ALBERT

All Library Books, journals and Electronic Records Telegrafenberg

X
feed icon rss

Your email was sent successfully. Check your inbox.

An error occurred while sending the email. Please try again.

Proceed reservation?

Export
Filter
  • General Chemistry  (5,879)
  • Inorganic Chemistry  (3,993)
  • Fisheries
  • Semiconductors II: surfaces, interfaces, microstructures, and related topics
  • 2010-2014  (2,105)
  • 1985-1989  (8,503)
  • 1945-1949  (1,372)
Collection
Keywords
Publisher
Years
Year
  • 1
    facet.materialart.
    Unknown
    Ctenochaetus marginatus (Valenciennes) (Pisces: Acanthuridae) en la Isla de Gorgona: Primer registro del género para el Pacífico colombiano (2010)
    Santa Marta (Colombia), INVEMAR
    Details
    Publication Date: 2021-05-19
    Description: The genus Ctenochaetus is reportad in the waters of the Colombian Pacific based on two specimens of C. marginatus (Valenciennes) collected in 1993 at Gorgona Island (2°59' N, 78° 12' W). These specimens differ inseveral morphometric characteristics from thosepreviously examined. Such differences appear to be an artifact of the small number of specimens formerly examined and the consequent narrow ranges reportad. We suggest that temperature variability affects the distribution of C. marginatus in the tropical eastern Pacific.
    Description: El género es Ctenochaetus reportad en las aguas del Pacífico colombiano a partir de dos especímenes de C. marginatus (Valenciennes) recogidos en 1993 en la Isla Gorgona (2 ° 59 'N, 78 ° 12' W). Estos ejemplares difieren inseveral características morfométricas de thosepreviously examinados. Estas diferencias parecen ser un artefacto del pequeño número de muestras examinadas anteriormente y reportad los rangos estrechos consecuente. Sugerimos que la variabilidad de la temperatura afecta la distribución de marginatus C en el Pacífico tropical oriental.
    Description: Published
    Keywords: Fisheries ; Fisheries
    Repository Name: AquaDocs
    Type: Journal Contribution
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
    PAPER (OA)
  • 2
    facet.materialart.
    Unknown
    Going against the flow: Effects of river damming in Cuban fisheries (2013)
    Details
    Publication Date: 2021-05-19
    Description: Over the last decade eutrophication of freshwater artificial reservoirs in Cuba occurred in parallel to oligotrophication of estuarine and coastal waters. These two processes influenced both freshwater and marine fisheries. A dramatic shift in species composition in freshwater fisheries has occurred, from dominance by cichlids (tilapia) to dominance by cyprinids. The high fishery yield from some reservoirs, and shift in species composition, seems related to progressive eutrophication of reservoirs by nutrient subsidies from different anthropogenic activities; particular those related to the size of urban areas within their watersheds. On the other hand, marine landings of estuarine-dependent species declined more significantly than for other groups associated with seagrass beds–coral reefs and oceanic waters. The ratio between catches of estuarine-dependent species and those associated with seagrass beds and coral reefs, decreased significantly over the last 20 years. The decrease in landings was more evident in typical estuarine species, such as shrimps (Litopenaeus schmitti and Farfantopenaeus notialis), mangrove oyster (Crassostrea rhizophorae) and mullets (Mugil spp.). River damming increased during the same period and is significantly correlated with these decreases. It is hypothesized that two different processes acted synergistically, leading to dramatic decreases of several orders of magnitude, in the catches of estuarine species over the last decade: the trapping of nutrients and sediments by river damming, and a drastic reduction in nutrient inputs from land-based sources due to reduced fertilizer use. These are postulated to have affected not only estuarine resources, but also the whole coastal ecosystem.
    Description: Durante la última década, la eutrofización de los embalses artificiales de agua dulce en Cuba se produjo en paralelo a oligotrophication de estuarios y costeras aguas. Estos dos procesos de influencia de agua dulce y la pesca marina. Un cambio dramático en la composición de las especies en la pesca de agua dulce se ha producido, de la dominación de los cíclidos (tilapia) a la dominación de ciprínidos. La alta producción de la pesca de algunos embalses, y el cambio en las especies composición, parece relacionada con la progresiva eutrofización de los embalses de las subvenciones de nutrientes de diferentes actividades antropogénicas, especialmente las relacionado con el tamaño de las zonas urbanas dentro de sus cuencas. Por otro lado, los desembarques de especies marinas de estuario-dependientes disminuyeron significativamente más que para otros grupos asociados con algas marinas Los arrecifes de coral-camas y las aguas oceánicas. La relación entre las capturas de las especies que dependen de los estuarios y las asociadas a las praderas marinas y Los arrecifes de coral, se redujo significativamente en los últimos 20 años. La disminución en los desembarques fue más evidente en especies típicas de estuarios, tales como camarones (Litopenaeus schmitti y Farfantopenaeus notialis), ostra de mangle (Crassostrea rhizophorae) y la lisa (Mugil spp.). El represamiento del Río aumentó durante el mismo período y se correlaciona significativamente con estas disminuciones. Se planteó la hipótesis de que dos procesos diferentes actúan de forma sinérgica, que conduce a una disminución drástica de varios órdenes de magnitud, en las capturas de las especies de estuario en la última década: la captura de nutrientes y sedimentos por represas río, y una reducción drástica de los aportes de nutrientes de fuentes terrestres, debido a la reducción del uso de fertilizantes. Se postula que han afectado no sólo a los recursos estuarinos, sino también todo el ecosistema costero.
    Description: Published
    Description: ríos
    Description: impactos antropogénicos
    Keywords: river ; Fisheries ; Eutrophication
    Repository Name: AquaDocs
    Type: Journal Contribution , Refereed , Article
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
    PAPER (OA)
  • 3
    facet.materialart.
    Unknown
    Capturas de sierras, serruchos y pintadas con redes de enmalles (2013)
    Details
    Publication Date: 2021-05-19
    Description: Se muestra la evolución de las capturas de las sierras y pintadas, se describen las 3 maneras en que las especies pueden quedar atrapadas en la redes de enmalles, así como también los tipos de redes (deriva, media agua y de fondo).
    Description: Published
    Description: Scomberomorus regalis
    Description: Scomberomorus maculatus
    Description: Scomberomorus cavalla
    Description: spanish mackerel
    Description: king mackerel
    Description: painted mackerel
    Description: enmalle
    Description: arte de pesca
    Keywords: Fisheries ; Artisanal fishing
    Repository Name: AquaDocs
    Type: Journal Contribution , Refereed , Article
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
    PAPER (OA)
  • 4
    facet.materialart.
    Unknown
    Las pesquerías de lisas y mojarras en lagunas costeras. (2013)
    Details
    Publication Date: 2021-05-19
    Description: Published
    Description: Mugil curema
    Description: Mugil liza
    Description: Mugil cephalus
    Description: Gerres cinereus
    Description: patao
    Description: coastal lagoons
    Keywords: Mullet fisheries ; Fisheries
    Repository Name: AquaDocs
    Type: Journal Contribution , Refereed , Article
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
    PAPER (OA)
  • 5
    facet.materialart.
    Unknown
    Tensores naturales y antrópicos al norte de Villa Clara, Cuba; efectos en la producción de ostión (crassostrea rhizophorae, Guilding, 1828) (2010)
    Details
    Publication Date: 2021-05-19
    Description: Production of mangrove oyster (Crassostrea rhizophorae Guilding, 1828), north of Villa Clara, Cuba Province, tends to decline since 1980, accentuating from 2003 on. Despite regulations to protect the resource, minimum legal size and catch closures, the year 2008 presents the landing smaller volumes of the past 50 years. An analysis of the variability of catches in relation to natural and human factors, allows for precipitating causes of low productivity of this fishery resource; between the most representatives are expanding storage capacity of river water, salinity increment, the increase in frequency and intensity of hurricanes and the mismanagement of the extraction of oyster.
    Description: La producción de ostión de mangle (Crassostrea rhizophorae, Guilding, 1828), al norte de la provincia de Villa Clara, Cuba, tiende a la disminución desde de 1980, acentuándose a partir del año 2003. A pesar de regulaciones para la protección del recurso, talla mínima legal y vedas de captura, el año 2008 presenta los menores volúmenes de desembarque de los últimos 50 años. Un análisis de la variabilidad de las capturas, en relación con factores naturales y antrópicos, permite establecer causas desencadenantes de la baja productividad de este recurso pesquero; las más representativas son, la ampliación en la capacidad de embalse de aguas fluviales, aumentos de la salinidad, el incremento en la frecuencia e intensidad de los huracanes y un manejo inadecuado de la actividad extractiva de ostión.
    Description: Crassostrea rhizophorae, Cuba
    Keywords: Fisheries ; Environmental effects ; Fisheries
    Repository Name: AquaDocs
    Type: Preprint
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
    PAPER (OA)
  • 6
    facet.materialart.
    Unknown
    Caso de Estudio No. 2: Estado de la pesquería de la langosta espinosa (Panulirus argus) y su relación con factores ambientales y antrópicos en Cuba. (2011)
    Instituto de Oceanología | Cuba
    Details
    Publication Date: 2021-05-19
    Description: Las capturas de langosta espinosa Panulirus argus (Latreille, 1804) en Cuba alcanzaron sus mayores volúmenes en la década de 1980 con un promedio anual de 11565 ton. En la década de 1990, la captura descendió a un promedio de 9327 ton, lo cual se ha visto agudizado entre 2000 y 2007 con un promedio de 6262 ton y una mayor variabilidad de las capturas, a pesar de un perfeccionamiento del sistema de manejo pesquero dado por: la disminución del esfuerzo pesquero y de la tasa de mortalidad por pesca desde 1999, el aumento del período de veda desde 2001 y el incremento gradual de la talla mínima legal de captura a partir de 2004. Los análisis más recientes sobre el estado de esta pesquería fueron presentados en el Quinto Taller Regional sobre la Evaluación y la Ordenación de la Langosta Común del Caribe en septiembre 2006 (Puga et al, 2006; FAO, 2007), donde se reconoció por la comunidad científica especializada que la pesquería de langosta cubana se encontraba bien manejada y plenamente explotada (no sobre- explotada) y se concluyó que además de la mortalidad por pesca, otros factores ajenos al sector pesquero estaban produciendo afectaciones en la abundancia del recurso, al causar daños al hábitat 1 en zonas de cría, influyendo negativamente por esta vía sobre el reclutamiento y la producción de langostas. Entre estos aspectos para Cuba se señalaron: la mayor frecuencia e intensidad de huracanes durante el último decenio, el desarrollo de las zonas costeras, la construcción de presas en las cuencas de captación de los ríos y de carreteras en el Archipiélago Sabana-Camagüey comunicando la isla principal con los cayos y los cayos entre si (pedraplenes).
    Description: Published
    Keywords: Fisheries ; Lobster fisheries ; Fisheries ; Environment management ; Recruitment ; Coastal zone management
    Repository Name: AquaDocs
    Type: Book Section
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
    PAPER (OA)
  • 7
    facet.materialart.
    Unknown
    Fauna asociada a la pesca del mero Epinephelus Morio (serranidae: pisces) con palangre de fondo en el Banco de Campeche, México. (2010)
    Details
    Publication Date: 2021-05-19
    Description: Se efectúa un estudio de la fauna acompañante del Mero, Epinephelus morio, en la pesquería con palangre de fondo del Banco de Campeche, México, durante el periodo 1987-2009. En la investigación se consideró información de 32 cruceros de investigación realizados en la etapa como parte del convenio pesquero firmado por Cuba y México para la evaluación sistemática del recurso. Se determinó la composición por especie y talla de las capturas, sus variaciones en la abundancia relativa, estructura de tallas, así como el índice de diversidad de Brillouin, la riqueza de especies (Margalef, 1980), la dominancia numérica y la constancia, estas ultimas valoradas según el esquema propuesto por Bodenheimer (1955). Se encontró que la fauna acompáñate de E. morio esta representada por 69 especies, agrupadas en 3 clases y 12 órdenes. De ellos, el orden mejor representado lo constituyó Perciformes con las familias Serranidae, Lutjanidae, Scombridae, Carangidae y Haemulidae como las más abundantes en número. Dentro de estas, dominaron las especies L. campechanus y O. chrysurus, apreciándose que las entidades mejor representadas son, L. campechanus (100%), O. chrysurus (96,87%) y M. bonaci (73,2%). Los largos medios observados se encontraron por encima de las tallas de primera maduración reportadas en la literatura. Sólo E. nigritus y L. analis presentaron individuos inmaduros. Se reportan tallas máximas superiores a las reportadas en la bibliografía en M. interstitiaslis (150cm), M. bonací (155cm) y E. nigritus (125cm). Se determinó que el rendimiento (cpue) y la diversidad de la fauna acompañante poseen una relación inversa con la disminución de la biomasa de mero. Por su parte, la diversidad y riqueza de especie presentaron sus mayores valores concordando con las temporadas de lluvias.
    Description: Mero Epinephelus morio, fauna acompañante, Banco de Campeche, México,
    Keywords: Fisheries ; Fauna ; Fisheries ; Fauna
    Repository Name: AquaDocs
    Type: Preprint
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
    PAPER (OA)
  • 8
    facet.materialart.
    Unknown
    Monitoreo anual de la pesquería del cobo (eustrombus gigas) en Caibarién, cayería norte de Villa Clara en el 2011. (2012)
    Details
    Publication Date: 2021-05-19
    Description: Se presentan los resultados de monitoreo de las poblaciones comerciales de cobo en el área comprendida entre los cayos El Cabezo y Boca de Sagua (220 49`N--230 04`N y los 790 35W—800 07´ `W), plataforma Norte de la Provincia de Villa Clara. A partir de los resultados de las densidades de individuos como índice de la abundancia y la estructura poblacional encontrada, se propone un potencial de captura de 104 TM (peso entero). Además, se definen las medidas de manejo para el uso sostenible del recurso Eustrombus gigas en esta zona. El aprovechamiento en carne desembarcada (Eviscerada y sin manto) para individuos adultos con talla comercial se obtiene por un factor de 0,074 (7,4%) del peso entero, que representa 7,7 TM. Se excluye el área protegida desde Las Picúas hasta Cayo Cristo.
    Description: cobo (Eustrombus gigas), Caibarién, Villa Clara
    Keywords: Monitoring ; Fisheries management ; Fisheries
    Repository Name: AquaDocs
    Type: Preprint
    Format: 4
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
    PAPER (OA)
  • 9
    facet.materialart.
    Unknown
    Etude environnementale et sociale du PRAO (Cap Vert, Sierra Léone, Libéria, Sénégal) (2010)
    Details
    Publication Date: 2021-05-19
    Description: La Commission Sous Régionale des Pêches (CSRP), qui est un organisme intergouvernemental de coopération halieutique dont l’objectif global est l’harmonisation à long terme, des politiques des pays membres en matière de préservation, de conservation et d'exploitation durable de leurs ressources halieutiques et le renforcement de leur coopération au profit du bien-être de leurs populations respectives, a obtenu par l’intermédiaire de la Banque mondiale, un Don du Fonds pour l’Environnement Mondial (FEM) et du Gouvernement du Japon, pour la préparation d’un Projet Régional des Pêches en Afrique de l’Ouest (PRAO) pour trouver une solution à la problématique susvisée. Ce projet implique 9 pays côtiers: la Mauritanie, le Cap Vert, le Sénégal, la Gambie, la Guinée Bissau, la Guinée, le Sierra Léone (Etats membres de la CSRP), ainsi que le Libéria et le Ghana. Le PRAO comprend trois composantes : (1) Bonne Gouvernance et Gestion Durable des Pêches ; (2) Réduction de la Pêche Illicite ; (3) Augmentation de la Contribution des Ressources Halieutiques dans les Economies Locales (incluant la réalisation d’infrastructures et équipements dans les pêcheries). Certes, les activités prévues dans le cadre du PRAO sont pressenties pour contribuer au développement du secteur de la pêche dans les pays ciblés et apporter des bénéfices aux populations locales. Toutefois, elles pourraient engendrer dans certains cas des effets négatifs aux niveaux environnemental et social (notamment celles prévues dans la composante 3), si des mesures adéquates ne sont pas prises au préalable. Afin de minimiser ces effets défavorables, il a été requis l’élaboration de la présente Evaluation Environnementale et Sociale (EES).
    Description: Commission Sous Régionale des Pêches (CSRP)
    Description: Published
    Description: ressource marine, ressource côtière, politique de pêhce, environnement, qualité des produits, pollution, gestion des pêches,aire marine protégée
    Keywords: Marine resources ; Fisheries ; Fishery management ; Coastal fisheries ; Quality assurance ; Environment management ; Marine resources ; Fisheries ; Fishery management ; Coastal fisheries ; Coastal zone ; Fishery regulations ; Fishery economics ; Marine pollution ; Quality control ; Illegal fishing ; Fishery organizations ; Quality assurance
    Repository Name: AquaDocs
    Type: Report
    Format: 111
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
    PAPER (OA)
  • 10
    facet.materialart.
    Unknown
    Suivi de l’activité de la pêche hauturière dans le gouvernorat de Medenine (sud de la Tunisie). (2013)
    INSTM, Institut national des sciences et technologies de la mer | Tunis
    Details
    Publication Date: 2021-05-19
    Description: Ce travail représente une contribution à l'étude de l'activité de pêche hauturière dans le gouvernorat de Médenine, particulièrement, au niveau du port de Zarzis ; durant la période (juin 2005-juin 2006). Il consiste à réaliser, grâce à des enquêtes menées au port, deux types d'analyses : une analyse quantitative afin de déterminer les débarquements saisonniers moyens des espèces les plus débarquées par la pêche hauturière et une analyse qualitative pour établir les structures démographiques des espèces les plus exploitées dans la région. Les résultats obtenus ont montré que, durant la période d'étude, les principales espèces débarquées par la pêche hauturière sont la sardinelle, le maquereau, le saurel, le rouget blanc, le pageot, la thonine, la seiche et la crevette royale. En examinant les débarquements saisonniers moyens des espèces les plus débarquées par type de pêche, nous avons remarqué que deux ou trois espèces dominent pour chaque saison. De plus, l'analyse des structures démographique des apports a montré que la majorité des individus débarqués sont matures, à l’exception du maquereau dont les captures sont constituées d’individus immatures, surtout pendant les saisons d’été et d’automne.
    Description: This work represents a contribution to the study of the offshore fishing activity in the governorate of Medenine, particularly at the port of Zarzis, during the period (june 2005-june 2006. It is to realize, through surveys conducted at the port, two types of analyzes: a quantitative analysis to determine the average seasonal landings of most landed species by fishing offshore units and qualitative analysis to determine the demographic structure of the most exploited species in the region. The obtained results showed that during the period of study, the main landed species by offshore fishing are sardinella, mackerel, horse mackerel, white mullet, sea bream, skipjack tuna, cuttlefish and the caramote prawn. By examining the average seasonal landings of the most landed species, we noticed that, for each season, two or three species dominate. Furthermore, analysis of demographic structures of the landings showed that the majority of landed individuals are mature, with the exception of mackerel catches which are composed of immature individuals, especially during the seasons of summer and autumn.
    Description: Published
    Description: analyse qualitative
    Description: pêche hauturière
    Keywords: Quality analysis ; Offshore ; Fisheries
    Repository Name: AquaDocs
    Type: Proceedings Paper , Refereed , Meeting abstract
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
    PAPER (OA)
  • 11
    facet.materialart.
    Unknown
    Técnicas de elaboración y "Curado" de cuerdas de Currican para la pesca en Taganga/Santa Marta, Colombia (2011)
    Santa Marta (Colombia), INVEMAR
    Details
    Publication Date: 2021-05-19
    Description: El presente artículo da una descripción detallada de la elaboración y del "curado" de cuerdas de curricán, utilizadas anteriormente para la pesca en Taganga, un pueblo pescador en la costa norte de Colombia. Antes del "curado", estas cuerdas de fibras de algodón y de fabricación industrial, eran o destorcidas o torcidas a mano nuevamente, o tensionadas y envueltas con una cuerda más delgada del mismo material. El "curado" que siguió a estas operaciones se efectuó tanto en una cocción de corteza de las raíces zanconas de mangle, y/o por medio de un frote de estas cuerdas con los hypocotylos del mismo árbol (Rhizophora manglr). Por medio de las técnicas aquí descritas, los pescadores aspiraban a aumentar la resistencia de sus aparejos de pesca en el agua de mar.
    Description: The present paper gives a detailed description of the elaboration and curing of curricán Unes, formerly used as fishing lines in Taganga, a small fishing village on the northem coast of Colombia. These lines, made of cotton fibers and produced industrially, were disassembled and then retwisted by hand, or tightened and then carefully covered with a thinner string of the same material. The curing {"curado") that followed these operations was achieved by immersion of the lines into a boiled infusión of the bark of the prop roots of mangroves (Rhizophora mangle) and/or a rinsing with the hypocotyls of the same trees. By means of the techniques mentioned, the fishermen sought to improve the resistance of their fishing gear to sea water.
    Description: Published
    Keywords: Fisheries ; Fishing ; Gear construction ; Fisheries ; Fishing
    Repository Name: AquaDocs
    Type: Journal Contribution
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
    PAPER (OA)
  • 12
    facet.materialart.
    Unknown
    Observations on the biology of the redlip Blenny, Ophioblennius atlanticus (Pisces: Blenniidae) on the Colombian Coast of the Caribbean (2011)
    Santa Marta (Colombia), INVEMAR
    Details
    Publication Date: 2021-05-19
    Description: During a 3 week study, a total of 55 individuals of the redlip blenny (Ophioblennius atlanticus) were observed for at least two 15-minute periods, and several for ten of such periods. The sizes of their territories were estimated, the color pattern of each specimen an intra and interspecific interactions were recorded. The mean territory size of the redlip blenny in the study area appeared to be greater than that of these blennies studied in Curacao and Barbados by NURSALL (1977), the difference reflecting perhaps different methods of identifying the territories or a lower density of O. atlanticus in the Santa Marta área. Territories did not appear to be as consistently defended at the study area as at Barbados/Curacao and our impression ¡s that individuals holding large territories are less likely to defend their borders. It seems possible that light colored individuals are protected by their coloration from attack by dark colored territory owners. In territorial defense the redlip blennies grabbed each other tighthy by the mouth and struggled in this position repeatedly for about 15 seconds. Interspecific antagonism was common in the present study, the redlip blennics defended their territory frequently against Eupomacentrus dorsopunicans or E. partitus.
    Description: Durante un estudio de tres semanas, un total de 5 i individuos del bií'nido Ojih'toblcnnius atlnniicur. fueron observados por lo menos durante dos períodos de 1 í minutos para cada individuo y en algunos casos hasta por 10 de estos periodos. Se estimó el área de sus respectivos territorios y se tomó notí de los patrones de coloración de cada espécimen y de las relaciones intra e interespecificas de ellos. El tamaño promedio del territorio de estos blénidos resultó ser mayor que el de los respectivos territorios estudiados por NURSALL (1977) en Curacao y Barbados. Esta diferencia posiblemente se debe a un método diferente de definir los territorios o refleja una densidad menor de la población de O. aílanticus en Santa Marta, Los territorios del área fueron defendidos con menor intensidad a como lo fueron los de Barbados/ Curacao y es nuestra impresión que individuos ocupando un territorio extenso tienden a defender sus límites en menor grado. El color claro de algunos individuos probablemente los protege de agresiones por parte de individuos de color oscuro. En el acto de defensa territorial intraespecífica, los blénidos se agarran por sus bocas y se sacuden mutuamente durante aproximadamente 15 segundos , pudiéndose repetir esti varias veces. Con frecuencia se observarondefensas de los territorios dirigidas hacia los peces doncella Eupomacentrus dorsopunicnas y E. partitus.
    Description: Published
    Keywords: Fisheries ; Biology ; Fisheries ; Biology
    Repository Name: AquaDocs
    Type: Journal Contribution
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
    PAPER (OA)
  • 13
    facet.materialart.
