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  • Articles  (145)
  • eutrophication  (89)
  • DSC
  • Springer  (145)
  • American Association for the Advancement of Science
  • American Meteorological Society
  • 1995-1999  (102)
  • 1990-1994  (43)
  • 1999  (102)
  • 1993  (43)
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  • Articles  (145)
Publisher
  • Springer  (145)
  • American Association for the Advancement of Science
  • American Meteorological Society
  • Wiley-Blackwell  (8)
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  • 1995-1999  (102)
  • 1990-1994  (43)
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  • 1
    ISSN: 1572-8935
    Keywords: TDI-based polyurethane elastomers ; Tg ; Tglobal transition ; DSC ; TSC/RMA ; DMA
    Source: Springer Online Journal Archives 1860-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: Abstract Thermal transitions of TDI-based polyurethane elastomers with PTMO as the soft segment were characterized by the depolarization technique in TSC and by using with the thermal windowing technique on selected specimens in the RMA measurements. Results indicate that the broadened thermal transition in the glass transition region as observed in the DSC thermogram is related to the combined Tg transition and the Tglobal transition in the TSC spectrum. This Tglobal transition is associated with the macromolecular property as detected by tan δ in DMA measurement. The increase in the Tg with a high NCO content may be explained by the structural modification found on the urethanic chain with the additional linkage of the hard segment that affects the cooperative motion of the molecular chain. Data measured from DSC, TSC/RMA and DMA with simulated DEA and wide angle X-ray data are presented for the characterization of the polyurethanes. The RMA measurement leads to a compensation search on Tg transition and provides pertinent thermokinetic data that correlates the NCO content with changes in enthalpy and entropy on the relaxation behaviors in the Tg transition of polyurethane elastomers.
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  • 2
    ISSN: 1573-0417
    Keywords: South Sweden ; Holocene ; diatoms ; pollen ; eutrophication ; catchment history
    Source: Springer Online Journal Archives 1860-2000
    Topics: Biology , Geosciences
    Notes: Abstract Diatoms, pollen, physical and magnetic analyses of the sediments have been used to reconstruct the development over the last 6000 years of Lake Bussjösjön, a small lake in southern Sweden. Stratigraphic variations in a core of more than 15 m reveal changes in diatom assemblages, which correspond closely to changes in pollen, loss-on-ignition, and magnetic measurements that are related to land use and vegetation changes in the catchment. From ca 6000 BP to 2700 BP, a forest surrounded what was then a slightly eutrophic lake. The sudden appearance of Cyclostephanos dubius (Fricke) Round and several epiphytic/epipsammic diatoms at 2700 BP coincides with deforestation of the catchment (2700 BP to 2500 BP). A change in land use from predominantly pasture to arable land from 1300 BP to 1100 BP caused a high level of soil erosion with a decrease of C. dubius and the increase of Stephanodiscus species. An increase of epiphytic/epipsammic species coincides with increased arable farming and the change from a field-rotation to a crop-rotation system, and shows not only an increase in eutrophication but also changes in water depth. The influence of the catchment through time resulted in a smaller, shallower and eutrophic to hypertrophic lake.
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  • 3
    ISSN: 1573-0417
    Keywords: diatoms ; biogenic silica ; pigments ; biomass ; trophic state changes ; eutrophication ; Lake Constance ; Germany
    Source: Springer Online Journal Archives 1860-2000
    Topics: Biology , Geosciences
    Notes: Abstract In Lake Constance, phosphorus concentrations and the seasonal development of phytoplankton communities in water samples from the pelagic zone were regularly recorded since the 1950's. Before the 1950's, there were occasional investigations of plankton communities since 1896. We compared these data with the sedimentary record in two sediment cores. Then, the eutrophication history of Lake Constance was inferred from diatoms. The record of biogenic silica in the cores is discussed with respect to diatom biomass increase. Diatom assemblages in the sediment cores precisely reflected the pelagic diatom development for the period 1971--1992. Both sediment cores and the water samples have a high interannual variability of diatom assemblages. Below a sediment depth of 27 cm (AD 1920), more than 50% of the diatoms were partly corroded, and we limited the reconstruction of trophic state changes to the interval of 1920--1993. Oligotrophic conditions of Lake Constance were indicated by the dominance of various Cyclotella taxa from 1920 to 1940. Since 1939/1940, increasing abundance of it Tabellaria fenestrata showed oligotrophic to mesotrophic conditions. Between 1953 and 1956, increasing Stephanodiscus hantzschii and disappearing Cyclotella indicated advanced eutrophication and total phosphorus values ranged between 8--10 mg m-3 during turnover in late winter. Further eutrophication was shown by disappearing T. fenestrata and increasing S. minutulus in 1963. Maximum TP concentrations of 87 mg m-3 occurred in 1979/80 and was accompanied by increasing abundances of Aulacoseira granulata. From 1986 to 1992, reoccurrence of Tabellaria fenestrata and Cyclotella indicate some recovery of Lake Constance. Biogenic silica and diatom abundances were similar among cores but indicate a 3--4 fold increase of diatom biomass only. This was far below the estimate of biomass increase from sedimentary pigment data (25 fold) and the estimate of phytoplankton data from the literature (70 fold).
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  • 4
    ISSN: 1573-0417
    Keywords: Lake Arendsee ; Germany ; freeze-core ; eutrophication ; calcite ; near-infrared reflectance
    Source: Springer Online Journal Archives 1860-2000
    Topics: Biology , Geosciences
    Notes: Abstract The present study explored whether rapid, non-destructive near-infrared reflectance spectroscopy (NIRS) could complement conventional paleolimnological and chemical analyses of sediment cores for greater efficiency and cost-effectiveness. The study used a 47-cm long freeze-core from the deepest point in Lake Arendsee, Mecklenburg Plain in northern Germany taken in 1993 to elucidate eutrophication history and to identify the pre-impact algal communities in this system. The core had been analyzed for total C, CO32-, N, P, and diatoms. Thirty-four of the 47 1-cm thick core sections were scanned by NIRS and calibrations were developed for total C, CO32-, N, P, N:P, total diatoms, and three dominant diatom species with different sedimentary profiles (Stephanodiscus binatus, Cyclotella rossii, and Fragilaria crotonensis). Total C ranged from 167-194 mg g-1 dry weight (d.w.), CO32- from 31.3-66.4 mg g-1 d. w., N from 9.9-17.4 mg g-1 d. w., and P from 0.7-6.0 mg g-1 d. w. Calibrations developed using multiple linear regression between NIR-predicted values and chemically-measured values were excellent for P (r2 〉 0.99), good for C, N, and N:P (r2 〉 0.93), and satisfactory for CO32-(r2 〉 0.8). Calibrations for total diatoms and for individual species were highly statistically significant (r2 between 0.54 and 0.69). Although the calibrations are not useful for reliable predictions of the content of diatoms in the samples, the results indicate that NIRS detects spectral properties associated with diatoms or lake conditions when they were present, and that further work is warranted to attempt to improve the results. The study demonstrated that rapid, non-destructive, simultaneous analysis of total C, CO32-, N, P, and N:P in sediment cores is feasible.
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  • 5
    ISSN: 1573-0417
    Keywords: Chrysophyceae ; Synurophyceae ; cyst ; acid deposition ; eutrophication ; cottage development ; Muskoka-Haliburton ; Canada
    Source: Springer Online Journal Archives 1860-2000
    Topics: Biology , Geosciences
    Notes: Abstract Chrysophyte cysts preserved in recent and pre-industrial lake sediment samples from 54 Muskoka-Haliburton (Ontario) lakes were used in a paleolimnological study to determine the impact of acidic precipitation and cottage development on water quality. A total of 246 cyst morphotypes were identified. Ecological preferences of cyst morphotypes were determined using multivariate statistical analysis, cluster analysis, and species-environment correlations. Recent cyst assemblages were related to water chemistry and lake morphometric variables using Redundancy Analysis (RDA). The distribution of morphotypes was related to a gradient of acid neutralising capacity (ANC), expressed through the association of variables related to buffering (i.e. longitude, watershed area, and ionic concentration) with the first axis (λ1 = 0.29). Cyst assemblages were also defined, to a lesser extent (λ2 = 0.06), by a trophic status gradient, created through the combination of total nitrogen (TN), total phosphorus (TP), volume-weighted cottage density, and lake depth variables. The identification of lakewater pH and trophic status as important determinants of cyst assemblage structure allowed for the reconstruction of acidification and eutrophication related water chemistry changes using fossil cyst assemblages. The reconstruction of pre-industrial (pre-1850) water quality conditions with fossil cyst assemblages indicated that pH significantly decreased in 24.1% of the study lakes and increased in 16.7% of the lakes. Increases in pH in more alkaline drainage basins are attributed to alkalinity generation processes induced by acidic precipitation as has been shown in other studies. Total phosphorus (TP) concentrations significantly declined in 12.9% of the lakes and increased in 16.6% of lakes. Increases in [TP] were linked to cottage development. Decreases in trophic status may be due to landuse changes, the result of the acidification occurring in the area, or warmer and drier climates. A comparison of chrysophyte cyst and diatom water quality inferences show similar trends in pH changes. There is a good agreement between diatom and chrysophyte bioindicators with respect to [TP] changes in oligotrophic lakes (〈 10 μg/L); however, diatom inferences suggest that lakes with current [TP] values greater than 10 μg/L have decreased in trophic status over time, while chrysophyte reconstructions suggest that these same lakes have become more productive systems.
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  • 6
    ISSN: 1573-0417
    Keywords: Lake Gościąż ; varved sediments ; human impact ; eutrophication
    Source: Springer Online Journal Archives 1860-2000
    Topics: Biology , Geosciences
    Notes: Abstract According to historical sources, the development of settlement around Lake Gości& aogon;ż during the last 330 yrs was intense at two time periods: the second half of the 1700's, and from ca. 1880 until 1944. The small farms were then abandoned, following which the lake surroundings were planted with forest trees. The presented study of human influence on the lake ecosystem and surrounding vegetation has been based on analyses of general sediment composition and its chemistry, pollen, Cyanobacteria, Chlorophyceae, Rotatoria, Cladocera, and a preliminary diatom survey. The history of human impact has been divided into four phases: 1. Phase of small local hamlets (before ca. 1770): The human impact was rather moderate then, but the cultivation of Canabis sativa, Secale cereale and later of Fagopyrum is evidenced from that time. 2. Phase of ‘Hollandii’ settlement (ca. 1770-1863). Its influence is indicated first by the recession of deciduous wood (Corylus, Carpinus) stands, which triggered drastic drop of calcium in sediments. The development of rural economy in the area, including, an extension of agriculture (Secale and other cereals, crucifers, potatoes), and animal breeding based partly on grazing in the forest, is evidenced only after 1820. 3. Phase of German colonization (1863-1944): In the early periods (before 1910) the pollen spectra do not document any essential change in the type of farming, however, a serious disturbance of the lake ecosystem and sediment chemistry is evidenced by the blooms of Araphidinae diatoms and Tetraedron minimum, a maximum frequency of Bosmina longirostris, disturbances of the regular spring blooms of Chrysophyceae, appearance of vivianite, distinct maxima of organic matter, potassium, and iron concentration in sediments and an increase of the sedimentation rate. An intensification of agricultural activities commenced around 1910; woods, including also pinewoods, were then heavily devastated, and farming extended on poor soils, what was symptomatic for the general poverty of population. Coincidently in the lake, Centriceae showed blooms, Araphidinae diatoms and Tetraedron minimum developed, and the content of potassium, iron and phosphorus increased substantially, indicating altogether rising eutrophication. 4. Phase of restoration of the natural landscape (after 1945): The farm degradation from ca. 1944 is very weakly expressed in pollen data, which show a substantial fall of farming indicators from 1953/6 only, when the whole area was used for forest plantation. It was accompanied by a certainly spontaneous development of Betula and Alnus woods, this process progressing till recent time. The gradual extinction of farming activity near Lake Gościąż was accompanied by abrupt changes in the lake ecosystem, expressed by the restored blooms of Chrysophyceae expansion of planktonic Cladocera, rapid decline of phosphorus and extinction of vivianite from sediments. As documented by the drop of Cu/Zn ratio, lake hypolimnion has been weakly oxidized since 1949, what was probably responsible for the drop of Fe and Mn content in sediments. Increasing strength of overturns affected preservation of laminae in sediments, which almost completely disappeared after 1966.
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  • 7
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    Journal of paleolimnology 21 (1999), S. 375-393 
    ISSN: 1573-0417
    Keywords: CaCO3 ; organic carbon ; iron ; manganese ; eutrophication
    Source: Springer Online Journal Archives 1860-2000
    Topics: Biology , Geosciences
    Notes: Abstract The concentrations of organic carbon (OC) and CaCO3 in lake sediments are often inversely related. This relation occurs in surface sediments from different locations in the same lake, surface sediments from different lakes, and with depth in Holocene sediments. Where data on accumulation rates are available, the relation holds for organic carbon and CaCO3 accumulation rates as well. An increase of several percent OC is accompanied by a decrease of several tens of percent CaCO3 indicating that the inverse relation is not due to simple dilution of one component by another. It appears from core data that once the OC concentration in the sediments becomes greater than about 12%, the CO2 produced by decomposition of that OC and production of organic acids lowers the pH of anoxic pore waters enough to dissolve any CaCO3 that reaches the sediment-water interface. In a lake with a seasonally anoxic hypolimnion, processes in the water column also can produce an inverse relation between OC and CaCO3 over time. If productivity of the lake increases, the rain rate of OC from the epilimnion increases. Biogenic removal of CO2 and accompanying increase in pH also may increase the production of CaCO3. However, the decomposition of organic matter in the hypolimnion will decrease the pH of the hypolimnion causing greater dissolution of CaCO3 and therefore a decrease in the rain rate of CaCO3 to the sediment-water interface.
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  • 8
    ISSN: 1573-0417
    Keywords: palaeolimnology ; environmental change ; sediment ; eutrophication ; chironomids ; Finland
    Source: Springer Online Journal Archives 1860-2000
    Topics: Biology , Geosciences
    Notes: Abstract The sedimentary chironomid stratigraphy in short-core samples covering approx. the past 150 years was studied in the northernmost basin of Lake Päijänne, southern Finland (62° 11′ N, 25° 48′ E). The basin has received effluent loading from the wood-processing industry and municipal waste water. Four developmental stages were distinguished based on the changes in chironomid assemblages: 1. Pre-industrial stage (dated by the210Pb method as covering approximately the period 1838–1936), 2. Stage of increasing pollution (approx. 1944–1973), 3. The ‘black decade’, or the period of worst pollution (approx. 1973–1983), and 4. Water protection stage (approx. 1983 onwards). During the first stage the basin suffered very little human interference and was oligotrophic, with values of 4.00–4.28 for Wiederholm's Benthic Quality Index (BQI). During the second stage it altered between weak mesotrophy and moderate mesotrophy, and the former profundal assemblages characterized byHeterotrissocladius subpilosus andMicropsectra were replaced bySergentia coracina andChironomus anthracinus gr. The BQI ranged from 2.75 to 3.50. This process led to the extirpation ofH. subpilosus. Eutrophication of the basin reached its climax during the ‘black decade’, representing moderate eutrophy with a BQI of 2.15. The profundal assemblages were composed mainly ofChironomus anthracinus gr. andC. plumosus gr. The adoption of more effective waste water purification processes in both the wood-processing industry and the municipal treatment plant markedly reduced effluent loading, especially BOD loading during the fourth stage, and this led to a recovery in the basin. At present it is mesotrophic, with a BQI of 2.90–3.00, and its biological conditions resemble those of the second stage in the 1950's and 1960's.
