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  • 04. Solid Earth::04.04. Geology::04.04.12. Fluid Geochemistry  (48)
  • 04. Solid Earth::04.07. Tectonophysics::04.07.02. Geodynamics  (18)
  • Apennines
  • Elsevier Science Limited  (33)
  • Elsevier  (30)
  • Blackwell Publishing Ltd  (5)
  • Elsevier Science  (2)
  • 2010-2014  (70)
  • 1990-1994
  • 1980-1984
  • 1925-1929
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  • 1
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    Carbon dioxide degassing and thermal energy release in the Monte Amiata volcanic-geothermal area (Italy) (2010)
    Elsevier
    Details
    Publication Date: 2021-01-07
    Description: The quaternary volcanic complex of Mount Amiata is located in southern Tuscany (Italy) and represents the most recent manifestation of the Tuscan Magmatic Province. The region is characterised by a large thermal anomaly and by the presence of numerous CO2-rich gas emissions and geothermal features, mainly located at the periphery of the volcanic complex. Two geothermal systems are located, at increasing depths, in the carbonate and metamorphic formations beneath the volcanic complex. The shallow volcanic aquifer is separated from the deep geothermal systems by a low permeability unit (Ligurian Unit). A measured CO2 discharge through soils of 1.8 109 mol a 1 shows that large amounts of CO2 move from the deep reservoir to the surface. A large range in d13CTDIC ( 21.07 to +3.65) characterises the waters circulating in the aquifers of the region and the mass and isotopic balance of TDIC allows distinguishing a discharge of 0.3 109 mol a 1 of deeply sourced CO2 in spring waters. The total natural CO2 discharge (2.1 109 mol a 1) is slightly less than minimum CO2 output estimated by an indirect method (2.8 109 mol a 1), but present-day release of 5.8 109 mol a 1 CO2 from deep geothermal wells may have reduced natural CO2 discharge. The heat transported by groundwater, computed considering the increase in temperature from the infiltration area to the discharge from springs, is of the same order of magnitude, or higher, than the regional conductive heat flow (〉200 mWm 2) and reaches extremely high values (up to 2700mWm 2) in the north-eastern part of the study area. Heat transfer occurs mainly by conductive heating in the volcanic aquifer and by uprising gas and vapor along fault zones and in those areas where low permeability cover is lacking. The comparison of CO2 flux, heat flow and geological setting shows that near surface geology and hydrogeological setting play a central role in determining CO2 degassing and heat transfer patterns.
    Description: Published
    Description: 860–875
    Description: 1.2. TTC - Sorveglianza geochimica delle aree vulcaniche attive
    Description: 2.4. TTC - Laboratori di geochimica dei fluidi
    Description: 4.5. Studi sul degassamento naturale e sui gas petroliferi
    Description: JCR Journal
    Description: reserved
    Keywords: Carbon dioxide degassing ; Monte Amiata ; 03. Hydrosphere::03.04. Chemical and biological::03.04.05. Gases ; 03. Hydrosphere::03.04. Chemical and biological::03.04.06. Hydrothermal systems ; 04. Solid Earth::04.04. Geology::04.04.12. Fluid Geochemistry ; 04. Solid Earth::04.08. Volcanology::04.08.06. Volcano monitoring
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
    Type: article
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  • 2
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    A major change in the sedimentation regime in the Crotone Basin (Southern Italy) around 3.7-3.6 Ma (2014)
    Elsevier
    Details
    Publication Date: 2021-05-17
    Description: The Lower Pliocene succession of the Crotone Basin (Calabrian Arc, Southern Italy) is mainly comprised of blue-grey marly clay with good magnetic properties. Here the bio-magnetostratigraphic data indicate a mean sedimentation rate of about 12–15 cm/kyr. Around 3.7–3.6 Ma a major change in the sedimentation regime occurred: the blue-grey hemipelagic marls grade rapidly into silty marls with a significant increase in the terrigenous fraction and with abundant siliceous remains throughout the whole interval. Magnetic properties of these sediments are very poor, but an integrated calcareous plankton biostratigraphy (foraminifera and nannofossils) infers a high average sedimentation rate (about 50–60 cm/kyr). The abrupt onset of this sedimentation regime in the Crotone Basin is contemporaneous with a major unconformity already recognized in the northern sector of the basin, part of amajor reorganization phase in the whole Apenninic–Maghrebid Chain known as “Globorotalia puncticulata event”. Reports of coeval siliceous sediments in other marginal basins of the Apennines (Southern Calabria, Southern and Northern Apennines) suggest that this “siliceous event” might have been regionally extensive, having important palaeoceanographical implications.We infer that the “siliceous event” is characterized by a combined tectonic- and climate-induced change in palaeoceanographic conditions. The tectonic triggering factors may have been linked to two synchronous events in the Tyrrhenian–Apennine system: 1) the shortening event also known as “G. puncticulata event”, and 2) the coeval opening of the Vavilov Basin in the Tyrrhenian Sea which yielded profound influences in terms of physiography and characteristics of the Crotone Basin. The consequent uplift of the Southern Apennines would have increased sediment supply and availability of silica, resulting in eutrophication and enhanced silica preservation. Strong winter mixing and possibly upwelling conditions could have increased primary productivity during heavy isotope stages Gi4, Gi2 and MG8, at the onset of the “siliceous event”. This important event, lasting from ca. 3.6 Ma to ca. 3.2 Ma, would have recorded a peculiar transitional period before further climatic deterioration and more drastic palaeoceanographic changes occurred around 3.1 Ma, leading to cyclic sapropel deposition in the whole of the Mediterranean sea.
    Description: Published
    Description: 398-410
    Description: 1A. Geomagnetismo e Paleomagnetismo
    Description: JCR Journal
    Description: restricted
    Keywords: Biostratigraphy ; Magnetostratigraphy ; Pliocene ; Calabrian Arc ; 04. Solid Earth::04.04. Geology::04.04.08. Sediments: dating, processes, transport ; 04. Solid Earth::04.04. Geology::04.04.10. Stratigraphy ; 04. Solid Earth::04.05. Geomagnetism::04.05.06. Paleomagnetism ; 04. Solid Earth::04.07. Tectonophysics::04.07.02. Geodynamics
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
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  • 3
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    Multidisciplinary study of the Tindari Fault (Sicily, Italy) separating ongoing contractional and extensional compartments along the active Africa–Eurasia convergent boundary (2013)
    Elsevier Science Limited
    Details
    Publication Date: 2020-12-15
    Description: The Africa–Eurasia convergence in Sicily and southern Calabria is currently expressed by two different tectonic and geodynamic domains: thewestern region, governed by a roughlyN–S compression generated by a continental collision; the eastern one, controlled by a NW–SE extension related to the south-east-directed expansion of the Calabro–Peloritan Arc. The different deformation pattern of these two domains is accommodated by a right-lateral shear zone (Aeolian–Tindari–Letojanni fault system) which, from the Ionian Sea, north of Mt. Etna, extends across the Peloritani chain to the Aeolian Islands. In this work, we study the evidence of active tectonics characterizing this shear zone, through the analysis of seismic and geodetic data acquired by the INGV networks in the last 15 years. The study is completed by structural and morphological surveys carried out between Capo Tindari and the watershed of the chain. The results allowed defining a clear structural picture depicting the tectonic interferences between the two different geodynamic domains. The results indicate that, besides the regional ~N130°E horizontal extensional stress field, another one, NE–SW-oriented, is active in the investigated area. Both tension axes are mutually independent and have been active up to the present at different times. The coexistence of these different active horizontal extensions is the result of complex interactions between several induced stresses: 1) the regional extension (NW–SE) related to the slab rollback and back-arc extension; 2) the strong uplift of the chain; 3) the accommodation between compressional and extensional tectonic regimes along the Aeolian– Tindari–Letojanni faults, through a SSE–NNW right-lateral transtensional displacement. In these conditions, the greater and recurring uplift activity is not able to induce a radial extensional dynamics, but, under the “directing” action of the shear system, it can only act on the regional extension (NW–SE) and produce the second system of extension (NE–SW).
    Description: Published
    Description: 1-17
    Description: 3.2. Tettonica attiva
    Description: JCR Journal
    Description: open
    Keywords: Africa–Eurasia convergence ; Aeolian–Tindari fault system ; Transform activity ; Stress and strain fields ; Multidisciplinary approach ; 04. Solid Earth::04.07. Tectonophysics::04.07.02. Geodynamics
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
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  • 4
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    Subduction-triggered magmatic pulses: A new class of plumes? (2011)
    Elsevier
    Details
    Publication Date: 2021-01-27
    Description: A variety of atypical plume-like structures and focused upwellings that are not rooted in the lower mantle have recently been discussed, and seismological imaging has shown ubiquitous small-scale convection in the uppermost mantle in regions such as the Mediterranean region, the western US, and around the western Pacific. We argue that the three-dimensional return flow and slab fragmentation associated with complex oceanic subduction trajectories within the upper mantle can generate focused upwellings and that these may play a significant role in regional tectonics. The testable surface expressions of this process are the outsidearc alkaline volcanism, topographic swell, and low-velocity seismic anomalies associated with partial melt. Using three-dimensional, simplified numerical subduction models, we show that focused upwellings can be generated both ahead of the slab in the back-arc region (though ~five times further inward from the trench than arc-volcanism) and around the lateral edges of the slab (in the order of 100 km away from slab edges). Vertical mass transport, and by inference the associated decompression melting, in these regions appears strongly correlated with the interplay between relative trench motion and subduction velocities. The upward flux of material from the depths is expected to be most pronounced during the first phase of slab descent into the upper mantle or during slab fragmentation. We discuss representative case histories from the Pacific and the Mediterranean where we find possible evidence for such slab-related volcanism.
    Description: Published
    Description: 54-68
    Description: 3.3. Geodinamica e struttura dell'interno della Terra
    Description: JCR Journal
    Description: reserved
    Keywords: subduction ; magmatism ; upper mantle convection ; geodynamic modeling ; 04. Solid Earth::04.07. Tectonophysics::04.07.02. Geodynamics
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
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  • 5
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    Role of the brittle–ductile transition on fault activation (2012)
    Elsevier Science Limited
    Details
    Publication Date: 2021-01-27
    Description: We model a fault cross-cutting the brittle upper crust and the ductile lower crust. In the brittle layer the fault is assumed to have stick–slip behaviour, whereas the lower ductile crust is inferred to deform in a steady-state shear. Therefore, the brittle–ductile transition (BDT) separates two layers with different strain rates and structural styles. This contrasting behaviour determines a stress gradient at the BDT that is eventually dissipated during the earthquake. During the interseismic period, along a normal fault it should form a dilated hinge at and above the BDT. Conversely, an over-compressed volume should rather develop above a thrust plane at the BDT. On a normal fault the earthquake is associated with the coseismic closure of the dilated fractures generated in the stretched hangingwall during the interseismic period. In addition to the shear stress overcoming the friction of the fault, the brittle fault moves when the weight of the hangingwall exceeds the strength of the dilated band above the BDT. On a thrust fault, the seismic event is instead associated with the sudden dilation of the previously over-compressed volume in the hangingwall above the BDT, a mechanism requiring much more energy because it acts against gravity. In both cases, the deeper the BDT, the larger the involved volume, and the bigger the related magnitude. We tested two scenarios with two examples from L’Aquila 2009 (Italy) and Chi-Chi 1999 (Taiwan) events. GPS data, energy dissipation and strain rate analysis support these contrasting evolutions. Our model also predicts, consistently with data, that the interseismic strain rate is lower along the fault segment more prone to seismic activation.
    Description: Published
    Description: 160-161
    Description: JCR Journal
    Description: open
    Keywords: faul activation ; 04. Solid Earth::04.07. Tectonophysics::04.07.02. Geodynamics
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
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  • 6
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    Origin and interactions of fluids circulating over the Amik Basin (Hatay, Turkey) and relationships with the hydrologic, geologic and tectonic settings (2014)
    Elsevier Science Limited
    Details
    Publication Date: 2021-06-15
    Description: We investigated the geochemical features of the fluids circulating over the Amik Basin (SE Turkey–Syria border), which is crossed by the Northern extension of theDSF (Dead Sea Fault) and represents the boundary area of three tectonic plates (Anatolian, Arabian and African plates). We collected 34 water samples (thermal and cold from natural springs and boreholes) as well as 8 gas samples (bubbling and gas seepage) besides the gases dissolved in the sampled waters. The results show that the dissolved gas phase is a mixture of shallow (atmospheric) and deep components either of mantle and crustal origin. Coherently the sampled waters are variable mixtures of shallow and deep ground waters, the latter being characterised by higher salinity and longer residence times. The deep groundwaters (fromboreholes deeper than 1000 m)have a CH4-dominated dissolved gas phase related to the presence of hydrocarbon reservoirs. The very unique tectonic setting of the area includes the presence of an ophiolitic block outcropping in the westernmost area on the African Plate, as well as basalts located to the North and East on the Arabic Plate. The diffuse presence of CO2-enriched gases, although diluted by the huge groundwater circulation, testifies a regional degassing activity. Fluids circulating over the ophiolitic block are marked by H2-dominated gases with abiogenic methane and high-pH waters. The measured 3He/4He isotopic ratios display contributions from both crustal and mantle-derived sources over both sides of the DSF. Although the serpentinization process is generally independent from mantle-type contribution, the recorded helium isotopic ratios highlight variable contents of mantle-derived fluids. Due to the absence of recent volcanism over the western side of the basin (African Plate), we argue that CO2-rich volatiles carrying mantle-type helium and enriched in heavy carbon, are degassed by deep-rooted regional faults rather than from volcanic sources.
    Description: Published
    Description: 23–39
    Description: 2T. Tettonica attiva
    Description: JCR Journal
    Description: restricted
    Keywords: Dead Sea Fault ; Hydrogeochemistry ; Gas geochemistry ; He isotopes ; C isotopes ; Ophiolites ; 03. Hydrosphere::03.02. Hydrology::03.02.03. Groundwater processes ; 03. Hydrosphere::03.04. Chemical and biological::03.04.02. Carbon cycling ; 03. Hydrosphere::03.04. Chemical and biological::03.04.03. Chemistry of waters ; 03. Hydrosphere::03.04. Chemical and biological::03.04.05. Gases ; 04. Solid Earth::04.04. Geology::04.04.12. Fluid Geochemistry
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
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  • 7
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    Fluid circulation in the upper brittle crust: Thickness distribution, hydraulic transmissivity fluid inclusion and isotopic data of veins hosted in the Oligocene sandstones of the Macigno Formation in southern Tuscany, Italy (2011)
    Elsevier
    Details
    Publication Date: 2020-11-30
    Description: We present structural analysis, fluid inclusion data on calcite and quartz, and isotopic composition of calcite forming veins occurring in the upper crustal level and hosted in Oligocene sandstone in southern Tuscany (Italy). The veins have been analysed in two sites few kilometres apart, along well-exposed coastal cliffs and in an abandoned quarry. These two sites were at a different depths at the time of the vein formation with a Δh ~ 100 m. Structural analysis of veins provided estimations of stress ratio (Φ = (σ2 − σ3)/(σ1 − σ3)), driving stress ratio (R′ = (Pf − σ3)/(σ1 − σ3)) and fluid overpressure (ΔPo = Pf − σ3) at the time of vein formation. The estimated ΔPo is in the range of 42–103 MPa, Φ = 0.24 and R′ = 0.45, indicating that fluid pressure was higher than the intermediate principal stress at the time of veins formation. The veins' thickness (t) shows a clear power-law distribution (D = 1.8835 and R2 = 0.9762) in the lowermost site (coast) and a negative exponential distribution (a = 0.6943 and R2 = 0.9921) in the uppermost site (abandoned quarry). The vein thickness distributions have been used to compute the average transmissivity of the veins in the two sites. The computed transmissivity for the vein formation is ~ 10−4 m2 s−1, with higher values attained by the veins having negative exponential thickness distribution. Fluid inclusions studies highlighted that in both calcite and quartz, water-rich inclusions, with salinities of 2.2–4.3 wt.% NaCl equiv., and methane-rich inclusions were coevally trapped during fluid un-mixing processes. Thermogenic origin, from thermal maturation of organic matter present in the Macigno Formation, is proposed for methane. Whereas, the similarity between the δ18O (from 14.9 to 17.4‰) and δ13C (from −0.4 to −2.4‰) data of representative calcite veins and the isotopic composition (δ18O: 16.1‰, δ13C: −1.0‰) of host-rock carbonate component, indicates that the fluid which formed calcite was in isotopic equilibrium with the carbonates present in the Oligocene sandstones. The calculated pressure–temperature conditions during the formation of these inclusions are prevalently within the 40–145 MPa and 160–260 °C ranges. The highest pressure values approximate the lithostatic pressure (~ 120 MPa) computed from geological data and are coherent with a geothermal gradient ranges of 35–45 °C/km. Whereas, the lower pressure values are comparable with hydrostatic pressure conditions. The pressure range indicated by fluid inclusion data is also comparable with the fluid pressure estimated from structural analysis. The considerable pressure range can be related to pressure cycling between lithostatic and hydrostatic conditions as a consequence of fault-valve actions and rock fracturing with subsequent pressure recover due to self-sealing process.
    Description: Published
    Description: 118-138
    Description: 3.2. Tettonica attiva
    Description: 3.3. Geodinamica e struttura dell'interno della Terra
    Description: JCR Journal
    Description: reserved
    Keywords: Vein systems ; Fluid type ; Fluid pressure ; Fluid inclusions ; Upper crust ; Tuscany ; 04. Solid Earth::04.04. Geology::04.04.09. Structural geology ; 04. Solid Earth::04.04. Geology::04.04.12. Fluid Geochemistry ; 04. Solid Earth::04.07. Tectonophysics::04.07.07. Tectonics
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  • 8
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    Magnetic fabric of Plio-Pleistocene sediments from the Crotone fore-arc basin: Insights on the recent tectonic evolution of the Calabrian Arc (Italy) (2014)
    Elsevier
    Details
    Publication Date: 2020-12-07
    Description: Low-field anisotropy of magnetic susceptibility (AMS) analyses were performed on 532 samples col-lected in 36 (mostly lower Pliocene to lower Pleistocene) marine clay sites from the Crotone basin, afore-arc basin located on top of the external Calabrian accretionary wedge. The Crotone basin formedsince mid-late Miocene under a predominant extensional tectonic regime, but it was influenced there-after by complex interactions with NW–SE left-lateral strike-faults bounding the basin, which also yieldedpost-1.2 Ma ~30◦counterclockwise block rotations. The basin is filled by continental to marine sedimentsyielding one of the thickest and best-exposed Neogene succession available worldwide. The deep-marinefacies – represented by blue-grey marly clays gave the best results, as they both preserved a clear mag-netic fabric, and provided accurate chronology based on previously published magnetostratigraphy andcalcareous plankton (i.e. foraminifers and nannofossils) biostratigraphy. Magnetic susceptibility rangeand rock magnetic analyses both indicate that AMS reflects paramagnetic clay matrix crystal arrange-ment. The fabric is predominantly oblate to triaxial, the anisotropy degree low (〈1.06), and the magneticfoliation mostly subparallel to bedding. Magnetic lineation is defined in 30 out of 36 sites (where thee12 angle is 〈35◦). By also considering local structural analysis data, we find that magnetic fabric wasgenerally acquired during the first tectonic phases occurring after sediment deposition, thus validatingits use as temporally dependent strain proxy. Although most of the magnetic lineations trend NW–SE andare orthogonal to normal faults (as observed elsewhere in Calabria), few NE–SW compressive lineationsshow that the Neogene extensional regime of the Crotone basin was punctuated by compressive episodes.Finally, compressive lineations (prolate magnetic fabric) documented along the strike-slip fault boundingthe basin to the south support the significance of Pleistocene strike-slip tectonics. Thus the Crotone basinshows a markedly different tectonics with respect to other internal and western basins of Calabria, asit yields a magnetic fabric still dominated by extensional tectonics but also revealing arc-normal short-ening episodes and recent strike-slip fault activity. The tectonics documented in the Crotone basin iscompatible with a continuous upper crustal structural reorganization occurring during the SE-migrationof the Calabria terrane above the Ionian subduction system.
