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  • 04. Solid Earth::04.04. Geology::04.04.12. Fluid Geochemistry  (16)
  • 03. Hydrosphere::03.01. General::03.01.06. Paleoceanography and paleoclimatology
  • Elsevier  (24)
  • American Geophysical Union (AGU)
  • Annual Reviews
  • Periodicals Archive Online (PAO)
  • 2005-2009  (24)
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  • 1945-1949
  • 2009  (8)
  • 2008  (16)
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  • 1
    Publikationsdatum: 2020-12-21
    Beschreibung: A sedimentary sequence spanning Marine Isotope Stage (MIS) 6 to MIS 2 in core LC07, recovered in the central Mediterranean, has been investigated in order to produce a high-resolution paleoceanographic reconstruction. The changes in productivity deduced from calcareous plankton relative abundances and independently confirmed by the BaXS fluctuations are linked to the stability of the water column which is mainly controlled by the water mass temperature. During glacial intervals, productivity was generally enhanced. Oligotrophic and warmer water masses with a deepened seasonal thermocline can be inferred for most of MIS5. The magnetic properties of the sediment show increased occurrences of North Africa dust in the central Mediterranean during cold phases, likely as a consequence of a more efficient erosive process triggered by southward displacement of the intertropical convergence zone. Although increases in both productivity and Saharan dust occurred during cold periods, the atmospheric inputs do not seem to contribute significantly to the fertilization of primary producers. A Shannon Index curve has been used to tentatively synthesize the variations of calcareous nannofossil assemblages through the last 150 kyr. The assemblage diversity sharply increased coincident with the transition from the penultimate glacial to the last interglacial, subsequently low diversity was gradually reached again in the last glacial.
    Beschreibung: Published
    Beschreibung: 26-41
    Beschreibung: 2.2. Laboratorio di paleomagnetismo
    Beschreibung: JCR Journal
    Beschreibung: reserved
    Schlagwort(e): calcareous nannofossils ; foraminifera ; paleoproductivity ; Late Pleistocene ; central mediterranean ; 03. Hydrosphere::03.01. General::03.01.06. Paleoceanography and paleoclimatology ; 04. Solid Earth::04.04. Geology::04.04.08. Sediments: dating, processes, transport ; 04. Solid Earth::04.05. Geomagnetism::04.05.07. Rock magnetism
    Repository-Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
    Materialart: article
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  • 2
    Publikationsdatum: 2021-01-07
    Beschreibung: The CO2 degassing process from a large area on the Tyrrhenian side of central Italy, probably related to the input into the upper crust of mantle fluids, was investigated in detail through the geochemical study of gas emissions and groundwater. Mass-balance calculations and carbon isotopes show that over 50% of the inorganic carbon in regional groundwater is derived from a deep source highlighting gas−liquid separation processes at depth. The deep carbonate−evaporite regional aquifer acts as the main CO2 reservoir and when total pressure of the reservoir fluid exceeds hydrostatic pressure, a free gas phase separates from the parent liquid and escapes toward the surface generating gas emissions which characterise the study area. The distribution of the CO2 flux anomalies and the location of high PCO2 springs and gas emissions suggest that the storage and the expulsion of the CO2 toward the atmosphere are controlled by the geological and structural setting of the shallow crust. The average CO2 flux and the total amount of CO2 discharged by the study area were computed using surface heat flow, enthalpy and CO2 molality of the liquid phase circulating in the deep carbonate−evaporite aquifer. The results show that the CO2 flux varies from 1×104 mol y−1 km−2 to 5×107 mol y−1 km−2, with an average value of 4.8×106 mol y−1 km−2, about five times higher than the value of 1×106 mol y−1 derived by Kerrick et al. [Kerrick, D.M., McKibben, M.A., Seward, T.M., Caldeira, K., 1995. Convective hydrothermal CO2 emission from high heat flow regions. Chem. Geol. 121, 285–293] as baseline for terrestrial CO2 emissions. The total CO2 discharged from the study area is 0.9×1011 mol y−1, confirming that Earth degassing from Tyrrhenian central Italy is a globally relevant carbon source
    Beschreibung: Published
    Beschreibung: 89–102
    Beschreibung: 2.4. TTC - Laboratori di geochimica dei fluidi
    Beschreibung: 4.5. Degassamento naturale
    Beschreibung: JCR Journal
    Beschreibung: reserved
    Schlagwort(e): Earth degassing ; carbon dioxide ; CO2 flux ; groundwater ; 04. Solid Earth::04.02. Exploration geophysics::04.02.01. Geochemical exploration ; 04. Solid Earth::04.04. Geology::04.04.12. Fluid Geochemistry ; 04. Solid Earth::04.08. Volcanology::04.08.01. Gases ; 04. Solid Earth::04.08. Volcanology::04.08.06. Volcano monitoring
    Repository-Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
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  • 3
    Publikationsdatum: 2021-06-25
    Beschreibung: We present the first helium isotope data for thermal waters and gas emissions on the islands of Terceira, Graciosa, Faial, Pico and Flores, as well as new data for Sao Miguel. The results allow us to track current mantle degassing associated with the Azores hot spot, to delineate its spatial distribution and to discuss its possible origin. As a general rule, we find that free gases tend to display somewhat higher 3He/4He ratio than groundwaters.We argue that this difference is likely due to radiogenic helium inputs to aquifers duringwater– rock interactions and, therefore, that gas phases are the fluid carriers with the most representative of mantle source signature. The measured 3He/4He ratios (normalized to the air ratio, Ra) range from lower-than-MORB values (5.23–6.07 Ra) on central Sao Miguel, to MORB values on Faial (8.53 Ra) and Flores (8.04 Ra) – located on either side of the Mid-Atlantic Ridge – and to plume-type values on Graciosa (11.2 Ra) and Terceira (13.5 Ra) where free gases also display ten times higher-than-MORB CO2/3He ratios (1.8–2.6×1010). Such a wide He isotopic range and its spatial distribution corroborate with available data for volcanic rocks, indicating that plume's head presently underlies the central part of the archipelago. The plume-type 3He/4He ratios on Terceira and Graciosa agree with geochemical and seismic evidence of a deep-rooted mantle plume feeding the Azores hot spot. Our finding that high 3He/4He ratios correspond to low 3He concentrations and high (arctype) CO2/3He values exclude a simple plume supply of 3He-rich primitive mantle. Instead, the simultaneity of both elevated CO2/3He and 3He/4He ratios is best explained by a 3He-rich contribution from the lower mantle diluted in a CO2-rich feeding plume that contains a recycled altered oceanic plate component. The alternative possibility of an enhanced time-integrated 3He/(U+Th) ratio in the Azores plume due to a greater compatibility of helium relative to U and Th during melting events is difficult to reconcile with the enriched pattern of volcanic rocks from the central islands. In any case, the Azores plume should derive from a mantle reservoir that could escape convective homogenization for a very long period of time, in agreement with subchondritic osmium isotopic ratios in volcanic rocks from the central islands of the archipelago.