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  • 9
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    Nutrient cycling in agroecosystems 36 (1993), S. 95-103 
    ISSN: 1573-0867
    Keywords: eutrophication ; phosphorus ; fertilizer ; Peel-Harvey estuary ; algal blooms
    Source: Springer Online Journal Archives 1860-2000
    Topics: Agriculture, Forestry, Horticulture, Fishery, Domestic Science, Nutrition
    Notes: Abstract An excess of plant nutrients has caused serious eutrophication in aquatic ecosystems of southwestern Australia manifested by excessive growth and accumulation of green and bluegreen algae. Phosphorus is generally the limiting nutrient for algal growth and phosphatic fertilizers applied to nutrient-deficient, leaching, sandy soils are the main source of P, supplemented by rural industry point sources. Nitrogen is the limiting nutrient in marine embayments with little drainage from the land. Measures to reduce the load of P delivered to drainage include basing fertilizer application rates on soil testing for P and the use of less soluble P fertilizers. Catchment management plans are being implemented with community involvement to reduce P loads and maintain agricultural production. This introductory paper reviews the history of eutrophication in southwestern Australia and of studies into its causes, principally in the large Peel-Harvey estuary. It briefly summarises other papers in this special issue concerned with different aspects of the problem: how to fertilize the land without causing eutrophication.
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  • 10
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    Nutrient cycling in agroecosystems 36 (1993), S. 123-125 
    ISSN: 1573-0867
    Keywords: agricultural development ; management measures ; eutrophication
    Source: Springer Online Journal Archives 1860-2000
    Topics: Agriculture, Forestry, Horticulture, Fishery, Domestic Science, Nutrition
    Notes: Abstract A number of factors have contributed to the development of eutrophication problems in south-western Australia. These include the climate of the region, the nature of the soils in the catchments of the waterbodies, and the practices necessary for the development of profitable agriculture. This paper provides a brief review of these factors, of the development of agriculture, and of management measures which have been developed to combat the causes of eutrophication.
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  • 11
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    Nutrient cycling in agroecosystems 36 (1993), S. 185-192 
    ISSN: 1573-0867
    Keywords: catchment management ; eutrophication ; Peel-Harvey catchment ; Western Australia ; nutrient losses from soil systems
    Source: Springer Online Journal Archives 1860-2000
    Topics: Agriculture, Forestry, Horticulture, Fishery, Domestic Science, Nutrition
    Notes: Abstract A broad programme for the management of the Peel-Harvey catchment was proposed in 1989. This has evolved into an approach which is regionally based and employs a collaborative way of working with landholder and agricultural industry groups to reduce current levels of nutrient loss to drainage. The programme also aims to coordinate the activities of government agencies, and includes land use planning instruments at various levels to ensure future developments incorporate catchment management objectives. Key operating principles are to ensure consistency and equity in the impact of management measures, close involvement of the community with the development of corrective policies and programmes, and the development of a community-wide awareness of the problem. In the early stages of the management programme, maximum effectiveness in reducing P loads has been pursued through identifying and controlling point sources of nutrients. Management of diffuse sources of P has concentrated on measures which do not have an economic penalty for the landholder. These measures include better water management to reduce phosphorus loss and to make better use of the winter excess of rainfall, using bauxite residue to improve the P retaining properties of sandy soils, and a fertilizer advisory programme based on assessing the nutrient requirements of individual landholders' soils.
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  • 12
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    Nutrient cycling in agroecosystems 34 (1993), S. 85-94 
    ISSN: 1573-0867
    Keywords: phosphorus leaching ; bauxite residue ; red mud ; soil amendment ; eutrophication ; sandy soils
    Source: Springer Online Journal Archives 1860-2000
    Topics: Agriculture, Forestry, Horticulture, Fishery, Domestic Science, Nutrition
    Notes: Abstract The Peel-Harvey estuary on the Swan Coastal Plain, Western Australia has become eutrophic partly because of the leaching of fertiliser phosphorus from sandy soils. The acid, coarse textured sandy soils are predominantly quartz, have a low iron and aluminium content and do not retain phosphorus. Red mud, derived from bauxite, is a by-product of the alumina industry and has the ability to retain phosphorus. Retention of phosphorus is enhanced when the red mud is neutralised with gypsum. Red mud has been suggested as a soil amendment to reduce phosphorus leaching. To investigate the reduction in the leaching of phosphorus from soils amended with red mud, weirs were constructed at the outlets from a pair of catchments to quantify the amount of phosphorus in the streamflow. Both catchments were deep grey Bassendean sand. One of the catchments was treated with 80 t/ha of red mud which had been neutralised with waste gypsum from the phosphate industry. The red mud was applied to the soil surface using conventional fertiliser spreading equipment. The other catchment was untreated. The red mud reduced phosphorus loss by 70% from 13.8 kg/ha on the untreated catchment, to 4.2 kg/ha on the treated catchment. Both catchments were treated with 20.4 kg/ha of phosphorus as superphosphate. The catchment treated with red mud also received a further 41.5 kg/ha of phosphorus from the phosphogypsum that was used to neutralise the red mud. Our results show that red mud reduces phosphorus leaching and is potentially a nutrient management option in sandy soils. Red mud has the potential to reduce the impact of agriculture on the estuarine environment and has implications for the continued expansion and intensification of agriculture in the Peel-Harvey catchment.
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  • 13
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    Nutrient cycling in agroecosystems 35 (1993), S. 1-12 
    ISSN: 1573-0867
    Keywords: Ammonia volatilization ; denitrification ; eutrophication ; nitrate leaching ; pollution ; soil degradation
    Source: Springer Online Journal Archives 1860-2000
    Topics: Agriculture, Forestry, Horticulture, Fishery, Domestic Science, Nutrition
    Notes: Abstract Total world consumption of fertilizer N, P2O5, and K2O in 1990/1991 was 78, 37, and 26 million tons per annum, respectively, with a projected yearly increase of demand of about 2 to 3%. Trends in crop production (maize and wheat) in the last four decades show that N application rates increased about 15 times whereas its accumulation in grain increased only 3 to 4 times. At the same time nutrient recovery by crops remained relatively low (e.g. about 50% for N). This represents a potentially alarming situation from environmental, economic and resource conservation points of view and indicates an urgent need for improving efficiency of fertilizer use. Anticipated benefits from slow/controlled release fertilizers (SRF/CRF) are addressed through two main processes: a. nutrient availability in the plant-soil system as affected by the interaction/competition between: plant roots, soil microorganisms, chemical reactions and pathways for loss; and b. matching nutrient release with plant demand. The various aspects of fertilization and environmental hazards associated with SRF/CRF and factors affecting nutrient use efficiency (NUE) are discussed in the light of these controlling processes. Environmental aspects include: pollution by nitrate, phosphate, and emission/volatilization of N2O or NH3; quality of food and fibers; and factors affecting soil degradation. Agronomic or physiologic aspects include: reduced losses of nutrients, labour saving, reduction of specific stress or toxicity, increased availability of nutrients and induction of synergistic effects between specific chemical forms of nutrients (e.g. interaction of mixed NH4/NO3 nutrition with K, effects of physiological acidification of the rhizosphere on P and Fe availability etc.). Despite the environmental and agronomic benefits offered by SRF/CRF their practical use in agriculture is still very limited. Possible measures which may encourage their use in practice are: a better assessment of expected benefits; attainment of improved technologies or concepts for producing more efficient and less expensive SRF/CRF; optimal design of fertilizer compositions to induce synergistic effects; better understanding of the mechanisms which control nutrient release; construction of conceptual and mathematical models for predicting release rates and patterns under both laboratory and field conditions, for supporting the technologist, farmer and environmentalist in their decision making.
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  • 14
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    Aquatic sciences 55 (1993), S. 76-86 
    ISSN: 1420-9055
    Keywords: Sa velinus alpinus ; growth ; Lake Geneva ; latitude ; eutrophication ; fish density
    Source: Springer Online Journal Archives 1860-2000
    Topics: Biology
    Notes: Abstract The growth rate of the Arctic charr,Salvelinus alpinus (L.), is exceptionally high in Lake Geneva; one of the highest every recorded. This can be explained by three factors: (1) the Arctic charr of Lake Geneva is the most southerly indigenous population in the world, (2) the trophic resources are important because of the eutrophication of the lake, (3) the fish density is low.
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  • 15
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    Journal of thermal analysis and calorimetry 39 (1993), S. 177-185 
    ISSN: 1572-8943
    Keywords: conducting polymers ; DSC ; heat-induced condensation reaction ; hydrogen-bonding ; intramolecular and inter-molecular interaction ; polyaniline ; poly(o-aminobenzoic acid) ; poly(o-aminobenzyl alcohol) ; TG
    Source: Springer Online Journal Archives 1860-2000
    Topics: Chemistry and Pharmacology
    Description / Table of Contents: Zusammenfassung Es wurden die thermischen Eigenschaften von Polyanilin (PANI), Poly(o-aminobenzoylsäure) (POABAC) und Poly(o-aminobenzylalkohol) (POABOL) ermittelt und mittels TG und DSC miteinander verglichen. Die höhere Thermostabilität von POABOL wird der wärmeinduzierten Kondensationsreaktion zwischen den Polymerketten zugeschrieben. Die DSC-Resultate weisen auf sowohl intra- als auch intermolekulare Wechselwirkungen in Form von Wasserstoffbrückenbindungen infolge der Substituenten in POABAC und POABOL hin. Diese Wechselwirkungen treten hauptsächlich in der dotierten Form auf und werden in großem Maße reduziert, wenn die Dotierungsmittel bei höheren Temperaturen ausgetrieben werden.
    Notes: Abstract The thermal characteristics of polyaniline (PANI), poly(o-aminobenzoic acid) (POABAC) and poly(o-aminobenzyl alcohol) (POABOL) are determined and compared by thermogravimetry (TG) and differential scanning calorimetry (DSC). The higher thermal stability of POABOL is attributed to heat-induced condensation between the polymer chains. The DSC results suggest both intra- and inter-molecular interaction in the form of hydrogen bonding due to the substituent group in POABAC and POABOL. These interactions, however, occur mainly in the doped from and is greatly reduced when the dopant is expelled from the system at higher temperatures.
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  • 16
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    Journal of thermal analysis and calorimetry 39 (1993), S. 393-411 
    ISSN: 1572-8943
    Keywords: azoxybenzenes ; binary systems of cholesteryl esters ; DSC ; thermomicroscopy
    Source: Springer Online Journal Archives 1860-2000
    Topics: Chemistry and Pharmacology
    Description / Table of Contents: Zusammenfassung Die binären Systeme von Cholesterylnonanoat und 4,4′-Bis(hexyloxy)azoxybenzol (1) und mit 4,4′-Bis(heptyloxy)azoxybenzol (2) besitzen induzierte smektischeA-Phasen mit Umwandlungspunktmaximum. Während bei (1) die smektischeA-Phase beim Erhitzen in ihrem ganzen Existenzbereich zur cholesterischen Phase umgewandelt wird, ist bei (2) das Maximum gegenüber der cholesterischen Phase stabilisert und geht direkt in die isotrope Schmelze über. Beide Maxima weisen das Molverhältnis 1∶1 auf. Im System (2) tritt außerdem eine smektischeC-Phase auf. Cholesterylhexadecanoat bildet mit Cholesterylnonanoat (3) und mit Cholesteryltetradecanoat (4) smektische und cholesterische Mischkristallreihen nach Typus I bzw. III Roozeboom. Durch die relative Stabilisierung von instabilen Festkristallmodifikationen der Komponenten in bestimmten Mischung sbereichen kommt es zur Ausbildung zusätzlicher, metastabiler Eutektika, die sich z.T. nicht in die thermodynamisch stabilen Formen umwandeln lassen. Dadurch ist es bei früheren Untersuchungen zu Irrtümern gekommen. In den Systemen (1) bis (3) bilden die Festkristalle einfache Eutektika, im System (4) Mischkristalle nach Typus V Roozeboom.
    Notes: Abstract The binary systems of cholesteryl nonanoate with 4,4′-bis(hexyloxy)azoxybenzene (1) and with 4,4′-bis(heptyloxy)azoxybenzene (2) show induced smecticA phases with transition point maximum. Whereas in (1) the smecticA phase is transformed into the cholesteric phase on heating within the whole range of its existence, in (2) the maximum of the smectic phase is stabilized compared with the cholesteric phase and clears into the isotropic melt directly. The molecular ratio of the maximum is 1∶1 in both cases. Moreover in system (2) a smecticC phase was observed. Cholesterylhexadecanoate forms series of smectic and cholesteric mixed crystals of type I resp. III Roozeboom with cholesteryl nonanoate (3) and with cholesteryl tetradecanoate (4). As the unstable solid modifications of the components become relatively stabilized in some mixtures, additional metastable eutectics are formed, which hardly allow to be transformed into the thermodynamic stable solid crystals. Thus errors happened at previous investigations. In the systems (1) to (3) the solid crystals show simple eutectics, in system (4) mixed crystals type V Roozeboom are formed.
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  • 17
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    Journal of thermal analysis and calorimetry 55 (1999), S. 9-19 
    ISSN: 1572-8943
    Keywords: ARC ; DSC ; HFC ; kinetics
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    Topics: Chemistry and Pharmacology
    Notes: Abstract Isopropylnitrate (IPN) is described as a detonable material used in propellants and explosives. While there is considerable information available on its sensitivity and compatibility with other materials, very little is known about its thermochemical properties. This paper will describe the results obtained from some DSC, heat flux calorimetry (HFC) and accelerating rate calorimetry (ARC) measurements. The ASTM DSC method using a hermetic aluminum pan having a lid with a laser-produced pin hole was used to determine the vapour pressure of IPN1. Results calculated from an Antoine equation are in substantial agreement with those determined from DSC measurements. From the latter measurements, the enthalpy of vaporization was determined to be 35.32±0.62 kJ mol−1. Attempts to determine vapour pressures above about 0.8 MPa resulted in significant decomposition of IPNg. The enthalpy change for decomposition in sealed glass systems was found to be -3.43±0.09 kJ g−1 and -3.85±0.03 kJ g−1, respectively from DSC and HFC measurements on IPN1 samples loaded in air. Slightly larger exotherms were observed for the HFC results in air than those in inert gas, suggesting some oxidation occurs. In contrast, no significant difference in the observed onset temperature of about 150°C was observed for both the HFC and ARC results. From DSC measurements, an Arrhenius activation energy for decomposition of 126±4 kJ mol−1 was found. These measurements were also conducted in sealed glass systems and decomposition appeared to proceed primarily from the liquid phase.
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  • 18
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    Journal of thermal analysis and calorimetry 55 (1999), S. 67-76 
    ISSN: 1572-8943
    Keywords: activation energy ; DSC ; ethylene-vinyl acetate copolymer ; TG ; TG/IR ; thermal degradation
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    Topics: Chemistry and Pharmacology
    Notes: Abstract When ethylene-vinyl acetate copolymer, EVA, is heated, a two-stage thermal degradation occurs following its melting. The vinyl acetate content of the copolymer was determined to be 43.8% by using TA 2950 and TA 2050 thermogravimetric instruments. TG/FTIR was used to detect the evolved gas. Acetic acid and trans-1-R-4-R'-cyclohexane were the main products evolved from EVA in the first and second stage, respectively. The apparent activation energies were determined for both stages by differential methods.
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  • 19
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    Journal of thermal analysis and calorimetry 55 (1999), S. 57-65 
    ISSN: 1572-8943
    Keywords: artificial ageing ; DSC ; dynamic crystallization ; isoconversional method
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    Topics: Chemistry and Pharmacology
    Notes: Abstract A crystallization kinetics analysis of several polypropylene-polyethylene (PP-PE), PP-rich copolymers was made by means of differential scanning calorimetry. The crystallization was studied via calorimetric measurements at different cooling rates. Several additives were added to the base material. Some test samples were subjected to artificial ageing processes. A modified isoconversional method was used to describe the crystallization process under non-isothermal conditions. The value of the Avrami parameter was determined for primary and secondary crystallization.
