ALBERT

Beschreibung: Methane (CH4) concentration and stable isotope (δ2H-CH4 and δ13C-CH4) depth distributions show large differences in the water columns of the Earth's largest CH4-containing anoxic basins, the Black Sea and Cariaco Basin. In the deep basins, the between-basin stable isotope differences are large, 83‰ for δ2H-CH4 and 9‰ for δ13C-CH4, and the distributions are mirror images of one another. The major sink in both basins, anaerobic oxidation of CH4, results in such extensive isotope fractionation that little direct information can be obtained regarding sources. Recent measurements of natural 14C-CH4 show that the CH4 geochemistry in both basins is dominated (∼64 to 98%) by inputs of fossil (radiocarbon-free) CH4 from seafloor seeps. We derive open-system kinetic isotope effect equations and use a one-dimensional (vertical) stable isotope box model that, along with isotope budgets developed using radiocarbon, permits a quantitative treatment of the stable isotope differences. We show that two main factors control the CH4 concentration and stable isotope differences: (1) the depth distributions of the input of CH4 from seafloor seeps and (2) anaerobic oxidation of CH4 under open-system steady state conditions in the Black Sea and open-system non-steady-state conditions in the Cariaco Basin.

Beschreibung: A series of 500 years long coupled general circulation model simulations has been performed, in which the sea surface temperatures (SSTs) in different tropical oceans have been prescribed from climatology. A statistically significant reduction by about one Sverdrup of the meridional overturning circulation (MOC) in the North Atlantic was found when the tropical Pacific SSTs do not vary interannually. Anomalously low salinities originating in the tropical Atlantic due to increased precipitation drive the reduction of the MOC. Climatological SSTs in the tropical Pacific lead to a “La Niña”-like state due to the nonlinear response of the atmosphere to SST anomalies. The shift of the mean atmospheric circulation in the tropical Pacific leads to a cyclonic anomaly over the eastern tropical Atlantic with a corresponding precipitation increase. The results suggest that changes in the SST variability of the tropical Pacific can drive changes in the mean state of remote regions.

Beschreibung: Uptake of half of the fossil fuel CO2 into the ocean causes gradual seawater acidification. This has been shown to slow down calcification of major calcifying groups, such as corals, foraminifera, and coccolithophores. Here we show that two of the most productive marine calcifying species, the coccolithophores Coccolithus pelagicus and Calcidiscus leptoporus, do not follow the CO2-related calcification response previously found. In batch culture experiments, particulate inorganic carbon (PIC) of C. leptoporus changes with increasing CO2 concentration in a nonlinear relationship. A PIC optimum curve is obtained, with a maximum value at present-day surface ocean pCO2 levels (∼360 ppm CO2). With particulate organic carbon (POC) remaining constant over the range of CO2 concentrations, the PIC/POC ratio also shows an optimum curve. In the C. pelagicus cultures, neither PIC nor POC changes significantly over the CO2 range tested, yielding a stable PIC/POC ratio. Since growth rate in both species did not change with pCO2, POC and PIC production show the same pattern as POC and PIC. The two investigated species respond differently to changes in the seawater carbonate chemistry, highlighting the need to consider species-specific effects when evaluating whole ecosystem responses. Changes of calcification rate (PIC production) were highly correlated to changes in coccolith morphology. Since our experimental results suggest altered coccolith morphology (at least in the case of C. leptoporus) in the geological past, coccoliths originating from sedimentary records of periods with different CO2 levels were analyzed. Analysis of sediment samples was performed on six cores obtained from locations well above the lysocline and covering a range of latitudes throughout the Atlantic Ocean. Scanning electron micrograph analysis of coccolith morphologies did not reveal any evidence for significant numbers of incomplete or malformed coccoliths of C. pelagicus and C. leptoporus in last glacial maximum and Holocene sediments. The discrepancy between experimental and geological results might be explained by adaptation to changing carbonate chemistry.

Beschreibung: Valu Fa Ridge is an intraoceanic back-arc spreading center located at the southern prolongation of the Lau basin. Bathymetric observations as well as detailed sampling have been carried out along the spreading axis in order to trace hydrothermal and volcanic activity and to study magma generation processes. The survey shows that widespread lava flows from recent volcanic eruptions covered most of the Vai Lili hydrothermal vent field; only diffuse low-temperature discharge and the formation of thin layers of siliceous precipitates have been observed. Evidence of present-day hydrothermal activity at the Hine Hina site is indicated by a thermal anomaly in the overlying water column. Our studies did not reveal any signs of hydrothermal activity either above the seismically imaged magma chamber at 22°25′S or across the southern rift fault zone (22°51′S). Lavas recovered along the Valu Fa Ridge range from basaltic andesites to rhyolites with SiO2 contents higher than reported from any other intraoceanic back-arc basin. On the basis of the highly variable degrees of crystal fractionation along axis, the development of small disconnected magma bodies is suggested. In addition, the geochemical character of the volcanic rocks shows that the transition zone from oceanic spreading to propagating rifting is located south of the Hine Hina vent field in the vicinity of 22°35′S.

Beschreibung: The impacts of the tropical Indian and Atlantic Oceans on ENSO are studied using a series of 500 years long GCM simulations, in which the tropical Indian and/or Atlantic Ocean SSTs are fixed. The results indicate that the tropical Indian and/or Atlantic Oceans SST anomalies substantially influence the coupling over the equatorial Pacific. In the absence of SST variability in the tropical Indian and/or Atlantic Ocean, the main ENSO period is shifted by almost one year. The total SST variance in the equatorial Pacific region is reduced if either Indian or Atlantic Ocean variability is present. At the same time the atmospheric ENSO teleconnections are damped more strongly than the SST. The results can be understood in the context of the recharge oscillator model. However, it is difficult to verify the feedback of the Indian and/or Atlantic Oceans onto ENSO only with statistical analyses of the coupled model control integration or observations.

Beschreibung: The structure of the subtropical South Indian Ocean Countercurrent (SICC) is revealed by altimeter-derived absolute geostrophic surface velocities. It is a narrow, eastward-flowing current between 22° and 26°S confined to planetary wave trains which propagate westward through the Indian Ocean. Multi-year averaging identifies it as a well-defined current between Madagascar and 80°E, continuing with lower intensity between 90° and 100°E. It virtually coincides with the northern limit of Subtropical Underwater subduction. Geostrophic currents from hydrographic sections closely correspond to these surface patterns. Volume transports of the countercurrent down to 800 dbar are of order (107 m3 s−1). Evidence is provided for a narrow branch of the South Equatorial Current (SEC) approaching Madagascar near 18°S and feeding the southern East Madagascar Current (EMC) which appears to continue westward around the southern tip of Madagascar. It then partially retroflects and nourishes the SICC.

Beschreibung: CTD measurements carried out in the southern Adriatic Sea and in the western Ionian basin (Eurafrican Mediterranean Sea) during May 2003 by the German research vessel Poseidon (Poseidon cruise 298) and numerical simulations are used to elucidate aspects of the abyssal circulation of this oceanic region. The observations reveal that dense waters of Adriatic origin were strongly diluted along their way on the Italian continental slope, whilst their characteristics remained better preserved in a region located further east. Numerical simulations carried out by means of a nonlinear, reduced-gravity plume model confirm the observations and contribute to explain their cause: The very steep topographic slope along the Italian shelf in the region of the Gulf of Taranto induces strong entrainment of intermediate waters in the bottom layers. Instead, the bottom waters of Adriatic origin which, along their path further east, encounter gentler topographic variations, are weakly diluted by turbulent mixing and, therefore, better preserve their original characteristics. The remarkable differences in the simulated turbulent mixing along these two different paths are accentuated by the presence of a noticeable zonal gradient of potential density existing in the near-bottom layers of the northern Ionian basin.

