ALBERT

Beschreibung: Lateglacial and Holocene faunal and stable-isotope records from benthic foraminifers in the eastern Mediterranean Sea (EMS) suggest a high spatiotemporal variability of deep-water oxygenation and biogeochemical processes at the sea floor during that time. Changes in the oxygenation and food availability of the deep-sea ecosystems are closely linked to the hydrology of the EMS borderlands; they reflect orbital and suborbital climate variations of the high northern latitudes and the African monsoon system. During the last glacial maximum, cool surface waters and high evaporation resulted in maximum convection and oxic deep-waters in all sub-basins. Strong wind-induced mixing fostered surface-water production with seasonal phytodetritus fluxes. During the glacial termination and the Holocene, oxygenation and food availability of deep-sea benthic ecosystems were characterized by a pronounced regional differentiation. Local deep-water formation and trophic conditions were particularly variable in the northern Aegean Sea as a response to changes in riverine runoff and Black Sea outflow. During the interval of sapropel S1 formation in the early Holocene, average oxygen levels decreased exponentially with increasing water depth, suggesting a basin-wide shallowing of vertical convection superimposed by local signals. In the northernmost Aegean Sea, deep-water ventilation persisted during the early period of S1 formation, owing to temperature-driven local convection and the absence of low-salinity Black Sea outflow. At the same time, severe temporary anoxia occurred in the eastern Levantine basin at water depths as shallow as 900 m. This area was likely influenced by enhanced nutrient input of the Nile river that resulted in high organic matter fluxes and related high oxygen-consumption rates in the water column. In the southern Aegean and Levantine Seas, we observe a gradual increase in deep-water residence times, preceding S1 formation by approximately 1–1.5 kyr. Once oxygen levels fell below a critical threshold, the benthic ecosystems collapsed almost synchronously with the onset of S1 deposition. The recovery of benthic ecosystems during the terminal phase of S1 formation is controlled by subsequently deeper convection and re-ventilation over a period of approximately 1500 years. After the re-ventilation of the various sub-basins had been completed during the middle and late Holocene, deep-water renewal was more or less similar to recent rates. During that time, deep-sea ecosystem variability was driven by short-term changes in food quantity and quality as well as in seasonality, all of which are linked to millennial-scale changes in riverine runoff and associated nutrient input.

Beschreibung: We present a new interface between the geochemical simulator PHREEQC and the open source language R. It represents a tool to flexibly and efficiently program and automate every aspect of geochemical modelling. The interface helps particularly to setup and run large numbers of simulations and visualise the results. Also profiting of numberless high-quality R extension packages, performing sensitivity analysis or Monte Carlo simulations becomes straightforward. Further, an algorithm to speedup reactive transport simulations starting from homogeneous or zone- homogeneous state is programmed and successfully evaluated through the interface. It proved effective and could therefore be included in any reactive transport simulator.

Beschreibung: We studied 40 artesian wells (AWs) in the Amu Darya Delta. These wells include high-salinity (∼ 52 g/l) and saline (5 – 24 g/l) waters but are mostly low-salinity waters (1.3 – 2.9 g/l). The low-salinity AWs cluster into three types, reflecting the variable mixing of different end-member solutes: (residual) brines and solutes deriving from silicate alteration, dissolution of limestone and dissolution of gypsum. The solutes are all undersaturated in calcite and gypsum, contain a substantial cation excess against dissolved inorganic carbon and are characterised by low Ca/SO4 ratios. On the basis of the hydrochemical mass budgets of model cases, we demonstrate that Na-rich Cl-brines (45-48%) and a Na2SO4-brine (30-47%) are the dominant solute components. The solutes derived from aluminium silicate alteration are minor components (7.3 – 19.4%). Even less important are solutes from limestone or gypsum dissolution (0.05 – 3.7%). These waters are unlikely to have originated from sediments hosting gypsum. The low-salinity AWs must have acquired their dominant hydrochemical signatures under non-equilibrium conditions between their remote (unknown) seepage areas and their discharge locations. This acquisition may have begun during the early hydrochemical groundwater evolution when meteoric or surface water passed the critical zone under an arid climate regime. Warmer saline AWs (∼40°C) hosted in deeper Cretaceous formations contain a high portion of NaCl-rich brine (85%) and some are saturated in gypsum. These waters were derived from fluids rising along faults from pre-Cretaceous strata. The high-salinity and relatively cold AWs discharge close to the retreating Aral Sea south of its western basin. These AWs are suboxic, and Si concentrations are very low. The AW hydrochemical signatures reflect the dissolution of halite and gypsum. We observed positive correlations between temperature, Br, B and Si. The temperature correlation with bromide likely documents the transformation of organically bound Br. The silica concentrations in low-salinity AWs southeast of the Aral Sea (eastern basin) are close to quartz saturation and define a chemical Si-geothermometer.

