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  • 04.08. Volcanology  (8)
  • Salinity  (5)
  • Elsevier  (10)
  • American Geophysical Union  (3)
  • Public Library of Science
  • 2015-2019  (13)
  • 1940-1944
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  • 1
    Publication Date: 2021-06-30
    Description: Soil CO2 flux and 222Rn activity measurements may positively contribute to the geochemicalmonitoring of active volcanoes. The influence of several environmental parameters on the gas signals has been substantially demonstrated. Therefore, the implementation of tools capable of removing (or minimising) the contribution of the atmospheric effects from the acquired time series is a challenge in volcano surveillance. Here, we present 4 years-long continuousmonitoring (fromApril 2007 to September 2011) of radon activity and soil CO2 flux collected on the NE flank of Stromboli volcano. Both gases record higher emissions during fall–winter (up to 2700 Bq * m−3 for radon and 750 g m−2 day−1 for CO2) than during spring–summer seasons. Short-time variations on 222Rn activity aremodulated by changes in soil humidity (rainfall), and changes in soil CO2 flux that may be ascribed to variations in wind speed and direction. The spectral analyses reveal diurnal and semi-diurnal cycles on both gases, outlining that atmospheric variations are capable to modify the gas release rate fromthe soil. The long-termsoil CO2 flux shows a slow decreasing trend, not visible in 222Rn activity, suggesting a possible difference in the source depth of the of the gases, CO2 being deeper and likely related to degassing at depth of the magma batch involved in the February–April 2007 effusive eruption. To minimise the effect of the environmental parameters on the 222Rn concentrations and soil CO2 fluxes, two different statistical treatments were applied: the Multiple Linear Regression (MLR) and the Principal Component Regression (PCR). These approaches allow to quantify theweight of each environmental factor on the two gas species and showa strong influence of some parameters on the gas transfer processes through soils. The residual values of radon and CO2 flux, i.e. the values obtained after correction for the environmental influence, were then compared with the eruptive episodes that occurred at Stromboli during the analysed time span (2007–2011) but no clear correlations emerge between soil gas release and volcanic activity. This is probably due to i) the distal location of the monitoring stations with respect to the active craters and to ii) the fact that during the investigated period no major eruptive phenomena (paroxysmal explosion, flank eruption) occurred. Comparison of MLR and PCR methods in time-series analysis indicates thatMLR can bemore easily applied to real time data processing in monitoring of open conduit active volcanoes (like Stromboli) where the transition to an eruptive phase may occur in relatively short times.
    Description: This researchwas partly funded by ItalianMinistry of University and Research (MIUR) and by University of Torino-Fondazione Compagnia di San Paolo. Additional fundswere provided by the Italian “Presidenza del Consiglio dei Ministri–Dipartimento della Protezione Civile (DPC)” through the DEVnet Project (a cooperative program between the Departments of Earth Sciences of the University of Torino and the University of Florence) and through the “Potenziamento Monitoraggio Stromboli” project. Additional funds for improving our computing hardware were provided by Fondazione Cassa di Risparmio di Torino.
    Description: Published
    Description: 65-78
    Description: 4V. Processi pre-eruttivi
    Description: JCR Journal
    Keywords: Stromboli volcano ; Continuous geochemical monitoring ; Soil CO2 flux ; Radon activity ; Environmental parameters ; Time series analyses ; 04.08. Volcanology
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
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  • 2
    Publication Date: 2022-10-26
    Description: Author Posting. © American Geophysical Union, 2019. This article is posted here by permission of American Geophysical Union for personal use, not for redistribution. The definitive version was published in Journal of Geophysical Research-Oceans 124(4), (2019):2861-2875, doi: 10.1029/2018JC014175.
