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  • Articles  (37)
  • diatoms  (25)
  • Geochemistry
  • Springer  (37)
  • 2020-2023
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  • Geosciences  (37)
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  • Articles  (37)
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  • Springer  (37)
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  • 1
    ISSN: 1437-3262
    Keywords: Key words Plate tectonics ; Geochemistry ; Trace fossils ; Late Precambrian ; Eocambrian stratigraphy and magmatism ; Gravity
    Source: Springer Online Journal Archives 1860-2000
    Topics: Geosciences
    Notes: Abstract  Stratigraphic correlations and tectonic analysis suggest that the Puncoviscana fold belt of northwestern Argentina was an intracontinental basin with bimodal igneous suites that formed in connection with the breakup of the Rodinia supercontinent (at ∼800 Ma). Several lines of evidences point to an initial lithosphere rupture, possibly induced by a rising mantle plume. The earliest synrift igneous products are represented by ultra-potassic dykes and alkaline lava flows of high LREE/HREE and low Zr/Nb–Y/Nb ratios. The dyke emplacements and the initiation of rifting were probably synchronous. They pass laterally and upwards (middle part of the Puncoviscana succession) into basalts of alkaline transitional character (OIB-like source). The distinctive chemical feature of these lavas are very similar to the source of oceanic island basalts; thus, they are thought to represent a magmatism associated with the rift and rift-drift transition stage. During this stage of rifting probably true oceanic crust was formed. The upper part of the Puncoviscana sequence, Late Precambrian/Lower Cambrian in age, comprises a thick and monotonous sequence of pillow lavas, massive basaltic flows and minor volcanic breccias and hyaloclastites. These lavas exhibit MORB trace element characteristics with high FeOt and TiO2, low K2O and P2O5, flat light REE spectra, little or no depletion in Nb and Ta. This volcanism consists of the major and latest effusive episode from the Puncoviscana basin which was slightly modified by subduction processes. The geodynamical model proposed for the generation of these volcanic rocks could have been developed in two stages. In the first stage the volcanic event is compatible with a progressive opening of a continental rift leading to formation of a mature oceanic basin. In contrast, the second stage shows the effects of a completed Wilson cycle including a primitive volcanic arc which continued until the accreted Cuyania-Arequipa-Belen-Antofalla (CABA) terrane against the proto-Gondwana western borderland of the Amazonian shield (∼535 Ma).
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  • 2
    ISSN: 1437-3262
    Keywords: L. Palaeozoic volcanics ; Amphibolites ; Geochemistry ; Petrogenesis ; Crustal contamination ; Palaeotectonic environment ; Orlica-Śnieżnik dome, Bohemian massif
    Source: Springer Online Journal Archives 1860-2000
    Topics: Geosciences
    Notes: Abstract Orthoamphibolites within and marginal to the Orlica-Śnieżnik dome in the eastern Bohemian massif are associated with a series of Proterozoic-Lower Palaeozoic supracrustal meta-sediments of the Stronie, Nové Město and Staré Město formations. Massive and variably foliated amphibolites range from common epidote-plagioclase-blue-green/green hornblende varieties to assemblages with diopside, garnet and brown amphibole. All the amphibolites have a basaltic composition and are divided into three main chemical groups which are intimately associated in the field: main series tholeiites, low-Ti tholeiites and alkali basalts. All groups exhibit a common enrichment in LIL elements+Nb+Ta (relative to high-field-strength elements) which reflects contamination by upper continental crust and/or pelagic sediment compositions. The gross chemistry of the tholeiitesapproaches that for MORB, although the geological environment and nature of crustal contamination suggests that the basaltic precursors were probably emplaced in a rifted ensialic basinal environment. If the amphibolites are representative of an early phase of the Lower Palaeozoic fragmentation of Gondwanaland, then rifting did not fully develop ocean crust. The wider significance of the chemical interpretation implies that some of the variation from Variscan Proterozoic-Palaeozoic metabasite suites that is ascribed to a complex of different eruptive settings could be accounted for by variable contamination and/or source composition.
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  • 3
    ISSN: 1437-3262
    Keywords: Key words Oman ; Chromite ; Paleogeography ; Geochemistry
    Source: Springer Online Journal Archives 1860-2000
    Topics: Geosciences
    Notes: Abstract  In Oman, the convergence between Arabia and Eurasia resulted in the Late Cretaceous overthrusting of oceanic crust and mantle lithosphere onto the Arabian continental margin. During this compressional event, a part of the continental plate was subducted to a depth of more than 60 km (0.5 GPa, 250–350  °C to more than 2.0 GPa, 550  °C) resulting in progressive metamorphism of the continental margin sediments, well exposed in the Saih Hatat tectonic window, northeastern Oman Mountains. We attempt to constrain the possibility of one continuous history of extension (starting along the east Arabian continental margin in the Permian) that was followed by one continuous history of convergence starting at 90 Ma near a dead oceanic ridge. This compression resulted in the observed progressive metamorphism by ophiolite overthrusting onto the continental margin. Constraining arguments are the palaeogeographic setting before ophiolite obduction of the As Sifah units and the Hawasina Complex near Ghurba. Detrital chromites in the Triassic–Cretaceous metasediments of the Hawasina Complex are compared with magmatic Semail chromites, and the whole-rock chemistry of these metasediments and associated metabasites are investigated. In contrast to former hypotheses, differences in the chemical composition between detrital and magmatic chromites, and the probable origin of all detrital chromites in the Hawasina Basin from Permian age oceanic rocks, suggest that the high-pressure metamorphic sediments of As Sifah can be considered as part of the basal deposits of the Hawasina Basin.
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  • 4
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    Journal of paleolimnology 15 (1996), S. 19-45 
    ISSN: 1573-0417
    Keywords: diatoms ; grain-size analysis ; lake-level changes ; Lake Michigan ; paleolimnology
    Source: Springer Online Journal Archives 1860-2000
    Topics: Biology , Geosciences
    Notes: Abstract Paleolimnological investigations of a marginal lake in the Lake Michigan basin revealed signals of long-term lake-level changes primarily controlled by climatic forces. Multiple analyses identified concurrent signals in sediment chemistry, grain size, and the microfossil record. Coarse-grained sediments, benthic diatoms, and nutrient response species increased as lake levels rose or fell. Finer sediments and higher percentages of taxa associated with stable thermocline conditions occurred during high-lake periods. Sedimentary evidence revealed corresponding strong high-lake signals c. 2500–2200, 1800–1500, 1170–730, and 500–280 BP. Low-lake periods occurred c. 1500–1170 and 700–500 B.P. An additional signal of lake-level decline was apparent beginning c. 280 BP but was interrupted by anthropogenic effects. Evidence of extreme low-lake levels (c. 1400–1300 BP), and signals for a medieval warming period (1030–910 BP) and the Maunder minimum (370–325 BP) indicate occurrence of short-lived dry climatic conditions.
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  • 5
    ISSN: 1573-0417
    Keywords: diatoms ; high arctic ; Ellesmere Island ; laminated sediments ; rheophilous ; river input ; marine isolation
    Source: Springer Online Journal Archives 1860-2000
    Topics: Biology , Geosciences
    Notes: Abstract Diatoms preserved in the sediments of Lake C2 (82°50′ N, 76°00′ W), a high arctic meromictic lake, track changes in the lake's salinity which have occurred as the basin was isolated from the sea. An assemblage dominated by marine taxa, such as Chaetoceros species, Nitzschia cylindrus and Diploneis spp., was replaced by a Cyclotella kuetzingiana var. planetophora dominated freshwater flora. A brief brackish period separates the two assemblages. Relatively little floristic change occurred within either the marine or freshwater periods, indicating rather stable environmental conditions, except that rheophilous diatoms fluctuated in relative abundance during the lacustrine phase, perhaps tracking past changes in discharge from inflowing streams. These may reflect periods of warmer, wetter environmental conditions.
