Call number:
AWI A12-13-0137
Description / Table of Contents:
The second edition of this internationally acclaimed text presents the latest developments in atmospheric science. It continues to be the premier text for both a rigorous and a complete treatment of the chemistry of the atmosphere, covering such pivotal topics as: chemistry of the stratosphere and troposphere; formation, growth, dynamics, and properties of aerosols; meteorology of air pollution; transport, diffusion, and removal of species in the atmosphere; formation and chemistry of clouds; interaction of atmospheric chemistry and climate; radiative and climatic effects of gases and particles; formulation of mathematical chemical/transport models of the atmosphere. All chapters develop results based on fundamental principles, enabling the reader to build a solid understanding of the science underlying atmospheric processes. Among the new material are three new chapters: Atmospheric radiation and photochemistry, gernal circulation of the atmosphere, and global cycles. In addition, the chapters Stratospheric chemistry, tropospheric chemistry, and organic atmospheric aerosols have been rewritten to reflect the latest findings. Readers familiar with the first edition will discover a text with new structures and new features that greatly aid learning. Many examples are set off in the text to help readers work through the application of concepts. Advanced material has been moved to appendices. Finally, many new problems, coded by degree of difficulty, have been added. A solutions manual is available. Throughly updated and restructured, the second edition of Atmospheric chemistry and physics is an ideal textbook for upper-level undergraduate and graduate students, as well as a reference for researchers in environmental engineering, meteorology, chemistry, and the atmospheric sciences.
Type of Medium:
Monograph available for loan
Pages:
xxviii, 1203 Seiten
,
Illustrationen
Edition:
Second edition
ISBN:
9780471720188
Series Statement:
A Wiley-Interscience publication
Language:
English
Note:
CONTENTS: Preface to the Second Edition. - Preface to the First Edition. - 1 The Atmosphere. - 1.1 History and Evolution of the Earth's Atmosphere. - 1.2 Climate. - 1.3 The Layers of the Atmosphere. - 1.4 Pressure in the Atmosphere. - 1.4.1 Units of Pressure. - 1.4.2 Variation of Pressure with Height in the Atmosphere. - 1.5 Temperature in the Atmosphere. - 1.6 Expressing the Amount of a Substance in the Atmosphere. - 1.7 Spatial and Temporal Scales of Atmospheric Processes. - Problems. - References. - 2 Atmospheric Trace Constituents. - 2.1 Atmospheric Lifetime. - 2.2 Sulfur-Containing Compounds. - 2.2.1 Dimethyl Sulfide (CH3SCH3). - 2.2.2 Carbonyl Sulfide (OCS). - 2.2.3 Sulfur Dioxide (SO2). - 2.3 Nitrogen-Containing Compounds. - 2.3.1 Nitrous Oxide (N2O). - 2.3.2 Nitrogen Oxides (NO* = NO + NO2). - 2.3.3 Reactive Odd Nitrogen (NOy). - 2.3.4 Ammonia (NH3). - 2.4 Carbon-Containing Compounds. - 2.4.1 Classification of Hydrocarbons. - 2.4.2 Methane. - 2.4.3 Volatile Organic Compounds. - 2.4.4 Biogenic Hydrocarbons. - 2.4.5 Carbon Monoxide. - 2.4.6 Carbon Dioxide. - 2.5 Halogen-Containing Compounds. - 2.5.1 Methyl Chloride (CH3C1). - 2.5.2 Methyl Bromide (CH3Br). - 2.6 Atmospheric Ozone. - 2.7 Particulate Matter (Aerosols). - 2.7.1 Stratospheric Aerosol. - 2.7.2 Chemical Components of Tropospheric Aerosol. - 