ALBERT

Description: Micro-Raman spectroscopy has been used on adult bivalve shells to investigate organic and inorganic shell components but has not yet been applied to bivalve larvae. It is known that the organic matrix of larval shells contains pigments, but less is known about the presence or source of these molecules in larvae. We investigated Raman spectra of seven species of bivalve larvae to assess the types of pigments present in shells of each species and how the ratio of inorganic : organic material changes in a dorso-ventral direction. In laboratory experiments, we reared larvae of three clam species in waters containing different organic signatures to determine if larvae incorporated compounds from source waters into their shells. We found differences in spectra and pigments between most species but found less intraspecific differences. A neural network classifier for Raman spectra classified five out of seven species with greater than 85% accuracy. There were slight differences between the amount and type of pigment present along the shell, with the prodissoconch I and shell margin areas being the most variable. Raman spectra of 1-day-old larvae were found to be differentiable when larvae were reared in waters with different organic signatures. With micro-Raman spectroscopy, it may be possible to identify some unknown species in the wild and trace their natal origins, which could enhance identification accuracy of bivalve larvae and ultimately aid management and restoration efforts.

Description: The stratigraphic successions exposed in Wadi El Mizeira have been dated through the analysis of the calcareous nannofossil assemblages. The results of this study indicate that the successions comprise the Santonian-Late Maastrichtian (Sudr Formation), the Paleocene (Esna Formation) and the Early Eocene (Thebes Formation). The following biozones were recognized: Late Santonian, CC16 Zone; Late Santonian/Early Campanian, CC17 Zone; Early Campanian, Aspidolithus parcus Zone (CC18) Zone; Late Maastrichtian, CC25c Zone; Early Paleocene (Late Danian), NP3 Zone and NP4 Zone; Late Paleocene (Thanethian-Selandian), NP5 Zone; Early Eocene, NP9b Zone, NP10a Zone, NP11 Zone, NP12 Zone and NP14 Zone. Several stratigraphic hiatus were recorded in the studied interval including the absence of Cretaceous nannofossil Zones CC19 to CC25b and CC26 as well as the early Paleocene Zones NP1 and NP2 and probably the basal part of Zone NP3, in addition to the absence of the Zones NP6 and NP7/8. These hiatus may be attributed to environmental conditions, structural activity and/or post depositional processes. This work represents the first attempt to evaluate the nannofossil taxa of the Wadi El Mizeira, Northeastern Sinai.

Description: Hemigrapsus sanguineus (Asian Shore Crab) has shown a remarkable ability to colonize rocky intertidal communities along the east coast of the United States since its introduction in the late 1980s and is an important predator of juvenile Mytilus edulis (Blue Mussel) in invaded habitats. In this study, we used two field-caging experiments and the Kaplan-Meier model to assess the impact of predation by Asian Shore Crab on the survival of juvenile Blue Mussels in an intertidal habitat of western Long Island Sound along the Connecticut coastline. Five treatment levels (high-density enclosure, low-density enclosure, exclosure, partial cage, and open plot) were used in the 2007 experiment. The high-density enclosure treatment was omitted in the 2010 experiment since there was no statistically significant difference in the proportion of mussels surviving between low- and high-density crab treatments in 2007. In 2007, we measured a statistically significant difference in mussel mortality between exclosure and crab-enclosure cages, with crabs lowering the median survival time for mussels from 15.4 to 7.6 days. In 2010, we again measured a statistically significant difference in mussel mortality between exclosure and crab-enclosure cages, suggesting a crab effect on mussel survival. In the 2010 experiment, approximately 25% of the mussel mortality was attributable to crab predation, which reduced median survival time for mussels from 12.8 to 5.6 days. The median survival time for mussels exposed to the full complement of factors affecting survival (open plots and partial cages) was only 2–3 days. Our study shows that predation by Asian crabs may account for up to 25% of the Blue Mussel mortality in the intertidal zone at Black Rock Harbor. Further studies focusing on the importance of other biotic and abiotic factors are needed to understand the apparent declines in Blue Mussel populations and the interannual variability in recruitment success in this area.

Description: Marine phytoplankton blooms are annual spring events that sustain active and diverse bloom-associated bacterial populations. Blooms vary considerably in terms of eukaryotic species composition and environmental conditions, but a limited number of heterotrophic bacterial lineages — primarily members of the Flavobacteriia, Alphaproteobacteria and Gammaproteobacteria — dominate these communities. In this Review, we discuss the central role that these bacteria have in transforming phytoplankton-derived organic matter and thus in biogeochemical nutrient cycling. On the basis of selected field and laboratory-based studies of flavobacteria and roseobacters, distinct metabolic strategies are emerging for these archetypal phytoplankton-associated taxa, which provide insights into the underlying mechanisms that dictate their behaviours during blooms.