Beschreibung: The extent of the Yermak Slide has been revised on the basis of new acoustic and detailed bathymetric data. The true geometry, with an affected area of at least 10,000 km2 and more than 2400 km3 of involved sedimentary material, puts the Yermak Slide among the largest exposed submarine slides worldwide, comparable to the Storegga Slide off central Norway. Details from the side's internal structure give evidence for one main slide event during MIS 3 followed by repeated minor events. The timing coincides with the transition of the Kapp Ekholm Interstadial into Glaciation G of Svalbard (Mangerud et al., 1998) and the buildup phase of the Svalbard-Barents Sea Ice Sheet. Thus the slide occurred during a period of falling sea level, increasing ice volume, and, presumably, increasing glaciotectonic activity. The side's geometry and internal physical appearance point to a tectonically induced partial shelf collapse.

Beschreibung: Surface seawater pCO2 and related parameters were measured at high frequency onboard the volunteer observing ship M/V Falstaff in the North Atlantic Ocean between 36° and 52°N. Over 90,000 data points were used to produce monthly CO2 fluxes for 2002/2003. The air-sea CO2 fluxes calculated by two different averaging schemes were compared. The first approach used gas transfer velocity determined from wind speed retrieved at the location of the ship and called colocated winds, while for the second approach a monthly averaged gas transfer velocity was calculated from the wind for each grid pixel including the variability in wind. The colocated wind speeds determined during the time of passage do not capture the monthly wind speed variability of the grid resulting in fluxes that were 47% lower than fluxes using the monthly averaged wind products. The Falstaff CO2 fluxes were in good agreement with a climatology using averaged winds. Over the entire region they differed by 2–5%, depending on the time-dependent correction scheme to account for the atmospheric in increase in pCO2. However, locally the flux differences between the ship measurements and the climatology were greater, especially in regions north of 45°N, like the eastern sector. A comparison of two wind speed products showed that the annual CO2 sink is 4% less when using 6 hourly NCEP/NCAR wind speeds compared to the QuikSCAT wind speed data.

Beschreibung: Bubbles evolving from active gas seeps can be traced by hydroacoustic imaging up to 1000 m high in the Black Sea water column. Although methane concentrations are not distinguishable between the water column above the deep seep and reference sites, atmospheric noble gas measurements clearly show the constant input of gases (mainly methane) via seepage into the Black Sea. Archaea (ANME-1, ANME-2) and methanotrophic bacteria detected with specific 16S rRNA-targeted oligonucleotide probes are related to active gas seeps in the oxic and anoxic water column. It is suggested that methane seeps have a much greater influence on the Black Sea methane budget than previously acknowledged and that ANME-1 and ANME-2 are injected via gas bubbles from the sediment into the anoxic water column mediating methane oxidation. Our results show further that only minor amounts of methane evolving from Black Sea gas seeps reach the atmosphere due to the very effective microbial barrier. Hence only major thermodynamically and/or tectonically triggered gas hydrate dissociation has the potential to induce rapid climate changes as suggested by the “clathrate gun hypothesis.”

Beschreibung: The zonal equatorial circulation of the upper 700 m in the central tropical Atlantic is studied based on 11 cross-equatorial ship sections taken at 23–29°W during 1999 to 2005 and on data from a pair of moored Acoustic Doppler current profilers deployed on the equator at 23°W during February 2004 to May 2005. The observations on the equator reveal the existence of two mean westward cores of the Equatorial Intermediate Current below the Equatorial Undercurrent. In contrast to the 2002 moored observations at the same position the intraseasonal variability during the mooring period is dominated by zonal instead of meridional velocity fluctuations.

Beschreibung: The investigations carried out between 2002 and 2004 during six field experiments within the Operational Radar and Optical Mapping in monitoring hydrodynamic, morphodynamic and environmental parameters for coastal management (OROMA) project aimed to improve the effectiveness of new remote sensing monitoring technologies such as shipborne imaging radars in coastal waters. The coastal monitoring radar of the GKSS Research Center, Geesthacht, Germany, is based on a Kelvin Hughes RSR 1000 X band (9.42 GHz) vertical (VV) polarized river radar and was mounted on board the research vessel Ludwig Prandtl during the experiments in the Lister Tief, a tidal inlet of the German Bight in the North Sea. The important progress realized in this investigation is the availability of calibrated X band radar data. Another central point of the study is to demonstrate the applicability of the quasi-specular scattering theory in combination with the weak hydrodynamic interaction theory for the radar imaging mechanism of the seabed. Radar data have been taken at very low grazing angles ≤2.6° of flood and ebb tide–oriented sand wave signatures at the sea surface during ebb tidal current phases. Current speeds perpendicular to the sand wave crest ≤0.6 m s−1 have been measured at wind speeds ≤4.5 m s−1 and water depths ≤25 m. The difference between the maximum measured and simulated normalized radar cross section (NRCS) modulation of the ebb tide–oriented sand wave is 27%. For the flood tide–oriented sand wave, a difference of 21% has been calculated. The difference between the minimum measured and simulated NRCS modulation of the ebb tide–oriented sand wave is 10%, and for the flood tide–oriented sand wave, a value of 43% has been derived. Phases of measured and simulated NRCS modulations correspond to asymmetric sand wave slopes. The results of the simulated NRCS modulation show the qualitative trend but do not always quantitatively match the measured NRCS modulation profiles because the quasi-specular scattering theory at very low grazing angle is a first-order theory.

Beschreibung: There is growing concern about the transfer of methane originating from water bodies to the atmosphere. Methane from sediments can reach the atmosphere directly via bubbles or indirectly via vertical turbulent transport. This work quantifies methane gas bubble dissolution using a combination of bubble modeling and acoustic observations of rising bubbles to determine what fraction of the methane transported by bubbles will reach the atmosphere. The bubble model predicts the evolving bubble size, gas composition, and rise distance and is suitable for almost all aquatic environments. The model was validated using methane and argon bubble dissolution measurements obtained from the literature for deep, oxic, saline water with excellent results. Methane bubbles from within the hydrate stability zone (typically below ∼500 m water depth in the ocean) are believed to form an outer hydrate rim. To explain the subsequent slow dissolution, a model calibration was performed using bubble dissolution data from the literature measured within the hydrate stability zone. The calibrated model explains the impressively tall flares (〉1300 m) observed in the hydrate stability zone of the Black Sea. This study suggests that only a small amount of methane reaches the surface at active seep sites in the Black Sea, and this only from very shallow water areas (〈100 m). Clearly, the Black Sea and the ocean are rather effective barriers against the transfer of bubble methane to the atmosphere, although substantial amounts of methane may reach the surface in shallow lakes and reservoirs.

Beschreibung: A coupled ecosystem-circulation model of the North Atlantic is used to examine the individual contributions by wind stress and surface heat fluxes to naturally driven interannual-to-decadal variability of air-sea fluxes of CO2 and O2 during 1948–2002. The model results indicate that variations in O2 fluxes are mainly driven by variations in surface heat fluxes in the extratropics (15°N to 70°N), and by wind stress in the tropics (10°S to 15°N). Conversely, variations in simulated CO2 fluxes are predominantly wind-stress driven over the entire model domain (18°S to 70°N); while variability in piston velocity and surface heat fluxes is less important. The simulated uptake of O2 by the North Atlantic amounts to 70 ± 11 Tmol yr−1 to which the subpolar region (45°N to 70°N) contributes by 62 ± 10 Tmol yr−1. Whereas the subpolar North Atlantic takes up more than 2/3 of the total carbon absorbed by the North Atlantic in our model (about 0.3 Pg C yr−1), interannual variability of air-sea CO2 fluxes reaches similar values (about 0.01 Pg C yr−1 each) in the subpolar (45°N to 70°N), the subtropical (15°N to 45°N) and the equatorial (10°S to 15°N) Atlantic.