Beschreibung: We applied scaled physical analogue experiments to investigate the early development of salt diapirs induced by differential sedimentary loading in an intra-continental basin realm (e.g. the North German Basin). During the experiments, deformation in a salt-analogue viscous layer was initiated by variations in the thickness of an overlying brittle material and subsequent accumulation of the brittle material further sustained deformation. A 2D optical image correlation system was used to monitor the strain evolution in the salt analogue material. Our models indicate that the formation of salt pillow structures can be achieved by minimum variations in the overburden loading. The increase of differential loading by adding synkinematic layers in the subsided areas causes not only an active piercing of the viscous layer through the brittle overburden but also an additional uplift in the adjacent areas. These elevations, named “secondary structures”, act as origins for a successive generation of diapirs. Consequently, an initial perturbation of the salt–sediment-interface can lead to a lateral propagation temporally shifted diapirs. The linkage between primary and secondary structures is reflected in the synkinematic overburden layers such as overlapping peripheral sinks in the transition zone between two diapirs. These sinks, in turn, are a frequently observable phenomenon around salt structures of the North German basin indicating that “secondary diapirism” is an underestimated process – besides regional tectonic stresses – influencing the evolution of salt structures.

Beschreibung: Calibration is a fundamental stage of the radiocarbon (14C) dating process if one is to derive meaningful calendar ages from samples’ 14C measurements. For the first time, the IntCal09 calibration curve (Reimer et al. 2009) provided an internationally ratified calibration data set across almost the complete range (0 to 50,000 cal BP) of the 14C timescale. However, only the last 12,550 cal yr of this record are composed of terrestrial data, leaving approximately three quarters of the 14C timescale necessarily calibrated via less secure, marine records (incorporating assumptions pertaining to the temporally variable “marine reservoir effect”). The predominantly annually laminated (varved) sediment profile of Lake Suigetsu, central Japan, offers an ideal opportunity to derive an extended terrestrial record of atmospheric 14C across the entire range of the method, through pairing of 14C measurements of terrestrial plant macrofossil samples (extracted from the sediment) with the independent chronology provided through counting of its annual laminations. This paper presents new data (182 14C determinations) from the upper (largely non-varved) 15 m of the Lake Suigetsu (SG06) sediment strata. These measurements provide evidence of excellent coherence between the Suigetsu 14C data and the IntCal09 calibration curve across the last ~12,000 cal yr (i.e. the portion of IntCal based entirely on terrestrial data). Such agreement demonstrates that terrestrial plant material picked from the Lake Suigetsu sediment provides a reliable archive of atmospheric 14C, and therefore supports the site as being capable of providing a high-resolution extension to the “wholly terrestrial” (i.e. non-reservoir-corrected) calibration curve beyond its present 12,550 cal BP limit.

Beschreibung: Scaled analogue experiments are used to investigate the indentation of two basement blocks into a sedimentary basin and the formation of a fold-and-thrust belt. The experimental set-up has two adjacent indenters moving in parallel with a velocity difference. The slow indenter moves with a relative velocity ranging from 40 to 80% of that of the fast one. In a first experimental series, quartz sand and low-friction glass beads represent the sediment stack and its basal detachment, respectively; silicone oil simulates a viscous detachment in the second series of experiments. The surface evolution and the spatio-temporal strain distribution are derived from particle image velocimetry (PIV). Together with the 3D finite structure derived by cutting the models at the end of each experiment, this allows the analysis of the structural evolution of the experimental wedges. Thrusting wedge development depends crucially on the relative velocity: when the slow indenter moves with a velocity of more than 55% of the fast indenter, a single curved thrust wedge develops. The wedge becomes decoupled along strike-slip zone at large velocity differences, i.e. when the slow indenter moves slower than 55% of the faster indenter. Consequently the thrust front is strongly curved at high (55–60%) and smoothly curved at low velocity differences (70–80%); in all cases curvature increases during indentation. Along the most strongly curved portion of the thrust wedge, the transfer zone rises, particle rotation and material transport oblique to the indentation direction occur directed toward the front of the slow indenter. Thrusting cycles are timed by the fast indenter and influence thrusting in front of the slow indenter. Thrusts nucleate in front of the fast indenter wedge and propagate laterally to the slow indenter front. This implies distant effects of wedge growth active hundreds of kilometres along-strike of orogens. Silicone oil as a detachment induces a low-angle wedge, which is less curved than in the glass beads experiments, and shows variable thrust vergence with fore- and back-thrusts. We compare our experimental results with the curved fold-and-thrust belts of the Tajik basin in front of the Hindu-Kush and Pamir indenters; our results are able to explain several first-order features.

