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  • Weitere Quellen  (78)
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  • 1
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    Elsevier
    In:  Amsterdam, 404 pp., Elsevier, vol. 19, pp. 503, (ISBN 0121341305)
    Publikationsdatum: 1998
    Schlagwort(e): Seismics (controlled source seismology) ; Reflection seismics ; Handbook of geophysics
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  • 2
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    Elsevier
    In:  Amsterdam, Elsevier, vol. 1, no. ALEX(01)-FR-77-01, AFTAC Contract F08606-76-C-0025, pp. 95-104, (ISBN 1-85312-745-0)
    Publikationsdatum: 1998
    Schlagwort(e): Inversion ; Elasticity ; Geothermics ; Scattering ; soil ; Modelling ; Fluids ; Acoustics
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  • 3
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    Elsevier
    In:  Amsterdam, 394 pp., Elsevier, vol. 46, no. XVI:, pp. 1-14, (ISBN 3-9808493-1-7)
    Publikationsdatum: 1998
    Schlagwort(e): oil ; gas ; Textbook of geophysics ; Textbook of engineering
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  • 4
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    Elsevier
    In:  Amsterdam, Elsevier, vol. 6, no. 22, pp. 71-80, (ISBN 0-87590-422-X)
    Publikationsdatum: 1998
    Schlagwort(e): Elasticity ; Textbook of geophysics ; Ritz ; Kirchhoff ; p-Ritz ; software ; Textbook of engineering
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  • 5
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    Elsevier
    In:  Amsterdam, 346 pp., Elsevier, vol. 1, no. 1, pp. 65-66, (ISBN 3-936546-23-1, 2. Auflage 2005. 876 Seiten + CD-ROM)
    Publikationsdatum: 1998
    Schlagwort(e): Seismology ; Textbook of geophysics ; Textbook of geology
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  • 6
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    Elsevier
    In:  Amsterdam, Elsevier, vol. 5, no. 1, pp. 799-804, (ISBN 1-4020-1777-4 (hb) and ISBN 1-4020-1778-2 (pb))
    Publikationsdatum: 1998
    Schlagwort(e): Handbook of geophysics ; Gravimetry, Gravitation ; Geomagnetics ; Hilbert transform ; digital signal analysis (also DSP) ; Data analysis / ~ processing ; Fast Fourier transf. ; Spectrum ; Correlation ; Filter- ; discrete ; DFT ; Maximum likelihood
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  • 7
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    Elsevier
    In:  Amsterdam, Elsevier, vol. 47, no. 22, pp. 65-70, (ISBN 3-7643-0253-4)
    Publikationsdatum: 1998
    Schlagwort(e): Modelling ; Finite Element Method ; Elasticity ; Error analysis ; Acoustics
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  • 8
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    Elsevier
    In:  Chemical Geology, 145 (3-4). pp. 287-323.
    Publikationsdatum: 2018-02-07
    Beschreibung: Detrital sediment is carried from land to the sea by three agents, rivers, glaciers, and winds. The shoreline is an arbitrary boundary within the detrital sediment transport system, which extends from a site of origin across areas of temporary storage to a site of long-term deposition. The most important of the agents moving sediment across the land is river transport, estimated to be in the order of 20×1012 kg of sediment annually at present. Analysis of drainage basins indicates that relief and runoff are the most important factors in determining the sediment load of rivers. The competence of rivers to transport sediment is governed by the volume flow, gradient, and the sediment load itself. Today, most large rivers are fed by snowmelt in highland areas, runoff from rainfall in the drainage basin, and groundwater inflow. Along the river course, water is lost to evaporation and groundwater infiltration. River courses can often be divided into two segments, a degradational section in which the gradient is relatively steep and little temporary storage of sediment takes place, and an aggradational section where the gradient is sharply reduced through meandering, and where large-scale temporary sediment storage forms a flood plain. Lakes trap sediment inland and prevent its transport to the sea. Today, many high and mid-latitude rivers are interrupted by lakes of glacial origin. There are also some large areas of internal drainage that deliver no sediment to the sea. The load carried by rivers has been markedly altered by human activity, and may have doubled over the past few thousand years, only to be reduced in the past century by the widespread construction of dams. The ancient use of fire in hunting and its subsequent use in clearing land has increased erosion. Extensive deforestation and cultivation processes have also increased the sediment supply. Dam construction is a relatively new factor and affects the sediment transport system by trapping sediment before it can reach the sea. The resulting lower sediment supply from rivers is, at least in part, compensated by increased coastal erosion. Glacial erosion is difficult to estimate. There is an ongoing controversy whether ice sheets are effective erosive agents or not. Estimates of the present global flux of glacial detritus range from 0.8–50×1012 kg annually, with the lower value most probable. The dust flux is in the order of 0.5 to 0.9×1012 kg annually, but may vary greatly with time.
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  • 9
    Publikationsdatum: 2019-01-24
    Beschreibung: The Laptev Sea is of great significance for studying the processes of the initial breakup of continents. It is the southern termination of the Gakkel spreading ridge and thus the location of structural features resulting from a continental margin/spreading ridge intersection. The present-day understanding of the Laptev Shelf geology is based on the Russian multichannel seismic reflection data and extrapolation of the terrestrial geology. Geologic and plate-kinematic data are used to constrain the interpretation of the seismic reflection data. The Laptev Rift System consists of several deep subsided rifts and high standing blocks of the basement. From west to east these are: the West Laptev and South Laptev rift basins, Ust' Lena Rift, East Laptev and Stolbovoi horsts, Bel'kov-Svyatoi Nos and Anisin rifts. The central and eastern parts of the shelf have the greatest contrasts in the gravity field ranging from −60 mGal over the rifts to 50 mGal over the horsts. The rifts contain up to five seismic stratigraphic units bounded by clear regional reflectors and underlain by folded heterogeneous basement. They are suggested to be Late Cretaceous to Holocene in age and reflect different stages of spreading ridge/continental margin interaction. The estimated total thickness of the rift-related sediments varies between 4 and 8–10 km while the sedimentary cover on the uplifts is significantly reduced and generally does not exceed 1–2 km. An eastward decrease of the total thickness of the sedimentary sections from about 10 km in the South Laptev Basin to 4–5 km in the Bel'kov-Svyatoi Nos Rift and the simplicity of the entire rift structure may indicate a rejuvenation of the rifts in the same direction. The entire rift system is covered by the uppermost seismic unit, which probably reflects a deceleration of the rifting during the last reorganization of the North American/Eurasian plate interaction since about 2 Ma.
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  • 10
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    Elsevier
    In:  Continental Shelf Research, 17 (15). pp. 1839-1867.
    Publikationsdatum: 2016-09-21
    Beschreibung: AVHRR satellite imagery of the southern Mid-Atlantic Bight during May 1993 revealed a large area of cold water over the shelf break and slope that appeared to spin up into a series of southward propagating anticyclonic eddies. The eddies had diameters of 35–45 km at the surface and moved southward at about 20 cm/sec. A radial TOYO CTD (to 50m) and ADCP velocity (to 400m) transect was conducted across the southern-most of these eddies. The upper 50 meters had minimum temperatures of less than 7°C and salinities of about 33 pss, characteristics similar to cold pool waters usually found over the continental shelf. ADCP velocity data from one of the eddies revealed anticyclonic flow extending to a depth of about 250m. The transport of cold pool water by the eddies was estimated to be 0.1 to 0.2 Sv which is of the same order as the annual mean alongshore transport of shelf water in this region. The origin of the deeper water within the eddy is unlikely to be the continental shelf because the shelf break is less than 100 m. The depth and velocity profiles along the TOYO transect were consistent with the constant potential vorticity eddy model of Flierl (1979) although the source of the eddy kinetic energy is uncertain. The cause for the exodus of cold pool water from the shelf, which extended northward to at least 38°N, is unclear but must involve the establishment of an alongshore baroclinic pressure gradient against the usual southwestward shelf flow. It is possible that the intrusion of Gulf Stream waters onto the shelf near Cape Hatteras was a precursor of this off shelf transport. The southern-most eddy was marked by high biological productivity and very high oxygen supersaturation. The phytoplankton bloom detected within the exported cold pool water, located over the continental slope, suggests a mechanism whereby production fueled by nutrients derived from the shelf can be locally exported into deep water
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  • 11
    Publikationsdatum: 2017-06-27
    Beschreibung: A seasonally-varying sedimentation pattern was observed for the alkenone flux measured with sediment traps in the northern North Atlantic. In the Norwegian Sea (traps were set at 500, 1000 and 3000 m) the alkenone flux varied between 0.1 and 7.1 μg m−2 d−1 and followed the seasonal pattern of the bulk parameters. Maximum fluxes occurred from mid-October until mid-November and were also high in May. A surprising result was that considerably higher particle fluxes were observed at 3000 m. For the alkenone flux, the highest additional input of 250% was observed during the period when sediment resuspension was greatest in summer. At the Barents Sea continental margin (traps at 1840 and 1950 m) the alkenone fluxes follow the sedimentation pattern of the bulk parameters, with a less visible signal of distinct seasonality observed in the 1950 m trap. The sedimentation of total alkenones varied between 0.8 and 144 μg m−2 d−1 at 1840 m and between 0.5 and 31.0 μg m−2 d−1 at 1950 m. Resuspension and lateral advection contributed significantly to measured fluxes in the two near-bottom traps. Alkenone concentrations were determined in faecal pellets of Appendicularia, ostracods and euphausids from selected samples at the Barents Sea site. The alkenone flux in pellets (4% to 24% of total) was 5 to 6 times higher at 1950 m depth than at 1840 m and the major part (77–78%) of the total flux of C37:3 reaching the near-bottom trap at 1950 m was associated with faecal pellets of the meso-zooplankton. Spatial and temporal variations of the U37k′ signals were observed, indicating that the imprint in the alkenone signal depends on the origin and transport pathway of the organic material. Strong deviations occur in areas where nepheloid layers contribute particles of long residence times to the primary flux.
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  • 12
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    Elsevier
    In:  Cold Regions Science and Technology, 27 (3). pp. 225-243.
