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  • Articles  (202,422)
  • Springer  (138,360)
  • American Institute of Physics  (28,587)
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  • 2010-2014
  • 2005-2009  (72,969)
  • 1985-1989  (73,458)
  • 1975-1979  (55,995)
  • 1945-1949
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  • 1
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    Springer
    In:  International Association of Geodesy Symposia
    Publication Date: 2020-02-12
    Description: The lAG International Symposium on Gravity, Geoid, and Space Missions 2004 (GGSM2004) was lield in the beautiful city of Porto, Portugal, from 30 August to 3 September 2004. This symposium encompassed the themes of Commission 2 (Gravity Field) of the newly structured lAG, as well as interdisciplinary topics related to geoid and gravity modeling, with special attention given to the current and planned gravi- dedicated satellite missions. The symposium also followed in the tradition of mid-term meetings that were held between the quadrennial joint meetings of the International Geoid and Gravity Commissions. The previous mid-term meetings were the International Symposia on Gravity, Geoid, and Marine Geodesy (Tokyo, 1996), and Gravity, Geoid, and Geodynamics (Banff, 2000). GGSM2004 aimed to bring together scientists from different areas in the geosciences, working with gravity and geoid related problems, both from the theoretical and practical points of view. Topics of interest included the integration of heterogeneous data and contributions from satellite and airborne techniques to the study of the spatial and temporal variations of the gravity field. In addition to the special focus on the CHAMP, GRACE, and GOCE satellite missions, attention was also directed toward projects addressing topographic and ice field mapping using SAR, LIDAR, and laser altimetry, as well as missions and studies related to planetary geodesy.
    Language: English
    Type: info:eu-repo/semantics/book
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  • 2
    Publication Date: 2020-02-12
    Keywords: 550 - Earth sciences
    Type: info:eu-repo/semantics/book
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  • 3
    Publication Date: 2020-11-23
    Description: Abstract: The simultaneous solution of the Planck equation (involving the widely used “dual-band” technique) using two shortwave infrared (SWIR) bands allows for an estimate of the fractional area of the hottest part of an active lava flow (fh), and the background temperature of the cooler crust (Tc). The use of a high spectral and spatial resolution imaging spectrometer with a wide dynamic range of 15 bits (DAIS 7915) in the wavelength range from 0.501 to 12.67 µm resulted in the identification of crustal temperature and fractional areas for an intra-crater hot spot at Mount Etna, Italy. This study indicates the existence of a relationship between these Tc and fh extracted from DAIS and Landsat TM data. When the dual band equation system is performed on a lava flow, a logarithmic distribution is obtained from a plot of the fractional area of the hottest temperature versus the temperature of the cooler crust. An entirely different distribution is obtained over active degassing vents, where increases in Tc occur without any increase in fh. This result indicates that we can use scatter plots of Tc vs. fh to discriminate between different types of volcanic activity, in this case between degassing vents and lava flows, using satellite thermal data.
    Description: Published
    Description: 641–651
    Description: 4V. Processi pre-eruttivi
    Description: JCR Journal
    Description: open
    Keywords: Mount Etna ; remote-sensing ; lava-flow ; degassing vent ; 04. Solid Earth::04.08. Volcanology::04.08.01. Gases
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
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  • 4
    Publication Date: 2021-03-01
    Description: On September 6, 2002, aML =5.6 earthquake, occurring some tens of kilometres offshore from the Northern Sicilian coast (Southern Tyrrhenian Sea), slightly damaged the city of Palermo and surroundings (degree 6 in the European Macroseismic Scale 1998). The macroseismic investigation of the shock and a detailed study of effects of the main earthquakes which affected Palermo in the past have been performed in order to evaluate the seismic response of the city. Moreover, the comparison of the recent event, which is instrumentally constrained, with historical earthquakes allows us to infer new insights on the seismogenic sources of the area, that seem located offshore in the Tyrrhenian sea. In the last 500 years, Palermo has never been completely destroyed but has suffered effects estimated between intensities 6 and 8 EMS-98 many times (1693, 1726, 1751, 1823, 1940, 1968, 2002). The damage scenarios of the analysed events have shown that damage distribution is strongly conditioned by soil response in the different parts of the city and by a high building vulnerability, mainly in the historical centre and in the south-eastern zone of the modern city. As a matter of fact, Palermo has always suffered greater effects than those reported for other nearby localities. The hazard assessment obtained using observed site intensities has shown that the probability of occurrence for intensity 8 (the strongest intensity observed in Palermo) exceeds 99% for 550 years, while the estimated mean return period is 152 ± 40 years. These results, in connection with building vulnerability due to the urban expansion before the introduction of seismic code, suggest that the city is exposed to a relatively high seismic risk.
    Description: Published
    Description: 525-543
    Description: partially_open
    Keywords: intensity ; damage ; earthquakes ; Italy ; macroseismics ; Palermo ; seismic hazard ; vulnerability ; 04. Solid Earth::04.06. Seismology::04.06.11. Seismic risk
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
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  • 5
    Publication Date: 2017-04-03
    Description: We compare the results obtained from the modelling of EDM, GPS, levelling and tilt data measured in the first part of the 19911993 eruption at Etna to the InSAR data acquired during the second part. The geodetic changes are very marked in the first half of the eruption and constrain a deflation source located at a few kilometers of depth ( 3 km b.s.l.), in agreement with other independent geophysical evidence. SAR data, available during the second part of the eruption, were analysed for different time intervals in the second part of the eruption. The interpretation of SAR interferograms reveals a large-scale but less marked deflation of the volcano that could be caused by a deeper source. This second source is in accord with a second deeper anomaly revealed by recent seismic investigations. The combination of geodetic data modelling and SAR images suggests a complex plumbing system composed at least of two possible storage regions located at different depths.
    Description: Published
    Description: 1345-1357
    Description: partially_open
    Keywords: Geodesy ; SAR Interferometry ; ground deformation ; Mt. Etna volcano ; 04. Solid Earth::04.03. Geodesy::04.03.06. Measurements and monitoring ; 04. Solid Earth::04.03. Geodesy::04.03.07. Satellite geodesy ; 04. Solid Earth::04.03. Geodesy::04.03.09. Instruments and techniques
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  • 6
    Publication Date: 2017-04-04
    Description: Analysis of the historical records of Etnas eruptive activity for the past three centuries shows that, after the large 1669 eruption, a period of about 60 years of low-level activity followed. Starting from 1727, explosive activity (strombolian, lava fountaining and subplinian) at the summit crater increased exponentially to the present day. Since 1763, the frequency of flank eruptions also increased and this value remained high until 1960; afterward it further increased sharply. In fact, the number of summit and flank eruptions between 1961 and 2003 was four times greater than that of the pre-1960 period. This long-term trend of escalating activity rules out a pattern of cyclic behaviour of the volcano. We propose instead that the 16702003 period most likely characterises a single eruptive cycle which began after the large 1669 eruption and which is still continuing. On the basis of the eruptive style, two distinct types of flank eruptions are recognised: Class A and Class B. Class A eruptions are mostly effusive with associated weak strombolian activity; Class B eruptions are characterised by effusive activity accompanied by intense, long-lasting, strombolian and lava fountaining activity that produces copious tephra fallouts, as during the 2001 and 20022003 eruptions. Over the past three centuries, seven Class B eruptions have taken place with vents located mainly on the south-eastern flank, indicating that this sector of the volcano is a preferential zone for the intrusion of volatile-rich magma rising from the deeper region of the Etna plumbing system.
    Description: Published
    Description: 732-742
    Description: partially_open
    Keywords: Etna ; Historical record ; Summit activity ; Flank eruptions ; Eruptive behaviour ; 05. General::05.02. Data dissemination::05.02.03. Volcanic eruptions
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
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  • 7
    Publication Date: 2017-04-04
    Description: The Monte Nuovo eruption is the most recent event that occurred at Phlegrean Fields (Italy) and lasted from 29 September to 6 October 1538. It was characterized by 2 days of quasi-sustained phreatomagmatic activity generating pumice-bearing pyroclastic density currents and forming a 130-m-high tuff cone (Lower Member deposits). The activity resumed after a pause of 2 days with two discrete Vulcanian explosions that emplaced radially distributed, scoria-bearing pyroclastic flows (Upper Member deposits). The juvenile products of Lower and Upper Members are, respectively, phenocryst-poor, light-coloured pumice and dark scoria fragments with K-phonolitic bulk compositions, identical in terms of both major and trace elements. Groundmass is formed by variable proportions of K-feldspar and glass, along with minor sodalite and Fe-Ti oxide present in the most crystallized samples. Investigations of groundmass compositions and textures were performed to assess the mechanisms of magma ascent, degassing and fragmentation along the conduit and implications for the eruptive dynamics. In pumice of the Lower Member groundmass crystal content increases from 13 to 28 vol% from the base to the top of the sequence. Products of the Upper Member consist of clasts with a groundmass crystal content between 30 and 40 vol% and of totally crystallized fragments. Crystal size distributions of groundmass feldspars shift from a single population at the base of the Lower Member to a double population in the remaining part of the sequence. The average size of both populations regularly increases from the Lower to the Upper Member. Crystal number density increases by two orders of magnitude from the Lower to the Upper Member, suggesting that nucleation dominated during the second phase of the eruption. The overall morphological, compositional and textural data suggest that the juvenile components of the Monte Nuovo eruption are likely to record variations of the magma properties within the conduit. The different textures of pumice clasts from the Lower Member possibly reflect horizontal gradients of the physical properties (P, T) of the ascending magma column, while scoriae from the second phase are thought to result from the disruption of a slowly rising plug crystallizing in response to degassing. In particular, crystal size distribution data point to syn-eruptive degassing-induced crystallization as responsible for the transition in eruptive style from the first to the second phase of the eruption. This mechanism not only has been proved to profoundly affect the dynamics of dome-forming calc-alkaline eruptions, but may also have a strong influence in driving the eruption dynamics of alkaline magmas of intermediate to evolved compositions.