    Beschreibung: Published
    Beschreibung: 70−80
    Beschreibung: 1.2. TTC - Sorveglianza geochimica delle aree vulcaniche attive
    Beschreibung: JCR Journal
    Beschreibung: reserved
    Schlagwort(e): hydrothemal fluids ; helium isotopes ; 04. Solid Earth::04.04. Geology::04.04.12. Fluid Geochemistry
    Repository-Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
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  • 4
    Publikationsdatum: 2017-04-04
    Beschreibung: The Antarctic region has profoundly affected the global climates of the past 50 million years, influencing sea levels, atmospheric composition and dynamics, and ocean circulation. A greater understanding of this region and the Antarctic cryosphere is crucial to a broader understanding of the global climates and palaeoceanography at all scales. Much of the information obtained during the last two decades derives from studies of sedimentary sequences drilled in and around Antarctica. Eight Ocean Drilling Program (ODP) legs have contributed significantly to the understanding of this evolution. These legs include Leg 113 in the Weddell Sea (Barker et al., 1988, 1990), Leg 114 in the Subantarctic South Atlantic (Ciesielski et al., 1988, 1991), Leg 119 in Prydz Bay and on Kerguelen Plateau (Barron et al., 1989, 1991), Leg 120 on Kerguelen Plateau (Schlich et al., 1989; Wise et al., 1992), Leg 177 in the southeast Atlantic sector of the Southern Ocean (Gersonde et al., 1999), Leg 178 on the Antarctic Peninsula (Barker et al., 2002), Leg 188 in Prydz Bay (O’Brien et al., 2001), and Leg 189 in the Tasmanian region (Exon et al., 2001). More recently, a series of three holes were drilled in McMurdo Sound, Ross Sea, as part of the Cape Roberts Project (CRP; Cape Roberts Science Team, 1998 1999, 2000; Hambrey et al., 1998; Barrett et al., 2000, 2001). In spite of these efforts, which have significantly advanced our understanding of the Cenozoic tectonics and palaeoenvironments of the Antarctic region, important questions and problems remain unresolved. Chief amongst these are the timing of the onset of the East Antarctic Ice Sheet (EAIS), the causes of the cooling events at around 24 and 14 Ma, and the warming events of the mid-Pliocene and Marine Isotope Stages 31 (1.07 Ma) and 11 (0.36 Ma) (Shackleton et al., 1995).
    Beschreibung: Published
    Beschreibung: 1-9
    Beschreibung: 3.8. Geofisica per l'ambiente
    Beschreibung: JCR Journal
    Beschreibung: reserved
    Schlagwort(e): Antarctic climate evolution ; 03. Hydrosphere::03.01. General::03.01.06. Paleoceanography and paleoclimatology
    Repository-Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
    Materialart: article
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  • 5
    Publikationsdatum: 2017-04-04
    Beschreibung: The Cenozoic evolution of the Antarctic cryosphere and fluctuations in its ice sheet cover are considered to be one of the major influences on low- and mid-latitude deep-sea sedimentary records. Long-term Cenozoic trends and short-term climate fluctuations (≤40 ka) alike are inferred to have been driven or modulated by changes in Antarctic ice sheet volume (Kennett, 1977; Imbrie and Imbrie, 1980; Zachos et al., 1997, 2001; Shackleton et al., 1999; Lear et al., 2000; Naish et al., 2001). Similarly, changes in sea level elevations at continental margins are also inferred to result from growth and decay in Antarctic ice sheet volume throughout the Cenozoic (Barrett et al., 1987; Haq et al., 1987). Yet, direct records of the Antarctic cryosphere and its ice sheets are sparse at best, and much of the inference remains untested. Recent efforts have begun to change this, and the last decade has seen several expeditions to the Antarctic and Southern Oceans, which have recovered new high-quality sedimentary core and seismic reflection records of Southern high-latitude Cenozoic ice sheets and climate. These include the Cape Roberts Project (CRP) (Cape Roberts Science Team, 1998; Hambrey et al., 1998; Cape Roberts Science Team, 1999; Barrett et al., 2000; Cape Roberts Science Team, 2000; Barrett et al., 2001; Davey et al., 2001), ODP Leg 177 (Gersonde et al., 1999, 2003), Leg 178 (Barker et al., 1999, 2002), Leg 182 (Feary et al., 2000; Hine et al., 2004), Leg 188 (O’Brien et al., 2001; Cooper et al., 2004), and Leg 189 (Exon et al., 2001, in press), and various RVIB NB Palmer and Polarstern cruises. Recent results from these expeditions were presented at a special session of the EGS–AGU Joint assembly held in Nice, France, in April 2003. The focus of the session was the many orders and scales of variation of Antarctic ice sheets and climate from Antarctic and sub-Antarctic records derived from outcrop studies, deep sea and continental margin drilling, and seismic reflection investigations. The session also included new modelling results utilizing new data from these recent expeditions and preliminary results of geophysical surveys defining sub-ice shelf and sea ice sedimentary basins identified as drilling targets in the near future under the ANDRILL program (Harwood et al., 2002; Florindo et al., 2003a).
    Beschreibung: Published
    Beschreibung: 1-7
    Beschreibung: 3.8. Geofisica per l'ambiente
    Beschreibung: JCR Journal
    Beschreibung: reserved
    Schlagwort(e): Antarctic climate evolution ; 03. Hydrosphere::03.01. General::03.01.06. Paleoceanography and paleoclimatology
    Repository-Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
    Materialart: article
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  • 6
    Publikationsdatum: 2017-04-03
    Beschreibung: Ocean Drilling Program holes 744Aand 748B represent key sections for calibration of Southern Ocean Eocene-Oligocene biostratigraphic zonations. Sites 744 and 748 were above the carbonate compensation depth throughout this time interval and contain good planktonic foraminiferal, calcareous nannofossil, and diatom biostratigraphic records. In particular, the Southern Ocean diatom biostratigraphic zonation for the Oligocene critically hinges on calibration of these two holes. Previous low-resolution magnetostratigraphic studies at these sites were hampered by limited sampling and technical difficulties, which prompted our high-resolution reinvestigation of the magnetostratigraphy. Magnetic polarity zonations for holes 744Aand 748B were constructed after inspection of vector component plots at 1-cm stratigraphic intervals from continuous u-channel measurements. The magnetizations are generally stable and a robust polarity stratigraphy has been obtained for both holes. The increased resolution of our study and identification of persistent secondary overprints, which were not recognised in previous studies, suggests that the previously published interpretations need to be revised. Our magnetostratigraphic interpretations for both holes are constrained by foraminiferal and calcareous nannofossil datums, as well as by Sr isotope ages. We have calibrated four diatom datums, which are synchronous at the two studied sites, to the geomagnetic polarity timescale, including the first occurrence (FO) of Lisitzinia ornata (27.8 Ma), the FO of Rocella vigilans var. B (27.8 Ma), the FO of Cavitatus jouseanus (30.9 Ma) and the FO of Rhizosolenia oligocaenica (33.8 Ma). The synchroneity of these datums suggests that diatom biostratigraphy has considerable potential for Palaeogene biostratigraphic correlation in the Southern Ocean. Although the ages of some datums are obscured by an unconformity in Hole 744A, our age model from Hole 748B suggests age estimates for the last common occurrence of Rocella vigilans var. A(~29.0 Ma), the FO of Rocella vigilans var. A(30.0 Ma) and the FO of Rhizosolenia antarctica (33.2 Ma). It should also be noted that the last occurrence of the calcareous nannofossil Chiasmolithus altus occurs in Chron C8r rather than C8n in our revised magnetostratigraphic interpretation, which indicates that this datum is not diachronous between low and mid latitudes as had previously been suggested. Significant unconformities are documented in both holes, in the middle Oligocene and in the middle late Oligocene, respectively, which probably resulted from periods of enhanced circumpolar deep-water circulation.