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  • 6
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    Journal of paleolimnology 16 (1996), S. 323-354 
    ISSN: 1573-0417
    Keywords: diatoms ; chrysophytes ; pollen ; charcoal ; hemlock decline ; Holocene ; Massachusetts
    Source: Springer Online Journal Archives 1860-2000
    Topics: Biology , Geosciences
    Notes: Abstract We examined the stratigraphic record of North Pond, a small, oligotrophic lake in western Massachusetts, U.S.A. to describe late and post-glacial watershed-lake interactions. In particular we investigated the effects of two similar vegetation changes in the watershed on lake biogeochemistry. There was a transient (about 100 years) decline in hemlock ca. 7500 yr B.P. that has not been recorded in other pollen stratigraphies in the northeast. The second event was the classical hemlock decline that occurred ca. 4800 yr B.P. and lasted about 2000 years. This decline occurred throughout the range of hemlock and is thought to have been caused by a pathogen. As the climate began to warm ca. 10 000 yr B.P., a spruce dominated boreal woodland was established in the watershed. Sediment chemistry data showed that as soils became more acidic, the lake also acidified as evidenced by diatom-inferred (DI) pH. Hemlock was established in the watershed by about 8000 yr B.P. This was accompanied by a slight decrease in DI pH. The transient hemlock decline ca. 7500 yr B.P. was associated with an increase in sedimentary charcoal particles, that suggested fire was responsible for its demise. The diatom stratigraphy indicated a brief, slight, increase in productivity and alkalinity and a brief decrease in lakewater dissolved organic carbon concentrations. Aquatic microfossil data indicated a decrease in the area of the littoral zone ca. 7500 yr B.P. Following the transient decline the lake became more acidic. There were only brief, subtle changes associated with the classical hemlock decline, including a slight decline in DI pH. Although the two disturbances involved a similar vegetation shift, the timing and mechanisms of the disturbances had a greater impact on lake biogeochemistry.
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  • 7
    ISSN: 1573-0417
    Keywords: diatoms ; lotic diatoms ; varves ; paleolimnology ; turbidities ; high arctic
    Source: Springer Online Journal Archives 1860-2000
    Topics: Biology , Geosciences
    Notes: Abstract Both habitat preferences and community associations for some of the most prominent pennate taxa in our profile were established using samples from the modern lake and its watershed. Habitat preferences were used to establish a simple indicator for the relative contribution of lotic communities in this lake (Lotic Index) and indicator taxa for both littoral (Achnanthes spp. and Cymbella spp.) and lotic (Hannaea arcus and Meridion circulare) communities. When profiled, the Lotic Index showed a clear positive relationship to sedimentation rate as recorded in the varves, while profiles of littoral indicator taxa show the opposite trends. It seems likely that the patterns we observed in the Lotic Index are related to changes in runoff. Apparently, there was a period of declining runoff beginning ca. two centuries ago and ending in the late 1800's. This was followed by increasing runoff lasting until the middle of the 20th century. A brief minimum occurred in ca. 1970 followed by a recovery by ca. 1980. A strong positive relationship was also found between the dates of major turbidites, exceptionally thick varves and the concentration of valves in the sediment. It is possible that many of the thicker varves in the profiles contain littoral material transported to the site of deposition by turbid interflows and underflows. For this reason, the concentration of valves in the sediment in our cores appears to be a proxy for sediment deposition from turbidity currents.
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  • 8
    ISSN: 1573-0417
    Keywords: diatoms ; biogenic silica ; pigments ; biomass ; trophic state changes ; eutrophication ; Lake Constance ; Germany
    Source: Springer Online Journal Archives 1860-2000
    Topics: Biology , Geosciences
    Notes: Abstract In Lake Constance, phosphorus concentrations and the seasonal development of phytoplankton communities in water samples from the pelagic zone were regularly recorded since the 1950's. Before the 1950's, there were occasional investigations of plankton communities since 1896. We compared these data with the sedimentary record in two sediment cores. Then, the eutrophication history of Lake Constance was inferred from diatoms. The record of biogenic silica in the cores is discussed with respect to diatom biomass increase. Diatom assemblages in the sediment cores precisely reflected the pelagic diatom development for the period 1971--1992. Both sediment cores and the water samples have a high interannual variability of diatom assemblages. Below a sediment depth of 27 cm (AD 1920), more than 50% of the diatoms were partly corroded, and we limited the reconstruction of trophic state changes to the interval of 1920--1993. Oligotrophic conditions of Lake Constance were indicated by the dominance of various Cyclotella taxa from 1920 to 1940. Since 1939/1940, increasing abundance of it Tabellaria fenestrata showed oligotrophic to mesotrophic conditions. Between 1953 and 1956, increasing Stephanodiscus hantzschii and disappearing Cyclotella indicated advanced eutrophication and total phosphorus values ranged between 8--10 mg m-3 during turnover in late winter. Further eutrophication was shown by disappearing T. fenestrata and increasing S. minutulus in 1963. Maximum TP concentrations of 87 mg m-3 occurred in 1979/80 and was accompanied by increasing abundances of Aulacoseira granulata. From 1986 to 1992, reoccurrence of Tabellaria fenestrata and Cyclotella indicate some recovery of Lake Constance. Biogenic silica and diatom abundances were similar among cores but indicate a 3--4 fold increase of diatom biomass only. This was far below the estimate of biomass increase from sedimentary pigment data (25 fold) and the estimate of phytoplankton data from the literature (70 fold).
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  • 9
    ISSN: 1573-0417
    Keywords: pollen ; diatoms ; algae ; ostracods ; stable isotopes ; palaeolimnology ; Holocene ; Morocco
    Source: Springer Online Journal Archives 1860-2000
    Topics: Biology , Geosciences
    Notes: Abstract Pollen, geochemical and sedimentological data from Sidi Ali, a montane Moroccan lake, provide a 7000 yr record of changes in climate, catchment vegetation and soil erosion intensity. Diatoms, non-silicious algae, macrophyte fossils and ostracods from the same core record the dynamics of the lake ecosystem. Oxygen isotope and trace-element ratios of benthic ostracods appear to be relatively insensitive to climatic variation in this open lake with low water-residence time, but diatom plankton / periphyton (P/L) ratios show lake-level variations that are probably climate controlled. At least two superimposed processes are recorded, but at different timescales: catchment vegetation and soils show long-term changes due to climate and human impact, whereas P/L ratios suggest century-scale oscillations in lake depth. The timing of changes in algal and macrophyte productivity and carbon cycling within the lake broadly corresponds to changes in terrestrial vegetation, suggesting either that lake nutrient status is linked to catchment vegetation and soils, or that both were influenced by climate. The lack of a sensitive and independent (non-biological) climate proxy makes it more difficult to assess the lake's ecological response to short-term climate variation. Overall, the lake's evolution has been influenced both by catchment-mediated nutrient flux and by changes in water balance, thus having characteristics in common with both temperate and arid zone lakes.