    Unknown
    Primer registro de albinismo en la Familia Muraenesocidae (Pisces: Anguilliformes), Cynoponticus savanna (Bancroft) (2011)
    Santa Marta (Colombia), INVEMAR
    Details
    Publication Date: 2021-05-19
    Description: Se registra por primera vez el fenómeno de albinismo en la familia de peces Muraenesocidae, con base en dos ejemplares de Cynoponticits savanna capturados en la Península de la Guajira. Caribe colombiano.
    Description: The phenomenom of albinism is reported for the first time in che fish family Muraenesocidae. Two anomalous individuals of Cynoponticus savanna were collected from the Guajira Península colombian Caribbean.
    Description: Published
    Keywords: Fisheries ; Albinism ; Fisheries ; Albinism ; New records
    Repository Name: AquaDocs
    Type: Journal Contribution
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
    PAPER (OA)
  • 14
    facet.materialart.
    Unknown
    Las pesquerías con nasas de placer, tranques y chinchorros (2013)
    Details
    Publication Date: 2021-05-19
    Description: Se muestran las capturas históricas de la biajaiba (1935-2000), la evolución de las capturas del pargo (una de las especies de mayor interés económico en Cuba). Se evalúa la utilización de éstas artes de pesca en especies comerciales y su implicación con daños al medio ambiente. Se tiene en cuenta que los pargos criollos, la biajaiba y el caballerote representan el 20 % de las capturas.
    Description: Published
    Description: pesquería artesanal
    Description: cubera
    Description: cherna criolla
    Description: pesca del alto
    Description: pargo
    Description: rabirrubia
    Description: caballerote
    Description: biajaiba
    Keywords: Fisheries ; Artisanal fishing
    Repository Name: AquaDocs
    Type: Journal Contribution , Non-Refereed , Article
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
    PAPER (OA)
  • 15
    facet.materialart.
    Unknown
    The condition factor of Mugil incilis Hancock (Pisces: Mugilidae) and its seasonal changes in the Cienaga Grande de Santa Marta (Colombia) (2011)
    Santa Marta (Colombia), INVEMAR
    Details
    Publication Date: 2021-05-19
    Description: Se ha estudiado la variación anual de la condición de la lisa Mugil incilis Hancock en la Ciénaga Grande de Santa Marta (CGSM), la mayor laguna costera del Caribe Colombiano, haciendo énfasis en la influencia ejercida por factores ambientales como la salinidad, la temperatura y la transparencia de las aguas sobre la condición de esta especie de Mugilidae. Las diferencias estacionales observadas en la condición de M. incilis están evidentemente relacionadas con su desarrollo gonadal y dependen de la disponibilidad de alimento. La dieta de M. incilis se basa en detritos y su suministro de alimento parece ser muy afectado por el aporte fluvial a la CGSM, el cual es también responsable de los cambios en la salinidad de la laguna, esto explica la relación inversa (r = -0.82) hallada entre la salinidad y la condición de M. incilis expresada por C = 0.9949 - 0.0057 S(°/oo). La variación anual de la salinidad sigue un patrón rítmico de cambios estacionales, no precisamente "in situ", sino en regiones continentales distantes: las cabeceras de los tributarios de la CGSM. Estas lisas desovan en aguas del Caribe adyacente a la CGSM y su período de migración (dic-marzo) comienza con su mejor condición física, y retornan a sus áreas de alimentación en la CGSM 2 a 4 semanas después, hasta el final de la migración, con su condición mínima ya que al parecer estas lisas no se alimentan durante su migración de desove. No se observaron cambios relacionados con las variaciones de la temperatura. Las aguas más turbias coincidieron con los sitios de alimentación de M. incilis.
    Description: The annual variation in condition of the mullet Mugil incilis Hancock has been studied in the Ciénaga Grande de Santa Marta (CGSM). The largest coastal lagoon on the Colombian Caribbean, with emphasis on the influence of such environmental factors as salinity, temperature and transparence of the waters on the condition of this species of Mugilidae. Seasonal differences observed in condition of M. incilis are evidently related to gonadal development and depend on food availability. The diet of M, incilis is based on detritus and its food supply seems to be very influenced by river discharge which also accounts for the salinity changes in the lagoon. this explains the in verse correlation (r = -0.82) found between salinity and condition of the mullets expressed as C = 0.9949 - 0.0057 S (°/oo). Annual salinity variation follows a rhythmic pattern of seasonal changes. not precisely "in situ", but in distant continental regions: the headwaters of the tributarles of the CGSM. These mullets spawn in Caribbean waters adjacent to the CGSM and their migración period (Dec-March) begins with their best physical condición, returning to their feeding áreas in the CGSM 2 or 4 weeks lacer, until the end of the migración, with their lowest condition since these mullets apparently do not feed at all during the spawning migration. No change related to temperature variations was observed. and turbid waters were the rule in M. incilis feeding sites.
    Description: Published
    Description: Mugil incilis
    Keywords: Fisheries ; Estuaries ; Ecology ; Coastal lagoons ; Fishery biology ; Fisheries ; Coastal lagoons ; Estuaries ; Fishery biology ; Ecology
    Repository Name: AquaDocs
    Type: Journal Contribution
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
    PAPER (OA)
  • 16
    facet.materialart.
    Unknown
    Historical development of Cuban fisheries: why we need an integrated approach to fisheries management? (2013)
    Gulf and Caribbean Fisheries Institute
    Details
    Publication Date: 2021-05-19
    Description: Un análisis de los datos arqueológicos e históricos sobre la pesca en Cuba muestra que el impacto de la población aborigen sobre los recursos pesqueros no fue significativo debido a su baja densidad poblacional y a las tecnologías de pesca. El interés por el oro, el tamaño de la población, las limitaciones tecnológicas para la pesca y preservación de las capturas así como las preferencias dietéticas de los españoles todas indican que la pesca tampoco fue una actividad económica importante durante los tres siglos que siguieron a la llegada de Colón. Las preferencias por la carne de res y el bacalao salado y la baja tasa de crecimiento poblacional durante el período colonial determinaron que la mayor parte de los recursos pesqueros, con la excepción del manatí y las tortugas marinas, permanecieran prácticamente inexplorados durante varios siglos después de la Conquista. Los datos estadísticos e históricos revelan que la pesca experimentó un rápido crecimiento desde 1950 y este patrón parece ser una característica común en el Caribe así como en otras partes del mundo. Las presiones sobre la vida marina fueron más evidentes en la segunda mitad del siglo xx cuando el crecimiento poblacional, las mejoras tecnológicas y las demandas del mercado aceleraron el sector pesquero así como la urbanización en la mayoría de los países del caribe.
    Description: Published
    Keywords: Integrated management ; Fisheries
    Repository Name: AquaDocs
    Type: Proceedings Paper , Refereed , Article
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
    PAPER (OA)
  • 17
    facet.materialart.
    Unknown
    Contribución al conocimiento de parasitos de peces de la Ciénaga Grande de Santa Marta I. Familia Acanthocolpidae (Trematoda: Digenea) (2011)
    Santa Marta (Colombia), INVEMAR
    Details
    Publication Date: 2021-05-19
    Description: Se describen y se ilustran seis especies de parásitos pertenecientes a la familia Acanthocolpidae encontradas en 19 especies de peces en su mayoría de considerable importancia económica. El estudio taxonómico de estos parásitos se realizó en la Ciénaga Grande de Santa Marta, al norte de Colombia, desde Enero de 1978 hasta Junio de 1979.
    Description: A taxonomic study for parasites found in 19 mostly economically important fish species was carried out in ihe Ciénaga Grande de Santa Marta (Northern Colombia) from January 1978 uritil June 1979. Six species of fish parasites belonging to the family Acanthocolpidae are described and illustrated herein.
    Description: Published
    Keywords: Fisheries ; Ecology ; Parasites ; Parasites ; Fisheries ; Ecology
    Repository Name: AquaDocs
    Type: Journal Contribution
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
    PAPER (OA)
  • 18
    facet.materialart.
    Unknown
    Aspectos biológicos del Calamar Argentino Illex argentinus (Castellanos) capturado por la flota cubana de pesca en el talud patagónico durante 1987 (2010)
    Santa Marta (Colombia), INVEMAR
    Details
    Publication Date: 2021-05-19
    Description: En 1987, se inicia un programa de muestreos biológicos del calamar argentino ///ex argentinas a bordo de barcos comerciales de la flota cubana de pesca que operan en la plataforma patagónica. La talla de los organismos para ambos sexos presenta un comportamiento estratificado por profundidades, los ejemplares de mayor tamaño se encuentran a profundidades superiores y viceversa, lo cual se ajusta a una recta de regresión (r2 = 0.88; a = 0.05). Las hembras alcanzaron largos promedio del manto superior a los machos, incrementándose la presencia de machos en las capturas desde enero a abril. Se estimaron los largos promedio de primera maduración, como 20.5 y 26.5 cm de largo del manto para machos y hembras respectivamente. Se observó un aumento de la proporción de individuos maduros de febrero a abril, haciéndose más marcado este fenómeno en los machos, que en su mayoría presentaban abundantes espermatóforos en el saco. Se obtuvo la relación largo-peso para hembras y machos y para la combinación de ambos sexos.
    Description: In 1987 a program for the biological sampling of squid ///ex argentinas, was begun on board of a fishing ship belonging to the Cuban Fisheries-Fleet, wich operates in the Patagonian Shelf. The lengths of both sexes presented a estratified pattern with individuals of larger size found in higher depths and viceversa; this pattern is adjusted to a regression line (r2 = 0.88; a = 0.05). Pernales reached average length larger (han males and the rate of males in catches increased from january to april. The first maturation average length was estimated about 20.5 cm for males and 26.5 cm for females. An increase of the rate of mature individuals was observed between february and april emphazasing ¡n males which showed abundant espermatophores in the sac.
    Description: Published
    Description: squid, Flota Cubana
    Keywords: Fisheries ; Squid culture ; Biological charts ; Biological data ; Fisheries ; Squid culture
    Repository Name: AquaDocs
    Type: Journal Contribution
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
    PAPER (OA)
  • 19
    facet.materialart.
    Unknown
    The differential effects of changing management regimes on yields from two fisheries exploiting the same resources (2013)
    Details
    Publication Date: 2021-05-19
    Description: A yield per recruit model has been used to compare the effects of mesh size increment on the yields and revenues of the fisheries of Cameroon under two different cases. Case 1 assumes the commercial fishery to move from the exploitation of three age-groups to two age-groups with no interactions with the artisanal fishery, whereas Case 2 takes into account these interactions. The difference in the percentage increase of yield per recruit between case 1 and case 2 is 61% at current fishing (46% and 18% yield per recruit increment in cases 1 and 2 respectively). The usually accepted long-term yield per recruit increment with increase of age at first capture (with a single non-interacting fisheries) is, in this case, cancelled out. However, the revenues increase by 72% and 63% in cases 1 and 2 respectively. Therefore the economic approach, compared with purely biological analyses, is more convincing. In general, as fisheries always interact, a single-fishery management approach should not be the rule as it is at present; management strategies should consider interactions between different fisheries and be based on their economic performances and not, as said earlier, on purely biological considerations. This is because a biological approach to fisheries management will, at best, be modified by economic factors, or, at worst, be ignored totally in favour of economic policies.
    Description: Published
    Keywords: Biology ; Fisheries ; Biological interaction ; Sciaenidae ; Fisheries development ; Fishery management ; Yield/recruit ; Commercial fisheries ; Artisanal fishing
    Repository Name: AquaDocs
    Type: Journal Contribution , Refereed , Article
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
    PAPER (OA)
  • 20
    facet.materialart.
    Unknown
    Quelles stratégies de suivi, contrôle et surveillance des ressources halieutiques en cogestion locale ? Etude de cas: la surveillance participative au niveau des sites pilotes du programme GIRMaC (2013)
    Details
    Publication Date: 2021-05-19
    Description: La pêche au Sénégal joue un rôle économique et social très important par une contribution globale de près de 11% du PIB primaire et 2,3% du PIB total. Elle occupe de façon directe et indirecte environ 600 000 personnes, soit près de 17% de la population active selon la DP M. Cependant ces dernières décennies, les études ont montré que le secteur traverse une crise aiguë se traduisant par une raréfaction croissante des ressources, notamment les espèces nobles qui ont une forte valeur commerciale. Cette crise est due entre autres à une surexploitation de ces ressources qui est le résultat d’un manque de maîtrise de l’effort de pêche surtout pour les pêcheries artisanales (80% des débarquements et plus de 60% des approvisionnements des industries de la place) au regard du volume de ressources disponibles. Ce manque de maîtrise est dû essentiellement par un défaut du suivi contrôle et surveillance au niveau de la pêche artisanale par l’Etat, qui n’a pas les moyens humains et matériels pour appliquer des mesures de gestion, qui pour la plupart ne sont pas adaptées aux réalités des acteurs à la base. L’objet de cette étude est d’analyser une nouvelle approche axée sur la surveillance participative basée sur l’émergence d’initiatives locales de cogestion au niveau des quatre (04) sites du programme GIRMaC que sont ; Ouakam, Ngaparou, Foundiougne et Bétenty. Il ressort de cette étude que : • Le secteur de la pêche traverse une crise aiguë due principalement selon les acteurs à un défaut de suivi, contrôle et surveillance tel que appliqué actuellement ; • L’approche de cogestion avec des bases juridiques cohérentes, comme le propose le programme GIRMaC peut être un moyen viable pour solutionner à la crise que traverse la pêche ; • D’une part le système Suivi Contrôle et Surveillance coûte cher, d’autre part que ces coûts sont fortement amoindris lorsque les acteurs participent à l’effort de surveillance, par une démarche de surveillance participative en cogestion.
    Description: Président : Omar Thiom THIAW, Professeur UCAD Membres : • Niokhor DIOUF, Chercheur IUPA. • Luis Tito Morais, Chercheur IRD Dakar. • Djiby THIAM, Chercheur GIRMac
    Description: Published
    Description: surveillance; contrôle; cogestion; effort de pêche; pêcherie; surexploitation; biodiversité; pêche artisanale
    Keywords: Ocean surveillance ; Ecosystem management ; Fishing effort ; Overexploitation ; Biodiversity ; Artisanal fishing ; Fisheries
    Repository Name: AquaDocs
    Type: Theses and Dissertations , Master thesis
    Format: 87
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
    PAPER (OA)
  • 21
    facet.materialart.
    Unknown
    Report of the EAF REGIONAL TASK GROUP MEETING AND ECOLOGICAL RISK ASSESSMENT METHODOLOGY WORKSHOP (SOUTH WEST INDIAN OCEAN) (2014)
    FAO | Rome
    Details
    Publication Date: 2021-01-30
    Description: The first meeting of the South West Indian Ocean EAF Regional Task Group (RTG) was held in Mombasa, Kenya, from 27 to 30 January 2009, together with an ecological risk assessment methodology workshop. It was attended by 20 partic ipants from the South West Indian Ocean (SWIO) countries, the South West Indian Ocean Fisheries Project (SWIOFP), the Agulhas and Somali Currents Large Marine Ecosystems (ASCLME) project, the Scientific Committee of the South West Indian Ocean Fisheries Commission, the United Nations Environment Programme (UNEP)/Nairobi Convention Implementation Unit, the African Union Commission and FAO. The RTG is an implementation structure under the EAF-Nansen project GCP/INT/003/NOR and serves as the forum for training in ecological risk assessment that is the methodology used for the identification and prioritization of issues requiring management attention. The main objectives of the meeting and workshop we re to discuss and facilitate key processes and activities for the implementation of the ecosystem approach to fisheries management in the South West Indian Ocean region including the modalities for the formation and functioning of the RTG and National Task Groups (NTGs). It was explained that, to be able to achieve the objectives of implementing an ecosystem approach to fisheries at the national level, certain key structures have to be in place including the NTG with representatives of key stakeholders in a given fishery and that would take the lead in the process. An overview of the key concepts and process of the ecological risk assessment methodology were clarified. Participants were also introduced to the preparation of EAF baseline reports to be used as initial input for the work on ecosystems approach to fisheries. It was explained that the preparation of the report is to be led by national and regional experts and overseen by the NTG. For the exercises the participants worked in three subgroups formed during the meeting with each group selecting a chairman who moderate d the discussions and a rapporteur. The participants expressed satisfaction with the development of a communication strategy for the project and especially with the participatory approach used.
    Description: FAO, NORAD, Institute of Marine Research
    Description: Published
    Description: National task groups
    Description: Regional task groups
    Description: Ecosystem Approach to Fisheries
    Keywords: Ecosystems ; Fisheries ; Ecosystems ; Fishery resources ; Fisheries management
    Repository Name: AquaDocs
    Type: Report , Non-Refereed
    Format: 36
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
    PAPER (OA)
  • 22
    facet.materialart.
    Unknown
    Déscription de l'activité ds flotilles pélagiques industrielles en 1986 dans la ZEEM mauritanienne (2013)
    Details
    Publication Date: 2021-05-19
    Description: Published
    Description: espéces pélagiques
    Description: sardine
    Description: pêche industrielle
    Keywords: Fisheries ; Pelagic fisheries ; Industrial fish ; Fish products ; Fishing industry ; Fishing fleet
    Repository Name: AquaDocs
    Type: Journal Contribution , Non-Refereed , Article
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
    PAPER (OA)
  • 23
    facet.materialart.
    Unknown
    NIOMR Newsletter, Jan-Jun 2010. (2014)
    Nigerian Institute for Oceanography and Marine Research | Lagos, Nigeria
    Details
    Publication Date: 2021-01-30
    Description: Published
    Description: Fisheries newsletter
    Keywords: Fisheries ; Marine sciences ; Fisheries literature
    Repository Name: AquaDocs
    Type: Report , Non-Refereed
    Format: 30pp.
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
    PAPER (OA)
  • 24
    facet.materialart.
    Unknown
    NIOMR Newsletter, Jan-Jun 2012. (2014)
    Nigerian Institute for Oceanography and Marine Research | Lagos, Nigeria
    Details
    Publication Date: 2021-01-30
    Description: Published
    Description: Fisheries newsletter
    Keywords: Fisheries ; Marine sciences ; Fisheries literature
    Repository Name: AquaDocs
    Type: Report , Non-Refereed
    Format: 34pp.
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
    PAPER (OA)
  • 25
    facet.materialart.
    Unknown
    NIOMR Newsletter, Jan-Apr 2009. (2014)
    Nigerian Institute for Oceanography and Marine Research | Lagos, Nigeria,
    Details
    Publication Date: 2021-01-30
    Description: Published
    Description: Fisheries newsletter
    Keywords: Fisheries ; Fisheries literature
    Repository Name: AquaDocs
    Type: Report , Non-Refereed
    Format: 11pp.
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
    PAPER (OA)
  • 26
    facet.materialart.
    Unknown
    Chaine froide dans la conservation du poisson (2013)
    Details
    Publication Date: 2021-05-19
    Description: Unpublished
    Description: conservation
    Description: chaine froide
    Description: poisson
    Keywords: Food conservation ; Fisheries ; Fish conversion ; Conservation (fishery products) ; Glass ; Fisheries
    Repository Name: AquaDocs
    Type: Journal Contribution , Non-Refereed , Article
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
    PAPER (OA)
  • 27
    facet.materialart.
    Unknown
    La pêche des senneurs dans la Baie du Lévrier en 1971 (2013)
    Details
    Publication Date: 2021-05-19
    Description: Published
    Description: Pêche
    Description: Senneur
    Keywords: Seining ; Fisheries ; Fisheries ; Seiners
    Repository Name: AquaDocs
    Type: Journal Contribution , Refereed , Article
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
    PAPER (OA)
  • 28
    facet.materialart.
    Unknown
    Etat des lieux de la filière de transformation artisanale des produits halieutiques au Sénégal (2013)
    Details
    Publication Date: 2021-05-19
    Description: ACDI;CRDI; République Française, Ministère des Affaires Etrangéres; CDE; Enda Graf Sahel;
    Description: Conseil Info MPEA, Projer d'Accés à l'information et au Conseil pour les microet petites entreprises agroalimentaires; Projet d'Appui aux Opérateurs/trices de l'Agroalimentaires (PAOA); Cintech Agroalimentaire; Groupe de Recherche et d'Echanges Technologiques (GRET); Enda GRaf Sahel; SNC-LAVALIN International
    Description: Published
    Description: transformation; transformation artisanale; échantillonage; collecte de données; commercialisation
    Keywords: Processing fishery products ; Biological sampling ; Data collections ; Marketing and distribution ; Fisheries
    Repository Name: AquaDocs
    Type: Theses and Dissertations , Master thesis
    Format: 41
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
    PAPER (OA)
  • 29
    facet.materialart.
    Unknown
    Pêcherie démersale côtière au Sénégal. Essai de modélisation de la dynamique de l'exploitation des stocks (2013)
    Details
    Publication Date: 2021-05-19
    Description: Français - Les traits essentiels de la côte sénégalaise, repères historiques de la pêche, communautés de pêcheurs, caractéristiques des flottes et modes d’accès à la ressource et d’interaction sont analysés. Les caractéristiques, tendances décroissantes de l’abondance,niveaux d’exploitation, mesures d’aménagement, relations interspécifiques, changements potentiels et sources de variation des stocks démersaux côtiers sont précisés. Les notions de tactiques et stratégies de pêche sont passées en revue, conceptualisées puis étudiées.Le modèle «Dynamique Conjointe Exploitation Ressource» utilisé repose sur la définition de 4 typologies. L’utilisation de méthodes de classification et de connaissances d’experts conduit à considérer 32 stocks, 31 strates, 82 tactiques et 25 flottilles artisanales et chalutières. Les typologies sont articulées avec la prise en compte de paramètres relatifs à l’économie, aux stocks, flottilles et règles de décisions. L’ajustement est satisfaisant en partie. Toutefois, le modèle garde son importance en matière de prospective et d’objectifs à atteindre via la définition de variables de contrôle. Notre travail peut être considéré comme une esquisse invitant à un groupe de travail élargi aux experts des institutions halieutiques nationales voire, sous-régionales. Des propositions sont faites sur les bases de données, les licences de pêche et l’étude des tactiques et stratégies à mener suivant des pas de temps raisonnables pour tenir compte du grand dynamisme des pêcheries. Dès lors qu'il s’agit de caractériser l'impact de la pêche sur l'écosystème, ces travaux sont des éléments essentiels des recherches à faire sur la dynamique des écosystèmes exploités. English - The essential features of the Senegalese coast, fisheries history, fishermen's communities, artisanal and trawling fleet’s characteristics and their way of accessing to the resource and interactions are described. The characteristics, evolutionary tendencies of abundance, level of exploitation, measures of fisheries management, interspecific relationship, potential evolutionary changes and sources of variation of coastal demersal stocks are specified. Tactics and strategies are reviewed, conceptualized and studied. We used the model "Dynamique Conjointe Exploitation Ressource" which lies on 32 stocks, 31 strata, 82 tactics, 25 fleets and several other parameters dealing with stocks, fleets, economy and making decision rules. The adjustment is partially satisfactory but the model is of great interest for prospective studies and objectives to reach once defined variables of control. Our work is an outline calling for an enlarged working group implying national or sub regional fisheries institutional experts. Tactics and strategies studies, re-actualized in artisanal fisheries, are performed for the first time in industrial fisheries. The typological approach is simple, pertinent, efficacy and fast. Propositions are made relatively to databases, fishing licenses and tactics and strategies studies that should be implemented according to a reasonable time steps in order to take into account the big dynamism of the Senegalese fisheries. As it is intended to characterize fisheries impact on ecosystem, these works are one of essential research elements on the dynamic of exploited ecosystems.
    Description: Published
    Description: pêcherie; démersale côtière; modélisation; stocks; écosystème; communauté de pêcheurs; eaux continentales; eaux marines; saison hydrologique; pêcheur; flottille; crevettier; capture; aménagement des pêcheries; pêche chalutière; pêche artisanale; licence de pêche; permis de pêche
    Keywords: Fisheries ; Demersal fisheries ; Modelling ; Stocks ; Ecosystems ; Community fishing ; Inland waters ; Marine water ; Hydrologic cycle ; Fishermen ; Fishing fleet ; Shrimp fisheries ; Capture fisheries ; Fisheries management ; Trawling ; Artisanal fishing ; Fishing licenses
    Repository Name: AquaDocs
    Type: Theses and Dissertations , Bachelor thesis
    Format: 234
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
    PAPER (OA)
  • 30
    facet.materialart.