Beschreibung: Comparing the organic matter (OM) composition of modern and past lake sediments contributes to the understanding of changes in lacustrine environments over time. We investigate modern plant and lake-water samples as well as modern and ancient sediment samples from the Tswaing Crater in South Africa using biomarker and stable carbon isotope analyses on bulk OM and specific biomarker compounds. The characteristic molecular markers for higher land plants (predominantly C3-type deciduous angiosperms) in Lake Tswaing are long-chain n-alkanes (n-C27−33), n-alkanols (n-C28+30), stigmasterol, β-sitosterol, β-amyrin, α-amyrin and lupeol. The C17 n-alkane, tetrahymanol, gammaceran-3-one and C29 sterols dominate the lipid fraction of autochthonously produced OM. By comparing stable carbon isotope analyses on bulk OM and the characteristic biomarkers, we follow the modern carbon cycle in the crater environment and find indications for methanotrophic activity in the lake from isotopically depleted moretene. A comparative study of core sediments reveals changes in the terrestrial (C3 versus C4) and aquatic bioproductivity and allows insights into the variability of the carbon cycle under the influence of changing climatic conditions for the time from the end of the last glacial (Termination I) to the late Holocene, ca. 14,000–2,000 calibrated years before present (years BP). The most pronounced changes occur in the aquatic realm after ca. 10,000 years BP when our results imply climate swings from more humid to more arid and after 7,500 years BP to gradually more humid conditions again, which can be related to a shift in the position of the Inter-Tropical Convergence Zone or to changes in the tropical atmosphere–ocean interaction. Long-chain alkenones (LCAs) have been identified in ancient lake sediments from Africa for the first time. They occur in samples older than 7,500 years BP and their distribution (dominance of C38 and of tri- over tetra-unsaturated LCAs) is distinctly different from other published records suggesting a to date unknown source organism.

Beschreibung: We study opportunities for CO2 sequestration in geological formations of the state North Rhine Westphalia in Germany. Simulations are performed for evaluating a potential site within the Bunter sandstone formation near the town of Minden in a depth of around 3,000 m using the numerical simulator TOUGHREACT. Our focus is on three CO2 storage mechanisms: (1) hydrodynamic trapping, (2) dissolution trapping, and (3) mineral trapping. The results show that due to buoyancy the injected CO2 phase initially migrates towards the top of the reservoir and is hydrodynamically trapped beneath the confining layer of the cap rock. Then, the CO2 spreads laterally and dissolves partially in the formation water. The dissolution of CO2 results in an increase of the density of the brine causing a downward migration until it settles after 10,000 years at the bottom of the reservoir. The simulations indicate that after 10,000 years, 15% (17 Mt) from a total of 114 Mt injected CO2 are trapped hydrodynamically, 20% (23 Mt) are trapped by dissolution, and 65% (74 Mt) are fixed in newly formed carbonates such as dawsonite, ankerite, and siderite. Within our study pressure increases near the injection well by a factor of 1.1 which is lower than the upper limit usually accepted in gas storage operations. The mineral reactions cause a net decrease of porosity and in turn a decrease of permeability down to 9% of the initial value in parts of the reservoir.

Beschreibung: Receiver functions are widely employed to detect P-to-S converted waves and are especially useful to image seismic discontinuities in the crust. In this study we used the P receiver function technique to investigate the velocity structure of the crust beneath the Northwest Zagros and Central Iran and map out the lateral variation of the Moho boundary within this area. Our dataset includes teleseismic data (Mb ≥ 5.5, epicentral distance from 30◦ to 95◦) recorded at 12 three component short-period stations of Kermanshah, Isfahan and Yazd telemetry seismic networks. Our results obtained from P receiver functions indicate clear Ps conversions at theMoho boundary. The Moho depths were firstly estimated from the delay time of the Moho converted phase relative to the direct P wave beneath each network. Then, we used the P receiver function inversion to find the properties of the Moho discontinuity such as depth and velocity contrast. Our results obtained from PRF are in good agreement with those obtained from the P receiver function modeling. We found an average Moho depth of about 42 km beneath the Northwest Zagros increasing toward the Sanandaj-Sirjan Metamorphic Zone and reaches 51 km, where two crusts (Zagros and Central Iran) are assumed to be superposed. The Moho depth decreases toward the Urmieh-Dokhtar Cenozoic volcanic belt and reaches 43 km beneath this area. We found a relatively flat Moho beneath the Central Iran where, the average crustal thickness is about 42 km. Our P receiver function modeling revealed a shear wave velocity of 3.6 km/s in the crust of Northwest Zagros and Central Iran increasing to 4.5 km/s beneath the Moho boundary. The average shear wave velocity in the crust of UDMA as SSZ is 3.6 km/s, which reaches to 4.0 km/s while in SSZ increases to 4.3 km/s beneath the Moho.

