ALBERT

Notes: Book reviewed in this article: The Identification of Soils for Forest Management. By Fiona Kennedy.

Notes: Abstract. A no-tillage (NT) system was developed in semiarid Morocco to improve the soil fertility and stabilize yield through conservation of water. Results in two long-term trials (4 and 11 years) were able to show the effects of a no-tillage system in increasing total soil organic matter and total nitrogen. Over time, the quality of the NT soil surface was improved compared with that under conventional tillage (CT) with disc harrows. This effect was the result of an increase in soil organic carbon (SOC) and a slight decline in pH. However, over time, nitrogen decreased in both tillage practices, especially in the 0–25 mm layer (from 0.59 to 0.57 t ha−1 and from 0.44 to 0.42 t ha−1 under NT and CT, respectively). After 4 years of NT an extra 5.62 t ha−1 of SOC was sequestered in the 0–25 mm layer, and after 11 years the SOC increased further to 7.21 t ha−1.

Notes: Book reviewed in this article: Agriculture, Hydrology and Water Quality. By P.M. Haygarth and S.C. Jarvis (Editors).

Notes: Abstract. For an efficient abatement of diffuse N pollution from arable land, it is important to have practical and reliable tools that can quantify the effect of different management practices on leaching, and also analyse the effect of alternative management scenarios aimed at reducing leaching. We present here an application of soilndb, a management-oriented model for quantifying nitrate leaching from arable land. Simulations with soilndb were compared with measurements of pipe-drain discharge of nitrate taken in a 14-year field experiment on a sandy loam soil in south-west Sweden. Following adjustment of parameters connected to litter and faeces decomposition and mineralization, the model gave satisfactory predictions of nitrate leaching for all 10 treatments. The temporal pattern was generally well captured by the model, as was confirmed by high model efficiency values (average = 0.59). This application also supports the model's ability to simulate the long-term influence of different crops and catch crops as well as different manure strategies on leaching. However, further studies should be done to evaluate the model under additional agro-environmental conditions (e.g. soils, climates, and crops).

Notes: Abstract. The Phosphorus Indicators Tool provides a catchment-scale estimation of diffuse phosphorus (P) loss from agricultural land to surface waters using the most appropriate indicators of P loss. The Tool provides a framework that may be applied across the UK to estimate P loss, which is sensitive not only to land use and management but also to environmental factors such as climate, soil type and topography. The model complexity incorporated in the P Indicators Tool has been adapted to the level of detail in the available data and the need to reflect the impact of changes in agriculture. Currently, the Tool runs on an annual timestep and at a 1 km2 grid scale.We demonstrate that the P Indicators Tool works in principle and that its modular structure provides a means of accounting for P loss from one layer to the next, and ultimately to receiving waters. Trial runs of the Tool suggest that modelled P delivery to water approximates measured water quality records. The transparency of the structure of the P Indicators Tool means that identification of poorly performing coefficients is possible, and further refinements of the Tool can be made to ensure it is better calibrated and subsequently validated against empirical data, as it becomes available.

Notes: Abstract. We present a semi-quantitative visual and tactile method for assessing soil physical fertility in terms of soil structure, root growth and soil surface condition. A block of topsoil is dug out with a spade. Horizontal layers (usually 2–4) are then identified as they appear. A brief one-page description of the soil is produced. Using a key, structural and rooting scores are assigned to each soil layer from the appearance of the soil and from its response to tactile assessment. These scores are then combined across depths, with weighting appropriate for the depth of each layer. A separate score was made of soil surface condition. Thus, overall soil physical fertility is assessed as three scores for topsoil structure, rooting and surface condition. The usefulness and sensitivity of the procedure were tested in two ley-arable organic rotation experiments on sandy loams in northeast Scotland.

Notes: Abstract. Eleven precipitated phosphates were evaluated as sources of phosphorus (P) for plant growth by comparing their effectiveness with that of monocalcium phosphate, a source of water soluble P that is generally considered to be fully plant available. The precipitated phosphates comprised struvites recovered from waste water discharges (mainly magnesium ammonium phosphate), laboratory synthesised struvites, a synthetic iron phosphate and a recovered calcium phosphate. Precipitating phosphates in these forms could be a way for removing P from waste water before it is discharged to rivers, so reducing the risk of eutrophication. Application to agricultural land would be one potential use for such phosphates. Evaluation was by pot experiments with a sandy loam soil and with a sandy clay loam soil using perennial ryegrass (Lolium perenne) as the test crop. The soils differed in pH (6.6 and 7.1) and in Olsen P (28 and 11 mg L−1). Measured variables were grass dry matter (DM) yield and grass P concentration which were used to calculate offtake of P in the harvested grass. DM yields of ryegrass and P offtakes given by the synthetic and recovered struvites were not significantly different statistically either between themselves or to MCP applied at the same rate. On this basis these struvites could be used to recycle P to similar soils and the effect of the P on crop yield should be similar to that of MCP

Notes: Abstract. The main inputs, outputs and transfers of potassium (K) in soils and swards under typical south west England conditions were determined during 1999/00 and 2000/01 to establish soil and field gate K budgets under different fertilizer nitrogen (N) (0 and 280 kg ha−1 yr−1) and drainage (undrained and drained) treatments. Plots receiving fertilizer N also received farmyard manure (FYM). Potassium soil budgets ranged, on average for the two years, from −5 (+N, drained) to +9 (no N and undrained) kg K ha−1 yr−1 and field gate budgets from +23 (+N, drained) to +89 (+N, undrained). The main inputs and outputs to the soil K budgets were fertilizer application (65%) and plant uptake (93%). Animals had a minor effect on K export but a major impact on K recycling. Nitrogen fertilizer application and drainage increased K uptake by the grass and, with it, the efficiency of K used. It also depleted easily available soil K, which could be associated with smaller K losses by leaching.

Notes: Abstract. Crops on sandy soils (〈5% clay) are exposed to K deficiency due to the small release and high leaching losses of K. Reliable tools are needed to improve the K management in cropping systems with limited K input, such as organic farming where import of nutrients are restricted according to the EC regulations. We investigated K balances and exchangeable K (Kexch) changes in an organic crop rotation experiment. Potassium leaching decreased from 42 kg ha−1 in 1998/99 to 21 kg ha−1 in 2000/01 as an average of a crop rotation (spring barley, grass-clover, winter wheat and pea/barley) with manure application and without catch crops. In the same period, spring Kexch decreased from 5.0 to 3.0 mg K 100 g soil−1 (0–20 cm). The retention of the straw K left in the field after harvest increased with decreasing levels of Kexch. The cereal crops did not respond to K application but in the pea/barley mixture the pea yield increased by 46%. The concordance between measured K balances and changes in Kexch was weak. Exchangeable K is suitable as a tool for K management on a rotational basis, and a Kexch above 3 mg 100 g soil−1 in the autumn should be avoided to minimize K leaching.

Notes: Abstract. Diagnosis of soil salinity and its spatial variability is required to establish control measures in irrigated agriculture. This article shows the usefulness of electromagnetic (EM) and soil sampling techniques to map salinity. We analysed the salinity of a 1-ha plot of surface-irrigated olive plantation in Aragon, NE Spain, by measuring the electrical conductivity of the saturation extract (ECe) of soil samples taken at 22 points, and by reading the Geonics EM38 sensor at 141 points in the horizontal (EMH) and vertical (EMV) dipole positions. EMH and EMV values had asymmetrical bimodal distributions, with most readings in the non-saline range and a sharp transition to relatively high readings. Most salinity profiles were uniform (i.e. EMH=EMV), except in areas with high salinity and concurrent shallow water tables, where the profiles were inverted as shown by EMH 〉 EMV, and by ECe being greater in shallow than in deeper layers. The regressions of ECe on EM readings predicted ECe with R2 〉 84% for the 0–100 to 0–150 cm soil depths. We then produced salinity contour maps from the 141 ECe values estimated from the electromagnetic readings and the 22 measured values of ECe. Owing to the high soil sampling density, the maps were similar (i.e. mean surface-weighted ECe values between 3.9 dS m−1 and 4.2 dS m−1), although the electromagnetically estimated ECe improved the mapping of details. Whereas soil sampling is preferred for analysing the vertical distribution of soil salinity, the electromagnetic sensor is ideal for mapping the lateral variability of soil salinity.

Notes: Abstract. The effects of soil management on soil losses from olive plantations in southern Spain were evaluated using the Revised Universal Soil Loss Equation (RUSLE), a review of published experiments, and preliminary results of an on-going field trial. Experimental data were used to parameterize the RUSLE for olive orchards under various soil management regimes. The predictions agreed qualitatively with the data available, and the model provided a simple way to assess the effects of soil management on erosion. Our results showed that no-tillage caused the greatest soil loss, while cover crops showed the least. Tillage and planting following contours proved only partially effective and did not reduce soil erosion as much as protective crops. One scenario studied suggests that, on slight to moderate slopes, land transformed from row crops to olive orchards may remain below the maximum tolerable soil erosion limit, if a cover crop is included between the trees. A scenario for marginal olive orchards located on steep slopes suggests that effective erosion control could only be achieved with a cover crop system that would have the side-effect of reducing the yield of rain-fed olives. Quantifying the effects of soil management on soil erosion in olive orchards is uncertain because very few experimental results are available. Further research that monitors soil loss in carefully selected long-term experiments at different scales and follows the changes in key soil parameters is urgently required to develop effective erosion control policies.

Notes: Abstract. Rainfall simulation experiments on a laboratory soil flume were conducted to test the hypothesis that the incorporation of slurry into the soil would reduce bacterial transport in overland flow. Presumptive faecal coliform (PFCs) concentrations were higher in the runoff from the surface applied treatment than from the incorporated treatments. The transport of PFCs and organic sediment were strongly correlated, with values of r ranging from 0.72 to 0.91.

Notes: Abstract. Land evaluation is the prediction of land performance over time under specific uses, to guide strategic land use decisions. Modern land evaluation has a 30 year history, yet the results have often been disappointing. Land users and planners have been reported to ignore land evaluations, perhaps reflecting poor quality, low relevance, or poor communication. To test the success of a large land evaluation exercise undertaken as part of micro-catchment project in Santa Catarina State, southern Brazil, we queried agricultural extensionists, considered as the primary land evaluation clients. We used a questionnaire with both structured and open questions, to determine their experiences with, and attitudes to, the current land evaluation method. The soil resource inventory and associated land evaluation had some usefulness, but were not in general used for their intended purpose, namely farm planning. This was mainly because they did not contain crucial information necessary to such planning in the actual context of the farmer taking decisions. The primary deficiencies were identified as:〈list xml:id="l1" style="custom"〉1no estimate of environmental degradation risk;2no financial analysis;3no social analysis of decision-makers' attitudes and preferences;4no risk assessment for weather, yields, profits and market; and5insufficiently-specific alternative land uses.These deficiencies could have been avoided with a demand-driven approach, evaluating and reporting according to the true needs and opportunities of the decision-makers.

Notes: Abstract. The residual value of mineral N fertilizer applied in the spring was investigated in a field experiment where four cereals (winter wheat, winter barley, spring barley and spring oats) had been grown at reduced (0.7N), normal (1N) or high (1.3N) N fertilizer rates for 20 to 28 years. The effect of previous N fertilizer dressing was tested in two succeeding years by replacing the original N rate with five test N rates ranging from 0 to 240 kg N ha−1 for winter cereals and 0 to 200 kg N ha−1 for spring cereals. In the first test year, winter wheat grown on plots previously supplied with the high rate of mineral fertilizer (202 kg N ha−1 yr−1) yielded more grain and straw and had a higher total N uptake than wheat on plots previously supplied with the normal (174 kg N ha−1 yr−1) or reduced (124 kg N ha−1 yr−1) rate. The grain yield response and N uptake was not significantly affected by the N supply in the test year. The winter wheat grown in the second test year was unaffected by the previous N supply. Grain and straw yield response and total N uptake for spring barley, winter barley and oats, were almost identical irrespective of the previous N rate.After 20 to 28 years there were no significant differences in soil C and N (0 to 20 cm) between soil receiving three rates of N fertilizer. Soil from differently fertilized oat plots showed no significant differences in N mineralizing capacity. Nitrate leaching losses from the soils at the three N rates were estimated and the N balances for the 20 to 28 years experimental period calculated. The data indicated a reduction in overall loss of 189 to 466 kg N ha−1 at the normal and high N rates compared with the reduced N rate. We conclude that the N supplying capacity and soil organic matter content of this fertile sandy loam soil under continuous cereal cropping with straw removal was not significantly affected by differences in N fertilizer residues.

