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  • phosphorus  (43)
  • Springer  (43)
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  • 2005-2009
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  • 1992  (43)
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  • Springer  (43)
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  • 1
    ISSN: 1420-9055
    Keywords: Sediment ; interstitial water ; phosphorus ; iron ; persulfate digestion
    Source: Springer Online Journal Archives 1860-2000
    Topics: Biology
    Notes: Abstract It is shown that sorption of orthophosphate to iron compounds, formed during persulfate digestion, can cause a significant underestimation of total dissolved phosphorus in interstitial waters rich in iron and poor in phosphorus. Labelling the samples with carrier free32PO4 before digestion allows to correct for these losses.
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  • 2
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    Aquatic sciences 54 (1992), S. 58-76 
    ISSN: 1420-9055
    Keywords: Eutrophication ; lake management ; phosphorus ; nitrogen ; chlorophyll-a ; slope estimator
    Source: Springer Online Journal Archives 1860-2000
    Topics: Biology
    Notes: Abstract We estimate the response of chl-a (mg · m−3) to changes in concentrations of total phosphorus (TP) by calculating the slopeS = Δchl-a/ΔTP in chl-a =f(TP) graphs. Results show that in years where algae are P-limited oligotrophic lakes respond less (median slope 0.21) to changes in nutrient concentrations than eutrophic lakes, (median slope 0.31) and these again less than hypereutrophic lakes, (median slope 1.02). We find no saturation value for the slope within the TP range considered (6–480 mg · m−3). Chl-a in eutrophic lakes responds more frequently to non-nutrient factors than oligotrophic and hypereutrophic lakes. Results obtained by replacing TP with a new nutrient parameter, TP′ = 0.056 · TP · IN0.226, in which inorganic nitrogen, IN, is factored in, suggest that nitrogen has an influence on chl-a in oligotrophic lakes. Blue-green algae respond less to changes in TP than other algal species, e.g., diatoms.
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  • 3
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    Aquatic sciences 54 (1992), S. 381-390 
    ISSN: 1420-9055
    Keywords: Eutrophication ; phosphorus ; lake restoration ; internal restoration measures for lakes ; Swiss lakes ; Lake Lugano (Lago di Lugano)
    Source: Springer Online Journal Archives 1860-2000
    Topics: Biology
    Notes: Abstract In most lakes eutrophication is linked to an excessive input of phosphorus. Lake restoration by reduction of P-input (external measure) has led to a considerable drop of the P-concentration in all major Swiss lakes as well as in many other lakes. Internal restoration measures such as artificial mixing, drainage of hypolimnetic water, flushing, aeration, biomanipulation and others serve to improve and accelerate the response of a lake to external measures. For the case of Lago di Lugano, a simple two-box model is employed to demonstrate that a reduction of the P-input to about 25% of the present values is necessary to reach the “P-criterion” (P-concentration below 30 µg/l). Internal measures could possibly accelerate the extremely slow response of the northern basin.
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  • 4
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    Plant foods for human nutrition 42 (1992), S. 313-318 
    ISSN: 1573-9104
    Keywords: Iron availability ; phosphorus ; soil iron level ; ascorbic acid ; oxalic acid ; spinach
    Source: Springer Online Journal Archives 1860-2000
    Topics: Agriculture, Forestry, Horticulture, Fishery, Domestic Science, Nutrition
    Notes: Abstract In vitro availability of iron along with ascorbic acid, oxalic acid and phosphorus content of two varieties of spinach (Pusa Jyoti and Allgreen) cultivated in soil with different levels of added iron was determined. Addition of graded levels of iron to soil markedly increased the total iron and phosphorus contents and significantly decreased the bio-availability of iron, ascorbic acid and oxalic acid contents of spinach. Ascorbic acid and oxalic acid contents markedly exerted a positive influence while phosphorus exerted a negative influence on the bio-availability of iron.
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  • 5
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    Wetlands ecology and management 1 (1992), S. 211-222 
    ISSN: 1572-9834
    Keywords: freshwater marsh ; freshwater wetland ; Great Lakes ; hydrology ; phosphorus ; water quality
    Source: Springer Online Journal Archives 1860-2000
    Topics: Biology
    Notes: Abstract A coastal wetland along Lake Erie (Ohio, U.S.A.) was studied to determine hydrologic and phosphorus budgets and spatial and temporal variation of phosphorus and related chemical parameters. The wetland was influenced by changing Lake Erie water levels, seiches, shifting shoreline sediments, and watershed inflow during a year of severe drought. The water budget for a 7-month period (March – September, 1988) had average inflow of 15 200 m3 day−1 from the watershed and 3.5 m3 day−1 from Lake Erie. The wetland increased in volume by 700 m3 day−1 despite a drought that resulted in 80% more evapotranspiration than rainfall as a barrier beach isolated the wetland from Lake Erie for 77% of the study period. Conductivity decreased by 34% as water flowed through the wetland and turbidity and total suspended solids were variable and statistically similar at inflow and outflow. Average total phosphorus concentrations in the inflow and outflow were also similar (247 and 248 µg P l−1 respectively) although total soluble phosphorus and soluble reactive phosphorus decreased significantly (α=0.05) from inflow to outflow (averages 94 to 45 µg P l−1 and 7.5 to 4.0 µg P l−1 respectively). Nutrient budgets from field data estimate a retention of 36% of the phosphorus, presumably in the sediments (0.8 mg P m−2 day−1). A general nutrient retention model, an estimated deposition rate from a sediment core and a simulation model predicted higher mass retention of phosphorus but similar percentage retention. Sommaire Un marecage qui côtoie le lac Erie (USA) a servi de site expérimental pour en déterminer les budgets d'eau et de phosphore, de même que pour la variation spatiale et temporelle du phosphore et d'autres facteurs chimiques. Le marécage a été influencé par: niveaux d'eau qui changeaient; seiches; sédiments mouvants du littoral; et afflux de la ligne de partage des eaux dans une année de grande sécheresse. Le budget d'eau dans une période de 7 mois (mars–septembre 1988) montre un afflux de 15 200 m3 jour−1 de la ligne de partage, et 3.5 m3 jour−1 du lac Erie. Le volume du marécage a augmenté par 700 m3 jour−1 malgré une sécheresse qui a produit plus d'évapotranspiration (80%) que de pluie pendant qu'une plage-obstacle a isolé le marecage du lac Erie pendant 77% de la période d'observation. La conductivité a diminué par 34% pendant que l'eau coulait, et la turbidité et les TSS ont varié, tout en démontrant des statistiques similaires à l'afflux et au déversement. Les moyennes pour les concentrations du total du phosphore à l'afflux et au déversement ont été similaires (247 and 248 µg P l−1), quoique le TSP et le SRP ont diminué (α=0.05) de l'afflux au déversement (donant des moyennes de 94 à 45 µg P l−1 et de 7.5 à 4.0 µg P l'−1). Les budgets de substances nutritives pour les données suggèrent une reténtion de 36% du phosphore, évidemment dans les sédiments (0.8 mg P m−2 jour−1). Un modèle pour la rétention des nutrients, un taux de déposition, estimé par un noyau de sédiments, et une simulation avaient prédit un plus grand taux de rétention de phosphore, mais un pourcentage similaire pour la rétention.