Description: An increasing body of research emphasizes that various biological processes in marine organisms are affected due to the uptake of anthropogenic atmospheric CO2 by the ocean in a process termed as ocean acidification (OA). The magnitude and direction of OA effects varies greatly among species and genotypes, highlighting different capabilities to adapt to increasing CO2. Direct OA impacts can be expected in the biochemical and elemental composition of primary producers (PP), which may be transferred to higher trophic levels, while indirect impacts can derive from altered trophic interactions as OA can modify plankton community composition. Fatty acids (FA) are the main component of lipids and cell membranes, with polyunsaturated fatty acids (PUFA) having additional important physiological and metabolic roles. Phytoplankton is the main source of essential biomolecules for heterotrophs as they cannot synthesize them de novo. Transference of organic essential macromolecules, in particular PUFA from phytoplankton-to-zooplankton-to-fish is a key factor influencing the life cycle of many organisms including humans. In the present work was investigated how OA influences the food quality of primary producers in terms of their fatty acid makeup at specie and community level, and how these OA-driven changes in the algae affect the fatty acid profile and life cycle of consumers. A combination of short- and long-term experiments on individual algal species, interaction between a single primary producer and one consumer, and natural plankton communities encompassing several producers and consumers were conducted in laboratory and natural conditions. In the short-term experiments at species level, the first and second laboratory study showed that CO2 can affect the biochemical composition of the diatoms Thalassiosira pseudonana and Cylindrotheca fusiformis, reducing their PUFA content; additionally the second diatom showed a reduced amount of amino acids. The interaction between a single primary producer and one consumer showed that when T. pseudonana cultured under high CO2 was used to feed the copepod Acartia tonsa, it affected their FA composition, severely impaired development and egg production rates. This demonstrated that a direct OA-driven shift in algal food quality can influence the reproduction success of upper trophic levels. At the community level, the third study conducted in a North Sea natural plankton assemblage subjected to a CO2 gradient showed that OA can modify phytoplankton community structures by favoring small phytoplankton cells with a comparatively low PUFA content. This community shift reduced PUFA content in primary producers was linked to a gradual PUFA decline in the dominant copepod species Calanus finmarchicus. In contrary, the fourth study revealed that the natural plankton community of the Baltic Sea experienced small differences in the algal community composition between CO2 treatments. The PUFA profile of the PP was influenced by phosphorus availability in the mesocosms, which was reflected by the PUFA composition of the copepod Acartia tonsa and Eurytemora affinis, but showed no significant CO2-related changes. This indicates that OA can affect the plankton community composition and its associated PUFA content, however this effect is lower in environments where communities are exposed to natural occurring high CO2 fluctuations like in the Baltic Sea, and that other essential nutrients have a stronger influence in the algal FA profile when present in limited amounts. In the long term experiments at species level, the fourth study determined that the coccolithophore Emiliania huxleyi and the diazotrophic cyanobacterium Trichodesmium sp. cultured over a thousand generations at high CO2 conditions showed a change in their FA content and composition. The FA profile of both algae presented a differentiate adaptation to high CO2 and particularly PUFA, which have metabolic functions in the cells, displayed evidence of adaptive evolution in both algae. These results highlight the diversity of OA responses among single plankton species and communities and that changes in biomolecular composition at the base of the marine food web are transferred to primary consumers. The thesis also highlights that the magnitude and direction of CO2-effects likely depends on the CO2 conditions and fluctuations the organisms are adapted to.

Description: The increasing scientific and economic interest in the visual exploration and monitoring of marine areas is creating huge amounts of new underwater image and video data and approaches to computationally assisted analysis are desperately needed. In this paper we propose an image patch feature representation concept, the Bag of Prototypes (BoP), to cope with the individual problems in underwater image analysis. We consider the case of seafloor classification, which is relevant in many contexts such as habitat mapping or the exploration of mineral resources and show, that the BoP concept allows an efficient and accurate tile-wise estimation of poly-metallic nodule coverage in relation to two differently acquired gold standards.

Description: Sunscreens have been shown to give the most effective protection for human skin from ultraviolet (UV) radiation. Chemicals from sunscreens (i.e., UV filters) accumulate in the sea and have toxic effects on marine organisms. In this report, we demonstrate that photoexcitation of inorganic UV filters (i.e., TiO2 and ZnO nanoparticles) under solar radiation produces significant amounts of hydrogen peroxide (H2O2), a strong oxidizing agent that generates high levels of stress on marine phytoplankton. Our results indicate that the inorganic oxide nanoparticle content in 1 g of commercial sunscreen produces rates of H2O2 in seawater of up to 463 nM/h, directly affecting the growth of phytoplankton. Conservative estimates for a Mediterranean beach reveal that tourism activities during a summer day may release on the order of 4 kg of TiO2 nanoparticles to the water and produce an increment in the concentration of H2O2 of 270 nM/day. Our results, together with the data provided by tourism records in the Mediterranean, point to TiO2 nanoparticles as the major oxidizing agent entering coastal waters, with direct ecological consequences on the ecosystem.

Description: Cold-water coral (CWC) reefs constitute one of the most complex deep-sea habitats harboring a vast diversity of associated species. Like other tropical or temperate framework builders, these systems are facing an uncertain future due to several threats, such as global warming and ocean acidification. In the case of Mediterranean CWC communities, the effect may be exacerbated due to the greater capacity of these waters to absorb atmospheric CO2 compared to the global ocean. Calcification in these organisms is an energy-demanding process, and it is expected that energy requirements will be greater as seawater pH and the availability of carbonate ions decrease. Therefore, studies assessing the effect of a pH decrease in skeletal growth, and metabolic balance are critical to fully understand the potential responses of these organisms under a changing scenario. In this context, the present work aims to investigate the medium- to long-term effect of a low pH scenario on calcification and the biochemical composition of two CWCs from the Mediterranean, Dendrophyllia cornigera and Desmophyllum dianthus. After 314 d of exposure to acidified conditions, a significant decrease of 70 % was observed in Desmophyllum dianthus skeletal growth rate, while Dendrophyllia cornigera showed no differences between treatments. Instead, only subtle differences between treatments were observed in the organic matter amount, lipid content, skeletal microdensity, or porosity in both species, although due to the high variability of the results, these differences were not statistically significant. Our results also confirmed a heterogeneous effect of low pH on the skeletal growth rate of the organisms depending on their initial weight, suggesting that those specimens with high calcification rates may be the most susceptible to the negative effects of acidification.

Description: Underwater optical wireless communication is an emerging technology, which can provide high data rate. High data rate communication is required for applications such as underwater imaging, networks of sensors and swarms of underwater vehicles. These applications pursue an affordable light source, which can be obtained by light emitting diodes (LED). LEDs offer solutions characterized by low cost, high efficiency, reliability and compactness based on off-the-shelf components such as blue and green light emitting diodes. In this paper we present our recent theoretical and experimental results in this field.

Description: INTRODUCTION: Lichens are self-sustaining partnerships comprising fungi as shape-forming partners for their enclosed symbiotic algae. They produce a tremendous diversity of metabolites (1050 metabolites described so far). OBJECTIVES: A comparison of metabolic profiles in nine lichen species belonging to three genera (Lichina, Collema and Roccella) by using an optimised extraction protocol, determination of the fragmentation pathway and the in situ localisation for major compounds in Roccella species. METHODS: Chemical analysis was performed using a complementary study combining a Taguchi experimental design with qualitative analysis by high-performance liquid chromatography coupled with mass spectrometry techniques. RESULTS: Optimal conditions to obtain the best total extraction yield were determined as follows: mortar grinding to a fine powder, two successive extractions, solid:liquid ratio (2:60) and 700 rpm stirring. Qualitative analysis of the metabolite profiling of these nine species extracted with the optimised method was corroborated using MS and MS/MS approaches. Nine main compounds were identified: 1 β-orcinol, 2 orsellinic acid, 3 putative choline sulphate, 4 roccellic acid, 5 montagnetol, 6 lecanoric acid, 7 erythrin, 8 lepraric acid and 9 acetylportentol, and several other compounds were reported. Identification was performed using the m/z ratio, fragmentation pathway and/or after isolation by NMR analysis. The variation of the metabolite profile in differently organised parts of two Roccella species suggests a specific role of major compounds in developmental stages of this symbiotic association. CONCLUSION: Metabolic profiles represent specific chemical species and depend on the extraction conditions, the kind of the photobiont partner and the in situ localisation of major compounds.

