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  • 1
    Publication Date: 2020-07-19
    Print ISSN: 0946-2171
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  • 2
  • 3
    Publication Date: 2020-07-08
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  • 4
  • 5
    Publication Date: 2020-07-08
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  • 6
    Publication Date: 2020-07-06
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  • 7
  • 8
  • 9
    Publication Date: 2007-03-16
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  • 10
    Publication Date: 2015-08-11
    Description: Systematic numerical study of near-infrared radiation formed during filamentation in air revealed the formation of robust light bullet first registered in the experiment (Chen et al. in Appl Phys B 91:219, 2008 ). The near-infrared light bullet propagates along the filament axis with the divergence 〈1 mrad and the quasi-constant duration of ~30 fs. The central wavelength of the bullet gradually increases from 860 to 900 nm during the propagation. The results of our numerical simulation are in agreement with the experiments (Chen et al. in Appl Phys B 91:219,  2008 ; Uryupina et al. in Appl Phys B 110:123, 2013 ).
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  • 11
    Publication Date: 2015-08-11
    Description: Flame flatness is one of the most critical factors in evaluating the performance of a flat-flame burner. In this paper, the flame flatness of a flat-flame burner is validated using a resolution-doubled one-dimensional wavelength modulation spectroscopy tomography (1D-WMST) technique that only uses one view of multiple parallel laser beams. When the interval of two neighboring parallel laser beams is Δ r , a designed novel geometry of the parallel laser beams realizes a doubled tomographic resolution of Δ r /2. Using the proposed technique, the distributions of temperature and H 2 O mole fraction in an axisymmetric premixed flame are simultaneously reconstructed and hence the flame flatness of a flat-flame burner can be validated. The flatness factor is quantitatively described by the similarity between the reconstructed and expected distributions of H 2 O mole fraction. For flat and non-flat flames, the experimental results agree well with the CFD simulation results, denoting that the resolution-doubled 1D-WMST technique provides a noninvasive, reliable and low cost way to validate the flame flatness of the flat-flame burner.
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  • 12
    Publication Date: 2015-08-11
    Description: We report on the optical performances of laccaic acid dye in solution at different concentrations and dye–poly(methyl methacrylate) composite thin films. The linear spectral characteristics including optical constants, i.e. refractive index ( n ) and extinction coefficient ( k ), were carried out in a comprehensive way through absorbance, fluorescence and ellipsometric studies. The nonlinear optical parameters such as nonlinear absorption coefficient β eff (or β 2 ), the imaginary third-order susceptibility (Im[ χ (3) ]) and the imaginary part of second-order hyperpolarizability ( γ ) of the samples were evaluated using the open-aperture Z-scan technique with a laser pulse duration of 10 ns at 532 nm wavelength. The corresponding numerical values of these parameters were of 10 −10 , 10 −11 and 10 −32 order, respectively. Two-photon absorption was revealed to be the main driving physical mechanism in the nonlinear response. This suggests that laccaic acid dye can be a potential candidate for NLO materials application.
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  • 13
    Publication Date: 2015-08-11
    Description: We demonstrate a sensor based on tunable diode laser absorption spectroscopy for the detection of hydrogen fluoride (HF) gas at ambient pressure. Absorption from the HF R(1) ro-vibrational peak at ν̃  = 4038.962 cm −1 (2.476 µm) in the fundamental (Δ ν  = 1) band is measured. A quantitative spectral fit based on HITRAN data is used to account for overlapping spectral peaks of HF and water vapor, with an rms residual noise of 5 × 10 −4 absorbance units. The sensor is optimized for the detection of transient variations in HF concentration. We measure noise-equivalent concentrations for HF of 38 parts-per-trillion by volume (ppt) for 1-s integration times and 2.3 ppt for 10-min integration times.
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  • 14
    Publication Date: 2015-08-11
    Description: We report on the absorption profile of the monoclinic holmium-doped \(\hbox {KY}(\hbox {WO}_4)_2\) crystal near the optic axis for the maximal absorption wavelength at 1960 nm. The full angular distribution of the absorption coefficient at the vicinity of such optical singularity has been experimentally and numerically investigated. Furthermore, laser experiments along the optic axis have been carried out. So-called conical refraction laser and classical Gaussian laser operation are compared near the optic axis, taking into account the complex absorption profile.
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  • 15
    Publication Date: 2015-08-11
    Description: We demonstrate a novel and compact fiber-probe pressure sensor based on a micro-Fabry–Perot interferometer (FPI). The device is fabricated by splicing both ends of a short-section simplified hollow-core photonic crystal fiber (SHC-PCF) with single-mode fibers. Then, a microchannel is drilled by a femtosecond laser micromachining in the SHC-PCF to allow air to diffuse in. The pressure sensing mechanism is based on the dependence of the air refractive index on pressure. We use both theory and experiment to investigate the sensing characteristics. A micro-FPI with a length of 272 μm demonstrates a pressure sensitivity of 4.071 nm/MPa at 1580 nm and a low-temperature sensitivity of 1.1 pm/°C at atmospheric pressure. We further study the temperature cross sensitivity of the sensor under different pressures. The sensor also shows strong stability and good reversibility, and may be potentially used in pressure sensing applications.
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  • 16
    Publication Date: 2015-08-11
    Description: We study the thermo-optic Goos–Hänchen (TOGH) effect in a prism–waveguide coupling structure with silicon-on-insulator waveguide. Stationary-phase method is utilized to calculate the TOGH shift. When the waveguide is regarded as a two-dimensional planar waveguide, a nonlinear relation between GH shift and temperature is obtained. Based on the noticeable TOGH effect, a sensitive temperature modulator or sensor can be realized. As the waveguide width is limited, the proposed structure can be regarded as a three-dimensional rectangular waveguide. We explore the GH shift and TOGH effect for different modes propagating in rectangular waveguide which show different linear relations between GH shift and temperature, which can be used to design mode-selective device based on TO effect.
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  • 17
    Publication Date: 2015-08-04
    Description: We report on an experimental study of vacuum-induced suppression and enhancement of four-wave mixing (FWM) signal in a composite atom–cavity system. By scanning the additional dressing field, the suppression ratio of the FWM signal can reach 90 % compared with 40 % without cavity. We attribute the enhanced suppression and enhancement to the atom–cavity coupling arising from a vacuum-induced Raman process, which amplifies the dressing effect from the additional field. Also, the dressing asymmetry of the atom–cavity coupling is discussed and used to estimate the nonlinearity of atomic medium in the cavity. The suppression and enhancement can be interpreted by a dressed-state picture and agree with theoretical calculations. The investigation may find applications in optical switch and quantum memory controlled by cavity.
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  • 18
    Publication Date: 2015-08-04
    Description: By simultaneously using a multi-walled carbon nanotube (MWCNT) and a monolayer graphene saturable absorber (SA) in the cavity, a laser-diode-pumped dual-loss-modulated passively Q-switched Tm:LuAG laser at 2 μm is demonstrated for the first time. In comparison with the singly passively Q-switched laser with MWCNT or monolayer graphene SA, the doubly passively Q-switched laser with both MWCNT and monolayer graphene SA can generate shorter pulse width and higher peak power. A maximum pulse width compression ratio of 2.8 and a highest peak power enhancement factor of 4 were obtained at the incident pump power of 5.8 W, respectively. The experimental results show that the dual-loss modulation is an efficient method to compress the pulse widths and improve the peak powers of the Q-switched lasers at 2 μm.
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  • 19
    Publication Date: 2015-08-04
    Description: Photoexcitation dynamics in a three-step photoionization of atomic uranium has been investigated using time-resolved two-color three-photon and delayed three-color three-photon photoionization signals. Investigations are carried out in an atomic beam of uranium coupled to a high-resolution time-of-flight mass spectrometer using three tunable pulsed dye lasers. Dependence of both the signals on the second-step laser photon fluence is studied. Excited-level-to-excited-level photoexcitation cross section and photoionization cross section from the second excited level are simultaneously determined by analyzing the two-color three-photon and three-color three-photon photoionization signals using population rate equation model. Using this methodology, photoexcitation and photoionization cross sections at seven values of the second-step laser wavelength have been measured. From the measured values of the photoexcitation cross sections, we have obtained excited-level-to-excited-level transition probabilities and compared these with the values reported in the literature.
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  • 20
    Publication Date: 2015-08-06
    Description: A theoretical analysis of the photorefractive sensitivity of Ti:PPLN ridge waveguides in comparison with conventional Ti:PPLN channel waveguides is presented. In particular, intensity-dependent photorefraction, effective indices, waveguide modes and power-dependent SHG in Ti:PPLN ridge and channel waveguides are modeled for a wide range of parameters. Results predict a much better damage resistance of Ti:PPLN waveguides with ridge geometry in comparison with conventional indiffused channels. This superiority of ridge waveguides is attributed to their higher effective refractive index contrast and more tightly confined guided modes. The theoretical predictions are supported by experimental results for second harmonic generation (SHG) at room temperature and for light-induced detuning characteristics of the phase-matching wavelength.
