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  • 1
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    Berlin : Birkhäuser | Wuppertal : Wuppertal Institut für Klima, Umwelt, Energie
    Publication Date: 2018-11-19
    Keywords: ddc:320
    Repository Name: Wuppertal Institut für Klima, Umwelt, Energie
    Language: German
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  • 2
    Publication Date: 2021-07-26
    Description: We present new geochemical and isotopic data for rock samples from two island arc volcanoes, Erromango and Vulcan Seamount, and from a 500 m thick stratigraphic profile of lava flows exposed on the SW flank of Vate Trough back-arc rift of the New Hebrides Island Arc (NHIA). The basalts from the SW rift flank of Vate Trough have ages of ~0.5 Ma but are geochemically similar to those erupting along the active back-arc rift. The weak subduction component in the back-arc basalts implies formation by decompression melting during early rifting and rifting initiation by tectonic processes rather than by lithosphere weakening by arc magma. Melting beneath Vate Trough is probably caused by chemically heterogeneous and hot mantle that flows in from the North Fiji Basin in the east. The melting zone beneath Vate Trough back-arc is separate from that of the arc front, but a weak slab component suggests fluid transport from the slab. Immobile incompatible element ratios in South NHIA lavas overlap with those of the Vate Trough depleted back-arc basalts, suggesting that enriched mantle components are depleted by back-arc melting during mantle flow. The slab component varies from hydrous melts of subducted sediments in the Central NHIA to fluids from altered basalts in the South NHIA. The volcanism of Erromango shows constant compositions for 5 million years, that is, there is no sign for variable depletion of the mantle or for a change of slab components due to collision of the D'Entrecasteaux Ridge as in lava successions further north.
    Keywords: 551.9 ; subduction zone ; back-arc basalt ; sediment subduction
    Language: English
    Type: article
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  • 3
    Publication Date: 2021-07-23
    Description: Soil water stable isotopes are widely used across disciplines (e.g., hydrology, ecology, soil science, and biogeochemistry). However, the full potential of stables isotopes as a tool for characterizing the origin, flow path, transport processes and residence times of water in different eco-, hydro-, and geological compartments has not yet been exploited. This is mainly due to the large variety of different methods for pore water extraction. While recent work has shown that matric potential affects the equilibrium fractionation, little work has examined how different water retention characteristics might affect the sampled water isotopic composition. Here, we present a simple laboratory experiment with two well-studied standard soils differing in their physico-chemical properties (e.g., clayey loam and silty sand). Samples were sieved, oven-dried and spiked with water of known isotopic composition to full saturation. For investigating the effect of water retention characteristics on the extracted water isotopic composition, we used pressure extractors to sample isotopically labelled soil water along the pF curve. After pressure extraction, we further extracted the soil samples via cryogenic vacuum extraction. The null hypothesis guiding our work was that water held at different tensions shows the same isotopic composition. Our results showed that the sampled soil water differed isotopically from the introduced isotopic label over time and sequentially along the pF curve. Our and previous studies suggest caution in interpreting isotope results of extracted soil water and a need to better characterize processes that govern isotope fractionation with respect to soil water retention characteristics. In the future, knowledge about soil water retention characteristics with respect to soil water isotopic composition could be applied to predict soil water fractionation effects under natural and non-stationary conditions. In this regard, isotope retention characteristics as an analog to water retention characteristics have been proposed as a way forward since matric potential affects the equilibrium fractionation between the bound water and the water vapour.
    Keywords: 551.9 ; pF value ; soil water isotopes ; soil water pool ; δ2H and δ18O analysis
    Language: English
    Type: article
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  • 4
    Publication Date: 2021-07-26
    Description: Garnet of eclogite (formerly termed garnet clinopyroxenite) hosted in lenses of orogenic garnet peridotite from the Granulitgebirge, NW Bohemian Massif, contains unique inclusions of granitic melt, now either glassy or crystallized. Analysed glasses and re-homogenized inclusions are hydrous, peraluminous, and enriched in highly incompatible elements characteristic of the continental crust such as Cs, Li, B, Pb, Rb, Th, and U. The original melt thus represents a pristine, chemically evolved metasomatic agent, which infiltrated the mantle via deep continental subduction during the Variscan orogeny. The bulk chemical composition of the studied eclogites is similar to that of Fe-rich basalt and the enrichment in LILE and U suggest a subduction-related component. All these geochemical features confirm metasomatism. In comparison with many other garnet+clinopyroxene-bearing lenses in peridotites of the Bohemian Massif, the studied samples from Rubinberg and Klatschmühle are more akin to eclogite than pyroxenites, as reflected in high jadeite content in clinopyroxene, relatively low Mg, Cr, and Ni but relatively high Ti. However, trace elements of both bulk rock and individual mineral phases show also important differences making these samples rather unique. Metasomatism involving a melt requiring a trace element pattern very similar to the composition reported here has been suggested for the source region of rocks of the so-called durbachite suite, that is, ultrapotassic melanosyenites, which are found throughout the high-grade Variscan basement. Moreover, the Th, U, Pb, Nb, Ta, and Ti patterns of these newly studied melt inclusions (MI) strongly resemble those observed for peridotite and its enclosed pyroxenite from the T-7 borehole (Staré, České Středhoři Mountains) in N Bohemia. This suggests that a similar kind of crustal-derived melt also occurred here. This study of granitic MI in eclogites from peridotites has provided the first direct characterization of a preserved metasomatic melt, possibly responsible for the metasomatism of several parts of the mantle in the Variscides.
    Keywords: 551.9 ; clinopyroxenite ; eclogite ; melt inclusions ; metasomatism ; orogenic peridotite
    Language: English
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  • 5
    Publication Date: 2021-07-27
    Description: Three synthetic reference glasses were prepared by directly fusing and stirring 3.8 kg of high-purity oxide powders to provide reference materials for microanalytical work. These glasses have andesitic major compositions and are doped with fifty-four trace elements in nearly identical abundance (500, 50, 5 µg g−1) using oxide powders or element solutions, and are named ARM-1, 2 and 3, respectively. We further document that sector-field (SF) ICP-MS (Element 2 or Element XR) is capable of sweeping seventy-seven isotopes (from 7Li to 238U, a total of sixty-eight elements) in 1 s and, thus, is able to quantify up to sixty-eight elements by laser sampling. Micro- and bulk analyses indicate that the glasses are homogeneous with respect to major and trace elements. This paper provides preliminary data for the ARM glasses using a variety of analytical techniques (EPMA, XRF, ICP-OES, ICP-MS, LA-Q-ICP-MS and LA-SF-ICP-MS) performed in ten laboratories. Discrepancies in the data of V, Cr, Ni and Tl exist, mainly caused by analytical limitations. Preliminary reference and information values for fifty-six elements were calculated with uncertainties [2 relative standard error (RSE)] estimated in the range of 1–20%.
    Keywords: 551.9 ; glass reference materials ; microanalysis ; sector-field ICP-MS ; LA-ICP-MS ; multiple-element quantification
    Language: English
    Type: article
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  • 6
    Publication Date: 2021-07-27
    Description: Basalts are ubiquitous in volcanic systems on several planetary bodies, including the Earth, Mars, Venus, and Jupiter's moon Io, and are commonly associated with sulfur dioxide (SO2) degassing. We present the results of an experimental study of reactions between SO2 and basaltic glasses. We examined Fe-free basalt, and Fe-bearing tholeiitic and alkali basalts with a range of Fe3+/Fetotal (0.05 to 0.79) that encompass the oxygen fugacities proposed for most terrestrial planetary bodies. Tholeiitic and alkali basalts were exposed to SO2 at 600, 700, and 800 °C for 1 hr and 24 hr. Surface coatings formed on the reacted basalts; these contain CaSO4, MgSO4, Na2SO4, Na2Ca(SO4)2, Fe2O3, Fe3O4, Fe-Ti-(Al)-oxides, and TiO2. Additionally, the SO2-basalt reaction drives nucleation of crystalline phases in the substrate to form pyroxenes and possible Fe-oxides. A silica-rich layer forms between the substrate and sulfate coatings. More oxidized basalts may readily react with SO2 to form coatings dominated by large Ca-sulfate and oxide grains. On less oxidized basalts (NNO−1.5 to NNO−5), reactions with SO2 will form thin, fine-grained aggregates of sulfates; such materials are less readily detected by spectroscopy and spectrometry techniques. In contrast, in very reduced basalts (lower than NNO−5), typical of the Moon and Mercury, SO2 is typically a negligible component in the magmatic gas, and sulfides are more likely.
