodies present more evident temporal variations, related to seasonal and anthropogenic effects. This paper also describes some important variations in water chemistry which had occurred by the time of the seismic event in early October 1999, particularly in the Olivella spring located on the northern flank of the volcano. At this site, a great decrease in water pH and redox potential, and increased dissolved CO2 contents and 3He/4He ratios were observed. These changes in chemical and isotope composition support the hypothesis of an input of magma-derived helium and carbon dioxide into the aquifer feeding the Olivella spring by the time of the earthquake.
    Description: Published
    Description: 81-104
    Description: partially_open
    Keywords: Vesuvius ; volcanic surveillance ; groundwater ; hydro-geochemistry ; oxygen-18 ; 03. Hydrosphere::03.04. Chemical and biological::03.04.03. Chemistry of waters ; 03. Hydrosphere::03.04. Chemical and biological::03.04.05. Gases ; 03. Hydrosphere::03.04. Chemical and biological::03.04.06. Hydrothermal systems ; 04. Solid Earth::04.08. Volcanology::04.08.06. Volcano monitoring
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  • 30
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    Chemical and isotopic equilibrium between CO2 and CH4 in fumarolic gas discharges: generation of CH4 in magmatic-hydrothermal systems (2005)
    Elsevier
    Details
    Publication Date: 2017-04-04
    Description: The chemical and isotopic composition of fumarolic gases emitted from Nisyros Volcano, Greece,and of a single gas sample from Vesuvio, Italy, was investigated in order to determine the origin of methane (CH4) within two subduction-related magmatic-hydrothermal environments. Apparent temperatures derived from carbon isotope partitioning between CH4 and CO2 of around 340°C for Nisyros and 470°C for Vesuvio correlate well with aquifer temperatures as measured directly and/or inferred from compositional data using the H2O-H2-CO2-CO-CH4 geothermometer. Thermodynamic modeling reveals chemical equilibrium between CH4, CO2 and H2O implying that carbon isotope partitioning between CO2 and CH4 in both systems is controlled by aquifer temperature. N2/3He and CH4/3He ratios of Nisyros fumarolic gases are unusually low for subduction zone gases and correspond to those of midoceanic ridge environments. Accordingly, CH4 may have been primarily generated through the reduction of CO2 by H2 in the absence of any organic matter following a Fischer-Tropsch-type reaction. However, primary occurrence of minor amounts of thermogenic CH4 and subsequent re-equilibration with co-existing CO2 cannot be ruled out entirely. CO2/3He ratios and 13CCO2 values imply that the evolved CO2 either derives from a metasomatized mantle or is a mixture between two components, one outgassing from an unaltered mantle and the other released by thermal breakdown of marine carbonates. The latter may contain traces of organic matter possibly decomposing to CH4 during thermometamorphism.
    Description: European community
    Description: Published
    Description: 2321–2334
    Description: partially_open
    Keywords: fumarolic gases ; hydrothermal systems ; chemical and isotopic equilibrium ; 03. Hydrosphere::03.04. Chemical and biological::03.04.06. Hydrothermal systems ; 04. Solid Earth::04.08. Volcanology::04.08.01. Gases
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  • 31
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    The aquatic geochemistry of arsenic in volcanic groundwaters from southern Italy (2005)
    Elsevier
    Details
    Publication Date: 2017-04-04
    Description: This paper discusses the abundance, speciation and mobility of As in groundwater systems from active volcanic areas in Italy. Using literature data and new additional determinations, the main geochemical processes controlling the fate of As during gas–water–rock interaction in these systems are examined. Arsenic concentrations in the fluids range from 0.1 to 6940 mg/l, with wide differences observed among the different volcanoes and within each area. The dependence of As content on water temperature, pH, redox potential and major ions is investigated. Results demonstrate that As concentrations are highest where active hydrothermal circulation takes place at shallow levels, i.e. at Vulcano Island and the Phlegrean Fields. In both areas the dissolution of As-bearing sulphides is likely to be the main source of As. Mature Cl-rich groundwaters, representative of the discharge from the deep thermal reservoirs, are typically enriched in As with respect to SO4-rich ‘‘steam heated groundwaters’’. In the HCO3 groundwaters recovered at Vesuvius and Etna, aqueous As cycling is limited by the absence of high-temperature interactions and by high-Fe content of the host rocks, resulting in oxidative As adsorption. Thermodynamic modelling suggests that reducing H2S-rich groundwaters are in equilibrium with realgar, whereas in oxidising environments over-saturation with respect to Fe oxyhydroxides is indicated. Under these oxidising conditions, As solubility decreases controlled by As co-precipitation with, or adsorption on, Fe oxy-hydroxides. Consistent with thermodynamic considerations, As mobility in the studied areas is enhanced in intermediate redox environments, where both sulphides and Fe hydroxides are unstable.
