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  • ddc:550.78
  • ddc:551.46
  • ddc:551.9
  • English  (143)
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  • 2020-2024  (97)
  • 2020-2023  (46)
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  • 2020-2024  (97)
  • 2020-2023  (46)
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  • 1
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    Nitrogen and Phosphorus Control Soil Methane Uptake in Tropical Montane Forests (2021)
    Details
    Publication Date: 2022-04-04
    Description: Tropical forests contribute about one third to global annual CH4 uptake by soils. Understanding the factors that control the soil‐atmosphere exchange of CH4 at a large scale is a critical step to improve the CH4 flux estimate for tropical soils, which is presently poorly constrained. Since tropical forest degradation often involves shifts in nutrient availabilities, it is critical to evaluate how this will affect soil CH4 flux. Here, we report how nitrogen (N; 50 kg N ha−1 yr−1), phosphorus (P; 10 kg P ha−1 yr−1), and combined N + P additions affect soil CH4 fluxes across an elevation gradient of tropical montane forests. We measured soil CH4 fluxes in a nutrient application experiment at different elevations over a period of 5 years. Nutrient additions increased soil CH4 uptake after 4–5 years of treatment but effects were not uniform across elevations. At 1,000 m, where total soil P was high, we detected mainly N limitation of soil CH4 uptake. At 2,000 m, where total soil P was low, a strong P limitation of soil CH4 uptake was observed. At 3,000 m, where total P was low in the organic layer but high in mineral soil, we found N limitation of soil CH4 uptake. Our results show that projected increases of N and P depositions may increase soil CH4 uptake in tropical montane forests but the direction, magnitude, and timing of the effects will depend on forests' nutrient status and plant‐microbial competition for N and P.
    Description: Plain Language Summary: CH4 is a potent greenhouse gas that contributes to global warming. Tropical forests are a natural sink of CH4 but increasing nutrient depositions due to industrialization may alter the sink strength of tropical forests. Our results show that projected increases of nitrogen and phosphorus depositions may increase soil CH4 uptake in tropical montane forests but the direction, magnitude, and timing of the effects will depend on forests' nutrients and plant‐microbial competition.
    Description: Key Points: Projected increases in nitrogen and phosphorus depositions in the tropics will stimulate soil methane uptake in tropical montane forests. The direction, magnitude, and timing of nutrient deposition effects on soil methane uptake will depend on forests' nutrient status. Nutrient limitations on ecosystem processes have to be investigated in actual field conditions.
    Description: Deutsche Forschungsgemeinschaft (DFG) http://dx.doi.org/10.13039/501100001659
    Description: https://doi.org/10.25625/XLNKNK
    Keywords: ddc:551.9 ; ddc:631.41
    Language: English
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  • 2
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    Iron Exports From Catchments Are Constrained by Redox Status and Topography (2022)
    Details
    Publication Date: 2022-04-04
    Description: Fe(III) hydroxides stabilize organic carbon (OC) and P in soils. Observations of rising stream Fe concentrations are controversially posited to result from a flushing of iron‐rich deeper soil layers or a decrease of competing electron acceptors inhibiting Fe reduction (NO3− $\mathrm{N}{{\mathrm{O}}_{3}}^{-}$ and SO42− $\mathrm{S}{{\mathrm{O}}_{4}}^{2-}$). Here, we argue that catchment topography constrains the release of Fe, OC, and P to streams. We therefore incubated organic topsoil and mineral subsoil and modified the availability of NO3− $\mathrm{N}{{\mathrm{O}}_{3}}^{-}$. We found that Fe leaching was highest in topsoil. Fe, OC, and P released at quantities proportional to their ratios in the source soil. Supply of NO3− $\mathrm{N}{{\mathrm{O}}_{3}}^{-}$ reduced Fe leaching to 18% and increased pore water OC:Fe and P:Fe ratios. Subsoil, however, was an insignificant Fe source (〈0.5%). Here, the leached quantities of Fe, OC and P were highly disproportionate to the soil source with an excess of released OC and P. We tested if experimental findings scale up using data from 88 German catchments representing gradients in NO3− $\mathrm{N}{{\mathrm{O}}_{3}}^{-}$ concentration and topography. Average stream Fe concentrations increased with decreasing NO3− $\mathrm{N}{{\mathrm{O}}_{3}}^{-}$ and were high in catchments with shallow topography where high groundwater levels support reductive processes and topsoils are hydrologically connected to streams; but Fe concentrations were low in catchments with steep topography where flow occurs primarily through subsoils. OC:Fe and P:Fe ratios in the streams similarly varied by NO3− $\mathrm{N}{{\mathrm{O}}_{3}}^{-}$ and topography. This corroborates the findings from the laboratory experiment and suggests that catchment topography and competing electron acceptors constrain the formation of Fe‐reducing conditions and control the release of Fe, OC, and P to streams.
    Description: Plain Language Summary: Iron is the second most abundant metal in the crust; its cycle is tightly connected to those of carbon, oxygen, and sulfur. The oxidized form (FeIII) is almost insoluble, but Fe can be mobilized by complexation or microbial Fe reduction. Both processes depend on availability of organic C. We found that Fe concentrations in streams were constrained by the topography of catchments and NO3− $\mathrm{N}{{\mathrm{O}}_{3}}^{-}$ abundance. Shallower catchments are characterized by higher groundwater tables connecting the organic topsoils efficiently to streams. NO3− $\mathrm{N}{{\mathrm{O}}_{3}}^{-}$ suppresses Fe reduction as a competing electron acceptor to Fe. We conclude that trends in soil wetness or atmospheric N deposition can change the stability of Fe and thus the release of PO43− $\mathrm{P}{{\mathrm{O}}_{4}}^{3-}$ and harmful metals to surface waters.
    Description: Key Points: Organic topsoils leach substantial amounts of Fe when incubated in the absence of NO3, a competing electron acceptor that inhibits Fe reduction. Shallow catchments with fluvially coupled topsoils and low NO3 availability release 200 fold more Fe than steep ones with high NO3 abundance. Catchment topography and NO3 availability explain 62%–64% of the variability of Fe concentration and OC:Fe and P:Fe ratios across 88 streams.
    Description: EFRE‐Europe
    Description: https://doi.org/10.4211/hs.43601618877945c5a46b715aa98db729
    Keywords: ddc:551.9
    Language: English
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  • 3
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    Water Isotopic Signature of Surface Snow Metamorphism in Antarctica (2021)
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    Publication Date: 2022-04-01
    Description: Water isotope ratios of ice cores are a key source of information on past temperatures. Through fractionation within the hydrological cycle, temperature is imprinted in the water isotopic composition of snowfalls. However, this signal of climatic interest is modified after deposition when snow remains at the surface exposed to the atmosphere. Comparing time series of surface snow isotopic composition at Dome C with satellite observations of surface snow metamorphism, we found that long summer periods without precipitation favor surface snow metamorphism altering the surface snow isotopic composition. Using excess parameters (combining D,17O, and 18O fractions) allow the identification of this alteration caused by sublimation and condensation of surface hoar. The combined measurement of all three isotopic compositions could help identifying ice core sections influenced by snow metamorphism in sites with very low snow accumulation.
    Description: Plain Language Summary: Water isotopes in ice core records are often used to reconstruct past climate temperature variations. Classically, the temperature signal is thought to be imprinted in water isotopes of precipitation, and then archived in the ice core as it falls, and in cold areas of Antarctica, piles up for very long period. Here, we show that the surface snow isotopic composition varies in between precipitation events, suggesting that there might be more than one contribution to the isotopic signal in ice core records. This is particularly important for low accumulation sites, where the snow at the surface remains exposed for very long time periods. The combined use of several isotopic ratios in surface snow helps us disentangle the processes that create this signal.
    Description: Key Points: During summer without precipitation, intense snow metamorphism shows a strong water isotopic signature. During summer without precipitation, intense snow metamorphism shows a strong water isotopic signature. The d‐excess and 17O‐excess of the snow is a proxy of snow metamorphism for low accumulation regions.
    Description: FP7 Ideas: European Research Council (FP7 Ideas) http://dx.doi.org/10.13039/100011199
    Description: Foundation Prince Albert of Monaco
    Description: Alexander von Humboldt‐Stiftung (Humboldt‐Stiftung) http://dx.doi.org/10.13039/100005156
    Description: DFG project CLIMAIC
    Description: https://doi.pangaea.de/10.1594/PANGAEA.934273
    Keywords: ddc:551.31 ; ddc:551.9
    Language: English
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  • 4
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    Impacts of Drying and Rewetting on the Radiocarbon Signature of Respired CO2 and Implications for Incubating Archived Soils (2021)
    Details
    Publication Date: 2022-04-01
    Description: The radiocarbon signature of respired CO2 (∆14C‐CO2) measured in laboratory soil incubations integrates contributions from soil carbon pools with a wide range of ages, making it a powerful model constraint. Incubating archived soils enriched by “bomb‐C” from mid‐20th century nuclear weapons testing would be even more powerful as it would enable us to trace this pulse over time. However, air‐drying and subsequent rewetting of archived soils, as well as storage duration, may alter the relative contribution to respiration from soil carbon pools with different cycling rates. We designed three experiments to assess air‐drying and rewetting effects on ∆14C‐CO2 with constant storage duration (Experiment 1), without storage (Experiment 2), and with variable storage duration (Experiment 3). We found that air‐drying and rewetting led to small but significant (α 〈 0.05) shifts in ∆14C‐CO2 relative to undried controls in all experiments, with grassland soils responding more strongly than forest soils. Storage duration (4–14 y) did not have a substantial effect. Mean differences (95% CIs) for experiments 1, 2, and 3 were: 23.3‰ (±6.6), 19.6‰ (±10.3), and 29.3‰ (±29.1) for grassland soils, versus −11.6‰ (±4.1), 12.7‰ (±8.5), and −24.2‰ (±13.2) for forest soils. Our results indicate that air‐drying and rewetting soils mobilizes a slightly older pool of carbon that would otherwise be inaccessible to microbes, an effect that persists throughout the incubation. However, as the bias in ∆14C‐CO2 from air‐drying and rewetting is small, measuring ∆14C‐CO2 in incubations of archived soils appears to be a promising technique for constraining soil carbon models.
    Description: Plain Language Summary: Soils play a key role in the global carbon cycle by sequestering carbon from the atmosphere for decades to millennia. However, it is unclear if they will continue to do so as the climate changes. Microbial decomposition of soil organic matter returns carbon back to the atmosphere, and radiocarbon dating of this returning CO2 (∆14C‐CO2) can be used to quantify how long carbon is stored in ecosystems. Incubating archived soils could provide unique insight into soil carbon sequestration potential by quantifying the change in ∆14C‐CO2 over time. However, air‐drying, duration of archiving, and subsequent rewetting of soils may bias estimates of sequestration potential by altering the balance of younger versus older carbon leaving the soil. We compared ∆14C‐CO2 from soils incubated with and without air‐drying and archiving, and found that the air‐dried soils appeared to release slightly older carbon than soils that had never been air‐dried. The amount of time the soils were archived did not have an effect. Since the bias from air‐drying and rewetting was small, incubating archived soils appears to be a promising technique for improving our ability to model soil carbon cycling under global climate change.
    Description: Key Points: ∆14C of CO2 measured in incubations of archived soils provides additional constraints for soil carbon models. Air‐drying and rewetting soils shifted the ∆14C of respired CO2 by 10‰–20‰ independent of the duration of storage. Differences in direction and magnitude of ∆14C‐CO2 shifts between forests and grasslands depended on sampling year and system C dynamics.
    Description: EC, H2020, H2020 Priority Excellent Science, H2020 European Research Council (ERC) http://dx.doi.org/10.13039/100010663
    Description: https://doi.org/10.5281/zenodo.4959705
    Keywords: ddc:551.9 ; ddc:631.41 ; ddc:550.724
    Language: English
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  • 5
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    Do tree species affect decadal changes in soil organic carbon and total nitrogen stocks in Danish common garden experiments? (2021)
    Blackwell Publishing Ltd | Oxford, UK
    Details
    Publication Date: 2022-04-01
    Description: Temperate forest soils are often considered as an important sink for atmospheric carbon (C), thereby buffering anthropogenic CO2 emissions. However, the effect of tree species composition on the magnitude of this sink is unclear. We resampled a tree species common garden experiment (six sites) a decade after initial sampling to evaluate whether forest floor (FF) and topsoil organic carbon (Corg) and total nitrogen (Nt) stocks changed in dependence of tree species (Norway spruce—Picea abies L., European beech—Fagus sylvatica L., pedunculate oak—Quercus robur L., sycamore maple—Acer pseudoplatanus L., European ash—Fraxinus excelsior L. and small‐leaved lime—Tilia cordata L.). Two groups of species were identified in terms of Corg and Nt distribution: (1) Spruce with high Corg and Nt stocks in the FF developed as a mor humus layer which tended to have smaller Corg and Nt stocks and a wider Corg:Nt ratio in the mineral topsoil, and (2) the broadleaved species, of which ash and maple distinguished most clearly from spruce by very low Corg and Nt stocks in the FF developed as mull humus layer, had greater Corg and Nt stocks, and narrow Corg:Nt ratios in the mineral topsoil. Over 11 years, FF Corg and Nt stocks increased most under spruce, while small decreases in bulk mineral soil (esp. in 0–15 cm and 0–30 cm depth) Corg and Nt stocks dominated irrespective of species. Observed decadal changes were associated with site‐related and tree species‐mediated soil properties in a way that hinted towards short‐term accumulation and mineralisation dynamics of easily available organic substances. We found no indication for Corg stabilisation. However, results indicated increasing Nt stabilisation with increasing biomass of burrowing earthworms, which were highest under ash, lime and maple and lowest under spruce. Highlights We studied if tree species differences in topsoil Corg and Nt stocks substantiate after a decade. The study is unique in its repeated soil sampling in a multisite common garden experiment. Forest floors increased under spruce, but topsoil stocks decreased irrespective of species. Changes were of short‐term nature. Nitrogen was most stable under arbuscular mycorrhizal species.
    Description: Deutsche Forschungsgemeinschaff (DFG)
    Keywords: ddc:551.9 ; ddc:631.41
    Language: English
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  • 6
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    Assessing the robustness of carbonate‐associated sulfate during hydrothermal dolomitization of the Latemar platform, Italy (2021)
    Details
    Publication Date: 2022-03-30
    Description: Carbonate‐associated sulfate (CAS) is an important proxy for reconstructing marine sulfur cycling throughout Earth's history. In order to assess the impact of carbonate neomorphism on δ34SCAS data, a mineralogical‐spatial transect from early diagenetic limestone into low‐temperature hydrothermal dolostone was analyzed in the middle Triassic Latemar platform interior, northern Italy. This study addresses the yet unconstrained question whether hydrothermal dolostone preserves a marine δ34SCAS signature and, hence, might represent an archive for past seawater sulfate. In this study, δ34SCAS values were measured in low‐temperature hydrothermal dolostone and compared with data from their corresponding precursor limestone. Results shown here reveal that δ34SCAS values for dolostone and precursor limestone are indistinguishable. This points to a rock‐buffered middle Triassic marine δ34S signature not affected by hydrothermal alteration. Hence, hydrothermal dolostone represents, under favorable conditions, an archive for unraveling past marine sulfur cycling.
    Description: Deutsche Forschungsgemeinschaft http://dx.doi.org/10.13039/501100001659
    Keywords: ddc:551.9 ; ddc:552
    Language: English
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  • 7
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    Formation of chondrule analogs aboard the International Space Station (2021)
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    Publication Date: 2022-03-30
    Description: Chondrules are thought to play a crucial role in planet formation, but the mechanisms leading to their formation are still a matter of unresolved discussion. So far, experiments designed to understand chondrule formation conditions have been carried out only under the influence of terrestrial gravity. In order to introduce more realistic conditions, we developed a chondrule formation experiment, which was carried out at long‐term microgravity aboard the International Space Station. In this experiment, freely levitating forsterite (Mg2SiO4) dust particles were exposed to electric arc discharges, thus simulating chondrule formation via nebular lightning. The arc discharges were able to melt single dust particles completely, which then crystallized with very high cooling rates of 〉105 K h−1. The crystals in the spherules show a crystallographic preferred orientation of the [010] axes perpendicular to the spherule surface, similar to the preferred orientation observed in some natural chondrules. This microstructure is probably the result of crystallization under microgravity conditions. Furthermore, the spherules interacted with the surrounding gas during crystallization. We show that this type of experiment is able to form spherules, which show some similarities with the morphology of chondrules despite very short heating pulses and high cooling rates.
    Description: Carl Zeiss Meditec AG http://dx.doi.org/10.13039/501100002806
    Description: BIOVIA Science Ambassador program
    Description: Bundesministerium für Wirtschaft und Energie http://dx.doi.org/10.13039/501100006360
    Description: Deutsches Zentrum für Luft‐ und Raumfahrt http://dx.doi.org/10.13039/501100002946
    Description: NanoRacks LLC
    Description: DreamUp
    Description: Deutsche Forschungsgemeinschaft http://dx.doi.org/10.13039/501100001659
    Description: Dr. Rolf M. Schwiete Stiftung
    Keywords: ddc:549 ; ddc:550.78
    Language: English
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  • 8
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    Increased petrogenic and biospheric organic carbon burial in sub‐Antarctic fjord sediments in response to recent glacier retreat (2021)
    John Wiley & Sons, Inc. | Hoboken, USA
    Details
    Publication Date: 2022-03-30
    Description: Fjords are recognized as hotspots of organic carbon (OC) burial in the coastal ocean. In fjords with glaciated catchments, glacier discharge carries large amounts of suspended matter. This sedimentary load includes OC from bedrock and terrigenous sources (modern vegetation, peat, soil deposits), which is either buried in the fjord or remineralized during export, acting as a potential source of CO2 to the atmosphere. In sub‐Antarctic South Georgia, fjord‐terminating glaciers have been retreating during the past decades, likely as a response to changing climate conditions. We determine sources of OC in surface sediments of Cumberland Bay, South Georgia, using lipid biomarkers and the bulk 14C isotopic composition, and quantify OC burial at present and for the time period of documented glacier retreat (between 1958 and 2017). Petrogenic OC is the dominant type of OC in proximity to the present‐day calving fronts (60.4 ± 1.4% to 73.8 ± 2.6%) and decreases to 14.0 ± 2.7% outside the fjord, indicating that petrogenic OC is effectively buried in the fjord. Beside of marine OC, terrigenous OC comprises 2.7 ± 0.5% to 7.9 ± 5.9% and is mostly derived from modern plants and Holocene peat and soil deposits that are eroded along the flanks of the fjord, rather than released by the retreating fjord glaciers. We estimate that the retreat of tidewater glaciers between 1958 and 2017 led to an increase in petrogenic carbon accumulation of 22% in Cumberland West Bay and 6.5% in Cumberland East Bay, suggesting that successive glacier retreat does not only release petrogenic OC into the fjord, but also increases the capacity of OC burial.
    Description: Deutsche Forschungsgemeinschaft http://dx.doi.org/10.13039/501100001659
    Keywords: ddc:552 ; ddc:551.9
    Language: English
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  • 9
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    Past and Future Climate Variability Uncertainties in the Global Carbon Budget Using the MPI Grand Ensemble (2021)
    Details
    Publication Date: 2022-03-25
    Description: Quantifying the anthropogenic fluxes of CO2 is important to understand the evolution of carbon sink capacities, on which the required strength of our mitigation efforts directly depends. For the historical period, the global carbon budget (GCB) can be compiled from observations and model simulations as is done annually in the Global Carbon Project's (GCP) carbon budgets. However, the historical budget only considers a single realization of the Earth system and cannot account for internal climate variability. Understanding the distribution of internal climate variability is critical for predicting the future carbon budget terms and uncertainties. We present here a decomposition of the GCB for the historical period and the RCP4.5 scenario using single‐model large ensemble simulations from the Max Planck Institute Grand Ensemble (MPI‐GE) to capture internal variability. We calculate uncertainty ranges for the natural sinks and anthropogenic emissions that arise from internal climate variability, and by using this distribution, we investigate the likelihood of historical fluxes with respect to plausible climate states. Our results show these likelihoods have substantial fluctuations due to internal variability, which are partially related to El Niño‐Southern Oscillation (ENSO). We find that the largest internal variability in the MPI‐GE stems from the natural land sink and its increasing carbon stocks over time. The allowable fossil fuel emissions consistent with 3 C warming may be between 9 and 18 Pg C yr−1. The MPI‐GE is generally consistent with GCP's global budgets with the notable exception of land‐use change emissions in recent decades, highlighting that human action is inconsistent with climate mitigation goals.
    Description: Key Points: We use a single‐model large ensemble to estimate uncertainties from internal climate variability in the global carbon budget. The land sink accounts for most internal climate uncertainty which may permit 9–18 Pg C yr−1 in allowable emissions by 2050 (for 3°C warming).
    Description: European Union's Horizon 2020
    Keywords: ddc:551.9 ; ddc:551.6
    Language: English
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  • 10
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    The Spectrum of Slip Behaviors of a Granular Fault Gouge Analogue Governed by Rate and State Friction (2021)
    Details
    Publication Date: 2022-03-25
    Description: Currently, it is unknown how seismic and aseismic slip influences the recurrence and magnitude of earthquakes. Modern seismic hazard assessment is therefore based on statistics combined with numerical simulations of fault slip and stress transfer. To improve the underlying statistical models we conduct low velocity shear experiments with glass micro‐beads as fault gouge analogue at confining stresses of 5–20 kPa. As a result, we show that characteristic slip events emerge, ranging from fast and large slip to small scale oscillating creep and stable sliding. In particular, we observe small scale slip events that occur immediately before large scale slip events for a specific set of experiments. Similar to natural faults we find a separation of scales by several orders of magnitude for slow events and fast events. Enhanced creep and transient dilatational events pinpoint that the granular analogue is close to failure. From slide‐hold‐slide tests, we find that the rate‐and‐state properties are in the same range as estimates for natural faults and fault rocks. The fault shows velocity weakening characteristics with a reduction of frictional strength between 0.8% and 1.3% per e‐fold increase in sliding velocity. Furthermore, the slip modes that are observed in the normal shear experiments are in good agreement with analytical solutions. Our findings highlight the influence of micromechanical processes on macroscopic fault behavior. The comprehensive data set associated with this study can act as a benchmark for numerical simulations and improve the understanding of observations of natural faults.
    Description: Plain Language Summary: Earthquakes occur when two continental plates slide past each other. The motion is concentrated at the interface of the two plates which is called a fault. In many cases the fault is filled with granular material, called gouge, that supports the pressure between the plates. Therefore, the properties of this gouge determine how fast and how large an earthquake can be. It also has an influence on the time between earthquakes. In our study, we examine a simplified version of a fault gouge in a simple small‐scale model. Instead of rock material we use glass beads and measure how different conditions affect the motion of the model. We find that our model reproduces features of fault gouge because it shows similar behavior. When there is no motion our model fault becomes stronger with a rate equal to fault gouge. Also, the type of strengthening is analogous to fault gouge. During slip, the glass beads become weaker as the slip velocity increases in a similar manner as in natural faults. These results improve the understanding of computer simulations and natural observations.
    Description: Key Points: Slip modes in granular gouge are akin to natural fault slip. Glass beads are a suitable granular analogue for fault gouge and show rate‐and‐state dependent friction. Enhanced creep and small scale events are signals for imminent failure and indicate fault criticality.
    Description: Deutsche Forschungsgemeinschaft (DFG) http://dx.doi.org/10.13039/501100001659
    Description: 亥姆霍兹联合会致力, Helmholtz‐Zentrum Potsdam ‐ Deutsches GeoForschungsZentrum GFZ (GFZ) http://dx.doi.org/10.13039/501100010956
    Keywords: ddc:550.78
    Language: English
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  • 11
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    Last Glacial central Mediterranean hydrology inferred from Lake Trasimeno’s (Italy) calcium carbonate geochemistry (2021)
    Details
    Publication Date: 2022-03-24
    Description: There is still a paucity of hydrological data explaining the relationship between (rapid, millennial‐scale) climate forcing and Mediterranean rainfall since the Last Glacial. We show that distinct lake‐level fluctuations at Lake Trasimeno (Italy) are associated with changing aridity in the central Mediterranean during the last ~47 800 years. The lake‐level fluctuations are reconstructed based on carbonate mineral content and carbonate mineral species, as well as the stable oxygen and carbon isotope (δ18O and δ13C) geochemistry of endogenic carbonates. Low lake levels are linked to high carbonate, Mg‐calcite and aragonite contents, and high δ18O and δ13C values. Inferred hydrological changes are linked to glacial–interglacial and, tentatively within the limitations of our chronology, to millennial‐scale climate variability as well as the intensity of the Atlantic Meridional Overturning Circulation (AMOC). Prior to the Last Glacial Maximum (LGM), during intervals equivalent to Marine Isotope Stage 3 (MIS 3), a stronger AMOC associated with Greenland interstadial periods (Dansgaard/Oeschger (D/O) warm periods) and stronger Asian monsoon probably coincide with increased precipitation in central Italy as inferred from high lake levels at Lake Trasimeno. Periods of weak AMOC intensity such as during Greenland stadials (D/O cold periods), during Heinrich events, and weak Asian monsoons are correlated with lake level lowstands, which imply relatively dry conditions in central Italy. Lake Trasimeno’s water level during the LGM and the Lateglacial (MIS 2) is relatively stable, with recorded changes showing distinct similarities to orbital configurations. Although muted, high latitude climate forcing is still evident in the data during peak glacial conditions. The transition from D/O‐like hydrological variability at Lake Trasimeno during MIS 3 to orbitally controlled fluctuations during the Lateglacial to Holocene transition coincides with an increasing amplitude in local winter and summer insolation, probably indicating increasing seasonality and a larger temperature gradient between low‐ and high‐latitude settings.
    Description: Deutscher Akademischer Austauschdienst http://dx.doi.org/10.13039/501100001655
    Keywords: ddc:551.9
    Language: English
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  • 12
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    Detrital apatite geochemistry and thermochronology from the Oligocene/Miocene Alpine foreland record the early exhumation of the Tauern Window (2021)
    Details
    Publication Date: 2022-03-24
    Description: The early exhumation history of the Tauern Window in the European Eastern Alps and its surface expression is poorly dated and quantified, partly because thermochronological and provenance information are sparse from the Upper Austrian Northern Alpine Foreland Basin. For the first time, we combine a single‐grain double‐dating approach (Apatite Fission Track and U‐Pb dating) with trace‐element geochemistry analysis on the same apatites to reconstruct the provenance and exhumation history of the late Oligocene/early Miocene Eastern Alps. The results from 22 samples from the Chattian to Burdigalian sedimentary infill of the Upper Austrian Northern Alpine Foreland Basin were integrated with a 3D seismic‐reflection data set and published stratigraphic reports. Our highly discriminative data set indicates an increasing proportion of apatites (from 6% to 23%) with Sr/Y values 〈0.1 up‐section and an increasing amount of apatites (from 24% to 38%) containing 〉1,000 ppm light rare‐earth elements from Chattian to Burdigalian time. The number of U‐Pb ages with acceptable uncertainties increases from 40% to 59% up‐section, with mostly late Variscan/Permian ages, while an increasing number of grains (10%–27%) have Eocene or younger apatite fission track cooling ages. The changes in the apatite trace‐element geochemistry and U‐Pb data mirror increased sediment input from an ≥upper amphibolite‐facies metamorphic source of late Variscan/Permian age – probably the Ötztal‐Bundschuh nappe system – accompanied by increasing exhumation rates indicated by decreasing apatite fission track lag times. We attribute these changes to the surface response to upright folding and doming in the Penninic units of the future Tauern Window starting at 29–27 Ma. This early period of exhumation (0.3–0.6 mm/a) is triggered by early Adriatic indentation along the Giudicarie Fault System.
    Description: Science Foundation Ireland http://dx.doi.org/10.13039/501100001602
    Description: Deutsche Forschungsgemeinschaft http://dx.doi.org/10.13039/501100001659
    Keywords: ddc:551.701 ; ddc:551.9
    Language: English
    Type: doc-type:article
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    Evolution of Sea Surface Hydrology Along the Western Australian Margin Over the Past 450 kyr (2021)
    Details
    Publication Date: 2022-03-24
    Description: We collected a suite of core top samples during R/V Sonne Cruise SO257 in May 2017 along the southwestern front of the Indo‐Pacific Warm Pool (IPWP) to monitor the variability of Southern Hemisphere tropical and subtropical sea surface hydrology and to assess temperature and salinity reconstructions with data sets reflecting conditions in the post‐monsoonal season. In our core top samples, a steep increase in planktic δ18O, associated with a decrease in sea surface temperature (SST), indicates that the southwestern front of the IPWP is located between 23° and 24°S during austral fall. We additionally reconstructed SST, sea surface salinity ,and δ18O seawater (δ18Osw) over the last 450 kyr in two sediment successions located within and beyond the monsoonal rain belt. Our records show that SST was highly coherent and phase‐locked with atmospheric pCO2 during the last 450 kyr. The regional differences in the δ18Osw records reveal that the Western Australian Margin north of 15°S remained seasonally under the influence of IPWP water masses, even during glacials. The temporal variability in upper ocean hydrology along the Western Australian Margin is not directly coupled to local monsoonal precipitation, but is strongly affected by advective mixing of Indonesian Throughflow derived water masses.
    Description: Key Points: Southwest front of modern Indo‐Pacific Warm Pool (IPWP) during austral fall is located between 23° and 24°S. Western Australian Margin north of 15°S remained seasonally influenced by IPWP throughout past 450 kyr. Upper ocean hydrology off Western Australia represents an integrated signal of monsoonal precipitation and advective mixing.
