ALBERT

Description: Igneous rocks were recovered from three sites on Hess Rise during Deep Sea Drilling Project Leg 62: altered basalt at Site 464, at the northern end of Hess Rise; and altered trachyte from Site 465, and rounded basalt pebbles in upper Albian to middle Miocene sediments from Site 466, both at the southern end of Hess Rise. Major-, minor-, and trace-element data for basalt from Hole 464 are consistent with these rocks being transitional tholeiites that have undergone low-temperature alteration by reaction with sea water. Trachyte from Hole 465A exhibits as many as three generations of plagioclase along with potash feldspar that are flow aligned in groundmasses alterted to smectites and random mixed-layer clays. Textural evidence indicates that these rocks were eruped subaerially. Chemical data show a range of values when plotted on two- and three-component variation diagrams. The observed variations may result in part from differentiation, but they also reflect the high degree of alteration. Several oxides and elements show strong correlation with H2O+: K2O, SiO2, Rb and Lu decrease and MgO increases with increasing H2O+. These trends, except for that of Lu, are consistent with experimentally determined changes in chemistry that accompany alteration. The trend for Lu has not been previously reported; it may result from a more-intense alteration of the HREE-rich mafic minerals than of the LREE-rich feldspars. Despite their alteration, the trachytes compare favorably with alkalic differentiates from oceanic islands. We interpret Hess Rise as a volcanic platform formed by eruption of off-ridge volcanic rocks onto MORB oceanic crust during the Aptian and Albian stages, after the basement had migrated away from the spreading center. By analogy with present oceanic islands, we propose that early tholeiitic basalts were followed by alkalic basalts and their differentiation products (trachytes), producing a volcanic archipelago of islands and seamounts. Subsequent tectonism and subsidence led to the present state of Hess Rise.

Description: Atomic-absorption spectrophotometry and instrumental neutron activation analysis were used to determine concentrations of SiO2, Al2O3, FeOt, MgO, CaO, Na2O, K2O, MnO, La, Ce, Sm, Eu, Tb, Yb, Lu, Sc, Co, Cr, Th, Hf, and Ta for 14 basalt samples from the lower portion of Hole 462A in the Nauru Basin. The basalts are similar to normal midocean ridge basalt (MORB) for the elements analyzed, and light rare-earth elements (LREE) are depleted relative to heavy rare-earth elements (HREE). Two samples are extensively altered to smectites and show significant reductions in Al2O3, CaO, MnO, Na2O, REE, Sc, Co, and Hf and gains in MgO and FeOt relative to unaltered samples. The increase in MgO and decrease in CaO indicate that alteration was caused by hydrothermal solutions.

Description: This chapter was previously intended to trace volcanic episodes through the Neogene and Pleistocene geological history recorded in the sedimentary sections drilled on the Emperor seamounts. Drilling disturbance, poor core recovery, and incomplete stratigraphic sections recovered from the seamounts have frustrated that plan, however. Moreover, the Leg 55 sedimentologists found in their smear-slide studies that transported island-arc tephra is scarce in the sediments, if present at all. So we have restricted our objective to description of the volcaniclastic admixture in sediments, as determined by mineralogical and geochemical data. We studied geochemistry of bulk samples (see Murdmaa et al., 1980), coarse-fraction mineralogy, and additional smear slides. The results obtained, however, do not tell much more about the volcaniclastic matter than did shipboard core descriptions.

Description: At Deep Sea Drilling Project (DSDP) Site 462, from mudline to 447 meters below the sea floor, Cenozoic nannofossil oozes and chalks have acoustic anisotropies such that horizontal sonic velocities are 0 to 2.5% faster than those in the vertical direction. In laminated chalk, anisotropy of 5% is typical, and in limestones, radiolarian oozes, porcellanites, and cherts, the anisotropies range from 4 to 13%. Middle Maestrichtian volcaniclastics from 447 meters to 560 meters below the sea floor have an acoustic anisotropy of 2 to 32%; 4 to 13% is typical. Basalt flows and sills occur between 560 meters and 1068 meters, and have no apparent anisotropy, but minor interbedded volcaniclastics have anisotropies from 0 to 20% (5% is typical). These volcaniclastics frequently have very small anisotropies, however, compared with the volcaniclastic sequence above the basalt section. Data in cross-plots of the laboratory-measured compressional sound velocity versus wet-bulk density, wet-water content, and porosity of sediments and sedimentary rock typically lie between the equations derived by Wyllie et al. (1956) and Wood (1941); the Wyllie et al. (1956) equation has a fair fit with similar basalt velocity cross-plots. Crossplots of thermal conductivity and sound velocity indicate only a fair correlation. Cross-plots of thermal conductivity versus porosity, wet-water content, and wet-bulk density correlate well with equations derived by Maxwell (1904), Ratcliff (1960), Parasnis (1960), and Bullard and Day (1961). Electrical formation factor versus porosity for sediments and sedimentary rock agrees with the Archie (1942) equation, with m values of 2.6; for basalt, an m of about 2.1 is typical. Basalt pore-water resistivities do not appear to be greatly different from sea water. Formation factors are greater than those derived from equations in Maxwell (1904), Winsauer et al. (1952), Boyce (1968), and Kermabon et al. (1969). An "apparent interstitial water resistivity" (Rwa) curve was derived from the density and induction logs. This Rwa curve indicated an anomaly, at 393.5 to 396.5 meters, which could be interpreted as (1) 76% hydrocarbons, (2) relatively fresh pore water (1.8 per mil salinity), or (3) low-grain-density (2.2 g/cm**3) semi-lithified porcellanite-chert. Porcellanite-chert is the most plausible interpretation. In situ temperatures measured by the Uyeda temperature probe were about 2 to 5°C (50%) higher than the equilibrium temperature (Lachenbruch and Brewer, 1959) extrapolated from two Gearhart-Owen continuous temperature logs; this discrepancy probably arises because the hole was washed out in this depth interval, so these extrapolated temperatures are probably not reliable. If one ignores all precautions as to temperature artifacts, then the equilibrium temperatures of the Gearhart-Owen temperature logs suggest that hydrothermal circulation is occurring in at least the upper 40 meters of the basalt section and heat is transferred by convection and not conduction. Hydrothermal circulation is probably not indicated, however, and the temperature anomalies probably result from excessive artificial cooling of the fractured basalt zones by circulation of water during drilling.