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  • 10
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    Journal of paleolimnology 22 (1999), S. 1-15 
    ISSN: 1573-0417
    Keywords: diatoms ; lake sediments ; acidification ; pH ; alkalinity ; colour ; regional estimates ; northern Sweden
    Source: Springer Online Journal Archives 1860-2000
    Topics: Biology , Geosciences
    Notes: Abstract Changes in lake-water pH, alkalinity and colour were inferred from diatoms in surface sediment samples and sediment samples from pre-industrial times from 118 northern Swedish lakes. This palaeolimnological study does not support the hypothesis that there is a large-scale modern acidification in the two northernmost counties of Sweden; pH had decreased significantly in eight lakes, while five had a significant increase. Partial least-squares regression of changes in water chemistry in relation to catchment characteristics was performed to evaluate the causes of the acidity status. Furthermore, temporal trends were assessed from long sediment cores from five acidic lakes. The results suggest that the presently acid lakes have faced a long-term acidification trend over several thousand years due to soil-forming processes and vegetation development. However, due to the acid sensitivity of the region, future acidification trends in northern Swedish lakes should be carefully observed and assessed.
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  • 11
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    Journal of paleolimnology 22 (1999), S. 71-80 
    ISSN: 1573-0417
    Keywords: circulation model ; diatoms ; Baltic Sea ; shoreline displacement ; palaeosalinity ; laminated sediments ; palaeoproductivity ; anoxia
    Source: Springer Online Journal Archives 1860-2000
    Topics: Biology , Geosciences
    Notes: Abstract During the last retreat of the Laurentide Ice Sheet in North America, many proglacial lakes formed as continental drainage was impounded against the southern and western ice margin. Lake Agassiz was the largest of these lakes. The bathymetry of Lake Agassiz at the Herman and Upper Campbell beach levels – formed at about 11.5–11.0 ka and 9.9–9.5 ka, respectively – was computer modelled in this study by first collecting data for the isostatically-deformed paleowater planes of the two lake levels (derived from isobase lines constructed from beach elevations), and then subtracting these from the modern topography of the former lake floor. Pixels with dimensions of 1/30 × 1/30 of a degree were used in the model. Using these data, the area and volume of the lake were also calculated: at the Herman level these were ∼152 500 km2 and ∼13 100 km3 respectively; at the Upper Campbell level these were ∼350 400 km2 and ∼38 700 km3. Contour maps showing the paleobathymetry of both periods in the lake's history were also constructed. Determining the paleobathymetry and volume of Lake Agassiz is an important step in understanding the impact that the lake had on its surrounding environment and on the rivers, lakes, and oceans into which it flowed.
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  • 12
    ISSN: 1573-0417
    Keywords: circulation model ; diatoms ; Baltic Sea ; shoreline displacement ; palaeosalinity ; laminated sediments ; palaeoproductivity ; anoxia
    Source: Springer Online Journal Archives 1860-2000
    Topics: Biology , Geosciences
    Notes: Abstract Five Holocene sediment cores from the northwestern Baltic proper were analysed for lithology, siliceous microfossil assemblages and geochemical parameters. The data indicate that surface water salinity and redox conditions below the halocline have changed drastically at least four times since the Baltic Sea changed from a fresh water lake (the Ancylus Lake) to a semi-enclosed brackish water sea (the Litorina Sea) c. 8500 yrs BP. These variations appear to be mainly effects of changes in water depth at the thresholds of inlet areas. Based on these changes, and earlier studies of the shoreline displacement in the inlet areas, we propose a tentative model for changes of large scale water circulation in the Baltic Sea during the last c. 8500 yrs. At the transition from fresh to brackish water 8500 14C yrs BP, upwelling of nutrient rich bottom water started to occur, causing a slight increase in primary production. Diatom assemblages in sediments indicate a slow rise in surface water salinity during this period. At 7000-6500 14C yrs BP, surface water salinity and primary production simultaneously increased, as anoxic bottom conditions were established at depth below the halocline. We suggest that high primary production was caused by increased input of oceanic water, leading to increased upwelling of nutrient rich bottom water. At the anoxic bottoms laminated sediments formed until 5000-4500 14C yrs BP. This period (c. 7000-4500 14C BP) was contemporaneous with the post-glacial transgression maximum in Öresund, and we suggest it represents the most saline phase of the Baltic Sea post-glacial history. Due to a regression in Öresund starting 4500 14C yrs BP, upwelling decreased and the halocline was lowered, resulting in decreased primary productivity and hence oxic deep water conditions. The diatom assemblages of the sediments indicate a lowering of salinity at the beginning of this period. We suggest that the second period of anoxic bottom conditions c. 2000-1500 14C yrs BP was caused by a change of dominating inflows from the Öresund to the Belt Sea. This resulted in decreased salinity of the inflowing water which did not penetrate to the deepest parts of the basin as frequently as before. The diatom record indicates both a second lowering of salinity and a change in the large scale water circulation at the beginning of this period.
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  • 13
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    Journal of paleolimnology 22 (1999), S. 149-158 
    ISSN: 1573-0417
    Keywords: acidity ; diatoms ; lake sediment ; paleolimnology ; pollen ; terrestrial vegetation ; Yuanyanf Lake ; Taiwan
    Source: Springer Online Journal Archives 1860-2000
    Topics: Biology , Geosciences
    Notes: Abstract Yuanyang Lake (24°35′N, 121°24′E), located at an altitude of 1,670 m within a nature preserve in northern Taiwan, is an acidic lake. Remains of diatoms and pollen from a 3.72-m sediment core were used to elucidate the relationships between the vegetation of the watershed and the paleolimnological environment. Past pH, saprobity level, and total P of the lake were inferred from the diatom assemblages and were analyzed with respect to changes in the terrestrial vegetation. The inferred pH values fluctuated only slightly, whereas the inferred saprobity level increased markedly towards the sediment surface. In the topmost sediment, a slight drop in the inferred pH was associated with a lowering in the saprobity index. This was interpreted as a possible result of recent anthropogenic acidification and changes in productivity related to changes in acidity. Based on pollen analyses, we conclude that Chamaecyparis persisted over at least the last four thousand years in the watershed. The vegetation in the watershed changed little during this period of time, which is consistent with the constancy of inferred pH values. A positive correlation between the inferred pH and δ13C values of the sediments was found.
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  • 14
    ISSN: 1573-0417
    Keywords: carbon isotopes ; diatoms ; lake management ; nitrogen isotopes ; phosphorus ; radium-226 ; sediments ; trophic state
    Source: Springer Online Journal Archives 1860-2000
    Topics: Biology , Geosciences
    Notes: Abstract We explored the use of carbon and nitrogen isotopes (δ13C and δ15N) in sedimented organic matter (OM) as proxy indicators of trophic state change in Florida lakes. Stable isotope data from four 210Pb-dated sediment cores were compared stratigraphically with established proxies for historical trophic state (diatom-inferred limnetic total phosphorus, sediment C/N ratio) and indicators of cultural disturbance (sediment total P and 226Ra activity). Diatom-based limnetic total P inferences indicate a transition from oligo-mesotrophy to meso-eutrophy in Clear Lake, and from eutrophy to hypereutrophy in Lakes Parker, Hollingsworth and Griffin. In cores from all four lakes, the carbon isotopic signature of accumulated OM generally tracks trophic state inferences and cultural impact assessments based on other variables. Oldest sediments in the records yield lower diatom-inferred total limnetic P concentrations and display relatively low δ13C values. In the Clear, Hollingsworth and Parker records, diatom-inferred nutrient concentrations increase after ca. AD 1900, and are associated stratigraphically with higher δ13C values in sediment OM. In the Lake Griffin core, both proxies display slight increases before ~1900, but highest values occur over the last ~100 years. As Lakes Clear, Hollingsworth and Parker became increasingly nutrient-enriched over the past century, the δ15N of sedimented organic matter decreased. This reflects, in part, the increasing relative contribution of nitrogen-fixing cyanobacteria to sedimented organic matter as primary productivity increased in these waterbodies. The Lake Griffin core displays a narrow range of both δ13C and δ15N values. Despite the complexity of carbon and nitrogen cycles in lakes, stratigraphic agreement between diatom-inferred changes in limnetic total P and the stable isotope signatures of sedimented OM suggests that δ13C and δ15N reflect shifts in historic lake trophic state.
