ALBERT

Description / Table of Contents: This volume of Reviews in Mineralogy attempts to synthesize our present understanding of certain aspects of the mineralogy and chemistry of the rock-forming carbonates. Hopefully, it reflects the presently more active areas of research. This review follows, by ten years, a major assessment of (sedimentary) carbonate minerals by Lippmann (1973). There is only minor overlap of subject material, and I hope that this difference reflects fairly how this field has developed. In some respects carbonates are unique, for they are one of the few mineral groups providing an abundant record of biological, physical, and chemical processes throughout much of geologic time. Because of their relative importance in sedimentary rocks, lowtemperature examples are given more emphasis here. Moreover, the obvious correlation with energy resources has been a significant factor contributing to the current resurgence of interest in this area. However, the broader interest in carbonates is also a reflection of their widespread occurrence in vastly different geologic environments, including metamorphic and igneous settings, as well as an appreciation of their role in both atmospheric and oceanic chemistry, both past and present. In this volume, some of the papers are general (i.e., those addressing crystal chemistry and phase relations), and they provide overviews of a fundamental nature and are of interest to many. Others are more specialized in coverage and generally reflect the different approaches used in carbonate geochemistry. The final chapter introduces transmission electron microscopy, a relatively new and powerful technique for mineralogical research that has great potential in carbonate research. Owing to the short time interval between the completion of manuscripts and publication, much of the newer material in this volume is still "fresh." The various reviewers, all gratefully acknowledged, were expeditious in their efforts. A hurried schedule, however, allows for unnoticed errors to persist; these should be brought to my attention.

Description / Table of Contents: Geochemistry is a science that is based on an understanding of chemical processes in the earth. One of the principal tools available to the chemist for understanding systems at equilibrium is thermodynamics. The awareness and application of thermodynamic techniques has increased at a very fast pace in geosciences; in fact, one may be so bold as to say that thermodynamics in geology has reached the "mature" stage, although much future thermodynamic research is certainly needed. However, the natural processes in the earth are often sluggish enough that a particular system may not reach equilibrium. This observation is being supported constantly by new experimental and field data available to the geochemist e.g. the non-applicability of the phase rule in some assemblages, the compositional inhomogeneities of mineral grains, the partial reaction rims surrounding original minerals, the lack of isotopic equilibration or the absence of minerals (e.g. dolomite), which should be present according to thermodynamics. The need to apply kinetics has produced a large number of papers dealing with kinetics in geochemistry. As an initial response to this growing field, a conference on geochemical transport and kinetics was conducted at Airlie House, VA, in 1973, sponsored by the Carnegie Institution of Washington. The papers there dealt with several kinetic topics including diffusion, exsolution, metasomatism and metamorphic layering. Since 1973 the number of kinetic papers has continued to increase greatly. Therefore, the time is ripe for a Short Course in Kinetics, which brings together the fundamentals needed to explain field observations using kinetic data. It is hoped that this book may serve, not only as a reference for researchers dealing with the rates of geochemical processes, but also as a text in courses on geochemical kinetics. One of us has found this need of a text in teaching a graduate course on geochemical kinetics at Harvard and at Penn State during the past several years. Finally, it is our hope that the book may itself further even more research into the rates of geochemical processes and into the quantification of geochemical observations. The book is organized with a rough temperature gradient in mind, i.e. low temperature kinetics at the beginning and igneous kinetics at the end (no prejudices are intended with this scheme!). However, the topics in each chapter are general enough that they can be applied often to any geochemical domain: sedimentary, metamorphic or igneous. The theory of kinetics operates at two complementary levels: the phenomenological and the atomistic. The former relies on macroscopic variables (e.g. temperature or concentrations) to describe the rates of reactions or the rates of transport; the latter relates the rates to the basic forces operating between the particular atomic or molecular species of any system. This book deals with both descriptions of the kinetics of geochemical processes. Chapter one sets the framework for the phenomenological theory of reaction rates. If any geochemical reaction is to be described quantitatively, the rate law must be experimentally obtained in a kinetically sound manner and the reaction mechanism must be understood. This applies to heterogeneous fluid-rock reactions such as those occurring during metamorphism, hydrothermal alteration or weathering as well as to homogeneous reactions. Chapter 2 extends the theory to the global kinetics of geochemical cycles. This enables the kinetic concepts of stability and feedback to be applied to the cycling of elements in the many reservoirs of the earth. Chapter 3 applies the phenomenological treatment of chapter 1 to diagenesis and weathering. The rate of dissolution of minerals as well as the chemical evolution of pore waters are discussed. The atomistic basis of rates of reaction, transition state theory, is introduced in Chapter 4. Transition state theory can be applied to relate the rate constants of geochemical reactions to the atomic processes taking place. This includes not only homogeneous reactions but also reactions that occur at the surface of minerals. Chapter 5 discusses the theory of irreversible thermodynamics and its application to petrology. The use of the second law of thermodynamics along with the expressions for the rate of entropy production in a system have been used successfully since 1935 to describe kinetic phenomena. The chapter applies the concepts to the growth of minerals during metamorphism as well as to the formation of differentiated layers (banding) in petrology. Chapter 6 describes the phenomenological theory of diffusion both in aqueous solutions and in minerals. In particular, the multicomponent nature of diffusion and its consequence in natural systems is elaborated. Chapter 7 provides the atomistic basis for the rates of reactions in minerals. Understanding of the rates of diffusion, conduction, order-disorder reactions or exsolution in minerals depends on proper description of the defects in the various mineral structures. Chapter 8 provides the kinetic theory of crystal nucleation and growth. While many of the concepts in the chapter can be applied to aqueous systems, the emphasis is on igneous processes occurring during crystallization of a melt. To fully understand both the mineral composition as well as the texture of igneous rocks, the processes whereby new crystals form and grow must be quantified by using kinetic theory. Due to space and time limitations (kinetics!) some topics have not been covered in detail. In particular, the mathematical solution of diffusion or conduction equations is discussed very well by Crank in his book, Mathematics of Diffusion, and so is not covered to a great extent here. The treatment of fluid flow (e.g. convection) is also not covered in the text.