    Beschreibung: Published
    Beschreibung: 145-168
    Beschreibung: 2.2. Laboratorio di paleomagnetismo
    Beschreibung: JCR Journal
    Beschreibung: reserved
    Schlagwort(e): Eocene ; Oligocene ; Ocean Drilling Program ; holes 744A and 748B ; Kerguelen Plateau ; Antarctica ; magnetostratigraphy ; biostratigraphy ; diatoms ; foraminifera ; calcareous nannofossils ; 03. Hydrosphere::03.01. General::03.01.06. Paleoceanography and paleoclimatology ; 04. Solid Earth::04.05. Geomagnetism::04.05.06. Paleomagnetism
    Repository-Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
    Materialart: article
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  • 7
    Publikationsdatum: 2017-04-04
    Beschreibung: El Chichón volcano (Chiapas, Mexico) erupted violently in March–April 1982, breaching through the former volcano–hydrothermal system. Since then, the 1982 crater has hosted a shallow (1–3.3 m, acidic (pH ∼ 2.2) and warm (∼ 30 °C) crater lake with a strongly varying chemistry (Cl/SO4=0–79 molar ratio). The changes in crater lake chemistry and volume are not systematically related to the seasonal variation of rainfall, but rather to the activity of near-neutral geyser-like springs in the crater (Soap Pool). These Soap Pool springs are the only sources of Cl for the lake. Their geyser-like behaviour with a long-term (months to years) periodicity is due to a specific geometry of the shallow boiling aquifer beneath the lake, which is the remnant of the 1983 Cl-rich (24,000 mg/l) crater lake water. The Soap Pool springs decreased in Cl content over time. The zero-time extrapolation (1982, year of the eruption) approaches the Cl content in the initial crater lake,meanwhile the extrapolation towards the future indicates a zero-Cl content by 2009±1. This particular situation offers the opportunity to calculate mass balance and Cl budget to quantify the lake–spring system in the El Chichón crater. These calculations show that the water balance without the input of SP springs is negative, implying that the lake should disappear during the dry season. The isotopic composition of lake waters (δD and δ18O) coincide with this crater lake-SP dynamics, reflecting evaporation processes and mixing with SP geyser and meteoric water. Future dome growth, not observed yet in the post-1982 El Chichón crater, may be anticipated by changes in lake chemistry and dynamics.
    Beschreibung: Published
    Beschreibung: 237–248
    Beschreibung: 1.2. TTC - Sorveglianza geochimica delle aree vulcaniche attive
    Beschreibung: 2.4. TTC - Laboratori di geochimica dei fluidi
    Beschreibung: JCR Journal
    Beschreibung: reserved
    Schlagwort(e): El Chichón volcano ; crater lake–Spring dynamics ; fluid geochemistry ; stable isotopes ; monitoring ; 04. Solid Earth::04.04. Geology::04.04.12. Fluid Geochemistry ; 04. Solid Earth::04.08. Volcanology::04.08.01. Gases ; 04. Solid Earth::04.08. Volcanology::04.08.06. Volcano monitoring ; 05. General::05.02. Data dissemination::05.02.01. Geochemical data
    Repository-Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
    Materialart: article
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  • 8
    Publikationsdatum: 2017-04-04
    Beschreibung: El Chichón crater lake appeared immediately after the 1982 catastrophic eruption in a newly formed, 1-km wide, explosive crater. During the first 2 years after the eruption the lake transformed from hot and ultraacidic caused by dissolution of magmatic gases, to a warm and less acidic lake due to a rapid “magmatic-tohydrothermal transition” — input of hydrothermal fluids and oxidation of H2S to sulfate. Chemical composition of the lake water and other thermal fluids discharging in the crater, stable isotope composition (δD and δ18O) of lake water, gas condensates and thermal waters collected in 1995–2006 were used for the mass-balance calculations (Cl, SO4 and isotopic composition) of the thermal flux from the crater floor. The calculated fluxes of thermal fluid by different mass-balance approaches become of the same order of magnitude as those derived from the energy-budget model if values of 1.9 and 2 mmol/mol are taken for the catchment coefficient and the average H2S concentration in the hydrothermal vapors, respectively. The total heat power from the crater is estimated to be between 35 and 60 MW and the CO2 flux is not higher than 150 t/day or ~200 gm−2 day−1.
    Beschreibung: Published
    Beschreibung: 472-481
    Beschreibung: 1.2. TTC - Sorveglianza geochimica delle aree vulcaniche attive
    Beschreibung: 2.4. TTC - Laboratori di geochimica dei fluidi
    Beschreibung: JCR Journal
    Beschreibung: reserved
    Schlagwort(e): El Chichón ; crater lake ; mass-energy budget ; CO2 flux ; 04. Solid Earth::04.04. Geology::04.04.12. Fluid Geochemistry ; 05. General::05.02. Data dissemination::05.02.01. Geochemical data ; 05. General::05.02. Data dissemination::05.02.04. Hydrogeological data
    Repository-Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
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  • 9
    Publikationsdatum: 2017-04-04
    Beschreibung: Quantifying the contribution of volcanism to global mercury (Hg) emissions is important to understand the pathways and the mechanisms of Hg cycling through the Earth's geochemical reservoirs and to assess its environmental impacts. While previous studies have suggested that degassing volcanoes might contribute importantly to the atmospheric budget of mercury, little is known about the amount and behaviour of Hg in volcanic aquifers. Here we report on detailed investigations of both the content and the speciation of mercury in aquifers of active volcanoes in Italy and Guadeloupe Island (Lesser Antilles). In the studied groundwaters, total Hg (THg) concentrations range from 10 to 500 ng/l and are lower than the 1000 ng/l threshold value for human health protection fixed by the World Health Organization [WHO (1993): WHO Guidelines for Drinking Water Quality- http://www.who.int/water_sanitation_health/GDWQ/index.htlm]. Positive co-variations of (THg) with sulphate indicate that Hg-SO4-rich acid groundwaters receive a direct input of magmatic/hydrothermal gases carrying mercury as Hg0 (gas). Increasing THg in a volcanic aquifer could thus be a sensitive tracer of magmatic gas input prior to an eruption. Since the complex behaviour and toxicity of mercury in waters depend on its chemical speciation, we carefully determined the different aqueous forms of this element in our samples.We find that dissolved elemental Hg0 (aq) and particulate-bound Hg (HgP) widely prevail in volcanic aquifers, in proportions that highlight the efficiency of Hg adsorption onto colloidal particles. Moreover, we observe that dissolved Hg0 aq and Hg(II) forms coexist in comparable amount in most of the waters, in stark contrast to the results of thermodynamic equilibrium modelling. Therefore, chemical equilibrium between dissolved mercury species in volcanic waters is either prevented by natural kinetic effects or not preserved in collected waters due to sampling/storage artefacts. Finally, we provide a first quantitative comparison of the relative intensity of aqueous transport and atmospheric emissions of mercury at Mount Etna, a very active basaltic volcano.