Description: For continuously-taken seafloor photographs of polymetallic nodule, automatic procedures of image processing and subsequent treatment of a vast amount of data have been developed for estimating parameters representing distribution of polymetallic nodules such as sizes, numbers, coverage and abundance of nodules. The authors discussed about the related topics, based on digital photographic data obtained from survey cruises conducted in Japanese license area in Clarion-Clipperton Fracture Zone. First, the authors calculated systematic errors of estimation which can be caused by miss-setting of the threshold values used in the automatic extraction of polymetallic nodules. Second, the degree of the heterogeneity of nodule distribution was estimated quantitatively by differences of statistical characteristics between adjacent seafloor photographs. Since strategies of the procedures such as segregation of connected nodules or distinction between nodule and other materials can also cause systematic difference of the estimation, the strategies should be explicitly pronounced for compilation of photographs and analyzed data with different backgrounds.

Description: The Atlantic meridional overturning circulation (AMOC) carries large amounts of heat into the North Atlantic influencing climate regionally as well as globally. Palaeo-records and simulations with comprehensive climate models suggest that the positive salt-advection feedback may yield a threshold behaviour of the system. That is to say that beyond a certain amount of freshwater flux into the North Atlantic, no meridional overturning circulation can be sustained. Concepts of monitoring the AMOC and identifying its vicinity to the threshold rely on the fact that the volume flux defining the AMOC will be reduced when approaching the threshold. Here we advance conceptual models that have been used in a paradigmatic way to understand the AMOC, by introducing a density-dependent parameterization for the Southern Ocean eddies. This additional degree of freedom uncovers a mechanism by which the AMOC can increase with additional freshwater flux into the North Atlantic, before it reaches the threshold and collapses: an AMOC that is mainly wind-driven will have a constant upwelling as long as the Southern Ocean winds do not change significantly. The downward transport of tracers occurs either in the northern sinking regions or through Southern Ocean eddies. If freshwater is transported, either atmospherically or via horizontal gyres, from the low to high latitudes, this would reduce the eddy transport and by continuity increase the northern sinking which defines the AMOC until a threshold is reached at which the AMOC cannot be sustained. If dominant in the real ocean this mechanism would have significant consequences for monitoring the AMOC.

Description: Summary During this cruise a detailed multi-disciplinary research program was conducted at the Peruvian oxygen minimum zone (OMZ) within the framework of the Kiel SFB 754. Investigations were primarily conducted along a depth transect at 12° S. Major aim was to advance understanding of how OMZ´s are maintained and to determine feedbacks of benthic nutrient release on the currently expanding Peruvian OMZ with a major focus on i. variability of benthic nutrient release in response to hydrodynamic forcing and regional differences in bottom water levels of oxygen (O2), nitrate (NO3-), nitrite (NO2-), and sedimentary carbon content, ii. diapycnal and advective fluxes of excess dinitrogen (N2), ammonium (NH4+), phosphorous (P), iron (Fe), silicate (Si), and radium isotopes between the benthic boundary layer, and the stratified interior ocean as well as their entrainment into the surface mixed layer and iii. processes involved in the respective benthic N, Fe, and P cycles. To achieve this goal, physical and biogeochemical measurements were conducted in the water column as well as at the sea floor. For investigations in the water column a total of 84 CTD casts, 41 micro-structure CTD, 20 in situ pump and 12 GoFlo deployments were performed. Sediment samples were obtained during 50 multiple corer casts, 12 gravity corers and 10 benthic chamber lander deployments. Furthermore a profiler lander was used to determine in situ microprofiles of O2, NO3- and nitrous oxide (N2O) in situ. Microprofiles were obtained using glass-microsensors that were pushed into the sediment in 300 μm increments. In order to obtain time series data on the oxygen distribution and the current regime oceanographic moorings were distributed along the 12°S transect in addition to four benthic satellite-landers each equipped with upward looking ADCPs. Lastly, a glider swarm was established at 12°S. These instruments were deployed for the duration of cruise M92 as well as for the subsequent M93 cruise. Deviating from the cruise proposal, more time was spent for station works at the depth transect at 12° S. Major aim of this cruise was to obtain a coherent data set of all involved groups, which however took slightly more time than originally planned, yet bears a high scientific potential. Additionally, it was discovered that at 12° S in shallow waters sulphide was released from the seabed into the bottom water. Furthermore, in water depths from about 120 to 200 m nitrite in addition to nitrate was available in high concentrations which affects the benthic nitrogen cycle to a hitherto unknown extent. Hence these stations were more intensely investigated than originally planned. Weather conditions were fine and all deployments of the scientific gear went very well. It is expected that after analyses and synthesis of the different data sets from the different disciplines the scientific questions above can be addressed to broad extent.

