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  • 101
    Publication Date: 2017-04-04
    Description: We provide new data on relative sea-level change from the late Holocene for two locations in the central Mediterranean: Sardinia and NE Adriatico. They are based on precise measures of submerged archaeological and tide notch markers that are good indicators of past sea-level elevation. Twelve submerged archaeological sites were studied: six, aged between 2.5 and 1.6 ka BP, located along the Sardinia coast, and a further six, dated 2.0 ka BP, located along the NE Adriatic coast (Italy, Slovenia and Croatia). For Sardinia, we also use beach rock and core data that can be related to Holocene sea level. The elevations of selected significant archaeological markers were measured with respect to the present sea level, applying corrections for tide and atmospheric pressure values at the time of surveys. The interpretation of the functional heights related to sea level at the time of their construction provides data on the relative changes between land and sea; these data are compared with predictions derived from a new glacio–hydro-isostatic model associated with the Last Glacial cycle. Sardinia is tectonically relatively stable and we use the sea-level data from this island to calibrate our models for eustatic and glacio–hydro-isostatic change. The results are consistent with those from another tectonically stable site, the Versilia Plain of Italy. The northeast Adriatic (Italy, Slovenia and Croatia) is an area of subsidence and we use the calibrated model results to separate out the isostatic from the tectonic contributions. This indicates that the Adriatic coast from the Gulf of Trieste to the southern end of Istria has Q1 tectonically subsided by 1.5m since Roman times.
    Description: Published
    Description: 2463-2486
    Description: 3.3. Geodinamica e struttura dell'interno della Terra
    Description: JCR Journal
    Description: reserved
    Keywords: sea level, archaeology, tectonics ; 04. Solid Earth::04.07. Tectonophysics::04.07.02. Geodynamics
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
    Type: article
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  • 102
    Publication Date: 2017-04-04
    Description: A prediction procedure of the hourly values of the critical frequency of the F2 ionospheric layer, foF2, based on the geomagnetic index, is presented. The geomagnetic index used in this study is the time-weighted accumulation magnetic index ap(s) based on the recent past history of the planetary index ap. The procedure is based on an empirical relationship between the ratio log(NmF2(t)/NmF2M(t)) and ap(s), where NmF2(t) is the hourly maximum electron density at the F2 peak layer and NmF2M(t) is its ‘quiet’ value. The prediction of foF2 has been calculated during periods of severe magnetic activity in the current solar cycle 23 using data processed at the Rome ionospheric observatory. The performance of the model, during negative ionospheric storms, can be considered satisfactory, given that the root mean square (r.m.s.), calculated between measured and forecasted foF2, ranged between 0.74–2.0 MHz.
    Description: Published
    Description: 674-680
    Description: 3.9. Fisica della magnetosfera, ionosfera e meteorologia spaziale
    Description: N/A or not JCR
    Description: reserved
    Keywords: Ionosphere ; Ionospheric ; storms ; F2 layer ; Prediction model ; Geomagnetic index ; 01. Atmosphere::01.02. Ionosphere::01.02.03. Forecasts
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
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  • 103
    Publication Date: 2017-04-04
    Description: Viscosity of water-bearing float glass (0.03–4.87 wt% H2O) was measured in the temperature range of 573–1523 K and pressure range of 50–500 MPa using a parallel plate viscometer in the high viscosity range and the falling sphere method in the low viscosity range. Melt viscosity depends strongly on temperature and water content, but pressure up to 500 MPa has only minor influence. Consistent with previous studies on aluminosilicate compositions we found that the effect of dissolved water is most pronounced at low water content, but it is still noticeable at high water content. A new model for the calculation of the viscosities as a function of temperature and water content is proposed which describes the experimental data with a standard deviation of 0.22 log units. The depression of the glass transition temperature Tg by dissolved water agrees reasonably well with the prediction by the model of Deubener [J. Deubener, R. Müller, H. Behrens, G. Heide, J. Non-Cryst. Solids 330 (2003) 268]. Using water speciation measured by near-infrared spectroscopy we infer that although the effect of OH groups in reducing Tg is larger than that of H2O molecules, the difference in the contribution of both species is smaller than predicted by Deubener et al. (2003). Compared to alkalis and alkaline earth elements the effect of protons on glass fragility is small, mainly because of the relatively low concentration of OH groups (max. 1.5 wt% water dissolved as OH) in the glasses.
    Description: Published
    Description: 223-236
    Description: 2.3. TTC - Laboratori di chimica e fisica delle rocce
    Description: JCR Journal
    Description: open
    Keywords: Glass transition ; Pressure effect ; FTIR measurements ; Alkali silicates ; Soda-lime-silica ; Fragility ; Viscosity ; Water in glass ; 04. Solid Earth::04.01. Earth Interior::04.01.05. Rheology
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
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  • 104
    Publication Date: 2017-04-04
    Description: Metamorphic and magmatic garnets are known to fractionate REE, with generally HREE-enriched patterns, and high Lu/ Hf and Sm/Nd ratios, making them very useful as geochemical tracers and in geochronological studies. However, these garnets are typically Al-rich (pyrope, almandine, spessartine, and grossular) and little is known about garnets with a more andraditic (Fe3+) composition, as frequently found in skarn systems. This paper presents LA-ICP-MS data for garnets from the Crown Jewel Au-skarn deposit (USA), discusses the factors controlling incorporation of REE into garnets, and strengthens the potential of garnet REE geochemistry as a tool to help understand the evolution of metasomatic fluids. Garnets from the Crown Jewel deposit range from Adr30Grs70 to almost pure andradite (Adr〉99). Fe-rich garnets (Adr〉90) are isotropic, whereas Al-rich garnets deviate from cubic symmetry and are anisotropic, often showing sectorial dodecahedral twinning. All garnets are extremely LILE-depleted, Ta, Hf, and Th and reveal a positive correlation of RREE3+ with Al content. The Al-rich garnets are relatively enriched in Y, Zr, and Sc and show ‘‘typical’’ HREE-enriched and LREE-depleted patterns with small Eu anomalies. Fe-rich garnets (Adr〉90) have much lower RREE and exhibit LREE-enriched and HREE-depleted patterns, with a strong positive Eu anomaly. Incorporation of REE into garnet is in part controlled by its crystal chemistry, with REE3+ following a coupled, YAG-type substitution mechanism ð½ X2þ VIII 1 ½REE3þ VIII þ1 ½ Si4þ IV 1½Z3þ IV þ1Þ, whereas Eu2+ substitutes for X2+ cations. Thermodynamic data (e.g., Hmixing) in grossular– andradite mixtures suggest preferential incorporation of HREE in grossular and LREE in more andraditic compositions. Variations in textural and optical features and in garnet geochemistry are largely controlled by external factors, such as fluid composition, W/R ratios, mineral growth kinetics, and metasomatism dynamics, suggesting an overall system that shifts dynamically between internally and externally buffered fluid chemistry driven by fracturing. Al-rich garnets formed by diffusive metasomatism, at low W/R ratios, from host-rock buffered metasomatic fluids. Fe-rich garnets grow rapidly by advective metasomatism, at higher W/R ratios, from magmatic-derived fluids, consistent with an increase in porosity by fracturing.
    Description: Published
    Description: 185-205
    Description: 3.6. Fisica del vulcanismo
    Description: 3.8. Geofisica per l'ambiente
    Description: JCR Journal
    Description: reserved
    Keywords: A LA-ICP-MS ; Crown Jewel ; 04. Solid Earth::04.01. Earth Interior::04.01.04. Mineral physics and properties of rocks ; 04. Solid Earth::04.02. Exploration geophysics::04.02.01. Geochemical exploration ; 04. Solid Earth::04.04. Geology::04.04.05. Mineralogy and petrology ; 04. Solid Earth::04.04. Geology::04.04.12. Fluid Geochemistry ; 04. Solid Earth::04.08. Volcanology::04.08.06. Volcano monitoring
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  • 105
    Publication Date: 2017-04-04
    Description: Tephra fallout represented a major source of hazard for eastern Sicily during the 2001 eruption of Mt. Etna (Italy) between 19 July and 6 August. Long-lasting explosive activity was generated from the 2570 m vent, producing a volcanic plume up to 5 km high above sea level. The eruption caused copious lapilli and ash fallout over the volcano flanks for several days. Flight operations were cancelled at the Catania and Reggio Calabria airports; health risk and economic damage put communities living close to this active volcano on the alert. The explosive activity at the 2570 m vent had three main phases characterized by phreatomagmatic, magmatic and vulcanian explosions. In this paper, we analyze the first explosive phase between 19 and 24 July that formed a tephra deposit on the volcano's south-east flanks. Immediately after the first phase of the eruption, numerous tephra samples were collected in order to draw an isomass map, calculate physical parameters for the eruption and analyze the plume dispersion on the basis of deposit geometry. The tephra deposit shows a bilobate shape due to the change with time of both the vigour of the eruption and the wind direction and velocity that caused a higher rate of particle accumulation along two dispersal axes (SE and SSE). The total mass of tephra erupted was calculated with two different fitting methods: exponential line segments and a power law fit on the semi-logarithmic plot of mass per unit area versus , resulting in values of 1.02 109 kg and 2.31 109 kg, respectively. The whole deposit grain-size was calculated applying the Voronoi tessellation method, it shows a mode of 2 and thus indicates a high degree of magma fragmentation during the first phase of the eruption. Plume dispersal was investigated by an advection–diffusion model to reconstruct the tephra deposit. In the modelling, we took into account the variations of wind direction and velocity, and eruption intensity by dividing the explosive phase into sixteen sub-eruptions and considering the final deposit as the sum of the mass computed for each sub-eruption. Using best fit procedures, we find that the optimal agreement between computed values and field data is obtained by using the total mass calculated with the power law fit and a terminal settling velocity distribution with a particle aggregation model. The computed tephra dispersal was able to reproduce the bilobate shape of the real deposit. This work proves that advection–diffusion models can describe sedimentation processes of weak, i.e., bent-over, long-lasting plumes if the variations of wind direction and velocity, and eruptive intensity are included.
    Description: Published
    Description: 147-164
    Description: 3.6. Fisica del vulcanismo
    Description: JCR Journal
    Description: reserved
    Keywords: Mt. Etna ; basaltic explosive activity ; violent strombolian eruption ; tephra deposit ; dispersal modelling ; 05. General::05.02. Data dissemination::05.02.03. Volcanic eruptions
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
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  • 106
    Publication Date: 2012-02-03
    Description: In Italy, the horizontal stress directions are well constrained in many regions, but the tectonic regime is not well known because the stress magnitudes are unknown. Our intention is to improve the knowledge of crustal stress in Italy, both at shallow depth and in low seismicity areas. Therefore, we inferred the tectonic regime from the comparison between the depth of breakout occurrence and the physical properties of the rocks in 20 boreholes. The critical value of the maximum horizontal stress, for which the effective tangential stress at the borehole wall overcomes the rock strength to form breakouts, could be computed from rock strength and density. Comparing the theoretical stress distributions for different tectonic regimes with the depth distribution of breakout occurrence, it is possible to infer the tectonic regime that fits best to the breakout depth distribution. We investigated boreholes up to 6 km deep located in different tectonic environments over the Italian peninsula: the Po Plain, the Apenninic chain, the Adriatic foredeep and the Tyrrhenian Quaternary volcanic region. These wells are characterised by breakout data of good quality (A, B and C, according to World Stress Map quality ranking system). The results are in general agreement with the style of faulting derived from earthquake focal mechanisms and other stress indicators. Our results show a predominance of a normal faulting (NF) regime in the inner Apennines and both normal faulting and strike–slip faulting (SS) style in the surrounding regions, possibly also associated with changes in the tectonic regime with depth.
    Description: Published
    Description: 21-35
    Description: reserved
    Keywords: active stress ; tectonic regime ; borehole breakout ; Italy ; 04. Solid Earth::04.07. Tectonophysics::04.07.05. Stress
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
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  • 107
    Publication Date: 2012-02-03
    Description: We have analysed borehole breakout data from 12 deep wells in order to constrain the direction of the minimum and maximum horizontal stress in a part of the Po Plain, northern Italy, characterised by a N–S prevailing compressional stress regime, and in order to shed light on the regional state of stress and on the correlation between the active stress field and the orientation of tectonic structures. The results have been compared with seismological data relating to 1988–1995 crustal seismicity (2.5〈Md〈4.8) and to the 1983 Parma (Ms=5.0) and the 1996 Reggio Emilia (Ms=5.1) events. Plio-Pleistocene mesostructural data are also described in order to better define the present-day stress field and to understand the active tectonic processes in particular stress provinces. The borehole breakout analysis, in accordance with the seismicity and mesostructural data, shows the presence of a predominant compression area, characterised by approximately N–S maximum horizontal stress, along the outer thrust of the Ferrara arc. Particularly, the breakout analysis indicates a minimum horizontal stress, N81W±22° relative to a total of eleven analysed wells, with 3746 m cumulative total length of breakout zones. Among these, nine wells are located in the same tectonic structure, consisting of an arc of asymmetric folds overthrust towards the NE. The breakout results for these wells are quite similar in terms of minimum horizontal stress direction (E–W oriented). The other two wells are located in the outside sector of the arc and one of them shows a different minimum horizontal stress direction, probably distinctive of another tectonic unit. On the basis of these new reliable stress indicators, the active compressive front in this area is located along the termination of the external northern Apenninic arc.
    Description: Published
    Description: 251-265
    Description: reserved
    Keywords: stress ; borehole breakout ; tectonics ; Italy ; Apennines ; 04. Solid Earth::04.07. Tectonophysics::04.07.05. Stress
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
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  • 108
    Publication Date: 2012-02-03
    Description: An integrated magneto-, bio- and cyclostratigraphic framework is presented for the Mid-Palaeocene interval from the (hemi) pelagic sea-cliff section of Zumaia in the Basque basin. The new ∼55 m long studied section expands about 3.5 Myr and closes the gap between previously published integrated studies in the section. The occurrence of magnetochron C26n is now documented, and its duration (complemented also by data from the Ibaeta section), and that for chrons C26r and C25r is estimated by counting precession related lithologic couplets assigned to have 21-kyr duration (C25r=∼1449 kyr, C26n=∼231 kyr, C26r=∼2877 kyr). Consequently, the Zumaia section now provides the first complete Palaeocene astronomically derived chronology, rendering this section a master reference section. Due to limitations in the orbital calculations and uncertainties in the radiometric dating method no robust tuning and absolute ages can be given for the moment. However, the FOs (First Occurrences) of key calcareous plankton species and the Mid Palaeocene Biotic Event (MPBE) are placed within the magnetostratigraphic and cyclostratigraphic template along the studied Mid-Palaeocene interval. In addition, the dataset provides the key elements for a proper settling of the Thanetian and Selandian Global Stratotype Section and Point (GSSPs), which is one of the primary objectives of the ICS (International Commission of Stratigraphy). We consider the base of chron C26n and the criteria associated to the lithostratigraphic change between the Danian Limestone Fm and the Itzurun marl Fm at Zumaia, as the respective delimiting points for the Thanetian and Selandian bases as recently agreed by the Paleocene Working Group of the International Subcommission of the Paleogene Stratigraphy of the ICS. Consequently, the duration of the Thanetian, Selandian and Danian component stages can be estimated at Zumaia to be about ∼3129 kyr, ∼2163 kyr and ∼4324 kyr respectively (see text for error considerations). However, the MPBE located 8 precession cycles below the base of C26n in correspondence to a short eccentricity maxima at Zumaia, could also serve as a guiding criteria to approximate or redefine the Thanetian base if this level demonstrated synchronous.
    Description: Published
    Description: 450–467
    Description: 2.2. Laboratorio di paleomagnetismo
    Description: JCR Journal
    Description: reserved
    Keywords: Astronomical Polarity Time Scale ; cyclostratigraphy; ; 04. Solid Earth::04.04. Geology::04.04.10. Stratigraphy
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
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  • 109
    Publication Date: 2017-04-04
    Description: A systematic survey of soil CO2 concentrations was carried out on the flanks of Somma^Vesuvius volcano in order to constrain possible pathways responsible of carbon dioxide diffuse degassing taking place during the present state of quiescence. Measurements were performed at 1162 sites in late winter^spring 2000,highlighting that soil CO2 concentrations range from 50 to 10500 ppmV. A statistical analysis was developed in order to define the threshold value of anomaly and separate the biogenic CO2 component,produced by soil respiration,from the inorganic component of deep provenance. A computer routine was also elaborated to interpret the grid of CO2 anomalous concentration values and define the actual location,orientation and length of degassing structures. The results obtained by this procedure reveal a main control of the regional stress field on the patterns of gas migration. The identified degassing lineaments are typically oriented along the Apenninic (NW^SE) and anti-Apenninic (NE^SW)trends,which are known to govern the past geological and structural evolution of the Campanian Plain and present seismicity and deformation pattern of Mount Vesuvius. A main degassing area was recognized on the eastern and southern flanks of the volcano,which likely relates to the geometry of the underlying carbonate basement,reaching its top (500 m depth) in this sector of the volcano.
    Description: Published
    Description: 55-79
    Description: partially_open
    Keywords: Somma-Vesuvius ; CO2 degassing ; Tectonics ; 04. Solid Earth::04.08. Volcanology::04.08.01. Gases
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
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  • 110
    Publication Date: 2017-04-04
    Description: This study presents a detailed analysis and interpretation of the seismicity that occurred on July 2-7 and August 22, 2000, during a ground uplift episode which started on March 2000 at Solfatara crater, Campi Flegrei. Earthquakes are located using a probabilistic grid-search procedure acting on a 3-D heterogeneous earth structure. The mainshock of the July swarm depicts a spectrum characterized by a few narrow peaks spanning the 1^5-Hz frequency band. For this event, we hypothesize a direct involvement of magmatic fluids in the source process. Conversely, the spectra of the August events are typical of shear failure. For these latter events, we evaluate the source properties from P-and Swave displacement spectra. Results for the most energetic shocks (Md around 2) yield a source radius in the order of 100 m and stress drop around 10 bars, in agreement with most of the earthquakes that occurred during the 1982-1984 bradyseismic crises. For the August swarm we identify two clusters of similar earthquakes. Application of highresolution relative location techniques to these events allows for the recognition of two parallel alignments trending NE^SW. The relationship among source dimension and relative location evidences overlapping of sources. This may be interpreted in terms of either a heterogeneous stress field or a lubrication process acting over the fault surface. For a selected subset of the August events, we also analyze the splitting of the shear waves: results are indicative of wave propagation through a densely fractured medium characterized by a distribution of cracks oriented NE-SW. The pattern of faulting suggested by relative locations and shear-wave splitting is not consistent with the surface trace of NW^SE striking faults. However, a detailed mesostructural analysis carried out over the Solfatara area indicated the occurrence of two main crack systems striking NW-SE and NE-SW. This latter system shows a strike consistent with that derived from seismic evidence. Results from a stress analysis of the crack systems indicate that a fluid overpressure within the NW-SE-striking faults is able to form NE-SW cracks. We found that the pressure of fluids Pf required to activate the NW-SE faults is less than cHmin, while the Pf value required to open the NE-SW cracks is higher than cHmax. Our main conclusions are: (a) the Solfatara area is affected by two orthogonal fracture systems, and the fluid pathway during the 2000 crisis mainly occurred along the NNE-SSW/NE-SW-striking crack system; (b) the July seismicity is associated to the upward migration of a pressure front triggered by an excess of fluid pressure from a small-size magmatic intrusion; conversely, the August events are associated to the brittle readjustment of the inflated system occurring along some lubricated structures.
    Description: Published
    Description: 229-246
    Description: partially_open
    Keywords: Seismicity ; Hydrothermal fuids ; Fuid pressure ; Faults ; 04. Solid Earth::04.04. Geology::04.04.09. Structural geology ; 04. Solid Earth::04.06. Seismology::04.06.08. Volcano seismology ; 04. Solid Earth::04.06. Seismology::04.06.09. Waves and wave analysis
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
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  • 111
    Publication Date: 2017-04-04
    Description: We have undertaken detailed observations of the formation of the `Laghetto´ cinder cone, a new cone that formed during a 2-week period of intense activity in Piano del Lago, on the upper slopes of Mount Etna in summer 2001. We describe the events leading to the formation of a small graben, the formation of pit craters on the base of the graben, the onset of phreatomagmatic activity, a transition to intense Strombolian activity, and a return to phreatomagmatic activity as the eruption came to an end. We discuss the reasons for these transitions, and describe the morphological development of the cone during these events. Arcuate cracks on the southern part of the cone were related to withdrawal of magma at the end of the eruption. Other slope instabilities that developed during the eruption include the formation of small radial grain flows on the outer flanks of the cone and the collapse into the crater of part of the crater rim. Some of the failure planes we observed were first identified using a FLIR TM 695 thermal infrared camera. This is the first time that infrared thermography has been used to detect instability of volcanic structures. Results obtained during this test case demonstrate that thermal cameras are a very useful tool for studies of volcanic instability.
    Description: Published
    Description: 225-239
    Description: partially_open
    Keywords: Etna volcano ; cinder cone ; volcano instability ; thermal images ; phreatomagmatic activity ; 04. Solid Earth::04.08. Volcanology::04.08.03. Magmas ; 04. Solid Earth::04.08. Volcanology::04.08.06. Volcano monitoring ; 04. Solid Earth::04.08. Volcanology::04.08.07. Instruments and techniques
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  • 112
    Publication Date: 2017-04-04
    Description: Oxygen isotopes of both rainwater and groundwater samples from Mt Etna were used to obtain information on recharge areas, flow paths, and the origin of wet air masses. Oxygen isotope composition was determined in rainwater samples collected for a period of 3 years (October 1997–October 2000), in 11 rain-gauges distributed along the flanks of Mt Etna from sea level to 2900 m of altitude. Values ranged from 213.8 to þ 1.9‰, the lowest values being measured at higher altitudes and/or during cooler periods. For rain-gauges located from sea level up to 1000 m altitude, volume weighted values defined an isotopic gradient of 22.7‰/km, which is in the range observed in the Mediterranean area. Higher-altitude gauges yielded a much lower gradient (20.6‰/km), probably due to the fact that vapour condensing at higher altitudes was mixed with an 18O-rich volcanic component deriving from the huge vapour output of the summit craters. The oxygen isotope composition of about 210 groundwater samples collected all around the volcano ranged from 29.3 to 25.0‰. The higher values measured on the eastern flank indicated that recharge occurs at lower altitudes on this flank. The low variability (0.30–0.65‰) of the monthly values gathered from 14 groundwater sampling points over a period of 2 years indicates that the groundwater system is isotopically well mixed. Some long-term trends may be explained by variations in annual recharge, due to the prevalent isotope composition of wet air masses.
    Description: National Group for Volcanology (G.N.V.), Italy.