    Description: Published
    Description: 67-79
    Description: 1A. Geomagnetismo e Paleomagnetismo
    Description: JCR Journal
    Description: restricted
    Keywords: Calabrian Arc, Anisotropy of magnetic susceptibility, Structural analysis, Fore-arc region ; 04. Solid Earth::04.04. Geology::04.04.08. Sediments: dating, processes, transport ; 04. Solid Earth::04.04. Geology::04.04.09. Structural geology ; 04. Solid Earth::04.05. Geomagnetism::04.05.06. Paleomagnetism ; 04. Solid Earth::04.05. Geomagnetism::04.05.07. Rock magnetism ; 04. Solid Earth::04.07. Tectonophysics::04.07.02. Geodynamics ; 04. Solid Earth::04.07. Tectonophysics::04.07.07. Tectonics
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  • 9
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    Seismicity in Central and Northern Apennines integrating the Italian national and regional networks (2010)
    Elsevier
    Details
    Publication Date: 2017-04-04
    Description: In this paper we present and discuss an improved picture of the seismicity distribution of the Umbria– Marche–Abruzzi Apennines as obtained through the integration of the national and the regional seismic networks operating from 2002 to 2006. During this period, both the Istituto Nazionale di Geofisica e Vulcanologia (INGV) National Seismic Network and the regional networks have been greatly improved. We compare the results of the integrated catalogue obtained in this study with the Catalogue of the Italian Seismicity between 1981 and 2001 [Castello, B., Selvaggi, G., Chiarabba, C., Amato, A., 2006. CSI Catalogo della sismicità italiana 1981–2002, versione 1.1. INGV-CNT, Roma.http://legacy.ingv.it/CSI )], confirming the basic known features of the seismic activity in the region, but also evidencing some original and interesting results. In particular, the new data set allows us to better define the geometry and kinematics of the crustal seismicity, which is confined to the upper 20 km and shows a clear general deepening from west to east. In the crust, we find additional evidence of extensional seismicity below the central portion of the belt and thrust/reverse faulting mechanisms at the outer fronts of the Apennines. Looking at the seismicity along the belt, it is also possible to observe aseismic regions, which could be due to either locked or creeping portions of the Apenninic fault system. At greater depth, the west-dipping seismicity distribution down to about 70 km confirms the hypothesis of a slab of Adriatic lithosphere subducted below the Apennines, but also suggests that there are strong lateral heterogeneities and possibly tears in the slab.
    Description: Published
    Description: 121-135
    Description: 1.1. TTC - Monitoraggio sismico del territorio nazionale
    Description: JCR Journal
    Description: reserved
    Keywords: Seismicity ; Seismic monitoring ; Focal mechanisms ; Subduction ; Apennines ; Italy ; 04. Solid Earth::04.06. Seismology::04.06.99. General or miscellaneous
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
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  • 10
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    Fluids-Faults relationships over the seismic area of Southern Apennine (Calabria region, Southern Italy): geochemical information from thermal and sulphurous water discharges. (2010)
    Elsevier
    Details
    Publication Date: 2017-04-04
    Description: The first comprehensive geochemical data-set of the fluids circulating over a 14,000 km2-wide seismic-prone area of the Southern Apennines, Calabria Region (Italy), is presented here. The geochemical investigations were carried out with the two-fold aim of constraining the origin and interactions of the circulating fluids and to investigate possible relationships with local faults. We collected 60 samples of both thermal and cold waters, from which we extracted the dissolved gases . The geochemical features of the water samples display different types and degrees of water-rock interactions, irrespective of the outlet temperature. The calculated equilibrium temperatures of the thermal waters (60-160°C) and the low heat flow of the whole study area, are consistent with a heating process due to deep water circulation and rapid upflow through lithospheric structures. The composition of the dissolved gases reveals that crustal-originating gases (N2 and CO2-dominated ) feed all the groundwaters. The 3He/4He ratios of the dissolved helium, in the range of 0.03 to 0.22Rac for the thermal waters and 0.05-0.63Rac for the cold waters (Rac = helium isotope ratio corrected for atmospheric contamination), are mainly the result of a two-component (radiogenic and atmospheric) mixing, although indications of mantle-derived helium are found in some cold waters. As the study area had been hit by 18 of the most destructive earthquakes (magnitude ranging from 5.9 to 7.2) occurring over a 280-year time span (1626-1908) in Southern Apennines, the reported results on the circulating fluids may represent the reference for a better inside knowledge of the fault-fluid relationships and for the development oflong-term geochemical monitoring strategies for the area.
    Description: In press
    Description: 3.2. Tettonica attiva
    Description: JCR Journal
    Description: open
    Keywords: Fluids/Fault interactions ; isotope geochemistry ; thermal waters ; dissolved gases ; 04. Solid Earth::04.04. Geology::04.04.12. Fluid Geochemistry
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  • 11
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    Anomalous fluid emission of a deep borehole in a seismically active area of Northern Apennines (Italy) (2010)
    Elsevier
    Details
    Publication Date: 2017-04-04
    Description: The Miano borehole of 1047 m depth is located close to the river Parma in the Northern Apennines, Italy. A measuring station is installed to observe the discharge of fluids continuously since November 2004. The upwelling fluid of this artesian well is a mixture of thermal water and methane as main components. In non-seismogenic areas, we would expect a relative constant fluid emission perhaps overlaid with long term variations from that kind of deep reservoirs during the time. However, the continuously record of the fluid emission, in particular the water discharge, the gas flow rate and the water temperature, show periods of stable values interrupted by anomalous periods of fluctuations in the recorded parameters. The anomalous variations of these parameters are of low amplitude in comparison to the total values but significant in their long-term trend. Meteorological influences of rain and barometric pressure were not detected in recorded data probably due to reservoir depth and relatively high reservoir overpressure. Influences due to the ambient temperature after the discharge were evaluated by statistical analysis. We consider that recorded changes in fluid emission parameters can be interpreted as a mixing process of different fluid components in depth by variations in pore pressure as result of seismogenic stress variation. Local seismicity was analyzed in comparison to fluid’s physico-chemical data. The analysis supports the idea of an influence to fluid transport conditions due to geodynamic processes exist. Water temperature data show frequent anomalies probably connected with possible precursory phenomena of local seismic events.
    Description: In press
    Description: 3.2. Tettonica attiva
    Description: JCR Journal
    Description: open
    Keywords: Fluids ; Earthquakes ; Continous monitoring ; 04. Solid Earth::04.04. Geology::04.04.12. Fluid Geochemistry
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  • 12
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    Mercury content and speciation in the Phlegrean Fields volcanic complex: Evidence from hydrothermal system and fumaroles (2010)
    Elsevier
    Details
    Publication Date: 2017-04-04
    Description: Mercury is outstanding among the global environmental pollutants of continuing concern. Although degassing of active volcanic areas represents an important natural source of mercury into the atmosphere, still little is known about the amount and behaviour of Hg in volcanic aquifers, especially regarding its chemical speciation. In order to assess the importance of mercury emissions from active volcanoes, thermal waters were sampled in the area surrounding La Solfatara, Pozzuoli bay. This is the most active zone of the Phlegrean Fields complex (coastal area north–west of Naples), with intense hydrothermal activity at present day. Studied groundwaters show total Hg (THg) concentrations range from 56 to 171 ng/l and are lower than the 1000 ng/l threshold value for human health protection fixed by the World Health Organization (WHO, 1993). We also carefully discriminated the different aqueous species of Hg in the collected water samples. Besides, original data on Hg determination in gaseous manifestations at La Solfatara crater are also reported. We measured volcanogenic mercury concentration and Hg/Stot ratio both in the volcanic plume and in fumarolic condensates in order to better constrain Hg reactivity once emitted into the atmosphere. Data on Hg/Stot reveal that there is no significant difference between Hg volcanic composition at the venting source (fumaroles) and in near-vent diluted volcanic plumes (1.6×10−5 and 1.9×10−5, respectively), suggesting that there is limited Hg chemical processing in volcanic fumarole plumes, at least on the timescales of a few seconds investigated here. Combining the mean fumaroles Hg/CO2 mass ratio of about 1.3×10−8 (molar ratio: 2.1×10−9) with the hydrothermal soil diffuse CO2 degassing of the area, the annual Hg flux from La Solfatara is estimated as 7 kg y−1 (0.007 t y−1). Current mercury emission from La Solfatara volcano represents a very small contribution to the estimated global volcanic budget for this element, and the estimated Hg flux is considerably lower than that estimated from open-conduit active basaltic volcanoes.
    Description: Published
    Description: 250–260
    Description: 1.2. TTC - Sorveglianza geochimica delle aree vulcaniche attive
    Description: 2.4. TTC - Laboratori di geochimica dei fluidi
    Description: 4.5. Studi sul degassamento naturale e sui gas petroliferi
    Description: JCR Journal
    Description: reserved
    Keywords: hydrothermal waters ; total mercury ; mercury speciation ; fumaroles ; 03. Hydrosphere::03.04. Chemical and biological::03.04.05. Gases ; 03. Hydrosphere::03.04. Chemical and biological::03.04.06. Hydrothermal systems ; 04. Solid Earth::04.04. Geology::04.04.12. Fluid Geochemistry ; 04. Solid Earth::04.08. Volcanology::04.08.06. Volcano monitoring
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
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  • 13
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    Can Earth's rotation and tidal despinning drive plate tectonics? (2010)
    Elsevier
    Details
    Publication Date: 2017-04-04
    Description: We re-evaluate the possibility that Earth's rotation contributes to plate tectonics on the basis of the following observations: 1) plates move along a westerly polarized flow that forms an angle relative to the equator close to the revolution plane of the Moon; 2) plate boundaries are asymmetric, being their geographic polarity the first order controlling parameter; unlike recent analysis, the slab dip is confirmed to be steeper along W-directed subduction zones; 3) the global seismicity depends on latitude and correlates with the decadal oscillations of the excess length of day (LOD); 4) the Earth's deceleration supplies energy to plate tectonics comparable to the computed budget dissipated by the deformation processes; 5) the Gutenberg–Richter law supports that the whole lithosphere is a self-organized system in critical state, i.e., a force is acting contemporaneously on all the plates and distributes the energy over the whole lithospheric shell, a condition that can be satisfied by a force acting at the astronomical scale. Assuming an ultra-low viscosity layer in the upper asthenosphere, the horizontal component of the tidal oscillation and torque would be able to slowly shift the lithosphere relative to the mantle.
    Description: Hungarian Scientific Research Fund OTKA in the framework of project K 60394
    Description: Published
    Description: 60-73
    Description: 3.3. Geodinamica e struttura dell'interno della Terra
    Description: JCR Journal
    Description: reserved
    Keywords: Plate tectonics ; Earth's rotation ; Tidal despinning ; Earth's energy budget ; 04. Solid Earth::04.07. Tectonophysics::04.07.02. Geodynamics
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  • 14
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    Extreme methane deuterium, nitrogen and helium enrichment in natural gas from the Homorod seep (Romania) (2011)
    Elsevier
    Details
    Publication Date: 2017-04-04
    Description: Methane (CH4) in terrestrial environments, whether microbial, thermogenic, or abiogenic, exhibits a large variance in C and H stable isotope ratios due to primary processes of formation. Isotopic variability can be broadened through secondary, post-genetic processes, such as mixing and isotopic fractionation by oxidation. The highest and lowest 13C and 2H (or D, deuterium) concentrations in CH4 found in various geologic environments to date, are defined as “natural” terrestrial extremes. We have discovered a new extreme in a natural gas seep with values of deuterium concentrations, δDCH4, up to+124‰that far exceed those reported for any terrestrial gas. The gas, seeping from the small Homorod mud volcano in Transylvania (Romania), also has extremely high concentrations of nitrogen (N92 vol.%) and helium (up to 1.4 vol.%). Carbon isotopes in CH4, C2H6 and CO2, and nitrogen isotopes in N2 indicate a primary organic sedimentary origin for the gas (a minor mantle component is suggested by the 3He/4He ratio, R/Ra~0.39). Both thermogenic gas formation modeling and Rayleigh fractionation modeling suggest that the extreme deuterium enrichment could be explained by an oxidation process characterised by a δDCH4 and δ13CCH4 enrichment ratio (ΔH/ΔC) of about 20, and may be accounted for by abiogenic oxidation mediated by metal oxides. All favourable conditions for such a process exist in the Homorod area, where increased heat flow during Pliocene–Quaternary volcanism may have played a key role. Finally we observed rapid variations (within 1 h) in C and H isotope ratios of CH4, and in the H2S concentrations which are likely caused by mixing of the deep oxidized CH4–N2–H2S–He rich gas with a microbial methane generated in the mud pool of one of the seeps. We hypothesize that the unusual features of Homorod gas can be the result of a rare combination of factors induced by the proximity of sedimentary organic matter, mafic, metal-rich volcanic rocks and salt diapirs,leading to the following processes: a) primary thermogenic generation of gas at temperatures between 130 and 175 °C; b) secondary alteration through abiogenic oxidation, likely triggered by the Neogene–Quaternary volcanism of the eastern Transylvanian margin; and c) mixing at the surface with microbial methane that formed through fermentation in the mud volcano water pool. The Homorod gas seep is a rare example that demonstrates how post-genetic processes can produce extreme gas isotope signatures (thus far only theorized), and that extremely positive δDCH4 values cannot be used to unambiguously distinguish between biotic and abiotic origin.
    Description: Published
    Description: 89-96
    Description: 4.5. Studi sul degassamento naturale e sui gas petroliferi
    Description: JCR Journal
    Description: reserved
    Keywords: Methane ; Deuterium ; Nitrogen ; Helium ; Seep ; Mud volcano ; 04. Solid Earth::04.04. Geology::04.04.12. Fluid Geochemistry
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
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  • 15
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    Abiotic methane flux from the Chimaera seep and Tekirova ophiolites (Turkey): Understanding gas exhalation from low temperature serpentinization and implications for Mars (2011)
    Elsevier
    Details
    Publication Date: 2017-04-04
    Description: The emission of abiotic methane (CH4) into the atmosphere from low temperature serpentinization in ophiolitic rocks is documented to date only in four countries, the Philippines, Oman, New Zealand, and Turkey. Serpentinization produces large amounts of hydrogen (H2) which in theory may react with CO2 or CO to form hydrocarbons (Fischer–Tropsch Type synthesis, FTT). Similar mechanisms have been invoked to explain the CH4 detected on Mars, so that understanding flux and exhalation modality of ophiolitic gas on Earth may contribute to decipher the potential degassing on Mars. This work reports the first direct measurements of gas (CH4, CO2) flux ever done on onshore ophiolites with present-day serpentinization. We investigated the Tekirova ophiolites at Çirali, in Turkey, hosting the Chimaera seep, a system of gas vents issuing from fractures in a 5000 m2 wide ophiolite outcrop. At this site at least 150–190 t of CH4 is annually released into the atmosphere. The molecular and isotopic compositions of C1–C5 alkanes, CO2, and N2 combined with source rock maturity data and thermogenic gas formation modelling suggested a dominant abiotic component (~80– 90%) mixed with thermogenic gas. Abiotic H2-rich gas is likely formed at temperatures below 50 °C, suggested by the low deuterium/hydrogen isotopic ratio of H2 (δDH2: −720‰), consistent with the low geothermal gradient of the area. Abiotic gas synthesis must be very fast and effective in continuously producing an amount of gas equivalent to the long-lasting (N2 millennia) emission of N100 t CH4 yr−1, otherwise pressurised gas accumulation must exist. Over the same ophiolitic formation, 3 km away from Chimaera, we detected an invisible microseepage of abiotic CH4 with fluxes from 0.07 to 1 g m−2 d−1. On Mars similar fluxes could be able to sustain the CH4 plume apparently recognised in the Northern Summer 2003 (104 or 105 t yr−1) over the wide olivine bedrock and outcrops of hydrated silicates in the Syrtis Major and Nili Fossae; just one seep like Chimaera or, more realistically, a weak, spatially sporadic microseepage, would be sufficient to maintain the atmospheric CH4 level on Mars.
    Description: Published
    Description: 96-104
    Description: 4.5. Studi sul degassamento naturale e sui gas petroliferi
    Description: JCR Journal
    Description: reserved
    Keywords: abiotic methane ; seepage ; serpentinization ; ophiolites ; Mars ; 03. Hydrosphere::03.04. Chemical and biological::03.04.05. Gases ; 04. Solid Earth::04.04. Geology::04.04.12. Fluid Geochemistry
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  • 16
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    Fluid origin, gas fluxes and plumbing system in the sediment-hosted Salton Sea Geothermal System (California, USA) (2011)
    Elsevier
    Details
    Publication Date: 2017-04-04
    Description: The Salton Sea Geothermal System (California) is an easily accessible setting for investigating the interactions of biotic and abiogenic geochemical processes in sediment-hosted hydrothermal systems. We present new temperature data and the molecular and isotopic composition of fluids seeping at the Davis-Schrimpf seep field during 2003–2008. Additionally, we show the first flux data for CO2 and CH4 released throughout the field from focused vents and diffuse soil degassing. The emitted gases are dominated by CO2 (~98%) and CH4 (~1.5%). By combining δ13CCO2 (as low as −5.4‰) and δ13CCH4 (−32‰to−17.6‰) with 3He/4He (R/RaN6) and δDCH4 values (−216‰to−150‰), we suggest, in contrast to previous studies, that CO2 may have a significant Sub-Continental Mantle source, with minimal crustal contamination, and CH4 seems to be a mixture of high temperature pyrolitic (thermogenic) and abiogenic gas. Water seeps show that δD and δ18O increase proportionally with salinity (Total Dissolved Solids in g/L) ranging from 1–3 g/L (gryphons) to 145 g/L (hypersaline pools). In agreement with elemental analyses, the isotopic composition of the waters indicate a meteoric origin, modified by surface evaporation, with little or no evidence of deep fossil or magmatic components. Very high Cl/Br (N3,000) measured at many seeping waters suggests that increased salinities result from dissolution of halite crusts near the seep sites. Gas flux measurements from 91 vents (pools and gryphons) give a conservative estimate of ~2,100 kg of CO2 and 11.5 kg of CH4 emitted per day. In addition soil degassing measured at 81 stations (20x20 m grid over 51,000 m2) revealed that 7,310 kg/d CO2 and 33 kg/d CH4 are pervasively released to the atmosphere. These results emphasise that diffuse gas emission from soil can be dominant (~75%) even in hydrothermal systems with large and vigorous gas venting. Sediment-hosted hydrothermal systems may represent an intermediate class of geologic methane sources for the atmosphere, with emission factors lower than those of sedimentary seepage in petroleum basins but higher than those of traditional geothermal-volcanic systems; on a global scale they may significantly contribute to the atmospheric methane budget.
    Description: Published
    Description: 67-83
    Description: 4.5. Studi sul degassamento naturale e sui gas petroliferi
    Description: JCR Journal
    Description: reserved
    Keywords: Salton Sea Geothermal System ; hydrothermal seeps ; gas and water geochemistry ; flux measurements ; mantle ; 03. Hydrosphere::03.04. Chemical and biological::03.04.05. Gases ; 04. Solid Earth::04.04. Geology::04.04.12. Fluid Geochemistry
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  • 17
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    Vein development during folding in the upper brittle crust: The case of tourmaline-rich veins of eastern Elba Island, northern Tyrrhenian Sea, Italy (2012)
    Elsevier
    Details
    Publication Date: 2017-04-04
    Description: Detailed structural analysis of tourmaline-rich veins hosted in the contact aureole of the ∼6 Ma Porto Azzurro granite in southeastern Elba Island, northern Tyrrhenian Sea is presented. Using geometric features of the veins, the physical conditions at the time of vein formation are estimated, namely the stress ratio (Φ = (σ2 − σ3)/(σ1 − σ3)), driving stress ratio (R′ = (Pf − σ3)/(σ1 − σ3)) and fluid overpressure (ΔPo = Pf − σ3). Two vein sets (A veins and B veins) have been recognized based on orientation and thickness distributions and infilling material. Analysis of vein pole distributions indicates Φ = 0.57 and R′ = 0.24 for the A veins and Φ = 0.58 and R′ = 0.47 for the B veins, and fluid pressures less than the intermediate stress magnitude. Analysis of geometric features of the veins gives estimated fluid overpressures of between ∼16 MPa (A veins) and ∼32 MPa (B veins). We propose a model for the tectonic environment of vein development, in which formation of secondary permeability in the deforming thermal aureole of the Porto Azzurro pluton was controlled by ongoing development of fracture systems in the hinge zone of a regional NNW–SSE trending fold that favored transport and localization of hydrothermal fluids.