Beschreibung: Direct observations at the Grand Banks have raised a quandary concerning the pathways of the lower branch of the meridional overturning circulation: In contrast to moored current meters that depict an intense, narrow Deep Western Boundary Current (DWBC), observations using different float types failed to show this continuous export path. Here, this issue is addressed by a Lagrangian analysis of synthetic particles in an eddy-resolving circulation model. Due to intense eddy activity around the Grand Banks, about 40% of the deep water in the DWBC is diverted into the interior, spreading southward along the western flank of the Mid-Atlantic Ridge or with the eddying flow field in the basin interior. Imposing constraints on the vertical displacements of particles similar to those experienced by observational floats further reduces their adherence to the DWBC, particularly near the southern tip of the Grand Banks.

Beschreibung: Atmospheric radiative transfer plays a central role in understanding global climate change and anthropogenic climate forcing, and in the remote sensing of surface and atmospheric properties. Because of their opacity and highly scattering nature, clouds (covering more than half the planet at any time) pose unique challenges in atmospheric radiative transfer calculations. Some widely-used assumptions regarding clouds—such as having a flat top and base, horizontal uniformity, and infinite extent—are amenable to simple one-dimensional (1-D) radiative transfer and are therefore attractive from a computational point of view. However, these assumptions are completely unrealistic and yield errors. The ever-increasing need to realistically simulate cloud radiative processes in remote sensing and energy budget applications has contributed to the recent rapid growth of the three-dimensional (3-D) radiative transfer (RT) community [e.g., Marshak and Davis, 2005].

Beschreibung: Thickness diffusivity (κ) according to the Gent and McWilliams parameterisation which accounts for eddy-driven advection in the ocean, is estimated using output from an eddy-resolving model of the Southern Ocean. A physically meaningful definition of rotational eddy fluxes leads almost everywhere to positive κ. Zonally averaged near surface values of κ remain smaller than 200 m2/s poleward of the polar front, increases between 60–45°S to about 600 m2/s and peak between 45–35° S at almost 3000 m2/s. κ stays high in the upper 500 m but decreases with depth and is essentially zero below 2500 m. In addition to the thickness diffusion (κ) there is eddy-induced eastward (westward) advection of isopycnal thickness at the poleward (equatorward) flank of the ACC pointing toward strong anisotropic lateral mixing.

Beschreibung: As one of the few places in the ocean where winter cooling and mixing creates conditions where water from the surface can penetrate into the deep ocean the Labrador Sea is an area of interest to people studying climate change in the ocean. Persistent cloud cover over this area makes it impossible to use infrared satellite imagery to relate space/time changes in sea surface temperature (SST) to changes in surface currents and air-sea interaction. Using passive microwave SSTs from the Advanced Microwave Scanning Radiometer (AMSR-E), we plot space/time changes in SST in the Labrador Sea and relate these changes to both simultaneous in situ measurements of temperature and numerical model SSTs. A direct comparison between the microwave SSTs, infrared SSTs, and in situ temperatures measured from profiling floats reveals that the microwave SSTs are a good representation of space/time changes in infrared SST and in ocean temperatures down to 10 m below the sea surface. Comparisons between the microwave SSTs and time series of temperatures at depths below 50 m reveal that winter/spring surface cooling makes the SST similar to temperatures at these deeper depths in the convection region of the central Labrador Sea. Detailed comparison of the annual cycle between the microwave SSTs and the model SST and 10 m currents reveals overall good agreement and some interesting differences.

Beschreibung: Long term mooring observations show a substantial warming of the Deep Labrador Current (DLC) during the last decade. In this paper we address the question of whether these water mass changes are accompanied by comparable changes in the deep western boundary current. Individual estimates of alongshore current from moored instruments and transports from Lowered ADCP sections indicate a systematic increase of the boundary current strength on the order of 15% of the mean from the period prior to 1999 to the period thereafter. A combination of these measurements allows the indexing of DLC intensity over the last decade.

Beschreibung: A new criterion, based on the shallowest extreme curvature of near surface layer density or temperature profiles, is established for demarking the mixed layer depth, h mix. Using historical global hydrographic profile data, including conductivity-temperature-depth and expendable bathythermograph data obtained during World Ocean Circulation Experiment, its seasonal variability and monthly to interannual anomalies are computed. Unlike the more commonly used Δ criterion, the new criterion is able to deal with both different vertical resolutions of the data set and a large variety of observed stratification profiles. For about two thirds of the profiles our algorithm produces an h mix/c that is more reliable than the one of the Δ criterion. The uncertainty for h mix/c is ±5 m for high- (〈5 m) and ±8 m for low- (〈20 m) resolution profiles. A quality index, QImix, which compares the variance of a profile above h mix to the variance to a depth of 1.5 × h mix, shows that for the 70% of the profile data for which a clearly recognizable well-mixed zone exists near the surface, our criterion identifies the depth of the well-mixed zone in all cases. The standard deviation of anomalous monthly h mix/c is typically 20–70% of the long-term mean h mix/c . In the tropical Pacific the monthly mean anomalies of h mix/c are not well correlated with anomalies of sea surface temperature, which indicate that a variety of turbulent processes, other than surface heat fluxes, are important in the upper ocean there. Comparisons between observed h mix/c and Massachusetts Institute of Techonology/ocean general circulation model/Estimating the Circulation and Climate of the Ocean model simulated mixed layer depth indicate that the KPP algorithm captures in general a 30% smaller mixed layer depth than observed.

Beschreibung: The Madeira-Tore Rise, located ∼700 km off the NW African coast, forms a prominent ridge in the east Atlantic. The age and origin of the rise are controversial. This study presents major and trace element, Sr, Nd, Pb, Hf isotope and 40Ar/39Ar age determinations from volcanic rocks dredged from different sites along the rise. In addition, isotopic compositions of rock samples from Great Meteor Seamount in the central Atlantic are presented. The new radiometric and paleontologically constrained ages identify two major episodes of volcanism: The first is the base of the rise (circa 80 to 〉95 Ma) and the second is seamounts on the rise (0.5–16 Ma). It is proposed that interaction of the Canary hot spot with the Mid-Atlantic spreading center formed the deep basement of the Madeira-Tore Rise and the J-Anomaly Ridge west of the Atlantic spreading center in the Mid-Cretaceous. Age and geochemical data and plate tectonic reconstructions suggest, however, that the recovered Late Cretaceous volcanic rocks represent late stage volcanism from the time when the Madeira-Tore Rise was still close to the Canary hot spot. Long after moving away from the influence of the Canary hot spot, the Madeira-Tore Rise was overprinted by late Cenozoic volcanism. Miocene to Pleistocene volcanism at the northern end of the rise can be best explained by decompression mantle melting beneath extensional sectors of the Azores-Gibraltar Fracture Zone (African-Eurasian plate boundary). The geochemical compositions of these volcanic rocks suggest that the magmas were variably contaminated by enriched material within or derived by melting of enriched material underplated at the base of the lithosphere, possibly originating from the Cretaceous Canary plume. Alternatively, these late Cenozoic volcanic rocks may have derived from decompression melting of enriched pyroxenitic/eclogitic material in the upper mantle. Isotopically more depleted Pliocene to Pleistocene volcanism at the southern end of the Madeira-Tore Rise may be related to the nearby Madeira hot spot.

Beschreibung: Mooring records collected in the central Labrador Sea are evaluated regarding the variability of the hydrographic properties of newly formed Labrador Sea Water (LSW) between 1994 and 2005. This time series is longer and of significantly higher temporal resolution than any discussed before in the context of decreasing convection activity. For the upper 1500 m depth range two distinct warming periods are identified from 1997 to 1999 and from 2003 to 2005 leading to a substantial temperature increase of 0.6°C over the recent decade. The time series of LSW source water properties suggest that ocean transport of heat and freshwater anomalies play a significant role in determining the ultimate convection depth. In 2005 the LSW temperature and salinity had reached high values comparable to those from the early 1970's, shortly after the passage of the Great Salinity Anomaly.