Description: The stratigraphic position of the glacially transported 'Scholle' (large-size erratic block) at Schobüll near Husum (Schleswig-Holstein) is now considered to be Devonian rather than 'Rotliegendes'. The 'Scholle', consisting of red clay and dolomite, is overlain by red-colored till without any flint but with up to 90% carbonate clasts (containing 15% dolomite), which indicates an eastern Baltic origin. The relationship of the 'Scholle' with the glacial till also points to an eastern Baltic origin for it, with up to 1 000 km transport distance.

Description: Ferromanganese nodules in the deep-sea and in freshwater lakes usually accrete layers rich in manganese oxides alternating with layers rich in iron oxides. The mechanism producing these alternating layers is unknown; indeed, the mechanism producing the nodules themselves is unknown. In Oneida Lake, New York, precipitants from the lake water and the surfaces of nodules at the sediment-water interface are enriched in Mn, whereas nodules buried in lake sediments have surface layers enriched in Fe. It is hypothesized here, using field and laboratory evidence, that reduction and mobilization of Mn from the nodule surface during periods of anoxic sediment cover produce the high Fe layers observed in the nodules.

Description: Manganese nodules made of radiating rods of well crystallized birnessite were sampled at 8 degree 481.2'N, 103 degree 53.8W, 1875 m below sea level by a dredge that also collected hyaloclastite and basaltic talus. The nodule field is on the floor of a caldera within a young tholeiitic seamount and was discovered and photographed during a deep-two survey. It is interpreted as a brecciated hydrothermal deposit, crystallized from an amorphous manganese oxide precipitate that formed when seawater-based hydrothermal fluids mixed with oxidized seawater. The nodules and surrounding igneous rocks have subsequently been encrusted with hydrogenous ferromanganese oxides.

Description: The successful drilling on Legs 51, 52, and 53 created a rare opportunity to investigate the long-term effects of seawater-rock interactions on the mineralogy and chemistry of basalts erupted on the sea floor. The purpose of this paper is to describe the weathering of the basalts in terms of the changes in their mineralogy and chemistry, and to compare the weathering observed in Hole 418A with that in the upper parts of Hole 417A.

Description: Two distinct sedimentary facies produced by sea-floor hydrothermal activity were cored during Deep Sea Drilling Project Leg 54. The first is equivalent to the typical basal iron- and manganese-rich, clayey mud recovered at many DSDP sites. It was sampled as a dispersed component throughout the cores taken in small sediment ponds in several sites within 120 km of the East Pacific Rise at 9°N. We infer that this component was originally deposited as iron hydroxides dispersed from high-temperature vents over the axial magma chamber of the East Pacific Rise. In the sediments, the iron hydroxides have reacted diagenetically with siliceous microfossil tests and detrital clays to form K- and Fe-rich clays with variable SiO2/Fe2O3 and Fe2O3/Al2O3, ratios.

Description: The cores and dredges described at this site were taken on the ANTIPROD II cruise from 21 February to 9 April 1980 by the Muséum National d'Histoire Naturelle from the R/V Marion Dufresne. A total of 10 cores were recovered and are available at MNHN for sampling and study.

Description: This report is Volume 3 of Descriptions of WHOI rock dredge samples. This series represents a major effort to catalog the rock dredge samples in the WHOI Sea Floor samples collection, and to disseminate this information throughout the scientific community. Volume 3 contains sample descriptions and station data for the dredge stations from five cruises during the period September 1978 through December 1980. The material in this and subsequent volumes of rock descriptions was largely prepared onboard ship by the participating scientists. Volume 3 was printed prior to volumes 1 and 2 because of the excellent documentation of the samples represented in this volume.

Description: The text studies the deep-sea red clays in the East-Central Pacific ocean (Tahiti-Touamotou Archipelago), their authigenic formation, transport and diagenetic character in particular through their composition in REE.

Description: The minor-element composition of concentric layers within a single ferromanganese nodule from the eastern North Pacific exhibits strong correlations with Fe and Mn contents but appears to be independent of pronounced mineralogic variations. On the basis of these correlations, the elemental composition of individual layers apparently is controlled by the relative contribution of two sources: seawater, and interstitial water of associated sediment. In contrast, the mineralogy of the nodule, consisting of birnessite in the outer few layers and todorokite in the inner layers, is considered to be a function of nodule diagenesis.