    Description: China Scholarship Council
    Description: German Federal Ministry of Education and Research
    Keywords: ddc:551.46
    Language: English
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  • 14
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    Tephra Deposition and Bonding With Reactive Oxides Enhances Burial of Organic Carbon in the Bering Sea (2021)
    Details
    Publication Date: 2022-03-24
    Description: Preservation of organic carbon (OC) in marine sediments exerts a major control on the cycling of carbon in the Earth system. In these marine environments, OC preservation may be enhanced by diagenetic reactions in locations where deposition of fragmental volcanic material called tephra occurs. While the mechanisms by which this process occurs are well understood, site‐specific studies of this process are limited. Here, we report a study of sediments from the Bering Sea (IODP Site U1339D) to investigate the effects of marine tephra deposition on carbon cycling during the Pleistocene and Holocene. Our results suggest that tephra layers are loci of OC burial with distinct δ13C values, and that this process is primarily linked to bonding of OC with reactive metals, accounting for ∼80% of all OC within tephra layers. In addition, distribution of reactive metals from the tephra into non‐volcanic sediments above and below the tephra layers enhances OC preservation in these sediments, with ∼33% of OC bound to reactive phases. Importantly, OC‐Fe coupling is evident in sediments 〉700,000 years old. Thus, these interactions may help explain the observed preservation of OC in ancient marine sediments.
    Description: Plain Language Summary: The burial of organic carbon (OC) in marine sediments is one of the major carbon sinks on Earth, meaning that it removes carbon dioxide from the ocean‐atmosphere system. However, the speed at which burial occurs varies across the globe, and is dependent on a range of factors, from the amount of nutrients in the water column, to the type of sediment. Despite evidence suggesting that when tephra is deposited to the seafloor carbon burial is enhanced, very little work has been done to investigate this process. We have therefore analyzed sediments from the Bering Sea, where volcanoes from the Aleutian Islands and Kamchatka regularly deposit tephra in the ocean. We found that OC burial is indeed associated with ash deposition, and importantly, that OC is preserved in the ash layers themselves. We show here that this carbon is preserved effectively because of chemical reactions between the OC and reactive iron, which is released by the ash, creating conditions which preserve carbon for hundreds of thousands of years.
    Description: Key Points: Tephra layers are loci of marine organic carbon (OC) burial with distinct carbon isotopic compositions. Preservation primarily linked to association of OC with reactive iron phases, accounting for ∼80% of all OC in tephra layers. OC‐reactive Fe coupling is observed in sediments 〉700,000 years old, indicating long‐term persistence of these complexes.
    Description: NERC
    Keywords: ddc:551.9
    Language: English
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  • 15
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    Effects of CO2 and Ocean Mixing on Miocene and Pliocene Temperature Gradients (2022)
    Details
    Publication Date: 2022-03-28
    Description: Cenozoic climate changes have been linked to tectonic activity and variations in atmospheric CO2 concentrations. Here, we present Miocene and Pliocene sensitivity experiments performed with the climate model COSMOS. The experiments contain changes with respect to paleogeography, ocean gateway configuration, and atmospheric CO2 concentrations, as well as a range of vertical mixing coefficients in the ocean. For the mid‐Miocene, we show that the impact of ocean mixing on surface temperature is comparable to the effect of the possible range in reconstructed CO2 concentrations. In combination with stronger vertical mixing, relatively moderate CO2 concentrations of 450 ppmv enable global‐mean surface, deep‐water, and meridional temperature characteristics representative of mid‐Miocene Climatic Optimum (MMCO) reconstructions. The Miocene climate shows a reduced meridional temperature gradient and reduced seasonality. In the case of enhanced mixing, surface and deep ocean temperatures show significant warming of up to 5–10°C and an Arctic temperature anomaly of 〉12°C. In the Pliocene simulations, the impact of vertical mixing and CO2 is less important for the deep ocean, which we interpret as a different sensitivity dependence on the background state and mixed layer dynamics. We find a significant reduction in surface albedo and effective emissivity for either a high level of atmospheric CO2 or increased vertical mixing. Our mixing sensitivity experiments provide a warm deep ocean via ocean heat uptake. We propose that the mixing hypothesis can be tested by reconstructions of the thermocline and seasonal paleoclimate data indicating a lower seasonality relative to today.
    Description: Plain Language Summary: Cenozoic climate changes have been associated with tectonic changes and altered atmospheric CO2 concentrations. Here, we present Miocene and Pliocene computer simulations where we changed paleogeography, ocean gateways, and atmospheric CO2 concentrations as well as vertical mixing in the ocean. We show that the effect of ocean mixing on temperature is comparable to the respective effect of a possible range of CO2 concentrations. In combination with stronger vertical mixing, relatively moderate CO2 concentrations of 450 ppmv allow surface and deep‐water temperatures representative for reconstructions of the climate optimum of the mid‐Miocene. In the Pliocene simulations, the influence of vertical mixing and CO2 is less important than in the Miocene. We provide a possible mechanism of ocean heat absorption, albedo, and emissivity changes including a deeper oceanic mixing layer and a lower seasonality in the Miocene compared to today.
    Description: Key Points: Miocene experiment with standard mixing and atmospheric CO2 of 600 ppm captures large‐scale temperature characteristics of the mid‐Miocene. With enhanced ocean mixing the temperature characteristics and meridional temperature gradient can be reproduced with a CO2 level of 450 ppm. Miocene shows a strong warming at polar latitudes and reduced seasonality, vertical mixing, and CO2 are less important for the Pliocene.
    Description: Alfred Wegener Institute Helmholtz Centre for Polar and Marine Research (AWI) http://dx.doi.org/10.13039/501100003207
    Description: Helmholtz Association (亥姆霍兹联合会致力) http://dx.doi.org/10.13039/501100009318
    Description: Helmholtz Climate Initiative RE‐KLIM
    Keywords: ddc:550.78
    Language: English
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    Chemical Evolution of the Exceptional Arctic Stratospheric Winter 2019/2020 Compared to Previous Arctic and Antarctic Winters (2021)
    Details
    Publication Date: 2022-03-28
    Description: The winter 2019/2020 showed the lowest ozone mixing ratios ever observed in the Arctic winter stratosphere. It was the coldest Arctic stratospheric winter on record and was characterized by an unusually strong and long‐lasting polar vortex. We study the chemical evolution and ozone depletion in the winter 2019/2020 using the global Chemistry and Transport Model ATLAS. We examine whether the chemical processes in 2019/2020 are more characteristic of typical conditions in Antarctic winters or in average Arctic winters. Model runs for the winter 2019/2020 are compared to simulations of the Arctic winters 2004/2005, 2009/2010, and 2010/2011 and of the Antarctic winters 2006 and 2011, to assess differences in chemical evolution in winters with different meteorological conditions. In some respects, the winter 2019/2020 (and also the winter 2010/2011) was a hybrid between Arctic and Antarctic conditions, for example, with respect to the fraction of chlorine deactivation into HCl versus ClONO2, the amount of denitrification, and the importance of the heterogeneous HOCl + HCl reaction for chlorine activation. The pronounced ozone minimum of less than 0.2 ppm at about 450 K potential temperature that was observed in about 20% of the polar vortex area in 2019/2020 was caused by exceptionally long periods in the history of these air masses with low temperatures in sunlight. Based on a simple extrapolation of observed loss rates, only an additional 21–46 h spent below the upper temperature limit for polar stratospheric cloud formation and in sunlight would have been necessary to reduce ozone to near zero values (0.05 ppm) in these parts of the vortex.
    Description: Key Points: The Arctic stratospheric winter 2019/2020 showed the lowest ozone mixing ratios ever observed and was one of the coldest on record. Chemical evolution of the Arctic winter 2019/2020 was a hybrid between typical Arctic and typical Antarctic conditions. Only an additional 21–46 h below PSC temperatures and in sunlight would have been necessary to reduce ozone to near zero locally.
    Description: International Multidisciplinary Drifting Observatory for the Study of the Arctic Climate (MOSAiC)
    Keywords: ddc:551.5 ; ddc:551.9
    Language: English
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    Volume Transport Time Series and Variability of the North Atlantic Eastern Boundary Current at Goban Spur (2021)
    Details
    Publication Date: 2022-03-23
    Description: The Eastern Boundary Current is an essential part of the water mass exchange between the subtropical and subpolar North Atlantic. Here, we study the offshore branch of the European Shelf Current (ESC) over the Goban Spur slope area off Ireland. Our analysis is based on current measurements obtained from a multiyear mooring effort, complemented by ship‐board observations along a hydrographic section, satellite‐derived estimates of absolute dynamic topography with geostrophic currents, and float trajectories. These data serve to quantify the offshore branch of the ESC on intraannual to interannual timescales. From the moored observations, we derive a mean poleward along‐slope volume flux of 3.7 ± 0.7 Sv for the period 2017–2019. Using a multilinear regression model and geostrophic surface velocities, we extend the time series to the period 1993–2019 and obtain a long‐term mean transport of 3.2 ± 0.4 Sv. Both time series show strong variability ranging from −7.5 to 15.7 Sv. The variability is linked to a dynamic eddy field, especially a stationary cyclonic circulation pattern near the mooring array, and meandering of current branches originating from the North Atlantic Current. We find no evidence of a consistent deep boundary current extending from the shelf break to the position of the offshore mooring (4,500 m depth), but confirm a persistent along‐slope flow at the shallower slope (1,500 m depth). Geostrophic surface velocities and float trajectories reveal that the offshore branch of the ESC does not follow a clear northward path from the eastern subtropical regions but rather indicate the intermittent character of the flow.
    Description: Plain Language Summary: In this study, we describe the European Shelf Current (ESC) in the eastern North Atlantic. The study area is the deeper part of the Goban Spur area off Ireland. We use current measurements of instruments deployed in the water column from 2016 to 2019 combined with satellite observations of surface circulation and drifting float paths. We aim to quantify the contribution of the offshore branch to the ESC system. We calculate a poleward volume transport following the slope that is on average 3.7 ± 0.7 Sverdrup (Sv; 1 Sv = 1 million cubic meter per second) for the period 2017–2019. We use a mathematical relation between mooring data and satellite observations to extend the time series to the period 1993–2019 and obtain an average transport of 3.2 ± 0.4 Sv. There occur strong changes over time ranging from −5 to 15 Sv. These changes are caused by rotating vortices (eddies), especially a counter‐clockwise rotating circulation pattern near the moorings, and changing positions of currents branching from the North Atlantic Current. We find that the offshore branch of the ESC does not follow a clear northward path from the eastern subtropical regions of the North Atlantic. Instead, the flow is of rather unsteady character.
    Description: Key Points: The analysis of multiplatform observational efforts is used to study the circulation at the North Atlantic Eastern Boundary. The volume transport of the offshore branch of the European Shelf Current is on average 3.2 ± 0.4 Sv for the period 1993–2019. Transport variability is in the range of −7.5–15.7 Sv and induced by eddies and meandering North Atlantic Current branches.
    Description: Bundesministerium für Bildung und Forschung (BMBF) http://dx.doi.org/10.13039/501100002347
    Description: Deutsche Forschungsgemeinschaft (DFG) http://dx.doi.org/10.13039/501100001659
    Keywords: ddc:551.46
    Language: English
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    The Transpolar Drift Influence on the Arctic Ocean Silicon Cycle (2021)
    Details
    Publication Date: 2022-03-23
    Description: During most of the year, diatom production in the ice‐covered Central Arctic Ocean (CAO) is limited by light availability and nutrient supply. Therefore, biological production is thought to be generally low, with higher biological production at the sea ice edge and over partially ice‐free shelf areas. The major surface ocean current in the CAO is the Transpolar Drift (TPD), which transports sea ice and water from the rivers and shelves of the Laptev and the East Siberian Seas across the CAO toward the Fram Strait, carrying high amounts of terrestrial‐derived material over long distances. We used Si isotopes (δ30Si) to better understand the difference between lower and higher biological production areas and how the TPD potentially affects the Si cycle in the CAO. Our data show low dissolved Si concentrations ([DSi]) paired with high values of δ30Si‐DSi in all surface samples indicating fractionation by diatoms. Specifically, outside the TPD influence, all nutrients were depleted and supply was limited due to stratified conditions, thus preventing further phytoplankton growth in the area during the sampling time in late summer‐early fall. In contrast, under the TPD influence, diatom primary production was limited by low nitrate and strongly limited by light due to the presence of sea ice, even though [DSi] values were much higher than outside the TPD. Based on δ30Si, we could identify low but measurable DSi utilization in the TPD, potentially highlighting the importance of sea ice‐attached diatoms transported to the CAO via the TPD for the Si cycle in this region.
    Description: Plain Language Summary: The growth of siliceous microalgae (diatoms) in the ice‐covered Central Arctic Ocean (CAO) can be limited by light and nutrient availability. Due to the limiting conditions, diatom growth is considered to be generally low, with highest growth rates at the sea ice edge and over partially ice‐free coastal areas. The major surface water current in the CAO is the Transpolar Drift (TPD), carrying ice and water from rivers and coastal areas across the CAO to the major outflow area, the Fram Strait. We used silicon isotopes to better understand how the TPD potentially influences the silicon cycle in the CAO. Our data show that diatom growth was taking place in all areas studied here, despite different growth limiting factors outside and under the TPD influence. In the area outside the TPD influence, nutrient availability was very low and its supply was limited, which prevented further diatom growth. Under the TPD influence, even with additional nutrient supply from the TPD, only low diatom growth was observed, most likely limited by light availability.
    Description: Key Points: Primary production and silicon utilization outside the Transpolar Drift are higher than under its influence due to more light availability. Primary production and lateral water transport under the Transpolar Drift influence were identified from silicon isotope composition. The Transpolar Drift delivers high dissolved silicon to the surface Arctic Ocean, a unique feature not seen in any other open ocean.
    Description: MCTI, Conselho Nacional de Desenvolvimento Científico e Tecnológico (CNPq) http://dx.doi.org/10.13039/501100003593
    Description: Deutsche Forschungsgemeinschaft (DFG) http://dx.doi.org/10.13039/501100001659
    Keywords: ddc:551.46
    Language: English
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    Atmospheric Wind Biases: A Challenge for Simulating the Arctic Ocean in Coupled Models? (2021)
    Details
    Publication Date: 2022-03-23
    Description: Many state‐of‐the‐art climate models do not simulate the Atlantic Water (AW) layer in the Arctic Ocean realistically enough to address the question of future Arctic Atlantification and its associated feedback. Biases concerning the AW layer are commonly related to insufficient resolution and excessive mixing in the ocean component as well as unrealistic Atlantic‐Arctic Ocean exchange. Based on sensitivity experiments with FESOM1.4, the ocean–sea‐ice component of the global climate model AWI‐CM1, we show that even if all impediments for simulating AW realistically are addressed in the ocean model, new biases in the AW layer develop after coupling to an atmosphere model. By replacing the wind forcing over the Arctic with winds from a coupled simulation we show that a common bias in the atmospheric sea level pressure (SLP) gradient and its associated wind bias lead to differences in surface stress and Ekman transport. Fresh surface water gets redistributed leading to changes in halosteric height distribution. Those changes lead to strengthening of the anticyclonic surface circulation in the Canadian Basin, so that the deep counterflow carrying warm AW gets reversed and a warm bias in the Canadian Basin develops. The SLP and anticyclonic wind bias in the Nordic Seas weaken the cyclonic circulation leading to reduced AW transport into the Arctic Ocean through Fram Strait but increased AW transport through the Barents Sea Opening. These effects together lead to a cold bias in the Eurasian Basin. An underestimation of sea ice concentration can significantly amplify the induced ocean biases.
    Description: Plain Language Summary: Coupled global climate models are used to predict anthropogenic climate change along with its impacts. The Arctic has experienced amplified warming in the recent decades compared to global mean warming and therefore is one region of intense climate research. In this context Atlantification of the Arctic Ocean has become a high priority topic. Atlantification describes the increasing impact of oceanic heat from the Atlantic Water (AW) layer of the Arctic Ocean on the sea ice cover. In climate models, the direction and strength of simulated AW circulation around the Arctic Ocean is known to be sensitive to ocean grid resolution, parametrization, boundary and surface forcing or a combination thereof. Here we show that biases in the atmospheric component of climate models can interrupt and even reverse the simulated AW circulation at depth. Such biases can be further amplified by a negative bias in simulated sea ice cover. This study shows how these surface biases can negatively impact the deep ocean circulation.
    Description: Key Points: Many state‐of‐the‐art climate models fail to simulate the properties of the Atlantic Water layer in the Arctic Ocean realistically. Biases in Arctic sea level pressure and surface winds in atmosphere models can reverse Atlantic Water circulation. The underestimation of sea‐ice cover amplifies this problem further.
    Description: European Union's Horizon 2020 Research and Innovation program
    Description: Helmholtz Association http://dx.doi.org/10.13039/501100009318
    Keywords: ddc:551.46
    Language: English
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    Triple‐Element Stable Isotope Analysis of Chloromethane Emitted by Royal Fern and Degraded by Club Moss (2023)
    Details
    Publication Date: 2023-09-12
    Description: 〈title xmlns:mml="http://www.w3.org/1998/Math/MathML"〉Abstract〈/title〉〈p xmlns:mml="http://www.w3.org/1998/Math/MathML" xml:lang="en"〉Chloromethane (CH〈sub〉3〈/sub〉Cl) is the most abundant natural chlorinated organic compound in the atmosphere playing an important role in catalyzing stratospheric ozone loss. Vegetation emits the largest amounts of CH〈sub〉3〈/sub〉Cl to the atmosphere but its source strength is highly uncertain leading also to large uncertainties in the global budget of CH〈sub〉3〈/sub〉Cl. Triple‐element stable isotope analysis may help to reduce uncertainties because it provides additional process‐level information compared to conventional quantification methods. In this study we performed experiments to obtain a first triple‐elemental isotopic fingerprint (〈sup〉2〈/sup〉H, 〈sup〉13〈/sup〉C, 〈sup〉37〈/sup〉Cl) of CH〈sub〉3〈/sub〉Cl emitted by a relevant plant species (royal fern, 〈italic〉Osmunda regalis〈/italic〉). Isotopic values of all three elements showed considerable differences compared to isotopic values of industrially manufactured CH〈sub〉3〈/sub〉Cl which bodes well for future applications to distinguish individual sources. Isotopic analysis of potential precursors (rain, methoxy groups) of CH〈sub〉3〈/sub〉Cl in plants revealed no measurable change of hydrogen and chlorine isotopic ratios during formation which may provide a simpler route to estimate the isotopic composition of CH〈sub〉3〈/sub〉Cl emissions. Plant degradation experiments of CH〈sub〉3〈/sub〉Cl were carried out with club moss (〈italic〉Selaginella kraussiana〈/italic〉) revealing significant isotopic fractionation for all three elements. The fractionation pattern characterized by epsilon and lambda is inconsistent with known biotic dechlorination reactions indicating a yet unreported biotic degradation mechanism for CH〈sub〉3〈/sub〉Cl. Overall, this study provides first insights into the triple‐elemental isotopic fingerprint of plant emissions and degradation. The results may represent important input data for future isotope‐based models to improve global budget estimates of CH〈sub〉3〈/sub〉Cl and to explore the yet unknown degradation pathways.〈/p〉
    Description: Plain Language Summary: Chloromethane is the most abundant chlorinated organic compound in the atmosphere. It contributes to the destruction of the ozone layer that protects us from skin cancer and genetic damage. Currently, we do not have a good understanding of the sources and removal processes of chloromethane in the atmosphere. In this paper, we use a technique that takes advantage of the different varieties of a chemical element. These so‐called isotopes behave differently during chemical reactions that lead to individual isotopic fingerprints depending on the source or removal process. We used isotopic fingerprints of all three chemical elements in chloromethane and showed that chloromethane produced by a plant (royal fern) differs substantially from chloromethane manufactured by industry. Other plant species such as club moss are able to remove chloromethane from the atmosphere but it is often not clear how this occurs. Isotopic analysis revealed that the studied club moss uses a unique, thus far unknown, way to break down chloromethane. This study demonstrates how information extracted from isotopic fingerprints will help to improve our understanding of sources and removal processes of chloromethane in the atmosphere. It can help to better predict how ozone destruction in the stratosphere affects us in the future.〈/p〉
    Description: Key Points: First triple‐element isotopic characterization of plant CH〈sub〉3〈/sub〉Cl emission and degradation. Plant degradation experiments suggest another yet unknown transformation pathway. Important input data for future isotope based models to improve understanding of global CH〈sub〉3〈/sub〉Cl budget.
    Description: Helmholtz Association http://dx.doi.org/10.13039/501100009318
    Description: Deutsche Forschungsgemeinschaft http://dx.doi.org/10.13039/501100001659
    Description: https://doi.org/10.48758/ufz.13388
    Keywords: ddc:551.9 ; CH3Cl ; ozone depletion ; isotopes ; plant emissions ; halogens
    Language: English
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    The composition of CI chondrites and their contents of chlorine and bromine: Results from instrumental neutron activation analysis (2021)
    Details
    Publication Date: 2023-09-13
    Description: 〈title xmlns:mml="http://www.w3.org/1998/Math/MathML"〉Abstract〈/title〉〈p xmlns:mml="http://www.w3.org/1998/Math/MathML" xml:lang="en"〉Between 1973 and 1994, 15 samples of CI chondrites were analyzed by neutron activation analysis at the Max‐Planck‐Institute for Chemistry, Department of Cosmochemistry in Mainz, Germany. The analyses comprise nine Orgueil samples and three samples of Ivuna, two of Alais and one of Tonk. Samples came from various sources and had masses between 5 and 600 mg. Most data are published here for the first time. The results for the nine Orgueil samples demonstrate the essentially homogeneous chemical composition of Orgueil at a level of a few milligrams. The analytical results of Ivuna, Alais, and Tonk agree, with only few exceptions, with the results of Orgueil analyses. All samples agree within ±3% in their contents of Sc, Ir, Cr, Fe, Co, Zn, and Se. The elements Sc and Ir represent the refractory component; Cr, Fe, and Co the main component; and Zn and Se the volatile component. Thus, in all CI chondrites there are essentially the same fractions of the fundamental cosmochemical components. The essentially identical chemical composition of all samples shows that their water contents are constant at about 20 ± 5 wt%. There is excellent agreement between the data listed here with data reported in the relevant literature. There is no doubt that the CI composition is a well‐defined entity, which is thought to represent the non‐gaseous compositions of the solar nebula and the photosphere of the Sun. In addition, we conclude that the recently proposed new CI chondritic chlorine and Br values are too low, when compared to earlier measurements.〈/p〉
    Keywords: ddc:551.9 ; CI chondrites ; composition ; chlorine ; bromine ; neutron activation analysis
    Language: English
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    Temporal Variability of Fluvial Sand Composition: An Annual Time Series From Four Rivers in SW Germany (2023)
    Details
    Publication Date: 2023-09-13
    Description: 〈title xmlns:mml="http://www.w3.org/1998/Math/MathML"〉Abstract〈/title〉〈p xmlns:mml="http://www.w3.org/1998/Math/MathML" xml:lang="en"〉The sampling of fluvial sediment is subject to many sources of uncertainty, for example, time and location, and the number of samples collected. It is nevertheless commonly assumed that a sample taken at one time and location provides a somewhat averaged compositional signal. Any spatial or temporal variability of this signal is often neglected. This study investigates how the composition of bed load sand changes over an observation period of 1 year in four river basins with differing bedrock geology in southwestern Germany. Up to 12 bulk sediment samples were taken at the same locations using the same approach and analyzed for their granulometry and geochemistry. The results indicate that (a) different grain sizes yield different compositions due to source rock composition and hydraulic sorting effects, (b) bulk sediment composition changes temporally due to changing grain‐size distribution, and (c) compared to the bulk sample, the composition of narrow grain sizes is temporally more stable but nevertheless has an average variability of 15%. Because heavy mineral‐bound elements such as Zr have the highest variability, we relate a major component of compositional variability to temporally varying heavy mineral concentrations in response to hydrodynamic processes. Mixing modeling demonstrates that the fluvial sand faithfully reflects its catchment geology and that the sediment sources do not change substantially during the observation period, even during a flooding event. We conclude (a) that the causes for compositional variability may be disentangled using chemical and granulometric time series data and (b) that narrow grain sizes yield representative source rock contributions.〈/p〉
    Description: Plain Language Summary: Sediment transported by rivers is generated by the erosion of the rocks present within the river catchment area. The composition of this sediment is controlled by various processes in the catchment, for example, climate, rock type, weathering, and flow strength. Geoscientists can use modern river sediment to understand how these processes impact sediment composition, and then apply this information to the geologic time. Sampling the river sediment is often the first step in such studies, but few studies consider the sources of uncertainty during sampling, for example, time and location of sampling, and number of collected samples. For this study, we returned to the same river location during the course of 1 year to take bulk sediment samples and analyzed how variable the size of sediment grains and the sediment chemistry are. We discovered that different grain sizes yield different chemical compositions, and this is caused by differences in rock type and hydraulic processes. Because the proportion of different grain sizes in the bulk sediment changes over the year due to water flow conditions, the chemistry of the bulk sediment sample changes over the year. We provide some quantitative estimates for this variability that should be considered in similar studies.〈/p〉
    Description: Key Points: Bed load sand from 4 rivers was sampled monthly over the course of 1 year to analyze the temporal compositional variability. Composition is grain‐size‐dependent, and narrow grain‐size fractions show less variability than bulk sediment samples. Composition changes during the year, and this is related to changing grain‐size distributions rather than changing sediment sources.
    Description: https://doi.pangaea.de/10.1594/PANGAEA.959006
    Keywords: ddc:551.9 ; geochemistry ; provenance ; grain‐size ; variability ; bed load ; fluvial sediment
    Language: English
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    Plane strain shear strength of unsaturated fiber-reinforced fine-grained soils (2021)
    Springer Berlin Heidelberg
    Details
    Publication Date: 2023-09-14
    Description: Discrete randomly distributed fibers are commonly used to improve the engineering characteristics of the soil and thus soil properties such as shear strength, compressibility, density, and hydraulic conductivity. Most studies have so far focused on describing the behavior of soils containing randomly distributed fibers under dried or saturated conditions. However, the water table may seasonally fluctuate, thus generating unsaturated soil conditions. Therefore, a better understanding of the hydro-mechanical properties of unsaturated improved soils is of high necessity. In this research, the shear strength parameters of fine-grained soils were evaluated using the biaxial device available at Ruhr Universität Bochum. The applied device was modified to test unsaturated fine-grained soils with various degrees of saturation using axis translation and vapor equilibrium techniques. The experiments were conducted on fine soils containing 0, 0.5, and 1% fiber contents under a wide range of matric suctions. The ductile behavior was more noticeable in samples with lower suctions and higher straw contents. Furthermore, the shear strength of both unreinforced and reinforced fine-grained soils considerably increased by an increase in the suction. Finally, shear band inclination increased by the suction while decreasing by straw content.
    Description: Ruhr-Universität Bochum (1007)
    Keywords: ddc:550.78 ; Plane strain condition ; Shear strength ; Soil reinforcement ; Suction ; SWCC
    Language: English
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    Hydrochemistry and environmental isotopes (18O, 2H, 3H, 3He/4He) of groundwater and floodwater in the great area of Hurghada, Eastern Desert of Egypt (2021)
    Springer Berlin Heidelberg
    Details
    Publication Date: 2023-09-14
    Description: Porous and fractured aquifers exist in the area of Hurghada, Eastern Desert of Egypt, whose recharge processes through the common flash floods are not identified. Hydrochemical parameters, stable isotopes 〈sup〉18〈/sup〉O, 〈sup〉2〈/sup〉H and tritium in floodwater and groundwater were applied in the area subject to study. Additionally, He isotopes were investigated in the deep wells in the faulted zone at the Abu Shaar Plateau. 〈sup〉3〈/sup〉H activity in all sampled points lies below the detection limit excluding a recent recharge component in groundwater. However, the hydrochemical ratios and the stable isotope signature confirm that the shallow wells and springs (Red Sea Hills group) are being recharged from modern precipitation. The hydrochemical parameters of the deep wells at the Abu Shaar Plateau (coastal plain group) confirm another origin for the ions rather than the modern precipitation. Together with the 〈sup〉18〈/sup〉O and 〈sup〉2〈/sup〉H values, the Br/Cl ratio of this group confirms the absence of seawater intrusion component and the role of the fault as a hydraulic barrier. These 〈sup〉18〈/sup〉O and 〈sup〉2〈/sup〉H values deviate from the GMWL confirming an evaporation effect and colder infiltration conditions and reveal strongly a possible mixing with the Nubian Sandstone in the region. The 〈sup〉3〈/sup〉He/〈sup〉4〈/sup〉He ratio confirms a mantle contribution of 2% from the total He components.
    Description: Open Access funding enabled and organized by Projekt DEAL
    Keywords: ddc:551.9 ; Groundwater ; Floodwater ; Hydrochemistry ; Water isotopes ; Helium isotopes ; Eastern desert of Egypt
    Language: English
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    Bioavailable DOC: reactive nutrient ratios control heterotrophic nutrient assimilation—An experimental proof of the macronutrient-access hypothesis (2021)
    Graeber, Daniel ; Tenzin, Youngdoung ; Stutter, Marc ; [et al.]