Beschreibung: On 12 September 2007, an Mw 8.4 earthquake occurred within the southern section of the Mentawai segment of the Sumatra subduction zone, where the subduction thrust had previously ruptured in 1833 and 1797. Traveltime data obtained from a temporary local seismic network, deployed between December 2007 and October 2008 to record the aftershocks of the 2007 event, was used to determine two-dimensional (2-D) and three-dimensional (3-D) velocity models of the Mentawai segment. The seismicity distribution reveals significant activity along the subduction interface and within two clusters in the overriding plate either side of the forearc basin. The downgoing slab is clearly distinguished by a dipping region of high Vp (8.0 km/s), which can be a traced to ∼50 km depth, with an increased Vp/Vs ratio (1.75 to 1.90) beneath the islands and the western side of the forearc basin, suggesting hydrated oceanic crust. Above the slab, a shallow continental Moho of less than 30 km depth can be inferred, suggesting that the intersection of the continental mantle with the subducting slab is much shallower than the downdip limit of the seismogenic zone despite localized serpentinization being present at the toe of the mantle wedge. The outer arc islands are characterized by low Vp (4.5–5.8 km/s) and high Vp/Vs (greater than 2.0), suggesting that they consist of fluid saturated sediments. The very low rigidity of the outer forearc contributed to the slow rupture of the Mw 7.7 Mentawai tsunami earthquake on 25 October 2010.

Beschreibung: Sub-diurnal variations in Earth rotation parameters as obtained from time-series of space geodetic observations contain substantial variability even after correcting for the effects of oceanic tides. These residuals are in particular apparent at frequencies of 1, 2 and 3 cycles per solar day, where atmospheric tides, principally excited by water vapor absorption and ozone heating in the middle atmosphere, are known to occur. By means of hourly data of the chemistry-climate model WACCM, the potential of atmospheric tides on the excitation of UT1 variations is re-assessed. Tidal signals are separated into migrating and non-migrating zonal waves for individual height levels. Only standing waves of wavenumber zero are found to be effective in exciting UT1 variations, which are subsequently discussed in terms of their characteristic surface pressure and vertically varying wind amplitudes.

Beschreibung: Regional ocean models are extraordinarily useful tools as complements to global models, since they work at higher spatial and temporal resolutions and parameters can be adapted to the particular conditions in the region of interest. These advantages are bought with new potential issues at the boundaries of the modelled region. At open boundaries, a global model has to provide boundary conditions such as velocity, temperature, and salinity, necessarily obtained at coarser resolution and with less accuracy. The region we focus on is the surroundings of South Africa, comprising parts of the Southern Atlantic and Southern Indian Ocean as well as the Southern Ocean down to the ice shelves of Antarctica.We attempt to better understand the dynamics of the Agulhas Current, which has been shown to have far-reaching impacts also on the Meridional Overturning Circulation and, thereby, on the world’s climate. With our study region expanded southwards, including a fraction of the Antarctic Circumpolar Current (ACC), we investigate the local current-current interactions which are conveyed by small-scale turbulences. In our analysis, we focus on sea surface height and ocean bottom pressure and the different forcing terms that influence these two variables. We configure a version of the Regional Ocean Modelling System (ROMS) to simulate ocean dynamics around South Africa, forced with ERA-Interim atmospheric data, and explore the sensitivity to various choices of boundary conditions. The horizontal resolution of 0.25 degrees - 0.25 degrees at 32 vertical levels is supposed to resolve mesoscale eddies as well as the climatologically important shedding of Agulhas rings. To show the capabilities of our model, we compare the output in terms of sea-surface heights to altimetric measurements provided by AVISO. In-situ data of ocean bottom pressure measured in the ACC path adds to the observational database. The study area is especially promising as, additionally, we can show whether the simulations of an integrated ocean bottom pressure signal correspond to the residuals in measurements of the Superconducting Gravimeter in Sutherland, South Africa.

