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  • Articles  (5,194)
  • Chemistry  (3,685)
  • United States
  • 2020-2023  (11)
  • 2010-2014  (1,524)
  • 1945-1949  (3,659)
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  • Articles  (5,194)
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  • 1
    Publication Date: 2021-05-19
    Description: Daily topical application of the aqueous ethanolic extract of the marine sea grass, Thalassia testudinum, on mice skin exposed to UVB radiation resulted in a dose dependent recovery of the skin macroscopic alterations over a 6-day period. Maximal effect (90%) occurred at a dose of 240 μg/cm2, with no additional effects at higher doses. Bioassay-guided fractionation of the plant extract resulted in the isolation of thalassiolin B (1). Topical application of 1 (240 μg/cm2) markedly reduces skin UVB-induced damage. In addition, thalassiolin B scavenged 2,2-diphenyl-2-picrylhydrazyl radical with an EC50=100 μg/ml. These results suggest that thalassiolin B is responsible for the skin regenerating effects of the crude extract of T. testudinum
    Description: Published
    Description: Flavonoids, Thalassiolin B, DPPH scavenged, antioxidant activity, Skin regenerating activity, Thalassia testudinum
    Keywords: Chemistry ; Pharmacology ; Chemistry ; Pharmacology
    Repository Name: AquaDocs
    Type: Journal Contribution
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  • 2
    Publication Date: 2021-05-19
    Description: Bioguided fractionation of Agelas cerebrum crude extract resulted in isolation of four bromopyrrole and four bromopyrrole aminoimidazole alkaloids, identified as 5-bromopyrrole-2-carboxylic acid (1), 4-bromopyrrole-2-carboxylic acid (2), 3,4-bromopyrrole-2-carboxylic acid (3), 4,5-bromopyrrole-2-carboxylic acid (4), oroidin (5), bromoageliferin (6), dibromoageliferin (7) and dibromosceptrin (8) on the basis of spectroscopic data analyses (UV, IR, HRMS, 1D and 2D NMR) and comparison with literature data. This is the first report of compounds 2 and 3 in a marine sponge belonging to the Agelas genus and the first evidence of the presence of 1 from a natural source.
    Description: Published
    Description: Agelas cerebrum, bromopyrrole alkaloids, antitumoral, antiprotozoal activity
    Keywords: Chemistry ; Alkaloids ; Sponges ; Alkaloids ; Sponges ; Chemistry
    Repository Name: AquaDocs
    Type: Journal Contribution
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  • 3
    Publication Date: 2021-05-19
    Description: La velocidad de descomposición de tres fenólicos, el p-hidroxibenzoico, el protocatecúico y el gálico, los cuales se diferencian en el número de grupos OH, fue investigada en el suelo. Con el aumento de grupos OH aumenta también la velocidad de descomposición microbial. El ácido gálico se descompone más rápido que el protocatecúico y este a su vez más rápido que el phidroxibenzoico.
    Description: The rate of decomposition of the three phenolics, p-hydroxybenzoic acid, protocatechuic acid and gallic acid, whose difference is the amount of OH-groups, was investigated in the soil. With the increase in OH-groups increases the rate of microbial decomposition. Gallic acid decomposes faster than protocatecuic acid and this again faster than p-hydroxybenzoic acid.