    Springer International Publishing
    Details
    Publication Date: 2023-11-28
    Description: We investigate the "macronutrient-access hypothesis", which states that the balance between stoichiometric macronutrient demand and accessible macronutrients controls nutrient assimilation by aquatic heterotrophs. Within this hypothesis, we consider bioavailable dissolved organic carbon (bDOC), reactive nitrogen (N) and reactive phosphorus (P) to be the macronutrients accessible to heterotrophic assimilation. Here, reactive N and P are the sums of dissolved inorganic N (nitrate-N, nitrite-N, ammonium-N), soluble-reactive P (SRP), and bioavailable dissolved organic N (bDON) and P (bDOP). Previous data from various freshwaters suggests this hypothesis, yet clear experimental support is missing. We assessed this hypothesis in a proof-of-concept experiment for waters from four small agricultural streams. We used seven different bDOC:reactive N and bDOC:reactive P ratios, induced by seven levels of alder leaf leachate addition. With these treatments and a stream-water specific bacterial inoculum, we conducted a 3-day experiment with three independent replicates per combination of stream water, treatment, and sampling occasion. Here, we extracted dissolved organic matter (DOM) fluorophores by measuring excitation-emission matrices with subsequent parallel factor decomposition (EEM-PARAFAC). We assessed the true bioavailability of DOC, DON, and the DOM fluorophores as the concentration difference between the beginning and end of each experiment. Subsequently, we calculated the bDOC and bDON concentrations based on the bioavailable EEM-PARAFAC fluorophores, and compared the calculated bDOC and bDON concentrations to their true bioavailability. Due to very low DOP concentrations, the DOP determination uncertainty was high, and we assumed DOP to be a negligible part of the reactive P. For bDOC and bDON, the true bioavailability measurements agreed with the same fractions calculated indirectly from bioavailable EEM-PARAFAC fluorophores (bDOC r〈sup〉2〈/sup〉 = 0.96, p 〈 0.001; bDON r〈sup〉2〈/sup〉 = 0.77, p 〈 0.001). Hence we could predict bDOC and bDON concentrations based on the EEM-PARAFAC fluorophores. The ratios of bDOC:reactive N (sum of bDON and DIN) and bDOC:reactive P (equal to SRP) exerted a strong, predictable stoichiometric control on reactive N and P uptake (R〈sup〉2〈/sup〉 = 0.80 and 0.83). To define zones of C:N:P (co-)limitation of heterotrophic assimilation, we used a novel ternary-plot approach combining our data with literature data on C:N:P ranges of bacterial biomass. Here, we found a zone of maximum reactive N uptake (C:N:P approx. 〉 114: 〈 9:1), reactive P uptake (C:N:P approx. 〉 170:21: 〈 1) and reactive N and P co-limitation of nutrient uptake (C:N:P approx. 〉 204:14:1). The “macronutrient-access hypothesis” links ecological stoichiometry and biogeochemistry, and may be of importance for nutrient uptake in many freshwater ecosystems. However, this experiment is only a starting point and this hypothesis needs to be corroborated by further experiments for more sites, by in-situ studies, and with different DOC sources.
    Description: Rural and Environment Science and Analytical Services Division http://dx.doi.org/10.13039/100011310
    Description: Helmholtz-Gemeinschaft http://dx.doi.org/10.13039/501100001656
    Description: Helmholtz-Zentrum für Umweltforschung GmbH - UFZ (4215)
    Keywords: ddc:551.9 ; Ecological stoichiometry ; Dissolved organic nitrogen ; PARAFAC ; Dissolved inorganic nitrogen ; Phosphate ; Ternary plots
    Language: English
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    Systematic Across‐Arc Variations of Molybdenum Isotopes in a Fluid‐Dominated Subduction Zone System (2023)
    Details
    Publication Date: 2023-11-27
    Description: 〈title xmlns:mml="http://www.w3.org/1998/Math/MathML"〉Abstract〈/title〉〈p xmlns:mml="http://www.w3.org/1998/Math/MathML" xml:lang="en"〉Mass‐dependent Mo isotope variations are a promising new tracer to study magmatic processes in different geological settings. We report the first Mo isotope data for the Kamchatka arc system in the Northwest Pacific, comprising basaltic lavas of a complete Southeast‐Northwest traverse from the volcanic arc front through to the back arc region. The majority of volcanic centers investigated directly override the Hawaii‐Emperor Seamount Chain, which is currently being subducted underneath the arc system. Our Mo isotope data show systematic trends with Ce/Pb, Ce/Mo, Nb/Zr, La/Sm, and 〈sup〉143〈/sup〉Nd/〈sup〉144〈/sup〉Nd ratios from the volcanic arc front to the back arc. Arc front lavas have higher δ〈sup〉98/95〈/sup〉Mo and lower Ce/Pb, Ce/Mo, Nb/Zr, La/Sm compared to back arc lavas. Because the involvement of subducted sediments can be excluded, we attribute the observed variations to a change in the mantle source composition from the arc front to the back arc regions. The isotopic and chemical budget of arc front lavas is dominated by a slab fluid component (high δ〈sup〉98/95〈/sup〉Mo, low Ce/Pb, Ce/Mo), whereas mantle‐like Ce/Pb, Ce/Mo, elevated Nb/Zr and La/Sm in the back arc samples suggest an enriched mantle source. Combined δ〈sup〉98/95〈/sup〉Mo, Nd, and Pb isotope data in back arc lavas are very similar to those observed for modern ocean island basalts from Hawaii. We thus explore the possibility that the back arc mantle was contaminated by a Hawaii‐type, enriched asthenospheric mantle component from the subducted Hawaii‐Emperor Seamount Chain.〈/p〉
    Description: Plain Language Summary: In subduction zones, tectonic plates—tens of kilometers thick and making up the outer shell of our planet—are on a collision course. Although the absolute convergence rates of these plates are minute (a few cm/year), the forces in this process are so large that one plate is pushed under the other, causing the lower plate to be recycled into the Earth's mantle over time scales of millions of years. The tangible consequences are high‐magnitude earthquakes and large‐volume volcanic eruptions along these convergent plate margins. It is thus important to better understand the geological processes that operate in subduction zones. Here, we have studied the chemical and isotopic composition of volcanic rocks from the Kamchatka subduction zone. Our results confirm that water, locked into the subducting plate while residing on the surface, is released into the hot, overlying mantle after subduction, causing the formation of large volumes of magma that eventually erupt in volcanoes on the Kamchatka Peninsula. Our data also indicate that the subducting plate, once pushed into the mantle, is being ripped apart, allowing buoyant mantle material from greater depth to rise and contribute to the large‐scale volcanism observed along this convergent plate margin.〈/p〉
    Description: Key Points: 〈list list-type="bullet"〉 〈list-item〉 〈p xml:lang="en"〉Molybdenum isotope systematics in arc basalts from Kamchatka are consistent with presence of a slab‐derived fluid in their mantle source〈/p〉〈/list-item〉 〈list-item〉 〈p xml:lang="en"〉Back arc basalts also show contribution from a geochemically enriched source〈/p〉〈/list-item〉 〈list-item〉 〈p xml:lang="en"〉Combined Mo, Nd, and Pb isotope and trace element data for back arc basalts suggest involvement of Hawaii‐type asthenospheric mantle〈/p〉〈/list-item〉 〈/list〉 〈/p〉
    Description: Deutsche Forschungsgemeinschaft http://dx.doi.org/10.13039/501100001659
    Description: https://doi.org/10.25625/P5BBFL
    Keywords: ddc:551.9 ; molybdenum isotopes ; slab fluid ; enriched mantle ; subduction ; Kamchatka ; Hawaii
    Language: English
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    Hydromechanical Investigations on the Self-propping Potential of Fractures in Tight Sandstones (2021)
    Springer Vienna
    Details
    Publication Date: 2023-11-15
    Description: The hydromechanical properties of single self-propping fractures under stress are of fundamental interest for fractured-rock hydrology and a large number of geotechnical applications. This experimental study investigates fracture closure and hydraulic aperture changes of displaced tensile fractures, aligned tensile fractures, and saw-cut fractures for two types of sandstone (i.e., Flechtinger and Fontainebleau) with contrasting mechanical properties, cycling confining pressure between 5 and 30 MPa. Emphasis is placed on how surface roughness, fracture wall offset, and the mechanical properties of the contact asperities affect the self-propping potential of these fractures under normal stress. A relative fracture wall displacement can significantly increase fracture aperture and hydraulic conductivity, but the degree of increase strongly depends on the fracture surface roughness. For smooth fractures, surface roughness remains scale-independent as long as the fracture area is larger than a roll-off wavelength and thus any further displacement does not affect fracture aperture. For rough tensile fractures, these are self-affine over a larger scale so that an incremental fracture wall offset likely leads to an increase in fracture aperture. X-ray microtomography of the fractures indicates that the contact area ratio of the tensile fractures after the confining pressure cycle inversely correlates with the fracture wall offset yielding values in the range of about 3–25%, depending, first, on the respective surface roughness and, second, on the strength of the asperities in contact. Moreover, the contact asperities mainly occur isolated and tend to be preferentially oriented in the direction perpendicular to the fracture wall displacement which, in turn, may induce flow anisotropy. This, overall, implies that relatively harder sedimentary rocks have a higher self-propping potential for sustainable fluid flow through fractures in comparison to relatively soft rocks when specific conditions regarding surface roughness and fracture wall offset are met.
    Description: Bundesministerium für Wirtschaft und Energie (DE)
    Description: China Scholarship Council http://dx.doi.org/10.13039/501100004543
    Description: Helmholtz-Zentrum Potsdam Deutsches GeoForschungsZentrum - GFZ (4217)
    Keywords: ddc:550.78 ; Self-propping fracture ; Mechanical aperture ; Hydraulic aperture ; Normal stress ; Fracture wall offset ; Surface roughness
    Language: English
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    Permeability Evolution During Shear Zone Initiation in Low-Porosity Rocks (2021)
    Springer Vienna
    Details
    Publication Date: 2023-11-15
    Description: Using an innovative experimental set-up (Punch-Through Shear test), we initiated a shear zone (microfault) in Flechtingen sandstone and Odenwald granite under in situ reservoir conditions while monitoring permeability and fracture dilation evolution. The shear zone, which has a cylindrical geometry, is produced by a self-designed piston assembly that punches down the inner part of the sample. Permeability and fracture dilation were measured for the entire duration of the experiment. After the shear zone generation, the imposed shear displacement was increased to 1.2 mm and pore pressure changes of ±5 or ±10 MPa were applied cyclically to simulate injection and production scenarios. Thin sections and image analysis tools were used to identify microstructural features of the shear zone. The geometry of the shear zone is shown to follow a self-affine scaling invariance, similar to the fracture surface roughness. The permeability evolution related to the onset of the fracture zone is different for both rocks: almost no enhancement for the Flechtingen sandstone and an increase of more than 2 orders of magnitude for the Odenwald granite. Further shear displacement resulted in a slight increase in permeability. A fault compaction is observed after shear relaxation which is associated to a permeability decrease by a factor more than 3. Permeability changes during pressure cycling are reversible when varying the effective pressure. The difference in permeability enhancement between the sandstone and the granite is related to the larger width of the shear zones.
    Description: ReSalt Project
    Description: H2020 European Research Council http://dx.doi.org/10.13039/100010663
    Description: Projekt DEAL
    Keywords: ddc:550.78 ; Microfault ; Fracture permeability ; Microstructure ; Fault architecture ; Roughness ; Sandstone ; Granite
    Language: English
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  • 29
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    Verification of Coupled Hydraulic Fracturing Simulators Using Laboratory-Scale Experiments (2021)
    Springer Vienna
    Details
    Publication Date: 2023-11-15
    Description: In this work, we aim to verify the predictions of the numerical simulators, which are used for designing field-scale hydraulic stimulation experiments. Although a strong theoretical understanding of this process has been gained over the past few decades, numerical predictions of fracture propagation in low-permeability rocks still remains a challenge. Against this background, we performed controlled laboratory-scale hydraulic fracturing experiments in granite samples, which not only provides high-quality experimental data but also a well-characterized experimental set-up. Using the experimental pressure responses and the final fracture sizes as benchmark, we compared the numerical predictions of two coupled hydraulic fracturing simulators—CSMP and GEOS. Both the simulators reproduced the experimental pressure behavior by implementing the physics of Linear Elastic Fracture Mechanics (LEFM) and lubrication theory within a reasonable degree of accuracy. The simulation results indicate that even in the very low-porosity (1–2 %) and low-permeability (10〈sup〉−18〈/sup〉 m〈sup〉2〈/sup〉 − 10〈sup〉−19〈/sup〉 m〈sup〉2〈/sup〉) crystalline rocks, which are usually the target of EGS, fluid-loss into the matrix and unsaturated flow impacts the formation breakdown pressure and the post-breakdown pressure trends. Therefore, underestimation of such parameters in numerical modeling can lead to significant underestimation of breakdown pressure. The simulation results also indicate the importance of implementing wellbore solvers for considering the effect of system compressibility and pressure drop due to friction in the injection line. The varying injection rate as a result of decompression at the instant of fracture initiation affects the fracture size, while the entry friction at the connection between the well and the initial notch may cause an increase in the measured breakdown pressure.
    Description: European Union's Horizon 2020 Research and Innovation programme
    Description: Commonwealth Scientific and Industrial Research Organisation http://dx.doi.org/10.13039/501100000943
    Description: RWTH Aachen (3131)
    Description: http://doi.org/10.5281/zenodo.3710746
    Keywords: ddc:550.78 ; Laboratory-experiments ; Hydraulic fracturing ; Simulation ; Leak-off ; Fracture toughness ; System compressibility ; Fracture radius ; Acoustic emission
    Language: English
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  • 30
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    Authors’ Reply to the Discussion by Crisci et al. (2021) on “Experimental Deformation of Opalinus Clay at Elevated Temperature and Pressure Conditions Mechanical Properties and the Influence of Rock Fabric” (2021)
    Springer Vienna
    Details
    Publication Date: 2023-11-15
    Description: This is a repond to the comments raised in Crisci´s et al. paper “Discussion on “Experimental Deformation of Opalinus Clay at Elevated Temperature and Pressure Conditions ¬ Mechanical Properties and the Influence of Rock Fabric” (2021). We are pleased to use the opportunity to clarify issues related to testing procedures and interpretation in more detail.
    Description: Bundesministerium für Bildung und Forschung http://dx.doi.org/10.13039/501100002347
    Description: Helmholtz-Gemeinschaft http://dx.doi.org/10.13039/501100001656
    Description: Helmholtz-Zentrum Potsdam Deutsches GeoForschungsZentrum - GFZ (4217)
    Keywords: ddc:550.78 ; Opalinus Clay ; Testing procedure ; Pore pressure generation ; Strain rate ; Drying-induced micro cracks
    Language: English
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    Immiscible silicate liquids: K and Fe distribution as a test for chemical equilibrium and insight into the kinetics of magma unmixing (2021)
    Springer Berlin Heidelberg
    Details
    Publication Date: 2023-11-15
    Description: Silicate liquid immiscibility leading to formation of mixtures of distinct iron-rich and silica-rich liquids is common in basaltic and andesitic magmas at advanced stages of magma evolution. Experimental modeling of the immiscibility has been hampered by kinetic problems and attainment of chemical equilibrium between immiscible liquids in some experimental studies has been questioned. On the basis of symmetric regular solutions model and regression analysis of experimental data on compositions of immiscible liquid pairs, we show that liquid–liquid distribution of network-modifying elements K and Fe is linked to the distribution of network-forming oxides SiO2, Al2O3 and P2O5. We use the responding equation for testing chemical equilibrium in experiments not included in the regression analysis and compositions of natural immiscible melts found as glasses in volcanic rocks. Departures from equilibrium that the test revealed in crystal-rich multiphase experimental products and in natural volcanic rocks imply kinetic competition between liquid–liquid and crystal–liquid element partitioning. Immiscible liquid droplets in volcanic rocks appear to evolve along a metastable trend due to rapid crystallization. Immiscible liquids may be closer to chemical equilibrium in large intrusions where cooling rates are lower and crystals may be spatially separated from liquids.
    Description: DeutscheForschungsGemeinschaft http://dx.doi.org/10.13039/501100001659
    Description: Russian Science Foundation http://dx.doi.org/10.13039/501100006769
    Description: Helmholtz-Zentrum Potsdam Deutsches GeoForschungsZentrum - GFZ (4217)
    Keywords: ddc:550.78 ; Experimental petrology ; Igneous rocks ; Silicate melts ; Liquid–liquid element distribution ; Symmetric regular solutions
    Language: English
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  • 32
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    Experimental Deformation of Opalinus Clay at Elevated Temperature and Pressure Conditions: Mechanical Properties and the Influence of Rock Fabric (2021)
    Springer Vienna
    Details
    Publication Date: 2023-11-15
    Description: The mechanical behavior of the sandy facies of Opalinus Clay (OPA) was investigated in 42 triaxial tests performed on dry samples at unconsolidated, undrained conditions at confining pressures (pc) of 50–100 MPa, temperatures (T) between 25 and 200 °C and strain rates (ε˙) of 1 × 10〈sup〉–3〈/sup〉–5 × 10〈sup〉–6〈/sup〉 s〈sup〉−1〈/sup〉. Using a Paterson-type deformation apparatus, samples oriented at 0°, 45° and 90° to bedding were deformed up to about 15% axial strain. Additionally, the influence of water content, drainage condition and pre-consolidation was investigated at fixed p〈sub〉c〈/sub〉–T conditions, using dry and re-saturated samples. Deformed samples display brittle to semi-brittle deformation behavior, characterized by cataclastic flow in quartz-rich sandy layers and granular flow in phyllosilicate-rich layers. Samples loaded parallel to bedding are less compliant compared to the other loading directions. With the exception of samples deformed 45° and 90° to bedding at p〈sub〉c〈/sub〉 = 100 MPa, strain is localized in discrete shear zones. Compressive strength (σ〈sub〉max〈/sub〉) increases with increasing p〈sub〉c〈/sub〉, resulting in an internal friction coefficient of ≈ 0.31 for samples deformed at 45° and 90° to bedding, and ≈ 0.44 for samples deformed parallel to bedding. In contrast, pre-consolidation, drainage condition, T and ε˙ do not significantly affect deformation behavior of dried samples. However, σ〈sub〉max〈/sub〉 and Young’s modulus (E) decrease substantially with increasing water saturation. Compared to the clay-rich shaly facies of OPA, sandy facies specimens display higher strength σmax and Young’s modulus E at similar deformation conditions. Strength and Young’s modulus of samples deformed 90° and 45° to bedding are close to the iso-stress Reuss bound, suggesting a strong influence of weak clay-rich layers on the deformation behavior.
    Description: Bundesministerium für Bildung und Forschung http://dx.doi.org/10.13039/501100002347
    Description: Helmholtz-Gemeinschaft http://dx.doi.org/10.13039/501100001656
    Description: Helmholtz-Zentrum Potsdam Deutsches GeoForschungsZentrum - GFZ (4217)
    Keywords: ddc:550.78 ; Clay rock ; Sandy facies of Opalinus Clay ; Triaxial deformation experiments ; Microstructural deformation mechanisms ; Pressure-, temperature- and strain rate-dependent mechanical behaviour ; Anisotropy
    Language: English
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    Experimental study and numerical modeling of the thermo-hydro-mechanical processes in soil freezing with different frost penetration directions (2021)
    Springer Berlin Heidelberg
    Details
    Publication Date: 2023-11-16
    Description: This research work presents an experimental and numerical study of the coupled thermo-hydro-mechanical (THM) processes that occur during soil freezing. With focusing on the artificial ground freezing (AGF) technology, a new testing device is built, which considers a variety of AGF-related boundary conditions and different freezing directions. In the conducted experiments, a distinction is made between two thermal states: (1) The thermal transient state, which is associated with ice penetration, small deformations, and insignificant water suction. (2) The thermal (quasi-) steady state, which has a much longer duration and is associated with significant ice lens formation due to water suction. In the numerical modeling, a special focus is laid on the processes that occur during the thermal transient state. Besides, a demonstration of the micro-cryo-suction mechanism and its realization in the continuum model through a phenomenological retention-curve-like formulation is presented. This allows modeling the ice lens formation and the stiffness degradation observed in the experiments. Assuming a fully saturated soil as a biphasic porous material, a phase-change THM approach is applied in the numerical modeling. The governing equations are based on the continuum mechanical theory of porous media (TPM) extended by the phase-field modeling (PFM) approach. The model proceeds from a small-strain assumption, whereas the pore fluid can be found in liquid water or solid ice state with a unified kinematics treatment of both states. Comparisons with the experimental data demonstrate the ability and usefulness of the considered model in describing the freezing of saturated soils.
    Description: Deutsche Forschungsgemeinschaft http://dx.doi.org/10.13039/501100001659
    Description: RWTH Aachen (3131)
    Keywords: ddc:550.78 ; Experimental study ; Frost heave ; Ice lens formation ; Phase-field modeling ; Soil freezing ; Thermo-hydro-mechanical coupling
    Language: English
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    Winter Vertical Diffusion Rates in the Arctic Ocean, Estimated From 7Be Measurements and Dissipation Rate Profiles (2023)
    Details
    Publication Date: 2023-10-26
    Description: Ocean turbulent mixing is a key process affecting the uptake and redistribution of heat, carbon, nutrients, oxygen and other dissolved gasses. Vertical turbulent diffusivity sets the rates of water mass transformations and ocean mixing, and is intrinsically an average quantity over process time scales. Estimates based on microstructure profiling, however, are typically obtained as averages over individual profiles. How representative such averaged diffusivities are, remains unexplored in the quiescent Arctic Ocean. Here, we compare upper ocean vertical diffusivities in winter, derived from the 7Be tracer‐based approach to those estimated from direct turbulence measurements during the year‐long Multidisciplinary drifting Observatory for the Study of Arctic Climate (MOSAiC) expedition, 2019–2020. We found that diffusivity estimates from both methods agree within their respective measurement uncertainties. Diffusivity estimates obtained from dissipation rate profiles are sensitive to the averaging method applied, and the processing and analysis of similar data sets must take this sensitivity into account. Our findings indicate low characteristic diffusivities around 10〈sup〉−6〈/sup〉 m〈sup〉2〈/sup〉 s〈sup〉−1〈/sup〉 and correspondingly low vertical heat fluxes.
    Description: Plain Language Summary: Ocean turbulent mixing plays an important role in the uptake and redistribution of heat, carbon, nutrients, oxygen and other properties. For example, this process delivers nutrients to the sunlit surface ocean where they are utilized to produce plants (phytoplankton) for the ecosystem food web. However, strong changes in density within the upper Arctic Ocean hinder vertical transport of nutrients, such that nutrient fluxes are generally smaller than those observed elsewhere in the world ocean. Furthermore, low vertical transport rates isolate the surface ocean from heat input from below which helps protect the ice from melting. Here, we compare the strength of upper ocean mixing, an important parameter for the calculation of vertical transport, derived from two independent methods during the MOSAiC (Multidisciplinary drifting Observatory for the Study of Arctic Climate) ice drift experiment, 2019–2020. This comparison allows us to better quantify the vertical diffusivity, and in turn also the vertical transport of for example, heat and nutrients in the ocean.
    Description: Key Points: Arctic Ocean vertical diffusivity (K〈sub〉z〈/sub〉) in the upper halocline in winter is O(10〈sup〉−6〈/sup〉) m〈sup〉2〈/sup〉 s〈sup〉−1〈/sup〉. Diffusivity estimates from 〈sup〉7〈/sup〉Be measurements and ocean microstructure profiling agree within a factor of 2. K〈sub〉z〈/sub〉 estimates from turbulent dissipation rate profiles are sensitive to the averaging method.
    Description: Bundesministerium für Bildung und Forschung http://dx.doi.org/10.13039/501100002347
    Description: Research Council of Norway
    Description: National Science Foundation http://dx.doi.org/10.13039/100000001
    Description: https://doi.org/10.1594/PANGAEA.939816
    Description: https://doi.org/10.26008/1912/bco-dmo.861596.1
    Keywords: ddc:551.46 ; Arctic Ocean ; vertical mixing ; halocline ; winter ; turbulent diffusivity ; microstructure profiling
    Language: English
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    Influence of plastic fines content on the liquefaction susceptibility of sands: monotonic loading (2021)
    Springer Berlin Heidelberg
    Details
    Publication Date: 2023-12-19
    Description: The paper presents an experimental study on the effect of plastic fines content on the undrained behavior and liquefaction susceptibility of sand–fines mixtures under monotonic loading. The results of undrained monotonic triaxial compression tests conducted on mixtures of Hostun sand with varying amount (0–20%) and type (kaolin and calcigel bentonite) of plastic fines are presented. The specimens were prepared with different initial densities using the moist tamping method and consolidated at two different isotropic effective stresses. The results demonstrate that for both types of plastic fines, an increase in the fines content leads to a more contractive response and lower values of mobilized deviatoric stress. Despite similar relative density and fines content, the sand–kaolin mixtures showed a more contractive behavior than the sand–calcigel specimens. The steady-state lines (SSLs) in e–p´ space generally move downwards with increasing clay content. While the slopes of the SSLs for the clean Hostun sand and the mixtures with 10 and 20% kaolin are quite similar, the SSL lines for the specimens containing 10% or 20% calcigel run steeper or flatter, respectively. The inclination of the SSL in the q–p′ plane was found independent of clay type and content. The sand–kaolin mixtures were observed to be more susceptible to instability and flow liquefaction than the sand–calcigel mixtures.
    Keywords: ddc:550.78 ; Instability line ; Plastic fines content ; Sand–fines mixtures ; Steady-state line ; Undrained monotonic triaxial tests
    Language: English
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    Sulphate reduction determines the long-term effect of iron amendments on phosphorus retention in lake sediments (2021)
    Springer Berlin Heidelberg
    Details
    Publication Date: 2024-01-12
    Description: Purpose: This field study aimed to guide the planning of iron amendments for phosphorus retention by investigating the long-term fate of iron added to two urban lakes (Plötzensee and Groß Glienicker See) in Berlin, Germany. The contributions of iron dosing to improve lake status as well as the relevance of competing processes for management success were evaluated. Methods: Sediment stratigraphy, as well as occurrence of iron minerals, and fluxes between water and sediment were examined using geochemical analyses (i.e. element composition, sequential extraction, X-ray diffraction, and pore water analyses). A one-box lake model was used to relate these fluxes to monitoring data from the water column and to sediment inventories. Results: In both lakes, the added iron was preserved in the sediment. Whereas phosphorus retention increased following the addition of iron to Groß Glienicker See, sulphur was retained by the excess iron in Plötzensee. This contrasting effect is attributed to significantly different sulphate reduction rates in two lakes (Wilcoxon rank sum test: W = 25, p = 0.008). According to the one-box model, sulphate reduction explained both the decrease in measured sulphate concentrations after iron application as well as the observed increase in sulphur deposition in the sediments. Conclusion: Management interventions involving iron amendments to enhance phosphorus retention must consider the competing process of iron sulphide formation during the entire management plan period, and additional iron may need to be applied to account for this effect.
    Description: Leibniz-Institut für Gewässerökologie und Binnenfischerei (IGB) im Forschungsverbund Berlin e.V. (3473)
    Keywords: ddc:551.9 ; Iron dosing ; Lake restoration ; Management implications ; Minerals ; Sulphur cycling ; Long-term field study ; One-box model
    Language: English
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    Laboratory Assessment of the Impact of Chemical Oxidation, Mineral Dissolution, and Heating on the Nitrogen Isotopic Composition of Fossil‐Bound Organic Matter (2022)
    Details
    Publication Date: 2023-01-21
    Description: Fossil‐bound organic material holds great potential for the reconstruction of past changes in nitrogen (N) cycling. Here, with a series of laboratory experiments, we assess the potential effect of oxidative degradation, fossil dissolution, and thermal alteration on the fossil‐bound N isotopic composition of different fossil types, including deep and shallow water scleractinian corals, foraminifera, diatoms and tooth enamel. Our experiments show that exposure to different oxidizing reagents does not significantly affect the N isotopic composition or N content of any of the fossil types analyzed, demonstrating that organic matter is well protected from changes in the surrounding environment by the mineral matrix. In addition, we show that partial dissolution (of up to 70%–90%) of fossil aragonite, calcite, opal, or enamel matrixes has a negligible effect on the N isotopic composition and N content of the fossils. These results suggest that the isotopic composition of fossil‐bound organic material is relatively uniform, and also that N exposed during dissolution is lost without significant isotopic discrimination. Finally, our heating experiments show negligible changes in the N isotopic composition and N content of all fossil types at 100°C. At 200°C and hotter, any N loss and associated nitrogen isotope changes appear to be directly linked to the sensitivity of the mineral matrix to thermal stress, which depends on the biomineral type. These results suggest that, so long as high temperature does not compromise the mineral structure, the biomineral matrix acts as a closed system with respect to N, and the N isotopic composition of the fossil remains unchanged.
    Description: Plain Language Summary: The ratio of the heavy and light isotopes of nitrogen (15N and 14N) in the organic material contained within the mineral structure of fossils can be used to reconstruct past changes in biological and chemical processes. With a series of laboratory experiments, we evaluate the potential effects of chemical conditions, fossil dissolution, and heating on the nitrogen isotopic composition (15N/14N ratio) of corals, foraminifera, diatoms and tooth enamel. Our results indicate that these processes do not have a significant effect on the 15N/14N of fossils, suggesting that the mineral matrix provides a barrier that isolates a fossil's organic nitrogen from the surrounding environment, preventing alteration of its 15N/14N. In addition, we show that if part of the fossil‐bound organic nitrogen is exposed by dissolution or heating, it is lost without affecting the 15N/14N of the organic material that remains in the mineral. These findings imply that the original 15N/14N ratio incorporated by the organism is preserved in the geologic record. Therefore, measurements of the nitrogen isotopes on fossils can provide faithful biological, ecological, and environmental information about the past.