Description: Compositional data for coexisting manganese nodules, micronodules, sediments and pore waters from five areas in the equatorial and S.W. Pacific have been obtained. This represents the largest study of its type ever undertaken to establish the distribution of elements between the various phases within the sediment column. The composition of manganese nodules, micronodules and sediments (on a carbonate-free basis) shows marked differences between the equatorial high productivity zone and the low productivity region of the S.W. Pacific. In the case of the nodules, th is reflects an increased supply of transition elements (notably Ni, Cu and Zn) to the nodules as a result of the in situ dissolution of siliceous tests within the sediment column in the equatorial Pacific high productivity zone. Micronodules display similar, but somewhat different, compositions to those of the associated nodules in each area. Micronodule composition is therefore influenced by the same basic factors that control nodule composition, but is modified by dissolution of the micronodules in situ within the sediment column. Locally, as in the area immediately south of the Marquesas Fracture Zone, the micronodule population is contaminated by small, angular volcanic rock fragments; this leads to apparently anomalous micronodule compositions. Micronodules appear to be a transient feature in the sediment column, especially in the equatorial Pacific. Dissolution of micronodules in the sediment column therefore represents an important source of elements for the growth of manganese nodules in the equatorial Pacific. Sediment composition is markedly influenced by the carbonate content. On a carbonate-free basis, the sediments from the equatorial high productivity zone are quite distinct in composition from those in the S.W. Pacific. This reflects differences in the lithology of the sediments. In the Aitutaki Passage, the local influence of volcanoclastic material in sediment composition has been established. The major cations and anions in pore waters measured here show no major differences between equatorial and S.W. Pacific sediments. Silica is, however, higher in equatorial Pacific pore waters reflecting the dissolution of siliceous tests in these sediments.

Description: New data for the direct measurement of the isotopic composition of neodymium in Atlantic Ocean seawater are compared with previous measurements of Pacific Ocean seawater and ferromanganese sediments from major ocean basins. Data for Atlantic seawater are in excellent agreement with Nd isotopic measurements made on Atlantic ferromanganese sediments and are distinctly different from the observed compositions of Pacific samples. These results clearly demonstrate the existence of distinctive differences in the isotopic composition of Nd in the waters of the major ocean basins and are characteristic of the ocean basin sampled. The average eNd(0) values for the major oceans as determined by data from seawater and ferromanganese sediments are as follows: Atlantic Ocean, eNd(0) = -12 ± 2; Indian Ocean, eNd(0) = -8 ± 2; Pacific Ocean, eNd(0) = -3 ± 2. These values are considerably less than eNd(0) value sources with oceanic mantle affinities indicating that the REE in the oceans are dominated by continental sources. The difference in the absolute abundance of 143Nd between the Pacific and Atlantic Oceans corresponds to ab. 10**6 atoms 143Nd per gram of seawater. The correspondence between the 143Nd/144Nd in seawater and in the associated sediments suggests the possible application of this approach to paleo-oceanography. Distinctive differences in eNd(0) values are observed in the Atlantic Ocean between deep-ocean water associated with North Atlantic Deep Water and near-surface water. This suggests that North Atlantic Deep Water may be relatively well mixed with respect to Nd isotopic composition whereas near-surface water may be quite heterogeneous, reflecting different sources for surface waters relative to deep water. This suggests that it may be possible to distinguish the sources of water masses within an ocean basin on the basis of Nd isotopic composition. The Nd isotopic variations in seawater are used to relate the residence time of Nd and mixing rates between the oceans.

Description: Initial data on the hydrogen-isotopic compositions in hydrous Mn minerals from various occurrences fall in a wide range from -298 to -84 per mil, relative to SMOW. DeltaD-values of todorokite and cryptomelane from Tertiary deposits show -89 and -150 per mil. 10 Angström-manganite and Delta-MnO2 from deep-sea nodules have relatively restricted DeltaD-values ranging from -96 to -84 per mil. The DeltaD-values for manganese bog ores from recent hot springs show almost -105 per mil. It is recognized that the isotopic values obtained for the deep-sea nodules and recent bog ores are slightly different ranged. Manganite and groutite are unique in their hydrogen-isotopic compositions, having the most depleted DeltaD-values ranging from -298 to -236 per mil. MnO(OH) minerals are more deuterium-depleted hydrous minerals than any other hydrothermal minerals from various ore deposits. Hydrogen-isotope fractionation factors between manganite and water were experimentally determined to be 0.7894, 0.7958 and 0.8078 at 150°, 200° and 250°C, respectively. the present experimental results indicate that if manganites were formed at temperatures below 250°C, under isotopic equilibrium conditions, most of the manganite mineralization in the Tertiary manganese deposits must have precipitated from meteoric hydrothermal solutions.

Description: This report is Volume 1 in the series of reports entitled "Descriptions of W.H.O.I. rock dredge samples". This series represents a major effort to catalog and prepare initial descriptions for all rock dredge samples in the W.H.O.I. Sea Floor Samples Collection, and to distribute this information throughout the scientific community. Volume 1 contains sample descriptions from approximately 382 dredging stations executed during the period 1960 through 1977. It also represents a digitized listing of all dredge station data for the entire W.H.O.I. Dredge Collection through 1980. This data is sorted by Marsden Square and can serve as a regional index for all rock descriptions included in Volumes 1-3.