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  • 21
    Publication Date: 2015-06-05
    Description: Two-color laser-induced incandescence (LII) measurements are carried out in diffusion flames and at the exhaust of a homemade soot generator, both fueled with ethylene and methane. Two-color prompt LII signals, their ratio and the corresponding temperature have been analyzed as a function of laser fluence. In particular, the effect of fuel, soot load and gas/particle initial temperature on LII measurements have been investigated. LII spectral measurements have also been performed in all conditions for validation. The results suggest that the incandescence is sensitive to both optical and non-optical physical properties of the particles. Moreover, soot volume fraction measurements are dependent on the laser fluence used, indicating that the soot temperature influences the refractive index absorption function. Such issues can be overcome by working at high laser fluences, where the saturation curves are independent from the experimental conditions if the soot absorption function near soot sublimation threshold is known.
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  • 22
    Publication Date: 2015-08-06
    Description: The complexation reactions between K + , Na + , and La 3+ cations and the macrocyclic ligand dibenzo-18-crown-6 (DB18C6) were studied in acetionitrile (AN)-dimethylformamide (DMF) binary mixtures. Also, the complexation of K + and Na + in 50% ethanol (EtOH)-50% DMF and 50% EtOH-50% AN binary mixtures was studied. The conductivity data show that the stochiometry of all the complexes is 1: 1. A non-linear behavior was observed for the log K f variation vs. composition of binary solvent, which was discussed in terms of heteroselective solvation and solvent-solvent interactions in binary solutions. It was found that the stability order of the complexes changes with composition of the mixed solvents. The stability sequence for AN-DMF (25 and 50 mol % DMF) solutions and pure AN at 25°C is [K(DB18C6)] + 〉 [Na(DB18C6)] + 〉 [La(DB18C6)] 3+ . However, at 75 mol % DMF it changes to [Na(DB18C6)] + 〉 [K(DB18C6)] + 〉 [La(DB18C6)] 3+ . The thermodynamical values (Δ H c po , Δ S c po ) for these complexation reactions were determined from the temperature dependence of the stability constants. The thermodynamics of the complexation reactions is affected by the nature and composition of the mixed solvents.
    Print ISSN: 0036-0244
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  • 23
    Publication Date: 2015-08-06
    Description: A single theoretical model for calculating heat conductivity coefficients is presented. The model is based on the mobility of ions and takes into account the characteristics of individual solvated ions and properties of the solvent. The model allows us to obtain heat conductivity coefficients for solutions of individual electrolytes and their mixtures in aqueous and non-aqueous solvents.
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  • 24
    Publication Date: 2015-08-06
    Description: Density (ρ) and viscosity (η) of aqueous hippuric acid (HA) solutions containing LiCl and MnCl 2 · 4H 2 O have been studied at 303.15 K in order to understand volumetric and viscometric behavior of these systems. Apparent molar volume (φ v ) of salts were calculated from density data and fitted to Massons relation and partial molar volumes (φ v 0 ) at infinite dilution were determined. Relative viscosity data has been used to determine viscosity A and B coefficients using Jones-Dole relation. Partial molar volume and viscosity coefficients have been discussed in terms of ion-solvent interactions and overall structural fittings in solution.
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  • 25
    Publication Date: 2015-08-06
    Description: The carboxyl-terminated polysiloxane (CTP) was successfully synthesized from amine-terminated polysiloxane and succinic anhydride and characterized by the 1 H NMR and 13 C NMR spectroscopy. The complexes of lanthanide ions (Eu 3+ , Tb 3+ , and Dy 3+ ) with CTP were prepared and show excellent fluorescence properties. Narrow-width red or green fluorescence was observed under UV irradiation, indicating the successful coordination and the presence of the intra-molecular energy transfer process. For the functionalized polysiloxane, the coordination number is hard to be confirmed due to polysiloxane excellent flexibility. In order to investigate the coordination number and structure of these products, the carboxyl-functionalized disiloxane (CFD) and luminescent materials on its basis (CFD-Ln) were synthesized and their coordination structure was confirmed by IR, fluorescence spectroscopy and XPS. Through the qualitative comparison between the CFD-Ln and CTP-Ln, the coordination structure of the CTP-Ln material was elucidated.
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  • 26
    Publication Date: 2015-08-06
    Description: The effect of the structure of benzimidazoles on their chromatographic retention on octadecyl silica gel from an aqueous acetonitrile eluent was studied. One- and many-parameter correlation equations were obtained by linear regression analysis, and their prognostic potential in determining the retention factors of benzimidazoles under study was analyzed.
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  • 27
    Publication Date: 2015-08-06
    Description: The structure and properties of nickelabenzene complex were examined by the Modified Perdew-Wang Exchange and Correlation method (mpw1pw91). The para -substitutions effect on the structure, frontier orbital energies, aromaticity and electronic spectra has been studied. Nucleus independent chemical shift (NICS) values show that these species are aromatic. Time dependent density functional theory (TD-DFT) was used to calculate the energy, oscillator strength and absorption maxima wavelength (λ max ) of various electronic transitions and their nature within molecules.
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  • 28
    Publication Date: 2015-08-06
    Description: Coefficients of the three-parameter polynomial equation of states are determined from experimental data on the ( p , ρ, T , x ) relationship for water-aliphatic alcohol (methanol, ethanol, and n -propanol) mixtures in the liquid and vapor phases and in the supercritical state: expansions of compressibility factor Z = p / RT ρ m into series in powers of reduced density ω = ρ m /ρ mcr ; reduced temperature τ = T/T cr and composition x (as the mole fraction of alcohol), \(Z = p/RT\rho _m = 1 + \sum\nolimits_{i = 1}^m {\sum\nolimits_{j = 0}^n {\sum\nolimits_{k = 0}^s {a_{ijk} \omega ^i \tau ^{ - j} x^k ;} } } p = RT\rho _m = [1 + \sum\nolimits_{i = 1}^m {\sum\nolimits_{j = 0}^n {\sum\nolimits_{k = 0}^s {a_{ijk} \omega ^i \tau ^{ - j} x^k } } ]} \) . The mean percentage errors of the calculated pressure values relative to the experimental values are 2% (liquid phase), 0.7% (vapor phase), and 0.5% (supercritical fluid).
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  • 29
    Publication Date: 2015-08-06
    Description: Acoustic parameters such as isentropic compressibility, βs, intermolecular free length, Lf, apparent molar volume (ϕ v ), solvation number, Sn, viscosity B coefficients of Jones-Dole equation etc., have been evaluated from the measured values of ultrasonic velocity, density and viscosity for the solutions of lanthanum(III) chloride in d-glucose (dextrose)-water mixed solvent system of various proportions at 303.15 K temperature and atmospheric pressure. The results are discussed in the light of ion-solvent interactions and the structural effect of the solute on the solvent in the solution.
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  • 30
    Publication Date: 2015-08-06
    Description: Monolythic medium-polar capillary columns based on pentaerythritol tetraacrylate were optimized for separation of peptides. The synthesis temperature and time, the fraction of monomer in the initial polymerization mixture, and the nature of alcohol contained in the complex porogen were chosen as optimization parameters. The highest efficiency was attained for columns obtained with 33 and 34% monomer at a polymerization time of 75 min and a temperature of 75°C. The columns with the optimum structure were effective in separation of a model mixture of five peptides. The sensitivity of the method was 200 ng of peptide per column.
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  • 31
    Publication Date: 2015-08-06
    Description: A study of metastable zone width (MSZW) and nucleation parameters for a cooling crystallization of DL-malic acid-water system is described in this paper. Experimental determination of the MSZW was performed using a laser method in order to carry out the estimation of nucleation parameters. Measured MSZWs can be affected by a variety of parameters, such as cooling rate, saturation temperature, agitation rate, and so on. In this work, the MSZWs were found to decrease with an increase of saturation temperature, and levels of agitation, while it increased with an increase of cooling rate. Two classical theoretical approaches, Nyvlt’s approach and self-consistent Nyvlt-like approach were used to analyze the experimental data on MSZWs.
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  • 32
    Publication Date: 2015-08-06
    Description: The conversion of 2,3,7,8-tetrachlorodibenzo- p -dioxin (TCDD) in diluted aqueous solutions at different absorbed doses of ionizing radiation using the 60 Co source is studied. The radiochemical yield of TCDD conversion is (0.3–1.5) × 10 −5 molecules/100 eV for solutions with 0.2–2 μg/L TCDD in open cells and 2.4 × 10 −5 molecules/100 eV for air-sparged 2 μg/L TCDD solutions. It is demonstrated that the absorbed dose of ionizing radiation (25 kGy) lowers the TCDD concentration in oxygen-containing aqueous solutions virtually to zero.