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  • 15
    ISSN: 1573-0417
    Keywords: Lake-level changes ; acquatic-moss layers ; Cladocera ; diatoms ; pollen ; cladoceran planktonic/littoral ratio
    Source: Springer Online Journal Archives 1860-2000
    Topics: Biology , Geosciences
    Notes: Abstract We studied Holocene lake-level fluctuations from a small lake, Iso Lehmälampi, southern Finland, utilizing cladoceran and diatom analyses. We report data from a sediment core (A) taken from the deepest part of the lake (8.1 m) where two layers of moss, mixed with gyttja, were found. These layers were formed in situ during the early Holocene (1. ca. 8100-7900, 2. ca. 7300 BP). Lake-level fluctuations were inferred also from another core C, which did not have moss layers. According to the ratio of planktonic/littoral Cladocera, the water level was high around 9000 BP and started to fall before 8000 BP. The lowering continued until 7000 BP and the moss layers were formed during this lowering. Water level was high again ca. 6000 BP and lowered towards ca. 4000 BP. The late Holocene is characterized by several rapid fluctuations of lake-level. The ratio of planktonic/littoral Cladocera and the diatom species composition in core A showed drastic changes between the moss layers and the non-moss gyttja sections of the core. We suggest that they reflect changes in sedimentary facies between the local moss environment and the pelagic bottom. Thus, cores which contain moss layers may lead to erroneous interpretations of lake-level fluctuations.
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  • 16
    ISSN: 1573-0417
    Keywords: diatoms ; pH ; weighted average partial least squares ; Guassian regression ; high-altitude lakes ; DOC ; optima ; Europe
    Source: Springer Online Journal Archives 1860-2000
    Topics: Biology , Geosciences
    Notes: Abstract A modern diatom-pH calibration data-set consisting of surface-sediment diatom assemblages from 118 lakes and 530 taxa is presented. The AL:PE data-set is from high-altitude or high-latitude lakes in the Alps, Norway, Svalbard, Kola Peninsula, UK, Slovenia, Slovakia, Poland, Portugal, and Spain (pH range = 4.5-8.0; DOC range = 0.2-3.2 mg l-1). In addition, 92 epilithon samples from 22 high-altitude or high-latitude lakes comprise an AL:PE epilithon diatom-pH data-set. Weighted averaging partial least squares regression is used to develop pH-inference models. The AL:PE data-set has a root-mean-square-error of prediction (RMSEP) of 0.33 and a maximum bias of 0.36 pH units and r2 of 0.82, as assessed by leave-one-out cross-validation. The epilithon data-set has, after data-screening and the deletion of one very obvious outlier, a RMSEP of 0.23 and a maximum bias of 0.18 pH units and r2 of 0.88. The 167 sample SWAP diatom-pH data-set from lowland or upland lakes in the UK, Norway, and Sweden has a RMSEP of 0.29 and a maximum bias of 0.23 pH units and r2 of 0.86. The pH optima, as estimated by weighted averaging and Gaussian regression, are compared for the three data-sets (AL:PE, SWAP, AL:PE epilithon). There is a good correspondence between the AL:PE and the AL:PE epilithon optima, but a consistent bias between the AL:PE and SWAP optima, with the SWAP optima being lower than the AL:PE estimates. The predictive performances of the AL:PE and SWAP calibration data-sets are compared using independent test samples and six core sequences, all from high-altitude lakes, one in south-east Siberia and five in eastern Scotland. The results show the importance of using the AL:PE data-set for inferring lake-water pH from diatom assemblages in high-altitude or high latitude lakes with low DOC concentrations.
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  • 17
    ISSN: 1573-0417
    Keywords: quaternary ; paleolimnology ; diatoms ; pollen ; magnetic properties ; lacustrine sediments ; Mexico
    Source: Springer Online Journal Archives 1860-2000
    Topics: Biology , Geosciences
    Notes: Abstract Paleoenvironmental studies have documented the late Pleistocene to Holocene evolution of the lakes in the central and southern parts of the basin of Mexico (Texcoco and Chalco). No information was available, however, for the lakes in the north-eastern part of this basin. The north-eastern and the central and southern areas represent, at present, different environmental conditions: an important gradient exists between the dry north and the moister south. To investigate the late Pleistocene to Holocene characteristics of the north-eastern lakes in the basin of Mexico two parallel cores (TA and TB) were drilled at the SE shore of Lake Tecocomulco. Stratigraphy, magnetic properties, granulometry, diatom and pollen analyses performed on these sediments indicate that the lake experienced a series of changes between ca. 〉 42,000 yr BP and present. Chronological control is given by five radiocarbon determinations. The base of the record is represented by a thick, rhyolitic air-fall tephra that could be older than ca. 50,000 yr BP. After this Plininan event, and until ca. 42,000 yr BP, Lake Tecocomulco was a moderately deep, freshwater lake surrounded by extended pine forests that suggest the presence of cooler and moister conditions than present. Between ca. 42,000 and 37,000 yr BP, the lake became shallower but with important fluctuations and pollen suggests slightly warmer conditions. Between ca. 37,000 and 30,000 yr BP the lake experienced two relatively deep phases separated by a dry interval. A second Plinian eruption, represented in the sequence by a dacitic an air-fall tephra layer dated at 31,000 yr BP, occurred in the area by the end of this dry episode. Between ca. 30,000 and 25,7000 yr BP Tecocomulco was a fresh to slightly alkaline lake with a trend towards lower level. After ca. 25,700 yr BP very low lake levels are inferred, and after ca. 16,000 yr BP the data indicate the presence of a very dry environment that was persistent until the middle Holocene. After 3,500 yr BP lacustrine conditions were re-established and the vegetation cover shows a change towards higher percentages of herbaceous taxa.
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  • 18
    ISSN: 1573-0417
    Keywords: paleolimnology ; arctic lakes ; diatoms ; specific conductivity ; Canonical Correspondence Analysis (CCA) ; Weighted Averaging (WA) ; paleoconductivity
    Source: Springer Online Journal Archives 1860-2000
    Topics: Biology , Geosciences
    Notes: Abstract Diatoms are identified and enumerated from the surface sediments of 100 lakes of Truelove Lowland, Devon Island, N.W.T., Canada. These lakes range from large oligotrophic lakes, to small tundra ponds, to coastal marine lagoons which are diverse in terms of ionic concentration and composition. The relationship between diatoms and 15 limnological variables is examined using Canonical Correspondence Analysis (CCA). Specific conductivity is identified as the most important variable influencing the distribution of diatoms in the Truelove lakes. A Weighted Averaging (WA) calibration model is developed to predict diatom-inferred specific conductivity. The reliability of the model is tested by evaluating the correlation between observed and diatom-inferred values and determining the error of prediction by bootstrapping. The applicability of the predictive conductivity equation is demonstrated by reconstructing the paleoconductivity history of Fish Lake.