    Description: Published
    Keywords: Chemical decomposition ; OH Groups ; Microbes ; Phenols ; Chemistry ; Phenols ; Chemistry
    Repository Name: AquaDocs
    Type: Journal Contribution
    Format: pp.141-143
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  • 4
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    Massachusetts Institute of Technology and Woods Hole Oceanographic Institution
    Publication Date: 2022-05-25
    Description: Submitted in partial fulfillment of the requirements for the degree of Doctor of Philosophy at the Massachusetts Institute of Technology and the Woods Hole Oceanographic Institution May 1998
    Description: Planktonic protozoan grazers have the potential to significantly affect the chemistry of particle-associated trace metals. This is due both to the importance of protists as consumers of bacterial-sized particles, and to the unique low-pH, enzyme-rich microenvironment of the grazer food vacuole. This thesis examines the role of protozoan grazers in the marine geochemistry of strongly hydrolyzed, particle-reactive trace metals, in particular Th and Fe. A series of tracer experiments was carried out in model systems in order to determine the effect of grazer-mediated transformations on the chemical speciation and partitioning of radioisotopes C9Fe, 234Th, 51Cr) associated with prey cells. Results indicate that protozoan grazers are equally able to mobilize intracellular and extracellular trace metals. In some cases, protozoan regeneration of trace metals appears to lead to the formation of metal-organic complexes. Protozoan grazing may generate colloidal material that can scavenge trace metals and, via aggregation, lead to an increase in the metal/organic carbon ratio of aggregated particles. Model system experiments were also conducted in order to determine the effect of grazers on mineral phases, specifically colloidal iron oxide (ferrihydrite). Several independent techniques were employed, including size fractionation ors9Fe-labeled colloids, competitive ligand exchange, and iron-limited diatoms as "probes" for bioavailable Fe. Experimental evidence strongly suggests that protozoan grazing can affect the surface chemistry and increase the dissolution rate of iron oxide phases through phagotrophic ingestion. In further work on protozoan-mediated dissolution of colloidal Fe oxides, a novel tracer technique was developed based on the synthesis of colloidal ferrihydrite impregnated with 133Ba as an inert tracer. This technique was shown to be a sensitive, quantitative indicator for the extent of ferrihydrite dissolution/alteration by a variety of mechanisms, including photochemical reduction and ligand-mediated dissolution. In field experiments using this technique, grazing by naturally occuring protistan assemblages was shown to significantly enhance the dissolution rate of colloidal ferrihydrite over that in non-grazing controls. Laboratory and field results indicate that, when integrated temporally over the entire euphotic zone, protozoan grazing may equal or exceed photoreduction as a pathway for the dissolution of iron oxides.
    Description: This work was financially supported by a Department of Defense ONR-NDSEG Graduate Fellowship, Office ofNaval Research AASERT Award (N00014-94-1-0711), and the National Science Foundation EGB Program (OCE-9523910).
    Keywords: Protozoa ; Water chemistry ; Trace elements in water ; Marine zooplankton ; Chemistry
    Repository Name: Woods Hole Open Access Server
    Type: Thesis
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  • 5
    Publication Date: 2022-10-26
    Description: © The Author(s), 2019. This article is distributed under the terms of the Creative Commons Attribution License. The definitive version was published in Little, C. M., Hu, A., Hughes, C. W., McCarthy, G. D., Piecuch, C. G., Ponte, R. M., & Thomas, M. D. The relationship between U.S. East Coast sea level and the Atlantic Meridional Overturning Circulation: a review. Journal of Geophysical Research-Oceans, 124(9), (2019): 6435-6458, doi:10.1029/2019JC015152.
    Description: Scientific and societal interest in the relationship between the Atlantic Meridional Overturning Circulation (AMOC) and U.S. East Coast sea level has intensified over the past decade, largely due to (1) projected, and potentially ongoing, enhancement of sea level rise associated with AMOC weakening and (2) the potential for observations of U.S. East Coast sea level to inform reconstructions of North Atlantic circulation and climate. These implications have inspired a wealth of model‐ and observation‐based analyses. Here, we review this research, finding consistent support in numerical models for an antiphase relationship between AMOC strength and dynamic sea level. However, simulations exhibit substantial along‐coast and intermodel differences in the amplitude of AMOC‐associated dynamic sea level variability. Observational analyses focusing on shorter (generally less than decadal) timescales show robust relationships between some components of the North Atlantic large‐scale circulation and coastal sea level variability, but the causal relationships between different observational metrics, AMOC, and sea level are often unclear. We highlight the importance of existing and future research seeking to understand relationships between AMOC and its component currents, the role of ageostrophic processes near the coast, and the interplay of local and remote forcing. Such research will help reconcile the results of different numerical simulations with each other and with observations, inform the physical origins of covariability, and reveal the sensitivity of scaling relationships to forcing, timescale, and model representation. This information will, in turn, provide a more complete characterization of uncertainty in relevant relationships, leading to more robust reconstructions and projections.
    Description: The authors acknowledge funding support from NSF Grant OCE‐1805029 (C. M. L.) and NASA Contract NNH16CT01C (C. M. L. and R. M. P.), the Regional and Global Model Analysis (RGMA) component of the Earth and Environmental System Modeling Program of the U.S. Department of Energy's Office of Biological & Environmental Research Cooperative Agreement DE‐FC02‐97ER62402 (A. H.), Natural Environment Research Council NE/K012789/1 (C. W. H.), Irish Marine Institute Project A4 PBA/CC/18/01 (G. D. M.), and NSF Awards OCE‐1558966 and OCE‐1834739 (C. G. P.). The National Center for Atmospheric Research is sponsored by National Science Foundation. The authors thank the two reviewers for their comments, and CLIVAR and the U.S. AMOC Science Team for inspiration and patience. All CMIP5 data used in Figures 4-6 are available at http://pcmdi9.llnl.gov/ website; the AMOC strength fields were digitized from Chen et al. (2018, supporting information Figure S3).