Notes: Abstract. A field experiment was undertaken to assess the effectiveness of a combined treatment, involving addition of Aspergillus niger-treated sugar beet (SB) residue in the presence of rock phosphate and mycorrhizal inoculation of seedlings with Pisolithus tinctorius. The aim was to improve the physical, chemical, biochemical and biological properties of a degraded semiarid Mediterranean soil. Short-term effects of such improvements on the establishment of Cistus albidus L. seedlings were evaluated. Eight months after planting, macronutrients (NPK), total carbohydrates, water-soluble C, water-soluble carbohydrates, microbial biomass C and enzyme activities (dehydrogenase, urease, protease, acid phosphatase and β-glucosidase) measured in the rhizosphere soil of C. albidus were increased greatly by addition of fermented SB residue. Soil structural stability improved only with the fermented SB addition (about 79% higher in the amended soils than in the non-amended soils). The mycorrhizal inoculation was the most effective treatment in improving the growth of C. albidus plants, but only slightly improved soil quality. Growth of inoculated plants was about 33% greater than plants grown in the amended soil and about 131% greater than control plants. The combined benefit of mycorrhizal inoculation of seedlings and addition of fermented SB residue to soil on plant growth was similar to that of the treatments applied individually.

Notes: Abstract. Organic agriculture (OA) aims to identify a production regime that causes less environmental problems than conventional agriculture (CA). We examined whether the two systems differ in their susceptibility to soil erosion by water. To account for the large heterogeneity within the rotations practised on different farms, we chose a statistical evaluation which modelled erosion using the USLE method from the cropping statistics for 2056 districts in Bavaria (70 547 km2; 29.8% arable). Physical conditions of erosion were determined in a rectangular grid yielding 13 125 grid-cells of c. 5 km2 each. For validation, erosion was measured in 10 sub-watersheds on two neighbouring OA and CA farms over 8 years (287 erosive events). On average, about 15% less erosion on arable land was predicted for OA than for CA due to the larger area of leys, although OA occupies areas that are susceptible to erosion more often than CA. The same conclusions could be drawn from the validation data. These data also demonstrated that erosion could be reduced considerably below 1 t ha−1 yr−1 with best management practices under both farming systems. In contrast, at the countrywide scale, cropping did not change adequately with site conditions favouring erosion. The need for erosion control seems not to influence crop rotation decisions on erosion-prone sites.

Notes: Abstract. The effects of various fallow management systems and cropping intensities on water infiltration were measured on an Alfisol at Ibadan in southwestern Nigeria. The objective was to determine the influence of the land use systems (a combination of crop–fallow sequences and intercropping types) on soil hydraulic properties obtained by disc permeameter and double-ring infiltration measurements. The experiment was established in 1989 as a split-plot design with four replications. The main plots were natural fallow, planted Pueraria phaseoloides and planted Leucaena leucocephala. The subplots were 1 year of maize/cassava intercrop followed by 3-year fallow (25% cropping intensity), or 2-year fallow (33% cropping intensity), or 1-year fallow (50% cropping intensity), or no fallow period (100% cropping intensity). Water infiltration rates and sorptivities were measured under saturated and unsaturated flow. Irrespective of land use, infiltration rates at the soil surface (121–324 cm h−1) were greater than those measured at 30 cm depth (55–144 cm h−1). This indicated that fewer large pores were present below 30 cm depth compared with 0–30 cm depth. Despite some temporal variation, sorptivities with the highest mean value of 93.5 cm h−½ increased as the cropping intensity decreased, suggesting a more continuous macropore system under less intensive land use systems. This was most likely due to continuous biopores created by perennial vegetation under long fallow systems. Intercropped maize and cassava yields also increased as cropping intensity decreased. The weak relationship between crop yields and hydraulic conductivity/infiltration rates suggests that the rates were not limiting.

Notes: Abstract. Hierarchical crop growth models can contribute significantly to land quality research because the yield gap between the estimated optimum and the actual crop production has been identified as a major land quality indicator. This study describes a three-level, hierarchical crop production model, simulating radiation-thermal, water-limited and natural production potentials of annual crops. Input requirements have been kept low to ensure its applicability to developing regions, which often have access only to limited data. The simplicity of this model also has disadvantages: inconsistencies have been reported when applying this model in semiarid regions, which are characterized by very irregular rainfall patterns. Revision of the water balance, which simulates the availability of water, was required. The modified model was validated using the experimental yields of maize and sunflower in Guquka, a semiarid region of South Africa. Yields were estimated very well, possible improvements to crop production were identified and implications for land-use planning highlighted. Yield gap analysis revealed that radiation, sunshine and temperature are favourable for crop production, but the heavy dependence on rainfall makes the region very vulnerable to drought, with devastating impact on yields. The generally low chemical soil fertility further reduces crop performance.

Notes: Abstract. A potential technique for reducing overwinter leaching from high N containing crop residues is to immobilize the N released during decomposition by co-incorporating materials of a wider C : N ratio. This article describes the use of laboratory incubation experiments to investigate the effects of a wide range of such amendment materials on the mineralization of N from sugar beet and brassica leaf residues in a sandy loam and a silt loam. These materials were of varying quality, with C : N ratio ranging from 15 : 1 to 520 : 1, and cellulose content from 0 to 34%. Amendments were added at a fixed rate of 3.5 mg C g−1 of dry soil, equivalent to around 10 t ha−1 C (to 20 cm depth). The soils were then incubated at 15°C, and net mineral N derived from the leaves was measured at regular intervals over 168 days. Net mineralization of residue N was greatest with molasses (C : N ratio of 18 : 1), whereas paper waste (C : N ratio of 520 : 1) reduced N mineralized by up to 90% compared with a soil-only control. As the concentration of cellulose and lignin in the amendment materials increased, so the amounts of N mineralized decreased, with 62 and 54% of variance in N mineralized explained by cellulose and lignin content, respectively. Reduced levels of mineral N were associated with higher levels of biomass-N. The levels of N2O-N lost from sugar beet residues on day 14 were significantly reduced from 66 to 5 g ha−1 where compactor (cardboard) waste had been mixed into sandy loam, but this effect was not observed in the silt loam. These techniques could lead to greater efficiency of N use in rotations through reduction in N losses, and provide alternative routes for disposal of wastes when the EC Landfill Directive is implemented.

Notes: Abstract. The Olsen method is an indicator of plant-available phosphorus (P). The effect of time and temperature on residual phosphate in soils was measured using the Olsen method in a pot experiment. Four soils were investigated: two from Pakistan and one each from England (calcareous) and Colombia (acidic). Two levels of residual phosphate were developed in each soil after addition of phosphate by incubation at either 10 °C or 45 °C. The amount of phosphate added was based on the P maximum of each soil, calculated using the Langmuir equation. Ryegrass was used as the test crop. The pooled data for the four soils incubated at 10 °C showed good correlation between Olsen P and dry matter yield or P uptake (r2= 0.85 and 0.77, respectively), whereas at 45 °C, each soil had its own relationship and pooled data did not show correlation of Olsen P with dry matter yield or P uptake. When the data at both temperatures were pooled, Olsen P was a good indicator of yield and uptake for the English soil. For the Pakistani soils, Olsen P after 45 °C treatment was an underestimate relative to the 10 °C data and for the Colombian soil it was an overestimate. The reasons for these differences need to be explored further before high temperature incubation can be used to simulate long-term changes in the field.

Notes: Abstract. Nitrous oxide (N2O) from animal excreta in grazed pasture systems makes up a significant component (c. 10%) of New Zealand's total greenhouse gas inventory. We report an effective method to decrease N2O emissions from animal urine patches by treating the soil with the nitrification inhibitor dicyandiamide (DCD), in a simulated grazed dairy pasture system under spray irrigation. The soil was a free-draining Lismore stony silt loam (Udic Haplustept loamy skeletal) and the pasture was a mixture of perennial ryegrass (Lolium perenne) and white clover (Trifolium repens). By treating the soil with DCD, N2O emissions were decreased by 76% following urine application in the autumn, from 26.7 kg N2O-N ha−1 without DCD to an average of 6.4 kg N2O-N ha−1 with DCD over the 6-month experimental period. N2O flux was decreased by 78% following urine application in the spring, from 18 kg N2O-N ha−1 without DCD to 3.9 kg N2O-N ha−1 with the application of DCD over the 3-month period. A single application of DCD immediately after urine was sufficient to effectively mitigate N2O emissions from the urine. The results showed that repeated applications of DCD after urine application, or mixing DCD with urine, offered no advantage over a single application of DCD immediately after urine deposition.

Notes: Abstract. Pig slurry was applied by open-slot injection to experimental plots on a sandy loam site at ADAS Gleadthorpe, Nottinghamshire. Volume and distribution of over-winter drainage were adjusted through the use of rainfall exclusion covers or irrigation. The resultant slurry N leaching over the range of drainage values tested (up to 300 mm) could be satisfactorily described by curve-fitting, using a quadratic or exponential function. Initial simulations of slurry N leaching using the manure nitrogen decision support system manner (v. 3.0) compared poorly with the experimental data, predicting both earlier and greater amounts of nitrate leaching. However, the lack of fit could be explained by consideration of the likely ammonia emissions following slurry injection, the actual volumetric soil moisture capacity at the experimental site and the likely time delay for the nitrification of slurry N following application. Good agreement between modelled and observed data was achieved when these factors were taken into account. The manner model was used to simulate nitrate leaching beyond the range of drainage treatments tested in the experiments and the anticipated sigmoidal relationship between nitrate leaching and drainage was observed. The model was then used to study the effects of manure application timing and the likely impact on nitrate leaching, across the range of rainfall conditions found in Great Britain. Simulations for a range of manure types were undertaken, with manures applied at rates up to the limit of permitted N loading on freely draining sandy loams. Rainfall inputs for these simulations were based on long-term average climatic data. Results are presented for two contrasting manure types, cattle slurry and poultry manure, both of which are subject to controls in Nitrate Vulnerable Zones (NVZs) in Great Britain.

Notes: Abstract. As measures to reduce point source inputs of phosphorus (P) to water have been introduced, the effect of diffuse P has become more evident. Land drains can act as an effective conduit for transfer of sediment and sediment P from agricultural land to surface waters. This article describes the development of a national risk map, identifying areas of agricultural land in England and Wales that are most likely to be prone to such losses. The map is based on data obtained from a variety of sources, including field studies, laboratory-based rainfall simulation experiments and secondary sources. From these studies, eight factors relating to soil HOST class, rainfall, soil moisture deficit, land use and the type and condition of land drains were identified as influential in the process of sediment and sediment P transfer. Each factor was weighted to provide an estimate of risk and the combined total was used to plot a national risk estimate at a resolution of 25 km2. The exercise suggests that large areas of England and Wales may be at risk of subsurface sediment and sediment P transfer from agricultural land to rivers. The scale of the map is insufficient for planning at the farm level, but further work incorporating similar data and principles could make it more applicable to potential end-users on the ground.

Notes: Abstract. Detailed morphological, physical, chemical, mineralogical and micromorphological studies were carried out to identify properties that influence the yield of deep-rooted crops in 29 Vertisols of semiarid central India, since existing land evaluation methods are not adequate to explain the yield of cotton obtained by farmers. The studies indicated that among the soil parameters, CaCO3 in the clay fraction, the exchangeable Ca/Mg ratio, exchangeable sodium percentage (ESP) and saturated hydraulic conductivity (HC) were the yield-influencing factors. The pedogenetic relationships between the semiarid climate, formation of pedogenic calcium carbonate, exchangeable Ca/Mg, ESP and HC have been established. In view of the pedogenetic processes that ultimately impair the drainage of soils, evaluation of Vertisols for deep-rooted crops on the basis of HC alone may help in planning and management of soils, not only in the Indian semiarid tropics, but also in similar climatic areas elsewhere.

Notes: Abstract. Water retention properties of 219 horizons were measured in Cambisols, Luvisols and Fluvisols, mainly from the Paris basin. We derived class pedotransfer functions (class PTFs) based on texture alone and in a second stage class PTFs based on classes combining texture and clod bulk density. The performance of these two types of PTFs were discussed at −330 and −15000 hPa water potential on an independent set of 221 horizons. Results showed that PTFs based on sets grouped by texture and clod bulk density provide estimates with an accuracy that is (i) greater than with class PTFs based on texture alone, and (ii) similar to the estimation accuracy recorded with continuous PTFs. As a consequence, the lack of interest in class PTFs should be reconsidered to bridge the gap between the available basic soil data and hydraulic properties which are generally missing, particularly when pertinent soil characteristics can be derived from the data available in soil databases. The two types of class PTFs providing gravimetric water contents at seven water potentials ranging from −10 to −15 000 hPa were converted to volumetric water content using the soil bulk density. Finally, the parameters of van Genuchten's water retention curve model were computed for every class PTF.