    Publikationsdatum: 2017-12-11
    Beschreibung: The main objective of this research paper is to estimate the new-ice production in the Laptev Sea flaw lead during the 1991/1992 winter season. A one-dimensional energy balance model was applied to calculate ocean-to-atmosphere heat flux and the resulting new-ice formation over open water. For a detailed estimate of regional ice production, the flaw lead was divided into 14 sections based on the analysis of NOAA-satellite images and Russian ice charts. Opening and maintenance of the lead sections are controlled by offshore winds, whereas closing of open water is caused by onshore winds. Since the orientation of the lead varies from section to section, the same regional wind forcing can cause different local lead behavior. Model results reveal that the seasonally accumulated thickness of new ice formed in the different lead sections—under the assumption of instantaneous lateral new-ice removal from the water surface—varies from 1.3 m to 13 m over temporarily open water and may reach 20 m over permanently open water. The corresponding ice volume produced in the sections varies between 3.4 km3 and 59 km3 and amounts to 258 km3 for the entire lead. The significant regional variations in new-ice production are due to differences in (i) the number of days that a lead section is open (open-lead days), (ii) the oceanic heat loss during open-lead days, and (iii) the areal extent of the lead sections. As compared to other studies,—at least during 1991/1992 winter season—the Laptev Sea flaw lead produced between 28 and 617% more initial sea ice than the Kara, Barents, East Siberian and Chukchi leads. Despite its limited areal extent of roughly 36,000 km2, which represents only 8% of the entire Laptev Sea, the flaw lead produces about 32% of the annual shelf ice. The ice production in the flaw lead is 5.3 times higher than the remainder of the shelf (7.4 m vs. 1.4 m). Furthermore, the Laptev Sea flaw lead produces 2.6% of the ice annually formed the entire Arctic Mediterranean Sea and contributes about 9% to the volume of the Siberian branch of the Transpolar Drift Ice System. This makes the Laptev Sea flaw lead a significant producer of Arctic sea ice on local and regional scales, whereas the contribution of lead ice to the entire volume of annually formed pack in high northern latitudes amounts only to roughly 1.3%.
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  • 13
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    Elsevier
    In:  Deep-Sea Research Part I-Oceanographic Research Papers, 45 (12). pp. 2189-2200.
    Publikationsdatum: 2015-08-27
    Beschreibung: The vestimentiferan tubeworm Riftia pachyptila derives most or all of its nutrition from intracellular chemosynthetic bacterial symbionts. Because purified preparations of symbionts respire nitrate, possibly nitrite, and oxygen, host transport of nitrate is a topic of interest. In the present study, we have developed a nitrate detection assay that utilizes a nitrite reductase-deficient Escherichia coli strain for the reduction of nitrate to nitrite, which is then determined spectrophotometrically. Nitrate and nitrite concentrations were measured in the blood and coelomic fluids of R. pachyptila collected from hydrothermal vent sites at 9°N and 13°N. The blood was shown to have nitrate concentrations up to one hundred times that of ambient sea water (40 μM). Blood nitrate levels reached concentrations of 〉1 mM, while nitrite was measured in the range of 400–700 μM. The concentrations of nitrate and nitrite in the coelomic fluids were 150–240 μM and 〈20 μM, respectively. The nitrate determination technique we present here is simple, applicable for laboratory and shipboard use on sea water or biological fluids, and works reliably within the 0.5 to 2000 μM range.
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  • 14
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    Elsevier
    In:  Marine Environmental Research, 45 (3). pp. 295-307.
    Publikationsdatum: 2017-05-30
    Beschreibung: Eight techniques for cleaning particulate material and epibionts from the tissue of Fucus vesiculosus were tested on seaweed collected from a metal-contaminated estuary in the southwest of England. When assessed by scanning electron microscopy, only one was found to have efficiently removed the particulate material on the tissue. This technique consisted of applying a 1:9 ethanol:seawater mixture to the surface of the thallus, and scraping with a PTFE spatula. Analysis of Cu, As, Fe, Mn, and Zn content in the tissues cleaned by this technique showed that, in this case, only Fe concentrations decreased significantly when compared to tissue cleaned by rinsing in seawater only. The study is the first to systematically assess cleaning techniques for marine macroalgae and illustrates the need for standard methods for the sampling and analysis of seaweed tissue
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  • 15
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    Elsevier
    In:  Marine Chemistry, 59 (3-4). pp. 283-300.
    Publikationsdatum: 2017-05-30
    Beschreibung: Variations in the speciation of iron in the northern North Sea were investigated in an area covering at least two different water masses and an algal bloom, using a combination of techniques. Catalytic cathodic stripping voltammetry was used to measure the concentrations of reactive iron (FeR) and total iron (FeT) in unfiltered samples, while dissolved iron (FeD) was measured by GFAAS after extraction of filtered sea water. FeR was defined by the amount of iron that complexed with 20 μM 1-nitroso-2-napthol (NN) at pH 6.9. FeT was determined after UV-digestion at pH 2.4. Concentrations of natural organic iron complexing ligands and values for conditional stability constants, were determined in unfiltered samples by titration. Mean concentrations of 1.3 nM for FeR, 10.0 nM for FeT and 1.7 nM for FeD were obtained for the area sampled. FeR concentrations increased towards the south of the area investigated, as a result of the increased influence of continental run off. FeR concentrations were found to be enhanced below the nutricline (below ∼40 m) as a result of the remineralisation of organic material. Enhanced levels of FeT were observed in some surface samples and in samples collected below 30 m at stations in the south of the area studied, thought to be a result of high concentrations of biogenic particulate material and the resuspended sediments respectively. FeD concentrations varied between values similar to those of FeT in samples from the north of the area to values similar to those of FeR in the south. The bloom was thought to have influenced the distribution of both FeR and FeT, but less evidence was observed for any influence on FeR and FeD. The concentration of organic complexing ligands, which could possibly include a contribution from adsorption sites on particulate material, increased slightly in the bloom area and in North Sea waters. Iron was found to be fully (99.9%) complexed by the organic complexing ligands at a pH of 6.9 and largely complexed (82–96%) at pH 8. The ligands were almost saturated with iron suggesting that the ligand concentration could limit the concentration of iron occurring as dissolved species.
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  • 16
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    Elsevier
    In:  Fitoterapia, 69 (6). p. 552.
    Publikationsdatum: 2015-10-07
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  • 17
    Publikationsdatum: 2017-05-30
    Beschreibung: Short-term iron enrichment experiments were carried out with samples collected in areas with different phytoplankton activity in the northern North Sea and northeast Atlantic Ocean in the summer of 1993. The research area was dominated by high numbers of pico-phytoplankton, up to 70,000 ml−1. Maximum chlorophyll a concentrations varied from about 1.0 μg l−1 in a high-reflectance zone (caused by loose coccoliths, remnants from a bloom of Emiliania huxleyi) and about 3.5 μg l−1 in a zone in which the phytoplankton were growing, to about 0.5 μg l−1 in the northeast Atlantic Ocean. From the high-reflectance zone to the northeast Atlantic Ocean, nitrate concentrations increased from 0.5 μM to 6.0 μM. Concentrations of reactive iron in surface water showed an opposite trend and decreased from about 2.6 nM in the high-reflectance zone to 〈1.0 nM in the northeast Atlantic Ocean. In the research area, no signs of true iron deficiency were found, but iron enrichments in the high-reflectance zone, numerically dominated by Synechococcus sp., resulted in increased nitrate uptake. Ammonium uptake was hardly affected. Strong support for the effect of Fe on cell physiology is given by the increase in the f-ratio. Net growth rates of the phytoplankton (changes in cell numbers over 24 h) were almost unchanged. Phytoplankton collected from the northeast Atlantic Ocean, did not show changes in the nitrogen metabolism upon addition of iron. Net growth rates in these incubations were low or negative, with only slightly higher values with additional iron.
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  • 18
    Publikationsdatum: 2015-11-24
    Beschreibung: An ultra-violet laser ablation microprobe (UVLAMP) has been applied for the first time to investigate argon partition coefficients for olivines and clinopyroxenes grown from silicate melts at 1 bar argon pressure. These preliminary measurements yield crystal/melt partition coefficients ranging from 0.138 (±0.01) to 0.013 (±0.003) for olivine and 0.589 (±0.003) to 0.0016 (±0.0005) for clinopyroxene. The higher values may indicate sub-microscopic melt inclusions, or some other heterogeneous distributions of `non-equilibrium' argon in the crystals. The lower values are probably more representative of true partition coefficients and fall at least an order of magnitude below the previously reported experimental data. The possibility of anomalous, high argon contents for crystals in previous studies is discussed in terms of surface adsorption, `trapped' argon and early partial melting.
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  • 19
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    Elsevier
    In:  In: From magma to tephra: Modelling physical processes of explosive volcanic eruptions. Developments in Volcanology (4). Elsevier, Amsterdam, Netherlands, pp. 173-245.
    Publikationsdatum: 2020-05-28
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  • 20
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    Elsevier
    In:  , ed. by Freundt, A. and Rosi, M. Developments in Volcanology, 4 . Elsevier, Amsterdam, 318 pp.
    Publikationsdatum: 2020-03-24
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  • 21
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    Elsevier
    In:  Earth and Planetary Science Letters, 160 . 369-381.
    Publikationsdatum: 2016-11-15
    Beschreibung: Oxygen isotope ratios were obtained from authigenic clinoptilolites from Barbados Accretionary Complex, Yamato Basin, and Exmouth Plateau sediments (ODP Sites 672, 797, and 762) in order to investigate the isotopic fractionation between clinoptilolite and pore water at early diagenetic stages and low temperatures. Dehydrated clinoptilolites display isotopic ratios for the zeolite framework (δ18Of) that extend from +18.7‰ to +32.8‰ (vs. SMOW). In combination with associated pore water isotope data, the oxygen isotopic fractionation between clinoptilolite and pore fluids could be assessed in the temperature range from 25°C to 40°C. The resulting fractionation factors of 1.032 at 25°C and 1.027 at 40°C are in good agreement with the theoretically determined oxygen isotope fractionation between clinoptilolite and water. Calculations of isotopic temperatures illustrate that clinoptilolite formation occurred at relatively low temperatures of 17°C to 29°C in Barbados Ridge sediments and at 33°C to 62°C in the Yamato Basin. These data support a low-temperature origin of clinoptilolite and contradict the assumption that elevated temperatures are the main controlling factor for authigenic clinoptilolite formation. Increasing clinoptilolite δ18Of values with depth indicate that clinoptilolites which are now in the deeper parts of the zeolite-bearing intervals had either formed at lower temperatures (17–20°C) or under closed system conditions.