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  • 6
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    Wetlands ecology and management 1 (1992), S. 239-247 
    ISSN: 1572-9834
    Keywords: biomass ; carbohydrates ; nitrogen ; phosphorus ; Phragmites australis ; potassium ; reed ; rhizome ; translocation ; wetland
    Source: Springer Online Journal Archives 1860-2000
    Topics: Biology
    Notes: Abstract Seasonal changes in rhizome concentrations of total nonstructural carbohydrates (TNC), water soluble carbohydrates (WSC), and mineral nutrients (N, P and K) were monitored in two Phragmites australis stands in southern Sweden. Rhizome biomass, rhizome length per unit ground area, and specific weight (weight/ length ratio) of the rhizomes were monitored in one of the stands. Rhizome biomass decreased during spring, increased during summer and decreased during winter. However, changes in spring and summer were small (〈 500 g DW m-2) compared to the mean rhizome biomass (approximately 3000 g DW m−2). Winter losses were larger, approximately 1000 g DW m-2, and to a substantial extent involved structural biomass, indicating rhizome mortality. Seasonal changes in rhizome length per unit ground area revealed a rhizome mortality of about 30% during the winter period, and also indicated that an intensive period of formation of new rhizomes occurred in June. Rhizome concentrations of TNC and WSC decreased during the spring, when carbohydrates were translocated to support shoot growth. However, rhizome standing stock of TNC remained large (〉 1000 g m−2). Concentrations and standing stocks of mineral nutrients decreased during spring/ early summer and increased during summer/ fall. Only N, however, showed a pattern consistent with a spring depletion caused by translocation to shoots. This pattern indicates sufficient root uptake of P and K to support spring growth, and supports other evidence that N is generally the limiting mineral nutrient for Phragmites. The biomass data, as well as increased rhizome specific weight and TNC concentrations, clearly suggests that “reloading” of rhizomes with energy reserves starts in June, not towards the end of the growing season as has been suggested previously. This resource allocation strategy of Phragmites has consequences for vegetation management. Our data indicate that carbohydrate reserves are much larger than needed to support spring growth. We propose that large stores are needed to ensure establishment of spring shoots when deep water or stochastic environmental events, such as high rhizome mortality in winter or loss of spring shoots due to late season frost, increase the demand for reserves.
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  • 7
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    Journal of chemical ecology 18 (1992), S. 2095-2105 
    ISSN: 1573-1561
    Keywords: Allelopathy ; Schizachyrium scoparium ; Ceratiola ericoides ; hydrocinnamic acid ; nitrogen ; phosphorus ; potassium ; fire ; sand pine scrub ; sandhill
    Source: Springer Online Journal Archives 1860-2000
    Topics: Biology , Chemistry and Pharmacology
    Notes: Abstract Bare zones around shrubs in the Florida scrub indicate the possibility of allelopathy by shrubs controlling the distribution of grasses invading from adjacent sandhills. The allelochemical, hydrocinnamic acid, has been identified as a breakdown product of ceratiolin, which is released from the shrubCeratiola ericoides. Here, hydrocinnamic acid (HCA) was shown to have a strongly inhibitory effect on shoot and root biomass of the grassSchizachyrium scoparium in greenhouse bioassays lasting 4.5 months. Linear increases in the concentration of HCA from 0 to 200 ppm, applied biweekly, resulted in exponential decreases in root and shoot biomass at harvest. Plants grown at 200 ppm HCA had root and shoot biomasses 13% and 17% of controls, respectively. Concurrent investigation of reduced nutrient levels indicated greater inhibition by HCA in a reduced nitrogen (N) treatment and in a reduced potassium (K) treatment relative to HCA inhibition in the full nutrient treatment. The negative slopes of the regressions of log of biomass on HCA concentration were steepest in the reduced N and reduced K treatments. Root and shoot biomasses in reduced N treatments were 20–43% and 24–34% less than the respective biomasses in the full nutrient treatment. Comparable reductions in the reduced K treatment were as much as 19% and 10% for root and shoot biomasses, respectively. The effects of HCA in a reduced phosphorus (P) treatment and in a reduced P and K treatment were not significantly different from the effects of HCA in the full nutrient treatment. Extraction of the soils at harvest indicated no buildup of HCA at the end of the experiment. The sensitivity ofSchizachyrium scoparium to HCA in general and increased sensitivity under low N and low K solutions may be important in the Florida scrub community where levels of N and K are known to be low.
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  • 8
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    Nutrient cycling in agroecosystems 31 (1992), S. 15-19 
    ISSN: 1573-0867
    Keywords: Tillage ; crop rotation ; cereal grain ; wheat ; nitrogen ; sulfur ; phosphorus ; no-till
    Source: Springer Online Journal Archives 1860-2000
    Topics: Agriculture, Forestry, Horticulture, Fishery, Domestic Science, Nutrition
    Notes: Abstract Efficient fertilizer use is a prerequisite for achieving optimum crop yield while avoiding environmental contamination. Cereal response to nitrogen (N), sulfur (S), and phosphorus (P) were determined for 6 years under differing tillage [conventional-till (CT) vs. no-till (NT)] and intensity of cropping (cereal/fallow vs. cereal/cereal). Semidwarf white winter wheat (Triticum aestivum L.) alternated yearly with either fallow or spring cereal [barley (Hordeum vulgare L.) or spring wheat] on a Typic Haploxeroll soil in a 415 mm rainfall zone. Fertilizer treatments were no fertilizer (None), N only (N), N plus S (NS), and N plus S plus P (NSP). Average application rate, when applied, was 109 kg N, 18 kg S, and 11 kg P ha−1. Average cereal yield without fertilizer was 1.82 t ha−1. Nitrogen increased grain yield in 6 of 6, S in 4 of 6, and P in 3 of 6 years, with P and S response significant the remaining years at the 10% probability level. Average yield increases were 1.11 t ha−1 for N, 0.93 t ha−1 for S, and 0.47 t ha−1 for P. The NT/CT yield ratio was 0.60, 0.75, 0.93, and 0.95 with None, N, NS, and NSP addition, respectively, indicating that N and S deficiency were more severe in no-till. Limited increase in the NT/CT ratio with P addition indicated that P deficiency was less affected by tillage. Winter wheat always yielded less under NT than CT regardless of fertility, whereas spring cereals reached equality when fertilized with NSP. Annually-cropped wheat yielded 52, 67, 89, and 90% of wheat after fallow with None, N, NS, and NSP, respectively. Thus N and S, but not P, deficiency was more intense with increased frequency of cropping. Adequate fertility was a prime prerequisite for efficient yield in all systems.
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  • 9
    ISSN: 1573-0867
    Keywords: manure ; Niger ; phosphorus ; Sahelian soils ; stochastic dominance framework
    Source: Springer Online Journal Archives 1860-2000
    Topics: Agriculture, Forestry, Horticulture, Fishery, Domestic Science, Nutrition
    Notes: Abstract Poor fertility status of sandy Sahelian soils represents a major constraint to cereal and legume production. Soil amendment options were evaluated, using a stochastic efficiency framework. Dominance analyses showed that in the presence of annual applications of 30 kg N ha−1 and 30 kg K ha−1, efficient soil amendment options comprise of either the annual application of 8.7 kg P ha−1 in the form of single superphosphates in combination with 5 tonnes manure ha−1 applied every three years or the annual application of 17.5 kg P ha−1 in the form of single superphosphates. Choice between these two efficient options depends on the availability of manure, deficiencies in sandy soils and farmer resource endowments.
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  • 10
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    Nutrient cycling in agroecosystems 32 (1992), S. 223-227 
    ISSN: 1573-0867
    Keywords: Soil testing ; phosphorus ; relative yield
    Source: Springer Online Journal Archives 1860-2000
    Topics: Agriculture, Forestry, Horticulture, Fishery, Domestic Science, Nutrition
    Notes: Abstract A greenhouse experiment, with Okra (Abelmoschus esculentus L.) as the test crop, was conducted on twenty-one soils ranging in Olsen's extractable phosphorus from 1.8 to 15.5µg Pg−1 soil. The experiment was conducted at Punjab Agricultural University, Ludhiana, India. The soils were nonsaline with pH ranging from 7.7 to 8.6. A critical level of 2.55µg Pg−1 soil was predicted by Cate and Nelson's (1971) statistical procedure. Because of a wide range in relative yields, this value did not accurately predict response to applied P. An approach to compute minimum response to applied fertilizer, which is likely to be obtained at a particular Olsen P level, has been presented. It involves calculation of lower 60 percent confidence limits for relative yield and fitting loge-linear regression to the transformed data. The regression was tested on a published data set and was found to hold well.