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  • 19
    ISSN: 1573-0417
    Keywords: diatoms ; Everglades ; phosphorus ; wetland ; calibration ; multivariate ; Florida
    Source: Springer Online Journal Archives 1860-2000
    Topics: Biology , Geosciences
    Notes: Abstract The relationship between diatom taxa preserved in surface soils and environmental variables at 31 sites in Water Conservation Area 2A (WCA-2A) of the Florida Everglades was explored using multivariate analyses. Surface soils were collected along a phosphorus (P) gradient and analyzed for diatoms, total P, % nitrogen (N), %carbon (C), calcium (Ca), and biogenic silica (BSi). Phosphorus varied from 315-1781 μg g-1, and was not found to be correlated with the other geochemical variables. Canonical correspondence analysis (CCA) was used to examine which environmental variables correlated most closely with the distributions in diatom taxa. Canonical correspondence analysis with forward selection, constrained and partial CCA, and Monte Carlo permutation tests of significance show the most significant changes in diatom assemblages along the P gradient (p 〈 0.01), with additional species differences correlated with soil C, N, Ca, and BSi. Weighted-averaging (WA) regression and calibration models of diatom assemblages to P and BSi were developed. The diatom-based inference model for soil [P] had a high apparent r2 (0.86) with RMSEboot = 218 μg g-1. Indicator diatom species identified by assessing species WA optima and WA tolerance to [P], such as Nitzschia amphibia and N. palea for high [P] (~1300-1400 μ g-1) and Achnanthes minutissima var. scotica and Mastogloia smithii for low [P] (~400-600 μg g-1), may be useful as monitoring tools for eutrophication in WCA-2A as well as other areas of the Everglades. Diatom assemblages analyzed by cluster analysis were related to location within WCA-2A, and dominant taxa within clusters are discussed in relation to the geochemical variables measured as well as hydrology and pH. Diversity of diatom assemblages and a ‘Disturbance Index’ based on diatom data are discussed in relation to the historically P-limited Everglades ecosystem. Diatom assemblages should be very useful for reconstructions of [P] through time in the Florida Everglades, provided diatoms are well preserved in soil cores.
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  • 20
    ISSN: 1573-0417
    Keywords: Africa ; climate change ; conductivity ; diatoms ; Ethiopia ; Holocene ; lake levels ; palaeolimnology ; Rift Valley
    Source: Springer Online Journal Archives 1860-2000
    Topics: Biology , Geosciences
    Notes: Abstract A 6,500-year diatom stratigraphy has been used to infer hydrochemical changes in Lake Awassa, a topographically closed oligosaline lake in the Ethiopian Rift Valley. Conductivity was high from ~6400-6200 BP, and from 5200-4000 BP, with two brief episodes of lower conductivity during the latter period. Although the timing of the conductivity changes is similar to the timing of lake-level change in the nearby Zwai-Shalla basin, their directions are the reverse of that expected from a climatic cause. Dissolution of the tephras which precede both phases of high conductivity cannot explain the increases in salinity, because rhyolitic tephras are only sparingly soluble. Instead, the pulsed input of groundwater made saline by the reaction of silicate minerals and volcanic glass with carbonic acid, formed from the solution of carbon dioxide degassed from magma under the Awassa Caldera, is suggested as a plausible mechanism for the observed change in lake chemistry. Diatom-inferred hydrochemistry cannot therefore be used to reconstruct climate change in Lake Awassa.
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  • 21
    ISSN: 1573-0417
    Keywords: varves ; diatoms ; eutrophication dynamics ; Amersee ; Starnberger See
    Source: Springer Online Journal Archives 1860-2000
    Topics: Biology , Geosciences
    Notes: Abstract Diatom assemblages in the annually laminated sediments of two neighboring, pre-alpine lakes (Ammersee and Starnberger See, Southern Germany) were analyzed and compared year by year. Within both varve records of the last decades, the same 4-phase-succession of planktonic diatom species is preserved, consisting of 1. a dominance of Cyclotella species 2. assemblages of Fragilaria crotonensis, Asterionella formosa and Stephanodiscus minutulus 3. a mass bloom of Aulacoseira islandica, and 4. a dominance of Stephanodiscus species. This diatom sequence is considered as a model of a 'basic species sequence of eutrophication'. Time lags and differences in the duration of the phases between both lakes show evidence of an earlier start for nutrient loading in Starnberger See than in Ammersee, and a faster development to a higher trophic state level in the latter. The different reactions of the lakes are attributed to hydrological differences such as the existence or lack of a major tributary, the size of the catchment area, and the water residence time. The reconstruction of the eutrophication dynamics appears to be reliably hindcast by the inference of total phosphorus (TP) concentrations using weighted averaging regression and calibration techniques. Remarkable differences in the occurrence of some diatoms in both stratigraphies, which are not related to the general changes of the 'basic species sequence of eutrophication' model, may be due to the epilimnetic silica content (e.g. Fragilaria crotonensis) or competitive weaknesses (e.g. Tabellaria flocculosa).
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  • 22
    ISSN: 1573-0417
    Keywords: diatoms ; temperature ; sediment traps ; seasonal succession ; resuspension ; Lake Holzmaar
    Source: Springer Online Journal Archives 1860-2000
    Topics: Biology , Geosciences
    Notes: Abstract The seasonal sedimentation pattern of diatom valves in Lake Holzmaar was investigated during 1995 by deploying sediment traps at three different lake depths. According to the sedimentation pattern, the major reproduction zone of diatoms was restricted to the upper 6 m of the water body. The population growth started late in April and blooms of Cyclotella cf. comensis Grun., which dominates the plankton diatoms, and Fragilaria crotonensis Kitton were collected in traps during June and September, and July, respectively. During summer, the seasonal sedimentation pattern of each taxon, as collected in the upper traps, was reflected in the concentrations in the lowest trap. However, in May and from September onwards, the community composition in the lowest trap and augmented trapping rates suggest both sediment focusing and resuspension of bottom sediments. The temperature signals as recorded by δ18O values of diatom valves should, therefore, reflect integrated temperatures between 0 and 6 m depth. However, temperatures during summer and autumn are expected to be accentuated in the sedimentary record since the isotopic signal is weighted by both the number and the weight-mass of the valves. During summer, the transfer of these signals by the sedimenting diatoms retains the information pattern recorded, while in spring and autumn/winter additional influxes caused by resuspension may somewhat alter those temperature informations. The proxy signals finally stored in the sediments, may, therefore, not precisely represent the successive temperatures currently recorded during 1995 within mid-lake.
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  • 23
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    Journal of paleolimnology 15 (1996), S. 129-132 
    ISSN: 1573-0417
    Keywords: meromixis ; diatoms ; laminations ; varves
    Source: Springer Online Journal Archives 1860-2000
    Topics: Biology , Geosciences
    Notes: Abstract Meromixis has several powerful effects on lakes, yet there is no single definitive sediment indicator of meromixis. In this study three sediment indicators of meromixis were compared in Brownie Lake, Minneapolis, Minnesota, a small eutrophic lake that became meromictic around 1925. The results show that in Brownie the onset of laminations and changes in the iron to manganese ratio most likely occurred before the development of permanently anoxic bottom water and that changes in the diatom assemblage occurred later, most likely only when meromixis was well developed.