Description: The JOIDES Paleoenvironment Panel had noted that the Neogene section had only been spot-cored on previous legs in the Western Atlantic (Legs 1, 2, 4, 11, and 43). The Panel accordingly requested that the complete section be recovered on Legs 51 through 53 in order to examine the transition from siliceous, Pacific-type Eocene sedimentation to non-siliceous sedimentation resulting from the gradual emergence of the Central American isthmus. It was also detremined to examine in detail the thick Cretaceous-Tertiary section overlying the basement.

Description: Thirty selected samples of pelagic and hydrothermal sediments retrieved on DSDP Leg 54 were chemically analyzed for major and minor oxide concentrations. Additionally, 11 samples of lithified carbonate sediments were petrologically studied. The pelagic sediments, which are described as foraminiferal biomicrite, were found to be generally higher in Fe and Zn, similar in Co content, and lower in Cu content, than the average Pacific pelagic sediments. Mineralogically, these samples are composed principally of calcite with minor amounts of quartz and clays. Hydrothermal sediments from Site 424 are divisible into three classes: (1) silica-rich, iron-poor smectites; (2) silica-poor, iron-rich mixtures of smectites and oxides; and (3) silica-poor, iron-rich materials, comprising mainly amorphous manganese oxides. Thus, two chemically distinct hydrothermal phases are recognizable: Class 1, iron-rich smectites, and Class 3, Mn-rich oxides and oxyhydroxides. Dolomite and pyrite were identified in X-ray diffraction studies of samples from Site 427.

Description: A near-bottom survey of a 24-km length of the East Pacific Rise (EPR) crest near the Leg 54 drill sites has established that the axial ridge is a 12- to 15-km-wide lava plateau, bounded by steep 300-meter-high slopes that in places are large outward-facing fault scarps. The plateau is bisected asymmetrically by a 1- to 2-km-wide crestal rift zone, with summit grabens, pillow walls, and axial peaks, which is the locus of dike injection and fissure eruption. About 900 sets of bottom photos of this rift zone and adjacent parts of the plateau show that the upper oceanic crust is composed of several different types of pillow and sheet lava. Sheet lava is more abundant at this rise crest than on slow-spreading ridges or on some other fastspreading rises. Beyond 2 km from the axis, most of the plateau has a patchy veneer of sediment, and its surface is increasingly broken by extensional faults and fissures. At the plateau's margins, secondary volcanism builds subcircular peaks and partly buries the fault scarps formed on the plateau and at its boundaries. Another deep-tow survey of a patch of young abyssal hills 20 to 30 km east of the spreading axis mapped a highly lineated terrain of inactive horsts and grabens. They were created by extension on inward- and outwardfacing normal faults, in a zone 12 to 20 km from the axis. Sediments sampled on the rise crest and flanks are mixtures of calcareous ooze and metalliferous precipitates, and they have been redistributed by southerly currents with average velocities of 9 cm/s.

Description: A submersible dive on a turbidite-covered spreading axis in Guaymas Basin photographed and sampled extensive terraces and ledges of talc. The rock contains siliceous microfossils, smectite, and euhedral pyrrhotite as well as rather pure iron-rich talc. Sulfur and oxygen isotopes indicate precipitation around a hydrothermal vent, at about 280°C.

Description: Leg 55 was conceived as part of the decade-long experiment to test the kinematic hot-spot hypothesis and several of its more imporant corollaries for the origin of the Hawaiian-Emperor chain. Also of particular importance was the question of whether the Hawaiian hot spot has remained fixed in the mantle. The specific primary objectives of Leg 55, were to determine (1) whether the known increase in the age of the volcanoes on the Hawaiian chain with distance from Kilauea continues northward along the Emperor Seamounts; (2) whether the lavas of the Emperor volcanoes are of the same chemical composition and were erupted in the same sequence as those of Hawaiian volcanoes; (3) the latitude of formation of Suiko Seamount as a test of hot-spot fixity; and (4) whether the Emperor Seamounts were once islands and, if so, to determine their post-volcanic and subsidence history.

Description: Aragonite mineralization was observed in serpentinized peridotites from the Romanche and Vema Fracture Zones in the Atlantic and the Owen Fracture Zone in the Indian Ocean, either in veins or as radial aggregates in cavities within the serpentinites. Evidence of incipient dissolution of the aragonite crystals was observed in one case. The aragonites tend to have lower Mg content (〈 0.03%) and higher Sr content (〉 0.95%) relative to other marine aragonites. Their 18O16O, 13C12C and 87Sr86Sr isotopic ratios suggest the aragonite was deposited at ocean floor temperatures from solutions derived from sea water circulating in fissures and fractures within the ultramafic rocks. The 18O16O ratios of the serpentines indicate serpentinization occurred at higher temperatures, probably deeper in the crust. Low-T reactions between circulating seawater and Mg-silicates (primarily serpentine and pyroxenes) caused high pH and enrichment of Mg and Ca in the solution, conditions favoring carbonate precipitation. Aragonite was formed rather than calcite presumably because the high Mg2+ concentration in the solution inhibited calcite precipitation. The high Sr content of the aragonites is probably related, at least in part, to their low temperature of formation. Opaque mineral grains containing over 8% NiO and over 40% MnO were observed concentrated along the margins of some of the aragonite veins, suggesting that Ni is one of the elements mobilized during reactions between ultramafic rocks and circulating seawater.