    Keywords: 552.26 ; 551.9 ; gas-solid reaction ; sulfur dioxide ; planetary crust ; sulfate ; volcanology ; geochemistry
    Language: English
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  • 7
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    Wuppertal : Wuppertal Institut für Klima, Umwelt, Energie
    Publication Date: 2014-08-15
    Keywords: ddc:320
    Repository Name: Wuppertal Institut für Klima, Umwelt, Energie
    Language: English
    Type: contributiontoperiodical , doc-type:contributionToPeriodical
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  • 8
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    Wuppertal : Wuppertal Institut für Klima, Umwelt, Energie
    Publication Date: 2018-11-21
    Description: This paper claims that countries of the North must develop a new model of wealth - one less harmful to the environment and capable of being applied throughout the world. There are reasons to be hopeful they will do so: first, they have the means at their disposal; second, it is a misconception that environmental protection is a cost; and third, there is mounting pressure for change as indicated by air, water and soil quality data. The challenge is to move the emphasis away from end-of-the-pipe pollution control to improving resource productivity. The best way of doing this is through the imposition of "green taxes" to raise resource prices. If governments compensate by cutting other taxes to make the change revenue-neutral, there would be real benefits to the environment and the economy, particularly in developing countries.
    Keywords: ddc:320
    Repository Name: Wuppertal Institut für Klima, Umwelt, Energie
    Language: English
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  • 9
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    Wuppertal : Wuppertal Institut für Klima, Umwelt, Energie
    Publication Date: 2016-04-28
    Keywords: ddc:600
    Repository Name: Wuppertal Institut für Klima, Umwelt, Energie
    Language: German
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  • 10
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    Mülheim : IWW | Wuppertal : Wuppertal Institut für Klima, Umwelt, Energie
    Publication Date: 2014-08-15
    Keywords: ddc:320
    Repository Name: Wuppertal Institut für Klima, Umwelt, Energie
    Language: German
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  • 11
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    München : Beck | Wuppertal : Wuppertal Institut für Klima, Umwelt, Energie
    Publication Date: 2014-08-15
    Keywords: ddc:320
    Repository Name: Wuppertal Institut für Klima, Umwelt, Energie
    Language: German
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  • 12
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    Wuppertal : Wuppertal Institut für Klima, Umwelt, Energie | Wuppertal : Wuppertal Institut für Klima, Umwelt, Energie
    Publication Date: 2016-04-28
    Keywords: ddc:600
    Repository Name: Wuppertal Institut für Klima, Umwelt, Energie
    Language: German
    Type: workingpaper , doc-type:workingPaper
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  • 13
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    Washington, DC : Island Press | Wuppertal : Wuppertal Institut für Klima, Umwelt, Energie
    Publication Date: 2016-04-28
    Keywords: ddc:600
    Repository Name: Wuppertal Institut für Klima, Umwelt, Energie
    Language: English
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  • 14
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    Wuppertal : Wuppertal Institut für Klima, Umwelt, Energie
    Publication Date: 2016-04-28
    Keywords: ddc:320
    Repository Name: Wuppertal Institut für Klima, Umwelt, Energie
    Language: German
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  • 15
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    Wuppertal : Wuppertal Institut für Klima, Umwelt, Energie
    Publication Date: 2016-04-28
    Keywords: ddc:600
    Repository Name: Wuppertal Institut für Klima, Umwelt, Energie
    Language: German
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  • 16
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    Wuppertal : Wuppertal Institut für Klima, Umwelt, Energie | Wuppertal : Wuppertal Institut für Klima, Umwelt, Energie
    Publication Date: 2016-04-28
    Keywords: ddc:320
    Repository Name: Wuppertal Institut für Klima, Umwelt, Energie
    Language: German
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  • 17
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    Wuppertal : Wuppertal Institut für Klima, Umwelt, Energie
    Publication Date: 2018-03-26
    Keywords: ddc:320
    Repository Name: Wuppertal Institut für Klima, Umwelt, Energie
    Language: German
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  • 18
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    Frankfurt : Insel-Verl. | Wuppertal : Wuppertal Institut für Klima, Umwelt, Energie
    Publication Date: 2014-08-15
    Keywords: ddc:320
    Repository Name: Wuppertal Institut für Klima, Umwelt, Energie
    Language: German
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  • 19
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    Wuppertal : Wuppertal Institut für Klima, Umwelt, Energie
    Publication Date: 2016-04-28
    Keywords: ddc:320
    Repository Name: Wuppertal Institut für Klima, Umwelt, Energie
    Language: German
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  • 20
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    Wuppertal : Wuppertal Institut für Klima, Umwelt, Energie
    Publication Date: 2014-08-15
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    Repository Name: Wuppertal Institut für Klima, Umwelt, Energie
    Language: German
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  • 21
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    Wuppertal : Wuppertal Institut für Klima, Umwelt, Energie
    Publication Date: 2016-04-28
    Keywords: ddc:320
    Repository Name: Wuppertal Institut für Klima, Umwelt, Energie
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  • 22
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    Wuppertal : Wuppertal Institut für Klima, Umwelt, Energie | Wuppertal : Wuppertal Institut für Klima, Umwelt, Energie
    Publication Date: 2014-08-15
    Keywords: ddc:320
    Repository Name: Wuppertal Institut für Klima, Umwelt, Energie
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  • 23
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    Wuppertal : Wuppertal Institut für Klima, Umwelt, Energie
    Publication Date: 2016-04-28
    Keywords: ddc:600
    Repository Name: Wuppertal Institut für Klima, Umwelt, Energie
    Language: German
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  • 24
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    Wuppertal : Wuppertal Institut für Klima, Umwelt, Energie
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    Keywords: ddc:600
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  • 25
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    Wuppertal : Wuppertal Institut für Klima, Umwelt, Energie
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  • 26
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    Wuppertal : Wuppertal Institut für Klima, Umwelt, Energie
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    Keywords: ddc:320
    Repository Name: Wuppertal Institut für Klima, Umwelt, Energie
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  • 27
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    München : Beck | Wuppertal : Wuppertal Institut für Klima, Umwelt, Energie
    Publication Date: 2016-04-28
    Keywords: ddc:320
    Repository Name: Wuppertal Institut für Klima, Umwelt, Energie
    Language: German
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  • 28
    Publication Date: 2018-03-26
    Keywords: ddc:600
    Repository Name: Wuppertal Institut für Klima, Umwelt, Energie
    Language: German
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  • 29
    Publication Date: 2016-04-28
    Keywords: ddc:320
    Repository Name: Wuppertal Institut für Klima, Umwelt, Energie
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  • 30
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    Rehburg-Loccum : Evang. Akad. Loccum | Wuppertal : Wuppertal Institut für Klima, Umwelt, Energie
    Publication Date: 2016-04-28
    Keywords: ddc:320
    Repository Name: Wuppertal Institut für Klima, Umwelt, Energie
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  • 31
    Publication Date: 2016-04-28
    Keywords: ddc:600
    Repository Name: Wuppertal Institut für Klima, Umwelt, Energie
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  • 32
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    Wuppertal : Wuppertal Institut für Klima, Umwelt, Energie
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  • 33
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    Wuppertal : Wuppertal Institut für Klima, Umwelt, Energie
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  • 34
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    Wuppertal : Wuppertal Institut für Klima, Umwelt, Energie | Wuppertal : Wuppertal Institut für Klima, Umwelt, Energie
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  • 35
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    Frankfurt am Main : Fischer | Wuppertal : Wuppertal Institut für Klima, Umwelt, Energie
    Publication Date: 2014-08-15
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  • 36
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  • 37
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    Wuppertal : Wuppertal Institut für Klima, Umwelt, Energie
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  • 38
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    Wuppertal : Wuppertal Institut für Klima, Umwelt, Energie
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  • 39
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    Rehburg-Loccum : Evang. Akad. Loccum | Wuppertal : Wuppertal Institut für Klima, Umwelt, Energie
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  • 40
    Publication Date: 2018-04-18