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  • 11
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    Nutrient cycling in agroecosystems 32 (1992), S. 259-267 
    ISSN: 1573-0867
    Keywords: Nitrogen ; phosphorus ; timber increment ; fertilization ; Pinus radiata
    Source: Springer Online Journal Archives 1860-2000
    Topics: Agriculture, Forestry, Horticulture, Fishery, Domestic Science, Nutrition
    Notes: Abstract Two trials inPinus radiata growing on different sites in N.S.W. allowed consideration of fertilizer applications after 2nd or 3rd thinning. The trials included factorial applications of N and P at a single thinning intensity plus a further treatment which allowed assessment of different thinning intensities. The most significant growth responses were obtained by application of N and P in combination. The largest response (additional productivity compared with the unfertilized control) occurred 4 years after application and after 7 years there was no additional absolute response for either of the two sites. The largest fertilizer response was 70 m3 ha−1 over 7 years on one site and 36 m3 ha−1 on the other, indicating differences in absolute responses between sites. It was concluded that in planning treatments the most responsive sites near the end of the rotation should be selected to maximise economic returns. Foliage analyses indicated differences between sites at the commencement of the study. It was concluded that either a single year of foliage analyses at study commencement is of value, or sampling every year of the study should be used to analyse responses, but a single year of analysis during or at the end of the study would not be of value.
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  • 12
    ISSN: 1573-515X
    Keywords: nitrogen ; phosphorus ; soil fertility ; tropical forest
    Source: Springer Online Journal Archives 1860-2000
    Topics: Chemistry and Pharmacology , Geosciences
    Notes: Abstract We measured concentrations of soil nutrients (0–15 and 30–35 cm depths) before and after the dry season in control and dry-season irrigated plots of mature tropical moist forest on Barro Colorado Island (BCI) in central Panama to determine how soil moisture affects availability of plant nutrients. Dry-season irrigation (January through April in 1986, 1987, and 1988) enhanced gravimetric soil water contents to wet-season levels (ca. 400 g kg−1 but did not cause leaching beyond 0.8 m depth in the soil. Irrigation increased concentrations of exchangeable base cations (Ca2+, Mg2+, K+, Na+), but it had little effect on concentrations of inorganic N (NH4 +C, NO3 − and S (SO4 2−). These BCI soils had particularly low concentrations of extractable P especially at the end of the dry season in April, and concentrations increased in response to irrigation and the onset of the rainy season. We also measured the response of soil processes (nitrification and S mineralization) to irrigation and found that they responded positively to increased soil moisture in laboratory incubations, but irrigation had little effect on rates in the field. Other processes (plant uptake, soil organic matter dynamics) must compensate in the field and keep soil nutrient concentrations at relatively low levels.
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  • 13
    ISSN: 1573-5036
    Keywords: nitrogen ; phosphorus ; root: shoot ratios ; secondary succession ; semiarid ; shrubland ; tissue nitrogen ; tissue phosphorus
    Source: Springer Online Journal Archives 1860-2000
    Topics: Agriculture, Forestry, Horticulture, Fishery, Domestic Science, Nutrition
    Notes: Abstract Above- and below-ground biomass production, nitrogen (N) and phosphorus (P) tissue concentrations, and root: shoot ratios were examined for five species that are characteristic of a semiarid successional sequence under controlled greenhouse conditions. In two simultaneous experiments, seedlings of one forb, two grass, and two shrub species important in a sagebrush successional sere, were subjected to seven levels of N and P. Results of the experiments suggest distinct differences in nutrient response patterns between early and late seral species. Early seral species produced more biomass but had lower tissue nutrient concentrations than late seral species. As N and P availabilities decreased, late seral species displayed characteristics indicative of increasing competitive advantage over those of early seral species. Root: shoot ratios of the five species primarily reflected patterns related to lifeform, but with some early and late seral characteristics. Results from this study 1) confirm that nutrient use pattern, nutrient availability, and seral position relationships characteristic of mesic ecosystems hold equally true for semiarid systems, and 2) suggest that nutrients are important organizing factors in semiarid ecosystems.
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  • 14
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    Plant and soil 142 (1992), S. 157-166 
    ISSN: 1573-5036
    Keywords: Acacia ; Eucalyptus regnans ; decomposition ; litterfall ; nitrogen ; phosphorus
    Source: Springer Online Journal Archives 1860-2000
    Topics: Agriculture, Forestry, Horticulture, Fishery, Domestic Science, Nutrition
    Notes: Abstract The N and P contents of the litter layer and the return of these nutrients in litterfall were measured in seven stands of Mountain Ash (Eucalyptus regnans) ranging in age from 5 years to about 250 years. Both annual litterfall and nutrient return were correlated with stand basal area and were high compared with other productive eucalypt forests. In contrast, the fall of dead eucalypt leaves was constant with stand age, demonstrating that sites are fully occupied at an early age. Similarly, amounts of N and P in total leaf fall (overstorey plus understorey) were constant with stand age, except for low amounts in the stand aged 40 years where Acacia spp., important fixers of atmospheric N, were not prevalent. The decomposition constant (k) of organic matter in the litter layer decreased with stand age, from 0.31 year-1 at age 5 years to 0.23 year-1 at age 250 years. These constants also applied to N and P, indicating a tight coupling between organic matter decomposition and release of these nutrients from litter. The litter layer released about 30 kg ha-1 of N at age 5 years, and about 70 kg ha-1 at age 80 years. These results are discussed in relation to growth of Mountain Ash following fire, and the subsequent retention and accumulation of N during stand development.
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  • 15
    ISSN: 1573-5036
    Keywords: critical concentration ; deficiency ; diagnosis ; growth rate ; lettuce ; luxury consumption ; nitrogen ; nitrate ; nutrient requirement ; petiole sap ; phosphorus ; phosphate ; potassium
    Source: Springer Online Journal Archives 1860-2000
    Topics: Agriculture, Forestry, Horticulture, Fishery, Domestic Science, Nutrition
    Notes: Abstract A method is described for determining the way in which growth rate varies with plant nutrient concentration using a simple nutrient interruption technique incorporating only 2 treatments. The method involves measuring the changes in growth and nutrient composition of otherwise well-nourished plants after the supply of one particular nutrient has been withheld. Critical concentrations are estimated from the relationship between the growth rate (expressed as a fraction of that for control plants of the same size which remained well-nourished throughout) and the concentration of the growth-limiting nutrient in the plants as deficiency developed. Trials of the method using young lettuce plants showed that shoot growth rate was directly proportional to total N (nitrate plus organic N) concentration, and linearly or near-linearly related to K and P concentration over a wide range; the corresponding relationship for nitrate was strongly curvi-linear. Critical concentrations (corresponding to a 10% reduction in growth rate) determined from these results were similar to critical values calculated from models derived from field data, but were generally higher than published estimates of critical concentration (based on reductions in shoot weight) for plants of a similar size. Reasons for these discrepancies are discussed. Nitrate, phosphate or potassium concentrations in sap from individual leaf petioles were highly sensitive to changes in shoot growth rate as deficiency developed, with the slope of the relationships varying with leaf position, due to differences both in their initial concentration and in the rates at which they were utilized in individual leaves. Each nutrient was always depleted more quickly in younger leaves than in older ones, providing earlier evidence of deficiency for diagnostic purposes. Although the plants were capable of accumulating nitrate, phosphate and potassium well in excess of that needed for optimum dry matter production during periods of adequate supply, the rate of mobilization of these reserves was insufficient to prevent reductions in growth rate as the plants became deficient. This brings into question the validity of the conventional concept that luxury consumption provides a store of nutrients which are freely available for use in times of shortage. The implications of these results for the use of plant analysis for assessing plant nutrient status are discussed.