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  • 24
    ISSN: 1573-0417
    Keywords: lake developmental history ; diatoms ; sediment chemistry ; glacial refugia ; Baffin Island ; Arctic Canada
    Source: Springer Online Journal Archives 1860-2000
    Topics: Biology , Geosciences
    Notes: Abstract Sediment diatom and chemical analyses of cores from three poorly buffered extra-glacial lakes on the northeastern margin of the Canadian Shield (Cumberland Peninsula, Baffin Island) record interactions between aquatic and terrestrial spheres that were influenced by late Quaternary climatic conditions. Although differences exist between each of the lakes, notably with regards to the intensity of pre-Holocene catchment erosion and the timing of the onset of organic sedimentation, an underlying pattern of lake ontogeny, common to all three lakes, is identified. Although intensified watershed erosion characterized the Late Wisconsinan and Neoglacial cold periods, the lakes nonetheless remained viable ecosystems at these times. Sudden catchment stabilization during the late-glacial to earliest Holocene is associated with incipient organic sedimentation. Lake-water pH increased at this time, likely in response both longer base cation residence times as lake flushing rates decreased, and enhanced alkalinity production from sediment biogeochemical reactions. Subsequently, as the catchments remained stable during the productive early Holocene (c.9–7 ka BP), then gradually received a renewed increase of minerogenic sedimentation, the breakdown of sources of lake alkalinity resulted in natural acidification. Burial of cation-rich mineral sediments and the loss of permanent sedimentary sinks for the products of microbial reduction likely impeded within-lake alkalinity production, and catchment-derived base cations appeared ineffective in curtailing pH declines. The general nature of the Holocene development of these lakes is similar to that observed elsewhere on crystalline terrains, following deglaciation. Our data therefore suggest that catchment glaciation is not a necessary precursor for models of lake development characterized by initial base cation enrichment and subsequent gradual acidification.
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  • 25
    ISSN: 1573-0417
    Keywords: Hamilton Harbour ; paleolimnology ; diatoms ; sediment isotopes ; palynology
    Source: Springer Online Journal Archives 1860-2000
    Topics: Biology , Geosciences
    Notes: Abstract Limnological changes in Hamilton Harbour, Lake Ontario, over the Holocene were investigated by using proxy evidence from diatoms and other siliceous microfossils in a radiometrically dated sediment core (HH26comp), together with environmental data derived from sediment pollen and oxygen and carbon isotope analyses. The evidence demonstrates that the site of Hamilton Harbour has changed over the past 8300 y from a shallow, separate waterbody, to a deep embayment of Lake Ontario. The earliest evidence, from 8300 BP to 7000 BP, is of a mesotrophic pond of moderate alkalinity, warmer than present, and probably with an extensive marginal wetland. An initial transitory connection with the rising water level of Lake Ontario was established at c. 7000 BP, possibly via a deep outlet channel. This connection is 2000 y earlier then previously estimated. Permanent confluence with Lake Ontario was established at c. 6200 BP, causing a decline in inferred trophic level and water temperatures. Microfossils reach a minimum at 4400 BP coincident with the Nipissing Flood. Decreased mixing of Lake Ontario water from about 4000 BP following the Nipissing Flood highstand is evidenced in isotopic and diatom data. Three isolated shifts in the diatom spectrum at c. 4900 BP, 4500 BP, and 3500 BP may be associated with extreme turbidity or storm deposit events. Between 3200 BP and 280 BP, Hamilton Harbour was evidently a moderately alkaline embayment of Lake Ontario, oligotrophic to mesotrophic, and relatively cooler than present. The final 280 y sedimentary record reveals the magnitude of anthropogenically induced changes to the harbour, including eutrophication and organic pollution.
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  • 26
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    Journal of paleolimnology 15 (1996), S. 65-77 
    ISSN: 1573-0417
    Keywords: diatoms ; lake sediments ; pH ; alkalinity ; colour ; weighted averaging (WA) ; weighted averaging partial least squares (WA-PLS) ; calibration ; Northern Sweden
    Source: Springer Online Journal Archives 1860-2000
    Topics: Biology , Geosciences
    Notes: Abstract The diatom composition in surface sediments from 119 northern Swedish lakes was studied to examine the relationship with lake-water pH, alkalinity, and colour. Diatom-based predictive models, using weighted-averaging (WA) regression and calibration, partial least squares (PLS) regression and calibration, and weighted-averaging partial least squares (WA-PLS) regression and calibration, were developed for inferences of water chemistry conditions. The non-linear response between the diatom assemblages and pH and alkalinity was best modelled by weighted-averaging methods. The lowest prediction error for pH was obtained using weighted averaging, with or without tolerance downweighting. For alkalinity there was still some information in the residual structure after extracting the first weighted-averaging component, which resulted in a slight improvement of predictions when using a two component WA-PLS model. The best colour predictions were obtained using a two component PLS model. Principal component analysis (PCA) of the prediction errors, with some characteristics of the training set included as passive variables, was performed to compare the results for the different alkalinity predictive models. The results indicate that calibration techniques utilizing more than one component (PLS and WA-PLS) can improve the predictions for lakes with diatom taxa that have broad tolerances. Furthermore, we show that WA-PLS performs best compared with the other techniques for those lakes that have a high relative abundance of the most dominant taxa and a corresponding low sample heterogeneity.
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  • 27
    ISSN: 1573-0417
    Keywords: palaeolimnology ; acidification ; diatoms ; chrysophytes ; pigments ; chironomids ; temperature ; Alps ; Italy
    Source: Springer Online Journal Archives 1860-2000
    Topics: Biology , Geosciences
    Notes: Abstract A palaeoecological study of an oligotrophic alpine lake, Paione Superiore (Italy), provided a record of historical changes in water quality. Historical trends in lake acidification were reconstructed by means of calibration and regression equations from diatoms, chrysophycean scales and pigment ratios. The historical pH was inferred by using two different diatom calibration data sets, one specific to the alpine region. These pH trends, together with the record of sedimentary carbonaceous particles and chironomid remains, indicate a recent acidification of this low alkalinity lake. Concentration of total organic matter, organic carbon, nitrogen, biogenic silica (BSiO2), chlorophyll derivatives (CD), fucoxanthin, diatom cell concentration and number of chironomid head capsules increased during the last 2–3 decades. When expressed as accumulation rates, most of these parameters tended to decrease from the past century to c. 1950, then all except P increased to the present day. A marked increase in sedimentary nitrogen may be related to atmospheric pollution and to the general increases in output of N in Europe. High C/N ratios indicate a prevailing allochthonous source of organic matter. Finally, the increase in measured air temperature from the mid-1800's appeared to be related to lake water pH before industrialization: cold periods generally led to lower pH and vice-versa. The more recent phenomenon of anthropogenic acidification has apparently decoupled this climatic-water chemistry relationship.
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  • 28
    ISSN: 1432-0495
    Keywords: Key words Sediments ; Mineralogy ; Geochemistry ; Heavy metals ; Biogeochemistry
    Source: Springer Online Journal Archives 1860-2000
    Topics: Geosciences
    Notes: Abstract We have studied sediments of the Piscinas beach (SW Sardinia, Italy), which is supplied by two streams that wash mine dumps of abandoned lead and zinc mines at Montevecchio and Ingurtosu, situated inland from the supply basin of the beach itself. A study of the texture, mineralogy and geochemistry of the sediments was conducted for the purpose of assessing the possible influence of the mine waste on the composition of the sediments, looking for any anomalous enrichments in heavy metals. Furthermore, to evaluate and quantify metal release into the sea, samples of Posidonia oceanica, a bioaccumulator marine plant, were also examined. The results indicate that the distribution of heavy metals in the foreshore sediments is particularly affected by the contribution of the streams, while in the shoreface the distribution is affected by the currents that disperse the sediments both out to sea and southwards. The metal contents of the Posidonia oceanica are correlated with the different stages of activity of the mines.