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  • 22
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    Elsevier
    In:  Organic Geochemistry, 29 (1-3). pp. 363-379.
    Publikationsdatum: 2017-08-09
    Beschreibung: Concentrations of hydrocarbon gases and stable carbon isotope ratios of methane from the water column of Shaban, Kebrit, Atlantis II and Discovery deeps, Red Sea, have been determined. Methane concentrations (yield C1) range from 〈 50 nL/L (Red Sea deep water) to ca. 22 × 10−3 L/L (Kebrit brine). Stable carbon isotopes of methane are between −30 and 43‰. Hydrocarbon gases in the brines are originally of thermogenetic origin (Kebrit: C1/C2∼ 57; δ13C1 ∼ −30‰). Methane concentrations in the transition zones between brines and Red Sea deep water decreased, especially in the Atlantis II/Discovery deeps, associated with a strong shift of δ13C1 to positive values. This shift is related to bacterial oxidation of methane in the transition zone between brine layers and overlying Red Sea deep water. Oxidized methane mixes with Red Sea deep water methane. A connection between the Atlantis II and the Discovery brine is postulated on the basis of the geochemical data.
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  • 23
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    Elsevier
    In:  Journal of Quantitative Spectroscopy and Radiative Transfer, 60 (3). pp. 355-363.
    Publikationsdatum: 2017-08-18
    Beschreibung: The single scattering properties of nonspherical raindrops have been calculated by means of the geometric optics approximation to ascertain the usefulness of lidar remote sensing of rainrates. Based on the theoretical hydrodynamical studies of Chuang and Beard (J. Atmos. Sci., 1990, 47, 1374Ð1389), a Chebyshe¤-series of shape coe¦cients has been selected to account for the size dependent particle nonsphericity. The single scattering calculations for randomly oriented raindrops with particle radii ranging from 0.5 to 4.5mm exhibit a very pronounced dependence of the phase matrix on particle shape. However, most of these changes are not monotonic with increasing size, which complicates correlations between rainrates and the radiative properties of the raindrops. A comparison of ray tracing results by Chebyshe¤-type particles and axis-ratio equivalent spheroids shows signiÞcant di¤erences for particles with radii larger than 1 mm. Backscattering intensity as well as linear and circular depolarization ratios for horizontally oriented raindrops show a non-monotonic increase with particle size. The size distribution averaged backscattering properties are poorly correlated with rainrates. We conclude that lidar remote sensing of rainrates does not seem to be a promising attempt. However, this conclusion may be subject to changes if raindrop oscillations, which have not been considered in this study, a¤ect the size distribution averaged backscattering properties.
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  • 24
    Publikationsdatum: 2017-08-21
    Beschreibung: Concentrations of 23 individual chlorobiphenyls (CBs) and 6 polyaromatic hydrocarbons (PAHs) were determined in different water masses of the North Atlantic Ocean around Iceland. The study was carried out in the framework of the second Intergovernmental Oceanographic Commission (IOC) baseline studies of contaminants in the North Atlantic Ocean, involving trace organics and trace elements. Concentrations of individual CBs were extremely low. In solution, they varied between 〈2 and 126 fg dm−3 and in suspension between 〈2 and 1400 fg dm−3. The values for their sum (∑CB) were between 10 and 1048 in solution, and 286–11 241 fg dm−3 in suspension. ∑PAHs were present in the 〈5–65 pg dm−3 range, p,p′-DDE and hexachlorobenzene were 〈2 fg dm−3. The concentrations of CBs and PAHs decreased from the surface towards the bottom at each station. The lowest concentrations were found in Norwegian Sea Deep Water (∑CB 10 fg dm−3), concurrent with the lowest halocarbon concentrations found during the cruise. Values in near-surface waters were considerably lower than those determined at mid-latitudes of the North Atlantic. These findings reflect the mixing of water bodies with higher CB concentrations from the central North Atlantic with less contaminated waters from the Arctic Ocean. Concentrations in suspension exceeded those in solution in most samples, as a result of the relatively high suspended matter concentrations in the waters around Iceland. Particulate CB and PAH concentrations were positively correlated with particulate organic carbon concentrations. This suggests that suspended organic material is a carrier for these relatively apolar organic compounds in the water column. The data do not support the co-distillation concept suggested in the literature.
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  • 25
    Publikationsdatum: 2017-08-21
    Beschreibung: In 1995, we participated in a number of WOCE Hydrographic Program cruises in the Indian Ocean as part of the Joint Global Ocean Flux Study (JGOFS) CO2 Survey sponsored by the Department of Energy (DOE). Two titration systems were used throughout this study to determine the pH, total alkalinity (TA) and total inorganic carbon dioxide (TCO2) of the samples collected during these cruises. The performance of these systems was monitored by making closed cell titration measurements on Certified Reference Materials (CRMs). A total of 962 titrations were made on six batches of CRMs during the cruises. The reproducibility calculated from these titrations was ±0.007 in pH, ±4.2 μmol kg−1 in TA, and ±4.1 μmol kg−1 in TCO2. The at-sea measurements on the CRMs were in reasonable agreement with laboratory measurements made on the same batches. These results demonstrate that the CRMs can be used as a reference standard for TA and to monitor the performance of titration systems at sea. Measurements made on the various legs of the cruise agreed to within 6 μmol kg−1 at the 15 crossover points. The overall mean and standard deviation of the differences at all the crossovers are 2.1±2.1 μmol kg−1. These crossover results are quite consistent with the overall reproducibility of the CRM analyses for TA (±4 μmol kg−1) over the duration of the entire survey. The TA results for the Indian Ocean cruises provide a reliable data set that when combined with TCO2 data can completely characterize the carbonate system.
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  • 26
    Publikationsdatum: 2017-08-18
    Beschreibung: Two single-operator multiparameter metabolic analyzers (SOMMA)-coulometry systems (I and II) for total carbon dioxide (TCO2) were placed on board the R/V Knorr for the US component of the Indian Ocean CO2 Survey in conjunction with the World Ocean Circulation Experiment-WOCE Hydrographic Program (WHP). The systems were used by six different measurement groups on 10 WHP Cruises beginning in December 1994 and ending in January 1996. A total of 18,828 individual samples were analyzed for TCO2 during the survey. This paper assesses the analytical quality of these data and the effect of several key factors on instrument performance. Data quality is assessed from the accuracy and precision of certified reference material (CRM) analyses from three different CRM batches. The precision of the method was 1.2 μmol/kg. The mean and standard deviation of the differences between the known TCO2 for the CRM (certified value) and the CRM TCO2 determined by SOMMA-coulometry were −0.91±0.58 (n=470) and −1.01±0.44 (n=513) μmol/kg for systems I and II, respectively, representing an accuracy of 0.05% for both systems. Measurements of TCO2 made on 12 crossover stations during the survey agreed to within 3 μmol/kg with an overall mean and standard deviation of the differences of −0.78±1.74 μmol/kg (n=600). The crossover results are therefore consistent with the precision of the CRM analyses. After 14 months of nearly continuous use, the accurate and the virtually identical performance statistics for the two systems indicate that the cooperative survey effort was extraordinarily successful and will yield a high quality data set capable of fulfilling the objectives of the survey.
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  • 27
    Publikationsdatum: 2017-06-26
    Beschreibung: The form of the Deccan-Maldives-Mascarene-Réunion hotspot trace suggests that it has, at least in part, been strongly controlled by crustal structures, especially fracture zones. This makes it difficult to assess the present-day or past location of the hotspot, and thus complicates the interpretation of African plate motion reconstruction. We present here results of a cruise to the Réunion area of which the aims were: (a) to determine the extent of present-day volcanism associated with the Réunion hotspot in the region; and (b) to examine the rôle of pre-existing oceanic crustal structures in controlling the location of present-day volcanism. Additionally, we examined the morphology and geology of the important extinct spreading centre southwest of Réunion abandoned when spreading jumped to separate Seychelles from India during the Deccan flood basalt episode some 60–65 Ma ago. The extensive bathymetrie, seismic and geological investigation shows that significant present-day hotspot volcanism is confined to the Piton de la Fournaise edifice on Réunion Island itself. Apparently, the location of recent Réunion volcanism has not been controlled by a crustal fracture and the major fracture zones on both sides of the island are not acting as magma conduits. For plate motion reconstruction and plume flux calculation purposes, Piton de la Fournaise must be taken as the present location of the Réunion hotspot. Accretion at the extinct spreading centre progressively ceased at the time of anomaly A27 (63 Ma), and was associated with marked propagation of the rift tips.
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  • 28
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    Elsevier
    In:  Earth and Planetary Science Letters, 158 . pp. 121-130.
    Publikationsdatum: 2020-03-20
    Beschreibung: A high resolution Pb isotope time-series for the last 26 Ma, dated by 10Be/9Be chronology, is reported for a north Indian Ocean ferromanganese crust. This record is compared with available Pb isotope time-series of six other crusts from the Atlantic, Indian and Pacific Oceans, each of which is based on 10Be/9Be chronology. The seven Pb isotope records reveal some remarkable features. In contrast to the Nd isotope time-series of these crusts which show a long-term (∼60 Ma) provinciality between the three main ocean basins, the Pb isotopes only show comparable provinciality over the last ∼5 Ma. Prior to about 15 Ma ago no distinct Indian Ocean Pb isotope signal existed. Within this established framework of Pb isotope distribution in the oceans the 208Pb/206Pb data for the north Indian Ocean crust reported here are anomalous. The 208Pb/206Pb ratio is particularly high and exceeds a value of 2.08 during the time interval from 20 to 8 Ma ago. Consideration of potential sources of Pb in the Indian Ocean which might provide such high 208Pb/206Pb ratios suggests that this crust most probably has recorded a time-varying erosional input of Pb from the Himalayas. The timing of the isotopic shift is in good agreement with maximum Himalayan exhumation rates deduced from crystallisation and cooling ages of synorogenic granites (20–14 Ma) and the sedimentation history of the Bengal Fan.