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  • 33
    Publication Date: 2015-08-06
    Description: The interactions of L-phenylalanine and L-tryptophan with nicotinic acid and uracyl in an aqueous buffer solution at pH 7.35 were studied by IR spectroscopy. The contributions of various functional groups to the complexation of aromatic amino acids with heterocyclic ligands were determined from the IR spectra of the starting substances and their mixtures.
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  • 34
    Publication Date: 2015-08-06
    Description: Thermal effects of the complexation of cobalt(II) ions with L-histidine at 298.15 K and several values of the ionic strength against the background of KNO3 are determined by means of direct calorimetry. The standard thermodynamic characteristics of the reactions of complexation in the aqueous solution have been calculated.
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  • 35
    Publication Date: 2015-08-06
    Description: A procedure for dispersing the single-walled carbon nanotubes (SWCNTs) for preparing stable suspensions with high concentrations of individual nanotubes in various alcohols was described. The obtained suspensions were studied by Raman spectroscopy. The solubility of the single-walled carbon nanotubes in alcohols was found to depend on the concentration of cholic acid. The ethanol-surfactant mixture was shown to be the best solvent for all alkanol-cholic acid mixtures (0.018 mol/kg) under study used for preparing time-stable suspensions of single-walled carbon nanotubes. The dissolving ability of aliphatic alcohols was found to decrease in the series: ethanol-isopropanol- tert -butanol-butanol-propanol.
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  • 36
    Publication Date: 2015-08-11
    Description: In this study, In 2 O 3 /Ag/MoO 3 (IAM) nano-multilayer films are designed, and optimum thickness of each layer is calculated. These films were deposited by thermal evaporation technique and then annealed in air atmosphere at different temperatures for 1 h. The effects of annealing temperature on electrical, optical, and structural properties of the IAM system were investigated. The UV–visible–near-IR transmittance and reflectance spectra confirmed that the annealing temperature has significant influence on the electro‐optical characteristics of IAM films. High-quality IAM films with a low sheet resistance of 8.2 (Ω/□) and the maximum optical transmittance of 85 % at 120 °C annealing temperature were obtained. The effect of heat treatment on surface roughness of the layers was also investigated. Figure-of-merit quantity showed that the IAM films annealed at 120 °C have the best performance. X-ray diffraction patterns showed that the crystallinity of the structures enhanced with increase in annealing temperature. Organic light-emitting diodes (OLEDs) were fabricated on IAM anodes. The current density–voltage–luminance (J–V–L) characteristic measurements show that the electroluminescence performances of OLED with IAM anode are improved compared with the conventional ITO-based device. The results indicate that the designed system is suitable for use as transparent conductive anode in optoelectronic devices.
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  • 37
    Publication Date: 2015-08-11
    Description: We demonstrate the effectiveness of silicon phase masks to implement spatially resolved, multispectral imaging capabilities in the range of terahertz frequencies, using a standard setup of basic interest for time-domain spectrometry with a single-cell source and a single-cell detector. Our principle primarily aims at the development of robust and inexpensive systems. It consists of appropriate space-to-time encoding, in order to ensure single-scan triggering and then take advantage of rapid and self-consistent measurements in the two-dimensional space. The process enables very efficient discrimination giving access to a relevant spatial resolution in the analysis of small size, planar assemblies made of inhomogeneous materials. Benchmark results are provided to validate the concept, thanks to prototyping phase masks with 2 × 2 pixels, prior evidencing actual performance limitations in the case of 3 × 3 pixels. Due to the frequency bandwidth of 0.1–1.5 THz in our setup and to the available operating conditions, currently acceptable pixel resolutions lie in the range of 3–4 mm. Numerical modeling by means of finite elements helps to discuss these numbers and to investigate the relevant theoretical issues, figuring the main propagation issues in connection with a sub-picosecond seed pulse throughout various masks. This involves diffraction and trailing edge effects when crossing the mask together with residual, parasitic reflections. Finally, we give a consistent prospective for improved performance, via realistic updates regarding the architecture of the setup and complementary post-processing. Further values for the attainable spatial resolution then range from 5 × 5 to 6 × 6 pixels.
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  • 38
    Publication Date: 2015-08-18
    Description: A combination of optical emission spectroscopy (OES) and cavity ring-down spectroscopy (CRDS) has enabled to determinate the number densities of CH(A 2 Δ) and CH(X 2 Π) radicals simultaneously in a cascaded arc plasma reactor operating with a CH 4 /Ar mixture. It is found that the number density of CH(A 2 Δ) radical increases with discharge current at first and then decreases. However, the number density of CH(X 2 Π) radical decreases with discharge current when the rate of CH 4 flow to total flow is lower than 1 %, while it increases slightly with discharge current when the rate is 1.5 %. The results reveal that CH radicals are deviation from excitation equilibrium. Although OES is the simplest and most straightforward means to investigate the CH radical behavior, it is not enough to provide the information of the CH(X 2 Π) number density, and additional methods, such as CRDS, are needed in the cascaded arc plasma jet.
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  • 39
    Publication Date: 2015-08-18
    Description: In this paper, we present a numerical study based on 3D FDTD (finite-difference time-domain) simulations that demonstrate the high sensitivity of the optical response of a bowtie nano-aperture antenna (BNA), engraved at the apex of a metal-coated tip, to the distance variation between it and a given substrate. This study mainly discussed the case of the collection mode regime of the BNA and considered the case of two different substrates (high and low refractive index). The coupling between the substrate and the BNA may greatly affect the properties of the optical resonance of the nano-antenna. A blueshift of the resonance wavelength, as large as \(\frac{\varDelta \lambda }{\lambda }=0.3\) , is obtained when the tip moves away over only 10 nm from the substrate (InP) interface. These results open the way to the design of stand-alone optical near-field probes that allow faithful interaction control with a given sample as a function of the distance between them.
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  • 40
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    Springer
    Publication Date: 2015-09-22
    Description: The present paper describes the research of the optical device for two-dimensional straightness measurement of technological machines. Mathematical study of an optical device, operating on the phase principle and measuring transversal displacements of machine parts in two directions ( X and Y ) during their linear longitudinal motion in a machine (alongside the Z axis), is presented. How to estimate the range of travel along the Z axis is analytically shown. At this range, the measurer gives correct measurements of transverse displacement. The necessary distance from the objective focus to the image plane was defined mathematically. The sample results of measuring the displacement of the table of a technological machine by using the optical device are presented in the paper. This optical device for non-contact straightness measurement can be used for measurement straightness in turning, milling, drilling, grinding machines and other technological machines, also in geodesy and cartography, and for moving accuracy testing of mechatronic devices, robotics and others.
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  • 41
    Publication Date: 2015-09-22
    Description: Non-resonant laser-induced thermal acoustics (LITA), a four-wave mixing technique, was applied to post-shock flows within a shock tube. Simultaneous single-shot determination of temperature, speed of sound and flow velocity behind incident and reflected shock waves at different pressure and temperature levels are presented. Measurements were performed non-intrusively and without any seeding. The paper describes the technique and outlines its advantages compared to more established laser-based methods with respect to the challenges of shock tube experiments. The experiments include argon and nitrogen as test gas at temperatures of up to 1000 K and pressures of up to 43 bar. The experimental data are compared to calculated values based on inviscid one-dimensional shock wave theory. The single-shot uncertainty of the technique is investigated for worst-case test conditions resulting in relative standard deviations of 1, 1.7 and 3.4 % for Mach number, speed of sound and temperature, respectively. For all further experimental conditions, calculated values stay well within the 95 % confidence intervals of the LITA measurement.
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  • 42
    Publication Date: 2015-09-24
    Description: Airflow induced by femtosecond laser (800 nm/1 kHz/25 fs) filamentation with different lengths was investigated in a laboratory cloud chamber. Various filament lengths were generated by adjusting laser energy and lens focal length. It was found that airflow patterns are closely related to filament intensity and length. Intense and long filaments are beneficial in updraft generation with large vortices above the filament, while intense and short filaments tend to promote the formation of well-contacted vortices below the filament. Differently patterned airflows induced elliptical snow piles with different masses. We simulated airflow in a cloud chamber numerically taking laser filaments as heat sources. The mechanisms of differently patterned airflow and snow formation induced by filaments were discussed.
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  • 43
    Publication Date: 2015-09-25
    Description: Tissue simulators, the so-called tissue phantoms, have been used to mimic human tissue for spectroscopic applications. Phantoms’ design depends on patterning the optical properties, namely absorption and scattering coefficients which characterize light propagation mechanisms inside the tissues. In this work, two calibration models based on measurements adopting integrating sphere systems have been used to determine the optical properties of the studied solid phantoms. Integrating sphere measurement results were fed into the calibration models using the multiple polynomial regression method and Newton–Raphson algorithm. The third-order polynomials have been used for optical properties predictions. Good agreement between the two models has been obtained. Role of solid phantoms’ components, namely titanium dioxide as a scatterer and black carbon as an absorber, has been discussed. Both of the two components showed observable effects on the absorption and scattering of light inside the solid tissue phantoms.