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    Repository Name: Wuppertal Institut für Klima, Umwelt, Energie
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  • 41
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    Wuppertal : Wuppertal Institut für Klima, Umwelt, Energie | Wuppertal : Wuppertal Institut für Klima, Umwelt, Energie
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    Keywords: ddc:600
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  • 42
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  • 43
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    Wuppertal : Wuppertal Institut für Klima, Umwelt, Energie | Wuppertal : Wuppertal Institut für Klima, Umwelt, Energie
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  • 44
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  • 45
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    Rehburg-Loccum : Evang. Akad. Loccum | Wuppertal : Wuppertal Institut für Klima, Umwelt, Energie
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    Keywords: ddc:320
    Repository Name: Wuppertal Institut für Klima, Umwelt, Energie
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    Wuppertal : Wuppertal Institut für Klima, Umwelt, Energie | Wuppertal : Wuppertal Institut für Klima, Umwelt, Energie
    Publication Date: 2016-04-28
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  • 47
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    Marburg : Metropolis-Verl. | Wuppertal : Wuppertal Institut für Klima, Umwelt, Energie
    Publication Date: 2016-04-28
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  • 48
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    London : Earthscan | Wuppertal : Wuppertal Institut für Klima, Umwelt, Energie
    Publication Date: 2014-08-15
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  • 49
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    Wuppertal : Wuppertal Institut für Klima, Umwelt, Energie
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  • 50
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    Wuppertal : Wuppertal Institut für Klima, Umwelt, Energie
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    Wuppertal : Wuppertal Institut für Klima, Umwelt, Energie | Wuppertal : Wuppertal Institut für Klima, Umwelt, Energie
    Publication Date: 2016-04-28
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    Wuppertal : Wuppertal Institut für Klima, Umwelt, Energie
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  • 53
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    Wuppertal : Wuppertal Institut für Klima, Umwelt, Energie
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  • 54
    Publication Date: 2016-04-28
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    Repository Name: Wuppertal Institut für Klima, Umwelt, Energie
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  • 55
    Publication Date: 2021-07-23
    Description: The in situ measurement of Sr isotopes in carbonates by MC-ICP-MS is limited by the availability of suitable microanalytical reference materials (RMs), which match the samples of interest. Whereas several well-characterised carbonate reference materials for Sr mass fractions 〉 1000 µg g−1 are available, there is a lack of well-characterised carbonate microanalytical RMs with lower Sr mass fractions. Here, we present a new synthetic carbonate nanopowder RM with a Sr mass fraction of ca. 500 µg g−1 suitable for microanalytical Sr isotope research (‘NanoSr’). NanoSr was analysed by both solution-based and in situ techniques. Element mass fractions were determined using EPMA (Ca mass fraction), as well as laser ablation and solution ICP-MS in different laboratories. The 87Sr/86Sr ratio was determined by well-established bulk methods for Sr isotope measurements and is 0.70756 ± 0.00003 (2s). The Sr isotope microhomogeneity of the material was determined by LA-MC-ICP-MS, which resulted in 87Sr/86Sr ratios of 0.70753 ± 0.00007 (2s) and 0.70757 ± 0.00006 (2s), respectively, in agreement with the solution data within uncertainties. Thus, this new reference material is well suited to monitor and correct microanalytical Sr isotope measurements of low-Sr, low-REE carbonate samples. NanoSr is available from the corresponding author.
    Keywords: 551.9 ; strontium isotopes ; laser ablation ; reference material ; calcium carbonate ; nanopowder ; MC-ICP-MS
    Language: English
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  • 56
    Publication Date: 2021-07-21
    Description: The continuous improvement of analytical procedures using multi-collector technologies in ICP-mass spectrometry has led to an increased demand for isotope standards with improved homogeneity and reduced measurement uncertainty. For magnesium, this has led to a variety of available standards with different quality levels ranging from artefact standards to isotope reference materials certified for absolute isotope ratios. This required an intercalibration of all standards and reference materials, which we present in this interlaboratory comparison study. The materials Cambridge1, DSM3, ERM-AE143, ERM-AE144, ERM-AE145, IRMM-009 and NIST SRM 980 were cross-calibrated with expanded measurement uncertainties (95% confidence level) of less than 0.030‰ for the δ25/24Mg values and less than 0.037‰ for the δ26/24Mg values. Thus, comparability of all magnesium isotope delta (δ) measurements based on these standards and reference materials is established. Further, ERM-AE143 anchors all magnesium δ-scales to absolute isotope ratios and therefore establishes SI traceability, here traceability to the SI base unit mole. This applies especially to the DSM3 scale, which is proposed to be maintained. With ERM-AE144 and ERM-AE145, which are product and educt of a sublimation–condensation process, for the first time a set of isotope reference materials is available with a published value for the apparent triple isotope fractionation exponent θapp, the fractionation relationship ln α(25/24Mg)/ln α(26/24Mg).
    Keywords: 551.9 ; delta scale ; traceability ; scale anchor ; absolute isotope ratio ; comparability ; triple isotope fractionation
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  • 57
    Publication Date: 2021-03-30
    Keywords: ddc:600
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  • 58
    Publication Date: 2021-05-18
    Description: Roadmaps for India's energy future foresee that coal power will continue to play a considerable role until the middle of the 21st century. Among other options, carbon capture and storage (CCS) is being considered as a potential technology for decarbonising the power sector. Consequently, it is important to quantify the relative benefits and trade-offs of coal-CCS in comparison to its competing renewable power sources from multiple sustainability perspectives. In this paper, we assess coal-CCS pathways in India up to 2050 and compare coal-CCS with conventional coal, solar PV and wind power sources through an integrated assessment approach coupled with a nexus perspective (energy-cost-climate-water nexus). Our levelized costs assessment reveals that coal-CCS is expensive and significant cost reductions would be needed for CCS to compete in the Indian power market. In addition, although carbon pricing could make coal-CCS competitive in relation to conventional coal power plants, it cannot influence the lack of competitiveness of coal-CCS with respect to renewables. From a climate perspective, CCS can significantly reduce the life cycle GHG emissions of conventional coal power plants, but renewables are better positioned than coal-CCS if the goal is ambitious climate change mitigation. Our water footprint assessment reveals that coal-CCS consumes an enormous volume of water resources in comparison to conventional coal and, in particular, to renewables. To conclude, our findings highlight that coal-CCS not only suffers from typical new technology development related challenges - such as a lack of technical potential assessments and necessary support infrastructure, and high costs - but also from severe resource constraints (especially water) in an era of global warming and the competition from outperforming renewable power sources. Our study, therefore, adds a considerable level of techno-economic and environmental nexus specificity to the current debate about coal-based large-scale CCS and the low carbon energy transition in emerging and developing economies in the Global South.
    Keywords: ddc:600
    Repository Name: Wuppertal Institut für Klima, Umwelt, Energie
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  • 59
    Publication Date: 2021-05-18
    Description: Water availability plays an important role in the expansion planning of utility-scale solar power plants, especially in the arid regions of the Middle East and North Africa. Although these power plants usually account for only a small fraction of local water demand, competition for water resources between communities, farmers, companies, and power suppliers is already emerging and is likely to intensify in future. Despite this, to date there has been a lack of comprehensive studies analyzing interdependencies and potential conflicts between energy and water at local level. This study addresses this research gap and examines the linkages between water resources and energy technologies at local level based on a case study conducted in Ouarzazate, Morocco, where one of the largest solar power complexes in the world was recently completed. To better understand the challenges faced by the region in light of increased water demand and diminishing water supply, a mixed-method research design was applied to integrate the knowledge of local stakeholders through a series of workshops. In a first step, regional socio-economic water demand scenarios were developed and, in a second step, water saving measures to avoid critical development pathways were systematically evaluated using a participatory multi-criteria evaluation approach. The results are a set of water demand scenarios for the region and a preferential ranking of water saving measures that could be drawn upon to support decision-making relating to energy and water development in the region.