Description: A submersible study has been conducted in February - March 1978 at the axis of the East Pacific Rise near 21°N. The expedition CYAMEX, the first submersible program to be conducted on the East Pacific Rise, is part of the French-American-Mexican project RITA (Rivera - Tamayo), a 3-year study devoted to detailed geological and geophysical investigations of the East Pacific Rise Crest. On the basis of the 15 dives made by CYANA in the axial area of the Rise, a morphological and tectonic zonation can be established for this moderately-fast spreading center. A narrow, 0.6 to 1.2 km wide zone of extrusion (zone 1), dominated by young lava flows, is flanked by a highly fissured and faulted zone of extension (zone 2) with a width of 1 to 2 km. Further out, zone 3 is dominated by outward tilted blocks bounded by inward-facing fault scarps. Active or recent faults extend up to 12 km from the axis of extrusion of the East Pacific Rise. This represents the first determination from direct field evidence of the width of active tectonism associated with an accreting plate boundary. Massive sulfide deposits, made principally of zinc, copper and iron, were found close to the axis of the Rise. Other signs of the intense hydrothermal activity included the discovery of benthic fauna of giant size similar to that found at the axis of the Galapagos Rift. We emphasize the cyclic character of the volcanicity. The main characteristics of the geology of this segment of the East Pacific Rise can be explained by the thermal structure at depth below this moderately-fast spreading center. The geological observations are compatible with the existence of a shallow magma reservoir centered at the axis of the Rise with a half-width of the order of 10 km.

Description: The JOIDES Active Margin Panel for Leg 58 decided that the drilling would occur in the north Philippine Sea, namely, the Shikoku Basin, the Daito Ridge and Basin province. The Shikoku Basin sites were selected to solve several problems concerning back-arc basins formed by ocean-floor spreading. The main objectives were: (1) to determine the age of the oldest sediment, so as to calibrate magnetic-anomaly ages and to provide a test for various spreading models suggested for the basin; (2) to investigate the mineralogy, petrology, and chemistry of basalt samples recovered by drilling, and to compare there basalts with those of midocean ridges, so as to understand the nature and source of magmatic materials in these basins; (3) to determine the distribution of sediment types in time, and to relate that distribution to the tectonic history of the basin.

Description: Of numerous island-arc systems in the western Pacific, the Mariana arc-trench system and the basins and submerged ridges lying west of them in the Philippine Sea seemed to be best suited to answer questions regarding arc-trench and back-arc basin formation. Three years of planning by the JOIDES Active Margin Panel, Ocean Crust Panel, and Planning Committee resulted in a proposed transect of drill sites aligned more or less along the 18th parallel. This South Philippine Sea transect was designed to investigate each major basin and ridge between the central part of the West Philippine Sea and the Mariana Trench and the Pacific Ocean plate immediately to the east.

Description: The Japan Trench area was identified a favorable place for studying convergent margins during the initial deliberations of the IPOD Active Margins Panel. The Leg 56-57 DSDP drill sampling along the Japan Trench transect has indicated that material tectonically accreted during the present convergent episode is limited to a surprisingly small zone. The limits seem well established by the seaward extent of crust with continental thickness and lithologies and by the age and thickness of a terrigenous slope apron covering the presumed but probably unsampled accreted oceanic material.

Description: 40Ar/39Ar incremental heating experiments on three samples dredged from Jingu Seamount indicate that Jingu is 55.4 ± 0.9 m.y. old — older than the Hawaiian-Emperor bend and younger than the two dated Emperor Seamounts to the north. Major-oxide chemistry and petrography show that the samples are similar to hawaiites and mugearites from the Hawaiian Islands. By analogy with Hawaiian alkalic volcanic rocks, groundmass plagioclase compositions (An40-47) indicate that the three Jingu samples are probably mugearites. These results suggest that Jingu is a Hawaiian-type volcano and that the Emperor volcanoes become progressively older from south to north, as predicted by the hot-spot hypothesis.

Description: The goal of Site 462 was to study the paleontologic, sedimentary, petrologic, tectonic, and magnetic histories of that area through Recent to Late Jurassic time by drilling a deep re-entry site into the Nauru Basin west of the Ralik Chain of the Marshall Islands. This area formed at a fast-spreading Pacific Plate boundary 145 to 155 m.y. ago, in the Late Jurassic. Cores from this area allow to better understand the biostratigraphic evolution and sedimentary processes in a Mesozoic open-ocean environment, the petrologic nature of fast-spreading oceanic crust, the tectonic history of the Late Jurassic Pacific Plate, and the nature of the Jurassic magnetic quiet zone.