Beschreibung: Oil-producing sills are commonly considered atypical reservoirs, although they can hold significant exploration potential. The need for a better understanding of fracture properties and petroleum system characteristics for this and similar igneous rock plays is the main motivation of our study. We explore the evolution of this play type by an analysis of the Los Cavaos oil field, located in the Malargue fold belt of the Neuquen Basin, Argentina, integrating multiscale fracture data from outcrops and subsurface. The field was created by a combination of intrusions and mild Miocene-Pliocene inversion. Production stems from thick cavity zones in naturally fractured andesitic sills emplaced in Upper Jurassic shale source rocks. Orientation patterns, fracture spacing, and length of fracture sets in the sill are consistent over several orders of magnitude. Large multiply connected and weakly cemented fractures are responsible for excellent interconnectedness in the reservoir. Fracture density is correlated with fault proximity, indicating a cogenetic evolution during active deformation. Abundant fractures in core with strike-slip to oblique striations support transpressional overprint during and after fracture formation. Although it is challenging to separate cooling from tectonic fractures, we propose two phases of fracturing, marked by a coexistence of subvertical and oblique fractures together with transpressional striae. Petrographic evidence suggests initial local oil expulsion and migration through microfractures, with opening displacements of 0.01 to 1 mm, followed by subsequent charging of the evolving intrasill cavity system as well as the bulk fracture system during cooling and mild deformation. We suggest that the observed patterns may be extrapolated to sills in similar geotectonic settings.

Beschreibung: Der Wasserspiegel des Toten Meeres sinkt rapide um durchschnittlich einen Meter pro Jahr. Dadurch hat der Salzsee bereits ein Drittel seiner Oberfläche verloren. Dies hat u. a. dramatische Auswirkungen auf die einzigartige Ökologie. Entlang der ausgedörrten Ufer bilden sich täglich neue so genannte Erdfälle oder Sinkholes, die bis zu 20 Meter tief sind. Gut 1000 dieser plötzlich einfallenden Sinkholes haben sich inzwischen an der Küstenlinie des Toten Meeres gebildet. Während der Messkampagne zum Dead Sea Integrated Research Project (DESIRE) 2007 wurde das Küstengebiet südlich von Ein Gedi zusätzlich mit einem Laser Mirror Scanner der Firma RIEGL beflogen, um entsprechende Sinkholes zu detektieren. Das Gebiet besitzt eine Ausdehnung von etwa 20 mal 4 km. Die Datenakquirierung erfolgte durch Befliegung in Nord-Süd-Richtung in 20 Streifen und einer Überdeckung von 50%. Für die Auswertung stand die Software TopPIT der Firma Trimble Geospatial zur Verfügung. Ziel der Befliegung ist neben der Berechnung eines Digitales Geländemodells (DGM) die Schaffung einer Bestandsaufnahme bestehender Sinkholes, durch die Veränderungen im Vergleich mit zukünftigen Aufnahmen aufgedeckt werden können. Zudem soll die Leistungsfähigkeit der eingesetzten Messmethode als geeignetes Verfahren nachgewiesen werden.

Beschreibung: On 2012 May 20 and 29, two damaging earthquakes with magnitudes Mw 6.1 and 5.9, respectively, struck the Emilia-Romagna region in the sedimentary Po Plain, Northern Italy, causing 26 fatalities, significant damage to historical buildings and substantial impact to the economy of the region. The earthquake sequence included four more aftershocks with Mw ≥ 5.0, all at shallow depths (about 7–9 km), with similar WNW–ESE striking reverse mechanism. The timeline of the sequence suggests significant static stress interaction between the largest events. We perform here a detailed source inversion, first adopting a point source approximation and considering pure double couple and full moment tensor source models. We compare different extended source inversion approaches for the two largest events, and find that the rupture occurred in both cases along a subhorizontal plane, dipping towards SSW. Directivity is well detected for the May 20 main shock, indicating that the rupture propagated unilaterally towards SE. Based on the focal mechanism solution, we further estimate the co-seismic static stress change induced by the May 20 event. By using the rate-and-state model and a Poissonian earthquake occurrence, we infer that the second largest event of May 29 was induced with a probability in the range 0.2–0.4. This suggests that the segment of fault was already prone to rupture. Finally, we estimate peak ground accelerations for the two main events as occurred separately or simultaneously. For the scenario involving hypothetical rupture areas of both main events, we estimate Mw = 6.3 and an increase of ground acceleration by 50 per cent. The approach we propose may help to quantify rapidly which regions are invested by a significant increase of the hazard, bearing the potential for large aftershocks or even a second main shock.