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  • 29
    Publikationsdatum: 2017-12-11
    Beschreibung: A PYE 2-(1-pyrenyl)ethyldimethylsilylated silica gel] column HPLC in combination with MDGC-ECD has been developed for a sensitive and selective determination of toxic mono- and non-ortho PCBs in environmental samples. This technique was applied to environmental samples such as coastal water, suspended particulate material (SPM), coastal sediment, mussels, fish, bird and marine mammal. Determination of PCB 156 along with non-ortho congeners acted as matrix-integrated quality control parameter. This hyphenated technique offers one of the most sensitive way of determining non-ortho PCBs but also reveals the immense complexity of the coelution problem which unnoticed results in over estimation of toxic PCBs in the environmental samples.
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  • 30
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    Elsevier
    In:  Marine Geology, 148 . pp. 9-20.
    Publikationsdatum: 2017-06-27
    Beschreibung: The deep-sea borehole seal CORK was deployed for the first time on a modern accretionary prism during ODP Leg 146 to the Cascadia Margin. Ten months after the deployment the fluid flow and geochemistry of the borehole fluids was investigated during several dives by DSRV Alvin. The chemical analysis of the borehole fluids revealed methane concentrations of more than 3.5 mM, whereas oxygen and dissolved ions as Cl, NO3, or PO4 are still close to the ambient seawater composition. The exceedingly high methane content measured at the top of the sealed borehole and the observed degassing during the ascent of the submersible indicates that the sampled fluid was initially saturated or close to saturation with respect to CH4. The hydrocarbons are characterized by ratios of 170–200 and δ13C values of − 59.5 to − 62.4%o which indicates a considerable admixture of thermogenic hydrocarbon gases. The occurrence of methane of partly thermogenic origin demonstrates that CH4 enters the sealed borehole in the lower, perforated section (94–178 mbsf) and accumulates at the top of the borehole. This suggests the occurrence of free gas within the encapsulated borehole. Considering the stability field of CH4-hydrates, the formation of these ice-like structures may take place and potentially results in a clogging of the top of the borehole. Such precipitates could result in a decoupling of the top of the borehole from the hydraulic and geochemical regime of the accretionary complex, an important aspect for future plans of CORK deployments.
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  • 31
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    Elsevier
    In:  Deep Sea Research Part I: Oceanographic Research Papers, 45 (4-5). pp. 507-527.
    Publikationsdatum: 2016-10-20
    Beschreibung: Hydrographic and tracer [chlorofluorocarbon (CFC), component F11] data in the tropical Atlantic off Brazil taken in spring 1994 are used to describe the development of the water mass characteristics of Antarctic Bottom Water (AABW) between 10 degrees S and 11 degrees N. To compute the AABW transports, geostrophic computations and directly measured velocity fields are combined. Velocity profiles were measured with the Pegasus profiling system and an ADCP attached to the CTD. The F11 increase from 10 degrees S to 11 degrees N, mainly in the upper part of the tracer-poor AABW, reveals the mixing of AABW along its path with the overlying North Atlantic Deep Water, which carries a significant F11 signal in the equatorial Atlantic. While propagating north of 5 degrees S, the AABW shifts to higher salinities at a given temperature. About one-third of the northward flowing AABW at 10 degrees S (4.8 Sv) and at 5 degrees S (4.7 Sv) west of about 31 degrees 30'W enters the Guiana Basin, mainly through the southern half of the Equatorial Channel at 35 degrees W (1.5-1.8 Sv). The other part recirculates and some of it flows through the Romanche Fracture Zone into the eastern Atlantic. In the Guiana Basin, west of 40 degrees W, the sloping topography and the strong, eastward flowing deep western boundary current might prevent the AABW from flowing west: thus it has to turn north at the eastern slope of the Ceara Rise (2.2 Sv). At 44 degrees W, north of the Ceara Rise, AABW flows west in the interior of the basin in a main core near 7 degrees 15'N (1.9 Sv). A net return how of about 0.5 Sv was found north of 8 degrees 43'N. A large fraction of the AABW (1.1 Sv) enters the eastern Atlantic through the Vema Fracture Zone, leaving only 0.3 Sv of AABW for the western Atlantic basins
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  • 32
    Publikationsdatum: 2018-01-09
    Beschreibung: The sediments recovered on ODP Leg 104 have been reported to be characterized by hiatuses. The hiatuses were defined by biostratigraphy and were believed to be caused by erosion related to temporary changes of bottom current composition and velocity. They have been associated with major paleoenvironmental changes, reorganization of global deep water production, and increased bottom water flows. Because of the importance of hiatuses for ongoing research, we decided to closely investigate the sedimentation history for the most significant Pliocene and Miocene biostratigraphic hiatuses by sedimentologic and geochemical means. The sedimentologic studies include clay mineral distributions, grain size data, and organic carbon concentrations. The geochemical studies include determination of Full-size image (〈1 K)Sr ratios, 10Be and Ir concentrations. The results of the sedimentologic studies suggest either that paleoenvironmental changes associated with hiatuses are not represented in the preserved sediments, or that the hiatuses are an artifact of interpretation of the biostratigraphic data. Strontium isotopes indicate continuous sedimentation for the interval investigated at Site 642, an interpretation confirmed by the steady decline in 10Be. Full-size image (〈1 K)Sr ratios in the interval from above and below proposed hiatuses H Full-size image (〈1 K) and Full-size image (〈1 K) at Site 643 display stronger changes with depth than expected by steady sedimentation. Ir data for this same interval indicate reduced sedimentation rates. Combining both, sedimentologic and geochemical evidence, the proposed hiatuses could not be confirmed and may represent preservation artifacts.
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  • 33
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    Elsevier
    In:  Progress in Oceanography, 42 . pp. 189-207.
    Publikationsdatum: 2016-10-07
    Beschreibung: In the context of the European OMEX Programme this investigation focused on gradients in the biomass and activity of the small benthic size spectrum along a transect across the Goban Spur from the outer Celtic Sea into Porcupine Abyssal Plain. The effects of food pulses (seasonal, episodic) on this part of the benthic size spectrum were investigated. Sediments sampled during eight expeditions at different seasons covering a range from 200 m to 4800 m water depth were assayed with biochemical bulk measurements: determinations of chloroplastic pigment equivalents (CPE), the sum of chlorophyll a and its breakdown products, provide information concerning the input of phytodetrital matter to the seafloor; phospholipids were analyzed to estimate the total biomass of small benthic organisms (including bacteria, fungi, flagellata, protozoa and small metazoan meiofauna). A new term `small size class biomass' (SSCB) is introduced for the biomass of the smallest size classes of sediment-inhabiting organisms; the reduction of fluorescein-di-acetate (FDA) was determined to evaluate the potential activity of ester-cleaving bacterial exoenzymes in the sediment samples. At all stations benthic biomass was predominantly composed of the small size spectrum (90% on the shelf; 97–98% in the bathyal and abyssal parts of the transect). Small size class biomass (integrated over a 10 cm sediment column) ranged from 8 g C m−2 on the shelf to 2.1 g C m−2 on the adjacent Porcupine Abyssal Plain, exponentially decreasing with increasing water depth. However, a correlation between water depth and SSCB, macrofauna biomass as well as metazoan meiofauna biomass exhibited a significantly flatter slope for the small size classes in comparison to the larger organisms. CPE values indicated a pronounced seasonal cycle on the shelf and upper slope with twin peaks of phytodetrital deposition in mid spring and late summer. The deeper stations seem to receive a single annual flux maximum in late summer. SSCB and heterotrophic activity are significantly correlated to the amount of sediment-bound pigments. Seasonality in pigment concentrations is clearly followed by SSCB and activity. In contrast to macro- and megafauna which integrate over larger periods (months/years), the small benthic size classes, namely bacteria and foraminifera, proved to be the most reactive potential of the benthic communities to any perturbations on short time scales (days/weeks). The small size classes, therefore, occupy a key role in early diagenetic processes.
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  • 34
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    Elsevier
    In:  Quaternary Science Reviews, 17 (8). pp. 689-694.
    Publikationsdatum: 2016-06-16
    Beschreibung: Despite the large decline in Northern Hemisphere summer insolation during the last 8000 years, neither sea level nor polar temperatures have as yet undergone any significant downturn. This behavior is consistent with the prediction by Kukla and Matthews (1972) that the Holocene interglacial will terminate suddenly with a jump to another of the climate system's modes of operation. This is what happened at the end of the last period of peak interglaciation. However, complicating the situation is evidence that ice sheet growth during the transition from marine stage 5e to 5d preceded the shut down of the Atlantic's conveyor circulation which is thought to have brought Europe's Eemian to a close. If so, then in the natural course of events, the end of the present interglaciation awaits the onset of ice cap growth. However, it must be kept in mind that the ongoing buildup of greenhouse gases may alter the natural course of events. In particular, the warming and wetting of the planet will gradually reduce the density of surface waters in the regions where deep waters form. As this reduction is not likely to be symmetrical between the northern Atlantic and the margin of the Antarctic continent, the current near balance between deep water production in the north and south may be disrupted causing an abrupt reorganization of the ocean's thermohaline circulation. Based on the paleoclimatic record, such a reorganization would have had a profound impact on the planet's climate.
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  • 35
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    Elsevier
    In:  International Journal for Parasitology, 28 (12). pp. 1939-1941.