Notes: Abstract. Soils can be used as a biospheric sink for carbon under Article 3.4 of the Kyoto Protocol and parties are able to use agricultural soil carbon sinks to contribute towards carbon emission reduction targets. This should be done ‘taking into account uncertainties, transparency in reporting, and verifiability’. Models are often tested against data sets of long-term changes in soil organic carbon (SOC), but most data sets have only mean SOC values available at each sample date, with no estimates of error about the mean. We show that when using data sets that do not include estimates of error about the mean, it is not possible to reduce the error (root mean squared error) between modelled and measured values below 6.8–8.5%, even with site-specific model calibration. Equivalent errors for model runs using regional default input values are 12–34%. Using error as an indicator of the certainty that can be attached to model projections, we show that a significant reduction in uncertainty is needed for Kyoto accounting. Uncertainties for modelling during the first Kyoto Commitment Period could be reduced by better replication of soil measurements at benchmark sites. This would allow model error to be separated from measurement error, which would allow more comprehensive model testing and, ultimately, more certainty to be attached to model predictions.

Notes: Abstract. Artificial urine containing 20.2 g N per patch of 0.2 m2 was applied in May and September to permanent grassland swards of a long-term experiment in the western uplands of Germany (location Rengen/Eifel), which were fertilized with 0, 120, 240, 360 kg N ha−1 yr−1 given as calcium ammonium nitrate. The effect on N2O fluxes measured regularly during a 357-day period with the closed-chamber technique were as follows. (1) N2O emission varied widely among the fertilized control areas without urine, and when a threshold water-filled pore space 〉60% was exceeded, the greater the topsoil nitrate content the greater the flux from the individual urine patches on the fertilized swards. (2) After urine application in May, 1.4–4.2% of the applied urine-N was lost as N2O from the fertilized swards; and after urine application in September, 0.3–0.9% of the applied urine-N was lost. The primary influence on N2O flux from urine patches was the date of simulated grazing, N-fertilization rate being a secondary influence. (3) The large differences in N2O emissions between unfertilized and fertilized swards after May-applied urine contrasted with only small differences after urine applied in September, indicating an interaction between time of urine application and N-fertilizer rate. (4) The estimated annual N2O emissions were in the range 0.6–1.6 kg N2O-N per livestock unit, or 1.4, 3.6, 4.1 and 5.1 kg N2O-N ha−1 from the 0–360 kg ha−1 of fertilizer-N. The study demonstrated that date of grazing and N-fertilizer application could influence the N2O emission from urine patches to such an extent that both factors should be considered in detailed large-scale estimations of N2O fluxes from grazed grassland.

Notes: Abstract. We studied the effects of five diverse non-agricultural organic wastes on soil composition, grass yield and grass nitrogen use in a 3–year field experiment. The applied wastes were distillery pot ale, dairy salt whey, abattoir blood and gut contents, composted green waste (two annual applications each), and paper-mill sludge (one annual application). With the exception of N immobilization in the paper-mill sludge treatment, the wastes had no unfavourable effects on the soil. In the 2–year treatments, grass dry matter yields from the abattoir and distillery wastes (26.3 t ha−1) were larger than those from a NH4NO3 fertilizer treatment (24.3 t ha−1) and from the dairy waste (20.4 t ha−1) and composted waste (22.8 t ha−1). Yield and N recovery were impaired markedly after the single application of paper-mill sludge, both in the year of application and in the following year. The results demonstrated clear differences in the ability of the applied wastes to provide crop-available N. We conclude that in order to improve prediction of both the benefits and risks from waste recycling to land, more information should be gathered on soil/waste/crop interactions.

Notes: Abstract. A laboratory study was conducted to investigate the effects of adding an intermediary byproduct of olive oil extraction (alperujo or solid olive-mill waste, SOMW) on the sorption, degradation and leaching of the herbicide simazine in a sandy loam soil. The effect of SOMW addition on soil porosity was also assessed. The soil was amended in the laboratory with SOMW at two different rates (5% and 10% w/w). Simazine sorption isotherms showed a great increase in herbicide sorption after SOMW addition to soil; sorption increased with the amount of SOMW added. Incubation studies showed extended persistence by reduced biodegradation of simazine in the soil amended with SOMW compared with the unamended soil. Although the addition of SOMW to soil increased the total porosity, breakthrough curves of simazine in handpacked soil columns showed that SOMW addition retarded the vertical movement of the herbicide through the soil and reduced the total amount of herbicide leached. It appeared that the longer residence time of simazine in the amended soil columns (〉20 days) compared with that in the unamended soil column (〈20 days) allowed enhanced degradation and/or irreversible sorption under column leaching conditions. The results revealed important changes in herbicide behaviour upon SOMW addition, confirming the need to assess these changes in order to optimize the combined use of organic wastes and soil-applied pesticides.

Notes: Abstract. Jute geotextiles are widely used to stabilize steep banks and road cuttings. Jute protects bare surfaces until seeded grass becomes established, then after several years, the jute decays. To evaluate two types of jute geotextiles, eight erosion plots were established in July 1994 at the Hilton Experimental Site, Shropshire, UK. On 10 April 1995, the plots were treated as follows:〈list xml:id="l1" style="custom"〉1jute geotextile net;2jute mat;3perennial rye grass (Lolium perenne); and4bare soil, with duplicates of each treatment.Over one year, sediment yields from jute net and jute mat were 1.1% and 1.2%, respectively, of the yield from the bare control. Although both had similar soil protection qualities, runoff was very different. The runoff from the jute net was 35% and the jute mat 247% of the control. Results demonstrate the effectiveness of jute net for erosion and runoff control, while the jute mat may both conserve soil and ‘harvest’ rain or redirect runoff.

Notes: Abstract. A predictive model of metal concentrations in crops was developed to optimize soil liming and sludge application strategies at a dedicated sewage sludge disposal site. Predictions of metal concentrations in plant tissue were derived from measured values of soil metal concentration, humus content and soil pH. The plant and soil data used to parameterize the model were collected on site using quadrat sampling of mature crop and underlying topsoil. The uptake model was used to map predicted metal concentrations in wheat grain and forage maize based upon a database of soil characteristics (metal content, % humus and pH) measured as part of a routine geochemical survey of the site. The effect of a management strategy to modify uptake of Cd by wheat by changing soil pH was investigated. The effect of soil dust adhering to maize plants at harvest was also simulated to investigate the importance of this pathway for Cd transfer to animal feed such as silage.The model gave satisfactory predictions for uptake of Cd and Zn but less useful simulations for Pb, Cu and Ni. The results for Cd uptake showed a greater dependence on soil pH in the case of wheat in comparison to maize. It is suggested that, for the study site, liming to pH 7.0 will reduce Cd concentrations in wheat grain to within EC legal standards. However the Cd content of maize may still exceed these guidelines, with a relatively minor contribution from contamination with soil dust.

Notes: Abstract. The transfer of suspended sediment (SS) and phosphorus (P) in overland flow from 30 m2 field plots receiving either nil, surface-applied or incorporated manure (slurry) were monitored to determine the vulnerability of land cropped to continuous forage maize to diffuse pollutant transfer in winter runoff. In the absence of slurry, P export was dominated by particulate forms, with up to 1 t SS ha−1 and 0.75 kg total P ha−1 collected from an individual storm event. Background concentrations of P in soluble (〈0.45 μm) form were large (c. 0.5 mg L−1) by eutrophication standards due to the previous build-up of soil P, and largely independent of SS concentrations. Largest P exports (representing up to 23% of the slurry P applied) were measured when dairy slurry (3–13% dry solids) was surface-applied. The P mobilized from the slurry accounted for up to 60% of total plot P export, with the majority occurring in a soluble bioavailable form during the first storm event. Initial P concentrations in runoff were in proportion to the amount of slurry P applied and significantly lower where rainfall was delayed after application. In one year, splitting the slurry application (3 × 10 kg ha−1) reduced total P export by 25% compared to a single surface application (30 kg P ha−1). In two years, incorporation of slurry, either by ploughing, or by tine cultivation, reduced the amount of overland flow by 50%, and the amount of P export by up to 60%, compared to the surface-applied slurry treatments. Timeliness of slurry spreading to avoid periods of wet weather and simple cultivation of maize fields after harvest are practical and effective options to minimize SS and P transfer in land runoff from maize fields. The results also draw attention to the need to grow maize, and apply slurry to fields with a low P loss risk.

Notes: Abstract. To determine the effects of low-input agriculture on soil properties, we compared several forms of arable land management in a rotation experiment lasting 8 years on a Cambisol in Lithuania. Conventional arable cropping with applications of inorganic fertilizers increased the potassium (K) status of the soil, but resulted in losses of nitrogen (N) from the soil by mineralization and leaching. With ley–arable integrated cropping, a similar fertilizer regime based on farmyard manure (FYM) augmented with inorganic fertilizers increased the phosphorus (P), K, organic matter and N in the soil, as well as increasing N loss by leaching. These two high-input regimes were compared to three systems with less or no input. A reference treatment with no input, which produced small crop yields, maintained its nutrient status and organic matter. An organic regime receiving FYM and green manure lost only P, but maintained its K and N status, while a second organic regime in which the FYM was replaced by composted sewage maintained its fertility. The microbial activity varied somewhat from treatment to treatment, with the largest numbers of almost all groups of microorganisms in the reference treatment. All treatments led to decreases in fulvic acid, and the soil managed conventionally lost humic acid, too. The content of humic acid increased in the treatments where FYM was applied and in the reference soil, and the fraction bound to calcium increased in the integrated and the first organic treatments. The soil structures under the integrated cropping and second organic regime were the most stable. Of the low-input systems, the second organic regime seemed the most sustainable.

Notes: Abstract. Emissions of N2O were measured after application of NH4NO3 fertilizer and incorporation of winter wheat and rye green manures in two field experiments in southeast England. Incorporation of green manure alone resulted in temporary immobilization of soil N, small N2O emissions and also low availability of N for the following crop. Emissions were increased after application of inorganic fertilizer, and were further increased from integrated management treatments whereby green manure residues were incorporated after fertilizer application. The highest emission was from the incorporated winter wheat green manure plus fertilizer treatment, with 1.5 kg N2O-N ha−1 (0.6% of N applied) being emitted over the first 55 days after incorporation. This high emission was attributed to the supply of C in the residues providing the energy for denitrification in the presence of large amounts of mineral N and the creation of anaerobic microsites during microbial respiration.

Notes: Abstract. Soil compaction has long been considered to be a problem in arable land, primarily because it causes damage to soil structure, which can lead to serious reduction in crop yields. However, few studies have sought to investigate the effects of soil compaction on the water transport regime of modified soil pore systems. We attempted to quantify the effects of soil compaction on the initiation of preferential flow by using dye tracers and image analysis. A laboratory methodology involving rainfall simulation enabled us to quantitatively evaluate differences in the mechanisms of water flow between two soil types at several degrees of compaction. The results suggested significant differences in the types of water flow pathways between clay loams and sandy loams at different extents of compaction. In the sandy loam, it was concluded that a high degree of compaction led to an increased likelihood of preferential flow, whereas a more uniform movement of soil water occurred at less compaction. By contrast, preferential routing of soil water was recorded in the clay loam, except at the highest measured compaction. The results indicate that the visual techniques of dye tracing and image analysis could enable improved understanding of flow pathways of soil water associated with soil compaction.

Notes: Abstract. Annual methane fluxes from an organic soil in eastern Finland, originally drained and planted with birch (Betula pendula) and then later cultivated, were studied for two years using a chamber technique. The agricultural soils growing grass or barley or without vegetation, generally acted as sinks for CH4. Surprisingly, the agricultural soils emitted CH4 during a warm dry summer. The CH4 oxidation capacity and CH4 uptake rate of the forested site was three times that of agricultural soils. Also, the forest soil better retained its capacity to take up CH4 during a dry summer. Despite periods of CH4 emission, the agricultural soils were annual sinks for CH4, with uptake rate of CH4-C varying from 0.1 to 3.7 kg ha−1 yr−1. The forested soil had a methane uptake rate of 3.9 kg CH4-C ha−1 yr−1. All the soils acted as sinks for CH4 during winter, which contributed up to half of the annual CH4 uptake. The capacity of soils to transport gases did not explain the larger CH4 uptake rate in the forest soil. At the same gas filled porosity, the forest soil had a much larger CH4 uptake rate than the agricultural soil. Neither the soil acidity (pH 4.5 and 6.0) nor high ammonium content appeared to limit CH4 uptake. The results suggest that CH4 oxidation in agricultural organic soil is more sensitive to soil drying than CH4 oxidation in forested organic soil.