    Description: Published
    Description: 282–299
    Description: partially_open
    Keywords: Isotope hydrology ; d18O ; Groundwater ; Rainwater ; Mt Etna ; 03. Hydrosphere::03.02. Hydrology::03.02.02. Hydrological processes: interaction, transport, dynamics ; 05. General::05.02. Data dissemination::05.02.04. Hydrogeological data
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  • 113
    Publication Date: 2017-04-04
    Description: Basaltic volcanism is most typically thought to produce effusion of lava, with the most explosive manifestations ranging from mild Strombolian activity to more energetic fire fountain eruptions. However, some basaltic eruptions are now recognized as extremely violent, i.e., generating widespread phreatomagmatic, subplinian and Plinian fall deposits. We focus here on the influence of conduit processes, especially partial open-system degassing, in triggering abrupt changes in style and intensity that occurred during two examples of basaltic Plinian volcanism. We use the 1886 eruption of Tarawera, New Zealand, the youngest known basaltic Plinian eruption and the only one for which there are detailed written eyewitness accounts, and the well-documented 122 BC eruption of Mount Etna, Italy, and present new grain size and vesicularity data from the proximal deposits. These data show that even during extremely powerful basaltic eruptions, conduit processes play a critical role in modifying the form of the eruptions. Even with very high discharge, and presumably ascent, rates, partial open-system behaviour of basaltic melts becomes a critical factor that leads to development of domains of largely stagnant and outgassed melt that restricts the effective radius of the conduit. The exact path taken in the waning stages of the eruptions varied, in response to factors which included conduit geometry, efficiency and extent of outgassing and availability of ground water, but a relatively abrupt cessation to sustained high-intensity discharge was an inevitable consequence of the degassing processes.
    Description: Published
    Description: 1-14
    Description: partially_open
    Keywords: basaltic Plinian eruption ; Etna ; Tarawera and explosive volcanism ; 04. Solid Earth::04.08. Volcanology::04.08.06. Volcano monitoring ; 05. General::05.02. Data dissemination::05.02.03. Volcanic eruptions
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  • 114
    Publication Date: 2017-04-04
    Description: Concepts of information theory are applied to global models of the geomagnetic field B of the last century. The temporal behavior of information content suggests that B is in a chaotic state with characteristic times close to those of its westward drift and of the convective overturn in the outer core and the secular variation shows a comparable characteristic time of predictability. The main implication of these results is the suggestive hypothesis that a possible geomagnetic reversal or excursion is currently in progress.
    Description: Published
    Description: 269-275
    Description: partially_open
    Keywords: information theory ; Kolmogorov entropy ; geomagnetic field ; geomagnetic reversals ; 04. Solid Earth::04.05. Geomagnetism::04.05.02. Geomagnetic field variations and reversals
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
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  • 115
    Publication Date: 2017-04-03
    Description: Remarkable changes in the local magnetic field were associated with the onset of the 2002–2003 flank eruption at Mt. Etna. After differential magnetic field measurements were filtered from the external noise by using adaptive filters, we recognized two stages in the total intensity changes, which are closely related to different volcanic events: (a) rapid variations of about 4–5 nT associated with October 26 seismic swarm recorded beneath the summit craters; (b) step-like variations of 9–10 nT coincident with October 27 eruptive fissures opening up in the north flank. These observations are generally consistent with those calculated from simple magnetic models of these volcanic processes, in which the magnetic changes are generated by stress redistribution due to magmatic intrusions at different depth. The magnetic data not only allow the timing of the intrusive event to be described in greater detail but also, together with other volcanological and geophysical evidences, permit some constraints to be set on the characteristics of propagation of a shallow dike. Firstly, at around midnight on 26 October magma was rapidly injected to a depth of 3–4 km just below the summit craters. Secondly, after 1:00 on 27 October, continued intrusion magma occurred upward and culminated a few hundred meters below the free surface fractured along a N–E direction. Thirdly, at about 2:28, magma gave rise to an explosive fissural vent at the northern base of the NE crater near 3000 m a.s.l. Finally, at about 5:00, the first eruptive fissure became active along the eastern border of the NE rift at 2500 m a.s.l. The rate of growth of the magnetic anomalies, moreover, leads to the interpretation that the magmatic intrusion travelled northward from base of the NE crater to the NE rift at approximately 14 m/min.
    Description: Published
    Description: 1-14
    Description: partially_open
    Keywords: eruptions ; monitoring ; magnetic methods ; volcanomagnetic modeling ; Mt. Etna ; 04. Solid Earth::04.05. Geomagnetism::04.05.04. Magnetic anomalies ; 04. Solid Earth::04.08. Volcanology::04.08.06. Volcano monitoring
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  • 116
    Publication Date: 2017-04-04
    Description: This survey proposes a new approach to identify buried caldera boundaries of a volcanic cone, combining (1) a systematic elliptic Fourier functions (EFF) analysis on the contour lines based on the external shape of the edifice with (2) self-potential (SP) measurements on volcano flanks. The methodology of this approach is to investigate the relationships between (1) vertical morphological changes inferred from EFF analysis and (2) lateral lithological transition inside the edifice inferred from SP/elevation gradients. The application of these methods on Misti volcano in southern Peru displays a very good correlation. The three main boundaries evidenced by hierarchical cluster analysis on the contour lines coincide with the two main boundaries characterised by SP signal and with a secondary SP signature related with a summit caldera. In order to explain these results showing a very good correlation between morphologic and lithologic changes as function of elevation, caldera boundaries have been suggested. The latter would be located at an average elevation of (1) 4350–4400 m, (2) 4950–5000 m, and (3) 5500– 5550 m. For the lowest boundary in elevation, the coincidence with the lateral extension of the hydrothermal system inferred from SP measurements suggests that caldera walls act as a barrier for lateral extension of hydrothermal systems. In the summit area, the highest boundary has been related with the summit caldera, inferred by a secondary SP minimum and geological evidence.
    Description: - Institut de Recherche pour le Développement (IRD) - Instituto Geofisico del Peru´ (IGP).
    Description: Published
    Description: 283– 297
    Description: partially_open
    Keywords: caldera ; elliptic Fourier functions ; geomorphology ; self-potential ; Misti volcano ; Peru ; 03. Hydrosphere::03.02. Hydrology::03.02.02. Hydrological processes: interaction, transport, dynamics ; 03. Hydrosphere::03.02. Hydrology::03.02.03. Groundwater processes ; 03. Hydrosphere::03.02. Hydrology::03.02.04. Measurements and monitoring ; 03. Hydrosphere::03.04. Chemical and biological::03.04.05. Gases ; 03. Hydrosphere::03.04. Chemical and biological::03.04.06. Hydrothermal systems ; 04. Solid Earth::04.01. Earth Interior::04.01.02. Geological and geophysical evidences of deep processes ; 04. Solid Earth::04.02. Exploration geophysics::04.02.04. Magnetic and electrical methods ; 04. Solid Earth::04.04. Geology::04.04.03. Geomorphology ; 04. Solid Earth::04.04. Geology::04.04.09. Structural geology ; 04. Solid Earth::04.04. Geology::04.04.11. Instruments and techniques ; 04. Solid Earth::04.08. Volcanology::04.08.05. Volcanic rocks ; 05. General::05.02. Data dissemination::05.02.04. Hydrogeological data ; 05. General::05.05. Mathematical geophysics::05.05.99. General or miscellaneous ; 05. General::05.08. Risk::05.08.99. General or miscellaneous ; 04. Solid Earth::04.08. Volcanology::04.08.08. Volcanic risk
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  • 117
    Publication Date: 2017-04-04
    Description: The southern portion ofthe Upper Rhine Graben, a major oblique rift among France, Germany and Switzerland, shows a weak instrumental seismic record despite its remarkable physiographic imprint within the Northern Alpine foreland. Since traces of active deformation can be found in this region and based on experience in other European areas with high seismic hazard and dense population, we searched for past earthquakes recorded in historical catalogues. Based on the fact that tectonic deformation cumulates through geological time and considering that long-term effects tend to leave characteristic signatures on present-day landscape arrangement, our goal was to identify faults that could have caused the damage of recorded historical events. We isolated five main earthquakes, ofmoderate Richter magnitude, essentially located on the E flank of the graben (as is the case with recent seismic activity). To such events, we were able to associate a specific prospective structure through the use ofa procedure thus far successfully employed in Southern European contexts. We concentrated on three events which showed (a) notable sensitivity to the density of the historical felt reports and (b) accordance with on-going subtle deformation pattern. Another, most relevant earthquake (M 5.5) yielded a promising match with the known deformation network in the region. As a template to better constrain earthquake cycle and damage potential, historical seismicity offers an invaluable tool, since it contains a specific record, although not always unambiguous. Cross-checking such data with pertinent geological information allows to devise a realistic fault geometry capable of being responsible for a specific seismic event.
    Description: Published
    Description: 403-425
    Description: open
    Keywords: historical seismicity ; seismogenic sources ; Upper Rhine Graben ; 04. Solid Earth::04.06. Seismology::04.06.05. Historical seismology
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  • 118
    Publication Date: 2017-04-04
    Description: Since the early 1970s enhanced eruptive activity of Mount Etna has been accompanied by selective geochemical changes in erupted lavas, among which a gradual increase of alkalis whose origin is still debated. Here we provide further insight into the origin of this recent evolution, based on a detailed study of the chemistry and dissolved volatile content of melt inclusions trapped in olivine crystals of unusual plagioclase-poor primitive basalt that was extruded during a highly explosive flank eruption in July–August 2001. Two types of lava were erupted simultaneously along a N–S fracture system. Trachybasalts from the upper vents (2950–2700 m) were simply drained out by fracturing of the central volcanic conduit. They are identical to summit crater lavas and contain Mg-poor olivines (Fo70–72) with evolved and volatile-poor melt inclusions that represent late-stage crystallisation during shallow open conduit degassing. In contrast, plagioclase-poor basalt (80% of total) extruded through the lower vents (2550–2100 m) derived from lateral dyke intrusion of a more primitive and volatile-rich magma across the sedimentary basement. This primitive melt is best preserved in rare Fo82.4–80.5 skeletal olivines present in lapilli deposits from the most powerful activities at the 2550 m vent. Its high dissolved contents of H2 O (3.4 wt.%), CO2 (0.11 to 0.41 wt.%), S (0.32 wt.%), Cl (0.16 wt.%) and F (0.094 wt.%) point to its closed system ascent from ∼400 to 250 MPa (∼12 to 6.5 km depth b.s.l.). However, the predominance of euhedral olivine phenocrysts with common reverse zoning (cores Fo76–78 and rims Fo78–80) and decrepited inclusions shows that most of the erupted basalt derived from a slightly more evolved, crystallizing body of the same magma that was invaded by the uprising primitive melt prior to erupting. The few preserved inclusions in these olivines indicate pre-eruptive storage of that magma body at about 5 km depth b.s.l., in coherence with seismic data. We propose that the 2001 flank eruption resulted from gradual overpressuring of Etna's shallow plumbing system due to the influx of volatile-rich primitive basalt that may have begun several months in advance. We find that this basalt is much richer in alkalis (2.0 wt.% K2 O) and has higher S/Cl (2.0) but lower Cl/K and Cl/F ratios than all pre-1970s Etnean lavas (1.4 wt.% K2 O, S/Cl=1.5), as further exemplified by melt inclusions in entrained olivine xenocrysts. Combining these new observations with previously published data, we argue that the 2001 basalt represents a new alkali-rich basic end-member feeding Mt. Etna, only few amount of which had previously been extruded during a 1974 peripheral eruption and, more recently, during brief paroxysmal summit events. Over the last three decades this new magma has progressively mixed with and replaced the former K-poorer trachybasalts filling the plumbing system, leading to extrusion of gradually more primitive and alkali-richer lavas. Its geochemical singularities cannot result from shallow crustal contaminations. Instead, they suggest the involvement of an alkali-richer but Cl-poorer arc-type component during recent magma genesis beneath Etna.
    Description: Published
    Description: 1-17
    Description: partially_open
    Keywords: Mt. Etna ; volatiles ; degassing ; eruptive mechanism ; magma geochemistry ; 04. Solid Earth::04.08. Volcanology::04.08.01. Gases ; 04. Solid Earth::04.08. Volcanology::04.08.03. Magmas ; 04. Solid Earth::04.08. Volcanology::04.08.06. Volcano monitoring ; 05. General::05.02. Data dissemination::05.02.01. Geochemical data
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  • 119
    Publication Date: 2017-04-04
    Description: A number of tumuli formed on the aa-dominated lava fan complex which developed in the medial zone of the 1983 flow-field of Mount Etna during the later stages of the eruption. This complex flow-field formed on shallow sloping ground below a scarp between 1900 and 1700 m asl. A major tube system fed a branching tube network in the fan complex. Numerous tumuli and break-outs of lava formed in the fan. Three main types of tumulus are identified: (1) Focal tumuli, which are formed from the break-up and uplift of `old´, thick lava crust and themselves become sustained sites for the distribution of lava both as flows and within distributary tubes. These focal tumuli are significant centres associated with major tubes. (2) Satellite tumuli, which are typically elongate, whale-back shaped features that branch out from focal tumuli. These satellite tumuli were initially lava flows erupted from a focal tumulus. The crust of the flow slowed or came to a halt and the rigid crust became uplifted and fractured, forming a dome-shaped ridge feature. These satellite tumuli continued to be fed from the focal tumulus and became sites of lava emission with numerous break-outs. (3) Distributary tumuli formed on the fan associated with short-lived break-outs from tubes and are relatively simple structures formed from limited effusion of toey lobes and pahoehoe lava. The major tumuli on the fan complex show distinct dilation fractures. The fracture surfaces provide good exposure of the crust and three distinct zones are recognised – an upper zone showing columnar jointing, a middle zone consisting of planar fracture surfaces and a basal zone with distinctive banded planar fracture surfaces showing evidence of both brittle and ductile formation. Using these data a model is proposed for tumulus growth. Field analysis of the fan complex shows how it was fed by a branching tube system, leading to flow thickening, formation of tumuli and numerous ephemeral boccas.
    Description: Published
    Description: partially_open
    Keywords: aa lava flow-field ; Mount Etna ; tumulus ; lava crust and lava tubes. ; 04. Solid Earth::04.08. Volcanology::04.08.02. Experimental volcanism ; 04. Solid Earth::04.08. Volcanology::04.08.03. Magmas ; 04. Solid Earth::04.08. Volcanology::04.08.06. Volcano monitoring
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  • 120
    Publication Date: 2017-04-04
    Description: The role of sector collapse in the generation of catastrophic volcanigenic tsunami has become well understood only recently, in part because of the problems in the preservation and recognition of tsunami deposits. Tinti et al. [Tinti, S., Bortolucci, E., Romagnoli, C., 2000. Computer simulations of tsunamis due to sector collapse at Stromboli, Italy. J. Volcanol. Geotherm. Res. 96, 103–128] modeled a tsunami produced by the c. 5,000 years BP collapse of the Sciara del Fuoco on the island volcano Stromboli. Although deposits associated with this event are generally lacking on the island, volcaniclastic breccias on the SE side of the island extending to an elevation above 120 m a.s.l. may have been generated by this tsunami. Deposits above 100 m are dominated by coarse breccias comprising disorganized, poorly sorted, nonbedded, angular to subangular lava blocks in a matrix of finer pyroclastic debris. These breccias are interpreted as a water-induced mass flow, possibly a noncohesive debris flow, generated as colluvial material on steep slopes was remobilized by the return flow of the tsunami wave, the run-up of which reached an elevation exceeding 120 m a.s.l. Finer breccias of subrounded to rounded lava blocks cropping out at 15 m a.s.l. are similar to modern high-energy beach deposits and are interpreted as beach material redeposited by the advancing tsunami wave. The location of these deposits matches the predicted location of the maximum tsunami wave amplitude as calculated by modeling studies of Tinti et al. [Tinti, S., Bortolucci, E., Romagnoli, C., 2000. Computer simulations of tsunamis due to sector collapse at Stromboli, Italy. J. Volcanol. Geotherm. Res. 96, 103–128]. Whereas the identification and modeling of paleo-tsunami events is typically based on the observation of the sedimentary deposits of the tsunami run-up, return flow may be equally or more important in controlling patterns of sedimentation.
    Description: Published
    Description: 329-340
    Description: partially_open
    Keywords: tsunami ; flank collapse ; landslide ; run-up ; return flow ; debris flow ; 04. Solid Earth::04.08. Volcanology::04.08.06. Volcano monitoring ; 04. Solid Earth::04.08. Volcanology::04.08.08. Volcanic risk
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  • 121
    Publication Date: 2017-04-04
    Description: We analyzed about 150 local earthquakes recorded in Southeastern Sicily from 1994 to 2001 and estimated coda- Q, intrinsic and scattering attenuation. We used the single scattering assumption to fit the amplitude envelopes of the coda at different frequency bands, obtaining a Qc varying with frequency as generally observed in tectonically active areas. Lapse time dependence has been also studied for the area, with the coda waves analyzed at window lengths ranging from 15 to 50 s, provided the coda duration permitted it. We found that Q0 ( Qc at 1 Hz) increases with lapse time and we interpreted this as due to increasing Qc with depth. Conversely, the frequency dependence coefficient n is mostly stationary at all the lapse time window lengths. Finally, using the independent estimates of Qc and the total Q ( QT) previously obtained for the area by other authors from direct S-waves of the same data set, we separated the intrinsic ( ) from the scattering ( ) attenuation factor. The results suggest that in Southeastern Sicily intrinsic dissipation plays a predominant role with respect to scattering phenomena.
    Description: Published
    Description: 55-66
    Description: partially_open
    Keywords: Coda waves ; Intrinsic attenuation ; Scattering ; Frequency dependence and Southeastern Sicily ; 04. Solid Earth::04.06. Seismology::04.06.03. Earthquake source and dynamics
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  • 122
    Publication Date: 2017-04-04
    Description: Chlorine- and sulphur-bearing compounds in fumarole discharges of the La Fossa crater at Vulcano Island (Italy) can be modelled by a mixing process between magmatic gases and vapour from a boiling hydrothermal system. This allows estimating the compounds in both endmembers. Magma degassing cannot explain the time variation of sulphur and HCl concentrations in the deep endmember, which are more probably linked to reactions of solid phases at depth, before mixing with the hydrothermal vapours. Based on the P^T conditions and speciation of the boiling hydrothermal system below La Fossa, the HCl and Stot contents in the hydrothermal vapours were used to compute the redox conditions and pH of the aqueous solution. The results suggest that the haematite magnetite buffer controls the hydrothermal fO2 values, while the pH has increased since the end of the 1970s. The main processes affecting pH values may be linked to Na^Ca exchanges between evolved seawater, feeding the boiling hydrothermal system, and local rocks. While Na is removed from water, calcium enters the solution, undergoes hydrolysis and produces HCl,lowering the pH of the water. The increasing water^rock ratio within the hydrothermal system lowers the Ca availability, so the aqueous solution becomes less acidic. Seawater flowing towards the boiling hydrothermal brine dissolves a large quantity of pyrite along its path. In the boiling hydrothermal system, dissolved sulphur precipitates as pyrite and anhydrite, and becomes partitioned in vapour phase as H2S and SO2. These results are in agreement with the paragenesis of hydrothermal alteration minerals recovered in drilled wells at Vulcano and are also in agreement with the isotopic composition of sulphur emitted by the crater fumaroles.
    Description: Published
    Description: 137-150
    Description: partially_open
    Keywords: chlorine ; sulphur ; hydrothermal system ; genetic processes ; Vulcano Island ; 04. Solid Earth::04.04. Geology::04.04.12. Fluid Geochemistry ; 04. Solid Earth::04.08. Volcanology::04.08.01. Gases ; 04. Solid Earth::04.08. Volcanology::04.08.04. Thermodynamics ; 04. Solid Earth::04.08. Volcanology::04.08.06. Volcano monitoring ; 05. General::05.02. Data dissemination::05.02.01. Geochemical data
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  • 123
    Publication Date: 2017-04-04
    Description: Radon levels were measured in 119 groundwater samples collected throughout the active volcanic area of Mt. Etna by means of a portable Lucas-type scintillation chamber. The measured activity values range from 1.8 to 52.7 Bq l 1. About 40% of the samples exceed the maximum contaminant level of 11 Bq l 1 proposed by the USEPA in 1991. The highest radon levels are measured in the eastern sector of the volcano, which is the seismically most active zone of the volcano. On the contrary the south-western sector, which is both seismically active and a site of intense magmatic degassing, display lower radon levels. This is probably due to the formation of a free gas phase (oversaturation of CO2) that strips the radon from the water. Comparison of the data gathered at Mt. Etna with those of other areas indicates that 222Rn activity in groundwater is positively correlated with both the content of parent elements in the aquifer rocks and the temperature of the geothermal systems that interacts with the sampled aquifers.
    Description: Published
    Description: 187–201
    Description: partially_open
    Keywords: Groundwater ; Radon ; Mount Etna ; Active volcanic areas ; 03. Hydrosphere::03.02. Hydrology::03.02.03. Groundwater processes ; 03. Hydrosphere::03.02. Hydrology::03.02.06. Water resources ; 03. Hydrosphere::03.04. Chemical and biological::03.04.03. Chemistry of waters ; 03. Hydrosphere::03.04. Chemical and biological::03.04.07. Radioactivity and isotopes ; 04. Solid Earth::04.08. Volcanology::04.08.06. Volcano monitoring ; 05. General::05.08. Risk::05.08.01. Environmental risk
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  • 124
    Publication Date: 2017-04-04
    Description: Mount Etna produced two significant eruptions in 2001 and 2002–2003, which we have analysed using geological, seismic and deformation data. These eruptions showed some similarities, such as the activating of two magmatic plumbing systems (central–lateral and eccentric), but they differed in their triggering mechanisms. While the 2001 eruption was largely the result of the emplacement of a N–S eccentric dike (independent from the central conduits) consistent with E–W regional extension, the 2002–2003 eruption occurred in response to a major flank slip on the eastern and southeastern sides of the volcano. This is demonstrated by the spatial and temporal distribution of seismicity and deformation preceding and accompanying the two eruptions. During the months prior to the 2001 eruption, most epicenters were concentrated on the southern flank, at depths of 5–15 km below sea level. During the 4 days before the eruption, earthquake hypocenters migrated to shallower levels (from 5 km bsl. upward) indicating the emplacement of the eccentric dike. This is confirmed by the patterns of ground fracturing observed in the field and deformation documented by electronic distance measurements (EDM). In contrast, the months before the 2002–2003 eruption were characterised by shallower seismicity, mainly concentrated along the active faults bordering the slipping flank sector. Flank slip accelerated in September 2002 and a second, more vigorous acceleration of flank slip occurred on 26–27 October 2002, accompanying the opening of eruptive vents. The very short (2 h) seismic crisis preceding the onset of eruptive activity stands in neat contrast with the 4 days of intense seismicity before the 2001 eruption. Subsequently, flank slip-deformation extended all over the eastern and southeastern flanks of the volcano, causing serious damage in this sector. The events of 2001–2003 can be seen as a continuous chain of intimately interacting processes including regional tectonics, magma accumulation and eruption, and flank instability. In this scenario the 2001 eruption led to increased flank instability that subsequently accelerated and culminated with the massive flank slip, which in turn facilitated the 2002–2003 eruption. This sequence of events points to a long-term feedback mechanism between magmatism and flank instability at Etna.