    Description: Key Points: Fossil‐bound organic matter is well protected by the mineral matrix from chemical changes in the surrounding environment. Partial dissolution of fossil calcite, aragonite, opal, and enamel has a negligible effect on their N isotopic composition and N content. During heating, fossil N content and isotopic composition remains unchanged if the structure of the inorganic matrix is not compromised.
    Description: Max Planck Society
    Description: Deutsche Forschungsgemeinschaft http://dx.doi.org/10.13039/501100001659
    Description: US National Science Foundation
    Description: Paul Crutzen Nobel Prize Fellowship
    Description: https://doi.org/10.5281/zenodo.6884681
    Keywords: ddc:551.9 ; nitrogen isotopes ; diagenesis ; foraminifera ; corals ; diatoms ; teeth
    Language: English
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    ICON‐O: The Ocean Component of the ICON Earth System Model—Global Simulation Characteristics and Local Telescoping Capability (2022)
    Details
    Publication Date: 2023-01-25
    Description: We describe the ocean general circulation model Icosahedral Nonhydrostatic Weather and Climate Model (ICON‐O) of the Max Planck Institute for Meteorology, which forms the ocean‐sea ice component of the Earth system model ICON‐ESM. ICON‐O relies on innovative structure‐preserving finite volume numerics. We demonstrate the fundamental ability of ICON‐O to simulate key features of global ocean dynamics at both uniform and non‐uniform resolution. Two experiments are analyzed and compared with observations, one with a nearly uniform and eddy‐rich resolution of ∼10 km and another with a telescoping configuration whose resolution varies smoothly from globally ∼80 to ∼10 km in a focal region in the North Atlantic. Our results show first, that ICON‐O on the nearly uniform grid simulates an ocean circulation that compares well with observations and second, that ICON‐O in its telescope configuration is capable of reproducing the dynamics in the focal region over decadal time scales at a fraction of the computational cost of the uniform‐grid simulation. The telescopic technique offers an alternative to the established regionalization approaches. It can be used either to resolve local circulation more accurately or to represent local scales that cannot be simulated globally while remaining within a global modeling framework.
    Description: Plain Language Summary: Icosahedral Nonhydrostatic Weather and Climate Model (ICON‐O) is a global ocean general circulation model that works on unstructured grids. It rests on novel numerical techniques that belong to the class of structure‐preserving finite Volume methods. Unstructured grids allow on the one hand a uniform coverage of the sphere without resolution clustering, and on the other hand they provide the freedom to intentionally cluster grid points in some region of interest. In this work we run ICON‐O on an uniform grid of approximately 10 km resolution and on a grid with four times less degrees of freedom that is stretched such that in the resulting telescoping grid within the North Atlantic the two resolutions are similar, while outside the focal area the grid approaches smoothly ∼80 km resolution. By comparison with observations and reanalysis data we show first, that the simulation on the uniform 10 km grid provides a decent mesoscale eddy rich simulation and second, that the telescoping grid is able to reproduce the mesoscale rich circulation locally in the North Atlantic and on decadal time scales. This telescoping technique of unstructured grids opens new research directions.
    Description: Key Points: We describe Icosahedral Nonhydrostatic Weather and Climate Model (ICON‐O) the ocean component of ICON‐ESM 1.0, based on the ICON modeling framework. ICON‐O is analyzed in a globally mesoscale‐rich simulation and in a telescoping configuration. In telescoping configuration ICON‐O reproduces locally the eddy dynamics with less computational costs than the uniform configuration.
    Description: https://swiftbrowser.dkrz.de/public/dkrz_07387162e5cd4c81b1376bd7c648bb60/kornetal2021
    Description: https://mpimet.mpg.de/en/science/modeling-with-icon/code-availability
    Keywords: ddc:551.46 ; ocean modeling ; ocean dynamics ; unstructured grid modeling ; local refinement ; structure preservation numerics
    Language: English
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    Thermal stress, cooling-rate and fictive temperature of silicate melts (2021)
    Springer Berlin Heidelberg
    Details
    Publication Date: 2023-08-08
    Description: The unknown cooling-rate history of natural silicate melts can be investigated using differential scanning heat capacity measurements together with the limiting fictive temperature analysis calculation. There are a range of processes occurring during cooling and re-heating of natural samples which influence the calculation of the limiting fictive temperature and, therefore, the calculated cooling-rate of the sample. These processes occur at the extremes of slow cooling and fast quenching. The annealing of a sample at a temperature below the glass transition temperature upon cooling results in the subsequent determination of cooling-rates which are up to orders of magnitude too low. In contrast, the internal stresses associated with the faster cooling of obsidian in air result in an added exothermic signal in the heat capacity trace which results in an overestimation of cooling-rate. To calculate cooling-rate of glass using the fictive temperature method, it is necessary to create a calibration curve determined using known cooling- and heating-rates. The calculated unknown cooling-rate of the sample is affected by the magnitude of mismatch between the original cooling-rate and the laboratory heating-rate when using the matched cooling-/heating-rate method to derive a fictive temperature/cooling-rate calibration curve. Cooling-rates slower than the laboratory heating-rate will be overestimated, while cooling-rates faster than the laboratory heating-rate are underestimated. Each of these sources of error in the calculation of cooling-rate of glass materials—annealing, stress release and matched cooling/heating-rate calibration—can affect the calculated cooling-rate by factor of 10 or more.
    Description: Georg-August-Universität Göttingen (1018)
    Keywords: ddc:550.78 ; Fictive temperature ; Annealing ; Thermal stress ; Cooling-rate ; Calorimetry
    Language: English
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    Influence of CO2 on the rheology of melts from the Colli Albani Volcanic District (Italy): foidite to phonolite (2021)
    Springer Berlin Heidelberg
    Details
    Publication Date: 2023-08-08
    Description: In this study, the influence of CO〈sub〉2〈/sub〉 on the rheology of silica poor and K-rich melts from highly explosive eruptions from the Colli Albani Volcanic District (Italy) (CAVD) is measured for the first time. The investigated melts range from foidite to tephri-phonolite to tephrite from the CAVD to a phonolite from the Vesuvius (Italy) with CO〈sub〉2〈/sub〉 concentrations up to 0.50 wt%. Viscosity and calorimetric measurements are performed in the glass transition range Tg between 600 and 780 °C. Although nominally anhydrous, the investigated melts contain H〈sub〉2〈/sub〉O concentrations up to 0.23 wt%. The data exhibit a decrease in viscosity of approx. 100.40 Pa s for the phonolitic composition with ~ 0.07 wt% CO〈sub〉2〈/sub〉 and a Tg reduced by approx. 14 °C. For the tephritic composition, Tg is approx. 5 °C lower and has a viscosity reduced by 100.25 Pa s for the sample containing ~ 0.5 wt% CO〈sub〉2〈/sub〉. Calorimetric measurements of the tephri-phonolite show lowered onset of Tg by approx. 6 °C for the melt with ~ 0.11 wt% CO2 and Tg of the foidite appears not to be influenced by a CO〈sub〉2〈/sub〉 concentration of ~ 0.37 wt% CO〈sub〉2〈/sub〉. However, these tephri-phonolitic and foiditic melts foamed during calorimetric measurements preventing a reliable measurement. It would appear that most of this overall drop in viscosity is caused by the small amounts of H〈sub〉2〈/sub〉O in the melts with CO〈sub〉2〈/sub〉 slightly reducing the viscosity or having no effect on viscosity. Additionally, it is shown that the reduction in viscosity decreases with an increasing degree of the depolymerisation for the investigated melts. Consequently, the explosive style of the CAVD eruptions is mainly caused by crystals and bubbles which form and rise during magma storage and ascent which increases the magma viscosity whereas the CO〈sub〉2〈/sub〉 in the melt slightly reduces the viscosity.
    Description: Deutsche Forschungsgemeinschaft http://dx.doi.org/10.13039/501100001659
    Description: Georg-August-Universität Göttingen (1018)
    Keywords: ddc:550.78 ; Viscosity ; Calorimetry ; Colli Albani ; Carbon dioxide ; Glass transition ; Foidite
    Language: English
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    The redox dependence of titanium isotope fractionation in synthetic Ti-rich lunar melts (2021)
    Springer Berlin Heidelberg
    Details
    Publication Date: 2023-08-08
    Description: Equilibria between Ti oxides and silicate melt lead to Ti isotope fractionation in terrestrial samples, with isotopically light Ti oxides and isotopically heavy coexisting melt. However, while Ti is mostly tetravalent in terrestrial samples, around 10% of the overall Ti is trivalent at f〈sub〉O2〈/sub〉 relevant to lunar magmatism (~ IW-1). The different valences of Ti in lunar samples, could additionally influence Ti stable isotope fractionation during petrogenesis of lunar basalts to an unknown extent. We performed an experimental approach using gas mixing furnaces to investigate the effect of Ti oxide formation at different f〈sub〉O2〈/sub〉 on Ti stable isotope fractionation during mare basalt petrogenesis. Two identical bulk compositions were equilibrated simultaneously during each experiment to guarantee comparability. One experiment was investigated with the EPMA to characterize the petrology of experimental run products, whereas the second experiment was crushed, and fabricated phases (i.e., oxides, silicates and glass) were handpicked, separated and digested. An aliquot of each sample was mixed with a Ti double-spike, before Ti was separated from matrix and interfering elements using a modified HFSE chemistry. Our study shows f〈sub〉O2〈/sub〉-dependent fractionation within seven samples from air to IW-1, especially ∆49Ti〈subs〈armalcolite〈/sub〉-melt and ∆49Ti〈sub〉armalcolite-orthopyroxene〈/sub〉 become more fractionated from oxidized to reduced conditions (− 0.092 ± 0.028-  − 0.200 ± 0.033 ‰ and  − 0.089 ± 0.027- − 0.250 ± 0.049 ‰, respectively), whereas ∆49Ti〈sub〉orthopyroxene〈/sub〉-melt shows only a minor fractionation (− 0.002 ± 0.017-0.050 ± 0.025 ‰). The results of this study show that Ti isotope fractionation during mare basalt petrogenesis is expected to be redox dependent and mineral-melt fractionation as commonly determined for terrestrial fO2 may not be directly applied to a lunar setting. This is important for the evaluation of Ti isotope fractionation resulting from lunar magmatism, which takes place under more reducing conditions compared to the more oxidized terrestrial magmatism.
    Description: Deutsche Forschungsgemeinschaft
    Description: Projekt DEAL
    Keywords: ddc:550.78 ; Titanium isotopes ; Lunar magma ocean ; Fractionation ; Experiments ; Ti oxides ; Armalcolite
    Language: English
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    Experimental observations of aquifer storage and recovery in brackish aquifers using multiple partially penetrating wells (2021)
    Springer Berlin Heidelberg
    Details
    Publication Date: 2023-08-08
    Description: Aquifer storage and recovery systems using multiple partially penetrating wells (MPPW-ASR) can form a viable solution to the problem of freshwater buoyancy when using brackish aquifers for freshwater storage. This study presents the result of a series of laboratory experiments that aimed at visualizing the shape of freshwater bodies injected into a brackish aquifer and determining the effect on the recovery efficiency (RE) of several MPPW-ASR operational variables. A model aquifer was built in a Plexiglas tank using glass beads and water was injected and abstracted through point and vertical wells, which were operated in various combinations. Numerical models were used to support the interpretation of the time-lapse photographs, and showed that three-dimensional flow effects had to be considered for a correct interpretation of the visible dye patterns. Upward migration of both fresh (during injection) and brackish water (during recovery) along the vertical wells was observed, indicating that the role of well infrastructure as conduits is a critical design criterion for real-world systems. Gravitational instabilities formed when freshwater did not extend all the way to the top of the aquifer, and this negatively impacted the RE by causing greater mixing. The positive freshwater buoyancy led to freshwater bodies that became narrower with depth, and the formation of thin, elongated buffer zones along the aquifer top in multicycle experiments. Up-coning below abstraction wells resulted in lower RE values, reinforcing the potential of scavenger wells to enhance MPPW-ASR system performance.
    Description: Bundesanstalt für Geowissenschaften und Rohstoffe (BGR) (4230)
    Keywords: ddc:550.78 ; Artificial recharge ; Laboratory experiments/measurements ; Numerical modelling ; Multiple partially penetrating wells ; Salt-water/fresh-water relations
    Language: English
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  • 43
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    Trace element fractionation between biotite, allanite, and granitic melt (2021)
    Springer Berlin Heidelberg
    Details
    Publication Date: 2023-08-08
    Description: The partitioning of a large suite of trace elements between biotite and water-saturated granitic melt was measured at 2 kbar and 700—800 ˚C. To reach equilibrium and to grow biotite crystals large enough for analysis, runs usually lasted from 30 to 45 days. In every charge, a few trace elements were initially doped at the 0.1—0.5 wt. % level and analyzed by electron microprobe after the run. First-row transition metal ions are highly compatible in biotite with D〈sup〉biotite/melt〈/sup〉 of 17 for Ti, 35 for V, 47 for Co, 174 for Ni, and 5.8 for Zn. A very notable exception is Cu with D〈sup〉biotite/melt〈/sup〉 〈 0.9. This is likely one of the reasons why Cu is enriched together with Mo (D〈sup〉biotite/melt〈/sup〉 = 0.29) in porphyry deposits associated with intermediate to felsic plutons, while the other transition metals are not. Both Nb and Ta are mildly compatible in biotite with D〈sup〉biotite/melt〈/sup〉 being larger for Nb (3.69) than for Ta (1.89). Moderate (15—30%) biotite fractionation would be sufficient to reduce the Nb/Ta ratio from the chondritic value to the range observed in the continental crust. Moreover, the strong partitioning of Ti into biotite implies that already modest biotite fractionation suppresses the saturation of Ti-oxide phases and thereby indirectly facilitates the enrichment of Ta over Nb in the residual melt. The heavy alkalis, alkaline earths, and Pb are only mildly fractionated between biotite and melt (D〈sup〉biotite/melt〈/sup〉 = 3.8 for Rb, 0.6 for Cs, 0.6 for Sr, 1.8 for Ba, 0.7 for Pb). The rare earth elements are generally incompatible in biotite, with a minimum for Dbiotite/melt of 0.03–0.06 at Gd, Tb, and Dy, while both the light and heavy rare earths are less incompatible (e.g. D〈sup〉biotite/melt〈/sup〉 = 0.6 for La and 0.3 for Yb). This behavior probably reflects a partitioning into two sites, the K site for the light rare earths and the octahedral Mg site for the heavy rare earths. There is no obvious dependence of the rare earth partition coefficients on tetrahedral Al in the biotite, presumably because charge balancing by cation vacancies is possible. Allanite was found as run product in some experiments. For the light rare earths, D〈sup〉allanite/melt〈/sup〉 is very high (e.g. 385 to 963 for Ce and Nd) and appears to increase with decreasing temperatures. However, the rather high solubility of allanite in the melts implies that it likely only crystallizes during the last stages of cooling of most magmas, except if the source magma is unusually enriched in rare earths.
    Description: Deutsche Forschungsgemeinschaft
    Description: Universität Bayreuth (3145)
    Keywords: ddc:550.78 ; Biotite ; Allanite ; Granite ; Partitioning ; Solubility ; Rare earths ; Niobium ; Tantalum ; Nb/Ta ratio ; Porphyry copper deposits
    Language: English
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  • 44
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    Sub-arc mantle enrichment in the Sunda rear-arc inferred from HFSE systematics in high-K lavas from Java (2021)
    Kirchenbaur, M. ; Schuth, S. ; Barth, A. R. ; [et al.]
    Springer Berlin Heidelberg
    Details
    Publication Date: 2023-08-08
    Description: Many terrestrial silicate reservoirs display a characteristic depletion in Nb, which has been explained in some studies by the presence of reservoirs on Earth with superchondritic Nb/Ta. As one classical example, K-rich lavas from the Sunda rear-arc, Indonesia, have been invoked to tap such a high-Nb/Ta reservoir. To elucidate the petrogenetic processes active beneath the Java rear-arc and the causes for the superchondritic Nb/Ta in some of these lavas, we studied samples from the somewhat enigmatic Javanese rear-arc volcano Muria, which allow conclusions regarding the across-arc variations in volcanic output, source mineralogy and subduction components. We additionally report some data for an along-arc sequence of lavas from the Indonesian part of the Sunda arc, extending from Krakatoa in the west to the islands of Bali and Lombok in the east. We present major and trace element concentrations, Sr–Nd–Hf–Pb isotope compositions, and high-field-strength element (HFSE: Nb, Ta, Zr, Hf, W) concentrations obtained via isotope dilution and MC-ICP-MS analyses. The geochemical data are complemented by melting models covering different source compositions with slab melts formed at variable P–T conditions. The radiogenic isotope compositions of the frontal arc lavas in combination with their trace element systematics confirm previously established regional variations of subduction components along the arc. Melting models show a clear contribution of a sediment-derived component to the HFSE budget of the frontal arc lavas, particularly affecting Zr–Hf and W. In contrast, the K-rich rear-arc lavas tap more hybrid and enriched mantle sources. The HFSE budget of the rear-arc lavas is in particular characterized by superchondritic Nb/Ta (up to 25) that are attributed to deep melting involving overprint by slab melts formed from an enriched garnet–rutile-bearing eclogitic residue. Sub-arc slab melting was potentially triggered along a slab tear beneath the Sunda arc, which is the result of the forced subduction of an oceanic basement relief ~ 8 Myr ago as confirmed by geophysical studies. The purported age of the slab tear coincides with a paucity in arc volcanism, widespread thrusting of the Javanese basement crust as well as the short-lived nature of the K-rich rear-arc volcanism at that time.
    Description: Deutscher Akademischer Austauschdienst http://dx.doi.org/10.13039/501100001655
    Description: Gottfried Wilhelm Leibniz Universität Hannover (1038)
    Keywords: ddc:551.9 ; Rear-arc volcanism ; Superchondritic Nb/Ta ; Muria ; Sunda arc
    Language: English
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    Linking gas and particle ejection dynamics to boundary conditions in scaled shock-tube experiments (2021)
    Springer Berlin Heidelberg
    Details
    Publication Date: 2023-08-02
    Description: Predicting the onset, style and duration of explosive volcanic eruptions remains a great challenge. While the fundamental underlying processes are thought to be known, a clear correlation between eruptive features observable above Earth’s surface and conditions and properties in the immediate subsurface is far from complete. Furthermore, the highly dynamic nature and inaccessibility of explosive events means that progress in the field investigation of such events remains slow. Scaled experimental investigations represent an opportunity to study individual volcanic processes separately and, despite their highly dynamic nature, to quantify them systematically. Here, impulsively generated vertical gas-particle jets were generated using rapid decompression shock-tube experiments. The angular deviation from the vertical, defined as the “spreading angle”, has been quantified for gas and particles on both sides of the jets at different time steps using high-speed video analysis. The experimental variables investigated are 1) vent geometry, 2) tube length, 3) particle load, 4) particle size, and 5) temperature. Immediately prior to the first above-vent observations, gas expansion accommodates the initial gas overpressure. All experimental jets inevitably start with a particle-free gas phase (gas-only), which is typically clearly visible due to expansion-induced cooling and condensation. We record that the gas spreading angle is directly influenced by 1) vent geometry and 2) the duration of the initial gas-only phase. After some delay, whose length depends on the experimental conditions, the jet incorporates particles becoming a gas-particle jet. Below we quantify how our experimental conditions affect the temporal evolution of these two phases (gas-only and gas-particle) of each jet. As expected, the gas spreading angle is always at least as large as the particle spreading angle. The latter is positively correlated with particle load and negatively correlated with particle size. Such empirical experimentally derived relationships between the observable features of the gas-particle jets and known initial conditions can serve as input for the parameterisation of equivalent observations at active volcanoes, alleviating the circumstances where an a priori knowledge of magma textures and ascent rate, temperature and gas overpressure and/or the geometry of the shallow plumbing system is typically chronically lacking. The generation of experimental parameterisations raises the possibility that detailed field investigations on gas-particle jets at frequently erupting volcanoes might be used for elucidating subsurface parameters and their temporal variability, with all the implications that may have for better defining hazard assessment.
    Description: Seventh Framework Programme http://dx.doi.org/10.13039/501100004963
    Description: Deutsche Forschungsgemeinschaft
    Description: European Research Council http://dx.doi.org/10.13039/501100000781
    Description: https://doi.org/10.5880/fidgeo.2020.030
    Keywords: ddc:550.78 ; Explosive volcanism, ; Experimental volcanology, ; Spreading angle, ; Shock-tube
    Language: English
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    Release characteristics of overpressurised gas from complex vents: implications for volcanic hazards (2020)
    Springer Berlin Heidelberg
    Details
    Publication Date: 2023-06-23
    Description: Many explosive volcanic eruptions produce underexpanded starting gas-particle jets. The dynamics of the accompanying pyroclast ejection can be affected by several parameters, including magma texture, gas overpressure, erupted volume and geometry. With respect to the latter, volcanic craters and vents are often highly asymmetrical. Here, we experimentally evaluate the effect of vent asymmetry on gas expansion behaviour and gas jet dynamics directly above the vent. The vent geometries chosen for this study are based on field observations. The novel element of the vent geometry investigated herein is an inclined exit plane (5, 15, 30° slant angle) in combination with cylindrical and diverging inner geometries. In a vertical setup, these modifications yield both laterally variable spreading angles as well as a diversion of the jets, where inner geometry (cylindrical/diverging) controls the direction of the inclination. Both the spreading angle and the inclination of the jet are highly sensitive to reservoir (conduit) pressure and slant angle. Increasing starting reservoir pressure and slant angle yield (1) a maximum spreading angle (up to 62°) and (2) a maximum jet inclination for cylindrical vents (up to 13°). Our experiments thus constrain geometric contributions to the mechanisms controlling eruption jet dynamics with implications for the generation of asymmetrical distributions of proximal hazards around volcanic vents.
    Description: European Research Council http://dx.doi.org/10.13039/501100000781
    Keywords: ddc:550.78 ; Explosive eruptions ; Crater asymmetry ; Vent asymmetry ; Gas jets ; Inclined jets ; Tilted eruptions
    Language: English
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    Vesicle shrinkage in hydrous phonolitic melt during cooling (2020)
    Springer Berlin Heidelberg
    Details
    Publication Date: 2023-06-23
    Description: The ascent of hydrous magma prior to volcanic eruptions is largely driven by the formation of H2O vesicles and their subsequent growth upon further decompression. Porosity controls buoyancy as well as vesicle coalescence and percolation, and is important when identifying the differences between equilibrium or disequilibrium degassing from textural analysis of eruptive products. Decompression experiments are routinely used to simulate magma ascent. Samples exposed to high temperature (T) and pressure (P) are decompressed and rapidly cooled to ambient T for analysis. During cooling, fluid vesicles may shrink due to decrease of the molar volume of H2O and by resorption of H2O back into the melt driven by solubility increase with decreasing T at P 〈 300 MPa. Here, we quantify the extent to which vesicles shrink during cooling, using a series of decompression experiments with hydrous phonolitic melt (5.3–3.3 wt% H2O, T between 1323 and 1373 K, decompressed from 200 to 110–20 MPa). Most samples degassed at near-equilibrium conditions during decompression. However, the porosities of quenched samples are significantly lower than expected equilibrium porosities prior to cooling. At a cooling rate of 44 K·s−1, the fictive temperature Tf, where vesicle shrinkage stops, is up to 200 K above the glass transition temperature (Tg), Furthermore, decreasing cooling rate enhances vesicles shrinkage. We assess the implications of these findings on previous experimental degassing studies using phonolitic melt, and highlight the importance of correctly interpreting experimental porosity data, before any comparison to natural volcanic ejecta can be attempted.
    Description: German Science Foundation
    Keywords: ddc:550.78 ; Decompression experiments ; Vesiculation ; Vesicle shrinkage ; Quench effect ; H2O resorption ; Fictive temperature
    Language: English
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  • 48
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    The effect of initial H2O concentration on decompression-induced phase separation and degassing of hydrous phonolitic melt (2020)
    Springer Berlin Heidelberg
    Details
    Publication Date: 2023-06-23
    Description: Supersaturation of H2O during magma ascent leads to degassing of melt by formation and growth of vesicles that may power explosive volcanic eruptions. Here, we present experiments to study the effect of initially dissolved H2O concentration (cH2Oini) on vesicle formation, growth, and coalescence in phonolitic melt. Vesuvius phonolitic melts with cH2Oini ranging between 3.3 and 6.3 wt% were decompressed at rates of 1.7 and 0.17 MPa·s−1 and at temperatures ≥ 1323 K. Decompression started from 270 and 200 MPa to final pressures of 150–20 MPa, where samples were quenched isobarically. Optical microscopy and Raman spectroscopic measurements confirm that the glasses obtained were free of microcrystals and Fe-oxide nanolites, implying that the experiments were superliquidus and phase separation of the hydrous melt was homogeneous. A minimum number of the initially formed vesicles, defined by the number density normalized to vesicle-free glass volume (VND), is observed at ~ 5 wt% cH2Oini with a logVND of ~ 5 (in mm−3). The logVND increases strongly towards lower and higher cH2Oini by one order of magnitude. Furthermore, an important transition in evolution of vesiculation occurs at ~ 5.6 wt% cH2Oini. At lower cH2Oini, the initial VND is preserved during further decompression up to melt porosities of 30–50%. At higher cH2Oini, the initial vesicle population is erased at low melt porosities of 15–21% during further decompression. This observation is attributed to vesicle coalescence favored by low melt viscosity. In conclusion, cH2Oini determines the VND of initial phase separation and the evolution of vesiculation during decompression that controls the style of volcanic eruptions.
    Description: German Science Foundation
    Keywords: ddc:550.78 ; Vesicle number density ; Phonolitic melt ; Spinodal decomposition ; Melt degassing ; H2O concentration ; Fe-oxide nanolites
    Language: English
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    The Deep‐Water Plume in the Northwestern Weddell Sea, Antarctica: Mean State, Seasonal Cycle and Interannual Variability Influenced by Climate Modes (2023)
    Details
    Publication Date: 2023-06-21
    Description: We provide an updated estimate of the annual‐mean, seasonal cycle and interannual variability of the transports and properties of the Weddell Sea Bottom Water (WSBW) plume in the northwestern Weddell Sea. For this we used a densely instrumented mooring array deployed across the continental slope between January 2017 and January 2019. We found that the annual‐mean WSBW transport is 3.4 ± 1.5 Sv, corresponding to a cross‐section area of 35 km2 and a maximum thickness of 203 m. The annual mean transport‐weighted properties of WSBW are −0.99°C (Θ), 34.803 g/kg (SA) and 28.44 kg/m3 (γn). The WSBW is characterized by 3 bottom‐intensified velocity cores, which display seasonal variations in flow speed and transport different varieties of WSBW. The seasonal peak of WSBW transport and density is reached in May (4.7 Sv, 28.443 kg m−3) while the minimum values are observed in February (2.8 Sv, 28.435 kg m−3). The coldest WSBW is found between March and May, and the warmest between August and October. The density decrease of WSBW observed in the austral autumn of 2018 can be explained by warmer ambient waters being entrained during the formation of WSBW. This was enabled by the weakening of the along‐shore winds associated with a positive Southern Annular Mode index, reinforced by a La Niña event in early 2018. The synchronous decrease of total WSBW transport and volume between September 2018 and February 2019 indicates a reduction in the export of the dense precursors of WSBW from the Weddell Sea continental shelf.
    Description: Plain Language Summary: The Meridional Overturning Circulation (MOC) redistributes heat and carbon dioxide in the world ocean. Thus, it plays an important role in the regulation of our planet's climate. The Weddell Sea is the main contributor to the deep branch of the MOC in the Southern Hemisphere. Despite the importance of this contribution, uncertainties still remain associated to the plume of dense waters transported along the continental slope of the Weddell Sea. To reduce these uncertainties, we analyzed the most densely instrumented mooring array deployed across the continental slope in the northwestern Weddell Sea. We found that this plume flows faster close to the seafloor and that it presents important seasonal and interannual variability. The Weddell Sea Bottom Water interannual variability is influenced by changes in the along‐shore winds driven by the phase of two important climate modes, the Southern Annular Mode and the El Niño‐Southern Oscillation, but also by changes in the export of the dense precursors of WSBW in its formation areas. Increasing our knowledge on the along‐slope plume variability and properties is important to better understand the causes behind the variability of the MOC observed further downstream.
    Description: Key Points: The Weddell Sea Bottom Water (WSBW) plume presents 3 velocity cores and a clear seasonal cycle, with maximum transports and densities in May and minimum in February. A +SAM, reinforced by a ‐ENSO, favors the warming of WSBW via a wind‐driven warming of the ambient waters entrained during its formation. We observed a marked decrease in WSBW density and transports between September 2018 and February 2019 compared to the previous year.