    Keywords: Sea level ; AMOC ; United States ; Coastal ; Climate model ; Review
    Repository Name: Woods Hole Open Access Server
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  • 6
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    Marine Fisheries Research Department, Southeast Asian Fisheries Development Center | Singapore
    In:  http://aquaticcommons.org/id/eprint/26299 | 23782 | 2019-03-27 06:00:01 | 26299 | Southeast Asian Fisheries Development Center, Marine Fisheries Research Department
    Publication Date: 2022-08-02
    Keywords: Chemistry ; Fisheries ; Malaysia ; Pesticides ; Biological sampling ; Fish ; Fishery products ; Biochemical analysis ; Lethal limits
    Repository Name: AquaDocs
    Type: book_section
    Format: application/pdf
    Format: application/pdf
    Format: 71-74
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  • 7
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    Marine Fisheries Research Department, Southeast Asian Fisheries Development Center | Singapore
    In:  http://aquaticcommons.org/id/eprint/26300 | 23782 | 2019-03-27 05:58:36 | 26300 | Southeast Asian Fisheries Development Center, Marine Fisheries Research Department
    Publication Date: 2022-08-02
    Keywords: Aquaculture ; Chemistry ; Fisheries ; Myanmar ; Pesticides ; Biological sampling ; Fish ; Fishery products ; Lethal limits
    Repository Name: AquaDocs
    Type: book_section
    Format: application/pdf
    Format: application/pdf
    Format: 75-83
    Format: 9
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  • 8
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    Marine Fisheries Research Department, Southeast Asian Fisheries Development Center | Singapore
    In:  http://aquaticcommons.org/id/eprint/26303 | 23782 | 2019-03-27 05:51:15 | 26303 | Southeast Asian Fisheries Development Center, Marine Fisheries Research Department
    Publication Date: 2022-08-02
    Keywords: Chemistry ; Fisheries ; Thailand ; Pesticides ; Biological sampling ; Fish ; Fishery products ; Dried products ; Lethal limits
    Repository Name: AquaDocs
    Type: book_section
    Format: application/pdf
    Format: application/pdf
    Format: 100-105
    Format: 6
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  • 9
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    Marine Fisheries Research Department, Southeast Asian Fisheries Development Center | Singapore
    In:  http://aquaticcommons.org/id/eprint/26826 | 23782 | 2019-11-21 00:56:12 | 26826 | Southeast Asian Fisheries Development Center, Marine Fisheries Research Department
    Publication Date: 2022-08-02
    Description: Presented in the paper is the standard procedure in the determination of K value which is an index to measure the enzymatic freshness of fish and squid. Specifically, reagents, apparatus and the analytical procedures needed and the calculations are presented.
    Keywords: Chemistry ; Fisheries ; Manuals ; Culture media ; Analysis ; Analytical techniques ; Methodology ; Chemical analysis ; Fishery products ; Fish inspection ; Fishery industry ; Food technology ; Standards ; Specifications
    Repository Name: AquaDocs
    Type: book_section
    Format: application/pdf
    Format: application/pdf
    Format: B-6.1-B-6.7
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  • 10
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    Marine Fisheries Research Department, Southeast Asian Fisheries Development Center | Singapore
    In:  http://aquaticcommons.org/id/eprint/26825 | 23782 | 2019-11-21 00:52:35 | 26825 | Southeast Asian Fisheries Development Center, Marine Fisheries Research Department
    Publication Date: 2022-08-02
    Description: Presented in the paper is the standard procedure in measuring K value in fish meat by means of the freshness testing paper technique.
    Keywords: Chemistry ; Fisheries ; Manuals ; Culture media ; Analysis ; Analytical techniques ; Methodology ; Chemical analysis ; Fishery products ; Fish inspection ; Fishery industry ; Food technology ; Standards ; Specifications
    Repository Name: AquaDocs
    Type: book_section
    Format: application/pdf
    Format: application/pdf
    Format: B-7.1-B-7.2
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  • 11
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    Marine Fisheries Research Department, Southeast Asian Fisheries Development Center | Singapore
    In:  http://aquaticcommons.org/id/eprint/26802 | 23782 | 2019-11-12 05:28:20 | 26802 | Southeast Asian Fisheries Development Center, Marine Fisheries Research Department
    Publication Date: 2022-08-02
    Description: Presented in the paper is the standard procedure in the measurement of pH in the fresh fish meat. Specifically, the procedures in sampling and sample preparation, apparatus and reagents required, and the analytical procedures are presented.