    Description: Published
    Description: 1283–1296
    Description: partially_open
    Keywords: Hydrogeochemistry ; Arsenic ; volcanic groundwaters ; speciation ; 03. Hydrosphere::03.01. General::03.01.01. Analytical and numerical modeling ; 03. Hydrosphere::03.02. Hydrology::03.02.02. Hydrological processes: interaction, transport, dynamics ; 03. Hydrosphere::03.02. Hydrology::03.02.03. Groundwater processes ; 03. Hydrosphere::03.04. Chemical and biological::03.04.03. Chemistry of waters ; 03. Hydrosphere::03.04. Chemical and biological::03.04.06. Hydrothermal systems
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    The buried caldera of Misti volcano, Peru, revealed by combining a self-potential survey with elliptic Fourier function analysis of topography (2005)
    Elsevier
    Details
    Publication Date: 2017-04-04
    Description: This survey proposes a new approach to identify buried caldera boundaries of a volcanic cone, combining (1) a systematic elliptic Fourier functions (EFF) analysis on the contour lines based on the external shape of the edifice with (2) self-potential (SP) measurements on volcano flanks. The methodology of this approach is to investigate the relationships between (1) vertical morphological changes inferred from EFF analysis and (2) lateral lithological transition inside the edifice inferred from SP/elevation gradients. The application of these methods on Misti volcano in southern Peru displays a very good correlation. The three main boundaries evidenced by hierarchical cluster analysis on the contour lines coincide with the two main boundaries characterised by SP signal and with a secondary SP signature related with a summit caldera. In order to explain these results showing a very good correlation between morphologic and lithologic changes as function of elevation, caldera boundaries have been suggested. The latter would be located at an average elevation of (1) 4350–4400 m, (2) 4950–5000 m, and (3) 5500– 5550 m. For the lowest boundary in elevation, the coincidence with the lateral extension of the hydrothermal system inferred from SP measurements suggests that caldera walls act as a barrier for lateral extension of hydrothermal systems. In the summit area, the highest boundary has been related with the summit caldera, inferred by a secondary SP minimum and geological evidence.
    Description: - Institut de Recherche pour le Développement (IRD) - Instituto Geofisico del Peru´ (IGP).
    Description: Published
    Description: 283– 297
    Description: partially_open
    Keywords: caldera ; elliptic Fourier functions ; geomorphology ; self-potential ; Misti volcano ; Peru ; 03. Hydrosphere::03.02. Hydrology::03.02.02. Hydrological processes: interaction, transport, dynamics ; 03. Hydrosphere::03.02. Hydrology::03.02.03. Groundwater processes ; 03. Hydrosphere::03.02. Hydrology::03.02.04. Measurements and monitoring ; 03. Hydrosphere::03.04. Chemical and biological::03.04.05. Gases ; 03. Hydrosphere::03.04. Chemical and biological::03.04.06. Hydrothermal systems ; 04. Solid Earth::04.01. Earth Interior::04.01.02. Geological and geophysical evidences of deep processes ; 04. Solid Earth::04.02. Exploration geophysics::04.02.04. Magnetic and electrical methods ; 04. Solid Earth::04.04. Geology::04.04.03. Geomorphology ; 04. Solid Earth::04.04. Geology::04.04.09. Structural geology ; 04. Solid Earth::04.04. Geology::04.04.11. Instruments and techniques ; 04. Solid Earth::04.08. Volcanology::04.08.05. Volcanic rocks ; 05. General::05.02. Data dissemination::05.02.04. Hydrogeological data ; 05. General::05.05. Mathematical geophysics::05.05.99. General or miscellaneous ; 05. General::05.08. Risk::05.08.99. General or miscellaneous ; 04. Solid Earth::04.08. Volcanology::04.08.08. Volcanic risk
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  • 33
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    Intrinsic and scattering attenuation from observed seismic codas in Southeastern Sicily (Italy) (2005)
    Elsevier
    Details
    Publication Date: 2017-04-04