    Unknown
    Etude sur le savoir écologique des pêcheurs artisans des petits pélagiques en Afrique du Nord-Ouest (2010)
    Details
    Publication Date: 2021-05-19
    Description: Agriculture, Nature and Food Quality, Den Haag (Netherlands); Ministerie Van Buitenlandse Zaken, Brussel (Belgium); Wageningen International, Wageningen (Netherlands)
    Description: Projet BBI 13286 : Pêche durable des petits pélagiques en Afrique Nord Ouest Ce rapport a été préparé avec le soutien financier de la Coopération néerlandaise (DGIS) dans le cadre de son Programme de politique internationale en matière de biodiversité (BBI).
    Description: Published
    Description: pêche traditionnelle; taille; échantillonnage; écosystème; upwelling; biomasse; filet maillant dérivant; senne tournante; senne moustiquaire; senne de plage; maquereau; chinchard; sardinelle; ethmalose; reproduction; courant; stocks; réglementation; pêche par espéce; engin de pêche; pélagique; zone côtière; pirogue; pêche artisanale; pêcheur
    Keywords: Biomass ; Ecosystems ; Fisheries ; Fishermen ; Stocks ; Ocean currents ; Winds ; Size ; Fishing effort ; Pelagic fisheries ; Sexual reproduction ; Multispecies fisheries ; Fisheries ; Artisanal fishing ; Fishermen ; Fishing effort ; Canoe fisheries ; Coastal zone ; Fishery engineering ; Protected resources ; Pelagic fisheries ; Cycles ; Sexual reproduction ; Multispecies fisheries ; Stocks ; Ocean currents ; Winds ; Biomass ; Upwelling ; Ecosystems ; Maritime legislation ; Size
    Repository Name: AquaDocs
    Type: Report
    Format: 53
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
    PAPER (OA)
  • 31
    facet.materialart.
    Unknown
    Traitement traditionnel et conservation des produits de la pêche en Mauritanie (2013)
    Details
    Publication Date: 2021-05-19
    Description: Published
    Description: conservation
    Description: produits
    Description: pêche
    Keywords: Conservation ; Fisheries ; Fish products
    Repository Name: AquaDocs
    Type: Journal Contribution , Non-Refereed , Article
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
    PAPER (OA)
  • 32
    facet.materialart.
    Unknown
    NIOMR Newsletter, May-Oct 2009. (2014)
    Nigerian Institute for Oceanography and Marine Research, | Lagos, Nigeria,
    Details
    Publication Date: 2021-01-30
    Description: Published
    Description: Fisheries newsletter
    Keywords: Fisheries ; Fisheries literature
    Repository Name: AquaDocs
    Type: Report , Non-Refereed
    Format: 8pp.
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
    PAPER (OA)
  • 33
    facet.materialart.
    Unknown
    Projet d'aménagement des stocks pélagiques partagés : Cas des pêcheries de mulets et de courbines en Mauritanie et au Sénégal (2011)
    Details
    Publication Date: 2021-01-30
    Description: En Afrique de l'Ouest, la zone littorale et ses ressources représentent une composante essentielle pour le développement. Près de 60% de la population est concentrée à moins de 20 km des côtes . La part des ressources halieutiques dans l'alimentation des populations est très importante et croissante. Au Sénégal par exemple, elles contribuent jusqu'à 70% des apports en protéines. A cela s'ajoute le poids socio-économique très important de la pêche en général et de la pêche artisanale en particulier devenue l'un des secteurs les plus stratégiques pour l'économie nationale en Mauritanie notamment. Le Cadre Stratégique de Lutte contre la Pauvreté du Gouvernement Mauritanien considère que : "compte tenu des possibilités qu'elle offre en terme de création d'emplois et de sécurité alimentaire notamment pour les populations pauvres, mais également de génération de recettes en devises, la pêche artisanale revêt une grande priorité, un plan décennal de développement lui sera consacré ".
    Description: Published
    Description: pêche artisanale; littoral; carpe; ethmalose; donnée; mulet; pélagique; pourtague; stock halieutique; pêche; communauté de pêcheurs; effort de pêche; PNBA; technique de pêche; senne tournante; sardinelle; gonade; filet de pêche; courbine; migration d'espèces; campagne de pêche; écosystème; dégradation d'habitats de poissons; enjeux socioéconomiques; commercialisation; conservation
    Keywords: Fisheries ; Fishermen ; Stocks ; Fish fillets ; Ecosystems ; Fishing effort ; Pelagic fisheries ; Artisanal fishing ; Fisheries ; Fishermen ; Stocks ; Capture fishery economics ; Fish eggs ; Fish fillets ; Fishing effort ; Fishery technology ; Mullet fisheries ; Pelagic fisheries ; Ecosystems
    Repository Name: AquaDocs
    Type: Report
    Format: 6
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
    PAPER (OA)
  • 34
    facet.materialart.
    Unknown
    Aquaculture and capture fisheries : a conceptual approach toward an integrated economic-ecological analysis (2012)
    Details
    Publication Date: 2022-05-25
    Description: Author Posting. © The Author(s), 2012. This is the author's version of the work. It is posted here by permission of Taylor & Francis for personal use, not for redistribution. The definitive version was published in Aquaculture Economics & Management 16 (2012): 167-181, doi:10.1080/13657305.2012.678551.
    Description: This study presents a framework for analyzing the interactions between aquaculture and capture fisheries in the context of ecosystem-based management. We extend a model of the economic and ecological systems in coastal New England by incorporating an aquaculture sector in a computable general equilibrium (CGE) model and by examining the forage fish and aquaculture link in a marine food web. We show that aquaculture and commercial fisheries interact in a complex way throughout the economic and ecological systems.
    Description: This work was supported by the NOAA Saltonstall-Kennedy Grant Program (Award No. NA09NMF4270097), the MIT Sea Grant College Program (NOAA Award No. NA10OAR4170086, Subaward No. 5710002974), and the Johnson Endowment of the WHOI Marine Policy Center.
    Description: 2013-06-08
    Keywords: Aquaculture ; Fisheries ; Ecosystem-based management ; CGE model ; Food web model ; Forage fish
    Repository Name: Woods Hole Open Access Server
    Type: Preprint
    Format: application/pdf
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
    PAPER (OA)
  • 35
    facet.materialart.
    Unknown
    Habitat damage, marine reserves, and the value of spatial management (2013)
    Ecological Society of America
    Details
    Publication Date: 2022-05-25
    Description: Author Posting. © Ecological Society of America, 2013. This article is posted here by permission of Ecological Society of America for personal use, not for redistribution. The definitive version was published in Ecological Applications 23 (2013): 959–971, doi:10.1890/12-0447.1.
    Description: The biological benefits of marine reserves have garnered favor in the conservation community, but “no-take” reserve implementation is complicated by the economic interests of fishery stakeholders. There are now a number of studies examining the conditions under which marine reserves can provide both economic and ecological benefits. A potentially important reality of fishing that these studies overlook is that fishing can damage the habitat of the target stock. Here, we construct an equilibrium bioeconomic model that incorporates this habitat damage and show that the designation of marine reserves, coupled with the implementation of a tax on fishing effort, becomes both biologically and economically favorable as habitat sensitivity increases. We also study the effects of varied degrees of spatial control on fisheries management. Together, our results provide further evidence for the potential monetary and biological value of spatial management, and the possibility of a mutually beneficial resolution to the fisherman–conservationist marine reserve designation dilemma.
    Description: M. G. Neubert acknowledges the support of the National Science Foundation (DMS-0532378, OCE-1031256) and a Thomas B. Wheeler Award for Ocean Science and Society. H. V. Moeller acknowledges support from a National Science Foundation Graduate Research Fellowship. This research is based in part on work supported by Award No. USA 00002 made by King Abdullah University of Science and Technology (KAUST).
    Keywords: Bioeconomics ; Destructive fishing practices ; Fisheries ; Habitat damage ; Marine protected areas ; Marine reserves ; Optimal control ; Optimal harvesting ; Spatial management
    Repository Name: Woods Hole Open Access Server
    Type: Article
    Format: application/pdf
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
    PAPER (OA)
  • 36
    facet.materialart.
    Unknown
    Projet pour le développement rationnel et durable du secteur de la pêche au Sénégal (INT/07/16M/SPA) (2013)
    Ministerio de Medio Ambiente y Medio Rural y Marino | Madrid (Espagne)
    Details
    Publication Date: 2021-05-19
    Description: Description du secteur de la pêche Avec la Mauritanie, le Sénégal est de loin le plus grand producteur de produits de pêche de la sous région. Avec 718 km de cote et un territoire maritime de 198km2, 15 745 km2 de superficie fluviale, 2 estuaires, des mangroves et un lac de 350km2, le Sénégal possède tous les atouts des plus grands producteurs de pêche. Le potentiel annuel de captures s’élève à 500 000 tonnes. Le secteur a subi une croissance spectaculaire ces trente dernières années : les débarquements sont passés 50 000 tonnes en 1965 à plus de 450 000 en 1997. Le secteur se compose principalement de deux sous-secteurs : la pêche industrielle et la pêche traditionnelle ou artisanale. Cette dernière, vielle de plusieurs siècles a su s’adapter et se moderniser au cours des dernières décennies. La flotte de pêche artisanale est dynamique et diversifiée ; selon les estimations, en 2005 il y avait plus de 13 000 pirogues. La pêche artisanale se concentre dans sept régions maritimes et fluviales du pays: Dakar, Thiès, Saint Louis, Fatick, Zinguinchor, Louga et Kaolack. Le port de Kayar dans la région de Thiès correspond à la principale zone de débarquement de la pêche artisanale avec environ 70% des débarquements. Dans le secteur industriel, les pêcheurs travaillent à bord d’une flottille de petits sardiniers, de 143 chalutiers destinés à la pêche d’espèces demersales, de 3 sardiniers et de 42 thoniers. Alors que le Sénégal domine largement le sous-secteur demersale avec 70% des chalutiers opérants, le pays ne possède que 6 thoniers contre 38 étrangers, dont une partie seulement des captures est débarquée au Sénégal. La pêche industrielle est concentrée autour de la capitale dans le Port autonome de Dakar et des ports secondaires de Saint Louis, Kaolack et Ziguinchor. Aujourd’hui, le secteur de la pêche sénégalaise est largement dominé par la pêche artisanale, qui constituait 90% des cargaisons totales des produits de la mer en 2006 avec 350 000 tonnes. Plus de 60% des produits de la pêche artisanale sont destinés à l’exportation et la transformation. En 2006, le secteur dans son ensemble représentait 9% du PIB du secteur primaire, 1.5% du PIB total, et 1/3 des devises étrangères (250 millions de dollars par an). Plus importante que le poids économique du secteur, est son poids social : la pêche génère indirectement 600 000 emplois, dont 67% au sein du secteur artisanal. En outre, les produits de la pêche comblent les besoins en protéines animales de la population sénégalaise à hauteur de 75%1. La pêche a connu une expansion spectaculaire au cours des dernières décennies grâce à l’impulsion de politiques publiques de développement basées sur une logique sectorielle productiviste. Une flotte nationale artisanale et industrielle a été progressivement mise en place ainsi que de fortes capacités de transformation industrielle. Cet engagement de l’Etat a ensuite connu un net ralentissement du fait, entre autre, des politiques d’ajustement structurel. Le renchérissement des coûts de production subséquents à la dévaluation du franc CFA en 1994 a lourdement affecté les pêcheurs. Parallèlement, avec la forte demande en produits halieutiques et en l’absence de politiques adéquates et cohérentes de gestion durable des ressources exploitables, une situation de surexploitation des ressources halieutiques s’est installée. En conséquence de la raréfaction des ressources halieutiques, la pêche sénégalaise traverse une crise sans précédent, dont les effets commencent à se faire sentir à tous les niveaux : appauvrissement des communautés de pêcheurs, menace de l’approvisionnement en poisson des populations, baisse des captures à haute valeur ajoutée, baisse des exportations, baisse de la rentabilité et des revenus des unités de pêche. Par ailleurs, de plus en plus d’établissements de transformation industrielle ferment (23 entreprises entre 1999 et 2006).
    Description: Ministerio de Medio Ambiente Y Medio Rural y Marino
    Description: Pablo Manuel Xandri Royo CTP Proyecto (INT/07/16M/SPA) Este trabajo se ha realizado en el marco del Convenio de Colaboración entre el actual Ministerio de Medio Ambiente y Medio Rural y Marino de España y la Organización Internacional del Trabajo de 28 de diciembre de 2007
    Description: Published
    Description: environnement; socio-économie; pêche; capture; débarquement; engin de pêche; femme; pêcheur; convention internationale; réglementation
    Keywords: Fisheries ; Marine environment ; Socioeconomic aspects ; Capture fisheries ; Landing statistics ; Fishing gear ; Women ; Fishermen ; Conventions ; Fishery regulations
    Repository Name: AquaDocs
    Type: Report , Non-Refereed
    Format: 208
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
    PAPER (OA)
  • 37
    facet.materialart.
    Unknown
    Le secteur des pêches au Sénégal: tendances, enjeux et orientations politiques (2013)
    Programme Kurukan Fugan (Union Européenne/Gouvernement du Sénégal/Enda Graf/Gret) | Dakar (Sénégal)
    Details
    Publication Date: 2021-05-19
    Description: Programme KURUKAN FUGAN (Union Européenne/Gouvernement du Sénégal/EndaGraf/GRET)
    Description: Published
    Description: politique de pêche; environnement marin; socio-économie; co-gestion; aquaculture; pêche artisanale; pêche industrielle; pêcherie; ONG; AMP; ressource halieutique; organisations professionnelles
    Keywords: Marine environment ; Socioeconomic aspects ; Fishery management ; Aquaculture ; Artisanal fishing ; Fisheries ; Industrial fish ; Fishery resources ; Fishing policy ; Protected areas ; Professionals
    Repository Name: AquaDocs
    Type: Book , Non-Refereed , Article
    Format: 26
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
    PAPER (OA)
  • 38
    facet.materialart.
    Unknown
    Accord visant à favoriser le respect par les navires de pêche en haute mer des mesures internationales de conservation et de gestion (2011)
    Details
    Publication Date: 2021-01-30
    Description: Ministère des Affaires Etrangères (Sénégal); Ambassade du Sénégal à Rôme (Italy)
    Description: "Action 21"; FAO; application de l'accord; responsabilité de l'état du pavillon; échange d'informations; tiers à l'accord; règlement des différents; adhésion; entrée en vigueur; réserves; amendements; retraits; fonction du dépositaire.
    Keywords: Fisheries ; International agreements ; International cooperation ; Fisheries ; International agreements ; Maritime legislation ; International cooperation
    Repository Name: AquaDocs
    Type: Other
    Format: 14
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
    PAPER (OA)
  • 39
    facet.materialart.
    Unknown
    La pesca en Cuba : apuntes para su historia (II) : la pesca desde 1492 hasta 1902 : etapa colonial (2013)
    Details
    Publication Date: 2021-09-18
    Description: En la época colonial algunas especies de peces cubanos retienen sus nombres por los cuales eran conocidos por los aborígenes: biajaca, biajaiba, cojinúa, jiguagua, cibí. Aún hoy se designan de igual forma. En esta época aparece la primera obra científica impresa en Cuba, los primeros pueblos pescadores y los primeros científicos.
    Description: Published
    Keywords: Fisheries
    Repository Name: AquaDocs
    Type: Journal Contribution , Refereed , Article
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
    PAPER (OA)
  • 40
    facet.materialart.
    Unknown
    La pesca en Cuba : apuntes para su historia (I) : la pesca en las comunidades primitivas : etapa precolombina (2013)
    Details
    Publication Date: 2021-09-18
    Description: Published
    Description: especies nativas
    Description: pesca
    Keywords: Fisheries ; Indigenous species ; Indigenous fishing
    Repository Name: AquaDocs
    Type: Journal Contribution , Refereed , Article
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
    PAPER (OA)
  • 41
    facet.materialart.
    Unknown
    La pesca en Cuba : apuntes para su historia (III) : la pesca desde 1902 hasta 1952 : etapa de la seudorrepública (2013)
    Details
    Publication Date: 2021-09-18
    Description: Published
    Keywords: Fisheries
    Repository Name: AquaDocs
    Type: Journal Contribution , Refereed , Article
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
    PAPER (OA)
  • 42
    facet.materialart.
    Unknown
    La Pesca de los peces de pico en Cuba (I) (2013)
    Details
    Publication Date: 2021-09-18
    Description: Recuento en forma breve de las pesquerías de estas especies durante varios siglos, en los cuales los sabios Parra y Felipe Poey ofrecen descripciones. Precios, lugares de captura y pescadores son los protagonistas.
    Description: Published
    Description: Emperador-Xiphias gladius
    Description: pez espada
    Description: castero-Makaira nigricans
    Description: aguja blanca-Tetrapturus albidus
    Keywords: Fisheries ; Fishes
    Repository Name: AquaDocs
    Type: Journal Contribution , Non-Refereed , Article
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
    PAPER (OA)
  • 43
    facet.materialart.
    Unknown
    La pesca de los peces de pico en Cuba (II). (2013)
    Details
    Publication Date: 2021-09-18
    Description: Causas del descenso en las pesquerías de estas especies a partir de 1975. Se describen las técnicas y artes de pesca empleadas y se abunda en la complejidad de las capturas y las características de los palangres empleados para cada especie. Una comparación es establecida además con países del área. De forma muy didáctica e instructiva.
    Description: Published
    Description: castero-Makaira nigricans
    Description: Emperador-Xiphias gladius
    Description: aguja blanca-Tetrapturus albidus
    Keywords: Fisheries ; Fishes
    Repository Name: AquaDocs
    Type: Journal Contribution , Non-Refereed , Article
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
    PAPER (OA)
  • 44
    facet.materialart.
    Unknown
    A review of interactions between cetaceans and fisheries in the Azores (2011)
    Details
    Publication Date: 2022-05-26
    Description: Author Posting. © John Wiley & Sons, 2010. This is the author's version of the work. It is posted here by permission of John Wiley & Sons for personal use, not for redistribution. The definitive version was published in Aquatic Conservation: Marine and Freshwater Ecosystems 21 (2011): 17-27, doi:10.1002/aqc.1158
    Description: 1. Interactions between cetaceans and fishing activity in the Archipelago of the Azores were examined using information contained in grey literature and previously unpublished data collected by observer programmes and research projects from 1998 to 2006. Together with a brief description of the economics, gear, fishing effort, and past and ongoing monitoring projects, levels of cetacean bycatch and interference were reported for each major fishery. 2. Cetaceans were present in 7% (n=973) and interfered in 3% (n=452) of the fishing events monitored by observers aboard tuna-fishing vessels. Interference resulted in a significantly higher proportion of events with zero catches but it was also associated with higher tuna catches. 3. There was a decreasing trend in the proportion of tuna-fishing events with cetacean presence or interference throughout this study, as well as a reduction in the estimates of dolphins captured annually by the whole fleet. 4. Observers reported cetacean depredation in 16% of the sets for demersal species and in 2% of the sets for swordfish. Cetacean presence and depredation were associated with higher overall catches and higher catches per unit effort in demersal fisheries. Bottlenose dolphins (Tursiops truncatus) were responsible for most depredation events in demersal fisheries, whereas in the swordfish fishery, depredation was associated with the presence of killer whales (Orcinus orca). There were no reports of cetacean bycatch in these fisheries. There were also no reports of cetaceans interacting in the experimental deep-sea fisheries that were examined. 5. Available data suggests that levels of interaction between cetaceans and Azorean fisheries are generally low and that the economic impact of cetacean interference is probably small. However, for several traditional fisheries there are no accurate data to determine levels of cetacean interaction. We recommend that existing observer programmes be expanded to increase observer coverage of the demersal and swordfish fisheries and allow monitoring of other existing and emerging fisheries.
    Description: M.A.S. was supported by an FCT postdoctoral (SFRH/BPD/29841/2006) grant, and R.P. was supported by an FCT doctoral grant (SFRH/BD/32520/2006).
    Keywords: Cetacean–fisheries interactions ; Depredation ; Bycatch ; Fisheries ; Atlantic Ocean ; Azores
    Repository Name: Woods Hole Open Access Server
    Type: Preprint
    Format: application/pdf
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
    PAPER (OA)
  • 45
    facet.materialart.
    Unknown
    Multiple genetic stocks of longfin squid Loligo pealeii in the NW Atlantic : stocks segregate inshore in summer, but aggregate offshore in winter (2011)
    Inter-Research
    Details
    Publication Date: 2022-05-26
    Description: Author Posting. © Inter-Research, 2006. This article is posted here by permission of Inter-Research for personal use, not for redistribution. The definitive version was published in Marine Ecology Progress Series 310 (2006): 263-270, doi:10.3354/meps310263.
    Description: The longfin squid Loligo pealeii is distributed widely in the NW Atlantic and is the target of a major fishery. A previous electrophoretic study of L. pealeii was unable to prove genetic differentiation, and the fishery has been managed as a single unit stock. We tested for population structure using 5 microsatellite loci. In early summer (June), when the squids had migrated inshore to spawn, we distinguished 4 genetically distinct stocks between Delaware and Cape Cod (ca. 490 km); a 5th genetic stock occurred in Nova Scotia and a 6th in the northern Gulf of Mexico. One of the summer inshore stocks did not show genetic differentiation from 2 of the winter offshore populations. We suggest that squids from summer locations overwinter in offshore canyons and that winter offshore fishing may affect multiple stocks of the inshore fishery. In spring, squids may segregate by genetic stock as they undertake their inshore migration, indicating an underlying mechanism of subpopulation recognition.
    Description: We acknowledge funding from WHOI Sea Grant NA16RG2273, the Massachusetts Environmental Trust (#98-04), and the Sholley Foundation.
    Keywords: Fisheries ; Spawning migration ; Microsatellites ; Population structure ; Population recognition ; Null alleles
    Repository Name: Woods Hole Open Access Server
    Type: Article
    Format: application/pdf
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
    PAPER (OA)
  • 46
    facet.materialart.
    Unknown
    Spillover from marine reserves and the replenishment of fished stocks (2010)
    Cambridge University Press
    Details
    Publication Date: 2022-05-26
    Description: Author Posting. © Foundation for Environmental Conservation, 2009. This article is posted here by permission of Cambridge University Press for personal use, not for redistribution. The definitive version was published in Environmental Conservation 36 (2009): 268-276, doi:10.1017/S0376892910000032.
    Description: No-take marine reserves are widely recognized as an effective conservation tool for protecting marine resources. Despite considerable empirical evidence that abundance and biomass of fished species increase within marine reserve boundaries, the potential for reserves to provide fisheries and conservation benefits to adjacent waters remains heavily debated. This paper uses statistical and population models to evaluate published empirical data on adult spillover from marine reserves and shows that spillover is a common phenomenon for species that respond positively to reserve protection, but at relatively small scales, detectable on average up to 800 m from reserve boundaries. At these small scales, local fisheries around reserves were likely unsustainable in 12 of 14 cases without the reserve, and spillover partially or fully offsets losses in catch due to reserve closure in the other two cases. For reserves to play a role in sustaining and replenishing larger-scale fished stocks, networks of reserves may be necessary, but as few exist this is difficult to evaluate. The results suggest reserves can simultaneously meet conservation objectives and benefit local fisheries adjacent to their boundaries.
    Description: Support was provided by a grant from the David and Lucille Packard Foundation to NCEAS for ecosystem-based management ofmarine systems, the Partnership for Interdisciplinary Studies of Coastal Oceans (PISCO) funded by the David and Lucile Packard Foundation and the Gordon and Betty Moore Foundation (contribution number 348), the Sustainable Fisheries Group supported by the Paul G. Allen Family Foundation and the Bahamas Biocomplexity Project (US NSF Biocomplexity grantOCE-0119976) andUS EPA Science to Achieve Results (R832223).