    Description: Published
    Description: 1509-1522
    Description: 3.2. Tettonica attiva
    Description: 3.3. Geodinamica e struttura dell'interno della Terra
    Description: JCR Journal
    Description: reserved
    Keywords: Thermal aureole ; Upper crust ; Deformation ; Fluid circulation ; Northern Apennines ; Elba Island ; 04. Solid Earth::04.04. Geology::04.04.09. Structural geology ; 04. Solid Earth::04.07. Tectonophysics::04.07.02. Geodynamics ; 04. Solid Earth::04.07. Tectonophysics::04.07.07. Tectonics
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  • 18
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    Wind as a main driver of the net ecosystem carbon balance of a semiarid Mediterranean steppe in the South East of Spain (2012)
    Blackwell Publishing Ltd
    Details
    Publication Date: 2017-04-04
    Description: Despite the advance in our understanding of the carbon exchange between terrestrial ecosystems and the atmosphere, semiarid ecosystems have been poorly investigated and little is known about their role in the global carbon balance. We used eddy covariance measurements to determine the exchange of CO2 between a semiarid steppe and the atmosphere over 3 years. The vegetation is a perennial grassland of Stipa tenacissima L. located in the SE of Spain. We examined diurnal, seasonal and interannual variations in the net ecosystem carbon balance (NECB) in relation to biophysical variables. Cumulative NECB was a net source of 65.7, 143.6 and 92.1 g C mˉ2 yrˉ1 for the 3 years studied, respectively. We separated the year into two distinctive periods: dry period and growing season. The ecosystem was a net source of CO2 to the atmosphere, particularly during the dry period when large CO2 positive fluxes of up to 15 μmol mˉ2 sˉ1 were observed in concomitance with large wind speeds. Over the growing season, the ecosystem was a slight sink or neutral with maximum rates of -2.3 μmol mˉ2 sˉ1. Rainfall events caused large fluxes of CO2 to the atmosphere and determined the length of the growing season. In this season, photosynthetic photon flux density controlled day-time NECB just below 1000 μmol mˉ2 sˉ1. The analyses of the diurnal and seasonal data and preliminary geological and gas-geochemical evaluations, including C isotopic analyses, suggest that the CO2 released was not only biogenic but most likely included a component of geothermal origin, presumably related to deep fluids occurring in the area. These results highlight the importance of considering geological carbon sources, as well as the need to carefully interpret the results of eddy covariance partitioning techniques when applied in geologically active areas potentially affected by CO2-rich geofluid circulation.
    Description: Published
    Description: 539–554
    Description: 4.5. Studi sul degassamento naturale e sui gas petroliferi
    Description: JCR Journal
    Description: reserved
    Keywords: alpha grass ; carbon sequestration ; ecosystem respiration ; eddy covariance ; geogas ; geothermal activity ; grasslands ; net ecosystem carbon balance ; 04. Solid Earth::04.04. Geology::04.04.12. Fluid Geochemistry
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  • 19
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    Seismogenic sources of the Adriatic domain (2012)
    Elsevier Science
    Details
    Publication Date: 2017-04-04
    Description: We present an overview of the seismogenic source model of the Adriatic domain included in the latest version of the DISS database (http://diss.rm.ingv.it/diss/) and in the European SHARE database (http://diss.rm.ingv.it/SHARE/). The model consists of Composite and Individual Seismogenic Sources located inside and along the margins of the Adria plate. In order to locate and parameterize the sources, we integrated a wide set of geological, geophysical, seismological and geodynamic data, either available from published literature or resulting from our own field work, seismic profile interpretations and numerical modelling studies. We grouped the sources into five regions based on geometrical and kinematic homogeneity criteria. Seismogenic sources of the Central Western Adriatic, North-Eastern Adriatic, Eastern Adriatic and Central Adriatic regions belong to the Northern Apennines, External Dinarides and offshore domains, respectively. They are characterized by NWeSE strike, reverse to oblique kinematics and shallow crustal seismogenic depth. Seismogenic sources of the Southern Western Adriatic region instead are EeW striking, dextral strike-slip faults, cutting both the upper and lower crust. The fastest moving seismogenic sources are the most southern thrusts of the Eastern Adriatic and the strike-slip sources of the Southern Western Adriatic, while the seismogenic sources of the Central Adriatic exhibit the lowest slip rates. Estimates of maximum magnitude are generally in good agreement with the historical and instrumental earthquake records, except for the North-Eastern Adriatic region, where seismogenic sources exhibit a potential for large earthquakes even though no strong events have been reported or registered. All sources included in the database are fully geometrically and kinematically parameterized and can be incorportaed in seismic hazard calculations and earthquake or tsunami scenario simulations.
    Description: Published
    Description: 191-213
    Description: 3.2. Tettonica attiva
    Description: JCR Journal
    Description: partially_open
    Keywords: Active tectonics ; Seismogenic sources ; Apennines ; External Dinarides ; Adriatic domain ; 04. Solid Earth::04.04. Geology::04.04.01. Earthquake geology and paleoseismology ; 04. Solid Earth::04.04. Geology::04.04.09. Structural geology ; 04. Solid Earth::04.06. Seismology::04.06.01. Earthquake faults: properties and evolution ; 04. Solid Earth::04.07. Tectonophysics::04.07.07. Tectonics
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  • 20
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    A pilot GIS database of active faults of Mt. Etna (Sicily): A tool for integrated hazard evaluation (2012)
    Elsevier Science Limited
    In:  Supplementary data associated with this article can be found in the online version, at http://dx.doi.org/10.1016/j.jvolgeores.2012.08. 013.
    Details
    Publication Date: 2017-04-04
    Description: A pilot GIS-based system has been implemented for the assessment and analysis of hazard related to active faults affecting the eastern and southern flanks of Mt. Etna. The system structure was developed in ArcGis® environment and consists of different thematic datasets that include spatially-referenced arc-features and associated database. Arc-type features, georeferenced into WGS84 Ellipsoid UTM zone 33 Projection, represent the five main fault systems that develop in the analysed region. The backbone of the GIS-based system is constituted by the large amount of information which was collected from the literature and then stored and properly geocoded in a digital database. This consists of thirty five alpha-numeric fields which include all fault parameters available from literature such us location, kinematics, landform, slip rate, etc. Although the system has been implemented according to the most common procedures used by GIS developer, the architecture and content of the database represent a pilot backbone for digital storing of fault parameters, providing a powerful tool in modelling hazard related to the active tectonics of Mt. Etna. The database collects, organises and shares all scientific currently available information about the active faults of the volcano. Furthermore, thanks to the strong effort spent on defining the fields of the database, the structure proposed in this paper is open to the collection of further data coming from future improvements in the knowledge of the fault systems. By layering additional user-specific geographic information and managing the proposed database (topological querying) a great diversity of hazard and vulnerability maps can be produced by the user. This is a proposal of a backbone for a comprehensive geographical database of fault systems, universally applicable to other sites.
    Description: Published
    Description: 170-186
    Description: 1.5. TTC - Sorveglianza dell'attività eruttiva dei vulcani
    Description: 3.2. Tettonica attiva
    Description: 4.3. TTC - Scenari di pericolosità vulcanica
    Description: 5.5. TTC - Sistema Informativo Territoriale
    Description: JCR Journal
    Description: reserved
    Keywords: GIS-based system ; Hazard assessment ; Volcano-tectonics ; Flank dynamics ; Georeferenced arc-features ; Active fault database ; 04. Solid Earth::04.01. Earth Interior::04.01.99. General or miscellaneous ; 04. Solid Earth::04.04. Geology::04.04.99. General or miscellaneous ; 04. Solid Earth::04.04. Geology::04.04.06. Rheology, friction, and structure of fault zones ; 04. Solid Earth::04.04. Geology::04.04.09. Structural geology ; 04. Solid Earth::04.06. Seismology::04.06.99. General or miscellaneous ; 04. Solid Earth::04.07. Tectonophysics::04.07.99. General or miscellaneous ; 04. Solid Earth::04.07. Tectonophysics::04.07.02. Geodynamics ; 04. Solid Earth::04.07. Tectonophysics::04.07.05. Stress ; 04. Solid Earth::04.07. Tectonophysics::04.07.07. Tectonics ; 04. Solid Earth::04.08. Volcanology::04.08.99. General or miscellaneous ; 04. Solid Earth::04.08. Volcanology::04.08.06. Volcano monitoring ; 04. Solid Earth::04.08. Volcanology::04.08.07. Instruments and techniques ; 05. General::05.08. Risk::05.08.99. General or miscellaneous
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  • 21
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    An alternative model for the recent evolution of the Northern–Central Apennines (Italy) (2012)
    Elsevier Science Limited
    Details
    Publication Date: 2017-04-04
    Description: The aim of this paper is to propose an alternative model for the Pliocene-Quaternary to present evolution of the Northern–Central Apennines by combining geometrical requirements (Riedel shear system) with existing structural and geological geometries (fault systems and their tectonic associations). We define three sectors characterized by different geological, seismological, geodetic and geothermal signatures: the North-Western Sector (NWS), the Western Central Sector (WCS) and the Eastern Central Sector (ECS). According to GPS data derived from literature the three blocks move independently. In particular, the NWS is bound between the ECS/WCS and the Alps; this constraint leads to a stress accumulation responsible for a fragmentation into further several blocks, which move either to the NE or SW. The WCS is relatively stable; the ECS moves towards NE and is characterized by the presence of numerous releasing and restraining bends, which can be related to the action of a main NNW–SSE left-lateral shear zone. Accordingly, the recent and active tectonic setting of the Northern–Central Apennines is rather related to the dynamics of the introduced blocks, caused by the push of the African plate against Europe, than to subduction processes.
    Description: Published
    Description: 55-63
    Description: 3.3. Geodinamica e struttura dell'interno della Terra
    Description: JCR Journal
    Description: restricted
    Keywords: Northern-Central Apennines ; Riedel shear system ; Strike slip ; Restraining and releasing bends ; 04. Solid Earth::04.07. Tectonophysics::04.07.02. Geodynamics
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  • 22
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    Seismic moment tensors and regional stress in the area of the December 2013–January 2014, Matese earthquake sequence (Italy) (2014)
    Elsevier Science Limited
    Details
    Publication Date: 2017-04-04
    Description: The main goal of this study is to provide moment tensor solutions for small and moderate earthquakes of the Matese seismic sequence in southern Italy for the period of December 2013–January 2014. We estimate the focal mechanisms of 31 earthquakes with local magnitudes related to the Matese earthquake seismic sequence (December 2013–January 2014) in Southern-Central Italy which are recorded by the broadband stations of the Italian National Seismic Network and the Mediterranean Very Broadband Seismographic Network (MedNet) run by the Istituto Nazionale di Geofisica e Vulcanologia (INGV). The solutions show that normal faulting is the prevailing style of seismic deformation in agreement with the local faults mapped outin the area. Comparisons with already published solutions and with seismological and geological information available allowed us to properly interpret the moment tensor solutions in the frame of the seismic sequence evolution and also to furnish additional information about less energetic seismic phases. Focal data were inverted to obtain the seismogenic stress in the study area. The results are compatible with the major tectonic domain of the area.
    Description: Published
    Description: 118-124
    Description: 2T. Tettonica attiva
    Description: JCR Journal
    Description: restricted
    Keywords: Moment tensors ; Southern Italy ; Apennines ; Stress inversion ; Seismicity and tectonics ; 04. Solid Earth::04.06. Seismology::04.06.03. Earthquake source and dynamics
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  • 23
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    Offshore and onshore seepage of thermogenic gas at Katakolo Bay (Western Greece) (2013)
    Elsevier Science Limited
    Details
    Publication Date: 2017-04-04
    Description: Considerable seepage of natural gas occurs throughout the Katakolo Bay, both at sea and on land, along the Ionian coast of Peloponnesus (Western Greece). Explosive levels of CH4 and toxic concentrations of H2S accumulating in the ground, pose a severe hazard for humans and tourist infrastructures. A wide offshore and onshore gas survey, including marine remote sensing, underwater exploration by a towed instrumented system, compositional and isotopic analyses, and flux measurements of gas, allowed us to assess that: (a) gas seepage takes place along two main normal faults; (b) offshore side-scan sonographs recorded at least 823 gas bubble plumes over an area of 94,200 m2, at depths ranging from 5.5 to 16 m; (c) offshore and onshore seeps release the same type of thermogenic gas (δ13CCH4~−34 to −36‰); (d) offshore gas showed increased stable carbon isotopic ratio of CO2 and propane, which suggests enhanced biodegradation of hydrocarbons; (e) isotopic data combined with thermogenic gas generation modeling and maturity plots, suggest that the gas is related to a deep Petroleum System with Jurassic carbonate reservoirs, Triassic source rocks, and Triassic evaporites; (f) H2S (δ34S: +2.4‰) is produced by thermochemical sulfate reduction in deep anhydrites, in contact with hydrocarbon-rich carbonates; (g) due to the shallow depth, more than 90% of CH4 released at the seabed enters the atmosphere, consistent with theoretical bubble dissolution models, with a mean plume output of 0.12 kg d−1; total offshore CH4 output was estimated in the range of 33 to 120 t y−1; and (h) in the onshore area at least 50 gas vents in the harbor and a large seep on the adjacent Faros hill, emit in total about 89 t CH4 y−1. Katakolo results to be one of the biggest thermogenic gas seepage zones in Europe.
    Description: Published
    Description: 115–126
    Description: 4.5. Studi sul degassamento naturale e sui gas petroliferi
    Description: JCR Journal
    Description: restricted
    Keywords: Gas seeps ; Thermogenic methane ; Bubble plumes ; Hydrocarbon biodegradation ; 04. Solid Earth::04.04. Geology::04.04.12. Fluid Geochemistry
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
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  • 24
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    Continuous monitoring of hydrogen and carbon dioxide at Mt Etna (2013)
    Elsevier Science Limited
    Details
    Publication Date: 2017-04-04
    Description: This study assessed the use of a H2 fuel cell as an H2-selective sensor for volcano monitoring. The resolution, repeatability, and cross-sensitivity of the sensor were investigated and evaluated under known laboratory conditions. A tailor-made device was developed and used for continuously monitoring H2 and CO2 at Mt Etna throughout 2009 and 2010. The temporal variations of both parameters were strongly correlated with the evolution of the volcanic activity during the monitoring period. In particular, the CO2 flux exhibited long-term variations, while H2 exhibited pulses immediately before the explosive activity that occurred at Mt Etna during 2010.
    Description: Published
    Description: 41–51
    Description: 1.2. TTC - Sorveglianza geochimica delle aree vulcaniche attive
    Description: JCR Journal
    Description: reserved
    Keywords: Soil CO2 flux ; H2 monitoring ; 04. Solid Earth::04.04. Geology::04.04.12. Fluid Geochemistry ; 04. Solid Earth::04.06. Seismology::04.06.10. Instruments and techniques ; 04. Solid Earth::04.08. Volcanology::04.08.06. Volcano monitoring
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  • 25
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    Societal need for improved understanding of climate change, anthropogenic impacts, and geo-hazard warning drive development of ocean observatories in European Seas (2011)
    Elsevier
    Details
    Publication Date: 2017-04-04
    Description: Society’s needs for a network of in situ ocean observing systems cross many areas of earth and marine science. Here we review the science themes that benefit from data supplied from ocean observatories. Understanding from existing studies is fragmented to the extent that it lacks the coherent long-term monitoring needed to address questions at the scales essential to understand climate change and improve geo-hazard early warning. Data sets from the deep sea are particularly rare with long-term data available from only a few locations worldwide. These science areas have impacts on societal health and well-being and our awareness of ocean function in a shifting climate. Substantial efforts are underway to realise a network of open-ocean observatories around European Seas that will operate over multiple decades. Some systems are already collecting high-resolution data from surface, water column, seafloor, and sub-seafloor sensors linked to shore by satellite or cable connection in real or near-real time, along with samples and other data collected in a delayed mode. We expect that such observatories will contribute to answering major ocean science questions including: How can monitoring of factors such as seismic activity, pore fluid chemistry and pressure, and gas hydrate stability improve seismic, slope failure, and tsunami warning? What aspects of physical oceanography, biogeochemical cycling, and ecosystems will be most sensitive to climatic and anthropogenic change? What are natural versus anthropogenic changes? Most fundamentally, how are marine processes that occur at differing scales related? The development of ocean observatories provides a substantial opportunity for ocean science to evolve in Europe. Here we also describe some basic attributes of network design. Observatory networks provide the means to coordinate and integrate the collection of standardised data capable of bridging measurement scales across a dispersed area in European Seas adding needed certainty to estimates of future oceanic conditions. Observatory data can be analysed along with other data such as those from satellites, drifting floats, autonomous underwater vehicles, model analysis, and the known distribution and abundances of marine fauna in order to address some of the questions posed above. Standardised methods for information management are also becoming established to ensure better accessibility and traceability of these data sets and ultimately to increase their use for societal benefit. The connection of ocean observatory effort into larger frameworks including the Global Earth Observation System of Systems (GEOSS) and the Global Monitoring of Environment and Security (GMES) is integral to its success. It is in a greater integrated framework that the full potential of the component systems will be realised.
    Description: Published
    Description: 1-33
    Description: 3.7. Dinamica del clima e dell'oceano
    Description: JCR Journal
    Description: reserved
    Keywords: Seafloor and water columnobservatories ; 01. Atmosphere::01.01. Atmosphere::01.01.02. Climate ; 01. Atmosphere::01.01. Atmosphere::01.01.04. Processes and Dynamics ; 01. Atmosphere::01.01. Atmosphere::01.01.08. Instruments and techniques ; 03. Hydrosphere::03.01. General::03.01.03. Global climate models ; 03. Hydrosphere::03.01. General::03.01.07. Physical and biogeochemical interactions ; 03. Hydrosphere::03.01. General::03.01.08. Instruments and techniques ; 03. Hydrosphere::03.03. Physical::03.03.01. Air/water/earth interactions ; 03. Hydrosphere::03.03. Physical::03.03.02. General circulation ; 03. Hydrosphere::03.03. Physical::03.03.03. Interannual-to-decadal ocean variability ; 03. Hydrosphere::03.03. Physical::03.03.05. Instruments and techniques ; 03. Hydrosphere::03.04. Chemical and biological::03.04.01. Biogeochemical cycles ; 03. Hydrosphere::03.04. Chemical and biological::03.04.02. Carbon cycling ; 03. Hydrosphere::03.04. Chemical and biological::03.04.03. Chemistry of waters ; 03. Hydrosphere::03.04. Chemical and biological::03.04.04. Ecosystems ; 03. Hydrosphere::03.04. Chemical and biological::03.04.05. Gases ; 03. Hydrosphere::03.04. Chemical and biological::03.04.06. Hydrothermal systems ; 03. Hydrosphere::03.04. Chemical and biological::03.04.08. Instruments and techniques ; 04. Solid Earth::04.01. Earth Interior::04.01.02. Geological and geophysical evidences of deep processes ; 04. Solid Earth::04.04. Geology::04.04.04. Marine geology ; 04. Solid Earth::04.04. Geology::04.04.11. Instruments and techniques ; 04. Solid Earth::04.04. Geology::04.04.12. Fluid Geochemistry ; 04. Solid Earth::04.05. Geomagnetism::04.05.05. Main geomagnetic field ; 04. Solid Earth::04.05. Geomagnetism::04.05.08. Instruments and techniques ; 04. Solid Earth::04.06. Seismology::04.06.06. Surveys, measurements, and monitoring ; 04. Solid Earth::04.06. Seismology::04.06.07. Tomography and anisotropy ; 04. Solid Earth::04.06. Seismology::04.06.08. Volcano seismology ; 04. Solid Earth::04.06. Seismology::04.06.10. Instruments and techniques ; 04. Solid Earth::04.07. Tectonophysics::04.07.02. Geodynamics ; 04. Solid Earth::04.07. Tectonophysics::04.07.03. Heat generation and transport ; 04. Solid Earth::04.07. Tectonophysics::04.07.04. Plate boundaries, motion, and tectonics ; 04. Solid Earth::04.07. Tectonophysics::04.07.07. Tectonics ; 04. Solid Earth::04.08. Volcanology::04.08.01. Gases ; 04. Solid Earth::04.08. Volcanology::04.08.02. Experimental volcanism ; 04. Solid Earth::04.08. Volcanology::04.08.06. Volcano monitoring ; 04. Solid Earth::04.08. Volcanology::04.08.07. Instruments and techniques ; 05. General::05.01. Computational geophysics::05.01.01. Data processing ; 05. General::05.02. Data dissemination::05.02.99. General or miscellaneous ; 05. General::05.02. Data dissemination::05.02.01. Geochemical data ; 05. General::05.02. Data dissemination::05.02.02. Seismological data ; 05. General::05.02. Data dissemination::05.02.03. Volcanic eruptions ; 05. General::05.02. Data dissemination::05.02.04. Hydrogeological data ; 05. General::05.08. Risk::05.08.01. Environmental risk ; 05. General::05.08. Risk::05.08.02. Hydrogeological risk
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  • 26
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    Seismotectonic features from accurate hypocentre locations in southern central Andes (western Argentina) (2011)
    Elsevier Science Limited
    Details
    Publication Date: 2017-04-04
    Description: A local seismic network, over a five-year period, recorded about 450 earthquakes in western Argentina. In this region, the geodynamics is controlled by the subduction of the Nazca plate beneath the South American lithosphere, which is characterised here by a sub-horizontal path before reassuming its downward descent. As accurate earthquake locations are of primary importance when studying the seismicity of a given area, events recorded by the local seismic network enable in-depth investigations into seismo-tectonic patterns, allowing to improve the earthquake source characterization and knowledge on the ongoing seismo-tectonics of the region. To this end, we performed a simultaneous 1-D inversion of both the velocity structure and the hypocentre location. The minimum 1-D model obtained is complemented by station corrections which lead to a first insight into the deeper 3-D structure. In addition, stability tests were performed to verify the robustness of our earthquake location results. They reveal a fairly stable hypocentre determination, demonstrating that the locations obtained by the inversion process are not systematically biased. The results show that Sierra Pie de Palo is characterised by a crustal seismogenic structure, dipping west and extending from its eastern boundary to about 30 km of depth. The study also provided new constraints on the geometry of the subducted slab. We noted a great concentration of shallower seismicity compared to that of the surrounding areas of the Wadati-Benioff zone, at the expected position of the Juan Fernandez Ridge (JFR). Our hypocentres indicate that JFR certainly influences the subduction style along its strike, leading to the formation of a bend in the slab geometry.