    Description: We analyzed about 150 local earthquakes recorded in Southeastern Sicily from 1994 to 2001 and estimated coda- Q, intrinsic and scattering attenuation. We used the single scattering assumption to fit the amplitude envelopes of the coda at different frequency bands, obtaining a Qc varying with frequency as generally observed in tectonically active areas. Lapse time dependence has been also studied for the area, with the coda waves analyzed at window lengths ranging from 15 to 50 s, provided the coda duration permitted it. We found that Q0 ( Qc at 1 Hz) increases with lapse time and we interpreted this as due to increasing Qc with depth. Conversely, the frequency dependence coefficient n is mostly stationary at all the lapse time window lengths. Finally, using the independent estimates of Qc and the total Q ( QT) previously obtained for the area by other authors from direct S-waves of the same data set, we separated the intrinsic ( ) from the scattering ( ) attenuation factor. The results suggest that in Southeastern Sicily intrinsic dissipation plays a predominant role with respect to scattering phenomena.
    Description: Published
    Description: 55-66
    Description: partially_open
    Keywords: Coda waves ; Intrinsic attenuation ; Scattering ; Frequency dependence and Southeastern Sicily ; 04. Solid Earth::04.06. Seismology::04.06.03. Earthquake source and dynamics
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
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    Fluid circulation at Stromboli volcano (Aeolian Islands, Italy) from self-potential and CO2 surveys (2005)
    Elsevier
    Details
    Publication Date: 2017-04-04
    Description: This work addresses the study of fluid circulation of the Stromboli island using a dense coverage of self-potential (SP) and soil CO2 data. A marked difference exists between the northern flank and the other flanks of the island. The northern flank exhibits (1) a typical negative SP/altitude gradient not observed on the other flanks, and (2) higher levels of CO2. The general SP pattern suggests that the northern flank is composed of porous layers through which vadose water flows down to a basal water table, in contrast to the other flanks where impermeable layers impede the vertical flow of vadose water. In the Sciara del Fuoco and Rina Grande-Le Schicciole landslide complexes, breccias of shallow gliding planes may constitute such impermeable layers whereas elsewhere, poorly permeable, fine-grained pyroclastites or altered lava flows may be present. This general model of the flanks also explains the main CO2 patterns: concentration of CO2 at the surface is high on the porous north flank and lower on the other flanks where impermeable layers can block the upward CO2 flux. The active upper part of the island is underlain by a well-defined hydrothermal system bounded by short-wavelength negative SP anomalies and high peaks of CO2. These boundaries coincide with faults limiting ancient collapses of calderas, craters and flank landslides. The hydrothermal system is not homogeneous but composed of three main subsystems and of a fourth minor one and is not centered on the active craters. The latter are located near its border. This divergence between the location of the active craters and the extent of the hydrothermal system suggests that the internal heat sources may not be limited to sources below the active craters. If the heat source strictly corresponds to intrusions at depth around the active conduits, the geometry of the hydrothermal subsystems must be strongly controlled by heterogeneities within the edifice such as craters, caldera walls or gliding planes of flank collapse, as suggested by the correspondence between SP^CO2 anomalies and structural limits. The inner zone of the hydrothermal subsystems is characterized by positive SP anomalies, indicating upward movements of fluids, and by very low values of CO2 emanation. This pattern suggests that the hydrothermal zone becomes self-sealed at depth, thus creating a barrier to the CO2 flux. In this hypothesis, the observed hydrothermal system is a shallow one and it involves mostly convection of infiltrated meteoric water above the sealed zone. Finally, on the base of CO2 degassing measurements, we present evidence for the presence of two regional faults, oriented N41‡ and N64‡, and decoupled from the volcanic structures.