    Beschreibung: Published
    Beschreibung: 96-106
    Beschreibung: 4.5. Studi sul degassamento naturale e sui gas petroliferi
    Beschreibung: JCR Journal
    Beschreibung: reserved
    Schlagwort(e): speciation ; volcanic aquifers ; total and dissolved mercury ; mercury cycling ; volatile budget ; 04. Solid Earth::04.04. Geology::04.04.12. Fluid Geochemistry
    Repository-Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
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  • 10
    Publikationsdatum: 2017-04-04
    Beschreibung: This special issue on "Antarctic Climate Evolution — view from the margin" presents results from modelling studies and reports on geoscience data aimed at improving our understanding of the behaviour of the Antarctic ice sheet and the climate of the region. This research field is of interest because of the sensitivity of the polar regions to global warming, and because of the influence of the Antarctic ice sheet on global sea level and climate through most if not all of the Cenozoic Era. The Antarctic ice sheet both responds to and forces changes on global climate and sea level. We need to be aware of the scale and frequency of these changes if we are to understand past patterns of environmental change elsewhere on earth. It was only three decades ago that we discovered from strata drilled in shelf basins on the Antarctic margin that the Antarctic ice sheet had a history that predated the Quaternary ice ages by over 20 million years (Hayes et al., 1975). Later that year the first interpretation of Antarctic glacial history through the Cenozoic Era from oxygen isotopes, recorded in foraminifera from deep-sea sediment cores, was published (Shackleton and Kennett, 1975). Revisions with a more extensive database have modified the story a little (Miller et al., 1987; Zachos et al., 2001), and there have been recent attempts to resolve the temperature–ice volume ambiguity (Lear et al., 2000). However, reports on strata drilled on the Antarctic margin have unambiguously shown the character of this huge ice sheet, which was oscillating in the Oligocene (Barrett et al., 1987; Barrett, 1999) with a period and magnitude comparable with the Northern Hemisphere ice sheets of the Quaternary (Naish et al., 2001a,b). In this issue we present further research on the history of the Antarctic ice sheet from Oligocene to recent times, most of them from the Antarctic margin, but with some on the nature of the deep-sea isotope record, and others using recently developed modeling techniques to investigate the influence of atmosphere, ocean and biosphere on past Antarctic climate. This special issue is the third in three years on the theme of Antarctic Climate Evolution. The first followed a workshop in Erice, Sicily, in 2001 to report on results from ANTOSTRAT, a SCAR-sponsored project for gathering and analysing circum-Antarctic seismic data for planning and promoting offshore drilling for climate history. The introduction to that issue (Florindo et al., 2003) provides a review of the recent history of circum-Antarctic drilling by the Ocean Drilling Program (Legs 113, 114, 119, 120, 177, 178, 188 and 189) and the Cape Roberts Project. For a more comprehensive review of earlier drilling in the Ross Sea region (Deep Sea Drilling Project Leg 28, Dry Valley Drilling Project, McMurdo Sound Sediment and Tectonic Studies, Cenozoic Investigations in the western Ross Sea) see Hambrey and Barrett (1993). The first of these issues (Florindo et al., 2003) featured a global plate reconstruction of the Southern Hemisphere through Cenozoic time with emphasis on evolution of Cenozoic seaways (Lawver and Gahagan, 2003) along with a study of the inception and early evolution of the EAIS using a new coupled global climate (GCM)– dynamic ice sheet model (DeConto and Pollard, 2003b), as well as data from recent drilling around the margin covering time period from Cretaceous to the present. A second special issue on the same theme (Florindo et al., 2005) also featured a mix of modelling and data papers with a focus on the Eocene–Oligocene boundary and the initiation of ice sheet growth, including a pioneering attempt to evaluate the relative influence of fluvial versus glacial processes in shaping the landscape of the Prydz Bay sector of Antarctica (Jamieson et al., 2005). The remainder of the issue comprised further papers on seismic stratigraphy and reports from drilling around the margin. The papers to be found in this special issue, like the previous two, maintain the mix of modelling- and data-oriented papers that reflect the range of this research.
    Beschreibung: Published
    Beschreibung: 1-8
    Beschreibung: 3.8. Geofisica per l'ambiente
    Beschreibung: JCR Journal
    Beschreibung: reserved
    Schlagwort(e): Antarctic climate evolution ; 03. Hydrosphere::03.01. General::03.01.06. Paleoceanography and paleoclimatology
    Repository-Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
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  • 11
    Publikationsdatum: 2017-04-04
    Beschreibung: A transect of three sites was drilled during Leg 188 of the Ocean Drilling Program (ODP), proximal to the East Antarctic Ice Sheet (EAIS) across the Prydz Bay continental shelf (Site 1166), slope (Site 1167), and rise (Site 1165). We present results of a palaeomagnetic and rock magnetic study of sediments recovered at sites 1165 and 1166. Magnetostratigraphic interpretations are presented for both holes and are mainly constrained by diatom and radiolarian biostratigraphies, interpreted in the light of recent refinements to Southern Ocean zonal schemes and datum calibrations for these microfossil groups. Site 1165 records a history of sedimentation on the continental rise extending back to earliest Miocene times (about 22 Ma). Several long-term changes characterise this record, including an overall trend of decreasing sedimentation rates from the bottom to the top of the hole. There is a progressive decrease in the sedimentation rate above about 308 mbsf (meters below sea floor), which is marked by a transition from dark-grey fissile claystones to greenish-grey diatom-bearing clays. At this transition, ice-rafted debris, sand grains, and total clay content also increase. The chronology presented here indicates a middle Miocene age (~14.3 Ma) for the lithological transition. Correlation to ODP Hole 747A from the Kerguelen Plateau suggests that this lithological transition coincides with the base of the Mi-3/3a δ18O event, which suggests palaeoclimatic control on middle Miocene sedimentation changes at Site 1165. Core recovery was poor at Site 1166. Consequently, the magnetostratigraphic data are of limited value. The deepest cores recovered at Site 1166 record brief intervals in the early history of the EAIS for the Prydz Bay region, extending back through the early stage of glaciation to pre-glacial times. An Early Cretaceous fluvio-lacustrine unit, lagoonal deposits and sandy fluvio-deltaic units of mid-late Eocene age contain a sporadic record of the transition from humid and mild conditions to cool temperate conditions.
    Beschreibung: Published
    Beschreibung: 69-100
    Beschreibung: 2.2. Laboratorio di paleomagnetismo
    Beschreibung: JCR Journal
    Beschreibung: reserved
    Schlagwort(e): magnetostratigraphy ; biostratigraphy ; Prydz Bay ; Antarctica ; Ocean Drilling Program ; sites 1165 and 1166 ; 03. Hydrosphere::03.01. General::03.01.06. Paleoceanography and paleoclimatology ; 04. Solid Earth::04.05. Geomagnetism::04.05.06. Paleomagnetism
    Repository-Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
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  • 12
    Publikationsdatum: 2017-04-04
    Beschreibung: Four groups of thermal springs with temperatures from 50 to 80 °C are located on the S–SW–W slopes of El Chichón volcano, a composite dome-tephra edifice, which exploded in 1982 with a 1 km wide, 160 m deep crater left. Very dynamic thermal activity inside the crater (variations in chemistry and migration of pools and fumaroles, drastic changes in the crater lake volume and chemistry) contrasts with the stable behavior of the flank hot springs during the time of observations (1974–2005). All known groups of hot springs are located on the contact of the basement and volcanic edifice, and only on the W–SW–S slopes of the volcano at almost same elevations 600–650 m asl and less than 3 km of direct distance from the crater. Three groups of near-neutral (pH≈6) springs at SW–S slopes have the total thermal water outflow rate higher than 300 l/s and are similar in composition. The fourth and farthest group on the western slope discharges acidic (pH≈2) saline (10 g/kg of Cl) water with a much lower outflow rate (b10 l/s). Water–rock interaction modeling of main types of the El Chichón thermal waters using regular log Q/K graphs (saturation indices vs temperature) showed maximum equilibrium temperature slightly higher than 200 °C. Acidic waters are equilibrated with some clay minerals at about 120 °C. Three main sources of the salinity of thermal water are suggested on the basis of mixing plots and isotopic data: a magmatic source for CO2, boron, sulfur and a limited part of Cl; volcanic rock source for the major cations and trace elements; the oil-bearing evaporitic basement source (oil-field brine?) for NaCl, Br, a part of Ca and some trace elements. All flank thermal springs end up in the river Rio Magdalena that has a variable seasonal flow rates from 4 to 20 m3/s. Any changes in the chemistry of springs must notably change the composition of the streams draining hot springs and eventually, Rio Magdalena. A monthly geochemical monitoring of Rio Magdalena and streams draining main hot springs would be a useful tool for surveying the activity of the volcano.