    Description: Published
    Description: 44-54
    Description: 3.2. Tettonica attiva
    Description: JCR Journal
    Description: restricted
    Keywords: Minimum 1-D velocity model ; high precision earthquake location ; seismogenic structure ; flat-slab subduction ; 04. Solid Earth::04.07. Tectonophysics::04.07.02. Geodynamics
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  • 27
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    New evidence of mantle heterogeneity beneath the Hyblean Plateau (southeast Sicily, Italy) as inferred from noble gases and geochemistry of ultramafic xenoliths (2011)
    Elsevier
    Details
    Publication Date: 2017-04-04
    Description: We analyzed major and trace elements, Sr and Nd isotopes in ultramafic xenoliths in Miocenic age Hyblean diatremes, along with noble gases of CO2-rich fluid inclusions hosted in the same products. The xenoliths consist of peridotites and pyroxenites, which are considered to be derived from the upper mantle. Although the mineral assemblage of peridotites and their whole-rock abundance of major elements (e.g., Al2O3 = 0.8–1.5 wt.%, TiO2 = 0.03–0.08 wt.%) suggest a residual character of the mantle, a moderate enrichment in some incompatible elements (e.g., LaN/YbN = 9–14) highlights the presence of cryptic metasomatic events. In this context a deep silicate liquid is considered the metasomatizing agent, which is consistent with the occurrence of pyroxenites as veins in peridotites. Both the Zr/Nb and 143Nd/144Nd ratios of the investigated samples reveal two distinct compositional groups: (1) peridotites with Zr/Nb ≈ 4 and 143Nd/144Nd ≈ 0.5129, and (2) pyroxenites with Zr/Nb ≈ 20 and 143Nd/144Nd ≈ 0.5130. The results of noble-gas analyses also highlight the difference between the peridotite and pyroxenite domains. Indeed, the 3He/4He and 4He/40Ar* ratios measured in the fluid inclusions of peridotites (respectively 7.0–7.4 ± 0.1 Ra and 0.5–8.2, where Ra is the atmospheric 3He/4He ratio of 1.38 × 10− 6) were on average lower than those for the pyroxenites (respectively 7.2–7.6 Ra and 0.62–15). This mantle heterogeneity is interpreted as resulting from a mixing between two end-members: (1) a peridotitic layer with 3He/4He ≈ 7 Ra and 4He/40Ar* ≈ 0.4, which is lower than the typical mantle ratio (~ 1–4) probably due to melt extraction events, and (2) metasomatizing mafic silicate melts that gave rise to pyroxenites characterized by 3He/4He ≈ 7.6 Ra, with a variable 4He/40Ar* due to degassing processes connected with the ascent of magma at different levels in the peridotite wall rock. The complete geochemical data set also suggests two distinct mantle sources for the xenolithic groups highlighted above: (1) a HIMU (high-μ)-type source for the peridotites and (2) a DM (depleted mantle)-type source for the pyroxenites.
    Description: Published
    Description: 70-81
    Description: 2.4. TTC - Laboratori di geochimica dei fluidi
    Description: JCR Journal
    Description: restricted
    Keywords: noble gases ; mantle ; xenoliths ; fluid inclusions ; 04. Solid Earth::04.04. Geology::04.04.12. Fluid Geochemistry
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  • 28
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    Strain and stress fields in the Southern Apennines (Italy) constrained by geodetic, seismological and borehole data (2012)
    Blackwell Publishing Ltd
    Details
    Publication Date: 2017-04-04
    Description: We present an improved evaluation of the current strain and stress fields in Southern Apennines (Italy) obtained through a careful analysis of geodetic, seismological and borehole data. In particular, our analysis provides an updated comparison between the accrued strain recorded by geodetic data, and the strain released by seismic activity in a region hit by destructive historical earthquakes. To this end, we have used 9 years of GPS observations (2001-2010) from a dense network of permanent stations, a dataset of 73 well constrained stress indicators (borehole breakouts and focal mechanisms of moderate to large earthquakes), and published estimations of the geological strain accommodated by active faults in the region. Although geodetic data are generally consistent with seismic and geologic information, previously unknown features of the current deformation in southern Italy emerge from this analysis. The newly obtained GPS velocity field supports the well-established notion of a dominant NE-SW-oriented extension concentrated in a ~50 km wide belt along the topographic relief of the Apennines, as outlined by the distribution of seismogenic normal faults. Geodetic deformation is, however, non uniform along the belt, with two patches of higher strain-rate and shear stress accumulation in the north (Matese Mountains) and in the south (Irpinia area). Low geodetic strain-rates are found in the Bradano basin and Apulia plateau to the east. Along the Ionian Sea margin of southern Italy, in southern Apulia and eastern Basilicata and Calabria, geodetic velocities indicate NW-SE extension which is consistent with active shallow-crustal gravitational motion documented by geological studies. In the west, along the Tyrrhenian margin of the Campania region, the tectonic geodetic field is disturbed by volcanic processes. Comparison between the magnitude of the geodetic and the seismic strain-rates (computed using a long historical seismicity catalogue) allow detecting areas of high correlation, particularly along the axis of the mountain chain, indicating that most of the geodetic strain is released by earthquakes. This relation does not hold for the instrumental seismic catalogue, as a consequence of the limited time span covered by instrumental data. In other areas (e.g. Murge plateau in central Apulia), where seismicity is very low or absent, the yet appreciable geodetic deformation might be accommodated in aseismic mode. Overall, the excellent match between the stress and the strain-rate directions in much of the Apennines indicates that both earthquakes and ground deformation patterns are driven by the same crustal forces.
    Description: Published
    Description: 1270-1282
    Description: 3.2. Tettonica attiva
    Description: JCR Journal
    Description: restricted
    Keywords: Satellite geodesy ; Plate motions ; Neotectonics ; Europe ; Apennines ; 04. Solid Earth::04.03. Geodesy::04.03.01. Crustal deformations
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  • 29
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    Can local earthquake tomography settle the matter about subduction in the Northern and Central Apennines? Response from a new high resolution P velocity and Vp/Vs ratio 3-D model (2012)
    Elsevier Science Limited
    Details
    Publication Date: 2017-04-04
    Description: According to the most common interpretation, the Apennines developed in Neogene and Quaternary times in the hanging wall of a west directed subduction zone. Seismic tomography is the most powerful tool to investigate large volume of Earth at depth, and it has been extensively applied to shed light on the geometry and shape of the subduction under the Italian peninsula. The various experiments were able to display the slab under the Southern Apennines, but even the most recent tomographic images were non-uniquely interpretable and left open questions about the characteristics of the subduction in the Northern-Central sector of the chain. We here present the results of an improved inversion experiment focused on the Northern and Central Apennines. The results do not show any pronounced subduction slab and the most evident anomaly is a low velocity body extending down to 100 km depth, located in a relatively small area under the western Tuscany. On the basis of accurate synthetic tests, we assess that, if established, a subduction like geometry should be visible in our tomographic images. We then conclude that no subduction is imaged in the Northern and Central Apennines. We thus interpret this anomaly as an asthenospheric flow. However, we cannot exclude that our result is due to intrinsic limitations of the methodology. In fact in response to the original question about the capability of local earthquake tomography to settle the matter about subduction, we underline that the absence of deep earthquakes to illuminate the model from below, the existence of seismic gaps in some sectors of the area under study even at shallow depth and the non uniqueness of interpretation of the tomographic images make local tomography unable to give alone definitive information on the deep structure of the Northern and Central Apennines.
    Description: Published
    Description: 63-73
    Description: 3.3. Geodinamica e struttura dell'interno della Terra
    Description: JCR Journal
    Description: restricted
    Keywords: Seismic tomography ; Apennines ; Subduction ; Asthenospheric upwelling ; 04. Solid Earth::04.06. Seismology::04.06.07. Tomography and anisotropy
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  • 30
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    Soil gases and SAR measurements reveal hidden faults on the sliding flank of Mt. Etna (Italy) (2012)
    Elsevier Science Limited
    Details
    Publication Date: 2017-04-04
    Description: From October 2008 to November 2009, soil CO2, radon and structural field surveys were performed on Mt. Etna, in order to acquire insights into active tectonic structures in a densely populated sector of the south-eastern flank of the volcano, which is involved in the flank dynamics, as highlighted by satellite data (InSAR). The studied area extends about 150 km2, in a sector of the volcano where InSAR results detected several lineaments that were not well-defined from previous geological surveys. In order to validate and better constrain these features with ground data evidences, soil CO2 and soil radon measurements were performed along transects roughly orthogonal to the newly detected faults, with measurement points spaced about 100 m. In each transect, the highest CO2 values were found very close to the lineaments evidenced by InSAR observations. Anomalous soil CO2 and radon values were also measured at old eruptive fractures. In some portions of the investigated area soil gas anomalies were rather broad over transects, probably suggesting a complex structural framework consisting of several parallel volcano-tectonic structures, instead of a single one. Soil gas measurements proved particularly useful in areas at higher altitude on Mt. Etna (i.e. above 900 m asl), where InSAR results are not very informative/ are fairly limited, and allowed recognizing the prolongation of some tectonic lineaments towards the summit of the volcano. At a lower altitude on the volcanic edifice, soil gas anomalies define the active structures indicated by InSAR results prominently, down to almost the coastline and through the northern periphery of the city of Catania. Coupling InSARwith soil gas prospectingmethods has thus proved to be a powerful tool in detecting hidden active structures that do not show significant field evidences.
    Description: This work was funded by the DPC-INGV project “Flank”
    Description: Published
    Description: 27-40
    Description: 3.2. Tettonica attiva
    Description: JCR Journal
    Description: reserved
    Keywords: CO2 ; Radon ; InSAR ; Faults ; Etna ; Volcano-tectonics ; 04. Solid Earth::04.03. Geodesy::04.03.01. Crustal deformations ; 04. Solid Earth::04.03. Geodesy::04.03.07. Satellite geodesy ; 04. Solid Earth::04.04. Geology::04.04.12. Fluid Geochemistry ; 04. Solid Earth::04.07. Tectonophysics::04.07.07. Tectonics ; 04. Solid Earth::04.08. Volcanology::04.08.01. Gases ; 04. Solid Earth::04.08. Volcanology::04.08.07. Instruments and techniques
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  • 31
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    The deformation offshore of Mount Etna as imaged by multichannel seismic reflection profiles (2012)
    Elsevier
    Details
    Publication Date: 2017-04-04
    Description: Despite the clear evidence of active flank dynamics that is affecting the eastern side of Mount Etna, the contribution of tectonic processes has not been yet understood. So far, the various models proposed to explain the observed flank deformation have been based on onshore structural data, coming from the volcanic edifice. The Ionian offshore of Mount Etna has been only recently investigated using multichannel seismic profiles, and offers the opportunity to image the structural features of the substrate of the unstable flank of the volcano. This contribution aims at describing the deformation located offshore Mount Etna using multichannel seismic profiles recently acquired during three seismic surveys. The onshore flank deformation of Mount Etna appears to be laterally confined by two tectonic guidelines, trending roughly E–W, located to the north and south of the deforming flank; the northern guideline, in particular, takes the surface expression of a sharp fault (Pernicana Fault). Though often assumed that these boundary structures continue offshore as linear features, connected to a frontal thrust ramp, the occurrence of this simple offshore structural system has not been imaged. In fact, seismic data show a remarkable degree of structural complexity offshore Mount Etna. The Pernicana Fault, for instance, is not continuing offshore as a sharp feature; rather, the deformation is expressed as ENE–WSW folds located very close to the coastline. It is possible that these tectonic structures might have affected the offshore of Mount Etna before the Pernicana Fault system was developed, less than 15 ka ago. The southern guideline of the collapsing eastern flank of the volcano is poorly expressed onshore, and does not show up offshore; in fact, seismic data indicate that the Catania canyon, a remarkable E–W-trending feature, does not reflect a tectonic control. Seismic interpretation also shows the occurrence of a structural high located just offshore the edifice of Mount Etna. Whereas a complex deformation affects the boundary of this offshore bulge, it shows only limited internal deformation. Part of the topography of the offshore bulge pre-existed the constructional phase of Mount Etna, being an extension of the Hyblean Plateau. Only in the northern part, the bulge is a recent tectonic feature, being composed by Plio-Quaternary strata that were folded before and during the building of Mount Etna. The offshore bulge is bounded by a thrust fault that can be related to the intrusion of the large-scale magmatic body below Mount Etna.
    Description: Published
    Description: 50-64
    Description: 3.2. Tettonica attiva
    Description: 3.3. Geodinamica e struttura dell'interno della Terra
    Description: 3.5. Geologia e storia dei vulcani ed evoluzione dei magmi
    Description: JCR Journal
    Description: restricted
    Keywords: Mount Etna offshore ; Volcano flank instability ; Active tectonics ; Multichannel reflection seismics ; Intrusive body ; 04. Solid Earth::04.04. Geology::04.04.04. Marine geology ; 04. Solid Earth::04.07. Tectonophysics::04.07.02. Geodynamics ; 04. Solid Earth::04.07. Tectonophysics::04.07.07. Tectonics ; 04. Solid Earth::04.08. Volcanology::04.08.02. Experimental volcanism
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  • 32
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    Foreland segmentation along an active convergent margin: New constraints in southeastern Sicily (Italy) from seismic and geodetic observations (2014)
    Elsevier Science Limited
    Details
    Publication Date: 2017-04-04
    Description: We performed an in-depth analysis of the ongoing tectonics of a large sector of southern Sicily, including the Hyblean Foreland and the front of the Maghrebian Chain, as well as the Ionian Sea offshore, through the integration of seismic and GPS observations collected in the nearly two decades. In particular, a dataset consisting of more than 1100 small-to moderate-magnitude earthquakes (1.0 ≤ ML ≤ 4.6) has been used for local earthquake tomography in order to trace the characteristics of the faulting systems, and for focal mechanisms computation to resolve the current local stress field and to characterise the faulting regime of the investigated area. In addition, GPS measurements, carried out on both episodic and continuous stations, allowed us to infer the main features of the current crustal deformation pattern. Main results evidence that the Hyblean Plateau is subject to a general strike–slip faulting regime, with a maximum horizontal stress axis NW–SE to NNW–SSE oriented, in agreement with the Eurasia–Nubia direction of convergence. The Plateau is separated into two different tectonic crustal blocks by the left-lateral strike–slip Scicli–Ragusa Fault System. The western block moves in agreement with central Sicily while the eastern one accommodates part of the contraction arising from the main Eurasia–Nubia convergence. Furthermore, we provided evidences leading to consider the Hyblean–Maltese Escarpment Fault System as an active boundary characterised by a left-lateral strike–slip motion, separating the eastern block of the Plateau from the Ionian basin. All these evidences lend credit to a crustal segmentation of the southeastern Sicily.
    Description: Published
    Description: 137-149
    Description: 1T. Geodinamica e interno della Terra
    Description: JCR Journal
    Description: open
    Keywords: Southeastern Sicily ; Seismotectonics ; Tomography ; Focal mechanisms ; Crustal stress ; Geodetic strain rate ; 04. Solid Earth::04.07. Tectonophysics::04.07.02. Geodynamics
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  • 33
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    Methane flux from miniseepage in mud volcanoes of SW Taiwan: Comparison with the data from Italy, Romania, and Azerbaijan (2013)
    Elsevier Science Limited
    Details
    Publication Date: 2017-04-04
    Description: Mud volcanoes (MVs) are considered important methane (CH4) sources for the atmosphere; gas is not only released from macro-seepage, i.e., from craters and visible gas bubbling manifestations, but also from invisible and pervasive exhalation from the ground, named miniseepage. CH4 flux related to miniseepage was measured only in a few MVs, in Azerbaijan, Italy, Japan, Romania and Taiwan. This study examines in detail the flux data acquired in 5 MVs and 1 ‘‘dry’’ seep in SW Taiwan, and further compares with other 23 MVs in Italy, Romania and Azerbaijan. Miniseepage from the six manifestations in SW Taiwan MVs and seeps annually contribute at least 110 tons of methane directly to the atmosphere, and represents about 80% of total degassing during a quiescent period. Combining miniseepage flux and geo-electrical data from the Wu-shan-ding MV revealed a possible link between gas flux and electrical resistivity of the vadose zone. This suggests that unsaturated subsoil is a preferential zone for shallow gas accumulation and seepage to the atmosphere. Besides, miniseepage flux in Chu-huo everlasting fire decreases by increasing the distance from the main gas channeling zone and molecular fractionation (methane/ethane ratio) is higher for lower flux seepage, consistently with what observed in other MVs worldwide. Measurements from Azerbaijan, Italy, Romania, and Taiwan converge to indicate that miniseepage is directly proportional to the vent output and it is a significant component of the total methane budget of a MV. A miniseepage vs. macro-seepage flux equation has been statistically assessed and it can be used to estimate theoretically at least the order of magnitude of the flux of miniseepage for MVs of which only the flux from vents was evaluated, or will be evaluated in future. This will allow a more complete and objective quantification of gas emission in MVs, thus also refining the estimate of the global methane emission from geological sources.
    Description: Published
    Description: 3–12
    Description: 4.5. Studi sul degassamento naturale e sui gas petroliferi
    Description: JCR Journal
    Description: restricted
    Keywords: Mud volcano ; Miniseepage ; Macro-seepage ; Global methane emission ; 04. Solid Earth::04.04. Geology::04.04.12. Fluid Geochemistry
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  • 34
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    Chemical and isotopic characterisation of bulk deposition in the Louros basin (Epirus, Greece) (2013)
    Elsevier Science Limited
    Details
    Publication Date: 2017-04-04
    Description: About 120 rainwater samples were collected through a network of five bulk collectors in the area of the Louros basin (Epirus, Greece) during the wet season from October 2008 to August 2009. They were analysed for their isotopic (δD and δ18O) and chemical (H+, Na+, K+, Mg2+, Ca2+, NH4 +, F−, Cl−, Br−, NO3 −, SO4 2 −) composition. A local meteoric water line (δD‰ = 5.80 ± 0.02 δ18O‰ + 0.02 ± 0.12) and a local isotopic lapse rate (−0.18 δ18O‰/100 m) were obtained considering the volume-weighted means of the five sampling sites. These results agree well with those obtained in nearby areas. The chemical composition of the samples allows to identify an almost entirely marine origin for chloride and sodium with decreasing deposition values at increasing distance from the coast. Nitrate and ammonium are almost completely of anthropogenic origin, calcium and potassium are overwhelmingly geogenic, sulphate has a prevailingly anthropogenic origin with a significant marine contribution and magnesium has a mixedmarine and soil dust origin. Finally, as for most of the Mediterranean area, rainwater acidity is buffered by the dissolution of the abundant geogenic carbonate aerosol.