    Keywords: Chemistry ; Fisheries ; Manuals ; Culture media ; Analysis ; Analytical techniques ; Methodology ; Chemical analysis ; Microbiological analysis ; Fishery products ; Processed fishery products ; Fish inspection ; Fishery industry ; Food additives ; Food technology ; Standards ; Specifications ; pH
    Repository Name: AquaDocs
    Type: book_section
    Format: application/pdf
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    Format: A-3.1-A-3.2
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  • 12
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    Marine Fisheries Research Department, Southeast Asian Fisheries Development Center | Singapore
    In:  http://aquaticcommons.org/id/eprint/26842 | 23782 | 2019-11-15 07:54:48 | 26842 | Southeast Asian Fisheries Development Center, Marine Fisheries Research Department
    Publication Date: 2022-08-02
    Description: Starch is commonly used in the production of fish jelly products as an extender and as binding agent. The paper provides the methodology in the determination of starch in fish jelly products. Instructions for sample preparation and the reagents needed are presented. Detailed procedures in the determination of the starch in a sample are provided.
    Keywords: Chemistry ; Fisheries ; Manuals ; Culture media ; Analysis ; Analytical techniques ; Methodology ; Chemical analysis ; Fishery products ; Fishery industry ; Food technology ; Standards ; Specifications ; Starch ; Additives ; Food additives
    Repository Name: AquaDocs
    Type: book_section
    Format: application/pdf
    Format: application/pdf
    Format: D-4.1-D-4.4
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  • 13
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    Marine Fisheries Research Department, Southeast Asian Fisheries Development Center | Singapore
    In:  http://aquaticcommons.org/id/eprint/26852 | 23782 | 2019-11-15 07:36:44 | 26852 | Southeast Asian Fisheries Development Center, Marine Fisheries Research Department
    Publication Date: 2022-08-02
    Description: Cholera is an acute specific infection caused by the organism, Vibrio cholera. Diagnosis may be confirmed by the presence of large numbers of the comma-shaped bacilli on direct microscopic examination of a fecal or vomitus smear, and by the isolation of the organism on culture. Fish and shellfish have been identified as vehicles of cholera. Large numbers of V. cholera must usually be ingested to cause cholera. Thus problems often occur when poor handling and inadequate refrigeration have allowed the organism to multiply. Presented in the paper is the methodology of determining the presence of Vibrio cholera in fish and fishery products.
    Keywords: Chemistry ; Fisheries ; Manuals ; Culture media ; Analysis ; Analytical techniques ; Methodology ; Fishery products ; Fishery industry ; Food technology ; Standards ; Specifications ; Aerobic bacteria ; Microbiological analysis ; Microorganisms ; Pathogenic bacteria ; Pathogens ; Health and safety ; Public health ; Microbial contamination ; Vibrio cholerae
    Repository Name: AquaDocs
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    Format: application/pdf
    Format: application/pdf
    Format: E-7.1-E-7.5
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  • 14
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    Marine Fisheries Research Department, Southeast Asian Fisheries Development Center | Singapore
    In:  http://aquaticcommons.org/id/eprint/26843 | 23782 | 2019-11-15 07:52:55 | 26843 | Southeast Asian Fisheries Development Center, Marine Fisheries Research Department
    Publication Date: 2022-08-02
    Description: Sodium chloride is an important additive for the production of fish jelly products. It extracts the salt soluble protein to give the gel strength of the final product. The paper provides the methodology in the determination of the amount of sodium chloride in fish jelly products. Instructions for sample preparation and the reagents needed are presented. Detailed procedures in the determination of the salt in a sample are provided.
    Keywords: Chemistry ; Fisheries ; Manuals ; Culture media ; Analysis ; Analytical techniques ; Methodology ; Chemical analysis ; Fishery products ; Fishery industry ; Food technology ; Standards ; Specifications ; Additives ; Food additives ; Salts ; Sodium chloride
    Repository Name: AquaDocs
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    Format: D-5.1-D-5.2
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  • 15
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    Marine Fisheries Research Department, Southeast Asian Fisheries Development Center | Singapore
    In:  http://aquaticcommons.org/id/eprint/26851 | 23782 | 2019-11-14 01:29:31 | 26851 | Southeast Asian Fisheries Development Center, Marine Fisheries Research Department
    Publication Date: 2022-08-02
    Description: Food poisoning due to Vibrio parahaemolyticus is a food-borne infection resulting from the ingestion of a large number of this organism (about 106-109 viable cells). The major symptoms are diarrhea and abdominal pain with headache, fever, and vomiting also occurring. The organisms are excreted during the acute stage of the illness after which they decrease rapidly. The differentiation of V. parahaemolyticus from other pathogenic species of Vibrio is based mainly on salt tolerance, Voges-Proskauer reaction, fermentation of sucrose, and growth at 43°C. Presented in the paper is the methodology of determining the presence of Vibrio cholera in fish and fishery products.