    Beschreibung: Published
    Beschreibung: 224–236
    Beschreibung: 2.4. TTC - Laboratori di geochimica dei fluidi
    Beschreibung: JCR Journal
    Beschreibung: reserved
    Schlagwort(e): volcano–hydrothermal system ; crater lake ; acidic water ; trace elements ; thermochemical modeling ; El Chichón volcano ; 04. Solid Earth::04.04. Geology::04.04.12. Fluid Geochemistry ; 04. Solid Earth::04.08. Volcanology::04.08.06. Volcano monitoring ; 05. General::05.02. Data dissemination::05.02.01. Geochemical data
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  • 13
    Publikationsdatum: 2017-04-04
    Beschreibung: Dynamic accumulation chamber methods have been extensively used to estimate the total output of CO2 released from active volcanic area. In order to asses the performance and reliability of a closed dynamic system several tests were carried out with different soil permeabilities and soil CO2 fluxes. A special device was used to create a constant one-dimensional CO2 flux through a soil column with a known permeability. Three permeabilities were investigated, ranging between 3.6 × 10− 2 and 3.5 × 10 μm2, as were several CO2 fluxes (ranging between 1.1 × 10− 6 and 6.3 × 10− 5 kg m− 2 s− 1). The results highlight that the accuracy of soil CO2 flux measurements strictly depends on the soil gas permeability and the soil CO2 flux regimen. Generally chamber measurements underestimate CO2 fluxes at low soil permeability and low soil CO2 fluxes, whereas appreciable overestimations occur for high permeability soil, especially for high soil CO2 fluxes. Other tests carried out with different settings for the measurement device, such as the chamber volume and the flux of the pump used to recirculate air through the chamber and the gas analyzer (recirculation flux), revealed a strong dependence of the closed dynamic chamber measurements on the recirculation flux. Low recirculation fluxes (0.2–0.4 l min− 1) decreased the performance of the measurement system, causing underestimations of the actual soil CO2 flux, whereas higher values (0.6–1.0 l min− 1) resulted in overestimations, especially for elevated soil CO2 fluxes. An empirical equation was deduced to allow accumulation chamber fluxes to be calculated very accurately based on soil gas permeabilities measured in the field.
    Beschreibung: Published
    Beschreibung: 387-393
    Beschreibung: 1.2. TTC - Sorveglianza geochimica delle aree vulcaniche attive
    Beschreibung: 4.5. Studi sul degassamento naturale e sui gas petroliferi
    Beschreibung: JCR Journal
    Beschreibung: reserved
    Schlagwort(e): Soil CO2 flux measuraments ; Closed dynamic chamber ; soil gas permeability ; 04. Solid Earth::04.02. Exploration geophysics::04.02.01. Geochemical exploration ; 04. Solid Earth::04.04. Geology::04.04.12. Fluid Geochemistry ; 04. Solid Earth::04.08. Volcanology::04.08.01. Gases ; 04. Solid Earth::04.08. Volcanology::04.08.06. Volcano monitoring ; 04. Solid Earth::04.08. Volcanology::04.08.07. Instruments and techniques
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  • 14
    Publikationsdatum: 2017-04-04
    Beschreibung: An extensive geochemical survey of the fluids released by the volcanic/geothermal system of Methana was undertaken. Gases were characterized based on the chemical and isotopic [helium (He) and carbon (C)] analysis of 27 samples. Carbon dioxide soil gas concentration and fluxes were measured at 179 sampling sites throughout the peninsula. Forty samples of thermal and cold groundwaters were also sampled and analysed to characterize the geochemistry of the aquifers. Gases of hydrothermal origin gave a preliminary geothermometric estimate of about 210 °C. The He-isotope composition indicated mantle contributions of up to 40%, and the C-isotope composition of CO2 indicated that it predominantly (〉90%) originated from limestone decomposition. The groundwater composition was suggestive of mixing between meteoric and hydrothermally modified sea-water endmembers and water–rock interaction processes limited to simple rock dissolution driven by an increased endogenous CO2 content. All of the thermal manifestations and anomalous degassing areas, although of limited extent, were spatially correlated with the main active tectonic system of the area. The total CO2 output of the volcanic system has been preliminary estimated to be less than 0.05 kg s–1. Although this value is very low compared to those of other volcanic systems, anomalous CO2 degassing at Methana – which is currently restricted to limited areas and at present is the only volcanic risk of the peninsula – is a potential gas hazard that warrants further assessment in future studies.
    Beschreibung: Published
    Beschreibung: 818-828
    Beschreibung: 1.2. TTC - Sorveglianza geochimica delle aree vulcaniche attive
    Beschreibung: JCR Journal
    Beschreibung: reserved
    Schlagwort(e): Methana ; south Aegean volcanic arc ; fluids geochemistry ; soil gases ; groundwaters ; 03. Hydrosphere::03.04. Chemical and biological::03.04.03. Chemistry of waters ; 03. Hydrosphere::03.04. Chemical and biological::03.04.05. Gases ; 03. Hydrosphere::03.04. Chemical and biological::03.04.06. Hydrothermal systems ; 04. Solid Earth::04.02. Exploration geophysics::04.02.01. Geochemical exploration ; 04. Solid Earth::04.04. Geology::04.04.12. Fluid Geochemistry ; 04. Solid Earth::04.08. Volcanology::04.08.01. Gases ; 04. Solid Earth::04.08. Volcanology::04.08.06. Volcano monitoring ; 04. Solid Earth::04.08. Volcanology::04.08.08. Volcanic risk
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  • 15
    Publikationsdatum: 2017-04-04
    Beschreibung: Research article
    Beschreibung: Quantifying the contribution of volcanism to global mercury (Hg) emissions is important to understand the pathways and the mechanisms of Hg cycling through the Earth's geochemical reservoirs and to assess its environmental impacts. While previous studies have suggested that degassing volcanoes might contribute importantly to the atmospheric budget of mercury, little is known about the amount and behaviour of Hg in volcanic aquifers. Here we report on detailed investigations of both the content and the speciation of mercury in aquifers of active volcanoes in Italy and Guadeloupe Island (Lesser Antilles). In the studied groundwaters, total Hg (THg) concentrations range from 10 to 500 ng/l and are lower than the 1000 ng/l threshold value for human health protection fixed by the World Health Organization [WHO (1993): WHO Guidelines for Drinking Water Quality- http://www.who.int/water_sanitation_health/GDWQ/index.htlm]. Positive co-variations of (THg) with sulphate indicate that Hg-SO4-rich acid groundwaters receive a direct input of magmatic/hydrothermal gases carrying mercury as Hg0 (gas). Increasing THg in a volcanic aquifer could thus be a sensitive tracer of magmatic gas input prior to an eruption. Since the complex behaviour and toxicity of mercury in waters depend on its chemical speciation, we carefully determined the different aqueous forms of this element in our samples.We find that dissolved elemental Hg0 (aq) and particulate-bound Hg (HgP) widely prevail in volcanic aquifers, in proportions that highlight the efficiency of Hg adsorption onto colloidal particles. Moreover, we observe that dissolved Hg0 aq and Hg(II) forms coexist in comparable amount in most of the waters, in stark contrast to the results of thermodynamic equilibrium modelling. Therefore, chemical equilibrium between dissolved mercury species in volcanic waters is either prevented by natural kinetic effects or not preserved in collected waters due to sampling/storage artefacts. Finally, we provide a first quantitative comparison of the relative intensity of aqueous transport and atmospheric emissions of mercury at Mount Etna, a very active basaltic volcano.