    Description: Published
    Description: 601-621
    Description: reserved
    Keywords: Phlegrean Fields ; Vulcanian explosion ; Degassing ; Groundmass crystallization ; Eruption dynamics ; 04. Solid Earth::04.08. Volcanology::04.08.01. Gases ; 04. Solid Earth::04.08. Volcanology::04.08.02. Experimental volcanism ; 05. General::05.02. Data dissemination::05.02.03. Volcanic eruptions
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  • 8
    Publication Date: 2017-04-04
    Description: In this work we present seismological and ground deformation evidence for the phase preparing the July 18 to August 9, 2001 flank eruption at Etna. The analysis performed, through data from the permanent seismic and ground deformation networks, highlighted a strong relationship between seismic strain release at depth and surface deformation. This joint analysis provided strong constraints on the magma rising mechanisms. We show that in the last ten years, after the 1991–1993 eruption, an overall accumulation of tension has affected the volcano. Then we investigate the months preceding the 2001 eruption. In particular, we analyse the strong seismic swarm on April 20–24, 2001, comprising more than 200 events (Mmax = 3.6) with prevalent dextral shear fault mechanisms in the western flank. The swarm showed a ca. NE-SW earthquake alignment which, in agreement with previous cases, can be interpreted as the response of the medium to an intrusive process along the approximately NNW-SSE volcano-genetic trend. These mechanisms, leading to the July 18 to August 9, 2001 flank eruption, are analogous to ones observed some months before the 1991–1993 flank eruption and, more recently, in January 1998 before the February-November 1999 summit eruption.
    Description: Published
    Description: 1469-1487
    Description: partially_open
    Keywords: Ground deformation ; volcano seismology ; Mt. Etna Volcano ; intrusive mechanism ; 04. Solid Earth::04.03. Geodesy::04.03.01. Crustal deformations ; 04. Solid Earth::04.06. Seismology::04.06.08. Volcano seismology
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
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  • 9
    Publication Date: 2017-04-04
    Description: Ground deformation occurring on the southern flank of Mt Etna volcano during the JulyAugust 2001 eruption was monitored by GPS measurements along an EW profile crossing the fissure system. This profile was measured eight times during the eruption, using the 'stop and go' semi-kinematic technique. Horizontal and vertical displacements between GPS surveys are reported for each station. The most significant event is a deformation episode occurring during the first week of the eruption, between 2527 July. Displacements were measured on benchmarks close to the eruptive fissure and the tensile 1989 fracture. Data inversions for measured displacements were performed using the Okada model. The model shows the narrowing of the 2001 dyke accompanied by a dextral dislocation along an east-dipping fault, parallel to the 1989 fracture.
    Description: Published
    Description: 336-341
    Description: partially_open
    Keywords: GPS ; Ground deformation ; Modelling ; Volcano monitoring ; 04. Solid Earth::04.03. Geodesy::04.03.07. Satellite geodesy ; 04. Solid Earth::04.03. Geodesy::04.03.09. Instruments and techniques ; 04. Solid Earth::04.08. Volcanology::04.08.06. Volcano monitoring
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  • 10
    Publication Date: 2017-04-04
    Description: The 200203 Mt Etna flank eruption began on 26 October 2002 and finished on 28 January 2003, after three months of continuous explosive activity and discontinuous lava flow output. The eruption involved the opening of eruptive fissures on the NE and S flanks of the volcano, with lava flow output and fire fountaining until 5 November. After this date, the eruption continued exclusively on the S flank, with continuous explosive activity and lava flows active between 13 November and 28 January 2003. Multi-disciplinary data collected during the eruption (petrology, analyses of ash components, gas geochemistry, field surveys, thermal mapping and structural surveys) allowed us to analyse the dynamics of the eruption. The eruption was triggered either by (i) accumulation and eventual ascent of magma from depth or (ii) depressurisation of the edifice due to spreading of the eastern flank of the volcano. The extraordinary explosivity makes the 200203 eruption a unique event in the last 300 years, comparable only with La Montagnola 1763 and the 2001 Lower Vents eruptions. A notable feature of the eruption was also the simultaneous effusion of lavas with different composition and emplacement features. Magma erupted from the NE fissure represented the partially degassed magma fraction normally residing within the central conduits and the shallow plumbing system. The magma that erupted from the S fissure was the relatively undegassed, volatile-rich, buoyant fraction which drained the deep feeding system, bypassing the central conduits. This is typical of most Etnean eccentric eruptions. We believe that there is a high probability that Mount Etna has entered a new eruptive phase, with magma being supplied to a deep reservoir independent from the central conduit, that could periodically produce sufficient overpressure to propagate a dyke to the surface and generate further flank eruptions.
    Description: Published
    Description: 314-330
    Description: partially_open
    Keywords: Multi-disciplinary study ; Mount Etna ; 2002–03 eruption ; Eccentric eruptions ; Flank activity ; Etna feeding system ; Volcanic processes ; 04. Solid Earth::04.08. Volcanology::04.08.06. Volcano monitoring ; 05. General::05.02. Data dissemination::05.02.03. Volcanic eruptions
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  • 11
    Publication Date: 2017-04-04
    Description: An anisotropic attenuation law, based on an anisotropic characterization of intensity distribution for seismogenic zones, is proposed. This approach, that distinguishes itself for its consistency to the observed data, initially reconfigured by filtering procedures, is particularly suitable for seismic hazard evaluation.
    Description: Published
    Description: 707-714
    Description: partially_open
    Keywords: Attenuation law ; virtual intensity distribution ; seismic hazard ; 04. Solid Earth::04.06. Seismology::04.06.11. Seismic risk
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
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  • 12
    Publication Date: 2017-04-04
    Description: A modelling of the observed macroseismic intensity of historical and instrumental earthquakes in southern Spain is proposed, with the aim of determining the macroseismic parameters for seismic hazard evaluation in a region in which the characterization of intensity distribution of seismic events shows different levels of difficulty referable to the complex faults system of the area in study. The adopted procedure allows an analytical determination of epicenters and principal attenuation directions of earthquakes with a double level of verification with reference to the maximum shaking area and structural lineaments of the region, respectively. The analyses, carried out on a suitable number of events, highlight, therefore, some elements for a preliminary characterization of a seismic zonation on the basis of the consistency between seismic intensity distribution of earthquakes and corresponding structural framework.
    Description: Published
    Description: 747-760
    Description: partially_open
    Keywords: Attenuation directions ; southern Spain ; macroseismic intensity ; virtual intensity ; 04. Solid Earth::04.07. Tectonophysics::04.07.07. Tectonics ; 04. Solid Earth::04.06. Seismology::04.06.11. Seismic risk
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  • 13
    Publication Date: 2017-04-04
    Description: Flank instability and collapse are observed at many volcanoes. Among these, Mt. Etna is characterized by the spreading of its eastern and southern flanks. The eastern spreading area is bordered to the north by the EW-trending Pernicana Fault System (PFS). During the 20022003 Etna eruption, ground fracturing along the PFS migrated eastward from the NE Rift, to as far as the 18 km distant coastline. The deformation consisted of dextral en-echelon segments, with sinistral and normal kinematics. Both of these components of displacement were one order of magnitude larger (~1 m) in the western, previously known, portion of the PFS with respect to the newly surveyed (~9 km long) eastern section (~0.1 m). This eastern section is located along a pre-existing, but previously unknown, fault, where displaced man-made structures give overall slip rates (11.9 cm/year), only slightly lower than those calculated for the western portion (1.42.3 cm/year). After an initial rapid motion during the first days of the 20022003 eruption, movement of the western portion of the PFS decreased dramatically, while parts of the eastern portion continued to move. These data suggest a model of spreading of the eastern flank of Etna along the PFS, characterized by eruptions along the NE Rift, instantaneous, short-lived, meter-scale displacements along the western PFS and more long-lived centimeter-scale displacements along the eastern PFS. The surface deformation then migrated southwards, reactivating, one after the other, the NNWSSE-trending Timpe and Trecastagni faults, with displacements of ~0.1 and ~0.04 m, respectively. These structures, along with the PFS, mark the boundaries of two adjacent blocks, moving at different times and rates. The new extent of the PFS and previous activity over its full length indicate that the sliding eastern flank extends well below the Ionian Sea. The clustering of seismic activity above 4 km b.s.l. during the eruption suggests a deep décollement for the moving mass. The collected data thus suggests a significant movement (volume 〉1,100 km3) of the eastern flank of Etna, both on-shore and off-shore.