    Description: Published
    Description: 235-255
    Description: partially_open
    Keywords: eruption triggering ; central–lateral vs. eccentric eruptions ; flank instability and slip ; volcano-tectonics ; Mt. Etna ; instrumental monitoring ; 04. Solid Earth::04.07. Tectonophysics::04.07.07. Tectonics ; 04. Solid Earth::04.08. Volcanology::04.08.06. Volcano monitoring ; 05. General::05.02. Data dissemination::05.02.03. Volcanic eruptions ; 04. Solid Earth::04.08. Volcanology::04.08.08. Volcanic risk
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  • 125
    Publication Date: 2017-04-04
    Description: This work addresses the study of fluid circulation of the Stromboli island using a dense coverage of self-potential (SP) and soil CO2 data. A marked difference exists between the northern flank and the other flanks of the island. The northern flank exhibits (1) a typical negative SP/altitude gradient not observed on the other flanks, and (2) higher levels of CO2. The general SP pattern suggests that the northern flank is composed of porous layers through which vadose water flows down to a basal water table, in contrast to the other flanks where impermeable layers impede the vertical flow of vadose water. In the Sciara del Fuoco and Rina Grande-Le Schicciole landslide complexes, breccias of shallow gliding planes may constitute such impermeable layers whereas elsewhere, poorly permeable, fine-grained pyroclastites or altered lava flows may be present. This general model of the flanks also explains the main CO2 patterns: concentration of CO2 at the surface is high on the porous north flank and lower on the other flanks where impermeable layers can block the upward CO2 flux. The active upper part of the island is underlain by a well-defined hydrothermal system bounded by short-wavelength negative SP anomalies and high peaks of CO2. These boundaries coincide with faults limiting ancient collapses of calderas, craters and flank landslides. The hydrothermal system is not homogeneous but composed of three main subsystems and of a fourth minor one and is not centered on the active craters. The latter are located near its border. This divergence between the location of the active craters and the extent of the hydrothermal system suggests that the internal heat sources may not be limited to sources below the active craters. If the heat source strictly corresponds to intrusions at depth around the active conduits, the geometry of the hydrothermal subsystems must be strongly controlled by heterogeneities within the edifice such as craters, caldera walls or gliding planes of flank collapse, as suggested by the correspondence between SP^CO2 anomalies and structural limits. The inner zone of the hydrothermal subsystems is characterized by positive SP anomalies, indicating upward movements of fluids, and by very low values of CO2 emanation. This pattern suggests that the hydrothermal zone becomes self-sealed at depth, thus creating a barrier to the CO2 flux. In this hypothesis, the observed hydrothermal system is a shallow one and it involves mostly convection of infiltrated meteoric water above the sealed zone. Finally, on the base of CO2 degassing measurements, we present evidence for the presence of two regional faults, oriented N41‡ and N64‡, and decoupled from the volcanic structures.
    Description: Published
    Description: 1^18
    Description: partially_open
    Keywords: Stromboli ; hydrothermal system ; self-potential ; soil gas ; carbon dioxide ; Aeolian islands ; 03. Hydrosphere::03.02. Hydrology::03.02.02. Hydrological processes: interaction, transport, dynamics ; 03. Hydrosphere::03.04. Chemical and biological::03.04.06. Hydrothermal systems ; 04. Solid Earth::04.04. Geology::04.04.12. Fluid Geochemistry ; 04. Solid Earth::04.08. Volcanology::04.08.01. Gases ; 05. General::05.02. Data dissemination::05.02.01. Geochemical data ; 04. Solid Earth::04.08. Volcanology::04.08.08. Volcanic risk
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  • 126
    Publication Date: 2017-04-04
    Description: Volcanism at Mount Etna (Italy) has been observed for millennia and inspired ancient mythologies as well as scientific thought through countless generations.Yetmuch of our understanding of the way this volcano works stems fromstudies of the past 20 years, and in particular from strengthened monitoring since the late 1980s. In addition, the eruptive activity of Etna has undergone significant changes during the past 13 years, and these have led to an improved understanding of the relationship between the plumbing system of the volcano and instability of its eastern to southern f lanks. Following the end of the 1991–1993 eruption, a new eruptive cycle began, which so far has produced about 0.23 km3 of lavas and pyroclastics (dense-rock equivalent). The cycle evolved frominitial recharging of the plumbing system and inf lation, followed by powerful summit eruptions and slow spreading of the eastern to southern f lanks, to a sequence of f lank eruptions accompanied by accelerated f lank displacement. Structurally, the volcanic system has become increasingly unstable during this period. Volcanological, geophysical and geochemical data allow the cause–effect and feedback relationships between magma accumulation below the volcano, f lank instability, and the shift from continuous summit activity to episodic f lank eruptions to be investigated. In this scenario, the growth of magma storage areas at a depth of 3–5 km below sea level exerts pressure against those f lank sectors prone to displacement, causing them to detach from the stable portions of the volcanic edifice. Geochemical data indicate that magma remains stored belowthe volcano, even during phases of intense eruptive activity, thus causing a net volumetric increase that is accommodated by f lank displacement. Instability can be enhanced by the forceful uprise ofmagma through the f lanks, as in 2001, when the f irst f lank eruption of the current eruptive cycle took place. Subsequent f lank eruptions in 2002–2003 and 2004– 2004, on the other hand, were, at least in part, facilitated by the opening of fractures at the head of moving f lank sector, although the eruptions were significantly dissimilar from one another. Renewed inflation of the volcano after the 2004–2005 eruption, continued displacement of the unstable f lank sector, and gradual resumption of summit activity in late-2005, demonstrate that the same feedback mechanisms continue to be active, and the Etna system remains highly unstable. The evolution of earlier eruptive cycles shows that a return to a state of relative stability is only possible once a voluminous f lank eruption effectively drains the magmatic plumbing system.
    Description: Published
    Description: 85–114
    Description: reserved
    Keywords: Mount Etna ; eruptive cycle ; volcano monitoring ; seismicity ; deformation ; geochemistry ; structural geology ; magma storage ; 03. Hydrosphere::03.04. Chemical and biological::03.04.05. Gases ; 04. Solid Earth::04.01. Earth Interior::04.01.02. Geological and geophysical evidences of deep processes ; 04. Solid Earth::04.03. Geodesy::04.03.06. Measurements and monitoring
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  • 127
    Publication Date: 2017-04-04
    Description: The attenuation of seismic waves is one of the basic physical parameters used in seismological studies and earthquake engineering, which is closely related to the seismicity and regional tectonic activity of a particular area. In this work, the seismic attenuation in the Straits of Messina, affected by several and strong historical earthquakes, was studied using waveforms recorded by a local seismic network composed of seven stations. We measured: the coda quality factor (Qc) in the Single Scattering model hypothesis; the direct quality factor (Qd) applying the Coda Normalization method for S-waves; and the intrinsic and scattering quality factor (Qi and Qs) by the Multiple Lapse Time Window Analysis (MLTWA) method. Coda Q values were obtained using different lapse times (40, 60 and 80 s) for the frequency bands centred at 1.5, 3, 6 and 12 Hz. Our findings indicate that Qc increases with increasing lapse time and that Qc is frequency dependent. This behaviour is usually correlated to the degree of tectonic complexity and to the presence of heterogeneities at several scales. In fact, by using the Coda Normalization method we obtained low Qd values, as expected for a heterogeneous and active zone. Finally, by the MLTWA method we observe that the contribution of the scattering attenuation (Qs −1) prevails on the intrinsic absorption (Qi −1) until 3 Hz. Conversely, Qi −1 and Qs −1 seem to be of the same order in the higher frequency bands.
    Description: Published
    Description: 173-185
    Description: reserved
    Keywords: Coda waves ; Intrinsic attenuation ; S-waves ; Scattering attenuation ; Straits of Messina ; 04. Solid Earth::04.06. Seismology::04.06.09. Waves and wave analysis
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  • 128
    Publication Date: 2017-04-04
    Description: We investigated the relationships between modelled strain produced by explosive activity through a volcanic conduit, observed paroxystic episodes on Mt. Etna, and high-precision continuous tilt signals recorded during such events from the tilt monitoring network. The tilt changes detected during two different explosive episodes were compared with those calculated from analytical models of ground deformation in order to constrain source properties. The July 22, 1998 subplinian explosion from Voragine crater produced small tilt changes (order of 0.5–1.5 μrad) recorded over the entire volcano edifice, implying a small storage at nearly 2.5 km below sea level. The 1998–2000 period was characterized by tens of spectacular lava fountains from the South-East crater. Very small tilt change (∼ 0.1 μrad) was recorded by a single station on the high north-eastern flank of Mt. Etna and indicated the action of a limited and shallow conduit with 1.5–1.9 km depth. These results provide a contribution to better infer the shallow plumbing system beneath Mt. Etna.
    Description: Published
    Description: 221–234
    Description: reserved
    Keywords: explosive activity ; tilt data ; volcano source modeling ; Mt. Etna ; 04. Solid Earth::04.08. Volcanology::04.08.06. Volcano monitoring ; 05. General::05.02. Data dissemination::05.02.03. Volcanic eruptions
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  • 129
    Publication Date: 2017-04-04
    Description: The pattern of volcanic tremor accompanyingthe 1989 September eruption at the south-east summit crater of Mount Etna is studied. In specific, sixteen episodes of lava fountaining, which occurred in the first phase of the eruption, are analysed. Their periodic behaviour, also evidenced by autocorrelation, allows us to define the related tremor amplitude increases as intermittent volcanic tremor episodes. Focusingon the regular intermittent behaviour found for both lava fountains and intermittent volcanic tremors, we tried an a posteriori forecast using simple statistical methods based on linear regression and the Student’ t-test. We performed the retrospective statistical forecast, and found that several eruptions would have been successfully forecast. In order to focus on the source mechanism of tremor linked to lava fountains, we investigated the relationship between volcanic and seismic parameters. A mechanism based on a shallow magma batch ‘regularly’ refilled from depth is suggested.
    Description: Published
    Description: open
    Keywords: Mount Etna ; lava fountain eruption ; volcanic tremor ; statistical a posteriori forecast ; 04. Solid Earth::04.08. Volcanology::04.08.06. Volcano monitoring
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  • 130
    Publication Date: 2017-04-04
    Description: The results of a detailed stratigraphic study, carried out in the areas located to the east and south-west of Mt. Epomeo at Ischia, are presented and compared with those of previous geological, archaeological and historical investigations to show the relationships among caldera resurgence, volcanism and slope instability in the past 5.5 ka. Resurgence at Ischia began at about 30 ka B.P. and occurred through intermittent uplifting and tectonic quietness phases. During the past 5.5 ka reactivation of faults and related volcanic activity was accompanied by emplacement of deposits generated by surface gravitational movements. These deposits were generated in four main phases, dated between 5.5 and 2.9 ka, around 2.9 ka, between 2.6 and 2.3 ka, and between 2.3 and 1.9 ka, respectively. Deposits formed by gravitational movements preceded and followed the emplacement of volcanic rocks, testifying that slope instability was induced by vertical movements, which also activated and/or reactivated faults and fractures that fed volcanism. The results of this study therefore suggest that, although slope failure can occur as a consequence of a variety of factors, resurgence has to be considered a factor inducing a particularly intense slope instability. Resurgence is accompanied by activation of faults and renewal of volcanism, causing oversteepening of the slopes and generating seismicity that could trigger surface gravitational movements. Furthermore, the availability of large amount of loose material, rapidly accumulated along the slopes during eruptions, favors landslide generation.
    Description: Published
    Description: 148–165
    Description: reserved
    Keywords: Slope instability ; Volcanism ; Volcano-tectonism ; Resurgent calderas ; Ischia ; 04. Solid Earth::04.04. Geology::04.04.03. Geomorphology ; 04. Solid Earth::04.04. Geology::04.04.10. Stratigraphy ; 04. Solid Earth::04.08. Volcanology::04.08.08. Volcanic risk
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  • 131
    Publication Date: 2017-04-04
    Description: The rationale of lava flow deviation is to prevent major damage, and, among the possible techniques, the opening of the flow leve¤es has often been demonstrated to be suitable and reliable. The best way to open the leve¤es in the right point, in order to obtain the required effect, is to produce an explosion in situ, and it is then necessary to map with the highest precision the temperature field inside the leve¤es, in order to design a safe and successful intervention. The leve¤es are formed by lava flows due to their non-Newtonian rheology, where the shear stress is lower than the yield stress. The leve¤es then cool and solidify due to heat loss into the atmosphere. In this work we present analytical solutions of the steady-state heat conduction problem in a leve¤e using the method of conformal mapping for simple geometrical shapes of the levee cross-section (triangular or square). Numerical solutions are obtained with a finite element code for more complex, realistic geometries.
    Description: Published
    Description: 241-251
    Description: open
    Keywords: steady-state temperature ; lava flow ; 04. Solid Earth::04.08. Volcanology::04.08.08. Volcanic risk
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  • 132
    Publication Date: 2017-04-04
    Description: We report new data on water solubility in two melt compositions representative of volcanic units of the Campi Flegrei Caldera (Italy). The first composition is a primitive shoshonite and the second one is a more evolved latitic composition that have been chosen because of their less evolved nature compared to the other erupted products of Campi Flegrei. Water solubility was investigated at pressures from 25 to 200 MPa and 1200 °C following synthesis in an Internal Heated Pressure Vessel (IHPV). The glasses obtained from water-saturated experiments were analysed using both Fourier Transform Infra Red spectroscopy (FTIR) and Karl Fischer Titration (KFT). KFT was used as an independent method to obtain water concentration for the calibration of molar absorptivities of infrared bands at ∼3550 cm−1 (total water), ∼4500 cm−1 (hydroxyl groups) and ∼5200 cm−1 (molecular water). Water solubility in the shoshonitic melts is similar to that of a basalt while a slightly higher water solubility is observed for the latitic composition. As regards the speciation, we have investigated the water speciation for the shoshonitic composition only and we have made a comparison between the data resulting using different molar absorptivities obtained for basaltic compositions similar to our shoshonite.
    Description: Published
    Description: 113–124
    Description: reserved
    Keywords: Water solubility ; Shoshonitic melts ; Latitic melts ; FTIR ; Molar absorptivity ; Water speciation ; 04. Solid Earth::04.01. Earth Interior::04.01.04. Mineral physics and properties of rocks ; 04. Solid Earth::04.01. Earth Interior::04.01.05. Rheology ; 04. Solid Earth::04.04. Geology::04.04.05. Mineralogy and petrology
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  • 133
    Publication Date: 2017-04-04
    Description: The island of Pantelleria is an active volcano located in the Sicily Channel (Southern Italy), in the middle of a continental rift system. Since the 1980s the island was periodically surveyed by using geodetic techniques (EDM, levelling, GPS and high precise gravimetry) to monitor the regional and local volcanic dynamics. Gravity data, collected between 1990 and 1998, show short and long wavelength changes due to the combined effect of shallow and deep sources. They reflect, to some degree, the structural setting of the island as delineated by the Bouguer anomaly field, which indicates that the island is broken up into two main basement blocks. The latter are bordered by two lineaments, probably regional faults related to the global geodynamics of the Sicily Channel Rift Zone. Moreover, the inverse correlation between the gravity and altimetric variations suggests that: i) Pantelleria is kinematically divided in two blocks; ii) the observed behaviour is strongly influenced by the geodynamics of the Sicily Channel. A new interpretation of the fully reprocessed data sets is presented, focusing on the spatial–temporal features of the horizontal ground deformation and gravity changes compared to the Bouguer anomaly and altimetric data. This leads to conclude that volcanism on the island has been probably strongly influenced by the global geodynamics of the Sicily Channel, and future eruptions are most likely to occur at the structural boundary separating the two blocks.
    Description: Published
    Description: 146– 162
    Description: reserved
    Keywords: Pantelleria ; geodesy ; deformation ; gravity ; volcanism ; geodynamics ; 04. Solid Earth::04.03. Geodesy::04.03.01. Crustal deformations ; 04. Solid Earth::04.03. Geodesy::04.03.05. Gravity variations ; 04. Solid Earth::04.03. Geodesy::04.03.06. Measurements and monitoring
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  • 134
    Publication Date: 2017-04-04
    Description: This paper documents arsenic concentrations in 157 groundwater samples from the island of Ischia and the Phlegrean Fields, two of the most active volcano-hosted hydrothermal systems from the Campanian Volcanic Province (Southern Italy), in an attempt to identify the environmental conditions and mineral-solution reactions governing arsenic aqueous cycling. On Ischia and in the Phlegrean Fields, groundwaters range in composition from NaCl brines, which we interpret as the surface discharge of deep reservoir fluids, to shallow-depth circulating fluids, the latter ranging from acid-sulphate steam-heated to hypothermal, cold, bicarbonate groundwaters. Arsenic concentrations range from 1.6 to 6900 μg·l−1 and from 2.6 to 3800 μg·l−1 in the Phlegrean Fields and on Ischia, respectively. They increase with increasing water temperature and chlorine contents, and in the sequence bicarbonate groundwatersbsteam-heated groundwatersbNaCl brines. According to thermochemical modeling, we propose that high As concentrations in NaCl brines form after prolonged water–rock interactions at reservoir T, fO2 and fH2S conditions, and under the buffering action of an arsenopyrite+pyrite+pyrrhotite rock assemblage. On their ascent toward the surface, NaCl brines become diluted by As-depleted meteoric-derived bicarbonate groundwaters, giving rise to hybrid water types with intermediate to low As contents. Steam-heated groundwaters give their intermediate to high As concentrations to extensive rock leaching promoted by interaction with As-bearing hydrothermal steam.
    Description: Published
    Description: 313–330
    Description: reserved
    Keywords: Arsenic geochemistry ; Hydrothermal systems ; Water–rock interaction ; Hydrogeochemistry ; Arsenopyrite ; 03. Hydrosphere::03.04. Chemical and biological::03.04.06. Hydrothermal systems
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  • 135
    Publication Date: 2017-04-04
    Description: We have analysed the deformation documented during unrest at the Campi Flegrei caldera, Italy, between 1981 and 2001. Via inverse modelling, we constrain the location, geometry and size of the source responsible for the continuing period of surface deformation.We present a critical re-evaluation of results from previously published models and for the first time invert post-1994 data to infer source parameters. Our evaluation is based on constraints from additional horizontal displacement data, mechanical properties of the country rocks, effects of volcanic surface loading and on other geophysical and geochemical observations. We invert leveling and tide-gauge data for a spherical point (Mogi-model) source, a penny-shaped crack and finally a prolate spheroid. Despite the good qualities of fit of both the Mogi-model and the penny-shaped source to the vertical displacement data, our critical evaluation of the implied source properties forces us to reject these models. We propose instead a vertical prolate spheroid located about 800 m East of Pozzuoli at a depth of 2.9 km (95% confidence bound 2.0 to 4.2 km) with an aspect ratio of 0.51 (95% bounds 0.37–0.69) as a more appropriate source model. This model best accounts for the criteria employed and the observed deformation between 1981 and 2001. Combined with results from the inversion of gravity change data (1982–1984) for the spheroidal source, we infer a hybrid nature of the source including both magmatic and hydrothermal components.
    Description: Published
    Description: 132– 145
    Description: reserved
    Keywords: caldera unrest ; geodesy ; data inversion ; magma ; hydrothermal system ; Campi Flegrei ; 04. Solid Earth::04.03. Geodesy::04.03.01. Crustal deformations
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  • 136
    Publication Date: 2017-04-04
    Description: 0
    Description: Published
    Description: 249-263
    Description: reserved
    Keywords: NONE ; 04. Solid Earth::04.06. Seismology::04.06.05. Historical seismology
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    Type: book chapter
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  • 137
    Publication Date: 2017-04-04
    Description: A large database of major, trace and isotope (Sr, Nd, Pb, O) data exists for rocks produced by the volcanic activity of Somma-Vesuvius volcano. Variation diagrams strongly suggest a major role for evolutionary processes such as fractional crystallization, contamination, crystal trapping and magma mixing, occurring after magma genesis in the mantle. Most mafic magmas are enriched in LILE (K, Rb, Ba), REE (Ce, Sm) and Y, show small Nb–Ta negative anomalies, and have values of Nb/Zr at about 0.15. Enrichments in LILE, REE, Nb and Ta do not correlate with Sr isotope values or degree of both K enrichment and silica undersaturation. The results indicate mantle source heterogeneity produced by slab-derived components beneath the volcano. However, the Sr isotope values of Somma-Vesuvius increase from 0.7071 up to 0.7081 with transport through the uppermost 11–12 km of the crust. The Sr isotope variation suggests that the crustal component affected the magmas during ascent through the lithosphere to the surface. Our new geochemical assessment based on chemical, isotopic and fluid inclusion data points to the existence of three main levels of magma storage. Two of the levels are deep and may represent long-lived reservoirs, and an uppermost crustal level that probably coincides with the volcanic conduit. The deeper level of magma storage is deeper than 12 km and fed the 1944 AD eruption. The intermediate level coincides with the seismic discontinuity detected by Zollo et al. (1996) at about 8 km. This intermediate level supplies magmas with 87Sr/86Sr values between 0.7071 and 0.7074, and δO18 8‰ that typically erupted both during interplinian (i.e. 1906 AD) and sub-plinian (472 AD, 1631 AD) events. The shallowest level of magma storage at about 5 km was the site of magma chambers for the Pompei and Avellino eruptions. New investigations are necessary to verify the proposed magma feeding system.
    Description: Published
    Description: 183-204
    Description: open
    Keywords: NONE ; 04. Solid Earth::04.08. Volcanology::04.08.03. Magmas ; 04. Solid Earth::04.08. Volcanology::04.08.05. Volcanic rocks ; 05. General::05.02. Data dissemination::05.02.01. Geochemical data
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  • 138
    Publication Date: 2017-04-04
    Description: Tropospheric volcanic plume features have been derived from airborne multispectral images collected during field measurement campaigns at the Mt. Etna volcano in June 1997, during a quiescent period, and in July 2001 during an eruptive period. Results have been obtained in terms of mapping the volcanic aerosol optical thickness (AOT), the A ˚ ngstro¨ m parameters and the water vapor content using different bands from visible to infrared. The AOT values show average values of 0.1 and 1, for quiescent and eruptive plumes, respectively, demonstrating that this geophysical parameter well indicates a major contribution of particulates in the explosive plume with respect to the quiescent one. The mapping of A ˚ ngstro¨ m parameters, in the explosive case, indicates the presence of larger particles and their distribution along the plume, while in the quiescent case indicates the particle size is dominated by small particles with an effective radius about 1 mm. Further in the quiescent case, the map of water vapor shows low values indicating that water vapor emitted condenses mainly in aerosols.
