ALBERT

Beschreibung / Inhaltsverzeichnis: This volume of Reviews in Mineralogy attempts to synthesize our present understanding of certain aspects of the mineralogy and chemistry of the rock-forming carbonates. Hopefully, it reflects the presently more active areas of research. This review follows, by ten years, a major assessment of (sedimentary) carbonate minerals by Lippmann (1973). There is only minor overlap of subject material, and I hope that this difference reflects fairly how this field has developed. In some respects carbonates are unique, for they are one of the few mineral groups providing an abundant record of biological, physical, and chemical processes throughout much of geologic time. Because of their relative importance in sedimentary rocks, lowtemperature examples are given more emphasis here. Moreover, the obvious correlation with energy resources has been a significant factor contributing to the current resurgence of interest in this area. However, the broader interest in carbonates is also a reflection of their widespread occurrence in vastly different geologic environments, including metamorphic and igneous settings, as well as an appreciation of their role in both atmospheric and oceanic chemistry, both past and present. In this volume, some of the papers are general (i.e., those addressing crystal chemistry and phase relations), and they provide overviews of a fundamental nature and are of interest to many. Others are more specialized in coverage and generally reflect the different approaches used in carbonate geochemistry. The final chapter introduces transmission electron microscopy, a relatively new and powerful technique for mineralogical research that has great potential in carbonate research. Owing to the short time interval between the completion of manuscripts and publication, much of the newer material in this volume is still "fresh." The various reviewers, all gratefully acknowledged, were expeditious in their efforts. A hurried schedule, however, allows for unnoticed errors to persist; these should be brought to my attention.

Beschreibung / Inhaltsverzeichnis: Geochemistry is a science that is based on an understanding of chemical processes in the earth. One of the principal tools available to the chemist for understanding systems at equilibrium is thermodynamics. The awareness and application of thermodynamic techniques has increased at a very fast pace in geosciences; in fact, one may be so bold as to say that thermodynamics in geology has reached the "mature" stage, although much future thermodynamic research is certainly needed. However, the natural processes in the earth are often sluggish enough that a particular system may not reach equilibrium. This observation is being supported constantly by new experimental and field data available to the geochemist e.g. the non-applicability of the phase rule in some assemblages, the compositional inhomogeneities of mineral grains, the partial reaction rims surrounding original minerals, the lack of isotopic equilibration or the absence of minerals (e.g. dolomite), which should be present according to thermodynamics. The need to apply kinetics has produced a large number of papers dealing with kinetics in geochemistry. As an initial response to this growing field, a conference on geochemical transport and kinetics was conducted at Airlie House, VA, in 1973, sponsored by the Carnegie Institution of Washington. The papers there dealt with several kinetic topics including diffusion, exsolution, metasomatism and metamorphic layering. Since 1973 the number of kinetic papers has continued to increase greatly. Therefore, the time is ripe for a Short Course in Kinetics, which brings together the fundamentals needed to explain field observations using kinetic data. It is hoped that this book may serve, not only as a reference for researchers dealing with the rates of geochemical processes, but also as a text in courses on geochemical kinetics. One of us has found this need of a text in teaching a graduate course on geochemical kinetics at Harvard and at Penn State during the past several years. Finally, it is our hope that the book may itself further even more research into the rates of geochemical processes and into the quantification of geochemical observations. The book is organized with a rough temperature gradient in mind, i.e. low temperature kinetics at the beginning and igneous kinetics at the end (no prejudices are intended with this scheme!). However, the topics in each chapter are general enough that they can be applied often to any geochemical domain: sedimentary, metamorphic or igneous. The theory of kinetics operates at two complementary levels: the phenomenological and the atomistic. The former relies on macroscopic variables (e.g. temperature or concentrations) to describe the rates of reactions or the rates of transport; the latter relates the rates to the basic forces operating between the particular atomic or molecular species of any system. This book deals with both descriptions of the kinetics of geochemical processes. Chapter one sets the framework for the phenomenological theory of reaction rates. If any geochemical reaction is to be described quantitatively, the rate law must be experimentally obtained in a kinetically sound manner and the reaction mechanism must be understood. This applies to heterogeneous fluid-rock reactions such as those occurring during metamorphism, hydrothermal alteration or weathering as well as to homogeneous reactions. Chapter 2 extends the theory to the global kinetics of geochemical cycles. This enables the kinetic concepts of stability and feedback to be applied to the cycling of elements in the many reservoirs of the earth. Chapter 3 applies the phenomenological treatment of chapter 1 to diagenesis and weathering. The rate of dissolution of minerals as well as the chemical evolution of pore waters are discussed. The atomistic basis of rates of reaction, transition state theory, is introduced in Chapter 4. Transition state theory can be applied to relate the rate constants of geochemical reactions to the atomic processes taking place. This includes not only homogeneous reactions but also reactions that occur at the surface of minerals. Chapter 5 discusses the theory of irreversible thermodynamics and its application to petrology. The use of the second law of thermodynamics along with the expressions for the rate of entropy production in a system have been used successfully since 1935 to describe kinetic phenomena. The chapter applies the concepts to the growth of minerals during metamorphism as well as to the formation of differentiated layers (banding) in petrology. Chapter 6 describes the phenomenological theory of diffusion both in aqueous solutions and in minerals. In particular, the multicomponent nature of diffusion and its consequence in natural systems is elaborated. Chapter 7 provides the atomistic basis for the rates of reactions in minerals. Understanding of the rates of diffusion, conduction, order-disorder reactions or exsolution in minerals depends on proper description of the defects in the various mineral structures. Chapter 8 provides the kinetic theory of crystal nucleation and growth. While many of the concepts in the chapter can be applied to aqueous systems, the emphasis is on igneous processes occurring during crystallization of a melt. To fully understand both the mineral composition as well as the texture of igneous rocks, the processes whereby new crystals form and grow must be quantified by using kinetic theory. Due to space and time limitations (kinetics!) some topics have not been covered in detail. In particular, the mathematical solution of diffusion or conduction equations is discussed very well by Crank in his book, Mathematics of Diffusion, and so is not covered to a great extent here. The treatment of fluid flow (e.g. convection) is also not covered in the text.