Notes: Abstract. A study was conducted to assess the impact of agricultural land use history on macro-aggregate (4.0–4.8 mm) stability in the 0–5 cm layers of Chromic and ‘Hydromorphic’ Vertisols in north Cameroon. Macroaggregate stability to water drop impact was determined and the ASI50 index calculated. Macroaggregates from fallow and zero-tilled cropped soils disaggregated in a stepwise manner. Macroaggregates from ploughed cropped soils collapsed in one step into semi-liquefied microaggregates and primary particles. On both soil types, the ASI50 index of samples from ploughed land was 10.0 mJ, compared to 16.4– 21.9 mJ from zero-tilled slash and burn land use. The stepwise disintegration of macroaggregates indicated the existence of a hierarchy of aggregation within the size range 2–5 mm. Slash and burn land use on zero-tilled Vertisols significantly increased sand-sized organic carbon content and the stability of macroaggregates to water impact.

Notes: Abstract. Field experiments were carried out to evaluate the relative efficacy of organic manures in improving the productivity and pest tolerance of rice growing in a lateritic soil. The effects of three commercial manures: processed city waste (PCW), vermicompost (VC) and oil cake pellets (OCP), were assessed in comparison to farmyard manure (FYM) and inorganic fertilizer all at the same total N applied. Of the organic manures tested, FYM produced the maximum straw and grain yields. Differences in yield among the organic manure treatments were mainly attributed to variation in the amounts of available N, P, K and micronutrients. Effect of manures on soil physical condition was not studied. The uptake of N, P and K by rice plants with FYM was significantly greater than all other commercial manures and inorganic fertilizer. The tolerance of rice plants to attack by pathogens and pests, measured in terms of grain yield was highest in the treatment with FYM. Among the commercial manures PCW showed the greatest promise and emerged as a potential alternative to FYM.

Notes: Abstract. Restoration of landfill sites to a vegetated after-use is severely compromised if soil-forming materials (SFMs) have to be used as substitute growing media for the restoration cap, owing partly to their poorly-developed structure. The effects of crushed brick material (brick), composted green-waste organic matter (OM) and potassium chloride salt (KCl) in a clay SFM were assessed at the Brogborough Landfill Site (Shank Group plc) in the county of Bedfordshire, UK. Soil structure was characterized three times in a two-year experimental period through measuring drainage water release and aggregate stability and size distribution. Crushed brick and composted OM at 100 t ha−1 improved the ability of the clay to release water by drainage. In addition, the composted OM was associated with an increase in the size of stable aggregates, whereas the brick amendment reduced the overall aggregate stability. The KCl amendment had no consistent effect. Some beneficial structural improvements were thus associated with the brick and OM amendments, although these were rarely significant at the 5% level and the effects declined over time in the absence of vegetation and re-application. Nevertheless, incorporation of crushed brick and organic amendments may offer a potential structure-improving option in clay SFMs prior to vegetation establishment.

Notes: Abstract. We examined the effect on soil nutrient status and sustainability of water percolation through an irrigated paddy field in Japan, to the depth of drainage (40 cm). The difference between amounts of nutrients leached by percolation and those supplied by irrigation indicated that 25–130 kg ha−1 Ca, 8–24 kg ha−1 Mg, from −1 to 9 kg ha−1 K, and 8–17 kg ha−1 Fe, respectively, were lost each year from the 0–40 cm soil layer during rice cultivation, when the supply from fertilization and rainfall and the loss in grain harvest were not accounted for. When the supply of K from rainfall and the loss in grain harvest were taken into account, a total K loss of about 10 kg ha−1 was estimated. The electrical neutrality of inorganic ions in the percolating water was always maintained. From these results we estimate that the amounts of exchangeable Ca and Mg in the soil to a depth of 40 cm would decrease by 50% within 50–260 and 30–100 years, respectively, if similar management were continued without fertilization. The total amount of carbon dioxide (ΣCO2) leached in percolating water during the period of rice cultivation was 120–325 kg C ha−1, which corresponded to 0.47–0.94% of the soil organic carbon to 40 cm depth.

Notes: Abstract. Use of high biomass crops such as the willow Salix viminalis to extract metals for soil remediation has been proposed as an alternative to the low biomass-producing hyperaccumulating plants. High yields compensate for the moderate heavy-metal concentrations in the shoots of such species. We report the first long-term trials using Salix viminalis to extract heavy metals from two contaminated soils, one calcareous (5 years) and one acidic (2 years). Total metals extracted by the plants were 170 g Cd ha−1 and 13.4 kg Zn ha−1 from the calcareous soil after 5 years, and 47 g Cd ha−1 and 14.5 kg Zn ha−1 from the acidic soil after 2 years; in the first year outputs were negligible. After 2 years, Salix had performed better on the acidic soil because of larger biomass production and higher metal concentrations in shoots. Addition of elemental sulphur to the soil did not yield any additional benefit in the long term, but application of an Fe chelate improved the biomass production. Cd and Zn concentrations were significantly higher in leaves than stems, highlighting the necessity to collect leaves as well as shoots. On both soils, concentration in shoots decreased with time, indicating a decrease in extraction efficiency.

Notes: Abstract. This study was undertaken to test the hypothesis that an improved system of catchment management in combination with appropriate cropping practices can sustain increased crop production and improve soil quality of Vertisols, compared with prevailing traditional farming practices. Initiated in 1976, the improved system consisted of integrated land management to conserve soil and water, with excess rainwater being removed in a controlled manner. This was combined with improved crop rotation (legume based) and integrated nutrient management. In the traditional system, sorghum or chickpea was grown in the post-rainy season with organic fertilizers, and in the rainy season the field was maintained as a cultivated fallow. The average grain yield of the improved system over 24 years was 4.7 t ha−1 yr−1, nearly a five-fold increase over the traditional system (about 1 t ha−1 yr−1). There was also evidence of increased organic C, total N and P, available N, P and K, microbial biomass C and N in the soil of the improved system. A positive relationship between soil available P and soil organic C suggested that application of P to Vertisols increased carbon sequestration by 7.4 t C ha−1 and, in turn, the productivity of the legume-based system, thus ultimately enhancing soil quality.

Notes: Abstract. Soil organic matter (SOM) is considered to be key to sustainability of agriculture in the tropics. In southern Brazil, no-tillage has been adopted widely to control soil erosion, but its impact on the dynamics of SOM is not well established. We measured soil carbon (C) and δ13C in two crop rotations, one of which contained C4 maize (Zea mays L.), after 21 years of contrasting tillage (conventional tillage versus no-tillage). Adjacent sites that reflected historic land-uses were also sampled. In the tillage experiment there was no effect of tillage on the total amount of C in the 0–40 cm profile (even when contrasting bulk density was accounted for), and the concentration of C differed only in the 0–5 cm and 5–10 cm layers. However, the occasional input of C4 material in the maize rotation resulted in a significant effect of rotation on δ13C (P 〈0.001). Using 13C as a tracer for the SOM formed since the start of the experiment, we estimated the abundance of ‘recent’ and ‘old’ C within each depth interval. We found the main effect of tillage was to increase the medium-term turnover of SOM, particularly in the subsoil (i.e. below 20 cm depth). Compared with no-tillage, there was almost five times more recent C in the subsoil, and 20% more recent C in the 0–40 cm profile as a whole.

Notes: Abstract. Leaching of faecal coliforms to rivers, lakes and groundwater following the spreading of animal slurry on land is of environmental and public health concern. A two-stage approach was adopted to modelling the transport processes by which Escherichia coli passes through the soil to receiving waters via field drains. First, parameter values were selected for the dual-porosity contaminant transport model macro to simulate through-soil flows, sorption and die-off of E. coli. These simulations reproduced experimental measurements showing rapid flows of the microorganisms to field drains after slurry spreading, which could be explained in terms of macropore flow in which trapping of colloids such as E. coli does not take place. Second, a series of predictive simulations was carried out to test the influence of soil and weather conditions on E. coli losses. These showed that losses are strongly influenced by soil wetness conditions at the time of spreading, and to a lesser degree by rainfall occurring soon after spreading. Selection of spreading ‘workdays’ with particular weather and soil wetness conditions is beneficial, which indicates opportunities for substantial reductions in the environmental risks of water pollution by E. coli and other faecal microorganisms.

Notes: Abstract. The purpose of the study was to determine the soil organic carbon (SOC) stock for Flanders, Belgium and to evaluate various methods for assessing SOC stock. The assessment methods first determined the SOC density (C mass per unit area) for pedons in a database of soil properties, and then spatially distributed the SOC density to soil and soil/land use categories on a map. The results showed that the pedon SOC density is influenced by drainage class, texture and land use/land cover. The SOC density estimation method significantly influences results and leads to differences of up to 6% in total estimated SOC stock for Flanders. Use of various spatial distributing methods creates differences of up to 2% in total estimated SOC stock. The largest difference in SOC stock estimate between any combination of assessment methods was 7% (125.6 Tg vs 134.9 Tg). These findings emphasize the importance of complete spatial soil databases of high quality that reduce uncertainty of estimates for use in research examining the role of soils in the C cycle. The results indicate that the need for these databases is greater than the need to standardize methods to determine the spatial distribution of SOC. A map of the distribution of SOC density shows that in Flanders a large proportion of SOC is stored in sandy soils in the north of the territory.

Notes: Abstract. The Bocage in the western part of Europe is an ancient rural landscape characterized by a network of hedgerows. The system studied here consists of hedges growing on earth and stone banks, which are found in the Armorican Massif (western France). Seven sites were analysed, which represented a large, but not complete, set of situations. We investigated the influence of hedges parallel to contour lines on soil characteristics, soil profile morphology and carbon storage at the hillslope scale. The analysis is based on a morphological description of the soil catena from the top of the hill to downslope of the hedge, and on measurements of bulk density and organic carbon in different soil profiles on the slopes. The results show that thickness of the organic horizon increases slowly from the top of the hill as far as the hedge, whereas under the hedge the bulk density is low and the soil organic carbon (SOC) storage large. Two effects of the hedges on SOC storage are apparent, namely, a local effect under the hedge, due to tree activity, and an anti-erosive effect at the hillslope scale. A rough approximation based on these data assessed the fraction of SOC storage attributed to the hedge network of between 13 and 38% of the total carbon stock.

Notes: Abstract. Muddy floods due to runoff are a widespread problem on the South Downs of southern England and are associated with increased growing of autumn-sown cereals over the last two decades. The 10.6 km2 Sompting catchment has been monitored over the 12-year period 1990/91–2001/02. A housing estate at the lower end of the catchment that was frequently inundated by muddy floods in the late 1980s and early 1990s has not been flooded since the winter of 1993/94, even during the heavy rainfall events of October and November 2000. This is a result of the ameliorative measures put in place in the early 1990s, primarily the reversion of some winter cereal fields to permanent grassland (set-aside). Other land management changes helped, for example, some parts of the catchment were put down to short-term grass leys and small dams were constructed to impound runoff. Flooding of the housing estate occurred when more than 30% of the catchment was covered by eroded fields, which contributed runoff to the valley floors leading down to the housing estate. The length of continuous down-valley flow was greater in the early 1990s compared with later years. The introduction of grassland reduced the risk of flooding not only by reducing the area contributing to runoff, but also by stopping valley floor flows linking up. Such measures to alleviate runoff, erosion and flooding fit well with policies proposed in the recent report by the UK Policy Commission on the Future of Farming and Food.

Notes: Abstract. Weakly weathered clay bedrock and samples of A horizon of a developed Biancana soil were incubated with compost or green manure in the presence of two physical forms of gypsum: one mined and ground and the other from flue-gas desulphurization (FGDG). The gypsum efficiency was evaluated in combination with two organic polymers: polyvinyl alcohol (PVA) and polyacrylamide. Compost and green manure increased permeability only in the presence of gypsum. The FGDG was more effective than the mined gypsum, alone or in combination with PVA.

Notes: Abstract. In the semiarid regions of sub-Saharan Africa, fertilizer recovery and nutrient release from organic sources are often moisture limited. Moreover, in these regions runoff brings about large nutrient losses from fertilizer or organic inputs. This study was conducted in the north sudanian climate zone of Burkina Faso (annual rainfall 800 mm, PET 2000 mm yr−1). We assessed the combined and interactive effects of two types of permeable barriers (stone rows and grass strips of Andropogon gayanus Kunth cv. Bisquamulatus (Hochst.) Hack.) and organic or mineral sources of nitrogen on erosion control and sorghum yield. The field experiment (Ferric Lixisol, 1.5% slope) was carried out during three rainy seasons and consisted of 2 replications of 9 treatments, in which the barriers were put along contours and combined with compost, manure and fertilizer nitrogen (N). Compared with the control plots, the average reduction in runoff was 59% in plots with barriers alone, but reached 67% in plots with barriers + mineral N and 84% in plots with barriers + organic N. On average, stone rows reduced soil erosion more than grass strips (66% versus 51%). Stone rows or grass strips without N input did not induce a significant increase of sorghum production. Supplying compost or manure in combination with stone rows or grass strips increased sorghum grain yield by about 142%, compared with a 65% increase due to mineral fertilizers. The sorghum grain yields at 1 m upslope from the grass strips were less than those 17 m from the grass strips. As stones do not compete with plants, the opposite trend was observed with stone rows. We conclude that for these nutrient depleted soils, permeable barriers improve nutrient use efficiency and therefore crop production. However, grass strips must be managed to alleviate shade and other negative effects of the bunds on adjacent crops.