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  • 29
    ISSN: 1432-0495
    Keywords: Sedimentation ; Geochemistry ; Mangrove environment
    Source: Springer Online Journal Archives 1860-2000
    Topics: Geosciences
    Notes: Abstract The textural and geochemical aspects of the sediments of a tropical mangrove ecosystem have been studied and discussed. The sediments are characterized by the abundance of silt and sand with minor amounts of clay. The mean size of the sediment ranges from 0.205 mm to 0.098 mm (fine to very fine grained sand). The sediments are very poorly sorted, negatively to very negatively skewed, and platy to extremely leptokurtic in nature. The organic carbon content of the sediments ranges from 0,33% to 4.93%, which is controlled by the particle size of the sediments. The CaCO3 content is five times the enrichment of organic carbon. This enhanced CaCO3 content of the mangrove sediments might be a result of the abundance of shell fragments in the sediments. The shell mining activities in the estuarine bed adjoining the Kumarakam mangroves also contribute a substantial amount of lime muds to the mangrove area, which in turn add CaCO3 to the sediments. The relative concentrations of heavy metals are Fe 〉 Mn 〉 Cr 〉 Zn 〉 Ni 〉 Cu. All heavy metals other than Fe show an increase in concentration compared to the other parts of the estuarine bed. Cluster analysis indicates that the contents of organic C, Fe and Mn have a marked bearing on the Cr, Zn, Ni, and Cu levels of the mangrove sediments.
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  • 30
    ISSN: 1432-0495
    Keywords: Key words Mangrove ; Geochemistry ; Biological productivity ; Anthropogenic impacts ; Heavy metal sink
    Source: Springer Online Journal Archives 1860-2000
    Topics: Geosciences
    Notes: Abstract  Spatial and temporal geochemical variations of various parameters in the water and sediment of a relatively small mangrove situated on the southeast coast of India were examined in detail for the first time. The water quality generally reflects the impact of seawater and the Vellar estuary (mixing effect) aided by evaporation and in situ biological productivity. The depletion and fluctuation of dissolved silica are controlled by biological processes. Nitrate and phosphate are contributed by fertilizer input from adjoining agriculture fields. Total suspended matter (TSM) shows an erratic range and trend due to deforestation and resuspension processes. Sand and silt constitute 70–90% of the sediments. Statistical analysis of the sediments shows the prevalence of a moderately high-energy environment with very effective winnowing activity. Organic matter content is higher in the mangrove sediments in comparison to adjacent estuaries. Water and sediment show fluctuations in their chemical concentration, but no specific trends could be identified. Heavy metals are also enriched in the mangrove sediments, indicating their unique chemical behavior and the existence of trapping mechanisms. Factor analysis and correlation analysis of water and sediments show the complexity of the system and the multitude of contributing sources. The core sediment chemistry suggests the depletion of metal input due to the damming of the detrital inputs. The Pichavaram mangrove seems to be relatively unpolluted, since the anthropogenic signal observed is small and acts as a sink for heavy metals contributed from a multitude of sources without an adverse effect.
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  • 31
    ISSN: 1432-0495
    Keywords: Key words Sedimentation ; Geochemistry ; Mangrove environment
    Source: Springer Online Journal Archives 1860-2000
    Topics: Geosciences
    Notes: Abstract The textural and geochemical aspects of the sediments of a tropical mangrove ecosystem have been studied and discussed. The sediments are characterized by the abundance of silt and sand with minoramounts of clay. The mean size of the sediment ranges from 0.205 mm to 0.098 mm (fine to very fine grained sand). The sediments are very poorly sorted, negatively to very negatively skewed, and platy to extremely leptokurtic in nature. The organic carbon content of the sediments ranges from 0.33% to 4.93%, which is controlled by the particle size of the sediments. The CaCO3 content is five times the enrichment of organic carbon. This enhanced CaCO3 content of the mangrove sediments might be a result of the abundance of shell fragments in the sediments. The shell mining activities in the estuarine bed adjoining the Kumarakam mangroves also contribute a substantial amount of lime muds to the mangrove area, which in turn add CaCO3 to the sediments. The relative concentrations of heavy metals are Fe〉Mn〉Cr〉Zn〉Ni〉Cu. All heavy metals other than Fe show an increase in concentration compared to the other parts of the estuarine bed. Cluster analysis indicates that the contents of organic C, Fe and Mn have a marked bearing on the Cr, Zn, Ni, and Cu levels of the mangrove sediments.
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  • 32
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    Environmental geology 38 (1999), S. 149-158 
    ISSN: 1432-0495
    Keywords: Key words Limestone ; Weathering ; Historical buildings ; Petrographical characteristics ; Geochemistry ; Physical properties
    Source: Springer Online Journal Archives 1860-2000
    Topics: Geosciences
    Notes: Abstract  I˙stanbul, the capital of the east Roman, Byzantine and Ottoman Empires embraces two continents, one arm reaching out to Asia, the other to Europe. It is therefore, a rich city in terms of monuments and historical cites. Shell limestones of Upper Miocene age are used as building stone in the majority of the monuments in I˙stanbul because of their attractiveness, availability and workability. The durability characteristics of the limestones are examined, and those factors that are responsible for atmospheric weathering are discussed, in a humid and marine environment with important problems of urban pollution, specifically due to traffic. In the present study weathering of the building stones were first examined in situ by macroscopic observations. The weathering that developed as a result of environmental effects since this limestone was first used in historical monuments has been affected 0.1–1.5 cm deep from the surface. The weathered facing stone of Şehzade Mehmed Mosque in I˙stanbul is undergoing a program of progressive replacement. During this study, samples were taken from this monument where the shell limestone was used. The stone surface was principally examined by means of Scanning Electron Microscopy (SEM). Petrographical and mineralogical analyses were made by using optical microscopy and X-ray diffraction method. The physico-chemical properties of these rocks control their weathering behaviour and reactivity. Major and trace element analyses and the effect of deterioration on the physical properties of the limestones (unit weight, porosity and water absorption) have also been investigated. Studies on the samples implies that weathering on the stone surface caused important variations on the physical characteristics of the rock.
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  • 33
    ISSN: 1432-0819
    Keywords: Key words Mount Meager ; Volcanic stratigraphy ; Pyroclastic flow ; Lahar ; Avalanche ; Petrography ; Geochemistry
    Source: Springer Online Journal Archives 1860-2000
    Topics: Geosciences
    Notes: Abstract  The Pebble Creek Formation (previously known as the Bridge River Assemblage) comprises the eruptive products of a 2350 calendar year B.P. eruption of the Mount Meager volcanic complex and two rock avalanche deposits. Volcanic rocks of the Pebble Creek Formation are the youngest known volcanic rocks of this complex. They are dacitic in composition and contain phenocrysts of plagioclase, orthopyroxene, amphibole, biotite and minor oxides in a glassy groundmass. The eruption was episodic, and the formation comprises fallout pumice (Bridge River tephra), pyroclastic flows, lahars and a lava flow. It also includes a unique form of welded block and ash breccia derived from collapsing fronts of the lava flow. This Merapi-type breccia dammed the Lillooet River. Collapse of the dam triggered a flood that flowed down the Lillooet Valley. The flood had an estimated total volume of 109 m3 and inundated the Lillooet Valley to a depth of at least 30 m above the paleo-valley floor 5.5 km downstream of the blockage. Rock avalanches comprising mainly blocks of Plinth Assemblage volcanic rocks (an older formation making up part of the Mount Meager volcanic complex) underlie and overlie the primary volcanic units of the Formation. Both rock avalanches are unrelated to the 2350 B.P. eruption, although the post-eruption avalanche may have its origins in the over-steepened slopes created by the explosive phase of the eruption. Much of the stratigraphic complexity evident in the Pebble Creek Formation results from deposition in a narrow, steep-sided mountain valley containing a major river.