    Keywords: Adult fish movement ; Fisheries ; Global ; Marine protected areas ; No-take reserves ; Spillover effect ; Synthesis
    Repository Name: Woods Hole Open Access Server
    Type: Article
    Format: application/pdf
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
    PAPER (OA)
  • 47
    Electronic Resource
    Electronic Resource
    Regulated flushing in a gravel-bed river for channel habitat maintenance: A Trinity River fisheries case study (1987)
    Springer
    Environmental management 11 (1987), S. 479-493 
    Details
    ISSN: 1432-1009
    Keywords: Flushing ; Scouring ; Channel Maintenance ; Fisheries ; Trinity River
    Source: Springer Online Journal Archives 1860-2000
    Topics: Energy, Environment Protection, Nuclear Power Engineering
    Notes: Abstract The operation of Trinity and Lewiston Dams on the Trinity River in northern California in the United States, combined with severe watershed erosion, has jeopardized the existence of prime salmonid fisheries. Extreme streamflow depletion and stream sedimentation below Lewiston have resulted in heavy accumulation of coarse sediment on riffle gravel and filling of streambed pools, causing the destruction of spawning, nursery, and overwintering habitat for prized chinook salmon (Salmo gairdnerii) and steelhead trout (Oncorhynchus tschawytscha). Proposals to restore and maintain the degraded habitat include controlled one-time remedial peak flows or annual maintenance peak flows designed to flush the spawning gravel and scour the banks, deltas, and pools. The criteria for effective channel restoration or maintenance by streambed flushing and scouring are examined here, as well as the mechanics involved. The liabilities of releasing mammoth scouring-flushing flows approximating the magnitude that preceded reservoir construction make this option unviable. The resulting damage to fish habitat established under the postproject streamflow regime, as well as damage to human settlements in the floodplain, would be unacceptable, as would the opportunity costs to hydroelectric and irrigation water users. The technical feasibility of annual maintenance flushing flows depends upon associated mechanical and structural measures, particularly instream maintenance dredging of deep pools and construction of a sediment control dam on a tributary where watershed erosion is extreme. The cost effectiveness of a sediment dam with a limited useful economic life, combined with perpetual maintenance dredging, is questionable.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1007/BF01867656
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
    Paper (German National Licenses)
    Fulltext
  • 48
    Electronic Resource
    Electronic Resource
    Age, growth and reproductive biology of the silky shark, Carcharhinus falciformis, and the scalloped hammerhead, Sphyrna lewini, from the northwestern Gulf of Mexico (1987)
    Springer
    Environmental biology of fishes 19 (1987), S. 161-173 
    Details
    ISSN: 1573-5133
    Keywords: Chondrichthyes ; Elasmobranchs ; Fisheries ; Ageing methods ; Growth rates ; Gestation periods ; Maturity ; Vertebral bands ; Weight-length relationships ; Life histories
    Source: Springer Online Journal Archives 1860-2000
    Topics: Biology
    Notes: Synopsis The silky shark, Carcharhinus falciformis, and scalloped hammerhead, Sphyrna lewini, represent 〉80% of the shark by-catch of the winter swordfish/tuna longline fishery of the northwestern Gulf of Mexico. This catch represents a potential supplemental fishery, yet little is known of the life histories of the two species. This report relates reproductive biology data to age and growth estimates for 135 C. falciformis and 78 S. lewini. Unlike other regional populations, C. falciformis in the Gulf of Mexico may have a seasonal 12 month gestation period. Males mature at 210–220 cm TL (6–7 yr); females at 〉225 cm TL (7–9 yr). Application of age at length data for combined sexes produced von Bertalanffy growth model parameter estimates of L∞ = 291 cm TL, K = 0.153, t0 = −2.2 yr. Adult male S. lewini outnumbered adult females in catches because of differences in the distributions of the sexually segregated population. Males mature at 180 cm TL (10 yr); females at 250 cm TL (15 yr). von Bertalanffy parameter estimates for combined sexes of this species were L∞ = 329 cm TL, K = 0.073, to = −2.2 yr.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1007/BF00005346
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
    Paper (German National Licenses)
    Fulltext
  • 49
    Electronic Resource
    Electronic Resource
    The need for conservation and management of Philippine coral reefs (1988)
    Springer
    Environmental biology of fishes 23 (1988), S. 141-154 
    Details
    ISSN: 1573-5133
    Keywords: Cyanide ; Diversity ; Development ; Ecology ; Environment ; Fisheries ; Pollution
    Source: Springer Online Journal Archives 1860-2000
    Topics: Biology
    Notes: Synopsis The biological diversity and productivity of Philippine coral reefs are threatened by siltation, destructive fishing methods, coral and shell collecting and overfishing. Destructive fishing includes: the widespread, illegal use of explosives; poisons such as sodium cyanide; muro-ami and kayakas fishing; and trawling. The recent decline in catch rates threatens the livelihood of 700 000 near-shore subsistence fishermen who catch 55% of the total landings. The new government under Corazon Aquino wishes to protect the marine environment through the creation of a viable marine conservation management plan, enforcement of existing laws and through cooperation between government, non-government and international agencies to provide education and research. The Department of Agriculture, which has the authority for fisheries, has designated the International Marinelife Alliance as the lead non-government agency involved with fund raising, net-training and finding alternatives to destructive fishing methods.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1007/BF00000745
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
    Paper (German National Licenses)
    Fulltext
  • 50
    Electronic Resource
    Electronic Resource
    Einfluß der Substituenten auf Aktivierungsenthalpie-,-entropie und -volumen beim Zerfall organischer Perester (1985)
    Weinheim : Wiley-Blackwell
    Berichte der deutschen chemischen Gesellschaft 118 (1985), S. 240-245 
    Details
    ISSN: 0009-2940
    Keywords: Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Description / Table of Contents: Influence of Substituents on the Enthalpy, Entropy and Volume of Activation in the Decomposition of Organic PerestersThe influence of the ester group on the decomposition of organic peroxides was studied on peresters of the pivalic and neodecanoic acid with tert-butyl, tert-amyl, 1-methyl-1-propylpentyl and 1,1,4-trimethylpentyl groups at temperatures of 393 to 473 K and pressures up to 3000 bar using a flow method. As expected the half-live times decrease with increasing temperature and increase with rising pressure. With increasing bulkiness of the substituents the rates of decomposition as well as the enthalpies of activation increase. This surprising fact can be explained by the simultaneous increase of the entropies and the volumes of activation.
    Notes: Der Einfluß der Estergruppe auf den Zerfall organischer Peroxide wurde an Perestern der Pivalin- und der Neodecansäure mit tert-Butyl-, tert-Amyl-, 1-Methyl-propylpentyl- sowie 1,1,4-Trimethylpentylresten bei Temperaturen von 393 bis 473 K und Drücken bis 3000 bar in einer Strömungsapparatur untersucht. Die Zerfallshalbwertszeiten nehmen erwartungsgemäß mit steigender Temperatur stark ab und mit steigendem Druck zu. Mit zunehmender Größe der Substituenten steigen sowohl die Zerfallsgeschwindigkeiten als auch die Aktivierungsenthalpien. Dieser überraschende Effekt kann durch die Vergrößerung der Aktivierungsentropie und des Aktivierungsvolumens erklärt werden.
    Additional Material: 1 Ill.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/cber.19851180123
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
    Paper (German National Licenses)
    Fulltext
  • 51
    Electronic Resource
    Electronic Resource
    Zur Lewis-Acidität von Nickel(0), III. Alkalimetall-hydridotrialkylaluminat-Komplexe von Ni(CDT) (1985)
    Weinheim : Wiley-Blackwell
    Berichte der deutschen chemischen Gesellschaft 118 (1985), S. 313-322 
    Details
    ISSN: 0009-2940
    Keywords: Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Description / Table of Contents: On the Lewis Acidity of Nickel(0), III. Alkali Metal Hydridotrialkylaluminate Complexes of Ni(CDT)Ni(CDT) reacts with hydridotrialkylaluminates of the alkali metals in ether/THF or ether/amine mixtures at temperatures below -50°C to form the temperature-sensitive compounds [MA(n-Donor)n]+[R3Al—H—Ni(CDT)]- (1-7) (MA = Li, Na; R = Me, Et, iBu). An Al—H—Ni three-centre bond is present in these complexes. On the basis of NMR data, the strength of the hydridoaluminate-nickel bond and the charge on nickel, caused by the hydridoaluminate residue, are compared with the corresponding characteristics of other ligand-Ni(CDT) complexes in which donor-acceptor σ-bonds are present.
    Notes: Ni(CDT)Abkürzungen: CDT = trans, trans, trans-1,5,9-Cyclododecatrien, COD = 1,5-Cyclooctadien, MA+ (solvatisiertes) Alkalimetall-Ion, PMDTA = N,N,N′,N″N″-Pentamethyldiethylentriamin, TMEDA = N,N,N′,N′-Tetramethylethylendiamin. reagiert mit Alkalimetall-hydridotrialkylaluminaten in Ether/THF-oder Ether/Amin-Mischungen als Lösungsmittel unterhalb von -50°C zu den thermisch labilen Verbindungen [MA(n-Donor)n]+[R3Al—H—Ni(CDT)]- (1-7) (MA = Li, Na; R = Me, Et, iBu). In diesen Komplexen liegt eine Al—H—Ni-Mehrzentrenbindung vor. Anhand NMR-spektroskopischer Daten lassen sich die Stärke der Hydridoaluminat-Nickel-Bindung und die Beladung des Nickels durch den Hydridoaluminat-Rest mit den Bindungsverhältnissen in anderen Ligand-Ni(CDT)-Komplexen mit Donor-Akzeptor-σ-Bindungen vergleichen.
    Additional Material: 2 Ill.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/cber.19851180128
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
    Paper (German National Licenses)
    Fulltext
  • 52
    Electronic Resource
    Electronic Resource
    Zur Lewis-Acidität von Nickel(0), I. Methyllithium-Komplexe von Nickel(0) (1985)
    Weinheim : Wiley-Blackwell
    Berichte der deutschen chemischen Gesellschaft 118 (1985), S. 275-297 
    Details
    ISSN: 0009-2940
    Keywords: Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Description / Table of Contents: On the Lewis Acidity of Nickel(0), I. Methyllithium Complexes of Nickel(0)The synthesis and properties of the methyllithium complexes of nickel(0) of the type (n-Donor)m-(LiCH3)Ni0(π-Ligand)n (1a-c, 16a-c, 20a-c) [n-Donor = chelating amine or THF; π-Ligand = CDT, ethene, or CO] are described. The structure of (PMDTA)(LiCH3)Ni(C2H4)2 (1b) has been determined by X-ray crystallography.  -  In these ate complexes, a carbanionic methyl group is σ-bonded to a nickel atom, the acceptor strength of which depend on the π-ligands. The chemical and spectroscopic properties indicate that the Ni—CH3 bond in the carbonyl complex is largely covalent whereas in the CDT and ethene compounds it is more polar. The CDT complex is thermolabile in solution. The findings are in agreement with the following series of increasing acceptor strength: Ni(CDT) 〈 Ni(C2H4)2 〈 Ni(CO)3.
    Notes: Es wird über die Synthese und Eigenschaften der Methyllithium-Komplexe von Nickel(0) (n-Donor)m(LiCH3)Ni0(π-Ligand)n Wir bezeichnen mitπ-Liganden solche Liganden, die als π-Akzeptoren mit einem Übergangsmetallatom dπ—pπ—oder dπ—dπ-Rückbindungen auszubilden vermögen (Alkene, CO, auch Phosphane);n-Donoren solche Liganden, die als „harte Basen“ (Ether, Amine) über ihre freien Elektronenpaare vornehmlich Hauptgruppenmetall-Ionen, d.h. „harte Säuren“ komplexieren;σ-Donoren solche Liganden, die  -  ohne über Akzeptororbitale zu verfügen  -  entweder polare Bindungen enthalten und Mehrzentrenbindungen eingehen können (Metallalkyle und -hydride) oder ein freies Elektronenpaar bereitstellen (Carbanionen, Phosphorane, Hydrid-Ion), wobei σ-Bindungen zu einem niederwertigen Übergangsmetallatom ausgebildet werden. (1a-c, 16a-c, 20a-c) mit Chelataminen oder THF als n-Donoren und CDTAbkürzungen: CDT = trans,trans,trans-l,5,9-Cyclooctadien; COT = Cyclooctatetraen; PMDTA = Pentamethyldiethylentriamin; TMEDA = Tetramethylethylendiamin; MA+A = Alkalimetall- bzw. quartäres Ammonium-Kation., Ethen oder CO als π-Liganden berichtet. Die Struktur von (PMDTA)(LiCH3)Ni(C2H4)2 (1b) wurde röntgenographisch bestimmt.  -  In diesen at-Komplexen ist eine carbanionische Methylgruppe über eine σ-Bindung an ein Nickelatom gebunden, dessen Akzeptorstärke von den π-Liganden abhängt. Chemische und spektroskopische Eigenschaften der Komplexe lassen für CDT oder Ethen als π-Liganden auf vergleichsweise polare, für den CDT-Komplex in Lösung dazu thermolabile Ni—CH3-Bindungen schließen, während für den Carbonyl-Komplex aufgrund von 13C-NMR-Daten eine überwiegend kovalente Ni—CH3-Bindung anzunehmen ist. Die Befunde stehen mit folgender Reihe zunehmender Akzeptorstärke im Einklang: Ni(CDT) 〈 Ni(C2H4)2 〈 Ni(CO)3.
    Additional Material: 5 Ill.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/cber.19851180126
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
    Paper (German National Licenses)
    Fulltext
  • 53
    Electronic Resource
    Electronic Resource
    Über das korrespondierende Verhalten von heteroatom-stabilisierten Carbokationen und dem Cycloheptatrien-Norcaradien-Gleichgewicht (1985)
    Weinheim : Wiley-Blackwell
    Berichte der deutschen chemischen Gesellschaft 118 (1985), S. 620-633 
    Details
    ISSN: 0009-2940
    Keywords: Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Description / Table of Contents: On the Correspondence of Heteroatom-stabilized Carbocations and the Cycloheptatriene-Norcaradiene EquilibriumThe effects of alkoxyiminium substituents on the cycloheptatriene-norcaradiene equilibria 1 ⇄ 2 have been investigated. Due to the energetics two classes of compounds were found (ΔH° 〈 0, and ΔH° 〉 0). The transfer of the substituent effect from carbocation to carbocyclus is inhibited by a p-phenylene group. From 1H and 13C NMR spectra at variable temperatures thermodynamic parameters are deduced and correlated with σR-constants obtained from 19F NMR spectroscopy. By extrapolation, the enthalpy difference for the unsubstituted cycloheptatriene and norcaradiene is calculated as 9.3 kcal/mol.
    Notes: Der Einfluß von Alkoxyiminium-Substituenten an C-7 auf die Lage des Cycloheptatrien-Norcaradien-Gleichgewichts 1 ⇄ 2 wird untersucht. Auf Grund der Energetik gibt es Verbindungen, bei denen Temperaturabsenkung eine Verschiebung des Gleichgewichts zum Norcaradien (ΔH° 〈 0) ergibt, bei anderen Beispielen ist ΔH° 〈 0. Eine p-Phenylenbrücke zwischen Kation und Carbocyclus blockiert den Substituenteneffekt. Aus den 1H- und 13C-NMR-Spektren bei verschiedenen Temperaturen wurden thermodynamische Daten ermittelt und mit den durch 19F-NMR bestimmten σR-Konstanten korreliert. Durch Extrapolation konnte die Enthalpiedifferenz des unsubstituierten Cycloheptatriens und Norcaradiens zu 9.3 kcal/mol abgeschätzt werden.
    Additional Material: 3 Ill.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/cber.19851180221
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
    Paper (German National Licenses)
    Fulltext
  • 54
    Electronic Resource
    Electronic Resource
    Hydrated oxocarbons, IV. Silylation of 1,1-dihydroxy compounds (1985)
    Weinheim : Wiley-Blackwell
    Berichte der deutschen chemischen Gesellschaft 118 (1985), S. 661-669 
    Details
    ISSN: 0009-2940
    Keywords: Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Description / Table of Contents: Hydratisierte Oxokohlenwasserstoffe, IV. Silylierung von 1,1-Dihydroxy-VerbindungenDie Anwendung von verschiedenen Silylierungsreagenzien auf mono- und polyvicinale 1,1-Di-hydroxy-Verbindungen wurde untersucht. Mit einigen dieser Reagenzien konnten aus Ninhydrin (2) und Rhodizonsäure (17) die entsprechenden geminalen Bis(trimethylsilyloxy)-Derivate 1 und 20 gewonnen werden. Während 1 leicht zu Hexamethyldisiloxan und Indantrion (4) fragmentiert, ist 20 thermisch relativ stabil, es gibt pyrolytisch bei 500°C nur Spuren des Tetraketons 21 ab. Andere Silylierungsreagenzien bewirken unerwartete C-Alkylierung oder C-Amidierung am Dihydroxykohlenstoff. Silylierungen von Perhydroxycyclobutan und -cyclohexan führen zu Ringaufspaltungs- bzw. Verengungsprodukten.
    Notes: The action of various silylating agents on mono- and polyvicinal 1,1-dihydroxy compounds has been investigated. Some of these reagents converted ninhydrin (2) and rhodizonic acid (17) into the corresponding geminal bis(trimethylsilyloxy) derivatives 1 and 20, respectively. Compound 1 readily fragments to form hexamethyldisiloxane and indantrione (4). The rhodizonic acid derivative 20 is, however, rather stable and even on pyrolysis at 500°C gives only traces of the tetraketone 21. With other silylating agents unexpected C-alkylation or C-amidation at the dihydroxy carbon is observed. Silylation of perhydroxycyclobutane and -cyclohexane leads to ring opened and contracted products.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/cber.19851180225
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
    Paper (German National Licenses)
    Fulltext
  • 55
    Electronic Resource
    Electronic Resource
    Cycloadditionen des Triphenylallenyl-Kations mit Cyclopentadien  -  Studium des Reaktionsmechanismus unter stabilen Ionen-Bedingungen (1985)
    Weinheim : Wiley-Blackwell
    Berichte der deutschen chemischen Gesellschaft 118 (1985), S. 694-703 
    Details
    ISSN: 0009-2940
    Keywords: Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Description / Table of Contents: Cycloadditions of the Triphenylallenyl Cation with Cyclopentadiene  -  Investigation of the Reaction Mechanism under Stable Ion ConditionsThe triphenylallenyl cation (5) reacts with cyclopentadiene in a concerted [4 + 2] and a stepwise [2 + 2] cycloaddition. The reaction mechanisms are elucidated by NMR spectroscopic observation of the intermediate carbenium ions.
    Notes: Das Triphenylallenyl-Kation (5) geht mit Cyclopentadien eine konzertierte [4 + 2]- sowie eine stufenweise [2 + 2]-Cycloaddition ein. Die Reaktionsmechanismen werden durch NMR-spektro-skopische Beobachtung der intermediären Carbenium-Ionen aufgeklärt.
    Additional Material: 2 Ill.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/cber.19851180229
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
    Paper (German National Licenses)
    Fulltext
  • 56
    Electronic Resource
    Electronic Resource
    Synthese und Struktur Platin-haltiger Tripeldecker- und Tetradecker-Komplexe (1985)
    Weinheim : Wiley-Blackwell
    Berichte der deutschen chemischen Gesellschaft 118 (1985), S. 729-740 
    Details
    ISSN: 0009-2940
    Keywords: Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Description / Table of Contents: Synthesis and Structure of Platinum-Containing Triple-Decker and Tetra-Decker ComplexesStacking of the acceptor sandwich bis(η5-2,3-dihydro-1H-1,3-diborolyl)platinum 1 (≙ (C2B2C)2Pt) with (C5H5)M fragments leads to the unsymmetrical triple-decker complexes (η5-C5H5)M-μ-(η5-C2B2C)Pt(η5-C2B2C) 2 (M = Co) and 3 (M = Ni) as well as to the symmetrical tetra-decker complexes [(η5-C5H5)M-μ-(η5-C2B2C)]2Pt 4 (M = Fe) and 5 (M = Ni). In these reactions 1 and (C5H5)Fe(C8H12) yield the tetra-decker 4, whereas with (C5H5)Co(C2H4)2 only the triple-decker 2 is formed. With [(C5H5)Ni(CO)]2 both the triple-decker 3 and the tetra-decker 5 are obtained. NMR studies on the diamagnetic complexes 2 (30 valence electrons), 4 (42 VE), and 5 (46 VE) indicate high-symmetrical conformations, or free rotation of the ligands. 2 and 3 crystallize isotypic; the X-ray structure analyses exhibit the triple-decker arrangement with antiperiplanar conformation of the heterocycles. 3 in comparison with 2 is elongated along the molecular axis. The tetra-deckers 4 and 5 also crystallize isotypic; for the first time a synclinale conformation of the bridging ligands is found.
    Notes: Aufstockung des Akzeptor-Sandwichs Bis(η5-2,3-dihydro-1H-1,3-diborolyl)platin 1 (≙ (C2B2C)2Pt) mit (C5H5)M-Fragmenten führt zu den unsymmetrischen Tripeldecker-Komplexen (η5-C5H5)M-μ(η5-C2B2C)Pt(η5-C2B2C) 2 (M = Co) und 3 (M = Ni) sowie zu den symmetrischen Tetradecker-Komplexen [(η5-C5H5)M-μ-(η5-C2B2C)]2Pt 4 (M = Fe) und 5 (M = Ni). Dabei ergibt die Reaktion von 1 mit (C5H5Fe(C8H12) den Tetradecker 4, während mit (C5H5)Co(C2H4)2 nur der Tripeldecker 2 entsteht. Mit [(C5H5)Ni(CO)]2 werden der Tripeldecker 3 und der Tetradecker 5 gebildet. NMR-Untersuchungen an den diamagnetischen Komplexen 2 (30 Valenzelektronen), 4 (42 VE) und 5 (46 VE) sprechen für hochsymmetrische Konformationen oder freie Rotation der Liganden. 2 und 3 kristallisieren isotyp; die Röntgenstrukturanalysen zeigen die Tripeldeckeranordnung mit antiperiplanarer Konformation der Heterocyclen. 3 ist im Vergleich zu 2 entlang der Molekülachse aufgeweitet. Die Tetradecker 4 und 5 kristallisieren ebenfalls isotyp, es wird erstmals eine synclinale Konformation der Brückenliganden gefunden.
    Additional Material: 4 Ill.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/cber.19851180232
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
    Paper (German National Licenses)
    Fulltext
  • 57
    Electronic Resource
    Electronic Resource
    Ein neuer Zugang zu Alkylthio(trifluoracetyl)furanen durch thermische [3 + 2]-Cycloadditionen neuer mesoionischer 1,3-Oxathiol-4-one an Alkine (1985)
    Weinheim : Wiley-Blackwell
    Berichte der deutschen chemischen Gesellschaft 118 (1985), S. 785-795 
    Details
    ISSN: 0009-2940
    Keywords: Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Description / Table of Contents: A New Entry to Alkylthio(trifluoroacetyl)furans by Way of Thermal [3 + 2]Cycloaddition Reactions of New Mesoionic 1,3-Oxathiol-4-ones to AlkynesAs cyclic carbonyl ylides, the novel 2-alkylthio-5-trifluoroacetyl-1,3-oxathiolylium-4-olates of type 1a-d combine with dimethyl acetylenedicarboxylate across the 2,5-position with formation of non-isolable primary adducts, which release COS to give the furandicarboxylic diesters 3a-d. Methyl propiolate reacts with 1a-c to produce mixtures of the regioisomeric furancarboxylic esters 4a-c and 5a-c, whose main components 4a-c are isolable. On the other hand, the reactions of phenylacetylene, 1-diethylaminopropyne, or (Z)-1-methoxy-1-buten-3-yne with 1a proceed with regiospecific formation of the furan derivatives 6, 7, or 8, respectively. The observed regioselectivities are qualitatively discussed on the basis of MO-perturbation theory.