2.7.3 Cloud Condensation Nuclei (CCN). - 2.7.4 Sizes of Atmospheric Particles. - 2.7.5 Sources of Atmospheric Paniculate. - 2.7.6 Carbonaceous Particles. - 2.7.7 Mineral Dust. - 2.8 Emission Inventories. - 2.9 Biomass Burning. - Appendix 2.1 Air Pollution Legislation. - Appendix 2.2 Hazardous Air Pollutants (Air Toxics). - Problems. - References. - 3 Chemical Kinetics. - 3.1 Order of Reaction. - 3.2 Theories of Chemical Kinetics. - 3.2.1 Collision Theory. - 3.2.2 Transition State Theory. - 3.2.3 Potential Energy Surface for a Bimolecular Reaction. - 3.3 The Pseudo-Steady-State Approximation. - 3.4 Reactions of Excited Species. - 3.5 Termolecular Reactions. - 3.6 Chemical Families. - 3.7 Gas-Surface Reactions. - Appendix 3 Free Radicals. - Problems. - References. - 4 Atmospheric Radiation and Photochemistry. - 4.1 Radiation. - 4.1.1 Solar and Terrestrial Radiation. - 4.1.2 Energy Balance for Earth and Atmosphere. - 4.1.3 Solar Variability. - 4.2 Radiative Flux in the Atmosphere. - 4.3 Beer-Lambert Law and Optical Depth. - 4.4 Actinic Flux. - 4.5 Atmospheric Photochemistry. - 4.6 Absorption of Radiation by Atmospheric Gases. - 4.7 Absorption by O2 and O3 122. - 4.8 Photolysis Rate as a Function of Altitude. - 4.9 Photodissociation of O3 to Produce O and O(1D). - 4.10 Photodissociation of NO2. - Problems. - References. - 5 Chemistry of the Stratosphere. - 5.1 Overview of Stratospheric Chemistry. - 5.2 Chapman Mechanism. - 5.3 Nitrogen Oxide Cycles. - 5.3.1 Stratospheric Source of NO* from N2O. - 5.3.2 NO* Cycles. - 5.4 HO* Cycles. - 5.5 Halogen Cycles. - 5.5.1 Chlorine Cycles. - 5.5.2 Bromine Cycles. - 5.6 Reservoir Species and Coupling of the Cycles. - 5.7 Ozone Hole. - 5.7.1 Polar Stratospheric Clouds. - 5.7.2 PSCs and the Ozone Hole. - 5.7.3 Arctic Ozone Hole. - 5.8 Heterogeneous (Nonpolar) Stratospheric Chemistry. - 5.8.1 The Stratospheric Aerosol Layer. - 5.8.2 Heterogeneous Hydrolysis of N2O5. - 5.8.3 Effect of Volcanoes on Stratospheric Ozone. - 5.9 Summary of Stratospheric Ozone Depletion. - 5.10 Transport and Mixing in the Stratosphere. - 5.11 Ozone Depletion Potential. - Problems. - References. - 6 Chemistry of the Troposphere. - 6.1 Production of Hydroxyl Radicals in the Troposphere. - 6.2 Basic Photochemical Cycle of NO2, NO, and O3. - 6.3 Atmospheric Chemistry of Carbon Monoxide. - 6.3.1 Low NO* Limit. - 6.3.2 High NO* Limit. - 6.3.3 Ozone Production Efficiency. - 6.3.4 Theoretical Maximum Yield of Ozone from CO Oxidation. - 6.4 Atmospheric Chemistry of Methane. - 6.5 The NO* and NOy, Families. - 6.5.1 Daytime Behavior. - 6.5.2 Nighttime Behavior. - 6.6 Ozone Budget of the Troposphere and Role of NO*. - 6.6.1 Ozone Budget of the Troposphere. - 6.6.2 Role of NO*. - 6.7 Tropospheric Reservoir Molecules. - 6.7.1 H2O2, CH3OOH, and HONO. - 6.7.2 Peroxyacyl Nitrates (PANs). - 6.8 Relative Roles of VOC and NOx in Ozone Formation. - 6.8.1 Importance of the VOC/NOx Ratio. - 6.8.2 Ozone Isopleth Plot. - 6.9 Simplified Organic/NOx Chemistry. - 6.10 Chemistry of Nonmethane Organic Compounds in the Troposphere. - 6.10.1 Alkanes. - 6.10.2 Alkenes. - 6.10.3 Aromatics. - 6.10.4 Aldehydes. - 6.10.5 Ketones. - 6.10.6 α, β-Unsaturated Carbonyls. - 6.10.7 Ethers. - 6.10.8 Alcohols. - 6.11 Atmospheric Chemistry of Biogenic Hydrocarbons. - 6.12 Atmospheric Chemistry of Reduced Nitrogen Compounds. - 6.12.1 Amines. - 6.12.2 Nitriles. - 6.12.3 Nitrites. - 6.13 