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  • 16
    ISSN: 1573-5036
    Keywords: cultivars ; grains ; maize ; nitrogen ; phosphorus ; potassium ; tropical climate
    Source: Springer Online Journal Archives 1860-2000
    Topics: Agriculture, Forestry, Horticulture, Fishery, Domestic Science, Nutrition
    Notes: Abstract An earlier study revealed considerable genotypic variation in grain N, P and K concentrations (GNC, GPC and GKC, respectively) in tropical maize. The expression of varietal differences in GNC, GPC and GKC, however, may depend on environmental conditions such as the N status of the soil. Two tropical maize hybrids (Suwan 2301 and CP 1) with comparable yielding capacity, but contrasting GNCs, GPCs and GKCs, were therefore grown at four levels of N in a field experiment at Farm Suwan (Thailand, latitude 14.5°N). Suwan 2301 exhibited a higher GNC than did CP 1 at all rates of N, but large differences in GPC and GKC were found only at high N fertilization. This was obviously due to individual grain yield responses of the cultivars to increasing rates of N fertilizer, demonstrating that grain nutrient concentrations are, at least in part, functions of the amount of grain carbohydrates which dilute a genetically and environmentally fixed amount of grain P and K. As compared to Suwan 2301, CP 1 accumulated less N, P and K in the grains at almost all levels of N fertilization, confirming our hypothesis that the cultivation of maize genotypes with low grain mineral nutrient concentrations may help third-world cash-crop farmers to reduce the need for scarce and costly mineral fertilizers. This finding has to be verified at reduced availability of soil −P, −K, and water.
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  • 17
    ISSN: 1573-515X
    Keywords: nitrogen fixation ; phosphorus ; internal loading ; water hyacinth ; floodplain ; Paraná ; flood-pulse hypothesis
    Source: Springer Online Journal Archives 1860-2000
    Topics: Chemistry and Pharmacology , Geosciences
    Notes: Abstract Some aspects of nutrient status and dynamics prevailing during low and high water conditions in the fringing floodplain ponds of the Paraná River dominated by the floating macrophyte Eichhornia crassipes are described. During summertime low water conditions, low DIN:DRP ratios (0.16–1.0) and low DIN (0.5–4.8 μmol.liter−1) in the root-zone of the floating meadows suggest that macrophyte growth is limited by nitrogen. DRP concentrations appear to be controlled more by abiotic sorption-dissolution than by biological reactions. Preflood nutrient fluxes from the sediments, as estimated from porewater profiles, show that a minimum of 1.19 and 0.38 mmol.m−2.d−1 of DIN and DRP were regenerated from the sediments, respectively. Heterotrophic N2 fixation is primarily associated with decaying litter (0.4 to 3.2 μmolN2.g−1.d−1). Nutrient recycling from sediments and meadow-litter, and heterotrophic N2 fixation (1.4 mmolN.m−2.d−1) appear sufficient to sustain high floating macrophyte productivity for long periods of time, without invoking large inputs from the river. The high water and early isolation periods are characterized by a very dynamic behavior of DIN, reflecting marked imbalances between N supply and demand by the biota. After hydrologic isolation of the ponds, DIN rapidly decreases to undetectable levels and stays low for the following 3 weeks, presumably as a result of high demand by phytoplankton and sediment bacteria. DIN increases again to high values 3–8 weeks after the flood, following the re-establishment of NH4 + fluxes from the sediments. Compared to DIN, DRP concentrations remain relatively high and change little during and after the flood. Because of their small amplitude and short duration, floods do not appear to stimulate floating macrophyte production in the Paraná.
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  • 18
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    Biogeochemistry 18 (1992), S. 19-35 
    ISSN: 1573-515X
    Keywords: Dinitrogen fixation ; nitrogen ; phosphorus ; competition ; legumes
    Source: Springer Online Journal Archives 1860-2000
    Topics: Chemistry and Pharmacology , Geosciences
    Notes: Abstract An analysis of data compiled from the literature confirms a strong inverse relationship between annual rates of nitrogen fixation and the soil nitrogen content in agricultural and pastoral ecosystems. However, this inverse relationship is strongly modified by the rate of application of phosphorus fertilizer, which strongly influences the activities of both symbiotic and non-symbiotic nitrogen fixing organisms. In the case of symbiotic legumes, the response of N-fixation to N and P is in part a result of changes in legume dominance within the plant community. These results, as well as supporting data presented from a review of experiments on nitrogen fixation in a variety of other terrestrial and aquatic ecosystems, provide important support for the hypothesis that phosphorus availability is a key regulator of nitrogen biogeochemistry.
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  • 19
    ISSN: 1573-515X
    Keywords: algae ; nitrogen ; nutrient ; phosphorus ; regeneration ; zooplankton
    Source: Springer Online Journal Archives 1860-2000
    Topics: Chemistry and Pharmacology , Geosciences
    Notes: Abstract Most ecosystem models consolidate members of food-webs, e.g. species, into a small number of functional components. Each of these is then described by a single state variable such as biomass. When a multivariate approach incorporating multiple substances within components is substituted for this univariate one, a ‘stoichiometric’ model is formed. Here we show that the Nitrogen:Phosphorus ratio within zooplankton herbivores varies substantially intraspecifically but not intraspecifically. By using stoichiometric theory and recent measurements of the N:P ratio within different zooplankton taxa, we calculate large differences in ratios of nutrients recycled by different zooplankton species. Finally, we demonstrate that N:P stoichiometry can successfully account for shifts in N- and P-limitation previously observed in whole-lake experiments. Species stoichiometry merges food-web dynamics with biogeochemical cycles to yield new insights.
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  • 20
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    Hydrobiologia 233 (1992), S. 225-233 
    ISSN: 1573-5117
    Keywords: ditches ; fish stock ; dredging ; biomanipulation ; eutrophication ; phosphorus
    Source: Springer Online Journal Archives 1860-2000
    Topics: Biology
    Notes: Abstract In the polder ‘Wormer, Jisp and Nek’, which forms part of a grossly eutrophicated region in the province North Holland, the effects of dredging and biomanipulation were studied in ditches. Four areas, including 5.7 ha surface water in total, were dammed up and dredged. It was feasible to remove the loose top-layer of sediments with a high content of phosphorus by modifications of the dredging machine. In two areas the fish stock was managed. The measures resulted in an improvement of the water quality: an increase of the transparency and a decrease of suspended solids, phosphorus, nitrogen and algae. The chlorophyll-a concentration decreased nearly to 100 µg l−1 (summer average). The relative densities of diatoms, green algae and cyanobacteria did not change. The zooplankton community was dominated by small rotifers and crustaceans both before and after restoration measures. Cladocerans were scarcely present. In the second year after the measures, submerged macrophytes developed.