Notes: Abstract. Nitrogen (N), phosphorus (P) and potassium (K) budgets were calculated for nine organic farms in the UK. The farms were situated on sandy loams, silty clay loams and silty loams over chalk with stockless farming systems and cattle, pig and poultry enterprises with a significant proportion of arable cropping. A soil surface nutrient budget was calculated for the target rotation on each farm using information about field management and measurements of the soil, crops and manure. Losses of N through leaching and volatilization were calculated independently using the nitcat and manner models. Nutrient budgets for seven of the farm rotations showed an N surplus, six a P surplus and three a K surplus. The ratio of N inputs supplied in the form of biological fixation : manure : atmospheric deposition was approximately 2 : 2 : 1 for stocked systems and 2 : 0 : 1 for stockless systems. Phosphorus surpluses resulted from supplementary P fertilizer (rock phosphate) and additional feed for non-ruminant livestock. The stockless system without P fertilizer resulted in a large P deficit and stocked systems, which relied on recycling manure alone, a small P deficit. Only rotations with large returns of manure or imported feed showed a K surplus or a balanced K budget.

Notes: Abstract. Phytoextraction is the remediation of heavy metal contaminated soils using plants that take up metals. Hyperaccumulating plants such as Thlaspi caerulescens are often studied for their possible use for decontamination of Cd and Zn rich soils, but few field trials have been reported, although they are necessary to validate the results of hydroponic and pot studies. This article reports field data for T. caerulescens grown on a calcareous and an acidic soil, both contaminated 20 years ago by either atmospheric depositions or septic-tank wastes. Accelerated cropping using transplants grown three times in eight months was compared to Thlaspi sown twice during the same period. Both were followed by one crop of sown Thlaspi. High Cd and Zn concentrations in the plant shoots compensated for the low biomass production. Annual metal exports with transplanted Thlaspi were 130 g Cd ha−1 and 3.7 kg Zn ha−1 on the calcareous soil and 540 g Cd ha−1 and 20 kg Zn ha−1 on the acidic soil. We concluded that within the framework of the Swiss legislation, remediation of Cd-contaminated soils could be achieved within less than 10 years with one crop of Thlaspi per year, but differences in soil properties could affect the rate of phytoextraction significantly. Total Zn content in both soils was too high to be remediated by T. caerulescens in a realistic time span. Thlaspi did not decrease the NaNO3-extractable fraction of Cd or Zn in either of the soils.

Notes: Abstract. We compared the effects of conventional and organic arable farming on soil organic matter (SOM) content, soil structure, aggregate stability and C and N mineralization, which are considered important factors in defining sustainable land management. Within one soil series, three different farming systems were selected, including a conventional and an organic arable system and permanent pasture without tillage. The old pasture represents optimal conditions in terms of soil structure and organic matter inputs and is characterized by high earthworm activity. More than 70 years of different management has caused significant differences in soil properties. SOM content, mineralization, earthworm activity and water-stable aggregation decreased as a result of tillage and arable cropping when compared with pasture, but were significantly greater under organic farming than under conventional farming. Total SOM contents between 0 and 20 cm depth amounted to 15, 24 and 46 g kg−1 for the conventional arable, organic arable and permanent pasture fields, respectively. Although less sensitive to slaking than the conventionally managed field, the soil under organic farming was susceptible to compaction when high pressures were exerted on the soil under wet conditions. The beneficial effects of organic farming are generally associated with soil biochemical properties, but soil physical aspects should also be considered. Depending on soil type and climate, organic farmers need to be careful not to destroy the soil structure, so that they can enjoy maximum advantage from their organic farming systems.

Notes: Abstract. Article 3.4 of the Kyoto Protocol allows carbon emissions to be offset by demonstrable removal of carbon from the atmosphere by improved management of agricultural soils. To make use of this possibility, a good estimate of soil organic carbon (SOC) stocks and baseline emissions (in 1990) are crucial factors. Over 210 000 topsoil (0–24 cm) measurements have been made in Belgian cropland in the period 1989–1999, which are available for seven different agro-pedological regions and for three periods (1989–91, 1992–95, 1996–99). We used this extensive SOC data set to estimate SOC stocks and fluxes in Belgian cropland. The measurements of SOC were extrapolated to 1 m depth using an exponential SOC depth distribution model, based on another large data set of over 5184 fully described soil profiles on Belgian cropland made during the National Soil Survey. The SOC data were combined with cropland area figures to calculate SOC stocks to 1 m depth. The 1990 baseline SOC flux of Belgian cropland was then obtained using two different calculation methods, which each yielded similar results and showed that SOC stocks were decreasing in the 1990s at a mean rate of 608 kton OC yr−1. Consequently, a large part of the Belgian cropland acted as a net source of CO2 emissions during the period 1989–1999.

Notes: Abstract. Less Intensive Farming and Environment (LIFE) management is a form of integrated farming which aims to meet farming's economic and environmental requirements. We used a farm-scale LIFE demonstration to measure nitrogen (N) leaching losses over a 6 year period (1995–2001) using ceramic suction cups and a meteorological model to give estimates of drainage volumes. Losses from the system averaged 49 kg N ha−1, with an average drainage nitrate concentration of 15.5 mg N L−1. Rainfall and its distribution strongly influenced the loss, and drainage N concentration only fell below the nominal target of 11.3 mg N L−1 (the EU limit for potable water) in the two wettest seasons. Crop type did not have a significant effect on either postharvest mineral N (PHMN) in soil or the leaching loss in the subsequent winter. However PHMN and overwinter N leaching declined with increasing crop yield. Overwinter crop N uptake increased with early sowing: leaching loss was only 5 kg N ha−1 under grass sown in early September. Measurements of PHMN, crop sowing date and drainage data were used to construct simple equations to predict average drainage N concentration under various scenarios. The large N loss from our site is partially attributable to soil type (shallow over limestone), indeed on similar soil the loss from a conventional farm nearby was greater. The LIFE practices of postharvest harrowing and late cereal sowing will minimize the need for agrochemical use but they stimulate mineralization and reduce plant N uptake in autumn, leaving more N at risk to leaching. Some assessment of all environmental impacts is needed if the benefits of integrated practices such as those used in LIFE are to be quantified.

Notes: Abstract. The concept and the effects of a multi-purpose grassed waterway (GWW) were investigated over an eight year period. A GWW, half of it seeded, the remainder left to natural succession, and an intensive soil consevation system in the fields nearby were established in an agricultural watershed (13.7 ha). This combination minimized the maintenance in the GWW without sward damaging sedimentation. In consequence the GWW, as well as providing safe drainage for surface runoff, also served additional ecological roles. During the experiment it reduced runoff and sediment delivery from the watershed by 39% and 82%, respectively. Moreover it improved biodiversity on the research farm and acted as a refuge for beneficial organisms. Soil mineral nitrogen content decreased by 84% after the installation of the GWW, indicating that although infiltration into the GWW was rapid, the risk of groundwater contamination from leached nitrate was diminished. The agricultural assets and drawbacks of establishing GWWs were also studied. We showed that the economic returns were more likely to be improved than reduced. Creating the GWW by natural succession had some advantages compared to seeding with grass.

Notes: Abstract. The accuracy of a ThetaProbe (Delta-T Devices Ltd, UK) to obtain repeated measures of soil water content in pot plants was tested. This alternative to balance determinations led to a large underestimation of water content, varying from 12.2 to 21.8% of the total water content, depending on soil type.

Notes: Soils represent a major sink for organic xenobiotic contaminants in the environment. The degree to which organic chemicals are retained within the soil is controlled by soil properties, such as organic matter, and the physico-chemical properties of the contaminant. Chemicals which display hydrophobic and lipophilic characteristics, as well as a recalcitrant chemical structure, will be retained within the soil, and depending on the ‘strength’ of the association may persist for long periods of time. This review describes the behaviour of hydrophobic organic contaminants in soils, focusing on the mechanisms controlling interactions between soil and contaminants. The bioavailability of contaminants in soil is also discussed, particularly in relation to contact time with the soil. It considers the degradation of organic contaminants in soil and the mechanisms microbes use to access contaminants. Finally, the review discusses the ‘pros’ and ‘cons’ of chemical and biological techniques available for assessing bioavailability of hydrophobic organic chemicals in soils, highlighting the need to quantify bioavailability by chemical techniques. It concludes by highlighting the need for understanding the interactions between the soil, contaminants and biota which is crucial to understanding the bioavailability of contaminants in soils.

Notes: Multivariate methods have been widely used for revealing the structures of communities, and in this paper we explore one particular method, namely correspondence analysis (also called reciprocal averaging), for studying humus profiles by the ‘method of small volumes’. The present study was done on humus profiles under holm oak (Quercus rotundifolia), an evergreen Mediterranean species, in the High Atlas of Morocco. Three sites (1500 m, 1700 m, 1900 m altitude) and 2 years (1999 and 2002) were compared. The humus form is Dysmull (mull with thick litter horizons), with variations in the thickness of the OL (entire leaves), OF (fragmented leaves with faecal pellets) and A (hemorganic) horizons according to altitude and year. The dead leaves are rapidly incorporated into holorganic (earthworm, insect) and hemorganic (enchytraeid) animal faeces, which form the bulk of the OF and A horizons. The S horizon (weathering parent rock) shows the greatest development of the root system. As altitude increases more fresh litter (OL) or more humified organic matter (OF, A) is accumulated. Variation from year to year is depicted by opposite differences in the amount of entire oak leaves and of dead roots. Humus components (classes) are used as active (main) variables, after standardization of their means and variances. The addition of numerous passive (additional) variables, standardized in the same way as active variables, enabled us to understand the influence of biological and climatic effects on the composition of humus profiles and soil trophic networks.

Notes: Microbial ecology is the key to understanding the function of biodiversity for organic matter cycling in the soil. We have investigated the impacts of farmyard manure added over 120 years on organic matter content, enzyme activities, total microbial biomass and structure of microbial populations in several particle-size fractions of a Luvic Phaeozem a few kilometres northeast of Halle, Germany. We compared two treatments: no fertilization (control) and 12 t farmyard manure (FYM) ha−1 year−1 since 1878. The fine fractions contained most C and N, microbial biomass, total amount of phospholipid fatty acids (PLFAs) and greatest invertase activity. Xylanase activity as well as fungal biomass increased only gradually with diminishing particle size, whereas the relative abundance of fungi decreased with diminishing particle size. The least diversity of the soil microbial community, indicated by the smallest Shannon index based on the abundance and amount of different PLFAs and small number of terminal restriction fragments (T-RFs) of 16S rRNA genes, was in the sand fractions. The results supported the hypothesis that this microhabitat is colonized by a less complex bacterial community than the silt and clay fractions. Addition of FYM had enhanced the amount of organic matter, total microbial biomass, and xylanase and invertase activity, and induced a shift of the microbial community towards a more bacteria-dominated community in the coarse sand fraction. Microbial communities in finer fractions were less affected by addition of FYM.

Notes: Predicting the rate at which rain infiltrates on steep slopes is very uncertain. There is no consistent information in the literature. We have therefore related infiltrability to slope gradient under field conditions by experimenting on a gravelly loamy soil occupying the upper half of a cultivated convex hill in northern Thailand. Fifteen 1 m × 1 m plots with slope gradients ranging from 16 to 63% were established, and simulated rain was allowed to fall on them at controlled rates and for fixed times. We obtained the following results. The surface fell 0.4–7.2 mm due to compaction and soil loss. The proportions of crust (0–40%) and embedded gravel (10–60%), the runoff coefficient (0.05–0.78 mm mm−1), the mean sediment concentrations (0–5.6 g l−1), and soil detachment (10–313 g m−2) were more pronounced on the gentle slopes than on the steep ones. The steady final infiltration rate (1–107 mm hour−1) increased sharply with increasing slope gradient. Microaggregates tended to behave like sand and become tightly packed on gentle slopes (packing crust). These results suggest that the vertical component of kinetic energy, which is greater on gentle slopes, has a dominant role. Nevertheless, the differences in compaction and in sediment concentration could not be ascribed to the vertical component of kinetic energy alone. On steep slopes the horizontal component of the kinetic energy is transformed into shear stress, hampering the development of crusts so that water can still infiltrate. On steeper slopes, the water film was thinner, thereby limiting the role of splash. We conclude that the relationship between slope gradient and infiltrability depends on the nature of the soil and must be examined in the light of surface crusting processes.