Beschreibung: In order to assess the contribution of quiescent degassing volcanoes to the global halo(hydro)carbon inventory, we have quantified volcanic fluxes of methyl halides (CH3Cl, CH3Br, and CH3I), ethyl halides (C2H5Cl, C2H5Br, and C2H5I), and higher chlorinated methanes (CH2Cl2, CHCl3, and CCl4). About every eight months over a 2-year period (July 2001 to July 2003), gas samples were collected and analyzed from high-temperature fumaroles (472°C–776°C) at the Nicaraguan subduction zone volcano Momotombo. Using a simultaneous record of trace and main compounds in fumarolic gases as well as SO2 fluxes of the plume, we were able to calculate halo(hydro)carbon fluxes for Momotombo and extrapolate our results to estimate halo(hydro)carbon fluxes for the whole Quaternary Nicaraguan volcanic arc and, in addition, for all volcanoes globally. The most abundant halohydrocarbon was CH3Cl with concentrations up to 19 ppmv. Further major halo(hydro)carbons were CH3Br, CH3I, CH2Cl2, CHCl3, CCl4, C2H5Cl, C2H5Br, C2H5I, and C2H3Cl with an average concentration of 0.20 to 720 ppbv. Estimated mean halo(hydro)carbon fluxes from Momotombo were in the range of 630–5000 g/yr for methyl halides, 49–260 g/yr for ethyl halides, and 2.4–24 g/yr for higher chlorinated methanes. When the results for Momotombo are scaled up to SO2 fluxes of the Nicaraguan volcanic transect, fluxes of 1.7 × 105 g/yr CH3Cl and 82 g/yr CCl4 are attained for Nicaragua. Scaled up to the estimated global SO2 flux, this translates to hypothetical global fluxes of 5.6 × 106 g/yr CH3Cl and 2.7 × 103 g/yr CCl4. These volcanic fluxes are negligible compared to global anthropogenic and natural emissions of about 3 × 1012 g/yr CH3Cl and 2 × 1010 g/yr CCl4.

Beschreibung: Analyses of sea surface height (SSH) records based on satellite altimeter data and hydrographic properties have suggested a considerable weakening of the North Atlantic subpolar gyre during the 1990s. Here we report hindcast simulations with high-resolution ocean circulation models that demonstrate a close correspondence of the SSH changes with the volume transport of the boundary current system in the Labrador Sea. The 1990s-decline, of about 15% of the long-term mean, appears as part of a decadal variability of the gyre transport driven by changes in both heat flux and wind stress associated with the North Atlantic Oscillation (NAO). The changes in the subpolar gyre, as manifested in the deep western boundary current off Labrador, reverberate in the strength of the meridional overturning circulation (MOC) in the subtropical North Atlantic, suggesting the potential of a subpolar transport index as an element of a MOC monitoring system.

Beschreibung: Stable strontium isotopes (here 88Sr/86Sr) are introduced as a new member of the nontraditional stable isotopes. We have developed a bracketing standard method for the determination of δ88/86Sr using an AXIOM MC-ICP-MS and normalizing to strontium SRM NBS987. For individual measurements the external reproducibility is better than about 25 ppm (1σ RSD). For the IAPSO seawater standard a δ88/86Sr value of 0. 381 ± 0.010‰ (2SEM) was determined. For the first time a temperature-dependent strontium isotope fractionation during calcium carbonate precipitation could be shown. Aragonite samples inorganically precipitated under temperature control between 10 and 50°C revealed a δ88/86Sr/temperature dependency of 0.0054(5)‰/°C (R2 = 0.987). In contrast, for natural coral samples (Pavona clavus) from a proxy calibration study (23 to 27°C) we did determine 0.033(5)‰/°C (R2 = 0.955). The processes causing this sixfold stronger temperature dependency for the natural coral samples have to be studied in more detail in future studies. In a first approach the different slopes can be interpreted as effects of kinetic fractionation of strontium ions with or without a hydrate shell of 22 to 29 water molecules.

Beschreibung: Physical transport processes of carbon, alkalinity, heat, and nutrients to a large extent control the partial pressure of CO2 at the sea surface and hence the oceanic carbon uptake. Using a state-of-the-art biogeochemical model of the North Atlantic at eddy-permitting resolution we show that biases in the simulated circulation generate errors in air-sea fluxes of CO2 which are still larger than those associated with the considerable uncertainties in parameterizations of the air-sea gas exchange. A semiprognostic correction method that adiabatically corrects the momentum equations while conserving water mass properties and tracers is shown to yield a more realistic description of the carbon fluxes into the North Atlantic at little additional computational cost. Owing to upper ocean flow patterns in better agreement with observations, simulated CO2 uptake in the corrected regional model is larger by 25% compared to the uncorrected model.

Beschreibung: The atmospheric response to the solar cycle has been previously investigated with the Freie Universität Berlin Climate Middle Atmosphere Model (FUB-CMAM) using prescribed spectral solar UV and ozone changes as well as prescribed equatorial, QBO-like winds. The solar signal is transferred from the upper to the lower stratosphere through a modulation of the polar night jet and the Brewer-Dobson circulation. These model experiments are further investigated here to show the transfer of the solar signal from the lower stratosphere to the troposphere and down to the surface during Northern Hemisphere winter. Analysis focuses on the transition from significant stratospheric effects in October and November to significant tropospheric effects in December and January. The results highlight the importance of stratospheric circulation changes for the troposphere. Together with the poleward-downward movement of zonal wind anomalies and enhanced equatorward planetary wave propagation, an AO-like pattern develops in the troposphere in December and January during solar maximum. In the middle of November, one third of eddy-forced tropospheric mean meridional circulation and surface pressure tendency changes can be attributed to the stratosphere, whereas most of the polar surface pressure tendency changes from the end of November through the middle of December are related to tropospheric mechanical forcing changes. The weakening of the Brewer-Dobson circulation during solar maximum leads to dynamical heating in the tropical lower stratosphere, inducing circulation changes in the tropical troposphere and down to the surface that are strongest in January. The simulated tropospheric effects are identified as indirect effects from the stratosphere because the sea surface temperatures are identical in the solar maximum and minimum experiment. These results confirm those from other simplified model studies as well as results from observations.

Beschreibung: We present new analytical data of major and trace elements for the geological MPI-DING glasses KL2-G, ML3B-G, StHs6/80-G, GOR128-G, GOR132-G, BM90/21-G, T1-G, and ATHO-G. Different analytical methods were used to obtain a large spectrum of major and trace element data, in particular, EPMA, SIMS, LA-ICPMS, and isotope dilution by TIMS and ICPMS. Altogether, more than 60 qualified geochemical laboratories worldwide contributed to the analyses, allowing us to present new reference and information values and their uncertainties (at 95% confidence level) for up to 74 elements. We complied with the recommendations for the certification of geological reference materials by the International Association of Geoanalysts (IAG). The reference values were derived from the results of 16 independent techniques, including definitive (isotope dilution) and comparative bulk (e.g., INAA, ICPMS, SSMS) and microanalytical (e.g., LA-ICPMS, SIMS, EPMA) methods. Agreement between two or more independent methods and the use of definitive methods provided traceability to the fullest extent possible. We also present new and recently published data for the isotopic compositions of H, B, Li, O, Ca, Sr, Nd, Hf, and Pb. The results were mainly obtained by high-precision bulk techniques, such as TIMS and MC-ICPMS. In addition, LA-ICPMS and SIMS isotope data of B, Li, and Pb are presented.