Description / Table of Contents: Although phyllosilicates are common in almost all types of rocks, their detailed study has not advanced in proportion to their importance. Books and reviews on this subject have been restricted primarily to the areas of clay mineralogy and soils. Such treatments understandably restrict coverage of the occurrences of the macroscopic-size species as well as much of their mineralogical and petrological nature. It was decided at the outset that not all phyllosilicates could be covered in a single book, and the size of this volume addressed only to the micas justifies the original decision. Kaolins, serpentines, chlorites, etc. will have to wait until some later date. This volume attempts to gather together much of our knowledge of micas, the most abundant phyllosilicate, and to indicate promising areas of future research. Chapters 1-3 lay the foundations of the classification, structures, and crystal chemistry of micas. Chapter 4 treats bonding and electrostatic modeling of micas. Chapters 5 and 6 cover spectroscopic and optical properties. Chapters 7-13, the bulk of the volume, are devoted to geochemistry and petrology. These include phase equilibria and the occurrences, chemistry, and petrology of micas in igneous, metamorphic, and sedimentary rocks, pegmatites, and certain ore deposits. Some treatments are exhaustive. All are at the forefront of our present knowledge, and indicate clearly the practical applications'of the study of micas to ascertaining various parameters of origin and crystallization history, as well as the many problems that still exist. The aim of this type of treatment is twofold -- to provide a handy reference volume for teachers and students and to enable researchers to pick more easily those directions and problems for which future research is most needed or is apt to be most productive or most challenging. X-ray powder patterns of micas in the literature are of surprisingly poor quality. The best are collated and supplemented with additional new patterns in the Appendix as an aid to identification.

Description / Table of Contents: Ice fog suppression experiments on the Fort Wainwright Power Plant cooling pond were conducted during the winters of 1974-76. Baseline information studies occupied a sizable portion of the available ice fog weather in 1974-75. Then hexadecanol was added to the pond and dramatically improved visibility by reducing fog generated from water vapor released by the pond at -14 C. Although this temperature was not low enough to create ice fog, the cold vapor fog created was equally as devastating to visibility in the vicinity of the pond. During the winter of 1975-76, suppression tests were continued using films of hexadecanol, mixes of hexadecanol and octadecanol, and ethylene glycol monobutyl ether (EGME). Suppression effectiveness at colder temperatures was stuided and limits to the techniques were probed. A reinforcing grid was constructed that prevented breakup of the film by wind and water currents. Lifetime tests indicated that EGME degrades much more slowly than either hexadecanol or the hexadecanol-octadecanol mix. The films were found to be very effective fog reducers at warmer temperatures but still allowed 20% to 40% of normal evaporation to occur. The vapor thus produced was sufficient to create some ice fog at lower temperatures, but this ice fog occurred less frequently and was more quickly dispersed than the thick fog that was present before application of the films.