Description: Before the present cruise, no hydrothermal vent sites had been explored in the south Atlantic south of 13°S. As a result of the work in SPP1144 (From Mantle to Ocean: Energy-, Materialand Lifecycles at Spreading Axes), Devey et al. (2010) proposed a model for the relation between volcanism and hydrothermalism. The aim of the cruise was to use a systematic approach to explore the Mid-Atlantic Ridge between 13° and 33°S for hydrothermal activity and plume dispersal by using combined AUV deployments and ship-based CTD casts. The cruise had the following scientific goals: - Testing the link between volcanism and hydrothermalism: The model proposed by Devey et al. (2010) suggests that hydrothermal activity will be almost constant on marked within-axis volcanic highs (as at Turtle Pits) but relatively seldom at deeper parts of the axis. As the time-scale of activity on the deeper parts of the ridges is likely to be on the order of 1000's of years we needed to use geography as a proxy for time - surveying multiple segments for hydrothermal activity to find one in the eruptive phase. - Testing the link between ridge morphology and strength of oceanic diapycnal mixing: The sampling of a large variety of ridge morphology should allow a better understand of the relation between mixing strength, flow properties, and bathymetric roughness. The strength of mixing above the ridge crest and in the axial valley determines to a large extent the vertical exchange of chemical species from the hydrothermal fluids and the ocean interior. - Large scale mapping of plume dispersal: Combined along-axis CTD (Conductivity, Temperature, Depth), plume chemistry (helium, methane, metals, rare elements), and current measurement can allow characterization of the large scale, particularly along axis, displacement of plume material and identification of possible pathways for larvae dispersal. - Closing the gap between 10°S and the Antarctic ridges of ridge crest explored for hydrothermal activity, a region of high importance for the definition of biogeographical boundaries. - Refining hydrothermal plume hunting techniques: The long-range AUV (Autonomous Underwater Vehicles) deployments coupled with ship-based CTD casts offered the possibility to survey whole segments in relatively short time-periods. Although a thorough analysis of the cruise results (particularly for physical oceanography) will require extensive post-cruise work, it is already clear that: 1. The marked within-axis highs show the expected chronic hydrothermal activity, confirming and reinforcing the proposed model. In addition we found the most southerly-known axial oceanic core complex and found it also to be associated with hightemperature venting. 2. Using co-registered AUV and CTD data over these highs we were able to map, for the first time, the 3D extent of hydrothermal plumes (see cover illustration). The combination of the vertical resolution of the CTD Tow-Yo with the horizontal resolution of a near-bottom (50m altitude) AUV raster gave an almost synoptic view of the venting over the entire summit. Together with the high-resolution side-scan data recorded by the AUV (which allowed us to identify and locate individual chimneys associated with the hydrothermal plumes and determine their geological setting) this provides the ideal basis for preparing to return to these biogeographically important sites to sample the ecosystems they sustain and determine the oceanographic features relevant for local larval dispersal. 3. On ridges without within-axis highs we also found occasional signs of hydrothermal activity, proving the efficiency of the combined AUV+CTD exploration method. An additional bonus from the AUV deployments was that we were able to simultaneously collect a single swath of high-frequency side-scan sonar data along the axial valley and hence derive information about the style and relative age of volcanism along-axis.

Description: Brackish coastal groundwater is enriched in Ra, which is transported to surface waters via submarine groundwater discharge (SGD). The Ra activity of the SGD end-member is influenced by a variety of environmental factors including salinity, pH, and isotope half-life. In the York River estuary (YRE), 223Ra, 224Ra, and 226Ra were measured in surface water and shallow groundwater across a range of salinities and additional Ra sources quantified (desorption and diffusion from sediments, input from tidal marshes). The Ra budget of the estuary indicated a major source of Ra that could only be satisfied by SGD. The apparent Ra flux was combined with groundwater Ra end-member activity to estimate SGD volume fluxes of 5–178 L m− 2 d− 1. Each isotope exhibited a different seasonal pattern, with significantly higher 224Ra flux during summer than winter, lower 226Ra SGD flux during summer than winter, and no seasonal differences in 223Ra SGD flux. However, the SGD 224Ra end-member activity varied with seasonal pore water salinity fluctuations, indicating end-member control on seasonal 224Ra flux. Each Ra isotope suggested a different SGD volume flux, indicating that different nuclide regeneration rates may respond to and reflect different flow mechanisms in the subterranean estuary. This work indicates that volume fluxes estimated using geochemical tracers are sensitive to SGD end-member variations and end-member variability must be well-characterized for reliable SGD flux estimates.

Description: In this paper we present an in-depth analysis and synthesis of published and newly acquired data on the chemical and isotopic composition of forearc fluids, fluid fluxes, and the associated thermal regimes in well-studied, representative erosional and accretionary subduction zone (SZ) forearcs. Evidence of large-scale fluid flow, primarily focused along faults, is manifested by widespread seafloor venting, associated biological communities, extensive authigenic carbonate formation, chemical and isotopic anomalies in pore-fluid depth-profiles, and thermal anomalies. The nature of fluid venting seems to differ at the two types of SZs. At both, fluid and gas venting sites are primarily associated with faults. The décollement and coarser-grained stratigraphic horizons are the main fluid conduits at accretionary SZs, whereas at non-accreting and erosive margins, the fluids from compaction and dehydration reactions are to a great extent partitioned between the décollement and focused conduits through the prism, respectively. The measured fluid output fluxes at seeps are high, ∼15–40 times the amount that can be produced through local steady-state compaction, suggesting that in addition, other fluid sources or non-steady-state fluid flow must be involved. Recirculation of seawater must be an important component of the overall forearc output fluid flux in SZs. The most significant chemical and isotopic characteristics of the expelled fluids relative to seawater are: Cl dilution; sulfate, Ca, and Mg depletions; and enrichments in Li, B, Si, Sr, alkalinity, and hydrocarbon concentrations, often distinctive δ18O, δD, δ7Li, δ11B, and δ37Cl values, and variable Sr isotope ratios. These characteristics provide key insights on the source of the fluid and the temperature at the source. Based on the fluid chemistry, the most often reported source temperatures reported are 120–150 °C. We estimate a residence time of the global ocean in SZs of ∼100 Myr, about five times faster than the previous estimate of ∼500 Myr by Moore and Vrolijk, similar to the residence time of ∼90 Myr for fluids in the global ridge crest estimated by Elderfield and Schultz, and ∼3 times longer than the 20–36 Myr estimate by German and von Damm and Mottl. Based on this extrapolated fluid reflux to the global ocean, subduction zones are an important source and sink for several elements and isotopic ratios, in particular an important sink for seawater sulfate, Ca and Mg, and an important source of Li and B.

Description: Three volcanic ash layers were identified in a deep-sea Core IR-GC1 from the north-eastern Indian Ocean, adjacent to western Indonesian arc. They were dominated by glass shards with minor mineral crystals, such as plagioclase, biotite, and hornblende. According to the morphology and major element compositions of the representative glass shards, combined with the 18O-based age, it is suggested that ash Layer A is correlated to the youngest Toba tuff (YTT), Layer B is supposed to be associated with a new eruption of Toba caldera in an age of 98 to 100 ka. Ash Layer C is different the geochemistry characteristics than those of Layer A and Layer B, suggesting that Layer C was not originated from Toba but registered another volcanic eruption event.