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  • 44
    Publication Date: 2015-09-25
    Description: We report a novel time-resolved photoacoustic-based technique for studying the thermal decomposition mechanisms of some secondary explosives such as RDX (hexahydro-1,3,5-trinitro-1,3,5-triazine), picric acid, 4,6-dinitro-5-(4-nitro-1 H -imidazol-1-yl)-1 H -benzo[ d ] [ 1 – 3 ] triazole, and 5-chloro-1-(4-nitrophenyl)-1 H -tetrazole. A comparison of the thermal decomposition mechanisms of these secondary explosives was made by detecting NO 2 molecules released under controlled pyrolysis between 25 and 350 °C. The results show excellent agreement with the thermogravimetric and differential thermal analysis (TGA–DTA) results. A specially designed PA cell made of stainless steel was filled with explosive vapor and pumped using second harmonic, i.e., λ  = 532 nm, pulses of duration 7 ns at a 10 Hz repetition rate, obtained using a Q-switched Nd:YAG laser. The use of a combination of PA and TGA–DTA techniques enables the study of NO 2 generation, and this method can be used to scale the performance of these explosives as rocket fuels. The minimum detection limits of the four explosives were 38 ppmv to 69 ppbv, depending on their respective vapor pressures.
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  • 45
    Publication Date: 2015-09-29
    Description: For the first time, spatial distribution of major and trace elements has been studied in cholesterol gallstones using time-of-flight secondary mass ion mass spectrometry (TOF-SIMS). The TOF-SIMS has been used to study the elemental constituents of the center and surface parts of the gallstone sample. We have classified the gallstone sample using Fourier transform spectroscopy. The detected elements in cholesterol gallstone sample were carbon (C), hydrogen (H), calcium (Ca), sodium (Na), potassium (K), strontium (Sr), copper (Cu), iron (Fe), chromium (Cr), mercury (Hg) and lead (Pb). The detected molecules in the cholesterol gallstone were CH 3 + , CO 3 + , CaCO 3 + and C 3 H + . Our results revealed that the contents of these elements in cholesterol gallstone were higher in the center part than that in the surface part. In the present paper, we have also presented the UV–Vis spectroscopic studies of the center and surface parts of the gallstone sample which indicated the presence of a higher content of cholesterol in the surface part and bilirubin in the center part.
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  • 46
    Publication Date: 2015-09-29
    Description: Numerical experiments are carried out to calculate continuum emissivity and opacity of plasmas produced from laser-irradiated Au and Pb targets as hohlraum wall materials. Targets are considered to be solid or porous with different initial densities. Simulation results show a good agreement compared with the measured data. The results show that under identical conditions, X-ray emission is higher for Au plasma; however, by decreasing initial densities, X-ray yield enhancement is greater for Pb plasma. By using a Pb target with initial density of about 1.14 g cm −3 instead of solid Au target, the same X-ray yield even more can be obtained. Calculations also show that in the conditions of solid density targets, Pb plasma offers a little lower opacity in soft X-ray region. Decreasing initial density of Pb causes its opacity to increase and get closer to the opacity of solid Au which in turn reduces energy losses in hohlraum wall.
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  • 47
    Publication Date: 2015-11-22
    Description: We report the two-photon interference properties of a photon pair generated in a type-II collinear periodically poled KTiOPO 4 (PPKTP) crystal pumped by a 406-nm diode laser capable of producing a single or dual longitudinal mode (LM). When the Hong–Ou–Mandel (HOM) interference signals in the PPKTP crystal pumped by a dual-mode diode laser were investigated at various crystal temperatures, it was found that the maximum visibility of the HOM interference signal depends on the relative strength of the dual LMs of the pump laser. The HOM interference pattern was numerically calculated considering the dual LM components of the pump laser diode and the crystal temperature, and was found to be in good agreement with the experimental results.
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  • 48
    Publication Date: 2015-11-22
    Description: One- and two-ring aromatics such as toluene and naphthalene are frequently used molecular tracer species in laser-induced fluorescence (LIF) imaging diagnostics. Quantifying LIF signal intensities requires knowledge of the photo-physical processes that determine the fluorescence quantum yield. Collision-induced and intramolecular energy transfer processes in the excited electronic state closely interact under practical conditions. They can be separated through experiments at variable low pressures. Effective fluorescence lifetimes of gaseous toluene, 1,2,4-trimethylbenzene, anisole, naphthalene, and 1-methylnaphthalene diluted in CO 2 were measured after picosecond laser excitation at 266 nm and time-resolved detection of fluorescence intensities. Measurements in an optically accessible externally heated cell between 296 and 475 K and 0.010–1 bar showed that effective fluorescence lifetimes generally decrease with temperature, while the influence of the bath-gas pressure depends on the respective target species and temperature. The results provide non-radiative and fluorescence rate constants and experimentally validate the effect of photo-induced cooling.
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  • 49
    Publication Date: 2015-11-21
    Description: ZnO and 0, 5, and 10 mol % Fe-doped ZnO–TiO 2 nanopowders were synthesized by the sol–gel Pechini method. The successful synthesis of coupled ZnO–TiO 2 nanopowders was evident by XRD. Scanning electron microscopy (SEM) revealed that the Fe ions were well incorporated into the ZnO–TiO 2 crystal lattice. The photocatalytic degradation of anionic surfactant (linear alkylbenzene sulfonate (LABS), was investigated in aqueous solution using ZnO and Fe-doped ZnO–TiO 2 nanoparticles. The degradation was studied under different conditions such as the Fe 3+ concentration, amount of photocatalyst, irradiation time, pH, initial concentration and presence of electron acceptor. The results showed that photocatalytic degradation of LABS was strongly influenced by these parameters. The best conditions for the photocatalytic degradation of LABS were obtained. It is found that under UV light irradiation, Fe-doping of ZnO–TiO 2 increases the efficiency of its photocatalytic activity in degradation of LABS than pure ZnO and ZnO–TiO 2 .
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  • 50
    Publication Date: 2015-11-21
    Description: The interaction of Ni(II) and Cu(II) with ethyl 4-(4-hydroxyphenyl)-6-methyl-2-oxo-1,2,3,4-tetrahydropyrimidine- 5-carboxylate [Ligand 1], 4-(1H-benzimidazol-2-yl)phenol [Ligand 2], and 2-(3-phenylamino- 4,5-dihydro-1,2-oxazol-5-yl)phenol [Ligand 3] have been studied by spectrophotometric technique at 0.01 M ionic strength and 28°C in 70% dioxane—water mixture. The data obtained were used to estimate the stability constant of these ligands. Spectrophotometric investigation of Ni(II) and Cu(II) complexes with these ligands shows 1: 1 complex formation. The formation of complexes has been studied by Job’s variation method. The values of conditional stability constants of Cu(II) complexes are greater than the corresponding Ni(II) complexes. The greater value of stability constant of Cu(II) complexes may be due to the fact of more stable nature of Cu(II). The value of stability constant of Cu(II)—Ligand 2 complex is greater than that of Cu(II)–Ligand 1 and Cu(II)–Ligand 3. The same of Ni(II)–Ligand 3 complex is greater than that of Ni(II)–Ligand 1 and Ni(II)–Ligand 2.
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  • 51
    Publication Date: 2015-11-24
    Description: We present a mid-infrared pulsed cavity ring-down spectroscopy (CRDS) setup based on difference frequency mixing of a tunable dye laser pumped by a Nd:YAG laser and the residual 1064 nm pulse in a temperature-stabilized lithium niobate (LiNbO 3 ) crystal. The performances of such a spectrometer have been investigated by studying the absorption spectrum of methane around 3 µm at room temperature. Our results show a minimum detectable absorption coefficient of 5 × 10 −8  cm −1 . Our approach combines the excellent sensitivity of CRDS with the wide tunable range of difference frequency generation (DFG) with a dye laser. However, the relatively low resolution of this spectrometer prevents the quantification of methane in a wide pressure range. To our knowledge, we report here the first realization and application of a pulsed DFG-based CRDS experiment used for sensitive trace gas detection.
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  • 52
    Publication Date: 2015-11-21
    Description: A constant pressure ab initio technique is applied in order to study the structural response of magnesium fluoride (MgF 2 ) under the hydrostatic pressure up to 800 GPa. The orthorhombic-to-tetragonal phase transformation of MgF 2 is obtained at 720 GPa. This phase transition is also analyzed from the total energy and enthalpy calculations, and it is found that this phase change should occur around 260 GPa. As far as we know, this tetragonal phase has not been obtained in any previous studies.