    Publikationsdatum: 2020-07-28
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  • 36
    Publikationsdatum: 2017-06-26
    Beschreibung: A sediment core, collected from the western part of the continental slope of the Ross Sea at 2380 m water depth, records events of the last two climatic cycles (250 kyr). A Full-size image (〈1 K)-based chronology was obtained and boundaries of the isotope stages were set assuming that biological productivity was enhanced during periods of less ice cover. Then, Full-size image (〈1 K), organic carbon, biogenic silica and biogenic Ba distributions were compared to the glacial–interglacial stage boundaries and corresponding ages of the Full-size image (〈1 K) record of Martinson et al. [Martinson, D.G., Pisias, N.G., Hays, J.D., Imbrie, J., Moore, T.C., Jr., Shackleton, N.J, 1987. Age dating and the orbital theory of the ice ages: development of a high-resolution 0 to 300,000-year chronostratigraphy. Quaternary Research, 27: 1–29]. Sediment accumulation rates ranged between 1.2 cm kyr−1 in the isotope stage 6 and 3.8 cm kyr−1 during the Holocene. Variations in the concentrations and fluxes of organic carbon, biogenic Ba, biogenic silica and Mn gave information on palaeoclimate changes. Processes of sediment redistribution in the Ross Sea margin were enlightened from a comparison of the measured and expected fluxes of Full-size image (〈1 K). Calculation of the focusing-corrected accumulation rates of biogenic Ba enabled us to evaluate the export palaeoproductivity. Corrected accumulation rates of biogenic components and calculated palaeoproductivities were low, compared to the Antarctic Polar Front in the Atlantic sector, throughout the last two climatic cycles. Glacial–interglacial changes of sea ice cover and ventilation of the Ross Sea were probably major causes of variations in biogenic particle flux and distribution of redox-sensitive elements within the sediment column.
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  • 37
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    Elsevier
    In:  Continental Shelf Research, 18 (14-15). pp. 1795-1806.
    Publikationsdatum: 2019-07-02
    Beschreibung: The effluent activity from a well-known pockmark structure in Eckernförde Bay was monitored for methane, salinity, and temperature signals in the water column intermittently over three years between 1991, 1993 and 1994. Groundwater discharge from an aquifer into the brackish waters of the western Baltic, dilutes bottom water salinities to values as low as 2.9‰. Seasurface height and the amount of precipitation preceding sampling periods by 5 days correlated significantly with the rate of groundwater discharge. Concentrations of methane in bottom water at the pockmark site were strongly influenced by seepage intensity. At two sampling sites (control and pockmark site) distinctly lower methane concentrations were observed towards the sea surface, although the entire water body of Eckernförde Bay appears to be affected by methane seeping from the sediments. This is supported by high methane concentrations above equilibrium with atmospheric methane throughout most of the year. Maximum concentration above the equilibrium value in surface waters was 2800‰. Methane flux from surface waters into the atmosphere follows strong seasonal variations, with maximum values in the winter (200–400 μmol m-2 d-1). The study reveals the important role of coastal oceans in the global methane cycle, as an intense but variable source of methane of largely unknown magnitude.
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  • 38
    Publikationsdatum: 2020-07-28
    Beschreibung: The sedimentary structure preserved within the seabed of Eckernförde Bay was investigated together with the oceanographic processes influencing that structure. A series of four cruises were undertaken during winter to summer conditions. An instrumented tetrapod was deployed to monitor boundary-layer processes controlling sediment transport. Coring devices recovered sediment to examine the benthic biological community, to measure rates of sedimentological processes, and to document sedimentary structure. During fair-weather conditions, the dominant mechanism for supplying sediment to Eckern-förde Bay is import from the Baltic Sea associated with internal waves. Earlier work has documented the erosion of shallow deposits during storms and the transport of this material to deeper sites in the Bay. Bottom shear stresses exerted in the Central Basin during all conditions are below critical stresses, which makes the Bay an excellent sediment trap. Sediment from both distant and local origins is reworked in the Central Basin of Eckernförde Bay by a pioneering community of benthic organisms, which is maintained by seasonal hypoxia/anoxia. The population is characterized by few species, small body sizes, young ages, and limited depth of mixing (∼1 cm). However, the community effectively pelletizes most of the sediment reaching the seabed. The very restricted thickness for the surface mixed layer (∼1 cm) and the substantial sediment accumulation rates (mean of 0.39 cm yr-1 for the Central Basin) give sediment a short exposure to modern oceanographic processes before being buried. These conditions allow for partial preservation of sediment deposited as storm layers, thus forming laminations of unpelletized sediment. These laminations separate thick beds of pelletized sediment deposited during fair weather or as thin storm layers (i.e., 〈1 cm thick). In general, the oceanographic processes in Eckernförde Bay allow for preservation of a high-resolution record of environmental processes. For example, changes recorded for the past half century indicate that slower sediment accumulation rates previously characterized some portions of the study area.
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  • 39
    Publikationsdatum: 2014-02-03
    Beschreibung: The development of a highly sensitive system for the shipboard determination of dissolved iron at the sub-nM level is presented. The technique is based on a flow injection method coupled with luminol chemiluminescence detection. Dissolved Fe(II+lII) levels are determined after Fe(III) reduction using sulphite and in-line matrix elimination/preconcentration on an 8-hydroxyquinoline (8-quinolinol) chelating resin column. The detection limit (3s) is 40 pM when 1.5 ml of sample is loaded onto the column, and the relative standard deviation is 3.2 (n=5) for a 1.0 nM Fe sample. One analytical cycle can be completed in 3 min. The automated method proved reliable when employed on-board the RRS James Clark Ross during Autumn 1996, mapping dissolvable Fe(II+III) levels along the Atlantic Meridional Transect from 50°N to 50°S. Data from vertical profiles through the upper water column are presented.
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  • 40
    Publikationsdatum: 2014-02-03
    Beschreibung: The validation of a fully automated dissolved Ni monitor for in situ estuarine studies is presented, based on adsorptive cathodic stripping voltammetry (AdCSV). Dissolved Ni concentrations were determined following on-line filtration and UV digestion, and addition of an AdCSV ligand (dimethyl glyoxime) and pH buffer (N-2-hydroxyethylpiperazine-N'-2-ethanesulphonic acid). The technique is capable of up to six fully quantified Ni measurements per hour. The automated in situ methodology was applied successfully during two surveys on the Tamar estuary (south west Britain). The strongly varying sample matrix encountered in the estuarine system did not present analytical interferences, and each sample was quantified using internal standard additions. Up to 37 Ni measurements were performed during each survey, which involved 13h of continuous sampling and analysis. The high resolution data from the winter and summer tidal cycle studies allowed a thorough interpretation of the biogeochemical processes in the studied estuarine system. Copyright (C) 1998 Elsevier Science B.V.
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  • 41
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    Elsevier
    In:  Analytica Chimica Acta, 377 (2-3). pp. 205-215.
    Publikationsdatum: 2014-02-04
    Beschreibung: Geochemical processes in estuarine and coastal waters often occur on temporally and spatially small scales, resulting in variability of metal speciation and dissolved concentrations. Thus, surveys, which are aimed to improve our understanding of metal behaviour in such systems, benefit from high-resolution, interactive sampling campaigns. The present paper discusses a high-resolution approach to coastal monitoring, with the application of an automated voltammetric metal analyser for on-line measurements of dissolved trace metals in the Gulf of Cadiz, south-west Spain. This coastal sea receives metal-rich inputs from a metalliferous mining area, mainly via the Huelva estuary. On-line measurements of dissolved Cu, Zn, Ni and Co were carried out on-board ship during an eight-day sampling campaign in the study area in June 1997. A pumping system operated continuously underway and provided sampled water from a depth of ca. 4m. Total dissolved metal concentrations measured on-line in the Gulf of Cadiz ranged between 〈5nM Cu (〈3nM Ni) ca. 50km off-shore and 60-90nM Cu (5-13nM Ni) in the vicinity of the Huelva estuary. The survey revealed steep gradients and strong tidal variability in the dissolved metal plume extending from the Huelva estuary into the Gulf of Cadiz. Further on-line measurements were carried out with the automatic metal monitor from the bank of the Odiel estuary over a full tidal cycle, at dissolved metal concentrations in the μM range. The application confirmed the suitability of the automated metal monitor for coastal sampling, and demonstrated its adaptability to a wide range of environmental conditions in the dynamic waters of estuaries and coastal seas. The near-real time acquisition of dissolved metal concentrations at high resolution enabled an interactive sampling campaign and therefore the close investigation of tidal variability in the development of the Huelva estuary metal plume. Copyright (C) 1998 Elsevier Science B.V.
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  • 42
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    Elsevier
    In:  Phytochemistry, 49 (1). pp. 137-143.
    Publikationsdatum: 2020-06-11
    Beschreibung: Eight new diterpenoids of labdane class, leopersin M-Q (1-3, 5, 6), 15-epi-leopersin O and Q (4, 7) and 19-hydroxygaleopsin (8) were isolated from the aerial parts of Leonurus persicus, besides a flavone, genkwanin (9). Their structures were established by spectroscopic means, mainly by 1D and 2D NMR.
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  • 43
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    Elsevier
    In:  Phytochemistry, 48 (5). pp. 867-873.
    Publikationsdatum: 2020-06-11
    Beschreibung: Four new allose-containing triterpenoid saponosides, scabriosides A, B, C and D were isolated from the roots of Scabiosa rotata. Their structures were established as 3-O-beta-D-xylopyranosyl-28-O-[beta-D-allopyranosyl (1--〉6)-beta-D-glucopyranosyl]-pomolic acid, 3-O-[alpha-L-rhamnopyranosyl (1--〉2)-beta-D-xylopyranosyl]-28-O-[beta-D-allopyranosyl (1--〉6)-beta-D-glucopyranosyl]-pomolic acid, 3-O-[alpha-L-rhamnopyranosyl (1--〉2)-alpha-L-arabinopyranosyl]-28-O-[beta-D-allopyranosyl (1--〉6)-beta-D-glucopyranosyl]-pomolic acid, and 3-O-[beta-D-glucopyranosyl (1--〉3)-alpha-L-rhamnopyranosyl (1--〉2)-beta-D-xylopyranosyl]-28-O-[beta-D-allopyranosyl(1--〉6) -beta-D-glucopyranosyl]-pomolic acid, respectively, by the help of spectral evidence (IR, 1D- and 2D-NMR, FAB-MS).
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  • 44
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    Elsevier
    In:  Continental Shelf Research, 18 (14-15). pp. 1671-1688.