    Keywords: Chemistry ; Fisheries ; Manuals ; Culture media ; Analysis ; Analytical techniques ; Methodology ; Fishery products ; Fishery industry ; Food technology ; Standards ; Specifications ; Aerobic bacteria ; Microbiological analysis ; Microorganisms ; Pathogenic bacteria ; Pathogens ; Health and safety ; Public health ; Microbial contamination ; Vibrio parahaemolyticus ; Vibrio cholerae
    Repository Name: AquaDocs
    Type: book_section
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    Format: E-8.1-E-8.6
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  • 16
    Electronic Resource
    Electronic Resource
    Weinheim : Wiley-Blackwell
    Chemie Ingenieur Technik - CIT 21 (1949) 
    ISSN: 0009-286X
    Keywords: Chemistry ; Industrial Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
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  • 17
    Electronic Resource
    Electronic Resource
    Weinheim : Wiley-Blackwell
    Chemie Ingenieur Technik - CIT 21 (1949), S. 6-8 
    ISSN: 0009-286X
    Keywords: Chemistry ; Industrial Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: Die Anordnung dient zur Messung von Dampfdruckerniedrigungen verdünnter Lösungen (10-3 Mol/l) insbesondere assoziierender Substanzen. Es wurde eine Meßanordnung entwickelt, in der die durch kleine Druckdifferenzen verursachte Ausbuchtung der Wölbung des Meniskus eines Hg-Manometers nach dem Prinzip eines Photometers lichtelektrisch mit einem Vakuumthermoelement gemessen wird. Die Anordnung gestattet unabhängig vom Gesamtdruck noch Druckschwankungen von 10-4 mm Hg zu messen.
    Additional Material: 4 Ill.
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  • 18
    ISSN: 0009-286X
    Keywords: Chemistry ; Industrial Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: Es werden einige Regeleinrichtungen besprochen, die zum Aufbau von im wesentlichen automatisch arbeitenden Destillationskolonnen sowohl für diskontinuierlichen als auch für kontinuierlichen Betrieb führten.
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  • 19
    Electronic Resource
    Electronic Resource
    Weinheim : Wiley-Blackwell
    Chemie Ingenieur Technik - CIT 21 (1949), S. 1-6 
    ISSN: 0009-286X
    Keywords: Chemistry ; Industrial Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: Unsere wichtigsten chemischen Großsynthesen gehen von Acetylen bzw. vom Kohlenoxyd-Wasserstoff-Gemisch aus. Die Arbeiten im letzten Jahrzehnt bezweckten, diese Rohstoffe unmittelbar aus dem Ferngas zu gewinnen. Von den entwickelten Verfahren verdient insbesondere das Sauerstoff-Verfahren Beachtung. Es liefert ein Synthesegas mit nur noch 0,2% Methan und ist unempfindlich gegen den im Ferngas vorhandenen organischen Schwefel. Eine etwa folgende Umsetzung des Kohlenoxydes mit Wasserdampf zu CO2 und Wasserstoff kann in unmittelbarem Ánschluß an der Kohlenwasserstoff-Spaltung vorgenommen werden, so daß kein neuer Dampfverbrauch auftritt. Während in der folgenden Arbeit über das Verfahren zur Verarbeitung des gesamten Ferngases auf Kohlenoxyd und Wasserstoff berichtet wird, wird in einer weiteren Arbeit die chemische Verwertung der einzelnen Bestandteile des Ferngases behandelt.
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  • 20
    Electronic Resource
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    Weinheim : Wiley-Blackwell
    Chemie Ingenieur Technik - CIT 21 (1949), S. 19-24 
    ISSN: 0009-286X
    Keywords: Chemistry ; Industrial Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: Nach den verfügbaren amerikanischen Quellen wird zusammenfassend über die seit etwa 1940 in Amerika erreichten Fortschritte auf dem Gebiet der Sauerstoff-Erzeugung und -Anwendung berichtet, besonders über Versuche an Austauschböden und Trennkolonnen für kleinere, meist leichtbewegliche Anlagen, über die Mittel zur Kälteerzeugung, über die Herstellung und den Versand von flüssigem Sauerstoff sowie über die unmittelbare Erzeugung von hochkomprimiertem Sauerstoff für die Flaschenfüllung durch Verdampfung des flüssigen Sauerstoffs im Zerlegungsapparat. Weiter wird ein neuer Austauschertyp besprochen und auf neu erschlossene Anwendungsgebiete für billigen, mäßig reinen Sauerstoff hingewiesen.