Beschreibung / Inhaltsverzeichnis: The spectral reflectance of natural snow in the range of 0.20- to about 0.40-micrometers wavelengths was studied in the laboratory using both continuous spectral scanning and fixed bandpass measurements. White barium sulfate pressed powder was used as a standard for comparison. The reflectance of fresh snow was found to be very high (usually nearly 100%) and only weakly wavelength dependent from 0.24 micrometers to the visible range. In the 0.20- to 0.24-micrometers portion of the spectrum, the reflectance was found to be quite erratic. Possible reasons for the irregularities in reflectance measurements are discussed.

Beschreibung / Inhaltsverzeichnis: This report discusses the relationship between an architect and a behavioral scientist. Some of the discussion applies to this cooperative work for design of buildings. The bulk, however, relates to the cooperation of architect and behavioral scientist while conducting research. Examples from collaborative research at Alaskan military installations are cited which demonstrate the roles and contributions of the two disciplines.

Beschreibung / Inhaltsverzeichnis: Cold weather limits the successful application of built-up roofing, but often a roof installation must be completed late in the fall or in the winter. The loose-laid protected membrane roof with a synthetic sheet membrane can be installed in the middle of the winter with complete reliability. A synthetic membrane is traditionally more expensive than built-up roofing (rising crude oil prices, however, have reversed this condition), but it has two special features besides its suitability for winter installation: it can be placed on a damp deck, if necessary, and, being losse-laid, it does not split because of deck movement. This report documents information on the installation of two roofs in Anchorage, Alaska, during January and February 1972, including a discussion of the necessary snow removal from the bare deck and the use of portable shelters for preparing the lap joints between sheets during very cold weather. The winter installation caused no special construction problems and the advantages of the synthetic membrane make it an attractive alternative to built-up roofing. The cost of loose-laid protected membrane roofs in Alaska was, in 1972, nearly $300 per square ($28/sq.m), including insulation. Prices are rising as labor costs rise and as more insulation is specified.

Beschreibung / Inhaltsverzeichnis: Abstract: The report deals with forces and power levels in cutting machines having adisc or drum that rotates about an axis perpendicular to the direction of advance. The forces on individual cutting tools are related to position on the rotor and to characteristics such as tool layout, rotor speed, rotor size, machine advance speed, and rotor torque. Integration leads to expressions for force components acting on the rotor axis, taking into account tool characteristics, cutting depth of the rotor, and rotor torque. These provide estimates of tractive thrust and thrust normal to the primary free surface. For self-propelled machines, this leads to considerations of traction, normal reaction, weight and balance, and power/weight ratios. Specific energy consumption is analyzed and related to machine characteristics and strength ofthe material being cut. Power per unit working area is discussed, and data for existing machines are summarized. Power requirements for ejection ofcuttings are analyzed, and the hydrodynamic resistance on underwater cuttings is treated. A number of worked examples are given to illustrate the principles discussed in the report.