    Description: Published
    Description: 981-994
    Description: 1.10. TTC - Telerilevamento
    Description: JCR Journal
    Description: reserved
    Keywords: Mt. Etna; Volcanic aerosol; Mivis; Radiative transfer model ; 05. General::05.02. Data dissemination::05.02.03. Volcanic eruptions
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  • 139
    Publication Date: 2017-04-04
    Description: We investigated chemical and isotopic compositions of clinopyroxene crystals from well age-constrained juvenile scoria clasts, lava flows, and hypoabyssal magmatic ejecta representative of the whole eruptive history of the Alban Hills Volcanic District. The Alban Hills is a Quaternary ultra-potassic district that was emplaced into thick limestone units along the Tyrrhenian margin of Italy. Alban Hills volcanic products, even the most differentiated, are characterised by low SiO2 content. We suggest that the low silica activity in evolving magmas can be ultimately due to a decarbonation process occurring at the magma/limestone interface. According to the liquid line of descent we propose, the differentiation process is driven by crystallisation of clinopyroxene+leuciteFapatiteFmagnetite coupled with assimilation of a small amount of calcite and/or with interaction with crustal CO2. By combining age, chemical data, strontium and oxygen isotopic compositions, and REE content of clinopyroxene, we give insights into the evolution of primitive ultrapotassic magmas of the Alban Hills Volcanic District over an elapsed period of about 600 kyr. Geochemical features of clinopyroxene crystals, consistent with data coming from other Italian ultrapotassic magmas, indicate that Alban Hills primary magmas were generated from a metasomatized lithospheric mantle source. In addition, our study shows that the 87Sr / 86Sr and LREE/HREE of Alban Hills magmas continuously diminished during the 600–35 ka time interval of the Alban Hills eruptive history, possibly reflecting the progressive depletion of the metasomatized mantle source of magmas.
    Description: Published
    Description: 330–346
    Description: JCR Journal
    Description: reserved
    Keywords: Clinopyroxene ; 87Sr / 86Sr ; REE ; Ultrapotassic rocks ; Alban Hills ; 04. Solid Earth::04.01. Earth Interior::04.01.99. General or miscellaneous ; 04. Solid Earth::04.08. Volcanology::04.08.03. Magmas
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  • 140
    Publication Date: 2017-04-04
    Description: On 9, January 2001 a seismic swarm, located on the south-eastern flank of Mt. Etna and with nearly identical waveforms, caused some damage to Zafferana Etnea village, 3 km from the epicentral area. An analysis of the seismicity occurring in the last 8 years in this area has revealed other earthquakes with the same characteristics; some pre-empted and followed (up to a few months) the 2001 January swarm, others were recorded more than five years beforehand. Using similarity of waveforms, these earthquakes were classified into three families. The use of a multiplet-technique has allowed to obtain the spatial distribution of the events with higher precision (mean error of 10-20 meters) with respect to traditional localization techniques. Mt. Etna earthquakes relocation clearly describes the geometry of the seismogenic tectonic structure; the hypocenters lie on a NE-SW oriented plane that is coincident with one of the focal planes obtained by first-arrival polarities. This alignment is also coherent with one of the main regional tectonic trends cutting the Mt. Etna area, and can be interpreted as a right-lateral strike seismic source on the south-eastern flank of Mt. Etna, distant from eruptive centres, which repeats from time to time and is able to produce strong energy releases.
    Description: Published
    Description: 281-289
    Description: 3.6. Fisica del vulcanismo
    Description: JCR Journal
    Description: reserved
    Keywords: Waveform correlation ; 05. General::05.02. Data dissemination::05.02.02. Seismological data
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  • 141
    Publication Date: 2017-04-04
    Description: Travertine deposits outcropping in the lower SW flank of Mt. Etna were studied for their mapping, as well as for their chemical, mineralogical and isotopic compositions. These deposits are dated to about 24 to 5 ka in the Adrano area, located at the western limit of the study area. In this area travertines show high Mg contents and are composed mostly of dolomite, thus apparently ruling out any primary deposition in favour of a diagenetic origin. Travertines outcropping near Paternò, in the east part of the study area, should be younger than 18 ka. Those located to the SSW of Paternò (Paternò–Diga) show high Sr contents and aragonite as dominant mineralogical phase, thus suggesting primary deposition. Those located to the Wof Paternò (Paternò Simeto–Stazione) are instead poor both in Mg and in Sr and show calcite as dominant phase. Carbon isotope composition of travertines indicates a magmatic origin of CO2 that formed them. Based on the estimated volume of travertines, between 10 and 20 Gg/a of CO2 were involved in their formation. The time-span of travertine formation coincided with the eruptive cycles of Ellittico and the first part of Mongibello, which were probably characterised by a greater amount of CO2 transported through groundwater circulation. Widespread travertine deposition probably ceased after the opening of the Valle del Bove depression that modified the volcanologic and hydrologic conditions in the summit crater area.
    Description: Istituto Nazionale di Geofisica e Vulcanologia
    Description: Published
    Description: 64–70
    Description: 4.5. Degassamento naturale
    Description: JCR Journal
    Description: open
    Keywords: Mt. Etna ; travertine deposits ; carbon isotope composition ; mineralogical composition ; chemical composition ; CO2 budget ; 03. Hydrosphere::03.04. Chemical and biological::03.04.02. Carbon cycling
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  • 142
    Publication Date: 2017-04-04
    Description: Here the authors present results of an isotope study on precipitation collected during a 2-a period from a rain-gauge network consisting of 6 stations located at different elevations in the Hyblean Mountains (HM) region, in south-eastern Sicily. The slope of the local meteoric water line (dD = 6.50 d18O + 9.87) obtained for the region suggests that precipitation is affected by evaporation during rainfall events. The main variations in rainwater isotope composition are due to seasonal effects and elevation. An average 2H excess value of +21.2&was found for precipitation events less affected by evaporation (i.e. when the rainfall was 〉65 mm/month). The spatial distribution of O isotope composition of precipitation shows a negative gradient from east and south to the inner areas. The depositional rate of Cl, used as a tracer of the origin of air masses, is highest at the coastal rain-gauges (SR and MRG stations) and lowest on the northern flank of the HM region (SC station). Based on these findings, a model is proposed for the origin of precipitation in the HM region, which assumes that a Mediterranean-derived component is the main source of moisture in the studied area. D/H and 18O/16O ratios of inferred meteoric recharge waters were also compared with the isotope composition of waters collected from the main local springs and wells. The best linear fit of the d18O vs dD relationship for Hyblean groundwater is dD = 4.85 d18O–2.01. The enrichment of heavy isotopes in Hyblean groundwater is probably due to evaporation occurring after precipitation events or to a recharging contribution from surface waters (lakes or rivers) enriched in heavy isotopes.
    Description: Published
    Description: 2082-2095
    Description: JCR Journal
    Description: reserved
    Keywords: Moisture source ; Hyblean Mountains ; 03. Hydrosphere::03.01. General::03.01.03. Global climate models ; 03. Hydrosphere::03.02. Hydrology::03.02.06. Water resources
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  • 143
    Publication Date: 2017-04-04
    Description: The phenomenon of earthquake clustering, i.e., the increase of occurrence probability for seismic events close in space and time to other previous earthquakes, has been modeled both by statistical and physical processes. From a statistical viewpoint the so-called epidemic model (ETAS) introduced by Ogata in 1988 and its variations have become fairly well known in the seismological community. Tests on real seismicity and comparison with a plain time-independent Poissonian model through likelihood-based methods have reliably proved their validity. On the other hand, in the last decade many papers have been published on the so-called Coulomb stress change principle, based on the theory of elasticity, showing qualitatively that an increase of the Coulomb stress in a given area is usually associated with an increase of seismic activity. More specifically, the rate-and-state theory developed by Dieterich in the ′90s has been able to give a physical justification to the phenomenon known as Omori law. According to this law, a mainshock is followed by a series of aftershocks whose frequency decreases in time as an inverse power law. In this study we give an outline of the above-mentioned stochastic and physical models, and build up an approach by which these models can be merged in a single algorithm and statistically tested. The application to the seismicity of Japan from 1970 to 2003 shows that the new model incorporating the physical concept of the rate-and-state theory performs not worse than the purely stochastic model with two free parameters only. The numerical results obtained in these applications are related to physical characters of the model as the stress change produced by an earthquake close to its edges and to the A and σ parameters of the rateand- state constitutive law.
    Description: Published
    Description: 141-153
    Description: JCR Journal
    Description: reserved
    Keywords: Earthquake interaction ; Rate-and-state ; Triggering ; Clustering ; Epidemic model ; Likelihood ; 04. Solid Earth::04.06. Seismology::04.06.02. Earthquake interactions and probability
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  • 144
    Publication Date: 2017-04-04
    Description: The INGV-Harvard European-Mediterranean Regional Centroid Moment Tensor (RCMT) Catalog collects solutions routinely computed since 1997 for earthquakes with moderate magnitude (4.5 ≤ M ≤ 5.5) in the Mediterranean region. The database represents an extension to smaller magnitudes of the Harvard global CMT catalog, based on analysis of seismograms recorded at regional distance, and modeling of intermediate period surface waves. The catalog includes about 600 events, 200 of which in the Italian region. This study extends the catalog back in time, for the Italian region, as long as made possible by available digital data – i.e. since 1977 – with the same analysis and inversion method used for current seismicity. As a result, we present here 65 new moment tensors, for years between 1977 and 1997. These solutions represent 45% of the total number of events analyzed, the existing seismograms being often too scarce to allow a stable solution. The new dataset includes events in many seismic zones where moderate seismicity had previously been scarcely documented, e.g., the Po Plain, the Central to Southern Apennines and the Adriatic Sea. The complete dataset, including previously determined RCMTs and CMTs, represents the seismic deformation in the Italian area during the last 25 years.
    Description: Published
    Description: 286-303
    Description: JCR Journal
    Description: reserved
    Keywords: Seismicity ; Moment tensors ; Seismic deformation ; Italian region ; 04. Solid Earth::04.06. Seismology::04.06.07. Tomography and anisotropy
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  • 145
    Publication Date: 2017-04-04
    Description: In the south-eastern corner of the Tyrrhenian basin, in the central Mediterranean Sea, a tight alignment of earthquakes along a well-defined Benioff zone marks one of the narrowest active trenches worldwide, where one of the last fragment of the former Tethys ocean is consumed. Seismic tomography furnishes snapshot images of the present-day position of this slab, and seismic anisotropy allows to reconstruct the past kinematics of the subduction process. Using seismic anisotropy fast directions as a proxy for the present and past mantle flow, we look backward for the seismic traces of the slab motion through the western-central Mediterranean mantle, from the starting locus of subduction toward its present day position. The result of combining independent data sets provides a coherent pattern of anisotropy that illustrates an example of slab rollback from its initiation point to its presentday position.
    Description: Published
    Description: 517-529
    Description: JCR Journal
    Description: reserved
    Keywords: Mediterranean ; Seismic ; 02. Cryosphere::02.02. Glaciers::02.02.03. Geomorphology
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
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  • 146
    Publication Date: 2017-04-04
    Description: A physical model based on the advective–diffusion theory was developed in order to describe the mixing between a deep gas source and the atmosphere. The model was used to predict the isotopic fractionation of carbon in soil CO2. Gas samples were collected at different depths in areas characterized by different geological settings and CO2 fluxes. The relative theoretical and experimental isotopic profiles were compared and a good agreement was found. These profiles show how the isotopic composition of CO2 changes through the upper few decimeters of soil and how the amount of the isotopic fractionation is strongly influenced by soil CO2 flux. Finally, the model was used to derive the carbon isotopic composition of unfractioned deep CO2 source for all the investigated sites
    Description: Published
    Description: 3016–3027
    Description: 1.2. TTC - Sorveglianza geochimica delle aree vulcaniche attive
    Description: 2.4. TTC - Laboratori di geochimica dei fluidi
    Description: 4.5. Degassamento naturale
    Description: JCR Journal
    Description: reserved
    Keywords: Carbon isotope fractionation ; soil degassing ; gas transport ; D13C(CO2) ; 04. Solid Earth::04.02. Exploration geophysics::04.02.01. Geochemical exploration ; 04. Solid Earth::04.04. Geology::04.04.12. Fluid Geochemistry ; 04. Solid Earth::04.08. Volcanology::04.08.01. Gases
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
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  • 147
    Publication Date: 2017-04-04
    Description: There is an urgent need to better constrain the global rates of mercury degassing from natural sources, including active volcanoes. Hitherto, estimates of volcanic fluxes have been limited by the poorly-determined speciation of Hg in volcanic emissions. Here, we present a systematic characterisation of mercury partitioning between gaseous (Hg(g)) and particulate (Hg(p)) forms in the volcanic plume of Mount Etna, the largest open-vent passively degassing volcano on Earth. We demonstrate that mercury transport is predominantly in the gas-phase, with a mean Hg(p)/Hg(g) ratio of ∼0.01 by mass. We also present the first simultaneous measurement of divalent gaseous mercury (HgII(g)) and total gaseous mercury (Hg(g)) in a volcanic plume, which suggests that Hg0(g) is the prevalent form of mercury in this context. These data are supported by the results of model simulations, carried out with HSC thermodynamic software. Based on a mean ‘bulk plume’ Hg/SO2 mass ratio of 8.7×10-6, and a contemporaneous volcanic SO2 flux of 0.8 Mt·yr-1, we estimate an Hg emission rate from Mt. Etna during passive degassing of 5.4 t·y-1 (range, 1.1-10 t·y-1). This corresponds to ~0.6% of global volcanic Hg emissions, and about 5% of Hg released from industrial activities in the Mediterranean area.
    Description: Published
    Description: 7377-7388
    Description: 1.2. TTC - Sorveglianza geochimica delle aree vulcaniche attive
    Description: 4.5. Degassamento naturale
    Description: JCR Journal
    Description: reserved
    Keywords: Atmospheric mercury ; Volcanic degassing ; Gaseous and particulate mercury ; Atmospheric budgets ; 01. Atmosphere::01.01. Atmosphere::01.01.01. Composition and Structure ; 01. Atmosphere::01.01. Atmosphere::01.01.04. Processes and Dynamics ; 01. Atmosphere::01.01. Atmosphere::01.01.07. Volcanic effects
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
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  • 148
    Publication Date: 2017-04-04
    Description: The seismic activity of Mt. Etna from April 1988 until the December 1991 eruption was monitored by means of permanent and temporary seismic network. Volcanic activity that occurred during this period was preceded and accompanied by the occurrence of deep (Z 〉/- 15 km) seismicity. This deep seismic activity, occurring a few days up to some weeks before the volcanic phases, was characterized by typical mainshock-aftershocks sequences. Both the observation of deep seismicity occurrence also before or during previous eruptions and the role played by tectonics as controller of the magma uprise suggest the hypothesis of a relation between the seismic energy released in the volcanic basement and the recharge mechanisms of the volcanic system.
    Description: Published
    Description: 277-289
    Description: 1.4. TTC - Sorveglianza sismologica delle aree vulcaniche attive
    Description: JCR Journal
    Description: reserved
    Keywords: deep earthquakes ; volcano ; Etna ; 04. Solid Earth::04.06. Seismology::04.06.08. Volcano seismology
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  • 149
    Publication Date: 2017-04-04
    Description: In the text
    Description: Published
    Description: 193-202
    Description: 3.3. Geodinamica e struttura dell'interno della Terra
    Description: JCR Journal
    Description: reserved
    Keywords: CROP ; wide-angle ; reflection ; 04. Solid Earth::04.07. Tectonophysics::04.07.07. Tectonics
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
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  • 150
    Publication Date: 2017-04-04
    Description: The analysis of gaseous compositions from Solfatara (Campi Flegrei, South Italy) fumaroles since the early 1980s, clearly reveals a double thermobarometric signature. A first signature at temperatures of about 360 C was inferred by methanebased chemical–isotopic geoindicators and by the H2/Ar geothermometer. These high temperatures, close to the critical point of water, are representative of a deep zone where magmatic gases flash the hydrothermal liquid, forming a gas plume. A second signature was found to be at around 200–240 C. At these temperatures, the kinetically fast reactive species (H2 and CO) re-equilibrate in a pure vapor phase during the rise of the plume. A combination of these observations with an original interpretation of the oxygen isotopic composition of the two dominant species, i.e. H2O and CO2, shed light on the origin of fumarolic fluids by showing that effluents are mixture between fluids degassed from a magma body and the vapor generated at about 360 C by the vaporization of hydrothermal liquids. A typical ‘andesitic’ water type (dD 20&, d18O 10&) and a CO2-rich composition ðXCO2 0:4Þ has been inferred for the magmatic fluids, while for the hydrothermal component a meteoric origin and a CO2 fugacity fixed by fluid-rock reaction at high temperatures have been estimated. In the time the fraction of magmatic fluids in the fumaroles increased (up to 0.5) at each seismic and ground uplift crisis (bradyseism) which occurred at Campi Flegrei, suggesting that bradyseismic crises are triggered by periodic injections of CO2-rich magmatic fluids at the bottom of the hydrothermal system
    Description: Published
    Description: 3040-3055
    Description: 1.2. TTC - Sorveglianza geochimica delle aree vulcaniche attive
    Description: 2.4. TTC - Laboratori di geochimica dei fluidi
    Description: 4.5. Degassamento naturale
    Description: JCR Journal
    Description: reserved
    Keywords: origin of the fumaroles ; 04. Solid Earth::04.04. Geology::04.04.12. Fluid Geochemistry ; 04. Solid Earth::04.08. Volcanology::04.08.06. Volcano monitoring
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
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  • 151
    Publication Date: 2017-04-04
    Description: The Alban Hills volcanic region (20 km south of Rome, in the Roman Province) emitted a large volume of potassic magmas (N280 km3) during the Quaternary. Chemical interactions between ascending magmas and the ∼7000–8000-m-thick sedimentary carbonate basement are documented by abundant high temperature skarn xenoliths in the eruptive products and have been frequently corroborated by geochemical surveys. In this paper we characterize the effect of carbonate assimilation on phase relationships at 200 MPa and 1150–1050 °C by experimental petrology. Calcite and dolomite addition promotes the crystallization of Ca-rich pyroxene and Mg-rich olivine respectively, and addition of both carbonates results in the desilication of the melt. Furthermore, carbonate assimilation liberates a large quantity of CO2-rich fluid. A comparison of experimental versus natural mineral, glass and bulk rock compositions suggests large variations in the degree of carbonate assimilation for the different Alban Hills eruptions. A maximum of 15 wt.% assimilation is suggested by some melt inclusion and clinopyroxene compositions; however, most of the natural data indicate assimilation of between 3 and 12 wt.% carbonate. Current high CO2 emissions in this area most likely indicate that such an assimilation process still occurs at depth. We calculate that a magma intruding into the carbonate basement with a rate of ∼1–2·106 m3/year, estimated by geophysical studies, and assimilating 3–12 wt.% of host rocks would release an amount of CO2 matching the current yearly emissions at the Alban Hills. Our results strongly suggest that current CO2 emissions in this region are the shallow manifestation of hot mafic magma intrusion in the carbonate-hosted reservoir at 5–6 km depth, with important consequences for the present-day volcanic hazard evaluation in this densely populated and historical area.
    Description: Published
    Description: 91-105
    Description: 3.5. Geologia e storia dei sistemi vulcanici
    Description: JCR Journal
    Description: reserved
    Keywords: limestone assimilation ; magma ; CO2 degassing ; experimental petrology ; Roman Province ; 04. Solid Earth::04.04. Geology::04.04.05. Mineralogy and petrology
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
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  • 152
    Publication Date: 2017-04-04
    Description: The Alban Hills ultrapotassic volcanic district is one of the main districts emplaced during Quaternary time along the Tyrrhenian margin of Italy. Alban Hills lava flows and scoria clasts are made up essentially of clinopyroxenes and leucites and their chemical composition is mostly K-foiditic. Differentiated products (MgO〈3 wt%) are characterized by low SiO2 concentration (〈50 wt%) and geochemical features indicate that this unique differentiation trend is driven by crystal fractionation plus carbonate crust interaction. Notably, the Alban Hills Volcanic District was emplaced into thick limestone units. With the aim of constraining the magmatic differentiation, we performed experiments on the Alban Hills parental composition (plagioclase-free phono-tephrite) under anhydrous, hydrous, and hydrous-carbonated conditions. Experiments were carried out at 1 atm, 0.5 GPa and 1 GPa, temperatures ranging from 1050 to 1300 °C, and H2O and CaCO3 in the starting material up to 2 and 7 wt%, respectively. The experiments performed at 0.5 GPa resulted to be the most representative of the Alban Hills plumbing system. Clinopyroxene and leucite are the main phases occurring under all the investigated conditions and the liquidus phases. Nevertheless, our experimental results demonstrate that the occurrence of CaCO3 in the starting material strongly affects phase relations. Experiments performed under hydrous conditions crystallize magnetite and phlogopite at relatively high temperature. This early crystallization drives the glass composition towards a silica enrichment, resulting in a differentiation trend moving from phono-tephritic (Alban Hills parental composition) to phonolitic compositions. This is in contrast with micro-textural evidences showing late crystallization of magnetite and phlogopite in the natural products and with the composition of the juvenile products. On the contrary, in the CaCO3-bearing experiments (i.e., simulating magma-carbonate interaction) the magnetite and phlogopite stability fields are strongly reduced. As a consequence, the melt differentiation is mainly controlled by the cotectic crystallization of clinopyroxene and leucite, resulting in a differentiation trend moving towards K-foiditic compositions. These experimental results are in agreement with micro-textural features and chemical compositions of Alban Hills natural products and with the magmatic differentiation model inferred by geochemical data. Magma-carbonate interaction is not a rare process and its occurrence has been demonstrated for different plumbing systems. However, the uniqueness of the Alban Hills liquid line of descent suggests that the efficacy of the carbonate contamination process is controlled by different factors, the dynamics of the plumbing system being one of the most important.
    Description: INGV-DPC Project V3_1 Colli Albani Project FIRB MIUR “Development of innovative technologies for the environmental protection from natural events”.
    Description: Published
    Description: On line First
    Description: 2.3. TTC - Laboratori di chimica e fisica delle rocce
    Description: JCR Journal
    Description: reserved
    Keywords: Alban Hills ; ultrapotassic rocks ; experimental petrology ; magma-carbonate interaction ; 04. Solid Earth::04.08. Volcanology::04.08.03. Magmas
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  • 153
    Publication Date: 2017-04-04
    Description: Italy is covered by a first-order triangulation network that was established between 1869 and 1908 and re-measured in patches between 1936 and 1963. We analyse the measurements made in the central part of Italy to form an estimate of the rate of strain in the Central Apennines. We conclude that the rate of strain in this region is too small to detect from the repeated triangulation measurement. This result places an upper bound of about 10(exp-7)/yr on the strain rate of the Central Apennines, and implies that the maximum rate of extension across the region is no higher than about 3 mm/yr.