    Description: EU Horizon 2020 Research and Innovation Program
    Description: German Research Foundation
    Description: Alfred Wegener Institute Helmholtz‐Center
    Description: https://doi.org/10.5281/zenodo.7500163
    Keywords: ddc:551.46 ; Weddell Sea ; WSBW ; Meridional Overturning Circulation ; SAM ; ENSO ; deep‐water plume
    Language: English
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  • 50
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    Constraints on the pre-eruptive magmatic history of the Quaternary Laacher See volcano (Germany) (2020)
    Springer Berlin Heidelberg
    Details
    Publication Date: 2023-06-21
    Description: Ba zonation patterns in sanidine phenocrysts from mafic and intermediate phonolite and crystal-rich cumulates from the Laacher See volcano (12.9 ka) in western Germany document diffusion times suggestive of periodic recharge events throughout the magma reservoir’s entire lifespan of ~ 24 ky. Phenocrysts analysed from samples that formed late at the base of the compositionally zoned magma reservoir by mixing and mingling between a resident phonolite magma and recharging basanite show resorption and thin (2–10 μm) late-stage Ba-rich overgrowth. Short diffusion profiles across these boundaries give diffusion times of ~ 1.5–3 years at most, which are interpreted to be the maximum duration between the most recent recharge by the basanite and eruption. The lack of such late overgrowth in samples from other parts of the phonolite reservoir suggests that effect of this mixing and mingling was limited to the crystal-rich base. Sanidines in the cumulates, by contrast, are generally devoid of zoned crystals. Only rare cumulate crystals with resorbed outer boundaries and very thin overgrowths (a few microns) with very sharp compositional changes imply the remobilization of cumulates only months before eruption. Based on the diffusion timescales and storage temperatures obtained in a previous study, we present a genetic model for the conditions and timing of storage and (re-)activation of the magma system prior to the eruption of Laacher See, which is the largest volcanic event in Central Europe since the last glaciation.
    Description: Deutscher Akademischer Austauschdienst http://dx.doi.org/10.13039/501100001655
    Keywords: ddc:551.9 ; Laacher see ; Diffusion chronometry ; Barium ; BSE images ; Magma storage
    Language: English
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    Global tide simulations with ICON-O: testing the model performance on highly irregular meshes (2020)
    Springer Berlin Heidelberg
    Details
    Publication Date: 2023-06-21
    Description: The global tide is simulated with the global ocean general circulation model ICON-O using a newly developed tidal module, which computes the full tidal potential. The simulated coastal M2 amplitudes, derived by a discrete Fourier transformation of the output sea level time series, are compared with the according values derived from satellite altimetry (TPXO-8 atlas). The experiments are repeated with four uniform and sixteen irregular triangular grids. The results show that the quality of the coastal tide simulation depends primarily on the coastal resolution and that the ocean interior can be resolved up to twenty times lower without causing considerable reductions in quality. The mesh transition zones between areas of different resolutions are formed by cell bisection and subsequent local spring optimisation tolerating a triangular cell’s maximum angle up to 84°. Numerical problems with these high-grade non-equiangular cells were not encountered. The results emphasise the numerical feasibility and potential efficiency of highly irregular computational meshes used by ICON-O.
    Description: Deutsche Forschungsgemeinschaft http://dx.doi.org/10.13039/501100001659
    Keywords: ddc:551.46 ; Ocean modelling ; Tides ; Unstructured grids ; Mesh refinement ; ICON-O
    Language: English
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  • 52
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    Tidal response to sea level rise and bathymetric changes in the German Wadden Sea (2020)
    Springer Berlin Heidelberg
    Details
    Publication Date: 2023-06-21
    Description: Tidally dominated coasts are directly affected not only by projected rise in mean sea level, but also by changes in tidal dynamics due to sea level rise and bathymetric changes. By use of a hydrodynamic model, which covers the entire German Bight (South-Eastern North Sea), we analyse the effects of sea level rise and potential bathymetric changes in the Wadden Sea on tidal current velocities. The model results indicate that tidal current velocities in the tidal inlets and channels of the Wadden Sea are increased in response to sea level rise. This is explained by the increased ratio of tidal prism to tidal inlet cross-sectional area, which is due to the characteristic hypsometry of tidal basins in the Wadden Sea including wide and shallow tidal flats and relatively narrow tidal channels. The results further indicate that sea level rise decreases ebb dominance and increases flood dominance in tidal channels. This is, amongst others, related to a decreased intertidal area again demonstrating the strong interaction between tidal wave and tidal basin hypsometry in the Wadden Sea. The bathymetry scenario defined in this study includes elevated tidal flats and deepened tidal channels, which is considered a potential future situation under accelerated sea level rise. Application of these bathymetric changes to the model mostly compensates the effects of sea level rise. Furthermore, changes in current velocity due to the altered bathymetry are in the same order of magnitude as changes due to mean sea level rise. This highlights the significance of considering potential bathymetric changes in the Wadden Sea for regional projections of the tidal response to sea level rise.
    Description: Bundesanstalt für Wasserbau (4234)
    Keywords: ddc:551.46 ; Sea level rise ; Tidal basin ; Tidal asymmetry ; Hypsometric control ; Hydrodynamic model ; Wadden Sea
    Language: English
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    Improvements in turbulence model realizability for enhanced stability of ocean forecast and its importance for downstream components (2020)
    Springer Berlin Heidelberg
    Details
    Publication Date: 2023-06-21
    Description: The numerical stability of ocean circulation models is of high significance in operational forecasting. A substantial improvement in numerical stability of the 3D-ocean model HBM could be achieved by the implementation of new realizability criteria in the turbulence closure scheme. Realizability criteria which were already well documented for closure functions without double diffusion were therefore extended to those using double diffusion. A purely technical validation method called ε-test which is suitable for the detection of numerical stability problems is presented, and the effect of the development in turbulence model is demonstrated under severe weather conditions during extreme storm events. Evaluation of statistics of longer simulations indicate that instabilities appeared only locally and temporary; nevertheless, a significant impact on drift products relying on the current forecasts could be demonstrated, which underlines the importance of realizability in turbulence closure schemes in comprehensive operational model systems including ocean circulation and downstream drift components.
    Description: Bundesamt für Seeschifffahrt und Hydrographie (BSH) (4225)
    Keywords: ddc:551.46 ; turbulence closure ; numerical stability / realizability ; operational forecasting systems
    Language: English
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  • 54
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    Estimates of wind power and radiative near-inertial internal wave flux (2020)
    Springer Berlin Heidelberg
    Details
    Publication Date: 2023-06-21
    Description: Energy transfer mechanisms between the atmosphere and the deep ocean have been studied for many years. Their importance to the ocean’s energy balance and possible implications on mixing are widely accepted. The slab model by Pollard (Deep-Sea Res Oceanogr Abstr 17(4):795–812, 1970) is a well-established simulation of near-inertial motion and energy inferred through wind-ocean interaction. Such a model is set up with hourly wind forcing from the NCEP-CFSR reanalysis that allows computations up to high latitudes without loss of resonance. Augmenting the one-dimensional model with the horizontal divergence of the near-inertial current field leads to direct estimates of energy transfer spectra of internal wave radiation from the mixed layer base into the ocean interior. Calculations using this hybrid model are carried out for the North Atlantic during the years 1989 and 1996, which are associated with positive and negative North Atlantic Oscillation index, respectively. Results indicate a range of meridional regimes with distinct energy transfer ratios. These are interpreted in terms of the mixed layer depth, the buoyancy frequency at the mixed layer base, and the wind field structure. The average ratio of radiated energy fluxes from the mixed layer to near-inertial wind power for both years is approximately 12%. The dependence on the wind structure is supported by simulations of idealized wind stress fronts with variable width and translation speeds.
    Description: Deutsche Forschungsgemeinschaft https://doi.org/10.13039/501100001659
    Description: Canadian Network for Research and Innovation in Machining Technology, Natural Sciences and Engineering Research Council of Canada https://doi.org/10.13039/501100002790
    Keywords: ddc:551.46 ; Near inertial waves ; Wind ocean coupling ; Internal gravity waves
    Language: English
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  • 55
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    Interactions between barotropic tides and mesoscale processes in deep ocean and shelf regions (2020)
    Springer Berlin Heidelberg
    Details
    Publication Date: 2023-06-21
    Description: The interactions between barotropic tides and mesoscale processes were studied using the results of a numerical model in which tidal forcing was turned on and off. The research area covered part of the East Atlantic Ocean, a steep continental slope, and the European Northwest Shelf. Tides affected the baroclinic fields at much smaller spatial scales than the barotropic tidal scales. Changes in the horizontal patterns of the M2 and M4 tidal constituents provided information about the two-way interactions between barotropic tides and mesoscale processes. The interaction between the atmosphere and ocean measured by the work done by wind was also affected by the barotropic tidal forcing. Tidal forcing intensified the transient processes and resulted in a substantial transformation of the wave number spectra in the transition areas from the deep ocean to the shelf. Tides flattened the sea-surface height spectra down to ~ k−2.5 power law, thus reflecting the large contribution of the processes in the high-frequency range compared to quasi-geostrophic motion. The spectra along sections parallel or normal to the continental slope differ from each other, which indicates that mesoscale turbulence was not isotropic. An analysis of the vorticity spectra showed that the flattening was mostly due to internal tides. Compared with the deep ocean, no substantial scale selectivity was observed on the shelf area. Particle tracking showed that the lengths of the Lagrangian trajectories increased by approximately 40% if the barotropic tidal forcing was activated, which contributed to changed mixing properties. The ratio between the horizontal and vertical scales of motion varied regionally depending on whether barotropic tidal forcing was included. The overall conclusion is that the barotropic tides affect substantially the diapycnal mixing.
    Description: Ministry of Science and Culture of Lower Saxony
    Description: BMBF
    Keywords: ddc:551.46 ; Tides ; Mesoscale processes ; Nonlinear interactions ; Diapycnal mixing ; Spectral energy ; European Northwest Shelf
    Language: English
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  • 56
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    Oxygen Consumption of Resuspended Sediments of the Upper Elbe Estuary: Process Identification and Prognosis (2021)
    Springer Netherlands
    Details
    Publication Date: 2023-08-25
    Description: The resuspension of sediment leads to an increased release of nutrients and organic substances into the overlying water column, which can have a negative effect on the oxygen budget. Especially in the warmer months with a lower oxygen saturation and higher biological activity, the oxygen content can reach critical thresholds in estuaries like the upper Elbe estuary. Many studies have dealt with the nutrient fluxes that occur during a resuspension event. However, the sediment properties that influence the oxygen consumption potential (OCP) and the different biochemical processes have not been examined in detail. To fill this gap, we investigated the biogeochemical composition, texture, and OCP of sediments at 21 locations as well as the temporal variability within one location for a period of 2 years (monthly sampling) in the upper Elbe estuary. The OCP of sediments during a seven-day resuspension event can be described by the processes of sulphate formation, nitrification, and mineralisation. Chlorophyll, total nitrogen (Ntotal), and total organic carbon showed the highest correlations with the OCP. Based on these correlations, we developed a prognosis model to calculate the OCP for the upper Elbe estuary with a single sediment parameter (Ntotal). The model is well suited to calculate the oxygen consumption of resuspended sediments in the Hamburg port area during the relevant warmer months and shows a normalised root mean squared error of 〈 0.11 ± 0.13. Thus, the effect of maintenance measures such as water injection dredging and ship-induced wave on the oxygen budget of the water can be calculated.
    Description: Hamburg Port Authority
    Description: Universität Hamburg (1037)
    Keywords: ddc:551.9 ; Sediment ; Resuspension ; Oxygen consumption ; Nutrients ; Elbe estuary ; Modelling
    Language: English
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    The Interface Between Magma and Earth's Atmosphere (2022)
    Details
    Publication Date: 2023-07-20
    Description: Volatiles released from magma can form bubbles and leave the magma body to eventually mix with atmospheric air. The composition of those volatiles, as derived from measurements made after their emission, is used to draw conclusions on processes in the Earth's interior or their influences on Earth's atmosphere. So far, the discussion of the influence of high‐temperature mixing with atmospheric air (in particular oxygen) on the measured volcanic gas composition is almost exclusively based on thermodynamic equilibrium (TE) considerations. By modeling the combined effects of C‐H‐O‐S reaction kinetics, turbulent mixing, and associated cooling during the first seconds after magmatic gas release into the atmosphere we show that the resulting gas compositions generally do not represent TE states, with individual species (e.g., CO, H2, H2S, OCS, SO3, HO2, H2O2) deviating by orders of magnitude from equilibrium levels. Besides revealing the chemical details of high‐temperature emission processes, our results question common interpretations of volcanic gas studies, particularly affecting the present understanding of auto‐catalytic conversion of volcanic halogen species in the atmosphere and redox state determination from volcanic plume gas measurements.
    Description: Plain Language Summary: A major fraction of magmatic gas emissions are released into the atmosphere from open vents. The emission processes are characterized by fast turbulent mixing with atmospheric air (within seconds) and associated rapid cooling. Hardly anything is known about the chemical kinetics within this brief mixing and cooling period. We simulate the chemical kinetics during the first seconds of hot magmatic gases in the atmosphere and find severe deviation to common interpretations and central thermodynamic equilibrium assumptions prevailing in volcanic gas geochemistry.
    Description: Key Points: We model the chemical kinetics of high‐temperature volcanic gas emissions within the first seconds of mixing with atmospheric air. We identify key chemical processes within the magma‐atmosphere interface and quantify influences on the volcanic plume composition. Our results question common assumptions prevailing in volcanic gas geochemistry and refine interpretations of gas emissions from open vents.
    Description: German Research Foundation
    Keywords: ddc:551.9 ; volcanic gas emissions ; kinetic chemistry modeling ; atmospheric chemistry ; magmatic redox states ; reactive halogen chemistry
    Language: English
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    Sedimentological evidence for seiching in a swell-dominated headland-bay system: Table Bay, Western Cape, South Africa (2021)
    Springer Berlin Heidelberg
    Details
    Publication Date: 2023-07-27
    Description: Table Bay, South Africa, is a typical headland-bay system with a shoreline that can be described by a logarithmic spiral. A peculiarity and unique feature of Table Bay is the juxtaposition of Robben Island opposite its headland. As a consequence, the bathymetry defines an ellipsoidal basin which was postulated to potentially resonate in the form of long-period standing waves (seiches). One aim of this study, therefore, was to investigate whether any evidence for such resonant oscillations could be detected in the geomorphology and sediment distribution patterns. Indeed, the ellipsoidal shape of the basin can be framed by two converging log-spirals with their centres located opposite each other, one off Robben Island and the other on the Cape Town side of the bay. The so-called apex line, which divides the two spirals into equal parts is aligned SW–NE, i.e. more or less parallel to the direction of ocean wave propagation. The distribution patterns of all sedimentary parameters were found to be characterised by a strikingly similar trend to either side of the apex line. This supports the hypothesis that the basin of Table Bay appears to resonate in the form of a mode 1 standing wave, with the node positioned above the apex line in the centre of the bay. The maximum period of such a standing wave was calculated to be around 37 min. The study demonstrates that large-scale sediment distribution patterns can reveal the existence of specific hydrodynamic processes in coastal embayments. It is recommended that this phenomenon be investigated in greater detail aimed at verifying the existence of resonant oscillations in Table Bay and, in the event, at establishing its precise nature and trigger mechanism.
    Description: Council for Geoscience and CSIR South Africa
    Description: Senckenberg Gesellschaft für Naturforschung (SGN) (3507)
    Keywords: ddc:551.46 ; Oceanography ; South Africa ; Table Bay ; ellipsoidal shape ; sediment distribution ; seiches
    Language: English
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    Hurricane Matthew in 2100: effects of extreme sea level rise scenarios on a highly valued coastal area (Palm Beach, FL, USA) (2021)
    Springer Berlin Heidelberg
    Details
    Publication Date: 2023-07-27
    Description: Sea-level rise represents a severe hazard for populations living within low-elevation coastal zones and is already largely affecting coastal communities worldwide. As sea level continues to rise following unabated greenhouse gas emissions, the exposure of coastal communities to inundation and erosion will increase exponentially. These impacts will be further magnified under extreme storm conditions. In this paper, we focus on one of the most valuable coastal real estate markets globally (Palm Beach, FL). We use XBeach, an open-source hydro and morphodynamic model, to assess the impact of a major tropical cyclone (Hurricane Matthew, 2016) under three different sea-level scenarios. The first scenario (modern sea level) serves as a baseline against which other model runs are evaluated. The other two runs use different 2100 sea-level projections, localized to the study site: (i) IPCC RCP 8.5 (0.83 m by 2100) and (ii) same as (i), but including enhanced Antarctic ice loss (1.62 m by 2100). Our results show that the effective doubling of future sea level under heightened Antarctic ice loss amplifies flow velocity and wave height, leading to a 46% increase in eroded beach volume and the overtopping of coastal protection structures. This further exacerbates the vulnerability of coastal properties on the island, leading to significant increases in parcel inundation.
    Description: Universität Bremen (1013)
    Description: https://github.com/pboyden/Palm_Beach_XBeach
    Keywords: ddc:551.46 ; Oceanography ; tropical cyclones ; coastal areas ; sea level scenarios ; hydrodynamic modeling ; morphodynamic modeling
    Language: English
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  • 60
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    Determination of Fracture Toughness of Mode I Fractures from Three-Point Bending Tests at Elevated Confining Pressures (2021)
    Springer Vienna
    Details
    Publication Date: 2023-07-27
    Description: Fracture toughness is one of the key parameters for the characterization of brittle rock fracturing. Yet, constraints on it mainly rest on measurements performed at ambient pressure, although rock fracturing frequently occurs at elevated pressures even in geotechnical applications. To address the lack of a generally accepted evaluation procedure for tests at elevated pressure we explored the conditions for initiation and propagation of mode I fractures in samples subjected to bending at elevated pressure by numerical modeling and analytical considerations of the involved angular moments. We derived an evaluation procedure and applied it to experimental observations for specimens with either a chevron or a single-edge notch of four different rocks (a granite, a limestone, a marble and a sandstone) subjected to three-point bending at confining pressures up to 30 MPa. Two sealing methods were considered. Specimens were either varnished or jacketed by a rubber tube, differing in whether pressure is allowed to build up inside the pre-fabricated notch or not, respectively. Irrespective of notch geometry and sealing method, the determined toughness values increase significantly with confining pressure. The apparent toughness determined for jacketed specimens is, however, larger than that for varnished specimens, for which toughness seems to reach a plateau with increasing pressure. The similarity of the pressure dependence of the toughness determined for varnished, i.e., uniformly pressurized, samples with that of other physical properties suggests that it is controlled by the closure of pre-existing micro-cracks; the absence of pressure dependence beyond some tens of MPa suggests that non-linearity effects may not be as severe at depths beyond a few kilometers as previously discussed. Our study points to the necessity of resolving numerical issues associated with compressed fractures and of further improving experimental facilities for the determination of fracture toughness at elevated pressure.
    Description: German Federal Ministry of Economy
    Description: Deutsche Forschungsgemeinschaft http://dx.doi.org/10.13039/501100001659
    Description: Ruhr-Universität Bochum (1007)
    Keywords: ddc:550.78 ; Toughness ; Confining pressure ; Three-point bending tests ; Chevron-edge notch
    Language: English
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    Damage Evolution of Coal with Inclusions Under Triaxial Compression (2021)
    Springer Vienna
    Details
    Publication Date: 2023-07-27
    Description: Along with the advance of the working face, coal experiences different loading stages. Laboratory tests and numerical simulations of fracture and damage evolution aim to better understand the structural stability of coal layers. Three-dimensional lab tests are performed and coal samples are reconstructed using X-ray computer tomography (CT) technique to get detailed information about damage and deformation state. Three-dimensional discrete element method (DEM)-based numerical models are generated. All models are calibrated against the results obtained from uniaxial compressive strength (UCS) tests and triaxial compression (TRX) tests performed in the laboratory. A new approach to simulate triaxial compression tests is established in this work with significant improved handling of the confinement to get realistic simulation results. Triaxial tests are simulated in 3D with the particle-based code PFC3D using a newly developed flexible wall (FW) approach. This new numerical simulation approach is validated by comparison with laboratory tests on coal samples. This approach involves an updating of the applied force on each wall element based on the flexible nature of a rubber sleeve. With the new FW approach, the influence of the composition (matrix and inclusions) of the samples on the peak strength is verified. Force chain development and crack distributions are also affected by the spatial distribution of inclusions inside the sample. Fractures propagate through the samples easily at low confining pressures. On the contrary, at high confining pressure, only a few main fractures are generated with orientation towards the side surfaces. The evolution of the internal fracture network is investigated. The development of microcracks is quantified by considering loading, confinement, and structural character of the rock samples. The majority of fractures are initiated at the boundary between matrix and inclusions, and propagate along their boundaries. The internal structure, especially the distribution of inclusions has significant influence on strength, deformation, and damage pattern.
    Description: Technische Universität Bergakademie Freiberg (3135)
    Keywords: ddc:550.78 ; Coal sample ; X-ray CT ; Sample reconstruction ; Triaxial compression test ; Discrete element modeling ; Flexible wall approach
    Language: English
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    Interannual Changes in Tidal Conversion Modulate M2 Amplitudes in the Gulf of Maine (2022)
    Details
    Publication Date: 2023-07-27
    Description: 〈title xmlns:mml="http://www.w3.org/1998/Math/MathML"〉Abstract〈/title〉〈p xmlns:mml="http://www.w3.org/1998/Math/MathML" xml:lang="en"〉The Gulf of Maine's lunar semidiurnal (M〈sub〉2〈/sub〉) ocean tide exhibits spatially coherent amplitude changes of ∼1–3 cm on interannual time scales, though no causative mechanism has been identified. Here we show, using a specially designed numerical modeling framework, that stratification changes account for 32%–48% (Pearson coefficient 0.58–0.69) of the observed M〈sub〉2〈/sub〉 variability at tide gauges from 1994 to 2019. Masking experiments and energy diagnoses reveal that the modeled variability is primarily driven by fluctuations in barotropic‐to‐baroclinic energy conversion on the continental slope south of the gulf's mouth, with a 1‐cm amplitude increase at Boston corresponding to a ∼7% (0.30 GW) drop in the area‐integrated conversion rate. Evidence is given for the same process to have caused the decade‐long M〈sub〉2〈/sub〉 amplitude decrease in the Gulf of Maine beginning in 1980/81. The study has implications for nuisance flooding predictions and space geodetic analyses seeking highest accuracies.〈/p〉
    Description: Plain Language Summary: The height of the twice‐daily tide at Boston is about 135 cm, but researchers have long noted that this value fluctuates by about 1–3 cm from year to year. Here we show that the annual tidal height changes—seen in fact throughout the Gulf of Maine—are closely linked to how seawater density is distributed three‐dimensionally in the region. In particular, as tidal currents enter the gulf over steep underwater topography, the vertical distribution of density determines how much of the incoming wave energy is scattered back as internal tides into the deeper Northwest Atlantic. In years where this conversion of wave energy drops by 7% from its nominal value of 4 Gigawatt, the surface tide at Boston typically increases by 1 cm. Climate‐induced changes in ocean temperature and density may strengthen or weaken the conversion effect and thus slightly alter the role of tides in coastal flood events.〈/p〉
    Description: Key Points〈: We propagate the M〈sub〉2〈/sub〉 tide through realistic, annually varying density structures (1993–2019) in a regional Gulf of Maine model. Stratification changes explain 32%–48% of the observed, cm‐level M〈sub〉2〈/sub〉 amplitude variability at coastal tide gauges from 1994 to 2019. Modeled M〈sub〉2〈/sub〉 changes mainly reflect fluctuations in the barotropic‐baroclinic energy conversion rate on the New England continental slope.
    Description: Austrian Science Fund http://dx.doi.org/10.13039/501100002428
    Description: Deutsche Forschungsgemeinschaft http://dx.doi.org/10.13039/501100001659
    Description: https://www.gesla.org/
    Description: https://www.tpxo.net/global/tpxo9-atlas
    Description: https://doi.pangaea.de/10.1594/PANGAEA.856844
    Description: https://marine.copernicus.eu/access-data
    Description: https://www.ncei.noaa.gov/products/northwest-atlantic-regional-climatology
    Keywords: ddc:551.46 ; ocean tides ; tidal conversion ; Gulf of Maine ; nuisance flooding
    Language: English
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    The composition of subduction zone fluids and the origin of the trace element enrichment in arc magmas (2021)
    Springer Berlin Heidelberg
    Details
    Publication Date: 2023-07-21
    Description: The partitioning of major and trace elements between eclogite and aqueous fluids with variable salinity was studied at 700–800 °C and 4–6 GPa in piston cylinder and multi anvil experiments. Fluid compositions were determined using the diamond trap technique combined with laser ablation ICP-MS measurements in the frozen state. In addition to NaCl, SiO2 is the main solute in the fluids. The fluid/eclogite partition coefficients of the large ion lithophile elements (LILE), such as Rb, Cs, Sr, and Ba as well as those of the light rare earths (LREE), of Pb, and of U increase by up to three orders of magnitude with salinity. These elements will therefore be efficiently transported by saline fluids. On the other hand, typical high field strength elements, such as Ti, Nb, and Ta, are not mobilized even at high salinities. Increasing temperature and pressure gradually increases the partitioning into the fluid. In particular, Th is mobilized by silica-rich fluids at 6 GPa already at low salinities. We show that we can fully reproduce the trace element enrichment pattern of primitive arc basalts by adding a few percent of saline fluid (with 5–10 wt% Cl) released from the basaltic slab to the zone of melting in the mantle wedge. Assuming 2 wt% of rutile in the eclogite equilibrated with the saline fluid produces a negative Nb Ta anomaly that is larger than in most primitive arc basalts. Therefore, we conclude that the rutile fraction in the subducted eclogite below most arcs is likely 〈 1 wt%. In fact, saline fluids would even produce a noticeable negative Nb Ta anomaly without any rutile in the eclogite residue. Metasomatism by sediment melts alone, on the other hand, is unable to produce the enrichment pattern seen in arc basalts. We, therefore, conclude that at least for primitive arc basalts, the release of hydrous fluids from the basaltic part of the subducted slab is the trigger for melting and the main agent of trace element enrichment. The contribution of sediment melts to the petrogenesis of these magmas is likely negligible. In the supplementary material, we provide a “Subduction Calculator” in Excel format, which allows the calculation of the trace element abundance pattern in primitive arc basalts as function of fluid salinity, the amount of fluid released from the basaltic part of the subducted slab, the fluid fraction added to the source, and the degree of melting.
    Description: DFG
    Description: Universität Bayreuth (3145)
    Keywords: ddc:551.9 ; Subduction zone fluids ; Fluid/eclogite partitioning ; Arc magmas ; Salinity ; Trace elements ; Nb Ta anomaly ; Primitive arc basalts
    Language: English
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    Temperature and Salinity Anomalies in the Sea Surface Microlayer of the South Pacific During Precipitation Events (2023)
    Details
    Publication Date: 2023-07-21
    Description: 〈title xmlns:mml="http://www.w3.org/1998/Math/MathML"〉Abstract〈/title〉〈p xmlns:mml="http://www.w3.org/1998/Math/MathML" xml:lang="en"〉We present the results of salinity (ΔS) and temperature (ΔT) anomalies in the sea surface microlayer (SML) in relation to the underlying mixed bulk water (bulk). Several light to moderate rain events were recorded in the southern Pacific near Fiji using our remotely operated catamaran. Precipitation and evaporation drive freshwater fluxes across the sea surface (i.e., the SML) and are the most essential processes of the hydrologic cycle. However, measurements of the SML during precipitation are rare, but necessary to fully understand freshwater exchange at the air‐sea interface. Here we show that freshwater can mix rapidly with the bulk water through wind‐induced mixing, as ΔS and ΔT show a clear dependence on wind speed. At high wind speeds (5.1–11.6 m s〈sup〉−1〈/sup〉), anomalies approach zero (ΔS = −0.02 ± 0.49 g kg〈sup〉−1〈/sup〉, ΔT = −0.09 ± 0.46°C) but can reach ΔS = 1.00 ± 0.20 g kg〈sup〉−1〈/sup〉 and ΔT = −0.37 ± 0.09°C at lower wind speeds (0–2 m s〈sup〉−1〈/sup〉). We find shallow freshwater lenses and fronts, likely caused by past rainfall, with ΔS and ΔT of up to −1.11 g kg〈sup〉−1〈/sup〉 and 1.77°C, respectively. Our observations suggest that freshwater lenses can be very shallow (〈1 m depth) and missed by conventional measurements. In addition, the temperature and salinity in the SML respond to freshwater fluxes instantaneously. It highlights the role of the SML in a mechanistic understanding of the fate of freshwater over the ocean and, therefore, the global hydrologic cycle.〈/p〉
    Description: Plain Language Summary: Rain and evaporation are the most important processes in the global water cycle, causing either the supply to or the removal of freshwater from the upper ocean, thereby changing the salinity of the sea surface. Evaporation also removes heat and lowers the temperature on the ocean surface. We used the measurements of sea surface microlayer (SML) salinity and temperature as key indicators to study hydrologic cycle processes during our cruise with the RV Falkor in the South Pacific and found that freshwater mixes rapidly with the underlying bulk water during strong winds (5.1–11.6 m s〈sup〉−1〈/sup〉). We also detected shallow freshwater lenses and fronts, most likely caused by past rainfall, with ΔS and ΔT of up to −1.11 g kg〈sup〉−1〈/sup〉 and 1.77°C, respectively. Our observations suggest that freshwater lenses can occur at the sea surface and that the SML respond to freshwater fluxes instantaneously. It highlights the role of the SML for future studies of the global hydrologic cycle.〈/p〉
    Description: Key Points: Small scale air‐sea interactions (freshwater fluxes) during precipitation were investigated in the southern Pacific. Temperature and salinity anomalies occur with a high spatial variability.Measurements with remote controlled catamaran revealed shallow freshwater lenses, which were not detectable with ship based measurements.