Description: Uncertainty over the identity and age of Toba tephras across peninsular India persists, with radiometric age dates contradicting earlier compositional data, which have been used to identify this important Stratigraphie marker as the Youngest Toba Tuff (YTT). To address this issue, new single glass shard analyses have been performed for samples from Morgaon and Bori (north-western India), which have recently been dated at c. 800 ka. These, and indeed all Toba tephra samples thus far analysed from India, show the presence of four populations of glass shards (defined by their Ba/Y ratio), which uniquely identifies them as products of the c. 75-ka Youngest Toba eruption. Confirmation that the YTT fingerprint is characteristic comes from new analyses of Oldest Toba Tuff (OTT) glass shards from five sites in the Indian Ocean. These are compositionally identical to Layer D from the ODP site 758 Sediment core (c. 800 ka), and belong to a single, low-Ba population, clearly different from YTT. These analyses show that there is essentially no reworked OTT material in the YTT eruption, and indicate unequivocally that all known Toba tephra occurrences in India belong to the c. 75-ka Youngest Toba eruption.

Description: All records of the 15 hexactinellid sponge species known to occur off Chile are reviewed, including the first record in the Southeastern Pacific of the genus Caulophacus Schulze, 1885, with the new species Caulophacus chilense sp. n. collected as bycatch in the deep water fisheries of the Patagonian toothfish Dissostichus eleginoides Smitt, 1898 off Caldera (27ºS), Region of Atacama, northern Chile. All Chilean hexactinellid species occur in bathyal to abyssal depths (from 256 up to 4142 m); nine of them are reported for the Sala y Gomez and Nazca Ridges, with one species each in the Juan Fernandez Archipelago and Easter Island. The Chilean hexactinellid fauna is still largely unknown, consisting of only 2.5 % of the known hexactinellid extant species. Further studies and deep water sampling are essential to assess their ecology and distribution, particularly in northern Chile.

Description: Structure I methane hydrates are formed in situ from water-in-mineral oil emulsions in a high pressure rheometer cell. Viscosity is measured as hydrates form, grow, change under flow, and dissociate. Experiments are performed at varying water volume fraction in the original emulsion (0–0.40), temperature (0–6 °C), and initial pressure of methane (750–1500 psig). Hydrate slurries exhibit a sharp increase in viscosity upon hydrate formation, followed by complex behavior dictated by factors including continued hydrate formation, shear alignment, methane depletion/dissolution, aggregate formation, and capillary bridging. Hydrate slurries possess a yield stress and are shear-thinning fluids, which are described by the Cross model. Hydrate slurry viscosity and yield stress increased with increasing water volume fraction. As driving force for hydrate formation decreases (increasing temperature, decreasing pressure), hydrate slurry viscosity increases, suggesting that slower hydrate formation leads to larger and more porous aggregates. In total, addition of water to a methane saturated oil can cause more than a fifty-fold increase in viscosity if hydrates form.

Description: A very close coupling exists between changes in atmospheric O2 and CO2 concentrations, owing to the chemistry of photosynthesis, respiration, and combustion. The coupling is not perfect, however, because CO2 variations are partially buffered by reactions involving the inorganic carbon system in seawater, which has no effect on O2. Measurements over the past two decades document variations in O2 on a range of space and time scales, including a long-term decrease driven mostly by fossil fuel burning and seasonal cycles driven by exchanges with the land biosphere and the oceans. In this chapter, these and other features seen in the measurements are described, also discussing variations in the tracer ‘atmospheric potential oxygen,’ which is a linear combination of O2 and CO2 designed to be insensitive to exchanges from the land biosphere and thereby sensitive mostly to oceanic processes. Challenges associated with measuring variations in O2 are addressed, and various applications of the observations are discussed, including quantifying the magnitude of the global land and ocean carbon sinks and testing ocean biogeochemical models. An updated budget for global carbon sinks based on O2 measurements from the Scripps O2 program is presented for the decades of the 1990s and 2000s.

Description: The behaviour of cemented soil and the role of cementation are reviewed based on experimental results. The review is presented in terms of geomechanics concepts in which the cemented soil may be modelled by elasticity and hardening plasticity concepts. No modelling equations are given, but the observed behaviour is analysed in view of the components entering into an elastoplastic model. These consist of an elastic range in stress space in which energy is not created or expended, a cementation yield surface, a 3D failure surface, a plastic potential, a yield surface and the associated plastic hardening law.

Description: Marine laminated sediments in dysoxic areas of the ocean floor are an excellent archive for high-resolution climate reconstructions. While the existence of discontinuities produced by natural events, such as underwater landslides (slumps), strong bottom currents, and/or bioturbation is usually acknowledged for long records, the extent of their influence on high-resolution sequences is usually not considered. In the present work we show strong evidence for multiple stratigraphic discontinuities in different gravity and box-cores retrieved off Pisco (Peru) covering the last 600 years. Chronostratigraphies are largely based on cross-correlation of distinct sedimentary structures (determined by X-ray image analysis) and validated using 210Pb, 241Am, and 14C profiles, as well as proxy records. The cross-correlation of distinct stratigraphic layers allows for chronostratigraphic tie points and clearly shows that some sedimentary sequences are continuous across scales of tens of kilometers, indicating that regional processes often determine laminae formation. Some differences in laminae thickness were found among cores, which could be explained by different sedimentation rates, spatially variable deposition of diatom blooms, changes in silica dissolution and partial deposition/erosion caused by bottom currents. Using multiple stratigraphic tie points provides clear evidence for laminated sequences present in some cores to be missing in other cores. Moreover, instantaneous depositions from upslope were identified in all the cores disrupting the continuity of the sediment records. These discontinuities (instantaneous deposits and missing sequences) may be due to slumps, possibly triggered by earthquakes and/or erosion by strong bottom currents. In spite of the missing sequences in some cores, a continuous composite record of the last six centuries was reconstructed from spliced sequences of the different cores, which provides a well-constrained temporal framework to develop further high-resolution proxies in this region. The present work shows that paleoreconstructions developed from single cores, particularly in areas with strong seismic activity and/or strong bottom currents, are subject to both temporal gaps and instantaneous depositions from upslope, both of which could be misinterpreted as abrupt climate changes or anomalous climate events. We stress the need for multiple cores to determine the stratigraphic continuity and chronologies for high-resolution records.