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  • 53
    Publication Date: 2015-11-25
    Description: A telescope-grating-deformable scheme is proposed to compensate the angular dispersion of ultrabroadband spectrum. A simple design consideration is formulated based on the large angular dispersion of the idler from noncollinear optical parametric amplification. A proof of principle experiment is demonstrated. A 3-μJ ultrabroadband near-infrared pulse with spectrum range from 700 to 1400 nm has been generated. The technique has great potential to provide an ultrabroadband seed with negligible angular dispersion for high-power amplification of few-cycle pulses.
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  • 54
    Publication Date: 2015-06-02
    Description: Up-conversion can be the main mechanism of energy losses in laser glasses with high concentration of erbium ions. This investigation is devoted to the evaluation of up-conversion parameters in several phosphate and silicate Er-doped glasses. Analysis of the luminescent lifetime shortening at high excitation level has shown that the up-conversion parameters in different glasses can differ by an order of magnitude. The smallest up-conversion was observed in Ba crown silicate glass and Li–Ln-phosphate glass.
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  • 55
    Publication Date: 2015-06-03
    Description: Wavefront aberrations are one of the largest uncertainty factors in present atom interferometers. We present a detailed numerical and experimental analysis of this effect based on measured aberrations from optical windows. By placing windows into the Raman beam path of our atomic gravimeter, we verify for the first time the induced bias in very good agreement with theory. Our method can be used to reduce the uncertainty in atomic gravimeters by one order of magnitude, resulting in an error of 〈3 × 10 −10 g, and it is suitable in a wide variety of atom interferometers with thermal or ultracold atoms. We discuss the limitations of our method, potential improvements, and its role in future generation experiments.
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  • 56
    Publication Date: 2015-06-03
    Description: In this review, we have discussed the potential application of the emerging imaging modality, i.e., optical coherence tomography (OCT) for glucose monitoring in biological tissues. OCT provides monitoring of glucose diffusion in different fibrous tissues like in sclera by determining the permeability rate with acceptable accuracy both in type 1 and in type 2 diabetes. The maximum precision of glucose measurement in Intralipid suspensions, for example, with the OCT technique yields the accuracy up to 4.4 mM for 10 % Intralipid and 2.2 mM for 3 % Intralipid.
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  • 57
    Publication Date: 2015-06-03
    Description: Optical-feedback cavity-enhanced absorption spectroscopy is a highly sensitive trace gas sensing technique that relies on feedback from a resonant intracavity field to successively lock the laser to the cavity as the wavelength is scanned across a molecular absorption with a comb of resonant frequencies. V-shaped optical cavities have been favoured in the past in order to avoid additional feedback fields from non-resonant reflections that potentially suppress the locking to the resonant cavity frequency. A model of the laser–cavity coupling demonstrates, however, that the laser can stably lock to a resonant linear cavity, within certain constraints on the relative intensity of the two feedback sources. By mode mismatching the field into the linear cavity, we have shown that it is theoretically and practically possible to spatially filter out the unwanted non-resonant component in order for the resonant field to dominate the feedback competition at the laser. A 5.3  \(\upmu \hbox {m}\)  cw quantum cascade laser scanning across a \(\hbox {CO}_2\) absorption feature demonstrated stable locking to achieve a minimum detectable absorption coefficient of \(2.7\,\times \,10^{-9}\,\hbox {cm}^{-1}\) for 1-s averaging. Detailed investigations of feedback effects on the laser output verified the validity of our theoretical models.
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  • 58
    Publication Date: 2016-07-14
    Description: A new method of pump-coupling in diode-pumped alkali vapor amplifier is reported, which uses ring-LD to tightly surround the alkali vapor cell for directly coupled side-pumping. The kinetic and fluid dynamic modeling, numerical approaches of the ring-LD side-pumped configuration are proposed and applied to the static and the flowing-gas Cs vapor amplifiers. Pump intensity and temperature distribution in the cell are simulated. Influences of some important factors on laser power are calculated and analyzed. Comparisons of different pumped configurations are made, demonstrating the highest utilizing efficiency of pump power of the ring-LD side-pumped configuration. Thus the model is very helpful for designing high-power side-pumped alkali vapor amplifiers.
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  • 59
    Publication Date: 2016-07-14
    Description: Within the frame of the one-electron approximation, we calculate the electron binding energies of the \(\hbox {Na}_{55}^-\) cluster which allows for the identification of the icosahedral structure of the cluster through comparison with experimental photoelectron spectroscopy data. The surface of the icosahedral cluster is represented as a slightly deformed spherical surface, and the corresponding splitting of the energy levels caused by this symmetry reduction is calculated. Subsequently, we demonstrate that the calculated energies of photoelectrons agree very well with the experimental values. This gives an unambiguous demonstration of the role of the cluster structure in photoelectron spectra, whereas electronic shell filling effects are less important.
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  • 60
    Publication Date: 2016-07-14
    Description: Turbulent mixing is highly important in flows that involve heat and mass transfer. Information on turbulent heat flux is needed to validate the mixing models implemented in numerical simulations. The calculation of turbulent heat fluxes requires instantaneous information on temperature and velocity. Even using minimally intrusive laser optical methods, simultaneous measurement of temperature and velocity is still a challenge. In this study, thermographic phosphor particles are used for simultaneous thermometry and velocimetry: conventional particle image velocimetry is combined with temperature-dependent spectral shifts of BAM:Eu 2+ phosphor particles upon UV excitation. The novelty of this approach is the analysis of systematic errors and verification using the well-known properties of a heated turbulent jet issuing into a low velocity, cold coflow. The analysis showed that systematic errors caused by laser fluence, multiple scattering, or preferential signal absorption can be reduced such that reliable measurement of scalar fluxes becomes feasible, which is a prerequisite for applying the method to more complex heat transfer problems.
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  • 61
    Publication Date: 2016-07-21
    Description: The liquid–solid catalytic reaction of epichlorohydrin and sodium butyrate with tetrabutylammonium bromide as a phase transfer catalyst was studied in this paper. The shrinking core model was applied. The analysis of the reaction based on the kinetic model showed a reaction-controlled regime at temperatures varying from 90 to 100°C. The exterior diffusivity was removed between 300 and 400 rpm. The internal diffusivity was removed when the particle size was 2 × 10 –4 m. Reaction rate constants were calculated at different temperatures. The correlation was obtained when the proposed kinetic model was applied to all the experimental data for predictive evaluations and the activation energy was 37.01 kJ mol –1 .
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  • 62
    Publication Date: 2016-07-21
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  • 63
    Publication Date: 2016-07-21
    Description: Based on the synthesis of hydroxyapatite (HA) with different morphologies, such as nanorod-like, flower-like and sphere-like assembled HA nanorods, a new strategy has been developed for the removal of heavy metal ions such as Pb 2+ , Cu 2+ , Mn 2+ , Zn 2+ . The dependence of removal efficiency on the morphology and the suspended concentration of trapping agent, the removal time and selectivity were evaluated and discussed. The experimental results proved that the removal capacity of flower-like assembled HA nanorods (NAFL-HA) was the best, and the maximum removal ratio for Pb 2+ ion was 99.97%. The mechanism of Pb 2+ removal was studied in detail, noting that some metal ions were completely incorporated into hydroxyapatitie to produce Pb-HA. It reveals that the metal ions capture by HA is mainly controlled by sample surface adsorption and co-precipitation, which are directly controlled by sample morphology.
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  • 64
    Publication Date: 2016-07-21
    Description: A way of determining the cation exchange capacity of montmorillonite by simultaneous thermal analysis is developed using as an example the bentonites of the 10th Khutor deposit (Republic of Khakassia) and the Vodopadnyi area (Sakhalin Island). A correlation is established between the cation exchange capacity of smectite and its weight loss upon heating in the range of dehydration; the enthalpy of dehydration of montmorillonite; and the weight loss and the enthalpy of thermal dissociation of ethylene glycol contained in the interlayer space of the mineral’s crystal structure. These data open up new possibilities for determining the cation exchange capacity of montmorillonite, the most important technological indicator of the natural clay nanomineral.
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  • 65
    Publication Date: 2016-07-23
    Description: Multicolor deep-ultraviolet femtosecond pulses are generated in a spectral range of 220–300 nm with pulse energies exceeding 1 μJ. Pulses with shorter wavelengths are also generated with the shortest wavelength of 185 nm. These pulses are generated through cascaded four-wave mixing induced in hydrogen gas by use of three-color femtosecond pump pulses at 1200, 800, and 267 nm. The third pulse dramatically enhances the intensities of the multicolor deep-ultraviolet pulses. The cross-phase modulation induced by the two intense near-infrared pulses broadens the spectral width of each multicolor emission, resulting in a spectral width supporting a transform-limited duration shorter than 10 fs.