Beschreibung: We present regional-scale mass balances for 25 drainage basins of the Antarctic Ice Sheet (AIS) from satellite observations of the Gravity and Climate Experiment (GRACE) for the years 2002–2011. Satellite gravimetry estimates of the AIS mass balance are strongly influenced by mass movement in the Earth interior caused by ice advance and retreat during the last glacial cycle. Here, we develop an improved glacial-isostatic adjustment (GIA) estimate for Antarctica using newly available GPS uplift rates, allowing us to more accurately separate GIA-induced trends in the GRACE gravity fields from those caused by current imbalances of the AIS. Our revised GIA estimate is considerably lower than previous predictions, yielding an (upper) estimate of apparent mass change of 48 ± 18 Gt yr−1. Therefore, our AIS mass balance of −103 ± 23 Gt yr−1 is considerably less negative than previous GRACE estimates. The Northern Antarctic Peninsula and the Amundsen Sea Sector exhibit the largest mass loss (−25 ± 6 Gt yr−1 and −126 ± 11 Gt yr−1, respectively). In contrast, East Antarctica exhibits a slightly positive mass balance (19 ± 16 Gt yr−1), which is, however, mostly the consequence of compensating mass anomalies in Dronning Maud and Enderby Land (positive) and Wilkes and George V Land (negative) due to interannual accumulation variations. In total, 7% of the area constitute more than half of the AIS imbalance (53%), contributing −151 ± 9 Gt yr−1 to global mean sea-level change. Most of this imbalance is caused by long-term ice-dynamic speed up expected to prevail in the future.

Beschreibung: Although studies on stable-carbon isotopes in trees from temperate zones provide abundant paleoclimatic data, tropical trees are still understudied in this context. Therefore this study examined the variability of intra- and inter-annual stable-carbon isotopic pattern in several tree species from various tropical climates. The delta C-13 Values of samples of 12 broadleaved trees (seven species) from various paleotropical and neotropical sites along a climatic moisture gradient were investigated. The inter-annual variability between species and sites was studied. Further the relationship between delta C-13 and precipitation time series was analyzed. Results show that tropical tree species show a similar variability in carbon isotopic composition as temperate tree species. Significant correlations between annual precipitation and tree-ring delta C-13 time series were negative. Successful crossdating of a tree-ring delta C-13 time series highlights the potential of carbon isotope measurements for tropical tree-ring analytical studies. Tropical broadleaved trees are able to capture a carbon isotopic signal in their annual rings even under everwet conditions and show good potential for paleoclimatic research.

Beschreibung: The Athabasca region of northern Alberta, Canada, is home to deposits of oil sands containing vast amounts (~ 173 billion barrels) of heavily biodegraded petroleum. Oil sands are recovered by surface mining or by in situ steam injection. The extraction of bitumen from oil sands by caustic hot water processing results in large volumes of fluid tailings, which are stored in on-site settling basins. There the tailings undergo a compaction and dewatering process, producing a slowly densifying suspension. The released water is recycled for extraction. The fine tailings will be reclaimed as either dry or wet landscapes. [1] To produce 1 barrel of crude oil, 2 tons of oil sand and 2 - 3 tons of water (including recycled water) are required. [2] Open pit mining and the extraction of the bitumen from the oil sands create large and intense disturbances of different landscapes. The area currently disturbed by mining operations covers about 530 km2 and the area of tailing ponds surpasses 130 km2. An issue of increasing importance is the land remediation and reclamation of oil sand areas in Canada and the reconstruction of these disturbed landscapes back to working ecosystems similar to those existing prior to mining operations. An important issue in this context is the identification of oil sand-derived organic compounds in the tailings, their environmental behaviour and the resulting chances and limitations with respect to land reclamation. Furthermore the biodegradation processes that occur in the tailings and that could lead to a decrease in hazardous organic compounds are important challenges, which need to be investigated. This presentation will give a detailed overview of our compositional and quantitative characterisation of the organic matter in oil sand, unprocessed and processed mature fine tailings samples as well as in tailings sands used as part of land reclamation. The analytical characterisation is based on the extraction of the soluble organic matter, its subsequent separation into asphaltenes, aliphatic hydrocarbons, aromatic hydrocarbons, neutral nitrogen, sulphur, oxygen (NSO) compounds and carboxylic acids. The asphaltene fractions are analysed using pyrolysis-GC, all other fractions are analysed by GC-MS. Additionally Fourier transform-ion cyclotron resonance-mass spectrometry (FT-ICR-MS) is used to study the chemical composition of the samples on the molecular level using different ionisation methods.