    Notes: Als cyclische Carbonyl-ylide nehmen die neuen 2-Alkylthio-5-trifluoracetyl-1,3-oxathiolylium-4-olate vom Typ 1a-d in 2,5-Stellung Acetylendicarbonsäure-dimethylester unter Bildung nicht-isolierbarer Primäraddukte auf, die unter COS-Abspaltung Furandicarbonester 3a-d liefern. Mit Propiolsäure-methylester reagiert 1a-c zu Gemischen aus den regioisomeren Furancarbonestern 4a-c und 5a-c, deren Hauptkomponenten 4a-c isolierbar sind. Dagegen vereinigen sich Phenylacetylen, 1-Diethylaminopropin bzw. (Z)-1-Methoxy-1-buten-3-in mit 1a regiospezifisch zu den Furan-Derivaten 6, 7 bzw. 8. Die beobachteten Regioselektivitäten werden qualitativ auf der Basis der MO-Störungstheorie diskutiert.
    Additional Material: 1 Ill.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/cber.19851180237
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
    Paper (German National Licenses)
    Fulltext
  • 58
    Electronic Resource
    Electronic Resource
    Notizen. Thermolysis and photolysis of hexachloro-tris-σ-homotropone and related compounds (1985)
    Weinheim : Wiley-Blackwell
    Berichte der deutschen chemischen Gesellschaft 118 (1985), S. 840-844 
    Details
    ISSN: 0009-2940
    Keywords: Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Thermolyse und Photolyse von Hexachlor-tris-σ-homotropon und verwandten VerbindungenTroponethylenacetal (2) reagiert mit überschüssigem CCl2 zu den Mono-, Bis- und Tris-Addukten 3, 4a, b und 5. Thermolyse von 5 führt nicht zum Hexachlor-tris-σ-homobenzol (1), ebensowenig wie die Photolyse des Ketons 6a, bei der unter Öffnung einer Cyclopropan-Brückenbindung das sterisch mehr gehinderte Isomere 6b erhalten wird. Die Photolyse von 8 verläuft ebenfalls nicht unter Decarbonylierung (→ 7) sondern unter Cyclopropanring-Öffnung zu 9 bzw. 10, wobei hier die von der Carbonylgruppe am weitesten entfernten Bindungen geöffnet werden.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/cber.19851180241
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
    Paper (German National Licenses)
    Fulltext
  • 59
    Electronic Resource
    Electronic Resource
    Schwefelextrusion aus 5(2H)-Isothiazolonen und 5(2H)-Isothiazolthionen zu intermediären Imidoylketenen und -thioketenen (1985)
    Weinheim : Wiley-Blackwell
    Berichte der deutschen chemischen Gesellschaft 118 (1985), S. 851-862 
    Details
    ISSN: 0009-2940
    Keywords: Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Description / Table of Contents: Sulfur Extrusion from 5(2H)-Isothiazolones and 5(2H)-Isothiazolethiones to give Intermediate Imidoyl Ketenes and Imidoyl ThioketenesFrom 5(2H-isothiazolethiones (2) and propylene oxide a series of new 5(2H-isothiazolones (7) was prepared. With tributylphosphane (or cyanide ions) 2 and 7 eliminated one sulfur atom. The resulting assumed imidoyl ketenes (8) and imidoyl thioketenes (3) could not be detected spectro-scopically. But by isolation of dimeric imidoyl thioketenes (1,3-dithietanes, 1) and trapping with alcohols, amines, or benzylideneisopropylamine to give derivatives of acrylic acid (4-6) or dihydropyrimidones (9) it is shown that 3 and 8 are probably intermediates.
    Notes: Aus 5(2H)-Isothiazolthionen (2) wurde mittels Propylenoxid eine Reihe neuer 5(2H)-Isothiazolone (7) hergestellt. Beide Substanzklassen reagieren mit Tributylphosphan (oder Cyanid-Ionen) unter Abspaltung eines Schwefelatoms zu vermuteten, spektroskopisch aber nicht nachgewiesenen Imidoyl-thioketenen (3) bzw. Imidoylketenen (8). Ihr intermediäres Auftreten wurde durch die Isolierung von dimeren Imidoyl-thioketenen (1,3-Dithietanen, 1) und durch Abfangreaktionen mit Alkoholen, Aminen oder Benzylidenisopropylamin zu den Derivaten der Acrylsäure 4-6 bzw. den Dihydropyrimidonen 9 wahrscheinlich gemacht.
    Additional Material: 4 Tab.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/cber.19851180302
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
    Paper (German National Licenses)
    Fulltext
  • 60
    Electronic Resource
    Electronic Resource
    Heterocyclische β-Enaminoester, 36. Das Cycloadditions-Ringerweiterungsprinzip beim 4,5-Dihydropyrrol: 6,7-Dihydro-1H-azepine, Pyrimido[4,5-b]azepine und 1,2,4-Triazolo[5′,1′: 2,3]pyrimido[4,5-b]azepin (1985)
    Weinheim : Wiley-Blackwell
    Berichte der deutschen chemischen Gesellschaft 118 (1985), S. 863-872 
    Details
    ISSN: 0009-2940
    Keywords: Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Description / Table of Contents: Heterocyclic β-Enamino Esters, 36. The Cycloaddition-Ring Enlargement Principle on 4,5-Dihydropyrroles: 6,7-Dihydro-1H-azepines, Pyrimido[4,5-b]azepines, and 1,2,4-Triazolo[5′,1′: 2,3]pyrimido[4,5-b]azepineThe 2-amino-1-tosyl-Δ2-pyrroline enamino esters 2a, b react with dichlorotriphenylphosphorane to give the iminophosphoranes 3a, b. With acetylenic esters (4a-c) the 6,7-dihydro-1H-azepines 6a-d are formed according to the cycloaddition-ring enlargement principle. Acids hydrolyze to afford the free azepine enamino esters 7a, c, d. With phenyl isocyanate 6a gives the carbodiimide 9, which upon treatment with 5% aq. NaOH cyclizes to give the pyrimido[4,5-b]azepine 10. Analogously, isopropylamine and hydrazine lead to the 2-N-substituted bicycles 11a, b; with triethyl orthoformiate 11a yields the novel 5:6:7-tricycle 13.
    Notes: Die 2-Amino-1-tosyl-Δ2-pyrrolin-enaminoester 2a, b reagieren mit Dichlortriphenylphosphoran zu den Iminophosphoranen 3a, b. Mit Acetylenestern (4a-c) entstehen nach dem Prinzip Cycloaddition-Ringerweiterung die 6,7-Dihydro-1H-azepine 6a-d. Säuren hydrolysieren zu den freien Azepin-enaminoestern 7a, c, d. Mit Phenylisocyanat ergibt 6a das Carbodiimid 9, das sich mit 5proz. Natronlauge zum Pyrimido[4,5-b]azepin 10 ringschließen läßt; Isopropylamin und Hydrazin führt analog zu den 2-N-substituierten Bicyclen 11a, b, 11a ergibt mit Orthoameisensäure-triethylester den neuen 5:6:7-Tricyclus 13.
    Additional Material: 5 Tab.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/cber.19851180303
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
    Paper (German National Licenses)
    Fulltext
  • 61
    Electronic Resource
    Electronic Resource
    Carbonylvanadate(-I) mit ungesättigten Liganden: 51V-NMR-und IR-spektroskopische Charakterisierung der Tieftemperaturspezies [V(CO)5L]-; L = N2, Alkin, Alken, CS2 und SO2 (1985)
    Weinheim : Wiley-Blackwell
    Berichte der deutschen chemischen Gesellschaft 118 (1985), S. 895-904 
    Details
    ISSN: 0009-2940
    Keywords: Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Description / Table of Contents: Carbonylvanadates(-I) Containing Unsaturated Ligands:51V NMR and IR Characterization of Low-temperature [V(CO)5L]- Complexes; L = N2, Alkyne, Alkene, CS2, and SO2UV irradiation of [Et4N]V(CO)6 + L in THF (L = alkyne, alkene) or 2-Me-THF (L = N2) at 200 K yields the pentacarbonylvanadates [V(CO)5L]- with end-on (N2) and side-on (alkynes, alkenes) coordinated ligands, respectively. [V(CO)5SO2]- (η1S) and [V(CO)5CS2]- (η2-C,S) were obtained from the reaction between [V(CO)5THF]- and L at 200 K. The N2 complex is also formed from [V(CO)5OCMe2]- and N2. The complexes are characterized by their IR and 51V NMR spectra. Shielding of the 51V nucleus decreases in the order alkene 〉 alkyne ≍ N2 〉 SO2 〉 CS2 〉 {O}. Compared to η1-coordination, η2-coordination gives rise to a deshielding contribution of 110 to 280 ppm. The compounds decompose at temperatures above 225 K (L = N2, 2-pentyne, 3-hexyne, cyclopentene, cyclohexene), 240 - 250 K (SO2, CS2, 1-pentene), or 285 K (1-hexyne); with PPh3, [V(CO)5PPh3]- is formed.
    Notes: Die UV-Bestrahlung von [Et4N][V(CO)6] + L in THF (L = Alkin, Alken) oder 2-Me THF (L = N2) bei 200 K führt zu Pentacarbonylvanadaten [V(CO)5L]- mit end-on (N2) bzw. side-on (Alkine, Alkene) gebundenen Liganden. [V(CO)5SO2]- (η1-S und [V(CO)5CS2]- (η2C,S) wurden durch Umsetzung von [V(CO)5THF]- mit L bei 200 K erhalten. Der N2-Komplex entsteht auch aus [V(CO)5OCMe2]- und N2. Die Komplexe werden durch ihre IR- und 51V-NMR-Spektren charakterisiert. Die Abschirmung am Kern 51V nimmt in der Reihe Alken 〉 Alkin ≍ N2 〉 SO2 〉 CS2 〉 {O} ab. Die η2-Koordination liefert gegenüber der η1-Koordination einen Entschirmugsbeitrag von 110 - 280 ppm. Die Verbindungen zersetzen sich bei Temperaturen oberhalb 225 K (L = N2, 2-Pentin, 3-Hexin, Cyclopenten, Cyclohexen), 240 - 250 K (SO2, CS2, 1-Penten) bzw. 285 K (1-Hexin); mit PPh3 erfolgt Umsetzung zu [V(CO)5PPh3]-.
    Additional Material: 2 Ill.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/cber.19851180307
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
    Paper (German National Licenses)
    Fulltext
  • 62
    Electronic Resource
    Electronic Resource
    (Trifluormethyl)selen(VI)-Verbindungen, Synthese und Eigenschaften von Tetrafluor(trifluormethyl)selen-halogeniden sowie Trifluormethanselenonaten (1985)
    Weinheim : Wiley-Blackwell
    Berichte der deutschen chemischen Gesellschaft 118 (1985), S. 943-951 
    Details
    ISSN: 0009-2940
    Keywords: Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Description / Table of Contents: (Trifluoromethyl)selenium(VI) Compounds, Synthesis and Properties of Tetrafluoro(trifluoromethyl)selenium Halides and TrifluoromethaneselenonatesFluorination of CF3SeF3 with liquid F2 or AgF2 leads to CF3SeF5, which decomposes to CF4 and SeF4. With water CF4 and SeOF2 are formed. Addition of ClF to CF3SeF3 gives CF3SeF4Cl, which splits mainly into CF3Cl and SeF4. Hydrolysis provides analogously CF3Cl and SeOF2. A neutral concentrated solution of KMnO4 oxydizes CF3SeO2H in water in good yields to CF3SeO3K, the free acid of which is obtained with 74% HClO4. The aqueous solution can be concentrated up to 90%, but above this concentration spontaneous decomposition to CF4, COF2, and SeO2 occurs. Trifluoromethaneselenonates are stable at room temperature but decompose when heated.
    Notes: Die Fluorierung von CF3SeF3 mit flüssigem Fluor bzw. AgF2 führt zu CF3SeF5 das thermisch in CF4 sowie SeF4 zerfällt und mit H2O zu CF4 und SeOF2 hydrolysiert. Durch Addition von ClF an CF3SeF3 entsteht CF3SeF4Cl, das sich hauptsächlich zu CF3Cl und SeF4 zersetzt. Die Hydrolyse liefert analog CF3Cl und SeOF2. Mit wäßr., gesättigter KMnO4 liefert CF3SeO2H in guter Ausbeute CF3SeO3K, aus dem die freie Säure mit 74proz. HClO4 erhalten wird. Sie läßt sich in wäßriger Lösung bis zu 90% anreichern und zerfällt bei weiterem Konzentrieren spontan zu CF4, COF2 und SeO2. Ihre Salze sind bei Raumtemperatur stabil und explodieren beim Erhitzen.
    Additional Material: 1 Ill.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/cber.19851180312
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
    Paper (German National Licenses)
    Fulltext
  • 63
    Electronic Resource
    Electronic Resource
    Metallkomplexe mit biologisch wichtigen Liganden, XXXIV. Allyl-Palladium(II)- und Triphenylphosphan-Gold(I)-Komplexe mit Nucleobasen und Nucleosiden (1985)
    Weinheim : Wiley-Blackwell
    Berichte der deutschen chemischen Gesellschaft 118 (1985), S. 931-942 
    Details
    ISSN: 0009-2940
    Keywords: Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Description / Table of Contents: Metal Complexes with Biologically Important Ligands, XXXIV. Allyl-Palladium(II) and Triphenylphosphane Gold(I) Complexes with Nucleobases and NucleosidesThe reactions of (η3-allyl)Pd(μ-Cl)2Pd(η3-allyl) (A) and (COD)Rh(μ-Cl)2Rh(COD) with nucleobases and nucleosides give the complexes (η3-C3H5)Pd(L)Cl (1) (L = inosine, adenosine, guanosine, cytosine, cytidine, 2-thiouracil, 2-thiocytosine) and (COD)Rh(cytosine)Cl (2), respectively. With adenosine and purine also ligand bridged complexes (η3-C3H5)(Cl)Pd—L—Pd(Cl)(η3-C3H5) (3) have been obtained. Ph3PAuCl reacts with the anions L′ of purine, adenine, uridine, and inosine to give the complexes Ph3PAuL′ (5). Ph3PAu+ is added to both N atoms of the dianion of uracil with formation of 6. The coordination of the nucleobases is discussed on the basis of the 1H and 13C NMR spectra. The X-ray structure of Ph3PAu(adeninate) (5b) has been determined.
    Notes: Die Umsetzung von (η3-Allyl)Pd(μ-Cl)2Pd(η3-Allyl) (A) sowie von (COD)Rh(μ-Cl)2Rh(COD) mit Nucleobasen und Nucleosiden liefert unter Spaltung der Chlorobrücken die Komplexe (η3C3H5)-Pd(L)Cl (1) (L = Inosin, Adenosin, Guanosin, Cytosin, Cytidin, 2-Thiouracil, 2-Thiocytosin) bzw. (COD)Rh(Cytosin)Cl (2). Mit Adenosin und Purin wurden auch Ligand-verbrückte Komplexe (η3-C3H5)(Cl)Pd—L—Pd(Cl)(η3-C3H5) (3) erhalten. Ph3PAuCl setzt sich mit den Anionen L′ von Purin, Adenin, Uridin und Inosin zu Ph3PAuL′ (5) um; Ph3PAu+ addiert sich an die beiden N-Atome des Dianions von Uracil unter Bildung von 6. Die Koordination der Nucleobasen wird anhand der 1H- und 13C-NMR-Spektren diskutiert. Die Struktur von Ph3PAu (Adeninat) (5b) wurde röntgenographisch bestimmt.
    Additional Material: 1 Ill.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/cber.19851180311
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
    Paper (German National Licenses)
    Fulltext
  • 64
    Electronic Resource
    Electronic Resource
    Bicyclofulvene, XI. Zur Frage der Spirokonjugation bei Spiro[cycloheptatrien-7,7′-norbornadien] (1985)
    Weinheim : Wiley-Blackwell
    Berichte der deutschen chemischen Gesellschaft 118 (1985), S. 1000-1007 
    Details
    ISSN: 0009-2940
    Keywords: Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Description / Table of Contents: Bicyclofulvenes, XI. On the Question of Spiroconjugation in Spiro[cycloheptatriene-7,7′-norbornadiene]The title compound 4 as well as the derivatives 5 und 6 have been prepared. The first band in the UV spectrum of 4 in n-heptane is blue-shifted by ca. 20 nm with respect to those of 5 and 6. Model calculations with the CNDO/S-CI method indicate that this hypsochromic shift as well as the bathochromic shift of the corresponding band of 2 relative to that of 3, cannot be explained by spiroconjugation. The thermolysis of 4 yields benzene, heptafulvalene (15), and fulveneallene (16). The latter products are probably derived from cycloheptatrienylidene (14) as an intermediate.
    Notes: Die Titelverbindung 4 sowie die Derivate 5 und 6 wurden dargestellt. Die erste Bande im UV-Spektrum von 4 in n-Heptan zeigt eine hypsochrome Verschiebung um ca. 20 nm verglichen mit den Banden in 5 und 6. Modellrechungen mit der CNDO/S-CI-Methode zeigen, daß, sowohl diese hypsochrome Verschiebung als auch die bathochrome Verschiebung der entsprechenden Bande von 2 im Vergleich zu 3 nicht auf Spirokonjugation beruht. Die Thermolyse von 4 ergibt neben Benzol Heptafulvalen (15) und Fulvenallen (16). Diese Produkte machen eine Spaltung von 4 in Benzol und Cycloheptatrienyliden (14) wahrscheinlich.
    Additional Material: 2 Ill.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/cber.19851180316
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
    Paper (German National Licenses)
    Fulltext
  • 65
    Electronic Resource
    Electronic Resource
    Neue Reagenzien, XXXII. Alkyldiphenylbismutane: Synthese, Eigenschaften und Halogenolyse (1985)
    Weinheim : Wiley-Blackwell
    Berichte der deutschen chemischen Gesellschaft 118 (1985), S. 1031-1038 
    Details
    ISSN: 0009-2940
    Keywords: Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Description / Table of Contents: New Reagents, XXXII. Alkyldiphenylbismutanes: Synthesis, Properties, and HalogenolysisAlkyldiphenylbismutanes 1 have been synthesized for the first time (61-92%). These compounds are air sensitive, not spontaneously inflammable liquids which decompose not below ≍ 170°C. The diphenylbismutino group is a very good equivalent for Cl- or Br-substituents at aliphatic residues since halogenolysis of the Bi-Alk bond with SO2Cl2 or Br2 already occurs at -40 to 0°C (corresponding fissions of As-Alk and Sb-Alk bonds afford heating to ≍ 130 or ≍ 220°C).
    Notes: Erstmals konnten Alkyldiphenylbismutane 1 synthetisiert werden (61-92%). Es sind luftempfindliche, nicht selbstentzündliche Flüssigkeiten, die sich erst bei ≍ 170°C zersetzen. Die Diphenylbismutino-Gruppe ist ein sehr gutes Äquivalent für aliphatisch gebundenes Chlor oder Brom, da die Halogenolyse der Bi-Alk-Bindung mit SO2Cl2 oder Br2 bereits bei - 40 bis 0°C abläuft (entsprechende Spaltungen von As-Alk- und Sb-Alk-Bindungen erfolgen bei ≍ 130 bzw. ≍ 220°C).
    Additional Material: 5 Tab.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/cber.19851180319
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
    Paper (German National Licenses)
    Fulltext
  • 66
    Electronic Resource
    Electronic Resource
    Dimere Phospha- und Thiastannylene: Ylidartige Diphospha- und Dithiadistannetane (1985)
    Weinheim : Wiley-Blackwell
    Berichte der deutschen chemischen Gesellschaft 118 (1985), S. 1045-1049 
    Details
    ISSN: 0009-2940
    Keywords: Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Description / Table of Contents: Dimeric Phospha- and Thiastannylenes: Ylide-type Diphospha- and DithiadistannetanesBis(di-tert-butylphosphino)tin(II) (1) is obtained from the reaction of potassium di-tert-butyl-phosphide with stannous chloride or with the stannous chloride-triethylphosphane complex. Bis(tert-butylthio)tin(II) (2) is prepared by reaction of (η5-C5H5)2Sn with 2-methyl-2-propanethiol or from stannous chloride and (tert-butylthio)trimethylsilane. In solution, 1 and 2 are PR2-and SR-bridged dimers, respectively. NMR spectra indicate that rapid scrambling of terminal and bridging substituents occurs in 2 but not in the cyclic \documentclass{article}\pagestyle{empty}\begin{document}$ \mathop {\rm P}\limits^ + - \mathop {\rm S}\limits^{\rm - } {\rm n} $\end{document} ylide 1.
    Notes: Bis(di-tert-butylphosphino)zinn(II) (1) entsteht durch Reaktion von Kalium-di-tert-butylphos-phid mit Zinndichlorid oder dem Zinndichlorid-Triethylphosphan-Komplex. Bis(tert-butylthio)-zinn(II) (2) wird hergestellt durch Umsetzung von (η5-C5H5)2Sn mit 2-Methyl-2-propanthiol und entsteht auch bei der Reaktion von Zinndichlorid mit (tert-Butylthio)trimethylsilan. 1 und 2 liegen in Lösung als PR2- bzw. SR-verbrückte Dimere vor. Kernresonanzspektren zeigen, daß bei dem cyclischen \documentclass{article}\pagestyle{empty}\begin{document}$ \mathop {\rm P}\limits^ + - \mathop {\rm S}\limits^{\rm - } {\rm n} $\end{document}-Ylid 1 im Gegensatz zu 2 auch in Ethern keine raschen Platzwechselvorgänge (Brücke/terminal) ablaufen.
    Additional Material: 1 Tab.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/cber.19851180321
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
    Paper (German National Licenses)
    Fulltext
  • 67
    Electronic Resource
    Electronic Resource
    Regioselektive Addition von Grignard-Reagenzien an 3-Methoxy- und 3-Nitrophthalsäureanhydrid (1985)
    Weinheim : Wiley-Blackwell
    Berichte der deutschen chemischen Gesellschaft 118 (1985), S. 1058-1070 
    Details
    ISSN: 0009-2940
    Keywords: Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Description / Table of Contents: Regioselective Addition of Grignard Reagents to 3-Methoxy- and 3-Nitrophthalic AnhydrideThe regioselectivity in the addition of the grignard reagents 5a and 6a to the anhydrides 1 and 2 is determined by the solvent system: in a highly selective manner (3: 97), the meta carbonyl group is attacked in tetrahydrofuran/tetramethylethylenediamine, while predominant, but relatively unselective (maximum 78:22) addition to the ortho carbonyl group is observed in diethyl ether. The influence of the solvent system on the regioselectivity is discussed. The LUMO-coefficients of the carbonyl carbon atoms in 1 and 2 were calculated.
    Notes: Die Addition der Grignard-Reagenzien 5a und 6a an die Anhydride 1 und 2 wird entscheidend vom Reaktionsmedium beeinflußt: in Tetrathydrofuran/Tetramethylethylendiamin wird hochselektiv (3: 97) die meta-ständige, in Diethylether dagegen überwiegend, aber mit nur geringer Selektivität (maximal 78: 22), die ortho-Carbonylgruppe angegriffen. Die Strukturen der dabei erhaltenen Addukte werden durch Umwandlung in die Ester 7-10, in die Lactone 11 sowie in die Ketone 12 und 13 bewiesen. Im Zusammenhang mit dem Versuch, die lösungsmittelabhängige Regioselektivität zu interpretieren, wurden die LUMO-Koeffizienten der Carbonylkohlenstoff-atome in 1 und 2 berechnet.
    Additional Material: 3 Tab.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/cber.19851180323
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
    Paper (German National Licenses)
    Fulltext
  • 68
    Electronic Resource
    Electronic Resource
    Cyanphosphorverbindungen, 8. Das ungewöhnliche Anion P2C10N102- (1985)
    Weinheim : Wiley-Blackwell
    Berichte der deutschen chemischen Gesellschaft 118 (1985), S. 1078-1085 
    Details
    ISSN: 0009-2940
    Keywords: Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Description / Table of Contents: Cyanophosphorus Compounds, 8. The Unusual Anion P2C10N102-The reaction P(CN)3 + CN- (as [18]crown-6-sodium salt) leads via the spectroscopically identified P(CN)4 - to a disproportionation PIII → PI + PV. P(CN)2 - and P2C10N102- (1) have been isolated as products (with Ph3PCHPPh3 + as counter ion). In the latter an anionic aminomalononitrile bridge connects a dicyanophosphino and a pentacyanophosphate group, -P(CN)2 and - P(CN)5-, respectively.