Beschreibung: In order to study electrical conductivity phenomena that are associated with subduction related fluid release and melt production, magnetotelluric (MT) measurements were carried out in southern Mexico along two coast to coast profiles. The conductivity-depth distribution was obtained by simultaneous two-dimensional inversion of the transverse magnetic and transverse electric modes of the magnetotelluric transfer functions. The MT models demonstrate that the plate southern profile shows enhanced conductivity in the deep crust. The northern profile is dominated by an elongated conductive zone extending 〉250 km below the Trans-Mexican Volcanic Belt (TMVB). The isolated conductivity anomalies in the southern profile are interpreted as slab fluids stored in the overlying deep continental crust. These fluids were released by progressive metamorphic dehydration of the basaltic oceanic crust. The conductivity anomalies may be related to the main dehydration reactions at the zeolite → blueschist → eclogite facies transitions and the breakdown of chlorite. This relation allows the estimation of a geothermal gradient of ∼8.5°C/km for the top of the subducting plate. The same dehydration reactions may be recognized along the northern profile at the same position relative to the depth of the plate, but more inland due to a shallower dip, and merge near the volcanic front due to steep downbending of the plate. When the oceanic crust reaches a depth of 80–90 km, ascending fluids produce basaltic melts in the intervening hot subcontinental mantle wedge that give rise to the volcanic belt. Water-rich basalts may intrude into the lower continental crust leading to partial melting. The elongated highly conductive zone below the TMVB may therefore be caused by partial melts and fluids of various origins, ongoing migmatization, ascending basaltic and granitic melts, growing plutons as well as residual metamorphic fluids. Zones of extremely high conductance (〉8000 S) in the continental crust on either MT profile might indicate extinct magmatism.

Beschreibung: Pliocene d18O records of shallow and deep dwelling planktonic foraminifers from the Caribbean (Ocean Drilling Program sites 999 and 1000), the tropical east Pacific (sites 1241 and 851), and the Atlantic (site 925, Ceara Rise, and site 1006, western Great Bahama Bank) were used to examine Atlantic-Caribbean-Pacific atmospheric and oceanic linkages associated with the progressive closure of the Central American Seaway (5.5–3 Ma). Comparisons indicate the development of an inner-Caribbean salinity gradient in the mixed layer and salinity changes on precessional periodicities after 4.4 Ma (site 1000), when the Pacific-Caribbean throughflow became significantly restricted. The high-amplitude variability in salinity is also observed at site 1006, monitoring the Caribbean outflow into the Atlantic. Comparisons of Caribbean and Atlantic planktonic d18O records suggest the North Atlantic subtropical gyre as a major source for high-salinity surface waters. Precession-induced variations in the volume transport of Pacific surface water masses through the Panamanian Seaway are considered a main factor to explain the Caribbean salinity minima. Results from a coupled climate model point to changes in the El Nin˜o–Southern Oscillation state as a potential trigger for changes in the amount of Pacific inflow into the Caribbean.

Beschreibung: In marine sedimentary environments, microbial methanotrophy represents an important sink for methane before it leaves the seafloor and enters the water column. Using benthic observatories in conjunction with numerical modeling of pore water gradients, we investigated seabed methane emission rates at cold seep sites with underlying gas hydrates at Hydrate Ridge, Cascadia margin. Measurements were conducted at three characteristic sites which have variable fluid flow and sulfide flux and sustain distinct chemosynthetic communities. In sediments covered with microbial mats of Beggiatoa, seabed methane efflux ranges from 1.9 to 11.5 mmol m−2 d−1. At these sites of relatively high advective flow, total oxygen uptake was very fast, yielding rates of up to 53.4 mmol m−2 d−1. In sediments populated by colonies with clams of the genus Calyptogena and characterized by low advective flow, seabed methane emission was 0.6 mmol m−2 d−1, whereas average total oxygen uptake amounted to only 3.7 mmol m−2 d−1. The efficiency of methane consumption at microbial mat and clam field sites was 66 and 83%, respectively. Our measurements indicate a high potential capacity of aerobic methane oxidation in the benthic boundary layer. This layer potentially restrains seabed methane emission when anaerobic methane oxidation in the sediment becomes saturated or when methane is bypassing the sediment matrix along fractures and channels.

Beschreibung: Gametes from five male and three female haddock ( Melanogrammus aeglefinus ) were crossed to produce 15 half-sibling families that were used to evaluate potential parental contributions to early life history variability. Larval morphology at 0 and 5 days post-hatch (dph) and time to starvation in the absence of food were examined. Maternal influences on larval standard length and yolk area were significant at 0 and 5 dph. Paternal effects on larval standard length were significant at 0 and 5 dph, whereas paternal effects on yolk area were only significant at 5 dph. Larval eye diameter was influenced by maternity at day 0 post-hatch and by both maternity and paternity at 5 dph. Myotome height of larvae was subject to maternal and paternal influences at 0 and 5 dph. Growth rate was significantly influenced by both paternity and maternity. Yolk utilization efficiency was significantly influenced by parental interaction, while the time taken for larvae to die in the absence of food was affected only by maternity. Results of this study not only confirm the importance of female contributions to larval development but also indicate a paternal influence on the development and the early life history success of marine fish.

Beschreibung: Northeast Asia is a region of broad deformation resulting from the convergence of the Eurasian (EU) and North American (NA) plates. Part of this convergence has been suggested to be relieved by the extrusion and deformation of the Okhotsk plate (OK). Three models for the deformation of the seismically active northwestern corner of the Okhotsk plate, based on different modes of deformation partitioning, are calculated and compared to observations from GPS, seismicity, and geology. The results suggest that this region is being extruded southeastward and deforming internally by a mixture of pure contraction, “smooth” extrusion, and “rigid” extrusion. Calculated extrusion rates are ∼3–5.5 mm/yr, comparable to estimates from geologic data, and internal deformation rates are ∼3.0 × 10−9 yr −1. Internal deformation may be only partially accommodated by seismicity, but the short time span of seismic data leaves this subject to large uncertainty.

Beschreibung: The highly active subduction zone of southern Chile was the source region of the 1960 Valdivia megathrust earthquake (Mw= 9.5), the largest earthquake ever recorded.This region is currently under investigation by the multidisciplinary TIPTEQ (From the Incoming Plate to Mega-Thrust Earthquake Processes) project, which is studying the structure, state, and deformation of the subduction zone lithosphere. Over 90 days, from December 2004 to February 2005,TIPTEQ scientists on cruise S0181 of the German research vessel (R/V Sonne acquired a broad variety of geophysical and geological data in the research area offshore Chile between 35°S and 48°S (Figure 1).These data include active and passive source seismics, heat flow probing, magnetics, magnetotellurics for studying Earth conductivity, highresolution multibeam bathymetry, and sediment probes from gravity cores.

Beschreibung: Acoustic float data collected near 800 m depth, are used to map zonal mean currents within the Antarctic Intermediate Water (AAIW) tongue in the equatorial Atlantic. Alternating zonal jets of 2° latitudinal width are revealed between 6°S and 6°N. Displacements from profiling floats drifting near 1000 m depth, also reveal similar zonal jets at the base of the AAIW layer. The strongest jets (15 cm s−1 peak) are found at 4°S, 2°S, 0°, 2°N and 4°N. They are coherent longitudinally over order of 3000 km and, poleward of 1°S and 1°N, generally coherent vertically between 800 m and 1000 m. Large seasonal fluctuations exist at both levels: within 1° of equator, AAIW at 800 m flows westward (8 cm s−1 mean) in boreal summer and fall but eastward (3 cm s−1 mean) in winter, whereas the flow at 1000 m is eastward in late fall and winter.