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  • 66
    Publication Date: 2016-07-27
    Description: In this work, we present a modification to conventional X-rays fluorescence using electrons as excitation source and compare it with the traditional X-ray excitation for the study of pigments. For this purpose, we have constructed a laser-based source capable to produce X-rays as well as electrons. Because of the large penetration depth of X-rays, the collected fluorescence signal is a combination of several material layers of the artwork under study. However, electrons are stopped in the first layers, allowing a more superficial analysis. We show that the combination of both excitation sources can provide extremely valuable information about the structure of the artwork.
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  • 67
    Publication Date: 2016-07-27
    Description: A correction for the undesirable effects of direct and indirect cross-interference from water vapour on ammonia (NH 3 ) measurements was developed using an optical laser sensor based on cavity ring-down spectroscopy. This correction relied on new measurements of the collisional broadening due to water vapour of two NH 3 spectral lines in the near infra-red (6548.6 and 6548.8 cm −1 ), and on the development of novel stable primary standard gas mixtures (PSMs) of ammonia prepared by gravimetry in passivated gas cylinders at 100 μmol mol −1 . The PSMs were diluted dynamically to provide calibration mixtures of dry and humidified ammonia atmospheres of known composition in the nmol mol −1 range and were employed as part of establishing a metrological traceability chain to improve the reliability and accuracy of ambient ammonia measurements. The successful implementation of this correction will allow the extension of this rapid on-line spectroscopic technique to exposure chamber validation tests under controlled conditions and ambient monitoring in the field.
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  • 68
    Publication Date: 2016-08-01
    Description: In this paper, we analyze the influence of large-scale segmentation errors in the morphology of high-performance optical gratings. It is thus assumed that the optical grating under consideration (typical lateral extends S are 10–1000 mm) can be spatially decomposed into a great many but unique sub-segments ( \(\ll S\) ; typical extends are 10–100  \(\upmu \mathrm{m}\) ). Any violation of the perfect periodicity will result in the generation of stray light, especially Rowland ghosts, which radiate into a small angular region around the grating’s diffraction orders. In this paper, we focus on three different kinds of segmentation errors. On the one hand, there are statistic as well as deterministic alignment errors between otherwise perfect sub-segments. On the other hand, we analyze the effect of chirping of geometrical parameters, i.e., the groove width, within every sub-segment. Most importantly, we find that the particular type of imperfection results in a unique characteristic of the according stray light spectrum which thus acts as a fingerprint. We come to this conclusion on three different ways. First, we rely on a simple theoretical model that is based on scalar diffraction theory. Second, we have performed rigorous numerical simulations for a high aspect ratio purely dielectric spectrometer grating ( \(\hbox {period} = {667}\,\mathrm{nm}\) ). Third, the very same grating was then fabricated by e-beam lithography and its stray light spectrum was measured with a purposely designed optical setup. Eventually, all different routes to analyze the problem turn out to be in very good agreement, and we are confident that stray light measurements can be used as an important tool in the detection of fabrication imperfections.
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  • 69
    Publication Date: 2016-08-04
    Description: We report diffusion coefficients of optically pumped lithium atoms in helium buffer gas. The free-induction decay and the spin-echo signals of ground-state atoms were optically detected in an external magnetic field with the addition of field gradient. Lithium hot vapor was produced in a borosilicate-glass cell at a temperature between 290 and \(360\,^{\circ }\hbox {C}\) . The simple setup using the glass cells enabled lithium atomic spectroscopy in a similar way to other alkali-metal atoms and study of the collisional properties of lithium atoms in a hot-vapor phase.
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  • 70
    Publication Date: 2016-08-05
    Description: We propose and demonstrate a laser frequency stabilization scheme which generates a dispersion-like tunable Doppler-free dichroic lock (TDFDL) signal. This signal offers a wide tuning range for lock point (i.e. zero-crossing) without compromising on the slope of the locking signal. The method involves measurement of magnetically induced dichroism in an atomic vapour for a weak probe laser beam in the presence of a counter-propagating strong pump laser beam. A simple model is presented to explain the basic principles of this method to generate the TDFDL signal. The spectral shift in the locking signal is achieved by tuning the frequency of the pump beam. The TDFDL signal is shown to be useful for locking the frequency of a cooling laser used for magneto-optical trap (MOT) for 87 Rb atoms.
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  • 71
    Publication Date: 2016-08-05
    Description: Detection of multiple transitions in NO and H 2 O using multi-mode absorption spectroscopy, MUMAS, with a quantum cascade laser, QCL, operating at 5.3 μm at scan rates up to 10 kHz is reported. The linewidth of longitudinal modes of the QCL is derived from pressure-dependent fits to experimental MUMAS data. Variations in the spectral structure of the broadband, multi-mode, output of the commercially available QCL employed are analysed to provide accurate fits of modelled MUMAS signatures to the experimental data.
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  • 72
    Publication Date: 2016-08-05
    Description: We propose a novel approach to site-resolved detection of a 2D gas of ultracold atoms in an optical lattice. A near-resonant laser beam is coherently scattered by the atomic array, and after passing a lens its interference pattern is holographically recorded by superimposing it with a reference laser beam on a CCD chip. Fourier transformation of the recorded intensity pattern reconstructs the atomic distribution in the lattice with single-site resolution. The holographic detection method requires only about two hundred scattered photons per atom in order to achieve a high reconstruction fidelity of 99.9 %. Therefore, additional cooling during detection might not be necessary even for light atomic elements such as lithium. Furthermore, first investigations suggest that small aberrations of the lens can be post-corrected in imaging processing.
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  • 73
    Publication Date: 2016-07-13
    Description: We experimentally demonstrate that the spectral resolution of Fourier transform interferometer could be greatly enhanced by using the dispersive property of semiconductor GaAs in the near infrared region and obtain the frequency distribution of the input light from interference pattern by defining a new frequency transform factor. The results show the effectiveness of this method in the slow light interference system.
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  • 74
    Publication Date: 2016-07-16
    Description: Characteristics of a ZnSe:Fe 2+ laser operating at room temperature of active polycrystalline elements with large transversal dimensions are investigated. The active elements had a shape of plates with diameters D  = 25–63 mm and width of ~4 mm, doped from two sides with iron ions by the diffusion method. The plates were doped in the process of hot isostatic pressing at an argon pressure of 100 MPa and temperature of 1250 °C for 75–151 h. The laser was pumped by a non-chain electrodischarge HF laser operated in a single-pulse mode. The employment of active elements with greater transversal dimensions resulted in a suppressed transversal parasitic oscillation at large diameters of the pumping spot. The generation energy of 1.43 J with the slope efficiency η slope  = 53 % and the total efficiency with respect to the energy absorbed in an active element η abs  ≈ 48 % was obtained on the sample of diameter D  = 63 mm.
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  • 75
    Publication Date: 2016-07-21
    Description: A fourteen-constant graphic scheme is proposed for evaluating the thermodynamic properties of branched paraffin hydrocarbons. Absolute entropy S f, 298 gas of 159 alkanes, of which 157 alkanes have yet to be studied experimentally, are calculated using 105 experimental data S f, 298 K, gas for alkanes CН 4 –С 32 Н 66 .
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  • 76
    Publication Date: 2016-07-21
    Description: The effect the degree of hydration has on optical and electrophysical properties of water/AOT/ n -hexane system is studied. It is found that AOT reverse micelles form aggregates whose dimensions grow along with the degree of hydration and temperature. Aggregation enhances their electrical conductivity and shifts the UV spectrum of AOT reverse emulsions to the red region. Four states of water are found in the structure of AOT reverse micelles.
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  • 77
    Publication Date: 2016-07-21
    Description: The content of oxygen in Ca 1− x Pr x MnO 3−δ ( x = 0.1) material with perovskite-like structure is determined at 750–950°C and oxygen partial pressures in the gas phase from 3 × 10 −6 to 0.55 atm. The regions of existence of orthorhombic, tetragonal, and cubic structural modifications are determined. The equilibrium constants, enthalpies, and entropies of reactions of the formation of defects are determined, allowing us to describe the experimental δ ( \({p_{{O_2}}}\) , Т ) dependences accurately and calculate the concentrations of manganese ions. It is shown that a change in Ca 0.9 Pr 0.1 MnO 3–δ structure has a considerable effect on the thermodynamic functions of reactions of the formation of defects.
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  • 78
    Publication Date: 2016-07-21
    Description: The complex rose-like inorganic templates assembled by the ZnO/ZnO 2 hybrid nanosheets have been constructed with hydrogen peroxide as an additive to control the structure of a precursor. The surface morphologies of the inorganic templates can be controlled by varying the reaction time and the amount of hydrogen peroxide. The process of the precursor growth takes a dissolution-growth route under hydrothermal conditions. The chemical composition of the precursor is determined by X-ray diffraction (XRD) and Raman analyses, indicating the existence of peroxide in the precursor. Combined with transmission electron microscopy (TEM) data, the ZnO/ZnO 2 hybrid precursor is proposed to act as an inorganic template for the growth of secondary crystal structures. The dandelion-like ZnO crystal is fabricated by using rose-like peroxide precursor as the inorganic template. The structural evolution of hierarchical ZnO crystal is studied by monitoring the influence of the reaction time.