Description: Forty basaltic rocks collected by submersible during the Cyamex expedition (1978) on the East PacifIc Rise at 21°N, a moderately fast spreading segment (6 cm/year opening rate) of the mid-ocean ridge, consist of angular pillow fragments and glass buds, sheet-flow slabs and samples of columnar pillars standing in collapsed fossillava pools. Most of the rocks are from the crestal are a of the Rise. The collection shows a striking petrographic homogeneity wh en compared with the range of basalts found on other segments of midocean ridges: olivine-phyric, or highly plagioclase-phyric rocks, so common in the slowspreading Famous are a in the Atlantic, are absent. All samples are typical lowpotassium oceanic tholeiites with a limited fractionation trend. Pillow-lavas, thin and thick sheet-flows cannot be distinguished by their major element compositions, as in the Galapagos rift which has the same spreading rate as the EPR at 21°N. Further, ferrobasalts have been described from the Galapagos rift, but do not appear in the Cyamex rocks. In the Cyamex area, olivine and plagioclase are the main silicate phases, and clinopyroxene is absent. In the pillows and sheet-flow samples, four generations of olivine and plagioclase crystals are distinguished. Samples from the fossillava pools are aphyric. The corresponding magma batches are presumed to have migrated rapidly through the magma chamber, and to have been extruded in large volumes, possibly during episodes ofhigh instantaneous opening rate. Fe-Ni and Fe-Cu-rich sulphide phases are common in an lava types as massive globules scatterred through the glass, or as microglobules decorating the walls of empty vesicles. Palagonite and Fe-Mn oxide thicknesses across the strike of the Rise indicate relative ages compatible with successive extrusions at the Rise axis.

Description: The four sites drilled during Leg 62 were needed to establish better regional coverage of the North Pacific Ocean. Although paleoenvironments were to be stressed on Leg 62, studies of igneous rocks from acoustic basement were planned, to determine ages, petrogenesis, alteration effects, rock magnetism, and Paleomagnetism of old parts of the Pacific crust. These studies were emphasized in order to establish the early history of oceanic plateaus and whether they are the result of midocean-ridge or intraplate volcanism.

Description: A primary objective of Leg 63 was to investigate the fluctuations of this eastern boundary current along a north-south transect off the Gulf of California. This information would aid in biostratigraphically correlating open-ocean planktonic zones with local California zonations. Spanning the last 30 m.y., the complicated tectonic history of the continental margin off California and Baja California comprises changes from a subduction zone to a transform boundary and then to an inactive margin. A second objective of Leg 63 was to define and clarify this history using information on sedimentation, unconformities, basement ages, and paleomagnetic reconstructions gained from drilling, in conjunction with geophysical data and pre-existing bottom samples.

Description: Undamaged deep-sea manganese nodules were retrieved from a box core from the central North Pacific and quickly preserved in formaldehyde solution. Light and scanning electron microscope studies of the nodule surface reveal the presence of a variety of fragile filamentous and coccoid bacterial morphotypes, associated with an organic film that covers the botryoid surface.

Description: Cores, submarine photography and dredges described in this report were taken during the R/V Melville Cruise Vulcan-1 in September 1980 by the School of Oceanography, Oregon State University. This cruise was part of the International Decade of Ocean Exploration (IDOE) Manganese Nodule Program (MANOP). It surveyed MANOP Sites H and M in the Pacific Ocean.

Description: The oxide portion of marine manganese nodules deserves intensive study because it probably reflects directly the conditions under which nodules form in the Bea. A better understanding of the nature of the oxides in nodules should therefore throw new light on basic problems of nodule origin.

Description: Methods of estimating manganese nodule grade and concentration were investigated using bottom photographs from a well-explored east-central Pacific manganese nodule deposit.

Description: Determination of radium, thorium, uranium isotopes, and 210Pb in sediments and sediment pore waters from North Equatorial Pacific deep-sea clay-silicous oozes shows that the radium and uranium isotopes are mobile in the pore water. The concentration-depth profiles of radium can be understood in terms of a diagenetic model which takes into account mixing of sediment particles by bioturbation, molecular diffusion in the pore water, adsorption onto particle surfaces, as well as radioactive production and decay. The 234U/238U activity ratios in several samples are higher than the seawater value, indicating some enrichment of 234U in the pore water. However, the absolute concentrations of 238U and 234U are 25% lower than those in seawater, suggesting that the sediments form a sink for uranium isotopes. 210Pb is present in the pore water at concentrations approx. 20% that of 226Ra. The origin of 210Pb in the pore water is uncertain and could be due either to its in situ mobilization in the sediments or subsequent production in the laboratory from the decay of 222Rn. 230Th is present in measurable concentrations in the pore waters, but its distribution does not show any systematic trend with depth or other parameters. The most likely source of 230/Th appears to be minute amounts of sediment particles collected in the pore waters during the squeezing operation.

Description: We report here that a manganese nodule from the Central Pacific manganese nodule province has been dated by fossil diatoms found in mud scraped from near the nodule's centre. The nodule was taken at DOMES Site B from Core B55-56 at 11°50.3'N and 137°28.2'W in a water depth of 4,892 m. It was resting on the sediment surface, with about 1.5 cm of the nodule bottom (of a total nodule height of 4.2 cm) buried in the mud. The top surface of the nodule was covered with a smooth manganese coating, but the bottom had a very rough, crusty texture. It was found that recent mud had leaked in through cracks in the nodule bottom, but that there were no pre-Pleistocene diatoms in this material. The date obtained was compared with the growth rate determined by the 230Th excess method and found to be in reasonable agreement. This study adds to the work of Harada1,2 on the biostratigraphy (mainly coccoliths) of manganese nodules.