Beschreibung / Inhaltsverzeichnis: Abstract: Models originally developed to describe the arching and the movement of granular materials through hoppers or chutes are applied to the arching and drift of pack ice in straits and gulfs having lengths of 50 to 500 km. Verification of the usefulness of the models is attempted by making comparisons with ice deformation patterns as observed via satellite imagery in the Bering Strait region and in Amundsen Gulf. The results are encouraging in that there is good correspondence between observed arching and lead patterns and those predicted by theory. In addition, values determined via the model for the angle of internal friction (≈ 30° to 35°) and the cohesive strength per unit thickness (≈ 2000 N/m) are similar to values obtained by other approaches. It is estimated that if the wind velocity parallel to the Bering Strait exceeds ≈ 6 m/s, there will be ice flow through the strait.

Beschreibung / Inhaltsverzeichnis: A brief discussion is given of the ways an icebreaker breaks ice. Since the icebreaking process is so complex, the solution of a mathematical model does not appear to be feasible. As an alternative, it is suggested that physical models be used to design icebreakers. The appropriate scaling laws for physical models are developed and their practical limitation discussed.

Beschreibung / Inhaltsverzeichnis: Subsurface aspects of the ore-forming process can be described in terms of standard chemical transport parameters such as T-P gradients, mineral solubilities, solvent chemistry and volume, diffusion parameters and energy flow. These necessary factors are rather easily assessed by geochemical, isotopic and structural studies. If deposition is in the surface environment, a complex array of factors will determine the success of the natural concentration process and the chances of preservation of a deposit. Basically, most large-scale ore-forming processes involve large fluid volumes and energy sources. Many environments where these requirements are met, the modern ocean ridge and the subduction environment, are still not well understood. The need for remote-sensing techniques in the submarine environment is stressed.

Beschreibung / Inhaltsverzeichnis: Abstract: This report presents data from an experimental program undertaken to develop information on proposed and existing chemical grout solutions to provide engineering properties in connection with grouting of soils in ambient temperatures of 39° ±1°F (3.88°C) and below. Twelve grout solutions were investigated, including organic chemicals, sodium silicates, cements, and clay (bentonite). Set or gel tests were performed on each chemical solution, in the center of which a thermocouple was placed for measuring the rates of heat of reaction, except those of the cements and the clay. These solutions consisted of the mixing portions of the chemicals and were placed into 4-in.-diam by approximately 6-in.-long cylinders at an ambient temperature of 39°F.

Beschreibung / Inhaltsverzeichnis: A broadbanded impulse radar system was used for aerial detection of accumulated frazil and brash ice in a 9.5-km reach of the St. Lawrence River near Ogden Island. The remote sensing and data reduction system developed for the project provided data sufficient for production of a contour map having 1-ft intervals. With this contour map, the accumulation pattern of frazil and brash ice could be analyzed. Recommendations are given for improving the performance of the aerial profiling system.

Beschreibung / Inhaltsverzeichnis: This report presents experimental results on the conditions of initiation of an ice jam by a simple surface obstruction, on the equilibrium thickness of an ice jam formed by accumulation and submergence of ice floes, and on the compression strength of floating, fragmented ice cover. In the study on ice jam initiation, it was found that the minimum concentration of floes in the opening of the obstruction at which a jam occurs is nearly independent of the ratio of width of constricted passage to channel width, and is proportional to a negative power of the ratio of floe length to width of constricted passage. From energy analysis of floe submergence, a relationship relating the thickness of a jam formed by accumulation and submergence of floes to the approach flow characteristics was derived and found to fit satisfactorily the experimental data. In experiments on compression strength of floating, fragmented ice cover it was found that the compressive strength is inversely proportional to compression velocity and independent of cover length.

Beschreibung / Inhaltsverzeichnis: Results of a study to determine the feasibility of using an impulse radar to detect moisture variations in the built-up roof at CRREL and to monitor the curing of concrete are presented. The results indicate that impulse radar can be used to detect wide variations in roof moisture associated with built-up roof surface deterioration and that this technique has the potential of providing a nondestructive test method for measuring the strength of concrete during curing.