    Description: Published
    Description: 417-430
    Description: partially_open
    Keywords: Volcano spreading ; Fracturing ; Mt. Etna ; Pernicana Fault System ; NE Rift ; 04. Solid Earth::04.04. Geology::04.04.09. Structural geology ; 04. Solid Earth::04.08. Volcanology::04.08.06. Volcano monitoring ; 05. General::05.02. Data dissemination::05.02.03. Volcanic eruptions ; 04. Solid Earth::04.08. Volcanology::04.08.08. Volcanic risk
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  • 14
    Publication Date: 2017-04-04
    Description: We have characterized pumice products belonging to the climactic phase of the 800-year-b.p. Quilotoa eruption. Bulk rock compositions, petrography, mineral, and glass chemistry and textural investigations were performed on the three end-member pumice types, namely white, gray, and mingled pumices. All the investigated pumice clasts are dacites characterized by the same bulk rock composition and mineralogical assemblage, but glass compositions and bulk textures change according to different pumice types. White pumice has higher crystallinity (~48 wt%), abundant euhedral pheno/microphenocrysts, no groundmass microlites, the most evolved glass compositions (7478 wt% SiO2), and heterogeneous vesicle populations marked by deformed and highly coalesced vesicles with thin walls. Gray pumice exhibits lower crystallinity (2936 wt%), abundant broken and/or resorbed crystals, ubiquitous groundmass phenocryst fragments and microlites, the widest range of glass compositions (6978 wt% SiO2), and quite homogeneous poorly deformed and coalesced vesicles with thicker walls. Mingled pumices are characterized by the alternation of bands or patches with white and gray pumice compositional and textural characteristics. We attribute heterogeneities in glass compositions and crystal and vesicle textures to processes occurring within volcanic conduits as magma is ascending to the surface. In particular, the above observations and results are consistent with an origin of a gray magma by heating of the original white magma in a strongly sheared region of the conduit because of a mechanism of viscous dissipation and crystal grinding and resorption at the conduit walls. The less viscous gray magma, therefore, would enable the onset and preservation of a high mass flux of the eruption otherwise difficult to explain for highly viscous crystal-rich dacitic magmas.
    Description: Published
    Description: 307-321
    Description: partially_open
    Keywords: Plinian eruption ; Crystal-rich magma ; Crystal grinding ; Pumice types ; Viscous dissipation ; 04. Solid Earth::04.08. Volcanology::04.08.03. Magmas ; 05. General::05.02. Data dissemination::05.02.03. Volcanic eruptions
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  • 15
    Publication Date: 2017-04-04
    Description: The anisotropic modelling of intensity distribution, affected by the construction of macroseismic planes, allows an analysis of the influence of each point of observed intensity on the analytical determination of epicenter and of the principal attenuation directions. Such a procedure is a vital aid in the cases in which the observed intensity points, that, for location or joined intensity level, are not consistent with an anisotropic model of intensity attenuation. A suitable filtering on intensity levels associated with the points of the intensity map, for a better modelling of observed intensity distribution, is proposed with the aim of a better seismic hazard evaluation
    Description: Published
    Description: 683-697
    Description: partially_open
    Keywords: Macroseismicity ; observed intensity filtering ; macroseismic planes ; 04. Solid Earth::04.06. Seismology::04.06.11. Seismic risk
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  • 16
    Publication Date: 2017-04-04
    Description: This paper shows the results of a detailed reprocessing of aeromagnetic data,obtained by the downward projection to the seabed. The area of interest is centered over the Tyrrhenian Basin,whose bathymetric –topographic lay-out is characterized by a somewhat irregular trend.The origin of the intense depth variations depends on the Tyrrhenian structural setting,that is associated with the presence of several tectonic lineaments,seamounts or volcanic islands.The data were characterized by good quality and dense sam- pling,but they have been reprocessed in order either to solve some problems in the original compilation,and to reduce the distor- tion of the geomagnetic anomaly field caused by the difference of distance between the survey level and the magnetic source.The reprocessed magnetic map is proposed as an e ffective analysis tool for the Tyrrhenian area that is characterized by high susceptibility lithotypes.Downward projection of the aeromagnetic data by BTM algorithm increases the de finition of the anomalous magnetic signal without distortions in the geometric pattern of the field,thus showing a more stable and effective association between the magnetic anomalies and their geological sources.This effect is particularly true for high frequency anomalies that are directly comparable after the topographic projection because the depth filtering effect is attenuated.Moreover,the BTM method has been applied for the first time to a regional scale survey that shows substantial advantages because no fictitious anomalies in the high frequency sector of the spectrum were generated.This has been a typical effect of the traditional downward projection methods widely used before.The final result is a BTM anomaly map that is able to show the structural connections between the geological magnetic sources of the Tyrrhenian Sea area.
    Description: Published
    Description: 265-277
    Description: reserved
    Keywords: Potential methods,marine geomagnetism,downward continuation,Tyrrhenian Sea ; 04. Solid Earth::04.02. Exploration geophysics::04.02.04. Magnetic and electrical methods
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  • 17
    Electronic Resource
    Electronic Resource
    Copenhagen : International Union of Crystallography (IUCr)
    Applied crystallography online 11 (1978), S. 73-79 
    ISSN: 1600-5767
    Source: Crystallography Journals Online : IUCR Backfile Archive 1948-2001
    Topics: Geosciences , Physics
    Notes: In order to avoid some of the disadvantages associated with the desmearing methods, a procedure has been developed where the smeared, primary, intensity data can be evaluated directly without desmearing. The procedure consists of the following: first, a model depending on a vector of unknowns, x = (x1, ...., xn), is constructed; then, an iterative search is made for the vector x, and a scale factor s, which corresponds to a local minimum in the error square sum based on the primary, slit-smeared, intensity data. The main advantages with the present method are that the comparison between theory and experiment is made directly with the experimental quantity; thus the experimental errors can be considered in this comparison. Furthermore, some of the disadvantages associated with the desmearing methods are avoided; the method is numerically stable and no extrapolations outside the measured angular range are necessary. Several data sets measured at different concentrations and with different, completely arbitrary, primary-beam weighting functions can be considered in the same refinement. The interparticle scattering effect may also be included in the least-squares refinement. The method is general, so that different models can be tested simply by changing only one subroutine of the computer program. It may also be used to evaluate data impaired by other types of resolution errors; for example, effects due to polychromatic radiation or resolution errors in neutron scattering. Two constructed examples of the application of the method are given: (1) the calculation of the dimensions and the molecular weight of particles with a shape which can be approximated with an ellipsoid of revolution; (2) the calculation of the dimensions and electron-density distribution for spherical particles.
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  • 18
    Electronic Resource
    Electronic Resource
    Copenhagen : International Union of Crystallography (IUCr)
    Applied crystallography online 11 (1978), S. 114-120 
    ISSN: 1600-5767
    Source: Crystallography Journals Online : IUCR Backfile Archive 1948-2001
    Topics: Geosciences , Physics
    Notes: A method is described for finding the peak limits of a Bragg reflection from an analysis of its profile. A `window' of ± 0.67σ[φ)(x)] is set up on each ordinate φ(x) in the tails of the profile and the pattern of the following ordinates is observed through the window. As the ordinate moves from the peak to the background the pattern changes and the limits of the peak may be recognized. Bragg reflections from three crystals have been analysed by this method and the limits found were generally wider than those determined by the method of Lehmann & Larsen [Acta Cryst. (1974), A30, 580–584] applied to the same data. The value of σ(I)/I was near the minimum and similar to the value from the corrected Lehmann–Larsen limits. The behaviour of the methods is also compared by representing the reflections by equivalent Gaussian profiles, and it is found that 〉99% of the Gaussian peak is within the limits found by the present method.
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  • 19
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    Applied crystallography online 11 (1978), S. 102-113 
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    Notes: Existing knowledge about Scherrer constants is reviewed and a summary is given of the interpretation of the broadening arising from small crystallites. Early work involving the half-width as a measure of breadth has been completed and Scherrer constants of simple regular shapes have been determined for all low-angle reflections (h2 + k2 + l2 ≤ 100) for four measures of breadth. The systematic variation of Scherrer constant with hkl is discussed and a convenient representation in the form of contour maps is applied to simple shapes. The relation between the `apparent' crystallite size, as determined by X-ray methods, and the `true' size is considered for crystallites having the same shape. If they are of the same size, then the normal Scherrer constant applies, but if there is a distribution of sizes, a modified Scherrer constant must be used.
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  • 20
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    Applied crystallography online 11 (1978), S. 137-140 
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    Notes: The resolution problem in X-ray energy-dispersive diffractometry is discussed. It is shown that for a given characteristic of the solid-state detector system and a given range of interplanar spacings, an optimum scattering angle can be easily found for any divergence of the incident and scattered beams.
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  • 21
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    Applied crystallography online 11 (1978), S. 148-150 
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    Notes: Spherical crystals of alloy phases too hard and brittle for grinding can be obtained by partial remelting and solidification of a powder sample. The alloy powder is blown through an argon-plasma jet melting the surface material of individual fragments, which solidify again as nearly perfect spheres. The yield is a mixture of different materials in which it is possible, however, after heat treatment to find good single crystals of the original composition. Spherical single crystals of Cu9Al4 have been produced by this method and used for a high-precision X-ray investigation described elsewhere.
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  • 22
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    Applied crystallography online 11 (1978), S. 157-158 
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    Notes: Completely transparent and colourless single crystals of PbGe3O7 were grown from a melt of composition PbO.2GeO2 at 1040 K by spontaneous crystallization. The compound melts incongruently at 1070 K. The unit cell is orthorhombic with lattice constants a = 5.270 (2), b = 14.088 (4), c = 16.054 (4) Å; D293 = 5.94 (4), Dx = 5.985 g cm−3 for Z = 8. The probable space group is Pcab (D152h). A reported phase of composition PbGe205 is shown to be a mixture of PbGe3O7 and α-PbGeO3. X-ray powder data are given.
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  • 23
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    Applied crystallography online 11 (1978), S. 238-242 
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    Topics: Geosciences , Physics
    Notes: An X-ray diffraction study of CsDNA has been carried out with the use of synchrotron radiation of wavelength λ = 1.2 Å. The geometry corresponds to a cylindrical specimen brought into a cylindrical beam of the same diameter and the absorption factor and the primary-beam attenuation factor have been calculated as functions of specimen μR for this geometry. The optimum size of a specimen is here about 1.5 times greater than that in the case of a plane-parallel beam used in International Tables for X-ray Crystallography [Vol. II, (1967), 2nd ed., p. 295. Birmingham: Kynoch Press]. Experimental and calculated primary-beam attenuation factors have been compared and the experimental value of the linear absorption coefficient μ of CsDNA has been estimated for various humidities. The agreement between μc = 78.1 and μo = 78.2 ± 3.6 cm−1 (relative humidity 66–75%) indicates that the geometrical model used is suitable to describe polymer fibres in a cylindrical beam of nearly the same size. It is seen from the observed μ values that there is one caesium ion per nucleotide (monomer unit of DNA molecule) in the specimens used.