    Description: Strong variability in sea surface salinity (SSS) in the Eastern Tropical Pacific (ETPac) on intraseasonal to interannual timescales was studied using data from the Soil Moisture and Ocean Salinity, Soil Moisture Active Passive, and Aquarius satellite missions. A zonal wave number‐frequency spectral analysis of SSS reveals a dominant timescale of 50–180 days and spatial scale of 8°–20° of longitude with a distinct seasonal cycle and interannual variability. This intraseasonal SSS signal is detailed in the study of 19 individual ETPac eddies over 2010–2016 identified by their sea level anomalies, propagating westward at a speed of about 17 cm/s. ETPac eddies trap and advect water in their core westward up to 40° of longitude away from the coast. The SSS signatures of these eddies, with an average anomaly of 0.5‐pss magnitude difference from ambient values, enable the study of their dynamics and the mixing of their core waters with the surroundings. Three categories of eddies were identified according to the location where they were first tracked: (1) in the Gulf of Tehuantepec, (2) in the Gulf of Papagayo, and (3) in the open ocean near 100°W–12°N. They all traveled westward near 10°N latitude. Category 3 is of particular interest, as eddies seeded in the Gulf of Tehuantepec grew substantially in the vicinity of the Clipperton Fracture Zone rise and in a region where the mean zonal currents have anticyclonic shear. The evolution of the SSS signature associated with the eddies indicates the importance of mixing to their dissipation.
    Description: This research was carried out in part at the Jet Propulsion Laboratory (JPL), California Institute of Technology, under a contract with NASA and part at LOCEAN (Sorbonne Université, CNRS, IRD, MNHN) under a CNES Postdoctoral fellowship. This work is supported by NASA Grants NNX11AE83G and NNX14AH38G and is a contribution to the TOSCA/SMOS‐Ocean proposal supported by CNES. We thank the reviewers for their thoughtfully comments that lead to a much‐improved manuscript. We benefited from numerous data sets made freely available and are listed here: The SMOS debias_v2 SSS have been produced by LOCEAN laboratory and ACRI‐st company that participate to the Ocean Salinity Expertise Center (CEC‐OS) of Centre Aval de Traitement des Donnees SMOS (CATDS). of CATDS at IFREMER, Plouzane, France (http://www.catds.fr/Products, see documentation: http://www.catds.fr/Products/Available‐products‐from‐CEC‐OS/L3‐Debiased‐Locean‐v2); the Aquarius/SAC‐D and SMAP data was produced by Remote Sensing Systems and distributed by PODAAC (https://podaac.jpl.nasa.gov/dataset/AQUARIUS_L3_SSS_SMI_7DAY_V4; https://podaac.jpl.nasa.gov/dataset/SMAP_RSS_L3_SSS_SMI_8DAY‐RUNNINGMEAN_V2); the SLA product is processed and distributed by CMEMS (http://marine.copernicus.eu); the global atlas of eddies is produced by AVISO (https://www.aviso.altimetry.fr/en/data/products/value‐added‐products/global‐mesoscale‐eddy‐trajectory‐product.html); the GPCP precipitation data set (http://eagle1.umd.edu/GPCP_CDR/Monthly_Data) is described in the project technical report (http://eagle1.umd.edu/GPCP_ICDR/GPCPmonthlyV2.3.pdf); Woods Hole Oceanographic Institution OAFlux evaporation data set (ftp://ftp.whoi.edu/pub/science/oaflux/data_v3); UCAR high‐resolution terrain data set (High res terrain data set https://rda.ucar.edu/datasets/ds759.2/#!description); Chelton et al. (1998) Global Atlas of the First‐Baroclinic Rossby Radius of Deformation and Gravity‐Wave Phase Speed (http://www‐po.coas.oregonstate.edu/research/po/research/rossby_radius/).
    Description: 2019-09-28
    Keywords: Eddies ; Mesoscale ; Salinity ; Pacific
    Repository Name: Woods Hole Open Access Server
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  • 3
    Publication Date: 2022-10-26
    Description: Author Posting. © American Geophysical Union, 2019. This article is posted here by permission of American Geophysical Union for personal use, not for redistribution. The definitive version was published in Journal of Geophysical Research-Oceans 124(2), (2019): 1322-1330, doi:10.1029/2018JC014106.
    Description: A Lagrangian model is constructed for a surface column of initial height h(0) that propagates at an average speed u and is subject to excess (i.e., net) evaporation of q m/year. It is shown that these parameters combine to form an evaporation length, L = uh(0)/q, which provides an estimate for the distance the column must travel before evaporating completely. While these changes in the surface water level due to evaporation are compensated by entrainment of water into the overall column, the changes in either near‐surface salinity or isotopic compositions are retained and can be measured. Observations of surface salinity and isotopic compositions of δ18O and δD along 1,000‐ to 3,500‐km long transects are used to estimate values of L in the Red Sea, Mediterranean Sea, Indian Ocean, and Gulf Stream. The variations of salinity, δ18O and δD in all four basins are linear. As anticipated, the estimated value of L is smallest in the slowly moving and arid Red Sea and is greatest in the fast‐moving Gulf Stream.