    Description: German Research Foundation
    Description: https://doi.org/10.7284/908805
    Description: https://www.rvdata.us/search/cruise/FK191120
    Description: https://bec.icm.csic.es/
    Description: https://smos-diss.eo.esa.int/
    Description: https://doi.org/10.48670/moi-00165
    Description: https://disc.gsfc.nasa.gov/datasets/GPM_3IMERGHH_06/summary
    Keywords: ddc:551.46 ; salinity and temperature anomalies ; sea surface microlayer ; freshwater fluxes ; global hydrologic cycle ; research catamaran
    Language: English
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    Stable Carbon Isotope Signature of Methane Released From Phytoplankton (2023)
    Details
    Publication Date: 2023-07-26
    Description: 〈title xmlns:mml="http://www.w3.org/1998/Math/MathML"〉Abstract〈/title〉〈p xmlns:mml="http://www.w3.org/1998/Math/MathML" xml:lang="en"〉Aquatic ecosystems play an important role in global methane cycling and many field studies have reported methane supersaturation in the oxic surface mixed layer (SML) of the ocean and in the epilimnion of lakes. The origin of methane formed under oxic condition is hotly debated and several pathways have recently been offered to explain the “methane paradox.” In this context, stable isotope measurements have been applied to constrain methane sources in supersaturated oxygenated waters. Here we present stable carbon isotope signatures for six widespread marine phytoplankton species, three haptophyte algae and three cyanobacteria, incubated under laboratory conditions. The observed isotopic patterns implicate that methane formed by phytoplankton might be clearly distinguished from methane produced by methanogenic archaea. Comparing results from phytoplankton experiments with isotopic data from field measurements, suggests that algal and cyanobacterial populations may contribute substantially to methane formation observed in the SML of oceans and lakes.〈/p〉
    Description: Plain Language Summary: Methane plays an important role in atmospheric chemistry and physics as it contributes to global warming and to the destruction of ozone in the stratosphere. Knowing the sources and sinks of methane in the environment is a prerequisite for understanding the global atmospheric methane cycle but also to better predict future climate change. Measurements of the stable carbon isotope composition of carbon—the ratio between the heavy and light stable isotope of carbon—help to identify methane sources in the environment and to distinguish them from other formation processes. We identified the carbon isotope fingerprint of methane released from phytoplankton including algal and cyanobacterial species. The observed isotope signature improves our understanding of methane cycling in the surface layers of aquatic environments helping us to better estimate methane emissions to the atmosphere.〈/p〉
    Description: Key Points: Stable carbon isotope values of methane emitted from six phytoplankton cultures incubated in the laboratory. Isotope fractionation between methane source signature and biomass of widespread algal and cyanobacterial species. Isotopic patterns of methane released by phytoplankton may be clearly distinguished from methane formed by methanogenic archaea.
    Description: Deutsche Forschungsgemeinschaft http://dx.doi.org/10.13039/501100001659
    Description: Spanish Ministry of Universities
    Description: https://doi.org/10.11588/data/YYLEKU
    Keywords: ddc:551.9 ; methane ; stable isotopes ; phytoplankton ; algae ; cyanobacteria ; methane paradox
    Language: English
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    Cone penetration tests in dry and saturated Ticino sand (2021)
    Springer Berlin Heidelberg
    Details
    Publication Date: 2023-07-29
    Description: It is commonly assumed that dry and saturated sands exhibit similar cone resistance–relative density relationships. Some studies pointed out that partial saturation and calcareous sands with considerable fines content are potential factors affecting these relationships. However, there is experimental evidence in Shaqour Bull Eng Geol Environ 66:59-70, (2006) that clean uncemented quartz sand may exhibit lower cone resistance in saturated conditions. The present study aims on contributing towards better understanding the effect of water saturation on cone resistance in sand. For this purpose, Ticino sand samples were prepared dry and saturated in a calibration chamber and cone penetration tests were performed over a wide range of relative densities and at two consolidation stresses. Overall, it was observed that dry and saturated samples exhibited similar cone resistances. Only slightly higher cone resistances were observed for dry samples at the lower consolidation stress. Two anomalous samples, which were tested dry at medium relative density, were found to exhibit way higher cone resistances than expected from published cone resistance–relative density relationships. The Young's modulus was observed to be proportional to cone resistance and independent of whether a sample was tested dry or saturated, being therefore considered as more robust soil property for cone resistance relationships.
    Description: Bundesministerium für Wirtschaft und Energie http://dx.doi.org/10.13039/501100006360
    Keywords: ddc:550.78 ; Cone penetration test ; Water saturation ; Dry sand ; Calibration chamber ; Relative density ; Young’s modulus
    Language: English
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    Determination of Cu, Zn, Ga, Ag, Cd, In, Sn and Tl in Geological Reference Materials and Chondrites by Isotope Dilution ICP-MS (2020)
    Details
    Publication Date: 2022-11-28
    Description: Mass fractions of Cu, Zn, Ga, Ag, Cd, In, Sn and Tl were determined via isotope dilution quadrupole ICP-MS in twenty-one geological reference materials (RMs) and the carbonaceous chondrites Orgueil (CI1), Murchison (CM2) and Allende (CV3). The RMs comprise basaltic/mafic (BCR-2, BE-N, BHVO-1, BHVO-2, BIR-1, BRP-1, JB-2, OKUM, W-2, WS-E), intermediate/felsic (AGV-2, G-2, JA-2, RGM-1), ultramafic (DTS-2b, MUH-1, PCC-1, UB-N) and sedimentary (MAG-1, OU-6) rocks. Pressure digestion was applied for nonbasaltic samples to ensure effective sample digestion. For basaltic RMs, hot plate digestion was found to be sufficient for a quantitative recovery of the target elements. To minimise interferences and increase ion beam intensities during isotope ratio analyses by ICP-MS, separation of the target elements was carried out from single sample aliquots using a novel anion exchange procedure. The intermediate precision (2s) estimated from two to four replicate analyses was usually 〈 4% and results are in agreement with literature data, where available. Especially for Ag and Tl, the intermediate precision was compromised, likely due to low ion beam intensities and, hence, higher background and blank contributions. For ultramafic RMs, nugget effects and incomplete digestion might compromise the intermediate precision. Results for the carbonaceous chondrites Orgueil (CI1), Murchison (CM2) and Allende (CV3) agree well with previously reported data.
    Keywords: ddc:551.9 ; isotope dilution ; chalcophile elements ; geological reference materials ; chondrites ; Q-ICP-MS
    Language: English
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    Chemical Geodynamics Insights From a Machine Learning Approach (2022)
    Details
    Publication Date: 2022-12-07
    Description: The radiogenic isotope heterogeneity of oceanic basalts is often assessed using 2D isotope ratio diagrams. But because the underlying data are at least six dimensional (87Sr/86Sr, 143Nd/144Nd, 176Hf/177Hf, and 208,207,206Pb/204Pb), it is important to examine isotopic affinities in multi‐dimensional data space. Here, we apply t‐distributed stochastic neighbor embedding (t‐SNE), a multi‐variate statistical data analysis technique, to a recent compilation of radiogenic isotope data of mid ocean ridge (MORB) and ocean island basalts (OIB). The t‐SNE results show that the apparent overlap of MORB‐OIB data trends in 2‐3D isotope ratios diagrams does not exist in multi‐dimensional isotope data space, revealing that there is no discrete “component” that is common to most MORB‐OIB mantle sources on a global scale. Rather, MORB‐OIB sample stochastically distributed small‐scale isotopic heterogeneities. Yet, oceanic basalts with the same isotopic affinity, as identified by t‐SNE, delineate several globally distributed regional domains. In the regional geodynamic context, the isotopic affinity of MORB and OIB is caused by capturing of actively upwelling mantle by adjacent ridges, and thus melting of mantle with similar origin in on, near, and off‐ridge settings. Moreover, within a given isotopic domain, subsidiary upwellings rising from a common deep mantle root often feed OIB volcanism over large surface areas. Overall, the t‐SNE results define a fundamentally new basis for relating isotopic variations in oceanic basalts to mantle geodynamics, and may launch a 21st century era of “chemical geodynamics.”
    Description: Plain Language Summary: The isotopic heterogeneity of basalts erupted at mid ocean ridges (MORB) and ocean islands (OIB) reflects the chemical evolution of Earth's mantle. The visual inspection of various 2D isotope ratio diagrams has fueled a four decade‐long discussion whether basalt heterogeneity reflects melting of only a small number of mantle components, and in particular, whether the apparent overlap of local data trends in global 2D isotope ratio diagrams indicates that melting of a common mantle component contributes to most MORB‐OIB. Here, we use multi‐variate statistical data analysis to show that the apparent overlap of MORB‐OIB data trends in 2D isotope ratio diagrams does not exist in multi‐dimensional isotope data space. Our finding invalidates any inference made for mantle compositional evolution based on the previously proposed existence of a common mantle component, its potential nature or distribution within the mantle. Rather, global MORB‐OIB sample small‐scale isotopic heterogeneities that are distributed stochastically in the Earth's mantle. Yet, MORB‐OIB with the same isotopic affinity, as identified by our multi‐variate data analysis, delineate several globally distributed regional domains. Within the regional geodynamic context, this discovery forms a fundamentally new basis for relating isotopic variations in MORB‐OIB to mantle geodynamics.
    Description: Key Points: Multi‐variate statistical data analysis (t‐distributed stochastic neighbor embedding) identifies global Sr‐Nd‐Hf‐Pb isotopic affinities of oceanic basalts. There is no “common mantle component;” rather, global mid ocean ridge‐ocean island basalts sample stochastically distributed small‐scale isotopic heterogeneities. Globally distributed regional domains of isotopically alike oceanic lavas define a new basis for relating isotopic variations to geodynamics.
    Description: Deutsche Forschungsgemeinschaft http://dx.doi.org/10.13039/501100001659
    Description: Schweizerischer Nationalfonds zur Förderung der Wissenschaftlichen Forschung http://dx.doi.org/10.13039/501100001711
    Description: DAAD, German Academic Exchange Service
    Description: https://doi.org/10.25625/0SVW6S
    Description: https://doi.org/10.25625/BQENGN
    Keywords: ddc:551.9 ; mantle heterogeneity ; MORB ; OIB ; geodynamics ; t‐SNE ; radiogenic isotopes ; machine learning
    Language: English
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    Pore Space Topology Controls Ultrasonic Waveforms in Dry Volcanic Rocks (2022)
    Details
    Publication Date: 2022-12-06
    Description: Pore space controls the mechanical and transport properties of rocks. At the laboratory scale, seismic modeling is usually performed in relatively homogeneous settings, and the influence of the pore space on the recorded wavefields is determined by rock‐fluid interactions. Understanding this influence in dry rocks is instrumental for assessing the impact of pore topology on waves propagating in heterogeneous environments, such as volcanoes. Here, we simulated the propagation of shear waves as a function of pore space parameters in computational models built as proxies for volcanic rocks. The spectral‐element simulations provide results comparable with ultrasonic experiments, and the outcome shows that the size, shape, volume, and location of pores impact amplitudes and phases. These variations intensify in waveform coda after multiple scattering. Our results confirm that pore topology is one of the primary regulators of the propagation of elastic waves in dry rocks regardless of porosity.
    Description: Plain Language Summary: Pores control the non‐elastic behavior and, in general, the petrophysical and mechanical properties of rocks. Such properties are essential to assess potential resources such as aquifers and reservoirs or hazards posed by earthquakes, volcanoes, and constructions. The factors controlling the elasticity of rocks are texture, pore space and the fluids filling the pores. While volcanoes represent a key target for rock characterization, measuring and modeling these factors in volcanic rocks remains challenging due to their intrinsic heterogeneities. In this study, we analyzed how pore space parameters influence the overall elastic properties of rocks by changing one parameter at a time. We created synthetic samples and performed computational simulations that show the individual contribution of the amount, size, location, and shape on waveform phases and amplitudes. The findings demonstrate that we can constrain the pore space in heterogeneous rocks in simple but realistic scenarios. Our results are the first step to provide computationaly‐driven forward models of seismic signals in heterogeneous volcanic media, necessary to predict the responses of volcanic rocks to stress.
    Description: Key Points: Computational modeling quantifies the influence of pore space topology on S‐wave propagation in volcanic rocks. Amount, size and location of pores impact ultrasonic wave propagation in dry rocks independently of porosity. Path effects dominate the waveforms and depend on the location of the pores.
    Description: https://doi.org/10.17632/b5p54xtvv9.3
    Keywords: ddc:550.78 ; volcanic rocks ; pore space topology ; S-wave propagation ; computational modeling
    Language: English
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    Probability Distributions of Radiocarbon in Open Linear Compartmental Systems at Steady‐State (2022)
    Details
    Publication Date: 2022-06-26
    Description: Radiocarbon (14C) is commonly used as a tracer of the carbon cycle to determine how fast carbon moves between different reservoirs such as plants, soils, rivers, or oceans. However such studies mostly emphasize the mean value (as Δ14C) of an unknown probability distribution. We introduce a novel algorithm to compute Δ14C distributions from knowledge of the age distribution of carbon in linear compartmental systems at steady‐state. Our results demonstrate that the shape of the distributions might differ according to the speed of cycling of ecosystem compartments and their connectivity within the system, and might contain multiple peaks and long tails. The distributions are also sensitive to the variations of Δ14C in the atmosphere over time, as influenced by the counteracting anthropogenic effects of fossil‐fuel emissions (14C‐free) and nuclear weapons testing (excess 14C). Lastly, we discuss insights that such distributions can offer for sampling and design of experiments aiming to capture the precise variance of Δ14C values present in the multi‐compartmental ecosystems.
    Description: Plain Language Summary: Radiocarbon (14C) is a radioactive isotope of carbon prominent in environmental sciences for tracing the dynamics of ecosystems, especially as recent changes in atmospheric radiocarbon allow tracking excess 14C created by nuclear weapons testing in the atmosphere on timescales shorter than what can be determined using radioactive decay. For climate change mitigation, a crucial uncertainty is the time carbon captured through photosynthesis spends in ecosystems before being released. For this purpose, radiocarbon can be valuable as a biological tracer; however, it is necessary to accurately link the real age of carbon and its radiocarbon age, as they usually differ. Forests and soils are open systems, connecting components with intrinsically different cycling timescales, so that the mean age comes from an age distribution that is usually unknown. Here, we developed an algorithm to compute the 14C contents for models consisting of multiple interconnected carbon pools. Our approach offers more accurate estimations of the mean 14C content of the system and computations of the distribution of 14C within the system at different points in time. Results obtained from this method can provide additional insights on the dynamics of the carbon cycle in multiple compartments, and can help to better interpret observations.
    Description: Key Points: Probability distributions of radiocarbon in ecosystem compartments can be derived from carbon age distributions. The shape of these distributions vary according to the speed of carbon cycling and the year of observation. Probability distributions of radiocarbon provide insights to study carbon dynamics and to interpret radiocarbon data.
    Description: Bundesministerium für Bildung und Forschung (BMBF) http://dx.doi.org/10.13039/501100002347
    Description: Max‐Planck‐Gesellschaft (MPG) http://dx.doi.org/10.13039/501100004189
    Description: https://doi.org/10.5281/zenodo.6373329
    Keywords: ddc:551.9
    Language: English
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    Multi‐Band Raman Analysis of Radiation Damage in Zircon for Thermochronology: Partial Annealing and Mixed Signals (2022)
    Details
    Publication Date: 2022-06-24
    Description: Four zircon Raman bands were previously calibrated to give consistent estimates of the accumulated self‐irradiation α‐dose in unannealed volcanic samples. Partial annealing of radiation damage produces inconsistent values because of differences in the relative annealing sensitivities. The damage estimates based on the external rotation band (DER) at ∼356 cm−1 and that based on the ν2(SiO4) band (D2) at ∼438 cm−1 are the most and least sensitive to damage annealing. The D2/DER‐ratio thus provides a numerical estimate of the extent of geologic annealing that a zircon sample has experienced. This ratio characterizes the thermal history of a zircon sample but also its state of radiation damage during the course of its geologic history, and thus the manner in which this state influences other thermochronologic methods. Meaningful interpretation of the zircon Raman age requires that the spectra are free of measurement artifacts. The major artifacts result from micrometer‐scale gradients of the damage densities within a zircon grain due to uranium and thorium zoning. The micrometer‐sized sampled volume may span different densities, producing overlapping spectra, causing apparent peak broadening, overestimated damage densities, and zircon Raman ages. The D3/D2‐ratio of the damage densities calculated from the ν3(SiO4) and ν2(SiO4) bands, most and least affected by overlap, is an efficient indicator of a meaningless signal. It reveals overlap in annealed and unannealed samples, because the used bands have similar responses to annealing. Multi‐band Raman maps can be converted to damage‐ratio maps for screening zircon mounts, and selecting spots for thermochronologic investigations.
    Description: Plain Language Summary: Radioactive processes cause damage to the lattice of zircon crystals. This damage can be measured with a Raman instrument. Such measurements are important for methods determining the ages and thermal histories of zircon grains in rocks. Thus, the Raman measurements must be reliable and meaningful. This work proposes tools for detecting effects that hinder the interpretation of zircon Raman data. These effects are mixed signals and loss of damage due to exposure to elevated temperatures in the geologic environment. Zircon Raman spectra have different bands that respond differently to mixed signals and temperature. The ratio of the damage estimates from the least and most temperature‐sensitive bands thus indicates partial annealing. Raman spectra of zoned zircons often straddle areas with different lattice damage. Their overlapping signals cause artificial band broadening, and a damage overestimation. The ratio of the damage estimated from the least and the most affected bands identifies mixed signals and allows to reject unsuitable samples. The damage ratios can also be plotted in maps for damage screening and for selecting optimal spots for measurements.
    Description: Key Points: Annealing and inhomogeneous damage are two main factors hindering radiation‐damage estimation for zircon Raman dating. Comparison of internal and external Raman bandwidths allows to detect partial annealing of radiation damage in zircon. Comparison of internal Raman bandwidths allows to detect artifactual broadening in zoned zircon.
    Description: Studienstiftung des Deutschen Volkes (Studienstiftung) http://dx.doi.org/10.13039/501100004350
    Description: http://dx.doi.org/10.25532/OPARA-155
    Keywords: ddc:549 ; ddc:551.9
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    Electrochemical Properties of Peat Particulate Organic Matter on a Global Scale: Relation to Peat Chemistry and Degree of Decomposition (2022)
    Details
    Publication Date: 2022-06-22
    Description: Methane production in peatlands is controlled by the availability of electron acceptors for microbial respiration, including peat dissolved organic matter (DOM) and particulate organic matter (POM). Despite the much larger mass of POM in peat, knowledge on the ranges of its electron transfer capacities—electron accepting capacity (EAC), and electron donating capacity (EDC)—is scarce in comparison to DOM and humic and fulvic acids. Moreover, it is unclear how peat POM chemistry and decomposition relate to its EAC and EDC. To address these knowledge gaps, we compiled peat samples with varying carbon contents from mid to high latitude peatlands and analyzed their EACPOM and EDCPOM, element ratios, decomposition indicators, and relative amounts of molecular structures as derived from mid infrared spectra. Peat EACPOM and EDCPOM are smaller (per gram carbon) than EAC and EDC of DOM and terrestrial and aquatic humic and fulvic acids and are highly variable within and between sites. Both are small in highly decomposed peat, unless it has larger amounts of quinones and phenols. Element ratio‐based models failed to predict EACPOM and EDCPOM, while mid infrared spectra‐based models can predict peat EACPOM to a large extent, but not EDCPOM. We suggest a conceptual model that describes how vegetation chemistry and decomposition control polymeric phenol and quinone contents as drivers of peat EDCPOM and EACPOM. The conceptual model implies that we need mechanistic models or spatially resolved measurements to understand the variability in peat EDCPOM and EACPOM and thus its role in controlling methane formation.
    Description: Plain Language Summary: Peatlands accumulated large amounts of carbon via photosynthesis and slow decomposition of senesced plant material. Microorganisms within the peat form methane. For this reason, peatlands are important global sources of the greenhouse gas methane and therefore can contribute to climate change. In order to produce methane, the microorganisms have to transfer electrons between compounds in respiration processes. Only recently, it has been found that the peat itself can reversibly transfer electrons and that its capacities to reversibly accept electron accepting capacity (EAC) and reversibly donate electron donating capacity (EDC) electrons are large. We investigated which conditions favor large or small EAC and EDC of peat so that we can better explain methane formation. We argue that vegetation and decomposition control the amount of phenols and quinones—molecules in the peat that presumably are responsible for most of the peat's EAC and EDC. The EAC and EDC probably are largest for peat formed from vegetation rich in quinones and phenols, such as shrubs, and smaller for other vegetation types, for example, certain mosses. Intense decomposition may reduce both the EAC and EDC.
    Description: Key Points: Peat particulate organic matter electron accepting and donating capacities per grams of carbon are smaller than for humic and fulvic acids. Both capacities are small in highly decomposed peat, unless it has larger amounts of quinones and phenols. We explain these patterns with parent vegetation chemistry and conditions during decomposition.
    Description: Deutsche Forschungsgemeinschaft (DFG) http://dx.doi.org/10.13039/501100001659
    Description: CAS | Youth Innovation Promotion Association (YIPA) http://dx.doi.org/10.13039/501100012492
    Description: https://github.com/henningte/redoxpeat
    Keywords: ddc:551.9
    Language: English
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    Thermolab: A Thermodynamics Laboratory for Nonlinear Transport Processes in Open Systems (2022)
    Details
    Publication Date: 2022-06-28
    Description: We developed a numerical thermodynamics laboratory called “Thermolab” to study the effects of the thermodynamic behavior of nonideal solution models on reactive transport processes in open systems. The equations of the state of internally consistent thermodynamic data sets are implemented in MATLAB functions and form the basis for calculating Gibbs energy. A linear algebraic approach is used in Thermolab to compute Gibbs energy of mixing for multicomponent phases to study the impact of the nonideality of solution models on transport processes. The Gibbs energies are benchmarked with experimental data, phase diagrams, and other thermodynamic software. Constrained Gibbs minimization is exemplified with MATLAB codes and iterative refinement of composition of mixtures may be used to increase precision and accuracy. All needed transport variables such as densities, phase compositions, and chemical potentials are obtained from Gibbs energy of the stable phases after the minimization in Thermolab. We demonstrate the use of precomputed local equilibrium data obtained with Thermolab in reactive transport models. In reactive fluid flow the shape and the velocity of the reaction front vary depending on the nonlinearity of the partitioning of a component in fluid and solid. We argue that nonideality of solution models has to be taken into account and further explored in reactive transport models. Thermolab Gibbs energies can be used in Cahn‐Hilliard models for nonlinear diffusion and phase growth. This presents a transient process toward equilibrium and avoids computational problems arising during precomputing of equilibrium data.
    Description: Plain Language Summary: The behavior of Earth materials, rocks, minerals, melts, fluids, and gases is important to predict physical processes in the Earth with computer models. The purpose of this is to study how the changes of variables such as fluid and solid composition influence the diffusion, fluid flow, and reaction in rocks. Here, we present a set of computer codes, called Thermolab, to calculate important physical properties such as density and chemical composition of solids, fluids, and melts in chemical equilibrium. The calculations are based on the Gibbs energy that exists for every material. We use computer codes, written in MATLAB/OCTAVE language, to show how this Gibbs energy is calculated and used to compute chemical equilibrium and find the physical properties such as density and chemical composition. We discuss techniques for accurate calculation of chemical equilibrium and physical properties in real rocks. Finally, we use Thermolab to formulate a computer model of fluids reacting with rocks. We find that chemical composition of the fluid and rock strongly affects the speed and shape of the boundary between reacted and unreacted rock. Thermolab can be used in phase growth models to investigate the way in which rocks develop toward equilibrium.
    Description: Key Points: Thermolab: a set of MATLAB codes is presented to perform equilibrium and nonequilibrium thermodynamic calculations. Local thermodynamic equilibrium is used to study effects of nonideality of solution models on nonlinear transport processes. Nonlinear diffusion processes are investigated with Thermolab providing a transient natural physical process toward equilibrium.
    Description: Deutsche Forschungsgemeinschaft (DFG) http://dx.doi.org/10.13039/501100001659
    Description: Russian Ministry of Science and Higher Education
    Description: https://hansjcv.github.io/Thermolab/
    Description: https://doi.org/10.5281/zenodo.6383253
    Keywords: ddc:551.9 ; ddc:541.36
    Language: English
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    Toward Reconciling Radiocarbon Production Rates With Carbon Cycle Changes of the Last 55,000 Years (2022)
    Details
    Publication Date: 2022-06-28
    Description: Since it is currently not understood how changes in 14C production rate (Q), and in the carbon cycle, can be combined to explain the reconstructed atmospheric Δ14C record, we discuss possible reasons for this knowledge gap. Reviewing the literature, we exclude that changes in the content of atoms in the atmosphere, which produce cosmogenic 14C after being hit by galactic cosmic rays, might be responsible for parts of the observed differences. When combining Q with carbon cycle changes, one needs to understand the changes in the atmospheric 14C inventory, which are partially counterintuitive. For example, during the Last Glacial Maximum, Δ14C was ∼400‰ higher compared with preindustrial times, but the 14C inventory was 10% smaller. Some pronounced changes in atmospheric Δ14C do not correspond to any significant changes in the atmospheric 14C inventory, since CO2 was changing simultaneously. Using two conceptually different models (BICYCLE‐SE and LSG‐OGCM), we derive hypothetical Qs by forcing the models with identical atmospheric CO2 and Δ14C data. Results are compared with the most recent data‐based estimates of Q derived from cosmogenic isotopes. Millennial‐scale climate change connected to the bipolar seesaw is missing in the applied models, which might explain some, but probably not all, of the apparent model‐data disagreement in Q. Furthermore, Q based on either data from marine sediments or ice cores contains offsets, suggesting an interpretation deficit in the current data‐based approaches.
    Description: Key Points: No important change found in the level of precursor material, which produces cosmogenic radiocarbon after being hit by galactic cosmic rays. Transient changes in the bipolar seesaw are needed in applied carbon cycle models to improve interpretation of the radiocarbon cycle. Sediment core‐ and ice core‐based radiocarbon production rates differ systematically, suggesting missing processes.
    Description: Bundesministerium für Bildung und Forschung (BMBF) http://dx.doi.org/10.13039/501100002347
    Description: Swedish Research Concil
    Description: Helmholtz Association (亥姆霍兹联合会致力) http://dx.doi.org/10.13039/501100009318
    Description: https://doi.org/10.1594/PANGAEA.871273
    Description: https://www.ncdc.noaa.gov/paleo-search/study/31772
    Description: https://doi.org/10.1594/PANGAEA.914500
    Description: https://www.iceandclimate.nbi.ku.dk/data/
    Description: https://doi.org/10.1594/PANGAEA.932965
    Keywords: ddc:551.9
    Language: English
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    Precipitation and Lake Water Evaporation Recorded by Terrestrial and Aquatic n‐Alkane δ2H Isotopes in Lake Khar Nuur, Mongolia (2022)
    Details
    Publication Date: 2022-06-28
    Description: The compound‐specific hydrogen isotopic composition (δ2H) of n‐alkanes is a valuable proxy to investigate hydrological conditions in lake sediments. While terrestrial n‐alkanes reflect the isotopic signal of the local precipitation, aquatic n‐alkanes incorporate the isotopic signal of the lake's water, which can be strongly modulated by evaporative enrichment. So far, the spatial distribution of the terrestrial and aquatic δ2H signal within lakes have not systematically been investigated. Here, we present compound‐specific δ2H results of terrestrial (δ2HC31) and aquatic (δ2HC23) n‐alkanes of surface sediment samples from Lake Khar Nuur, a semi‐arid and high‐altitude lake in the Mongolian Altai, and additionally investigate the δ2H signal of topsoils from the catchment. Our results show that the majority of the n‐alkane δ2H values from the catchment topsoils correspond well with modeled local growing season precipitation (JJAS). However, few samples in the northern catchment show more positive δ2H values possibly due to increased evapo(transpi)ration by southward exposition and shallower soils there. The only small variability of δ2HC31 in the surface sediments is in the range of most topsoils δ2H from the catchment, and thus, well reflects local growing season precipitation. δ2HC23 in surface sediment samples from the central and deepest parts of the lake, that is, the lake's sediment accumulation zones, shows distinctly more positive δ2HC23 values due to evaporative lake water enrichment. Consequently, Δaq‐terr, which is the isotopic offset between δ2HC23 and δ2HC31, indicates distinct lake water enrichment in the lake's accumulation zones and is a valuable proxy to investigate past hydrological changes.
    Description: Key Points: The hydrogen isotopic composition of terrestrial C31 n‐alkanes reflects the local growing season precipitation at Lake Khar Nuur. Aquatic C23 n‐alkanes incorporate the isotopic signal of the lake's water, which is strongly modulated by evaporative enrichment. The isotopic offset between C23 and C31 is a valuable proxy for evaporation in the lake and past hydrological changes in the catchment.
    Description: https://doi.pangaea.de/10.1594/PANGAEA.940115
    Keywords: ddc:551.9
    Language: English
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    Formation of fused aggregates under long‐term microgravity conditions aboard the ISS with implications for early solar system particle aggregation (2022)
    Koch, Tamara E. ; Spahr, Dominik ; Tkalcec, Beverley J. ; [et al.]
    Details
    Publication Date: 2022-10-13
    Description: In order to gain further insights into early solar system aggregation processes, we carried out an experiment on board the International Space Station, which allowed us to study the behavior of dust particles exposed to electric arc discharges under long‐term microgravity. The experiment led to the formation of robust, elongated, fluffy aggregates, which were studied by scanning electron microscopy, electron backscatter diffraction, and synchrotron micro‐computed tomography. The morphologies of these aggregates strongly resemble the typical shapes of fractal fluffy‐type calcium‐aluminum‐rich inclusions (CAIs). We conclude that a small amount of melting could have supplied the required stability for such fractal structures to have survived transportation and aggregation to and compaction within planetesimals. Other aggregates produced in our experiment have a massy morphology and contain relict grains, likely resulting from the collision of grains with different degrees of melting, also observed in some natural CAIs. Some particles are surrounded by igneous rims, which remind in thickness and crystal orientation of Wark–Lovering rims; another aggregate shows similarities to disk‐shaped CAIs. These results imply that a (flash‐)heating event with subsequent aggregation could have been involved in the formation of different morphological CAI characteristics.