Description / Table of Contents: Special environmental factors that influence the design, laying and maintenance of undersea pipelines and cables in polar waters are described. Various approaches to the protection of submarine pipes and cables are considered, and prime emphasis is given to burial techniques for shallow water. A wide range of methods for trenching and burying are discussed, and technical data are given.

Description / Table of Contents: Abstract: Measurements of the concentrations of Aitken nuclei in maritime air were made near Barrow, Alaska, in June 1975 with a modified Nolan-Pollack small-particle detector. The concentrations varied from 50 to 300 particles cm^-3 depending upon meteorological conditions. The mean Aitken nuclei count was 100 particles cm^-3 for diameters greater than 2 x 10^-3 μm. Transmission electron micrographs of aerosols in maritime air near Barrow were taken. The size range was measured to be 0.01 to 2.5 μm in diameter with the most frequently observed diameter being 0.04 μm. The volume of the maritime air and the collection efficiency of aerosol particles on filmed grids for electron microscopy were measured. The aerosol concentrations were found to be 76 to 101 particles cm^-3 ; the mean concentration was calculated to be 87 particles cm^-3. The aerosol particles in the maritime air were identified by electron microscopy and selected area electron diffraction analysis. About 20% of the aerosol particles were identified, and 80% of the particles were too small for electron diffraction analysis. Sea salt particles constituted 2% of the total, and clay minerals 3%; these particles were considered to be of natural origin. Solid combustion by-products such as coagulated carbon particles and fly ash particles constituted 16%. Despite the comparative remoteness of the sampling site, the measurements indicate that many anthropogenic aerosols were found using an electron microscope.

Description / Table of Contents: A model investigation of drifting snow conditions was conducted in a hydraulic flume using a sand-water analog. Model results were evaluated to define modeling parameters that would allow quantitative correlation between measured prototype drift conditions and the model. The modeled structure was the standard plan snow fence designed by the Wyoming Highway Department and installed along Interstate Highway 80 in 1971. The performance of this system was documented by the Rocky Mountain Forest and Range Experiment Station of the U.S. Forest Service. Models of the fence were constructed for three heights and two geometric scales. Geometric scaling was based on terrain roughness and boundary layer thickness considerations, while velocity scaling was based on particle fall velocity and threshold of motion characteristics. Simulation of the atmospheric boundary layer was found to be of primary importance. Velocity scaling analysis suggested the use of a 'significant wind' concept based on a combination of velocity magnitude and frequency. Similarity of precipitation rate was not essential, and could be altered within limits to adjust the time scale. The response of the model to the shape of model elements was significant. Although the model is distorted and inexact similarity is achieved, it appears useful on a practical basis.

Description / Table of Contents: The theory of non-coaxial in-plane plastic deformation of soils that obey the Coulomb yield criterion is presented. The constitutive equations are derived by use of the geometry of the Mohr circle and the theory of characteristic lines. It is found that, for solving a boundary value problem, the non-coaxial angle must be given such values that enable us to accommodate the presupposed type of flow in the given domain satisfying the given boundary conditions. The non-coaxial angle is contained in the constitutive equations as a parameter. Therefore, the plastic material obeying the Coulomb yield criterion is a singular material whose constitutive equations are not constant with material but are variable with flow conditions.

Description / Table of Contents: The use of radio-echo sounding records to indicate the presence of internal layers within large ice sheets is of interest to glaciologists because it offers a means of tracking the internal properties of the ice sheets over large distances. The interpretation of the reflections obtained in this manner is more valuable, however, if a physical property change relating to the glaciological regime can be related to the dielectric property change producing the radio-echo reflections. In this report, we use the measured physical properties of core to bedrock taken at Cape Folger, East Antarctica (66 deg 22 min s, 111 deg (E), 324-m depth), to compute a profile of dielectric properties and from this, a depth-reflection coefficient profile for comparison with observed radio-echo reflections. The measurements available on physical properties are: density variations, bubble size and shape changes, and crystal fabric variations. The depths of the strong reflections shown on the available radio-echo records are in reasonable agreement with the depths corresponding to the highest reflection coefficients computed from the combined physical property measurements. In calculations to differentiate the separate effects of different physical properties, it appears that density variations account for the primary contributions to the calculated dielectric property changes corresponding to the highest reflection coefficients. However, bubble changes alone can also account for reasonable, though lower, reflection coefficients at the appropriate depths. Crystal fabric variations correspond poorly with the reflection locations. Density variations are normally associated with depositional events in the history of the ice sheet.

