Publication Date:
2023-08-28
Description:
Aragonite mineralization was observed in serpentinized peridotites from the Romanche and Vema Fracture Zones in the Atlantic and the Owen Fracture Zone in the Indian Ocean, either in veins or as radial aggregates in cavities within the serpentinites. Evidence of incipient dissolution of the aragonite crystals was observed in one case. The aragonites tend to have lower Mg content (〈 0.03%) and higher Sr content (〉 0.95%) relative to other marine aragonites. Their 18O16O, 13C12C and 87Sr86Sr isotopic ratios suggest the aragonite was deposited at ocean floor temperatures from solutions derived from sea water circulating in fissures and fractures within the ultramafic rocks. The 18O16O ratios of the serpentines indicate serpentinization occurred at higher temperatures, probably deeper in the crust. Low-T reactions between circulating seawater and Mg-silicates (primarily serpentine and pyroxenes) caused high pH and enrichment of Mg and Ca in the solution, conditions favoring carbonate precipitation. Aragonite was formed rather than calcite presumably because the high Mg2+ concentration in the solution inhibited calcite precipitation. The high Sr content of the aragonites is probably related, at least in part, to their low temperature of formation. Opaque mineral grains containing over 8% NiO and over 40% MnO were observed concentrated along the margins of some of the aragonite veins, suggesting that Ni is one of the elements mobilized during reactions between ultramafic rocks and circulating seawater.
Keywords:
Aluminium oxide; Calcium oxide; Deposit type; DEPTH, sediment/rock; Description; Dredge; DRG; Electron microprobe (EMP); G-7309; G-7309-81; Gerda; Identification; Iron oxide, FeO; Magnesium oxide; Manganese oxide; Nickel oxide; NOAA and MMS Marine Minerals Geochemical Database; NOAA-MMS; Potassium oxide; Romanche Fracture Zone, Atlantic Ocean; Sample code/label; Silicon dioxide; Sodium oxide; Substrate type
Type:
Dataset
Format:
text/tab-separated-values, 14 data points