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  • 24
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    Applied crystallography online 11 (1978), S. 293-294 
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  • 25
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    Applied crystallography online 11 (1978), S. 293-293 
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  • 26
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    Applied crystallography online 11 (1978), S. 294-294 
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  • 27
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    Applied crystallography online 11 (1978), S. 346-375 
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    Notes: Recent advances in the small-angle scattering of X-rays, neutrons and light by polymers are reviewed. The three techniques are compared, from both experimental and theoretical points of view. Applications are discussed for the study of homophase and heterophase polymers, both in solution and in the solid state, as well as for unoriented and oriented crystalline polymers.
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  • 28
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    Applied crystallography online 11 (1978), S. 477-477 
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    Notes: The conformations of different IgG antibodies were studied before and after interaction with antigen (hapten). In every case a strong change of the conformation was observed. Binding of hapten caused a decrease of the radius of gyration by 2 to 8% and a decrease of the volume by 3 to 10%, depending on the degree of saturation with hapten. Two IgG antibodies (anti-poly-d-alanyl) were split by enzymes into fragments which contain one binding site (Fab′) and two binding sites (Fab′)2, respectively, for hapten. No changes of conformation were observed with these fragments upon the interaction with hapten. These findings lead to the conclusion that the conformation change does not take place within the area of the combining site but relatively far away, at the area of the hinge region and/or the Fc-fragment.
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  • 29
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    Applied crystallography online 11 (1978), S. 464-465 
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    Notes: A design study was made of a neutron small-angle scattering (SAS) instrument for use at Argonne National Laboratory's proposed Intense Pulsed Neutron Source, IPNS-II (Carpenter & Werner, 1976; Werner, 1977; Carpenter, 1977). The instrument design incorporates several features: a converging-slit collimator, wavelength band-limiting choppers, capacity for large samples, and a two-dimensional detector. Machine design-dependent parameters are considered in a Monte-Carlo code that produces estimates of the instrumental resolution function and available flux at the sample. It was found that the calculated flux on sample exceeds that at steady-state reactor instruments of comparable resolution.
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    Applied crystallography online 11 (1978), S. 473-477 
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    Notes: A comparative analysis of the sperm-whale myoglobin structure in the crystal and in solution has been carried out with the technique previously formulated by the authors which uses the large-angle X-ray diffuse scattering for investigating the protein structure in solution. A `modified cube method', correctly taking into account the cavities within the protein molecule accessible to the solvent, is proposed for an accurate estimate of the solvent influence and for calculation of the scattering intensities. A comparison of the theoretical myoglobin scattering curves with the experimental scattering curve of this protein obtained by Stuhrmann shows rather noticeable quantitative divergences, which can be eliminated by a small increase in the distance between the `hairpin' GH and the other part of the protein molecule. It is also shown that several other physically reasonable shifts of helices (or groups of helices) do not lead to an agreement between the experimental and theoretical scattering indicatrices.
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  • 31
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    Applied crystallography online 11 (1978), S. 466-472 
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    Notes: The density-contrast method, commonly used in X-ray (and neutron) small-angle scattering studies of macromolecules in solution, can yield a wealth of information if; (a) the solute is monodisperse and the solution is ideal: (b) each macromolecule in solution has a volume associated with it inside of which the density distribution is independent of the density of the solvent. More specifically it has been pointed out that in this case an expression of the molecular weight can be obtained which does not involve the partial specific volume, provided that the X-ray experiments are performed on an absolute scale. On the other hand, it is well known that X-ray scattering experiments on an ideal solution of identical macromolecules can yield the molecular weight for any composition of the solvent, provided solute, solvent and partial specific volumes are defined and measured at constant chemical potential. Therefore a combination of X-ray scattering and densimetry experiments allows one to verify to what extent condition (b) holds true. Such a set of experiments has been performed on Rhesus monkey low-density serum lipoproteins, the solvent being water containing variable amounts of NaBr. It is concluded that in this case condition (b) is fulfilled. Moreover several important aspects of the analysis of the X-ray scattering curves can be verified.
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    Applied crystallography online 11 (1978), S. 479-482 
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    Notes: The theory of the technique currently in use for measuring distances between subunits in macromolecular aggregates by neutron small-angle scattering is outlined. It is shown that estimates for the radii of gyration of subunits within aggregates can be extracted from neutron distance data, in addition to the distances themselves. The current status of efforts to apply these methods to determine the structure of the E. coli ribosome is discussed.
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  • 33
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    Applied crystallography online 11 (1978), S. 483-484 
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    Notes: Neutron-scattering studies of chromatin core particles in solutions containing various mixtures of D2O/H2O and small molecules (glycerol) show that the water closely associated (or bound) with the particles is largely in the outer DNA-rich regions. This confirms the fact that the particles contain a core composed of the hydrophobic regions of histone proteins.
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  • 34
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    Applied crystallography online 11 (1978), S. 514-519 
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    Notes: The use of the polymers tagged with heavy atoms in random positions along the chains (randomly tagged polymers) in small-angle X-ray scattering is proposed as a new method for measuring the chain conformations in concentrated solutions and in bulk polymers. The experimentally determined excess scattering from the tagged chains dispersed in the system is shown to be proportional to the scattering function of the hypothetical chains that have no tags but have the conformation of the tagged chains when the heavy atoms have sufficiently large scattering power. It has been experimentally verified that the effect of the tags on the chain conformation can be eliminated by the extrapolation of the apparent values, measured for a series of tagged polymers with various tag content, to zero tag content. The radii of gyration of the polystyrene chains (M = 1.1 × 105) in the bulk and in concentrated solutions in a good solvent and a θ-solvent have been determined. The chain dimension in a good solvent (toluene at 25°C) decreases rapidly first and then gradually approaches the unperturbed dimension with increasing polymer concentration. The dimension in a θ-solvent (trans-decalin at 21.2°C) is independent of the polymer concentration. The conformation of the polystyrene chains in the bulk was found to be a Gaussian coil.
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  • 35
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    Applied crystallography online 11 (1978), S. 525-530 
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    Notes: Small-angle X-ray scattering from oriented mats and random suspensions of polyethylene single crystals has been studied. A modification of the Guinier equation for platelets was derived to accommodate the two-phase nature of polymer lamellae. This modification also permitted the modelling of various degrees of interaction between lamellae and suspending media. Dried crystal mats show an increase in fold period on contact with potential solvents. Crystals which have never been dried show no evidence of penetration of the fold surface by the same liquids. Apparently the drying process causes a reorganization of the surface of the lamellae. Since the fold surfaces of crystals in suspension are unaffected by the liquids used, it is reasonable to assume a `tight' fold surface model. Crystallinities calculated with this model are in excellent agreement with recent differential scanning calorimetric data on crystals kept in suspension.
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  • 36
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    Applied crystallography online 11 (1978), S. 519-523 
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    Notes: The study of semi-dilute polyelectrolyte solutions by small-angle neutron scattering shows that the correlation function S(q) of all the chains presents a peak for a value q = qh of the scattering vector q. This is taken as evidence for some organization among the elongated polyions. This phenomenon has been observed for a fraction of polymethacrylic acid of very low molecular weight. The experiments show essentially: (1) the progressive vanishing of the peak with the addition of a neutral salt at constant polyelectrolyte concentration; (2) the variation of qh with the polyelectrolyte concentration c, qh ∝ c1/2; (3) the decrease of the peak intensity as the charge density of the chain increases. These results, which indicate the important role of the electrostatic interactions on this organization phenomenon, are discussed in terms of a lattice model and a recently proposed isotropic model.
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    Applied crystallography online 11 (1978), S. 535-539 
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    Notes: The concept of interface distribution functions [Ruland (1977). Colloid Polym. Sci. 255, 417–427] has been applied to the evaluation of the small-angle scattering of a series of polyethylene samples. The results indicate that the statistics of the lamellar stacking is not necessarily determined by next-neighbor interactions and that non-negligible volume fractions of amorphous domains outside the lamellar systems are observed in a number of samples.
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  • 38
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    Applied crystallography online 11 (1978), S. 551-557 
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    Notes: Crystallization of a linear polyethylene from the melt was followed in situ with the ORNL 10-meter SAXS camera [Hendricks (1978). J. Appl. Cryst. 11, 15–30]. Specimens were rapidly cooled in the X-ray beam in tandem birdcage furnaces from 1̃80°C to temperatures between 115 and 126°C, and scattering patterns were recorded for 30 s in 50 s intervals. Because of this relatively high-speed data acquisition rate, it was possible to obtain data in time periods which were short compared to the rate of change of the scattering patterns. The SAXS curves showed shapes which changed continuously during crystallization. The scattering curves are the superposition of a zero-angle peak and a Bragg maximum. Guinier plots of the zero-angle peak manifest scattering by lamellae of constant thickness. The thickness value is nearly that expected for crystallites at these crystallization temperatures. A model in which skeletal spherulites form and then later fill in is consistent with these results. Decreasing SAXS intensity and changing Bragg peak intensities indicate crystal thickening during cooling to room temperature.