    Description: Published
    Description: 261-267
    Description: reserved
    Keywords: Apennines; strain; extension tectonics; triangulation ; 04. Solid Earth::04.03. Geodesy::04.03.01. Crustal deformations
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  • 154
    Publication Date: 2017-04-04
    Description: A rain gauge network consisting of five sites located at different altitudes, ranging from 320 to 1285 m.a.s.l., was installed at Mt. Vulture volcano (southern Italy). Rain water samples were collected monthly over a two-year period and their isotopic composition (d18O and dD) was analyzed. During the same period, circulating groundwater was sampled from 24 springs and wells distributed throughout the study area. Monthly isotopic composition values were used to determine the local meteoric water line (LMWL). Its slope is slightly lower than the relationship defined by Longinelli and Selmo (Longinelli, A., Selmo, E., 2003. Isotopic composition of precipitation in Italy: a first overall map. J. Hydrol. 270, 75–88) for southern Italy. The groundwater samples analyzed were distributed essentially along the LMWL. The weighted local meteoric water line (WLMWL), defined through the mean values weighted by the rainfall amount, however, may define in a short range the meteoric end-member in the local hydrological cycle more precisely. Since most of the groundwater sampling locations do not show seasonal variations in their stable isotope values, the flow system appears to be relatively homogeneous. The mean altitude of the recharge by rainfall infiltration was estimated on the basis of the local vertical isotopic gradient d18O. A few springs, which show anomalous isotopic values, reveal more regional circulation systems, associated with tectonic structures responsible for the ascent of deeper water.
    Description: Published
    Description: 87-97
    Description: 1.2. TTC - Sorveglianza geochimica delle aree vulcaniche attive
    Description: JCR Journal
    Description: reserved
    Keywords: stable isotope ; meteoric recharge ; 01. Atmosphere::01.01. Atmosphere::01.01.99. General or miscellaneous
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
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  • 155
    Publication Date: 2017-04-04
    Description: We study the dynamic traction and the slip velocity evolution within the cohesive zone during the propagation of a dynamic rupture using rate- and state-dependent constitutive laws. We solve the elastodynamic equation for a 2-D in-plane crack using a finite difference algorithm. We show that rate and state constitutive laws allow a quantitative description of the dynamic rupture growth. We confirm the findings of previous studies that slip weakening (SW) is a characteristic behavior of rate and state friction. Our simulations show that the state variable evolution controls the slip acceleration and the slip-weakening behavior. These modeling results help in understanding the physical interpretation of the breakdown process and the weakening mechanisms. We compare the time histories of slip velocity, state variable and total dynamic traction to investigate the temporal evolution of slip acceleration and stress drop during the breakdown time. Because the adopted analytical expression for the state variable evolution controls the slip velocity time histories, we test different evolution laws to investigate slip duration and the healing mechanisms. We show that the classic slowness or slip laws do not yield fast restrengthening or self-healing, although they appropriately describe rupture initiation, propagation and the long-term restrengthening during the interseismic period. Self-healing rupture mode, yielding to short slip durations, has been obtained for homogeneous faults by modifying the evolution law introducing a fast restrengthening of dynamic traction immediately after the weakening phase. In this study, we discuss how the direct effect of friction and the friction behavior at high slip rates affect the weakening and healing mechanisms.
    Description: Published
    Description: 241-262
    Description: 3.1. Fisica dei terremoti
    Description: JCR Journal
    Description: reserved
    Keywords: fault friction ; earthquake rupture ; rate- ad state dependent constitutive laws ; cohesive zone ; slip weakening ; fracture energy ; 04. Solid Earth::04.06. Seismology::04.06.03. Earthquake source and dynamics
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
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  • 156
    Publication Date: 2017-04-04
    Description: Preceded by four days of intense seismicity and marked ground deformation, a new eruption of Mt. Etna started on 17 July and lasted until 9 August 2001. It produced lava emission and strombolian and phreatomagmatic activity from four different main vents located on a complex fracture system extendingfrom the southeast summit cone for about 4.5 km southwards, from 3000 to 2100 m elevation (a.s.l.). The lava emitted from the lowest vent cut up an important road on the volcano and destroyed other rural roads and a few isolated country houses. Its front descended southwards to about 4 km distance from the villages of Nicolosi and Belpasso. A plan of intervention, including diversion and retainingbarriers and possibly lava flow interruption, was prepared but not activated because the flow front stopped as a consequence of a decrease in the effusion rate. Extensive interventions were carried out in order to protect some important tourist facilities of the Sapienza and Mts. Silvestri zones (1900 m elevation) from being destroyed by the lava emitted from vents located at 2700 m and 2550 m elevation. Thirteen earthen barriers (with a maximum length of 370 m, height of 10^12 m, base width of 15 m and volume of 25 000 m3) were built to divert the lava flow away from the facilities towards a path implyingconsiderably less damage. Most of the barriers were oriented diagonally (110^135‡) to the direction of the flow. They were made of loose material excavated nearby and worked very nicely, resistingthe thrust of the lava without any difficulty. After the interventions carried out on Mt. Etna in 1983 and in 1991^1992, those of 2001 confirm that earthen barriers can be very effective in controlling lava flows.
    Description: Elsevier
    Description: Published
    Description: 231-243
    Description: 1.5. TTC - Sorveglianza dell'attività eruttiva dei vulcani
    Description: JCR Journal
    Description: reserved
    Keywords: lava flow control; earthen barriers; Mt; Etna 2001 eruption ; 04. Solid Earth::04.08. Volcanology::04.08.08. Volcanic risk
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  • 157
    Publication Date: 2017-04-04
    Description: This paper presents a global ocean implementation of a multi-component model of marine pelagic biogeochemistry coupled on-line with an ocean general circulation model forced with climatological surface fields (PELAgic biogeochemistry for Global Ocean Simulations, PELAGOS). The final objective is the inclusion of this model as a component in an Earth System model for climate studies. The pelagic model is based on a functional stoichiometric representation of marine biogeochemical cycles and allows simulating the dynamics of C, N, P, Si, O and Fe taking into account the variation of their elemental ratios in the functional groups. The model also includes a parameterization of variable chlorophyll/carbon ratio in phytoplankton, carrying chl as a prognostic variable. The first part of the paper analyzes the contribution of non-local advective–diffusive terms and local vertical processes to the simulated chl distributions. The comparison of the three experiments shows that the mean chl distribution at higher latitudes is largely determined by mixing processes, while vertical advection controls the distribution in the equatorial upwelling regions. Horizontal advective and diffusive processes are necessary mechanisms for the shape of chl distribution in the sub-tropical Pacific. In the second part, the results have been compared with existing datasets of satellite-derived chlorophyll, surface nutrients, estimates of phytoplankton community composition and primary production data. The agreement is reasonable both in terms of the spatial distribution of annual means and of the seasonal variability in different dynamical oceanographic regions. Results indicate that some of the model biases in chl and surface nutrients distributions can be related to deficiencies in the simulation of physical processes such as advection and mixing. Other discrepancies are attributed to inadequate parameterizations of phytoplankton functional groups. The model has skill in reproducing the overall distribution of large and small phytoplankton but tends to underestimate diatoms in the northern higher latitudes and overestimate nanophytoplankton with respect to picoautotrophs in oligotrophic regions. The performance of the model is discussed in the context of its use in climate studies and an approach for improving the parameterization of functional groups in deterministic models is outlined.
    Description: We thank the Goddard Space Flight Center DAAC for SeaWiFS and CZCS satellite data and Yves Dandonneau for the GeP&CO pigment data and methodological explanations. We also acknowledge the availability of data from the US and International JGOFS websites and from the World Ocean Database. We acknowledge the support by the EU projects ENSEMBLES [project no. GOCE-CT-2003-505539] and DYNAMITE [project no. 00393(GOCE)]. We thank Job Baretta and an anonymous reviewer for their critical comments, which helped us to improve the manuscript.
    Description: Published
    Description: 110-134
    Description: 3.7. Dinamica del clima e dell'oceano
    Description: JCR Journal
    Description: reserved
    Keywords: Global biogeochemical cycles ; Ocean general circulation model ; Ecosystem model ; OPA ; ERSEM ; PELAGOS ; 03. Hydrosphere::03.01. General::03.01.01. Analytical and numerical modeling ; 03. Hydrosphere::03.01. General::03.01.07. Physical and biogeochemical interactions ; 03. Hydrosphere::03.04. Chemical and biological::03.04.01. Biogeochemical cycles ; 03. Hydrosphere::03.04. Chemical and biological::03.04.02. Carbon cycling ; 03. Hydrosphere::03.04. Chemical and biological::03.04.04. Ecosystems
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  • 158
    Publication Date: 2017-04-04
    Description: Two strong flank eruptions occurred in July–August 2001 and from late October 2002 to late January 2003 at Mt. Etna volcano. The two eruptions mainly involved the upper southern flank of the volcano, a particularly active area during the last 30 years, damaging several tourist facilities and threatening some villages. The composite eruptive activity on the upper southern flank of Mt. Etna during 2001–2003 has confirmed “a posteriori” the results of a multidisciplinary study, started well before its occurrence by combining geological, seismic and geochemical data gathered in this part of the volcano. We were able, in fact, to highlight fractured zones likely to be re-activated in the near future in this area, where the largest majority of eruptive fissures in the recent past opened along N120° to N180° ranging directions. The spatial distribution of earthquake epicentres during the period June 30th 2000–June 30th 2001 showed the greatest frequency in a sector compatible with both the direction of the main fissures of the pre-2001 period and that of the 2001 and 2002 lateral eruptions. Soil CO2 and soil temperature surveys carried out in the studied area during the last 3 years have revealed anomalous release of magmatic fluids (mainly CO2 and water vapour) along some NNW–SSE-trending volcano-tectonic structures of the area even during inter-eruptive periods, indicating persistent convective hydrothermal systems at shallow depth connected with the main feeder conduits of Etna. The temporal changes in both seismic and geochemical data from June 30th, 2000 to June 30th, 2001 were compared with the evolution of volcanic activity. The comparison allowed to recognize at least two sequences of anomalous signals (August to December 2000 and April to June 2001), likely related to episodes of step-like magma ascent towards the surface, as indicated by the following eruptive episodes. The N120° to N180° structural directions are in accord with one of the main structural lines affecting eastern Sicily; they would be important pathways for magma uprise to the surface that will keep on feeding the eruptive activity of Etna in the near future. This study also pointed out the high instability of the southern slope of Etna, a sector where the potential hazard by lava flow invasion will remain high also in the near future.
    Description: Published
    Description: 20
    Description: partially_open
    Keywords: Mt. Etna ; fault detection ; soil gas ; historical eruptive fissures ; eruptive activity ; local seismicity ; 04. Solid Earth::04.08. Volcanology::04.08.03. Magmas
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  • 159
    Publication Date: 2017-04-04
    Description: One of the seven potentially active andesite stratovolcanoes in southern Peru, Misti (5822 m), located 17 km northeast and 3.5 km above Arequipa, represents a major threat to the population (f900,000 inhabitants). Our recent geophysical and geochemical research comprises an extensive self-potential (SP) data set, an audioâ magnetotelluric (AMT) profile across the volcano and CO2 concentrations in the soil along a radial profile. The SP survey is the first of its kind in providing a complete mapping of a large andesitic stratovolcano 20 km in diameter. The SP mapping enables us to analyze the SP signature associated with a subduction-related active volcano. The general SP pattern of Misti is similar to that of most volcanoes with a hydrogeologic zone in the lower flanks and a hydrothermal zone in the upper central area. A quasi-systematic relationship exists between SP and elevation. Zones with constant SP/altitude gradients (Ce) are observed in both hydrogeologic (negative Ce) and hydrothermal (positive Ce) zones. Transition zones between the different Ce zones, which form a concentric pattern around the summit, have been interpreted in terms of lateral heterogeneities in the lithology. The highest amplitudes of SP anomalies seem to coincide with highly resistive zones. The hydrothermal system 6 km in diameter, which extends over an area much larger than the summit caldera, may be constrained by an older, concealed collapse caldera. A sealed zone has apparently developed through alteration in the hydrothermal system, blocking the migration of CO2 upward. Significant CO2 emanations are thus observed on the lower flanks but are absent above the hydrothermal zone.
    Description: - Institut de Recherche pour le Developpement (IRD) - Instituto Geofısico del Peru´ (IGP)
    Description: Published
    Description: 343-360
    Description: partially_open
    Keywords: Misti volcano ; self-potential ; audioâ magnetotelluric ; electrical resistivity ; structural discontinuity ; hydrothermal system ; Peru ; 04. Solid Earth::04.08. Volcanology::04.08.01. Gases ; 04. Solid Earth::04.08. Volcanology::04.08.06. Volcano monitoring ; 04. Solid Earth::04.08. Volcanology::04.08.07. Instruments and techniques
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  • 160
    Publication Date: 2017-04-04
    Description: A new apparatus, Venturi Effect System (VES), designed for sampling volcanic plumes is described and tested at Vulcano (Italy). This device, together with purified basic NH4OH solutions, supplies optimal conditions to obtain reliable Stotal/Cl/F ratios and enrichment factors for metallic trace elements (MTE). Good concordance for acid gas ratios and metal enrichment factors in both the gas phase and the related plume allows the procedure to be validated. The VES appears in Vulcano conditions as a simple, robust and easily portable apparatus that allows reliable collection of both acid gases and MTE within a single sample and the analysis with current chemical methods (High Pressure Liquid Chromatography, Inductively Coupled Plasma-Mass Spectrometry. This apparatus may be suitable for more difficult volcanoes where only the plume can be sampled.
    Description: Published
    Description: 95-103
    Description: partially_open
    Keywords: volcanic plume ; acid gases ; metallic trace elements ; sampling ; monitoring ; 03. Hydrosphere::03.02. Hydrology::03.02.02. Hydrological processes: interaction, transport, dynamics ; 03. Hydrosphere::03.02. Hydrology::03.02.03. Groundwater processes
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    Type: article , article
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  • 161
    Publication Date: 2017-04-04
    Description: Data from two dense arrays of short-period seismometers are used to retrieve source locations of the explosion quakes at Stromboli volcano. Slowness vectors stimated at both arrays with the zero-lag cross-correlation technique constitute the experimental data set. A probabilistic approach based on a grid search spanning the volcano interior is used to calculate the probability of the source location. Results depict a shallow source, located beneath the crater area, at depths not greater than 500 m below the surface. Results are slightly different from, but comparable to, those obtained in a companion experiment carried out in the same time period using a broad-band seismometer network, which show a source shifted some hundreds of meters northwest of the crater area. The method is revealed to be effective and useful for future studies having the purpose of real-time tracking of the explosion quakes and tremor.
    Description: Published
    Description: 123-142
    Description: partially_open
    Keywords: Stromboli ; Array ; Explosion quake ; Source location ; 04. Solid Earth::04.02. Exploration geophysics::04.02.06. Seismic methods ; 04. Solid Earth::04.06. Seismology::04.06.06. Surveys, measurements, and monitoring ; 04. Solid Earth::04.06. Seismology::04.06.08. Volcano seismology ; 04. Solid Earth::04.06. Seismology::04.06.09. Waves and wave analysis ; 04. Solid Earth::04.06. Seismology::04.06.10. Instruments and techniques ; 04. Solid Earth::04.08. Volcanology::04.08.06. Volcano monitoring
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  • 162
    Publication Date: 2017-04-04
    Description: We report a detailed study of trace metals in groundwaters from the Somma-Vesuvius volcanic complex and present a model of the chemical processes that control the fate of these components during gas–water–rock interactions. Trace metal concentrations in Vesuvian groundwaters range from 0.01 to 0.1 Ag/l for ultra-trace elements (Sb, Cs, Co, Cd, and Pb) up to 0.1–10 mg/l for minor elements (Fe and Sr), leading to water–rock ratios from ~0.5 to 10 9 when normalized to trace element concentrations in the host rocks. Our results indicate non-isochemical dissolution of local volcanic rocks by groundwaters,during which mobile trace elements (As, Se, Mo, V, Li) are enriched and elements such as Al, Pb, Co, and Mn are depleted in the aqueous phase compared to the pristine composition of unleached rocks. Speciation computation and mineral–solution equilibria provide insights into the processes controlling the abundance and mobility of both major and trace elements in the fluids and allow quantitative modeling of gas–water–rock interactions. This latter was done using a forward reaction path model based on the principle of irreversible reactions involving minerals and aqueous solutions (Helgeson, H.C., 1968. Evaluation of irreversible reactions in geochemical processes involving minerals and aqueous solutions: I. Thermodynamic relations. Geochim. Cosmochim. Acta, 32, 853–877), and incorporating transition-state theory to account for rates of mineral dissolution reactions (Aagaard, P., Helgeson, H.C., 1982. Thermodynamic and kinetic constraints on reaction rates among minerals and aqueous solutions, 1. Theoretical considerations. Amer. J. Sci., 282, 237–285). The EQ3NR/6 software package (Wolery, T.J.,1994. EQ3NR, Letter report: EQ3/6 version 8.0. Differences from version 7. UCRL_ID_129749, Lawrence Livermore National Laboratory, Livermore, California) was used to simulate the reaction paths and the aqueous concentrations of trace elements with increasing extent of rock weathering. Fairly good matching between the modeled and analytical groundwater compositions supports the validity of our approach and provides reliable information on the main sources and sinks of trace metals during gas–water–rock interactions in the volcanic aquifer of Vesuvius.
    Description: Published
    Description: 289– 311
    Description: partially_open
    Keywords: trace elements ; Vesuvius ; EQ3/6 ; kinetics ; weathering ; 04. Solid Earth::04.08. Volcanology::04.08.04. Thermodynamics ; 04. Solid Earth::04.08. Volcanology::04.08.06. Volcano monitoring ; 05. General::05.02. Data dissemination::05.02.01. Geochemical data
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  • 163
    Publication Date: 2017-04-04
    Description: A simple semianalytical model to simulate ash dispersion and deposition produced by sustained Plinian and sub-Plinian eruption columns based on the 2D advection-dispersion equation was applied. The eruption column acts as a vertical line source with a given mass distribution and neglects the complex dynamics within the eruption column. Thus, the use of the model is limited to areas far from the vent where the dynamics of the eruption column play a minor role. Vertical wind and diffusion components are considered negligible with respect to the horizontal ones. The dispersion and deposition of particles in the model is only governed by gravitational settling, horizontal eddy diffusion, and wind advection.The model accounts for different types and size classes of a user-defined number of particle classes and changing settling velocity with altitude. In as much as wind profiles are considered constant on the entire domain, the model validity is limited to medium-range distances (about 30–200 km away from the source). The model was used to reconstruct the tephra fall deposit from the documented Plinian eruption of Mt. Vesuvius, Italy, in 79 A.D. In this case, the model was able to broadly reproduce the characteristic medium-range tephra deposit. The results support the validity of the model, which has the advantage of being simple and fast to compute. It has the potential to serve as a simple tool for predicting the distribution of ash fall of hypothetical or real eruptions of a given magnitude and a given wind profile. Using a statistical set of frequent wind profiles, it also was used to construct air fall hazard maps of the most likely affected areas around active volcanoes where a large eruption is expected to occur.
    Description: Published
    Description: 273-294
    Description: partially_open
    Keywords: Ash fall ; Settling velocity ; Computer model ; Vesuvius 79 A.D. ; 05. General::05.01. Computational geophysics::05.01.05. Algorithms and implementation
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  • 164
    Publication Date: 2017-04-04
    Description: The evolution of scaling characteristics of the local geomagnetic field and of the seismicity at Etna volcano is studied in relation to the strong eruptive activity occurred here from 2000 to 2002. Scaling laws are found in the hourly time variability of magnetic data and in the seismicity pattern. The scaling exponents suggest the presence of persistent temporal fluctuations. Clear links between the dynamics of the measured data and the eruptive volcanic episodes are revealed. Fractal dimensions of seismicity seem to be always correlated to the beginning of main eruptive events, while strong alterations of the dynamics of the local magnetic field take place only when the eruptive fractures opened very close to the magnetic sites.
    Description: Published
    Description: 96-106
    Description: partially_open
    Keywords: scaling characteristics ; volcanic eruptions ; geomagnetic field ; seismic activity ; Mt. Etna ; 04. Solid Earth::04.05. Geomagnetism::04.05.02. Geomagnetic field variations and reversals ; 05. General::05.02. Data dissemination::05.02.03. Volcanic eruptions
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  • 165
    Publication Date: 2017-04-04
    Description: HAZMAP is a FORTRAN code for the solution of the equations of diffusion, transport and sedimentation of small particles, in order to model the dispersion of ash generated by a convective column. The model was developed simplifying the advection–diffusion sedimentation equation for volcanic ash transport in the atmosphere from three to two dimensions and using a semi-analytical computational method to greatly reduce the required computer time and memory. HAZMAP can be used either to simulate the mass distribution of the deposit if a wind profile is given (‘deposit mode’), or to define the probability of a given accumulation of mass on the ground if a statistical set of wind profiles is provided (‘‘probability mode’’). The model needs the definition of the physical system (spatial distribution of the point sources, total erupted mass, settling velocity distribution, wind velocity profile, atmospheric turbulent diffusion coefficients), and of a computational grid. The output values of mass accumulation on the ground or the probability of mass accumulation are computed on a regular grid, suitable for further analysis.
    Description: Published
    Description: 837-845
    Description: partially_open
    Keywords: Ashfall ; Fortran code ; Volcanology ; Volcanic hazard ; Semi-analytical model ; 05. General::05.01. Computational geophysics::05.01.05. Algorithms and implementation
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  • 166
    Publication Date: 2017-04-04
    Description: Here, a new technique for the determination of dissolved He isotope ratios in ground-waters is presented. This method is based on the extraction and subsequent equilibrium of dissolved gases in an added ‘‘host’’ gas phase. Ultra pure N2 is placed in glass flasks (250 cc), containing water samples, that were hermetically sealed after their collection. After shaking in an ultrasonic bath for 10 min, an aliquot of the separated gas phase was removed from the flask for MS analysis. 3He/4He ratios are measured by using a modified double collector mass spectrometer (VG 5400-TFT). Helium and Ne concentrations are calculated by comparing the partial pressures of masses 4 and 20 of the samples with those of the air-standard measured by a quadrupole mass spectrometer (QMS;VG Quartz). Using He and Ne equilibrium partitioning coefficients, it is possible to calculate the amount of gas originally dissolved in the water. The technique was tested on both air-saturated waters (ASW) and thermal waters from Stromboli (Aeolian Islands, South Italy), the results of which confirmed good reproducibility (ffi5%) and accuracy (ffi3%) of the data. The method was then applied to three thermal water samples collected from the same volcanic area and the results compared with those of a fumarolic and a soil gas. The isotope ratios for dissolved He gave values of 4.06–4.23 Ra, which are significantly higher than those previously reported in the literature (3.0, 3.5 and 2.9 Ra) and that measured at the fumarole (3.09 Ra), suggesting a newer and higher isotopic signature for the volcanic system. The proposed method appears to be a useful tool in the determination of 3He/4He ratios in ground-water systems, especially when free gases are not available or are dangerous to collect.