Beschreibung: Observational estimates of middepth tracer tongues in the equatorial Atlantic are reviewed and are compared with results from several eddy-resolving model simulations. Local maxima of chlorofluorocarbon (CFC) concentrations along the equator at around 1500 m depth are related to mean eastward jet structures in the models at similar depth ranges and can also be identified in several simulated tracer distributions. Similar to the observations, strong eastward jets are located in the simulations 1°–2° north and south of the equator. The model simulations show, in addition, consistent with the CFC observations, weaker jets at around 4°–6°N/S and 8°–10°N/S, suggestive of a large-scale alternating eastward/westward current system in the western tropical Atlantic in this depth range. Lagrangian transport estimates in the model using float diagnostics show a transport of 1–3 Sv in each of the eastward jets 1°–2°N/S off the equator compared to 3–12 Sv throughflow into the South Atlantic, with no seasonal cycle apparent in the transport fractioning. Comparing different model solutions reveals the choice of the subgrid-scale mixing parameterization as important for the amplitudes of the jets. Enhanced (reduced) diapycnal mixing is related to stronger (weaker) jets.

Beschreibung: We compare total dissolved inorganic carbon (DIC) and chlorofluorocarbon (CFC) measurements in the northwest Atlantic made during the Transient Tracers in the Ocean, North Atlantic Study (TTO‐NAS) in 1981 with modern measurements from a cruise in 2004. The observed changes in the DIC and CFC fields are compared to those predicted from an eddy‐permitting ocean circulation model. The rapid, but time‐variable, atmospheric CFC increase in relation to the relatively steady anthropogenic CO2 increase influences the relationship between the observed uptake of DIC and CFC. We demonstrate the importance of ocean mixing in the calculation of anthropogenic CO2 (Cant) based on transient tracer data by comparing our observations to a “no‐mixing” scenario. We further find that the Cant is in transient steady state in the North Atlantic; that is, the Cant concentration increases proportionally over time through the whole water column in a manner that is directly related to the time‐dependent surface concentration.

Beschreibung: Deep and shallow subsurface temperature maxima (Tmax) in the Labrador Sea are found to be the result of anomalous freshwater input during past decades in particular during the early 1990s. The deep Tmax is associated with a specific water mass imported into the Labrador Sea. The shallow Tmax is of local origin and created by anomalous heat input in 1999, not eroded by surface buoyancy forcing in recent years. Both are associated with stability maxima: the deep Tmax is a barrier for maximum convection depth, the shallow Tmax separates the water in a layer ventilated by overturning and a layer modified through lateral fluxes only. The shallow Tmax is exported into the subpolar gyre. A complementary shallow Tmax in the Greenland Sea suggest a concerted response of deep convection regions to anomalous freshwater input: diminished vertical mixing and dominance of lateral heat/salt fluxes underneath Tmax, shallow convection above it.

Beschreibung: The Sr/Ca ratio of biogenic carbonate is widely used as a proxy for paleotemperature. This application is supported by empirical calibrations of Sr/Ca as a function of temperature, but it is also known that Sr uptake in calcite gauged by KdSr = equation image is affected by other variables, including bulk precipitation rate (KdSr increases with increasing precipitation rate). There are no data from controlled experiments specifically addressing the effect of radial growth rate of individual crystals on KdSr. For this reason, we conducted two series of experiments to explore Sr partitioning at varying growth rates: (1) growth from a CaCl2–NH4Cl–SrCl2 solution by diffusion of CO2 from an ammonium carbonate source (“drift” experiments) and (2) “drip” precipitation of calcite on a substrate, using a steady flow of CaCl2–SrCl2 and Na2CO3 solutions, mixed just before passage through a tube and dripped onto a glass slide precoated with calcite (“cave‐type” experiments). The growth rates of individual crystals were determined by periodic monitoring of crystal size through time or, roughly, by comparison of the final size with the duration of the experiment. Electron microprobe analyses across sectioned crystals grown in the drift experiments show that the concentration of Sr is high in the center (where radial growth rates are highest) and decreases systematically toward the edge. The center‐to‐edge drop in Sr concentration is a consequence of the slowing radial growth rate as individual crystals become larger. In general, high crystal growth rate (V) enhances Sr uptake in calcite due to a type of kinetic disequilibrium we refer to as “growth entrapment.” The apparent KdSr ranges from 0.12 to 0.35 as V increases from 0.01 nm/s to 1 μm/s at 25°C.

Beschreibung: The Ocean Drilling Program (ODP), an international partnership of scientists and research institutions organized to explore the Earth's evolution and structure, provides researchers around the world access to a vast repository of geological and environmental information recorded far below the ocean surface in sea floor sediments and rocks. The Joint Oceanographic Institutions, Inc. manages ODP under contract with the National Science Foundation. Like all good things, however, even the ODP--widely hailed as one of the best examples of international cooperation in all of geosciences--must come to an end.

Beschreibung: A suite of basin-scale models of the thermohaline and wind-driven circulation in the Atlantic Ocean is used to study the mechanisms of decadal variability in the shallow subtropical-tropical cells (STCs). The emphasis is on the spatial patterns of the transport anomalies in the tropical thermocline, particularly their manifestation in the equatorial current system and on the relative role of changes in the deep meridional overturning cell (MOC) associated with variations in the formation of Labrador Sea Water (LSW) in the subpolar North Atlantic. Using wind stress and heat flux variations based on NCEP/NCAR-reanalysis products, the variability of the zonally integrated STC transports is similar to that obtained in a recent regional model study, corroborating the role of both the southern and northern STC in supporting wind-driven transport anomalies of O(2 Sv) near the equator. Sensitivity experiments indicate that changes in subarctic MOC transports associated with the strong variability in LSW formation during the last decades contributed a signal of O(0.3 Sv) to the upper-layer equatorial transports. Whereas the local wind-driven variability clearly dominates on interannual-decadal timescales and is confined to depths down to 150 m, the weak MOC-related signal is primarily reflected in an interdecadal modulation of the STC transports. While a strong part in the STC's transport anomalies is associated with the western boundary current (NBC), there is an important contribution also by weaker, interior ocean flow anomalies which tend to counteract the variability of the NBC.

Beschreibung: This study provides the first monthly resolved, 41-year record of geochemical variations (δ18O and Sr/Ca) in a fast-growing Diploria strigosa brain coral from Guadeloupe, Caribbean Sea. Linear regression yields a significant correlation of coral Sr/Ca (δ18O) with instrumental sea surface temperature (SST) on both monthly and mean annual scales (e.g., r = −0.59 for correlation between Simple Ocean Data Assimilation (SODA) SST and Sr/Ca, and r = −0.66 for δ18O; mean annual scale, p 〈 0.0001). The generated coral Sr/Ca (δ18O)-SST calibration equations are consistent with each other and with published equations using other coral species from different regions. Moreover, a high correlation of coral Sr/Ca and δ18O with local air temperature on a mean annual scale (r = −0.78 for Sr/Ca; r = −0.73 for δ18O; p 〈 0.0001) demonstrates the applicability of geochemical proxies measured from Diploria strigosa corals as reliable recorders for interannual temperature variability. Both coral proxies are highly correlated with annual and seasonal mean time series of major SST indices in the northern tropical Atlantic (e.g., r = −0.71 for correlation between the index of North Tropical Atlantic SST anomaly and Sr/Ca, and r = −0.70 for δ18O; mean annual scale, p 〈 0.001). Furthermore, the coral proxies capture the impact of the El Niño–Southern Oscillation on the northern tropical Atlantic during boreal spring. Thus fast-growing Diploria strigosa corals are a promising new archive for the Atlantic Ocean.