    Beschreibung: In press
    Beschreibung: 4.5. Degassamento naturale
    Beschreibung: JCR Journal
    Beschreibung: open
    Schlagwort(e): Fluid geochemistry ; volcanic mercury ; 04. Solid Earth::04.04. Geology::04.04.12. Fluid Geochemistry
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  • 16
    Publikationsdatum: 2017-04-04
    Beschreibung: Methane, the most abundant hydrocarbon in the atmosphere, plays an important role in the Earth’s atmospheric chemistry and radiative balance being the second most important greenhouse gas after CO2. Methane is released to the atmosphere by a wide number of sources, both natural and anthropogenic, with the latter being twice as large as the former (Kvenvolden and Rogers, 2005). It has recently been established that significant amounts of geological methane, produced within the Earth’s crust, are currently released naturally into the atmosphere (Etiope, 2004). Among natural sources the volcanic/geothermal emissions are probably the least constrained. Recent estimations for volcanic and geothermal systems in Europe (Etiope et al. 2007) gave a rather large provisional range (4-16 kt/a) that claims for much more field measurements in order to widen the current database and decrease the present uncertainties. Pantelleria is an active volcanic complex, at present in quiescent status, hosting a high enthalpy geothermal system. Explorative geothermal wells tapped an exploitable water-dominated reservoir at 600-800 m depth with maximum measured temperatures of 250 °C. While some data are available on diffuse CO2 fluxes, data on CH4 are available only for fumarolic fluids. In the present study we measured CH4 fluxes in the area of Favara Grande characterized by intense diffuse degassing and widespread signs of geothermal activity (fumaroles, steaming grounds and large zones devoid of vegetation). Values range from negative (-43 to 0 mgCH4 m2 day), typical of soils with methanotrophic activity, up to 3500 mgCH4 m2 day in the most thermalized area. The preliminary estimate of the methane release from the area of Favara Grande is about 2.5 t/a. Extrapolation to the whole volcanic/geothermal system of Pantelleria gives about 10 t/a.
    Beschreibung: Published
    Beschreibung: Davos, Switzerland
    Beschreibung: 1.2. TTC - Sorveglianza geochimica delle aree vulcaniche attive
    Beschreibung: 4.5. Studi sul degassamento naturale e sui gas petroliferi
    Beschreibung: open
    Schlagwort(e): soil gases ; methane output ; 04. Solid Earth::04.04. Geology::04.04.12. Fluid Geochemistry ; 04. Solid Earth::04.08. Volcanology::04.08.01. Gases
    Repository-Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
    Materialart: Poster session
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  • 17
    Publikationsdatum: 2017-04-04
    Beschreibung: The island of Vulcano (Aeolian arc, Southern Italy) has displayed several periods of volcanic unrest since the end of the last eruption (1890). We report here results obtained from a long-term survey concerning variations of both the steam output and the exhaling surface area at the sun~mit crater fumarolic field of La Fossa. The field measurements analysed in a Geographiciil Information System (GIS: show a highly dynamic volcanic system in which deep variations in the geochemishy and the temperature of the released fluids were accompanied by fluctuations in the mass output of steam and the topography of the crater field. The use of a GIS facilitated digitized reconstructions of maps of the crater field in addition to analysis (of the steam flux data. The furnarolic field expanded its surface area from 50 m2 in 1983 to more than 2400 m* in 1995, accompanied by an increase in steam output from 152 to about 1400 tonnes per day. The possibility that the observed phenomena are related to volcano-tectonic activity and to magma uprising is taken into consideration.
    Beschreibung: Published
    Beschreibung: 253-263
    Beschreibung: 1.2. TTC - Sorveglianza geochimica delle aree vulcaniche attive
    Beschreibung: JCR Journal
    Beschreibung: reserved
    Schlagwort(e): volcanic surveillance ; Steam output ; tectonic lines ; flux ; 04. Solid Earth::04.04. Geology::04.04.12. Fluid Geochemistry
    Repository-Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
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  • 18
    Publikationsdatum: 2017-04-04
    Beschreibung: On February 27, 2007 a new eruption started at Stromboli that lasted until April 2 and included a paroxysmal explosion on March 15. Geochemical monitoring carried out over several years revealed some appreciable variations that preceded both the eruption onset and the explosion. The carbon dioxide (CO2) flux from the soil at Pizzo Sopra La Fossa markedly increased a few days before the eruption onset, and continued during lava effusion to reach its maximum value (at 90,000 g m−2 d−1) a few days before the paroxysm. Almost contemporarily, the δ13CCO2 of the SC5 fumarole located in the summit area increased markedly, peaking just before the explosion (δ13CCO2~−1.8‰). Following the paroxysm, helium (He) isotopes measured in the gases dissolved in the basal thermal aquifer sharply increased. Almost contemporarily, the automatic station of CO2 flux recorded an anomalous degassing rate. Also temperatures and the vertical thermal gradient, which had been measured since November 2006 in the soil at Pizzo Sopra La Fossa, showed appreciable variabilities that lasted until the end of the eruption. The geochemical variations indicated the degassing of a new batch of volatile-rich magma that preceded and probably fed the paroxysm. The anomalous 3He/4He ratio suggested that the ascent of a second batch of volatile-rich magma toward the surface was probably responsible of the resumption of the ordinary activity. A comparison with the geochemical variations observed during the 2002–2003 eruption indicated that the 2007 eruption was less energetic.