    Keywords: ddc:600
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  • 60
    Publication Date: 2021-05-21
    Description: This article aims to analyse the potential for international climate governance to promote the decarbonisation of land transport. It first summarises challenges and barriers that impede the transformation of the sector. On this basis, the article discusses how international governance could potentially assist with overcoming these barriers and mobilising potentials. Subsequently, the article analyses to what extent existing international governance institutions deliver on the potential identified. The analysis finds that while there is a large number of international institutions trying to promote the decarbonisation of land transport, none of them emerge saliently as hubs or core institutions. There is a substantial amount of activity to generate and disseminate knowledge and learning, but the potential for providing guidance and signal, setting rules, providing transparency/accountability and means of implementation could be further exploited. The article concludes with suggestions on how international governance may be strengthened.
    Keywords: ddc:320
    Repository Name: Wuppertal Institut für Klima, Umwelt, Energie
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  • 61
    Publication Date: 2021-05-18
    Description: Climate change is a transformation challenge. It requires the transformation of a patchwork of independent socio-technical systems. These complex systems have their own specific challenges and path dependencies. Lukas Hermwille introduces a perspective on socio-technical complexity to the study of global climate governance and asks what governance arrangements on the international level, in particular the United Nations Framework Convention of Climate Change (UNFCCC) and its Paris Agreement, can offer to facilitate and foster the required transformational change. His work shows the importance of the discursive power of global climate governance, shifting the expectations and visions of the future of key actors and, as a corollary, changing their investment decisions of today towards a more sustainable future.
    Keywords: ddc:320
    Repository Name: Wuppertal Institut für Klima, Umwelt, Energie
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  • 62
    Publication Date: 2021-05-06
    Description: Agriculture is an economic sector with massive impact on biodiversity and agrobiodiversity. Sustainable diets represent a critical policy leverage and a realistic opportunity to reduce the environmental impact of the agro-food sector while improving human health at the same time. Eating out is an increasingly common habit for many consumers and, by offering sustainable dishes, catering companies can play a central role. To do this, they need to understand and correctly assess the sustainability of their food portfolio, but assessment tools are not well established yet. The NAHGAST project, of which this study was part, developed and tested a sustainability assessment tool for catering companies based on concrete targets defined per meal. This study addresses the lack of methods to evaluate the impact of food on biodiversity, with a particular focus on agrobiodiversity. The work illustrates a context-specific application of an enhanced DPSIR model to structure information and select indicators, and proposes a transdisciplinary use of existing metrics. Further research is needed in order to define scientifically sound target values or sustainability ranges for each indicator per meal, in order to calculate them. Strengths and limits of the study are discussed.
    Keywords: ddc:600
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  • 63
    Publication Date: 2021-05-18
    Description: Non-residential buildings in the European Union consume more than one third of the building sector's total. Many non-residential buildings are owned by municipalities. This paper reports about an energy saving competition that was carried out in 91 municipal buildings in eight EU member states in 2019. For each public building an energy team was formed. The energy teams' activities encompassed motivating changes in the energy use behaviour of employees and small investments. Two challenges added an element of gamification to the energy saving competition. To assess the success of the energy saving competition, an energy performance baseline was calculated using energy consumption data of each public building from previous years. Energy consumption in the competition year was monitored on a monthly base. After the competition the top energy savers from each country were determined by the percentage-based reduction of energy consumption compared to the baseline. On average, the buildings had an electricity and heat consumption in 2019 that was about 8 % and 7 %, respectively, lower than the baseline. As an additional data source for the evaluation, a survey among energy team members was conducted at the beginning and after the energy competition. Support from superiors, employee interest and motivation and behaviour change as assessed by energy team members show a positive, if weak or moderate, correlation with changes in electricity consumption, but not with changes in heat consumption.
    Keywords: ddc:600
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  • 64
    Publication Date: 2021-04-28
    Description: Die Stadt Mannheim kann spätestens bis zum Jahr 2050 vollständig klimaneutral werden und damit einen maßgeblichen Beitrag zur Umsetzung der Ziele des Pariser Klimaabkommens auf kommunaler Ebene leisten. Das ist das zentrale Ergebnis der vorliegenden "Energierahmenstudie Mannheim", die das Energieunternehmen MVV in Abstimmung mit der Stadt beim Wuppertal Institut in Auftrag gegeben hat. Die Studie untersucht und beschreibt die Handlungsmöglichkeiten und Umsetzungsvoraussetzungen in den Bereichen Strom, Wärme, Verkehr und Industrie.
    Keywords: ddc:600
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  • 65
    Publication Date: 2021-05-10
    Description: Nowadays, high expectations are set for a digitally enabled circular economy (CE), to enhance resource efficiency. Tracing, tracking, and storing information is most important for this. In this paper, the application of Internet of Things (IoT) and Distributed Ledger Technology (Blockchain) are hence discussed by presenting the case of professional Electrical and Electronic Equipment (EEE) in Italy. Within the context of CE, prevention of electronic waste (WEEE) is extremely relevant as it is a fast-growing waste stream, and the products contain environmentally damaging substances as well as valuable and rare materials. The use of a proper combination of IoT and blockchain can help the producers to keep control on products until EEE end-of-life, while promoting CE strategies and supporting decision-making. Based on the outcomes of five interviews conducted in 2019 to companies of the EEE sector, potential improvements in the EEE end-of-use management are discussed. After providing the definition of requirements for both the technical solution and its testing are provided, three solution variations and the related business models are created and presented, as well as considerations on their environmental and economic impacts. The study shows how digital technologies can support the appropriate and circular management of EEE products and WEEE.
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  • 66
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    Stuttgart : Kohlhammer
    Publication Date: 2021-07-05
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    Language: German
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  • 67
    Publication Date: 2021-05-06
    Description: Electronics containing growing quantities of high value and critical metals are increasingly used in automobiles. The conventional treatment practice for end-of-life vehicles (ELV) is shredding after de-pollution and partial separation of spare parts. Despite opportunities for resource recovery, the selective separation of components containing relevant amounts of critical metals for the purpose of material recycling is not commonly implemented. This article is aimed to contribute to recycling strategies for future critical metal quantities and the role of extended material recovery from ELVs. The study examines the economic feasibility of dismantling electronic components from ELVs for high value metal recycling. The results illustrate the effects of factors as dismantling time, labour costs and logistics on the economic potential of resource recovery from ELVs. Manual dismantling is profitable for only a few components at the higher labour costs in western/northern parts of Europe and applicable material prices, including the inverter for hybrid vehicles, oxygen sensor, side assistant sensor, distance and near distance sensors. Depending on the vehicle model, labour costs and current material prices, manual dismantling can also be cost-efficient for also some other such as the heating blower, generator, starter, engine and transmission control, start/stop motor, drive control, infotainment and chassis control.
    Keywords: ddc:600
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  • 68
    Publication Date: 2021-05-21
    Description: This article develops a sectoral approach to the analysis of global climate governance. This approach advances the assessment of global climate governance by focusing on complexes of intergovernmental and transnational institutions co-governing key socio-technical sectoral systems. The actual and potential contribution of these sectoral institutional complexes to advancing decarbonization can be assessed according to five key governance functions: (1) providing guidance and signal to actors, (2) setting rules to facilitate collective action, (3) enhancing transparency and accountability, (4) offering support (finance, technology, capacity-building), and (5) promoting knowledge and learning. On this basis, we can assess the potential of international cooperation to address the challenges specific sectoral systems face in the climate transition as well as the extent to which existing sectoral institutional complexes deliver on this potential. This provides a solid starting point for developing options for filling identified gaps and enhancing the effectiveness of global climate governance.
    Keywords: ddc:320
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  • 69
    Publication Date: 2021-07-28
    Description: Cities and urban consumers play a central role in the transition to a decarbonized society. Building on existing studies that identify the significant contributions of lifestyle changes, this study proposes a practical methodology for modeling and exploring city-specific carbon footprint reduction pathways through lifestyle changes to decarbonization. It uses an input-output approach with mixed-unit consumption data and the concept of adoption rates, which is applicable to multiple cities with widely available subnational household consumption data. This paper illustrates the use of this methodology by exploring the consumption-based mitigation pathways of 52 Japanese cities with 65 lifestyle change options covering mobility, housing, food, consumer goods, and leisure domains. The results revealed that city-specific impacts of a variety of lifestyle change options can differ by as much as a factor of five among cities, even in the urban context within the same country. Due to this city-level heterogeneity, the priority options of decarbonized lifestyles, such as among shared mobility, low-carbon diets, and longevity of consumer goods, have shifted between cities. The analysis suggests that ambitious urban lifestyle changes can potentially reduce their carbon footprints to meet the 1.5 ℃ target. However, due to the overlaps of mitigation potentials between multiple lifestyle change options, the necessary levels of adoption and coverage are extensive (i.e., adoption rates of 0.6-0.9). Importantly, adopting lifestyle changes with an efficiency strategy (e.g., the introduction of end-use technologies) or sufficiency strategy (e.g., behavioral changes in consumption amounts and modes) alone is not enough; the only way to succeed is through the combination of both strategies. This paper calls for a target-based exploration and identification of city-specific priorities of lifestyle change options to facilitate consumption-oriented mitigation policies and stakeholder actions to address the climate impacts of urban consumption.