Notes: Two recent investigations have reported contradictory trends concerning the effect of image resolution on the surface fractal dimension of soil pores, evaluated via image analysis. In one case, dealing with a preferential flow pathway and an ideal fractal, image resolution had no influence on the estimated fractal dimension, whereas in the other case, involving images of soil thin sections, the surface fractal dimension decreased significantly with image resolution. In the present paper, we try to determine the extent to which these conflicting observations may have been due to the different ways in which image resolution was varied. By narrowing down (up to 400 times) the field of view on progressively smaller portions of a textbook surface fractal, the von Koch island, one causes its apparent surface fractal dimension to decrease significantly. On the other hand, changing the resolution of images of soil thin sections (up to 6 times), while keeping the magnification constant, does not lead to appreciable changes in the surface fractal dimension. These results demonstrate that there is no real conflict in earlier reports, as long as both the resolution and the magnification of images are taken into account in image-based evaluations of surface fractal dimensions of soil pores.

Notes: The sandy microdune systems of the Sahel are important for biomass production, in that they trap and store water. We have studied the movement of water over and in a dune and the chemistry of the water to understand this aspect of the systems. We experimented with simulated rain using a field sprinkling infiltrometer. We applied demineralized water with a chemical composition similar to that of the natural rain on a 1-m2 plot. The plot was delimited by a metallic two-level setting: the first enabled us to collect surface runoff, while the second measured subsurface flow. Water samples were taken at 5- to 10-minute intervals throughout each simulation for chemical analysis (alkalinity, SO42–, F–, NO3–, Ca2+, Mg2+, Na+, K+ and Si). Mass balances, combined with a simple mixture model involving one tracer (chloride) and two reservoirs (old and new waters), were calculated. The equilibrating pressures of the CO2 (pCO2) and the saturation index with respect to specified minerals (e.g. calcite, fluorite, silicates) were also calculated by the AQUA ion-pair model. The solute concentrations decrease in surface runoff as well as in subsurface water, except for F– and Si in the subsurface. The pCO2 decreased to a pressure less than the atmospheric pressure. The difference between measured concentrations and concentrations computed with the mixing model highlighted interactions between the soil and water. The dissolution of calcite which consumes CO2, and the cation exchanges, dominated, whereas the dissolutions of fluorite, silicates and gypsum appear secondary. Reactive mineral stocks were quickly exhausted, especially in the surface flow.

Notes: Rates of solute diffusion fundamentally affect the properties of flooded soils, but the effects of flooding on solute diffusion have not previously been studied in detail. Four soils with widely differing chemical and physical properties were packed to a range of bulk densities, flooded for varying times, and the self-diffusion of chloride through the soils measured. Diffusion impedance factors were derived from the results. In each soil the impedance factor decreased linearly with increase in bulk density, and between soils impedance factors increased with increasing clay content. The impedance factor decreased by up to 20% during the first 3–6 weeks following flooding, but with prolonged flooding it increased to at least its initial value. Concomitantly the cation exchange capacities of the soils increased by between 30 and 100%, there was reductive dissolution of soil iron, probably both structural iron in soil clays and iron oxyhydroxide coatings on clay surfaces, and subsequently there was re-precipitation of ferrous iron, probably as mixed carbonates and hydroxides. The decreases in diffusion impedance factors were consistent with the increases in cation exchange capacity and changes in soil iron, and the subsequent increases were consistent with re-crystallization of mixed ferrous–ferric compounds. We conclude that the effects of changes in redox on diffusion impedance will be important in some soils, although they are smaller than the effects of water content per se.

Notes: The surface composition of particles present in the fine earth (〈 2 mm) of 50 soil horizons differing in composition and pedogenetic origin (13 soil profiles) was analysed by X-ray photoelectron spectroscopy (XPS) to assess the capability and limitations of this technique and to gain better knowledge of the soil samples. The surfaces were systematically enriched in carbon, sometimes up to 1000 times, indicating that the soil particle surfaces are coated with organic substances, even in horizons where the bulk organic content is less than 0.1 g kg−1. The distribution of carbon in the various oxidation states was 0.569 ± 0.008 C[0], 0.275 ± 0.004 C[+1], 0.089 ± 0.003 C[+2] and 0.066 ± 0.002 C[+3] for most horizons (mean ± standard error, 69 data). Only Andosol surface horizons systematically had surface organic matter in a more oxidized state. After correcting the results for the presence of organic coatings, we found that Si was generally depleted and Al enriched at the surface of soil particles, while Fe was either depleted or enriched depending on the sample considered. However, the coating of the coarser soil particles by the finer ones and their differential composition explained this observation and limits the interest of XPS for characterizing the surface enrichment of inorganic elements in crude soil samples. These limitations should be considered when interpreting XPS results in future work. Nevertheless, XPS can analyse the adsorbed organic matter and its functional composition of carbon without the need for any chemical or physical extraction that might alter the structure and composition of the organic molecules.

Notes: Al hydroxide polymers (AlHO) can significantly influence the cation exchange behaviour of clays. We have determined the effect of synthesized AlHO on Ca–Na, Zn–Na and Pb–Na exchange for a series of exchanger compositions and two Al loadings at pH 6.0 and an ionic strength of 0.01 m. The preference for Ca on the siloxane surface of the clay–AlHO system (CAlHO) was greater than for the pure clay, and the average KV (Vanselow selectivity coefficient) was determined to be 2.16 and 1.24, respectively. The selectivity coefficients for the exchange reactions Zn–Na and Pb–Na were not directly determined in CAlHO systems, because heavy-metal ions bind as well to the clay surface as to the AlHO over a wide range of pH. We have estimated the effect of the presence of AlHO on the selectivity coefficients of Zn–Na and Pb–Na exchange by extrapolation of the experimental results of Ca–Na, Zn–Na and Pb–Na exchange for pure clay and Ca–Na exchange for CAlHO. The average KV was increased by the presence of the AlHO from 1.23 to 2.16 for Zn–Na exchange and from 1.59 to 2.77 for Pb–Na exchange. The increase in the preference for the divalent cations is probably caused by parallel alignment of clay platelets by sorption of AlHO. Increasing the amount of AlHO did not change the selectivity for Ca–Na exchange, and probably the structure of the system or the arrangement of the clay platelets and AlHO particles was not substantially changed. This was supported by the linear reduction of the cation exchange capacity with amount of AlHO present at pH 6.6. It seems likely that the selectivity coefficients for Ca–Na, Zn–Na and Pb–Na exchange that we found apply in naturally occurring montmorillonite–AlHO systems.

Notes: The aim was to characterize dissolved organic matter in soils under different tree species. Molecular size distribution and chemical composition of dissolved organic carbon and nitrogen were determined in water extracts from humus layers and mineral soils taken from silver birch (Betula pendula Roth.), Norway spruce (Picea abies (L.) Karst.) and Scots pine (Pinus sylvestris L.) stands. Concentrations of tannins and 15 phenolic acids in the humus layers were measured. Per unit of organic matter, the concentrations of dissolved organic C and N were larger in birch and spruce humus layers than in the pine humus layer. In the underlying mineral soil, the concentrations of dissolved organic C were similar at all sites, but the concentration of dissolved organic N was greater in spruce and pine soils than in birch soil. In all soils, the 10–100 kDa fraction was the most abundant molecular size group and hydrophobic acids the most abundant chemical group of dissolved organic C. In all humus layers, hydrophobic acids and hydrophilic bases were the major components of dissolved organic N. There were only minor differences in the concentrations of total tannins in the humus layers under different tree species. Small-molecule tannins (about 〈 0.5 kDa) were most abundant in the birch humus, and large-molecule tannins in the pine humus. Coniferous humus contained more ferulic and p-coumaric acids than did the birch humus. The concentrations of 3,4 and 3,5-dihydroxybenzoic acid, vanillic acid and 4-hydroxybenzoic acid were similar in all soils.

Notes: Plant-pathogenic nematodes are a major cause of crop damage worldwide, the current chemical nematicides cause environmental damage, but alternatives such as biological control are less effective, so further understanding of the relationship between nematodes, nematicides, biological control agents and soil and rhizosphere microorganisms is needed.Microbial populations from roots of cabbage and tomato plants infested with the root-knot nematode Meloidogyne incognita were compared with those from plants where the nematode was controlled by the nematicide aldicarb, or a nematophagous fungus with biological control potential, Pochonia chlamydosporia. The total numbers of culturable bacteria and fungi in rhizosphere soil were similar in all three treatments for both plants, around 100-fold more than in control soil in which there were no plants. However, there were clear differences in the catabolic diversity, assessed by Biolog EcoPlate™ carbon substrate utilization assays, between microbial populations from unplanted soil and the rhizosphere. In cabbage, a poor host for M. incognita, the rhizosphere population from P. chlamydosporia-treated plants was distinct from the population from untreated and aldicarb-treated plants. In tomato, a host susceptible to the nematode, the catabolic diversity of populations from aldicarb- and P. chlamydosporia-treated plants was similar and differed from the untreated, nematode-infested plants. The genetic diversity of the fast-growing heterotrophic bacteria in the tomato rhizosphere, indicated by PCR fingerprinting with ERIC primers, was very different in the infested roots, whereas the profiles of isolates from both aldicarb- and P. chlamydosporia-treated roots were similar. Evidently, nematodes have a greater impact on the rhizosphere population of a susceptible host, tomato, than a poor one, cabbage, and nematode-infested roots are colonized by a different subpopulation of soil microbes from that on plants where infection is controlled, illustrating differences in root morphology and physiology.

Notes: We have developed the fractal approach to modelling variations in soil bulk density and porosity with scale of measurement or sample size. A new expression is derived for each quantity based on the pore–solid fractal (PSF) model of soil structure. This new general expression covers a range of fractal media and accommodates existing fractal models as special cases. Model outputs cover a range of scaling behaviour expressed in terms of monotonic functions, from increasing density and decreasing porosity, through constant porosity and density to decreasing density and increasing porosity with increasing scale of measurement. We demonstrate the link between this new model for the scaling of porosity and bulk density and the water retention model for the PSF. The model for scaling bulk density is fitted to data on aggregate bulk density and shown to yield good fits describing bulk density decreasing with increasing aggregate size. Porosity scaling is also inferred from the fitting of water retention data. Inferred porosities from different fittings are shown to follow decreasing, scale-invariant and increasing values with decreasing size of structural unit, and these theoretical results emphasize the need for further experimental investigation on the basic issue of density scaling in soil science.

Notes: Irrigation by surge flooding does not always wet the soils thoroughly, and we have investigated the reasons for this on an irrigated plot in northern Senegal by monitoring the water budget during a rice cropping season (100 days). The amount of water added during each irrigation event was measured, and evapotranspiration and infiltration were estimated with lysimeters and Muntz infiltration rings, respectively. At the same time, piezometric levels, neutron probe values and water tension data were recorded at two stations in the plot. These measurements showed unusual results: infiltration rate was less than 1 × 10−6 mm s−1 (less than 0.1 mm a day), there was a constant water deficit during the entire irrigation period, around 50 cm deep, and tensiometers at 40 cm reacted very slowly to water infiltration. The water fluxes in the vadose zone derived from these data showed clearly a discrepancy between fluxes calculated from hydraulic gradients and fluxes calculated from mass conservation. The hydraulic gradients suggested a zero flux plane at 40 cm below the surface, but the calculated values of the fluxes overestimated by several orders of magnitude the infiltration rates determined on the plot, whereas fluxes determined from mass conservation matched far better. These results show that air was entrapped between the shallow water table and the wetting front, and this inhibited water infiltration. Modelling water flow down the soil profile with a computer program for simulating one-dimensional water movement (Hydrus) confirmed that single-phase models cannot describe imbibition in this situation. Simple infiltration models based on a modified Green–Ampt equation accounting for air compression and air counter-flow, however, fit experimental infiltration data much better. We demonstrated that where surge flooding is associated with a shallow water table, as in many large irrigation schemes, one must take into account the presence of air to quantify the flow of water into the soil.

Notes: Incorporating straw into the ploughed layer of soil affects the dynamics of carbon and nitrogen. A precise quantification of its short-term effect in agricultural fields is difficult because biological and physical processes interact and take place simultaneously. As an alternative to experimentation, investigations have turned to simulations using mechanistic models, and we have taken this approach. The goal of our study was to test a mechanistic and one-dimensional model of transport and biotransformation (PASTIS) against a data set obtained in a field experiment in northern France. We tested carbon and nitrogen dynamics by measuring C mineralization rates, the rates of gross immobilization and mineralization of N (using 15N tracing), and inorganic pools of N in the soil profile during 1 year in a bare soil with or without addition of wheat straw. Most of the model parameters were determined in independent experiments. We estimated the biological parameters from incubation experiments in the laboratory. The simulated results were in good agreement with experimental data, particularly for gross N rates. Hypotheses concerning the pathway of microbial assimilation and the dependence of decomposition on the size of the biomass were tested. The simulated net N immobilization due to addition of straw (8000 kg dry matter ha−1) reached a maximum of 64 kg N ha−1 after 2 months, whereas the observed value was 66 kg N ha−1. The model indicated that after 13 months the incorporation of straw had reduced the net amount of nitrogen mineralized by 13% and the amount of leached nitrate by 27%. The sensitivity analysis to the depth of straw incorporation indicated that the deeper was the incorporation the less was the leaching and the mineralization of nitrogen.