    Description: Published
    Description: 665–673
    Description: partially_open
    Keywords: dissolved helium isotopes ; gas water interaction ; 03. Hydrosphere::03.02. Hydrology::03.02.03. Groundwater processes ; 03. Hydrosphere::03.04. Chemical and biological::03.04.06. Hydrothermal systems ; 04. Solid Earth::04.08. Volcanology::04.08.01. Gases
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  • 167
    Publication Date: 2017-04-04
    Description: Large-scale flank instability on Mount Etna is associated with a distinct set of faults radiating generally from the summit area and restricted to the volcanic edifice itself. New observations and mapping of very recent and continuing deformation along these faults and related structures have been analysed in combination with published information, including recent seismic and eruption data, enabling the faults to be placed in three groups. Two of these, the Pernicana fault system (PFS) and the Ragalna fault system (RFS) bound, respectively, the northern and south-western margins of instability. Their activity responds to cycles of magma pressure associated with flank eruptions, together with subsequent deflation as gravity dominates. These cycles may operate at different depths, with the RFS bordering deep-seated instability. Their positions appear governed by the contact, in the substrate of the volcano, between relatively weak early Quaternary clays and stronger rocks of the Apennine–Maghrebian Chain that rise towards the north and west in the subsurface, buttressing the edifice in these directions. The unstable mass to the un-buttressed south and east is thus defined by its weak substrate and displays structures similar to those produced in model experiments. The third fault group, the Mascaluci–-Trecastagni fault system, borders a rather faster-moving zone of instability in the eastern part of the large unstable mass, outlining one element in a nested pattern in map view. Low-angle detachments below the unstable zones are thought to occur at different levels above a deep and laterally extensive detachment associated with the RFS, producing a nested pattern in section as well. This is illustrated by the PFS where the long-recognised western half of the fault borders a fast moving zone of instability riding above a detachment that daylights as a thrusted deformation front marked by recurring landsliding at an approximate mid-slope position on the volcano. Downslope, the newly recognised eastern extension of the PFS, exhibiting slip-rates an-order-of-magnitude lower than the western segment, is thought to border a deeper slow-moving detachment that daylights offshore. Windows of deformed sub-Etnean clays at anomalously high altitudes may indicate where similar detachments, no longer mechanically favoured and now inactive, have daylighted. As a result, the edifice can be considered, overall, as consisting of multiple unstable areas, nested in plan view and with basal detachments occurring at different levels in section. This model of edifice behaviour is regarded as an evolving one, with detachments waxing and waning in their activity as flank movement progresses.
    Description: Published
    Description: 137-153
    Description: partially_open
    Keywords: Mount Etna ; instability; flank faults ; volcano collapse models ; 04. Solid Earth::04.04. Geology::04.04.09. Structural geology ; 04. Solid Earth::04.08. Volcanology::04.08.06. Volcano monitoring
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  • 168
    Publication Date: 2017-04-04
    Description: New geochemical data on dissolved major and minor constituents in 276 groundwater samples from Etna aquifers reveal the main processes responsible for their geochemical evolution and mineralisation. This topic is of particular interest in the light of the progressive depletion of water resources and groundwater quality in the area. Multivariate statistical analysis reveal 3 sources of solutes: (a) the leaching of the host basalt, driven by the dissolution of magmaderived CO2; (b) mixing processes with saline brines rising from the sedimentary basement below Etna; (c) contamination from agricultural and urban wastewaters. The last process, highlighted by increased concentrations of SO4,NO3, Ca, F and PO4, is more pronounced on the lower slopes of the volcanic edifice, associated with areas of high population and intensive agriculture. However, this study demonstrates that natural processes (a) and (b) are also very effective in producing highly mineralised waters, which in turn results in many constituents (B, V, Mg) exceeding maximum admissible concentrations for drinking water.
    Description: Published
    Description: 863–882
    Description: partially_open
    Keywords: Hydrogeochemistry ; water quality ; Mt. Etna ; 03. Hydrosphere::03.02. Hydrology::03.02.03. Groundwater processes ; 03. Hydrosphere::03.02. Hydrology::03.02.04. Measurements and monitoring ; 03. Hydrosphere::03.02. Hydrology::03.02.06. Water resources ; 03. Hydrosphere::03.04. Chemical and biological::03.04.03. Chemistry of waters
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  • 169
    Publication Date: 2017-04-04
    Description: Geochemical research was carried out on cold and hot springs at Popocatepetl (Popo) volcano (Mexico) in 1999 to identify a possible relationship with magmatic activity. The chemical and isotopic composition of the fluids is compatible with strong gas–water interaction between deep and shallow fluids. In fact, the isotopic composition of He and dissolved carbon species is consistent with a magmatic origin. The presence of a geothermal system having a temperature of 80–1008 C was estimated on the basis of liquid geothermometers. A large amount of dissolved CO2 in the springs was also detected and associated with high CO2 degassing.
    Description: Published
    Description: 91– 108
    Description: partially_open
    Keywords: Popocatepetl volcano ; helium isotope composition ; carbon isotope composition ; dissolved gases ; gas–water interaction ; 03. Hydrosphere::03.02. Hydrology::03.02.03. Groundwater processes ; 03. Hydrosphere::03.04. Chemical and biological::03.04.05. Gases ; 03. Hydrosphere::03.04. Chemical and biological::03.04.06. Hydrothermal systems ; 04. Solid Earth::04.04. Geology::04.04.12. Fluid Geochemistry ; 04. Solid Earth::04.08. Volcanology::04.08.01. Gases
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  • 170
    Publication Date: 2017-04-04
    Description: We describe the reactivation and the successive evolution of the shallow plumbing system of Mt. Etna between the end of the largest flank eruption of the last three centuries (1991–1993) and the subterminal eruption from South-East Crater (SEC), which occurred between February and mid-November 1999. Our analysis is based on observations of the volcanic activity and petrological studies of the erupted volcanics. Bulk rock, mineral and glass compositions have been determined for more than 80 samples erupted from the four summit craters between October 1995 and February 1999. These data allow us to recognise significant compositional variations among the products of different craters. In particular, volcanics produced between 1995 and 1999 by Bocca Nuova (BN), Voragine (VOR) and North-East Crater (NEC) show limited compositional variations and are similar to those observed during recent eruptions (e.g., 1991–93). More primitive magmas have been produced during the more vigorous fire fountains episodes. On the contrary, the South-East Crater produced slightly more differentiated volcanics than those of the other summit craters following its reactivation (November 1996) until the end of 1998. Whole rock compositions of products from this crater show low CaO/Al2O3, whereas interstitial glasses have lower MgO and higher alkali contents than those from the other craters. However, since the beginning of 1999, and just before the start of the subterminal eruption from SEC, the volcanics erupted from this crater progressively changed in composition, becoming similar to those of the other craters. This trend indicates that within the conduits of the summit craters, distinct thermal and fluid-dynamical regimes can evolve, controlling the cooling and crystallisation of Etna magmas.
    Description: Published
    Description: 55-71
    Description: partially_open
    Keywords: Mount Etna ; crystal fractionation ; petrologic monitoring and magmatic process ; 04. Solid Earth::04.04. Geology::04.04.05. Mineralogy and petrology ; 04. Solid Earth::04.08. Volcanology::04.08.03. Magmas ; 04. Solid Earth::04.08. Volcanology::04.08.05. Volcanic rocks
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  • 171
    Publication Date: 2017-04-04
    Description: We have developed a quantitative model of CO2 and H2O isotopic mixing between magmatic and hydrothermal gases for the fumarolic emissions of the La Fossa crater (Vulcano Island, Italy). On the basis of isotope balance equations, the model takes into account the isotope equilibrium between H2O and CO2 and extends the recent model of chemical and energy two-end-member mixing by Nuccio et al. (1999). As a result,the H2O and CO2 content and the dD, d18O, and d13C isotope compositions for both magmatic and hydrothermal end-members have been assessed. Low contributions of meteoric steam, added at a shallow depth, have been also recognized and quantified in the fumaroles throughout the period from 1988 to 1998. Nonequilibrium oxygen isotope exchange also seems to be occurring between ascending gases and wall rocks along some fumarolic conduits. The d13CCO2 of the magmatic gases varies around -3 to 1‰ vs. Peedee belemnite (PDB), following a perfect synchronism with the variations of the CO2 concentration in the magmatic gases. This suggests a process of isotope fractionation because of vapor exsolution caused by magma depressurization. The hydrogen isotopes in the magmatic gases (-1 to -35‰ vs. standard mean ocean water [SMOW]), as well as the above d13CCO2 value, are coherent with a convergent tectonic setting of magma generation, where the local mantle is widely contaminated by fluids released from the subducted slab. Magma contamination in the crust probably amplifies this effect. The computed isotope composition of carbon and hydrogen in the hydrothermal vapors has been used to calculate the dD and d13C of the entire hydrothermal system, including mixed H2O-CO2 vapor, liquid water, and dissolved carbon. We have computed values of about 10‰ vs. SMOW for water and -2 to -6.5‰ vs. PDB for CO2. On these grounds, we think that Mediterranean marine water (dDH2O 10‰) feeds the hydrothermal system. It infiltrates at depth throughout the local rocks, reaching oxygen isotope equilibrium at high temperatures. Interaction processes between magmatic gases and the evolving seawater also seem to occur, causing the dissolution of isotopically fractionated aqueous CO2 and providing the source for hydrothermal carbon. These results have important implications concerning fluid circulation beneath Vulcano and address the more convenient routine of geochemical surveillance.
    Description: Published
    Description: 759–772
    Description: partially_open
    Keywords: isotope geochemistry ; volcanic gases ; mixing modeling ; 04. Solid Earth::04.04. Geology::04.04.12. Fluid Geochemistry ; 04. Solid Earth::04.08. Volcanology::04.08.01. Gases ; 04. Solid Earth::04.08. Volcanology::04.08.03. Magmas ; 04. Solid Earth::04.08. Volcanology::04.08.06. Volcano monitoring ; 05. General::05.02. Data dissemination::05.02.01. Geochemical data
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  • 172
    Publication Date: 2017-04-04
    Description: The results of the 7 years (1994-2000) of monthly monitoring of spring water before and during eruptions show response to volcanic activity. Low salinity and temperature characterize most of the springs, which are located on the flanks of Popocatepetl Volcano. The pH ranges from 5.8 to 7.8 and temperature from 3 to 36 jC. Oxygen and hydrogen isotopic data show that the water is of meteoric origin, but SO4 2 , Cl , F , HCO3 , B, and SO4 2- /Cl- variations precede main eruptive activity, which is considered linked to influx of magmatic gases and acid fluids that react with sublimates and host rock and mix with the large water system. Na +, Ca2 + , SiO2 and Mg2 + concentrations in the water also increased before eruptive activity. The computed partial pressure of CO2 in equilibrium with spring waters shows values higher than air-saturated water (ASW), with the highest values up to 0.73 bar of pCO2. Boron is detected in the water only preceding the larger eruptions. When present, boron concentration is normally under health standard limits, but in two cases the concentration was slightly above. Other components are within health standard limits, except for F- in one spring.
    Description: Published
    Description: 207– 229
    Description: partially_open
    Keywords: Volcano monitoring ; Spring water chemistry ; Popocatepetl ; Mexico ; 04. Solid Earth::04.04. Geology::04.04.12. Fluid Geochemistry ; 04. Solid Earth::04.08. Volcanology::04.08.06. Volcano monitoring ; 05. General::05.02. Data dissemination::05.02.01. Geochemical data
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  • 173
    Publication Date: 2017-04-04
    Description: This work deals with the integration of different surveying methodologies for the definition of very accurate Digital Terrain Models (DTM) and/or Digital Surface Models (DSM): in particular, the aerial digital photogrammetry and the terrestrial laser scanning were used to survey the Vesuvio volcano, allowing the total coverage of the internal cone and surroundings (the whole surveyed area was about 3 km×3 km). The possibility to reach a very high precision, especially from the laser scanner data set, allowed a detailed description of the morphology of the volcano. The comparisons of models obtained in repeated surveys allow a detailed map of residuals providing a data set that can be used for detailed studies of the morphological evolution. Moreover, the reflectivity information, highly correlated to materials properties, allows for the measurement and quantification of some morphological variations in areas where structural discontinuities and displacements are present.
    Description: Published
    Description: 123-138
    Description: JCR Journal
    Description: partially_open
    Keywords: Vesuvio; TLS; aerial digital photogrammetry; models; integration ; 04. Solid Earth::04.03. Geodesy::04.03.06. Measurements and monitoring
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  • 174
    Publication Date: 2017-04-04
    Description: The 2002 earthquake sequence of October 31 and November 1 (main shocks Mw=5.7) struck an area of the Molise region in Southern Italy. In this paper we analyzed the co-seismic deformation related to the Molise seismic sequence, inferred from GPS data collected before and after the earthquake, that ruptured a rather deep portion of crust releasing a moderate amount of seismic energy with no surface rupture. The GPS data have been reduced using two different processing strategies and softwares (Bernese and GIPSY) to have an increased control over the result accuracy, since the expected surface displacements induced by the Molise earthquake are in the order of the GPS reliability. The surface deformations obtained from the two approaches are statistically equivalent and show a displacement field consistent with the expected deformation mechanism and with no rupture at the surface. In order to relate this observation with the seismic source, an elastic modeling of fault dislocation rupture has been performed using seismological parameters as constraints to the model input and comparing calculated surface displacements with the observed ones. The sum of the seismic moments (8.9×1017 Nm) of the two main events have been used as a constraint for the size and amount of slip on the model fault while its geometry has been constrained using the focal mechanisms and aftershocks locations. Since the two main shocks exhibit the same fault parameters (strike of the plane, dip and co-seismic slip), we modelled a single square fault, size of 15 km×15 km, assumed to accommodate the whole rupture of both events of the seismic sequence. A vertical E–W trending fault (strike=266°) has been modeled, with a horizontal slip of 120 mm. Sensitivity tests have been performed to infer the slip distribution at depth. The comparison between GPS observations and displacement vectors predicted by the dislocation model is consistent with a source fault placed between 5 and 20 km of depth with a constant pure right-lateral strike-slip in agreement with fault slip distribution analyses using seismological information. The GPS strain field obtained doesn't require a geodetic moment release larger than the one inferred from the seismological information ruling out significant post-seismic deformation or geodetic deformation released at frequencies not detectable by seismic instruments. The Molise sequence has a critical seismotectonic significance because it occurred in an area where no historical seismicity or seismogenic faults are reported. The focal location of the sequence and the strike-slip kinematics of main shocks allow to distinguish it from the shallower and extensional seismicity of the southern Adriatic block from the northern one.
    Description: Published
    Description: 21-35
    Description: JCR Journal
    Description: reserved
    Keywords: GPS ; molise earthquake ; 04. Solid Earth::04.06. Seismology::04.06.06. Surveys, measurements, and monitoring
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  • 175
    Publication Date: 2017-04-04
    Description: The 5 April 2003 paroxysmal explosion at Stromboli volcano was one of the strongest explosive events of the last century. It occurred while the effusive eruption, begun on 28 December 2002 and finished on 22 July 2003, was still on going and the summit craters of the volcano were obstructed. In this paper, we present a reconstruction of the sequence of events based on thermal and visual images collected from helicopter before, during and immediately after the paroxysm. One month before the blast, ash emission and temperature increase at the bottom of the summit craters were observed. An increasing amount of juvenile components in the emitted ash during March suggested that the magma level within the crater was rising accordingly. Hot degassing vents at the bottom of the summit craters were not persistent, and the craters remained almost entirely obstructed by talus accumulation until the paroxysm occurred. Three minutes before the explosion, we recorded a significant increase in temperature inside Crater 1, accompanied by a thicker gas plume. Thirty-two seconds before the blast, reddish ash was emitted from Crater 1. The paroxysm produced a vulcanian explosion that opened the feeder conduit, obstructed for over three months. The blast was accompanied by a shock wave recorded by the INGV seismic network at 07:13:37 GMT. Explosions with hot material started from Crater 1, and after 15 s propagated to Crater 3, about 100 m away. The velocity of ejecta was ~80 m s 1, and increased when the eruptive plumes from both craters merged together during the vulcanian phase. An eruptive column rose 1 km above the top of the volcano, and explosions continued mainly at Crater 3. The paroxysm lasted about 9 min, with bombs up to 4 m wide falling on the village of Ginostra, on the west flank of the island, and destroying two houses. This event signalled the start of the declining phase of the effusive eruption, suggesting that the feeder conduit was returning to its former steady conditions, with open vents and continuous, mild strombolian activity.
    Description: Published
    Description: 160-175
    Description: reserved
    Keywords: vulcanian explosion ; paroxysm ; magma–water interaction ; thermal image analysis ; 04. Solid Earth::04.08. Volcanology::04.08.06. Volcano monitoring
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  • 176
    Publication Date: 2017-04-04
    Description: In this paper we discuss the data collected by a large aperture array of broadband seismometers and a continuously recording gravity station during the 2002–2003 eruption of Etna volcano (Italy). Seismic signals recorded during the eruption are dominated by volcanic tremor whose energy spans the 0.5–5 Hz frequency band. On three different occasions (12 November, 19–20 November and 8–9 December 2002), we observed marked increases of the tremor amplitude (up to a factor of 4), which occurred simultaneously with gravity decreases (up to 30 μGal). The three concurrent gravity/tremor anomalies last 6 to 12 hours and terminate with rapid (up to 2 hours) changes, after which the signals return back to their original levels. Based on volcanological observations encompassing the simultaneous anomalies, we infer that the accumulation of a gas cloud at some level in the conduit plexus feeding a new eruptive vent could have acted as a joint source. This study highlights the potential of joint gravity–seismological analyses to both investigate the internal dynamic of a volcano and to improve the confidence of volcanic hazard assessment.
    Description: Published
    Description: 616-629
    Description: reserved
    Keywords: Etna ; volcanic tremor ; gravity changes ; foam layer ; 04. Solid Earth::04.03. Geodesy::04.03.04. Gravity anomalies ; 04. Solid Earth::04.03. Geodesy::04.03.05. Gravity variations ; 04. Solid Earth::04.06. Seismology::04.06.08. Volcano seismology
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  • 177
    Publication Date: 2017-04-03
    Description: Mount Etna has developed at the intersection of two regional tectonic lineaments, the NNW–SSE trending Hybleo–Maltese escarpment, which separates the thick inland continental crust of the African platform from the Ionian Mesozoic oceanic crust, and the NE–SW Messina–Fiumefreddo fault that marks a rift zone between south Calabria and north-eastern Sicily, extending as far as the Mt. Etna area. All tectonic features affect, with outstanding surface features, the eastern side of the volcano. The eastern flank of the volcano is affected by a long-term motion toward ESE. In 1997, in order to increase the detail of the ground deformation pattern on the lower eastern flank of Mt. Etna, a new GPS network, the “Ionica” network, was installed on this sector of the volcano. This GPS network consists of 24 stations and covers the lower eastern flank of the volcano from the town of Catania to Taormina and from the coastline up to an altitude of about 1300 m. All the new stations consist in self-centring benchmarks; this kind of benchmark allows all station set-up errors to be avoided. Before the merging of the Ionica network to the frame of the global GPS network of Mt. Etna (in June 2001), three surveys were carried out on this network: in September 1997, August 1998 and January 2001. From the ground deformation pattern, it is possible to distinguish two different sectors, showing different characteristics of deformation. The southern part of the network shows a more uniform distribution of the vertical motion with a mean SE-ward horizontal component while the northern one shows an heterogeneous vertical motion with a ESE-ward horizontal component. Furthermore, a higher velocity is detected between 1997 and 1998, due to the additional stress induced by a shallow intrusion on the NW flank of the volcano. The model resulting from data inversions defines a wide sliding plane beneath the entire eastern flank of the volcano with a low dip angle. The expected velocity vectors fit well the observed ones, even if the measured velocities are still quite higher than expected, at lowermost stations. The vertical inclination of the velocity vectors measured during the 1998–2001 period, gradually decreases from West to East suggesting a sort of rotational movement of the south-eastern flank, interrupted by some anomalous vectors on the lower part, that show higher vertical velocities. These anomalies, being located on a wedge defined by the intersection of the main NNW–SSE and NE–SW fault systems and near the Timpe faults, are probably due to the activity of the vertical faults cutting the lower eastern flank of Mt. Etna. Stations lying on the hanging wall and on the footwall of the Timpe fault system are affected by similar horizontal displacements, meaning that these structures are moving eastwards together with the sliding flank; this evidence suggests that the Timpe faults are probably second order structures, with respect to the detachment surface. These results depict a structural framework of the eastern flank of Mt. Etna in which the low angle dislocation can be considered as a first order approximation of an actual listric plane and the current active part of the Timpe fault system is confined above the detachment surface.
    Description: Published
    Description: 357-369
    Description: reserved
    Keywords: ground deformation ; flank dynamics ; volcano–tectonics ; Etna volcano ; 04. Solid Earth::04.03. Geodesy::04.03.01. Crustal deformations ; 04. Solid Earth::04.03. Geodesy::04.03.07. Satellite geodesy ; 04. Solid Earth::04.08. Volcanology::04.08.07. Instruments and techniques
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  • 178
    Publication Date: 2017-04-04
    Description: Our knowledge of the degassing pattern of sulphur, chlorine and fluorine during ascent and eruption of basaltic magmas is still fragmental and mainly limited to water-poor basalts. Here we model and discuss the pressure-related degassing behaviour of S, Cl and F during ascent, differentiation and extrusion of H2O–CO2-rich alkali basalt on Mount Etna (Sicily) as a function of eruptive styles. Our modelling is based on published and new melt inclusion data for dissolved volatiles (CO2, H2O, S, Cl, F) in quenched explosive products from both central conduit (1989–2001) and lateral dyke (2001 and 2002) eruptions. Pressures are obtained from the dissolved H2O and CO2 concentrations, and vapour–melt partition coefficients of S, Cl and F are derived from best fitting of melt inclusion data for each step of magma evolution. This allows us to compute the compositional evolution of the gas phase during either open or closed system degassing and to compare it with the measured composition of emitted gases. We find that sulphur, chlorine and fluorine begin to exsolve at respective pressures of ∼140 MPa, ∼100 MPa and ≤10 MPa during Etna basalt ascent and are respectively degassed at 〉95%, 22–55%, and ∼15% upon eruption. Pure open system degassing fails to explain gas compositions measured during either lateral dyke or central conduit eruptions. Instead, closed-system ascent and eruption of the volatile-rich basaltic melt well accounts for the time-averaged gas composition measured during 2002-type lateral dyke eruptions (S/Cl molar ratio of 5±1, 35% bulk Cl loss). Extensive magma fragmentation during the most energetic fountaining phases enhances Cl release (55%) and produces a lower S/Cl ratio of 3.7, as actually measured. Comparatively slower magma rise in the central conduits of Etna favours both sulphide saturation of the melt and greater chlorine release (55%), resulting in a distinct S/Cl evolution path and final ratio in eruptive gas. In both eruption types, any previous bubble–melt separation at depth leads to increased S/Cl and S/F ratios in emitted gas. High S/Cl ratios measured during some discrete eruptive events can thus be explained by transitions from closed (deep) to open (shallow) system degassing, with differential gas transfer extending down to ∼2 km depth below the vents. This depth coincides with the base of the volcanic pile where structural discontinuities and the high magma vesicularity (60%) may favour separate gas flow. Finally, the excess S–Cl–F gas discharge through Etna summit craters during non-eruptive periods requires a mixed supply from shallow magma degassing in the volcanic conduits and deeper-derived SO2-rich bubbles from the sub-volcano plumbing system. Our modelling provides a useful reference framework for interpreting the monitored variations of S, Cl and F in Mount Etna gas emissions as a function of volcanic activity. More broadly, the observations made for S, Cl and F degassing on Etna may apply to other basaltic volcanoes with water-rich magmas, such as in arcs.