    Description: Published
    Description: 399-410
    Description: 4.4. Scenari e mitigazione del rischio ambientale
    Description: JCR Journal
    Description: restricted
    Keywords: Precipitation ; Neutralization ; Stable isotopes ; Chemical composition ; Bulk deposition ; 01. Atmosphere::01.01. Atmosphere::01.01.02. Climate ; 01. Atmosphere::01.01. Atmosphere::01.01.03. Pollution ; 01. Atmosphere::01.01. Atmosphere::01.01.07. Volcanic effects ; 02. Cryosphere::02.03. Ice cores::02.03.06. Precipitation ; 04. Solid Earth::04.04. Geology::04.04.12. Fluid Geochemistry
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  • 35
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    The episodic and abrupt geochemical changes at La Fossa fumaroles (Vulcano Island, Italy) and related constraints on the dynamics, structure, and compositions of the magmatic system (2013)
    Elsevier Science Limited
    Details
    Publication Date: 2017-04-04
    Description: Herein we report on the chemical and isotopic (C, H, O, and He) compositions of the fluids from La Fossa crater fumaroles of Vulcano from 1999 to 2010. Consistent with records obtained since the end of the 1980s, our data show that the geochemical features of the fumarole system have experienced several episodes of remarkable change, each lasting no more than a few months. Typical signatures of these short-term anomalies are large increments in CO2, N2, and He concentrations, coupled to increased 13C/12C isotopic ratios, but their meaning remains widely debated. Within a model of fumarolic fluids based on mixing between hydrothermal and magmatic endmembers, we have developed a novel approach to constrain chemical (He/ CO2 and N2/He) and isotopic (13C/12C, D/H, and 3He/4He) ratios of the magmatic endmember during the short-term anomalies. Although much of the geochemical variability in fumaroles results from changes in mixing proportions, the magmatic fluid unquestionably shows significant variations in time. The magmatic He/CO2, N2/He, 13C/12C, and 3He/4He values throughout 1988–1996 differed from those feeding the anomaly at the end of 2004. Early clues of the new magmatic fluid appeared in 1998–1999, far from any short-term anomaly, whereas new and old magmatic fluids coexisted after 2004. We quantitatively prove that the detected geochemical changes are consistent with the degassing path of a magma having a latitic composition, and suggest the presence of two magma ponding levels at slightly different pressures, where bubble–melt decoupling can occur. The different He-isotope compositions at these levels suggest low hydraulic connectivity typical of a complex reservoir with dike and sill structures. In this framework, the short-term geochemical anomalies are probably due to gas accumulation at the top of magma bodies followed by massive escape, or activation of new degassing levels in the reservoir, for which the stress field almost certainly plays a key role. Such a scenario explains the observed increases in both fumarole output and shallow high-frequency seismicity (due to increased pore pressure) during the anomalies, while being consistent with the concomitant absence of any deep seismicity or ground deformation, eventually related to magma movement.
    Description: Published
    Description: 158-178
    Description: 1.2. TTC - Sorveglianza geochimica delle aree vulcaniche attive
    Description: JCR Journal
    Description: restricted
    Keywords: fumarole geochemistry ; magma degassing ; thermodynamic modeling ; noble gas geochemistry ; carbon isotopes ; 04. Solid Earth::04.04. Geology::04.04.12. Fluid Geochemistry ; 04. Solid Earth::04.08. Volcanology::04.08.01. Gases ; 04. Solid Earth::04.08. Volcanology::04.08.03. Magmas ; 04. Solid Earth::04.08. Volcanology::04.08.04. Thermodynamics ; 04. Solid Earth::04.08. Volcanology::04.08.06. Volcano monitoring
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  • 36
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    Relations between deformation and upper crustal magma emplacement in laboratory physical models (2011)
    Elsevier
    Details
    Publication Date: 2020-05-28
    Description: This paper presents analogue models for the emplacement of granitic magmas in upper crustal levels with different mechanical layering during shortening, extension and strike–slip deformation. In particular, we investigated how a weak layer embedded in the upper brittle crust can control the level of magma emplacement. The adopted experimental setup was used to examine the control of soft rocks on the movement of magma through a deforming brittle crust. Model results indicate that the occurrence of a weak (soft) layer embedded in brittle (stiff) material has an impact on the level of magma emplacement. The level of emplacement during both extension and shortening was systematically deeper for models with a soft layer than for purely brittle models. During strike–slip deformation the magma pierced the surface in both purely brittle and brittle–ductile models.
    Description: Published
    Description: 139-146
    Description: 3.2. Tettonica attiva
    Description: 3.3. Geodinamica e struttura dell'interno della Terra
    Description: JCR Journal
    Description: reserved
    Keywords: Mechanical layering of upper crust ; Magma emplacement ; Analogue modelling ; 04. Solid Earth::04.01. Earth Interior::04.01.05. Rheology ; 04. Solid Earth::04.04. Geology::04.04.09. Structural geology ; 04. Solid Earth::04.04. Geology::04.04.12. Fluid Geochemistry
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  • 37
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    Fault architecture in the Main Ethiopian Rift and comparison with experimental models: Implications for rift evolution and Nubia–Somalia kinematics (2012)
    Elsevier
    Details
    Publication Date: 2020-05-28
    Description: The Main Ethiopian Rift (MER) offers a complete record of the time–space evolution of a continental rift. We have characterized the brittle deformation in different rift sectors through the statistical analysis of a new database of faults obtained from the integration between satellite images and digital elevation models, and implemented with field controls. This analysis has been compared with the results of lithospheric-scale analogue models reproducing the kinematical conditions of orthogonal and oblique rifting. Integration of these approaches suggests substantial differences in fault architecture in the different rift sectors that in turn reflect an along-axis variation of the rift development and southward decrease in rift evolution. The northernmost MER sector is in a mature stage of incipient continental rupture, with deformation localised within the rift floor along discrete tectono-magmatic segments and almost inactive boundary faults. The central MER sector records a transitional stage in which migration of deformation from boundary faults to faults internal to the rift valley is in an incipient phase. The southernmost MER sector is instead in an early continental stage, with the largest part of deformation being accommodated by boundary faults and almost absent internal faults. The MER thus records along its axis the typical evolution of continental rifting, from fault-dominated rift morphology in the early stages of extension toward magma-dominated extension during break-up. The extrapolation of modelling results suggests that a variable rift obliquity contributes to the observed along-axis variations in rift architecture and evolutionary stage, being oblique rifting conditions controlling the MER evolution since its birth in the Late Miocene in relation to a constant post ca. 11 Ma ~ N100°E Nubia–Somalia motion.
    Description: Published
    Description: 479-492
    Description: 3.2. Tettonica attiva
    Description: 3.3. Geodinamica e struttura dell'interno della Terra
    Description: JCR Journal
    Description: reserved
    Keywords: continental rifting ; East African Rift ; Main Ethiopian Rift ; rift kinematics ; plate kinematics ; 04. Solid Earth::04.04. Geology::04.04.09. Structural geology ; 04. Solid Earth::04.07. Tectonophysics::04.07.02. Geodynamics ; 04. Solid Earth::04.07. Tectonophysics::04.07.07. Tectonics
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  • 38
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    Microseepage in drylands: Flux and implications in the global atmospheric source/sink budget of methane (2010)
    Elsevier
    Details
    Publication Date: 2017-04-04
    Description: Drylands are considered a net sink for atmospheric methane and a main item of the global inventories of the greenhouse gas budget. It is outlined here, however, that a significant portion of drylands occur over sedimentary basins hosting natural gas and oil reservoirs, where gas migration to the surface takes place, producing positive fluxes of methane into the atmosphere. New field surveys, in different hydrocarbonprone basins, confirm that microseepage, enhanced by faults and fractures in the rocks, overcomes the methanotrophic consumption occurring in dry soil throughout large areas, especially in the winter season. Fluxes of a few units to some tens of mg m−2 day−1 are frequent over oil–gas fields, whose global extent is estimated at 3.5–4.2 million km2; higher fluxes (〉50 mg m−2 day−1) are primarily, but not exclusively, found in basins characterized by macro-seeps. Microseepage may however potentially exist over a wider area (∼8 million km2, i.e. 15% of global drylands), including the Total Petroleum Systems, coal measures and portions of sedimentary basins that have experienced thermogenesis. Based on a relatively large and geographically dispersed data-set (563 measurements) from different hydrocarbon-prone basins in USA and Europe, upscaling suggests that global microseepage emission exceeding 10 Tg year−1 is very likely. Microseepage is then only one component of a wider class of geological sources, including mud volcanoes, seeps, geothermal and marine seepage, which cannot be ignored in the atmospheric methane budget.
    Description: Published
    Description: 265-274
    Description: 4.5. Studi sul degassamento naturale e sui gas petroliferi
    Description: JCR Journal
    Description: restricted
    Keywords: microseepage ; methane flux ; soil sink ; drylands ; petroleum ; greenhouse gas ; 04. Solid Earth::04.04. Geology::04.04.12. Fluid Geochemistry
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  • 39
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    Benthic habitat characterization and distribution from two representative sites of the deep-water SML Coral Province (Mediterranean) (2010)
    Elsevier
    Details
    Publication Date: 2017-04-04
    Description: Two sites (MS04 and MS06) from the Santa Maria di Leuca (SML) Coral Province were analyzed by a video and acoustic survey during the National Italian Project Apulian Plateau Bank Ecosystem Study (APLABES). Site MS04 (Atlantis Mound) is characterized by a sub-conical mound, 500 m wide and 25 m high, located at a water depth of about 650 m. Site MS06 (Yellow Chain) comprises several elongated reliefs (NNW–SSE-oriented), up to 25 m high and 500 m in maximum lateral extent, located at a depth of between 490 and 540 m. At both sites, two main mesohabitats (mound and intermound) containing several coral-bearing and -barren macrohabitats were observed in recorded videos and detected in side-scan sonographs. The coral-rich macrohabitats, characterized by densely packed colonies of the scleractinians Madrepora oculata and, secondarily, Lophelia pertusa (M/L), are typically restricted to the mound areas. The mud-dominated ones, almost devoid of M/L colonies, are more common within the intermound mesohabitat. However, on the most extensive mounds, both macrohabitat typologies exist. They are heterogeneously distributed on the mound surface, often showing a clear differentiation along two opposite flanks of the same topographic feature. M/L-rich macrohabitats are preferentially located on top and along the mound northeastern flank, showing a typical step-like distribution, probably reflecting the arrangement of hard substrate outcrops. Along this flank, fan-shaped Madrepora colonies and sponges are often oriented NNW–SSE, implying, together with other evidence, a primary southwestern current flow. The hard-bottom macrohabitats of the southwestern mound flank are generally restricted to sparse exposed, subvertical to overhanging scarps as well as to heterometric boulders located at the scarp base. Their fauna is mainly characterized by small-sized organisms (such as sponges and solitary scleractinians) although m-sized boulders may locally host very large antipatharian colonies (Leiopathes glaberrima). The heterogeneous distribution of the observed benthic macrohabitats seems to be strictly related to the local topography, the main current flow (and consequently larvae/food supply per unit of time), and the substrate typology (hard- vs. soft-bottom).
    Description: Published
    Description: 380-396
    Description: 4.5. Studi sul degassamento naturale e sui gas petroliferi
    Description: JCR Journal
    Description: restricted
    Keywords: Deep-watercoralmound ; Habitat ; Mediterranean ; Madrepora ; Lophelia ; Visual survey ; Acoustic survey ; 04. Solid Earth::04.04. Geology::04.04.12. Fluid Geochemistry
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  • 40
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    Nuclear Instruments and Methods in Physics Research Section A: Accelerators, Spectrometers, Detectors and Associated Equipment (2010)
    Elsevier
    Details
    Publication Date: 2017-04-04
    Description: GEMS (Gamma Energy Marine Spectrometer) is a prototype of an autonomous radioactivity sensor for underwater measurements, developed in the framework for a development of a submarine telescope for neutrino detection (KM3NeT Design Study Project). The spectrometer is highly sensitive to gamma rays produced by 40K decays but it can detect other natural (e.g., 238U,232Th) and anthropogenic radio-nuclides (e.g., 137Cs). GEMS was firstly tested and calibrated in the laboratory using known sources and it was successfully deployed for a long-term (6 months) monitoring at a depth of 3200 m in the Ionian Sea (Capo Passero, offshore Eastern Sicily). The instrument recorded data for the whole deployment period within the expected specifications. This monitoring provided, for the first time, a continuous time-series of radioactivity in deep-sea.
    Description: In press
    Description: 4.5. Studi sul degassamento naturale e sui gas petroliferi
    Description: JCR Journal
    Description: open
    Keywords: NaI(Tl) sensor ; underwater spectrometer ; marine radioactivity ; 04. Solid Earth::04.04. Geology::04.04.12. Fluid Geochemistry
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  • 41
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    Helium and argon isotopic compositions of mantle xenoliths from Tallante and Calatrava, Spain. (2011)
    Elsevier
    Details
    Publication Date: 2017-04-04
    Description: We have analyzed by single-step crushing helium and argon isotopes in olivine and orthopyroxene from mantle xenoliths of Calatrava (CLV) in central Spain and Tallante (TL) in southeast Spain. The investigation focused on carefully selected samples previously characterized in terms of major and trace elements on both bulk rock and constituent minerals, and Sr and Nd isotopes on clinopyroxene separates. Six analyses were performed on protogranular spinel lherzolites from CLV, and 17 were performed on spinel harzburgites, lherzolites, and orthopyroxenites from TL. The 40Ar/36Ar ratio was between 296 and 622, indicating atmospheric contamination, which probably occurred during exposure to the surface. The helium-isotope ratio (3He/4He) ranged between 3.6 and 6.5 Ra in CLV samples and between 1.4 and 5.7 Ra in TL samples. There was a positive correlation between the 3He/4He and 4He/40Ar* ratios, possibly reflecting diffusive fractionation between 3He, 4He, and 40Ar within mantle sections interacting with ascending melts. However, the difference between the maximum 3He/4He ratios measured in CLV and TL appears to be related to significant differences in the metasomatic melts that affected the two sectors of the lithospheric mantle. In agreement with the findings of previous studies, the helium isotopes at CLV are compatible with metasomatism due to ascending HIMU-type asthenospheric melts. In contrast, the lower 3He/4He values recorded at TL suggest subduction-related metasomatic components that are possibly related to the Cenozoic subduction of the Betic system. Such event plausibly introduced crust-derived fluids that metasomatized the mantle wedge, slightly decreasing its 3He/4He value. Noble gases appear decoupled from other elements during these mantle processes, since comparatively low 3He/4He values have been recorded also in samples that are relatively unmetasomatized in terms of incompatible lithophile elements. We hypothesize a role for volatile-dominated, CO2-rich fluids progressively decoupling from the ascending metasomatic melts and migrating in the surrounding peridotite matrix to form a diffuse aureola enriched in noble gases.
    Description: Published
    Description: 18-26
    Description: 3.5. Geologia e storia dei vulcani ed evoluzione dei magmi
    Description: JCR Journal
    Description: reserved
    Keywords: noble gas ; xenoliths ; 04. Solid Earth::04.04. Geology::04.04.12. Fluid Geochemistry
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  • 42
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    Diffuse hydrothermal methane output and evidence of methanotrophic activity within the soils at Sousaki (Greece) (2011)
    Blackwell Publishing Ltd
    Details
    Publication Date: 2017-04-04
    Description: Methane soil flux measurements have been made in 38 sites at the geothermal system of Sousaki (Greece) with the closed chamber method. Fluxes range from –47.6 to 29,150 mg m-2 d-1 and the diffuse CH4 output of the system has been estimated at 19 t a-1. Contemporaneous CO2 flux measurements showed a moderate positive correlation between CO2 and CH4 fluxes. Comparison of the CO2/CH4 soil flux ratios with the CO2/CH4 ratio of the gases of the main gas manifestations provided evidence for methanotrophic activity within the soil. Laboratory CH4 consumption experiments confirmed the presence of methanotrophic microorganisms in soil samples collected at Sousaki. Consumption was generally in the range from –4.9 to –38.9 pmolCH4 h-1 g-1 but could sometimes reach extremely high values (–33,000 pmolCH4 h-1 g-1.). These results are consistent with recent studies on other geothermal systems that revealed the existence of thermoacidophilic bacteria exerting methanotrophic activity in hot, acid soils, thereby reducing methane emissions to the atmosphere.
    Description: Published
    Description: 97–107
    Description: 4.5. Studi sul degassamento naturale e sui gas petroliferi
    Description: JCR Journal
    Description: reserved
    Keywords: Sousaki ; accumulation chamber ; soil degassing ; hydrothermal systems ; methane output ; methanotrophic activity ; 01. Atmosphere::01.01. Atmosphere::01.01.07. Volcanic effects ; 04. Solid Earth::04.04. Geology::04.04.12. Fluid Geochemistry ; 04. Solid Earth::04.08. Volcanology::04.08.01. Gases
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  • 43
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    Gas seepage from Tokamachi mud volcanoes, onshore Niigata Basin (Japan): Origin, post-genetic alterations and CH4–CO2 fluxes (2011)
    Elsevier
    Details
    Publication Date: 2017-04-04
    Description: Methane and CO2 emissions from the two most active mud volcanoes in central Japan, Murono and Kamou (Tokamachi City, Niigata Basin), were measured in from both craters or vents (macro-seepage) and invisible exhalation from the soil (mini- and microseepage). Molecular and isotopic compositions of the released gases were also determined. Gas is thermogenic (d13CCH4 from 32.9‰ to 36.2‰), likely associated with oil, and enrichments of 13C in CO2 (d13CCO2 up to +28.3‰) and propane (d13CC3H8 up to 8.6‰) suggest subsurface petroleum biodegradation. Gas source and post-genetic alteration processes did not change from 2004 to 2010. Methane flux ranged within the orders of magnitude of 101–104 gmˉ2 dˉ1 in macro-seeps, and up to 446 g mˉ2 dˉ1 from diffuse seepage. Positive CH4 fluxes from dry soil were widespread throughout the investigated areas. Total CH4 emission from Murono and Kamou were estimated to be at least 20 and 3.7 ton aˉ1, respectively, of which more than half was from invisible seepage surrounding the mud volcano vents. At the macro-seeps, CO2 fluxes were directly proportional to CH4 fluxes, and the volumetric ratios between CH4 flux and CO2 flux were similar to the compositional CH4/CO2 volume ratio. Macro-seep flux data, in addition to those of other 13 mud volcanoes, supported the hypothesis that molecular fractionation (increase of the ‘‘Bernard ratio’’ C1/(C2 + C3)) is inversely proportional to gas migration fluxes. The CH4 ‘‘emission factor’’ (total measured output divided by investigated seepage area) was similar to that derived in other mud volcanoes of the same size and activity. The updated global ‘‘emission-factor’’ data-set, now including 27 mud volcanoes from different countries, suggests that previous estimates of global CH4 emission from mud volcanoes may be significantly underestimated.
    Description: Published
    Description: 348-359
    Description: 4.5. Studi sul degassamento naturale e sui gas petroliferi
    Description: JCR Journal
    Description: restricted
    Keywords: Methane ; natural gas ; mud volcanoes ; seepage ; 04. Solid Earth::04.04. Geology::04.04.12. Fluid Geochemistry
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  • 44
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    Geochemical evidence for and characterization of CO2 rich gas sources in the epicentral area of the Abruzzo 2009 earthquakes (2011)
    Elsevier
    Details
    Publication Date: 2017-04-04
    Description: We describe the results of a detailed hydrogeochemical campaign on the groundwater circulating in two regional aquifers located in the area of the Abruzzo 2009 earthquakes. The influx of deeply derived CO2 rich gases into the two aquifers is highlighted by the 13C isotopic composition of dissolved carbon species. The source of the gas is roughly localised beneath the epicentral area of the earthquakes where the presence of sources of fluids under high pressure is suggested by seismological investigations. The carbon isotopic-mass balance of the aquifers indicates that the amount of the deep CO2 dissolved and transported by the groundwaters is ~530 t/day. The chemical and isotopic composition of the gas entering the aquifers, named Abruzzo gas, has been derived by comparing the data measured in the springs with the results of a gas–water– rock reaction model, that simulates the evolution of the chemical and isotopic composition of groundwater affected by the input of a deeply-derived CO2 rich gas phase. The composition of Abruzzo gas is compared to that of 40 large gas emissions located in central Italy. The gas becomes progressively richer in radiogenic elements (4He and 40Ar) and in N2, from the volcanic complexes in the west to the Apennines in the east. The Abruzzo gas, in agreement with its location, well matches the composition of the gases emitted in the pre- Apennine region. These geochemical features, consistent with the structural setting of the region, indicate increasing residence times of the gas in the crust moving from west to east. In particular we suggest that the strong increase in radiogenic crustal gases reflects the occurrence of deep traps where the gas is stored at high pressures for a long time and that such high pressure gas pockets play a major role in the generation of Apennine earthquakes.