    Keywords: ddc:600
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  • 70
    Publication Date: 2021-07-28
    Description: This paper examines the Global Climate Action Agenda (GCAA) and discusses options to improve sub- and non-state involvement in post-2020 climate governance. A framework that stimulates sub- and non-state action is a necessary complement to national governmental action, as the latter falls short of achieving low-carbon and climate-resilient development as envisaged in the Paris Agreement. Applying design principles for an ideal-type orchestration framework, we review literature and gather expert judgements to assess whether the GCAA has been collaborative, comprehensive, evaluative and catalytic. Results show that there has been greater coordination among orchestrators, for instance in the organization of events. However, mobilization efforts remain event-driven and too little effort is invested in understanding the progress of sub- and non-state action. Data collection has improved, although more sophisticated indicators are needed to evaluate climate and sustainable development impacts. Finally, the GCAA has recorded more action, but relatively little by actors in developing countries. As the world seeks to recover from the COVID-19 crisis and enters a new decade of climate action, the GCAA could make a vital contribution in challenging times by helping governments keep and enhance climate commitments; strengthening capacity for sub- and non-state action; enabling accountability; and realizing sustainable development.
    Keywords: ddc:320
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  • 71
    Publication Date: 2021-08-06
    Description: Energy sufficiency is one of the three energy sustainability strategies, next to energy efficiency and renewable energies. We analyse to what extent European governments follow this strategy, by conducting a systematic document analysis of all available European National Energy and Climate Plans (NECPs) and Long-Term Strategies (LTSs). We collect and categorise a total of 230 sufficiency-related policy measures, finding large differences between countries. We find most sufficiency policies in the transport sector, when classifying also modal shift policies to change the service quality of transport as sufficiency policies. Types of sufficiency policy instruments vary considerably from sector to sector, for instance the focus on financial incentives and fiscal instruments in the mobility sector, information in the building sector, and financial incentive/tax instruments in cross-sectoral application. Regulatory instruments currently play a minor role for sufficiency policy in the national energy and climate plans of EU member states. Similar to energy efficiency in recent decades, sufficiency still largely referred to as micro-level individual behaviour change or necessary exogenous trends that will need to take place. It is not treated yet as a genuine field of policy action to provide the necessary framework for enabling societal change.
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  • 72
    Publication Date: 2021-05-18
    Keywords: ddc:320
    Repository Name: Wuppertal Institut für Klima, Umwelt, Energie
    Language: German
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  • 73
    Publication Date: 2021-05-06
    Description: Die geopolitische Situation ist im Umbruch. Wir sind im Übergang zu einer multipolaren Situation, die Hegemonialkonkurrenten organisieren sich in Blöcken. Die Stratifizierung des Raumes der Wirtschaft, "Globalisierung" genannt, verliert ihre Basis, die strikte Trennung von der Politik der Hegemonialkonkurrenten. Wirtschaft wird nun in Dienst genommen für politische Ziele. Das erfordert Aufrüstung in Mitteln der Wirtschaftskriegsführung. China und die USA sind darin weit vorangegangen. Die EU hat entschieden, ihrerseits nachzurüsten, um auf Augenhöhe zu kommen.
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  • 74
    Publication Date: 2021-05-21
    Description: This concluding article derives six major findings from the contributions to this special issue. First, the barriers and challenges to decarbonisation vary significantly across sectoral systems. Second, and similarly, the need and potential for the five functions of international governance institutions to contribute to effective climate protection also vary widely. Third, while the pattern is uneven, there is a general undersupply of international climate governance. Fourth, the sectoral analyses confirm that the UNFCCC and Paris Agreement play an important overarching role but remain limited in advancing effective sectoral governance. Fifth, while non-environmental institutions may present important barriers to decarbonisation, more synergistic effects are possible. Sixth, our sectoral approach provides a sound basis on which to identify sector-specific policy options. The paper then offers reflections on the merits and limitations of the sectoral approach, before identifying avenues for future research to further advance the agenda.
    Keywords: ddc:320
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  • 75
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    Manno : University of Applied Sciences and Arts of Southern Switzerland
    Publication Date: 2021-05-21
    Description: To what extent can designers direct their professional practices towards serving the common good? Design constitutes itself anew with every project. Each project is both conditioned and made possible through a unique constellation of actors, timeframes, objectives, skills, etc. which arise from both social values and political agendas. We discuss the different approaches of two selected design projects by the authors, and the respective strategies and methods. While the designers' ambition in both projects was certainly to change an existing situation into a preferred one - the first by the means of interactive user engagement, the second through the idea of semi-finished product semantics - we emphasize on the challenges and ambiguities arising from the evolutionary process of design, aiming at the common good. Eventually we conclude that design processes can serve as a tool to debate rather than create the common good.
    Keywords: ddc:600
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  • 76
    Publication Date: 2021-05-06
    Description: Flexible, system-oriented operating strategies are becoming increasingly important in terms of achieving a climate-neutral energy system transformation. Solid-oxide electrolysis (SOEC) can play an important role in the production of green synthesis gas from renewable energy in the future. Therefore, it is important to investigate the extent to which SOEC can be used flexibly and which feedback effects and constraints must be taken into account. In this study, we derived a specific load profile from an energy turnaround scenario that supports the energy system. SOEC short-stacks were operated and we investigated the impact that the load profile has on electrical stack performance and stack degradation as well as the product gas composition by means of Fourier-transform infrared spectroscopy. The stacks could follow the grid-related requirement profiles of secondary control power and minute reserves very well with transition times of less than two minutes per 25% of relative power. Only short-term disturbances of the H2/CO ratio were observed during transitions due to the adjustment of feed gases. No elevated degradation effects resulting from flexible operation were apparent over 1300 h, although other causes of degradation were present.
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  • 77
    Publication Date: 2021-03-04
    Keywords: ddc:320
    Repository Name: Wuppertal Institut für Klima, Umwelt, Energie
    Language: German
    Type: contributiontoperiodical , doc-type:contributionToPeriodical
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  • 78
    Publication Date: 2021-05-06
    Description: Local implementation projects for sector coupling play an important role in the transformation to a more sustainable energy system. Despite various technical possibilities, there are various barriers to the realisation of local projects. Against this backdrop, we introduce an inter- and transdisciplinary approach to identifying and evaluating different power-to-X paths as well as setting up robust local implementation projects, which account for existing drivers and potential hurdles early on. After developing the approach conceptually, we exemplify our elaborations by applying them to a use case in the German city of Wuppertal. It can be shown that a mix of several interlinked interdisciplinary methods as well as several participatory elements is suitable for triggering a collective, local innovation process. However, the timing and extent of end-user integration remain a balancing act. The paper does not focus on a detailed description of power-to-X (PtX) as a central pillar of the sustainable transformation of the energy system. Rather, it focuses on the innovative methodological approach used to select a suitable use path and design a corresponding business model. The research approach was successfully implemented in the specific case study. However, it also becomes clear that the local-specific consideration entails limitations with regard to the transferability of the research design to other spatial contexts.