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  • 21
    ISSN: 1573-5117
    Keywords: River Rhine ; phytoplankton ; suspended material ; carbon ; nitrogen ; phosphorus
    Source: Springer Online Journal Archives 1860-2000
    Topics: Biology
    Notes: Abstract The spatial and temporal distribution of element concentrations were monitored together with chlorophyll a as an indicator of algal density to assess the effect of phytoplankton on the elemental composition (C, N, P) of suspended materials in the lower Rhine. The high concentrations of particulate C, N and P in the river were found to decrease in the delta and to increase again in the estuarine turbidity zone. Phytoplankton blooms increased the concentrations of particulate C, N, and P significantly in the upstream part of the river. In summer 1989, 15–65% of the particulate C and 20–75% of the particulate N were attributable to phytoplankton. Together with published data these observations indicate that in eutrophic rivers, the input of organic materials from the catchment is strongly modified and supplemented by in situ growth of phytoplankton. During seaward transport the phytoplankton and the particulate elements disappeared from the river water concomitantly with the suspended matter, indicating an increased retention of these elements due to sedimentation. In contrast, soluble ammonia, nitrite and phosphate increased in the tidal reaches of the river because of local input in the harbour and city of Rotterdam and because of mineralization. Therefore the total nutrient load of the Rhine estimated at the German/Dutch border does not reflect the actual input into the sea.
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  • 22
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    Hydrobiologia 240 (1992), S. 45-59 
    ISSN: 1573-5117
    Keywords: arctic lakes ; trace metals ; lake sediments ; manganese ; iron ; phosphorus ; sediment-water flux ; diagenesis ; Toolik Lake
    Source: Springer Online Journal Archives 1860-2000
    Topics: Biology
    Notes: Abstract The sediments within Toolik Lake in arctic Alaska are characterized by extremely low rates of organic matter sedimentation and unusually high concentrations of iron and manganese. Pore water and solid phase measurements of iron, manganese, trace metals, carbon, nitrogen, phosphorus, and sulfur are consistent with the hypothesis that the reduction of organic matter by iron and manganese is the most important biogeochemical reaction within the sediment. Very low rates of dissolved oxygen consumption by the sediments result in an oxidizing environment at the sediment-water interface. This results in high retention of upwardly-diffusing iron and manganese and the formation of metal-enriched sediment. Phosphate in sediment pore waters is strongly adsorbed by the metal-enriched phases. Consequently, fluxes of phosphorus from the sediments to overlying waters are very small and contribute to the oligotrophic nature of the Toolik Lake aquatic system. Toolik Lake contains an unusual type of lacustrine sediment, and in many ways the sediments are similar to those found in oligotrophic oceanic environments.
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  • 23
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    Hydrobiologia 243-244 (1992), S. 395-403 
    ISSN: 1573-5117
    Keywords: Lake Päijänne ; pulp mills ; BOD ; phosphorus ; water quality
    Source: Springer Online Journal Archives 1860-2000
    Topics: Biology
    Notes: Abstract Lake Päijänne, the second largest lake in Finland, has been seriously polluted since the 1960s due to the effluents from pulp and paper mills, notably the Äänekoski sulphate and sulphite pulp mills situated about 50 km north of the lake, and the sulphite pulp mill and paper mills of Jämsänkoski and Kaipola on Central Lake Päijänne. A sulphite lye evaporation and combustion plant installed at the Jämsänkoski sulphite pulp mill in 1969 reduced the organic pollution of Central Päijänne. Lignin concentration decreased and the oxygen balance improved. The sulphite pulp mill was closed in 1981 and replaced by a thermo-mechanical pulp mill. Eutrophication is the main threat to water quality in Central Lake Päijänne at present. A significant improvement in the water quality, especially in oxygen balance, was achieved in the watercourse of Äänekoski and in Northern Päijänne after replacement of the old sulphite and sulphate pulp mills at Äänekoski by a large sulphate pulp mill with a biological purification plant employing the activated sludge method. The BOD7-loading dropped from 46 to 3–4 t d−1, but the nutrient loading has not decreased sufficiently, and the Äänekoski watercourse and Northern Päijänne are still eutrophic.
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  • 24
    ISSN: 1573-5117
    Keywords: eutrophication ; lake restoration ; flushing ; Veluwemeer ; algal species ; transparency ; phosphorus ; nitrogen
    Source: Springer Online Journal Archives 1860-2000
    Topics: Biology
    Notes: Abstract Total phosphorus and chlorophyll decreased significantly after reduction of the external phosphorus loading and the start of flushing Veluwemeer with polder water in 1979. Flushing of Veluwemeer has had a large impact on nutrient dynamics. Especially in the first winter, dilution was the main cause of changes in water quality. On a longer term the increase of the inactivation of phosphorus in sediments is important. Oscillatoria agardhii has been brought to the margins of its habitat. Three successive cold winters were an additional causal factor in the disappearance of Oscillatoria agardhii and the dominance of diatoms and green algae from 1985 onwards. Due to higher detritus and inorganic suspended matter concentrations transparency increased less than expected. Since 1985 chlorophyll only contributes for a small percentage to the transparency. In the present situation further improvement of the water quality of Veluwemeer is questionable, as the phosphorus concentration in the lake and the polder water is almost the same. Therefore it is recommanded to shift flushing operations, at least in the winter period, from Veluwemeer towards Wolderwijd.
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  • 25
    ISSN: 1573-5117
    Keywords: eutrophication ; lake restoration ; phosphorus ; sediments ; internal loading ; chemomanipulation
    Source: Springer Online Journal Archives 1860-2000
    Topics: Biology
    Notes: Abstract After a reduction of the external phosphorus loading to a lake, an internal loading from the sediments may delay the improvement of the water quality. The accepted method to combat internal loading is careful dredging of the upper sediment layers (Cooke et al., 1986), but this method is costly and time consuming. Addition of phosphorus binding agents to the sediments might offer an alternative. In the Netherlands the use of aluminum compounds, the most common phosphorus binding agent, for water quality improvement purposes is not favoured. Therefore a sediment treatment with a solution of iron(III)chloride was tested. Iron was chosen because it is considered to be a natural binder of phosphate. 100 g m−2 of Fe3+ were added to the sediments of the shallow (1.75 m average depth) and eutrophic Lake Groot Vogelenzang (The Netherlands) in October and November 1989. The iron(III)chloride solution was diluted 100 times with lake water and mixed with the surface sediments with a water jet. Following the addition the concentrations of total phosphorus (Fig. 1), chlorophyll-a and suspended solids decreased. This improvement of the water quality lasted for three months. After this time the total phosphorus concentration increased again, but remained at a lower level than in spring and summer of 1989. The phosphorus release rate from the sediments as measured from intact sediment cores decreased from 4 to 1.2 mg P m−2 d−1 (n = 5), and the bioavailability of the sediment phosphorus, as measured with bioassays, decreased from 34 to 23% (n = 5) shortly after the treatment. One year after the treatment the release rate was increased to 3 mg P m−2 d−1 (n = 5). Before treatment, the lake was thought to have a residence time of over one year. However, the chloride added to the lake disappeared according to a dilution rate of 0.03 d−1 or a retention time of about 35 days. A high external loading due to rapid flushing with phosphorus-rich water from surrounding lakes possibly prevented a more durable improvement in water quality. Another possibility is that the iron addition has lost its phosphate binding capacity due to reduction or binding with other anions like carbonate or sulphide. Therefore the suitability of the method to reduce internal loading and especially the long term availability of added iron to bind phosphorus needs additional proof. The treatment of the 18 ha area of Lake Groot Vogelenzang took three weeks. The operational costs were about US$ 125000. This is fast and cheap compared to dredging. Application of the technique is limited to those cases where the sediments are not polluted with micro-pollutants and the water depth need not be increased.