    Notes: Die Reaktion P(CN)3 + CN- (als [18]Krone-6-Natriumsalz) führt über das nur spektroskopisch erkennbare P(CN)4- zur Disproportionierung PIII → PI + PV. Als Produkte können (mit Ph3PCHPPh3 + als Kation) P(CN)2- und P2C10N102- (1) gefaßt werden. In letzterem sind ein Dicyanphosphino-und ein Pentacyanophosphatrest, -P(CN)2 bzw. - P(CN)5-, über eine anionische Aminomalononitrilbrücke miteinander verbunden.
    Additional Material: 2 Ill.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/cber.19851180325
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
    Paper (German National Licenses)
    Fulltext
  • 69
    Electronic Resource
    Electronic Resource
    Addition von Aldehyden an aktivierte Doppelbindungen, XXXV. α-Ketosäuren als Äquivalent für Aldehyde in der Thiazoliumsalz-katalysierten Addition (1985)
    Weinheim : Wiley-Blackwell
    Berichte der deutschen chemischen Gesellschaft 118 (1985), S. 1115-1125 
    Details
    ISSN: 0009-2940
    Keywords: Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Description / Table of Contents: Addition of Aldehydes to Activated Double Bonds, XXXV. α-Keto Acids as an Equivalent for Aldehydes in the Thiazolium Salt-Catalyzed Additionα-Keto acids can be used instead of aldehydes in the thiazolium salt-catalyzed addition to vinyl ketones. The yields of γ-diketones 1-7 resulting from the aliphatic α-keto acids are equivalent with those obtained from the aldehydes. The diketo acids 9-19 are prepared from the easily accessible 2-oxodiacids. Phenylpyruvic acids are easier to prepare than the phenylacetalehydes and give better yields compared with the corresponding aldehydes in the addition to vinyl ketones leading to the γ-diketones 20-29. These diketones are converted to cyclopentenones. The dihydrofurylglyoxylic ester 40 leads to the diketone 43, which is converted to the diketone 44. There is no aldehyde known equivalent to that keto acid.
    Notes: α-Ketosäuren können anstelle von Aldehyden in die Thiazoliumsalz-katalysierte Addition an Vinylketone eingesetzt werden. So entstehen die γ-Diketone 1-7 aus den α-Ketosäuren der aliphatischen Reihe in Ausbeuten, die der Aldehydaddition entsprechen. Aus den gut zugänglichen 2-Oxodisäuren werden die Diketosäuren 9-19 erhalten. Phenylbrenztraubensäuren sind besser als Phenylacetaldehyde zu synthetisieren und liefern in der Addition an Vinylketone zu den γ-Diketonen 20-29 bessere Ausbeuten. Diese Diketone wurden in Cyclopentenone übergeführt. Aus dem Dihydrofurylglyoxylsäure-ethylester 40 kann das Diketon 43 und daraus das Diketon 44, erhalten werden, ein entsprechender Aldehyd ist nicht bekannt.
    Additional Material: 3 Tab.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/cber.19851180328
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
    Paper (German National Licenses)
    Fulltext
  • 70
    Electronic Resource
    Electronic Resource
    Masthead (1985)
    Weinheim : Wiley-Blackwell
    Berichte der deutschen chemischen Gesellschaft 118 (1985) 
    Details
    ISSN: 0009-2940
    Keywords: Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/cber.19851180501
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
    Paper (German National Licenses)
    Fulltext
  • 71
    Electronic Resource
    Electronic Resource
    Heterocyclische 8π-Systeme, 16. Eliminierung an 2-Alkoxy-3-hydroxyindolinen (1985)
    Weinheim : Wiley-Blackwell
    Berichte der deutschen chemischen Gesellschaft 118 (1985), S. 1726-1731 
    Details
    ISSN: 0009-2940
    Keywords: Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Heterocyclic 8π-Systems, 16. Elimination Reactions of 2-Alkoxy-3-hydroxyindolinesThermolysis of 2-ethoxy-3-hydroxyindolines 1a-f affords oxindoles 3a-f as main products and the corresponding 3-indolinones 2a-f as by-products. The reaction course via indole 2,3-oxide intermediates is discussed. For this reason rearrangement reactions of 3-hydroxyindoleninium salts 4a, f are investigated.
    Additional Material: 3 Tab.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/cber.19851180439
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
    Paper (German National Licenses)
    Fulltext
  • 72
    Electronic Resource
    Electronic Resource
    Chirale Lactole, IV. Selektivitäten bei Acetalisierungsreaktionen enantiomerenreiner Lactole am Beispiel von Octahydro-8,9,9-trimethyl-5,8-methano-2H-1-benzopyran-2-ol (1985)
    Weinheim : Wiley-Blackwell
    Berichte der deutschen chemischen Gesellschaft 118 (1985), S. 1733-1745 
    Details
    ISSN: 0009-2940
    Keywords: Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Description / Table of Contents: Chiral Lactols, IV. Selectivities in Acetal Formation Reactions of Enantiomerically Pure Lactols using Octahydro-8,9,9-trimethyl-5,8-methano-2H-1-benzopyran-2-ol as a ModelA synthesis of the lactol 1 is described and its application as a reagent for the resolution of racemates is demonstrated in several examples. By means of X-ray and conformation analysis a general rule is given, which allows to predict the absolute configuration of acyclic alkyl-aryl-carbinols from the course of acetal formation between an enantiomerically pure lactol and the racemic alcohol.
    Notes: Eine Synthese für das Lactol 1 wird beschrieben und seine Eignung als Reagens zur Racemattrennung an einigen Beispielen gezeigt. Aufgrund einer Röntgenstruktur und konformationsanalytischer Überlegungen wird eine allgemeine Regel erarbeitet, nach welcher die Absolutkonfiguration acyclischer Alkyl-aryl-carbinole aus dem Verlauf der Acetalisierungsreaktion eines enantiomerenreinen Lactols mit dem racemischen Alkohol vorhergesagt werden kann.
    Additional Material: 1 Ill.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/cber.19851180502
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
    Paper (German National Licenses)
    Fulltext
  • 73
    Electronic Resource
    Electronic Resource
    Aufbau Germylidin-verbrückter Drei- und Vierkerncluster (1985)
    Weinheim : Wiley-Blackwell
    Berichte der deutschen chemischen Gesellschaft 118 (1985), S. 1746-1757 
    Details
    ISSN: 0009-2940
    Keywords: Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Description / Table of Contents: Buildup of Germylidyne-bridged Tri- and Tetranuclear ClustersReaction of organogermanium trihalides with KCo(CO)4 yields the trinuclear clusters RGeCo3(CO)9 (1, R = Me, Ph, tBu) as well as the new tetranuclear clusters (RGe)2Co4(CO)11 (3, R = Ph, tBu). The dinuclear complexes LnM — GeI2 — MLn (4-6, = FeCp(CO)2, Co(CO)4, NiCpCO) resulting from insertion of GeI2 into metal-metal bonds react with KCo(CO)4 to form the clusters LnM — GeCO3(CO)9 (7-9). Metal exchange reactions produce the hetero tetranuclear clusters (tBuGe)2Co3(CO)8M′Ln = MoCp(CO)2, NiCp). Crystal structure analyses were performed for Cp(CO)2Fe — GeCo3(CO)9 (7) and (tBuGe)2Co3(CO)8NiCp (11).
    Notes: Die Umsetzung von Organogermaniumtrihalogeniden mit KCo(CO)4 liefert sowohl die Dreikerncluster RGeCo3(CO)9 (1, R = Me, Ph, tBu) als auch die neuen Vierkerncluster (RGe)2Co4(CO)11 (3, R = Ph, tBu). Die durch Insertion von Gel2 in Metall-Metall-Bindungen entstehenden Zweikernkomplexe LnM — GeI2 — MLn (4-6, MLn = FeCp(CO)2, Co(CO)4, NiCpCO) setzen sich mit KCo(CO)4 zu den Clustern LnM — GeCO3(CO)9 (7-9) um. Metallaustauschreaktionen liefern die Heterovierkerncluster (tBuGe)2Co3(CO)8M′Ln (10, 11, M′Ln = MoCp(CO)2, NiCp). Von Cp(CO)2Fe — GeCo3(CO)9 (7) und (tBuGe)2Co3(CO)8NiCp (11) wurden Kristallstrukturanalysen durchgeführt.
    Additional Material: 2 Ill.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/cber.19851180503
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
    Paper (German National Licenses)
    Fulltext
  • 74
    Electronic Resource
    Electronic Resource
    1,3-Dithienium- und 1,3-Dithioleniumsalze, II. Synthese monocyclothioacetalisierter 1,3-Diketone aus Silylenolethern (1985)
    Weinheim : Wiley-Blackwell
    Berichte der deutschen chemischen Gesellschaft 118 (1985), S. 1798-1808 
    Details
    ISSN: 0009-2940
    Keywords: Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Description / Table of Contents: 1,3-Dithienium- and 1,3-Dithiolenium Salts, II. Synthesis of Monocyclothioacetalized 1,3-Diketones from Silyl Enol EthersThe 1,3-dithienium and 1,3-dithiolenium salts 3, available from the dithiols 1 or the cyclic thioacetals 4 (n = 2, 3) by reaction with the acyl chlorides 2, trityl tetrafluoroborate (5), and sulfuryl chloride (7), react in good yields with the silyl enol ethers 10 to give the new monocyclothioacetalized 1,3-Diketones 11. The synthetic of 11 as partially protected 1,3-Diketones is demonstrated exemplarily by dethioacetalization to the 1,3-dicarbonyl compounds 13.
    Notes: Die aus den Dithiolen 1 oder den cyclischen Thioacetalen 4 (n = 2, 3) durch Umsetzung mit den Acylchloriden 2, Trityl-tetrafluoroborat (5) und Sulfurylchlorid (7) erhältlichen 1,3-Dithienium-bzw. 1,3-Dithioleniumsalze 3 reagieren in guten Ausbeuten mit den Silylenolethern 10 zu den neuen monocyclothioacetalisierten 1,3-Diketonen 11. Das synthetische Potential von 11 als partiell geschützten 1,3-Diketonen wird exemplarisch durch Dethioacetalisierung zu den 1,3-Dicarbonylverbindungen 13 demonstriert.
    Additional Material: 2 Tab.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/cber.19851180507
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
    Paper (German National Licenses)
    Fulltext
  • 75
    Electronic Resource
    Electronic Resource
    Syntheses and ENDOR studies of selectively deuterated galvinoxyl radicals. Complete Determination of the 13C hyperfine coupling constants of Coppinger's radical (1985)
    Weinheim : Wiley-Blackwell
    Berichte der deutschen chemischen Gesellschaft 118 (1985), S. 1782-1797 
    Details
    ISSN: 0009-2940
    Keywords: Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Description / Table of Contents: Synthesen und ENDOR-Untersuchungen selektiv deuterierter Galvinoxyl-Radikale. Vollständige Bestimmung der 13C-Hyperfeinkopplungskonstanten von Coppingers RadikalDie Synthese einiger selektiv deuterierter Galvinole und deren Oxidation zu den korrespondierenden Galvinoxyl-Radikalen, z.B. Coppingers Radikal und Yangs Biradikal, wird beschrieben. Am Beispiel der Dublettradikale wird gezeigt, daß 13C-ENDOR-Spektroskopie auch ohne 13C-Isotopenanreicherung möglich ist. Im Falle von Coppingers Radikal gelang die vollständige Ermittlung der 13C-Hyperfeinkopplungskonstanten. Die ENDOR-Untersuchung von selektiv deuteriertem Yangs Biradikal in glasartiger Matrix erlaubte eine eindeutige Zuordnung der Singale zu Molekülpositionen, und es ließen sich Rückschlüsse auf die Radikalsymmetrie und die behinderte Rotation der tert-Butylgruppen ziehen. In den ENDOR-Spektren regellos orientierter Bisgalvinoxyl-Biradikale im Triplettzustand findet man scharfe Signale bei den freien Kern-Zeeman-Frequenzen, die von NMR-Übergängen im Ms = 0-Spinzustand herrühren. Es wird gezeigt, daß die betreffenden Deuterium-Signale infolge der Quadrupolwechselwirkung der Deuteriumkerne aufgespalten sind.
    Notes: The synthesis of selectively deuterated galvinols is described. Oxidation results in the formation of the respective galvinoxyl free radicals, e.g., Coppinger's radical and Yang's biradical. It is shown that 13C ENDOR signals can be detected for the doublet radicals without 13C labelling, i.e., in natural abundance. The complete set of 13C hyperfine coupling constants of Coppinger's radical could be determined. The ENDOR study of selectively deuterated Yang's biradical in a glassy matrix allowed an unambiguous assignment of the signals to molecular positions, and conclusions with respect to the symmetry of the radical and the hindered rotation of the tert-butyl groups could be drawn. Randomly oriented bisgalvinoxyl biradicals in the triplet spin state give rise to sharp ENDOR lines at the free nuclear Zeeman frequencies due to NMR transitions in the Ms = 0 electron spin manifold, and it is demonstrated that the respective 2H ENDOR lines show quadrupole splittings.
    Additional Material: 4 Ill.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/cber.19851180506
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
    Paper (German National Licenses)
    Fulltext
  • 76
    Electronic Resource
    Electronic Resource
    Darstellung von (η6-Aren)2Cr2(CO)3-Komplexen mit einer formalen Cr ≡ Cr-Dreifachbindung aus η6-ArenCr(CO)2NCCH3 (1985)
    Weinheim : Wiley-Blackwell
    Berichte der deutschen chemischen Gesellschaft 118 (1985), S. 1825-1835 
    Details
    ISSN: 0009-2940
    Keywords: Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Description / Table of Contents: Synthesis of (η6-arene)2Cr2(CO)3 Complexes Containing a Formal Cr ≡ Cr Triple Bond Starting from η6-areneCr(CO)2NCCH3The photochemical reaction of η6-ArCr(CO)3 (Ar = benzene, toluene, m-xylene, mesitylene, methyl benzoate, and fluorobenzene) with acetonitrile in hexane or p-tolunitrile in THF, resp., yields complexes η6-ArCr(CO)2NCR (1 - 10). Solutions of the red acetonitrile complexes yield on warming or UV photolysis by dissoziation of the nitrile and one CO ligand in the presence of benzene the new black coordination compounds (η6-Ar)2Cr2(CO)3 (11 - 16). The spectra and an X-ray structure determination of the benzene derivative 11 verify a Cr2-unit with a formal triple bond bridged by three CO ligands. The asymmetric unit of 11 contains two halves of molecules with Cr — Cr distances of 222.6 and 221.6 pm.
    Notes: Bei der photochemischen Umsetzung von η6-ArCr(CO)3 (Ar = Benzol, Toluol, m-Xylol, Mesitylen, Benzoesäure-methylester und Fluorbenzol) mit Acetonitril in Hexan bzw. p-Tolunitril in THF entstehen Komplexe η6-ArCr(CO)2NCR (1-10). Lösungen der roten Acetonitrilkomplexe bilden in der Wärme oder bei UV-Bestrahlung unter Abspaltung des Nitril- und eines CO-Liganden in Gegenwart von Benzol die neuen schwarzen Komplexe (η6-Ar)2Cr2(CO)3 (11-16). Die Spektren und die Röntgenstrukturanalyse des Benzolderivats 11 belegen eine von drei CO-Liganden verbrückte, formal eine Dreifachbindung aufweisende Cr2-Einheit. Die asymmetrische Enheit von 11 enthält zwei Molekülhälften mit Cr — Cr-Abständen von 222.6 bzw. 221.6 pm.
    Additional Material: 1 Ill.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/cber.19851180509
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
    Paper (German National Licenses)
    Fulltext
  • 77
    Electronic Resource
    Electronic Resource
    Reaction of 1-oxa-3-azabutatrienium salts with tertiary carboxamides (1985)
    Weinheim : Wiley-Blackwell
    Berichte der deutschen chemischen Gesellschaft 118 (1985), S. 1876-1886 
    Details
    ISSN: 0009-2940
    Keywords: Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Description / Table of Contents: Reaktion von 1-Oxa-3-azabutatrienium-Salzen mit tertiären CarbonsäureamidenDie α-Chlorisocyanate 1 reagieren mit tertiären Carbonsäureamiden oder Acyliminen 3 in Gegenwart von Lewis-Säuren (SbCl5, FeCl3) unter milden Bedingungen zu den aminosubstituierten 2-Azaallenium-Salzen 5a - t. Die nur mäßig starken Elektrophile 5 setzen sich mit Methanol zu den Acetalen 8 und 10 um. Eine Röntgenstrukturanlyse von 5a zeigt, daß die -Einheit dieses Moleküls gewinkelt ist (128°). Es besteht eine Proportionalität zwischen der Wellenzahl der antisymmetrischen Valenzschwingung von 2-Azaallenium-Salzen und dem -Bindungswinkel. Die durch die sp2-Kohlenstoffe der -Einheit von 5a definierten Ebenen stehen nahezu senkrecht (84°) aufeinander.
    Notes: α-Chloro isocyanates 1 react with tertiary carboxamides or acylimines 3 in the presence of Lewis acids (SbCl5, FeCl3) to give the amino-substituted 2-azaallenium salts 5a - t under mild conditions. With methanol the moderately strong electrophiles 5 afford the acetals 8 and 10. According to an X-ray structural analysis, the C = N = C unit of 5a is bent by 128°. There exists a linear relationship between the wave number of the antisymmetric stretching vibration of 2-azaallenium salts and the bond angle. The planes defined by the sp2 carbons of the moiety of 5a are almost perpendicular (84°) with respect to each other.
    Additional Material: 2 Ill.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/cber.19851180513
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
    Paper (German National Licenses)
    Fulltext
  • 78
    Electronic Resource
    Electronic Resource
    Bildung von Oxetanen bei der photosensibilisierten Oxidation von Enaminen (1985)
    Weinheim : Wiley-Blackwell
    Berichte der deutschen chemischen Gesellschaft 118 (1985), S. 1927-1935 
    Details
    ISSN: 0009-2940
    Keywords: Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Description / Table of Contents: Formation of Oxetanes via Photo-sensitized Oxidation of EnaminesPhotooxidations of the enamines 1 and 5 in toluene give rise to the formation of the usual reaction products. In methanol, however, the oxetanes 8 and 13, respectively, are isolated as the main photooxidation products. Both the mechanism of their formation as well as some reactions of 8 and 13 are discussed. Oxidation of 13 with m-chloroperbenzoic acid produces the aldehyde 15 via a multi-step reaction.
    Notes: Die Photooxidation der Enamine 1 bzw. 5 in Toluol liefert die erwarteten Reaktionsprodukte. In Methanol entstehen dagegen die Oxetane 8 bzw. 13 als Hauptprodukt der Photooxidation. Die Reaktionen dieser Verbindungen werden beschrieben. Die Oxidation von 13 mit m-Chlorperbenzoesäure führt über einen mehrstufigen einheitlichen Reaktionsablauf zum Aldehyd 15. Der Bildungsmechanismus der Oxetane 8 und 13 wird diskutiert.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/cber.19851180517
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
    Paper (German National Licenses)
    Fulltext
  • 79
    Electronic Resource
    Electronic Resource
    Die Elektronenstruktur von 1,4-disubstituierten Butantetronen (1985)
    Weinheim : Wiley-Blackwell
    Berichte der deutschen chemischen Gesellschaft 118 (1985), S. 1917-1926 
    Details
    ISSN: 0009-2940
    Keywords: Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Description / Table of Contents: The Electronic Structure of 1,4-Disubstituted ButanetetronesThe He(I) photoelectron (PE) spectra of the disubstituted butanetetrones 1 a - e have been recorded. The assignment of the first PE bands is based on semiempirical calculations. For 1 a - e the first bands could be assigned to ionization events from lone pair combinations on the oxygen atoms and in the case of 1 b - e additionally to ionizations from π-orbitals localized on the aromatic rings. The comparison between the PE bands of 1 d, 1,3-diphenyl-1,2,3-propanetrione, benzil, and benzophenone yields the result that the energy split between the n-orbital energies con-verges towards a value of about 3 eV. The interactions among the lone pairs and between lone pairs and the σ frame in 2 b - d are discussed, based on INDO calculations using localized orbitals.
    Notes: Die He(I)-Photoelektronen(PE)-Spektren der 1,4-disubstituierten Butantetrone 1 a - e wurden gemessen und anhand semiempirischer Rechnungen zugeordnet. Bei 1 a - e wurden die ersten Banden Ionisationen aus Linearkombinationen der einsamen Elektronenpaare an den Sauerstoffen und im Fall von 1 b - e noch zusätzlich Ionisationen aus den aromatischen π-Orbitalen zugeordnet. Der Vergleich zwischen den PE-Banden von 1 d, 1,3-Diphenyl-1,2,3-propantrion, Benzil und Benzophenon zeigt, daß die Aufspaltung zwischen den n-Orbitalenergien einem Grenzwert von etwa 3 eV zustrebt. Die Wechselwirkung zwischen den n-Orbitalen, den n-Orbitalen und dem σ-Gerüst (Through-Space- und Through-Bond-Wechselwirkung) in den vic. Di-, Tri- und Tetra-ketonen 2 b - d wird anhand von lokalisierten Orbitalen, die nach der INDO-Methode erhalten werden, diskutiert.
    Additional Material: 7 Ill.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/cber.19851180516
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
    Paper (German National Licenses)
    Fulltext
  • 80
    Electronic Resource
    Electronic Resource
    Azaborolinyl-Komplexe, XVI. Synthese und Untersuchung von (1,2-Azaborolinyl)tricarbonyl-Komplexen des Chroms, Molybdäns und Wolframs (1985)
    Weinheim : Wiley-Blackwell
    Berichte der deutschen chemischen Gesellschaft 118 (1985), S. 1949-1958 
    Details
    ISSN: 0009-2940
    Keywords: Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Description / Table of Contents: Azaborolinyl Complexes, XVI. Synthesis and Investigation of (1,2-Azaborolinyl)tricarbonyl Complexes of Chromium, Molybdenum, and Tungsten1-tert-Butyl-2-methyl-1,2-azaborolinyllithium reacts with the hexacarbonyls of chromium, molybdenum, and tungsten to give the complex salts Li[(Ab)M(CO)3] (Ab = azaborolinyl ligand, M = Cr (2), Mo (3), and W (4)). With Me3ECl (E = Ge, Sn, Pb) they form the corresponding germyl, stannyl, and plumbyl derivatives. The molecular and crystal structures of (Ab)(CO)3Cr—SnMe3 (2b) and (Ab)(CO)3Mo—SnMe3 (3b) show the azaborolinyl rings to be pentahapto-bonded, inspite of a small folding of the rings, leading to a longer distance of the boron atoms to the metal atoms. The IR, 1H, 11B, and 13C NMR data prove equivalent structures for the other complexes. The existence of enantiomers in the cell results from the crystal structure investigations of 2b and 3b and is caused by the prochiral character of the azaborolinyl rings.
    Notes: 1-tert-Butyl-2-methyl-1,2-azaborolinyllithium reagiert mit den Hexacarbonylen von Chrom, Molybdän und Wolfram zu den komplexen Salzen Li[(Ab)M(CO)3] (Ab = Azaborolinyl-Ligand, M = Cr (2), Mo (3) und W (4)). Diese bilden mit Me3ECl (E = Ge, Sn, Pb) die entsprechenden Germyl-, Stannyl- und Plumbylderivate. Die Molekül- und Kristallstrukturen von (Ab)(CO)3Cr—SnMe3 und (2b) und (Ab)(CO)3Mo—SnMe3 (3b) weisen die Azaborolinylringe als pentahapto-gebunden aus, trotz einer leichten Faltung der Ringe, durch die die Boratome einen größeren Abstand zu den Metallatomen erreichen. Die IR-, 1H-, 11B- und 13C-NMR-Daten beweisen äquivalente Strukturen für die übrigen Komplexe. Aus den Kristallstrukturuntersuchungen von 2b und 3b geht die Anwesenheit von Enantiomeren in der Zelle hervor, verursacht durch den prochiralen Charakter der Azaborolinylringe.