    Description: Published
    Description: 389–398
    Description: 2.4. TTC - Laboratori di geochimica dei fluidi
    Description: 4.5. Studi sul degassamento naturale e sui gas petroliferi
    Description: JCR Journal
    Description: reserved
    Keywords: carbon dioxide ; Abruzzo earthquakes ; carbon isotopes ; helium isotopes ; 04. Solid Earth::04.04. Geology::04.04.12. Fluid Geochemistry ; 04. Solid Earth::04.06. Seismology::04.06.03. Earthquake source and dynamics ; 04. Solid Earth::04.06. Seismology::04.06.06. Surveys, measurements, and monitoring ; 04. Solid Earth::04.06. Seismology::04.06.10. Instruments and techniques
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  • 45
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    Evidence of large scale deformation patterns from GPS data in the Italian subduction boundary (2011)
    Elsevier
    Details
    Publication Date: 2017-04-04
    Description: We present the velocity field in Italy derived from over 300 continuous GPS stations operated in the 1998– 2009 time span. The GPS network maps the whole country with a mean inter-site distance of about 50 km and provides a valuable source of data to study the ongoing deformation processes in the central Mediterranean. The estimated horizontal and vertical velocity fields show major significant features and also less known second-order kinematic features. A general uplift characterizes the whole Apennines and Alpine belts that follow the topographic ridge, whereas the Po Plain shows a gradually increasing subsidence from west to east. The Apennines belt displays a distinctive extension (50–80 10−9 yr−1)while compressive tectonic regimes characterize northern Sicily, eastern Alps and the northeast front of the northern Apennines (25–50 10−9 yr−1). Second-order deformation patterns, on large scale wavelength (~100 km) have been detected on the accretionary prism of central and southern Apennines that are highly correlated with other geophysical data (Vp anomalies, seismic anisotropy, etc.) and related to deep rooted sections (70– 100 km), marked by different subduction regimes. Apparently at this scale-length the observed deformations are governed by the lithosphere as a whole. We interpret these deformations as a result of different subduction mechanisms, such as variations of the subduction rollback velocity affecting different segments of the subduction zone and/or to mantle flows in proximity of the slab edges. Further south, in central-southern Sicily, we detect a contraction of (−1.1±0.2) mm/yr that probably accommodates part of the Africa–Eurasia convergence on the outer thrust front of the Apennines–Maghrebides belt. This hypothesis agrees with an independent analysis of the seismicity associated to the Sicilian Basal Thrust, thought to be still active. The ITRF2005 estimates of the new GPS velocity field are available also in SINEX format as supplementary file S1.
    Description: Published
    Description: 230-241
    Description: 1.9. Rete GPS nazionale
    Description: 3.3. Geodinamica e struttura dell'interno della Terra
    Description: JCR Journal
    Description: restricted
    Keywords: GPS velocity field ; Apennines ; Alps ; Adria ; Plate kinematics ; Subduction zone ; 04. Solid Earth::04.03. Geodesy::04.03.99. General or miscellaneous
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  • 46
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    An overview of experimental models to understand a complex volcanic instability: Application to Mount Etna, Italy (2012)
    Elsevier Science Limited
    Details
    Publication Date: 2017-04-04
    Description: Volcanic edifices are often unable to support their own load, triggering the instability of their flanks. Many analogue models have been aimed, especially in the last decade, at understanding the processes leading to volcano flank instability; general behaviors were defined and the experimental results were compared to nature. However, available data at well-studied unstable volcanoes may allow a deeper understanding of the specific processes leading to instability, providing insights also at the local scale. Etna (Italy) constitutes a suitable example for such a possibility, because of its well-monitored flank instability, for which different triggering factors have been proposed in the last two decades. Among these factors, recent InSAR data highlight the role played by magmatic intrusions and a weak basement, under a differential unbuttressing at the volcano base. This study considers original and recently published experimental data to test these factors possibly responsible for flank instability, with the final aim to better understand and summarize the conditions leading to flank instability at Etna. In particular, we simulate the following processes: a) the longterm activity of a lithospheric boundary, as the Malta Escarpment, separating the Ionian oceanic lithosphere from the continental Sicilian lithosphere, below the most unstable east flank of the volcano; b) spreading due to a weak basement, with different boundary conditions; c) the pressurization of a magmatic reservoir, as that active during the 1994–2001 inflation period; d) dike emplacement, as observed during the major 2001 and 2002–2003 eruptions. The experimental results suggest that: 1) the long-term activity of a lithospheric tectonic boundary may create a topographic slope which provides a differential buttressing at the volcano base, a preparing factor to drive longer-term (〉105 years) instability on the east flank of the volcano; 2) volcano spreading (b104 years) has limited effect on flank instability at Etna; 3) magmatic intrusions (b101 years), both in the form of Mogi-like sources or dikes, provide the most important conditions to trigger flank instability on the shorter-term.
    Description: Thisworkwas partially funded by INGV and the Italian DPC (DPC-INGV project V4 “Flank”).
    Description: Published
    Description: 98-111
    Description: 1.5. TTC - Sorveglianza dell'attività eruttiva dei vulcani
    Description: 3.2. Tettonica attiva
    Description: 3.5. Geologia e storia dei vulcani ed evoluzione dei magmi
    Description: 3.6. Fisica del vulcanismo
    Description: JCR Journal
    Description: reserved
    Keywords: volcano instability ; analogue modeling ; Etna ; unbuttressing ; 04. Solid Earth::04.01. Earth Interior::04.01.99. General or miscellaneous ; 04. Solid Earth::04.04. Geology::04.04.99. General or miscellaneous ; 04. Solid Earth::04.04. Geology::04.04.06. Rheology, friction, and structure of fault zones ; 04. Solid Earth::04.04. Geology::04.04.09. Structural geology ; 04. Solid Earth::04.07. Tectonophysics::04.07.99. General or miscellaneous ; 04. Solid Earth::04.07. Tectonophysics::04.07.02. Geodynamics ; 04. Solid Earth::04.07. Tectonophysics::04.07.05. Stress ; 04. Solid Earth::04.07. Tectonophysics::04.07.07. Tectonics ; 04. Solid Earth::04.08. Volcanology::04.08.99. General or miscellaneous ; 04. Solid Earth::04.08. Volcanology::04.08.02. Experimental volcanism ; 04. Solid Earth::04.08. Volcanology::04.08.03. Magmas ; 04. Solid Earth::04.08. Volcanology::04.08.07. Instruments and techniques ; 04. Solid Earth::04.08. Volcanology::04.08.08. Volcanic risk
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
    Type: article
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  • 47
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    An innovative method for continuous measurement of soil CO2 flux (2013)
    Elsevier Science Limited
    Details
    Publication Date: 2017-04-04
    Description: Herein, we present a method for continuous measurement of soil CO2 flux that is completely new and distinct from existing instruments. The foremost difference is that instead of using an infrared gas analyser (IRGA), the new device measures soil CO2 flux by means of a simple pressure sensor, measuring pressure transients inside a closed polymeric tube inserted into the soil. This allows continuous measurements even in soil placed in environments that could potentially damage IRGA. In addition, due to the innovative operating principle, measurements of soil CO2 flux can be effortlessly performed also in strongly harsh weather conditions. Theoretical equations were derived for calculating soil CO2 flux solely using measured transient values. The reliability of the equations was rigorously tested with a variety of experiments. Continuous measurements over four months, acquired in a high-emission area on the Island of Vulcano, compared favourably with the data obtained using an established method.
    Description: Published
    Description: 102-109
    Description: 1.5. TTC - Sorveglianza dell'attività eruttiva dei vulcani
    Description: JCR Journal
    Description: restricted
    Keywords: Soil CO2 flux measurements ; Continuous monitoring ; Methods of measurement ; Polymeric membranes ; 04. Solid Earth::04.04. Geology::04.04.12. Fluid Geochemistry ; 04. Solid Earth::04.08. Volcanology::04.08.01. Gases ; 04. Solid Earth::04.08. Volcanology::04.08.06. Volcano monitoring ; 04. Solid Earth::04.08. Volcanology::04.08.07. Instruments and techniques
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  • 48
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    Defining a 3D physical model for the hydrothermal circulation at Campi Flegrei caldera (Italy) (2013)
    Elsevier Science Limited
    Details
    Publication Date: 2017-04-04
    Description: Our study is aimed to develop a 3D physical model of the Campi Flegrei geothermal system, in order to achieve a more accurate and comprehensive representation of the hydrothermal processes occurring in the caldera. The new model, developed by using the TOUGH2 code simulator, accounts for the caldera rocks' physical properties, bathymetry and water table topography. In particular, the computational domain is constrained by density values obtained by tomographic inversion of gravity data collected during several surveys at CF both onshore and offshore the caldera. Empirical relations between density and porosity and between porosity and permeability, derived by published data on samples cored in deep wells or collected in outcrops, allowed us to characterize the main rocks physical parameters controlling the dynamic of the CF geothermal system. We have performed and compared several simulations investigating the effects of the injection at depth, underneath Solfatara crater, of a hot gaseous mixture rich in CO2. We show that, with respect to the available literature on 2D axisymmetric models, the effects of the water table topography together with the bathymetry and the heterogeneous distribution of the rocks' physical properties, lead to important differences in the hydrothermal circulation of fluids at CF. These constraints allow the activation of convective cells with different behaviors, which produce variable patterns of temperature inside the hydrothermal system. As a consequence, the predominant effect is again represented by a central plume below the Solfatara crater, but with a non-axisymmetric structure and a wider extension. Additionally, high temperature zones are present near the coastline and in the middle part of the submerged area of the caldera with a SE–NW alignment. Moreover, our results indicate that, the submerged part of the CF caldera would deserve a more accurate study and survey, being affected by phenomenon of heating and degassing. This information could be very useful in terms of hazard assessment and volcanic risk mitigation in such an active and densely inhabited volcanic and geothermal area.
    Description: Published
    Description: 172-182
    Description: 1.2. TTC - Sorveglianza geochimica delle aree vulcaniche attive
    Description: 2.4. TTC - Laboratori di geochimica dei fluidi
    Description: 4.5. Studi sul degassamento naturale e sui gas petroliferi
    Description: JCR Journal
    Description: restricted
    Keywords: Campi Flegrei ; Geothermal system ; 3D model ; Water table topography ; 03. Hydrosphere::03.02. Hydrology::03.02.04. Measurements and monitoring ; 04. Solid Earth::04.04. Geology::04.04.12. Fluid Geochemistry ; 04. Solid Earth::04.08. Volcanology::04.08.01. Gases ; 04. Solid Earth::04.08. Volcanology::04.08.07. Instruments and techniques
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  • 49
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    The cuticle micromorphology of in situ Erica arborea L. exposed to long-term volcanic gases (2013)
    Elsevier Science Limited
    Details
    Publication Date: 2017-04-04
    Description: Epidermis micromorphology of in situ Erica arborea L. exposed for generations to long-term effect of volcanic gases in Pisciarelli and Solfatara di Pozzuoli areas have been studied by X-ray analyses, SEM and TEM observations. In particular, the aim of this study is to investigate the effects of volcanic gases on extant and possibly fossil plants. Plants of the same species living in a nearby control site were also studied for comparison. SEM coupled with EDX analysis was used to localize different elements within the leaves (mesophyll, cell wall and cuticle). After conventional and cryo preparation, SEM of mature leaves ascertained that the abaxial side is more serrate in fumigated leaves and hairs, epicuticular wax alterations have also been noted. Leaves experiencing chronic fumigation display stomata more sunken with respect to the epidermal surface. TEM of transverse and longitudinal sections of cuticle showed an outer A2 granular amorphous layer and external to a B1 fibrillous layer. Significant statistical variations of ultrastructural components of the cuticle revealed a response of E. arborea to this extreme environment. At the ultrastructural level, significant variations in thickness of the cell wall plus cuticle, cell wall and A2 layer among fumigated and non-fumigated leaves have been found. In the studied localities a positive correlation between atmospheric CO2 concentration and the thickness of A2 layer also exists. The results are of interest being applicable in the understanding of plant cuticle responses during periods of normal vs. volcanic activity.
    Description: Published
    Description: 197– 206
    Description: 1.2. TTC - Sorveglianza geochimica delle aree vulcaniche attive
    Description: 2.4. TTC - Laboratori di geochimica dei fluidi
    Description: 4.5. Studi sul degassamento naturale e sui gas petroliferi
    Description: JCR Journal
    Description: restricted
    Keywords: Phlegrean Fields ; Erica arborea ; Volcanic gases ; Epidermis ; Cuticle ultrastructure ; 03. Hydrosphere::03.02. Hydrology::03.02.04. Measurements and monitoring ; 03. Hydrosphere::03.04. Chemical and biological::03.04.04. Ecosystems ; 04. Solid Earth::04.04. Geology::04.04.12. Fluid Geochemistry ; 04. Solid Earth::04.08. Volcanology::04.08.01. Gases
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
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  • 50
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    Chlorine isotope composition of volcanic gases and rocks at Mount Etna (Italy) and inferences on the local mantle source (2013)
    Elsevier Science Limited
    Details
    Publication Date: 2017-04-04
    Description: We present the first chlorine isotope compositional data for gases and lavas from Mount Etna (Italy), and to our knowledge, of active Mediterranean volcanism. We investigated lavas erupted and gases discharged during 2008-2011 from a high-temperature fumarole (HT; 〉300°C) and plume gases from both North East and Central Craters. Most of the samples vary in a narrow range of chlorine isotope composition (37Cl values ≈ 0 ± 0.7‰) with gases partially overlapping with rocks. Only HT gases sampled in 2009 have been clearly affected by secondary processes (37Cl values 〉 15.9‰), resulting in partial removal of chlorine and isotopic fractionation producing a 37Cl enrichment in the residual gaseous HCl. These secondary processes also affect, although to a lesser extent, plume gases from North East Crater (NEC). Although post-magmatic processes are able to modify the chlorine isotope composition, 37Cl values are not affected by magma degassing for residual fractions ≥ 0.3 in the melt, or any effect is within our data variability. Finally, 37Cl values and Cl/K ratios of magmatic chlorine constrain the Etnean source to be compatible with depleted mantle (DMM) contaminated by altered oceanic crust (AOC), in agreement with indications from more common isotopic tracers of mantle processes.
    Description: Published
    Description: 134-142
    Description: 1.2. TTC - Sorveglianza geochimica delle aree vulcaniche attive
    Description: JCR Journal
    Description: restricted
    Keywords: Mount Etna ; chlorine isotope ; plume ; fumarole ; degassing ; mantle source ; 04. Solid Earth::04.04. Geology::04.04.07. Rock geochemistry ; 04. Solid Earth::04.04. Geology::04.04.12. Fluid Geochemistry ; 04. Solid Earth::04.08. Volcanology::04.08.01. Gases ; 04. Solid Earth::04.08. Volcanology::04.08.05. Volcanic rocks
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
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  • 51
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    A geochemical traverse along the “Sperchios Basin e Evoikos Gulf” graben (Central Greece): Origin and evolution of the emitted fluids (2014)
    Elsevier Science
    Details
    Publication Date: 2017-04-04
    Description: The studied area is a 130 km long fast spreading graben in Central Greece. Its complex geodynamical setting includes both the presence of a subduction slab at depth responsible for the recent (Quaternary) volcanic activity in the area and the western termination of a tectonic lineament of regional importance (the North-Anatolian fault). A high geothermal gradient is made evident by the presence of many thermal springs with temperatures from 19 to 82 C, that discharge along the normal faults bordering the graben. In the period 2004e2012, 58 gas and 69 water samples were collected and their chemical and isotopic analysis revealed a wide range of compositions. Two main groups of thermal waters can be distinguished on the basis of their chemical composition. The first, represented by dilute waters (E.C. 〈0.6 mS/cm) of the westernmost sites, is characterised by the presence of CH4-rich and mixed N2eCH4 gases. The second displays higher salinities (E.C. from 12 to 56 mS/cm) due to mixing with a modified marine component. Reservoir temperatures of 150e160 C were estimated with cationic geothermometers at the easternmost sites. Along the graben, from west to east, the gas composition changes from CH4- to CO2-dominated through mixed N2eCH4 and N2eCO2 compositions, while at the same time the He isotopic composition goes from typical crustal values (〈0.1 R/RA) up to 0.87 R/RA, showing in the easternmost sites a small (3e11%) but significant mantle input. The d13C values of the CO2-rich samples suggest a mixed origin (mantle and marine carbonates).
    Description: Published
    Description: 295-308
    Description: 2T. Tettonica attiva
    Description: JCR Journal
    Description: restricted
    Keywords: Rift zone ; geothermal activity ; Helium isotopes ; Carbon isotopes ; 03. Hydrosphere::03.02. Hydrology::03.02.02. Hydrological processes: interaction, transport, dynamics ; 03. Hydrosphere::03.02. Hydrology::03.02.03. Groundwater processes ; 03. Hydrosphere::03.04. Chemical and biological::03.04.03. Chemistry of waters ; 03. Hydrosphere::03.04. Chemical and biological::03.04.05. Gases ; 03. Hydrosphere::03.04. Chemical and biological::03.04.06. Hydrothermal systems ; 04. Solid Earth::04.04. Geology::04.04.12. Fluid Geochemistry
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  • 52
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    Atmospheric sources and sinks of volcanogenic elements in a basaltic volcano (Etna, Italy) (2011)
    Elsevier
    Details
    Publication Date: 2017-04-04
    Description: This study reports on the first quantitative assessment of the geochemical cycling of volcanogenic elements, from their atmospheric release to their deposition back to the ground. Etna’s emissions and atmospheric depositions were characterised for more than 2 years, providing data on major and trace element abundance in both volcanic aerosols and bulk depositions. Volcanic aerosols were collected from 2004 to 2007, at the summit vents by conventional filtration techniques. Precipitation was collected, from 2006 to 2007, in five rain gauges, at various altitudes around the summit craters. Analytical results for volcanic aerosols showed that the dominant anions were S, Cl, and F, and that the most abundant metals were K, Ca, Mg, Al, Fe, and Ti (1.5–50 lg m 3). Minor and trace element concentrations ranged from about 0.001 to 1 lg m 3. From such analysis, we derived an aerosol mass flux ranging from 3000 to 8000 t a 1. Most analysed elements had higher concentrations close to the emission vent, confirming the prevailing volcanic contribution to bulk deposition. Calculated deposition rates were integrated over the whole Etna area, to provide a first estimate of the total deposition fluxes for several major and trace elements. These calculated deposition fluxes ranged from 20 to 80 t a 1 (Al, Fe, Si) to 0.01–0.1 t a 1 (Bi, Cs, Sc, Th, Tl, and U). Comparison between volcanic emissions and atmospheric deposition showed that the amount of trace elements scavenged from the plume in the surrounding of the volcano ranged from 0.1% to 1% for volatile elements such as As, Bi, Cd, Cs, Cu, Tl, and from 1% to 5% for refractory elements such as Al, Ba, Co, Fe, Ti, Th, U, and V. Consequently, more than 90% of volcanogenic trace elements were dispersed further away, and may cause a regional scale impact. Such a large difference between deposition and emission fluxes at Mt. Etna pointed to relatively high stability and long residence time of aerosols in the plume.