    Publikationsdatum: 2020-07-28
    Beschreibung: Methane gas bubbles, generated by biochemical processes, are ubiquitous in the organic-rich, muddy sediments of coastal waters and shallow adjacent seas. Seismic surveys have provided considerable information on the spatial distribution of these gassy sediments. The basic biogeochemical processes responsible for methane generation and consumption are well known and models of acoustic and mechanical behavior of gassy sediments have been developed and tested under laboratory conditions. In spite of the considerable past effort, methane bubble distribution and concentration and the resultant sediment behavior have remained unpredictable prior to the studies described herein. This special issue of Continental Shelf Research describes the results of joint US/German led experiments designed to physically characterize and model the effects of benthic boundary layer processes on seafloor structure, properties, and behavior in the gassy sediments of Eckernforde Bay, Baltic Sea. Spatial and temporal distribution of the acoustic turbidity horizon, methane concentration, and the volume, size, shape, and distribution of bubbles are described for the first time. A kinetic model of the complex biochemical interactions of bacterial methane production and consumption, advective and diffusive transport processes, organic supply, and sedimentation rates has successfully been used to predict methane and sulfate concentration profiles, rates of biogeochemical reactions, and gas volumes. The spatial distribution and strength of acoustic turbidity is accurately predicted by these biochemical models, whereas the seasonal migration of the acoustic turbidity horizon correlates with changes in sediment temperature and is modeled using methane solubility. Short-term ebullition of methane from the sediment surface correlates with rapid change in bottom pressure or an increase in hydraulic flow from subbottom aquifers. Fine-scale characterization of bubble volume, shape, and size distribution coupled with concomitant in situ measurement of sound speed, attenuation, and scattering strength has allowed validation of frequency dependent acoustic scattering and propagation models. Eckernforde Bay is without doubt the most studied and well-understood area of gassy sediments and as such provides a 'natural laboratory' for future studies.
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  • 45
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    Unbekannt
    Elsevier
    In:  Continental Shelf Research, 18 (14-15). pp. 1893-1915.
    Publikationsdatum: 2020-07-28
    Beschreibung: A bottom-mounted, circularly scanning sonar was used to observe the methane-rich seafloor of Eckernforde Bay during the months of April and May in 1993, Event-like changes in the acoustic signal were observed and are shown to be caused by scatterers in the water column that are interpreted to be gas bubbles rising in columns having transverse dimensions 2-5 m. The events do not correlate with seafloor current stress, temperature, or refraction due to stratification, but a strong correlation is seen with pressure at the seafloor, consistent with gas ebullition due to pressure release. It is not possible to definitively exclude scattering from pelagic animals as the cause of these events, but the observed localization at a few spots on the seafloor appears to be inconsistent with the biological explanation. These data are insufficient to determine the flux of free methane, but bounds are estimated and suggestions are made for future measurements that could determine flux
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  • 46
    Publikationsdatum: 2016-11-15
    Beschreibung: Gabbro and minor metabasalt fragments of MORB composition were found on three of the seven Canary Islands. On Gran Canaria, they occur as metamorphosed (greenschist facies) metabasalt and metagabbro clasts in Miocene fanglomerates and sandstones overlying the shield basalts. On Lanzarote and La Palma, MORB gabbros occur as xenoliths in Pleistocene and historic basanite scoria cones and lava flows. The MORB xenoliths are interpreted as fragments of layers 2 and 3 of the underlying Mesozoic oceanic crust, based on mineral compositions (An-rich plagioclase, Ti- and Al-poor clinopyroxene, ± orthopyroxene ± olivine), depleted major and trace element signatures, and Jurassic ages (ca. 180 Ma) determined on single primary plagioclase and secondary amphibole crystals using the 40Ar/39Ar laser technique. The Lanzarote gabbros are very mafic (mg# 87 to 89 in clinopyroxene), moderately deformed, and highly depleted. Gran Canaria gabbros are more evolved (mg# 69 to 83 in clinopyroxene) and texturally mostly isotropic. La Palma MORB gabbros have a range of compositions (mg# 68 to 83 in clinopyroxene), some rocks being strongly metasomatized by interaction with basanite magma. The occurrence of MORB fragments on Lanzarote provides definite evidence that oceanic crust beneath the Canary Island archipelago continues at least as far east as the eastern Canary Islands. We postulate that MORB gabbros on Lanzarote which are commonly associated with peridotite xenoliths, represent the base of oceanic layer 3 where gabbros and peridotites were possibly tectonically interleaved. Such tectonic mixing would explain the enigmatic seismic velocities in this area. Gabbro xenoliths from La Palma were derived from within layer 3, probably from wall rock close to magma reservoirs emplaced during the Pleistocene/Holocene growth of La Palma. The Gran Canaria xenoliths are interpreted to represent the metamorphosed layer 2 and upper layer 3. The abundance of lower crustal xenoliths emphasizes the importance of the lower crust and crust-mantle boundary zone as a major level of magma accumulation.
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  • 47
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    Unbekannt
    Elsevier
    In:  Chemical Geology, 145 (3-4). pp. 447-460.
    Publikationsdatum: 2019-06-11
    Beschreibung: The similarity of the Lu–Hf and Sm–Nd isotope system during most mantle differentiation processes makes the combination of 176Hf/177Hf and 143Nd/144Nd a very sensitive indicator of a select number of processes. This paper present new Hf-isotope data for a large number of ocean islands and examines the Hf–Nd–Pb isotope relations of oceanic volcanics. Except for HIMU islands, St. Helena and Tubaii, the Hf and Nd isotope ratios in ocean island basalts (OIB) are extremely well correlated. It is argued that crustal recycling (by either continental or oceanic sediments) most likely did not cause the Hf–Nd variations. The correlated 176Hf/177Hf–143Nd/144Nd variations in OIB most likely represent the time integrated fractionations which are the result of melting in the presence of garnet. The Hf-isotope systematics of HIMU-type OIB are consistent with these basalts representing recycled oceanic crust and thus support the earlier hypothesis on the origins of HIMU basalts. Chondrites form an array that is at high angle with the OIB array. This allows a choice in the 143Nd/144Nd and 176Hf/177Hf values for chondritic bulk earth. With a choice of bulk earth at the extreme end of the OIB array the shift of OIB to higher 176Hf/177Hf can be explained by either isolation of a significant amount of basalts from the mantle for several billions of year or by fractionation and isolation of small amounts (〈1%) of perovskite, during the early history of the Earth. The large range in Hf-isotopes for a limited range in Nd-isotopes in MORB can be explained by addition of small amounts (≪1%) of the perovskite material back into the MORB mantle. If chondritic BE is chosen to be internal to the OIB, the well correlated Hf–Nd isotope characteristics in OIB argue against the fractionation of perovskite during the early history of the Earth and the shape of the MORB field remains an enigma.
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  • 48
    Publikationsdatum: 2019-07-01
    Beschreibung: DSDP/ODP drilling in the northern North Atlantic reveals that so far the onset of northern hemisphere cooling deduced from the occurrence of ice-rafted debris (IRD) in deep-sea sediments can be traced back to the middle Miocene. The Greenland ice sheet has probably the longest history on the northern hemisphere. Leg 151 site 909 (Fram Strait) recovered a unique continuous sediment record dating from early/middle Miocene. The composition of the coarse fraction indicates that the oldest IRD pulses are documented around 14 Ma in the Fram Strait (site 909) and around 12.6 Ma on the Vöring Plateau (leg 104, site 642) in the Norwegian–Greenland Sea. Fram Strait site 909 indicates a further stepwise increase of northern hemisphere cooling by serveral IRD pulses during late Miocene (between 10.8 and 8.6 Ma, around 7.2, 6.8 and 6.3 Ma), which ultimately led to a drastic intensification of northern hemisphere glaciation during Plio–Pleistocene. The deep-sea sediment records show that Plio–Pleistocene strengthening of IRD pulses have been observed since approximately 4.0 Ma in the westernmost Norwegian–Greenland Sea and Labrador Sea; by contrast, strengthening of IRD pulses are observed at approximately 3.2–2.7 Ma on the eastern side of the Norwegian–Greenland Sea, including the Barents Sea margin. Sediment composition and physical properties of the drilled, mostly terrigenous sections reveal that orbital parameters have controlled major aspects of shallow and deep-water environments with frequency domains related to 41 ka periods of obliquity dominant in the pre-glacial Miocene, Pliocene and early Quaternary and to 100 ka periods of eccentricity dominant during the past 600,000–700,000 years. The stratigraphy of ice-rafted material reveals a frequently and rapidly changing history of the dynamics of various segments in ice sheets around the Norwegian–Greenland Sea. It is particularly evident from the composition of the ice-rafted material that the Eurasian ice sheets delivered IRD to the eastern part of the Norwegian–Greenland Sea, whereas Greenland source areas are represented in the drill sites of the east Greenland continental margin and in the Labrador Sea. The stratigraphic sequences on the Yermak Plateau suggest that the Svalbard ice sheet may have extended far to the north prior to oxygen isope stage 16 but not since then. Invasions of temperate Atlantic waters during interglacials can be observed as short-lived and rather irregular events. It never reached the area off eastern Greenland except during the Pliocene interval, when tundra floras were able to develop on north-eastern Greenland and planktonic foraminifers suggesting the presence of temperate water masses in the Fram Strait as been documented in the drill sites from the Yermak Plateau.
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  • 49
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    Unbekannt
    Elsevier
    In:  Deep Sea Research Part I: Oceanographic Research Papers, 45 (7). pp. 1085-1109.
    Publikationsdatum: 2019-07-02
    Beschreibung: Production of biogenic silica and dissolution processes in the water column and surface sediment are important aspects for the investigation and reconstruction of present and past productivity of the ocean. Although the geological record of biogenic silica is often used as a proxy for paleoceanographic processes in the Southern Ocean, little is known about the present regional distribution of biogenic silica flux and accumulation and their relation to primary production in surface waters. Based on more than 130 sediment and pore water samples, the regional differences of the biogenic silica flux to the sea floor of the southern South Atlantic were investigated. In contrast to biogenic silica content, the dissolved Si-flux through the sediment/water interface, caused by intense dissolution of BSi in surface sediments, reflects biogenic production in surface waters. This was inferred by observed increases of Si-fluxes in regions of recurrent polynya formation or in the vicinity of Marginal Ice Zones as at the Weddell-Scotia Sea boundary. In the Scotia Sea, where no benthic fluxes were reported before, we found a considerable burial of biogenic silica and biogenic silica fluxes to the sea floor of ∼800–1300 mmol m-2 a-1. This is a significantly higher flux than derived for the known opal accumulation area in the SE Atlantic, further to the east in the Antarctic Circumpolar Current, where a flux of ∼600–767 mmol m-2 a-1 was observed. This shows that the Scotia Sea is not a gap within the Circumpolar Antarctic Opal Belt as previously assumed. The geochemical budget for different sub-regions of the South Atlantic was considered by a Geographic Information System. In contrast to most previous attempts, this ensures the accurate consideration of the spatial distribution of sampling sites, a crucial aspect for the accuracy of geochemical budgets. For the South Atlantic we calculated the flux of biogenic silica to the sea floor as ∼5.1×1012 mol a-1. Only ∼0.84×1012 mol a-1 is buried in these sediments, which is considerably less than previous estimates.