Beschreibung: Recently and independently published estimates of global net community production which were based on seasonal changes of either nutrients (NO3 and PO4 (Louanchi and Najjar, 2000)) and salinity normalized dissolved inorganic carbon (NCt (Lee, 2001)) in the surface ocean indicate that the stoichiometry of new production strongly differs from the well‐established remineralization ratios in the deep ocean (the Redfield ratio). This difference appears to be most pronounced in the North Atlantic Ocean. Data quality issues as well as methodological differences in the data analysis applied in the published studies, however, make this comparison of nutrient‐ and carbon‐based estimates ambiguous. Here I present an analysis based on a combination of historical data (World Ocean Atlas and Data 1998) and empirical approaches and provide a reassessment of the C:N elemental ratio of new (export) production in the North Atlantic. It is found that the estimate of winter nutrient fields is the most crucial step in estimating basin‐scale, time‐integrated C:N ratios of new production. An approach is developed which allows an estimate of winter nitrate and total CO2 concentrations which are consistent with estimates from an isopycnal outcrop analysis where these are available. Regional trends in the spring + summer integrated C:N ratio of new production suggest an increase from high latitudes toward the subtropics. The basin‐integrated C:N ratio of new production between 40°N and 65°N is 11.4 ± 1.4, far exceeding the Redfield ratio. The bulk Corg:Cinorg rain ratio estimated for the same region is 7.7. The fate of organic carbon produced in excess of the Redfield equivalent of nitrate uptake is discussed. It is suggested that a considerable fraction of excess carbon is remineralized above the depth of the winter mixed layer.

Beschreibung: The "standard model" for the genesis of the oceans is that they are exhalations from Earth's deep interior continually rinsed through surface rocks by the global hydrologic cycle. No general consensus exists, however, on the water distribution within the deeper mantle of the Earth. Recently Dixon et a/. [2002] estimated water concentrations for some of the major mantle components and concluded that the most primitive (FOZO) are significantly wetter than the recycling associated EM or HIMU mantle components and the even drier depleted mantle source that melts to form MORB. These findings are in striking agreement with the results of numerical modeling of the global water cycle that are presented here. We find that the Dixon et a/. [2002] results are consistent with a global water cycle model in which the oceans have formed by efficient outgassing of the mantle. Present-day depleted mantle will contain a small volume fraction of more primitive wet mantle in addition to drier recycling related enriched components. This scenario is consistent with the observation that hotspots with a FOZO-component in their source will make wetter basalts than hotspots whose mantle sources contain a larger fraction of EM and HIMU components.

Beschreibung: High-resolution bulk sediment (magnetic susceptibility and aragonite content) and δ18O records from two different planktonic foraminifera species were analyzed in an early Pliocene core interval from the Straits of Florida (Ocean Drilling Program site 1006). The δ18O record of the shallow-dwelling foraminifera G. sacculifer and the aragonite content are dominated by sub-Milankovitch variability. In contrast, magnetic susceptibility and the δ18O record of the deeper-dwelling foraminifera G. menardii show precession cycles. The relationship between the aragonite and the paleoproxy data suggests that the export of sediment from the adjacent Great Bahama Bank was triggered directly by atmospheric processes rather than by sea level change. We propose a climate mechanism that bears similarities with the semiannual cycle component of eastern equatorial Pacific sea surface temperatures under present-day conditions.

Beschreibung: Multiproxy geologic records of δ18O and Mg/Ca in fossil foraminifera from sediments under the Eastern Pacific Warm Pool (EPWP) region west of Central America document variations in upper ocean temperature, pycnocline strength, and salinity (i.e., net precipitation) over the past 30 kyr. Although evident in the paleotemperature record, there is no glacial-interglacial difference in paleosalinity, suggesting that tropical hydrologic changes do not respond passively to high-latitude ice sheets and oceans. Millennial variations in paleosalinity with amplitudes as high as ∼4 practical salinity units occur with a dominant period of ∼3–5 ky during the glacial/deglacial interval and ∼1.0–1.5 ky during the Holocene. The amplitude of the EPWP paleosalinity changes greatly exceeds that of published Caribbean and western tropical Pacific paleosalinity records. EPWP paleosalinity changes correspond to millennial-scale climate changes in the surface and deep Atlantic and the high northern latitudes, with generally higher (lower) paleosalinity during cold (warm) events. In addition to Intertropical Convergence Zone (ITCZ) dynamics, which play an important role in tropical hydrologic variability, changes in Atlantic-Pacific moisture transport, which is closely linked to ITCZ dynamics, may also contribute to hydrologic variations in the EPWP. Calculations of interbasin salinity average and interbasin salinity contrast between the EPWP and the Caribbean help differentiate long-term changes in mean ITCZ position and Atlantic-Pacific moisture transport, respectively.

Beschreibung: The residual dark unit of the most recent eastern Mediterranean sapropel (S1) is usually overlain by sediments with enhanced concentrations of MnOx in two separated layers. The variability and magnitude of the Mn enrichment at different locations and water depths indicate that Mn must have been added preferentially to sediments at intermediate (1–2 km) water depths. We propose a two-stage mechanism for the Mn enrichment that involves decreasing oxygenation with increasing water depth. This mechanism involves the loss of reduced Mn2+ from the deepest sediments (〉2 km water depth) into overlying anoxic waters and a variable gain of MnOx in sediments in contact with oxygenated waters at shallower depth. In the S1 unit that receives the extra MnOx input, an upper higher Mn-enriched zone (〉3 wt %) is maintained continuously at the top of the accumulating S1 unit because the pore waters are anoxic at shallow sediment depth while bottom waters are oxic to some degree. In a reactive-transport model, the Mn enrichment in the upper zone could not be supported by normal sediment diagenesis. Thus the MnOx in the upper Mn horizon must have formed mainly in the water column. The MnOx in the upper Mn-enriched zone adsorbed Mo and Li from seawater in a similar manner as other Mn-enriched oxic sediments, nodules, and crusts, with a Mn:Mo ratio of ∼600:1, a Mn:Li ratio of ∼750:1, and a δ98/95MoMOMO of −2.5 ‰.

Beschreibung: Deformation experiments on Black Hills quartzite with three different initial water contents (as-is, water-added, and vacuum-dried) were carried out in the dislocation creep regime in order to evaluate the effect of water on the recrystallized grain size/flow stress piezometer. Samples were deformed in axial compression at temperatures of 750°–1100°C, strain rates between 2 × 10−7 s−1 and 2 × 10−4 s−1 and strains up to 46% using a molten salt assembly in a Griggs apparatus. An increase of the initial water content at otherwise constant deformation conditions caused a decrease in flow stress, an effect known as hydrolytic weakening. The total water content of the starting material was analyzed by Karl Fischer titration (KFT) and Fourier transform infrared (IR) spectroscopy, and quenched samples were analyzed microstructurally and by IR. Changes in the dynamic recrystallization microstructure correlate with changes in flow stress, but there is no independent effect of temperature, strain rate or water content. IR absorption spectra of the deformed spectra indicate that different water contents were maintained in the three sample sets throughout the experiments. However, the amounts of water measured within the vacuum-dried (∼260 ± 40 ppm H2O), the as-is (∼340 ± 50 ppm H2O), and the water-added (∼430 ± 110 ppm H2O) samples are significantly smaller than the initial content of the quartzite (∼640 ± 50 ppm H2O). Water from the inclusions in the starting material adds to the free fluid phase along the grain boundaries, which probably controls the water fugacity and the flow strength, but this water is largely lost during IR sample preparation. Vacuum-dried as well as water-added samples have the same recrystallized grain size/flow stress relationship as the piezometer determined for as-is samples. No independent effect of water on the piezometric relationship has been detected.

Beschreibung: The mean meridional circulation across the equator in the Indian Ocean is characterized by the shallow Cross-Equatorial Cell (CEC). At the western boundary, the Somali Current transports thermocline waters northward which then upwell, mostly off Northeast Africa. The upwelled waters are taking up heat and then exported back southward by southward near-surface Ekman and Sverdrup transports. The CEC is closed by subduction in the southeastern subtropics and includes contributions from the Indonesian Throughflow. In an analysis of output from the SODA assimilation, a decadal slowdown of the different branches of the CEC is demonstrated here.