Beschreibung: This study reveals the first analyses of the composition and activity of the microbial community of a saline CO2 storage aquifer. Microbial monitoring during CO2 injection has been reported. By using fluorescence in situ hybridisation (FISH), we have shown that the microbial community was strongly influenced by the CO2 injection. Before CO2 arrival, up to 6 × 106 cells ml−1 were detected by DAPI staining at a depth of 647 m below the surface. The microbial community was dominated by the domain Bacteria that represented approximately 60% to 90% of the total cell number, with Proteobacteria and Firmicutes as the most abundant phyla comprising up to 47% and 45% of the entire population, respectively. Both the total cell counts as well as the counts of the specific physiological groups revealed quantitative and qualitative changes after CO2 arrival. Our study revealed temporal outcompetition of sulphate-reducing bacteria by methanogenic archaea. In addition, an enhanced activity of the microbial population after five months CO2 storage indicated that the bacterial community was able to adapt to the extreme conditions of the deep biosphere and to the extreme changes of these atypical conditions.

Beschreibung: In order to assess the importance of different pollution sources for the increase in element concentration and accumulation, historical changes in selected elements were studied in the annually laminated sediment of Lake Korttajärvi in Central Finland (62°20′N; 25°41′E). The sediment chronology based on varve counting (256 BC to AD 2005) provided a unique opportunity to explore and date signals of metal emissions, including the ancient metallurgical activities of the Roman Empire at the beginning of the Current Era. Records of this kind are mostly lacking in Finland and northernmost Europe. The stratigraphic sequence of element concentrations did not reflect any major changes in the lake, but changes in element accumulation rates provided distinct pollution signals caused by airborne fallout, catchment erosion, and to some extent municipal wastewater loading. The maximum bulk sedimentation recorded in the twentieth century was 11-fold and organic sedimentation 4-fold higher than the mean background sedimentation rate (256 BC to AD 1019). The increase in the accumulation rates of the majority of the elements, such as Cd, Sn, Pb, Si, Ni, B, Cu, Zn, Sr, Na, K, Sb, Ca, Cr, U and Mg, in descending order, was at least equal to that of bulk sedimentation or much greater, especially for Cd, Sn, and Pb. Changes in the accumulation of Co, Fe, Mn, Mo and As were small and mainly followed those of organic sedimentation. The earliest pollution signals were those of Pb recorded in AD 1055–1141. A weak signal of Pb pollution from the Roman Era was detected in metal concentrations, but this could not be confirmed by the accumulation rate data for Pb.

Beschreibung: Observations of the ocean-induced magnetic field by the CHAMP magnetic space mission have the potential to be used as a constraint when examining ocean dynamics. This has initiated theoretical studies on the prediction of the poloidal magnetic field induced by the horizontal ocean-circulation flow. This study deals with the computation and analysis of the toroidal magnetic field induced by the tidal ocean-circulation flow on the background of the main Earth’s geomagnetic field. Since the induced toroidal magnetic field cannot be modelled by the single-layer approximation model used to predict the poloidal magnetic field, we treat the ocean as a spherical layer of a finite thickness and compute the toroidal magnetic field by a matrix-propagator technique with a source of electric currents in the ocean layer. Our numerical simulations based on the OMCT tidal ocean velocities show that the induced toroidal magnetic field is extremely sensitive to the vertical gradient of horizontal ocean flow. The larger this gradient, the stronger the induced toroidal magnetic field. Specifically, its magnitudes vary from 10−2 nT for barotropic flow to several nT for baroclinic flow. We show that the induced toroidal magnetic field generated by M2 tidal forcing is comparable in amplitude to the induced poloidal part of the field. The induced toroidal and poloidal magnetic fields differ, however, in their spatial behaviour.