    Additional Material: 4 Ill.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/cber.19851180519
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
    Paper (German National Licenses)
    Fulltext
  • 81
    Electronic Resource
    Electronic Resource
    2,4-Diazabicyclo[3.3.1]nonan-Gerüste aus cis-Benzoltrioxid (1985)
    Weinheim : Wiley-Blackwell
    Berichte der deutschen chemischen Gesellschaft 118 (1985), S. 2044-2078 
    Details
    ISSN: 0009-2940
    Keywords: Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Description / Table of Contents: 2,4-Diazabicyclo[3.3.1]nonane Skeletons from cis-Benzene TrioxideBy treating cis-benzene trioxide (1) with guanidine in buffered tert-butyl alcohol solution the 1:1-adducts DL-(1α,2β,4β,5α,6α,10α)- 8-imino-3-oxa-7,9-diazatricyclo[4.3.1.02,4]decane-5,10-diol (13a) and DL-(1α,2α,3β,5β,6α,7α)- 9-imino-4-oxa-8,10-diazatricyclo[5.3.0.03,5]decane-2,6-diol (12a) resulting from 1,3(1,2)-bridging in 1 are obtained in 88 - 91% (9 - 12%) yields. Trifluoroacetamidine (acetamidine) is also selectively 1,3-added to 1. From 13a via generally regiospecific hydrolysis (26a), thiolysis (30a, d) ammonolysis (34a), hydrazinolysis (34d), and HCl-/HBr- addition (39a, c) access to highly functionalised 2,4-diazabicyclo[3.3.1]nonane derivatives is opened. During the “ring-chain tautomerism” observed for 26a and 34d (28a, 36d) the adamantoid orthocarbonic acid intermediates (27a, 35d) cannot be identified directly. The spectroscopic structure elucidations (not always unequivocal because i.a. of conformational flexibility of the skeletons) are confirmed by X-ray structural analysis for 29f, 36e, 38, und 43.
    Notes: Bei der Umsetzung von cis-Benzoltrioxid (1) mit Guanidin in gepufferter tert-Butylalkohol-Lösung werden mit 88 - 91% (9 - 12%) Ausbeute die aus der 1,3(1,2)-Überbrückung in 1 hervorgehenden 1:1-Addukte DL-(1α,2β,4β,5α,6α,10α)- 8-Imino-3-oxa-7,9-diazatricyclo[4.3.1.02,4]decan5,10-diol (13a) und DL-(1α,2α,3β,5β,6α,7α)- 9-Imino-4-oxa-8,10-diazatricyclo[5.3.0.03,5]decan-2,6-diol (12a) gewonnen. Auch Trifluoracetamidin (Acetamidin) wird an 1 bevorzugt 1,3-addiert. Aus 13a gewinnt man durch jeweils regiospezifische Hydrolyse (26a), Thiolyse (30a, d), Ammonolyse (34a), Hydrazinolyse (34d) und HCl/HBr-Addition (39a, c) Zugang zu hochfunktionalisierten 2,4-Diazabicyclo[3.3.1]nonan-Derivaten. Bei der für 26a und 34d beobachteten „Ring-Ketten-Tautomerie“ (28a, 36d) sind die adamantoiden Orthokohlensäure-Intermediate (27a, 35d) nicht nachweisbar. Die u. a. wegen der konformativen Flexibilität der Gerüste nicht immer eindeutigen spektroskopischen Strukturzuordnungen werden durch Röntgenstrukturanalysen für 29f, 36e, 38 und 43 gesichert.
    Additional Material: 4 Ill.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/cber.19851180527
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
    Paper (German National Licenses)
    Fulltext
  • 82
    Electronic Resource
    Electronic Resource
    Untersuchungen an Diazoverbindungen und Aziden, 58. Dikation-ether, 5. Formamidinium-substituierte Diazophosphoryl-Verbindungen: Synthese, Eigenschaften und Reaktionen zu Tetrazolen (1985)
    Weinheim : Wiley-Blackwell
    Berichte der deutschen chemischen Gesellschaft 118 (1985), S. 2105-2117 
    Details
    ISSN: 0009-2940
    Keywords: Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Description / Table of Contents: Investigations on Diazo Compounds and Azides, 58. Dication Ethers, 5. Formamidinium-substituted Diazophosphoryl Compounds: Synthesis, Properties, and Reactions Leading to TetrazolesElectrophilic diazoalkane substitution of diazophosphoryl compounds 4a - c by bis(formamidinium) ethers 3a, b leads to formamidinium-substituted (diazomethyl)phosphoryl compounds 5. These can also be considered as alkenediazonium salts, but the contribution from this resonance structure is low according to 1H NMR and IR data. Reaction of 5a - c with another equivalent of 4a - c under slightly modified conditions yields 2-vinyl-2H-tetrazoles 6 and 7. The identity of the tetrazoles has been confirmed by X-ray structure analysis of 6c as well as by thermolysis of 6c leading to pyrazole 12 which then was hydrolyzed to give the NH-pyrazole 13.
    Notes: Die Diazophosphoryl-Verbindungen 4a - c reagieren mit den Bis(formamidinium)ethern 3a, b im Sinne einer elektrophilen Diazoalkan-Substitution zu Formamidinium-substituierten (Diazomethyl)phosphoryl-Verbindungen 5. Diese lassen sich auch als Olefindiazoniumsalze auffassen, jedoch deuten 1H-NMR- und IR-Daten nur auf einen geringen Anteil dieses Bindungszustandes hin. Unter leicht modifzierten Reaktionsbedingungen reagieren 5a - c mit einem weiteren Äquivalent von 4a - c zu den 2-Vinyl-2H-tetrazolen 6 und 7. Die Identität der Tetrazole wird durch eine Röntgenstrukturanalyse von 6c sowie die Thermolyse von 6c zum Pyrazol 12 und dessen Hydrolyse zum NH-Pyrazol 13 belegt.
    Additional Material: 2 Ill.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/cber.19851180530
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
    Paper (German National Licenses)
    Fulltext
  • 83
    Electronic Resource
    Electronic Resource
    The molecular and electronic structure of dipiperidinosquaraine (1985)
    Weinheim : Wiley-Blackwell
    Berichte der deutschen chemischen Gesellschaft 118 (1985), S. 2118-2126 
    Details
    ISSN: 0009-2940
    Keywords: Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Description / Table of Contents: Molekulare und elektronische Struktur von DipiperidinoquadratainDipiperidinoquadratain (9) kristallisiert im orthorhombischen Gitter, Raumgruppe Pnab, mit 4 Molekülen in einer Elementarzelle mit den Abmessungen a = 7.1798(9), b = 9.5362(8) und c = 18.788(2) Å. Das Molekül liegt auf einem Symmetriezentrum, d.h. der Vierring (C — C = 1.456(1) Å) ist genau planar; die Stickstoff- und Sauerstoffatome sind fast mit dem Ring coplanar, mit C — O = 1.2396(7) und C — N = 1.3112(7) Å. Sowohl die experimentellen als auch die theoretischen Daten zeigen beachtliche C — N- und C — O-π-Bindungen, aber nur eine geringfügige C — C-π-Bindung im Quadratainsystem. Die Berechnungen ergeben starke 1,3-abstoßende Wechselwirkungen im Vierring. Ringfaltung, ein sonst üblicher Mechanismus bei der Vermeidung solcher Abstoßungen, wird hier durch die starke C — N-π-Bindung verhindert.
    Notes: Dipiperidinosquaraine (9) crystallizes in the orthorhombic system, space group Pnab, with four molecules in a cell of dimensions a = 7.1798(9), b = 9.5362(8), and c = 18.788(2) Å. The molecule is located over a center of symmetry, so the four-membered ring (C - C = 1.456(1) Å av) is exactly planar; the nitrogen and oxygen atoms are nearly coplanar with the ring, with C — O = 1.2396(7) and C — N = 1.3112(7) Å. Both experimental and theoretical evidence indicates the presence of considerable C — N and C — O π-bonding, but only a small amount of C — C π-bonding in the squaraine system. The calculations indicate the presence of strong 1,3-repulsive interactions within the four-membered ring. Ring puckering, which is a common mechanism to alleviate these repulsions, is prevented here by the extensive C — N π-bonding.
    Additional Material: 3 Ill.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/cber.19851180531
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
    Paper (German National Licenses)
    Fulltext
  • 84
    Electronic Resource
    Electronic Resource
    The He(Iα) PE spectra and electronic absorption spectra of hexafluorocyclobutanone and of tetrafluoro-1,2-cyclobutane-dione (1985)
    Weinheim : Wiley-Blackwell
    Berichte der deutschen chemischen Gesellschaft 118 (1985), S. 2127-2133 
    Details
    ISSN: 0009-2940
    Keywords: Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Description / Table of Contents: Die He(Iα)-PE-Spektren und Elektronenabsorptionsspektren von Hexafluorcyclobutanon und Tetrafluor-1,2-cyclobutandionDie He(Iα)-PE-Spektren und die Elektronenabsorptionsspektren von Hexafluorcyclobutanon (3) und Tetrafluor-1,2-cyclobutandion (4) wurden gemessen. Die Zuordnung der ersten Banden beider Spektrentypen basiert hauptsächlich auf der Korrelation mit den entsprechenden Spektren der unsubstituierten Verbindungen Cyclobutanon (1) und 1,2-Cyclobutandion (2) sowie auf den Resultaten semiempirischer Rechnungen. Die Banden in den PE-Spektren von 3 und 4 werden im Vergleich zu den PE-Banden von 1 und 2 durch den Perfluor-Effekt um 1.6 bzw. 1.5 eV zu höheren Energien verschoben. Vergleicht man die Energie der ersten Bande in den Elektronenspektren von 1 und 3 bzw. 2 und 4, so findet man, daß diese Bande bathochrom um etwa 5000 cm-1 durch die Perfluor-Substitution verschoben wird. Dies wird dadurch erklärt, daß beim Ersatz der H-Atome durch F-Atome die Energie des LUMOs (π*) stärker abgesenkt wird als die des HOMOs (n).
    Notes: The He(Iα) PE and the electronic absorption spectra of hexafluorocyclobutanone (3) and tetrafluoro-1,2-cyclobutanedione (4) have been recorded. The assignment of the observed bands in both types of spectra is mainly based on the correlation with the corresponding spectra of the parent compounds cyclobutanone (1) and 1,2-cyclobutanedione (2), and in addition on the results of semiempirical calculations. As a result of the perfluoro effect, the bands in the PE spectra of 3 and 4 are shifted towards higher ionization energies by 1.6 eV and 1.5 eV relative to the corresponding bands in the PE spectra of 1 and 2. A comparison of the positions of the first band in the electronic spectra of 1 and 3, as well as of 2 and 4, shows that this band is shifted bathochromically by about 5000 cm-1 as a consequence of the perfluoro substitution. This is explained as being due to a stronger lowering of the LUMO (π*) energy than that of the HOMO (n) energy, induced by the replacement of the H-by F-atoms.
    Additional Material: 3 Ill.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/cber.19851180532
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
    Paper (German National Licenses)
    Fulltext
  • 85
    Electronic Resource
    Electronic Resource
    Cycloadditionen des 1-(4-Methoxyphenyl)-2,2-dimethylvinyl-Kations an Olefine (1985)
    Weinheim : Wiley-Blackwell
    Berichte der deutschen chemischen Gesellschaft 118 (1985), S. 2974-2992 
    Details
    ISSN: 0009-2940
    Keywords: Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Description / Table of Contents: Cycloadditions of 1-(4-Methoxyphenyl)-2,2-dimethylvinyl Cation to Olefins1-Bromo-1-(4-methoxyphenyl)-2-methyl-1-propene (1) reacts with cyclohexene, cycloheptene, (Z)-cyclooctene and the silver salts AgBF4, via the vinyl cation 2 by cycloaddition to form the cyclobutenes 7b-d. Cyclobutene 8 is obtained from (Z)- and (E)- and (E)-2-butene. Besides the cyclobutene derivatives, the isomeric cyclopropane compound 10d is also formed in the reaction of 1 with (Z)-cyclooctene under the same conditions, with cyclopentene only the cyclopropane derivative is formed. Copper (I) triflate-olefin complexes can be used in place of silver slats to generate the vinyl cation 2, whereby cyclobutenes 7 are formed preferably. - In contrast to vinyl bromide 1, 1-(4-methoxyphenyl)-2-methyl-1-propenyl triflate (5) reacts with cyclopentene, cyclohexene, cyloheptene, (Z)- and (E)-cyclooctene to give mostly the corresponding cyclopropane derivatives 10. The stereoisomeric cyclopropyl compounds 19 are obtained from (Z)- and (E)-2-butene. - The mechanisms of silver-catalysed and silver-free cycloaddition reactions are discussed.
    Notes: 1-Brom-1-(4-methoxyphenyl)-2-methyl-1-propen (1) reagiert mit Cyclohexen, Cyclohepten, (Z)-Cycloocten und den Silbersalzen AgBF4 bzw. AgSbF6 über das Vinylkation 2 unter Cycloaddition überwiegend zu den Cyclobutenen 7b-d. Mit (Z)- und (E)-2- Buten wird das Cyclobuten 8 erhalten. Bei der Umsetzung von 1 unter den gleichen Bedingungen entsteht mit Cyclopenten das Cyclopropanderivat 10a, mit (Z)-Cycloocten entsteht neben dem Cyclobutenderivat 7d die isomere Cyclopropanverbindung 10d. An Stelle der Silbersalze können auch Kupfer(I)-triflat-Olefin-Komplexe zur Erzeugung des Vinylkations 2 verwendet werden, wobei ebenfalls bevorzugt die Cyclobutene 7 erhalten werden. - Im Gegensatz zum Vinylbromid 1 reagiert das 1-(4-Methoxyphenyl)-2-methyl-1-propenyl-triflat (5) mit Cyclopenten, Cyclohexen, Cyclohepten und (Z)- bzw. (E)-Cycloocten überwiegend zu den entsprechenden Cyclopropanderivaten 10. Mit (Z)- und (E)-2-Buten werden die stereoisomeren Cyclopropylverbindungen 19 erhalten. - Die Mechanismen der silbersalzkatalysierten und silberfreien Cycloadditionsreaktionen werden diskutiert.
    Additional Material: 3 Tab.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/cber.19851180731
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
    Paper (German National Licenses)
    Fulltext
  • 86
    Electronic Resource
    Electronic Resource
    Basische Metalle, LVI Reaktionen von (Pentamethylcyclopentadienyl)rhodium(I)-Komplexen mit Dihalogen- und Trihalogenmethanen (1985)
    Weinheim : Wiley-Blackwell
    Berichte der deutschen chemischen Gesellschaft 118 (1985), S. 3032-3040 
    Details
    ISSN: 0009-2940
    Keywords: Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Description / Table of Contents: Basic Metals, LVI. Reactions of (Pentamethylcyclopentadienyl)rhodium(I) Complexes with Dihalo- and TrihalomethanesC5Me5Rh(CO)2 and C5Me5Rh(CO)L (L=PMe3, PMe2Ph, P(OMe)3) react with dihalo- and trihalomethanes to give (pentamethylcyclopentadienyl)rhodium complexes containing CH2X and CHX2 (X=Cl, Br, I, CN) as ligands. The reactions of [C5Me5RhCH2I(L)I] (L=CO, PMe3) with NaOCH3, PMe3, and PPh3 lead in some cases to substitution (e.g., formation of [C5Me5RhCH2OMe(PMe3)I] and [C5Me5Rh(CH2PPh3)(PMe3)I]X), in some cases to cleavage of the Rh - C bond. [C5Me5RhCH2I(CO)I] reacts with CH2(PPh2)2 to form the cyclic ylide complex [Ph2(I)]I.
    Notes: Durch Reaktion von C5Me5Rh(CO)2 und C5Me5Rh(CO)L (L=PMe3, PMe2Ph, P(OMe)3) mit Dihalogen- und Trihalogenmethanen werden (Pentamethylcyclopentadienyl)rhodium-Komplexe mit CH2X und CHX2 (X=Cl, Br, I, CN) als Liganden synthetisiert. Die Umsetzungen von [C5Me5RhCH2I(L)I] (L=CO, PMe3) mit NaOCH3, PMe3 und PPh3 verlaufen teilweise unter Substitution (Bildung z.B. von [C5Me5RhCH2OMe(PMe3)I] und [C5Me5Rh(CH2PPh3)(PMe3)I]X), teilweise aber auch unter Spaltung der Rh - C-Bindung. [C5Me5RhCH2I(CO)I] reagiert mit CH2(PPh2)2 zu dem cyclischen Yild-Komplex [Ph2(I)]I.
    Additional Material: 3 Tab.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/cber.19851180804
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
    Paper (German National Licenses)
    Fulltext
  • 87
    Electronic Resource
    Electronic Resource
    Monoozonolysen von acyclischen konjugierten Dienen (1985)
    Weinheim : Wiley-Blackwell
    Berichte der deutschen chemischen Gesellschaft 118 (1985), S. 3041-3057 
    Details
    ISSN: 0009-2940
    Keywords: Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Description / Table of Contents: Monoozonolyses of Acyclic Conjugated DienesMonoozonolyses of isoprene (1a), 2-methyl-3-phenyl-1,3-butadiene (1b), 2,3-diphenyl-1,3-butadiene (25), and 2,3,4,5-tetramethyl-2,4-hexadiene (34) have been examined in pentane and in methanol. The dienes 1a, b and 25 afforded all possible α,β-unsaturated monoozonides and α,β-unsaturated methoxy hydroperoxides, respectively, whereas diene 34 gave no ozonide and no α,β-unsaturated methoxy hydroperoxide. From the dienes 25 and 34, the corresponding monoepoxides have been formed additionally. The results allow some conclusions concerning the regioselectivity of ozone attack at the unsymmetrically substituted dienes 1a, b as well as concerning the cleavage directions of primary ozonides.
    Notes: Monoozonolysen von Isopren (1a), 2-Methyl-3-phenyl-1,3-butadien (1b), 2,3-Diphenyl-1,3-butadien (25) und 2,3,4,5-Tetramethyl-2,4-hexadien (34) in Pentan und in Methanol wurden untersucht. Die Diene 1a, b und 25 lieferten alle möglichen α,β-ungesättigten Monoozonide bzw. α,β-ungesättigten Methoxyhydroperoxide; das Dien 34 ergab kein Ozonid und kein α,β-ungesättigtes Methoxyhydroperoxid. Aus den Dienen 25 und 34 wurden zusätzlich auch die entsprechenden Monoepoxide erhalten. Die Ergebnisse erlauben Rückschlüsse auf die Regioselektivität des Ozonangriffes an den unsymmetrisch substituierten Dienen 1a, b sowie über die Spaltungsrichtungen von Primärozoniden.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/cber.19851180805
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
    Paper (German National Licenses)
    Fulltext
  • 88
    Electronic Resource
    Electronic Resource
    Photolyse des 9-Azidotriptycens. - Struktur des Dimeren eines extrem gespannten Brückenkopfimins (1985)
    Weinheim : Wiley-Blackwell
    Berichte der deutschen chemischen Gesellschaft 118 (1985), S. 3058-3069 
    Details
    ISSN: 0009-2940
    Keywords: Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Description / Table of Contents: Photolysis of 9-Azidotriptycene. - Structure of the Dimer of a Severely Strained Bridgehead IminePhotolysis of 9-azidotriptycene (4) in cyclohexane affords molecular nitrogen and a dimer of the intermediate bridgehead imine 5 in 69% yield. The dimer is very sensitive towards traces of acid and irradiation in the presence of oxygen. The structure of the dimer is elucidated by spectroscopic methods as well as by an X-ray diffraction analysis. In solution approximately equal amounts of the (racemic) diastereomers 10 A and B are present which interconvert via an energy barrier of ΔG413≠ = ca. 90 kJ · mol-1. In contrast, in the crystalline state only diastereomer 10 A exists. The distereomer 10 A crystallizes as a racemate in the monoclinic space group P21/n (No. 14) with four molecules per cell. As the first step in the formation of 10 A, B we assume a dimerization of the bridgehead imine 5 producing 12 which rearranges to 10 A, B via a proton shift (→13) and subsequent opening of one of the 4H-azepine rings. The results are indicative of some diradical character of the bridgehead imine 5.
    Notes: Die Photolyse des 9-Azidotriptycens (4) in Cyclohexan ergibt neben Stickstoff mit 69% Ausbeute ein Dimeres des intermediären Brückenkopfimins 5. Das Dimere ist sehr empfindlich gegen Säurespuren und Belichten in Gegenwart von Luftsauerstoff. Die Struktur des Dimeren wird spektroskopisch und durch Röntgenbeugungsanalyse aufgeklärt. In Lösung liegen etwa gleiche Mengen der Diastereomeren 10 A und B vor, die sich mit ΔG413≠ =ca. 90 kJ · mol-1 ineinander umwandeln. Im Kristall existiert dagegen nur das Diastereomere 10 A, das als Racemat monoklin in der Raumgruppe P21/n (Nr. 14) mit vier Molekülen in der Elementarzelle kristallisiert. Als ersten Schritt der Bildung von 10 A, B nehmen wir eine Dimerisierung des Brückenkopfimins 5 zu 12 an, das sich durch Protonenwanderung (→13) und Öffnung eines 4H-Azepinrings in 10A, B umlagert. Die Ergebnisse sprechen für einen gewissen Diradikalcharakter des Brückenkopfimins 5.
    Additional Material: 2 Ill.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/cber.19851180806
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
    Paper (German National Licenses)
    Fulltext
  • 89
    Electronic Resource
    Electronic Resource
    Über sterisch gehinderte freie Radikale, XII. Das Radikal tert-Butyldiphenylmethyl, sein Dimeres sowie deren Autoxidation. Eine Neuuntersuchung (1985)
    Weinheim : Wiley-Blackwell
    Berichte der deutschen chemischen Gesellschaft 118 (1985), S. 450-456 
    Details
    ISSN: 0009-2940
    Keywords: Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Description / Table of Contents: Sterically Hindered Free Radicals, XII. The Radical tert-Butyldiphenylmethyl, Its Dimer, and Their Autoxidation. A ReinvestigationThe radical Ph2C.  -  tBu (1) dimerizes giving reversibly the quinonoid derivative 3, and not the ethane-like 2 as reported in the literature. In equilibrium there are less radicals 1 than in the case of triphenylmethyl, ΔHdiss = 18.5 ± 2 kcal/mol for 3. Both the radical 1 and its dimer 3 are rapidly oxidized by oxygen. 1 gives the dialkyl peroxide 6 which fragmentates already at 20°C mainly to benzophenone and tBu., 3 leads to the ketone 7, probably via the hydroperoxide 10. 3 rearranges catalysed by acid and by base as well via a 1,5-hydrogen migration forming the benzenoid derivative 4. Preparative and ESR details are given.
    Notes: Das Radikal Ph2C.  -  tBu (1) dimerisiert reversibel zum chinoiden Derivat 3 und nicht zum ethan-artigen 2, wie in der Literature berichtet. Im Gleichgewicht liegt weniger Radikal 1 vor als im Fall von Triphenylmethyl, ΔHDiss = 18.5 ± 2 kcal/mol für 3. Sowohl das Radikal 1 wie sein Dimeres 3 werden durch Sauerstoff rasch oxidiert. 1 gibt das Dialkylperoxid 6, das schon bei 20°C fragmentiert, hauptsächlich zu Benzophenon und tBu., 3 führt zum Keton 7, wahrscheinlich über das Hydroperoxid 10. 3 lagert sich, sowohl säure- wie basenkatalysiert, unter 1,5-H-Verschiebung um in das benzoide Derivat 4. Einzelheiten zu den Darstellungen sowie zur ESR-Spektroskopie werden angegeben.