    Keywords: ddc:600
    Repository Name: Wuppertal Institut für Klima, Umwelt, Energie
    Language: English
    Type: article , doc-type:article
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  • 79
    Publication Date: 2021-05-18
    Description: We conduct a systematic, interdisciplinary review of empirical literature assessing evidence on induced innovation in energy and related technologies. We explore links between demand-drivers (both market-wide and targeted); indicators of innovation (principally, patents); and outcomes (cost reduction, efficiency, and multi-sector/macro consequences). We build on existing reviews in different fields and assess over 200 papers containing original data analysis. Papers linking drivers to patents, and indicators of cumulative capacity to cost reductions (experience curves), dominate the literature. The former does not directly link patents to outcomes; the latter does not directly test for the causal impact of on cost reductions). Diverse other literatures provide additional evidence concerning the links between deployment, innovation activities, and outcomes. We derive three main conclusions. (1) Demand-pull forces enhance patenting; econometric studies find positive impacts in industry, electricity and transport sectors in all but a few specific cases. This applies to all drivers - general energy prices, carbon prices, and targeted interventions that build markets. (2) Technology costs decline with cumulative investment for almost every technology studied across all time periods, when controlled for other factors. Numerous lines of evidence point to dominant causality from at-scale deployment (prior to self-sustaining diffusion) to cost reduction in this relationship. (3) Overall Innovation is cumulative, multi-faceted, and self-reinforcing in its direction (path-dependent). We conclude with brief observations on implications for modeling and policy. In interpreting these results, we suggest distinguishing the economics of active deployment, from more passive diffusion processes, and draw the following implications. There is a role for policy diversity and experimentation, with evaluation of potential gains from innovation in the broadest sense. Consequently, endogenising innovation in large-scale models is important for deriving policy-relevant conclusions. Finally, seeking to relate quantitative economic evaluation to the qualitative socio-technical transitions literatures could be a fruitful area for future research.
    Keywords: ddc:600
    Repository Name: Wuppertal Institut für Klima, Umwelt, Energie
    Language: English
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  • 80
    Publication Date: 2021-07-05
    Description: Cross-country evidence on the adoption of energy-efficient retrofit measures (EERMs) in residential buildings is critical to supporting the development of national and pan-European policies aimed at fostering the energy performance upgrade of the building stock. In this light, the aim of this paper is to advance in the understanding of the probability of certain EERMs taking place in eight EU countries, according to a set of parameters, such as building typology, project types, and motivation behind the project. Using these parameters collected via a multi-country online survey, a set of discrete-choice (conditional logit) models are estimated on the probability of selecting a choice of any combination of 33 EERMs across the sampled countries. Results show that actions related to the building envelope are the most often-addressed across countries and single building elements or technology measures have a higher probability of being implemented. The modelling framework developed in this study contributes to the scientific community in three ways: (1) establishing an empirical relationship among EERMs and project (i.e., retrofit and deep retrofit), (2) identifying commonalities and differences across the selected countries, and (3) quantifying the probabilities and market shares of various EERMs.
    Keywords: ddc:600
    Repository Name: Wuppertal Institut für Klima, Umwelt, Energie
    Language: English
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  • 81
    Publication Date: 2021-09-27
    Description: In the Antarctic ozone hole, ozone mixing ratios have been decreasing to extremely low values of 0.01–0.1 ppm in nearly all spring seasons since the late 1980s, corresponding to 95–99% local chemical loss. In contrast, Arctic ozone loss has been much more limited and mixing ratios have never before fallen below 0.5 ppm. In Arctic spring 2020, however, ozonesonde measurements in the most depleted parts of the polar vortex show a highly depleted layer, with ozone loss averaged over sondes peaking at 93% at 18 km. Typical minimum mixing ratios of 0.2 ppm were observed, with individual profiles showing values as low as 0.13 ppm (96% loss). The reason for the unprecedented chemical loss was an unusually strong, long-lasting, and cold polar vortex, showing that for individual winters the effect of the slow decline of ozone-depleting substances on ozone depletion may be counteracted by low temperatures.
    Keywords: 551.9 ; ozone ; stratosphere ; ozone loss ; Arctic ; ozone hole ; temperature
    Language: English
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  • 82
    Publication Date: 2021-09-27
    Description: Micron-sized HNO3-containing particles in polar stratospheric clouds are known to denitrify the polar winter stratosphere and support chemical ozone loss. We show that populations of nitric acid trihydrate (NAT) particles with volume-equivalent median radii of 3–7 μm can be detected vortex-wide by means of infrared limb sounding. Key for detection are the applied optical characteristics of highly aspherical particles consisting of the β-NAT phase. Spectroscopic signatures and ambient conditions of detected populations show that these particles play a key role in denitrification of the Arctic winter stratosphere. Complementary gas-phase HNO3 observations indicate collocated highly efficient HNO3 sequestration within days and are consistent with measured spectral signals of populations of large NAT particles. High amounts of condensed gas-phase equivalent HNO3 exceeding 10 ppbv and long persistence of detected populations, despite expected gravitational settling, imply that our understanding of the particles is incomplete.
    Keywords: 551.9 ; polar winter ; stratosphere ; denitrification ; nitric acid trihydrate ; infrared limb sounding
    Language: English
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  • 83
    Publication Date: 2021-09-27
    Description: The Global Carbon Budget 2018 (GCB2018) estimated by the atmospheric CO 2 growth rate, fossil fuel emissions, and modeled (bottom-up) land and ocean fluxes cannot be fully closed, leading to a “budget imbalance,” highlighting uncertainties in GCB components. However, no systematic analysis has been performed on which regions or processes contribute to this term. To obtain deeper insight on the sources of uncertainty in global and regional carbon budgets, we analyzed differences in Net Biome Productivity (NBP) for all possible combinations of bottom-up and top-down data sets in GCB2018: (i) 16 dynamic global vegetation models (DGVMs), and (ii) 5 atmospheric inversions that match the atmospheric CO 2 growth rate. We find that the global mismatch between the two ensembles matches well the GCB2018 budget imbalance, with Brazil, Southeast Asia, and Oceania as the largest contributors. Differences between DGVMs dominate global mismatches, while at regional scale differences between inversions contribute the most to uncertainty. At both global and regional scales, disagreement on NBP interannual variability between the two approaches explains a large fraction of differences. We attribute this mismatch to distinct responses to El Niño–Southern Oscillation variability between DGVMs and inversions and to uncertainties in land use change emissions, especially in South America and Southeast Asia. We identify key needs to reduce uncertainty in carbon budgets: reducing uncertainty in atmospheric inversions (e.g., through more observations in the tropics) and in land use change fluxes, including more land use processes and evaluating land use transitions (e.g., using high-resolution remote-sensing), and, finally, improving tropical hydroecological processes and fire representation within DGVMs.
    Keywords: 551.9 ; atmospheric inversions ; global carbon budget ; dynamic global vegetation models ; carbon cycle
    Language: English
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  • 84
    Publication Date: 2021-10-12
    Description: During seawater circulation in permeable intertidal sands, organic matter degradation alters the composition of percolating fluids and remineralization products discharge into surficial waters. Concurrently, coastal seawater nutrient and organic matter composition change seasonally due to variations in pelagic productivity. To assess seasonal changes in organic matter degradation in the intertidal zone of a high energy beach (Spiekeroog Island, southern North Sea, Germany), we analyzed shallow pore waters for major redox constituents (oxygen [O2], manganese [Mn], and iron [Fe]) and inorganic nitrogen species (nitrite [NO2−], nitrate [NO3−], and ammonium [NH4+]) in March, August, and October. Surface water samples from a local time series station were used to monitor seasonal changes in pelagic productivity. O2 and NO3− were the dominating pore water constituents in March and October. Dissolved Mn, Fe, and NH4+ were more widely distributed in August. Seasonal changes in seawater temperature as well as organic matter and nitrate supply by seawater were assumed to affect microbial rates and degradation pathways. Pore water and seawater variability led to seasonally changing constituent effluxes to surface waters. Mn, Fe, and NH4+ effluxes are minimal in March and reached their maximum in August. Furthermore, the intertidal sands switched from a net dissolved inorganic nitrogen sink in March to a net source in August. In conclusion, seasonal effects on intertidal pore water biogeochemistry affect constituent fluxes across the sediment-water interface. The seasonality of the beach bioreactor must be considered when fluxes are extrapolated to annual timescales.