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  • 20
    ISSN: 1572-8943
    Keywords: dioximine complexes of Co ; DSC ; kinetic compensation effect ; kinetic parameters of thermal decomposition
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    Topics: Chemistry and Pharmacology
    Notes: Abstract 14 mixed Co(III) dioximine chelates of the types [Co(Diox·H)2(amine)2]X (X = Br, I, NO3, ClO4) and H[Co(Diox·H)2(N3)2], respectively (Diox·H2-1,2-cyclohexane dione dioxime (nyoxime), 1,2-cycloheptane dione dioxime (heptoxime) 1,2-cyclooctane dione dioxime (octoxime) were obtained and their thermal decompositions were studied in an argon atmosphere. After the dehydration of the crystallohydrates, both types of complexes exhibit 3 decomposition stages. For the [Co(Diox·H)2(amine)2]X type complexes (X = Br, I) the first endothermal stage is the substitution of an amine molecule for the external sphere anion and this process is followed by two exothermal decomposition stages. With H[Co(Diox·H)2(N3)2] type complexes the first and third processes are relatively slow, but the second process is very fast, corresponding to a vertical portion of the TG curves. From the TG curves kinetic parameters were derived for 11 processes and the validity of a non-linear compensation law was observed.
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  • 21
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    Journal of thermal analysis and calorimetry 56 (1999), S. 51-57 
    ISSN: 1572-8943
    Keywords: DSC ; enthalpies ; NaAlF4 ; Na5Al3F14
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    Topics: Chemistry and Pharmacology
    Notes: Abstract Beside the two well-known minerals cryolite, Na3AlF6, and chiolite, Na5Al3F14, the binary system NaF-AlF3 also contains a third compound, NaAlF4, sodium tetrafluoroaluminate. Solid NaAlF4 has been prepared from its vapour under controlled conditions. The stability of NaAlF4 has been investigated by differential scanning calorimetry. It is shown that the disproportionation of the compound: 5NaAlF4(s)=Na5Al3F14(s)+2AlF3(s) takes place at considerable rate between 700 and 900 K. The enthalpy of this reaction is calculated and found to be -66.9 kJ. Enthalpies of the two solid state transitions α-Na3AlF6 → β-Na3AlF6 and α-AlF3 → β-AlF3 have also been measured and new values are reported. The enthalpy of formation of chiolite, Na5Al3F14, at 900 K has been recalculated from enthalpy increment data obtained by drop calorimetry. A value of ΔH900 o = -7513.6±12.0 kJ mol-1 has been obtained. This value is in disagreement with the recommended value given in JANAF Thermochemical Tables given at 900 K ΔHf o = -7559.2 kJ mol-1.
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  • 22
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    Journal of thermal analysis and calorimetry 56 (1999), S. 925-929 
    ISSN: 1572-8943
    Keywords: DSC ; equilibrium ; Fe-Ni distribution ; monosulfide solid solution ; pentlandite
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    Topics: Chemistry and Pharmacology
    Notes: Abstract Two mixtures of pentlandite and the monosulfide solid solution (mss) have been synthesized. The bulk compositions of the samples are Fe6Ni3S8 and Fe3Ni6S8. Differential scanning calorimetry detected exothermic process in the samples under heating. The process takes place in temperature range between phase transition in the mss (near 400 K) and 690 K and is governed by diffusion. X-ray powder diffraction has showed that equilibrium Fe-Ni distribution between pentlandite and the mss is achieved after short-time heating up to 670 K.
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  • 23
    ISSN: 1572-8943
    Keywords: cure kinetics ; DSC ; epoxy resin ; SAN ; thermoplastic blends
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    Topics: Chemistry and Pharmacology
    Notes: Abstract Cure kinetics using a differential scanning calorimetry (DSC) technique were analyzed for a thermoplastic modified tetraglycidyl-4,4′-diaminodiphenylmethane (TGDDM) epoxy resin cured with diaminodiphenylsulphone (DDS), an aromatic diamine. The neat resin and its blends with the poly(styrene-co-acrylonitrile) (SAN) of various compositions were studied by applying a phenomenological model proposed by Kamal. Kinetic parameters were determined by fitting experimental data. This model gives a good description of cure kinetics up to the onset of vitrification. Diffusion control was incorporated to describe the cure in the latter stages of cure. The results showed that the addition of SAN did not alter the nature of the reaction, but the reaction rates and final conversions decreased when SAN contents increase, due to reduction of mobility of the reacting species.
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  • 24
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    Journal of thermal analysis and calorimetry 56 (1999), S. 1285-1304 
    ISSN: 1572-8943
    Keywords: amorphous state ; combined techniques ; drug design ; drug product development ; drug substance ; drug technology ; DSC ; excipients ; failure investigations ; hydrates ; MDSC ; microcalorimetry ; pharmaceuticals ; polymorphism ; polymers ; preformulation ; process optimization ; purity ; quality control ; solvates ; stability ; sub-ambient DSC ; TG ; temperature resolved X-ray diffraction ; water interactions ; thermal microscopy ; water sorption-desorption
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    Topics: Chemistry and Pharmacology
    Notes: Abstract Modern thermal analysis, microcalorimetry and new emerging combined techniques which deliver calorimetric, microscopic and spectroscopic data offer a powerful analytical battery for the study of pharmaceuticals. These techniques are very useful in all steps of development of new drug products as well as methods for quality control in production. The characterization of raw materials enables to understand the relationships between polymorphs, solvates and hydrates and to choose the proper development of new drug products with very small amount of material in a very short time. Information on stability, purity is valuable for new entities as well as for marketed drug substances from different suppliers. Excipients which vary from single organic or inorganic entity to complexes matrixes or polymers need to be characterized and properly controlled. The thermodynamic phase-diagrams are the basis of the studies of drug-excipients interactions. They are very useful for the development of new delivery systems. A great number of new formulations need proper knowledge of the behaviour of the glass transition temperature of the components. Semi-liquid systems, interactions in aqueous media are also successfully studied by these techniques.
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    Journal of thermal analysis and calorimetry 57 (1999), S. 61-73 
    ISSN: 1572-8943
    Keywords: amorphous ; combined techniques for polymorphism ; DSC ; MKS 492 ; polymorphism ; purine ; quantitative determination ofamorphous and polymorphs ; solvent mediated transitions ; temperature resolved X-ray diffraction ; TG ; thermodynamic relation between polymorphs ; xanthine
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    Topics: Chemistry and Pharmacology
    Notes: Abstract The polymorphic behaviour of the purine derivative MKS 492 was studied with investigations of suspensions of selected samples in different solvents and of samples obtained by crystallizations. The samples were analyzed by DSC, TG and X-ray diffraction. Six different crystalline modifications called A, B, B’, C, D and E and an amorphous form were identified. Four pure crystalline modifications, A, B, C and D have been manufactured and characterized by DSC, X-ray, IR, solubilities, densities, hygroscopicity and dissolution measurements. The four forms A, C, D and E are monotrop to the form B. The form B is enantiotrop to the form B’, which revealed the highest melting point of all known polymorphs. This form B’ is only stable at high temperature. Temperature resolved X-ray diffraction was very helpful for proper interpretation of the thermal events. The melting peaks of the forms A and C and the endothermic peak corresponding to the enantiotropic transition B into B’ occur in a narrow range of temperature. The form B which is the most stable one at room temperature has been chosen for further development. Quantitative methods to determine the content of the forms A, C and D in samples of form B or to determine the content of form A, B and D in form C have been developed by using X-ray diffraction. Limits of detection are 1 or 2%. For the quantitative determination of the amorphous fraction, X-ray diffraction and microcalorimetry are compared. For high amounts of the amorphous fraction, the X-ray diffraction method is preferred because it is faster. Microcalorimetry is very attractive for levels below 10% amorphous content. The lowest limit of detection is obtained by microcalorimetry, about 1%.
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  • 26
    ISSN: 1572-8943
    Keywords: crystal modifications ; DSC ; Gibbs free energy function ; molecular modelling ; solution calorimetry
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    Topics: Chemistry and Pharmacology
    Notes: Abstract The thermodynamic energy relationship between two crystal modifications of cimetidine was investigated and compared with differences in their processing properties with respect to transformation from one modification to the other. The crystal energies of the two modifications A and D were found to be almost identical and therefore the polymorphs are regarded as virtually isoenergetic crystals. This statement is based on DSC measurements of the melting points and of the enthalpies of fusion for the two crystal forms, which enable the calculation of the Gibbs free energy functions. Furthermore, the statement is supported by measurements of the enthalpies of solution in two different solvents. Both DSC and solution experiments reveal a slightly higher stability of the D modification with respect to the A form. In addition, tribomechanical treatment also indicates modification D to be the more stable one, as well as the higher density of the D form. No transformation during DSC at low heating rate was found which could be used in a stability consideration. As the explicit crystal structures of the two modifications are resolved, it was possible to calculate crystal energies theoretically as well. The theoretical results showed a remarkable difference in the crystal energies at zero degree Kelvin. Furthermore, they were just contradicting experimental findings by stating A being more stable than D. Possible reasons for this discrepancy and the feasibility of today's calculation methods with respect to prediction of stability properties are discussed.
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    Journal of thermal analysis and calorimetry 57 (1999), S. 631-642 
    ISSN: 1572-8943
    Keywords: DSC ; fluorocarbon chain ; polymerizability ; polymorphic behaviors ; X-ray diffraction
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    Topics: Chemistry and Pharmacology
    Notes: Abstract The molecular aggregation of acrylic and methacrylic acid esters containing long-fluorocarbon chains: 2-(perfluoroalkyl)ethyl acrylate (FFnEA) and 2-(perfluoroalkyl)ethyl methacrylate (FFnEMA) (F(CF2)nCH2CH2OCOC(X)=CH2, where X=H, CH3 and n=6, 8, 10) was investigated by differential scanning calorimetry (DSC) and temperature controlled X-ray powder diffraction measurement. These compounds exhibited some characteristic polymorphic behaviors depending on the length of fluorocarbon chain and the α-position methyl group. The solid-state polymerization by γ-ray irradiation was studied for these compounds in the various crystal forms. In the solid-state polymerization, highest polymerizability was observed in the crystal form that exists in the highest temperature region for each compound.
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    Journal of thermal analysis and calorimetry 58 (1999), S. 29-38 
    ISSN: 1572-8943
    Keywords: benzoicacid ; controlled release ; DSC ; ethyl cellulose ; FTIR
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    Topics: Chemistry and Pharmacology
    Notes: Abstract The physical state of benzoic acid (BA) and its interaction with ethyl cellulose (EC) were examined in ethyl cellulose—benzoic acid matrices by Differential Scanning Calorimetry (DSC). The glass transition temperature (Tg) of EC of various matrices having BA in solid solution form (upto 27.7%) was reduced. The BA in matrices containing more than 38.9% drug exhibited distinct melting endotherms due to crystalline form. The peak temperatures of these endotherms were lowered and they broadened as the concentration was lowered. The solubility of BA increased at its melting point as compared to ambient temperature. The melting enthalpy of BA, when plotted as a function of its concentration yielded a straight line with intercept of 330 mg g−1 of matrix. This is the solubility of BA in EC at its melting temperature. Fourier Transform Infra Red Spectroscopy (FTIR) investigations confirmed that hydrogen bonding occurred between EC and BA through hydroxyl groups.
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  • 29
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    Journal of thermal analysis and calorimetry 58 (1999), S. 363-368 
    ISSN: 1572-8943
    Keywords: DSC ; lipid ; phase behaviour ; synchrotron radiation ; X-ray diffraction
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    Topics: Chemistry and Pharmacology
    Notes: Abstract The phase behaviour and phase stability of lipids are of importance in an understanding of the biological functions of cell membranes. Among a variety of physical techniques employed to study the phase behaviour and structural properties of polar lipids, differential scanning calorimetry and X-ray diffraction have proved to be successful and are the most frequently used methods. Applications involving a combination of the two techniques, particularly when synchrotron radiation is used as the light source of X-ray diffraction, are reviewed in this article.
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    Journal of thermal analysis and calorimetry 58 (1999), S. 653-662 
    ISSN: 1572-8943
    Keywords: dehydration ; DSC ; TG ; water ; zeolites
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    Topics: Chemistry and Pharmacology
    Notes: Abstract A procedure for measurement of the heat of zeolite dehydration by scanning heating has been designed. Simultaneous data on heat flow (DSC) and mass loss (TG) are required for evaluation. The heating rate depends on the experimental conditions (point-spread function, sample mass, crucible design, and calorimetric reproducibility). Dehydration measurements have three advantages as compared with the sorption procedure: i) one can investigate samples with irreversible dehydration; ii) no approximation model is needed for calculation of the partial molar heat of dehydration; and iii) the procedure is not labor-consuming. The procedure was tested on the natural zeolites heulandite, chabazite and mordenite. The results are close to those measured by the sorption procedure. The partial molar heat of dehydration was found to depend on the water content. It increases from 50 to 87 J mol−1 K−1 for heulandite, from 53 to 81 J mol−1 K−1 for chabazite, and from 51 to 71 J mol−1 K−1 for mordenite. The approximation of the heat of sorption by linear regression was found to be wrong. Detection of a ‘phase transitioN’ after this approximation has no meaning.
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    Journal of thermal analysis and calorimetry 58 (1999), S. 725-739 
    ISSN: 1572-8943
    Keywords: DDC ; DSC ; DTA ; transformation-governed TA
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    Topics: Chemistry and Pharmacology
    Notes: Abstract The described instrumental method makes it possible that the quasi-static heating technique, well applicable to thermogravimetric measurements, (see Part I of this paper) can be used in the case of DTA and DSC examinations, too. Based on the new type of curves the characteristic transformation temperatures, the whole course of the transformation in dependence of sample temperature, the extent of the enthalpy change caused by the transformation or by its partial processes can accurately be determined. The essentially greater accuracy of the measurements — in comparison to the conventional ones — is due to the quasi-static heating technique which ensures that the transformations should take place under quasi-equilibrium conditions.
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  • 32
    ISSN: 1572-8943
    Keywords: alkylureas ; DOAB vesicles ; DSC ; gel-liquid transitions ; urea
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    Topics: Chemistry and Pharmacology
    Notes: Abstract The gel to liquid-crystal transition for vesicles in aqueous solution formed by dimethyldi-n-octadecylammonium bromide (DOAB) occurs at 44.7°C. Moreover, the shapes of the scans recorded by a sensitive DSC microcalorimeter are very similar when the vesicular solutions are prepared starting with solid DOAB and comparable amounts of either solid urea or solid alkylureas. Therefore, the DOAB vesicles in aqueous solution accommodate this class of solutes without marked changes in the melting temperature and the enthalpy of the transition. The contrast with effects of added surfactants and simple organic solutes such as THF and ethanol is particularly significant.
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    Journal of thermal analysis and calorimetry 55 (1999), S. 807-816 
    ISSN: 1572-8943
    Keywords: DSC ; hydrogen-bond ; IR ; lithium formate monohydrate ; Raman spectroscopy
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    Topics: Chemistry and Pharmacology
    Notes: Abstract Differential scanning calorimetry (DSC) and thermogravimetric analysis (TG) of lithium formate monohydrate (LiHCOO·H2O) were performed in the temperature range 300–700 K. The DSC/TG measurements show that the dehydration process to anhydrous lithium formate (LiHCOO) is complex and occurs in two stages. The data are correlated to the structure and to the arrangement of the molecules in the crystal, including the hydrogen-bonding. Infrared transmittance and Raman spectra of this crystal are reported and commented on.