Description / Table of Contents: A broadbanded impulse radar system was used for aerial detection of accumulated frazil and brash ice in a 9.5-km reach of the St. Lawrence River near Ogden Island. The remote sensing and data reduction system developed for the project provided data sufficient for production of a contour map having 1-ft intervals. With this contour map, the accumulation pattern of frazil and brash ice could be analyzed. Recommendations are given for improving the performance of the aerial profiling system.

Description / Table of Contents: This report presents experimental results on the conditions of initiation of an ice jam by a simple surface obstruction, on the equilibrium thickness of an ice jam formed by accumulation and submergence of ice floes, and on the compression strength of floating, fragmented ice cover. In the study on ice jam initiation, it was found that the minimum concentration of floes in the opening of the obstruction at which a jam occurs is nearly independent of the ratio of width of constricted passage to channel width, and is proportional to a negative power of the ratio of floe length to width of constricted passage. From energy analysis of floe submergence, a relationship relating the thickness of a jam formed by accumulation and submergence of floes to the approach flow characteristics was derived and found to fit satisfactorily the experimental data. In experiments on compression strength of floating, fragmented ice cover it was found that the compressive strength is inversely proportional to compression velocity and independent of cover length.

Description / Table of Contents: The results of axial double point-load tests on disk samples of snow and ice obtained from the area of McMurdo Sound, Antarctica, are presented. They show the effects of temperature, sample length, load point diameter and specific gravity on failure load. It was determined that 13 samples should be tested to obtain a representative mean strength index. The results show that the axial double point-load test has good possibilities as a rapid field test for determining the unconfined comrpessive strength of snow and ice but that further evaluation of the variables affecting test results must be made.

Description / Table of Contents: Ten roofs in Concord, New Hampshire, were surveyed for wet insulation using a hand-held infrared camera. Suspected wet areas were marked on the roof with spray paint and roof samples were obtained to verify wet and dry conditions. Recommendations for maintenance and repair were made based on infrared findings, water contents, and visual examinations. An incremental economic study is presented to serve as a guide in determining the most cost-effective approach.

Description / Table of Contents: A brief discussion is given of the ways an icebreaker breaks ice. Since the icebreaking process is so complex, the solution of a mathematical model does not appear to be feasible. As an alternative, it is suggested that physical models be used to design icebreakers. The appropriate scaling laws for physical models are developed and their practical limitation discussed.

Description / Table of Contents: A literature search was made for information on the accretion of ice on ocean structures and on methods for control. The bulk of the reports were in Russian, with some additional Japanese, British, American, Canadian, and Icelandic sources. Analysis of icing reports indicated that sea spray is the most important cause of ship icing, with lesser amounts due to freezing rain, snow, and fog. Icing is a potential danger whenever air temperatures are below the freezing point of water and the sea temperature is 6 C or lower. Theoretical work on the ice accretion process is discussed, and a method is suggested, based on Russian experiments, for calculating the sea spray accumulation rate for cylindrical and flat surfaces as a function of water source temperature, air temperature, and wind speed. Other factors that influence icing severity are ship size and configuration, angle between ship course and water heading, and ship speed. Icing in the north temperate latitudes generally occurs in the rear of barometric depressions. Maps showing limits of various degrees of icing severity are included. Atmospheric icing measurements on tall land-based structures are presented, and potential maximum accumulations estimated. Control measures are discussed, though no completely effective method is available. Mechanical (impaction) methods are the most common, but experiments have been conducted on heated, icephobic, and deformable surfaces, and with freezing point depressants. No device for the unequivocal measurement of ice accumulation is available, though some experimental methods are suitable for controlled testing; it is recommended that a device be developed.

Description / Table of Contents: Abstract: Ageneral computer model to simulate municipal snow removal has been developed. Programs which aid in the routing of snowplows are a part of this package. Once vehicle routes are created, the simulation program can be used to assess situations varying both equipment and meteorological parameters. Time for each plow to complete its route is calculated. Considerations are made for the above variable parameters plus plowing windrow, route starting depth, overlapping truck routes and intersection delay time. The effects of storm length, snowfall rate and starting depth on total plowing time are examined in a test case.