    Keywords: 551.9 ; submarine groundwater discharge ; subterranean estuary ; oxygen ; nitrogen ; manganese ; iron
    Language: English
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  • 85
    Publication Date: 2021-10-14
    Description: A geoarchaeological soil phosphorus (P) prospection is used to identify a gate within the prehistoric rampart of the Milseburg hillfort (Hesse, Germany). This study compares the application of a P fractionation scheme and P extraction with ammonium-oxalate. We hypothesized that oxalate-extractable P (P-ox) and the related degree of P saturation (DPS) could replace the more expensive and time-consuming fractionation schemes for geoarchaeological investigations. Comparing the results, the P fractionation helped to verify the existence of another section of the prehistoric ramparts and to identify the location of a gate within it. It also helped to discover the archaeologically relevant soil depths in the investigated area. This information could not be retrieved from the P-ox data alone. Soil P-ox contents and DPS values are relatively unspecific with regard to prehistoric land use. However, DPS at least indicates settled versus unsettled areas. Still, the results of the P fractionation more clearly delineate Iron Age land use areas including settlement, non-settlement, rampart, and rampart gap (probable gate). Thus, in geoarchaeological contexts, this method seems to be preferable to a singular P-ox extraction. However, for better results, P-ox determination could be integrated into a P fractionation scheme.
    Keywords: 551.9 ; 631.4 ; Milseburg ; oxalate-extractable phosphorus ; phosphorus fractionation ; phosphorus saturation ; soil phosphorus prospection
    Language: English
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  • 86
    Publication Date: 2021-10-14
    Description: Riparian zones are important buffer zones for streams as they are hotspots of nitrate transformation and removal in agricultural catchments. However, mixing of water from different sources and various transformation processes can complicate the quantification of nitrate turnover in riparian zones. In this study, we analyzed nitrate concentration and isotope data in riparian groundwater along a 2-km stream section in central Germany. We developed a mathematical model combining end-member mixing and isotope modeling to account for mixing of river water and groundwater and quantify nitrate transformation in riparian groundwater. This enabled us to explicitly determine the extent of denitrification (as process leading to permanent nitrate removal from riparian groundwater) and transient nitrate removal by additional processes associated with negligible isotope fractionation (e.g., plant uptake and microbial assimilation) and to perform an extensive uncertainty analysis. Based on the nitrogen isotope data of nitrate, the simulations suggest a mean removal of up to 27% by additional processes and only about 12% by denitrification. Nitrate removal from riparian groundwater by additional processes exceeded denitrification particularly in winter and at larger distance from the river, underlining the role of the river as organic carbon source. This highlights that nitrate consumption by additional processes predominates at the field site, implying that a substantial fraction of agricultural nitrogen input is not permanently removed but rather retained in the riparian zone. Overall, our model represents a useful tool to better compare nitrogen retention to permanent nitrogen removal in riparian zones at various temporal and spatial scales.
    Keywords: 551.9 ; denitrification ; riparian zones ; nitrate ; isotope analysis ; mixing model ; eutrophication
    Language: English
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  • 87
    Publication Date: 2021-10-14
    Description: Emissions of the potent greenhouse gas methane (CH4) from streams and rivers are a significant component of global freshwater methane emissions. The distribution of CH4 production and oxidation within stream sections and in vertical sediment profiles is not well understood, and the environmental controls on CH4 production and emission in such systems create a significant challenge for assessing larger-scale dynamics. Here we investigate factors driving the spatial variability of sediment potential methane production (PMP) and potential methane oxidation (PMO) in a temperate stream network in Germany. PMP was highly variable, ranging from 5 × 10−4 to 28.58 μg CH4 gDW−1 d−1 and PMO ranged from 0.43 μg CH4 gDW−1 d−1 to 14.41 μg CH4 gDW−1 d−1. Important drivers of spatial variability of PMP and PMO in the sediments of the stream main-stem were related to fine sediment fraction and organic carbon content. At smaller spatial scale, that is, in a sub-catchment stream section, the drivers were more complex and included sediment nitrogen and organic carbon content, as well as porewater dissolved organic carbon, dissolved organic matter quality, and metal concentrations. As with reservoirs and impounded rivers, fine sediment deposition and organic carbon content were found to be key controls on the spatial variability of CH4 production and oxidation. These findings enhance our understanding of CH4 dynamics, improve the potential for identifying CH4 production hotspots in small streams, and provide a potential means for upscaling emission rates in larger-scale assessments.
    Keywords: 551.9 ; carbon cycle ; streams ; methane ; sediment ; porewater ; grain size
    Language: English
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  • 88
    Publication Date: 2021-10-14
    Description: Separate evaluation of methane (CH4) emission dynamics (e.g., oxidation, production, and transportation) at the soil-plant-atmosphere and soil-water-atmosphere interfaces has been limited in tropical rice paddies, but it is crucial for comprehending the entire CH4 cycles. We investigated CH4 oxidation, production, and transportation through plant and water pathways during the reproductive stage in a tropical Thailand rice paddy field using natural abundance carbon stable isotope ratios (δ13CH4 and δ13CO2). Mass balance equations using δ13CH4 and δ13CO2 in soil gases indicated that CH4 oxidation in the planted soil exceeded those in the interrow soil due to oxygen supply through rice roots. In addition, at 1–11 cm depth acetate fermentation was the dominant process in the planted soil, whereas in the interrow soil the dominant process was H2/CO2 reduction. The water pathway showed a significant negative correlation between CH4 flux and released δ13CH4 over 24 hr, driven by a diel change in episodic ebullition, steady ebullition, and diffusion, all due to diel changes in soil temperature and atmospheric pressure. In contrast, the plant pathway showed a significant positive relationship between CH4 flux and emitted δ13CH4 throughout one day. A comparison of the diel change in emitted δ13CH4 between the water and plant pathways showed that the rice plants transported CH4 in soil bubbles without any large isotopic fractionation. The diel change in the plant-mediated CH4 transportation was mainly controlled by diel changes in soil bubble expansion and CH4 diffusion through plants, which were probably regulated by diel changes in soil temperature and atmospheric pressure.
    Keywords: 551.9 ; CH4 ; carbon stable isotopes ; rice paddy ; plant pathway ; water pathway ; diel CH4 transportation
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  • 89
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    Wuppertal : Wuppertal Institut für Klima, Umwelt, Energie | Wuppertal : Wuppertal Institut für Klima, Umwelt, Energie
    Publication Date: 2022-02-18
    Keywords: ddc:320
    Repository Name: Wuppertal Institut für Klima, Umwelt, Energie
    Language: German
    Type: workingpaper , doc-type:workingPaper
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  • 90
    Publication Date: 2021-10-01
    Description: Neodymium (Nd) isotopes extracted from authigenic sediment phases are increasingly used as a proxy for past variations in water mass provenance. To better constrain the controls of water mass provenance and nonconservative effects on the archived Nd isotope signal, we present a new depth transect of Nd isotope reconstructions from the Blake Bahama Outer Ridge along the North American continental margin covering the past 30 ka. We investigated five sediment cores that lie directly within the main flow path of the Deep Western Boundary Current, a major advection route of North Atlantic Deep Water. We found offsets between core tops and seawater Nd isotopic compositions that are observed elsewhere in the Northwest Atlantic. A possible explanation for this is the earlier suggested redistribution of sediment by nepheloid layers at intermediate as well as abyssal depths, transporting material downslope and along the continental margin. These processes potentially contributed to Nd isotope excursions recorded in Northwest Atlantic sediment cores during the Bølling-Allerød and early Holocene. An Atlantic-wide comparison of Nd isotope records shows that the early Holocene excursions had an additional contribution from conservative advection of unradiogenic dissolved Nd. Nevertheless, the trends of the Nd isotope records are in general agreement with previous reconstructions of water mass provenance from the entire Atlantic and also reveal millennial-scale changes during the last deglaciation in temporal high resolution, which have rarely been reported before. Further, the new records confirm that during cold periods the Northwest Atlantic was bathed by an increased contribution of southern sourced water.
    Keywords: 551.9 ; neodymium isotopes ; deglaciation ; water masses ; Last Glacial Maximum ; benthic exchange
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  • 91
    Publication Date: 2021-11-19
    Description: This paper presents an approach for assessing lifestyle carbon footprints and lifestyle change options aimed at achieving the 1.5 °C climate goal and facilitating the transition to decarbonized lifestyles through stakeholder participatory research. Using data on Finland and Japan it shows potential impacts of reducing carbon footprints through changes in lifestyles for around 30 options covering food, housing, and mobility domains, in comparison with the 2030 and 2050 per-capita targets (2.5-3.2 tCO2e by 2030; 0.7-1.4 tCO2e by 2050). It discusses research opportunities for expanding the footprint-based quantitative analysis to incorporate subnational analysis, living lab, and scenario development aiming at advancing sustainability science on the transition to decarbonized lifestyles.