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  • 79
    Publication Date: 2016-07-21
    Description: The process of butene-1 isomerization in the presence of two groups of samples of zeolite-containing catalyst (ZCC) that earlier participated in the traditional and oxidative catalytic cracking of vacuum gasoil is investigated. It is established that the nature of the reaction mixture and conditions of the cracking process are key factors in forming the acidic and basic properties of the catalyst. It is shown that the highest activity in the butene-1 isomerization into cis -/ trans -butene-2 is demonstrated by ZCC samples that participated in the oxidative catalytic cracking (oxycracking). It is suggested that the enhanced catalytic activity of this group of ZCC samples was related to the availability of acid–base centers in the form of radical-like oxygen along with protic- and aprotic-type acidic centers in the structure of the oxidative compaction products.
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  • 80
    Publication Date: 2016-07-21
    Description: Heats of solution of crystalline α-aminobutyric acid in water and in aqueous solutions of potassium hydroxide at 298.15 K are measured by means of direct calorimetry. Standard enthalpies of formation of the amino acid and products of its dissociation in an aqueous solution are calculated.
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  • 81
    Publication Date: 2016-07-21
    Description: The optimized geometries and interaction energies of the intermolecular heterodimers of coronene with o -, m -, and p -dimethylbenzenes (xylenes) calculated by DFT in the PBE0 and B97D functionals were compared. The applicability of coronene as a model for qualitative assessment of the interaction of mononuclear aromatic compounds with the graphite surface was demonstrated. The necessity of including long-range dispersion interactions in DFT calculations of the dimerization energies of aromatic systems was shown. The sorption enthalpies of p - and m -xylenes were shown to be almost equal irrespective of the conditions of the chromatographic experiment. The preferred sorption of p - over m -xylene on graphite is solely due to the entropy factor.
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  • 82
    Publication Date: 2016-07-21
    Description: The phosphine oxidation reaction with oxygen in alcohol solutions of copper (I, II) halides is studied. Kinetic parameters, intermediates, and by-products are studied by means of NMR 31 Р-, IR-, UV-, and ESR- spectroscopy; and by magnetic susceptibility, redox potentiometry, gas chromatography, and elemental analysis. A reaction mechanism is proposed, and the optimum conditions are found for the reaction of oxidative alkoxylation phosphine.
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  • 83
    Publication Date: 2016-07-21
    Description: The effect the conditions of thermal treatment have on a specific surface and the number of primary adsorption centers is studied. The relationship between changing adsorption characteristics and changes in the structure of nanofibrous aluminum oxide is considered.
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  • 84
    Publication Date: 2016-07-21
    Description: Three morphologies of ZnO nanomaterials (ZnO-hand grenade, ZnO-rod and ZnO-particle) were synthesized via a facile hydrothermal method. The as prepared ZnO nanomaterials were used as photoelectrodes to fabricate dye sensitized solar cells (DSSCs). Of the three samples, ZnO-particle displays the highest photovoltaic conversion efficiency which can be attributed to the high surface area to absorb light more efficiently. Intensity modulated photocurrent spectroscopy (IMPS), and intensity-modulated voltage spectroscopy (IMVS) indicate that ZnO-rod provides superior electron transfer kinetics: fast electron transfer and long electron lifetimes with suppressed recombination.
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  • 85
    Publication Date: 2016-07-21
    Description: The thermodynamic characteristics of sorption of 24 organic compounds of various classes from the gas phase on the binary stationary phase based on polyethylene glycol 400 and permethylated β-cyclodextrin were determined. The influence of geometrical structure and optical activity of organic compounds on the possibility of forming sorbate–macrocycle complexes was examined. It was found that the studied stationary phase shows the enantioselectivity towards low-polar terpenes under the conditions of gas chromatography.
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  • 86
    Publication Date: 2016-07-21
    Description: A new effect leading to the slowing of recombination in a weakly nonideal ion plasma is considered. The solvation of ions is included in the explanation of the results from studying a gas discharge afterglow in a fluorine atmosphere. It is shown that recombination in such a system is slowed in comparison to the standard relationships for ideal plasma. The formation and composition of cluster ions in such a medium are considered. The relationship between the variation in the kinetics of recombination and the course of the process according to a complicated mechanism with the intermediate formation of metastable cluster pairs is established. A quantitative model is built and a formula allowing us to describe the recombination rate over a wide range of parameters of the medium is obtained. It is shown that the proposed model is in good agreement with the experimental data.
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  • 87
    Publication Date: 2016-07-21
    Description: The solubility of lead oxide in NaOH + (20%)Na 2 CO 3 and NaOH + (40%)Na 2 CO 3 melts was studied by the isothermal saturation method. The model mechanisms of dissolution were considered. The thermodynamic parameters were calculated.
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  • 88
    Publication Date: 2016-07-21
    Description: Using a variety theoretical approaches within the Debye, Davidson–Cole, and Forsman models, and an approach based on the Dissado–Hill theory, dielectric spectra of 2,3-butanediol in the temperature range of 298 to 423 K are analyzed. It is shown that the dielectric spectra of 2,3-butanediole are described by the Davidson–Cole equation, and the β DC parameter depends strongly on temperature. The spectrum of dielectric relaxation of 2,3-butanediol within the Debye theory is presented as the sum of two areas of dispersion, and conclusions are drawn regarding possible mechanisms of dispersion responsible for the obtained fields. The relaxation times of 2,3-butanediol, calculated using different equations describing the nonlinear behavior of relaxation times, are compared. The dipole moments of clusters are obtained for the first time using the Dissado–Hill cluster model, and a preliminary analysis of them is performed.
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  • 89
    Publication Date: 2016-07-21
    Description: The volume ratios in acetonitrile–ethyl acetate (90 : 10, 95 : 5), acetonitrile–isopropanol–ethyl acetate (70 : 15 : 15, 80 : 5 : 15), and isopropanol–1-butanol (50 : 50) mixtures were determined. Their mixing with water (1 : 1) and storage at–10°C led to partitioning into two immiscible liquid phases without formation of the ice phase. The mixtures were shown to be useful as hydrophilic extractants in low-temperature liquidliquid extraction of phenol from aqueous solutions.
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  • 90
    Publication Date: 2016-07-21
    Description: The model that considers the nonideality of aqueous solutions of electrolytes with allowance for independent contributions of hydration of ions of various types and electrostatic interactions was substantiated using the cluster ion model. The empirical parameters in the model equations were found to be the hydrophilic and hydrophobic hydration numbers of ions in the standard state and the dispersion of their distribution over the stoichiometric coefficients. A mathematically adequate description of the concentration dependences of the osmotic coefficients and average ion activity coefficients of electrolytes was given for several systems. The difference in the rate of the decrease in the hydrophilic and hydrophobic hydration numbers of ions leads to extremum concentration dependences of the osmotic coefficients, which were determined by other authors from isopiestic data for many electrolytes and did not find explanation.
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  • 91
    Publication Date: 2016-07-24
    Description: The hole transport buffer layer (HTL) known as PEDOT:PSS is found to be sensitive to polar solvents often used in the preparation of solution-processed perovskite-based solar cell. We employed \(\hbox {CH}_{3}\,\hbox {NH}_{3}\,\hbox {PbI}_{3}\) perovskite absorber sandwiched between two charge transport layers to analyze the effect of precursor solvent. By introducing skin-depth interfacial defect layer (IDL) on PEDOT:PSS film we studied the overall performance of the devices using one-dimensional device simulator. Both enhanced conductivity and variations in valence band offset (VBO) of IDL were considered to analyze device performance. A power conversion efficiency (PCE) of the devices was found to grow by 35 % due to increased conductivity of IDL by a factor of 1000. Furthermore, we noted a drastic reduction in PCE of the device by reducing the work function of IDL by more than 0.3eV . The thickness of interfacial defect layer was also analyzed and found to decrease the PCE of the devices by 18 % for fourfold increase in IDL thickness. The analysis was remarkably reproduced the experimentally generated device parameters and will help to understand the underlying physical process in perovskite-based solar cell.
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  • 92
    Publication Date: 2016-07-26
    Description: We present a diode laser system optimized for laser cooling and atom interferometry with ultra-cold rubidium atoms aboard sounding rockets as an important milestone toward space-borne quantum sensors. Design, assembly and qualification of the system, combing micro-integrated distributed feedback (DFB) diode laser modules and free space optical bench technology, is presented in the context of the MAIUS (Matter-wave Interferometry in Microgravity) mission. This laser system, with a volume of 21 l and total mass of 27 kg, passed all qualification tests for operation on sounding rockets and is currently used in the integrated MAIUS flight system producing Bose–Einstein condensates and performing atom interferometry based on Bragg diffraction. The MAIUS payload is being prepared for launch in fall 2016. We further report on a reference laser system, comprising a rubidium stabilized DFB laser, which was operated successfully on the TEXUS 51 mission in April 2015. The system demonstrated a high level of technological maturity by remaining frequency stabilized throughout the mission including the rocket’s boost phase.