    Description: Published
    Description: 7401-7425
    Description: 1.2. TTC - Sorveglianza geochimica delle aree vulcaniche attive
    Description: JCR Journal
    Description: reserved
    Keywords: trace elements ; volcanic plume chemistry ; bulk deposition ; Etna ; 01. Atmosphere::01.01. Atmosphere::01.01.07. Volcanic effects ; 03. Hydrosphere::03.03. Physical::03.03.01. Air/water/earth interactions ; 03. Hydrosphere::03.04. Chemical and biological::03.04.03. Chemistry of waters ; 04. Solid Earth::04.04. Geology::04.04.12. Fluid Geochemistry ; 05. General::05.02. Data dissemination::05.02.01. Geochemical data
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  • 53
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    Evidence for a recent change in the shallow plumbing system of Mt. Etna (Italy): Gas geochemistry and structural data during 2001–2005 (2012)
    Elsevier Science Limited
    Details
    Publication Date: 2017-04-04
    Description: We analyzed crater SO2 fluxes from Mt Etna, together with soil CO2 effluxes from the volcano's flanks, in the period from 2001 to 2005. Between the 2001 and 2002–2003 eruptions, persistently low values of both parameters suggest that no new gas-rich magma was accumulating at shallow depth (b5 km) within Etna's central conduit, whereas very high SO2 sin-eruptive fluxes during the two eruptions indicated sudden decompression of an un-degassed magma rising along newly-formed eccentric conduits. In November 2003, soil CO2 data indicate migration of gas-rich magma from deep (〉10 km) to shallow (b5 km) portions of the feeding conduits, preceded by an increase in crater SO2 fluxes. A similar behavior was observed also during and after the following 2004–2005 eruption. This degassing style matches a period of increased structural instability of the volcanic edifice caused by acceleration of spreading that affected both its eastern and southern flanks. Spreading could have triggered progressively deeper depressurization in the central conduit, inducing release of the more soluble gas (SO2) first, and then of CO2, contrary to what was observed before the 2001 eruption. This suggests that the edifice has depressurized, promoting ascent of fresh-magma and increasing permeability favouring release of CO2 flux. By integrating geochemical and structural data, previous degassing models developed at Mt. Etna have been updated to advance the understanding of eruptive events that occurred in recent years.
    Description: This work was funded by grants from the Istituto Nazionale di Geofisica e Vulcanologia (INGV) and from the Dipartimento per la Protezione Civile (Italy).
    Description: Published
    Description: 90-97
    Description: 1.2. TTC - Sorveglianza geochimica delle aree vulcaniche attive
    Description: 1.5. TTC - Sorveglianza dell'attività eruttiva dei vulcani
    Description: 3.5. Geologia e storia dei vulcani ed evoluzione dei magmi
    Description: 3.6. Fisica del vulcanismo
    Description: 4.5. Studi sul degassamento naturale e sui gas petroliferi
    Description: JCR Journal
    Description: reserved
    Keywords: Geochemical modeling ; volcano monitoring ; volcanic gases ; Tectonics and magmatism ; flank collapse ; 04. Solid Earth::04.01. Earth Interior::04.01.99. General or miscellaneous ; 04. Solid Earth::04.04. Geology::04.04.99. General or miscellaneous ; 04. Solid Earth::04.04. Geology::04.04.09. Structural geology ; 04. Solid Earth::04.04. Geology::04.04.12. Fluid Geochemistry ; 04. Solid Earth::04.07. Tectonophysics::04.07.99. General or miscellaneous ; 04. Solid Earth::04.07. Tectonophysics::04.07.02. Geodynamics ; 04. Solid Earth::04.07. Tectonophysics::04.07.05. Stress ; 04. Solid Earth::04.07. Tectonophysics::04.07.07. Tectonics ; 04. Solid Earth::04.08. Volcanology::04.08.99. General or miscellaneous ; 04. Solid Earth::04.08. Volcanology::04.08.01. Gases ; 04. Solid Earth::04.08. Volcanology::04.08.03. Magmas ; 04. Solid Earth::04.08. Volcanology::04.08.04. Thermodynamics ; 04. Solid Earth::04.08. Volcanology::04.08.06. Volcano monitoring ; 04. Solid Earth::04.08. Volcanology::04.08.07. Instruments and techniques ; 05. General::05.08. Risk::05.08.99. General or miscellaneous
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  • 54
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    Influence of volcanic gases on the epidermis of Pinus halepensis Mill. in Campi Flegrei, Southern Italy: A possible tool for detecting volcanism in present and past floras (2012)
    Elsevier Science Limited
    Details
    Publication Date: 2017-04-04
    Description: Cuticle micromorphology together with epidermal and epistomatal wax, in both current- and first-year-old needles of conifer Pinus halepensis (Aleppo pine) trees growing under volcanic gas fumigation was analysed in Pisciarelli area, Campi Flegrei, Southern Italy. As a control, current- and first-year-old needles growing far from volcanic gas emission were also sampled. Using a multidisciplinary approach with SEM, TEM and X-ray, volcanic gases were shown to cause degradation on epicuticular and epistomatal waxes. Significant statistical variations of ultrastructural components of the cuticle, with 30 measurements, including total thickness of the cuticle, and details and proportions of all different layers, and use of confidence interval, revealed a high degree of sensitivity of Aleppo pine to this extreme environment. In the present study, non-significant thickness variations of the cell wall plus cuticle among current- and first-year-old needles of both fumigated and non fumigated trees have been found. However, at the ultrastructural level, significant variations in cell wall and total cuticle thickness, especially within the three zones of B1 fibrillar layer, revealed different equilibria for each of the four types of material. Using energy dispersive X-ray microanalysis, no sulphur was found in either cuticle or epidermal cells, but the presence of H2S in the fumarole gas is suspected to cause indirect and/or direct cuticle alterations of wax structure. Ultrastructural characters of plant cuticles related to emission of volcanic gases during the geological past are also discussed. Among these considerations, an identification key enabling distinction between non fumigated and fumigated materials with 9 characters, provides a good tool detecting the influence of volcanism for extant and fossil plants.
    Description: Published
    Description: 1–17
    Description: 1.2. TTC - Sorveglianza geochimica delle aree vulcaniche attive
    Description: 2.4. TTC - Laboratori di geochimica dei fluidi
    Description: 4.5. Studi sul degassamento naturale e sui gas petroliferi
    Description: JCR Journal
    Description: restricted
    Keywords: Campi Flegrei ; Volcanic gases ; Pinus halepensis ; Hydrogen sulphide (H2S) ; 04. Solid Earth::04.03. Geodesy::04.03.06. Measurements and monitoring ; 04. Solid Earth::04.04. Geology::04.04.12. Fluid Geochemistry ; 04. Solid Earth::04.08. Volcanology::04.08.01. Gases ; 04. Solid Earth::04.08. Volcanology::04.08.07. Instruments and techniques
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  • 55
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    Insights from fumarole gas geochemistry on the origin of hydrothermal fluids on the Yellowstone Plateau (2012)
    Elsevier Science Limited
    Details
    Publication Date: 2017-04-04
    Description: The chemistry of Yellowstone fumarole gases shows the existence of two component waters, type MC, influenced by the addition of deep mantle fluid, and type CC, influenced by crustal interactions (CC). MC is high in 3He/4He (22 Ra) and low in 4He/40Ar ( 1), reflecting input of deep mantle components. The other water is characterized by 4He concentrations 3–4 orders of magnitude higher than air-saturated meteoric water (ASW). These high He concentrations originate through circulation in Pleistocene volcanic rocks, as well as outgassing of Tertiary and older (including Archean) basement, some of which could be particularly rich in uranium, a major 4He source. Consideration of CO2–CH4–CO–H2O–H2 gas equilibrium reactions indicates equilibration temperatures from 170 C to 310 C. The estimated temperatures highly correlate with noble-gas variations, suggesting that the two waters differ in temperature. Type CC is 170 C whereas the MC is hotter, at 340 C. This result is similar to models proposed by previous studies of thermal water chemistry. However, instead of mixing the deep hot component simply with cold, meteoric waters we argue that addition of a 4He-rich component, equilibrated at temperatures around 170 C, is necessary to explain the range in fumarole gas chemistry.
    Description: Published
    Description: 265–278
    Description: 2.4. TTC - Laboratori di geochimica dei fluidi
    Description: 4.5. Studi sul degassamento naturale e sui gas petroliferi
    Description: JCR Journal
    Description: restricted
    Keywords: hydrothermal fluids ; Yellowstone Plateau ; 04. Solid Earth::04.03. Geodesy::04.03.06. Measurements and monitoring ; 04. Solid Earth::04.04. Geology::04.04.12. Fluid Geochemistry ; 04. Solid Earth::04.08. Volcanology::04.08.01. Gases
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  • 56
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    The attenuation mechanism of S-waves in the source zone of the 1999 Chamoli earthquake (2013)
    Elsevier Science Limited
    Details
    Publication Date: 2017-04-04
    Description: In the present study the attenuation mechanism of seismic wave energy in and around the source area of the Chamoli earthquake of 29th March 1999 is estimated using the aftershock data. Most of the analyzed events are from the vicinity of the Main Central Thrust (MCT), which is a well-defined tectonic discontinuity in the Himalayas. Separation of intrinsic (Q 1 i ) and scattering (Q 1 s ) attenuation coefficient is done over the frequencies 1, 2, 4, 8 and 16 Hz using Multiple Lapse Time Window Analysis (MLTWA) method. It is observed that S-waves and their coda are primarily attenuated due to scattering attenuation and seismic albedo is very high at all the frequencies. A comparison of attenuation characteristics obtained using these aftershock data with those obtained using data of general seismicity of this region reveal that at lower frequencies both intrinsic and scattering attenuation for Chamoli was much higher compared to those for Garwhal-Kumaun region using general seismicity data. At higher frequencies intrinsic attenuation for Chamoli is lower than and scattering attenuation is comparable to those obtained using general seismicity data of Garwhal-Kumaun region.
    Description: A partial support has been given by Italy INGV-DPC (Istituto Nazionale di Geofisica e Vulcanologia and Dipartimento di Protezione Civile) Projects UNREST and SPEED, and by Italy’s Ministry of Education PRIN project (Seismic Hazard in Central Apennines, UR Del Pezzo).
    Description: Published
    Description: 446-454
    Description: 1T. Geodinamica e interno della Terra
    Description: 4T. Fisica dei terremoti e scenari cosismici
    Description: JCR Journal
    Description: restricted
    Keywords: MLTWA ; Intrinsic attenuation ; Scattering attenuation ; Chamoli Himalayas ; Himalayas ; 04. Solid Earth::04.06. Seismology::04.06.07. Tomography and anisotropy ; 04. Solid Earth::04.06. Seismology::04.06.09. Waves and wave analysis ; 04. Solid Earth::04.07. Tectonophysics::04.07.02. Geodynamics
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  • 57
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    Advective heat transport associated with regional Earth degassing in central Apennine (Italy) (2014)
    Elsevier Science Limited
    Details
    Publication Date: 2017-04-04
    Description: In this work we show that the main springs of the central Apennine transport a total amount of heat of ∼2.2 109 J s−1. Most of this heat (57%) is the result of geothermal warming while the remaining 43% is due to gravitational potential energy dissipation. This result indicates that a large area of the central Apennines is very hot with heat flux values 4300 mWm−2. These values are higher than those measured in the magmatic and famously geothermal provinces of Tuscany and Latium and about 1/3 of the total heat discharged at Yellowstone. This finding is surprising because the central Apennines have been thought to be a relatively cold area. Translated by CO2 rich fluids, this heat anomaly suggests the existence of a thermal source such as a large magmatic intrusion at depth. Recent tomographic images of the area support the presence of such an intrusion visible as a broad negative velocity anomaly in seismic waves. Our results indicate that the thermal regime of tectonically active areas of the Earth, where meteoric waters infiltrate and deeply circulate, should be revised on the basis of mass and energy balances of the groundwater systems.
    Description: Published
    Description: 65–74
    Description: 1.2. TTC - Sorveglianza geochimica delle aree vulcaniche attive
    Description: 2.4. TTC - Laboratori di geochimica dei fluidi
    Description: 4.5. Studi sul degassamento naturale e sui gas petroliferi
    Description: JCR Journal
    Description: restricted
    Keywords: heat flux ; CO2 Earth degassing ; central Apennine ; 03. Hydrosphere::03.02. Hydrology::03.02.04. Measurements and monitoring ; 04. Solid Earth::04.04. Geology::04.04.12. Fluid Geochemistry ; 04. Solid Earth::04.08. Volcanology::04.08.01. Gases
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  • 58
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    Sulphur-gas concentrations in volcanic and geothermal areas in Italy and Greece: Characterising potential human exposures and risks (2013)
    Elsevier Science Limited
    Details
    Publication Date: 2017-04-04
    Description: Passive samplers were used to measure the atmospheric concentrations of SO2 naturally emitted at three volcanoes in Italy (Etna, Vulcano and Stromboli) and of H2S naturally emitted at three volcanic/geothermal areas in Greece (Milos, Santorini and Nisyros). The measured concentrations and dispersion patterns varied with the strength of the source (open conduits or fumaroles), the meteorological conditions and the area topography. At Etna, Vulcano and Stromboli, SO2 concentrations reach values that are dangerous to people affected by bronchial asthma or lung diseases (〉1000 μg m−3). H2S values measured at Nisyros also exceed the limit considered safe for the same group of people (〉3000 μg m−3). The data obtained using passive samplers represent time-averaged values over periods from a few days up to 1 month, and hence concentrations probably reached much higher peak values that were potentially also dangerous to healthy people. The present study provides evidence of a peculiar volcanic risk associated with tourist exploitation of active volcanic areas. This risk is particularly high at Mt. Etna, where the elderly and people in less-than-perfect health can easily reach areas with dangerous SO2 concentrations via a cableway and off-road vehicles
    Description: Published
    Description: 1-13
    Description: 4.5. Studi sul degassamento naturale e sui gas petroliferi
    Description: JCR Journal
    Description: restricted
    Keywords: Sulphur dioxide ; Hydrogen sulphide ; Volcanic risks ; Gas hazard ; 01. Atmosphere::01.01. Atmosphere::01.01.07. Volcanic effects ; 04. Solid Earth::04.04. Geology::04.04.12. Fluid Geochemistry ; 04. Solid Earth::04.08. Volcanology::04.08.01. Gases ; 04. Solid Earth::04.08. Volcanology::04.08.08. Volcanic risk
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  • 59
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    Active degassing of mantle-derived fluid: A geochemical study along the Vulture line, southern Apennines (Italy (2013)
    Elsevier Science Limited
    Details
    Publication Date: 2017-04-04
    Description: We report the results of a geochemical study of gas emissions along a NE–SW transect in southern Italy in order to test the hypothesis that the region around Monte Vulture is affected by degassing of mantle-derived fluids through a lithospheric discontinuity. We also investigated lavas from the Monte Vulture volcano displaying 3He/4He (up to ~6.0 Ra) and Sr isotopes that are consistent with an origin inmantle that has hadminimal pollution from subducted Adriatic slab. Similar 3He/4He in fluids from around Mt. Vulture indicate that the deep volcanic systemis still degassing. Mantle-derived He occurs in fluids along the length of the Vulture line, reinforcing the hypothesis that it is a deep tectonic discontinuity along which mantle fluids and/or melts advect to the surface. The CO2/3He ratios are highly variable (2.7×108–2.15×1011) in response to processes such as gas dissolution into aquifers, addition of crustal gases and degassing fractionation.
    Description: Published
    Description: 65-74
    Description: 1.2. TTC - Sorveglianza geochimica delle aree vulcaniche attive
    Description: JCR Journal
    Description: restricted
    Keywords: nonle gases ; mantle degassing ; tectonics ; Mt. Vulture ; 04. Solid Earth::04.04. Geology::04.04.12. Fluid Geochemistry
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
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  • 60
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    Comment on “CO2 variability in mid-ocean ridge basalts from syn-emplacement degassing: Constraints on eruption dynamics ” by Soule et al. [Earth Planet. Sci. Lett. (2012) 327–328, 39–49] (2013)
    Elsevier Science Limited
    Details
    Publication Date: 2017-04-04
    Description: Commenton “CO2 variabilityinmid-oceanridge basalts fromsyn-emplacementdegassing: Constraintsoneruptiondynamics”
    Description: Published
    Description: 251-253
    Description: 1.2. TTC - Sorveglianza geochimica delle aree vulcaniche attive
    Description: JCR Journal
    Description: restricted
    Keywords: non-equilibrium degassing, modeling, CO2, bubble growth, MORB, gas geochemistry ; 04. Solid Earth::04.04. Geology::04.04.12. Fluid Geochemistry ; 04. Solid Earth::04.08. Volcanology::04.08.01. Gases ; 04. Solid Earth::04.08. Volcanology::04.08.04. Thermodynamics
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  • 61
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    A two-component mantle source feeding Mt. Etna magmatism: Insights from the geochemistry of primitive magmas (2013)
    Elsevier Science Limited
    Details
    Publication Date: 2017-10-06
    Description: Themajor elements, trace elements and Sr and Nd isotopes of selected Etnean primitive rocks (b15 ky BP) were studied in order to characterize their mantle source. The noble-gas geochemistry of fluid inclusions in minerals fromthe same lavaswas also investigated. Themajor element compositions ofwhole rocks and minerals showed that these products are among the most primitive atMt. Etna, comprising 6.3–17.5 wt.% MgO. The variable LREE (Light Rare Earth Elements) enrichment relative to MORB (Mid-Ocean Ridge Basalt) (Lan/Ybn = 11–26), togetherwith the patterns of certain trace-element ratios (i.e., Ce/Yb versus Zr/Nb and Th/Y versus La/Yb), can be attributed to varying degrees of melting of a common mantle source. Numerical simulations performed with the MELTS program allowed the melting percentages associated with each product to be estimated. This led us to recalculate the hypothetical parental trace-element content of the Etneanmantle source, whichwas common to all of the investigated rocks. The characteristics of the Sr, Nd and He isotopes confirmed the primitive nature of the rocks,with themost-depleted and primitive lava being that ofMt. Spagnolo (SPA; 143Nd/144Nd = 0.512908 87Sr/ 86Sr = 0.703317–0.703325 and 3He/4He = 7.6 Ra), and highlighted the similarity of the mantle sources feeding the volcanic activity of Mt. Etna and the Hyblean Plateau (a region to the south of Mt. Etna and characterized by oldermagmatismthan Mt. Etna). The coupling of noble gases and trace elements suggests an origin for the investigated Etnean lavas from melting of a Hyblean-like mantle, consisting of a two-component source where a peridotitic matrix is veined by 10% pyroxenite. A variable degree of mantle contamination by crustal-like fluids, probably related to subduction, is proposed to explain the higher Sr-isotope and lowerNd-isotope values in some rocks (143Nd/144Nd up to 0.512865 and 87Sr/86Sr up to 0.703707). This process probably occurred in the source prior tomagma generation, refertilizing some portions of themantle. Accordingly, the estimated degree of melting responsible for each magma appears to be related to its 87Sr/86Sr enrichment. In contrast, the decoupling between 3He/4He and 87Sr/86Sr ratios requires the occurrence in the crustal reservoirs of further processes capable of shifting the He isotope ratio towards slightly more radiogenic values, such as magma aging or a contribution of shallow fluid. Therefore, different residence times in the Etnean reservoir and/or various rates of magma ascent could be key parameters for preserving the original He isotope marker of the Etnean mantle source.
    Description: Published
    Description: 243-258
    Description: 5V. Sorveglianza vulcanica ed emergenze
    Description: JCR Journal
    Description: restricted
    Keywords: Mt. Etna ; Hyblean Plateaux ; Primitive magma ; Mantle metasomatism ; Peridotite ; Pyroxenite ; 04. Solid Earth::04.01. Earth Interior::04.01.03. Mantle and Core dynamics ; 04. Solid Earth::04.04. Geology::04.04.07. Rock geochemistry ; 04. Solid Earth::04.04. Geology::04.04.12. Fluid Geochemistry
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  • 62
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    Deep-sea survey for the detection of methane at the “Santa Maria di Leuca” cold-water coral mounds (Ionian Sea, South Italy) (2010)
    Elsevier
    Details
    Publication Date: 2017-04-04
    Description: The “Santa Maria di Leuca” Cold-Water Coral (CWC) province (northern Ionian Sea) was investigated for the first time to detect eventual occurrence of methane anomalies as a possible indication of hydrocarbon seepage stimulating the coral growth. Most coral mounds have developed in correspondence with tectonic scarps and faults, orthogonal to the southern margin and trending NW-SE, which could be potential sites of gas escape. A visual and instrumental inspection was performed by using a new deep-sea probe equipped with video-cameras, sonar, CTD, methane sensors, and a water sampler. Eight areas were explored by 10 surveys, depths ranging from 380 to 1100 m, for a total of more than 26 h of continuous video and instrumental recording. Sediments were also sampled by gravity corers and analysed in laboratory. The images allowed to assess distribution, abundance and geometry of the colonies, most of which are developed on morphological highs often characterised by tectonic scarps. All data indicate however the lack of a significant occurrence of methane, both in seawater and sediments. No direct or indirect expressions of gas seepage were recognised on the seabed. Weak methane anomalies were detected only in seawater at the base of some fault-linked scarps, where more reducing conditions and bacterial methanogenesis are possibly enhanced by less water circulation. The faults are not fluid-bearing as previously suggested by high-resolution geophysical signatures. The development of the coral colonies thus cannot be attributed to seeping fluids, but to a favourable physiographic position with exposure to nutrient-rich currents.