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  • 34
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    Journal of thermal analysis and calorimetry 55 (1999), S. 789-796 
    ISSN: 1572-8943
    Keywords: alkaline earth malonates ; DSC ; DTA ; kinetic parameters ; TG ; thermal decomposition
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    Topics: Chemistry and Pharmacology
    Notes: Abstract The thermal decomposition of strontium and barium malonates has been studied isothermally and non-isothermally employing simultaneous TG-DTG-DTA, DSC, XRD and IR spectroscopic techniques. DSC of these malonates has been recorded both in oxygen and nitrogen atmospheres. The decomposition is a single step process and the end product formed is carbonate. The energy of activation and frequency factor values for the decomposition of strontium malonate are 547 kJ mol−1 and 1041 s−1 respectively. The activation energy and frequency factor values for isothermal dehydration of barium malonate sester-hydrate are 57–111 kJ mol−1 and 107–1012 s−1 respectively and the corresponding values for decomposition from DSC are 499.5 kJ mol−1 and 1044 s−1 respectively. The higher thermal stability of strontium malonate as compared to that of barium salt is ascribed to its being anhydrous so that decomposition proceeds without restructuring. Their thermal stabilities have also been compared with that of respective oxalate salts.
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    Journal of thermal analysis and calorimetry 56 (1999), S. 7-15 
    ISSN: 1572-8943
    Keywords: ALE ; CVD ; DSC ; DTA ; EGA ; EL display ; solar cell ; sol-gel ; spray pyrolysis ; super-conductor ; TG ; thin films
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    Topics: Chemistry and Pharmacology
    Notes: Abstract Processing thin films for advanced applications, for instance in electronics and optoelectronics, involves several steps starting from precursor synthesis and ending up with the devices. Especially when optimizing the first steps of this chain of processes, thermoanalytical techniques play an important role. The review will focus on the main chemical deposition methods (CVD, ALE, spray pyrolysis, sol-gel) giving selected examples of problem-solving by thermal analysis. The techniques discussed are TG, DTA/DSC, EGA and their combinations. High-temperature X-ray diffraction (HTXRD) is also a powerful tool for in situ studies of thin films. The examples are taken from solar cell, superconductor and flat panel electroluminescent display technologies.
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    Journal of thermal analysis and calorimetry 56 (1999), S. 429-435 
    ISSN: 1572-8943
    Keywords: DSC ; nickel sulphide ; TG ; toughened glass ; X-ray diffraction
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    Topics: Chemistry and Pharmacology
    Notes: Abstract Nickel sulphide (NiS) was characterised using X-ray diffraction, thermal gravimetric analysis (TG) and differential scanning calorimetry (DSC). The 'as received' Millerite, stoichiometric NiS, observed to be slightly nickel deficient, was found to readily decompose in a nitrogen atmosphere at elevated temperatures (450°C max.) to the sulphur deficient Godlevskite, Ni7S6. DSC and X-ray measurements demonstrated that the high temperature form of the Godlevskite was readily stabilised at room temperature. The kinetics of the α-β re-transformation in Godlevskite were then investigated using DSC and were observed to be first order.
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    Journal of thermal analysis and calorimetry 56 (1999), S. 547-552 
    ISSN: 1572-8943
    Keywords: cobalt oxysalts ; DSC ; enthalpy of decomposition ; enthalpy of dehydration ; thermal decomposition
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    Topics: Chemistry and Pharmacology
    Notes: Abstract Differential scanning calorimetry (DSC) was used to determine the molar enthalpies of dehydration and decomposition of CoC2O4·2H2O, Co(HCOO)2·2H2O and [Co(NH3)6]2(C2O4)3·4H2O. The first stage of dissociation of each compound is a single-step dehydration both in air and argon atmospheres. The next stages are decomposition processes influenced by experimental parameters. The enthalpies of dehydration and decomposition vary from compound to compound in each atmosphere. The obtained data have been related to the macromechanisms proposed for the thermal decomposition and the parallel-consecutive decomposition-oxidation processes.
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    Journal of thermal analysis and calorimetry 56 (1999), S. 783-792 
    ISSN: 1572-8943
    Keywords: complex process ; DSC ; isoconversional methods ; kinetics ; model-free kinetics ; peak maximum evolution methods ; simulations
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    Topics: Chemistry and Pharmacology
    Notes: Abstract In the case of a complex mechanism of two parallel independent reactions, peak maximum evolution methods and model-fitting methods give only a mean value of the kinetic parameters, while isoconversional methods are useful to describe the complexity of the mechanism. Isothermal and non-isothermal isoconversional methods can be used to elucidate the kinetics of the process. Nevertheless, isothermal isoconversional methods can be limited by restrictions on the temperature regions experimentally available because of duration times or detection limits.
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    Journal of thermal analysis and calorimetry 56 (1999), S. 947-951 
    ISSN: 1572-8943
    Keywords: combustion ; crude oil ; DSC ; TG/DTG
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    Topics: Chemistry and Pharmacology
    Notes: Abstract This paper investigates the minimum oil content necessary for self-sustained combustion, which is introduced as a criterion for the selection of suitable reservoirs for in-situ combustion processes. Differential scanning calorimetry was used to determine the heat values of oil-limestone mixtures. The minimum temperature required for the total consumption of the fuel was obtained by thermogravimetry (TG/DTG). The minimum amount of oil necessary to sustain combustion was calculated from these two parameters and compared with the oil content of the reservoir. Reservoirs with an oil content greater than or equal to this minimum value were considered feasible. It was seen that the fields examined are generally not suitable for in-situ combustion processes.
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    Journal of thermal analysis and calorimetry 56 (1999), S. 1155-1161 
    ISSN: 1572-8943
    Keywords: crystallisation ; DMA ; DSC ; PCL ; polymer ; temperature modulation
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    Topics: Chemistry and Pharmacology
    Notes: Abstract Temperature modulated dynamic mechanical analysis (TMDMA) was performed in the same way as temperature modulated DSC (TMDSC) measurements. As in TMDSC TMDMA allows the investigation of reversible and non-reversible phenomena during crystallisation of polymers. The advantage of TMDMA compared to TMDSC is the high sensitivity for small and slow changes in crystallinity, e.g. during re-crystallisation. The combination of TMDMA and TMDSC yields new information about local processes at the surface of polymer crystallites. It is shown that during and after isothermal crystallisation the surface of the individual crystallites is in equilibrium with the surrounding melt.
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    Journal of thermal analysis and calorimetry 56 (1999), S. 1141-1146 
    ISSN: 1572-8943
    Keywords: crystallization ; DSC ; heavy ion irradiation ; melting ; PBT films ; poly(butyleneterephthalate) films
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    Topics: Chemistry and Pharmacology
    Notes: Abstract The influence of heavy ion-irradiation (Ar 5.5 MeV amu-1, 5·1011 ion cm-2) on the melting and crystallization of two PBT films subjected to different modes of thermal treatment was investigated. Differences were observed between the processes occurring in both initial films, due to differences in crystalline phase content. The course of melting and crystallization in heavy ion-irradiated films during first heating, cooling and second heating differs from that in the initial films. The density data and DSC results indicate a decreased crystalline phase content in the PBT films after irradiation.
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    Journal of thermal analysis and calorimetry 56 (1999), S. 1353-1357 
    ISSN: 1572-8943
    Keywords: DSC ; terpenoids ; TG ; thermal behaviour
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    Topics: Chemistry and Pharmacology
    Notes: Abstract The terpenoids acetyl sitosterol, lupeol, acetyl diosgenin and stigmasterol were studied. Comparison of the thermogravimetric curves and the activation energies of the terpenoids suggested the following sequence of thermal stability: acetyl sitosterol 〈 acetyl diosgenin 〈 lupeol 〈 stigmasterol. The DSC curves allowed determination of the melting points and the degrees of purity. Comparison of the TG and DSC curves revealed the presence of phase transitions without mass loss that were attributed to rearrangements in the terpenoid molecules.
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    Journal of thermal analysis and calorimetry 57 (1999), S. 371-375 
    ISSN: 1572-8943
    Keywords: C14E8 ; detergent ; DSC ; polyethylene glycol tetradecyl ether ; thermal transition
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    Topics: Chemistry and Pharmacology
    Notes: Abstract A narrow, reversible endothermic main transition is found in the aqueous micellar phase of octaethylene glycol tetradecyl ether (C14E8) by DSC, characterized by a transition temperature of 41°C and a ΔH value of 0.5 kcal mol−1, which is not observed by light scattering. This transition is assigned to a cooperative conformational rearrangement of the assembled amphiphilic detergent molecules and not to a micelle aggregation process. It is suggested that the detergent’s polar head group is primarily involved in this rearrangement.
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  • 44
    ISSN: 1572-8943
    Keywords: DSC ; iron(II)-oxime complexes ; kinetic parameters ; Mössbauer spectroscopy
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    Topics: Chemistry and Pharmacology
    Notes: Abstract A number of 15 [Fe(Diox#x00B7;H)2L2] type chelates and [Fe(Diox)3(BOR)2] clathrochelates (Diox#x00B7;H2 — dimethylglyoxime, glyoxime, propoxime, nyoxime, furyl-dioxime; L-pyridine, alkyl-pyridine derivatives, diethyl-phenyl-phosphine, diethyl-p-tolyl-phosphine) were obtained and characterized by means of far and middle FTIR and Mössbauer spectroscopic methods. Some structural problems were discussed on the basis of the optical data. The DSC measurements show the higher thermal stability of the clathrochelates without O—H⋯O intramolecular hydrogen bonds (with asymmetric octahedral structure), as compared to the [Fe(Diox#x00B7;H)2L2] trans, symmetric chelates containing O—H⋯O bonds. The kinetic parameters of the thermal decomposition of the complexes have been derived using the nomogram method.
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  • 45
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    Journal of thermal analysis and calorimetry 57 (1999), S. 745-752 
    ISSN: 1572-8943
    Keywords: confinement effects ; DSC ; dynamic light scattering ; finite-size effects ; glass transition ; o-terphenyl
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    Topics: Chemistry and Pharmacology
    Notes: Abstract Calorimetry is the method first used by Jackson and McKenna to study the effect of finite-size on the molecular dynamics of glass-formers confined in nano-meter scale pores. It was found that the glass transition is shifted to lower temperature as pore size decreases. Since then, other spectroscopic techniques have corroborated this finding and given more information on the molecular dynamics. These results are used to compare with the predictions of several theories of glass transition, and in particular the coupling model of the author.
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  • 46
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    Journal of thermal analysis and calorimetry 57 (1999), S. 847-851 
    ISSN: 1572-8943
    Keywords: DSC ; linear low-density polyethylene(LLDPE) ; low density polyethylene (LDPE) ; polymer blend ; thermal properties
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    Topics: Chemistry and Pharmacology
    Notes: Abstract A forensic sample consisting of melt-recrystallized polymers that was recovered from the scene of a fire in a factory was identified by differential scanning calorimetry. The factory commonly used two kinds of film sheets, A and B, made by different manufacturers. It was necessary to decide whether the forensic sample related to material A or B. The forensic sample and reference samples of materials A and B were subjected to infrared spectroscopy and pyrolysis gas chromatograph mass spectrometry measurements, which revealed their polyethylene nature. The thermal behaviour of the samples was examined by differential scanning calorimetry (DSC) and they were found to be blends of two kinds of polyethylenes, low-density polyethylene and linear low-density polyethylene. The samples could be identified and distinguished from each other via the DSC measurements.
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  • 47
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    Journal of thermal analysis and calorimetry 58 (1999), S. 369-373 
    ISSN: 1572-8943
    Keywords: critical temperature ; DSC ; HNNC ; non-isothermal
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    Topics: Chemistry and Pharmacology
    Notes: Abstract Two methods for estimating the critical temperature (Tb) of thermal explosion for the highly nitrated nitrocellulose (HNNC) are derived from the Semenov's thermal explosion theory and two non-isothermal kinetic equations, dα/dt=Af(α)e−E/RT and dα/dt=Af(α)[1+E/(RT)(1–To/T)]e−E/RT, using reasonable hypotheses. We can easily obtain the values of the thermal decomposition activation energy (E), the onset temperature (Te) and the initial temperature (To) at which DSC curve deviates from the baseline of the non-isothermal DSC curve of HNNC, and then calculate the critical temperature (Tb) of thermal explosion by the two derived formulae. The results obtained with the two methods for HNNC are in agreement to each other.
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  • 48
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    Journal of thermal analysis and calorimetry 39 (1993), S. 217-220 
    ISSN: 1572-8943
    Keywords: DSC ; edible oils ; isothermal method ; kinetics
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    Topics: Chemistry and Pharmacology
    Description / Table of Contents: Zusammenfassung Unter Einsatz der isothermen Methode wurden kinetische Untersuchungen der thermooxidativen Zersetzung einiger Speiseöle durchgeführt. Zur Bestimmung des Umwandlungsgrades wurde ein DS-Kalorimeter von DuPont eingesetzt. Grundlage der Untersuchung bildeten Leinöl, Rizinusöl und Olivenöl.
    Notes: Abstract The thermooxidative decompositions of some edible oils were investigated. Isothermal measurements of convention were made with a Du Pont differential scanning calorimeter. Linseed oil, castor oil, olive oil and cod-liver oil were investigated.
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  • 49
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    Journal of thermal analysis and calorimetry 55 (1999), S. 155-164 
    ISSN: 1572-8943
    Keywords: DSC ; glass ; relaxation ; structure
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    Topics: Chemistry and Pharmacology
    Notes: Abstract The enthalpic relaxation of the title glasses, studied by differential scanning calorimetry, is well described by a mathematical model based on the stretched exponential relaxation function with the relaxation time proportional to the actual viscosity. The dependence of viscosity on temperature and the fictive temperature was expressed by Mazurin's approximation. The relaxation parameters obtained correlated significantly with the glass composition, indicating the changes in the structural of the TiO2 role near a TiO2 content of 3–4 mol%.
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  • 50
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    Journal of thermal analysis and calorimetry 55 (1999), S. 165-172 
    ISSN: 1572-8943
    Keywords: DSC ; nickel(II) squarate ; phase transition ; TG-DTA ; triamine
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    Topics: Chemistry and Pharmacology
    Notes: Abstract [NiL2]C4O4·nH2O [where n=2 when L=diethylenetriamine(dien) and N-(3-aminopropyl)-1,3-propanediamine (dpt); n=3 when L=N-(2-aminoethyl)-1,3-propanediamine (aepn); n=0 when L=N2-methyldiethylenetriamine (medien)] and Ni(tmdien)C4O4·2H2O (where tmdien=1,4,7 trimethyl-diethylenetriamine) have been synthesised and investigated thermally in the solid state. Ni(dpt)C4O4·H2O has also been synthesised pyrolytically in the solid state from the corresponding bis complex. All the complexes possess octahedral geometry. The squarate anion takes part in coordination only in monotriamine species. [Ni(medien)2]C4O4 upon heating undergoes phase transition (270–285°C; ΔH=4.9 kJ mol−1) accompanied by colour change pink to grey. Thermal stability decreases with increase in chain length of the triamines.
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  • 51
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    Journal of thermal analysis and calorimetry 56 (1999), S. 305-310 
    ISSN: 1572-8943
    Keywords: amorphous palladium alloys ; DSC ; hydrogenation ; mechanical alloying ; phenylacetylene ; structural characterization ; X-ray diffractometry ; X-ray photoelectron spectroscopy
    Source: Springer Online Journal Archives 1860-2000
    Topics: Chemistry and Pharmacology
    Notes: Abstract Amorphous PdZr, PdCuZr and PdCuSi alloy ribbons and powders are characterized by DSC, XRD and XPS in the as-received state and after treatments with oxygen, hydrogen or dilute hydrogen fluoride solution. Zr-containing alloys are shown to undergo substantial structural changes resulting in palladium enrichment on their surface, whereas no apparent changes in the bulk structure are found for PdCuSi. Catalytic activity and selectivity of the pretreated samples were tested in the hydrogenation of phenylacetylene.