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  • 21
    Electronic Resource
    Electronic Resource
    Weinheim : Wiley-Blackwell
    Chemie Ingenieur Technik - CIT 21 (1949), S. 15-18 
    ISSN: 0009-286X
    Keywords: Chemistry ; Industrial Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: Bei Kohlenoxyd-Hydrierungen unter Drucken zwischen 300 und 1000 at und Temperaturen über 400° erwiesen sich z. T. sog. „kohlenoxydfeste“ metallische Werkstoffe, insbesondere Stähle mit mehr als 13% Chrom, für den praktischen Betrieb als ungeeignet, obwohl sie anscheinend von Kohlenoxyd nicht abgebaut wurden. Es wurden daher 20 derartige Stähle und 6 eisenfreie Metallproben gegenüber Wassergas bei 1000 at und Temperaturen zwischen 300 und 450° untersucht und aus den Ergebnissen Folgerungen für die praktische Verwendungsmöglichkeit im Apparafebau gezogen.
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  • 22
    Electronic Resource
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    Weinheim : Wiley-Blackwell
    Chemie Ingenieur Technik - CIT 21 (1949), S. 24-30 
    ISSN: 0009-286X
    Keywords: Chemistry ; Industrial Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Additional Material: 3 Ill.
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  • 23
    Electronic Resource
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    Weinheim : Wiley-Blackwell
    Chemie Ingenieur Technik - CIT 21 (1949), S. 31-31 
    ISSN: 0009-286X
    Keywords: Chemistry ; Industrial Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
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  • 24
    Electronic Resource
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    Weinheim : Wiley-Blackwell
    Chemie Ingenieur Technik - CIT 21 (1949), S. 31-32 
    ISSN: 0009-286X
    Keywords: Chemistry ; Industrial Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
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  • 25
    Electronic Resource
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    Weinheim : Wiley-Blackwell
    Chemie Ingenieur Technik - CIT 21 (1949), S. 33-37 
    ISSN: 0009-286X
    Keywords: Chemistry ; Industrial Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
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  • 26
    Electronic Resource
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    Weinheim : Wiley-Blackwell
    Chemie Ingenieur Technik - CIT 21 (1949), S. 37-38 
    ISSN: 0009-286X
    Keywords: Chemistry ; Industrial Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
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  • 27
    Electronic Resource
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    Weinheim : Wiley-Blackwell
    Chemie Ingenieur Technik - CIT 21 (1949), S. 38-38 
    ISSN: 0009-286X
    Keywords: Chemistry ; Industrial Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
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  • 28
    Electronic Resource
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    Weinheim : Wiley-Blackwell
    Chemie Ingenieur Technik - CIT 21 (1949), S. 32-32 
    ISSN: 0009-286X
    Keywords: Chemistry ; Industrial Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
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  • 29
    Electronic Resource
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    Weinheim : Wiley-Blackwell
    Chemie Ingenieur Technik - CIT 21 (1949), S. 39-39 
    ISSN: 0009-286X
    Keywords: Chemistry ; Industrial Chemistry
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    Notes: Die Angabe, daß sich die Ausscheidung von Härtebildern mit Orthophosphaten in wässeriger Lösung unter Bildung von Tricalciumphosphat vollziehe, ist unzutreffend. Der Niederschlag dürfte vielmehr die Formel des Hydroxylapatits haben.
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    Notes: Bis 1940 war die Anwendung hoher Vakua fast nur auf das Laboratorium beschränkt, in der Technik evakuierte nur die Röhrenindustrie bis auf Drucke von beinahe 10-7 mm Hg, aber es handelte sich auch hier meist nur um verhältnismäßig kleine Volumina. Die anschließende Entwicklung wurde durch mehrere Ereignisse besonders gefördert: durch die Konstruktion hervorragender Pumpen in Deutschland und Amerika, durch die Schaffung guter Gläser in Jena, durch die Erfolge der Vakuumdestillation von Fetten, Ölen und empfindlichen organischen Substanzen in England, Deutschland und später in USA, und schließlich durch das amerikanische Atombombenprojekt, wo bereits bei der Gasdiffusions- und elektromagnetischen Trennung der Uran-Isotope die ersten großen Vakuum-Probleme auftraten. Heute ist selbst die großtechnische Erzeugung von Hochvakuum zwischen -100° und + 1000° C ein untergeordnetes Problem der Verfahrenstechnik geworden.