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  • 39
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    Applied crystallography online 11 (1978), S. 558-563 
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    Notes: The microdomain structure of polystyrene-polyisoprene A-B type block copolymers was analysed by small-angle X-ray scattering (SAXS) as an ideal model system for a pseudo two-phase solid structure. The structure was analysed in terms of spatial distribution, size, and the interracial structure of the dispersed domains of one component (A segments) in the matrix of the other (B segments). The SAXS analyses were performed with two collimating systems, a Rigaku Denki camera (essentially a four-slit system with the addition of Soller slits) and a Kratky camera, which had widely different slit-length and slit-width weighting functions and was used to investigate instrumental effects, especially the role of the Soller slits in the obtaining of reliable desmeared intensity data in the tail of the SAXS curve. Comparison of the results indicated that the Soller slits facilitate the accurate evaluation of the interfacial thickness from the desmeared intensity data in the tail. The accuracy of the infinite slit-height approximation and the effect of truncating the higher-order terms in Ih (the intensity associated with the interphase) on the estimated interfacial thickness are discussed. The infinite slit-height approximation leads to values 25–35% smaller than the exact value (23 Å), and the truncation also leads to a value of the interfacial thickness smaller (19 Å) than the value (23 Å) based on the full analysis. The value obtained is in good agreement with the values predicted from the statistical-mechanical theories of block copolymers in bulk.
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    Applied crystallography online 11 (1978), S. 572-577 
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    Notes: Isothermal decomposition of a Au-60 at.% Pt alloy, quenched from the solid as well as the liquid state, has been studied with the D11 neutron small-angle scattering spectrometer at ILL, Grenoble. An incident neutron wavelength of 6.7 Å was used and measurements were carried out in the range of scattering vector [β = 4πsin θ/λ] from 2.8 × 10−2 to 21 × 10−2 Å−1. The preliminary results indicate that decomposition of this alloy at 550°C takes place by a spinodal mode, although deviations were observed from linear spinodal theory, even at very early times. Slower aging kinetics were observed in liquid-quenched alloy as compared with solid-quenched. Liquid quenching is more efficient in suppressing quench clustering than is solid quenching. However, liquid quenching yields an extremely fine-grained material, which thereby enhances discontinuous precipitation at grain boundaries, competing with decomposition in the bulk. A Rundman–Hilliard analysis was used for the early stages of the spinodal reaction to obtain an interdiffusion coefficient of the order of 10−16 cm2 s−1 at 550°C for the solid-quenched alloy.
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    Applied crystallography online 11 (1978), S. 564-568 
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    Notes: Two methods for performing small-angle electron scattering (SAES) experiments in transmission electron microscopes are described: the long-camera-length method and the selected-area-diffraction method. It is shown experimentally that angular resolutions of a few microradians and a few tenths of milliradians, respectively, are easily obtained by these two methods. A number of examples of the application of SAES to problems in materials science are presented. The use of new high-brightness electron sources is expected to produce significant increases in angular resolution, and the use of electron-energy analyzers will permit the separation of most of the inelastic contribution to the SAES intensity distribution.
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    Applied crystallography online 11 (1978), S. 583-588 
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    Notes: The creep properties in high-temperature alloys are dependent on the presence of second and higher phase components. In particular in the nimonic group of alloys the size distribution and concentration of the γ′ phase are crucial factors in the resistance to creep. A possible mechanism for degradation of creep resistance is the Ostwald ripening of the γ′ phase. A sample of Nimonic 105 (Trademark of Henry Wiggin and Co. Ltd) was subjected simultaneously to a stress of 500 MPa and a temperature of 800°C in situ in the beam using a specially developed cell on the small-angle scattering facility (D 11A) at the Institut Laue Langevin. Scattering patterns were taken continuously and spectra were recorded every ̃20 min; the macroscopic creep was also recorded. Measurements were taken up to the point of fracture. A peak in the intensity was observed at a scattering vector κ (= 4π sin θ/λ) of 0.005 Å−1 which is believed to be the lowest value at which such an effect has been observed in alloys. The observed variation in the scattering after treatment for multiple scattering and absorption corrections is discussed in terms of particle size and size distribution.
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    Applied crystallography online 11 (1978), S. 658-661 
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    Notes: A double-mirror monochromator in which one of the mirrors is considerably longer than conventionally employed has been used to collect diffraction data from crystalline tobacco mosaic virus (TMV) protein (unit cell: 224 × 228 × 174 Å). Considerable improvements in speed of data collection are observed over both customary focusing optics and pinhole collimation. Quantitative comparisons are made of the quality of data collected from TMV protein by this method and by the use of nickel-filtered radiation.
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    Applied crystallography online 11 (1978), S. 654-657 
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    Notes: Correlation between the symmetry of the two-dimensional flux-line lattice (FLL) and the real crystal lattice (CL) has been studied in a superconducting niobium sphere by means of small-angle neutron diffraction. A double-perfect-silicon-crystal diffractometer enabled precise determination of the three interfluxoid distances corresponding to the FLL basic cell. A systematic study of the anisotropic behavior was made as a function of temperature and magnetic field amplitude for fields parallel to a few high-symmetry CL axes in the (1{\bar 1}0) plane. In addition, at T = 4.30 K progressive deformation of the FLL was studied as the sample was rotated in the (1{\bar 1}0) and (100) planes. The FLL was found to be hexagonal only for fields parallel to the threefold CL axis. Twofold symmetry prevailed for other CL directions in these planes except near the fourfold axis, where either of two distorted triangular lattices existed, preserving the reflection symmetry in composite, but not individually. When compared to current models for fluxoid-CL interactions, the present results show that no theory predicts the observed behavior quantitatively under general conditions, but some models agree well for certain high-symmetry CL axes.
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    Applied crystallography online 11 (1978), S. 669-669 
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    Notes: Some multiplicities for the Laue class \bar 31m are not correct in several standard texts.
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    Applied crystallography online 11 (1978), S. 650-653 
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    Notes: The double-perfect-crystal small-angle diffraction technique enables measurement of scattering angles to within an accuracy of 0.3′′ of arc. At a wavelength of 2.55 Å, this provides a resolution of 3 × 10−6 Å−1 in the scattering vector. This technique has been used to study the anisotropic behavior of the critical parameters B0 and Hc1, characteristic of the first-order magnetic phase transition which occurs in low-κ type II superconductors. Magnetic fields were applied parallel to several crystal axes in the (1{\bar 1}0) and (100) planes of a large single-crystal sphere of pure niobium, resulting in well defined flux-line lattices (FLL). Measurement of the FLL cell area in the intermediate, mixed-state-field region gives the equilibrium flux density B0, which results from an attractive interaction between fluxoids. In addition, field variation of the scattered neutron intensity allows measurement of the transition field between the mixed state and intermediate mixed state. This transition field is related to the lower critical field Hc1 and enables its determination to a precision of 0.2%. Data at T = 4.3 K display a small anisotropic effect of about 2% in B0 and 1% in Hc1. Although orientation effects of this magnitude are difficult to resolve by bulk measurements, the neutron data are in accord with magnetization data. The temperature dependence of these parameters is found to be in qualitative but not quantitative agreement with current theoretical models.
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    Applied crystallography online 11 (1978), S. 669-669 
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    Notes: An amendment to a computer program for determining multiplicities of powder reflections [Rouse & Cooper (1977). J. Appl. Cryst. 10, 134–135] has been made to correct an error in the multiplicity values given for some reflections for space groups with {\bar 3}1m Laue symmetry, which exists in some of the standard texts.
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    Applied crystallography online 11 (1978), S. 662-668 
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    Notes: A method is described for precision measurement of lattice parameters in cubic crystals, interplanar spacings and angles between crystallographic directions for single crystals of any system. The minimum measurable values of angle between crystallographic directions, Δd/d and Δa/a have been found to be ̃105 rad, ̃3 × 10−5, and ̃5 × 10−5, respectively.
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    Applied crystallography online 11 (1978), S. 670-671 
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    Notes: The cell constants of recrystallized diphenylsilanediol were refined from precision powder data taken with Cr Kα1 (2.28962 Å): a = 14.493 (5); b = 15.012 (6); c = 9.897 (6) Å; α = 100.84 (9); β = 100.01 (5); γ = 120.77 (5); U = 1721.6 Å3; Z = 6; Dm (25°C) = 1.255 (3); Dx = 1.252 g cm−3.
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    Applied crystallography online 11 (1978), S. 671-671 
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    Applied crystallography online 11 (1978), S. 673-674 
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    Applied crystallography online 11 (1978), S. 675-680 
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    Notes: The simulation of the photography remains the worst part in the calculation of transmission electron micrographs and X-ray topographs. Storage displays have been used to enhance this part of the process and the different possibilities of these screens studied. The quality of all simulations has been substantially increased by using these displays, which are now in common use.
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    Applied crystallography online 11 (1978), S. 684-687 
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    Topics: Geosciences , Physics
    Notes: A high-resolution energy-dispersive diffractometer is described, which uses a synchrotron source and a scanning channel-cut silicon crystal. The technique is demonstrated with a powdered sample of BaTiO3 and analysis of the profiles demonstrates the anomalous particle-size effect reported by Anliker, Brugger & Känzig [Helv. Phys. Acta (1954), 27, 99–124].
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    Applied crystallography online 11 (1978), S. 719-720 
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    Applied crystallography online 11 (1978), S. 720-720 
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  • 56
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    Applied crystallography online 21 (1988), S. 4-10 
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    Notes: A fixture is described for collecting X-ray diffraction data from biomolecule crystals under gas pressures up to 300 atm (30 MPa). The fixture is completely portable and can be used on conventional diffractometers. Normal procedures for crystal mounting, alignment and data collection require only slight modification. A test data set of the protein sperm whale metmyoglobin under a gas pressure of 145 atm of N2 gas has been collected to a nominal resolution of 2.0 Å using Cu Kα radiation and refined to an R-factor of 16.2%. Data collection beyond 2.0 Å resolution is hampered by the presence of strong powder diffraction from the beryllium shroud.