Beschreibung: Time variable gravity fields, reflecting variations of mass distribution in the system Earth is one of the key parameters to understand the changing Earth. Mass variations are caused either by redistribution of mass in, on or above the Earth's surface or by geophysical processes in the Earth's interior. The first set of observations of monthly variations of the Earth gravity field was provided by the US/German GRACE satellite mission beginning in 2002. This mission is still providing valuable information to the science community. However, as GRACE has outlived its expected lifetime, the geoscience community is currently seeking successor missions in order to maintain the long time series of climate change that was begun by GRACE. Several studies on science requirements and technical feasibility have been conducted in the recent years. These studies required a realistic model of the time variable gravity field in order to perform simulation studies on sensitivity of satellites and their instrumentation. This was the primary reason for the European Space Agency (ESA) to initiate a study on ''Monitoring and Modelling individual Sources of Mass Distribution and Transport in the Earth System by Means of Satellites''. The goal of this interdisciplinary study was to create as realistic as possible simulated time variable gravity fields based on coupled geophysical models, which could be used in the simulation processes in a controlled environment. For this purpose global atmosphere, ocean, continental hydrology and ice models were used. The coupling was performed by using consistent forcing throughout the models and by including water flow between the different domains of the Earth system. In addition gravity field changes due to solid Earth processes like continuous glacial isostatic adjustment (GIA) and a sudden earthquake with co-seismic and post-seismic signals were modelled. All individual model results were combined and converted to gravity field spherical harmonic series, which is the quantity commonly used to describe the Earth's global gravity field. The result of this study is a twelve-year time-series of 6-hourly time variable gravity field spherical harmonics up to degree and order 180 corresponding to a global spatial resolution of 1 degree in latitude and longitude. In this paper, we outline the input data sets and the process of combining these data sets into a coherent model of temporal gravity field changes. The resulting time series was used in some follow-on studies and is available to anybody interested.

Beschreibung: The weathering and erosion processes that produce and destroy regolith are widely recognized to be positively correlated across diverse landscapes. However, conceptual and numerical models predict some limits to this relationship that remain largely untested. Using new global data compilations of soil production and weathering rates from cosmogenic nuclides and silicate weathering fluxes from global rivers, we show that the weathering-erosion relationship is capped by certain ‘speed limits’. We estimate a soil production speed limit of between 320 to 450 t km−2 yr−1 and the associated weathering rate speed limit of roughly 150 t km−2 yr−1. These limits appear to be valid for a range of lithologies, and also extend to mountain belts, where soil cover is not continuous and erosion rates outpace soil production. We argue that the presence of soil and regolith is a requirement for high weathering fluxes from a landscape, and that rapidly eroding, active mountain belts are not the most efficient sites for weathering.

Beschreibung: Im Rahmen der Klimapolitik wird die Lagerung von Kohlenstoffdioxid in tiefen Gesteinsschichten als eine potenzielle Maßnahme für die Reduktion der Treibhausgasemissionen und gegen die globale Klimaerwärmung gesehen. Mit dieser entwicklungsfähigen Technologie sind aber auch Ängste der Bevölkerung in den geplanten Zielgebieten verbunden: Ist eine langfristige und sichere Speicherung ohne Gefährdung des Menschen und der Umwelt möglich? Wissenschaft und Technik, unter besonderer Berücksichtigung der Erfahrungen vom Forschungsstandort Ketzin, helfen diese Frage zu beantworten.

Beschreibung: In the framework of the Dead Sea Integrated Research project (DESIRE), 59 seismological stations were deployed in the region of the Dead Sea Basin. Twenty of these stations recorded data of sufficiently high quality between May and September 2007 to be used for ambient seismic noise analysis. Empirical Green’s functions are extracted from cross-correlations of long term recordings. These functions are dominated by Rayleigh waves, whose group velocities can be measured in the frequency range from 0.1 to 0.5 Hz. Analysis of positive and negative correlation lags of the Green’s functions makes it possible to identify the direction of the source of the incoming energy. Signals with frequencies higher than 0.2 Hz originate from the Mediterranean Sea, while low frequencies arrive from the direction of the Red Sea. Travel times of the extracted Rayleigh waves were measured between station pairs for different frequencies, and tomographically inverted to provide independent velocity models. Four such 2D models were computed for a set of frequencies, all corresponding to different sampling depths, and thus together giving an indication of the velocity variations in 3D extending to a depth of 10 km. The results show low velocities in the Dead Sea Basin, consistent with previous studies suggesting up to 8 km of recent sedimentary infill in the Basin. The complex structure of the western margin of the Basin is also observed, with sedimentary infill present to depths not exceeding 5 km west of the southern part of the Dead Sea. The high velocities associated with the Lisan salt diapir are also observed down to a depth of ~5 km. The reliability of the results is confirmed by checkerboard recovery tests.

Beschreibung: Many studies on ecosystem resilience often lack sufficiently long time scales to determine potential cycles of landscape response. In this paper we review some examples on how palaeoecology has provided an important aid to modern ecology in understanding ecosystem resilience. We focus some of these ideas on two Holocene sites from Southern Spain (Zoñar and Gádor) where current plant diversity is very high. Both sites presented resilient pattern at centennial and millennial time scales with several stable phases. Vegetation in Zoñar proved to be very sensitive to environmental changes, especially moisture availability while forest in Gádor responded elastically to fire and drought to a threshold level when the forest recede to a more open landscape. We conclude that any serious attempt to understand ecosystem resilience should include the long-term perspective.