    Description: Published
    Description: 772-786
    Description: reserved
    Keywords: Mt Etna ; volatiles ; magma degassing ; eruptive mechanisms ; modelling ; 04. Solid Earth::04.08. Volcanology::04.08.01. Gases ; 04. Solid Earth::04.08. Volcanology::04.08.03. Magmas
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  • 179
    Publication Date: 2017-04-04
    Description: The first measurements of volcanic/hydrothermal water vapor and heat flux using eddy covariance (EC) were made at Solfatara crater, Italy, June 8–25, 2001. Deployment at six different locations within the crater allowed areas of focused gas venting to be variably included in the measured flux. Turbulent (EC) fluxes of water vapor varied between 680 and 11200g H2O m−2 d−1. Heat fluxes varied diurnally with the solar input, and the volcanic component of sensible heat ranged from ∼25 to 238W m−2. The highest measurements of both sensible and latent heat flux were made downwind of hot soil regions and degassing pools and during mid-day. The ratio of average volcanic heat (both latent and sensible) to CO2 flux resulted in an equivalent H2O/CO2 flux ratio of 2.2 by weight, which reflects the deep source H2O/CO2 gas ratio. The amount latent heat flux/evaporation was determined to be consistent both with what would be expected from the magnitude of CO2 fluxes and the fumarolic H2O/CO2 ratio, as well as with observed surface temperatures and wind speeds given a moist soil. This suggests that the water vapor that condenses in the shallow subsurface is remobilized at the soil–atmosphere interface through variable evaporation dependent on the deep heat flux and surface temperature. The results suggest that EC provides a quick and easy method to monitor average H2O/CO2 ratios continuously in volcanic regions, providing another important tool for volcanic hazards monitoring.
    Description: Published
    Description: 72–82
    Description: reserved
    Keywords: eddy covariance ; volcanic ; heat flux ; water vapor ; hydrothermal ; degassing ; flux ; emissions ; 03. Hydrosphere::03.04. Chemical and biological::03.04.05. Gases ; 03. Hydrosphere::03.04. Chemical and biological::03.04.06. Hydrothermal systems ; 03. Hydrosphere::03.04. Chemical and biological::03.04.08. Instruments and techniques
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  • 180
    Publication Date: 2017-04-04
    Description: We review the main results, with several new analyses, obtained in recent times about the structure, present dynamics and hazard evaluation at Somma–Vesuvius volcanic complex. We present a global review and interpretation of structural features, both at local and regional scale, constrained both by seismic and petrological data. The local structure of Somma–Vesuvius is reviewed in three depth ranges, shallow, intermediate and deep. The shallow velocity structure is inferred by the joint inversion of shot and local earthquake arrival time data. The main feature pointed out at shallow depth is a high velocity anomaly at the crater axis, extending down to about 5 km of depth. Such an anomaly, first observed at Vesuvius, seems to be common to many other volcanoes. It can be interpreted in terms of the presence of solidified residual magma in the shallow conduits, accumulated in last eruptive cycles. The local seismicity is strongly clustered around this anomaly, due to the focusing effect of the rigidity contrast. The seismic occurrence appears as a result of the superposition of a background level, mainly due to gravitational instability of the Vesuvius cone, and of intense activity episodes, which possibly reflect episodic internal activity. Two main zones of magma accumulation in the upper crust are evidenced by the joint interpretation of seismic and petrological data. The first one, located in the depth range 4–6 km, is mainly constrained by the crystallisation depth of phonolitic magmas which fed Plinian and sub-Plinian eruptions; the second one, around 11–15 km of depth, is mainly constrained by reflected–converted seismic waves, and in agreement with crystallization depths inferred for the moderate eruptions. The study of the deep structure, performed by regional tomography with teleseisms, further points out magma roots at higher depths (15–30 km). An additional result for the deep structure, studied at regional scale and very important for geodynamic interpretations of the Tyrrhenian volcanisms, has been the evidence for a subducting slab under the Apennines, in an area where previous models hypothesised a slab window. New original studies of crystal growth (phenocrystals and microlites) on the eruptive products allow to infer typical times of magma rising from such reservoirs, which appear very low, on the order of minutes to tens of minutes. Static deformation at this volcano, in the last 30 yr, has been detected by the joint use of levelling, GPS and DIFSAR techniques. It indicates subsidence, very concentrated in the crater area and in a narrow strip all around the volcanic edifice, with maximum rates less than 0.01 m/yr. Static deformation in the crater area appears in agreement with the mechanism of gravitational instability generating local volcanotectonic seismicity, while the peculiar pattern around the volcanic edifice is probably due to the combination of extensional stress and volcanic loading, generating a ring normal fault-like structure. While the key results about structure and dynamics help to define pre-eruptive scenarios, a new probabilistic procedure to combine volcanological data and computer simulations has been used, in this paper, to build hazard maps giving the probability, at each location in the area, to be hit by a pyroclastic flow or to experience a destructive fall-out deposit. The review and new results of this work give then the first complete picture of the state of the art in our knowledge about Somma–Vesuvius volcano.
    Description: Published
    Description: 73-111
    Description: reserved
    Keywords: volcano structure ; volcano dynamics ; volcanic hazard ; Mount Vesuvius ; 04. Solid Earth::04.08. Volcanology::04.08.08. Volcanic risk
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  • 181
    Publication Date: 2017-04-04
    Description: The goal of this paper is to describe how continuous gravity measurements can improve the geophysical monitoring of a volcano. Here the experience of 15 yr in continuous gravity on Vesuvius is presented. A wide set of dynamic phenomena (i.e. geodynamics, seismicity, volcanic activity) can produce temporal gravity changes, with a spectrum varying from short (1–10 s) to longer (more than 1 yr) periods. An impending eruption, for instance, is generally associated with the ascent of magma producing changes in the density distribution at depth, and leading to ground deformation and gravity changes observed at surface. The amplitude of such gravity variations is often quite small, on the order of 10 9–10 8 g (10–102 nm/s2; 1–10 AGal), where g is the mean value of normal gravity (9.806 199 203 m/s2), so their detection requires instruments with high sensitivity and stability, providing high quality data. Natural, man-made and instrumental sources are present on the gravity records affecting the Signal to Noise Ratio. Such effects may hide the subtle volcanic signals. The main natural noise is due to ocean–atmosphere dynamics and seismic activity. New approaches to model the instrumental response of mechanical gravity sensors (based on the inter-comparison among superconducting, mechanical and absolute gravimeters) and to investigate the temporal trends of the instrumental sensitivity are proposed. In fact, variations of the calibration factors can be considered the main cause preventing the repeatability of highprecision gravity measurements and inducing phase and amplitude perturbations in recorded gravity signals. A modelling of the background gravity noise level was performed at the Vesuvius station. Moreover, the bfar fieldQ effects produced by large earthquakes on the gravity station have been also investigated. Finally, the time dependent behaviour of the tidal gravimetric factors, the non-stationary components of the gravity field detected at Vesuvius and the results of absolute and relative gravity measurements are interpreted in the framework of its present-day dynamics, mainly characterized by the low level of seismicity, small ground deformation, gravity changes and moderate gas emission.
    Description: Published
    Description: 270– 282
    Description: reserved
    Keywords: Vesuvius ; gravity ; record ; volcanic processes ; 04. Solid Earth::04.03. Geodesy::04.03.05. Gravity variations ; 04. Solid Earth::04.03. Geodesy::04.03.06. Measurements and monitoring ; 04. Solid Earth::04.08. Volcanology::04.08.06. Volcano monitoring
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  • 182
    Publication Date: 2017-04-04
    Description: A scattering image of the Campi Flegrei caldera has been obtained using coda wave envelopes from local microearthquake data recorded at a portable 12-station digital network. This was operated during the paroxysmic phase of the ground uplift (bradyseism) that occurred in the years 1983–1984. The Nishigami technique has been used to obtain the 3D distribution of the strong scatterers in an earth volume with a horizontal extension of 20 km×20 km and a vertical thickness of 6 km. This earth volume was segmented in blocks of 2 km×2 km×2 km for the outer section, and in blocks of 1 km×1 km×1 km for the inner section. The inversion was performed using a hybrid jackknife-SVD method that has allowed qualitative control of the stability and robustness of the solution. The results show that the scatterers revealed by the coda envelopes, which were band-pass filtered at a center frequency of 18 Hz, match the inner border of the caldera rim, which is well outlined on land by geological observations. The scatterer position also delineates this border well beneath sea level. These results are in close agreement with recently obtained seismic velocity tomography. The scatterers imaged at the 6 and 12 Hz band-pass frequencies are located around the zone of maximum uplift, beneath Solfatara crater, where most of the present residual volcanic activity is concentrated.
    Description: Published
    Description: 269-280
    Description: reserved
    Keywords: Scattering tomography ; Campi Flegrei caldera ; Seismic attenuation ; Inversion techniques ; 04. Solid Earth::04.06. Seismology::04.06.99. General or miscellaneous
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  • 183
    Publication Date: 2017-04-04
    Description: The exceptionally persistent activity of Stromboli volcano has lasted for at least 1400 years. The normal strombolian activity is periodically interrupted by more energetic explosions (1–2 per year) and by sporadic effusive episodes (every 10–20 years). Normal activity and effusive episodes are characterized by crystal-rich high-K to shoshonitic basalts issuing from a volatile-poor shallow system. Crystal-poor pumice are emitted only during more violent explosions, and are thought to derive from deep pulses of volatile-rich magma. Shallow level degassing induces massive crystallization of deep pulses of feeding magma that, continuously mixing with the resident one, produces the crystal-rich shoshonite of the persistent activity. We examined the crystallization history of the crystal-rich, shallow reservoir using plagioclase Crystal Size Distribution (CSD) analysis of scoriae and lavas emitted in the past twenty years. CSDs show a linear dependence from crystal size in the size interval 0.06–1.2 mm; number density of larger crystals is biased by right hand truncation effects. CSDs slopes and intercepts are quite constant during the whole considered time span revealing a system that is close to the equilibrium also from a kinetic point of view. The linear crystal size distribution are reached by the system through episodes of growth and resorption, respectively occurring in the degassed and undegassed magma during the continuous mixing in the feeding system. Plagioclase net growth rate (2*10−11 cm/s) results from a balance of growth (10−10 cm/s) and resorption episodes which induce spectacular zoning and resorption textures in crystals larger than 200 μm. CSDs of mafic phases cannot be accurately acquired on each single sample due to poor counting statistics; the evaluation of pyroxene and olivine CSD on the whole data set, however, confirms the conclusions acquired from plagioclase CSDs.
    Description: Published
    Description: JCR Journal
    Description: open
    Keywords: crystal size distribution ; plagioclase growth ; magma residence time ; 04. Solid Earth::04.08. Volcanology::04.08.03. Magmas
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  • 184
    Publication Date: 2017-04-04
    Description: Knowledge of the physical, chemical and thermodynamic properties of silicate melts and glasses is required to understand magma formation and evolution at all scales of observation. As is illustrated by the papers published in this special issue of Chemical Geology, there is a complex interplay between microscopic and macroscopic features. Whereas determining the microscopic structure of glasses and melts is useful to understand how macroscopic properties vary with pressure, temperature and composition, studies of macroscopic properties in turn put strong constraints on which microscopic aspects are actually relevant to a given problem. In this issue this approach is successfully applied to a variety of topics which range from melt rheology to volatile solubility or from spectroscopic investigations of silicate speciation to computer simulation studies of melt/glass structure. These papers were originally presented and discussed in April 2005 at the Vienna meeting of the European Union of Geosciences. They represent an up-to-date overview of current research in the field, ranging from classical approaches to new science and technology solutions which will help expand our research possibilities. We thank the Chemical Geology staff and all contributors and colleagues who made this volume possible.
    Description: Published
    Description: 1
    Description: open
    Keywords: NONE ; 04. Solid Earth::04.08. Volcanology::04.08.01. Gases
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  • 185
    Publication Date: 2017-04-04
    Description: Three lava flows (hereafter, flows A, B, and C) from Salina Island (Italy) consist of basaltic andesitic enclaves dispersed in a dacitic matrix. Enclaves represent 8–12 vol.% of the erupted magma. The number of enclaves and the surface covered by the enclaves at each outcrop do not vary significantly with the distance from the vent in the flows A and B. These feature reflect the dynamics of magma mingling within the reservoir and not the kinematics of the lava flow. In the flow C, these parameters vary irregularly. The statistical entropy S(t) of the enclaves, which is a measure of their spatial distribution (dispersion), is estimated in outcrops located at different distance from the vent. The Kolmogorov–Sinai entropy rate k, which describes the variations of S(t) with time, is also determined. In the lava flow A, S(t) increases linearly with time t for 0btb0.4; k is 0.04. For tN0.5, S(t) attains its maximum value and maintains constant with increasing t. In the lava flow B, S(t) linearly increases with t, and k is 0.01. In the lava flow C, there is not correlation between S(t) and t. The comparison between the results from the analysis of the Porri enclaves and those from numerical experiments on the variation of S(t) in chaotic advective mixing systems and from previous experimental models on magma mixing, allow us to draw some conclusions on dynamics of the basaltic andesite– dacite mingling in the magma chamber. Fully chaotic magma mingling systems show three evolution stages. An initial stage, which is unknown because of the disruption of the initial configuration of the interacting magmas, a second stage characterized by a linear increase of the statistical entropy with time, and a third stage, in which the uniformity of the system is reached, and the entropy does not vary with increasing time. A system in which the uniformity is never attained, is characterized by irregular variations of S(t) with time. In the flows A and B, the relations between S(t) and t are consistent with those of a fully chaotic dynamics possibly associated to convection. The basaltic andesite was uniformly distributed in the dacitic host due to the occurrence of convective movements driven by the injection of the basaltic andesite within the dacitic chamber. The mingling system recorded by the lava flow A evolved with a higher rate with respect to that of the flow B. This suggests that chaotic advection (stirring and folding) is more efficient in the magmatic system A than in B. On the contrary, the mingling system C is characterized by a non-uniform distribution of the basaltic andesite within dacite. This reflects the occurrence of a dynamics in which stirring and folding processes do not operate efficiently and are unable to uniformly distribute the dispersed phase within the continuous one. The decrease of k from A to B, and the lack of a measurable k in C, along with the observation that A and B were emitted before C, indicate that the efficiency of advective movements within the Porri magma chamber declined with decreasing time. Mingled magmas characterized by a homogeneous spatial distribution of enclaves or an initially inhomogeneous distribution evolving towards a homogeneous one are indicative of efficient advection processes that may favor magma mixing. Mingled magmas characterized by an inhomogeneous distribution of enclaves suggest low dynamical interaction between the two end-members. Magma mixing is not allowed.
    Description: Published
    Description: 128–140
    Description: JCR Journal
    Description: reserved
    Keywords: volcanology ; petrology ; magma mingling ; enclaves ; lava flows ; entropy ; 04. Solid Earth::04.08. Volcanology::04.08.03. Magmas
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  • 186
    Publication Date: 2017-04-04
    Description: On 28 December 2002, the persistent Strombolian activity at Stromboli was interrupted by the sudden onset of lava emission onto the Sciara del Fuoco slope, a horseshoe-shaped depression on the NW flank of the volcano. The effusive episode went on until 22 July 2003 and produced a cumulative volume of lavas of 11×106 m3 ranking the event as the largest occurred in the past 30 years. The eruptive vents were mainly located in the NE sector of the Sciara del Fuoco depression, at an elevation of 550–600 m a.s.l. On 30 December, the eastern portion of the Sciara del Fuoco collapsed producing a tsunamigenic landslide. On 5 April 2003, a paroxysmal eruption occurred at the summit craters during which crystal-poor pumiceous products were emitted. The paroxysm did not interrupt the lava emission. The Strombolian activity at the summit craters gradually resumed starting from March 2003 and fully recovered by the end of July. Periodic sampling of the lava at the active vents was carried out during the entire effusive event. All the analysed samples are shoshonitic basalts (SiO2 48.5–50.4 wt.%; K2O 2.1–2.4 wt.%) in the range of composition observed in the products erupted during the past 20 years. They bear about 50 vol.% zoned crystals of plagioclase An90–60, diopside–augite and olivine Fo70–73 in a compositionally homogeneous shoshonitic groundmass. Bulk rock major and trace element contents measured with different methodologies at different laboratories show only minor variations. Sr and Nd isotope ratios are close to those of the crystal-rich scoriae erupted in the previous years. Despite of small compositional variations related to the emptying of the zoned topmost portion of the conduit, the data show that the switch from Strombolian explosive to effusive activity is not associated with changes of the textures and composition of the erupted products. Slight but somehow systematic variation of trace elements and isotope ratios between products erupted before and after the 5 April eruption are likely accounted by limited mixing between the fresh, volatile-rich, crystal-poor, magma erupted as pumice during the paroxysm, and the volatile-poor, crystal-rich magma feeding the lava flow. The uniform composition of the erupted lava indicates the presence of a large volume of well-mixed, crystal-rich, homogeneous magma residing in the shallow plumbing system of the volcano. Two possible trigger mechanism of the effusive event are here proposed: (i) a discrete input of fresh magma into the lower part of the shallow magmatic system occurred some months before the eruption and was followed by crystallisation, degassing and mixing with the crystal-rich shallow magma which re-homogenised the system. These processes eventually led to the rise of the magma at a higher level and failure of the conduit walls. (ii) The onset of the effusion may represent the consequence of a gradual rise of the magma level in the conduits occurred in the past two decades. The process of progressive refilling, initiated after the 1985 effusive eruption, ultimately culminated on 28 December 2002 with the failure of the conduit wall and the opening of vents 100–150 m below the summit craters
    Description: Published
    Description: 263-284
    Description: JCR Journal
    Description: reserved
    Keywords: Stromboli volcano ; Aeolian Islands ; 2002–2003 eruption ; Mineralogy ; Geochemistry ; Sr isotope ; 04. Solid Earth::04.08. Volcanology::04.08.03. Magmas
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  • 187
    Publication Date: 2017-04-04
    Description: Tropical Pacific interannual variability is examined in nine state-of-the-art coupled climate models, and compared with observations and ocean analyses data sets, the primary focus being on the spatial structure and spectral characteristics of El Nin˜o-Southern Oscillation (ENSO). The spatial patterns of interannual sea surface temperature (SST) anomalies from the coupled models are characterized by maximum variations displaced from the coast of South America, and generally extending too far west with respect to observations. Thermocline variability is characterized by dominant modes that are qualitatively similar in all the models, and consistent with the ‘‘recharge oscillator’’ paradigm for ENSO. The meridional scale of the thermocline depth anomalies is generally narrower than observed, a result that can be related to the pattern of zonal wind stress perturbations in the central-western equatorial Pacific. The wind stress response to eastern equatorial Pacific SST anomalies in the models is narrower and displaced further west than observed. The meridional scale of the wind stress can affect the amount of warm water involved in the recharge/discharge of the equatorial thermocline, while the longitudinal location of the wind stress anomalies can influence the advection of the mean zonal temperature gradient by the anomalous zonal currents, a process that may favor the growth and longer duration of ENSO events when the wind stress perturbations are displaced eastwards. Thus, both discrepancies of the wind stress anomaly patterns in the coupled models with respect to observations (narrow meridional extent, and westward displacement along the equator) may be responsible for the ENSO timescale being shorter in the models than in observations. The examination of the leading advective processes in the SST tendency equation indicates that vertical advection of temperature anomalies tends to favor ENSO growth in all the CGCMs, but at a smaller rate than in observations. In some models it can also promote a phase transition. Longer periods tend to be associated with thermocline and advective feedbacks that are in phase with the SST anomalies, while advective tendencies that lead the SST anomalies by a quarter cycle favor ENSO transitions, thus leading to a shorter period.
    Description: Published
    Description: 274–298
    Description: JCR Journal
    Description: reserved
    Keywords: El Nino phenomena ; Climatic changes ; Permanent thermocline ; Winds ; Surface temperature ; 03. Hydrosphere::03.01. General::03.01.02. Equatorial and regional oceanography ; 03. Hydrosphere::03.01. General::03.01.03. Global climate models ; 03. Hydrosphere::03.01. General::03.01.04. Ocean data assimilation and reanalysis
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  • 188
    Publication Date: 2017-04-04
    Description: This paper presents a global ocean implementation of a multi-component model of marine pelagic biogeochemistry coupled online with an ocean general circulation model forced with climatological surface fields (PELAgic biogeochemistry for Global Ocean Simulations, PELAGOS). The final objective is the inclusion of this model as a component in an Earth System model for climate studies. The pelagic model is based on a functional stoichiometric representation of marine biogeochemical cycles and allows simulating the dynamics of C, N, P, Si, O and Fe taking into account the variation of their elemental ratios in the functional groups. The model also includes a parameterization of variable chlorophyll/carbon ratio in phytoplankton, carrying chl as a prognostic variable. The first part of the paper analyzes the contribution of non-local advective–diffusive terms and local vertical processes to the simulated chl distributions. The comparison of the three experiments shows that the mean chl distribution at higher latitudes is largely determined by mixing processes, while vertical advection controls the distribution in the equatorial upwelling regions. Horizontal advective and diffusive processes are necessary mechanisms for the shape of chl distribution in the sub-tropical Pacific. In the second part, the results have been compared with existing datasets of satellite-derived chlorophyll, surface nutrients, estimates of phytoplankton community composition and primary production data. The agreement is reasonable both in terms of the spatial distribution of annual means and of the seasonal variability in different dynamical oceanographic regions. Results indicate that some of the model biases in chl and surface nutrients distributions can be related to deficiencies in the simulation of physical processes such as advection and mixing. Other discrepancies are attributed to inadequate parameterizations of phytoplankton functional groups. The model has skill in reproducing the overall distribution of large and small phytoplankton but tends to underestimate diatoms in the northern higher latitudes and overestimate nanophytoplankton with respect to picoautotrophs in oligotrophic regions. The performance of the model is discussed in the context of its use in climate studies and an approach for improving the parameterization of functional groups in deterministic models is outlined. © 2006 Elsevier B.V. All rights reserved.