    Beschreibung: Published
    Beschreibung: 246-254
    Beschreibung: 1.2. TTC - Sorveglianza geochimica delle aree vulcaniche attive
    Beschreibung: JCR Journal
    Beschreibung: reserved
    Schlagwort(e): geochemistry ; eruption ; dissolved gases ; Stromboli ; volcanic activity ; 03. Hydrosphere::03.02. Hydrology::03.02.03. Groundwater processes ; 03. Hydrosphere::03.04. Chemical and biological::03.04.03. Chemistry of waters ; 03. Hydrosphere::03.04. Chemical and biological::03.04.05. Gases ; 03. Hydrosphere::03.04. Chemical and biological::03.04.06. Hydrothermal systems ; 04. Solid Earth::04.04. Geology::04.04.12. Fluid Geochemistry ; 04. Solid Earth::04.08. Volcanology::04.08.01. Gases ; 04. Solid Earth::04.08. Volcanology::04.08.06. Volcano monitoring ; 05. General::05.02. Data dissemination::05.02.01. Geochemical data ; 05. General::05.02. Data dissemination::05.02.03. Volcanic eruptions
    Repository-Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
    Materialart: article
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  • 19
    Publikationsdatum: 2017-04-04
    Beschreibung: Neogene intermontane basins in Almería Province, SE Spain, display excellent exposures of Messinian (Late Miocene) sequences. The Sorbas, Almería-Níjar and Vera basins maintained connection with the Mediterranean throughout the Messinian, except during the major desiccation phase leading to the formation of salt in the deep centre of the Western Mediterranean. These basins were part of the Western Mediterranean with no separate link to the Atlantic Ocean. The presence of normal marine sediments in these basins reflects the Western Mediterranean watermass. Messinian pre-evaporitic sediments in the basins of southeastern Almería do not show gradual change towards evaporite deposits. Instead they contain stenohaline invertebrates right up to a major erosion surface that separates them from overlying gypsum deposits. This contradicts suggestion of progressive salinity increase in this part of the Western Mediterranean prior to the Messinian Salinity Crisis (MSC); it also indicates that initiation of evaporite precipitation was not synchronous throughout the Mediterranean Basin. There is no major erosion surface within or at the top of the evaporites in these Almería basins, and the gypsum beds exhibit upward transition to siliciclastic and carbonate deposits. This is inconsistent with a model of Messinian Mediterranean evaporite formation whereby deposition of marginal evaporites was followed by their erosion during drawdown that resulted in formation of evaporites in the centre of the Western Mediterranean. The presence of stenohaline biotas in siliciclastic deposits interbedded with the gypsum and in the Messinian post-evaporitic sediments, challenges the view that a long-standing large body of brackish water (the Lago Mare) filled the Western Mediterranean following the MSC and prior to Early Pliocene flooding. It also contradicts the concept of many relatively small brackish basins spread across an otherwise desiccated Western Mediterranean basin. The basins of southeastern Almería record normal marine Early Messinian sedimentation that was abruptly interrupted by sealevel fall. This drawdown most likely resulted in precipitation of evaporites in the central deep Western Mediterranean basin. Following this episode, final marine reflooding of the Western Mediterranean took place during the Late Messinian, and the Mediterranean Sea rose to a level similar to, or higher than, that preceding the Salinity Crisis.
    Beschreibung: Published
    Beschreibung: 131-154
    Beschreibung: 2.2. Laboratorio di paleomagnetismo
    Beschreibung: JCR Journal
    Beschreibung: reserved
    Schlagwort(e): Almería ; Evaporites ; Messinian Salinity Crisis ; Palaeoenvironments ; Western Mediterranean ; Spain ; 03. Hydrosphere::03.01. General::03.01.06. Paleoceanography and paleoclimatology ; 04. Solid Earth::04.05. Geomagnetism::04.05.06. Paleomagnetism
    Repository-Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
    Materialart: article
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  • 20
    Publikationsdatum: 2017-04-04
    Beschreibung: A new method combining measurements of soil CO2 flux and determinations of the carbon isotopic composition of soil CO2 efflux was developed in order to qualitatively and quantitatively characterise the CO2 source feeding the soil CO2 diffuse degassing. The method was tested in March 2007 at the Solfatara of Pozzuoli volcano degassing area (Naples, Italy) where more than 300 measurements of soil CO2 flux and determinations of the carbon isotopic composition of soil CO2 efflux were performed, surveying Solfatara crater and its surroundings. The wide range of CO2 flux and CO2 isotopic composition values (from 8.4 g m−2 d−1 to 28,834 g m−2 d−1, and from 0.73‰ to −33.54‰, respectively), together with their statistical distributions suggests the occurrence of multiple CO2 sources feeding soil degassing. The combined interpretation of flux and isotopic data allows us to identify and characterise two distinct gas sources: a hydrothermal and a biogenic source. The soil CO2 from the hydrothermal source is characterised by a mean δ13CCO2 of −2.3‰±0.9‰, hence close to the isotopic composition of the fumarolic CO2 (δ13CCO2=−1.48‰± 0.22‰) and by a mean CO2 flux of 2875 g m−2 d−1. The CO2 from the biogenic source is characterised by a mean δ13CCO2 of −19.4‰±2.1‰, and by a mean CO2 flux of 26 g m−2 d−1, which are both in the range of the typical values for biologic CO2 soil degassing. This reliable characterisation of the biogenic CO2 flux would not have been possible by solely applying a statistical analysis of the CO2 flux values, which is commonly applied in volcanological studies for the partitioning between background fluxes and anomalous CO2 fluxes. A map of the Solfatara diffuse degassing structure was derived from the estimated threshold for the biogenic CO2 flux, highlighting that soil degassing of hydrothermal CO2 mixed in different proportion with biogenic CO2 occurs over a large area (~0.8 km2), which extends over the inner part of the Solfatara crater as well as the eastern periphery, corresponding with a NW–SE fault system. The presented method and data analysis are important means of surveillance of the volcanic activity.
    Beschreibung: Published
    Beschreibung: 372–379
    Beschreibung: 1.2. TTC - Sorveglianza geochimica delle aree vulcaniche attive
    Beschreibung: 2.4. TTC - Laboratori di geochimica dei fluidi
    Beschreibung: 4.5. Degassamento naturale
    Beschreibung: JCR Journal
    Beschreibung: reserved
    Schlagwort(e): CO2 soil degassing ; CO2 flux ; carbon dioxide ; carbon isotopes ; 03. Hydrosphere::03.04. Chemical and biological::03.04.05. Gases ; 03. Hydrosphere::03.04. Chemical and biological::03.04.06. Hydrothermal systems ; 04. Solid Earth::04.04. Geology::04.04.12. Fluid Geochemistry ; 04. Solid Earth::04.08. Volcanology::04.08.01. Gases
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  • 21
    Publikationsdatum: 2017-04-04
    Beschreibung: Lake Averno is situated in the homonymous crater in the northwestern sector of the Campi Flegrei active volcanic system in Campania region, Italy. In February 2005 a fish kill event was observed in the lake, prompting a geochemical survey to ascertain the possible cause. In February 2005 a geochemical survey revealed that the lake water was unstratified chemically and isotopically, presumably, as a result of lake overturn. This fish kill phenomenon was recorded at least two other times in the past. In contrast to the February 2005 results, data collected in October 2005, shows the Lake Averno to be stratified, with an oxic epilimnion (surface to 6 m) and an anoxic hypolimnion (6 m to lake bottom at about 33 m). Chemical and isotopic compositions of Lake Averno waters suggest an origin by mixing of shallow waters with a Na–Cl hydrothermal component coupled with an active evaporation process. The isotopic composition of Dissolved Inorganic Carbon, as well as the composition of the non-reactive dissolved gas species again supports the occurrence of this mixing process. Decreasing levels of SO4 and increasing levels of H2S and CH4 contents in lake water with depth, strongly suggests anaerobic bacterial processes are occurring through decomposition of organic matter under anoxic conditions in the sediment and in the water column. Sulfate reduction and methanogenesis processes coexist and play a pivotal role in the anaerobic environment of the Lake Averno. The sulfate reducing bacterial activity has been estimated in the range of 14–22 μmol m−2 day−1. Total gas pressure of dissolved gases ranges between 800 and 1400 mbar, well below the hydrostatic pressure throughout the water column, excluding the possibility, at least at the survey time, of a limnic eruption. Vertical changes in the density of lake waters indicate that overturn may be triggered by cooling of epilimnetic waters below 7 °C. This is a possible phenomenon in winter periods if atmospheric temperatures remain frosty for enough time, as occurred in February 2005. The bulk of these results strongly support the hypothesis that fish kill was caused by a series of events that began with the cooling of the epilimnetic waters with breaking of the thermal stratification, followed by lake overturn and the rise of toxic levels of H2S from the reduced waters near the lake bottom.