Notes: Lime, mined gypsum and some gypsum-like by-products have been frequently applied to soil to counter acidity. We have examined the changes in the chemical and mineralogical properties of three acid soils resulting from the application of three industrial by-products (phosphogypsum, red gypsum and sugar foam). We did so in laboratory experiments on suspensions of soil in saturated solutions of the by-products. A sizeable fraction of the Al released by exchange with Ca of the amendments remained on the mineral surfaces as Al polymers, as suggested by changes in the CuCl2-, oxalic–oxalate- and DTPA-extractable Al contents. Polymerization of Al was promoted by corresponding neutral and basic pH of red gypsum and sugar foam saturated solutions, respectively. Sorption of these Al polymers was particularly favourable in those horizons with more clay fraction and variable-charge clay minerals. On the other hand, in most cases there was little or no detectable sorption of sulphate, thus excluding precipitation of crystalline or amorphous basic Al sulphates to alleviate Al toxicity. Based on the reduction of the Al saturation of the exchange complex in the soils, as well as on the small contents of heavy metals and natural radionuclides of the three by-products, these can be considered effective alternatives to mined gypsum and lime for alleviating soil acidity and reducing toxic concentrations of Al in agricultural, acid soils.

Notes: There is no simple and general relationship between the thermal conductivity of a soil, λ, and its volumetric water content, θ, because the porosity, n, and the thermal conductivity of the solid fraction, λs, play a major part. Experimental data including measurements of all the variables are scarce. Using a numerical modelling approach, we have shown that the microscopic arrangement of water influences the relation between λ and θ. Simulated values for n ranging from 0.4 to 0.6, λs ranging from 2 to 5 W m−1 K−1 and θ from 0.1 to 0.4 can be fitted by a simple linear formula that takes into account n, λs and θ. The results given by this formula and by the quadratic parallel (QP) model widely used in physical property studies are in satisfactory agreement with published data both for saturated rocks and for unsaturated soils. Consequently, the linear formula and the QP model can be used as practical and efficient tools to investigate the effects of water content and porosity on the thermal conductivity of the soil and hence to optimize the design of thermal in situ techniques for monitoring water content.

Notes: Use of isotope methods to measure the availability of phosphorus (P) in soils that are well supplied with P is well established. We have evaluated such methods for acid tropical soils with very small P contents, which are less well studied. The isotopically exchangeable P in soil suspensions (E value) and that in plant growth experiments (L value) were measured in soils that had received varying amounts of P fertilizer in two field experiments in Colombia. We determined the E values over 4–5 weeks of equilibration allowing for the kinetics of isotope exchange. The decrease in radioactivity in the soil solution at a particular time, t, divided by that at the start (rt/R) was described by three parameters (r1/R, r∞/R, and a coefficient n) derived from the time course of isotopic exchange over 100 minutes. Values of Et were calculated either from measured values of rt/R or those extrapolated until 12 weeks. Agrostis capillaris was grown on the same soils labelled with carrier-free 33P-orthophosphate ions to obtain L values. Agreement between E values derived from measured and extrapolated values of rt/R was satisfactory, but errors in n and r∞/R limited the precision with which we could estimate E values. For most soils, the P concentrations in the soil solution were greater than the detection limit of the malachite green method (0.9 µg l−1) but smaller than its quantification limit (3.6 µg l−1). In the soils with the least available P, the P content of the seed limited the determination of the L value. The E values were strongly correlated, but not identical, with the L values measured for the same time of isotopic exchange. We conclude that these approaches are not precise enough to detect in these soils the ability of a plant to access slowly exchangeable forms of P or to quantify the mineralization of organic P. However, these isotope techniques can be used to estimate the total fraction of added fertilizer P that remains available to the plants.

Notes: Clay–Al hydroxide polymers (CAlHO) can bind heavy metals effectively and may play an important role in the adsorption behaviour and metal binding capacity of soils. We studied the dependence of Al loading and pH on the adsorption of Zn on Na-saturated montmorillonite–Al hydroxide polymer systems. The available binding sites on Al hydroxide polymers (AlHO) had a very strong affinity for Zn ions. Zinc binding on the clay surface became important when the binding sites on the AlHO were nearly all occupied. The pH had a very strong effect on the Zn binding. At pH 6.6 much more Zn could be adsorbed to the AlHO than at pH 5.0. The effect of the Al:clay ratio on Zn binding was influenced by pH. At pH 6.6, Zn binding to the AlHO, expressed per mole AlHO, was independent of the Al:clay ratio, whereas at pH 5.0 this relation was dependent. This is related to the constant charge of the AlHO at pH 6.6, whereas at pH 5.0 the charge decreases with increasing Al:clay ratio. If clay–Al hydroxide polymers are present in the soil their Zn binding to the AlHO will strongly influence the availability of the Zn.

Notes: Aluminium (Al) is abundant in soils, but the influence of Al on the mineralization of dissolved organic carbon and thus on carbon sequestration in soil is only poorly understood. We investigated the extent and rate of mineralization of dissolved organic carbon at various Al/C ratios.Dissolved organic carbon extracted from Oi and Oa layers under coniferous and deciduous forest was incubated with initial molar Al/C ratios from 〈 0.004 to 0.44 for 130 days. Mineralization was quantified by measurement of CO2. Rapidly and slowly mineralizable pools of dissolved organic C and their decomposition rate constants and half-lives (as a measure of labile and stable C) were modelled with a double exponential equation.Increasing initial Al/C ratios up to 0.1 led to a considerable decrease in mineralization (up to 50% compared with control samples). The half-life of the stable C pool increased up to 4-fold, whereas the half-life of the labile C pool was unaffected. Ratios of Al/C 〉 0.1 did not further decrease the mineralization, but led to increasing concentrations of free Al3+ in solution, and to increasing Al/C ratios in the precipitate, indicating that the Al complexation capacity of dissolved organic C was exceeded. Decrease in mineralization as well as formation of particulate organic matter (up to 56% of initial dissolved organic C) affected mainly the stable pool. Mineralization of dissolved organic C can be predicted from UV absorption by use of exponential regressions, but adding an Al variable did not improve the prediction significantly.We conclude that Al influences substantially the biodegradability of dissolved organic C percolating into the mineral soil, which may have consequences for the carbon sequestration in the soil. Declining Al concentrations would increase the mineralization of dissolved organic C only if the Al/C ratio becomes less than the ‘threshold value’ in the range of the Al complexation capacity of the dissolved organic C.

Notes: The sequestration of carbon (C) in soil is not completely understood, and quantitative information about the amounts of organic carbon in the various fractions and their rates of turnover could improve understanding. We aimed (i) to quantify the amounts of C derived from maize at various depths in the soil in a long-term field experiment with and without fertilization using 13C/12C analysis, (ii) to model changes in the organic C, and (iii) to compare measured and modelled pools of C. The organic C derived from the maize was measured in soil samples collected to a depth of 65 cm from four plots, two of which had been under continuous maize and two under continuous rye during long-term field experiments with NPK and without fertilization. The fractionation procedures included particle-size fractionation and extractions in water and in pyrophosphate solution. We used the Rothamsted Carbon Model to model the dynamics of the carbon from 13C data. The amounts of C derived from maize in the Ap horizon after 39 years of continuous maize cropping were 9.5% of the total organic C (where unfertilized) and 14.0% where NPK had been applied. Fertilization did not affect the residence time of carbon in the soil. The amounts of C derived from maize in water extracts were 21% of the total organic C (where unfertilized) and 22% where NPK had been applied. The extracts that were soluble in pyrophosphate and insoluble in acid were depleted in C from maize (the amounts were 5% and 7% of the total organic C, respectively). The results of the 13C natural abundance technique were used to model the dynamics of the organic C. Both the total organic C and the C derived from maize in the particle-size fraction 0–63 μm agreed well with the total and maize-derived sums of the model pools ‘inert organic matter’, ‘humified organic matter’ and ‘microbial biomass’. The model suggested that 64% (unfertilized) or 53% (NPK) of the organic C in the Ap horizon were inert. Only one of three published equations to determine the size of the inert pool agreed well with these model results.

Notes: Risk assessment of heavy metals in soil requires an estimate of the concentrations in the soil solution. In spite of the numerous studies on the distribution of Cd and Zn in soil, few measurements of the distribution coefficient in situ, Kd, have been reported. We determined the Kd of soils contaminated with Cd and Zn by measuring metal concentrations in the soil and in the soil solution and attempted to predict them from other soil variables by regression. Soil pH explained most of the variation in logKd (R2 = 0.55 for Cd and 0.70 for Zn). Introducing organic carbon content or cation exchange capacity (CEC) as second explanatory variable improved the prediction (R2 = 0.67 for Cd and 0.72 for Zn), but these regression models, however, left more than a factor of 10 of uncertainty in the predicted Kd. This large degree of uncertainty may partly be due to the variable degree of metal fixation in contaminated soils. The labile metal content was measured by isotopic dilution (E value). The E value ranged from 18 to 92% of the total metal content for Cd and from 5 to 68% for Zn. The prediction of Kd improved when metals in solution were assumed to be in equilibrium with the labile metal pool instead of the total metal pool. It seems necessary therefore to discriminate between ‘labile’ and ‘fixed’ pools to predict Kd for Cd and Zn in field contaminated soils accurately. Dilute salt extracts (e.g. 0.01 m CaCl2) can mimic soil solution and are unlikely to extract metals from the fixed pool. Concentrations of Cd and Zn in the soil solution were predicted from the concentrations of Cd and Zn in a 0.01 m CaCl2 extract. These predictions were better correlated with the observations for field contaminated soils than the predictions based on the regression equations relating logKd to soil properties (pH, CEC and organic C).

Notes: Chloropyromorphite, CPM, Pb5(PO4)3Cl, is one of the most insoluble lead minerals. Inducing the formation of CPM by application of phosphate to soil has been suggested for immobilizing Pb at contaminated sites. We have examined the effect of organic matter on the completeness and the rate of CPM precipitation and on the particle size and the mobility of CPM crystals. We did experiments at pH 3–7 and with varying content of dissolved organic C, 0–72 mg C l−1, mixing Pb(NO3)2 (0.5 mmol l−1) and phosphate (2 mmol l−1) solutions. The organic matter was extracted from samples of a forest floor. The precipitates were identified by X-ray diffraction, and their size and shape were analysed by scanning electron microscopy and by photon correlation spectroscopy. The presence of organic matter in the solutions did not affect the mass of CPM that precipitated within 30 minutes at pH 5, 6 and 7. At pH 3 and 4, however, organic matter strongly inhibited the precipitation. The particles were markedly smaller in solutions containing organic matter than without at all pHs and passed through water-saturated columns filled with calcareous sand, whereas the precipitates from the carbon-free solutions did not. We suggest that the organic matter blocked the surfaces of crystal seeds and impaired crystal growth. At high pH, organic matter may additionally decrease the crystal size of the individual crystals by increasing the number of crystal seeds. We conclude that organic matter in the solution might limit the potential of phosphate to immobilize Pb in soil because it favours the formation of mobile colloids.

Notes: Recent studies have pointed to the occurrence in soil organic matter of an insoluble macromolecular fraction, resistant to drastic alkali and acid hydrolysis. This non-hydrolysable fraction may contribute to the stable carbon pool in the soil and thus be important for the global carbon budget. We have developed a method to isolate such chemically resistant components, whilst ensuring complete elimination of the hydrolysable constituents of the organic matter but avoiding the formation of insoluble compounds via Maillard-type condensation reactions. Maize leaves, material especially susceptible to artefact formation, were used for this optimization. Several of the treatments that we tested, including the Klason lignin protocol, proved unsuitable. The most suitable protocol, by progressive hydrolysis with trifluoroacetic and hydrochloric acid, revealed a non-hydrolysable fraction in maize leaves accounting for about 5% by weight of the leaves and corresponding chiefly to lignin and condensed tannins. The protocol was applied to a forest soil and to the soil from an adjacent plot cleared 35 years ago and since cropped continuously with maize. The abundance, chemical composition and sources of the non-hydrolysable fraction of these two soils were determined by a combination of spectroscopy, pyrolysis and electron microscopy. This fraction accounted for about 6% of the total organic carbon of both soils; it contains aliphatic moieties, black carbon, melanoidins and, we think, condensed tannins.