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  • 52
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    Journal of thermal analysis and calorimetry 56 (1999), S. 1203-1209 
    ISSN: 1572-8943
    Keywords: conformation of myosin ; DSC ; EPR ; spin labelling
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    Topics: Chemistry and Pharmacology
    Notes: Abstract The internal dynamics and the thermal stability of myosin in rabbit psoas muscle fibres in different intermediate states of the ATP hydrolysis cycle were studied by differential scanning calorimetry (DSC) and electron paramagnetic resonance (EPR) spectroscopy. Three overlapping endotherms were detected in rigor, in strongly binding and weakly binding state of myosin to actin. The transition at 58.4°C can be assigned to the nucleotide-binding domain. The transition at highest temperature represents the unfolding of the actin and the contributions arising from the actin-myosin interaction. The transition of 54°C reflects the interaction between the subunits of myosin. Nucleotide binding induced shifts of the melting temperatures and produced variations in the calorimetric enthalpy changes. The changes of the EPR parameters indicated local rearrangements of the internal structure in myosin heads.
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  • 53
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    Journal of thermal analysis and calorimetry 56 (1999), S. 1323-1327 
    ISSN: 1572-8943
    Keywords: chloramphenicol ; DSC ; quality control ; TG
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    Topics: Chemistry and Pharmacology
    Notes: Abstract The stability and thermal behaviour of chloramphenicol and various of its mixtures were investigated. The thermogravimetric and stability constant results showed that the chloramphenicol base is thermally more stable than the tablet in the studied formulation. The reduction in stability was attributed to the presence of starch in the formulation. The thermal decompositions of the chloramphenicol base and the tablet obey first-order kinetics.
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  • 54
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    Journal of thermal analysis and calorimetry 56 (1999), S. 1311-1316 
    ISSN: 1572-8943
    Keywords: alumina ; aluminum oxide ; compact ; DSC ; particles ; pentaerythritol tetraacetate ; pharmaceuticals ; powder ; thermal resistance ; transient state
    Source: Springer Online Journal Archives 1860-2000
    Topics: Chemistry and Pharmacology
    Notes: Abstract The previously described method involving the use of transient DSC was applied to pharmaceutical powder compacts and to ceramic powder compacts. The samples were prepared by compressing powders of pentaerythritol tetraacetate and two kinds of alumina powder (differing in particle size distribution) up to a pressure of 20 MPa by using a jig. For pentaerythritol tetraacetate, a linear relationship was obtained between the parameter obtained by DSC and the compaction pressure.
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  • 55
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    Journal of thermal analysis and calorimetry 56 (1999), S. 1005-1010 
    ISSN: 1572-8943
    Keywords: DSC ; enthalpic relaxation ; glass transition ; physical ageing
    Source: Springer Online Journal Archives 1860-2000
    Topics: Chemistry and Pharmacology
    Notes: Abstract Enthalpic relaxation has been used to model the development of the glass transition in polymers, using kinetic parameters determined separately. For this purpose the Kohlrausch-Williams-Watt stretched exponential function, relating the extent of relaxation, Φ(t), to time t and an average relaxation time, τa, i.e. $$1 - \Phi \left( t \right) = \exp \left( { - t/ta} \right)^{\beta }$$ where β is inversely related to the breadth of the relaxation spectrum, has been adopted. The relaxation time dependence on temperature was taken to follow the modified Arrhenius relationship, $$\tau _a = A\exp \left[ {\frac{{X\Delta H}}{{RT}} + \frac{{\left( {1 - X} \right)\Delta H}}{{RT'}}} \right]$$ where T is the storage and T′ the fictive temperature, X is the structure factor and ΔH the activation enthalpy. Both have been found to describe the process of enthalpic relaxation in polymer glasses and a direct comparison has been made with the change in specific heat observed with different cooling rates in DSC experiments. The effect of variables, such as activation enthalpies, pre-exponential factors, and the non-linear factors such as X and β on the observed Tgs and the temperature range over which the transition occurred have been determined.
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  • 56
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    Journal of thermal analysis and calorimetry 57 (1999), S. 283-291 
    ISSN: 1572-8943
    Keywords: DSC ; fish ; general proteolytic activity ; pyloric caeca ; ripening ; salted herring product
    Source: Springer Online Journal Archives 1860-2000
    Topics: Chemistry and Pharmacology
    Notes: Abstract The thermoanalytical behaviour of pyloric caeca during salting and ripening was investigated using a Perkin Elmer DSC 7. Not only the thermal stability of the muscle proteins was influenced by salting but also that of pyloric caeca. It was recognised that the salting itself leads to a remarkable increase of the transition temperature compared with raw herring. An influence of the salt:fish ratio could be observed. The higher the salt content the higher the increase of the denaturation temperature. During ripening the transition temperature remained on a high level or showed only a slight decrease during the investigation period. The dependency from the salt content remained evident. The increase of the transition temperature was accompanied by a decrease of the transition enthalpy. The increase of thermal stability is connected with a decrease of the general proteolytic activity in pyloric caeca. Possibly, the enzymes are diffusing from the pyloric caeca into the muscle and cause there an increase of enzymatic activity observable in North Sea herring accompanied by a decrease of activity in pyloric caeca itself. Simultaneous the thermal stability of pyloric caeca is lowered. The reason for the differences in ripening could be seen in some enzyme-inhibiting factors unknown until now.
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  • 57
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    Journal of thermal analysis and calorimetry 57 (1999), S. 409-414 
    ISSN: 1572-8943
    Keywords: DSC ; thermal denaturation ; vegetative bacteria
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    Topics: Chemistry and Pharmacology
    Notes: Abstract Thermal stability of vegetative cells of Listeria monocytogenes, Escherichia coli and Lactobacillus plantarum was studied by counting viable fractions and determining DSC curves of their suspensions. DSC curves in the 5–99°C range showed a series of endothermic transitions between 50 and 60°C, where the heat destruction of cells occurred. Heat denaturation of DNA required a higher temperature than cell killing. Thermal death was strongly influenced by the pH, composition and NaCl content of the suspending buffer. A mathematical model developed by us enabled comparison of DSC peak temperatures and temperatures required for loss of viability.
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  • 58
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    Journal of thermal analysis and calorimetry 57 (1999), S. 517-526 
    ISSN: 1572-8943
    Keywords: DSC ; humic substances ; thermal properties
    Source: Springer Online Journal Archives 1860-2000
    Topics: Chemistry and Pharmacology
    Notes: Abstract Differential Scanning Calorimetry combined with Fourier transform infrared spectroscopy, was applied to the study of a number of fulvic and humic acids extracted from soils, peat, river and seawater. The thermal patterns obtained were related to the nature and origin of samples. The low-temperature endotherms were attributed to dehydration and loss of peripheral polysaccharide chains. The endotherm at 250°C observed for soil FA was ascribed to partial decarboxylation of more labile surface COOH groups, whereas the high-temperature exotherms at about 500°C were related to the degree of polycondensation of the aromatic network of the humic molecules.
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  • 59
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    Journal of thermal analysis and calorimetry 58 (1999), S. 13-18 
    ISSN: 1572-8943
    Keywords: DSC ; enthalpic relaxation ; polyurethane ; TSDC
    Source: Springer Online Journal Archives 1860-2000
    Topics: Chemistry and Pharmacology
    Notes: Abstract Polyurethane acrylate resins cured by two different ways, a thermal way and a photochemical way, are investigated by means of differential scanning calorimetry (DSC) and thermally stimulated depolarization currents (TSDC). Even if both curing methods lead to the same material from a chemical point of view, we show that important differences exist between the thermocured resin and the photocured resin in terms of molecular relaxation behaviour.
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  • 60
    ISSN: 1572-8943
    Keywords: DMTA ; DSC ; mechanical properties ; metallocene catalysts ; polyethylene
    Source: Springer Online Journal Archives 1860-2000
    Topics: Chemistry and Pharmacology
    Notes: Abstract A series of high density polyethylenes (HDPE) were synthesized via homogeneous polymerization with metallocene catalyst in two different reactors (glass and stainless steel). The thermal and mechanical properties of the polyethylenes, synthesized with two types of reactor and different reaction parameters, are discussed.
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  • 61
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    Journal of applied phycology 11 (1999), S. 69-78 
    ISSN: 1573-5176
    Keywords: seaweed ; algal blooms ; eutrophication ; general mechanisms ; management
    Source: Springer Online Journal Archives 1860-2000
    Topics: Biology
    Notes: Abstract Seaweed responses to eutrophication and their role in coastal eutrophication processes were compared at 8 different sites along the European coasts from the Baltic to the Mediterranean as part of the EU-ENVIRONMENT Project Marine Eutrophication and benthic Macrophytes (EUMAC). Structural and functional changes of marine benthic vegetation typical of eutrophic waters, in particular mass development (blooms) of certain seaweeds, are not merely the result of increased nutrient loading, but must be attributed to complex interactions of primary and secondary effects during the eutrophication process. Due to species-specific physiological properties of the algae (nutrient kinetics, growth potential, light, temperature requirements), the combined effects of abiotic and biotic factors on juvenile or adult developmental stages control the development of algal blooms in different ways. In particular the role of light, temperature, water motion and oxygen depletion, as well as of grazers, on early and adult developmental stages of the algae are considered. The result are discussed in the context of coastal eutrophication control and management.
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  • 62
    ISSN: 1573-5125
    Keywords: denitrification ; eutrophication ; estuary ; nitrogen ; sediment-water exchange
    Source: Springer Online Journal Archives 1860-2000
    Topics: Biology
    Notes: Abstract In this review of sediment denitrification in estuaries and coastal ecosystems, we examine current denitrification measurement methodologies and the dominant biogeochemical controls on denitrification rates in coastal sediments. Integrated estimates of denitrification in coastal ecosystems are confounded by methodological difficulties, a lack of systematic understanding of the effects of changing environmental conditions, and inadequate attention to spatial and temporal variability to provide both seasonal and annual rates. Recent improvements in measurement techniques involving 15 N techniques and direct N2 concentration changes appear to provide realistic rates of sediment denitrification. Controlling factors in coastal systems include concentrations of water column NO 3 − , overall rates of sediment carbon metabolism, overlying water oxygen concentrations, the depth of oxygen penetration, and the presence/absence of aquatic vegetation and macrofauna. In systems experiencing environmental change, either degradation or improvement, the importance of denitrification can change. With the eutrophication of the Chesapeake Bay, the overall rates of denitrification relative to N loading terms have decreased, with factors such as loss of benthic habitat via anoxia and loss of submerged aquatic vegetation driving such effects.
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  • 63
    ISSN: 1573-5125
    Keywords: eutrophication ; feeding ; growth ; Mytilus edulis ; validation
    Source: Springer Online Journal Archives 1860-2000
    Topics: Biology
    Notes: Abstract EMMY is an ecophysiological model of the growth and reproduction of a single mussel (Mytilus edulis L.). It contains feedback loops in the uptake and metabolism of food and in the partitioning of carbon and nitrogen to the internal state variables somatic tissue, storage, organic shell matrix and gametes. In this paper EMMY is used to simulate individual mussel growth in a series of mesocosm experiments with different inorganic nutrient loads (N and P). The experiments explore the impact of eutrophication reduction scenarios on mussel growth under defined and controlled conditions. In earlier studies EMMY was calibrated using expert knowledge on growth and reproduction during a period of 5 years. The resulting calibrated model was validated for system inputs and observations of three ecosystems with significantly different food and silt concentrations. EMMY reproduced the mussel growth sufficiently accurate in ecosystems with moderate or high food concentrations. In this study EMMY was adapted in order to cope with low food concentrations, then recalibrated (using the original calibration data and procedure) and applied without further calibration to 3 replicated mesocosm experiments. The EMMY simulations in this study show the ecophysiological response of mussels to different food (phytoplankton and detritus) concentrations. It is concluded that the mussels can adapt to significantly reduced food concentrations, due to inorganic nutrient load reduction, and still maintain growth.
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  • 64
    ISSN: 1573-5176
    Keywords: ecological engineering ; biofilter ; aquaculture ; seaweeds ; mariculture ; eutrophication ; Gracilaria ; shrimp farming ; mangroves ; ecological footprint
    Source: Springer Online Journal Archives 1860-2000
    Topics: Biology
    Notes: Abstract Rapid scale growth of intensive mariculture systems can often lead to adverse impacts on the environment. Intensive fish and shrimp farming, being defined as throughput-based systems, have a continuous or pulse release of nutrients that adds to coastal eutrophication. As an alternative treatment solution, seaweeds can be used to clean the dissolved part of this effluent. Two examples of successfully using seaweeds as biofilters in intensive mariculture systems are discussed in this paper. The first example shows that Gracilaria co-cultivated with salmon in a tank system reached production rates as high as 48.9 kg m−2 a−1, and could remove 50% of the dissolved ammonium released by the fish in winter, increasing to 90–95% in spring. In the second example, Gracilaria cultivated on ropes near a 22-t fish cage farm, had up to 40% higher growth rate (specific growth rate of 7% d−1) compared to controls. Extrapolation of the results showed that a 1 ha Gracilaria culture gave an annual harvest of 34 t (d. wt), and assimilated 6.5% of the released dissolved nitrogen. This production and assimilation was more than twice that of a Gracilaria monoculture. By integrating seaweeds with fish farming the nutrient assimilating capacity of an area increases. With increased carrying capacity it will be possible to increase salmon cage densities before risking negative environmental effects like eutrophication and toxic algal blooms sometimes associated with the release of dissolved nutrients. The potential for using mangroves and/or seaweeds as filters for wastes from intensive shrimp pond farming is also discussed. It is concluded that such techniques, based on ecological engineering, seems promising for mitigating environmental impacts from intensive mariculture; however, continued research on this type of solution is required.
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  • 65
    ISSN: 1573-5125
    Keywords: eutrophication ; mesocosm ; phytoplankton ; zooplankton ; macrobenthos
    Source: Springer Online Journal Archives 1860-2000
    Topics: Biology
    Notes: Abstract The effects of nutrient loading on phytoplankton, zooplankton and macrozoobenthos in experimental ecosystems was studied in a 7-month experiment. The mesocosms were designed to mimic the major physical characteristics (irradiance, temperature, mixing) of the Dutch coastal zone in the river Rhine plume. Three different nutrient loading scenarios were used, representing present and future conditions. The level of the spring phytoplankton bloom was determined by phosphorus loading, whereas during summer the nitrogen loading determined phytoplankton biomass. The differences in nutrient loading did not result in shifts in phytoplankton species composition. With exception of the early phase of the spring bloom, diatoms dominated phytoplankton biomass in all nutrient treatments. This was ascribed to microzooplankton grazing on smaller algal species. Microzooplankton biomass showed a positive correlation with primary production, and also significant differences between nutrient treatments. Copepod development was limited, probably due to competition with microzooplankton and predation by benthic fauna. Macrobenthos biomass correlated with primary production, and was lower in the lowest nutrient treatment.