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  • 26
    ISSN: 1573-5117
    Keywords: model ; simulation ; eutrophication ; phosphorus ; P/C ratio ; lake ecosystem
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    Topics: Biology
    Notes: Abstract The phosphorus cycle in the ecosystem of the shallow, hypertrophic Loosdrecht lakes (The Netherlands) was simulated by means of the dynamic eutrophication model PCLOOS. The model comprises three algal groups, zooplankton, fish, detritus, zoobenthos, sediment detritus and some inorganic phosphorus fractions. All organic compartments are modelled in two elements, carbon and phosphorus. Within the model system, the phosphorus cycle is considered as completely closed. Carbon and phosphorus are described independently, so that the dynamics of the P/C ratios can be modelled. The model has been partly calibrated by a method based on Bayesian statistics combined with a Range Check procedure. Simulations were carried out for Lake Loosdrecht for the periods before and after the restoration measures in 1984, which reduced the external phosphorus loading to the lake from ca. 2 mgP m−2 d−1 to 1 mgP m−2 d−1. The model outcome was largely comparable withthe measured data. Total phosphorus has slowly decreased from an average 130 µgP l−1 to ca. 80 µgP l−1, but chlorophyll-a (ca. 150 µg 1−1, summer-averaged) and seston concentrations (8–15 mgC 1−1) hardly changed since the restoration measures. About two-thirds of the seston consisted of detritus, while the phytoplankton remained dominated by filamentous cyanobacteria. The P/C ratio of the seston decreased from ca. 1.0% to 0.7%, while the P/C ratios of zooplankton, zoobenthos and fish have remained constant and are much higher. The system showed a delayed response to the decreased phosphorus loading until a new equilibrium was reached in ca. five years. Major reasons for the observed resilience of the lake in responding to the load reduction are the high phosphorus assimilation efficiency of the cyanobacteria and the high internal recycling of phosphorus. A further reduction of nutrient loading, perhaps in combination with additional measures like biomanipulation, will be the most fruitful additional restoration measure.
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  • 27
    ISSN: 1573-5117
    Keywords: Microcystis ; microbial activity ; sediment ; phosphorus ; internal loading
    Source: Springer Online Journal Archives 1860-2000
    Topics: Biology
    Notes: Abstract Variations in microbial biomass and activity in the sediments of hypereutrophic Lake Vallentunasjön were followed during a period of 5 years. The data were compared to the calculated release of phosphorus from the sediments during the same period. A strong co-variation was found between biomass of Microcystis, heterotrophic bacterial activity in the sediments and internal phosphorus loading. These parameters exhibited mainly a declining trend during the investigation period. A pronounced stability of the sediment chemistry, including the fractional composition of the sediment phosphorus, during the studied period indicates that microbial activity affected the phosphorus release from the sediments. Calculations of the percentage of sediment bacteria that was associated to the mucilage of Microcystis colonies imply, together with the specific bacterial production, that Microcystis in the sediment stimulates bacterial production. In the highly phosphorus-saturated sediments of Lake Vallentunasjön this would ultimately lead to an increased release of phosphorus from the sediment. Lake Vallentunasjön does not follow the common pattern of recovery after reduction of external phosphorus loading. The large biomasses and long survival of Microcystis in the sediment are probably important reasons for the delayed recovery of the lake.
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  • 28
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    Hydrobiologia 235-236 (1992), S. 585-596 
    ISSN: 1573-5117
    Keywords: estuary ; iron ; phosphorus ; organic carbon ; aggregation ; sedimentation
    Source: Springer Online Journal Archives 1860-2000
    Topics: Biology
    Notes: Abstract The turnover of iron, phosphorus and organic carbon was followed in the Öre Estuary, northern Sweden, during the spring flood periods of 1989 and 1990. River-supplied material rapidly sediments out of the water column and is primary deposited within the estuary. The removal of iron and phosphorus is complete, with the calculated sedimentation exceeding the total amounts of particulate and dissolved iron and phosphorus supplied by the river. Aggregation of dissolved or colloidal iron-phosphate complexes due to increasing salinity and pH in combination with adsorption on rapidly sedimentating inorganic particles is suggested to explain this estuarine filter effect. Organic carbon is only affected by aggregation and sedimentation to a minor extent.
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  • 29
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    Hydrobiologia 243-244 (1992), S. 105-111 
    ISSN: 1573-5117
    Keywords: phosphorus ; transformations ; humic forest lake
    Source: Springer Online Journal Archives 1860-2000
    Topics: Biology
    Notes: Abstract Research on epilimnetic phosphorus transformations in lakes had led to the establishment of a generalised picture which is promoted in reviews and textbooks. However, it would be wrong to believe that this established view can be applied to all lakes. Certainly the transformations of phosphorus in the summer epilimnia of small, coloured, humic forest lakes in southern Finland show features which deviate markedly from the generally accepted paradigm. (1) The plankton appears to be limited simultaneously by P and N rather than being strongly P limited. (2) Particulate P is typically a rather small fraction of the total P. (3) Molybdate reactive P may be a large part of the total P, although much of this MRP is not free orthophosphate, especially in highly humic lakes. (4) Turnover times for PO4-P are normally long (50–1000 minutes); turnover times appear to be longer in highly humic lakes. (5) Added 32 PO4 passes rapidly to macrozooplankton, apparently with rapid turnover of zooplankton phosphorus. (6) Sedimentation of phosphorus from the typically shallow epilimnion appears high, but may be partially compensated by biological retrieval of phosphorus from the phosphorus-rich hypolimnion.
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  • 30
    ISSN: 1573-5117
    Keywords: fertilization ; phosphorus ; nitrogen ; phytoplankton ; zooplankton
    Source: Springer Online Journal Archives 1860-2000
    Topics: Biology
    Notes: Abstract Lake Hecklan, in central Sweden, was fertilized with phosphorus and nitrogen during thermal stratification (late May-early Oct) 1984–1987. The nutrient additions were relatively small and raised the total phosphorus concentrations from 6 to 10 µg l−1. The working hypothesis was that this moderate increase in the phosphorus concentration could increase the phytoplankton biomass without adverse changes in the planktonic community structure. The fertilization increased the phytoplankton biomass from 0.1 to a maximum of 2 mm3 l−1. Chrysophyceae and Cryptophyceae dominated throughout the experimental period. Thus, the phytoplankton composition remained typical for a Swedish forest lake and provided a potential for increased zooplankton growth. An increased growth of zooplankton was indicated by increased biomass of Cladocera and Copepoda in 1984 and 1985, and by increased fecundity of herbivorous zooplankton.
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  • 31
    ISSN: 1573-5117
    Keywords: nutrient regeneration ; phosphorus ; nitrogen ; sediment ; lakes
    Source: Springer Online Journal Archives 1860-2000
    Topics: Biology
    Notes: Abstract The mineralization of phosphorus and nitrogen from seston was studied in consolidated sediment from the shallow Lake Arreskov (July and November) and in suspensions without sediment (July). In the suspension experiment, phosphorus and nitrogen were mineralized in the same proportions as they occurred in the seston. During the 30 days suspension experiment, 47 and 43% of the particulate phosphorus and nitrogen, respectively, was mineralized with constant rates. Addition of seston to the sediment had an immediate enhancing effect on oxygen uptake, phosphate and ammonia release, whereas nitrate release decreased due to denitrification. The enhanced rates lasted for 2–5 weeks, while the decrease in nitrate release persisted throughout the experiment. The increase in oxygen uptake (equivalent to 21% of the seston carbon) was, however, only observed in the July experiment. The release of phosphorus and nitrogen from seston decomposing on the sediment surface differed from the suspension experiments. Thus, between 91 and 111% of the phosphorus in the seston was released during the experiments. Due to opposite directed effects on ammonium and nitrate release, the resulting net release of nitrogen was relatively low. A comparison of C/N/P ratios in seston, sediment and flux rates indicated that nitrogen was mineralized faster than phosphorus and carbon. Some of this nitrogen was lost through denitrification and therefore not measurable in the flux of inorganic nitrogen ions. This investigation also suggests that decomposition of newly settled organic matter in sediments have indirect effects on sediment-water exchanges (e.g. by changing of redox potentials and stimulation of denitrification) that modifies the release of mineralized phosphate and nitrogen from the sediment.