Description: The unusual petrological diversity of abyssal lavas erupted along some segments of the Galapagos spreading center is a direct consequence of the propagation (elongation) of these segments into older oceanic crust. With increasing distance behind propagating rift tips, relatively unfractionated MORB erupted close to the tips are joined first by FeTi basalts (bimodal assemblage) and then by a wide range of basaltic and siliceous lavas. Further behind propagating rift tips, this broad range diminishes again, approaching the narrow compositional range of adjacent normal ridge segments. These compositional variations reflect the evolution of the subaxial magmatic system beneath the newly forming spreading center as it propagates through a pre-existing plate. We envisage this evolution as proceeding from small, isolated, ephemeral magma chambers through increasing numbers of larger, increasingly interconnected chambers to the steady-state buffered system of a normal ridge. Throughout this evolution, magma supply rates gradually increase and cooling rates of crustal magma bodies decrease. High degrees of crystal fractionation are favored only when a delicate balance between cooling rate and resupply rate of primitive magma is achieved. At other propagating and non-propagating ridge-transform intersections the degree to which the balance is achieved and the length of ridge over which it evolves control the distribution of fractionated lavas. These effects may be evaluated provided a number of tectonic variables including transform length, spreading and propagation rates are taken into account.

Description: The southernmost part of the Sohm Abyssal Plain in the Northwest Atlantic Basin is geographically distal with respect to the major source of Quaternary terrigenous material transported from the Canadian Maritime Provinces. An assessment of the proportion of more locally introduced sediment relative to that derived from distal sources is based largely on size and compositional analyses of Quaternary piston core samples. These data are supplemented by radiocarbon dating of selected core samples, bottom photographs, conductivity-temperature-depth profiles, and seismic records. The premises of the study are that (a) locally derived sediment should be most abundant near high-relief bathymetric features such as seamounts and abyssal hills, and (b) such material should contain enhanced proportions of reworked volcanic debris and alteration products. Core analyses reveal that the amounts of these are directly related to proximity of volcanic ocean-bottom features, and that a significant, although not total, amount of such volcanic materials recovered from cores are derived from submarine weathering of basalt. Associated with this assemblage are nannofossils, dating from the Quaternary to the Upper Cretaceous, reworked from older strata. This increased proportion of volcanic and related products and reworked faunas near seamounts and basement rises strongly implies that such topographic features continue to serve as major source terrains. Locally derived volcanic materials, however, are usually disseminated and masked on the Sohm Abyssal Plain, particularly in sectors receiving large amounts of terrigenous turbidites and biogenic suspensates, and/or undergoing reworking by bottom currents. We propose that the volcanic fraction can serve as a useful index, or "yardstick," to interpret the role of locally derived material in abyssal plain sedimentation. A sedimentation model is developed to illustrate the premise that as access to land-derived sources diminishes, the proportion of terrigenous components is reduced while pelagic and volcanic fractions are enhanced. Thus, sediment accumulating in abyssal plains almost totally isolated from terrigenous sources would comprise significant amounts of pelagic (including wind-blown) and volcanic components.

Description: Nine nodules collected from throughout the deep North Pacific were analyzed for their mineralogy and major-element composition before and after leaching with Chester-Hughes solution. Data indicate that the mineral phillipsite accounts for the major part (〉 75%) of the aluminosilicate fraction of all nodules. It is suggested that formation of phillipsite takes place on growing nodule surfaces coupled with the oxidation of absorbed manganous ion. All the nodules could be described as ternary mixtures of amorphous iron fraction (Fe-Ti-P), manganese oxide fraction (Mn-Mg Cu-Ni), and phillipsite fraction (Al-Si-K-Na), these fractions accounting for 96% of the variability of the chemical composition.

Description: An area of about 22,000 km² on the northern Blake Plateau, off the coast of South Carolina, contains an estimated 2 billion metric tons of phosphorite concretions, and about 1.2 billion metric tons of mixed ferromanganese-phosphorite pavement. Other offshore phosphorites occur between the Blake Plateau and known continental deposits, buried under variable thicknesses of sediments. The phosphorite resembles other marine phosphorites in composition, consisting primarily of carbonate-fluorapatite, some calcite, minor quartz and other minerals. The apatite is optically pseudo-isotropic and contains about 6% [CO3]**2- replacing [PO4]**3- in its structure. JOIDES drillings and other evidence show that the phosphorite is a lag deposit derived from Miocene strata correlatable with phosphatic Middle Tertiary sediments on the continent. It has undergone variable cycles of erosion, reworking, partial dissolution and reprecipitation. Its present form varies from phosphatized carbonate debris, loose pellets, and pebbles, to continuous pavements, plates, and conglomeratic boulders weighing hundreds of kilograms. No primary phosphatization is currently taking place on the Blake Plateau. The primary phosphate-depositing environment involved reducing conditions and required at least temporary absence of the powerful Gulf Stream current that now sweeps the bottom of the Blake Plateau and has eroded away the bulk of the Hawthorne-equivalent sediments with which the phosphorites were once associated.

Description: Crusts composed of nontronite and ferromanganese oxides were recovered from Explorer Ridge, a spreading ridge segment in the northeastern Pacific Ocean located off the west coast of Canada. The chemical and mineralogical composition of the crusts closely resembles that of the mound-like hydrothermal deposits recently discovered at the FAMOUS site on the Mid-Atlantic Ridge and on the Galapagos spreading centre. Compositional anomalies suggest that the crusts are precipitates of hydrothermal vent solutions which were ejected discontinuously and subsequently mixed with seawater.