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  • 57
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    Applied crystallography online 21 (1988), S. 15-22 
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    Notes: Aspects of the optics of the energy-dispersive scheme for X-ray absorption spectroscopy are discussed. The idea of a set of monochromatic focus points related to a set of local Rowland circles is introduced to account for the source-size effect on the energy resolution. It is shown that there exists an optimized location of the position-sensitive detector where the energy resolution is no longer source-size dependent. In addition, the stability of the dispersive optical system has been estimated and a 10 meV energy-scale reliability is currently achieved.
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    Applied crystallography online 21 (1988), S. 38-41 
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    Notes: The determination of the full three-dimensional stress tensor in a specimen by X-ray diffraction requires that the strain be measured with the sample tilted in both a positive and a negative sense for different rotations of the sample in its own plane. The error introduced in the measured strain as a function of the position of the specimen relative to the X-ray diffractometer axis is investigated and it is shown that the negative tilt values are more sensitive to sample position than the positive tilt values. The determination of the shear stress components uses the difference between the measured strain at equivalent positive and negative tilts and hence it is shown that displacement of the sample could lead to incorrect deductions concerning the presence and magnitude of the shear stress components.
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    Applied crystallography online 21 (1988), S. 10-15 
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    Notes: Syncrystallization can be analysed through a new approach: the determination of the `tensor of compositional deformation'. It is a convenient way to take structural anisotropy into account and to point out the directions of strongest and weakest modifications of the intermolecular interactions due to the substitution process. The example of 2-chloronaphthalene-2-methylnaphthalene alloys is given in order to illustrate the interest of this new tool.
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    Applied crystallography online 21 (1988), S. 28-33 
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    Notes: The first test of a position-sensitive photomultiplier in a thermal neutron diffraction topography experiment is reported: a spatial resolution was obtained of ∼200 μm in FWHM over a sensitive area of size ∼8 × 8 mm (∼1600 pixels) and a detection efficiency of the order of 15% when using a 0.25 mm thick ZnS–LiF (NE 426) scintillator. The advantages of this detector, its foreseeable improvements, and the scientific problems it could help to solve are discussed.
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    Applied crystallography online 21 (1988), S. 76-76 
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    Applied crystallography online 21 (1988), S. 79-85 
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    Notes: A laboratory dispersive mode spectrometer, capable of operating in either the analysing crystal transmission mode or a reflection mode, is described. Extended X-ray absorption fine structure (EXAFS) spectra of Re and ReO2, obtained in the transmission mode, compare favourably with those from a scanning spectrometer at a synchrotron source. Factors affecting resolution, intensity and background in this transmission mode are discussed. Experiments with asymmetric reflection geometries, which have shown both improved resolution for X-ray absorption near edge structure (XANES) and reduced collection times, are reported. Methods of reducing backgrounds due to multiple Bragg reflections and Compton scattering are proposed.
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    Applied crystallography online 21 (1988), S. 102-105 
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    Notes: From studies on six petrographic components of Polish coals by the radial distribution function method and the interatomic distances calculated from them the proportions of atoms with sp2 and sp3 hybridization and the extent of units with sp3-type structure were determined. From these data and the results of the pair-function analysis performed in paper I [Grigoriew (1988). J. Appl. Cryst. 21, 97–101], the model interpretation of the structure of these materials was carried out by matching experimental and model pair functions P(r). The model was defined as an average structural unit which scatters X-rays coherently. It appears that such units in these materials are larger than previously expected and for vitrinites and fuzinites they are in the form of turbostratic layers. The process of formation of stacks of layers was observed in components with the lowest degree of ordering.
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    Applied crystallography online 21 (1988), S. 218-223 
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    Notes: The general principles of single- and double-crystal spectrometers are described using the three-dimensional DuMond diagram and new formulae for the resolution of the spectrometers are deduced. A method for measuring the fine structure of spectral lines with high precision is suggested and a generalized method of refraction correction is discussed. The Cu Kα line profile is measured carefully by double-crystal spectrometers using (nS, nS) and (nV, nR) arrangements, and a hump is found unambiguously on the long-wavelength side of the Cu Kα1 line.
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    Applied crystallography online 21 (1988), S. 311-316 
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    Notes: Measured orientation relationships between neighbouring grains in single-phase α- and β- and dual-phase α + β-brasses are analysed by means of the χ2-test. The orientation relationships are characterized by the three Euler angles and hence can be represented as points in orientation space. A description of the symmetry relations of equivalent points in this space is given and then the distribution function for random orientation relationships is derived. This distribution is compared with the distribution of the measured orientation relationships using only a single χ2-test for each boundary type. The results of the tests are the same as obtained from the analysis of axis-angle pairs, in which case twoχ2-tests are necessary. None of the measured distributions is random.
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    Applied crystallography online 21 (1988), S. 355-362 
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    Notes: The heavy-atom labeling method is applied to small-angle X-ray scattering (SAXS) based on contrast variation in order to derive information on the inner structure of proteins. The formulation of the contrast variation is extended to express explicitly the contribution of the bound heavy atoms to SAXS. The present method reveals two important features concerning bound heavy atoms, namely their number and their distribution. The application of this method to solubilized bacteriorhodopsin (bR) with iodination revealed the following characteristics of structure. The number of bound iodine atoms is 20, indicating that the solubilized bR is composed of a trimer of bR molecules. The mean square distance between the iodine position and the center of the trimer is about 1660 Å2, indicating that the most active tyrosine residues are located near the outer rim of a bR trimer. The distribution of iodine atoms is symmetric about the center.
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    Applied crystallography online 21 (1988), S. 369-371 
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    Notes: The program of multislice calculations written by Ishizuka [User's Manual of Multislice and Image-Simulation Programs (1982). Center for Solid-State Science, Arizona State University, USA] for large central computers has been successfully transferred to the 16-bit PDP-11/24 minicomputer, without disturbing its features and capacities. The structural modifications of the transferred program lead to a great reduction of the calculation time for running on the PDP-11/24. The function of halftone output of calculated diffraction patterns has been developed and added to the package. This package proves to be especially effective in image simulations for complex structures (medium or large unit cells) on a minicomputer.
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    Applied crystallography online 21 (1988), S. 380-381 
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    Applied crystallography online 21 (1988), S. 381-382 
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    Applied crystallography online 21 (1988), S. 382-382 
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    Applied crystallography online 21 (1988), S. 384-384 
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    Applied crystallography online 21 (1988), S. 406-415 
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    Notes: Pseudo-hexagonally twinned orthorhombic crystals generally exhibit three domain variants related by mirror planes or (approximately) by 120° rotations. The reciprocal lattices of the three domains coincide partially. Those reciprocal-lattice points hkl with h + k = 2N coincide or are split depending upon the deviation of the a:b ratio from orthohexagonality (i.e. a:b = tan 60°). With (white-beam) synchrotron radiation these domains are simultaneously imaged by Laue X-ray topography for these reflections. Lattice points hkl with h + k = 2N + 1 are `single' and only one of the three domain variants is imaged in such reflections. Two examples of these twins are presented, LiNH4SO4 and (NH4)2SO4. In the former case the lattice is closer to the ideal ratio a:b = tan 60° than the latter. These two cases are contrasted. Both materials are subject to some extent to radiation damage in the synchrotron beam.
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    Applied crystallography online 21 (1988), S. 416-425 
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    Notes: It is demonstrated with computer simulations that a bimodal distribution (narrow and broad) of reflection profile broadening effects, such as crystallite size and microstrain, can lead to several spurious results when the profiles are modeled by single pseudo-Voigt functions in Rietveld refinement (RR), e.g. mixing parameter η 〉 1 (`super-Lorentzian'), a few observed data points lying consistently above the calculated peak maxima for some reflections, misrepresentation of the background level and shape, and in special cases well defined small observed peaks not seen in the calculated pattern as though they belonged to an additional minor phase. With a bimodal model (two pseudo-Voigt functions) the RR's accurately returned the profile, mixing, and background parameters used in the data synthesis both without and with counting statistical fluctuations simulated in the data. The RR method thus demonstrates remarkable ability to sort out complex specimen characteristics when accurate modeling functions are used.
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    Applied crystallography online 21 (1988), S. 452-457 
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    Notes: The crystal structure of α-CrPO4, previously solved from high-resolution synchrotron powder X-ray data, has been refined by the Rietveld method. The peak shape variation is well fitted by a convolution of Gaussian and Lorentzian terms, which incorporate both instrumental and sample-broadening contributions. The structure has also been refined using medium-resolution neutron diffraction data, and the results of the two experiments are compared with a reported single-crystal study. The three sets of coordinates are found to be in good agreement, demonstrating the potential of structure determination and refinement using powder data.
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    Applied crystallography online 21 (1988), S. 398-405 
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    Notes: A range of `normal' divergence (0.25, 1.0°) and receiving (0.1, 0.2, 0.4 mm) slit dimensions has been used to determine their effect on the peak profile parameters obtained by Rietveld analysis of X-ray powder diffraction data from a conventional X-ray source. The instrument is a standard Bragg–Brentano diffractometer equipped with a diffracted-beam monochromator and Soller slits. The instrumental profile characteristics are provided by a sample of coarsely crystalline Si, and the effects of small particle size and isotropic strain by fluorite, CaF2. Results are discussed for refinements of the full diffraction patterns (24 to 140°), and of the individual peaks at 28, 47 and 88° in each pattern. The use of a wide receiving slit aperture (i.e. 0.4 vs 0.1 mm) provides (i) increased peak intensities, (ii) much improved values of the Rietveld agreement indices (especially at low angles), (iii) slightly more Gaussian peak shapes, and (iv) slightly wider peaks. A wider divergence slit (i.e. 1.0 vs 0.25°) has only a small effect on the refinement results. The Voigt and pseudo-Voigt peak shape models are seriously deficient for low-angle peaks when axial divergence is larger than about 2°, but are otherwise satisfactory. The CaF2 peaks are wider and more Lorentzian in character (at high angles) than those obtained for Si, owing to the presence of very small (350 Å) and strained crystals; in this case, the peak shape/width characteristics can be adequately modelled at all diffraction angles, regardless of axial divergence. Quantitative information about crystal size and strain can be extracted from the CaF2 pattern by direct incorporation of the instrumental profile into the parameters of the Voigt function during Rietveld refinement.