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  • 32
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    Hydrobiologia 229 (1992), S. 23-41 
    ISSN: 1573-5117
    Keywords: TOC ; COD ; humic ; colour ; Secchi ; phosphorus ; carbon ; permanganate
    Source: Springer Online Journal Archives 1860-2000
    Topics: Biology
    Notes: Abstract 18 Swedish forest lakes covering a wide range of dystrophy were studied in order to quantify and characterize the organic matter in the water with respect to origin (allochthonous or autochthonous), physical state (particulate or dissolved) and phosphorus content. Samples were collected repeatedly during a two-year period with unusually variable hydrological conditions. Water from three different depths and from tributaries was analysed with standard monitoring methods, including water colour, Secchi disk transparency, total organic carbon (TOC), CODCr, CODMn, total phosphorus and molybdate reactive phosphorus. Interrelationships were used to compare different methods and to assess the concentration and composition of organic matter. It is estimated that in remote softwater lakes of the Swedish forest region, autochthonous carbon is typically 〈 5 g m−3. Most lakes in this region receive significant amounts of humic matter originating from coniferous forest soils or peatland in the catchment area. In most humic lakes with a water colour of ≥ 50 g Pt m−3, more than half of the organic carbon in the surface water is of allochthonous origin, and in polyhumic lakes (〉 200 g Pt m−3) the proportion can exceed 90%. Secchi depth readings were related similarly to organic matter from both sources and provided good estimates of TOC with a single optical measurement. Water colour was used to distinguish allochthonous and autochthonous matter. High concentrations of phosphorus were found in humic waters, most of it being molybdate reactive, and probably associated with humic matter rather than as dissolved free inorganic forms. CODMn yielded only 25–60% of TOC and appears to include mainly truly dissolved substances of low molecular weight.
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  • 33
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    Hydrobiologia 230 (1992), S. 193-200 
    ISSN: 1573-5117
    Keywords: nitrogen ; phosphorus ; ricefield system ; drainage channels ; mediterranean Deltas
    Source: Springer Online Journal Archives 1860-2000
    Topics: Biology
    Notes: Abstract Nitrogen and phosphorus released into the water of a main drainage channel in the Ebro Delta was measured during a period of rice cultivation. An increase in total nitrogen and phosphorus in its different forms in accordance with the increase in cultivated area drained was observed. A significant correlation between the release of nutrients into the water and the nutrient load, for both nitrogen and phosphorus, if we consider the release of nutrients per unit of length of the channel and increased total phosphorus content of the water that flows through it during the period of rice cultivation. Physical and chemical changes in the water as a result of ricefield metabolism may explain the differences observed in nitrogen and phosphorus cycles between Ebro and Rhône Deltas, two mediterranean deltaic systems where a large area with similar drainage system is used for rice cultivation.
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  • 34
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    Hydrobiologia 243-244 (1992), S. 341-349 
    ISSN: 1573-5117
    Keywords: mass balance ; modelling ; phosphorus ; sedimentation ; CSTR ; PFR
    Source: Springer Online Journal Archives 1860-2000
    Topics: Biology
    Notes: Abstract Mass balance models for elongated lakes have been developed. In these models particular attention is paid to the hydraulic description of the lake and to the description of net sedimentation. The hydraulic description is a linear combination of CSTR and PFR, with a coefficient regulating the degree of mixing. The PFR description was modified so that also additional input along the lake can be considered. Net sedimentation is described either as a first order or a second order reaction. Both voluminal and areal sedimentation is possible in the models. The models were tested against phosphorus balance data for two Finnish lakes. Lake Haukivesi and Lake Päijänne. In both lakes the PFR model with additional input together with second order net sedimentation gave the best fit to observations. The values of the sedimentation coefficients are not universal but vary from lake to lake. They are also dependent on the hydraulic description used in the model. There is a critical point for the monitoring of the lake at which measurements give the same sedimentation coefficient regardless of the hydraulic description.
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  • 35
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    Plant and soil 145 (1992), S. 45-50 
    ISSN: 1573-5036
    Keywords: acidity ; manganese ; pH ; phosphorus ; soil solution wheat
    Source: Springer Online Journal Archives 1860-2000
    Topics: Agriculture, Forestry, Horticulture, Fishery, Domestic Science, Nutrition
    Notes: Abstract A pot experiment was carried out in order to test the hypothesis that manganese nutrition of wheat was dependent on the phosphorus status of soil as well as on its pH and manganese status. An arable mineral soil whose lime and phosphorus status had been massively adjusted more than 18 years previously was compared with identical soil not so adjusted. Wheat plants were grown to maturity in these soils. Analyses were carried out on both soil and plant samples at intervals. Data for soil pH, soil solution concentrations of manganese and phosphorus, plant dry weight and tissue concentrations of manganese and phosphorus are presented. Concentrations of manganese were depressed in leaf tissue of plants from limed soils and also in high phosphorus soils. The depressed values for limed treatments were explained in terms of depressed soil solution manganese concentrations resulting from elevated pH. The results for high phosphorus soils could not be related to soil solution composition. It was suggested that high soil phosphorus resulted in elevated plant phosphorus which interfered in the uptake and/or translocation of manganese.
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  • 36
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    Plant and soil 145 (1992), S. 65-70 
    ISSN: 1573-5036
    Keywords: calcifuge plants ; phosphorus ; deficient absorption ; Deschampsia flexuosa ; Jasione montana ; Rumex acetosella ; Silene rupestris
    Source: Springer Online Journal Archives 1860-2000
    Topics: Agriculture, Forestry, Horticulture, Fishery, Domestic Science, Nutrition
    Notes: Abstract Germination, seedling establishment and growth of calcifuge plants in Swedish limestone soils of Archean and Ordovician age were studied. As previously demonstrated for Viscaria vulgaris, establishment of Rumex acetosella and Silene rupestris did not succeed unless CaHPO4 (at the rate of 10 mmol dm-3 of soil) was supplied. Growth of Deschampsia flexuosa was enhanced by phosphate addition, whereas establishment success of Jasione montana was poor, regardless of phosphate treatment. Establishment and growth in an acidic gneiss soil, used as a reference for the species studied, was good. Total, total inorganic, exchangeable, and soil solution P were considered in all soils and treatments. It is proposed that the calcifuge behaviour of plants is quite often caused by inability to solubilize the native phosphate of limestone soils.
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  • 37
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    Plant and soil 146 (1992), S. 163-168 
    ISSN: 1573-5036
    Keywords: genetic variability ; NIR ; ploidy ; phosphorus ; wheat
    Source: Springer Online Journal Archives 1860-2000
    Topics: Agriculture, Forestry, Horticulture, Fishery, Domestic Science, Nutrition
    Notes: Abstract More efficient utilization of phosphorus by wheat plants is needed to extend the useful life of the phosphate reserves in the world, to reduce the cost of producing crops, and to improve the value of the grain and the straw produced. In this paper definitions of efficient use of phosphorus by wheat are reviewed, genotypic variation in phosphorus efficiency is reported, some consequences of breeding for greater efficiency are discussed, and ways to select more efficient genotypes are suggested.
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  • 38
    ISSN: 1573-9171
    Keywords: EPR ; radical ; fluorine ; conformation ; phosphorus
    Source: Springer Online Journal Archives 1860-2000
    Topics: Chemistry and Pharmacology
    Notes: Abstract EPR spectra of radical adducts of phosphonyl radicals with 2-hydroperfluoro-4-methyl- and 4,4-dimethyl-2-pentene have been studied. The molecular mechanics method has been used to determine the preferred conformation of the (CF3)2CF-CF-HCF3P(O)(OMe)2 radical. The eclipsed conformation of the C–P bond and 2p z -orbital of an unpaired electron is stabilized due to steric factor and hyperconjugation.