    Keywords: ddc:600
    Repository Name: Wuppertal Institut für Klima, Umwelt, Energie
    Language: English
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  • 92
    Publication Date: 2021-12-01
    Description: Methane (CH4) production in the ocean surface mixed layer is a widespread but still largely unexplained phenomenon. In this context marine algae have recently been described as a possible source of CH4 in surface waters. In the present study we investigated the effects of temperature and light intensity (including daylength) on CH4 formation from three widespread marine algal species Emiliania huxleyi, Phaeocystis globosa, and Chrysochromulina sp. Rates of E. huxleyi increased by 210% when temperature increased in a range from 10°C to 21.5°C, while a further increase in temperature (up to 23.8°C) showed reduction of CH4 production rates. Our results clearly showed that CH4 formation of E. huxleyi is controlled by light: When light intensity increased from 30 to 2,670 μmol m−2 s−1, CH4 emission rates increased continuously by almost 1 order of magnitude and was more than 1 order of magnitude higher when the daylength (light period) was extended from 6/18 hr light-dark cycle to continuous light. Furthermore, light intensity is also an important factor controlling CH4 emissions of Chrysochromulina sp. and P. globosa and could therefore be a species-independent regulator of phytoplankton CH4 production. Based on our results, we might conclude that extensive blooms of E. huxleyi could act as a main regional source of CH4 in surface water, since blooming of E. huxleyi is related to the seasonal increase in both light and temperature, which also stimulate CH4 production. Under typical global change scenarios, E. huxleyi will increase its CH4 production in the future.
    Keywords: 551.9 ; 557.7 ; marine phytoplacton ; CH4 production ; temperature influence ; light intensity influence ; daylength influence
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  • 93
    Publication Date: 2021-12-03
    Description: The first step of complete transformation will be utilizing digital technologies and applications to improve current procedures, processes, and structures (Improve). Next, complete digitalisation will pave the way for new business models and framework conditions (Convert). Finally, comprehensive transformation of the economy and value creation will ensure the effective reorientation of society and lifestyles towards sustainability (Transform). This last step is critical for a successful ecological transformation, or a "green transformation", must be placed front and centre during international debate. Through this report, we aim to highlight and discuss the opportunities that digitalisation can bring to Germany. In particular, we will discuss three exemplary areas of ecological transformation where action is necessary: 1) A digital and circular economy that uses data to increase resource efficiency. 2) Intelligent, sustainable mobility that connects us in eco-friendly ways. 3) Transparent transitions towards sustainable food chains and agriculture. This report represents the first phase of the Shaping Digital Transformation project. In this report, we will outline the framework of our project to create a starting point for further debates.
    Keywords: ddc:600
    Repository Name: Wuppertal Institut für Klima, Umwelt, Energie
    Language: English
    Type: report , doc-type:report
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  • 94
    Publication Date: 2021-12-03
    Description: Digitale Technologien und Anwendungen tragen dazu bei, gegenwärtige Verfahren, Prozesse und Strukturen zu verbessern (Improve) oder erste Schritte in eine neue Ausrichtung von Geschäftsmodellen oder Rahmenbedingungen zu gehen (Convert). Gleichzeitig muss die Digitalisierung aber auch für einen umfassenden Umbau von Wirtschaft und Wertschöpfung sowie für die ökologische Neuorientierung von Gesellschaft und Lebensstilen wirksam werden (Transform). Gerade diese letzte Wirkungsebene wird entscheidend für den Erfolg des ökologischen Wandels sein und muss stärker in den Fokus der Debatte rücken. Hier setzt das Projekt "Digitalisierung gestalten - Transformation zur Nachhaltigkeit ermöglichen" an. Innerhalb des Projekts sollen die besonderen Transformationspotenziale der Digitalisierung herausgearbeitet und für Deutschland am Beispiel von drei ausgewählten Handlungsfeldern zu diskutiert werden: 1) Digitale Circular Economy - mit Daten zur Ressourceneffizienz. 2) Intelligente Mobilität im Umweltverbund - vernetzt, attraktiv und klimaschonend. 3) Transparenz für eine nachhaltige Agrar- und Ernährungswende. Diese Studie ist der Startpunkt des Projekts. In dieser skizzieren die Forschenden die Potenziale der Digitalisierung als eine Erfolgsvoraussetzung für den ökologischen Systemwandel in den genannten Bereichen.
    Keywords: ddc:600
    Repository Name: Wuppertal Institut für Klima, Umwelt, Energie
    Language: German
    Type: report , doc-type:report
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  • 95
    Publication Date: 2021-12-10
    Description: This paper develops policy measures for a "just transition" based on a case study conducted in Germany's Rhineland lignite mining district. Semi-structured guided interviews served as the methodological approach. Expert interviews were conducted with representatives of citizen initiatives, trade unions and the Federal State of North Rhine-Westphalia. The results reveal the need for policy measures in different areas: First, employees working for subcontractors of the lignite industry have a high risk of losing their jobs because there are virtually no support policies for them. Second, there needs to be more input by civic initiatives regarding the process of structural change. And last, land needs to be prevented from becoming a scarce resource in the Rhineland area due to current mining legislation. We use an actor-centred institutionalist framework to derive governance approaches in line with the needs of various stakeholders.
    Keywords: ddc:320
    Repository Name: Wuppertal Institut für Klima, Umwelt, Energie
    Language: English
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  • 96
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    Bonn : Friedrich-Ebert-Stiftung
    Publication Date: 2021-11-11
    Keywords: ddc:320
    Repository Name: Wuppertal Institut für Klima, Umwelt, Energie
    Language: German
    Type: report , doc-type:report
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  • 97
    Publication Date: 2021-11-11
    Keywords: ddc:320
    Repository Name: Wuppertal Institut für Klima, Umwelt, Energie
    Language: German
    Type: contributiontoperiodical , doc-type:contributionToPeriodical
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  • 98
    Publication Date: 2021-11-11
    Keywords: ddc:600
    Repository Name: Wuppertal Institut für Klima, Umwelt, Energie
    Language: German
    Type: report , doc-type:report
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  • 99
    Publication Date: 2021-11-11
    Description: Das Klimaabkommen von Paris ist ein Abkommen der Vereinten Nationen. Mit Artikel 4.1 wurde die Treibhausgasneutralität zum Ziel aller globalen Klimapolitik gemacht. Die Begriffe Klimaneutralität und Treibhausgasneutralität werden vom Klimasekretariat der Vereinten Nationen in der öffentlichen Kommunikation synonym verwendet. Die Europäische Kommission hat sich bisher im Zuge der Umsetzung ebenfalls für die synonyme Verwendung entschieden. In Deutschland ist es anders - da herrscht begriffliches Chaos.
    Keywords: ddc:320
    Repository Name: Wuppertal Institut für Klima, Umwelt, Energie
    Language: German
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  • 100
    Publication Date: 2021-11-11
    Description: On the one hand, a large number of companies have committed to achieve net zero emissions and many of them foresee to offset some remaining emissions with carbon credits, suggesting a surge of future demand. Yet, the supply side of the voluntary carbon market is struggling to align its business model with the new legal architecture of the Paris Agreement. This article juxtaposes these two perspectives. It provides an overview of the plans of 482 major companies with some form of neutrality/net zero pledge and traces the struggle on the supply side of the voluntary carbon market to come up with a viable business model that ensures environmental integrity and contributes to achieving the objectives of the Paris Agreement. Our analysis finds that if carbon credits are used to offset remaining emissions against neutrality objectives, these credits need to be accounted against the host countries' Nationally Determined Contributions (NDCs) to ensure environmental integrity. Yet, operationalizing this approach is challenging and will require innovative solutions and political support. Key policy insights: There is a growing mismatch between the faith placed in carbon credits by private sector companies and the continued quest for a common position of the main suppliers of the voluntary carbon market. The voluntary carbon market has not yet found a way to align itself with the new legal architecture of the Paris Agreement in a credible and legitimate way. Public policy support at the national and international level will be needed to operationalize a robust approach for the market’s future activities.
    Keywords: ddc:320
    Repository Name: Wuppertal Institut für Klima, Umwelt, Energie
    Language: English
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