    Description: Published
    Description: 431-440
    Description: 4.5. Studi sul degassamento naturale e sui gas petroliferi
    Description: JCR Journal
    Description: restricted
    Keywords: Methane ; Corals ; Seepage ; Marine geology ; 04. Solid Earth::04.04. Geology::04.04.12. Fluid Geochemistry
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
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  • 63
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    Geofluids and natural gas in Romania, and the 10th International Conference on Gas Geochemistry (2010)
    Blackwell Publishing Ltd
    Details
    Publication Date: 2017-04-04
    Description: This thematic issue of Geofluids includes 11 papers representing the three main topics discussed in the 10th edition of the International Conference on Gas Geochemistry (ICGG-10): (i) gas in petroleum systems and seepage, (ii) gas in geothermal systems and volcanoes and (iii) gas, seismicity and geohazards. ICGG-10 was held in 2009 in Romania, a country extraordinarily rich in surface gas manifestations, that offers innumerable opportunities for innovative studies on gas geochemistry. We briefly describe the present knowledge on gases occurring both in petroliferous sedimentary basins and geothermal areas of Romania. The 11 contributions of this special issue, which include data from eight countries, are then summarised. Based on these papers and other works presented at the ICGG-10, we find that significant advances in analytical capabilities, data treating and interpretation have led to innovative insights into the origin, distribution and environmental impact of gases migrating to the Earth’s surface. It is increasingly clear, in particular, that gas geochemistry can be more effective for petroleum exploration, volcano-tectonic, geodynamic and environmental studies, if multiparametric studies are performed and the data are interpreted in the geological context.
    Description: Published
    Description: 457-462
    Description: 4.5. Studi sul degassamento naturale e sui gas petroliferi
    Description: JCR Journal
    Description: restricted
    Keywords: geothermal gas ; international conference on gas geochemistry ; natural gas ; romania ; seeps ; 04. Solid Earth::04.04. Geology::04.04.12. Fluid Geochemistry
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
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  • 64
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    Origin and flux of a gas seep in the Northern Alps (Giswil, Switzerland) (2010)
    Blackwell Publishing Ltd
    Details
    Publication Date: 2017-04-04
    Description: Natural gas seeps in the Alpine region are poorly investigated. However, they can provide useful information regarding the hydrocarbon potential of sedimentary Alpine units and related geofluid migration, typically controlled by pressurized gas accumulations and tectonics. A gas seep located near Giswil, in the Swiss Northern Alps, was investigated, for the first time, for molecular and isotopic gas composition, methane flux to the atmosphere, and gas flux variations over time. The analyses indicated that the gas was thermogenic (CH4 〉 96%; d13C1: )35.5& to )40.2&) and showed evidence of subsurface petroleum biodegradation (13C-enriched CO2, and very low C3+ concentrations). The source rock in the region is marine Type II kerogen, which is likely the same as that providing thermogenic gas in the nearby Wilen shallow well, close to Lake Sarnen. However, the lack of d13CCO2 and d13C3 data for that well prevented us from determining whether the Wilen and Giswil seeps are fed by the same reservoir and seepage system. Gas fluxes from the Giswil seep, measured using a closedchamber system, were significant and mainly from two major vents. However, a substantial gas exhalation from the soil occurs diffusely in an area of at least 115 m2, leading to a total CH4 output conservatively estimated to be at least 16 tonnes per year. Gas flux variations, monitored over a 1-month period by a special tent and flowmeter, showed not only daily meteorological oscillations, but also an intrinsic ‘pulsation’ with periods of enhanced flux that lasted 2–6 h each, occurring every few days. The pulses are likely related to episodes of gas pressure build-up and discharge along the seepage system. However, to date, no relationship to seismicity in the active Sarnen strike-slip fault system has been established.
    Description: Published
    Description: 476-485
    Description: 4.5. Studi sul degassamento naturale e sui gas petroliferi
    Description: JCR Journal
    Description: restricted
    Keywords: Alps ; isotopes ; methane ; organic geochemistry ; seeps ; Switzerland ; 04. Solid Earth::04.04. Geology::04.04.12. Fluid Geochemistry
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  • 65
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    Methane emissions from Earth’s degassing: Implications for Mars (2010)
    Elsevier
    Details
    Publication Date: 2017-04-04
    Description: The presence of methane on Mars is of great interest, since one possibility for its origin is that it derives from living microbes. However, CH4 in the martian atmosphere also could be attributable to geologic emissions released through pathways similar to those occurring on Earth. Using recent data on methane degassing of the Earth, we have estimated the relative terrestrial contributions of fossil geologic methane vs. modern methane from living methanogens, and have examined the significance that various geologic sources might have for Mars. Geologic degassing includes microbial methane (produced by ancient methanogens), thermogenic methane (from maturation of sedimentary organic matter), and subordinately geothermal and volcanic methane (mainly produced abiogenically). Our analysis suggests that not, vert, similar80% of the “natural” emission to the terrestrial atmosphere originates from modern microbial activity and not, vert, similar20% originates from geologic degassing, for a total CH4 emission of not, vert, similar28.0×107 tonnes year−1. Estimates of methane emission on Mars range from 12.6×101 to 57.0×104 tonnes year−1 and are 3–6 orders of magnitude lower than that estimated for Earth. Nevertheless, the recently detected martian, Northern-Summer-2003 CH4 plume could be compared with methane expulsion from large mud volcanoes or from the integrated emission of a few hundred gas seeps, such as many of those located in Europe, USA, Mid-East or Asia. Methane could also be released by diffuse microseepage from martian soil, even if macro-seeps or mud volcanoes were lacking or inactive. We calculated that a weak microseepage spread over a few tens of km2, as frequently occurs on Earth, may be sufficient to generate the lower estimate of methane emission in the martian atmosphere. At least 65% of Earth’s degassing is provided by kerogen thermogenesis. A similar process may exist on Mars, where kerogen might include abiogenic organics (delivered by meteorites and comets) and remnants of possible, past martian life. The remainder of terrestrial degassed methane is attributed to fossil microbial gas (not, vert, similar25%) and geothermal-volcanic emissions (not, vert, similar10%). Global abiogenic emissions from serpentinization are negligible on Earth, but, on Mars, individual seeps from serpentinization could be significant. Gas discharge from clathrate-permafrost destabilization should also be considered. Finally, we have shown examples of potential degassing pathways on Mars, including mud volcano-like structures, fault and fracture systems, and major volcanic edifices. All these types of structures could provide avenues for extensive gas expulsion, as on Earth. Future investigations of martian methane should be focused on such potential pathways.
    Description: In press
    Description: 4.5. Studi sul degassamento naturale e sui gas petroliferi
    Description: JCR Journal
    Description: restricted
    Keywords: Mars ; Methane ; Earth’s degassing ; Seepage ; 04. Solid Earth::04.04. Geology::04.04.12. Fluid Geochemistry
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
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  • 66
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    Methane emissions from Earth’s degassing: Implications for Mars (2011)
    Elsevier
    Details
    Publication Date: 2022-02-16
    Description: The presence of methane on Mars is of great interest, since one possibility for its origin is that it derives from living microbes. However, CH4 in the martian atmosphere also could be attributable to geologic emissions released through pathways similar to those occurring on Earth. Using recent data on methane degassing of the Earth, we have estimated the relative terrestrial contributions of fossil geologic methane vs. modern methane from living methanogens, and have examined the significance that various geologic sources might have for Mars. Geologic degassing includes microbial methane (produced by ancient methanogens), thermogenic methane (from maturation of sedimentary organic matter), and subordinately geothermal and volcanic methane (mainly produced abiogenically). Our analysis suggests that not, vert, similar80% of the “natural” emission to the terrestrial atmosphere originates from modern microbial activity and not, vert, similar20% originates from geologic degassing, for a total CH4 emission of not, vert, similar28.0×107 tonnes year−1. Estimates of methane emission on Mars range from 12.6×101 to 57.0×104 tonnes year−1 and are 3–6 orders of magnitude lower than that estimated for Earth. Nevertheless, the recently detected martian, Northern-Summer-2003 CH4 plume could be compared with methane expulsion from large mud volcanoes or from the integrated emission of a few hundred gas seeps, such as many of those located in Europe, USA, Mid-East or Asia. Methane could also be released by diffuse microseepage from martian soil, even if macro-seeps or mud volcanoes were lacking or inactive. We calculated that a weak microseepage spread over a few tens of km2, as frequently occurs on Earth, may be sufficient to generate the lower estimate of methane emission in the martian atmosphere. At least 65% of Earth’s degassing is provided by kerogen thermogenesis. A similar process may exist on Mars, where kerogen might include abiogenic organics (delivered by meteorites and comets) and remnants of possible, past martian life. The remainder of terrestrial degassed methane is attributed to fossil microbial gas (not, vert, similar25%) and geothermal-volcanic emissions (not, vert, similar10%). Global abiogenic emissions from serpentinization are negligible on Earth, but, on Mars, individual seeps from serpentinization could be significant. Gas discharge from clathrate-permafrost destabilization should also be considered. Finally, we have shown examples of potential degassing pathways on Mars, including mud volcano-like structures, fault and fracture systems, and major volcanic edifices. All these types of structures could provide avenues for extensive gas expulsion, as on Earth. Future investigations of martian methane should be focused on such potential pathways.
    Description: Published
    Description: 182-195
    Description: 4.5. Studi sul degassamento naturale e sui gas petroliferi
    Description: JCR Journal
    Description: restricted
    Keywords: Mars ; Methane ; Earth’s degassing ; Seepage ; 04. Solid Earth::04.04. Geology::04.04.12. Fluid Geochemistry
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  • 67
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    Distinguishing contributions to diffuse CO2 emissions in volcanic areas from magmatic degassing and thermal decarbonation using soil gas 222Rn–δ13 C systematics: Applicationto Santorini volcano,Greece (2014)
    Elsevier Science Limited
    Details
    Publication Date: 2022-06-10
    Description: Between January 2011 and April 2012, Santorini volcano (Greece) experienced a period of unrest characterised by the onset of detectable seismicity and caldera-wide uplift. This episode of inflation represented the first sizeable intrusion of magma beneath Santorini in the past 50 years. We employ a new approach using 222 Rn– δ 13 C systematics to identify and quantify the source of diffuse degassing at Santorini during the period of renewed activity. Soil CO 2 flux measurements were made across a network of sites on Nea Kameni between September 2010 and January 2012. Gas samples were collected in April and September 2011 for isotopic analysis of CO 2 ( δ 13 C), and radon detectors were deployed during September 2011 to measure ( 222 Rn). Our results reveal a change in the pattern of degassing from the summit of the volcano (Nea Kameni) and suggest an increase in diffuse CO 2 emissions between September 2010 and January 2012. High-CO 2 -flux soil gas samples have δ 13 C ∼ 0 .Using this value and other evidence from the literature we conclude that these CO 2 emissions from Santorini were a mixture between CO 2 sourced from magma, and CO 2 released by the thermal or metamorphic breakdown of crustal limestone. We suggest that this mixing of magmatic and crustal carbonate sources may account more broadly for the typical range of δ 13 CvaluesofCO 2 (from ∼− 4 to ∼+ 1 )in diffuse volcanic and fumarole gas emissions around the Mediterranean, without the need to invoke unusual mantle source compositions. At Santorini a mixing model involving magmatic CO 2 (with δ 13 C of − 3 ± 2 and elevated ( 222 Rn)/CO 2 ratios ∼ 10 5 –10 6 Bqkg − 1 )andCO 2 released from decarbonation of crustal limestone (with ( 222 Rn)/CO 2 ∼ 30–300 Bqkg − 1 ,and δ 13 Cof + 5 ) can account for the δ 13 C and ( 222 Rn)/CO 2 characteristics of the ‘high flux’ gas source. This model suggests ∼ 60% of the carbon in the high flux deep CO 2 end member is of magmatic origin. This combination of δ 13 Cand( 222 Rn) measurements has potential to quantify magmatic and crustal contributions to the diffuse outgassing of CO 2 in volcanic areas, especially those where breakdown of crustal limestone is likely to contribute significantly to the CO 2 flux
    Description: Published
    Description: 180-190
    Description: 1.2. TTC - Sorveglianza geochimica delle aree vulcaniche attive
    Description: 2.4. TTC - Laboratori di geochimica dei fluidi
    Description: 4.5. Studi sul degassamento naturale e sui gas petroliferi
    Description: JCR Journal
    Description: restricted
    Keywords: volcanic unrest ; soil gas measurements ; carbon isotopic analysis ; magmatic degassing ; 03. Hydrosphere::03.02. Hydrology::03.02.04. Measurements and monitoring ; 04. Solid Earth::04.04. Geology::04.04.12. Fluid Geochemistry ; 04. Solid Earth::04.08. Volcanology::04.08.01. Gases ; 04. Solid Earth::04.08. Volcanology::04.08.07. Instruments and techniques
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  • 68
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    Evidence of a recent rapid subsidence in the S–E Cyclades (Greece): An effect of the 1956 Amorgos earthquake? (2012)
    Elsevier Science Limited
    Details
    Publication Date: 2022-11-23
    Description: An underwater geomorphological survey along the coasts of six Cycladic islands (Sifnos, Antiparos, Paros, Naxos, Iraklia and Keros) revealed widespread evidence of a recent 30–40 cm submergence, part of which may have seismic origin. Comparison with information reported from earthquakes having affected the area suggests that at least part of the recent submergence might be an effect of the 1956 Amorgos earthquake. Modelling of the co-seismic and short-term post-seismic effects of the earthquake revealed that part of the observed subsidence may be explained in some of the islands by a fast post-seismic relaxation of a low-viscosity layer underlying the seismogenic zone. However far-field observations are underestimated by our model, and may be affected by a wider deformation field induced by the largest aftershock of the Amorgos sequence, or by other earthquakes.
    Description: Published
    Description: 27-40
    Description: 3.3. Geodinamica e struttura dell'interno della Terra
    Description: JCR Journal
    Description: restricted
    Keywords: tidal notch ; sea level change ; 04. Solid Earth::04.07. Tectonophysics::04.07.02. Geodynamics
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  • 69
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    Gas geochemistry of the magmatic-hydrothermal fluid reservoir in the Copahue–Caviahue Volcanic Complex (Argentina) (2014)
    Elsevier Science Limited
    Details
    Publication Date: 2024-05-09
    Description: Copahue volcano is part of the Caviahue–Copahue Volcanic Complex (CCVC),which is located in the southwestern sector of the Caviahue volcano-tectonic depression (Argentina–Chile). This depression is a pull-apart basin accommodating stresses between the southern Liquiñe–Ofqui strike slip and the northern Copahue–Antiñir compressive fault systems, in a back-arc setting with respect to the Southern Andean Volcanic Zone. In this study, we present chemical (inorganic and organic) and isotope compositions (δ13C-CO2, δ15N, 3He/4He, 40Ar/36Ar, δ13C-CH4, δD-CH4, and δD-H2O and δ18O-H2O) of fumaroles and bubbling gases of thermal springs located at the foot of Copahue volcano sampled in 2006, 2007 and 2012. Helium isotope ratios, the highest observed for a Southern American volcano (R/Ra up to 7.94), indicate a non-classic arc-like setting, but rather an extensional regime subdued to asthenospheric thinning. δ13C-CO2 values (from −8.8‰ to −6.8‰ vs. V-PDB), δ15N values (+5.3‰ to +5.5‰ vs. Air) and CO2/3He ratios (from 1.4 to 8.8 × 109) suggest that the magmatic source is significantly affected by contamination of subducted sediments. Gases discharged from the northern sector of the CCVC show contribution of 3He-poor fluids likely permeating through local fault systems. Despite the clear mantle isotope signature in the CCVC gases, the acidic gas species have suffered scrubbing processes by a hydrothermal system mainly recharged by meteoric water. Gas geothermometry in the H2O-CO2-CH4-CO-H2 system suggests that CO and H2 re-equilibrate in a separated vapor phase at 200°–220 °C. On the contrary, rock–fluid interactions controlling CO2, CH4 production from Sabatier reaction and C3H8 dehydrogenation seem to occur within the hydrothermal reservoir at temperatures ranging from 250° to 300 °C. Fumarole gases sampled in 2006–2007 show relatively low N2/He and N2/Ar ratios and high R/Ra values with respect to those measured in 2012. Such compositional and isotope variations were likely related to injection of mafic magma that likely triggered the 2000 eruption. Therefore, changes affecting the magmatic systemhad a delayed effect on the chemistry of the CCVC gases due to the presence of the hydrothermal reservoir. However, geochemical monitoring activities mainly focused on the behavior of inert gas compounds (N2 and He), should be increased to investigate the mechanism at the origin of the unrest started in 2011.
    Description: Published
    Description: 44–56
    Description: 1.2. TTC - Sorveglianza geochimica delle aree vulcaniche attive
    Description: 2.4. TTC - Laboratori di geochimica dei fluidi
    Description: 4.5. Studi sul degassamento naturale e sui gas petroliferi
    Description: JCR Journal
    Description: restricted
    Keywords: Fluid geochemistry ; Copahue volcano ; Fumarolic fluid ; Hydrothermal reservoir ; Volcanic unrest ; 03. Hydrosphere::03.02. Hydrology::03.02.04. Measurements and monitoring ; 04. Solid Earth::04.04. Geology::04.04.12. Fluid Geochemistry ; 04. Solid Earth::04.08. Volcanology::04.08.01. Gases ; 04. Solid Earth::04.08. Volcanology::04.08.07. Instruments and techniques
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  • 70
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    Diffuse soil emission of hydrothermal gases (CO2, CH4, and C6H6) at Solfatara crater (Campi Flegrei, southern Italy) (2014)
    Elsevier Science Limited
    Details
    Publication Date: 2024-05-09
    Description: Measurements of soil fluxes of hydrothermal gases, with special emphasis on C6H6, as well as chemical composition of mono-aromatic compounds in fumaroles and air, were carried out in April 2012 at the Solfatara crater (Campi Flegrei, Southern Italy) to investigate the distribution and behavior of these species as they migrate through the soil from their deep source to the atmosphere. Soil fluxes of CO2, CH4 and C6H6 exhibit good spatial correlation, suggesting that diffuse degassing is mainly controlled by local fractures. The calculated total output of diffuse C6H6 from Solfatara is 0.10 kg day 1, whereas fluxes of CO2 and CH4 are 79 103 and 1.04 kg day 1, respectively. A comparison between soil gas fluxes and fumarole composition reveals that within the crater soil CH4 is significantly affected by oxidation processes, which are more efficient for low gas fluxes, being dependent on the residence time of the uprising hydrothermal gases at shallow depth. Benzene degradation, mainly proceeding through oxidation via benzoate, seems to be strongly controlled by the presence of a shallow SO2 4 -rich aquifer located in the central and southwestern sectors of the crater, suggesting that the process is particularly efficient when SO2 4 acts as terminal electron acceptor (SO4 reduction). Relatively high C6H6/C7H8 ratios, typical of hydrothermal fluids, were measured in air close to the main fumarolic field of Solfatara crater. Here, C6H6 concentrations, whose detection limit is 0.1 lgm 3, are more than one order of magnitude higher than the limit value for ambient air (5 lgm 3). This suggests that hydrothermal fluids have a strong impact on air quality in the immediate surroundings of the fumarolic vents. Significant concentrations of endogenous mono-aromatics were also detected in air samples collected from the northern and western sides of the crater, where these gas compounds are mostly fed by diffuse degassing through the crater bottom soil.
    Description: Published
    Description: 142–153
    Description: 1.2. TTC - Sorveglianza geochimica delle aree vulcaniche attive
    Description: 2.4. TTC - Laboratori di geochimica dei fluidi
    Description: 4.5. Studi sul degassamento naturale e sui gas petroliferi
    Description: JCR Journal
    Description: restricted
    Keywords: hydrothermal gases ; Solfatara crater ; 03. Hydrosphere::03.02. Hydrology::03.02.04. Measurements and monitoring ; 04. Solid Earth::04.04. Geology::04.04.12. Fluid Geochemistry ; 04. Solid Earth::04.08. Volcanology::04.08.01. Gases ; 04. Solid Earth::04.08. Volcanology::04.08.07. Instruments and techniques
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
    Type: article
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