Description: The next generation of seismic imaging algorithms will use full wavefield migration, which regards multiple scattering as indispensable information. These algorithms will also include autonomous velocity-updating in the migration process, called joint migration inversion. Full wavefield migration and joint migration inversion address industrial requirements to improve the images of highly complex reservoirs as well as the industrial ambition to produce these images more automatically (automation in seismic processing). In these vision papers on seismic imaging, full wavefield migration and joint migration inversion are formulated in terms of a closed-loop, estimation algorithm that can be physically explained by an iterative double-focusing process (full wavefield Common Focus Point technology). A critical module in this formulation is forward modelling, allowing feedback from the migrated output to the unmigrated input (‘closing the loop’). For this purpose, a full wavefield modelling module has been developed, which uses an operator description of complex geology. Full wavefield modelling is pre-eminently suited to function in the feedback path of a closed-loop migration algorithm. ‘The Future of Seismic Imaging’ is presented as a coherent trilogy of papers that propose the migration framework of the future. In Part I, the theory of full wavefield modelling is explained, showing the fundamental distinction with the finite-difference approach. Full wavefield modelling allows the computation of complex shot records without the specification of velocity and density models. Instead, an operator description of the subsurface is used. The capability of full wavefield modelling is illustrated with examples. Finally, the theory of full wavefield modelling is extended to full wavefield reverse modelling (FWMod−1), which allows accurate estimation of (blended) source properties from (blended) shot records.

Description: The next generation seismic imaging algorithms will consider multiple scattering as indispensable information, referred to as FullWavefieldMigration. In addition, these algorithms will also include autonomous velocity updating in the migration process, referred to as Joint Migration Inversion. Full wavefield migration and joint migration inversion address the industrial needs of improving images of very complex reservoirs as well as the industry ambition of producing these images in a more automatic manner (‘automation in seismic processing’). In this vision paper on seismic imaging, full wavefield migration and joint migration inversion are formulated in terms of a closed-loop, estimation algorithm that can be physically explained by an iterative double focusing process (full wavefield Common- Focus-Point technology). A critical module in this formulation is forward modelling, allowing feedback from migrated output to unmigrated input (‘closing the loop’). For this purpose a full wavefield modelling module has been developed that utilizes an operator description of complex geology. Full wavefield modelling module is pre-eminently suited to function in the feedback path of a closed-loop migration algorithm. ‘The Future of Seismic Imaging’ is presented as a coherent trilogy, proposing in three consecutive parts the migration framework of the future. In part I it was shown that the proposed full wavefield modelling module algorithm differs fundamentally from finite difference modelling, as velocities and densities need not be provided. Instead, full wavefield modelling module uses an operator description of the subsurface. In Part II it was shown how the theory of Primary WavefieldMigration can be extended to Full Wavefield Migration by correcting for elastic transmission effects and by utilizing multiple scattering. In Part III it is shown how the full wavefield migration technology can be extended to Joint Migration Inversion, allowing full wavefield migration of blended data without knowledge of the velocity. Velocities are part of the joint migration inversion output, being obtained by an operator-driven parametric inversion process. The potential of the proposed joint migration inversion algorithm is illustrated with numerical examples.

Description: The next-generation seismic imaging algorithms will consider multiple scattering as indispensable information, being referred to as Full-WavefieldMigration. In addition, these algorithms will also include autonomous velocity updating in the migration process, being referred to as Joint Migration Inversion. Full-Wavefield Migration and Joint Migration Inversion address the industrial needs to improve images of very complex reservoirs as well as the industrial ambition to produce these images in a more automatic manner (automation in seismic processing). In this vision paper on seismic imaging, Full-Wavefield Migration and Joint Migration Inversion are formulated in terms of a closed-loop estimation algorithm that can be physically explained by an iterative double focusing process (full-wavefield common-focus-point technology). A critical module in this formulation is forward modelling, allowing feedback from migrated output to unmigrated input (closing the loop). For this purpose, a full-wavefield modelling module has been developed, which utilizes an operator description of complex geology. The full-wavefield modelling module is pre-eminently suited to function in the feedback path of a closed-loop migration algorithm. ‘The Future of Seismic Imaging’ is presented as a coherent trilogy, proposing the migration framework of the future in three consecutive parts. In Part I, it was shown that the proposed full-wavefield modelling module algorithm differs fundamentally from finite-difference modelling because velocities and densities need not be provided. Instead, an operator description of the subsurface is used. In addition, the concept of reverse modelling was introduced. In Part II, it is shown how the theory of Primary Wavefield Migration can be extended to Full-Wavefield Migration by correcting for angle-dependent transmission effects and by utilizing multiple scattering. The potential of the Full-Wavefield Migration algorithm is illustrated with numerical examples. A multidirectional migration strategy is proposed that navigates the Full- Wavefield Migration algorithm through the seismic data cube in different directions.

Description: Forazoline A, a novel antifungal polyketide with in vivo efficacy against Candida albicans, was discovered using LCMS-based metabolomics to investigate marine-invertebrate-associated bacteria. Forazoline A had a highly unusual and unprecedented skeleton. Acquisition of 13C–13C gCOSY and 13C–15N HMQC NMR data provided the direct carbon–carbon and carbon–nitrogen connectivity, respectively. This approach represents the first example of determining direct 13C–15N connectivity for a natural product. Using yeast chemical genomics, we propose that forazoline A operated through a new mechanism of action with a phenotypic outcome of disrupting membrane integrity.

Description: Caledonian amphibolite-facies shear zones developed in granulitefacies anorthosites and anorthositic gabbros of the Bergen Arcs, western Norway, allow a detailed study of the relationships between fluid-infiltration, mineral reactions, the evolution of microstructure and deformation mechanisms. A sequence of rocks from the relatively pristine granulites into a shear zone has been studied by optical microscopy, electron microprobe microanalysis (EMPA), scanning electron microscopy (SEM), electron backscatter diffraction (EBSD) and transmission electron microscopy (TEM), focusing on the progressive development of microstructure in the plagioclase feldspars, leading up to their deformation in the shear zone. At the outcrop scale, fluid infiltration into the granulites is marked by a distinct colour change in the plagioclase from lilac-brown to white.This is associated with the breakdown of the intermediate composition plagioclase (-An50) in the granulite to a complex intergrowth of Na-rich and Ca-rich domains. EBSD analysis shows that this intergrowth retains the crystallographic orientation of the parent feldspar, but that the Ca-rich domains contain low-angle grain boundaries. Within the shear zone, this complex intergrowth coarsens by grain boundary migration, annihilating these grain boundaries but retaining the Na-rich and Ca-rich zoning pattern. Analysis of nearest-neighbour misorientations of feldspar grains in the shear zone demonstrates that local crystallographic preferred orientation (CPO) is inherited from the parent granulite grain orientations. Random pair misorientation angle distributions show that there is no CPO in the shear zone as a whole, nor is there significant shape preferred orientation (SPO) in single grains. These observations are interpreted in terms of fluid-induced weakening and deformation by dissolution- precipitation (pressure solution) creep.