    Description: The salinity and δ18O data collected aboard the Indian Ocean cruise described in Srivastava et al. (2007) can be accessed at this website (https://www.nodc.noaa.gov). The salinity, δ18O and δD data collected during the Red Sea cruise of the Interuniversity Institute for Marine Sciences, Eilat, described in Steiner et al. (2014) and can be accessed in the supporting information section of doi: 10.1073/pnas.1414323111. H. B. acknowledges the support provided by the Eshkol Foundation of the Israel Ministry of Science.
    Description: 2019-07-26
    Keywords: Air-sea interaction ; Evaporation ; Semienclosed basins ; Salinity ; Stable isotopes ; Thermohaline circulation
    Repository Name: Woods Hole Open Access Server
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  • 4
    Publication Date: 2021-03-16
    Description: The Nevado del Ruiz volcano is considered one of the most active volcanoes in Colombia, which can potentially threaten approximately 600,000 inhabitants. The existence of a glacier and several streams channelling in some main rivers, flowing downslope, increases the risk for the population living on the flank of the volcano in case of unrest, because of the generation of lahars and mudflows. Indeed, during the November 1985 subplinian eruption, a lahar generated by the sudden melting of the glacier killed twenty thousand people in the town of Armero. Moreover, the involvement of the local hydrothermal system has produced in the past phreatic and phreatomagmatic activity, as occurred in 1989. Therefore, the physico-chemical conditions of the hydrothermal system as well as its contribution to the shallow thermal groundwater and freshwater in terms of enthalpy and chemicals require a close monitoring. The phase of unrest occurred since 2010 and culminated with an eruption in 2012, after several years of relative stability, stillmaintains amoderate alert, as required by the high seismicity and SO2 degassing. In October 2013, a sampling campaign has been performed on thermal springs and stream water, located at 2600–5000 m of elevation on the slope of Nevado del Ruiz, analyzed for water chemistry and stable isotopes. Some of these waters are typically steam-heated (low pH and high sulfate content) by the vapour probably separating from a zoned hydrothermal system. By applying a model of steam-heating, based on mass and enthalpy balances, we have estimated themass rate of hydrothermal steam discharging in the different springs. The composition of the hottest thermal spring (Botero Londono) is probably representative of a marginal part of the hydrothermal system, having a temperature of 250 °C and low salinity (Cl ~1500 mg/l), which suggest, along with the retrieved isotope composition, a chiefly meteoric origin. The vapour discharged at the steam vent “Nereidas” (3600 m asl) is hypothesized to be separated from a high temperature hydrothermal system. Based on its composition and on literature data on fluid inclusions, we have retrieved the P-T-X conditions of the deep hydrothermal system, aswell as its pH and fO2. The vapour feeding Nereidas would separate from a biphasic hydrothermal system characterized by the following parameters: t= 315 °C, P= 15 MPa, NaCl = 10 wt%, CO2=5 wt%, and similar proportion between liquid and vapour. Considering also the equilibria involving S-bearing gases and HCl, pH would approach the value of 1.5 while fO2 would correspond to the FeO-Fe2O3 buffer. Chlorine content is estimated at 10,300mg/l. Changes in the magmatic input into the hydrothermal system couldmodify its degree of vapourization and/or P-T-X conditions, thus inducing corresponding variations in vapour discharges and thermal waters. These findings, paralleled by contemporary measurements of water flow rates, could give significant clues on risk evaluation.