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    Notes: Es wird über Versuche mit zwei Ausführungen von Pilzglocken aus Porzellan berichtet, die in Rektifizierböden eingebaut waren. Wirkung, Druckverlust und Flüssigkeitsinhalt der Sälen wurden ermittelt. Um eine gute Wirkung zu erreichen, müssen die Einzelabmessungen des Bodens entsprechend gewählt werden. Auch der Einbau einer Staurippe erhöht die Bodenwirkung.
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    Notes: Die hier beschriebenen Methoden sollen es dem Schichtarbeiter mit einfachen Mitteln ermöglichen, kurzfristig eine gefährliche Acetylen-Anreicherung zu erkennen. Die Ergebnisse werden mit denen quantitativer Methoden verglichen.
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    Notes: Der im folgenden beschriebene Kolbenverdichter arbeitet mit ungeschmierten Kolben und Stopfbüchsen. Die Abdichtung wird durch Labyrinthdichtungen erreicht. Dadurch behält das verdichtete Medium die ursprüngliche Reinheit, so daß der Verdichter in der chemischen Industrie und der Lebensmittelindustrie da verwendet werden kann, wo völlig reine Druckluft gebraucht wird.
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    Notes: In den letzten Jahren hat die Fluorchemie, insbesondere die verschiedener organischer fluorierter Verbindungen, erheblich an praktischer Bedeutung gewonnen. Da in einigen Veröffentlichungenz. B. DECHEMA-Werkstofftabellen 1948; ferner Ind. Engng. Chem. 39, 12a u. 91a [1947]. bereits auf die gute Eignung des Silbers als Apparatebauwerkstoff für technische Reaktionen mit Fluorverbindungen hingewiesen worden ist, seien nachstehend einige quantitative Angaben gemasht, die das Ergebnis einer 1944 laboratoriumsmäßig durchgeführten Korrosionsprüfung darsfellen.
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    Notes: Die technisch-wissenschaftliche Forschung der letzten Jahrzehnte brachte eine Erweiterung und Vertiefung unserer Erkenntnisse über die beim gekoppelten Wärme- und Stoffaustausch sich abspielenden Vorgänge. Trotzdem blieben noch Fragen ungeklärt, deren erschöpfende Behandlung für die rechnerische Erfassung baispielsweise der Trocknungsvorgänge unerläßlich ist. Zu diesen Fragen gehört der Zusammenhang zwischen Luftzustand und Gutstemperatur während des Trocknens bei bestimmten Arten der Gasströmung. Im folgenden werden diese Verhältnisse untersucht, wobei sich eine gute Übereinstimmung zwischen theoretischen und experimentellen Ergebnissen ergibt.
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    Notes: Die bisherigen Definitionen des Wirkungsgrades von Wärmeaustauschern konnten zwangsläufig nicht in jeder Hinsicht befriedigen. Es wird auch immer schwierig sein, einen Wirkungsgrabegriff auf energetischer Grundlage aufzustellen, solange der Wärmeaustauschapparat allein betrachtet wird, da sich Wärme- und Druckverluste jeweils verschieden auswirken. Daher sollte auch das Arbeitsverfahren, in das der Wärmeaustauscher eingeschaltet ist, mit in Betracht gezogen werden. Im folgenden wird gezeigt, daß sich dann ein auf energetischer Grundlage beruhender Gütegradbegriff schaffen läßt, der zwar von Fall zu Fall neu aufgestellt werden muß, dafür aber eine Reihe von Vorteilen für den Erzeuger und den Abnehmer von Wäreaustauschapparaten bietet.
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    Notes: Der Auslaufbecher DIN 53211 ist ein einfaches, praktisch leicht zu handhabendes Betriebs-Gerät zur Beurteilung der Konsistenz besonders von Farben und Lacken. Die vorliegende Untersuchung zeigt, innerhalb welcher Grenzen der Auslaufbecher tatsächlich geeignet ist, ein zuverlässiges Maß für die Konsistenz mit ihren Nebenerscheinungen, z. B. für die Viskosität usw., zu sein. Der experimentelle Zusammenhang zwischen Auslaufzeit und Viskosität wird durch Versuche mit 11 Normalflüssigkeiten ermittelt. Die genaue Analyse der Versuchsergebnisse gibt einen interessanten Einblick in die Strömungsvorgänge bei diesem Gerät.