Description: Kelp forests represent a major habitat type in coastal waters worldwide and their structure and distribution is predicted to change due to global warming. Despite their ecological and economical importance, there is still a lack of reliable spatial information on their abundance and distribution. In recent years, various hydroacoustic mapping techniques for sublittoral environments evolved. However, in turbid coastal waters, such as off the island of Helgoland (Germany, North Sea), the kelp vegetation is present in shallow water depths normally excluded from hydroacoustic surveys. In this study, single beam survey data consisting of the two seafloor parameters roughness and hardness were obtained with RoxAnn from water depth between 2 and 18 m. Our primary aim was to reliably detect the kelp forest habitat with different densities and distinguish it from other vegetated zones. Five habitat classes were identified using underwater-video and were applied for classification of acoustic signatures. Subsequently, spatial prediction maps were produced via two classification approaches: Linear discriminant analysis (LDA) and manual classification routine (MC). LDA was able to distinguish dense kelp forest from other habitats (i.e. mixed seaweed vegetation, sand, and barren bedrock), but no variances in kelp density. In contrast, MC also provided information on medium dense kelp distribution which is characterized by intermediate roughness and hardness values evoked by reduced kelp abundances. The prediction maps reach accordance levels of 62% (LDA) and 68% (MC). The presence of vegetation (kelp and mixed seaweed vegetation) was determined with higher prediction abilities of 75% (LDA) and 76% (MC). Since the different habitat classes reveal acoustic signatures that strongly overlap, the manual classification method was more appropriate for separating different kelp forest densities and low-lying vegetation. It became evident that the occurrence of kelp in this area is not simply linked to water depth. Moreover, this study shows that the two seafloor parameters collected with RoxAnn are suitable indicators for the discrimination of different densely vegetated seafloor habitats in shallow environments.

Description: Eutrophication, coupled with loss of herbivory due to habitat degradation and overharvesting, has increased the frequency and severity of macroalgal blooms worldwide. Macroalgal blooms interfere with human activities in coastal areas, and sometimes necessitate costly algal removal programmes. They also have many detrimental effects on marine and estuarine ecosystems, including induction of hypoxia, release of toxic hydrogen sulphide into the sediments and atmosphere, and the loss of ecologically and economically important species. However, macroalgal blooms can also increase habitat complexity, provide organisms with food and shelter, and reduce other problems associated with eutrophication. These contrasting effects make their overall ecological impacts unclear. We conducted a systematic review and meta-analysis to estimate the overall effects of macroalgal blooms on several key measures of ecosystem structure and functioning in marine ecosystems. We also evaluated some of the ecological and methodological factors that might explain the highly variable effects observed in different studies. Averaged across all studies, macroalgal blooms had negative effects on the abundance and species richness of marine organisms, but blooms by different algal taxa had different consequences, ranging from strong negative to strong positive effects. Blooms' effects on species richness also depended on the habitat where they occurred, with the strongest negative effects seen in sandy or muddy subtidal habitats and in the rocky intertidal. Invertebrate communities also appeared to be particularly sensitive to blooms, suffering reductions in their abundance, species richness, and diversity. The total net primary productivity, gross primary productivity, and respiration of benthic ecosystems were higher during macroalgal blooms, but blooms had negative effects on the productivity and respiration of other organisms. These results suggest that, in addition to their direct social and economic costs, macroalgal blooms have ecological effects that may alter their capacity to deliver important ecosystem services.

Description: The convergence between the Indian plate and the southern margin of the Eurasian continent created an active continental margin from Late Jurassic until about 40 Ma ago, which then evolved to form the Himalaya and the Tibetan Plateau during the continental collision stage. Post-collisional magmatism in southern Tibet, north of the Yarlung Zangbo Suture Zone (YZSZ) has been active since 45 Ma and is related to normal faulting and extensional tectonism. To date no such magmatism was reported within the YZSZ itself. This paper reports on the discovery of Miocene shoshonites within the YZSZ. They are significant because the magma traveled, at least in part, through oceanic crust, thus limiting interaction with the continental crust to the mid-crustal level and which affected the post-collisional magmatic rocks occurring in the northern part of the subduction system. In addition, xenoliths and xenocrysts of crustal origin in these rocks constrain the nature of metamorphic rocks underlying the YZSZ at mid-crustal level. The geochemical signatures of the shoshonitic rocks, including Nd and Sr isotope systematics, indicate derivation from a garnet-bearing middle continental crustal source. Crustal imprint complicates modeling of the petrogenetic processes which occurred prior to mid-crustal ponding of the magma which took place between 11 and 17 Ma at depths of 40 to 50 km. The significant role of crustal contamination raises serious concerns about models proposed for similar magmatic activity elsewhere in the Himalaya and the Tibetan Plateau.

Description: A Monte Carlo numerical simulation for computing the received power for an underwater optical communication system is discussed and validated. Power loss between receiver and transmitter is simulated for a variety of receiver aperture sizes and fields of view. Additionally, pointing-and-tracking losses are simulated.

Description: Arc magmas are commonly assumed to form by melting of sub-arc mantle that has been variably enriched by a component from the subducted slab. Although most magmas that reach the surface are not primitive, the impact of assimilation of the arc crust is often ignored with the consequence that trace element and isotopic compositions are commonly attributed only to varying contributions from different components present in the mantle. This jeopardises the integrity of mass balance recycling calculations. Here we use Sr and O isotope data in minerals from a suite of volcanic rocks from St Lucia, Lesser Antilles arc, to show that assimilation of oceanic arc basement can be significant. Analysis of 87Sr/86Sr in single plagioclase phenocrysts from four Soufrière Volcanic Complex (SVC; St Lucia) hand samples with similar composition (87Sr/86Sr = 0.7089–0.7091) reveals crystal isotopic heterogeneity among hand samples ranging from 0.7083 to 0.7094 with up to 0.0008 difference within a single hand sample. measurements in the SVC crystals show extreme variation beyond the mantle range with +7.5 to ‰ for plagioclase (), +10.6 to ‰ for quartz (), +9.4 to ‰ for amphibole () and +9 to ‰ for pyroxene () while older lavas (Pre-Soufriere Volcanic Complex), with less radiogenic whole rock Sr composition (87Sr/86Sr = 0.7041–0.7062) display values closer to mantle range: +6.4 to ‰ for plagioclase () and +6 to ‰ for pyroxene (). We argue that the 87Sr/86Sr isotope disequilibrium and extreme values provide compelling evidence for assimilation of material located within the arc crust. Positive correlations between mineral and whole rock 87Sr/86Sr, 143Nd/144Nd and 206,207,208Pb/204Pb shows that assimilation seems to be responsible not only for the isotopic heterogeneity observed in St Lucia but also in the whole Lesser Antilles since St Lucia encompasses almost the whole-arc range of isotopic compositions. This highlights the need for detailed mineral-scale investigation of oceanic arc suites to quantify assimilation that could otherwise lead to misinterpretation of source composition and subduction processes.