    Description: Published
    Description: 40-53
    Description: 2V. Struttura e sistema di alimentazione dei vulcani
    Description: JCR Journal
    Keywords: Nevado del Ruiz ; Water isotopes ; Geothermal system ; Equilibrium modelling ; Water chemistry ; 04.08. Volcanology ; 03.02. Hydrology
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
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  • 5
    Publication Date: 2021-03-19
    Description: Syneruptive gas flux time series can, in principle, be retrieved from satellite maps of SO2 collected during and immediately after volcanic eruptions, and used to gain insights into the volcanic processes which drive the volcanic activity. Determination of the age and height of volcanic plumes are key prerequisites for such calculations. However, these parameters are challenging to constrain using satellite-based techniques. Here, we use imagery from OMI and GOME-2 satellite sensors and a novel numerical procedure based on back-trajectory analysis to calculate plume height as a function of position at the satellite measurement time together with plume injection height and time at a volcanic vent location. We applied this new procedure to three Etna eruptions (12 August 2011, 18 March 2012 and 12 April 2013) and compared our results with independent satellite and ground-based estimations. We also compare our injection height time-series with measurements of volcanic tremor, which reflects the eruption intensity, showing a good match between these two datasets. Our results are a milestone in progressing towards reliable determination of gas flux data from satellite-derived SO2 maps during volcanic eruptions, which would be of great value for operational management of explosive eruptions.
    Description: 1) European Research Council under the European Union's Seventh Framework Programme (FP/2.007-2013)/ERC Grant Agreement no. 279802, project 283 CO2Volc. 2) MEDiterranean SUpersite Volcanoes 280 (MED-SUV) WP 3.3.3
    Description: Published
    Description: 79-91
    Description: 5V. Dinamica dei processi eruttivi e post-eruttivi
    Description: JCR Journal
    Keywords: Volcanic SO2 ; Trajectory modelling ; Remote sensing ; Volcanic tremor ; 04.08. Volcanology
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
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  • 6
    Publication Date: 2021-06-30
    Description: Volcanic activity exhibits a wide range of eruption styles, from relatively slow effusive eruptions that produce lava flows and lava domes, to explosive eruptions that can inject large volumes of fragmented magma and volcanic gases high into the atmosphere. Although controls on eruption style and scale are not fully understood, previous research suggests that the dynamics of magma ascent in the shallow subsurface (〈 10 km depth) may in part control the transition from effusive to explosive eruption and variations in eruption style and scale. Here we investigate the initial stages of explosive eruptions using a 1D transient model for magma ascent through a conduit based on the theory of the thermodynamically compatible systems. The model is novel in that it implements finite rates of volatile exsolution and velocity and pressure relaxation between the phases. We validate the model against a simple two-phase Riemann problem, the Air-Water Shock Tube problem, which contains strong shock and rarefaction waves. We then use the model to explore the role of the aforementioned finite rates in controlling eruption style and duration, within the context of two types of eruptions at the Soufrière Hills Volcano, Montserrat: Vulcanian and sub-Plinian eruptions. Exsolution, pressure, and velocity relaxation rates all appear to exert important controls on eruption duration. More significantly, however, a single finite exsolution rate characteristic of the Soufrière Hills magma composition is able to produce both end-member eruption durations observed in nature. The duration therefore appears to be largely controlled by the timescales available for exsolution, which depend on dynamic processes such as ascent rate and fragmentation wave speed.
    Description: Published
    Description: 110-139
    Description: 5V. Dinamica dei processi eruttivi e post-eruttivi
    Description: JCR Journal
    Keywords: Magma ascent ; Conduit dynamics ; Soufrière Hills Volcano ; Finite-rate exsolution ; Pressure relaxation ; Velocity relaxation ; 04.08. Volcanology ; Numerical modeling
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
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  • 7
    Publication Date: 2019-11-22
    Description: The dynamics of effusive events is controlled by the interplay between conduit geometry and source conditions. Dyke‐like geometries have been traditionally assumed for describing conduits during effusive eruptions, but their depth‐dependent and temporal modifications are largely unknown. We present a novel model which describes the evolution of conduit geometry during effusive eruptions by using a quasi steady state approach based on a 1‐D conduit model and appropriate criteria for describing fluid shear stress and elastic deformation. This approach provides time‐dependent trends for effusion rate, conduit geometry, exit velocity, and gas flow. Fluid shear stress leads to upward widening conduits, whereas elastic deformation becomes relevant only during final phases of effusive eruptions. Simulations can reproduce different trends of effusion rate, showing the effect of magma source conditions and country rock properties on the eruptive dynamics. This model can be potentially applied for data inversion in order to study specific case studies.
    Description: Published
    Description: 7471-7480
    Description: 5V. Processi eruttivi e post-eruttivi
    Description: JCR Journal
    Keywords: Magma ascent ; Effusive eruption ; Conduit geometry ; 04.08. Volcanology
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
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  • 8
    Publication Date: 2022-05-25
    Description: © The Author(s), 2017. This article is distributed under the terms of the Creative Commons Attribution License. The definitive version was published in Regional Studies in Marine Science 18 (2018): 1-10, doi:10.1016/j.rsma.2017.12.004.