    Beschreibung: Published
    Beschreibung: 305–316
    Beschreibung: 1.2. TTC - Sorveglianza geochimica delle aree vulcaniche attive
    Beschreibung: 2.4. TTC - Laboratori di geochimica dei fluidi
    Beschreibung: 4.5. Degassamento naturale
    Beschreibung: JCR Journal
    Beschreibung: reserved
    Schlagwort(e): lake Averno ; dissolved gases ; stable isotopes ; stable isotopes ; 03. Hydrosphere::03.04. Chemical and biological::03.04.05. Gases ; 03. Hydrosphere::03.04. Chemical and biological::03.04.06. Hydrothermal systems ; 04. Solid Earth::04.04. Geology::04.04.12. Fluid Geochemistry ; 04. Solid Earth::04.08. Volcanology::04.08.06. Volcano monitoring
    Repository-Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
    Materialart: article
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  • 22
    Publikationsdatum: 2017-04-04
    Beschreibung: The Early/Middle Eocene (Ypresian/Lutetian) transition is represented by a hiatus in many North European sections, including those in which the classic stratotypes were originally defined. However, the Global Stratotype Section and Point of the Lutetian Stage, which is still pending definition, should be placed at a globally correlatable event included within that unrepresented interval. The Pyrenean Eocene outcrops display sedimentary successions that offer the rare opportunity to analyse the Ypresian/Lutetian boundary interval in almost continuous sections and in very different settings. Seven reference stratigraphic sections were selected on the basis of their quality and correlated by means of biomagnetostratigraphic data. This correlation framework casts light on the sequence of chronostratigraphic events that characterize the Ypresian/Lutetian boundary interval, which may prove useful in defining the main correlation criterion of the base of the Lutetian. All of the Pyrenean sections show a similar sedimentary evolution, despite being up to 350 km apart from each other, containing deposits of different origins (intrabasinal carbonate sediments, siliciclastic sediments sourced from the Iberian plate, and terrigenous sediments sourced from the uplifting Pyrenees) and despite having been accumulated in different sedimentary environments (from continental to deep marine) and in different geodynamic settings (piggy-back basin, foreland basin and cratonic margin). This common evolution can be readily interpreted in terms of a sea-level driven depositional sequence whose lowstand and transgressive systems tracts are included within the Ypresian/Lutetian boundary interval. The Pyrenean Ypresian/Lutetian depositional sequence can reasonably be correlated with depositional sequences from classic North European areas, shedding light on the palaeoenvironmental history which in those areas has not been recorded. Furthermore, these depositional sequences may possibly correlate with others from the Antarctic Ocean and from New Jersey, as well as with oceanic temperature variations, suggesting that they might be the result of climatically-driven glacioeustatic sea-level changes. Should this hypothesis prove correct, it would confirm previous suggestions that the onset of Antarctic glaciations needs to be backshifted to the late Ypresian at least.
    Beschreibung: Published
    Beschreibung: 313-332
    Beschreibung: 2.2. Laboratorio di paleomagnetismo
    Beschreibung: JCR Journal
    Beschreibung: reserved
    Schlagwort(e): Eocene ; Lutetian ; Chronostratigraphy ; Sequence stratigraphy ; Climate ; Pyrenees ; 03. Hydrosphere::03.01. General::03.01.06. Paleoceanography and paleoclimatology ; 04. Solid Earth::04.04. Geology::04.04.10. Stratigraphy ; 04. Solid Earth::04.05. Geomagnetism::04.05.02. Geomagnetic field variations and reversals ; 04. Solid Earth::04.05. Geomagnetism::04.05.06. Paleomagnetism
    Repository-Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
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  • 23
    Publikationsdatum: 2017-04-04
    Beschreibung: Chemical and isotopic analyses of the main gas manifestations of the island of Pantelleria (Italy) were used to gain insight on the origin of the released methane. Results indicate that the most probable origin is through abiogenic reactions within the hydrothermal system. Methane and CO2 flux measurements from the soils were made with the accumulation chamber method in an area of about 0.015 km2 within the main fumarolic area of the island (Favara Grande). The 23 measurements range from –34 to 3550 mg m-2 d-1 for CH4 and from 0.6 to 379 g m-2 d-1 for CO2. The relationships between CH4 and CO2 fluxes and the CH4/CO2 ratios in the gases collected between 25 and 100 cm depth provide evidence for methanotrophic processes within the soils. Methane output for the surveyed area was calculated in 2.5 t a-1 and extrapolated to about 5-10 t a-1 for the entire volcanic/hydrothermal system of the island. Previous higher estimates of the CH4 output at Pantelleria (Etiope et al., 2007 - J. Volcanol. Geotherm. Res., 165, 76 – 86) were based on soil CO2 output and CH4/CO2 ratios in fumarolic gases; the present work provides the first direct CH4 flux data and it suggests that methanotrophic activity in the soil could be substantial in reducing the CH4 emission to the atmosphere.
    Beschreibung: Published
    Beschreibung: 147-157
    Beschreibung: 1.2. TTC - Sorveglianza geochimica delle aree vulcaniche attive
    Beschreibung: 4.5. Studi sul degassamento naturale e sui gas petroliferi
    Beschreibung: JCR Journal
    Beschreibung: reserved
    Schlagwort(e): hydrothermal systems ; gas geochemistry ; isotope composition ; methane output ; methanotrophic consumption ; 01. Atmosphere::01.01. Atmosphere::01.01.07. Volcanic effects ; 04. Solid Earth::04.04. Geology::04.04.12. Fluid Geochemistry ; 04. Solid Earth::04.08. Volcanology::04.08.01. Gases
    Repository-Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
    Materialart: article
    Standort Signatur Erwartet Verfügbarkeit
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  • 24
    Publikationsdatum: 2024-05-09
    Beschreibung: A geochemical survey of thermal waters collected from submarine vents at Panarea Island (Aeolian Islands, southern Italy) was carried out from December 2002 to March 2007, in order to investigate i) the geochemical processes controlling the chemical composition of the hydrothermal fluids and ii) the possible relations between the chemical features of the hydrothermal reservoir and the activity of the magmatic system. Compositional data of the thermal water samples were integrated in a hydrological conceptual model, which describes the formation of the vent fluid by mixing of seawater, seawater concentrated by boiling, and a deep, highly-saline end-member, whose composition is regulated by water-rock interactions at relatively high temperature and shows clear clues of magmatic-related inputs. The chemical composition of concentrated seawater was assumed to be represented by that of the water sample having the highest Mg content. The composition of the deep end-member was instead calculated by extrapolation assuming a zero-Mg end-member. The Na–K–Ca geothermometer, when applied to the thermal end-member composition, indicated an equilibrium temperature of approximately 300 °C, a temperature in agreement with the results obtained by gas-geothermometry.
    Beschreibung: Published
    Beschreibung: 246-254
    Beschreibung: 3V. Proprietà chimico-fisiche dei magmi e dei prodotti vulcanici
    Beschreibung: JCR Journal
    Beschreibung: reserved
    Schlagwort(e): low-pH waters; shallow submarine hydrothermal springs; Panarea Island ; 04. Solid Earth::04.04. Geology::04.04.12. Fluid Geochemistry
    Repository-Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
    Materialart: article
    Standort Signatur Erwartet Verfügbarkeit
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