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  • 50
    Publikationsdatum: 2021-05-04
    Beschreibung: Some aspects of the biology and fishery of Octopus vulgaris caught by trawlers in the Balearic Sea (Western Mediterranean) are studied. The analysis of the size–frequency distribution followed the growth of specimens from January (6–7 cm ML) to August (11–12 cm ML). The sex ratio was estimated for each season and it was not significantly different from 1 : 1 in any of them. The stomach contents revealed that the octopus fed predominantly on crustaceans and fishes. Another octopus species, Eledone moschata, is present in this fishery but its catches were clearly lower than those of O. vulgaris. The analysis of the importance of these two species in relation to the rest of the commercial catch showed that octopuses represent between 20–40% of the total catch for trawlers. The highest catch rates (kg/h) were obtained in spring and at the beginning of summer. Time-series analysis of monthly catches from January 1981 to August 1996 showed two main oscillations. The lower one, with a periodicity of 12 months, reflects the annual biological cycle of the species; on the other hand, the higher one has a periodicity of 92 months, the time series available being too short to confirm the significance of this period.
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  • 51
    Publikationsdatum: 2021-04-22
    Beschreibung: A small-scale trap fishery for many benthic species is carried out along the coastal shelves of the Canary Islands (Central-East Atlantic) by small boats (7.5 to 12.4 m in length). The target species of the fishery are seabreams (Sparidae), but substantial numbers of octopus (Octopus vulgaris) are also landed. In this paper, we report fishing data for octopus landed at the port of Mogán (Southwest of Gran Canaria) from 1989 to 1996. The landing of O. vulgaris increased steadily from 1989 to 1994, from 7 t to 25 t. However, in 1995, the catch fell to the level of 1989 (7 t), and in 1996 was only 6 t, the lowest figure for the decade. The CPUE shows two seasonal peaks of maximal abundance, one in April–May and the other in September–November, both coinciding with reproductive periods, while the lowest figure is in summer (July–August). We describe the fishing methods and the seasonal variations of the catch records and fishing effort in relation to years and market strategies.
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  • 52
    Publikationsdatum: 2021-04-29
    Beschreibung: The cuttlefish Sepia pharaonis (maximum 250 mm mantle length, ML) and S. dollfusi (maximum 150 mm ML) are widely distributed in the Indo-Pacific from the Red Sea to Japan and Australia. They are the primary fishery in the Suez Canal and the most valuable commercial cephalopods in the northern Indian Ocean. However, their reproductive biology, essential for fishery management, is poorly known. Four maturity stages were described using morphology and histology. Based on the proportions of each maturity stage, as well as various maturity indices, spawning was found to take place from March to June for S. pharaonis and January to April for S. dollfusi. The size at maturity for S. pharaonis was 61 and 122 mm ML for males and females, respectively. In contrast, the size at maturity for S. dollfusi was similar in both the sexes (75 and 84 mm ML for males and females, respectively). Fecundity was estimated by counting the number of maturing and mature ova, which varied from 75 to 1525 for S. pharaonis and 30 to 273 for S. dollfusi. The monthly size-frequency distribution of ova provides evidence for the accuracy of the fecundity estimates. The data suggest that reproduction extends over ≈6–9 months; this probably represents the latter 1/2–2/3 of the life cycle, and may be typical for sepioid and teuthoid cephalopods.
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  • 53
    Publikationsdatum: 2021-04-29
    Beschreibung: The feeding ecology of Greenland halibut (Reinhardtius hippoglossoides) on the deep slope of the northeast Newfoundland continental shelf was investigated based on stomach analysis. Stomach samples were collected from the spring 1992 Canadian bottom trawl fishery at depths of 1000–1250 m. The squid, Gonatus spp., predominated in the diet, representing the first known instance of reliance of Greenland halibut upon this bathypelagic squid as prey in Canadian waters. A change from predation primarily upon pelagic prey, reported in earlier studies, may be related to annual variability in abundance and distribution of both Greenland halibut and its principal pelagic fish prey species, capelin (Mallotus villosus). Seasonal effects may account for the absence of epipelagic, juvenile Gonatus spp. from the diet. There was a linear size relationship in observed predation which may reflect a common size-related depth distribution pattern between predator and prey or, more likely, prey selectivity. At larger sizes, Greenland halibut switched from Gonatus spp. to groundfish as its principal prey. The importance of Gonatus spp. in the deep continental slope trophic web is reviewed.
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  • 54
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    Unbekannt
    Elsevier
    In:  Continental Shelf Research, 18 (14-15). pp. 1859-1892.
    Publikationsdatum: 2020-07-28
    Beschreibung: Acoustic turbidity caused by the presence of gas bubbles in seafloor sediments is a common occurrence worldwide,but is as yet poorly understood. The Coastal Benthic Boundary Layer experiment in the Baltic off northern Germany was planned to better characterize the acoustic response of a bubbly sediment horizon. In this context, in situ measurements of compressional wave speed and attenuation were made over the frequency range of 5–400 kHz in gassy sediments of Eckernförde Bay. Dispersion of compressional speed data was used to determine the upper limit of the frequency of methane bubble resonance at between 20 and 25 kHz. These data, combined with bubble size distributions determined from CT scans of sediments in cores retained at ambient pressure, yield estimates of effective bubble sizes of 0.3–5.0 mm equivalent radius. The highly variable spatial distribution of bubble volume and bubble size distribution is used to reconcile the otherwise contradictory frequency-dependent speed and attenuation data with theory. At acoustic frequencies above resonance (〉25 kHz) compressional speed is unaffected by bubbles and scattering from bubbles dominates attenuation. At frequencies below resonance (〈1 kHz) ‘compressibility effects’ dominate, speed is much lower (250 m s-1) than bubble-free sediments, and attenuation is dominated by scattering from impedance contrasts. Between 1.5 and 25 kHz bubble resonance greatly affects speed and attenuation. Compressional speed in gassy sediments (1100–1200 m s-1) determined at 5–15 kHz is variable and higher than predicted by theory (〈250 m s-1). These higher measured speeds result from two factors: speeds are an average of lower speeds in gassy sediments and higher speeds in bubble-free sediments; and the volume of smaller-sized bubbles which contribute to the lower observed speeds is much lower than total gas volume. The frequency-dependent acoustic propagation is further complicated as the mixture of bubble sizes selectively strips energy near bubble resonance frequencies (very high attenuation) allowing lower and higher frequency energy to propagate. It was also demonstrated that acoustic characterization of gassy sediments can be used to define bubble size distribution and fractional volume.
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  • 55
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    Unbekannt
    Elsevier
    In:  Biological Conservation, 86 (1). pp. 37-56.
    Publikationsdatum: 2021-06-15
    Beschreibung: Large numbers of seabirds are killed each year within the Australian Fishing Zone (AFZ) by Japanese longline vessels targeting tuna. In recent years the estimated rate of seabird bycatch in the AFZ has been in the order of 0.15 birds/1000 hooks, translating to mortalities of 1000–3500 birds per year. These estimates are absolute minima because not all birds killed remain on hooks to be observed hauled aboard the vessels. The observed seabird catch rate varies annually, seasonally and spatially. Most birds are killed: (a) during the summer fishing season (October to March), even though most fishing effort occurs in winter; (b) when longlines are set during the day; (c) in the waters around southern Australia. Uncertainties in the observed catch rates prevent confident assessment of trends, but seabird catch rates do not appear to be showing a sustained decrease. The process of the incidental collection of seabird bycatch data (by observers whose priority is to fish sampling tasks) renders the seabird bycatch data inadequate for reliable assessment of trends in total numbers of birds killed over time. Sixteen seabird species of birds killed on longlines in the AFZ have been identified. These include black-browed (Diomedea melanophris), shy (D. cauta), grey-headed (D. chrysostoma), yellow-nosed (D. chlororhynchos) and wandering albatrosses (D. exulans), flesh-footed shearwaters (Puffinus carneipes) and white-chinned petrels (Procellaria aequinoctialis). Seventy-four per cent of birds killed were albatrosses and the species composition of the bycatch varied with seasons and areas. Most species of birds killed were characterised by unequal representation of sex and age cohorts, and these unequal representations were not consistent between fishing grounds or seasons.
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  • 56
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    Unbekannt
    Elsevier
    In:  Science of the Total Environment, 220 (1). pp. 71-80.
    Publikationsdatum: 2021-06-28
    Beschreibung: Three hundred and fifty individuals of 12 species of cephalopods which differed in their feeding habitats were sampled from the French Atlantic coast to the sub-Arctic region (Bay of Biscay, English Channel, west Irish coast and Faroe Islands) and analysed for their cadmium contents. Comparison of the Cd levels of the cephalopods showed that those from the sub-Arctic area contained very high Cd concentrations compared to those from lower latitudes such as along the French Atlantic coast. High Cd levels in cephalopods from the sub-Arctic zone correspond closely to the reported high Cd concentrations in the tissues of top vertebrate predators from the same area. Comparison of the weekly Cd intakes for the Faroe Island pilot whales with the `Provisional Tolerable Weekly Intake' for humans recommended by the World Health Organisation, showed that top vertebrate predators are often subjected to Cd doses far in excess of those recommended for humans. Our limited survey results suggest that cephalopods constitute an important source of Cd for cephalopod predators, and that this bioaccumulation effect is most evident at high latitudes.
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  • 57
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    Unbekannt
    Elsevier
    In:  Journal of Experimental Marine Biology and Ecology, 229 (2). pp. 289-302.