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  • 66
    ISSN: 1573-5125
    Keywords: estuaries ; eutrophication ; resource management
    Source: Springer Online Journal Archives 1860-2000
    Topics: Biology
    Notes: Abstract Anthropogenic nutrient enrichment of the coastal zone is now a well-established fact. However, there is still uncertainty about the mechanisms through which nutrient enrichment can disrupt biological communities and ecosystem processes in the coastal zone. For example, while some estuaries exhibit classic symptoms of acute eutrophication, including enhanced production of algal biomass, other nutrient-rich estuaries maintain low algal biomass and primary production. This implies that large differences exist among coastal ecosystems in the rates and patterns of nutrient assimilation and cycling. Part of this variability comes from differences among ecosystems in the other resource that can limit algal growth and production – the light energy required for photosynthesis. Complete understanding of the eutrophication process requires consideration of the interacting effects of light and nutrients, including the role of light availability as a regulator of the expression of eutrophication. A simple index of the relative strength of light and nutrient limitation of algal growth can be derived from models that describe growth rate as a function of these resources. This index can then be used as one diagnostic to classify the sensitivity of coastal ecosystems to the harmful effects of eutrophication. Here I illustrate the application of this diagnostic with light and nutrient measurements made in three California estuaries and two Dutch estuaries.
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  • 67
    ISSN: 1573-5125
    Keywords: eutrophication ; bacteria ; dynamics ; macrotidal estuary ; Bay of Somme
    Source: Springer Online Journal Archives 1860-2000
    Topics: Biology
    Notes: Abstract A stratified methodology for water sampling on tidal flats was adopted in 1988 and 1989 in the Bay of Somme. Analyses of nutrients, particulate matter and faecal germs showed the poor mixing of fresh and marine water and the weakness of stratification of the water column. Freshwater is pushed by marine water to the inner reaches of the bay and there are only a few lenses with true estuarine characteristics. In 1990, water was sampled simultaneously on the Somme river, the tidal flats and in the open sea, in order to point out estuarine gradients of several physical and chemical parameters and their evolution during a tidal cycle. The role of continental inputs was confirmed for faecal pollution, nitrate (20–25 mg l−1), nitrite and silicate. The importance of ammonium excreted by the estuarine benthic populations was highlighted. High concentrations of continental chlorophyll (450 mg m−3) were also measured and contribute, with nitrates and ammonium, to eutrophication in the Bay of Somme. Pollution of the southern part of the bay by marine waters was regularly observed during the flow, raising doubts about the purifying capacity of sea-water and the conservation of faecal bacteria. A regular survey of fresh-water inputs and sea-water quality, offshore and within the bay, is considered to enable estimation of their respective influences in eutrophication processes in the Bay of Somme.
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  • 68
    ISSN: 1573-5117
    Keywords: lake restoration ; eutrophication ; phosphates ; iron-dosing ; lake-bottom treatment ; water-jet
    Source: Springer Online Journal Archives 1860-2000
    Topics: Biology
    Notes: Abstract A new, flexible, fast, robust and economic technique was developed to treat sediment in shallow lakes with phosphate binding chemicals. The upper 0.15 m of the sediment is thoroughly mixed with ferric chloride using a water-jet manifold coupled to a dosing pump and a navigation control system. Its logistics were tried out in a small, shallow and hypertrophic peat lake, Lake Groot Vogelenzang.
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  • 69
    ISSN: 1573-5117
    Keywords: eutrophication ; sediments ; palaeolimnology ; phosphorus ; diatoms ; chironomids ; lake restoration ; Finland
    Source: Springer Online Journal Archives 1860-2000
    Topics: Biology
    Notes: Abstract The eutrophicated Enäjärvi was studied by paleolimnological analyses and sediment mapping. The sedimentary record indicates that the lake nutrient balance had deteriorated due to lowering of the lake water level in the year 1928. From that event onwards Chironomus plumosus and Cyclotella astraea characterize the chironomid and diatom communities. The concentrations of sedimentary total and mobile phosphorus show that since then the internal load of phosphorus has controlled the nutrient cycle of the lake. The areal distribution of mobile phosphorus can be explained by dominant wind directions and wind resuspension of the sediment is the key factor in the nutrient cycle. Restoration of Enäjärvi must be based on actions which stabilize the surface sediment and improve its natural phosphorus-binding capacity. They include the regulation of lake water to as high a level as possible and the removal of the majority of roach.
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  • 70
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    Hydrobiologia 269-270 (1993), S. 235-242 
    ISSN: 1573-5117
    Keywords: diatom flora ; ebridians ; marine sediments ; eutrophication ; Baltic Sea
    Source: Springer Online Journal Archives 1860-2000
    Topics: Biology
    Notes: Abstract A sediment core, 55 cm long, from station F81 in the Gotland Basin of the Baltic Sea was analysed for diatoms and ebridians. Chrysophyte stomatocysts found in the core were also counted but not identified. The aim was to trace environmental changes, e.g. eutrophication and salinity variations. There is evidence that eutrophication has been increasing in the Baltic Sea in recent decades. Brackish-marine plankton diatoms dominate the entire core and reflect the local planktonic taxa rather well. The dominant taxon is the polyhalobous Actinocyclus octonarius. The main biostratigraphical change within the core analysed takes place at a depth of about 22 cm, where the abundance of diatoms, and especially of Chaetoceros spp., Thalassiosira hyberborea var. pelagica and T. baltica start to increase. This may reflect eutrophication which can be estimated to have started c. 200 years ago.
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  • 71
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    Hydrobiologia 251 (1993), S. 309-320 
    ISSN: 1573-5117
    Keywords: eutrophication ; water quality protection ; nutrient load ; nutrient retention
    Source: Springer Online Journal Archives 1860-2000
    Topics: Biology
    Notes: Abstract Water quality of Lake Balaton, particularly that of its south-western basin (the Keszthely-Bay), has been deteriorating faster and faster. The greatest transporter of inorganic nutrients to the Bay is the Zala River. The lower valley of the river was part of the lake until about 200 years ago. Later, a large part of the area was turned to a wetland, while the smaller part dried up. To retain the nutrients from Keszthely-Bay, the former marshland is now being reconstructed: the so-called Kis-Balaton Water Protection System (KBWPS). The first part of the System, the Hidvégi-Pond, has been operating since the middle of 1985. The second stage, the Fenéki-Pond, to be finished by the end of this century, is now under construction. The main purpose of the KBWPS is to gain enough time to build up the technology necessary for an adequate protection of Lake Balaton. From the beginning of the operation of the Hidvégi-Pond a multidisciplinary research program has been carried out to monitor the hydrological, hydraulical, ecological, and biological processes in the reservoir. This program focused on nitrogen and phosphorus loadings and retention. Input and output loads were estimated from daily measurements. The mechanisms of retention were studied in special projects. With the exception of TN, nutrient retention increased from year to year. In 1990, 96% of PO4-P, 87% NO3-N, and 58% of TP were retained. This efficiency exceeds expectations. Retention of TN is the lowest (about 20%), due to N2-fixation by blue-green algae. However, the second stage needs to be implemented, since there is an additional external load from the watershed of the lower valley, and nutrient release takes place during decomposition of the organic matter which leaves the Hidvégi-Pond.
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  • 72
    ISSN: 1573-5117
    Keywords: fen lakes ; hydrology ; eutrophication ; productivity ; element cycling ; recovery
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    Topics: Biology
    Notes: Abstract Most relatively large (〉 250 ha) and shallow (〈 2 m), Dutch lakes originate from large-scale peat mining. Originally, their water tables were regulated by natural processes such as evapotransporation, precipitation, drainage and seepage (up and downwards). These lakes used to be oligo to mesotrophic, and the phytoplankton consisted mainly of diatoms and green algae. However, 30 years ago filamentous cyanobacteria were also present. Owing to the intensification of agriculture in the surroundings of the lakes, their management developed more and more towards a man-made reservoir function. This management resulted in inflow of eutrophic water from the agricultural areas in winter. In summer the lakes were increasingly used as a water supply. This supply is compensated by water imported mainly from the River Rhine. The impacts of this reservoir function on the limnology of the Dutch fen lakes are discussed with the Tjeukemeer, the Loosdrechtse Plassen and the Reeuwijkse Plassen as examples. All these lakes have become typical eutrophic waters with high turbidity, dominance of filamentous cyanobacteria and bream and complete loss of submerged macrophytes. Finally, methods and results of manipulation procedures to restore these waters are discussed.
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  • 73
    ISSN: 1573-5117
    Keywords: Phosphorus ; sediment ; lakes ; eutrophication
    Source: Springer Online Journal Archives 1860-2000
    Topics: Biology
    Notes: Abstract The contribution of sediment release to the phosphorus budget of hypereutrophic Onondaga Lake was determined through laboratory measurements made on intact cores. Rates ranged from 9–21 mg P m−2 d−1 with a mean of 13 mg P m−2 d−1, values similar to those observed in other lakes of comparable trophic state. There was no statistically significant trend in rates in time (July versus September) or in space (location along the major N/S axis of the lake). Rates of sediment phosphorus release measured in the laboratory compared favorably with the observed rate of soluble reactive phosphorus accumulation in the lake's hypolimnion. The sediments are the second largest source of phosphorus for Onondaga Lake, contributing 24% of the overall phosphorus load to the system.
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  • 74
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    Hydrobiologia 269-270 (1993), S. 243-249 
    ISSN: 1573-5117
    Keywords: diatoms ; eutrophication ; sediments ; Gulf of Riga ; Baltic Sea
    Source: Springer Online Journal Archives 1860-2000
    Topics: Biology
    Notes: Abstract Twenty one superficial sediment samples from areas of high and moderate eutrophication in the Gulf of Riga were studied with respect to siliceous microfossils, mainly diatoms. The results seem to imply that the number of taxa and the abundance of the frustules are affected by runoff from rivers and the degree of eutrophication in different parts of the Gulf. Areas with high eutrophication, e.g. the river estuaries, have diatom assemblages of varying composition, while in areas with moderate eutrophication the composition is almost constant and the influx of freshwater diatoms and littoral periphyton small. The high abundance and low diversity of brackish-marine and brackish, planktonic diatoms seem to be a result of an influx of nutrients and pollutants in the water and bottom sediments. The sea ice diatoms occurring in the Baltic waters and also in the Gulf of Riga tend to be resistant to eutrophication or are even favoured by it.
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  • 75
    ISSN: 1573-5117
    Keywords: diatoms ; paleolimnology ; eutrophication ; varved sediment ; phosphorus accumulation
    Source: Springer Online Journal Archives 1860-2000
    Topics: Biology
    Notes: Abstract Lake Vesijärvi was loaded by sewage from the City of Lahti for 60 years until 1976 when the discharge was diverted. Paleolimnological analyses of the varved bottom sediment indicate that the sedimentation rate within the Enonselka basin, the most eutrophic part of the lake, has been as high as 2 cm yr−1, and total phosphorus accumulation was 20–40 g P m−2 yr−1, during the last 20 years. Within the less eutrophic Laitialanselkä basin, the sedimentation rate did not exceed 1 cm yr−1, and the formation of varved sediment only began at the end of the 1960's, i.e. about 10 years later than in Enonselkä. Planktonic diatom production was highest in the Enonselka basin. The most abundant diatoms in the sediment between 1970–1985 were Asterionella formosa, Aulacoseira islandica and Stephanodiscus spp. Fragilaria crotonensis and Tabellaria fenestrata had low abundances in the middle of the 1970's but increased again at the end of the 1970's. Asterionella formosa and Diatoma elongatum reached their maxima between 1979–1984 when the hypolimnion of the Enonselk/:a basin was aerated artificially. In the Laitialanselkä basin, the production of planktonic diatoms has been lower and the species composition of the diatom community differed from that in Enonselkä. However, at the end of 1980's the total accumulation of diatoms in Laitialanselkä approached levels which were observed at the end of 1950's in Enonselkä, prior to the rapid eutrophication period. The production and thereby the sedimentation of diatoms has decreased towards the end of the 1980's in Enonselkä, indicating reduced nutrient availability in the lake water. This reduction was due to the decreased external loading of phosphorus as well as to the decreased release of phosphorus from the sediment as a result of improved oxygen balance in the hypolimnion.
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  • 76
    ISSN: 1573-5117
    Keywords: sedimentary diatoms ; oligohumic lakes ; oligotrophy ; eutrophication
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    Topics: Biology
    Notes: Abstract Sedimentary diatom assemblages in two large oligotrophic clear-water lakes were analysed, to assess their present ecological state and possible eutrophication due to diffuse nutrient loading. The lakes Pyhäjärvi and Puruvesi (Finnish lake district) are proportionally large for their catchment areas which accounts for their long retention times (ca 7 and 11 yr) and oligohumic character. Pyhäjärvi was studied by pairwise comparison of surface sediment diatom assemblages collected in 1985 and 1990 at 12 sites from different parts of the lake. In Puruvesi, the stratigraphy of diatoms was analysed in two short cores from 8 m and 32 m depths. The diatom assemblages of the two lakes are rather similar, and quite distinct from the assemblages of the mesohumic large lakes of the area. Cyclotella kuetzingiana is the most common planktonic dia- tom, but Aulacoseira ambigua abounds in Pyhäjärvi at sites with local sources of eutrophication. A diverse assemblage of benthic forms, especially Fragilaria and Achnanthes spp. characterizes the shallow bottoms in both lakes. There was little change within the short-core diatom profiles of Puruvesi, but the floral composition of the 8-m and 32-m sites differed markedly. The 8-m site, with 60–70% of benthic forms, represents illuminated bottom, on which much of the buried algae have lived in situ, while the deeper site is true profundal, dominated by sedimented planktonic algae. In Pyhäjärvi there was a slight increase in the benthic diatoms from 1985 to 1990, coinciding with increased phosphorus and chlorophyll concentrations as well as Secchi depth lowering. We interprete this observation as a very early step of eutrophication, of which first the sessile algal communities of the illuminated bottom areas have benefited.
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  • 77
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    Hydrobiologia 253 (1993), S. 179-192 
    ISSN: 1573-5117
    Keywords: Heterotrophic bacteria ; polyphosphate metabolism ; dissimilatory manganese and iron reduction ; ecological niche ; phosphorus cycle ; eutrophication
    Source: Springer Online Journal Archives 1860-2000
    Topics: Biology
    Notes: Abstract The purpose of this study was to find theoretical evidence that bacteria, in particular those capable of polyphosphate (polyP) metabolism, are directly implicated in sediment phosphorus (P) dynamics and control P metabolism of freshwater ecosystems. The specific attributes and functional role of such bacteria were investigated on successive levels of ecological organization: individual microorganism, microbial community, freshwater ecosystem. The results of this systematic approach have been formulated as a number of hypotheses. (1) PolyP metabolism is the mechanism which enables individual polyP bacteria to survive and grow under the fluctuating redox conditions characteristic of their habitat at the sediment-water interface. (2) PolyP metabolism together with anaerobic Mn and/or Fe respiration is the mechanism that confers upon polyP bacteria the advantage required to fill a unique ecological niche within the microbial community to which they belong. (3) To the freshwater ecosystem as a whole bacterial polyP metabolism is a homeostatic mechanism which limits P availability and makes ecosystem productivity self-correcting as a function of oxygen availability. Bacterial polyP pools in the sediment are vital components of the P cycle. It was suggested that the impact of this bacterial mechanism should be tested with regard to the eutrophication issue.
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    Hydrobiologia 251 (1993), S. 143-148 
    ISSN: 1573-5117
    Keywords: Danube Delta ; flood zones ; phosphorus ; nitrogen ; eutrophication
    Source: Springer Online Journal Archives 1860-2000
    Topics: Biology
    Notes: Abstract The change of concentration of total reactive phosphorus (TRP) and dissolved inorganic nitrogen (DIN) was studied in the lower Danube river and in selected lakes situated in the wetland area of the Danube Delta. The differences Danube Delta in nutrient concentration in the river waters entering the delta and the delta in different sites (especially lakes) of the wetland area are considered to reflect retention in the system. The highest retention was found in periods of moderate and low water level when the surface-to-volume ratio of the lakes was high. In these periods the in-lake concentration of TRP and DIN could be as low as 11 and 23% of the values found in the inflowing river.