    Description: BIOVIA
    Description: Nordlicht GmbH
    Description: Deutsche Forschungsgemeinschaft http://dx.doi.org/10.13039/501100001659
    Description: Bundesministerium für Wirtschaft und Energie http://dx.doi.org/10.13039/501100006360
    Description: NanoRacks LLC
    Description: Dr. Rolf M. Schwiete Stiftung http://dx.doi.org/10.13039/501100020027
    Description: Deutsches Zentrum für Luft‐ und Raumfahrt http://dx.doi.org/10.13039/501100002946
    Description: DreamUp
    Description: Carl Zeiss Meditec AG http://dx.doi.org/10.13039/501100002806
    Keywords: ddc:550.78
    Language: English
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    Microbially promoted calcite precipitation in the pelagic redoxcline: Elucidating the formation of the turbid layer (2022)
    Details
    Publication Date: 2022-10-12
    Description: Large bell‐shaped calcite formations called “Hells Bells” were discovered underwater in the stratified cenote El Zapote on the Yucatán Peninsula, Mexico. Together with these extraordinary speleothems, divers found a white, cloudy turbid layer into which some Hells Bells partially extend. Here, we address the central question if the formation of the turbid layer could be based on microbial activity, more specifically, on microbially induced calcite precipitation. Metagenomic and metatranscriptomic profiling of the microbial community in the turbid layer, which overlaps with the pelagic redoxcline in the cenote, revealed chemolithoautotrophic Hydrogenophilales and unclassified β‐Proteobacteria as the metabolic key players. Bioinformatic and hydrogeochemical data suggest chemolithoautotrophic oxidation of sulfide to zero‐valent sulfur catalyzed by denitrifying organisms due to oxygen deficiency. Incomplete sulfide oxidation via nitrate reduction and chemolithoautotrophy are both proton‐consuming processes, which increase the pH in the redoxcline favoring authigenic calcite precipitation and may contribute to Hells Bells growth. The observed mechanism of microbially induced calcite precipitation is potentially applicable to many other stagnant sulfate‐rich water bodies.
    Description: Deutsche Forschungsgemeinschaft http://dx.doi.org/10.13039/501100001659
    Description: CONACYT‐FONCICYT‐DADC
    Description: https://doi.org/10.11588/data/TMYLWS
    Description: https://doi.org/10.11588/data/GYLDH5
    Keywords: ddc:551.9
    Language: English
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    Geostandards and Geoanalytical Research Bibliographic Review 2020 (2022)
    Weis, Ulrike ; Stoll, Brigitte ; Förster, Michael W. ; [et al.]
    Details
    Publication Date: 2022-10-19
    Description: Key Points: Literature review of 7200 geoanalytical publications for the year 2020. 628 selected articles with summaries of target analytes, relevant reference materials and producers. Selected publications include data obtained by new analytical developments and improved analytical protocols for established RMs, and identifies recently developed RMs for specific scientific topics. image
    Description: This bibliographic review gives an overview of scientific publications in 2020 that contribute important data for geoanalytical reference materials (RMs).
    Keywords: ddc:551.9
    Language: English
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    A Triad Photoanode for Visible Light‐Driven Water Oxidation via Immobilization of Molecular Polyoxometalate on Polymeric Carbon Nitride (2022)
    Details
    Publication Date: 2022-08-04
    Description: Due to their availability, low cost, nontoxicity, and tunability, polymeric carbon nitrides (CNx) represent one of the most attractive materials classes for the development of fully sustainable photo(electro)catalytic systems for solar‐driven water splitting. However, the development of CNx‐based photoanodes for visible light‐driven water oxidation to dioxygen is rather challenging, particularly due to issues related to photoelectrode stability and effective coupling of the light absorber with water oxidation catalysts. Herein, a triadic photoanode comprising a porous TiO2 electron collector scaffold sensitized by CNx coupled to a molecular cobalt polyoxometalate (CoPOM = [Co4(H2O)2(PW9O34)2]10) catalyst is reported. Complete water oxidation to dioxygen under visible (λ 〉 420 nm) light irradiation is demonstrated, with photocurrents down to relatively low bias potentials (0.2 V vs RHE). Furthermore, polyethyleneimine (PEI), a cationic polymer is shown to act as an effective and non‐sacrificial electrostatic linker for immobilization of the anionic CoPOM onto the negatively charged surface of CNx. The optimized deposition of CoPOM using the PEI linker translates directly into improved efficiency of the transfer of photogenerated holes to water molecules and to enhanced oxygen evolution. This work thus provides important design rules for effective immobilization of POM‐based catalysts into soft‐matter photoelectrocatalytic architectures for light‐driven water oxidation.
    Description: A triadic photoanode comprised of a porous TiO2 electron collector scaffold sensitized by polymeric carbon nitride and coupled to a molecular cobalt polyoxometalate (CoPOM) catalyst exhibits visible (λ 〉 420 nm) light‐driven water oxidation to dioxygen. The beneficial role of the cationic polyethyleneimine polymer as an effective electrostatic linker for immobilization of CoPOM onto carbon nitride is highlighted.
    Description: Deutsche Forschungsgemeinschaft http://dx.doi.org/10.13039/501100001659
    Description: Vector Stiftung http://dx.doi.org/10.13039/501100013912
    Keywords: ddc:551.9
    Language: English
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    Inspecting the Reliability of Geochemical Facies Identified for the Waterworks' Capture Zone in Germany (2022)
    Blackwell Publishing Ltd | Malden, US
    Details
    Publication Date: 2022-09-27
    Description: Little research attention has been given to validating clusters obtained from the groundwater geochemistry of the waterworks' capture zone with a prevailing lake‐groundwater exchange. To address this knowledge gap, we proposed a new scheme whereby Gaussian finite mixture modeling (GFMM) and Spike‐and‐Slab Bayesian (SSB) algorithms were utilized to cluster the groundwater geochemistry while quantifying the probability of the resulting cluster membership against each other. We applied GFMM and SSB to 13 geochemical parameters collected during different sampling periods at 13 observation points across the Barnim Highlands plateau located in the northeast of Berlin, Germany; this included 10 observation wells, two lakes, and a gallery of drinking production wells. The cluster analysis of GFMM yielded nine clusters, either with a probability ≥0.8, while the SSB produced three hierarchical clusters with a probability of cluster membership varying from 〈0.2 to 〉0.8. The findings demonstrated that the clustering results of GFMM were in good agreement with the classification as per the principal component analysis and Piper diagram. By superimposing the parameter clustering onto the observation clustering, we could identify discrepancies that exist among the parameters of a certain cluster. This enables the identification of different factors that may control the geochemistry of a certain cluster, although parameters of that cluster share a strong similarity. The GFMM results have shown that from 2002, there has been active groundwater inflow from the lakes towards the capture zone. This means that it is necessary to adopt appropriate measures to reverse the inflow towards the lakes.
    Description: Article impact statement: The probability of cluster membership quantified using an algorithm should be validated against another probabilistic‐based classifier.
    Description: Federal Ministry of Education and Research http://dx.doi.org/10.13039/501100002347
    Keywords: ddc:551.9 ; ddc:551.49
    Language: English
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    The detection of bacterial exometabolites in marine dissolved organic matter through ultrahigh‐resolution mass spectrometry (2022)
    John Wiley & Sons, Inc. | Hoboken, USA
    Details
    Publication Date: 2022-10-01
    Description: Bacteria play a key role in sustaining the chemodiversity of marine dissolved organic matter (DOM), yet there is limited direct evidence of a major contribution of bacterial exometabolites to the DOM pool. This study tests whether molecular formulae of intact exometabolites can be detected in natural DOM via untargeted Fourier‐transform ion cyclotron resonance mass spectrometry (FT‐ICR‐MS). We analyzed a series of quantitative mixtures of solid‐phase extracted DOM from the deep ocean, of a natural microbial community and selected model strains of marine bacteria. Under standard instrument settings (200 broadband scans, mass range 92–1000 Da), 77% of molecular formulae were shared between the mesocosm and marine DOM. However, there was 〈 10% overlap between pure bacterial exometabolome with marine DOM, and in mixing ratios closest to mimicking natural environments (1% bacterial DOM, 99% marine DOM), only 4% of the unique bacterial exometabolites remained detectable. Further experiments with the bacterial exometabolome DOM mixtures using enhanced instrument settings resulted in increased detection of the exometabolites at low concentrations. At 1000 and 10,000 accumulated scans, 23% and 29% of the unique molecular formulae were detectable at low concentrations, respectively. Moreover, windowing a specific mass range encompassing a representative fraction of exometabolites tripled the number of unique detected formulae at low concentrations. Routine FT‐ICR‐MS settings are thus not always sufficient to distinguish bacterial exometabolome patterns from a seawater DOM background. To observe these patterns at higher sensitivity, we recommend a high scan number coupled with windowing a characteristic region of the molecular fingerprint.
    Description: Deutsche Forschungsgemeinschaft http://dx.doi.org/10.13039/501100001659
    Keywords: ddc:551.46 ; ddc:579.3 ; ddc:
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    Tides, Stratification, and Counter Rotation: The German Bight ROFI in Comparison to Other Regions of Freshwater Influence (2022)
    Details
    Publication Date: 2022-10-01
    Description: The characteristics of tidal velocity profiles and their relation to stratification are investigated based on high‐resolution field data collected at four locations in the German Bight Region of Freshwater Influence (ROFI) in the North Sea. The deployments each include two to three tidal cycles and were conducted during field campaigns in August 2016 and May 2018. The depth‐averaged semidiurnal tidal motion is dominated by a standing wave directed toward the coast, but modified by a smaller, coast‐parallel progressive wave contribution. The time series of the tidal velocity profiles consistently show tidal asymmetries with higher flood than ebb velocities near the surface and counter‐clockwise rotation of the velocity trajectories at depth. Near the surface, phase‐locked periodic changes in the sense of rotation within the tidal cycle are evident for three deployments, resulting in periodic counter‐rotation of the upper and lower layer. During these episodes, stratification of the water column is observed. Counter‐rotation is initiated after a sudden decoupling developing from the surface downward, with subsequent rapid development of stratification and velocity shear. The observed decoupling is most likely triggered by advection of the plume‐induced lateral surface density gradient by weakly sheared ebb currents toward the study site. Due to the dominance of the standing wave in the German Bight ROFI, the observed intra‐tidal variations of stratification are more similar to the Liverpool Bay and differ significantly from the Rhine ROFI, where the tidal dynamics are controlled by a progressive Kelvin wave.
    Description: Plain Language Summary; The water velocities in the German Bight are strongly influenced by river freshwater input and semidiurnal tides. While the freshwater input from the rivers has a stratifying effect, tidal motion as well as wind and waves induce mixing. These forces compete in controlling the state of the water column in a complex manner. In theory, tidal motion should describe elliptical paths. However, in reality, these ellipses can be modified for example, by periodically occurring stratification. To assess the characteristics of the semidiurnal tidal velocity profile and its variability, four instruments to measure current velocity profiles were deployed in the German Bight during August 2016 and May 2018. Measurements were carried out for the duration of up to three tidal cycles, accompanied by parallel profiles of water temperature and salinity taken from the anchored ship nearby. Results show that periodic stratification related to the river freshwater plume is associated with periodically counter‐rotating tidal currents during the tidal cycle. The measurement position relative to the location of the density front of the plume appears to be critical for the occurrence of counter‐rotation. The observed dynamics are qualitatively compared to two other well‐studied coastal ocean regions of freshwater influence.
    Description: Key Points: High‐resolution velocity and density data from the German Bight Region of Freshwater Influence are used to assess M2 tidal properties and intra‐tidal variability. M2 tidal motion is a hybrid of standing and progressive waves, with the standing wave contribution dominating. Periodic counter‐rotation of upper‐ and lower‐layer current trajectories during the tidal cycle is related to water column stratification.
    Description: Deutsche Forschungsgemeinschaft http://dx.doi.org/10.13039/501100001659
    Description: https://doi.org/10.1594/PANGAEA.919168
    Description: https://doi.pangaea.de/10.1594/PANGAEA.943958
    Description: https://doi.pangaea.de/10.1594/PANGAEA.943955
    Description: https://doi.org/10.1594/PANGAEA.897214
    Keywords: ddc:551.46
    Language: English
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    Analytical Artefacts Preclude Reliable Isotope Ratio Measurement of Internal Water in Coral Skeletons (2022)
    de Graaf, Stefan ; Vonhof, Hubert B. ; Reijmer, John J. G. ; [et al.]
    Details
    Publication Date: 2022-10-01
    Description: Internal water in cold‐water and tropical coral skeletons was extracted and measured for its oxygen and hydrogen isotope ratios. Water was extracted by crushing pieces of coral hard tissue in a percussion device connected to either a cavity ring‐down spectroscopy (CRDS) system or an isotope ratio mass spectrometry (IRMS) system. Despite most samples yielding sufficient water, each analytical system produces distinct isotope patterns. Experiments show that several characteristics specific to biominerals give rise to discrepancies and analytical artefacts that preclude the acquisition of reproducible isotope data. The main complication is that internal water in biogenic carbonates is distributed in an open interconnected micro‐network that readily exchanges with external water and potentially facilitates interaction with hydration water in the finely dispersed organic matrix in the coral skeleton. Furthermore, only an isotopically fractionated part of the internal water is released from the coral skeletons upon crushing. Altogether, isotope ratio measurement of internal water in corals with bulk crushing techniques does not give primary fluid isotope ratios useful for (palaeo‐)environmental or microbiological studies. As the resulting isotope patterns can show systematic behaviour per technique, isotope data may be erroneously interpreted to reflect the original calcifying fluid when using only a single technique to isotopically characterise internal fluids in coral skeletons.
    Description: Key Points: Free water trapped inside coral skeletons was extracted and isotopically analyzed on two commonly used techniques for fluid inclusion isotope analysis. Measured oxygen and hydrogen isotope ratios do not reproduce between the techniques due to several analytical artefacts. The water extracted from coral skeletons is not of primary origin.
    Description: Nederlandse Organisatie voor Wetenschappelijk Onderzoek http://dx.doi.org/10.13039/501100003246
    Description: Western Indian Ocean Marine Science Association http://dx.doi.org/10.13039/501100009106
    Keywords: ddc:551.9
    Language: English
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    Benthic Carbon Remineralization and Iron Cycling in Relation to Sea Ice Cover Along the Eastern Continental Shelf of the Antarctic Peninsula (2022)
    Details
    Publication Date: 2022-10-04
    Description: Rapid and profound climatic and environmental changes have been predicted for the Antarctic Peninsula with so far unknown impact on the biogeochemistry of the continental shelves. In this study, we investigate benthic carbon sedimentation, remineralization and iron cycling using sediment cores retrieved on a 400 mile transect with contrasting sea ice conditions along the eastern shelf of the Antarctic Peninsula. Sediments at comparable water depths of 330–450 m showed sedimentation and remineralization rates of organic carbon, ranging from 2.5 to 13 and 1.8–7.2 mmol C m−2 d−1, respectively. Both rates were positively correlated with the occurrence of marginal sea ice conditions (5%–35% ice cover) along the transect, suggesting a favorable influence of the corresponding light regime and water column stratification on algae growth and sedimentation rates. From south to north, the burial efficiency of organic carbon decreased from 58% to 27%, while bottom water temperatures increased from −1.9 to −0.1°C. Net iron reduction rates, as estimated from pore‐water profiles of dissolved iron, were significantly correlated with carbon degradation rates and contributed 0.7%–1.2% to the total organic carbon remineralization. Tightly coupled phosphate‐iron recycling was indicated by significant covariation of dissolved iron and phosphate concentrations, which almost consistently exhibited P/Fe flux ratios of 0.26. Iron efflux into bottom waters of 0.6–4.5 μmol Fe m−2 d−1 was estimated from an empirical model. Despite the deep shelf waters, a clear bentho‐pelagic coupling is indicated, shaped by the extent and duration of marginal sea ice conditions during summer, and likely to be affected by future climate change.
    Description: Plain Language Summary: The seafloor of the shallow shelf seas plays a significant role in the recycling of organic carbon and acts as a nutrient source for algae growth in the upper water layers. In Antarctic waters, the change in sea ice cover has a great impact on the growth of algae and the subsequent sinking of organic carbon to the seafloor. With global warming, profound changes in sea ice cover are expected for the Antarctic Peninsula. To better understand its imprint on the seafloor, we collected sediment samples from different locations along the eastern shelf of the Antarctic Peninsula and measured how changes in sea ice cover influence the accumulation and recycling of organic carbon. We found that moderate sea ice cover of 5%–35% increases the amount of organic carbon received by the seafloor and that the fraction that is buried in the sediments decreases from south (58%) to north (27%). We further measured that more iron, an important micro‐nutrient for algae growth, can be released from the seafloor the more organic carbon accumulates. Thus, sea ice conditions determine the organic carbon accumulation, turnover, and nutrient release at the seafloor, which are likely to be affected by future climate change.
    Description: Key Points: Antarctic shelf sediments underlying marginal sea ice cover exhibit high sedimentation and remineralization rates of organic carbon. A high degree of sedimentary Fe‐recycling is found which scales with organic carbon remineralization rates. Coupling between P and Fe recycling is observed with a constant P/Fe flux ratio of 0.26 for sediments with high Fe and P recycling rates.
    Description: Alfred Wegener Institute Helmholtz Centre for Polar and Marine Research http://dx.doi.org/10.13039/501100003207
    Description: https://doi.org/10.1594/PANGAEA.942455
    Keywords: ddc:551.9
    Language: English
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    Arctic – Atlantic Exchange of the Dissolved Micronutrients Iron, Manganese, Cobalt, Nickel, Copper and Zinc With a Focus on Fram Strait (2022)
    Details
    Publication Date: 2022-10-04
    Description: The Arctic Ocean is considered a source of micronutrients to the Nordic Seas and the North Atlantic Ocean through the gateway of Fram Strait (FS). However, there is a paucity of trace element data from across the Arctic Ocean gateways, and so it remains unclear how Arctic and North Atlantic exchange shapes micronutrient availability in the two ocean basins. In 2015 and 2016, GEOTRACES cruises sampled the Barents Sea Opening (GN04, 2015) and FS (GN05, 2016) for dissolved iron (dFe), manganese (dMn), cobalt (dCo), nickel (dNi), copper (dCu) and zinc (dZn). Together with the most recent synopsis of Arctic‐Atlantic volume fluxes, the observed trace element distributions suggest that FS is the most important gateway for Arctic‐Atlantic dissolved micronutrient exchange as a consequence of Intermediate and Deep Water transport. Combining fluxes from FS and the Barents Sea Opening with estimates for Davis Strait (GN02, 2015) suggests an annual net southward flux of 2.7 ± 2.4 Gg·a−1 dFe, 0.3 ± 0.3 Gg·a−1 dCo, 15.0 ± 12.5 Gg·a−1 dNi and 14.2 ± 6.9 Gg·a−1 dCu from the Arctic toward the North Atlantic Ocean. Arctic‐Atlantic exchange of dMn and dZn were more balanced, with a net southbound flux of 2.8 ± 4.7 Gg·a−1 dMn and a net northbound flux of 3.0 ± 7.3 Gg·a−1 dZn. Our results suggest that ongoing changes to shelf inputs and sea ice dynamics in the Arctic, especially in Siberian shelf regions, affect micronutrient availability in FS and the high latitude North Atlantic Ocean.
    Description: Plain Language Summary: Recent studies have proposed that the Arctic Ocean is a source of micronutrients such as dissolved iron (dFe), manganese (dMn), cobalt (dCo), nickel (dNi), copper (dCu) and zinc (dZn) to the North Atlantic Ocean. However, data at the Arctic Ocean gateways including Fram Strait and the Barents Sea Opening have been missing to date and so the extent of Arctic micronutrient transport toward the Atlantic Ocean remains unquantified. Here, we show that Fram Strait is the most important gateway for Arctic‐Atlantic micronutrient exchange which is a result of deep water transport at depths 〉500 m. Combined with a flux estimate for Davis Strait, this study suggests that the Arctic Ocean is a net source of dFe, dNi and dCu, and possibly also dCo, toward the North Atlantic Ocean. Arctic‐Atlantic dMn and dZn exchange seems more balanced. Properties in the East Greenland Current showed substantial similarities to observations in the upstream Central Arctic Ocean, indicating that Fram Strait may export micronutrients from Siberian riverine discharge and shelf sediments 〉3,000 km away. Increasing Arctic river discharge, permafrost thaw and coastal erosion, all consequences of ongoing climate change, may therefore alter future Arctic Ocean micronutrient transport to the North Atlantic Ocean.
    Description: Key Points: Fram Strait is the major gateway for Arctic‐Atlantic exchange of the dissolved micronutrients Fe, Mn, Co, Ni, Cu and Zn. The Arctic is a net source of dissolved Fe, Co, Ni and Cu to the Nordic Seas and toward the North Atlantic; Mn and Zn exchange are balanced. Waters of the Central Arctic Ocean, including the Transpolar Drift, are the main drivers of gross Arctic micronutrient export.
    Description: German Research Foundation
    Description: Netherlands Organization for Scientific Research
    Description: https://doi.pangaea.de/10.1594/PANGAEA.859558
    Description: https://doi.pangaea.de/10.1594/PANGAEA.871030
    Description: https://doi.pangaea.de/10.1594/PANGAEA.868396
    Description: https://doi.pangaea.de/10.1594/PANGAEA.905347
    Description: https://dataportal.nioz.nl/doi/10.25850/nioz/7b.b.jc
    Description: https://doi.pangaea.de/10.1594/PANGAEA.933431
    Description: https://www.bco-dmo.org/dataset/718440
    Description: https://doi.org/10.1594/PANGAEA.936029
    Description: https://doi.org/10.1594/PANGAEA.936027
    Description: https://doi.pangaea.de/10.1594/PANGAEA.927429
    Keywords: ddc:551.9
    Language: English
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    Holocene variability in sea‐ice conditions in the eastern Baffin Bay‐Labrador Sea – A north–south biomarker transect study (2022)
    Saini, Jeetendra ; Stein, Ruediger ; Fahl, Kirsten ; [et al.]
    Details
    Publication Date: 2022-10-05
    Description: Reconstructions of sea‐surface conditions during the Holocene were achieved using three sediment cores from northeastern Baffin Bay (GeoB19948‐3 and GeoB19927‐3) and the Labrador Sea (GeoB19905‐1) along a north–south transect based on sea‐ice IP25 and open‐water phytoplankton biomarkers (brassicasterol, dinosterol and HBI III). In Baffin Bay, sea‐surface conditions in the Early Holocene were characterized by extended (early) spring sea ice cover (SIC) prior to 7.6 ka BP. The conditions in the NE Labrador Sea, however, remained predominantly ice‐free in spring/autumn due to the enhanced influx of Atlantic Water (West Greenland Current, WGC) from 11.5 until ~9.1 ka BP, succeeded by a period of continued (spring–autumn) ice‐free conditions between 9.1 and 7.6 ka BP corresponding to the onset of Holocene Thermal Maximum (HTM)‐like conditions. A transition towards reoccurring ice‐edge and significantly reduced SIC conditions in Baffin Bay is evident in the Middle Holocene (~7.6–3 ka BP) probably caused by the variations in the WGC influence associated with the ice melting and can be characterized as HTM‐like conditions. These HTM‐like conditions are predominantly recorded in the NE Labrador Sea area shown by (spring–autumn) ice‐free conditions from 5.9–3 ka BP. In the Late Holocene (last ~3 ka), our combined proxy records from eastern Baffin Bay indicate low in‐situ ice algae production; however, enhanced multi‐year (drifted) sea ice in this area was possibly attributed to the increased influx of Polar Water mass influx and may correlate with the Neoglacial cooling. The conditions in the NE Labrador Sea during the last 3 ka, however, continued to remain (spring–autumn) ice‐free. Our data from the Baffin Bay–Labrador Sea transect suggest a dominant influence of meltwater influx on sea‐ice formation throughout the Holocene, in contrast to sea‐ice records from the Fram Strait area, which seem to follow predominantly the summer insolation trend.
    Description: image
    Description: Deutsche Forschungsgemeinschaft (DFG) http://dx.doi.org/10.13039/501100001659
    Keywords: ddc:551.46
    Language: English
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    Strain Signals Governed by Frictional‐Elastoplastic Interaction of the Upper Plate and Shallow Subduction Megathrust Interface Over Seismic Cycles (2022)
    Details
    Publication Date: 2022-10-06
    Description: The behavior of the shallow portion of the subduction zone, which generates the largest earthquakes and devastating tsunamis, is still insufficiently constrained. Monitoring only a fraction of a single megathrust earthquake cycle and the offshore location of the source of these earthquakes are the foremost reasons for the insufficient understanding. The frictional‐elastoplastic interaction between the megathrust interface and its overlying wedge causes variable surface strain signals such that the wedge strain patterns may reveal the mechanical state of the interface. To contribute to this understanding, we employ Seismotectonic Scale Modeling and simplify elastoplastic megathrust subduction to generate hundreds of analog seismic cycles at a laboratory scale and monitor the surface strain signals over the model's forearc across high to low temporal resolutions. We establish two compressional and critical wedge configurations to explore the mechanical and kinematic interaction between the shallow wedge and the interface. Our results demonstrate that this interaction can partition the wedge into different segments such that the anelastic extensional segment overlays the seismogenic zone at depth. Moreover, the different segments of the wedge may switch their state from compression/extension to extension/compression domains. We highlight that a more segmented upper plate represents megathrust subduction that generates more characteristic and periodic events. Additionally, the strain time series reveals that the strain state may remain quasi‐stable over a few seismic cycles in the coastal zone and then switch to the opposite mode. These observations are crucial for evaluating earthquake‐related morphotectonic markers and short‐term interseismic time series of the coastal regions.
    Description: Key Points: Analog earthquake cycle experiments provide observations to evaluate the surface strain signals from the shallow megathrust. The extensional segment of the forearc overlays the seismogenic zone at depth. The strain state may remain quasi‐stable over a few seismic cycles in the coastal zone.
    Description: SUBITOP Marie Sklodowska‐Curie Action project from the European Union's EU Framework Programme
    Description: Deutsche Forschungsgemeinschaft (CRC 1114) “Scaling Cascades in Complex Systems”
    Description: https://doi.org/10.5880/fidgeo.2022.015
    Keywords: ddc:551.8 ; ddc:550.78
    Language: English
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    Growth of microaerophilic Fe(II)‐oxidizing bacteria using Fe(II) produced by Fe(III) photoreduction (2022)
    Details
    Publication Date: 2022-06-17
    Description: Iron(II) (Fe(II)) can be formed by abiotic Fe(III) photoreduction, particularly when Fe(III) is organically complexed. Light‐influenced environments often overlap or even coincide with oxic or microoxic geochemical conditions, for example, in sediments. So far, it is unknown whether microaerophilic Fe(II)‐oxidizing bacteria are able to use the Fe(II) produced by Fe(III) photoreduction as electron donor. Here, we present an adaption of the established agar‐stabilized gradient tube approach in comparison with liquid cultures for the cultivation of microaerophilic Fe(II)‐oxidizing microorganisms by using a ferrihydrite‐citrate mixture undergoing Fe(III) photoreduction as Fe(II) source. We quantified oxygen and Fe(II) gradients with amperometric and voltammetric microelectrodes and evaluated microbial growth by qPCR of 16S rRNA genes. We showed that gradients of dissolved Fe(II) (maximum Fe(II) concentration of 1.25 mM) formed in the gradient tubes when incubated in blue or UV light (400–530 nm or 350–400 nm). Various microaerophilic Fe(II)‐oxidizing bacteria (Curvibacter sp. and Gallionella sp.) grew by oxidizing Fe(II) that was produced in situ by Fe(III) photoreduction. Best growth for these species, based on highest gene copy numbers, was observed in incubations using UV light in both liquid culture and gradient tubes containing 8 mM ferrihydrite‐citrate mixtures (1:1), due to continuous light‐induced Fe(II) formation. Microaerophilic Fe(II)‐oxidizing bacteria contributed up to 40% to the overall Fe(II) oxidation within 24 h of incubation in UV light. Our results highlight the potential importance of Fe(III) photoreduction as a source of Fe(II) for Fe(II)‐oxidizing bacteria by providing Fe(II) in illuminated environments, even under microoxic conditions.