    Description: Published
    Description: 1^18
    Description: partially_open
    Keywords: Stromboli ; hydrothermal system ; self-potential ; soil gas ; carbon dioxide ; Aeolian islands ; 03. Hydrosphere::03.02. Hydrology::03.02.02. Hydrological processes: interaction, transport, dynamics ; 03. Hydrosphere::03.04. Chemical and biological::03.04.06. Hydrothermal systems ; 04. Solid Earth::04.04. Geology::04.04.12. Fluid Geochemistry ; 04. Solid Earth::04.08. Volcanology::04.08.01. Gases ; 05. General::05.02. Data dissemination::05.02.01. Geochemical data ; 04. Solid Earth::04.08. Volcanology::04.08.08. Volcanic risk
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  • 35
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    Dissolved helium isotope ratios in ground-waters: a new technique based on gas–water re-equilibration and its application to Stromboli volcanic system (2005)
    Elsevier
    Details
    Publication Date: 2017-04-04
    Description: Here, a new technique for the determination of dissolved He isotope ratios in ground-waters is presented. This method is based on the extraction and subsequent equilibrium of dissolved gases in an added ‘‘host’’ gas phase. Ultra pure N2 is placed in glass flasks (250 cc), containing water samples, that were hermetically sealed after their collection. After shaking in an ultrasonic bath for 10 min, an aliquot of the separated gas phase was removed from the flask for MS analysis. 3He/4He ratios are measured by using a modified double collector mass spectrometer (VG 5400-TFT). Helium and Ne concentrations are calculated by comparing the partial pressures of masses 4 and 20 of the samples with those of the air-standard measured by a quadrupole mass spectrometer (QMS;VG Quartz). Using He and Ne equilibrium partitioning coefficients, it is possible to calculate the amount of gas originally dissolved in the water. The technique was tested on both air-saturated waters (ASW) and thermal waters from Stromboli (Aeolian Islands, South Italy), the results of which confirmed good reproducibility (ffi5%) and accuracy (ffi3%) of the data. The method was then applied to three thermal water samples collected from the same volcanic area and the results compared with those of a fumarolic and a soil gas. The isotope ratios for dissolved He gave values of 4.06–4.23 Ra, which are significantly higher than those previously reported in the literature (3.0, 3.5 and 2.9 Ra) and that measured at the fumarole (3.09 Ra), suggesting a newer and higher isotopic signature for the volcanic system. The proposed method appears to be a useful tool in the determination of 3He/4He ratios in ground-water systems, especially when free gases are not available or are dangerous to collect.
    Description: Published
    Description: 665–673
    Description: partially_open
    Keywords: dissolved helium isotopes ; gas water interaction ; 03. Hydrosphere::03.02. Hydrology::03.02.03. Groundwater processes ; 03. Hydrosphere::03.04. Chemical and biological::03.04.06. Hydrothermal systems ; 04. Solid Earth::04.08. Volcanology::04.08.01. Gases
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    Isotopic, chemical and dissolved gas constraints on spring water from Popocatepetl volcano (Mexico): evidence of gas–water interaction between magmatic component and shallow fluids (2005)
    Elsevier
    Details
    Publication Date: 2017-04-04
    Description: Geochemical research was carried out on cold and hot springs at Popocatepetl (Popo) volcano (Mexico) in 1999 to identify a possible relationship with magmatic activity. The chemical and isotopic composition of the fluids is compatible with strong gas–water interaction between deep and shallow fluids. In fact, the isotopic composition of He and dissolved carbon species is consistent with a magmatic origin. The presence of a geothermal system having a temperature of 80–1008 C was estimated on the basis of liquid geothermometers. A large amount of dissolved CO2 in the springs was also detected and associated with high CO2 degassing.
    Description: Published
    Description: 91– 108
    Description: partially_open
    Keywords: Popocatepetl volcano ; helium isotope composition ; carbon isotope composition ; dissolved gases ; gas–water interaction ; 03. Hydrosphere::03.02. Hydrology::03.02.03. Groundwater processes ; 03. Hydrosphere::03.04. Chemical and biological::03.04.05. Gases ; 03. Hydrosphere::03.04. Chemical and biological::03.04.06. Hydrothermal systems ; 04. Solid Earth::04.04. Geology::04.04.12. Fluid Geochemistry ; 04. Solid Earth::04.08. Volcanology::04.08.01. Gases
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