Description / Table of Contents: The repair and maintenance costs of low slope roofs are high and their life expectancy is less than desired. The increasing use of insulation is accompanied by a greater incidence of problems. The experience in cold regions amplifies these experiences. Protected membrane roofs have the prerequisites for better performance and the experience to date is encouraging. The results of performance measurements of three roofs built by the Corps of Engineers verify that the membrane remains at nearly constant temperature, independent of the weather, and that the insulation retains its integrity despite periodic wetting. Moisture absorption is slow and appears to stabilize in time due to the self-drying nature of the roof. Heat losses are increased due to rain, and extra insulation should be added to compensate for these losses. The resistance of protected membrane roofs to fire, traffic, impact, and other adverse forces is superior. So far, the initial cost of protected membrane roofs is at a premium, primarily due to the cost of concrete pavers. The initial cost premium can be justified, however, by the reduced repair and maintenance costs as indicated to date, and by the longer life expectancy of the protected membrane. The high probability of superior performance and cost effectiveness is a compelling reason to incorporate protected membrane roofs increasingly in Government construction.

Description / Table of Contents: Large areas of grounded sea ice have been reported by early arctic explorers and more recently by the U.S. Coast Guard. The ESSA, ERTS, NOAA and DMSP satellites now provide multispectral imagery with sufficiently high resolution to allow detailed sequential observations to be made of the movement and spatial extent of arctic sea ice. This report discusses the location, formation and decay of five large (greater than 30 sq km) islands of grounded sea ice in the southern Chukchi Sea as observed for an extended period of time using satellite imagery. Measurements of the bathymetry around one grounded sea ice feature are presented along with observations made and photos taken from the ice surface. The potential use of these sea ice islands as research stations is also discussed.

Description / Table of Contents: This report covers a series of cantilever beam tests designed to determined the efficacy of adding reinforcement to an ice cover. Tests were run using 1-in.-diam tree branches, 3/16-in.-diam wire rope and 9/16-in. half-round wood dowels as reinforcement for both seawater and freshwater ice. The results show a definite advantage derived from using reinforcement, even when poorly placed. The results also show that reinforced ice carries a load even after it cracks. Thus, after the initial cracks there is time to remove people and equipment before final breakthrough. One must bear in mind, however, that reinforcement has disadvantages. The darker reinforcement absorbs solar radiation and thereby causes earlier weakening of the ice cover. Also, in many cases the time and effort required to place reinforcement may exceed those required to achieve equal strength by additional thickening of the ice sheet. This study has shown that understanding of the failure mechanism of ice under repetitive loading is poor and that future studies should be performed on this problem. Also, this study covered only cantilever beams. The actual field problem is strengthening a three-dimensional sheet. Hence, distribution and orientation of the reinforcement should be addressed in future studies.

Description / Table of Contents: A literature review of revegetation and biological aspects of restoration research was completed for arctic and sub­arctic North America. Although there is a great deal of climatic variation in this region it is generally characterized by extreme conditions, such as a short growing season and permafrost. Most of the revegetation research has been undertaken in the last six years as a result of increased natural resource development. The primary goal has been erosion control, with aesthetics, minimization of thermokarst, and production of browse as other objectives. Revege­tation and long-term restoration methods depend upon such variables as the site conditions, nutrient regime (especially as this is influenced by the climatic conditions in the Arctic and Subarctic), plant adaptations, and the selection of native or introduced species. Technologies which have been developed to meet these conditions primarily include seedbed preparation, use of seed mixes, and fertilization and seeding methods. Most of the research has focused on the use of agronomic grasses and legumes. These are selected on the basis of a number of factors, such as cold hardiness and growth form prior to evaluation in the laboratory and the field. The most successful species to date have been Arctared fescue and Nugget bluegrass in the Arctic, while these two as well as creeping red fescue, meadow foxtail, Frontier reed canarygrass, Durar hard fescue, slender wheatgrass, and Icelandic poa did well in the Subarctic. Similar methods have been attempted to a more limited extent with evaluation of native herbaceous and woody species which seem promising on the basis of natural succession studies. There are a number of continuing research needs for arctic anc subarctic revegetation. These include fertilization strategies, development of specialized techniques (such as sprigging) for native species, and longer term studies. It is particularly important to integrate short term revegetatio methods with long-term restoration goals.

Description / Table of Contents: The effects of snow temperature and initial density on the stress vs density and stress vs deformation relationships were investigated for shallow compacted snow in the density range of 0.28 to 0.76 g/cu m, for stress range of 0.5 to 72 bars and a temperature range of -1 to -34 C at a deformation rate of 40 cm/s. A decrease in temperature increases the resistance to stress, the effect increasing with applied stress. For any stress, an increase in the initial density results in an increase in the resulting density, the effect decreasing with an increase in stress. The approximate yield envelopes, which define the stress required to initiate any deformation of snow of a particular density and temperature, were determined. Rapid compaction of snow results in extensive recrystallization, significantly different from that of naturally compacted snow. At a stress of 72 bars, transformation to ice occurs only at temperature above -10C.