Description: Submersible exploration on the eastern Pacific Ridge near 21 ° N has revealed an active hydrothermal system. It is manifested by the emission in the marine environment of hot and Highly mineralized fluids (370 ° C maximum). These fluids precipitate on contact with seawater and deposits of massive sulphides are built at the outlet of their sources. The mineralogical and geochemical study of the products associated with the emissions of hot fluids provides an initial evaluation of this type of deposit and leads to a comparison between the hydrothermalism responsible for the formation of sulphides and the hydrothermalism responsible for the formation of metal rich crusts formed of iron smectites and manganese oxides. This study is carried out with conventional mineralogical and geochemical investigations (optical and electronic microscopy, X-ray diffraction, X-ray fluorescence spectrometry, electron microprobe, neutron activation and mass spectrometry).

Description: Methods of estimating manganese nodule grade and concentration were investigated using data from a well-explored east-central Pacific manganese nodule deposit. Bulk chemical analyses of 159 nodules recovered from 21 box cores show that the range in metal values between nodules from a single box core is commonly small but may be greater than the range in mean metal content of nodules from widely separated box cores. The metal exhibiting the greatest variability in the 21 box cores is Zn, followed in decreasing order by Cu, Mn, Co, Ni, and Fe. Approximately half of the box cores required analysis of 11 nodules or more to predict metal content within plus or minus 10 percent of the mean value.

Description: A model that predicts the flux of 222Rn out of deep-sea sediment is presented. The radon is ultimately generated by 230Th which is stripped from the overlying water into the sediment. It is shown that the continental contribution of ionium is not significant, and that at low sedimentation rates, biological mixing and erosional processes strongly affect the surface concentration of the ionium. Two cores from areas of slow sediment accumulation, one from a manganese nodule region of the central Pacific and one from the Rio Grande Rise in the Atlantic were analyzed at closely spaced intervals for 230Th, 226Ra, and 210Pb. The Pacific core displayed evidence of biological mixing down to 12 cm and had a sedimentation rate of only 0.04 cm/kyr. The Atlantic core seemed to be mixed to 8 cm and had a sedimentation rate of 0.07 cm/kyr. Both cores had less total excess 230Th than predicted. Radium sediment profiles are generated from the 230Th model. Adsorbed, dissolved, and solid-phase radium is considered. According to the model, diffusional losses of radium are especially important at low sedimentation rates. Any particulate, or excess radium input is ignored in this model. The model fits the two analyzed cores if the fraction of total radium available for adsorption-desorption is about 0.5-0.7, and if K, the distribution coefficient, is about 1000. The flux of radon out of the sediments is derived from the model-generated radium profiles. It is shown that the resulting standing crop of SUP-222 Rn in the overlying water may be considered as an added constraint in budgeting 230Th and 226Ra in deep-sea sediments.

Description: Specimens dredged from within the summit of a volcanic seamount during an oceanographic cruise in the Eolian Island Arc (South Tyrrhenian Sea) where examined. Mineralization, which forms veins and pockets within a silty-clayey material, consists mainly of todorokite with scarce birnessite. The chemistry (Mn 48%, Fe 0.26 %, Ni 249 ppm, Co 223 ppm) and the mineralogy of the deposit are discussed; the findings, compared with data from some of the literature, suggest a hydrothermal genesis with extreme fractionations of Mn from Fe. A process explaining the anomalous Cu content (8 200 ppm) of the deposit is also suggested.

Description: The purpose of this volume, the tenth in a series of similar publications (Goodell, 1964, 1965, 1968; Frakes 1971, 1973 ; Cassidy et al., 1977), is to continue a presentation to the research community of sediment core descriptions and attendant data of cored and otherwise obtained sediments retrieved in waters of the Southern Ocean aboard the research vessel, ARA Islas Orcadas (formerly, USNS Eltanin), as a part of the circumpolar survey begun by Eltanin in 1962 (see issue of Antarctic Journal of the United States, Vol. 8, No. 3, 1973). The data presented herein are concerned with the results of coring activities aboard cruise 1578 of Islas Orcadas, the fourth marine geology coring cruise of this vessel under the terms of the present United States-Argentine agreement. The core descriptions are organised as follows: 1) a brief summary of the coring objectives of the cruise, together with a discussion of core recovery; 2) a table and map of station location data for materials retrieved; 3) a table of tentative age-dates for each piston core; 4) an explanation of the laboratory procedures and descriptive criteria used in the description of the sediments, and 5) lithologic descriptions of the piston and trigger cores, and the piston and trigger core bag samples.

Description: The sulfide deposit at Site 471 occurs between overlying pelagic sediment and underlying basalt. The deposit is vertically zoned and consists, from top to bottom, of the following mineral assemblages: (1) pyrite, chalcopyrite, and Zn-sulfide in chert and calcite gangue (~ 35 cm thick); (2) a 5-cm-thick metalliferous sediment layer and (3) a 4-cm-thick chert layer. The calcite gangue appears at a later stage than chert gangue in the sequence of deposition, also filling in voids and fractures. The manganese content of calcite is particularly high and varies systematically, reaching a maximum at the top of the massive sulfide portion of the deposit.