Beschreibung / Inhaltsverzeichnis: A literature search was made for information on the accretion of ice on ocean structures and on methods for control. The bulk of the reports were in Russian, with some additional Japanese, British, American, Canadian, and Icelandic sources. Analysis of icing reports indicated that sea spray is the most important cause of ship icing, with lesser amounts due to freezing rain, snow, and fog. Icing is a potential danger whenever air temperatures are below the freezing point of water and the sea temperature is 6 C or lower. Theoretical work on the ice accretion process is discussed, and a method is suggested, based on Russian experiments, for calculating the sea spray accumulation rate for cylindrical and flat surfaces as a function of water source temperature, air temperature, and wind speed. Other factors that influence icing severity are ship size and configuration, angle between ship course and water heading, and ship speed. Icing in the north temperate latitudes generally occurs in the rear of barometric depressions. Maps showing limits of various degrees of icing severity are included. Atmospheric icing measurements on tall land-based structures are presented, and potential maximum accumulations estimated. Control measures are discussed, though no completely effective method is available. Mechanical (impaction) methods are the most common, but experiments have been conducted on heated, icephobic, and deformable surfaces, and with freezing point depressants. No device for the unequivocal measurement of ice accumulation is available, though some experimental methods are suitable for controlled testing; it is recommended that a device be developed.

Beschreibung / Inhaltsverzeichnis: A computer program to calculate the increased live load on a snow-covered roof due to rain-on-snow is given. For the 25-year rainstorm falling on a heavy snow load on a flat roof in Hanover, New Hamsphire, and additional 98 kg/m2 (20 lb/ft2) of liquid water is added to the live load. The additional load due to rain-on-snow is very sensitive to the snow properties and characteristics of the roof. A wide range of live loads is possible, depending on the particular circumstances.

Beschreibung / Inhaltsverzeichnis: The breakup of the Chena River was observed and documented during the spring of 1975 and 1976. This study attempted to determine the potential for damage to the proposed Chena River flood control dam from ice and debris during breakup. Results of this study were compared to those of a 1974 companion study. In 1975, ice thickness were determined to be 15% thinner than in 1974 and ice volume was 33% smaller. No major ice floes were observed in 1975 and no significant flooding occurred, although the approaches to a bridge at the damsite were eroded by debris and high water immediately after breakup. The 1976 breakup was milder than that of 1975. Minor flooding in the lower river was caused by jamming of a few large ice pieces, but no property damage resulted.

Beschreibung / Inhaltsverzeichnis: A laboratory experimental study was conducted on a scale model of an annular flow ice-water heat sink to be used to store the waste heat produced in a hardened defense installation operating in an isolated mode. The study ex­amined: 1) scaling relationships for predicting the performance of prototype units using data from scale models, 2) the accuracy of a computer prediction technique developed during an earlier study, 3) the heat transfer phenom­enon at the ice-water interface, and 4) some practical aspects related to the operation of a prototype installation. The scaling relationships and the computer program were found to be sufficiently accurate for use in developing a proto­type sink design. During operation the scale model sink provided an almost constant low temperature source of coolant water for approximately one-half its useful life and thereafter behaved like an ordinary stored water reservoir type heat sink. No significant operational problems were discovered.

Beschreibung / Inhaltsverzeichnis: Two performance indicators, effectiveness and thermal efficiency, are defined and used to evaluate the year-round performance of three protected membrane roofs in Alaska and New Hampshire. Effectiveness is a measure of the deviations of ceiling temperatures from a yearly average, with large diviations indicating erratic performance in the roofing-insulation system and small departures indicating a thermally stable system. Thermal efficiency, the ratio of calculated heat loss to measured heat loss, is affected by climatic conditions such as rain, snow, solar radiation and wind. Thermal efficiency values of 100% or greater are possible since the calculated heat loss is based only on the inside and outside air temperature differences and the thermal properties of the roof components. Results of the year-round evaluation indicate that the three protected membrane roofs generally have high values of both effectiveness and thermal efficiency.

Beschreibung / Inhaltsverzeichnis: Abstract: The amount of force that an ice sheet can apply to a vertical pile was tested by lowering a hydraulic ram device into a hole cut in an existing ice sheet. The device had a large base and shoved a relatively narrow vertical pile in a horizontal direction. Test variables were: pile widths - 1.5 in. to 36.7 in.; pile shapes - flat, round, 45 ° and 90° wedges; ice thickness - 2.6 in. to 8.8 in.; and ram speed - 0.07 in./sec to 18.75 in./sec; but not all shapes and sizes were tested at all speeds. Air temperature was 20 ° F (-6.7 ° C). Forces and displacements were measured electronically. The findings are presented as a table of test results and as bar graphs of the resultant ice pressures versus the pile width-to-ice-thickness ratio, pile width and shape combination and pile velocity. The types of failures in the ice sheet were classified as crushing, splitting, buckling, bending, and creeping. The ice sheet generally withstood a high initial load followed by several lower peak load levels. The maximum ice pressure measured was 610 psi for a 12.6-in.-diam round pile in 8.4-in.-thick ice.