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  • 39
    ISSN: 1573-5117
    Keywords: eutrophication ; lakes ; phosphorus ; chloride ; loading ; dynamic mass balance model ; sensitivity analysis
    Source: Springer Online Journal Archives 1860-2000
    Topics: Biology
    Notes: Abstract In 1984 a frequent monitoring programme was started in the hypertrophic S.W. Frisian lake district, with emphasis on total phosphorus (TP) and chloride (Cl−). The main objectives of the project were: to quantify the phosphorus flows, to gain insight in the process of eutrophication, and to simulate management scenarios. The seasonal variability in the lakes is due mainly to the man-made hydrology: reception of humic-rich polder water in wet periods (winter) and inlet of chloride-rich Usselmeer water in dry periods (summer). The yearly means of TP concentrations in the lakes (Tjeukemeer, Groote Brekken and Slotermeer) ranged from 0.23 to 0.29 mg l−1. However, much higher concentrations (0.9 mg l−1) were found in periods with high inflow of polder water. The simulations with a mass balance showed an acceptable similarity between measured and simulated concentrations of TP as well as of Cl−. Chloride was modelled to verify the accuracy of a hydrodynamic model. A sensitivity analysis of the apparent settling rate in the P model showed that sensitivity was lowest in simulations of Groote Brekken and highest in simulations of Slotermeer, the difference being attributable to the influence of the water residence time. The model was found to be appropriate for simulating management scenarios.
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  • 40
    ISSN: 1573-5117
    Keywords: nitrogen ; phosphorus ; underwater light ; primary production ; secondary production
    Source: Springer Online Journal Archives 1860-2000
    Topics: Biology
    Notes: Abstract The study provides a 2.5 year record of Rhenosterkop Dam (KwaNdebele, South Africa) plankton population dynamics and production in relation to physical and chemical changes which occurred during the trophic depression and stabilization phases of the reservoir. The mean volume of the reservoir was 4% of full storage capacity. Water temperatures ranged from 14 °C to 27 °C. Due to inorganic suspensoids, the euphotic zone averaged 2.6 m. An anaerobic zone developed each summer. The nitrogen, soluble reactive phosphorus (SRP) and silica concentrations did not displaya seasonal pattern, but the latter two nutrients declined over the study. The dominant phytoplankton group was the cryptophytes while the zooplankton population was dominated by crustaceans. Chlorophyll a concentrations ranged from 1.1 to 27 mg m−3 and were positively correlated to silica and SRP concentrations and inversely with NH4-N concentrations. Primary production ranged from 22.6 to 375 mgC m−2 h−1; changes in Amax were positively correlated to silica and SRP concentrations. Total zooplankton dry weight biomass varied from 〈0.5 to 〉4 mg l−1. Annual zooplankton (secondary) production was 8 to ∼ 15 gC m−3 a−1; both primary and secondary production were greatest in the first 12 months of study and remained at low levels for the remainder, similar to the trends for silica and SRP. The data indicate that the reservoir shifted from eutrophic to mesotrophic during the study, typical of events in new reservoirs, and that changes in the plankton populations were largely the result of changing nutrient concentrations.
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  • 41
    ISSN: 1573-5117
    Keywords: Lakes ; sediments ; iron ; phosphorus ; phosphate release
    Source: Springer Online Journal Archives 1860-2000
    Topics: Biology
    Notes: Abstract Analysis of Danish lakes showed that both mean winter and mean summer concentrations of lake water total phosphorus in the trophogenic zone correlated negatively with the total iron to total phosphorus ratio (Fe:P) in surface sediments. No correlation was found between the water total phosphorus concentration and either the sediment phosphorus concentration alone or with sediment calcium concentration. The increase in total phosphorus from winter to summer, which is partly a function of net internal P-loading, was lowest in lakes with high Fe:P ratios in the surface sediment. A study of aerobic sediments from fifteen lakes, selected as representative of Danish lakes with respect to the sediment Fe and phosphorus content, showed that the release of soluble reactive phosphorus was negatively correlated with the surface sediment Fe:P ratio. Analysis of phosphate adsorption properties of surface sediment from 12 lakes revealed that the capability of aerobic sediments to buffer phosphate concentration correlated with the Fe:P ratio while the maximum adsorption capacity correlated with total iron. Thus, the Fe:P ratio may provide a measure of free sorption sites for orthophosphate ions on iron hydroxyoxide surfaces. The results indicate that provided the Fe:P ratio is above 15 (by weight) it may be possible to control internal P-loading by keeping the surface sediment oxidized. Since the Fe:P ratio is easy to measure, it may be a useful tool in the management of shallow lakes.
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  • 42
    ISSN: 1573-5117
    Keywords: acid lakes ; ATP ; in situ enclosures ; liming ; phosphatases ; phosphorus ; phytoplankton community
    Source: Springer Online Journal Archives 1860-2000
    Topics: Biology
    Notes: Abstract A bioassay was developed, involving steady-state ATP level determinations, for estimation of phosphate demand and deficiency in natural phytoplankton communities. The studies were performed on phytoplankton from the moderately acidified Lake Njupfatet in central Sweden before and after liming. Phytoplankton samples from in situ enclosure experiments with low-dose enrichments of nitrate and phosphate and removal of large (〉 100 µm) zooplankton and from the lake water were collected. The phytoplankton were concentrated by through-flow centrifugation and post-cultured in the laboratory with or without the addition of phosphate. A relative increase in the ATP:chlorophyll a ratio after the phosphate treatment as compared to samples without phosphate enrichment was found to be a highly reproducible indicator of phosphate deficiency in the natural phytoplankton population. In contrast, the absolute ATP:chlorophyll a ratio varied substantially between different sampling occasions. No phosphate deficiency was detected in phytoplankton from the acidic lake or from fertilized in situ enclosures. However, phytoplankton from in situ enclosures without added nutrients showed evidence of phosphate limitation after 21 days incubation. Also, the phytoplankton community developed a significant phosphate deficiency the summer after lake liming. The results from the ATP analyses are compared with chemical data of the lake water, phytoplankton community structure and phosphatase activities in the lake before and after liming. The average total biomass of phytoplankton and the average Tot-P measured during May to September decreased with appr. 30% after liming while Tot-N was essentially unaffected and the phosphatase activities increased by 1000–2000%.
    Type of Medium: Electronic Resource
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  • 43
    Electronic Resource
    Electronic Resource
    Springer
    Microchimica acta 109 (1992), S. 201-209 
    ISSN: 1436-5073
    Keywords: phosphonate base scale inhibitor ; brine ; direct current plasma ; inductively coupled plasma atomic emission spectrometry ; phosphorus
    Source: Springer Online Journal Archives 1860-2000
    Topics: Chemistry and Pharmacology
    Notes: Abstract The determination of phosphonate base scale inhibitors in brines by direct current plasma (DCP) and inductively coupled plasma atomic emission spectrometry (ICP-AES) is described. The first method is based on a direct nebulization of the brine samples and plasma using the phosphorus line at 213.618 nm. The second method involves extraction of phosphorus as phospho-antimonyl molybdate complex into methylisobutyl ketone (MIBK) phase and analysis of the extract for molybdenum using the Mo 313.260 nm line. Comparison between the proposed methods and an established recommended method [1] shows excellent agreement between the results in addition to the sensitivity and ease of automation provided by AES.
    Type of Medium: Electronic Resource
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