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  • 34
    ISSN: 1573-868X
    Keywords: Chlorophyll a ; primary productivity ; diatoms ; Thalassiosira ; cast and west distribution pattern ; midwinter ; subarctic North Pacific ; naked ciliates ; copepods
    Source: Springer Online Journal Archives 1860-2000
    Topics: Geosciences
    Notes: Abstract We have determined chlorophyll a (Chla) concentration, primary productivity, cell density and species composition of diatoms, and the number of microzooplankton at the surface in the subarctic North Pacific in January 1996. The wet weight of copepods obtained by vertical tows from 150 m to the surface was also measured during the cruise. Chla concentration and primary productivity tended to be higher in the region west of 180°, the western subarctic North Pacific (WSNP), than east of 180°, the eastern subarctic North Pacific (ESNP). The same results were observed for the total diatom cell densities and for the genera Thalassiosira and Denticulopsis. Significant linear relationships were observed between the Thalassiosira cell density and Chla concentration and primary productivity, indicating that Thalassiosira contributes to the high-WSNP and low-ESNP distribution patterns of Chla concentration and primary productivity. Moreover, naked ciliate abundance tended to be lower in the WSNP than in the ESNP, whereas copepod biomass showed an inverse trend. Significantly negative Spearman rank correlations were found between the Thalassiosira cell density and the number of naked ciliates and between the number of naked ciliates and the wet weight of copepods. These results indicate that copepod grazing indirectly controls Thalassiosira cell density via predation on the naked ciliates. We conclude that the high copepod biomass in the WSNP is a factor controlling the high-WSNP and low-ESNP Thalassiosira abundance and hence Chla concentration and primary productivity patterns.
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  • 35
    ISSN: 0016-7835
    Keywords: Key words L. Palaeozoic volcanics ; Amphibolites ; Geochemistry ; Petrogenesis ; Crustal contamination ; Palaeotectonic environment ; Orlica-Śnieżnik dome ; Bohemian massif
    Source: Springer Online Journal Archives 1860-2000
    Topics: Geosciences
    Notes: Abstract  Orthoamphibolites within and marginal to the Orlica-Śnieżnik dome in the eastern Bohemian massif are associated with a series of Proterozoic-Lower Palaeozoic supracrustal meta-sediments of the Stronie, Nové Město and Staré Město formations. Massive and variably foliated amphibolites range from common epidote–plagioclase–blue-green/green hornblende varieties to assemblages with diopside, garnet and brown amphibole. All the amphibolites have a basaltic composition and are divided into three main chemical groups which are intimately associated in the field: main series tholeiites, low-Ti tholeiites and alkali basalts. All groups exhibit a common enrichment in LIL elements+Nb+Ta (relative to high-field-strength elements) which reflects contamination by upper continental crust and/or pelagic sediment compositions. The gross chemistry of the tholeiites approaches that for MORB, although the geological environment and nature of crustal contamination suggests that the basaltic precursors were probably emplaced in a rifted ensialic basinal environment. If the amphibolites are representative of an early phase of the Lower Palaeozoic fragmentation of Gondwanaland, then rifting did not fully develop ocean crust. The wider significance of the chemical interpretation implies that some of the variation from Variscan Proterozoic-Palaeozoic metabasite suites that is ascribed to a complex of different eruptive settings could be accounted for by variable contamination and/or source composition.
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  • 36
    ISSN: 0016-7835
    Keywords: Key words Sediment-hosted deposits ; Magnesite ; Siderite ; Bashkir mega-anticline ; Riphean ; Metasomatism ; Geochemistry
    Source: Springer Online Journal Archives 1860-2000
    Topics: Geosciences
    Notes: Abstract In the Bashkir mega-anticline (western Urals) stratabound magnesite, siderite, fluorite and base-metal deposits are hosted by a sequence of Riphean sediments with a thickness of more than 12 km. The giant deposits of siderite (Bakal) and sparry magnesite (Satka) belong to the largest known mineral deposits of this type on Earth but are still disputed with respect to their origin. Both the Fe- and Mg-carbonate ores are clearly characterized by mimetic preservation of sedimentary and diagenetic textures of the host carbonate sediments, giving evidence of epigenetic metasomatic replacement. In the stratiform magnesite deposits of Satka, O- and C-isotopes, REE pattern and the lithostratigraphic position of the ore, point to the reflux of early diagenetic Mg-rich brines being responsible for the selective replacement of brecciated dolomite. The Bakal siderite deposits are hosted by Lower Riphean carbonate rocks and are controlled by a Lower to Middle Riphean unconformity marked by deep erosion and subsequent transgression-related sedimentation of coarse clastics. Their independence of carbonate lithofacies and their trace element distribution are indicative of metasomatic processes. Fe-bearing fluids have probably been generated by low-grade metamorphic (catagenetic) devolatization from underlying argillites, causing the metasomatic formation of large siderite ore bodies in the Bakal carbonates due to the focusing of the fluid flow by the overlying Mid-Riphean coarse clastics.
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  • 37
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    Geologische Rundschau 85 (1996), S. 162-171 
    ISSN: 0016-7835
    Keywords: Key words KTB pilot hole ; Metabasites ; Geochemistry ; Sr ; Nd isotopes ; Fluid ; Lamprophyre
    Source: Springer Online Journal Archives 1860-2000
    Topics: Geosciences
    Notes: Abstract  Geochemical analyses were interpreted on the dominant lithological units and on a deep crustal fluid from the Continental Deep Drilling Project (KTB) Pilot Hole, situated at the western margin of the Variscan Bohemian Massif. The biotite gneiss (from 384 m depth) shows a rare earth element pattern very similar to the European shale composite with Nd model ages of 940 Ma (CHUR) and 1.4 Ga (DM). The lamprophyre dike in the upper profile (1549 m), a nepheline and olivine normative basalt, is geochemically and isotopically similar to rocks from the Tertiary Central European Volcanic Province. The lower metabasite sequence (3575–4000 m), with an intrusion age of approximately 500 Ma, is made up primarily of highly metamorphosed subalkalic olivine basalts. The geochemical characteristics of the metabasites are a (La/Yb)N of 5–10, an La concentration of 20–50 times chondrite as well as (87Sr/86Sr)i of 0.7035–0.7038 and εNd(T) of 4–6. These values suggest a depleted mantle source for the igneous precursors, evolving by assimilation-fractional crystallization processes with up to 25% of upper crust into the ultramafic, basaltic, and intermediate rock types of the metabasite sequence. The strong geochemical and chronological similarities between the KTB metabasites and rocks from the Münchberg Massif suggest that these units belong to the same lithological complex. The high salinity as well as the radiogenic 87Sr/86Sr ratio of 0.709413 in the KTB fluid from 4000 m depth might be the result of migrating fluids reacting with the regional Permo-Mesozoic evaporite deposits, followed by extensive Sr isotopic exchange with the upper crust.
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