Beschreibung: Combined measurements of Mg/Ca and stable oxygen isotopes in tests of the planktonic foraminifer G. bulloides from Ocean Drilling Program (ODP) Site 1172A (East Tasman Plateau) allowed us to reconstruct sea surface temperature (SSTMg/Ca), sea surface salinity (SSS), and hence variations in the Subtropical Convergence (STC) in the southwestern Tasman Sea over the last four major glacial-interglacial changes. During interglacials the commonly enhanced SSTMg/Ca and SSS correspond to a lowered marine productivity and a lowered terrigenous flux, implying that the STC separating cool, high-nutrient Subantarctic Surface Water from warm, saline, oligotrophic Subtropical Surface Water and hence the band of zonal westerlies responsible for the eolian dust flux were located south of East Tasman Plateau. The warm East Australian Current was well established during warm periods and propagated far south. During glacial times, SSTMg/Ca and SSS were lower, while both marine productivity and eolian flux increased. Such conditions prevailed during glacial Marine Isotope Stages MIS 12, MIS 10, and to a lesser degree MIS 6 and implied the extended northward influence of Subantarctic SurfaceWater and a shift of the STC to 〈44�S. The overall climatic signal at Site 1172A appears to be largely attenuated when compared to published climate records from comparable latitudes to the west and to the east. SSTMg/Ca amplitudes were more pronounced in the subantarctic Indian Ocean and at Chatham Rise. They exhibit a consistent pattern suggesting that latitudinal shifts of the STC occurred synchronously in the subantarctic Indian Ocean and at Chatham Rise but were largely damped at East Tasman Plateau due to the influence of the East Australian Current.

Beschreibung: [1] Radiogenic isotope compositions (Sr, Nd, Pb, Hf, and Os) of sediment-hosted seafloor ferromanganese crusts and sediments incrusted with ferromanganese oxyhydroxides from the Lesser Antilles island arc were measured to distinguish between hydrogenous (seawater-derived) and hydrothermal metal sources. The ages of the precipitates range between recent (last few thousand years) and a few 100 kyr as deduced from 10Be and Co concentrations. Evidence from the presence of bladed todorokite and nontronite, together with the major element and REE composition, suggests that a significant proportion of these sediment-hosted precipitates formed at relatively low temperatures from a mixture of seawater and hydrothermal fluids associated with island arc volcanism. The radiogenic isotope compositions of all metals mentioned above, except Pb, show large differences in hydrothermal versus hydrogenous contributions over space and time. In contrast to precipitates of high-temperature fluids which mainly scavenge their REE contents from seawater the crusts of this study show 143Nd/144Nd of up to 0.512817 (ɛNd = +3.5). This is close to the signature of the nearby island arc rocks and far above the expected local seawater ratio of ∼0.51209 (ɛNd = −10.7). These crusts also show high 176Hf/177Hf (up to 0.283102), low 87Sr/86Sr (up to 0.7069), and low 187Os/188Os (up to 0.16) compared with local seawater, as expected from hydrothermal, island-arc-derived metal contributions. In contrast, the Pb isotope signatures of the crusts cannot be explained by mixing between seawater and hydrothermal sources. It is suggested that Pb was either removed from the ascending fluids within the sediment column before they reached seawater or the temperatures were too low to leach significant amounts of Pb from the rocks or sediments. External sources such as Saharan dust, particulate inputs from the Orinoco River, or even incongruent release of Pb isotopes from the island arc rock-derived particles must have contributed to the observed Pb isotope variability. Our results suggest that submarine hydrothermalism originating from intraoceanic island arc volcanism creates distinct geochemical environments for the dispersion of hydrothermal fluids and may be an important mechanism to supply metals of hydrothermal origin to seawater.

Beschreibung: The Deep Western Boundary Current east of the Grand Banks has been observed during 1999–2005 by moored current-meter stations and shipboard current profiling sections. These recent observations can be compared with those of a WOCE moored array deployed during 1993–95 at the same location. Overall, the observations of Deep Water currents east of the Grand Banks reported here do not support suggestions of a basin-wide "slowdown" of the Atlantic Meridional Overturning Circulation.

Beschreibung: The Labrador Sea is an important area of deep water formation and is hypothesized to be a significant sink for atmospheric CO2 to the deep ocean. Here we examine the dynamics of the CO2 system in the Labrador Sea using time-series data obtained from instrumentation deployed on a mooring near the former Ocean Weather Station Bravo. A 1-D model is used to determine the air-sea CO2 uptake and penetration of the CO2 into intermediate waters. The results support that mixed-layer pCO2 remained undersaturated throughout most of the year, ranging from 220 μatm in mid-summer to 375 μatm in the late spring. Net community production in the summer offset the increase in pCO2 expected from heating and air-sea uptake. In the fall and winter, cooling counterbalanced a predicted increase in pCO2 from vertical convection and air-sea uptake. The predicted annual mean air to sea flux was 4.6 mol m−2 yr−1 resulting in an annual uptake of 0.011 ± 0.005 Pg C from the atmosphere within the convection region. In 2001, approximately half of the atmospheric CO2 penetrated below 500 m due to deep convection.

Beschreibung: Spectral potential and kinetic energy densities and fluxes in horizontal wavenumber space are estimated in an eddy-resolving model of the North Atlantic. In agreement to recent observational results near surface kinetic energy fluxes are negative over wide regions of the North Atlantic, indicative of an inverse energy cascade. This inverse kinetic energy cascade is found over a wide depth range but both the spectral kinetic energy density and the corresponding flux show no clear dependency on Rossby radius or Rhines scale. Potential energy fluxes tend to be positive and show a direct potential energy cascade towards a scale which is related to the Rossby radius in the subtropical North Atlantic.

Beschreibung: We installed a dense, amphibious, temporary seismological network to study the seismicity and structure of the seismogenic zone in southern Chile between 37° and 39°S, the nucleation area of the great 1960 Chile earthquake. 213 local earthquakes with 14.754 onset times were used for a simultaneous inversion for the 1-D velocity model and precise earthquake locations. Relocated artificial shots suggest an accuracy of the earthquake hypocenter of about 1 km (horizontally) and 500 m (vertically). Crustal events along trench-parallel and transverse, deep-reaching faults reflect the interseismic transpressional deformation of the forearc crust due to the subduction of the Nazca plate. The transverse faults seems to accomplish differential lateral stresses between subduction zone segments. Many events situated in an internally structured, planar seismicity patch at 20 to 40 km depth near the coast indicate a stress concentration at the plate's interface at 38°S which might in part be induced by the fragmented forearc structure.

Beschreibung: In order to assess the dissolution effect on foraminiferal Mg/Ca ratios, we analyzed Mg/Ca of seven planktonic foraminiferal species and four of their varieties from Caribbean core tops from ∼900–4700 m water depth. Depending on the foraminiferal species and variety, Mg/Ca start to decline linearly below Δ[CO32−] levels of ∼18–26 μmol/kg by ∼0.04–0.11 mmol/mol per 1 μmol/kg Δ[CO32−], similar to decreases of ∼0.5–0.8 mmol/mol per kilometer below ∼2500–3000 m water depth. Above these species-specific critical levels, Mg/Ca remains stable with higher intraspecific Mg/Ca variability than below. We developed routines to correct Mg/Ca from below these critical thresholds for dissolution effects, which reduce the overall intraspecific variability by ∼24–64%, and provide dissolution-corrected Mg/Ca appropriate to calculate Holocene paleotemperatures. When taking into account only dissolution-unaffected Mg/Ca from 〈2000 m, the systematic succession of foraminiferal species according to their Mg/Ca reflects expected calcification depths.