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    Notes: Die Aufzeichnung polarographischer Kurven in Tintenschrift gestattet einfachstes Modellieren und Auswerten der Kurven. Für den Betrieb normaler Tintenschreiber unter Verstärkung der Elektrodenströme mittels Verstärker in Saugschaltung1 wurde während des Krieges ein vollelektrisch arbeitendes Zusatzgerät durchgebildet, in dem alle erforderlichen Schaltelemente und Verstellorgane zur Kurvenaufnahme untergebracht sind. Die einfach zu bedienende, robuste und universell verwendbare polarographische Meßeinrichtung läßt sich auch in technischen Betrieben zur Durchführung von Serienanalysen verwenden. Seine Wirkungsweise wird im folgenden unter Beifügung einiger charakteristischer Kurven erläutert.
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    Notes: Vielen Betrieben steht Kühlwasser zur Verfügung, das reich an Carbonathärte ist und daher leicht Versteinungen der Leitungen hervorruft. Um diese Steinbildung zu verhindern, hat sich der Zusatz geringer Mengen an Natriumhexametaphosphat bewährt. Während man zur Prüfung der Brauchbarkeit von Zusätzen bisher einfache Becherglasversuche angestellt hat, haben die Verfasser ein geeignetes, im Laboratorium durchführbares Prüfverfahren entwickelt, wobei die wesentlichen betrieblichen Faktoren berücksichtigt werden können. Im folgenden wird diese Apparatur beschrieben und dann werden damit erzielte Versuchsergebnisse mitgeteilt, die mit den in der Praxis gemachten Erfahrungen gut übereinstimmen. In einem Anhang wird schließlich über Becherglasversuche mit organischen Zusätzen berichtet.
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    Chemie Ingenieur Technik - CIT 21 (1949), S. 135-135 
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    Chemie Ingenieur Technik - CIT 21 (1949), S. 129-135 
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    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: In der vorhergehenden Arbeit1 war über ein Verfahren berichtet worden, nach dem aus Ferngas durch Totalspaltung mit Sauerstoff Synthesegas gewonnen werden kann. Das Ferngas enthält jedoch eine Reihe von wertvollen Bestandteilen, die für die Verarbeitung auf Synthesegas zu schade sind. Im folgenden wird beschrieben, wie diese Produkte zu isolieren sind und welche Möglichkeit für ihre Weiterverarbeitung gegeben ist. Dabei wird insbesondere das Sauerstoff-Verfahren besprochen, bei dem Methan und Sauerstoff erst nach vollendeter Mischung einer Flammenreaktion unterworfen werden, die durch Einspritzen von Wasser unterbrochen wird.
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    Chemie Ingenieur Technik - CIT 21 (1949), S. 136-136 
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    Source: Wiley InterScience Backfile Collection 1832-2000
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    Notes: Das indirekte Verfahren, nach dem Phosphat- bzw. Fluor-lonen durch die Extinktionsabnahme des Eisensalicylat-Komplexes bestimmt werden, kann auch für die Bestimmung der Schwefelsäure in Nitriersäure-Gemischen nutzbar gemacht werden.
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    Notes: Als Beitrag zur Weiterentwicklung des Verfahrens wird die Struktur von Zerstäubernebeln und die Tropfenbewegung besprochen und ein Weg zur Berechnung des Trocknungsverlaufes gezeigt.
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    Chemie Ingenieur Technik - CIT 21 (1949), S. 139-142 
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    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: Fehler in der Bemessung von Vakuumleitungen führen im chemischen Betrieb nicht nur zu einer Erhöhung der laufenden Kosten, sondern können auch Anlaß zu Qualitäts minderungen geben, da dann bei höheren Drucken und damit bei unzulässig hohen Temperaturen gearbeitet werden muß. Es werden daher im folgenden Richtlinien für die Bemessung von Vakuumleitungen aufgestellt und an H and eines Nomogrammes erläutert.
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    Notes: Die härtbaren und thermoplastischen Kunststoffe sowie die synthetischen Kautschuksorten werden wegen ihrer Korrosionsbeständigkeit an zahlreichen Stellen des chemischen Apparatebaues verwendet, darüber hinaus auch in der Textilchemie, Nahrungsmittelindustrie und Metallurgie als Baumaterial oder als Hilfsmittel für Geräte, Anlagen und Apparate.
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    Notes: Die Bedeutung, die das Pektin für die Lebensmittelversorgung und für andere zahlreiche Industriezweige erlangt hat, gibt Veranlassung dazu die verschiedenen Methoden aufzuzeigen, die zu seiner Gewinnung führen, und kurz auf die Wege hinzuweisen die in der Weiterentwicklung des bisher Erreichten von der neueren Forschung beschritten werden.
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    Chemie Ingenieur Technik - CIT 21 (1949), S. 153-153 
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    Chemie Ingenieur Technik - CIT 21 (1949), S. 148-153 
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