Notes: The understanding of cation binding in the mor layer is important to correctly assess the biogeochemical cycling of metals and other cations in forested ecosystems. In a series of batch experiments, the binding of cations was examined in two mor layers from central Sweden. We examined the effect of Ca and Al on the binding of Zn, and also the binding of added Pb, Cu and Cd. Two models, WinHumicV and the Stockholm Humic Model (SHM), were tested for their ability to describe the data obtained. We found that for Zn, the pH at 50% sorption was increased from 2.8 to 4.2 after the addition of 3 mM Al. The proton titration data were well described by both WinHumicV and SHM after optimization of the concentrations of ‘active’ Al and humic substances. Applying generic parameters for cation binding produced deviations between the model simulations and the observations, particularly for the dissolved Pb and Cu concentrations, which were underestimated. A revised set of cation complexation constants was presented that improved the fit, particularly for SHM. For WinHumicV, there were still poor overall fits. The difference in model performance may be due to the greater number of adjustable parameters in the SHM, but probably also to other model-specific differences. According to the SHM simulations, the binding of Ca, Mg and Mn was mainly non-specific, whereas Pb, Cu and Al were bound as mono- or bidentate complexes. For Zn and Cd, binding occurred through both counter-ion accumulation and monodentate complexation.

Notes: Metal availability in soils is strongly related with sorption processes and the possible association of the metal ions with a particular particle-size fraction. Therefore, studies of metal retention by a soil will be aided if retention by different size fractions is also studied. Sorption of copper on a calcareous soil and its textural fractions was studied in batch assays. The soil was amended over 3 years with two agroindustrial residues, a composted olive mill sludge and vinasse. Sorption of Cu on the calcareous soil was very large (110 mmol kg−1) and was enhanced by both amendments. Metal retention by the clay fraction of the unamended soil was less than that of the whole soil, but increased dramatically after amendment with olive mill sludge. This was caused by the larger calcite content in this fraction as well as the increase in organic matter content. The amount of Cu sorbed was very large in the silt fraction, again because of the carbonate content of this fraction (300–460 g kg−1). Copper sorption decreased dramatically after removal of carbonate. Copper retention tended to be enhanced by organic amendments. This was particularly evident in the silt fraction, as a consequence of the organic matter accumulation in this fraction.Copper sorption on the calcareous soil and its silt fractions (unamended and amended) was irreversible. By contrast, desorption was measurable from all the carbonate-free samples (both whole soil and textural fractions), although in all cases a large hysteresis was observed. We conclude that carbonate was the main component responsible for the lack of reversibility.

Notes: The organic carbon content of soil is positively related to the specific surface area (SSA), but large amounts of organic matter in soil result in reduced SSA as determined by applying the Brunauer–Emmett–Teller (BET) equation to the adsorption of N2. To elucidate some of the controlling mechanisms of this relation, we determined the SSA and the enthalpy of N2 adsorption of separates with a density 〉 1.6 g cm−3 from 196 mineral horizons of forest soils before and after removal of organic matter with NaOCl. Likewise, we investigated these characteristics before and after sorption of increasing amounts of organic matter to four mineral soil samples, oxides (amorphous Al(OH)3, gibbsite, ferrihydrite, goethite, haematite), and phyllosilicates (kaolinite, illite).Sorption of organic matter reduced the SSA, depending on the amount sorbed and the type of mineral. The reduction in SSA decreased at larger organic matter loadings. The SSA of the mineral soils was positively related to the content of Fe oxyhydroxides and negatively related to the content of organic C. The strong reduction in SSA at small loadings was due primarily to the decrease in the micropores to which N2 was accessible. This suggests preferential sorption of organic matter at reactive sites in or at the mouths of micropores during the initial sorption and attachment to less reactive sites at increasing loadings. The exponential decrease of the heat of gas adsorption with the surface loading points also to a filling or clogging of micropores at early stages of organic matter accumulation. Desorption induced a small recovery of the total SSA but not of the micropore surface area.Destruction of organic matter increased the SSA of all soil samples. The SSA of the uncovered mineral matrix related strongly to the amounts of Fe oxyhydroxides and the clay. Normalized to C removed, the increase in SSA was small in topsoils and illuvial horizons of Podzols rich in C and large for the subsoils containing little C. This suggests that micropores preferentially associate with organic matter, especially at small loadings. The coverage of the surface of the soil mineral matrix as calculated from the SSA before and after destruction of organic matter was correlated only with depth, and the relation appeared to be linear.We conclude that mineralogy is the primary control of the relation between surface area and sorption of organic matter within same soil compartments (i.e. horizons). But at the scale of complete profiles, the surface accumulation and stabilization of organic matter is additionally determined by its input.

Notes: Cadmium (Cd) inputs and losses from agricultural soils are of great importance because of the potential adverse effects Cd can pose to food quality, soil health and the environment in general. One important pathway for Cd losses from soil systems is by leaching. We investigated loss of Cd from a range of contrasting New Zealand pasture soils that had received Cd predominantly from repeated applications of phosphate fertilizer. Annual leaching losses of Cd ranged between 0.27 and 0.86 g ha–l, which are less than most losses recorded elsewhere. These losses equate to between 5 and 15% of the Cd added to soil through a typical annual application of single superphosphate, which in New Zealand contains on average 280 mg Cd kg−1 P. It appears that Cd added to soil from phosphate fertilizer is fairly immobile and Cd tends to accumulate in the topsoil. The pH of the leachate and the total volume of drainage to some extent control the amount of Cd leached. Additional factors, such as the soil sorption capacity, are also important in controlling Cd movement in these pasture soils. The prediction of the amount of Cd leached using the measured concentrations of Cd in the soil solution and rainfall data resulted in an overestimation of Cd losses. Cadmium concentrations in drainage water are substantially less than the current maximum acceptable value of 3 µg l−1 for drinking water in New Zealand set by the Ministry of Health.

Notes: The potential of imaging spectroscopy for the assessment of seasonal dry-matter (DM) yield and sward quality was studied. Relationships between spatial heterogeneity of tiller density, light interception, ground cover and seasonal DM yield were developed. Sward heterogeneity was quantified by the spatial standard deviation of ground cover and of logarithmically transformed ground cover, and patterns in ground cover transects were quantified by wavelet entropy. An experiment was conducted with eight control (C) swards, eight naturally damaged (ND) swards and twelve artificially damaged (AD) swards. Swards were established in containers and spectroscopic images were recorded twice weekly.Seasonal DM yield was linearly related to a combination of means of ground cover and index of reflection intensity (r2 = 0·93). Spatial variation of tiller density was larger for AD and ND swards than for C swards. Values of the spatial standard deviation of ground cover and wavelet entropy were larger for AD and ND swards than for C swards. A single spatial standard deviation of ground cover value of 13% discriminated ND and AD swards from C swards. Seasonal means of wavelet entropy (r2 = 0·70) and the spatial standard deviation of ground cover (r2 = 0·63) at harvest were linearly related to seasonal DM yield. It is concluded that imaging spectroscopy can be used for assessing seasonal DM yield and sward heterogeneity.

Notes: On a Flemish sandy loam soil, cut and grazed swards were compared at different levels of mineral nitrogen (N) fertilization. Economically optimal N fertilization rates were 400 (or more) and 200 kg N ha−1 yr−1 on cut and grazed swards respectively. Considering the amounts of residual soil nitrate-N in autumn, these N rates also met the current Flemish legal provisions, i.e. no more than 90 kg ha−1 nitrate-N present in the 0–90 cm soil layer, measured between 1 October and 15 November. The N use efficiency was considerably higher in cut grassland systems than in grazed systems, even when the animal component of a cut and conservation system was included. The results indicate that, for cut grasslands, two N application rates should be considered: intensively managed grasslands with high amounts of N (400 kg ha−1 yr−1 or more) or extensively managed grasslands with white clover and no more than 100 kg N ha−1 yr−1.

Notes: The aim of the investigation was to determine the influence of variations in thickness and colour of agricultural plastic film on silage preservation conditions and grass silage quality. For this purpose, 30 cylindrical plastic containers (mini-silos; 0·3 m3) were filled with chopped grass and covered with five films of different thickness and colour: 90 μm, white; 125 μm, green; 150 μm, black; 200 μm, green and 200 μm, white. Four replications of each film type were placed in the open air. Two replications were housed indoors and exposed to an ‘artificial sky’ in a test apparatus. The surface temperature of the films was found to be strongly dependent on film thickness and colour. Results of the chemical analysis of silages did not reveal any significant influence of the films. This was also the case when restricting the analysis to the uppermost silage layer. The results showed that under the conditions of this experiment, well preserved forage can be produced with films of differing colour, as well as of lesser thickness.

Notes: Narrow-leaved bird's-foot-trefoil (Lotus tenuis) is a perennial forage legume adapted to waterlogged and heavy and infertile soils and can replace alfalfa (Medicago sativa) in areas with these soils in Argentina. Its seeds are hard and water-impermeable but the effects of environmental factors on seed dormancy and germination are not known. The objective was to evaluate the hypothesis that water availability during seed development and maturation affects the degree of hardseededness in L. tenuis by changing seed coat properties, conditioning water uptake through the seed coat; and subsequently affecting dormancy, germination and speed of germination. Seeds were harvested in December/January and in February in both 1993/1994 and 1994/1995 from a permanent pasture of L. tenuis growing in a Hapludol soil in San Miguel del Monte province of Buenos Aires. Environmental conditions of each anthesis-harvest period were determined. Seeds of each harvest were subjected to chilling, washing and mechanical scarification. After 12 months seeds from each harvest were observed in a scanning electron microscope. The water deficit of the soil and relative humidity were greater in the second than the first anthesis-harvest period in both seasons. In 1993/1994 the control treatment in December had a higher germination rate than the February control seeds (0·40 vs. 0·20) and a faster germination rate. Mechanical scarification and chilling significantly enhanced the germination rate (0·95) and its speed in seeds of both harvests. Low temperatures significantly enhanced germination rate, starting after 60 d for the seeds harvested in December, and 90 d for the seeds harvested in February. In 1994/1995 the results were similar but both the January and February control treatments had higher germination rates (0·60 vs. 0·40) than in the previous year. Seeds harvested in February were more dormant in both years. These differences could be explained by the conditions in February anthesis-harvest period in both years that could have hastened the natural dehydration process of seed, changing integument structure and enhancing its impermeability.

Notes: In a replicated field experiment carried out in Northern Ireland in 1998, the effects of sowing date (17 April, 5 May, 19 May and 1 June), cultivar of forage maize (Hudson and Diamant) and treatments with no mulch (NP), total cover plastic mulch (TC), TC plastic mulch removed at eight-leaf growth stage (EL) and punch plastic mulch (PU) on the rate of development of the crop and the accumulation of dry matter (DM) in the whole plant and cobs were described. Soil and air temperatures under the mulch treatments and in the open were recorded and the daily accumulation of Ontario heat units (OUs) calculated for each treatment based on the air temperatures experienced by the crop for the periods that it was under plastic mulch and in the open.The interval from sowing to emergence was proportional to the accumulated heat units above a soil base temperature of 8·2°C. The phenology of leaf emergence varied widely in terms of calendar date across the sowing date and plastic mulch treatments but relative to adjusted OUs the treatments were more closely aligned. Treatment PU advanced the crop less than the other mulch treatments relative to calendar date but, relative to OUs, more than these treatments. Physical damage to plants emerging through the TC treatment and air temperatures exceeding 40°C during the first month under treatments TC and EL did not appear to retard physiological development. The total adjusted OUs to reach 50% silking ranged from 1432 to 1753. Close relationships were found between the total OUs from silking to harvest and the whole crop DM content, cob DM content, cob yield and starch concentration of the whole crop at harvest so that differences between the treatments could largely be accounted for by the differences in silking date. It was concluded that the OU system can provide a reasonable model of maize growth for crops sown under TC plastic mulch providing air temperatures under the plastic are used for the period that the crop experiences them. However, the OU system is less reliable for crops grown under punch plastic because of the soil warming effect of the mulch that is not taken into account by the OU system.

Notes: Three Lolium perenne L. genotypes collected from different natural habitats were tested for the effects of their fungal endophyte Neotyphodium spp. on plant growth and seed yield. Half the clones of the originally infected plants were subjected to fungicide treatment to eradicate the endophytes. In an experiment, the clones were planted separately into pots and were either watered adequately or subjected to drought stress. In the genotype collected from a dry site, the endophyte infection reduced plant growth at an adequate water supply, but increased regrowth under drought. In the genotype from a periodically either flooded or dry site, endophyte infection significantly promoted the development of reproductive tillers and seed production (effects which are associated with adaptation to drought). In contrast, the genotype that originated from a wet site showed higher sensitivity to drought stress when endophyte infection was present. The results suggest that environmental conditions in the original habitat of the plants may influence the symbiotic interaction between plant and fungus, probably through natural selection. However, endophyte-induced increases in root dry weight and root/shoot ratio were recorded for all three genotypes. These features could be beneficial for plant persistence, especially on sites where water is the growth-limiting factor.