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    Hydrobiologia 260-261 (1993), S. 239-253 
    ISSN: 1573-5117
    Keywords: algal associations ; zonation patterns ; fucoids ; pollution impact ; eutrophication
    Source: Springer Online Journal Archives 1860-2000
    Topics: Biology
    Notes: Abstract During the last two decades conditions in the polluted shelf area of the Northern Adriatic became critical, leading to eutrophication and anoxia. They are reflected in changes and degradation of the macrophytobenthos with simultaneous increase of phytoplankton blooms. Pollution-induced changes of the benthic algal vegetation comprise altered zonation patterns and leading algal associations along with a decrease in species number and fresh weight biomass. A reduction or absence of fucoid stands was observed in the eulittoral and sublittoral. Fucus virsoides was in most cases replaced by ephemeral species which form distinct zones during spring and by turf-like mats of Gelidium pusillum. Sublittoral Cystoseira stands were either reduced or absent, replaced by populations of Halopteris scoparta, Dictyota dichotoma, Halopithys incurvus, Padina pavonica and under extreme conditions by Ulva rigida with Scytosiphon lomentaria and Enteromorpha species during spring. A decreased depth penetration of macroalgae was observed in polluted sites. It seems likely that amorphous mucus aggregations resulting probably from excess phytoplankton blooms which were found during summer months of the last few years, have a deleterious effect on macroalgae.
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  • 80
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    Hydrobiologia 265 (1993), S. 15-44 
    ISSN: 1573-5117
    Keywords: nutrient cycling ; eutrophication ; water management ; long-term changes ; estuarine food-web ; estuary ; coastal lagoon ; The Netherlands ; man-induced disturbance
    Source: Springer Online Journal Archives 1860-2000
    Topics: Biology
    Notes: Abstract In this review several aspects of the functioning of the Dutch estuaries (Ems-Dollard, Wadden Sea, Oosterschelde, Westerschelde, Grevelingen and Veerse Meer) have been compared. A number of large European rivers (especially Rhine) have a prevailing influence on the nutrient cycling of most Dutch estuaries. Owing to the increased loading of the estuaries with nitrogen and phosphorus compounds, effects of eutrophication on the biological communities could be demonstrated, mainly in the western Wadden Sea. The causality, however, of the relation between increased nutrient loading and increased biomass and production of primary producers in the turbid tidal Dutch ecosystems is questioned. The most obvious biological effects of eutrophication have been observed in a non-tidal brackish lagoon, Veerse Meer. The estuarine food web received major attention. Budget studies of the main primary producers revealed a dominance of phytoplankton in all Dutch estuaries, followed by microphytobenthos in the tidal systems and macrophytes in the lagoons. The quantitative distribution of primary producers and primary and secondary consumers shows remarkable similarities along the physical and chemical estuarine gradients, notwithstanding the large variability in space and the considerable inconstancy over time. Among the secondary consumers (waterfowl, marine fish, larger invertebrates) the levels of organic carbon consumption — expressed in g C m−2 y−1 — are almost the same, when tidal estuaries are compared with non-tidal lagoons, notwithstanding the fact that the consumer populations show large qualitative differences. The transfer from primary consumers to secondary consumers reveals a bottle neck: especially during late winter, when macrozoobenthos reaches its lowest biomass, food may be a serious limiting resource for large numbers of migratory waders foraging on the intertidal flats. The consequences of the Deltaplan, the closure of several estuaries in the southwest of the Netherlands and their subsequent transfer into non-tidal lagoons, offer complicated case studies of ecosystem changes. Several examples of long-term trends in ecosystem development in Grevelingen lagoon have been discussed.
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    Hydrobiologia 408-409 (1999), S. 139-144 
    ISSN: 1573-5117
    Keywords: eutrophication ; ecological modelling ; multiple regression
    Source: Springer Online Journal Archives 1860-2000
    Topics: Biology
    Notes: Abstract A research was made on the potential use of neural network based models in eutrophication modelling. As a result, an algorithm was developed to handle the practical aspects of designing, implementing and assessing the results of a neural network based model as a lake management tool. To illustrate the advantages and limitations of the neural network model, a case study was carried out to estimate the chlorophyll-aconcentration in Keban Dam Reservoir as a function of sampled water quality parameters (PO4phosphorus, NO3nitrogen, alkalinity, suspended solids concentration, pH, water temperature, electrical conductivity, dissolved oxygen concentration and Secchi depth) by a neural network based model. Alternatively, the same system was solved with a linear multiple regression model in order to compare the performances of the proposed neural network based model and the traditional linear multiple regression model. For both of the models, the linear correlation coefficients between the logarithms of observed and calculated chlorophyll-aconcentrations were calculated. The correlation coefficient R, the best linear fit between the observed and calculated values, was evaluated to assess the performances of the two models. R values of 0.74 and 0.71 were obtained for the neural network based model and the linear multiple regression model, respectively. The study showed that the neural network based model can be used to estimate chlorophyll-awith a performance similar to that of the traditional linear multiple regression method. However, for cases where the input and the output variables are not linearly correlated, neural network based models are expected to show a better performance.
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  • 82
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    Hydrobiologia 408-409 (1999), S. 375-387 
    ISSN: 1573-5117
    Keywords: eutrophication ; multi-lake studies ; phosphorus ; nitrogen ; chlorophyll-a ; transparency ; zooplankton ; macrophytes
    Source: Springer Online Journal Archives 1860-2000
    Topics: Biology
    Notes: Abstract Monitoring data obtained from 231 freshwater lakes and ponds in the Netherlands, covering the period 1980–1996, were used to analyse the relationships between (a) transparency and chlorophyll-a, and the effect of system characteristics on this relationship, (b) chlorophyll-aand nutrient concentrations, and the effect of biological variables and (c) nutrient concentrations and nutrient loading. (a) Chlorophyll-aimposes a maximum on water transparency, but deviations from this maximum can be large. Reducing chlorophyll-a, therefore, does not guarantee a sufficient improvement of transparency. Soil type and the average depth of a lake were shown to influence the relationship between chlorophyll-aand transparency. (b) The maximum ratios of both chlorophyll-a: total-P and chlorophyll-a: total-N were higher in systems dominated by filamentous cyanobacteria than in systems dominated by other algae, indicating the efficiency of the former group with respect to nutrients. In systems with an areal coverage with submersed macrophytes above 5%, concentrations of chlorophyll-aand nutrients were lower than in systems with lower coverages. The ratios between chlorophyll-aand nutrients were lower at coverages larger than 10%. This indicates both bottom-up and top-down control of algae by macrophytes. Grazing pressure by zooplankton was also found to lower the chlorophyll-a: nutrient ratios. (c) System specific linear relationships were found between the average concentrations of total-P and total-N in the incoming water and the summer mean concentration in the lake. This allows the assessment of admissible loads for individual lakes, with narrower confidence limits compared to traditional relationships based on combined data from many lakes. From the analysis, it is concluded that the chain of relationships from nutrient loading to transparency is complex, and depends on biological variables as well as system characteristics.
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  • 83
    ISSN: 1573-5117
    Keywords: epiphytes ; macroalgae ; Cystoseira (host plant) ; seasonality ; eutrophication ; Mediterranean
    Source: Springer Online Journal Archives 1860-2000
    Topics: Biology
    Notes: Abstract Epiphytic macroalgal assemblages growing on Cystoseira species were examined at typical oligotrophic and eutrophic sites of the east coast of Attica (Aegean Sea, Greece) from November 1995 to September 1996. The epiphytic patterns of C. spinosa Sauvageau thriving in the oligotrophic area of Dikastika and of C. compressa (Esper) Gerloff & Nizzamudin growing in the eutrophic environment of Avlida, were compared through a cross-transplantation experiment. Seasonality effects on epiphytic assemblages were observed. The species composition was exclusive for each locality, reflecting differences in the trophic status of the two sites. No specific pattern of epiphytes' distribution was found on the hosts. The prolific epiphytic growth in the oligotrophic site resulted in a reduction of the photosynthetic tissue of both hosts (C. spinosa and the transplanted C. compressa) and the survivorship of host plants was not negatively affected by the physical drag caused by the high epiphyte densities. Cystoseira spinosa survived in oligotrophic conditions despite its heavy epiphytic load. C. compressa was also able to cope with the adverse epiphytic influence in the eutrophic conditions of Avlida; although being perennial, it sheds parts of its stipe and branches before the resting period and sprouts prior to other algae at the beginning of spring.
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  • 84
    ISSN: 1573-5117
    Keywords: phytoplankton ; eutrophication ; water quality modelling ; nutrients ; restoration
    Source: Springer Online Journal Archives 1860-2000
    Topics: Biology
    Notes: Abstract The aim of the study was to assess the effect of nutrient loading and water level regulation of water quality in Lake Võrtsjärv. The lake is highly eutrophic and it has a high value for fisheries and recreation. A water quality model was developed in order to make predictions of the effects of the different possible restoration measures (reduction of nutrient loading, water level regulation) planned to be carried out. Two phytoplankton groups, diatoms and cyanobacteria, were included in the model. Their contribution to the total algal biomass is dominating. The other state variables of the model are concentration of soluble reactive phosphorus (SRP), concentration of inorganic nitrogen and concentration of dissolved oxygen. The ecological model was constructed using continuously stirred tank reactor (CSTR) hydraulics. The zero-dimensional approach could be used because the lake is shallow and has no thermal stratification. According to the model, external nutrient loading has a very small effect on the biomass of cyanobacteria, whereas the effect is clearer when diatoms are concerned. The contribution of water level to biomass is very significant for both diatoms and cyanobacteria.
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    Hydrobiologia 394 (1999), S. 219-232 
    ISSN: 1573-5117
    Keywords: restoration ; alternative stable states ; eutrophication ; macrophytes ; shallow lakes
    Source: Springer Online Journal Archives 1860-2000
    Topics: Biology
    Notes: Abstract Lake Apopka (Florida, USA) changed in 1947 from being a clear, macrophyte-dominated lake, used primarily for fishing, into a turbid algal lake with a poor fishery. The lake has resisted various efforts to reverse the change and restore the previous state. The restoration approach emphasizes the reduction in phosphorus inputs to reduce algal blooms and clear the water. We examined the question of whether a deep-lake approach with nutrient reductions is going to work on this large (area 124 km2) and shallow (mean depth 1.7 m) lake, or if techniques such as drawdowns or wind barriers developed for shallow lakes using the theory of alternative stable states are more applicable. The assumptions upon which the current restoration is based are not supported. The poor transparency is due more to resuspended sediments than plankton algae, so the current Secchi disk depth of 0.23 m is predicted to increase to 0.34 m with any reasonable reduction in algal levels. The failure of the macrophytes to become re-established probably is due more to unstable sediments than lack of light reaching the lake bed, and the marsh flow-way developed by the St Johns River Water Management District will be ineffective in removing particles from the lake. It would take more than 300 years to remove the fluid mud and more than 800 years to remove the rest of the low density sediments. We conclude that the loss of macrophytes in Lake Apopka is an example of a forward switch in the theory of alternative stable states, and that it will take more than a nutrient reduction program to bring about the reverse switch to a macrophyte state. We suggest an alternative approach using wave barriers to create refuges for plants, macroinvertebrates, and fish to restore Lake Apopka's largemouth bass fishery.
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    Hydrobiologia 404 (1999), S. 19-26 
    ISSN: 1573-5117
    Keywords: sediment ; phosphorus ; eutrophication ; biomanipulation ; fish ; Sweden
    Source: Springer Online Journal Archives 1860-2000
    Topics: Biology
    Notes: Abstract Lake Ringsjön did not respond with decreased algal production following a substantial reduction in external phosphorus loading. This is typical of many shallow lakes which for decades have received excessive amounts of nutrients. The inertia is due to large amounts of phosphorus (P) stored in sediments and biota, causing internal phosphorus loading. Much of this phosphorus is thought to be released from the organic-rich profundal sediments. In Lake Ringsjön, only one third of the total bottom area is covered by such sediments, the rest being dominated by sand and silt. In the profundal sediments bulk P content was not exceptionally high (approximately 2 mg P·g DW−1), while the pore water phosphate concentrations, especially in Sätofta Basin, were very high, indicating large potential for phosphorus release to the water. This is also indicated by the large proportion of Fe- and Al-bound P in the sediments of Sätofta Basin. Although there are no direct quantifications of phosphorus release from the sediments in Lake Ringsjön, measurements of phosphorus concentrations in the water mass as well as budget calculations for the three basins clearly show a high capacity for internal loading. Phosphorus concentrations generally increase during summer, when external additions are minimal. Until 1980, the annual external phosphorus addition to Lake Ringsjön greatly exceeded the output, showing that the lake was an efficient phosphorus trap. Since then, input and output have been balanced, but in recent years signs that the lake is once again retaining phosphorus on an annual basis are evident. There are marked differences between the three basins, with Western Basin generally retaining phosphorus, while the upstream Eastern Basin and Sätofta Basin during the 1980s often exported phosphorus. It is not possible to evaluate the effects of the fish biomanipulation on the internal loading of phosphorus from the sediment.
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    Hydrobiologia 404 (1999), S. 19-26 
    ISSN: 1573-5117
    Keywords: sediment ; phosphorus ; eutrophication ; biomanipulation ; fish ; Sweden
    Source: Springer Online Journal Archives 1860-2000
    Topics: Biology
    Notes: Abstract Lake Ringsjön did not respond with decreased algal production following a substantial reduction in external phosphorus loading. This is typical of many shallow lakes which for decades have received excessive amounts of nutrients. The inertia is due to large amounts of phosphorus (P) stored in sediments and biota, causing internal phosphorus loading. Much of this phosphorus is thought to be released from the organic-rich profundal sediments. In Lake Ringsjön, only one third of the total bottom area is covered by such sediments, the rest being dominated by sand and silt. In the profundal sediments bulk P content was not exceptionally high (approximately 2 mg P·g DW−1), while the pore water phosphate concentrations, especially in Sätofta Basin, were very high, indicating large potential for phosphorus release to the water. This is also indicated by the large proportion of Fe- and Al-bound P in the sediments of Sätofta Basin. Although there are no direct quantifications of phosphorus release from the sediments in Lake Ringsjön, measurements of phosphorus concentrations in the water mass as well as budget calculations for the three basins clearly show a high capacity for internal loading. Phosphorus concentrations generally increase during summer, when external additions are minimal. Until 1980, the annual external phosphorus addition to Lake Ringsjön greatly exceeded the output, showing that the lake was an efficient phosphorus trap. Since then, input and output have been balanced, but in recent years signs that the lake is once again retaining phosphorus on an annual basis are evident. There are marked differences between the three basins, with Western Basin generally retaining phosphorus, while the upstream Eastern Basin and Sätofta Basin during the 1980s often exported phosphorus. It is not possible to evaluate the effects of the fish biomanipulation on the internal loading of phosphorus from the sediment.
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  • 88
    ISSN: 1573-5117
    Keywords: eutrophication ; acidification ; macrophyte communities ; weakly mineralized streams ; France
    Source: Springer Online Journal Archives 1860-2000
    Topics: Biology
    Notes: Abstract The Northern Vosges streams are subjected to acidification upstream and to eutrophication downstream. A bio-indicator scale of the degree of eutrophication and of the level of acidification, based on four aquatic macrophyte communities, was established in these weakly mineralized streams. Aquatic plant communities therefore begin as Group A, develop into Group B and become Group C or D downstream. The A community was characterized by bryophytes (Scapania undulata, Sphagnum sp.) and Potamogeton polygonifolius in oligotrophic, acidified to weakly acidified, and poorly buffered streams. The B community, defined by P. polygonifolius and the appearance of Ranunculus peltatus and Callitriche species (C. platycarpa, C. hamulata) was found in oligotrophic waters with a higher buffer capacity than the A community. The C community was determined by the disappearance of P. polygonifolius and the appearance of Elodea species (E. canadensis, E. nuttallii) and rare species in mesotrophic and neutral streams. The D community, with very high nutrient loading, was characterized by the abundance of Callitriche obtusangula, by the presence of Amblystegium riparium, Fissidens crassipes and the development of filamentous algae. This macrophyte sequence corresponded to an upstream to downstream zonation, which was characterized by an increase in buffer capacity and in nutrient levels and a decrease in protons and aluminium load.