    Additional Material: 1 Ill.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/cber.19851180206
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
    Paper (German National Licenses)
    Fulltext
  • 90
    Electronic Resource
    Electronic Resource
    Beiträge zur Chemie des Bors, 146. Über die Reaktion von Tetrazadiborinanen mit Heterokumulenen: Pseudodipolare [2 + 3]-Cycloadditionen (1985)
    Weinheim : Wiley-Blackwell
    Berichte der deutschen chemischen Gesellschaft 118 (1985), S. 483-494 
    Details
    ISSN: 0009-2940
    Keywords: Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Description / Table of Contents: Contributions to the Chemistry of Boron, 146 Reactions of Tetrazadiborinanes with Heterocumulenes: Pseudodipolar [2 + 3]-CycloadditionsCO2, COS, and CS2 scavenge the 1,3-dipolar unit \documentclass{article}\pagestyle{empty}\begin{document}$ {\rm R'}\mathop {{\rm B - }}\limits^ \oplus {\rm NR - }\mathop {\rm N}\limits^{\rm \Theta } {\rm R} $\end{document} from the tetrazadiborinanes 3. [2 + 3]-Cycloadducts are formed in a pseudodipolar reaction, namely oxadiaza- and thiadiazaborolidines of type 7, 8 and 4. A reaction mechanism is suggested.  -  The thiadiazaborolidine 4b contains a planar five-membered ring according to an X-ray structure determination. Short BN, NN, and CN bond distances suggest a heteroaromatic ring system. High polarity is associated with the thioxo group. In contrast, the oxadiazaborolidinones 8a, b are in an equilibrium with their dimers in solution.
    Notes: CO2, COS und CS2 fangen aus den Tetrazadiborinanen 3e) den 1,3-Dipol \documentclass{article}\pagestyle{empty}\begin{document}$ {\rm R'}\mathop {{\rm B - }}\limits^ \oplus {\rm NR - }\mathop {\rm N}\limits^{\rm \Theta } {\rm R} $\end{document} ab. In einer pseudodipolaren Reaktion bilden sich als [2 + 3]-Cycloaddukte die Oxadiaza- und Thiadiazaborolidine 7, 8 und 4. Ein Reaktionsmechanismus wird diskutiert.  -  Nach Röntgenstrukturanalyse enthält 4b einen planaren Fünfring. Kurze BN-, NN- und CN-Abstände legen ein heteroaromatisches System nahe, wobei der Thioxo-Gruppe eine erhebliche Polarität zuzuweisen ist. Die Oxadiazaborolidinone 8a, b stehen in Lösung im Gleichgewicht mit ihrem Dimeren.
    Additional Material: 2 Ill.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/cber.19851180210
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
    Paper (German National Licenses)
    Fulltext
  • 91
    Electronic Resource
    Electronic Resource
    The colour of chelates of boron. An X-ray structural investigation of bis(4-methylphenyl)boryl and 9-borabicyclo-[3.3.1]nonyl acetylacetonates (1985)
    Weinheim : Wiley-Blackwell
    Berichte der deutschen chemischen Gesellschaft 118 (1985), S. 670-675 
    Details
    ISSN: 0009-2940
    Keywords: Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Description / Table of Contents: Die Farbe von Bor-Chelaten. Röntgenstruktur-Untersuchung von Bis(4-methylphenyl)boryl- und 9-Borabicyclo[3.3.1]nonyl-acetylacetonatenDie Molekülstrukturen des farblosen Bis(4-methylphenyl)boryl- und des orangefarbenen 9-Borabicyclo[3.3.1]non-9-yl-acetylacetonats (4 und 5) wurden durch Röntgenstrukturanalyse ermittelt. Die C—O-Abstände in 4 sind merklich (ca. 0.029 Å) länger als die in 5. Es wird vermutet, daß der unterschiedliche π-Charakter in den C—O-Bindungen die Verschiebungen im Elektronenspektrum der verschiedenen Chelate von 1,3-Diketonen und verwandten Verbindungen verursacht.
    Notes: The molecular structures of the colourless bis(4-methylphenyl)boryl and the orange coloured 9-borabicyclo[3.3.1]non-9-yl acetylacetonates (4 and 5, respectively) have been determined by X-ray analysis. The C—O bond lengths in 4 are significantly (about 0.029 Å) longer than in 5. It is suggested that variation of the π bond order in the C—O bonds is responsible for the shifts in the electronic spectra observed for the various chelates of 1,3-diketones and related compounds.
    Additional Material: 1 Ill.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/cber.19851180226
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
    Paper (German National Licenses)
    Fulltext
  • 92
    Electronic Resource
    Electronic Resource
    2-Azaallenium salts from the reaction of 1-oxa-3-azabutatrienium salts with cyanamides and carbodiimides (1985)
    Weinheim : Wiley-Blackwell
    Berichte der deutschen chemischen Gesellschaft 118 (1985), S. 1887-1902 
    Details
    ISSN: 0009-2940
    Keywords: Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Description / Table of Contents: Darstellung von 2-Azaallenium-Salzen durch Reaktionen von 1-Oxa-3-azabutatrienium-Salzen mit Cyanamiden und CarbodiimidenDie 1-Oxa-3-azabutatrienium-Salze 2 reagieren mit disubstituierten Cyanamiden unter [2 + 2 + 2]-Cycloaddition zu den 2-(Alkylidenamino)-4,6-diamino-1,3,5-oxadiazinium-Salzen 7a - o, die man als oxysubstituierte 2-Azaallenium-Salze betrachten kann. Durch Anlagerung von Methanol entstehen die Oxadiazinium-Salze 8a, d, p. Aus 2n und Dimethylcyanamid erhält man das 2-Azaallenium-Salze 11, dessen Bildung eine [1,5]-isocyanatotrope Umlagerung einschließt. Die Butatrienium-Salze 2 reagieren meist mit zwei Äquivalenten Carbodiimid vom Typ R1 — N = C = N — CHR22 zu den 2-Azaallenium-Salzen 17a - k, die durch eine [1,5]-Hydridverschiebung entstehen. Sterisch anspruchsvoll substituierte Butatrienium-Salze 2 lagern drei Moleküle Diisopropylcarbodiimid and und ergeben die 1,3,5-Triazinium-Salze 20n, o. Es werden Röntgenstruktur-analysen der Verbindungen 7a und 17a angegeben.
    Notes: 1-Oxa-3-azabutatrienium salts 2 react with disubstituted cyanamides under [2 + 2 + 2] cycloaddition affording the 2-(alkylideneamino)-4,6-diamino-1,3,5-oxadiazinium salts 7a - o, which can be regarded as oxy-substituted 2-azaallenium salts. Addition of methanol leads to the oxadiazinium salts 8a, d, p. From 2n and dimethylcyanamide the 2-azaallenium salt 11 was obtained, which must be formed by an [1,5] isocyanatotropic rearrangement. Most butatrienium salts 2 react with two equivalents of carbodiimides R1 — N = C = N — CHR22 to form the 2-azaallenium salts 17a - k. The reaction mechanism includes an [1,5] hydride shift. Bulky substituted butatrienium salts 2 add three molecules of diisopropylcarbodiimide to give the 1,3,5-triazinium salts 20n, o. X-Ray structural analyses for 7a and 17a are reported.
    Additional Material: 2 Ill.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/cber.19851180514
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
    Paper (German National Licenses)
    Fulltext
  • 93
    Electronic Resource
    Electronic Resource
    Iminokohlenstoff-Dianionen der C4-Reihe mit Cyaniminofunktionen (1985)
    Weinheim : Wiley-Blackwell
    Berichte der deutschen chemischen Gesellschaft 118 (1985), S. 1903-1916 
    Details
    ISSN: 0009-2940
    Keywords: Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Description / Table of Contents: Iminocarbon Dianions of the C4-Series with Cyanoimino GroupsSuitable activated squaric acid derivatives react with the anion of cyanamide to yield novel iminocarbon dianions of the C4-series 8 - 11, in which the oxygens of the squarate dianion are successively replaced by one, two, three, or four cyanoimino groups. Besides the synthesis of mixed substituted iminocaron monoanions such as 12, 13, 25, and 26 is described. Spectroscopic data are discussed, 13C NMR data are compared with those of other pseudooxocarbons of the C3- and C4-series. The structure of the first isolable C4-iminocarbon 11′ is proved by X-ray diffraction, which confirmed 11′ to be a delocalized bond system just like the squarate dianion or the other pseudooxocarbons of the C4-series.
    Notes: Geeignet aktivierte Quadratsäurederivate lassen sich mit dem Anion des Cyanamids zu neuen Iminokohlenstoff-Dianionen der C4-Reihe 8 - 11 umsetzen, in denen die Sauerstoffunktionen des Quadratats sukzessive durch ein, zwei, drei oder vier Cyaniminogruppen ersetzt sind. Daneben wird die Darstellung gemischt substituierter Iminokohlenstoff-Monoanionen wie 12, 13, 25 und 26 beschrieben. Spektroskopische Daten werden diskutiert, 13C-NMR-Daten mit denen anderer Pseudooxokohlenstoffe der C3- und C4-Serie verglichen. Die Konstitution des ersten isolierbaren C4-Iminokohlenstoffs 11′ wird durch eine Röntgenstrukturanalyse belegt, die bestätigt, daß 11′ analog dem Quadratat und den anderen Pseudooxokohlenstoffen der C4-Reihe ein delokalisiertes Bindungssystem besitzt.
    Additional Material: 2 Ill.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/cber.19851180515
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
    Paper (German National Licenses)
    Fulltext
  • 94
    Electronic Resource
    Electronic Resource
    Anisotropieeffekte konjugierter cyclischer Systeme, VI. Struktur und magnetische Anisotropie mesitylsubstituierter Ferrocene (1985)
    Weinheim : Wiley-Blackwell
    Berichte der deutschen chemischen Gesellschaft 118 (1985), S. 1968-1982 
    Details
    ISSN: 0009-2940
    Keywords: Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Description / Table of Contents: Anisotropy Effects of Conjugated Cyclic Systems, VI. Structure and Magnetic Anisotropy of Mesityl-substituted FerrocenesTwo isomeric ferrocene derivatives have been obtained from 2-(2-ethyl-4,6-dimethylphenyl)-1,3-dimethylcyclopentadiene (22a). The exo,exo- (9) as well as the endo,endo-configuration (10) of these were determined by X-ray structure analysis. The assignment of the 1H NMR signals of the methyl groups in the spectrum of 1,1′,3,3′-tetramethyl-2,2′-dimesitylferrocene (7) is derived from the spectra of 9 and 10. Signals of methyl groups in exo-position of the mesitylferrocene are shifted by -0.74 ppm to higher magnetic field. Signals of methyl groups in endo-position directed towards the iron atom are shifted downfield by +0.71 ppm. Therefore, ferrocene develops a diamagnetic anisotropy which is similar to that of benzene.
    Notes: Aus 2-(2-Ethyl-4,6-dimethylphenyl)-1,3-dimethylcyclopentadien (22a) werden zwei isomere Ferrocenderivate erhalten. Durch Röntgenstrukturanalysen wird deren exo,exo-(9) bzw. endo,endo-Konfiguration (10) bestimmt. Anhand der 1H-NMR-Spektren dieser Ferrocene ist die Zuordnung der Methylgruppensignale im 1H-NMR-Spektrum des 1,1′,3,3′-Tetramethyl-2,2′-dimesitylferrocens (7) bewiesen. Signale von Methylgruppen in exo-Stellung des Mesitylferrocens werden um -0.74 ppm nach hohem Magnetfeld und solche von zum Eisenatom gerichteten in endo-Stellung um +0.71 ppm nach tiefem Feld verschoben. Daraus leitet sich für Ferrocen eine dem Benzol ähnliche diamagnetische Anisotropieverteilung ab.
    Additional Material: 3 Ill.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/cber.19851180521
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
    Paper (German National Licenses)
    Fulltext
  • 95
    Electronic Resource
    Electronic Resource
    Synthese und Struktur von Lithiumkomplexen mit pentahapto-gebundenen Tris(trimethylsilyl)cyclopentadienyl-Liganden (1985)
    Weinheim : Wiley-Blackwell
    Berichte der deutschen chemischen Gesellschaft 118 (1985), S. 1959-1967 
    Details
    ISSN: 0009-2940
    Keywords: Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Description / Table of Contents: Synthesis and Structure of Lithium Complexes with pentahapto-Bonded Tris(trimethylsilyl)cyclo-pentadienyl LigandsReaction of tris(trimethylsilyl)cyclopentadienyllithium (2) with the nitrogen bases quinuclidine, tetramethylethylenediamine, and pentamethyldiethylenetriamine leads to the isolation of the crystalline, air-sensitive 1:1-adducts 3, 4, and 5, resp., which are monomeric in the gas phase, in solution, and in the solid state. X-Ray structure determinations show that in 3-5 the cyclopentadienyl ring is pentahapto-bonded to the lithium atom. The bonding in these π-complexes is discussed; the complex 3 fulfills the criteria for a nido-cluster.
    Notes: Umsetzung von Tris(trimethylsilyl)cyclopentadienyllithium (2) mit den Stickstoffbasen Chinuclidin, Tetramethylethylendiamin und Pentamethyldiethylentriamin führt zur Isolierung der kristallinen, luftempfindlichen 1:1-Addukte 3, 4 und 5, die in der Gasphase, in Lösung und im festen Zustand monomer vorliegen. Kristallstrukturuntersuchungen zeigen, daß in 3-5 der Cyclopentadienylring pentahapto an das Lithiumatom gebunden ist. Die Bindungsverhältnisse in diesen π-Komplexen werden diskutiert; der Komplex 3 erfüllt die Kriterien für einen nido-Cluster.
    Additional Material: 2 Ill.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/cber.19851180520
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
    Paper (German National Licenses)
    Fulltext
  • 96
    Electronic Resource
    Electronic Resource
    Selektive Reduktion von Cyclohexadienonen mit Fe2(CO)9 und Wasser (1985)
    Weinheim : Wiley-Blackwell
    Berichte der deutschen chemischen Gesellschaft 118 (1985), S. 1983-1995 
    Details
    ISSN: 0009-2940
    Keywords: Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Description / Table of Contents: Selective Reduction of Cyclohexadienones with Fe2(CO)9 and waterSelective monohydrogenation of cross conjugated 2,5-cyclohexadien-1-ones 1 with Fe2(CO)9 and water forming under unusually mild conditions the cyclohexadienol complexes 2 is applied to various related compounds. The regioselectivity of this reaction is tested with differently substituted derivatives. A mechanism explaining the observed regioselectivities and the pH dependence of the stereochemistry is discussed.
    Notes: Die unter ungewöhnlich milden Bedingungen verlaufende selektive Monohydrierung gekreuzt konjugierter 2,5-Cyclohexadien-1-one 1 mit Fe2(CO)9 und Wasser zu den Cyclohexadienol-Komplexen 2 wird auf verschiedene verwandte Verbindungen übertragen. Die Regioselektivität der Reaktion wird an unterschiedlich substituierten Derivaten geprüft. Es wird ein Mechanismus diskutiert, der die beobachteten Regioselektivitäten und die pH-Abhängigkeit der Stereochemie erklärt.
    Additional Material: 1 Tab.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/cber.19851180522
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
    Paper (German National Licenses)
    Fulltext
  • 97
    Electronic Resource
    Electronic Resource
    Synthese mittlerer und großer Ringe, X. (+)- und (-)-[6]Paracyclophan-8-carbonsäure aus (+)- und (-)-3,6-Hexanooxepin-4-carbonsäure (1985)
    Weinheim : Wiley-Blackwell
    Berichte der deutschen chemischen Gesellschaft 118 (1985), S. 1996-2010 
    Details
    ISSN: 0009-2940
    Keywords: Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Description / Table of Contents: Synthesis of Medium and Large Rings, X. (+)- and (-)-[6]Paracyclophane-8-carboxylic Acid from (+)- and (-)-3,6-Hexanooxepin-4-carboxylic AcidThe racemic 3,6-hexanooxepin-4-carboxylic acid ((±)-2d), available in five steps from cyclooctyne and 3-(acetoxymethyl)furan, can be resolved into the enantiomers (+)- and (-)-2d using (+)(R)-1-(1-naphthyl)ethylamine. A stereospecific synthesis of (+)- and (-)-[6]paracyclophane-8-carboxylic acid ((+)- and (-)-4b) is possible from (+)- and (-)-2d as starting materials. Key steps of this synthesis are the transannular addition of bromine to give (-)- and (+)-3a and a subsequent McMurry reaction. The problems involved in the interpretation of the CD-spectra of the oxepin ester (+)-2e and of (+)-4b are discussed in detail.
    Notes: Die aus Cyclooctin und 3-(Acetoxymethyl)furan in fünf Stufen erhältliche racemische 3,6-Hexanooxepin-4-carbonsäure ((±)-2d) kann mit (+)(R)-1-(1-Naphthyl)ethylamin in die Enantiomeren (+)- und (-)-2d gespalten werden. Ausgehend von (+)- und (-)-2d ist eine stereospezifische Synthese von (+)- und (-)-[6]Paracyclophan-8-carbonsäure ((+)- und (-)-4b) möglich. Schlüsselschritte sind dabei die transannulare Bromaddition zu (-)- und (+)-3a und eine anschließende McMurry-Reaktion. Die Probleme der Interpretation der CD-Spektren des Oxepinesters (+)-2e und der Phancarbonsäure (+)-4b werden eingehend diskutiert.
    Additional Material: 4 Ill.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/cber.19851180523
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
    Paper (German National Licenses)
    Fulltext
  • 98
    Electronic Resource
    Electronic Resource
    Beiträge zur Chemie des Bors, 152. 1,3,2,4-Diazaphosphaboretidine und 1,3,2,4-Diazasilaboretidine durch intra- und intermolekulare Cyclokondensation (1985)
    Weinheim : Wiley-Blackwell
    Berichte der deutschen chemischen Gesellschaft 118 (1985), S. 2030-2043 
    Details
    ISSN: 0009-2940
    Keywords: Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Description / Table of Contents: Contributions to the Chemistry of Boron, 152. 1,3,2,4-Diazaphosphaboretidines and 1,3,2,4-Diazasilaboretidines Prepared via Intra- and Intermolecular Cyclocondensation1,3,2,4-Diazaphospha(sila)boretidines 5 and 9 are accessible via thermal decomposition of compounds of type E(NR′—BR2)2 (8) or from organoboron dihalides or boron trihalides and E(NR′Li)2 [E = Si(CH3)2, CH3(O)P, R(S)P, CH3P]. The formation of 1,3-di-tert-butyl-4-methyl-(or ethyl)-1,3,2,4-diazaphospha(sila)boretidines from the precursor E(NR′—BR2)2 proceeds by an intramolecular cyclocondensation. NMR data reveal less shielded B and P atoms in the new heterocycles as compared with noncyclic compounds; this is attributed to a strained ring system. A tetracoordinated as well as a tricoordinated boron atom is observed in CH3(O)P(NR′BR2)2 compounds resulting from intramolecular BO coordination.
    Notes: 1,3,2,4-Diazaphospha(sila)boretidine 5 und 9 sind über die thermische Zersetzung von Verbindungen des Typs E(NR′-BR2)2 (8) oder durch Umsetzung von Organylbordihalogeniden bzw. Bortrihalogeniden mit N-Lithio-Verbindungen E(NR′Li)2 [E = Si(CH3)2, CH3(O)P, R(S)P, CH3P] zugänglich. Es wird gezeigt, daß die 1,3-Di-tert-butyl-4-methyl-bzw. -4-ethyl-1,3,2,4-diazaphospha(sila)boretidine aus der Vorstufe E(NR′-BR2)2 durch eine intramolekulare Cyclokondensation entstehen. Nach NMR-Daten sind die Bor- und Phosphor-Kerne in den Vierring-Heterocyclen als Folge der Ringspannung schlechter abgeschirmt als in nichtcyclischen Derivaten. Vierfach koordiniertes Bor liegt neben dreifach koordiniertem in den Verbindungen CH3(O)P-(NR′BR2)2 vor. Dies geht auf intramolekulare BO-Koordination zurück.
    Additional Material: 1 Ill.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/cber.19851180526
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
    Paper (German National Licenses)
    Fulltext
  • 99
    Electronic Resource
    Electronic Resource
    Synthese von 4-Oxo-4H-benzothiazolo[3,2-a]pyrimidin-1-ium-2-olaten und ihre Cycloadditionen an elektronenarme und elektronenreiche Alkine sowie an o-Chloranil (1985)
    Weinheim : Wiley-Blackwell
    Berichte der deutschen chemischen Gesellschaft 118 (1985), S. 2079-2094 
    Details
    ISSN: 0009-2940
    Keywords: Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Description / Table of Contents: Synthesis of 4-Oxo-4H-benzothiazolo[3,2-a]pyrimidin-1-ium-2-olates and their Cycloaddition Reactions to Electron-poor and Electron-rich Alkynes as well as to o-ChloranilThe synthesis and physical properties of the title compounds 3a - d, prepared from 1 and bis(2,4,6-trichlorophenyl) malonates 2a - d, are described. As cyclic 1,4-dipoles, the betaines 3 combine with dimethyl acetylenedicarboxylate, dibenzoylethyne or bis(diethylamino)ethyne with formation of primary adducts of type 4, which release methyl isocyanate to give pyrido[2,1-b]-benzothiazole derivatives 5a - g, whereas the reaction of 3a with bis(diethylamino)ethyne yields the betaine 7. With unsymmetrically substituted alkynes like methyl propiolate or 1-(diethyl-amino)propyne, 3 reacts with regiospecific formation of 8a - f. On the other hand, the reaction of 3a with o-chloranil proceeds with regiospecific formation of the 1,4-benzodioxin derivative 11. In the case of 8, the observed regiospecificities are in agreement with the results of MNDO calculations and MO-perturbation theory.
    Notes: Die Synthese und physikalischen Eigenschaften der Titelverbindungen 3a - d aus 1 und Malonsäure-bis(2,4,6-trichlorphenylestern) 2a - d werden beschrieben. Als cyclische 1,4-Dipole vereinigen sich die Betaine 3 mit Acetylendicarbonsäure-dimethylester, Dibenzoylethin oder Bis(diethyl-amino)ethin zu Primäraddukten vom Typ 4, die unter Methylisocyanat-Abspaltung Pyrido-[2,1-b]benzothiazol-Derivate 5a - g liefern, während 3a mit Bis(diethylamino)ethin das Betain 7 ergibt. Mit unsymmetrisch substituierten Alkinen, wie Propiolsäure-methylester oder 1-(Diethyl-amino)propin, reagiert 3 regiospezifisch zu 8a - f. Andererseits führt die Umsetzung von 3a mit o-Chloranil regiospezifisch zu dem 1,4-Benzodioxin-Derivat 11. Die bei 8 beobachteten Regiospezifitäten sind mit den Ergebnissen aus MNDO-Rechnungen und der MO-Störungstheorie in Einklang.
    Additional Material: 1 Ill.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/cber.19851180528
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
    Paper (German National Licenses)
    Fulltext
  • 100
    Electronic Resource
    Electronic Resource
    Thermolabile Hydrocarbons, XXVII. 2,3-Di-1-adamantyl-2,3-dimethylbutane; Long Bonds and Low Thermal Stability (1985)
    Weinheim : Wiley-Blackwell
    Berichte der deutschen chemischen Gesellschaft 118 (1985), S. 4665-4673 
    Details
    ISSN: 0009-2940
    Keywords: Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Description / Table of Contents: Thermolabile Kohlenwasserstoffe, XXVII. 2,3-Di-1-adamantyl-2,3-dimethylbutan; lange Bindungen und geringe thermische StabilitätDie Titelverbindung 2 wurde durch Wurtz-Synthese dargestellt und eine Kristallstrukturanalyse durchgeführt. Die Strukturdaten des sehr stark deformierten Molekülgerüstes - drei benachbarte CqCq-Bindungen sind länger als 164 pm, CqCqCq-Bindungswinkel sind bis 118° aufgeweitet - werden durch Rechnungen mit dem MM 2-Kraftfeld sehr gut wiedergegeben. Nach den Kraftfeldrechnungen ist 2 der am stärksten gespannte, nach kinetischen Messungen der thermisch labilste Vertreter der bereits früher bearbeiteten CqCq-Alkane.
    Notes: The title compound 2 was prepared by a Wurtz procedure. Its highly deformed structure was determined by X-ray analysis and matched with high precision by MM 2 force field calculations. The three neighbouring CqCq bonds are longer than 164 pm and the CqCqCq bond angles are 118°. According to MM 2 calculations and a kinetic investigation 2 is the most strained and least stable member of the CqCq alkane series investigated previously2).
    Additional Material: 2 Ill.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/cber.19851181203
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
    Paper (German National Licenses)
    Fulltext
Close ⊗
This website uses cookies and the analysis tool Matomo. More information can be found here...