    Description: The variations of temperature and salinity in the Sudanese coastal zone of the Red Sea are studied for the first time using measurements acquired from survey cruises during 2009–2013 and from a mooring during 2014–2015. The measurements show that temperature and salinity variability above the permanent pycnocline is dominated by seasonal signals, similar in character to seasonal temperature and salinity oscillations observed further north on the eastern side of the Red Sea. Using estimates of heat flux, circulation and horizontal temperature/salinity gradients derived from a number of sources, we determined that the observed seasonal signals of temperature and salinity are not the product of local heat and mass flux alone, but are also due to alongshore advection of waters with spatially varying temperature and salinity. As the temperature and salinity gradients, characterized by warmer and less saline water to the south, exhibit little seasonal variation, the seasonal salinity and temperature variations are closely linked to an observed seasonal oscillation in the along-shore flow, which also has a mean northward component. We find that the inclusion of the advection terms in the heat and mass balance has two principal effects on the computed temperature and salinity series. One is that the steady influx of warmer and less saline water from the south counteracts the long-term trend of declining temperatures and rising salinities computed with only the local surface flux terms, and produces a long-term steady state in temperature and salinity. The second effect is produced by the seasonal alongshore velocity oscillation and most profoundly affects the computed salinity, which shows no seasonal signal without the inclusion of the advective term. In both the observations and computed results, the seasonal salinity signal lags that of temperature by roughly 3 months.
    Description: The SPS surveys were funded by the Norwegian Norad’s Program for Master Studies and organized by IMR–RSU in Port Sudan. The central Red Sea mooring data were acquired as part of a WHOI–KAUST collaboration funded by Award Nos. USA00001, USA00002, and KSA00011 to the WHOI by the KAUST in the Kingdom of Saudi Arabia. The work of I. Skjelvan and A.M. Omar was partly supported by the Research Council of Norway through the MIMT Center for Research-based Innovation. This work is part of a Ph.D. project at GFI–UiB funded by the Norwegian Quota program .
    Keywords: Coastal Red Sea ; Temperature ; Salinity ; Time series ; Seasonality ; Alongshore advection
    Repository Name: Woods Hole Open Access Server
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  • 9
    Publication Date: 2017-09-11
    Description: Telica volcano, in north-west Nicaragua, is a young stratovolcano of intermediate magma composition producing frequent Vulcanian to phreatic explosive eruptions. The Telica stratigraphic record also includes examples of (pre)historic sub-Plinian activity. To refine our knowledge of this very active volcano, weanalyzedmajor element composition and volatile content of melt inclusions fromsomestratigraphically significant Telica tephra deposits. These include: (1) the Scoria Telica Superior (STS) deposit (2000 to 200 years Before Present; Volcanic Explosive Index, VEI, of 2–3) and (2) pyroclasts from the post-1970s eruptive cycle (1982; 2011). Based on measurements with nanoscale secondary ion mass spectrometry, olivine-hosted (forsterite [Fo] N 80) glass inclusions fall into 2 distinct clusters: a group of H2O-rich (1.8–5.2 wt%) inclusions, similar to those of nearby Cerro Negro volcano, and a second group of CO2-rich (360–1700 μg/g CO2) inclusions (Nejapa, Granada). Model calculations show that CO2 dominates the equilibrium magmatic vapor phase in the majority of the primitive inclusions (XCO2 N 0.62–0.95). CO2, sulfur (generally b2000 μg/g) and H2O are lost to the vapor phase during deep decompression (P N 400 MPa) and early crystallization of magmas. Chlorine exhibits a wide concentration range (400–2300 μg/g) in primitive olivine-entrapped melts (likely suggesting variable source heterogeneity) and is typically enriched in the most differentiated melts (1000–3000 μg/g). Primitive, volatile-rich olivine-hosted melt inclusions (entrapment pressures, 5–15 km depth) are exclusively found in the largest-scale Telica eruptions (exemplified by STS in our study). These eruptions are thus tentatively explained as due to injection of deep CO2-rich mafic magma into the shallow crustal plumbing system. More recent (post-1970), milder (VEI 1–2) eruptions, instead, do only exhibit evidence for low-pressure (P b 50–60 MPa), volatile-poor (H2O b 0.3–1.7 wt%; CO2 b 23–308 μg/g) magmatic conditions. These are manifested as andesitic magmas, recording multiple magma mixing events, in pyroxene inclusions.Wepropose that post-1970s eruptions are possibly related to the high viscosity of resident magma in shallow plumbing system (b2.4 km), due to crystallization and degassing