    Publikationsdatum: 2021-07-21
    Beschreibung: Temperature and ration level can differentially affect growth and life history characteristics of marine organisms. In this experiment we reared juvenile cuttlefish, Sepia elliptica, under two feeding regimes (satiation and half satiation) and two temperature regimes (25 and 30°C). This study examined differences in somatic growth, muscle tissue structure and composition as a function of temperature and food levels. We estimated body mass and the concentration of water, carbohydrate, protein and lipid in the mantle muscle tissue for each individual. Both high water temperature and high feeding rations increased growth rates. Temperature appeared to change the rates of muscle fibre generation and fibre growth similarly. In contrast, the ration level altered the relative rates of fibre production and fibre growth. The muscle tissue of individuals reared at 30°C had higher concentrations of carbohydrate and protein. In contrast, increasing ration levels only increased carbohydrate concentrations in the muscle tissue. The muscle tissue of reared juveniles had lower concentrations of carbohydrate and protein than wild individuals of similar size. In conclusion, water temperature and feeding levels both affect somatic growth, but the nature of the effect at the sub-organismal level differs.
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  • 58
    Publikationsdatum: 2017-01-04
    Beschreibung: Atmospheric and dissolved methane (CH4) and nitrous oxide (N2O) were measured in the unique coastal ecosystem of the Bodden waters, including the western Oder estuary, (southern Baltic Sea) during five campaigns between 1994 and 1997. The CH4 saturations, ranging from 105-15 500%, showed great spatial and temporal variability with maximum values in September and minimum values in December. The N2O saturations were in the range of 91-312% with a maximum in March. Enhanced concentrations of both gases were observed only in the western Oder estuary near the mouth of the Peene River. Thus, we conclude that the distributions of CH4 and N2O in the investigated Bodden waters are, directly or indirectly, linked to the Peene River runoff and not to the Oder River. Our estimate of the annual CH4 emissions from the Bodden waters to the atmosphere indicates a significant contribution (c. 17%) to the overall CH4 emissions from the Baltic Sea. In contrast, the Bodden waters represent only a small source for atmospheric N2O. CH4 production rates estimated from sediment slurry experiments revealed a significant spatial variability and indicated that methanogenic activity was related to acetate consumption in the surface sediment layer. Sedimentary CH4 production might depend on different amounts of accumulation of organic material. (C) 1998 Academic Press
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  • 59
    Publikationsdatum: 2017-05-23
    Beschreibung: A new generation multiple collector plasma source mass spectrometer (PSMS) produced by Nu Instruments Ltd is evaluated. The instrument has a double-focusing Nier–Johnson analyser with laminated magnet and a novel variable dispersion ion optical arrangement, enabling all masses to be located in the centre of the Faraday collectors of a fixed static array. mThe performance of the instrument has been assessed through the analysis of NBS-981 Pb using a Tl doping technique with Faraday collector efficiencies and amplifier gains determined independently. A second method of analysis involves comparison of interspersed standard and sample Pb measurements with effective gains for each collector determined from the standards. In both cases the repetition of Pb isotope measurement is competetive with the thermal ionization mass spectrometry (TIMS) double-spike method
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  • 60
    Publikationsdatum: 2016-11-14
    Beschreibung: Two ferromanganese crusts from the Indian Ocean and one from the Atlantic Ocean have been analysed for 10Be/9Be, 143Nd/144Nd and 208,207,206Pb/204Pb ratios as a function of depth beneath their growth surfaces. 10Be/9Be ratios provide growth rate estimates for these crusts between 1.55 and 2.82 mm Ma−1 and further suggest that 87Sr/86Sr in crusts do not in any case examined so far provide reliable estimates for growth rates. A crust ALV-539 from 35°N in the western N. Atlantic has ϵNd and Pb-isotope variations indistinguishable from crust BM-1969.05 from 39°N in the N. Atlantic [K.W. Burton, H.-F. Ling, R.K. O'Nions, Closure of the central American isthmus and its impact on North Atlantic deepwater circulation, Nature (London) 386 (1997) 382–385] when 10Be/10Be ratios are used to estimate growth rates. Both crusts provide evidence for a marked change in deepwater composition in the western N. Atlantic with a reduction in ϵNd and an increase in 206Pb/204Pb from ∼8 Ma ago towards the present day. The two crusts from the Indian Ocean show comparatively small variations in ϵNd between −8.0 and −7.0 over the last 20 Ma and do not show the large shift in ϵNd seen in the Atlantic crusts. Comparison of ϵNd in the crusts analysed here with those published previously [H.-F. Ling, K.W. Burton, R.K. O'Nions, B.S. Kamber, F. von Blanckenburg, A.J. Gibb, J.R. Hein, Evolution of Nd and Pb isotopes in central Pacific seawater from ferromanganese crusts, Earth Planet. Sci. Lett. 146 (1997) 1–12; K.W. Burton, H-F. Ling, R.K. O'Nions, Closure of the central American isthmus and its impact on North Atlantic deepwater circulation, Nature (London) 386 (1997) 382–385] shows that provinciality in the present-day ϵNd structure of the Pacific, Atlantic and Indian Oceans has been maintained over ∼20 Ma or more despite the palaeogeographic changes that have occurred within this period. These include the closure of the Panama gateway and the uplift of the Himalayas. Superimposed on this broad inter-ocean structure are changes in ϵNd of the western N. Atlantic which may relate to the Panama gateway closure and shifts in the ϵNd of equatorial Pacific deepwater from 3–5 Ma ago. The absence of any such structure in ϵNd of the southwest and central Indian Ocean suggests that Himalayan erosion products such as preserved in the Bengal Fan sediments have not contributed significantly to Indian Ocean deepwater over the last 20 Ma. There is no straightforward relationship between records of 87Sr/86Sr in the global ocean and ϵNd in ocean deepwater as would be expected if inputs of radiogenic Sr and unradiogenic Nd were coupled.
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  • 61
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    Elsevier
    In:  Continental Shelf Research, 18 . pp. 915-922.
    Publikationsdatum: 2016-09-21
    Beschreibung: Off the Brazilian coast near Ubatuba, an upwelling event of South Atlantic Central Water (SACW) has been observed that transfer nutrient-rich water from 300 to 400 m depth onto the continental shelf to depths less than 35 m. Earlier work showed that SACW is present on the shelf quite frequently; however, nutrient data as natural tracers of water masses, are largely undocumented so far. During the upwelling process the water advanced over the shelf increasing its nutrients concentrations and depleting its content of dissolved oxygen due to the regeneration process. The ratios of regeneration relative to their open ocean origin amount to 4.6 mu M for nitrate, 0.43 mu M for phosphate and 5.7 mu M for silicate on average, while the dissolved oxygen depletes by 114.9 mu M,
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  • 62
    Publikationsdatum: 2016-11-14
    Beschreibung: Surface exposure dating requires the knowledge of cosmogenic nuclide production rates. When determining time-integrated production rates the exposure ages of the calibration samples need to be accurately known. The landslide of Köfels (Austria) is very well suited for this purpose. It is the largest landslide in the crystalline Alps of Austria dating back to 7800±100 years BC (AMS 14C dating of buried wood), which is well within the 14C dendro calibration curve. Exposed quartz veins were sampled from the tops of large boulders from the toe of the landslide for analysis of 10Be and 26Al. To calculate sea level, high geomagnetic latitude (≥60°), open sky radionuclide production rates, corrections were applied for altitude and latitude, for shielding by surrounding mountains, for sample geometry, vegetation and snow cover, and for sample thickness. The production rates for an exposure age of 10,000 years are 5.75±0.24 10Be atoms/yr g SiO2 and 37.4±1.9 26Al atoms/yr g SiO2. A 26Al/10Be ratio of 6.52±0.43 can be calculated. The influence of the geomagnetic field on these production rates has been estimated using two different geomagnetic field records. Our production rates should be a good approximation for the use of surface exposure dating between about 5000 and 13,000 years BP.
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  • 63
    Publikationsdatum: 2018-06-20
    Beschreibung: The influence of ice drift upon the thermohaline structure of the upper sea-layer was studied based on CTD-probing near the edge of the eastern Kara Sea ice cover. This study was aimed at investigating the dynamics and spatial-temporal variability of thermohaline frontal boundaries connected with the moving ice edges of different concentration. Investigations revealed that locally mixed thin layers are formed in the subsurface layer under the influence of ice drift. Under conditions of uninterrupted stratification, redistribution and capture of suspended matter within these thin layers may occur. Furthermore, under conditions of freezing and demolition of density stratification in the surface layer, this matter can be redistributed and incorporated into sea ice.
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  • 64
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    Elsevier
    In:  Materials Characterization, 40 (2). pp. 73-96.
    Publikationsdatum: 2018-07-25
    Beschreibung: About 900 slags and iron objects from the period 700 b.c. to 1850 a.d. have been examined and analyzed by classical optical microscopy and by energy dispersive analytical methods. Although ancient iron objects are extremely heterogeneous, a definite correlation between the metal phase and its slag inclusions is shown; for example, wüstite-rich slags are located in ferrite, whereas glassy slags are located in pearlite. The ratios SiO2/Al2O3, Al2O3/CaO, and so forth, of the slag inclusions are shown to be helpful in identifying the production site or provenance of an ancient iron object. These ratios are further shown not to be the same in irons produced by the direct process and in irons produced by fining or puddling. Emphasis is on iron production methods in Sweden, Norway, and Denmark, illuminating Scandinavian iron-making practices through 2500 years. The slag analysis method developed here may, however, be extended to yield information on other European sites.
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    Potsdam Institute for Climate Impact Research
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    In:  Modellierung des Wasser- und Stofftransportes in großen Einzugsgebieten: Zusammenfassung der Beiträge des Workshops am 15. Dezember 1997 in Potsdam | PIK Reports ; 43
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    Potsdam Institute for Climate Impact Research
    In:  Umwelt und Sicherheit: Die Rolle von Umweltschwellenwerten in der empirisch-quantitativen Modellierung | PIK Reports ; 41
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    In:  The Odra/Oder flood in summer 1997: Proceedings of the European Expert Meeting in Potsdam, 18 May 1998 | PIK Reports ; 48
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