Atmospheric Chemistry (Gas Phase) of Sulfur Compounds. - 6.13.1 Sulfur Oxides. - 6.13.2 Reduced Sulfur Compounds (Dimethyl Sulfide). - 6.14 Tropospheric Chemistry of Halogen Compounds. - 6.14.1 Chemical Cycles of Halogen Species. - 6.14.2 Tropospheric Chemistry of CFC Replacements: Hydrofluorocarbons (HFCs) and Hydrochlorofluorocarbons (HCFCs). - Problems. - References. - 7 Chemistry of the Atmospheric Aqueous Phase. - 7.1 Liquid Water in the Atmosphere. - 7.2 Absorption Equilibria and Henry's Law. - 7.3 Aqueous-Phase Chemical Equilibria. - 7.3.1 Water. - 7.3.2 Carbon Dioxide-Water Equilibrium. - 7.3.3 Sulfur Dioxide-Water Equilibrium. - 7.3.4 Ammonia-Water Equilibrium. - 7.3.5 Nitric Acid-Water Equilibrium. - 7.3.6 Equilibria of Other Important Atmospheric Gases. - 7.4 Aqueous-Phase Reaction Rates. - 7.5 S(IV)-S(VI) Transformation and Sulfur Chemistry. - 7.5.1 Oxidation of S(IV) by Dissolved O3. - 7.5.2 Oxidation of S(IV) by Hydrogen Peroxide. - 7.5.3 Oxidation of S(IV) by Organic Peroxides. - 7.5.4 Uncatalyzed Oxidation of S(IV) by O2. - 7.5.5 Oxidation of S(IV) by O2 Catalyzed by Iron and Manganese. - 7.5.6 Comparison of Aqueous-Phase S(IV) Oxidation Paths. - 7.6 Dynamic Behavior of Solutions with Aqueous-Phase Chemical Reactions. - 7.6.1 Closed System. - 7.6.2 Calculation of Concentration Changes in a Droplet with Aqueous-Phase Reactions. - Appendix 7.1 Thermodynamic and Kinetic Data. - Appendix 7.2 Additional Aqueous-Phase Sulfur Chemistry. - 7.A.1 S(IV) Oxidation by the OH Radical. - 7.A.2 Oxidation of S(IV) by Oxides of Nitrogen. - 7.A.3 Reaction of Dissolved SO2 with HCHO. - Appendix 7.3 Aqueous-Phase Nitrite and Nitrate Chemistry. - 7.A.4 NOx Oxidation. - 7.A.5 Nitrogen Radicals. - Appendix 7.4 Aqueous-Phase Organic Chemistry. - Appendix 7.5 Oxygen and Hydrogen Chemistry. - Problems. - References. - 8 Properties of the Atmospheric Aerosol. - 8.1 The Size Distribution Function. - 8.1.1 The Number Distribution nN(Dp). - 8.1.2 The Surface Area, Volume, and Mass Distributions. - 8.1.3 Distributions Based on In Dp and log Dp. - 8.1.4 Relating Size Distributions Based on Different Independent Variables. - 8.1.5 Properties of Size Distributions. - 8.1.6 The Lognormal Distribution. - 8.1.7 Plotting the Lognormal Distribution. - 8.1.8 Properties of the Lognormal Distribution. - 8.2 Ambient Aerosol Size Distributions. - 8.2.1 Urban Aerosols. - 8.2.2 Marine Aerosols. - 8.2.3 Rural Continental Aerosols. - 8.2.4 Remote Continental Aerosols. - 8.2.5 Free Tropospheric Aerosols. - 8.2.6 Polar Aerosols. - 8.2.7 Desert Aerosols. - 8.3 Aerosol Chemical Composition. - 8.4 Spatial and Temporal Variation. - 8.5 Vertical Variation. - Problems. - References. - 9 Dynamics of Single Aerosol Particles. - 9.1 Continuum and Noncontinuum Dynamics: The Mean Free Path. - 9.2 The Drag on a Single Particle: Stokes' Law. - 9.2.1 Corrections to Stokes' Law: The Drag Coefficient. - 9.2.2 Stokes' Law and Noncontinuum Effects: Slip Correction Factor. - 9.3 Gravitational Settling of an Aerosol Particle. - 9.4 Motion of an Aerosol Particle in an External Force Field. - 9.5 Brownian Motion of Aerosol Particles. - 9.5.1 Particle Diffusion. - 9.5.2 Aerosol Mobility and Drift Velocity. - 9.5.3 Mean Free Path of an Aerosol Particle. - 9.6 Aer
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AWI Reading room
Branch Library:
AWI Library
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