    Description: Published
    Description: 131-148
    Description: 1V. Storia eruttiva
    Description: JCR Journal
    Keywords: Telica, Nicaragua ; 04.08. Volcanology
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
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  • 10
    Publication Date: 2017-12-13
    Description: This study focuses on the interaction among deep volcanic/hydrothermal gases, groundwater and soil gases at Vulcano Island (Aeolian Archipelago, Italy). The chemical-physical parameters of the groundwater, the total dissolved inorganic carbon (TDIC) and the isotopic composition of the CO2 dissolved in groundwater are reported and discussed. Furthermore, a comparison between soil gases and groundwater indicates that groundwater and soil gases show the same qualitative information, giving a good overall picture of the main degassing zones of a volcanic system, whereas the soil gas discharge provides an evaluation of the mass released by the deep feeding system. This approach can be a useful tool both to characterize mixing and/or interaction processes among different sources and for a monitoring of degassing activity of a volcanic system.
    Description: Published
    Description: 116-119
    Description: 2V. Struttura e sistema di alimentazione dei vulcani
    Description: 4V. Dinamica dei processi pre-eruttivi
    Description: N/A or not JCR
    Keywords: Soil CO2 flux ; Dissolved gases ; Isotope composition of CO2 ; Groundwaters ; Vulcano Island ; 03.02. Hydrology ; 04.08. Volcanology
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
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  • 11
    Publication Date: 2022-05-25
    Description: © The Author(s), 2016. This article is distributed under the terms of the Creative Commons Attribution License. The definitive version was published in Journal of Hydrology: Regional Studies 11 (2017): 147-165, doi:10.1016/j.ejrh.2015.12.056.
    Description: The study region encompasses the nearshore, coastal waters off west Maui, Hawaii. Here abundant groundwater—that carries with it a strong land-based fingerprint—discharges into the coastal waters and over a coral reef. Coastal groundwater discharge is a ubiquitous hydrologic feature that has been shown to impact nearshore ecosystems and material budgets. A unique combined geochemical tracer and oceanographic time-series study addressed rates and oceanic forcings of submarine groundwater discharge at a submarine spring site off west Maui, Hawaii. Estimates of submarine groundwater discharge were derived for a primary vent site and surrounding coastal waters off west Maui, Hawaii using an excess 222Rn (t1/2 = 3.8 d) mass balance model. Such estimates were complemented with a novel thoron (220Rn, t1/2 = 56 s) groundwater discharge tracer application, as well as oceanographic time series and thermal infrared imagery analyses. In combination, this suite of techniques provides new insight into the connectivity of the coastal aquifer with the near-shore ocean and examines the physical drivers of submarine groundwater discharge. Lastly, submarine groundwater discharge derived constituent concentrations were tabulated and compared to surrounding seawater concentrations. Such work has implications for the management of coastal aquifers and downstream nearshore ecosystems that respond to sustained constituent loadings via this submarine route.
    Description: This research was primarily funded by the USGS Coastal and Marine Geology Program (CMGP). CRG acknowledges support from the National Oceanic and Atmospheric Administration, Project R/SB-12, which is sponsored by the University of Hawaii Sea Grant College Program, SOEST, under Institutional Grant No. NA14OAR4170071 from NOAA Office of Sea Grant, Department of Commerce.