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    Applied crystallography online 21 (1988), S. 438-451 
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    Notes: Experimentally measured scattering data differ from theoretical curves because of departures from point geometry in a real instrument. In a small-angle neutron scattering (SANS) instrument, there are essentially three contributions to the smearing of an ideal curve: (1) the finite divergence of the beam, (2) the finite resolution of the detector, and (3) the poly chromatic nature of the beam. Where the scattering is azimuthally symmetric about the incident beam, indirect Fourier transform (IFT) methods may be used not only to smear an ideal scattering curve, but also to desmear an observed pattern. For experiments where the assumption of azimuthal symmetry cannot be made, alternative procedures based on Monte Carlo (MC) techniques have been developed which simulate the smearing of a given theoretical scattering function. This procedure permits the evaluation of smearing effects in anisotropic systems. Both IFT and MC procedures are illustrated with a range of applications from data taken on the 30 m SANS facility at Oak Ridge National Laboratory. It is shown that for experiments with scattering dimensions 〈 200 Å smearing effects are small (〈 5%) and that dimensions up to ̃1200 Å may be accurately resolved after proper evaluation of resolution effects. The procedures described may also be extended to include small-angle X-ray scattering, and an example of one such application is given.
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    Applied crystallography online 21 (1988), S. 471-478 
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    Notes: The development of multidetectors for use in X-ray and neutron scattering experiments has created an interest in methods for integrating Bragg peaks in three-dimensional data arrays representing intensity scattered from single crystals. A method of using a priori information, extracted from the strongest peaks, to obtain statistically optimum results has been developed at the Institut Laue–Langevin (ILL), Grenoble. The method is outlined in this paper and results of its application to neutron diffraction are discussed.
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    Applied crystallography online 21 (1988), S. 496-503 
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    Notes: Conventional methods and problems of differential X-ray spectroscopy using characteristic radiation are briefly described. The principles of energy-dispersive methods of differential spectroscopy are then described, covering both high- and low-resolution systems. By using digital electronics to control the modulation, errors associated with timing are reduced to well below those associated with the random nature of X-ray emission. By delaying demodulation until the final counting stage, thus using only one chain of electronic processors, errors associated with two chains of different characteristics are eliminated. Stability of the source is no longer an important criterion and the method is ideally suited for use with synchrotron radiation sources where beam intensity decays with a half-life of a few hours. It is also possible to derive the modulation cycles from the oscillator that controls the electron bunches in the storage ring, thereby making possible time-resolved and phase-sensitive studies.
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    Applied crystallography online 21 (1988), S. 512-515 
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    Notes: The restrained least-squares refinement procedure PROLSQ of Hendrickson & Konnert [Hendrickson (1985). Methods in Enzymology, Vol. 115, edited by H.W. Wyckoff, C. H.W. Hirs & S.N. Timasheff, pp. 252–270. Orlando: Academic Press] has been implemented on a 30-processor Sequent Balance 21000 shared-memory parallel processor. The adaptation of PROLSQ to a general-purpose parallel computer offers the potential of performance increase as the physical limits are approached in traditional sequential and vector processing hardware.
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    Applied crystallography online 21 (1988), S. 524-529 
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    Notes: A method for estimating the interface widths in multiple quantum well (MQW) structures is described. Generally it has been assumed that the average interface shapes on each side of a quantum well are the same, yet there is no reason to assume that this is correct. The method presented here can predict the interface profile on both sides of a quantum well and therefore detect the presence of any asymmetry. The results are compared with the more familiar predictive Fourier transform approach and qualitative agreement is observed, although the latter cannot predict any asymmetry. Deducing the interface width from the predictive Fourier transform method can be difficult because of series termination effects and could possibly be misleading if insufficient satellites are measured. The limitations are essentially by-passed with the described approach. A simple method for deriving period variations is also given and in the example presented this amounts to about two monolayers. The interface widths in this example are 6.5 and 5.4 monolayers and these best-fit values give an R-factor just above that which could be expected from the data. Also the fit for two similarly graded interfaces results in a significant worsening in the agreement.
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    Applied crystallography online 21 (1988), S. 835-839 
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    Notes: Small-angle neutron scattering measurements have been performed on a three-component microemulsion system consisting of water, hexane and didodecyl-dimethylammonium bromide. For a water-to-surfactant weight ratio of 0.95 and less than 5 wt% surfactant, these measurements are best fit by a model with a Gaussian size distribution of spherical water droplets in hexane. The average water core radius is determined to be about 2.9 nm. On addition of water while the same water-to-surfactant ratio is maintained, there is some evidence that the basic unit of the microstructure remains a sphere with the same radius. The interaction between the spheres is found to be attractive, and the spheres may be connected for volume fractions of water larger than 5%.
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    Applied crystallography online 21 (1988), S. 864-869 
    ISSN: 1600-5767
    Source: Crystallography Journals Online : IUCR Backfile Archive 1948-2001
    Topics: Geosciences , Physics
    Notes: Small-angle scattering has been used to follow the heat-induced smoothing of rough fumed silica particles by viscous sintering. When analyzed by a fractal surface model, the surfaces evolved from a fractal dimension of 2.5–2.7 to 2.0. The specific surface area σ(r) for a given resolution r could be described by the simple law σ(r) = σ0(r/r*)2−D, where σ0 is the specific surface area for smooth particles and r* is a characteristic length that is the same for all the fumed silicas studied and is comparable to the primary particle size. This is the first indication of a universal relation between fractal surfaces, albeit within a closely related class of materials.
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  • 83
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    Applied crystallography online 21 (1988), S. 883-885 
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    Source: Crystallography Journals Online : IUCR Backfile Archive 1948-2001
    Topics: Geosciences , Physics
    Notes: A cell dynamical system (CDS) is defined by a map which takes a configuration on a lattice at a time t to a configuration at time t + 1. Phase-ordering dynamics, block copolymers etc. have been modeled in terms of CDS. With the phase-ordering dynamics model, the scaling exponent (and the universal function) for the form factor in the scaling regime and the effect of noise on these have been studied. It is clearly observed that, for the ordering process in the (critically quenched) conserved order parameter case, the scaling exponent crosses over from ̃0.28 to ̃0.33. This crossover is delayed with the introduction of noise, with larger amplitudes of noise causing a greater delay.
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  • 84
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    Applied crystallography online 21 (1988), S. 905-910 
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    Source: Crystallography Journals Online : IUCR Backfile Archive 1948-2001
    Topics: Geosciences , Physics
    Notes: X-ray synchrotron powder data were collected from a capillary sample of a small-molecule organic peptide compound, glycylglycine (NH2CH2CONHCH2COOH) by step-scanning at 1° intervals with a linear position-sensitive detector covering an angular range of 2.7° in order to test the feasibility of recording a high-resolution pattern and using the data for Rietveld analysis. Appropriate corrections for detector linearity and position were implemented, and comparison with a diagram recorded with a single scintillation detector and a crystal analyser system showed similar quality for the two sets of data. A detailed comparison of the refined atomic coordinates and those of an earlier X-ray single-crystal study showed the estimated standard deviations to be significantly underestimated in both refinements. A linear detector should be particularly useful for small samples and capillary specimens of moderately absorbing materials.
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  • 85
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    Applied crystallography online 21 (1988), S. 935-942 
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    Source: Crystallography Journals Online : IUCR Backfile Archive 1948-2001
    Topics: Geosciences , Physics
    Notes: Computer simulation of 2H to 6H transformation by non-random insertion of layer displacement faults in a random space and time sequence has been performed. The model employed by Pandey, Lele & Krishna [Proc. R. Soc. London Ser. A, (1980), 369, 435–477], which is based on the sequential insertion of layer displacement faults, allows faulting of one-third of the total number of layers on completion of the transformation. The results of the simulation show that the transformation gets arrested because of the formation of interfaces by the impingement of independently formed 6H regions and that the fraction of faulted layers which can be inserted is just 0.276. It is shown that these interfaces are such that they do not lead to any broadening of the 6H reflections common with 2H. While this is in agreement with the theoretical predictions of Pandey et al., the diffuse intensity distribution calculated for the arrested state shows significant departures.
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  • 86
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    Applied crystallography online 21 (1988), S. 967-971 
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    Source: Crystallography Journals Online : IUCR Backfile Archive 1948-2001
    Topics: Geosciences , Physics
    Notes: Stroboscopic X-ray topography has been performed to observe the different states of acoustic vibrations in quartz resonators with a time resolution of 1 ns. These experiments have been made at LURE (Orsay, France) using the pulsed light delivered by the DCI storage ring. The studied resonators have shown that the vibration is affected by the nature, the density and the distribution of the defects.
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  • 87
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    Applied crystallography online 21 (1988), S. 991-991 
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    Source: Crystallography Journals Online : IUCR Backfile Archive 1948-2001
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  • 88
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    Applied crystallography online 21 (1988), S. 993-993 
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    Source: Crystallography Journals Online : IUCR Backfile Archive 1948-2001
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  • 89
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    Applied crystallography online 21 (1988), S. 983-984 
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    Source: Crystallography Journals Online : IUCR Backfile Archive 1948-2001
    Topics: Geosciences , Physics
    Notes: Version 1.1 of MISSYM is now available and the following new features have been added: a HELP facility to guide and caution the user; the input of a distance tolerance for axes and planes, and a separate tolerance for inversion centers and translations; the possibility of flagging atomic positions as `possibly disordered'; the possibility of allowing for errors in assigning chemical types; the possibility to extract the symmetry for a single atom type; the option to run from sensible default values. This version is more flexible than, but not quite as fast as, the original. Only one-third of structures require the full application of MISSYM because simple conditions, simultaneously satisfied by about two-thirds of the structures published recently, rule out the possibility of extra symmetry in the model. The existence of an efficient computer program for flagging the cases of overlooked symmetry should not give a false sense of security or be used to justify short cuts in the preliminary study of crystal symmetry.