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  • 89
    ISSN: 1573-5117
    Keywords: Neva Bay ; Gulf of Finland ; eutrophication ; phytoplankton ; zooplankton ; zoobenthos
    Source: Springer Online Journal Archives 1860-2000
    Topics: Biology
    Notes: Abstract A comparative study of the long-term data (1982–1996) on the ecosystems' state in Neva Bay and the eastern Gulf of Finland showed spatial differences and temporal changes in the structure and functioning of the aquatic communities. Recent data revealed progressing eutrophication in the southern part of Neva Bay, viz. a pronounced increase of primary production and the prevalence of the production process over the decomposition of organic matter which had never been observed in Neva Bay before. At present, biomass of benthos has dramatically decreased in the eastern part but increased in the south-western areas of the bay. Structure and spatial distribution of zooplankton communities have changed both in Neva Bay and the eastern Gulf of Finland. In the latter part of the estuary, blue-green algae became a dominating group of phytoplankton indicating serious alterations in the ecosystem caused by anthropogenic stress.
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  • 90
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    Hydrobiologia 393 (1999), S. 117-125 
    ISSN: 1573-5117
    Keywords: microbial communities ; biomass ; biomarkers ; eutrophication ; season ; sediments
    Source: Springer Online Journal Archives 1860-2000
    Topics: Biology
    Notes: Abstract Seasonal changes in sedimentary microbial communities were investigated using biomarker analysis from samples collected in spring and autumn 1995 from Hiroshima Bay and Suo Nada of the Seto Inland Sea of Japan. Surface sediment samples were analysed for several sediment parameters and phospholipid ester-linked fatty acids (PLFA). Total PLFA concentration, which is indicative of microbial biomass, was high in autumn and low in spring in Hiroshima Bay but no such significant seasonal difference of PLFA concentration was observed in Suo Nada. PLFA composition of the sediments were dominated by saturated PLFA, branched PLFA and monounsaturated PLFA. Regional variation in the PLFA composition was less pronounced than the seasonal variation. The presence of the characteristic polyunsaturated fatty acids (PUFA) revealed that microeukaryotes were always present in small proportions. The aerobic prokaryotes and eukaryotes group were predominant in spring, whereas in autumn, the Gram-positive bacteria group was predominant. Monounsaturated PLFA/branched PLFA ratio was high in spring and low in autumn, indicating the relative dominance of these biomarker fatty acids. Significant seasonal differences of sediment parameters, PLFA groups and microbial groups were observed in Hiroshima Bay. In Suo Nada, these parameters showed similar patterns to Hiroshima Bay but the differences of most of the parameters were insignificant. Furthermore, principal components analysis (PCA) revealed a significant shift in microbial community structure between the two seasons, indicating a clear response of microbial communities to changes in sediment parameters.
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  • 91
    ISSN: 1573-5117
    Keywords: littoral fish ; Archipelago Sea ; Baltic Sea ; eutrophication
    Source: Springer Online Journal Archives 1860-2000
    Topics: Biology
    Notes: Abstract A collapse of the littoral fish populations was found in the middle archipelago zone near the Island of Seili (northern Baltic Sea) when fish populations were studied in summer 1996 in a comparable way with earlier studies done in the early 1970s and 1980s. A similar comparison was made in the outer archipelago (the islands off the island of Utö), but no evident change was found. Reasons for the decline in littoral fish stocks are discussed, but no single-cause effect can be pointed out. Among possible explanations is a substantial increase of eutrophication in the middle archipelago together with increasing ferry traffic which both cause structural changes in the littoral environment of the study area.
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  • 92
    ISSN: 1573-5117
    Keywords: plain streams ; nutrients ; eutrophication ; organic pollution
    Source: Springer Online Journal Archives 1860-2000
    Topics: Biology
    Notes: Abstract The Argentine pampean streams exist in a traditionally agricultural region, but they also receive a supply of contaminants in the more urban zones. The objectives of this study are: 1. To analyze the physical, chemical and microbiological characteristics of the streams in the Luján river basin; and 2. To describe the annual variation of some chemical characteristics (primarily nutrients) in one of the streams. Two samplings (winter and summer) were made in 20 streams to determine some physical, chemical and microbiological variables. Topographical variables were also estimated in each stream. Additionally, in one of the streams (Las Flores), monthly measurements of current velocity, flow, and dissolved nitrogen, phosphorus and oxygen were taken during 4 years. The streams are characterized by high nutrient contents. There is no strong heterogeneity in stream chemical characteristics within the same period, however seasonal variations are important . The principal components analysis suggests the existence of two axes of variation within the basin. One reflects a pollution gradient that increases downstream; the other axis shows that waters change from high to low alkalinity and from less to more eutrophic. In Las Flores stream, nutrient concentration varied greatly between years. The concentration of soluble reactive phosphorus was significantly correlated with stream flow (P 〈 0.05). Though there was no correlation between nitrate levels and flow, some estimates indicated that these ions are in high concentrations in the groundwater. The physiognomical characteristics of pampean streams differ greatly from those described in temperate streams of the northern hemisphere, and it may be assumed that they also exhibit distinct functional characteristics.
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  • 93
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    Hydrobiologia 395-396 (1999), S. 365-378 
    ISSN: 1573-5117
    Keywords: urban lakes ; eutrophication ; wildfowl ; management ; education
    Source: Springer Online Journal Archives 1860-2000
    Topics: Biology
    Notes: Abstract Urban lakes are very different from other lakes: they are shallow, highly artificial and often hypertrophic yet more people come into contact with them than rural, natural lakes. Our knowledge of their ecology and management is poor. This paper describes a project under the EU Life programme to understand and ecologically manage the most important urban lakes in the London Borough of Wandsworth. One main lake has been evaluated: Battersea Park Lake. The magnitude of anthropogenic impacts are quantified and remedies explored. Computer-based decision trees for urban lake management have been developed and are illustrated.
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  • 94
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    Hydrobiologia 395-396 (1999), S. 403-409 
    ISSN: 1573-5117
    Keywords: eutrophication ; shallow lakes ; Netherlands
    Source: Springer Online Journal Archives 1860-2000
    Topics: Biology
    Notes: Abstract Due to the limited perspectives of the Dutch national policy and due to the unique conditions and constraints of individual lake systems, tailor-made programs are needed for the restoration of freshwater lakes. Based on an evaluation of several restoration projects, a guideline is provided to enable water managers to develop such a restoration program. This guide-line is summarized in the paper and important topics, such as the definition of targets and standards, system identification and measures, are highlighted. Targets should include a natural reference, but also the constraints imposed by other functions of the lake. Monitoring and system identification are necessary to determine the extent of remedial measures and whether they should focus on external nutrient sources, internal sources or other factors, such as the food web structure. It is advocated that for lakes which have not degraded to a green, algal-dominated, turbid state, prevention or re-establishment of its ability to self-restore are preferred to ‘intensive surgery’ on the system. Lake re-creation can be applied if the system is heavily perturbed. In that case the re-creation of a more beneficial system is a more fair-minded approach than restoration of the natural state.
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  • 95
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    Hydrobiologia 395-396 (1999), S. 389-401 
    ISSN: 1573-5117
    Keywords: legislation ; eutrophication ; phosphorus ; nitrogen ; wildlife conservation ; SSSI
    Source: Springer Online Journal Archives 1860-2000
    Topics: Biology
    Notes: Abstract There is no single piece of legislation which comprehensively addresses the problem of eutrophication of freshwater lakes. An examination is made of the extent to which national and EU laws applicable in England and Wales may be used to reduce phosphorus inputs to eutrophicated lakes. This case study is then used to outline the shortcomings of existing legislation and the future challenges for lake eutrophication control. Applicable legislation may be divided into that relating to nature conservation, to water quality and to agricultural extensification. Nature conservation laws are applicable, in that lakes designated as Sites of Special Scientific Interest (SSSIs), are theoretically safeguarded from degradation. The main limitation of the SSSI system lies in the boundary definition process under which, as a rule, no other category of legally protected land may be designated. Thus, the use of surrounding buffer land to protect water quality at the catchment level is generally precluded. The introduction of consultation areas around SSSIs of international importance under the EU Directive on Habitats is unlikely to alleviate the problem, since the area involved remains minimal compared to the extent of the majority of catchments. Intensive agricultural practices are responsible for significant nutrient enrichment of rivers and lakes, so that legislation aimed at extensification is also relevant. Examples of agricultural extensification include the Environrnentally Sensitive Areas programme and various options available for Set-Aside land. However, the prime purpose of such initiatives is the alleviation of surplus and budgetary problems and, as such, they fall short of a fully integrated approach to the ecological management of farmland. Nutrient enrichment is, essentially, a water quality issue, but policy and legislation in this area are not yet sufficiently developed to address the problem comprehensively. The current regulatory process for water quality carries the potential to work comparatively well for point sources under the system of consents to discharge. This potential is limited, however, by the paucity of information available on ecologically acceptable concentrations of phosphorus in discharges. In addition, the consents system is not constructed to deal effectively with diffuse agricultural losses of phosphorus, since, unlike point sources, these tend to arise from the cumulative effect of many activities. The main legislative challenge for lake eutrophication control lies in the area of diffuse agricultural losses of phosphorus. In this respect, experience in the U.S.A. reveals that the use of comprehensive and catchment-wide ‘Best Management Practices’ is capable of producing significant water quality improvements, providing that some degree of mandatory compliance is incorporated.
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  • 96
    ISSN: 1573-5117
    Keywords: Scotland ; lochs ; eutrophication ; acidification ; toxic substances ; classification
    Source: Springer Online Journal Archives 1860-2000
    Topics: Biology
    Notes: Abstract The development of a national scheme for the standing waters of Scotland is described. It classifies waters along three gradients – phosphorus, loss of acid neutralising capacity and degree of contamination with toxic suubstances. A series of case studies provide examples of the application of the classification in lake management.
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  • 97
    ISSN: 1573-5117
    Keywords: Integrated lake management ; biomanipulation ; lake recovery ; phosphorus ; nitrogen ; eutrophication ; restoration
    Source: Springer Online Journal Archives 1860-2000
    Topics: Biology
    Notes: Abstract The majority of Danish lakes are highly eutrophic due to high nutrient input from domestic sources and agricultural activities. Reduced nutrient retention, and more rapid removal, in catchments as a result of agricultural drainage of wetlands and lakes and channelisation or culverting of streams also play a role. Attempts have recently been made to reduce nutrient loading on lakes by intervening at the source level and by improving the retention capacity of catchment areas. The former measures include phosphorus stripping and nitrogen removal at sewage works, increased use of phosphate-free detergents, and regulations concerning animal fertiliser storage capacity, fertiliser application practices, fertilisation plans and green cover in winter. In order to improve nutrient retention capacity of catchments, wetlands and lakes have been re-established and channelised streams have been remeandered. In addition, cultivation-free buffer strips have been established alongside natural streams and there has been a switch to manual weed control. These measures have resulted in a 73% reduction of the mean total phosphorus concentration of point-source polluted streams since 1978; in contrast, there has been no significant change in the total nitrogen concentration. Despite the major reduction in stream phosphorus concentrations, lake water quality has often not improved. This may reflect a too high external or internal phosphorus loading or biological resistance. Various physico-chemical restoration measures have been used, including dredging and oxidation of the hypolimnion with nitrate and oxygen. Biological restoration measures have been employed in 17 Danish lakes. The methods include reducing the abundance of cyprinids, stocking with 0+ pike ( Esox lucius) to control 0+ cyprinids, and promoting macrophyte recolonization by protecting germinal submerged macrophyte beds against grazing waterfowl and transplanting out macrophyte shoots. In several lakes, marked and long-lasting improvements have been obtained. The findings to date indicate that fish manipulation has a long-term effect in shallow lakes, providing nutrient loading is reduced to a level so low as to ensure an equilibrium lake water phosphorus concentration of less than 0.05–0.1 mg phosphorus l−1. If nitrogen loading is very low, however, positive results may be obtained at higher phosphorus concentrations. Macrophyte refuges and transplantation seem to be the most successful as restoration measures in the same nutrient-phosphorus regime as fish manipulation.
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  • 98
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    Hydrobiologia 395-396 (1999), S. 13-18 
    ISSN: 1573-5117
    Keywords: interdisciplinary science ; environmental politics ; eutrophication ; broads ; environmental valuation
    Source: Springer Online Journal Archives 1860-2000
    Topics: Biology
    Notes: Abstract Restoring lakes from a degraded state is a costly and risky enterprise. It is costly partly because ‘rewinding’ the cycles of degradation involves great scientific uncertainties. Therefore, the only way forward is by careful, expensive monitoring, and much adaptation of treatment as the evidence unfolds. This process requires much patience and political commitment. Therefore, the economic challenge is to find a relationship between the ecological exploration of restoration techniques and the economic justification of the outcome. Unfortunately, the basis of that justification is an economy that creates environmental degradation. So there is a cruel circularity in the economic appraisal: the process of benefit calculation is predicted on an economy that is, at present, non sustainable. This suggests that there should be another approach to economic valuation, based more on participatory processes of involving interests with a stake in the outcome and in the gains and losses that will inevitably be incurred in reaching the outcome of lake restoration. In that process, ecological science plays a vital role of explaining possible future pathways for restoration, and the dilemma of uncertainty is handled by creating various scenarios rather than models. The real challenge, therefore, is to devise a fair and full process of bargaining over lake futures, within which both ecology and economics play important, but subsidiary roles.
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  • 99
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    Hydrobiologia 395-396 (1999), S. 19-28 
    ISSN: 1573-5117
    Keywords: eutrophication ; lake ; management ; restoration ; Wisconsin
    Source: Springer Online Journal Archives 1860-2000
    Topics: Biology
    Notes: Abstract Lake degradation results from excessive nutrient inputs, toxic substances, habitat loss, overfishing, species invasions and extirpations. The scientific basis of lake degradation is generally well understood, although each restoration project requires some level of new site-specific research. Remediation may require management actions which are difficult to implement for social or institutional reasons. Even where large-scale remediations are attempted, it is difficult to sustain scientific assessments for long enough to evaluate success. Collaborations of scientists and managers have sometimes succeeded in overcoming limitations to lake restoration, and produced important advances in our capability to restore lakes.
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  • 100
    ISSN: 1573-5117
    Keywords: Phragmites ; eutrophication ; wetlands ; nutrient
    Source: Springer Online Journal Archives 1860-2000
    Topics: Biology
    Notes: Abstract In the frame of the research program EUREED (Effects of interaction between eutrophication and major environmental factors on the ecosystem stability of reed (Phragmites australis) vegetation in European land-water ecotones), three reed stands, established near Alcácer do Sal, Lagoa de Albufeira and Montargil, were studied. The stands were monitored monthly between December 1993 and December 1994 for productivity, soil and water chemistry. The relationship between the concentration of some metals in soil and water and its influence on the stability of the reed vegetation was studied. Environmental factors, such as salinity, negative redox potential on the root system and high Cu, Na and Zn concentrations in soil did not affect the normal development of reed vegetation and its capability to recover after mechanical damage.
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