    Keywords: Regional groundwater flow ; Submarine groundwater discharge ; Radon ; Thoron ; Thermal infrared ; Oceanographic time series ; Salinity
    Repository Name: Woods Hole Open Access Server
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  • 12
    Publication Date: 2024-05-09
    Description: The carbon isotopic composition of dissolved C-bearing species is a powerful tool to discriminate the origin of carbon in thermal waters from volcanic and hydrothermal systems. However, the δ13C values of dissolved CO2 and TDIC (Total Dissolved Inorganic Carbon) are often different with respect to the isotopic signature that characterizes the potential carbon primary sources, i.e. deep hydrothermal reservoirs, magmatic gases and organic activity. The most commonly invoked explanation for such isotopic values is related to mixing processes between deep and shallow end-members. Nevertheless, experimental and empirical investigations demonstrated that isotopic fractionation due to secondary processes acting on the uprising fluids from the hydrothermal reservoirs is able to reproduce the measured isotopic values. In this paper,we investigated the chemistry of thermalwaters, collected at Campi Flegrei and Vulcano Island (southern Italy),whose origin is related to interaction processesamongmagmatic gases, meteoric water, seawater and hosting rocks. A special focus was dedicated to the δ13C values of dissolved CO2 (δ13CCO2(aq)) and total dissolved inorganic carbon (δ13CTDIC). The δ13CCO2(aq) and δ13CTDIC values in the water samples fromboth these systems ranged from(i) those measured in fumarolic gases, likely directly related to the deep hydrothermal-magmatic reservoir, and (ii) those typically characterizing biogenic CO2, i.e. produced by microbially-driven degradation of organic matter. A simple mixingmodel of the two end-members, apparently explaining these intermediate carbon isotopic values, contrastswith the chemical composition of the dissolved gases. On the contrary, isotopic fractionation due to secondary processes, such as calcite precipitation, affecting hydrothermal fluids during their underground circulation, seems to exhaustively justify both the chemical and isotopic data. If not recognized, these processes, which frequently occur in volcanic and hydrothermal systems, may lead to an erroneous interpretation of the carbon source, causing an underestimation of the contribution of the hydrothermal/magmatic fluids to the dissolved carbon species. These results pose extreme caution in the interpretation of intermediate δ13CCO2(aq) and δ13CTDIC values for the assessment of the carbon budget of hydrothermal- volcanic systems.
    Description: Published
    Description: 46–57
    Description: 2V. Struttura e sistema di alimentazione dei vulcani
    Description: 4V. Dinamica dei processi pre-eruttivi
    Description: JCR Journal
    Keywords: Thermal waters ; Carbon isotopes ; Dissolved CO2 ; TDIC ; Volcanic-hydrothermal systems ; Secondary fractionation processes ; 04.08. Volcanology ; 03.02. Hydrology
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
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  • 13
    Publication Date: 2022-05-25
    Description: © The Author(s), 2016. This article is distributed under the terms of the Creative Commons Attribution License. The definitive version was published in Continental Shelf Research 124 (2016): 165-181, doi:10.1016/j.csr.2016.06.005.
    Description: A new hydrographic climatology has been created for the continental shelf region, extending from the Labrador shelf to the Mid-Atlantic Bight. The 0.2-degree climatology combines all available observations of surface and bottom temperature and salinity collected between 1950 and 2010 along with the location, depth and date of these measurements. While climatological studies of surface and bottom temperature and salinity have been presented previously for various regions along the Canadian and U.S. shelves, studies also suggest that all these regions are part of one coherent system. This study focuses on the coherent structure of the mean seasonal cycle of surface and bottom temperature and salinity and its variation along the shelf and upper slope. The seasonal cycle of surface temperature is mainly driven by the surface heat flux and exhibits strong dependency on latitude (r≈−0.9). The amplitude of the seasonal cycle of bottom temperature is rather dependent on the depth, while the spatial distribution of bottom temperature is correlated with latitude. The seasonal cycle of surface salinity is influenced by several components, such as sea-ice on the northern shelves and river discharge in the Gulf of St. Lawrence. The bottom salinity exhibits no clear seasonal cycle, but its spatial distribution is highly correlated with bathymetry, thus Slope Water and its intrusion on the shelf can be identified by its relatively high salinity compared to shallow, fresher shelf water. Two different regimes can be identified, especially on the shelf, separated by the Laurentian Channel: advection influences the phasing of the seasonal cycle of surface salinity and bottom temperature to the north, while in the southern region, river runoff and air-sea heat flux forcing are dominant, especially over the shallower bathymetry.
    Description: Support from NSF OCE PO to Y-OK (OCE-1242989 and OCE-1435602) and SJL (OCE-1332666).
    Keywords: Seasonal climatology ; Temperature ; Salinity ; Dataset ; Shelf
    Repository Name: Woods Hole Open Access Server
    Type: Article
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