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  • 93
    Publication Date: 2016-07-26
    Description: We demonstrate fourfold coherent combining in a gas-filled hollow-fiber compressor with 92 % efficiency. Our passive approach relies on the use of carefully oriented birefringent plates for temporal pulse dividing and combining. We perform a detailed theoretical and experimental analysis of the effects degrading the combining process, as polarization change or nonlinear interactions between pulse replicas. We show how to overcome these limitations to generate 10-fs output pulses with high temporal quality.
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  • 94
    Publication Date: 2016-07-29
    Description: Characteristics of annular beams propagating through atmospheric turbulence along a downlink path and an uplink path are studied in detail by using numerical simulation method. It is found that in downlink the influence of atmospheric turbulence on the characteristics is quite different from that in uplink because of the altitude-dependent index structure constant. It is shown that, when the zenith angle θ is not large enough, it is always \(\sigma_{{I\,{\text{up}}}}^{2} 〉 \sigma_{{I\,{\text{down}}}}^{2}\) on propagation whatever the value of the obscure ratio ε is, where \(\sigma_{{I\,{\text{up}}}}^{2}\) and \(\sigma_{{I\,{\text{down}}}}^{2}\) are the on-axis scintillation index in uplink and downlink, respectively. However, when θ is large enough, \(\sigma_{{I\,{\text{down}}}}^{2}\) is close to \(\sigma_{{I\,{\text{up}}}}^{2}\) as the propagation distance z increases, and \(\sigma_{{I\,{\text{up}}}}^{2}\) and \(\sigma_{{I\,{\text{down}}}}^{2}\) overlap each other as ε increases. Furthermore, as z increases, \(\sigma_{{I\,{\text{up}}}}^{2}\) approaches an asymptotical value when θ is not large enough, and the saturation phenomenon of \(\sigma_{{I\,{\text{up}}}}^{2}\) appears when θ is large enough. But the asymptotical value and the saturation phenomenon of \(\sigma_{{I\,{\text{down}}}}^{2}\) never appear. On the other hand, the energy focusability in downlink is better than that in uplink, and the difference of energy focusability between a downlink and an uplink increases with increasing θ or decreasing ε . In addition, in downlink there may exist sidelobes of intensity distributions when θ is not large enough, but the sidelobes never appear in uplink.
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  • 95
    Publication Date: 2016-08-02
    Description: We study the dispersion of the extraordinary dielectric function real and imaginary parts in the wide terahertz-frequency range of the lowest polariton branch for bulk LiNbO 3 and Mg:LiNbO 3 crystals. At frequencies 0.1–2.5 THz, both dispersion parts are measured by means of standard time-domain terahertz spectroscopy, and at higher frequencies up to 5.5 THz, the dielectric function real part is determined using a common scheme of spontaneous parametric down-conversion under near-forward Raman scattering by phonon polaritons. A special approach is applied for measuring of the dielectric function imaginary part at frequencies 1–3 THz, based on the analysis of visibility of three-wave second-order interference under spontaneous parametric down-conversion. The generalized approximate expressions are obtained for complex dielectric function dispersion within the lower polariton branches of LiNbO 3 and Mg:LiNbO 3 . It is shown that the well-known decrease in terahertz-wave absorption of lithium niobate crystals under Mg-doping is caused by changes in the defect structure and reduction of coupling of the terahertz-frequency polaritons with Debye relaxational mode.
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  • 96
    Publication Date: 2016-08-06
    Description: We report improved fluorescence contrast between dyes by two-photon excitation with polarization-shaped laser pulses after transmission through a kagome fiber utilizing the anisotropy of the dye molecules. Particularly phase- and polarization-tailored pulse shapes are employed for two-photon excited fluorescence of dyes in a liquid environment at the distal end of the kagome fiber. The distortions due to the optical fiber properties are precompensated in order to receive predefined polarization-shaped laser pulses after the kagome fiber. This enables to optimally excite one dye in one polarization direction and simultaneously the other dye in the other polarization direction. The presented method has a high potential for endoscopic applications due to the unique properties of kagome fibers for guiding ultrashort laser pulses.
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  • 97
    Publication Date: 2016-07-08
    Description: A new nonlinear optical material, 4-[(2 E )-3-(3-fluorophenyl) prop-2-enoyl] benzonitrile (3FPB), belonging to chalcone family was synthesized and characterized by FTIR and linear absorption spectroscopy. Single-crystal X-ray diffraction reveals that the new material crystallizes in monoclinic system with P 2 1 /c space group and lattice parameters a  = 6.4841(2) Å, b  = 13.6038(5) Å, c  = 14.6418(6) Å, α  = 90.00°, β  = 94.552(2)° and γ  = 90°. The crystallographic perfection of the synthesized material has been analyzed by X-ray powder diffraction. The X-ray powder diffraction peaks of the sample were indexed with hkl values. The UV–visible spectrum for 3FPB crystals showed the optical transmittance window and a lower cutoff wavelength of absorption at 343 nm. The direct transition band gap energy and indirect transition energy gap were determined using Tauc’s plots. The thermal stability and melting point of the material have been investigated by thermogravimetric analysis/differential thermal analysis (TGA/DTA). The Thermogravimetric curve showed the absence of any phase transition before melting point. Third-order nonlinear absorption and optical limiting experiment were carried out using open-aperture Z -scan experiment with Nd:YAG laser nanosecond pulses at a wavelength of 532 nm.
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  • 98
    Publication Date: 2016-06-23
    Description: We analyzed the surfaces of vitreous silica (quartz) and borosilicate glass (Pyrex) substrates exposed to rubidium (Rb) vapor by X-ray photoelectron spectroscopy (XPS) to understand the surface conditions of alkali metal vapor cells. XPS spectra indicated that Rb atoms adopted different bonding states in quartz and Pyrex. Furthermore, Rb atoms in quartz remained in the near-surface region, while they diffused into the bulk in Pyrex. For these characterized surfaces, we measured light-induced atom desorption (LIAD) of Rb atoms. Clear differences in time evolution, photon energy dependence, and substrate temperature dependence were found; the decay of LIAD by continuous ultraviolet irradiation for quartz was faster than that for Pyrex, a monotonic increase in LIAD with increasing photon energy from 1.8 to 4.3 eV was more prominent for quartz, and LIAD from quartz was more efficient at higher temperatures in the range from 300 to 580 K, while that from Pyrex was almost independent of temperature.
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  • 99
    Publication Date: 2016-06-24
    Description: Mid-infrared cavity ring-down spectroscopy (CRDS) using an external cavity, widely tunable pulsed quantum cascade laser operating at 3.8 μm, was employed for simultaneous detections of ethanol, ether and acetone in this paper. The experiments were performed with a maximum cavity mirror reflectivity of 99.915 % between the wave number 2614 and 2634 cm −1 , leading to an effective optical path length of 588 m. The absorption spectra of ethanol, ether and acetone were measured with high spectral resolution in the range of 2614–2634 cm −1 , and the spectroscopic analysis of the mixture of ethanol, ether and acetone with overlapping absorption spectra was demonstrated. The experimentally achieved detection limits ( \(3\sigma\) , or three times of standard deviation) for ethanol, ether and acetone were 157, 60 and 280 ppb, respectively. The simultaneously measured concentration results were in good agreement with the results with the standard gravimetric method, indicated that the mid-infrared CRDS has the potential for multi-component trace gas detection as well as for spectroscopic measurements of multi-broadband absorbers.
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  • 100
    Publication Date: 2016-06-28
    Description: Infrared to visible upconversion fluorescent nanoparticles of Gd 2 O 3 codoped with Ho 3+ /Yb 3+ ions are synthesized via thermal decomposition process. The X-ray diffraction analysis of as-synthesized nanoparticles and annealed sample at 1000 °C has shown body-centered cubic phase of Gd 2 O 3 . The synthesized phosphor has shown intense green emission upon 980-nm excitation. High-contrast latent fingermarks on some difficult semi-porous and non-porous surfaces under 980-nm diode laser excitation were developed through powder dusting and colloidal solution spraying techniques and the results are compared with the commercial green luminescent fingermark powder. The latent fingermarks were developed on transparent (biological glass slides), single-color (aluminum foil) and multicolor (plywood, plastic bottle and book cover page) background surfaces. The present study depicts that the upconversion-based latent fingermarks detection using Gd 2 O 3 :Ho 3+ /Yb 3+ phosphor material is suitable over the other conventional powders and has potential for practical applications in forensic science.
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