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  • 90
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    Applied crystallography online 21 (1988), S. 572-576 
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    Source: Crystallography Journals Online : IUCR Backfile Archive 1948-2001
    Topics: Geosciences , Physics
    Notes: A suite of Fortran computer programs is described which generates simplified stereo schematic drawings (cartoons) of protein structures similar to the hand-drawn figures of Richardson [Methods Enzymol. (1985), 115, 359–380]. α-helices are represented by helical ribbons, β-strands by twisted arrows and random coils and reverse turns by smooth `ropes'. Such drawings are useful in visualizing the folding and topology of proteins.
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  • 91
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    Applied crystallography online 21 (1988), S. 581-581 
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  • 92
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    Applied crystallography online 21 (1988), S. 602-612 
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    Source: Crystallography Journals Online : IUCR Backfile Archive 1948-2001
    Topics: Geosciences , Physics
    Notes: To obtain adequate intensity in small-angle X-ray and neutron scattering measurements, the apertures that define the incident and scattered beams often must be made so large that the measured intensity is an average over an appreciable interval of scattering angles. Allowance must frequently be made for the resulting distortion of the measured scattering curve. A technique previously developed by Hendricks & Schmidt [Acta Phys. Austriaca (1967), 26, 96–112; Acta Phys. Austriaca (1973), 37, 20–30] for describing collimation effects is outlined. This method makes use of a function called the `weighting function', which specifies the width of the interval over which the intensity is averaged and indicates the emphasis given to scattering angles within this interval. A new calculation of the weighting function for `pinhole' collimating systems, which employ circularly symmetric apertures instead of long narrow slits, is presented. Several techniques for performing collimation corrections are described, and a review is given of results that several workers have recently obtained in studies of collimation effects in pinhole systems.
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  • 93
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    Applied crystallography online 21 (1988), S. 639-644 
    ISSN: 1600-5767
    Source: Crystallography Journals Online : IUCR Backfile Archive 1948-2001
    Topics: Geosciences , Physics
    Notes: The multiple scattering of neutrons in small-angle neutron scattering experiments has been studied using the technique of Monte Carlo simulation. As a test of the approach investigations have been performed on strongly scattering samples of a system of monodisperse spheres in vacuo: the results are in excellent agreement with semianalytic calculations by Schelten & Schmatz [J. Appl. Cryst. (1980), 13, 385–390]. The scattering by systems of monodisperse spheres embedded in a medium has also been studied: the standard procedure for subtraction of the scattering by the medium slightly oversubtracts the multiple scattering due to the medium alone. The wavelength dependence of the single and multiple scattering in light water has been estimated and compared with experimental measurements by groups at the Institut Laue–Langevin, Grenoble, France.
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  • 94
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    Applied crystallography online 21 (1988), S. 669-674 
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    Source: Crystallography Journals Online : IUCR Backfile Archive 1948-2001
    Topics: Geosciences , Physics
    Notes: The method of contrast variation has its origins in microscopy and the numerous stains and staining techniques used to improve the visibility of particular structures. The microscopic method has remained largely qualitative, but effective, especially in cell biology. With scattering techniques where images cannot be formed, one of the first uses of contrast variation was by Bragg & Perutz [Acta Cryst. (1952), 5, 277–283] in their early X-ray diffraction studies of haemoglobin crystals, but extensive applications began twenty years later in studies of macromolecules in solution. At this time a theoretical basis and quantitative method were developed, and neutron scattering as well as X-ray scattering from macromolecules became possible. The value of hydrogen/ deuterium (H/D) changes for contrast variation was quickly recognized, and neutron scattering with H/D manipulation is now the dominant form of contrast variation used in scattering experiments.
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    Applied crystallography online 21 (1988), S. 675-680 
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    Topics: Geosciences , Physics
    Notes: Small-angle scattering is a technique capable of supplying only limited information about the structures of biological materials. Nevertheless, small-angle methods can contribute significantly to our understanding of biological systems when appropriately applied. Several successful applications of small-angle scattering to biological problems are discussed to illustrate the ways in which the method can be used to good effect.
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  • 96
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    Applied crystallography online 21 (1988), S. 692-700 
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    Topics: Geosciences , Physics
    Notes: Small-angle neutron scattering has been used to investigate the chain conformation of the hard and soft segments in short-segment polyether–polyester and polyether–polyurethane materials. The method of phase-contrast matching was used to eliminate the coherent neutron scattering due to the two-phase microstructure in these materials. The partial deuterolabelling necessary for this technique also provides a neutron scattering contrast between labelled and unlabelled segments. The structure factor for each segment type is determined from the coherent scattering from such deuterolabelled materials. In all of the materials examined, the poly(tetramethylene oxide) (PTMO) soft segment was found to be in a slightly extended conformation relative to bulk PTMO at room temperature. Upon heating, the PTMO segments contracted to a more relaxed conformation. In one polyether–polyurethane sample, the radius of gyration of the PTMO segment increased again at high temperatures, indicating phase mixing. The hard-segment radii of gyration in the polyether–polyester materials were found to increase with temperature, indicating a transition from a chain-folded conformation at room temperature to a more extended conformation at higher temperatures. The radius of gyration of the whole polyether–polyester chain first decreased then increased with temperature, indicative of the combined effects of the component hard- and soft-segment chain conformation changes. The hard-segment radius of gyration in a polyether–polyurethane was observed to decrease with temperature.
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  • 97
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    Applied crystallography online 21 (1988), S. 737-743 
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    Source: Crystallography Journals Online : IUCR Backfile Archive 1948-2001
    Topics: Geosciences , Physics
    Notes: The physics of simple colloidal systems is usually dominated by three independent length scales: the particle size, the average interparticle distance, and the range of the interparticle potential. The dispersed particles typically have characteristic dimensions in the range 5–100 nm, often with spherical or cylindrical symmetry. Dispersion densities vary over volume fractions ranging from 0.5 to 10−4, with the corresponding mean interparticle distances ranging from about 1 to 10 diameters (in spherical systems). The interaction potential may be very short ranged (hard sphere), very long ranged (Coulomb or dipolar), or anywhere in between (screened Coulomb), and the correlations exhibited in the dispersion may be gas-like, liquid-like or crystalline, depending on the range of the potential relative to the interparticle distance. This rich phase behaviour is responsible for the remarkable importance of colloidal studies in many areas of condensed-matter physics and biophysics, but it poses often intractable problems in developing the statistical mechanical descriptions necessary for an understanding of scattering data from colloids. A review is presented of the considerable recent progress in this field, in the context of small-angle neutron scattering experiments on colloids in which the potentials are dominated by either screened Coulomb or magnetic dipolar interactions; in the case of magnetic colloids (ferrofluids), the use of polarization analysis will also be discussed.
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  • 98
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    Applied crystallography online 21 (1988), S. 777-780 
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    Source: Crystallography Journals Online : IUCR Backfile Archive 1948-2001
    Topics: Geosciences , Physics
    Notes: Time-dependent anisotropic small-angle neutron scattering (SANS) patterns of rodlike micelles in a shear gradient Γ, suddenly changing its value from zero to a constant value, are presented. The time resolution of the experiment was 100 ms. By an analysis of the steady-state pattern a rotational diffusion coefficient D of ̃2 s−1 is deduced. Furthermore it is shown that in a well aligned sample the SANS pattern is sensitive to the rod length distribution in spite of correlation peaks which are caused by repulsive inter-micellar interaction.
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    Applied crystallography online 21 (1988), S. 818-822 
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    Source: Crystallography Journals Online : IUCR Backfile Archive 1948-2001
    Topics: Geosciences , Physics
    Notes: Small-angle scattering measurements from protonated polystyrene (PSH) and mixtures of deuterated and protonated toluene (C7D8 and C7H8) are presented. The data are compared with the simple `quasi-isotropic' Vineyard model, corrected for third- and higher-order multiple scattering by Monte Carlo methods. This model agrees surprisingly well with all protonated samples over the total thickness range considered. The empirical Jacrot g factor in the expression I(Q) = K(1 − T)g(λ)/4π works well over a more limited thickness range. The effective differential cross section can be calculated using Melkonian total cross sections, and this gives an absolute scattered intensity which is 9% lower than a calibration performed at Oak Ridge National Laboratory. Scattering from oversize samples must be back shielded. The model requires an anisotropic kernel to predict D/H toluene mixtures.
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    Applied crystallography online 21 (1988), S. 828-831 
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    Source: Crystallography Journals Online : IUCR Backfile Archive 1948-2001
    Topics: Geosciences , Physics
    Notes: Time-resolved light-scattering studies have been undertaken to elucidate the dynamics of phase dissolution in aqueous HPC (hydroxypropylcellulose) liquid-crystalline solutions. HPC solutions phase separate during heating, but return to a single phase upon cooling. A temperature versus composition phase diagram has been established on the basis of cloud point measurements. The behavior of phase separation resembles a lower critical solution temperature, but there is a discontinuity in the curve without a clear minimum or critical point. In the temperature quench experiments the scattering peak decays with time but its position remains stationary, which is in good accord with the linear theory. The kinetic behavior of phase dissolution of 10 wt% aqueous HPC solutions has been quantitatively analyzed in the context of the linear theory.
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