    Description: Published
    Description: 110-134
    Description: JCR Journal
    Description: reserved
    Keywords: Global biogeochemical cycles ; Ocean general circulation model ; Ecosystem model ; OPA ; ERSEM ; PELAGOS ; 03. Hydrosphere::03.01. General::03.01.07. Physical and biogeochemical interactions ; 03. Hydrosphere::03.04. Chemical and biological::03.04.01. Biogeochemical cycles
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
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  • 189
    Publication Date: 2017-04-04
    Description: It has recently been demonstrated that methane emission from lithosphere degassing is an important component of the natural greenhouse-gas atmospheric budget. Globally, the geological sources are mainly due to seepage from hydrocarbon-prone sedimentary basins, and subordinately from geothermal/volcanic fluxes. This work provides a first estimate of methane emission from the geothermal/volcanic component at European level. In Europe, 28 countries have geothermal systems and at least 10 countries host surface geothermal manifestations (hot springs, mofettes, gas vents). Even if direct methane flux measurements are available only for a few small areas in Italy, a fair number of data on CO2, CH4 and steam composition and flux from geothermal manifestations are today available for 6 countries (Czech Republic, Germany, Greece, Iceland, Italy, Spain). Following the emission factor and area-based approach, the available data have been analyzed and have led to an early and conservative estimate of methane emission into the atmosphere around 10,000 ton/yr (4000–16,000 ton/yr), basically from an area smaller than 4000 km2, with a speculative upper limit in the order of 105 ton/yr. Only 4–18% of the conservative estimate (about 720 ton/yr) is due to 12 European volcanoes, where methane concentration in volcanic gases is generally in the order of a few tens of ppmv. Volcanoes are thus not a significant methane source. While the largest emission is due to geothermal areas, which may be situated next to volcanoes or independent. Here inorganic synthesis, thermometamorphism and thermal breakdown of organic matter are substantial. Methane flux can reach hundreds of ton/yr from small individual vents. Geothermal methane is mainly released in three countries located in the main high heat flow regions: Italy, Greece, and Iceland. Turkey is likely a fourth important contributor but the absolute lack of data prevents any emission estimate. Therefore, the actual European geothermal–volcanic methane emission could be easily projected to the 105 ton/yr levels, reaching the magnitude of some other natural sources such as forest fires or wild animals.
    Description: Published
    Description: 76-86
    Description: 4.5. Degassamento naturale
    Description: JCR Journal
    Description: reserved
    Keywords: Methane ; volcanoes ; Geothermal vents ; 04. Solid Earth::04.08. Volcanology::04.08.01. Gases
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
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  • 190
    Publication Date: 2017-04-04
    Description: A detailed structural and geophysical study of the Somma–Vesuvius volcanic complex was carried out by integrating mesostructural measurements, focal mechanisms and shear-wave splitting analysis. Fault-slip and focal mechanism analysis indicate that the volcano is affected by NW–SE-, NE–SW-trending oblique-slip faults and by E–W-trending normal faults. Magma chamber s. responsible for plinianrsub-plinian eruptions i.e. A.D. 79 and 1631. formed inside the area bounded by E–W-trending normal faults. The post-1631 fissural eruptions i.e. 1794 and 1861.occurred along the main oblique-slip fault segments. The movements of the Vesuvius faults are mainly related to the regional stress field. A local stress field superposed to the regional one is also present but evidences of magma or gravity induced stresses are lacking. The local stress field acts inside the caldera area being related to fault reactivation processes. The present-day Vesuvius seismic activity is due to both regional and local stress fields. Shear-wave splitting analysis reveals an anisotropic volume due to stress induced cracks NW–SE aligned by faulting processes. Since the depth extent of the anisotropic volume is at least 6 km b.s.l., we deduce the NW–SE-trending oblique-slip fault system represents the main discontinuity on which lies the volcano. This discontinuity is responsible for the morphological lowering of the edifice in its southwestern side.
    Description: Published
    Description: 199-218
    Description: 3.6. Fisica del vulcanismo
    Description: JCR Journal
    Description: reserved
    Keywords: structure of volcanoes ; stress field ; seismology ; tectonics ; 04. Solid Earth::04.06. Seismology::04.06.08. Volcano seismology
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
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  • 191
    Publication Date: 2017-04-04
    Description: New estimates on the Quaternary slip rate of the active transform margin of North Anatolia are provided. We investigated the area struck by the 12th November 1999, Mw 7.1 earthquake, that ruptured the Düzce fault segment of the North Anatolian Fault. In order to analyze the spectacular tectonically driven cumulative landforms and the drainage pattern settings, we carried out a 1:25,000-scale geological and geomorphological mapping along the fault trace. We reconstruct and describe, as offset geomorphic markers, right-hand stream deflections and fluvial terraces inset into alluvial fan deposits. Radiocarbon dating indicates that ~100 m stream deflections were built up by the last ~7000 yrs of fault activity. Conversely, two documented and correlated Late Pleistocene fluvial terraces are horizontally offset by ~300 and ~900 m, respectively. These were dated by means of Optically Stimulated Luminescence (OSL) to ~21 ka BP and 60 ka BP. Assuming a constant rate of deformation for the Düzce Fault, ages and related offsets translate to consistent slip-rates that yield an average slip-rate of 15.0 ± 3.2 mm/yr for the last 60 ka. Thus, the Düzce Fault importantly contributes to the North Anatolian margin deformation, suggesting a present-day partitioning of displacement rates with the Mudurnu fault to the south and confirming its important role in the seismic hazard of the area.
    Description: This research is supported by the European Commission Project “Relief”: Large earthquake faulting and implications for seismic hazard assessment in Europe: The Izmit-Düzce earthquake sequence of 1999, Turkey, Mw 7.4, 7.1, EVG1-CT-2002-00069.
    Description: Published
    Description: in press
    Description: 3.2. Tettonica attiva
    Description: JCR Journal
    Description: partially_open
    Keywords: Tectonic geomorphology ; Geomorphic markers ; Slip rate ; Strike-slip ; 1999 Düzce earthquake ; 04. Solid Earth::04.06. Seismology::04.06.01. Earthquake faults: properties and evolution
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
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  • 192
    Publication Date: 2017-04-04
    Description: The westernmost part of the Gulf of Corinth (Greece) is an area of very fast extension (~15 mm/yr according to geodetic measurements) and active normal faulting, accompanied by intense coastal uplift and high seismicity. This study presents geomorphic and biological evidence of Holocene coastal uplift at the western extremity of the Gulf, where such evidence was previously unknown. Narrow shore platforms (benches) and rare notches occur mainly on Holocene littoral conglomerates of uplifting small fan deltas. They are perhaps the only primary paleoseismic evidence likely to provide information on earthquake recurrence at coastal faults in the specific part of the Rift system, whereas dated marine fauna can provide constraints on average Holocene coastal uplift rate. The types of geomorphic and biological evidence identified are not ideal, and there are limitations and pitfalls involved in their evaluation. In a first approach, 5 uplifted paleoshorelines may be indentified, at 0.4- 0.7, 1.0-1.3, 1.4-1.7, 2.0-2.3 and 2.8-3.4 m a.m.s.l. They probably formed after 1728 or 2250 Cal. B.P. (depending on the marine reservoir correction used in the calibration of measured radiocarbon ages). A most conservative estimate for the average coastal uplift rate during the Late Holocene is 1.6 or 1.9 mm/yr minimum (with different amounts of reservoir correction). Part of the obtained radiocarbon ages of Lithophaga sp. allows for much higher Holocene uplift rates, of the order of 3-4 mm/yr, which cannot be discarded given that similar figures exist in the bibliography on Holocene and Pleistocene uplift at neighbouring areas. They should best be cross-checked by further studies though. That the identified paleoshoreline record corresponds to episodes of coastal uplift only, cannot be demonstrated beyond all doubt by independent evidence, but it appears the most likely interpretation, given the geological and active-tectonic context and, what is known about eustatic sea-level fluctuations in the Mediterranean. Proving that the documented uplifts were abrupt (i.e., arguably coseismic), is equally difficult, but reasonably expected and rather probable. Five earthquakes in the last ca. 2000 yrs on the coastal fault zone responsible for the uplift, compare well with historical seismicity and the results of recent on-fault paleoseismological studies at the nearby Eliki fault zone. Exact amounts of coseismic uplift cannot be determined precisely, unless the rate of uniform ("regional") non-seismic uplift of Northern Peloponnesus at the specific part of the Corinth Rift is somehow constrained.
    Description: European Community project 3HAZ-Corinth
    Description: Published
    Description: on line first
    Description: 3.2. Tettonica attiva
    Description: JCR Journal
    Description: open
    Keywords: Coastal fault zone ; Shore platforms ; Holocene shorelines ; Paleoseismology ; Coastal uplift ; 04. Solid Earth::04.04. Geology::04.04.01. Earthquake geology and paleoseismology
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
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  • 193
    Publication Date: 2017-04-04
    Description: The ground deformation produced by a spherical overpressure source in a heterogeneous elastic and/or viscoelastic medium is investigated by numerical models based on the finite element method. Sources are assumed to be located at different depths beneath Mount Etna, Sicily, Italy, the structure of which is approximated as axially symmetric. Finite element modelling allows to incorporate in the analysis realistic features such as topographic relief and the laterally heterogeneous multi-layered structure inferred from seismic tomography. In order to avoid introducing artifacts in the solution, great care was taken to calibrate the computational domain necessary to reproduce analytical results accurately. An elastic analysis, performed initially, shows significant changes of the deformation field with respect to homogeneous half-space solutions: topography induces slight but detectable changes in the deformation field; in particular the maximum value of the vertical component is shifted away from the symmetry axis. When introducing the elastic heterogeneities, the ground deformation is found to be more confined to the proximity of the axis and its amplitude is mostly sensitive to the presence of low rigidity layers above the source. The ratio of maximum radial to vertical deformation is significantly larger for deeper sources. A further development of the model includes the study of inelastic properties assuming a Maxwell viscoelastic rheology for different layers. If the viscoelastic rheology is applied only to layers deeper than the source, the solutions are affected in different ways according to the distance of the source from the viscoelastic layer. If a viscoelastic layer is present above the source, a very large amplification (by more than 100%) of the surface deformation is predicted by the model; moreover, uplift transients are found to be followed by subsidence, without invoking any decrease in source overpressure. The most striking effects are observed when the source is embedded within a viscoelastic layer: in this case a static equilibrium configuration is not attained and, in the long term, both components of deformation reverse their signs in proximity to the axis. Furthermore, the surface deformation becomes nearly independent of source depth, in the long term. Simple physical explanations are proposed for the different cases.
    Description: Published
    Description: 89-110
    Description: 3.6. Fisica del vulcanismo
    Description: JCR Journal
    Description: reserved
    Keywords: Mount Etna ; surface deformation ; topographic effect ; finite element method ; rheological layering ; overpressure source ; 04. Solid Earth::04.03. Geodesy::04.03.08. Theory and Models
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
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  • 194
    Publication Date: 2017-04-04
    Description: Northern Apulia is an emerged portion of the Adriatic microplate, representing the foreland–foredeep area of a stretch of the Apennine chain in southern Italy. The interaction between the relatively rigid microplate and the contiguous more deformable domains is responsible for the intense seismicity affecting the chain area. However strong, sometimes even disastrous, earthquakes have also hit northern Apulia on several occasions. The identification of the causative faults of such events is still unclear and different hypotheses have been reported in literature. In order to provide guidelines and constraints in the search for these structures, a comprehensive re-examination and reprocessing of all the available seismic data has been carried out taking into consideration 1) the characteristics of historical events, 2) the accurate relocation of events instrumentally recorded in the last 20 years, 3) the determination of focal mechanisms and of the regional stress tensor. The results obtained bring to light a distinction between the foreland and foredeep areas. In the first region there is evidence of a regional stress combining NWcompression and NE extension, thus structures responsible for major earthquakes should be searched for among strike–slip faults, possibly with a slight transpressive character. These structures could be either approximately N–S oriented sinistral or E–Wdextral faults. In the foredeep region there is a transition toward transtensive mechanisms,with strikes similar to those of the previous zone, or maybe also towardsNWoriented normal faults,more similar to those prevailing in the southern Apennine chain in relation to a dominant NE extension; this appears to be the effect of a reduction of the NW compression, probably due to a decrease in efficiency of stress transmission along the more tectonised border of the Adriatic microplate.
    Description: Published
    Description: 9 - 35
    Description: 3.2. Tettonica attiva
    Description: JCR Journal
    Description: reserved
    Keywords: Northern Apulia ; Historical earthquakes ; 04. Solid Earth::04.06. Seismology::04.06.03. Earthquake source and dynamics ; 04. Solid Earth::04.07. Tectonophysics::04.07.02. Geodynamics
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
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  • 195
    Publication Date: 2017-04-04
    Description: The exceptionally persistent activity of Stromboli volcano has lasted for at least 1400 years. The normal strombolian activity is periodically interrupted by more energetic explosions (1–2 per year) and by sporadic effusive episodes (every 10–20 years). Normal activity and effusive episodes are characterized by crystal-rich high-K to shoshonitic basalts issuing from a volatile-poor shallow system. Crystal-poor pumice are emitted only during more violent explosions, and are thought to derive from deep pulses of volatile-rich magma. Shallow level degassing induces massive crystallization of deep pulses of feeding magma that, continuously mixing with the resident one, produces the crystal-rich shoshonite of the persistent activity. We examined the crystallization history of the crystal-rich, shallow reservoir using plagioclase Crystal Size Distribution (CSD) analysis of scoriae and lavas emitted in the past twenty years. CSDs show a linear dependence from crystal size in the size interval 0.06–1.2 mm; number density of larger crystals is biased by right hand truncation effects. CSDs slopes and intercepts are quite constant during the whole considered time span revealing a system that is close to the equilibrium also from a kinetic point of view. The linear crystal size distribution are reached by the system through episodes of growth and resorption, respectively occurring in the degassed and undegassed magma during the continuous mixing in the feeding system. Plagioclase net growth rate (2 × 10− 11 cm/s) results from a balance of growth (10− 10 cm/s) and resorption episodes which induce spectacular zoning and resorption textures in crystals larger than 200 μm. CSDs of mafic phases cannot be accurately acquired on each single sample due to poor counting statistics; the evaluation of pyroxene and olivine CSD on the whole data set, however, confirms the conclusions acquired from plagioclase CSDs.
    Description: Published
    Description: 86-98
    Description: 2.4. TTC - Laboratori di geochimica dei fluidi
    Description: JCR Journal
    Description: reserved
    Keywords: crystal size distribution ; plagioclase growth ; magma residence time ; 04. Solid Earth::04.08. Volcanology::04.08.03. Magmas
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
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  • 196
    Publication Date: 2017-04-04
    Description: For some time, onset of the Antarctic Circumpolar Current (ACC) was considered to have caused or stabilised full Antarctic glaciation. Recently, however, the importance of the ACC in this role has been questioned. In order to understand the relationship between the ACC and Antarctic glaciation, and thence the importance of ocean circulation to palaeoclimate, we need to determine the development history of both processes. To this end, we summarise all published estimates of ACC onset. The time of onset, of shallow circulation or deep, is uncertain, whether based on tectonic studies or the interpretation of changes in the sediment record. Two potential final barriers to circumpolar flow have been identified; south of Tasmania and south of South America. The former is well constrained by tectonics and marine geology to before 32Ma for a deep gap, with a shallow gap in place by 35.5Ma at the latest. These ages fit nicely with the onset of full Antarctic glaciation at 33–34 Ma, although some workers question the causality. Estimates of the time of opening of the latter range widely, whether based on tectonics or sedimentary geology, from as recently as 6Ma to as early as 41 Ma, with the gap depth uncertain also. Resolution of the tectonics-based uncertainties by additional survey being most probably both time-consuming and inconclusive, and the geological estimates being open to alternative interpretations, we define an optimal strategy for additional sampling and measurement, designed to resolve the time of onset more certainly, possibly also resolving between deep and shallow opening, and thereby constraining the ACC role. Sample sites would have to be close to likely final barriers, to avoid extraneous influence, and within modern zones of ACC influence, ideally would form a depth transect, and would have continuous, mixed terrigenous and biogenic sections. A wide range of carefully selected parameters would be measured at each.
    Description: Published
    Description: 2388–2398
    Description: 2.2. Laboratorio di paleomagnetismo
    Description: JCR Journal
    Description: reserved
    Keywords: Antarctic Circumpolar Current ; Palaeoclimate ; Drake Passage ; 04. Solid Earth::04.04. Geology::04.04.99. General or miscellaneous
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
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  • 197
    Publication Date: 2017-04-04
    Description: The eastern border of the Middle Valley of the Tiber River is characterized by several Plio-Pleistocene paleoshorelines, which extend for about 100 km along the western margin of the Central Apennines (Italy). We studied these paleoshorelines by the means of geological and paleontological analyses and new 87Sr/86Sr isotope analyses. The youngest and uppermost paleoshorelines have been detected and mapped through detailed geologic and stratigraphic surveys, which led to the recognition of nearshore deposits, cliff breccias, alignments of Lithophaga borings, fossil abrasion notches and wave-cut platforms. The altitude of these paleoshorelines decreases almost regularly in the NNW–SSE direction from 480 to 220 m a.s.l. Measurements of the 87Sr/86Sr isotope ratio have been conducted on corals and mollusks collected from sediments outcropping close to the paleoshorelines. The isotopic dating results indicate numerical values that range between 0.70907 and 0.70910 all over the 100-km outcrop. These results, together with biostratigraphic data, constrain the age of the youngest paleoshorelines to 1.65–1.50 Ma. These paleoshorelines are thus considered almost isochronous, giving an estimated uplift rate of 0.34–0.17±0.03 mm/a moving from NNW to SSE. Shape, length and continuity of the 100-km-long observed movements indicate that the studied paleoshorelines are an important marker of the Quaternary uplift of the Central Apennines.
    Description: Published
    Description: 487-501
    Description: 3.2. Tettonica attiva
    Description: JCR Journal
    Description: reserved
    Keywords: Early Pleistocene ; shoreline ; uplift ; Apennines ; Sr isotope ; 04. Solid Earth::04.04. Geology::04.04.99. General or miscellaneous
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
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  • 198
    Publication Date: 2017-04-04
    Description: Recent studies provide evidence for a possible imminent change of polarity or an excursion of the geomagnetic field. In this paper we explore the possibility that the present trends are persistent, looking at the behaviour of some physical quantities of the recent geomagnetic field with particular attention to the last century. Analysis of the mean square value of the field over the last 400 years shows a linear decay that if extrapolated will be zero in around 1000 years, while if we extrapolate the field over Antarctica it will go to zero in around 300 years. The information content of the geomagnetic field has been decaying from around 1690, but began to decrease more rapidly at around 1775 and even more rapidly after 1900. An intermittent synchronicity between the exponential field decay and the increase latitudinal speed of the south geomagnetic pole with similar (decaying or growing) timescales can be interpreted as evidence for a present persistent turbulence of the geomagnetic field. From this work it emerges that the present situation is likely to persist further into the future, probably for another century, but longer predictions are not possible.
    Description: Published
    Description: 217-226
    Description: 3.4. Geomagnetismo
    Description: JCR Journal
    Description: reserved
    Keywords: Geomagnetic field ; geomagnetic reversal ; persistent turbolence ; 04. Solid Earth::04.05. Geomagnetism::04.05.02. Geomagnetic field variations and reversals
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
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  • 199
    Publication Date: 2017-04-04
    Description: A new parallel code for the simulation of the transient, 3D dispersal of volcanic particles in the atmosphere is presented. The model equations, describing the multiphase flow dynamics of gas and solid pyroclasts ejected from the volcanic vent during explosive eruptions, are solved by a finite-volume discretization scheme and a pressure-based iterative non-linear solver suited to compressible multiphase flows. The solution of the multiphase equation set is computationally so demanding that the simulation of the transient 3D dynamics of eruptive columns would not be cost-effective on a single workstation. The new code has been parallelized by adopting an ad hoc domain partitioning scheme that enforces the load balancing in the presence of a large number of topographic blocking-cells. An optimized communication layer has been built over the Message-Passing Interface. It is shown that the present code has a remarkable efficiency on several high-performance platforms and makes it possible, for the first time, to simulate fully 3D eruptive scenarios on realistic volcano topography.
    Description: Published
    Description: 541-560
    Description: 3.6. Fisica del vulcanismo
    Description: JCR Journal
    Description: reserved
    Keywords: Message passing interface ; Computational fluid dynamics ; Multiphase flow ; Explosive eruption ; 04. Solid Earth::04.08. Volcanology::04.08.08. Volcanic risk
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
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  • 200
    Publication Date: 2017-04-04
    Description: A new high-resolution Apparent Polar Wander Path (APWP) segment has been obtained from the magnetostratigraphy of four Kimmeridgian to Lower Aptian sections in the Northern Apennines (Italy). The use of paleomagnetic data for determination of the Adria APWP was hampered by the large local rotations linked to Apennine tectonics, characterized by folds and thrusts developed during the Neogene. To overcome this problem, we have computed relative rotations between time overlapping sections and realigned them in a common declination reference frame (namely the Bosso section). We synthesized a new high-resolution 150 to 125 Ma APWP for Adria, which has a similar shape to the time-equivalent segment of the synthetic APWP of Africa of Besse and Courtillot [J., Besse, V., Courtillot, Apparent and true polar wander and the geometry of the geomagnetic field over the last 200 Myr, J. Geophys. Res. 107(B11) (2002), doi:10.1029/200JB000050]. A 26° clockwise rotation of our combined Adria APWP places it in almost perfect overlap with African data of same age, confirming that the Adria promontory moved coherently with Africa during this time span, whereas the counterclockwise rotation of Adria with respect to Africa was introduced later, most probably during Apennines orogenesis. Finally, we discuss in relation with worldwide plate evolution the peculiar shape of our APWP, which displays a hairpin turn during Berriasian time, and dates the main Late Jurassic/Early Cretaceous change in plate motion at around anomaly M16.
    Description: Published
    Description: 329-342
    Description: 3.4. Geomagnetismo
    Description: JCR Journal
    Description: reserved
    Keywords: paleomagnetism ; Apparent Polar Wander Path ; magnetostratigraphy ; Adria ; Italy ; 04. Solid Earth::04.05. Geomagnetism::04.05.06. Paleomagnetism
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
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