    Description: Deutsche Forschungsgemeinschaft http://dx.doi.org/10.13039/501100001659
    Description: Ministerium für Wissenschaft, Forschung und Kunst Baden‐Württemberg http://dx.doi.org/10.13039/501100003542
    Description: Bundesministerium für Bildung und Forschung http://dx.doi.org/10.13039/501100002347
    Keywords: ddc:579.317 ; ddc:551.9
    Language: English
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    Simulated Future Trends in Marine Nitrogen Fixation Are Sensitive to Model Iron Implementation (2022)
    Details
    Publication Date: 2022-06-17
    Description: Biological nitrogen fixation is an important oceanic nitrogen source, potentially stabilizing marine fertility in an increasingly stratified and nutrient‐depleted ocean. Iron limitation of low latitude primary producers has been previously demonstrated to affect simulated regional ecosystem responses to climate warming or nitrogen cycle perturbation. Here we use three biogeochemical models that vary in their representation of the iron cycle to estimate change in the marine nitrogen cycle under a high CO2 emissions future scenario (RCP8.5). The first model neglects explicit iron effects on biology (NoFe), the second utilizes prescribed, seasonally cyclic iron concentrations and associated limitation factors (FeMask), and the third contains a fully dynamic iron cycle (FeDyn). Models were calibrated using observed fields to produce near‐equivalent nutrient and oxygen fits, with productivity ranging from 49 to 75 Pg C yr−1. Global marine nitrogen fixation increases by 71.1% with respect to the preindustrial value by the year 2100 in NoFe, while it remains stable (0.7% decrease in FeMask and 0.3% increase in FeDyn) in explicit iron models. The mitigation of global nitrogen fixation trend in the models that include a representation of iron originates in the Eastern boundary upwelling zones, where the bottom‐up control of iron limitation reduces export production with warming, which shrinks the oxygen deficient volume, and reduces denitrification. Warming‐induced trends in the oxygen deficient volume in the upwelling zones have a cascading effect on the global nitrogen cycle, just as they have previously been shown to affect tropical net primary production.
    Description: Plain Language Summary: Phytoplankton need nutrients to grow. Two of those nutrients are nitrogen and iron. Climate change projections suggest that in the future there could be less nitrogen supplied to the surface ocean, which might reduce phytoplankton growth. Less phytoplankton growth could impact a wide range of ocean services, like fishing and fossil carbon draw‐down. However, some phytoplankton have the ability to add “new” nitrogen to the surface ocean directly from the atmosphere. In this study, we explore how this biological fixation of new nitrogen might change into the future using three models. These models differ in how iron is represented, but all do equally well in representing the observed nutrient and oxygen distribution. Biological nitrogen fixation slightly decreases with climate change in the very complex iron model and the moderately complex iron model, but it increases strongly (by more than 70% by the year 2100) in the model that does not include iron effects on biology. Our study addresses the importance of iron models and how they can change our view of how the ocean responds to climate change.
    Description: Key Points: Models performing similarly with respect to global NO3, PO4, and O2 distributions yield diverse responses in marine N2 fixation to warming. Marine N2 fixation trends are sensitive to whether iron limits primary production in upwelling regions, for example, the Eastern Tropical Pacific.
    Description: Helmholtz Research School for Ocean System Science and Technology
    Description: New Zealand Ministry of Business, Innovation and Employment
    Description: https://data.geomar.de/downloads/20.500.12085/673e7de0-20ab-4dd3-afe9-c4bfb00b1faf/
    Keywords: ddc:551.9
    Language: English
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    The Effect of Land Use Classification on the Gas‐Phase and Particle Composition of the Troposphere: Tree Species Versus Forest Type Information (2022)
    Details
    Publication Date: 2022-06-17
    Description: Relationships between vegetation and air quality are intricate and still not fully understood. For regional air quality assessments, a better understanding of the diverse feedback mechanisms is crucial. The present article investigates the impact of land use data set detailedness on air quality predictions. Therefore, two different land use data sets were applied for simulations with COSMO‐MUSCAT for Germany in May 2014. One data set includes detailed information about tree species while the second one obtains generalized widely applied land use classes including mixed and coniferous forests. Moreover, we examined the role of agricultural NO soil emissions, agricultural biomass density enhancements, and model resolution. For a more comprehensive implementation of the secondary organic aerosol (SOA) formation, the SOA module was extended considering additional biogenic volatile organic compound (BVOC) precursor groups from isoprene, α‐pinene, limonene, and sesquiterpene oxidations. The model studies showed substantial differences in BVOC emission patterns between the two land use data sets. The application of detailed tree species information leads to complex BVOC emission patterns with high emission spots. In contrast, coarser forest information lead to standardized comprehensive emissions which result in 50% higher BVOC emissions. These differences affect both the atmospheric oxidizing potential and the production rates of SOA precursors. Land use induced regional differences (tree species minus forest information) in NOx (±2.5%), ozone (−2.5%), OH (±50%), NO3 radical (+70%) concentrations, and SOA (−60%) mass are modeled. Overall, the simulations demonstrate that detailed land use information, extended organic chemistry treatment, and high spatial resolution are mandatory for air quality assessments.
    Description: Plain Language Summary: Trees are associated with being the lungs of the atmosphere as they filter out harmful substances from the air, they store CO2, and produce oxygen via photosynthesis. Other by‐products of photosynthesis are biogenic volatile organic compounds (BVOCs). BVOCs are chemical substances with a high vapor pressure already at room temperatures, so they quickly evaporate from the leaves into the surrounding air and are responsible for the characteristic forest smell. The amount and composition of BVOC emissions strongly depend on the tree species. Every plant has its own distinct emission properties. The chemical degradation of BVOCs impacts the chemical composition of the troposphere and is connected to ground level ozone production and the formation of secondary organic aerosols (SOA), contributing substantially to particulate matter (PM). On a global scale, standardized BVOC emission information on forest levels are often used, but for regional air quality assessments detailed plant specific information is crucial, but still often lacking. Therefore, two different land use data sets were applied in the present study to investigate the impact of standardized forest versus detailed tree‐species information for Germany in May 2014. The study reveals changes in NOx (±2.5%), ozone (−2.5%), OH (±50%), NO3 radical (+70%), and SOA (−60%) concentrations.
    Description: Key Points: Detail of land use data sets crucial for biogenic volatile organic compound emission strength and composition. Composition and concentration variation of these organic compounds induce changes in regional air quality predictions. Detailed land use information, extended organic matter treatment, and high‐resolution simulations are mandatory for air quality assessments.
    Description: Deutsche Bundesstiftung Umwelt (DBU) http://dx.doi.org/10.13039/100007636
    Description: https://doi.org/10.5281/zenodo.4783106
    Description: http://ebas.nilu.no/
    Keywords: ddc:551.5 ; ddc:551.9
    Language: English
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    Effects of the Hydrous Domain in the Mantle Wedge on Magma Formation and Mixing at the Northeast Lau Spreading Center, SW Pacific (2022)
    Details
    Publication Date: 2022-08-09
    Description: Abundant volcanic activity occurs in the back‐arc region of the northern Tofua island arc where the Northeast Lau Spreading Center (NELSC) propagates southwards into older crust causing the formation of numerous seamounts at the propagating rift tip. An off‐axis volcanic diagonal ridge (DR) occurs at the eastern flank of the NELSC, linking the large rear‐arc volcano Niuatahi with the NELSC. New geochemical data from the NELSC, the southern propagator seamounts, and DR reveal that the NELSC lavas are tholeiitic basalts whereas the rear‐arc volcanoes typically erupt lavas with boninitic composition. The sharp geochemical boundary probably reflects the viscosity contrast between off‐axis hydrous harzburgitic mantle and dry fertile mantle beneath the NELSC. The new data do not indicate an inflow of Samoa plume mantle into the NELSC, confirming previously published He isotope data. The NELSC magmas form by mixing of an enriched and a depleted Indian Ocean‐type upper mantle end‐member implying a highly heterogeneous upper mantle composition in this area. Most NELSC lavas are little affected by a slab component implying that melting is adiabatic beneath the spreading center. The DR lavas show the influence of a component from the subducted Louisville Seamount Chain, which was previously thought to be restricted to the nearby arc volcanoes Niuatoputapu and Tafahi. This signature is rarely detected along the NELSC implying little mixing of melts from the low‐viscosity hydrous portion of the mantle wedge beneath the rear‐arc volcanoes into the melting region of the dry mantle beneath the NELSC.
    Description: Plain Language Summary: Volcanic activity is abundant at subduction zones and the chemical analysis of the erupted rocks allows to determine the material transport in the Earth's mantle. The Northeast Lau Spreading Center (NELSC) forms by extension and volcanism behind the northern Tofua island arc. Several large volcanic structures occur east of the NELSC and the lavas of these off‐axis volcanoes are chemically and isotopically distinct implying little mixing with the magmas of the NELSC. The differences suggest decompression melting of relatively dry mantle beneath the NELSC whereas the off‐axis volcanoes reflect melting of water‐rich mantle affected by fluids from the subducting Pacific Plate. The sharp geochemical boundary between the NELSC and off‐axis volcanoes is probably due to a large viscosity contrast between hydrous harzburgitic mantle and dry fertile mantle. Element and isotope ratios indicate that the NELSC magmas form by mixing of enriched and depleted portions of the upper mantle, and we do not find evidence for inflow of the Samoa deep mantle plume from the north. Some of the off‐axis lavas contain a component from a volcanic chain that was subducted some 4 million years ago and that was previously only known in two volcanoes of the Tofua island arc.
    Description: Key Points: Variably enriched mantle sources melt beneath the Northeast Lau Spreading Center (NELSC) but there is no evidence for Samoa mantle plume inflow. Relatively dry fertile mantle beneath NELSC causes sharp geochemical boundary with hydrous harzburgitic North Tonga mantle wedge. Subducted Louisville Seamount Chain material affects rear‐arc volcanism.
    Description: Bundesministerium für Bildung und Forschung (BMBF) http://dx.doi.org/10.13039/501100002347
    Description: Deutsche Forschungsgemeinschaft (DFG) http://dx.doi.org/10.13039/501100001659
    Keywords: ddc:551.21 ; ddc:551.116 ; ddc:551.9
    Language: English
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    Collisional mixing between inner and outer solar system planetesimals inferred from the Nedagolla iron meteorite (2021)
    Details
    Publication Date: 2022-07-28
    Description: The ungrouped iron meteorite Nedagolla is the first meteorite with bulk Mo, Ru, and Ni isotopic compositions that are intermediate between those of the noncarbonaceous (NC) and carbonaceous (CC) meteorite reservoirs. The Hf‐W chronology of Nedagolla indicates that this mixed NC–CC isotopic composition was established relatively late, more than 7 Myr after solar system formation. The mixed NC–CC isotopic composition is consistent with the chemical composition of Nedagolla, which combines signatures of metal segregation under more oxidizing conditions (relative depletions in Mo and W), characteristic for CC bodies, and more reducing conditions (high Si and Cr contents), characteristic for some NC bodies, in a single sample. These data combined suggest that Nedagolla formed as the result of collisional mixing of NC and CC core material, which partially re‐equilibrated with silicate mantle material that predominantly derives from the NC body. These mixing processes might have occurred during a hit‐and‐run collision between two differentiated bodies, which also provides a possible pathway for Nedagolla's extreme volatile element depletion. As such, Nedagolla provides the first isotopic evidence for early collisional mixing of NC and CC bodies that is expected as a result of Jupiter's growth.
    Description: Deutsche Forschungsgemeinschaft http://dx.doi.org/10.13039/501100001659
    Keywords: ddc:551.9 ; ddc:549.112
    Language: English
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    Scaling Laws in Aeolian Sand Transport Under Low Sand Availability (2022)
    Details
    Publication Date: 2022-11-01
    Description: The transport of sand by wind shapes the Earth's surface and constitutes one major factor for the emission of dust aerosols. The accurate modeling of wind‐blown sand transport is thus important to achieve reliable climate simulations and to make predictions about the propagation of desertification. Previous models of wind‐blown sand were designed to compute sand transport rates over a thick sand layer, such as the surface of large, active sand dunes. However, natural soils encompass a broad range of low sand availability conditions, such as crusted or bare soils. It has been a long‐standing open question how wind‐blown sand transport rates respond to wind velocity when the bare ground is covered by a thin layer of sand. Here we calculate the trajectories of wind‐blown sand grains and find that sand transport rates increase faster with wind speed under low sand availability conditions than over sand dunes. The reason for this behavior is elucidated in our simulations: The hopping sand grains fly higher the less sand is covering the hard surface. We obtain mathematical expressions for the sand transport rates as a function of the thickness of sand covering the bare soil, which will be important to improve climate models.
    Description: Key Points: We introduce a particle‐based model in investigating Aeolian (wind‐blown) sand transport when the sand cover on the soil is sparse. The scaling of the Aeolian transport rate with the wind shear velocity has a dependency on the sand cover thickness. There is an anomaly in the functional dependence of the transport rate on the sand cover thickness, depending on the rigid ground roughness.
    Description: Deutsche Forschungsgemeinschaft http://dx.doi.org/10.13039/501100001659
    Description: https://doi.org/10.6084/m9.figshare.19469501
    Keywords: ddc:550.78
    Language: English
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    Surface Wave and Roller Dissipation Observed With Shore‐Based Doppler Marine Radar (2022)
    Details
    Publication Date: 2023-01-19
    Description: Surface wave energy and dissipation are observed across the surf zone. Utilizing the concept of surface rollers, a new scaling is introduced to obtain the energy flux and dissipation related to rollers from Doppler velocities measured by a shore‐based X‐band marine radar. The dissipation of wave energy and hence the transformation of the incoming wave height (or energy) is derived using the coupled wave and roller energy balance equations. Results are compared to in‐situ wave measurements obtained from a wave rider buoy and two bottom mounted pressure wave gauges. A good performance in reproducing the significant wave height is found yielding an overall root‐mean‐square error of 0.22 m and a bias of −0.12 m. This is comparable to the skill of numerical wave models. In contrast to wave models, however, the radar observations of the wave and roller energy flux and dissipation neither require knowledge of the bathymetry nor the incident wave height. Along a 1.5 km long cross‐shore transect on a double‐barred, sandy beach in the southern North Sea, the highest dissipation rates are observed at the inner bar over a relatively short distance of less than 100 m. During the peak of a medium‐severe storm event with significant wave heights over 3 m, about 50% of the incident wave energy flux is dissipated at the outer bar.
    Description: Plain Language Summary: Ocean waves are carrying a large amount of mechanical energy which they have gained from the wind blowing over the ocean surface. At the coast this energy supply generates strong water motions, creates forces on coastal structures, moves sand, and can cause coastal erosion. It is therefore important to know when, where, and to what extent wave energy is reduced under different environmental conditions. The majority of the energy is removed by wave breaking. However, this process is still not completely understood which is partly due to fact that it is difficult to observe. This is particularly the case during storm conditions when it is very complicated to install and recover measurement equipment in the ocean. The present work describes a methodology to obtain such measurements using a special radar device which is installed at the beach; hence, it is not being impacted by harsh wave conditions. This approach will enable scientists to perform long‐term monitoring of wave breaking thus opening new opportunities to study beach processes and coastal changes.
    Description: Key Points: high‐resolution observations of surface wave and roller dissipation as well as the transformation of wave height across the surf zone. the concept of surface rollers is applied to shore‐based X‐band Doppler radar data. in storm conditions, 50% of the wave energy is dissipated at a submerged outer sandbar, but strongest dissipation occurs further inshore.
    Description: Helmholtz Association http://dx.doi.org/10.13039/501100009318
    Description: http://codm.hzg.de/codm
    Description: https://doi.org/10.1594/683PANGAEA.898407
    Description: https://doi.org/10.1594/PANGAEA.942014
    Description: https://doi.org/10.5281/zenodo.5787131
    Keywords: ddc:551.46 ; wave breaking ; X‐band radar ; roller concept ; close‐range remote sensing ; energy dissipation ; wave transformation
    Language: English
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  • 95
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    The Role of Turbulence in Fueling the Subsurface Chlorophyll Maximum in Tidally Dominated Shelf Seas (2022)
    Details
    Publication Date: 2023-01-26
    Description: Glider observations show a subsurface chlorophyll maximum (SCM) at the base of the seasonal pycnocline in the North Sea during stable summer conditions. A colocated peak in the dissipation rate of turbulent kinetic energy suggests the presence of active turbulence that potentially generates a nutrient flux to fuel the SCM. A one‐dimensional turbulence closure model is used to investigate the dynamics behind this local maximum in turbulent dissipation at the base of the pycnocline (PCB) as well as its associated nutrient fluxes. Based on a number of increasingly idealized forcing setups of the model, we are able to draw the following conclusions: (a) only turbulence generated inside the stratified PCB is able to entrain a tracer (e.g., nutrients) from the bottom mixed layer into the SCM region; (b) surface wind forcing only plays a secondary role during stable summer conditions; (c) interfacial shear from the tide accounts for the majority of turbulence production at the PCB; (d) in stable summer conditions, the strength of the turbulent diapycnal fluxes at the PCB is set by the strength of the anticyclonic component of the tidal currents.
    Description: Plain Language Summary: Many midlatitude shelf seas are vertically stratified in summer, where a warm surface layer sits on top of a cold, dense bottom layer. Both of these layers are unproductive environments for phytoplankton—the bottom layer is light limited, and the surface layer is nutrient‐limited. However, abundant phytoplankton is observed directly at the interface between surface and bottom layers. In order to sustain this phytoplankton, nutrient‐rich bottom water needs to be mixed with interface water. While both wind and tides are major causes for mixing in the coastal ocean, we find that the tides alone provide sufficient stirring at the right place to potentially act as an effective fuel pump for the phytoplankton. Interestingly, it is not the strength of the tides alone that counts, rather the sense of rotation of the tidal currents; rotation opposite to the Earth's spin causes more stirring than rotation along with it.
    Description: Key Points: Turbulence and chlorophyll both peak at the base of the pycnocline on a mid‐latitude shelf. Locally generated turbulence at the pycnocline base is a fuel pump for the subsurface chlorophyll maximum. Amplitude and polarity of the M2 tide govern the local generation of turbulence at the pycnocline base.
    Description: Helmholtz Association
    Description: https://doi.org/10.5281/zenodo.3525787
    Description: https://oceancolor.gsfc.nasa.gov/l3/
    Description: https://www.cen.uni-hamburg.de/icdc/data/ocean/nsbc.html
    Keywords: ddc:551.46 ; shelf seas ; storms ; North Sea ; turbulence ; straification ; marginal stability ; subsurface chlorophyll maximum ; fuel pump ; modeling
    Language: English
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  • 96
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    Locally Resolved Stress‐State in Samples During Experimental Deformation: Insights Into the Effect of Stress on Mineral Reactions (2022)
    Details
    Publication Date: 2023-01-20
    Description: Understanding conditions in the Earth's interior requires data derived from laboratory experiments. Such experiments provide important insights into the conditions under which mineral reactions take place as well as processes that control the localization of deformation in the deep Earth. We performed Griggs‐type general shear experiments in combination with numerical models, based on continuum mechanics, to quantify the effect of evolving sample geometry of the experimental assembly. The investigated system is constituted by CaCO3 and the experimental conditions are near the calcite‐aragonite phase transition. All experimental samples show a heterogeneous distribution of the two CaCO3 polymorphs after deformation. This distribution is interpreted to result from local stress variations. These variations are in agreement with the observed phase‐transition patterns and grain‐size gradients across the experimental sample. The comparison of the mechanical models with the sample provides insights into the distribution of local mechanical parameters during deformation. Our results show that, despite the use of homogeneous sample material (here calcite), stress variations develop due to the experimental geometry. The comparison of experiments and numerical models indicates that aragonite formation is primarily controlled by the spatial distribution of mechanical parameters. Furthermore, we monitor the maximum pressure and σ1 that is experienced in every part of our model domain for a given amount of time. We document that local pressure (mean stress) values are responsible for the transformation. Therefore, if the role of stress as a thermodynamic potential is investigated in similar experiments, an accurate description of the state of stress is required.
    Description: Plain Language Summary: To understand processes in the Earth's interior, we can simulate the extreme conditions via laboratory experiments by compressing and heating millimeter‐sized samples. Such experiments provide important insights into mineral reactions and processes that control deformation in the Earth. We performed rock deformation experiments close to calcite‐aragonite phase (CaCO3) transition. Deforming the sample leads to stress variations due to the experimental geometry. These variations are documented by locally occurring phase transition and variation in the grain‐size. We performed computer simulations of the deforming sample to quantify, for the first time, the effect of sample geometry on the distribution of mechanical variables, such as stress, pressure, or deformation, inside the sample. The new findings document that any mechanical variable cannot be treated as homogeneous within the sample because the variations can be significant. Deforming the sample leads to stress concentrations. By comparing the experimental observations and simulation results, we show that locally high pressure triggers the phase transition to aragonite, the high‐pressure polymorph. This has important consequences for further thermodynamic interpretations of systems under stress, where the role of deformation, pressure, or maximum principal stress on mineral reactions is investigated.
    Description: Key Points: Heterogeneous stress distribution in deformation experiments is investigated by numerical models, locally resolving mechanical variables. Resolving the mechanical variables in experiments suggests a link between local pressure (mean stress) variations and phase transition. Thermodynamic interpretations of deformed samples require a detailed understanding of local mechanical parameters.
    Description: ETH Zürich Foundation http://dx.doi.org/10.13039/501100012652
    Description: https://doi.org/10.5281/zenodo.6974768
    Keywords: ddc:550.78 ; deformation experiments ; numerical modeling ; phase transition ; rock deformation ; localization ; stress variations
    Language: English
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  • 97
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    Decadal Prediction of Marine Heatwaves in MPI‐ESM (2022)
    Details
    Publication Date: 2023-01-20
    Description: Marine Heatwaves (MHW) are SST extremes that can have devastating impacts on marine ecosystems and can influence circulation patterns in the ocean and the atmosphere. Here, we present a first attempt to study the decadal predictability of MHW in an ensemble of decadal hindcasts based on the Max Planck Institute Earth System Model. For the global mean we find significant skill for the multiyear MHW trends but we cannot predict the interannual to decadal variability of MHW. In the Subpolar North Atlantic, we can predict the interannual to decadal variability of MHW days and frequency up to lead year 8. We demonstrate that in the Subpolar North Atlantic, any increase in SST is accompanied by more MHW and vice versa. Thereby we gain additional information about the decadal evolution of SST that go beyond predicting the yearly mean SST.
    Description: Plain Language Summary: Marine Heatwaves (MHW) are periods with extremely warm ocean temperatures that can be disruptive for many marine ecosystems. Here, we provide an attempt to predict the evolution of MHW in the global ocean for the following two to ten years. With this analysis we improve our understanding of the predictability of surface temperatures in the global ocean. We find that there are strong regional differences in the predictability of MHW. One region where MHW can be predicted successfully is the Subpolar North Atlantic. We show that an increase in mean ocean temperature also results in an increase in MHW.
    Description: Key Points: Global mean multiyear trends for Marine Heatwaves (MHW) days and frequency can be skillfully predicted for the following two to eight years. In the Subpolar North Atlantic, yearly characteristics MHW days and frequency are predictable up to leadyear eight. Any increase in SST in the Subpolar North Atlantic is accompanied by an increase in MHW and vice versa.
    Description: Copernicus Climate Change Service
    Description: Deutsche Forschungsgemeinschaft
    Description: http://hdl.handle.net/hdl:21.14106/f2fdc61b13828ed5284f4e4ab41e63f8a84c6e52
    Keywords: ddc:551.46 ; Marine Heatwaves ; decadal predictions ; North Atlantic ; extreme events
    Language: English
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  • 98
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    Pseudo-total antimony content in topsoils of the Berlin Metropolitan Area (2020)
    Springer Berlin Heidelberg
    Details
    Publication Date: 2023-06-08
    Description: Purpose: Sb is a metalloid that naturally occurs in traces in the Northern German Lowland Area, only. Its frequent and still growing demand for industrial purposes and its release during coal combustion and by vehicular emissions lead to an enrichment of Sb in topsoils. Numerous analyses on heavy metals have been conducted in the urban environment so far, but although Sb can be ecologically harmful and potentially carcinogenic, only few studies on Sb in soils were carried out.
    Description: Materials and methods: Due to the formation of anthropogenic soils by men, especially in the course of industrialization and after World War II, more than 50% of the Berlin soils consist of anthropogenic material like redeposited natural material, debris, waste, or ashes. This composition of soils of the Berlin Metropolitan Area can function as a model for other metropolitan regions of Central Europe. In the urban and peri-urban area of Berlin, analysis of more than 900 topsoil samples has been performed measuring the content of 12 heavy metals and metalloids (Al, As, Cd, Co, Cr, Cu, Fe, Mn, Ni, Pb, Sb, and Zn). As a reference for the natural environment, soil profiles of typical parent rock material have been investigated taking also the regional (0.3 mg/kg), the local background value (0.61 mg/kg), and the baseline value (0.07 mg/kg) for Sb into account.
    Description: Results: By doing so, we could show the spatial distributional pattern of Sb in the Berlin Metropolitan Area and statistically evaluate our results in dependency of land-use, parent material, and soil parameters such as organic carbon content and pH. Thereby, we could prove an average enrichment two to six times over the regional background value. Median Sb content is very low in forest topsoils (0.54 mg/kg) and reaches its maximum in roadside soils (1.75 mg/kg). Technogenic materials, vehicular emissions, industrial processes, and (former) land-use are the predominant factors for Sb enrichment and distribution in the study area. Some single samples show an enrichment of up to 600% of the regional background value for topsoils.
    Description: Conclusion: Our study revealed that the Sb content in the Berlin Metropolitan Area is elevated compared to natural environments. Furthermore, we could demonstrate that Sb is a previously neglected key pollutant, specific to metropolitan areas. Due to the high environmental relevance, further Sb data from selected investigated spaces in other metropolises and specific land-use types are needed to assess the potential environmental risk of Sb in metropolitan areas.
    Description: Humboldt-Universität zu Berlin (1034)
    Keywords: ddc:551.9 ; Trace metals ; Urban geochemistry ; Pollution index ; Technogenic soils ; Antimony (Sb) ; Urban structure type
    Language: English
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  • 99
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    Impact of sedimentation history for As distribution in Late Pleistocene-Holocene sediments in the Hetao Basin, China (2020)
    Springer Berlin Heidelberg
    Details
    Publication Date: 2023-06-08
    Description: Purpose: To understand the impact of geochemical sedimentation history for arsenic (As) distribution in the sediment profiles of the Hetao Basin, we (1) evaluated sediments provenance and variations of weathering intensities, (2) attempted to reconstruct the depositional environments, and (3) explored the As and Fe speciation in the sediments. Combining the information above, different sedimentation facies were distinguished in the vertical profiles.
    Description: Methods: Two sediments cores were drilled up to 80 m depth. Major and trace element compositions, including rare earth elements (REE), were analyzed. Carbon isotope ratios (δ13Corg) of embedded organic matter in the sediments were analyzed by isotope ratio mass spectrometry (IR-MS). Arsenic and Fe speciation of the sediments were determined by sequential extractions.
    Description: Results and discussion: The similar REE geochemistry of rocks from the Lang Mountains and sediments in the Hetao Basin indicated that the sediments originated from the Lang Mountains. The C/N ratio (~ 4 to ~ 10) in combination with δ13Corg (− 27‰ to −2 4‰) suggested that sediments were mainly deposited in aquatic environments. The unconfined aquifer equaled the lacustrine deposit with less intensive weathering during last glacial maximum (LGM). Here, the As content (average, 5.4 mg kg−1) was higher than in the aquifer sediments below (average, 3.6 mg kg−1).
    Description: Conclusion: Higher content of releasable As in combination with paleolake-derived organic matter aquifer sediments probably contributes to higher groundwater As concentration in the unconfined aquifer. This study provides the first insight into the impact of sedimentation history on As distributions in sediment profiles in the Hetao Basin.
    Description: China Scholarship Council http://dx.doi.org/10.13039/501100004543
    Keywords: ddc:551.9 ; Sediment basin ; Sedimentation history ; Arsenic provenance ; Weathering intensities ; Organic carbon isotopic signature ; Arsenic speciation
    Language: English
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  • 100
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    Geochemical focusing and sequestration of manganese during eutrophication of Lake Stechlin (NE Germany) (2020)
    Scholtysik, Grzegorz ; Dellwig, Olaf ; Roeser, Patricia ; [et al.]
    Springer International Publishing
    Details
    Publication Date: 2023-06-17
    Description: Significant sedimentation of manganese (Mn) in form of manganese oxides (MnOx) and the subsequent formation of authigenic calcium-rich rhodochrosite (Mn(Ca)CO3) were observed in the seasonally stratified hard water Lake Stechlin in north-eastern Germany. This manganese enrichment was assumed to be associated with recent eutrophication of the formerly oligotrophic lake. The mechanisms and processes involved were examined by analysing: (i) short sediment cores obtained from seven locations along a depth transect ranging from 69.5 m (the deepest point) to 38 m; (ii) sediment traps located at 20 m and 60 m water depths; (iii) water column profiles; and (iv) porewater profiles at 69.5 m and 58 m depths. Sedimentary Mn enrichment was observed at water depths below 56 m and increased to more than 25 wt% at the deepest site. Between 2010 and 2017, Mn accumulation at the deepest site was 815 g Mn m−2. Transfer of Mn from the shallower towards the deepest parts of the lake was initiated by reductive dissolution of MnOx and diffusion of dissolved Mn from the sediment to the overlying water column. Manganese was then dissipated via turbulent mixing and subsequently oxidised to MnOx before being transported towards the deepest zone. Transformation of the redeposited MnOx to Mn(Ca)CO3 favoured the final burial of Mn. We show that eutrophication and the areal spreading of anoxic conditions may intensify diagenetic processes and cause the spatial redistribution of Mn as well as its effective burial. Contrary to many previous findings, we show that increases of Mn and Mn/Fe can also be used as indicators for increasing anoxic conditions in previously oligotrophic lakes.
    Description: Leibniz-Gemeinschaft http://dx.doi.org/10.13039/501100001664
    Description: Leibniz-Institut für Gewässerökologie und Binnenfischerei (IGB) im Forschungsverbund Berlin e.V. (3473)
    Keywords: ddc:551.9 ; Lacustrine sediments ; Geochemical focusing ; Eutrophication ; Diagenesis ; Rhodochrosite ; Varves
    Language: English
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