Description: April 28 – May 22, 2013 Pointe-a-Pitre (Guadeloupe) – Mindelo (Cape Verde)

Description: Three new compounds, trichoderiol C (1), citrinoviric acid (4), and penicillenol D (5), together with seven known compounds, trichoderiol A (2), lignoren (3), penicillenol B1 (6), penicillenol B2 (7), cyclo-(Leu-Pro) (8), cyclo-(Ile-Pro) (9), and cyclo-(Phe-Pro) (10), were isolated from the marine-derived fungus Trichoderma citrinoviride. The structures of these compounds were elucidated using spectroscopic methods, including 1D and 2D nuclear magnetic resonance and high-resolution mass spectrometric analyses. Among these compounds, 4 and 5 showed moderate cytotoxic effects on the A-375 cell line, with IC50 values of 85.7 and 32.6 μM, respectively.

Description: Two discontinuous tephra layers were discovered at Burney Spring Mountain, northern California. Stratigraphic relationships suggest that they are two distinct primary fall tephras. The geochemistries of these tephras from electron probe microanalysis were compared with those of known layers found in the area to test for potential correlations, using clustering analysis on geochemistry. In most cases, geochemical data from a tephra layer can be assigned to a single cluster, but in some cases the analyses are spread over several clusters. This spreading is a direct result of mixing and reworking of several tephra layers. The mixing, in turn, appears to be related to the influence of wind in a marshy environment.

Description: May 25 – June 28, 2013 Mindelo (Cape Verde) – Fortaleza (Brazil)

Description: July 01 – July 28, 2013 Fortaleza (Brazil) – Walvis Bay (Namibia)

Description: The synthetic production of monodisperse single magnetic domain nanoparticles at ambient temperature is challenging. In nature, magnetosomes--membrane-bound magnetic nanocrystals with unprecedented magnetic properties--can be biomineralized by magnetotactic bacteria. However, these microbes are difficult to handle. Expression of the underlying biosynthetic pathway from these fastidious microorganisms within other organisms could therefore greatly expand their nanotechnological and biomedical applications. So far, this has been hindered by the structural and genetic complexity of the magnetosome organelle and insufficient knowledge of the biosynthetic functions involved. Here, we show that the ability to biomineralize highly ordered magnetic nanostructures can be transferred to a foreign recipient. Expression of a minimal set of genes from the magnetotactic bacterium Magnetospirillum gryphiswaldense resulted in magnetosome biosynthesis within the photosynthetic model organism Rhodospirillum rubrum. Our findings will enable the sustainable production of tailored magnetic nanostructures in biotechnologically relevant hosts and represent a step towards the endogenous magnetization of various organisms by synthetic biology.

Description: Marine phytoplankton blooms are annual spring events that sustain active and diverse bloom-associated bacterial populations. Blooms vary considerably in terms of eukaryotic species composition and environmental conditions, but a limited number of heterotrophic bacterial lineages — primarily members of the Flavobacteriia, Alphaproteobacteria and Gammaproteobacteria — dominate these communities. In this Review, we discuss the central role that these bacteria have in transforming phytoplankton-derived organic matter and thus in biogeochemical nutrient cycling. On the basis of selected field and laboratory-based studies of flavobacteria and roseobacters, distinct metabolic strategies are emerging for these archetypal phytoplankton-associated taxa, which provide insights into the underlying mechanisms that dictate their behaviours during blooms.

Description: Stock‐based and ecosystem‐based indicators are used to provide a new diagnosis of the fishing impact and environmental status of European seas. In the seven European marine ecosystems covering the Baltic and the North‐east Atlantic, (i) trends in landings since 1950 were examined; (ii) syntheses of the status and trends in fish stocks were consolidated at the ecosystem level; and (iii) trends in ecosystem indicators based on landings and surveys were analysed. We show that yields began to decrease everywhere (except in the Baltic) from the mid‐1970s, as a result of the over‐exploitation of some major stocks. Fishermen adapted by increasing fishing effort and exploiting a wider part of the ecosystems. This was insufficient to compensate for the decrease in abundance of many stocks, and total landings have halved over the last 30 years. The highest fishing impact took place in the late 1990s, with a clear decrease in stock‐based and ecosystem indicators. In particular, trophic‐based indicators exhibited a continuous decreasing trend in almost all ecosystems. Over the past decade, a decrease in fishing pressure has been observed, the mean fishing mortality rate of assessed stocks being almost halved in all the considered ecosystems, but no clear recovery in the biomass and ecosystem indicators is yet apparent. In addition, the mean recruitment index was shown to decrease by around 50% in all ecosystems (except the Baltic). We conclude that building this kind of diagnosis is a key step on the path to implementing an ecosystem approach to fisheries management.

Description: Submarine landslides on open continental slopes can be far larger than any slope failure on land and occur in locations worldwide on gradients of 〈2°. Significantly elevated pore pressure is necessary to overcome the sediment’s shearing resistance on such remarkably low gradients, but the processes causing such overpressure generation are contentious, especially in areas with slow sedimentation rates. Here we propose that the progressive loss of interparticle bonding and fabric could cause such high excess pore pressure. Slow sedimentation may favour the formation of a structural framework in the sediment that is load-bearing until yield stress is reached. The bonds then break down, causing an abrupt porosity decrease and consequently overpressure as pore fluid cannot escape sufficiently rapidly. To test this hypothesis, we implement such a loss of structure into a 2D fully coupled stress-fluid flow Finite Element model of a submerged low angle slope, and simulate consolidation due to slow sedimentation. The results suggest that destructuring could indeed be a critical process for submarine slope stability.

Description: There are more than 100 oil and gas fields in Iraq, containing more than 137 billion barrels of recoverable oil and more than 106 TCF of recoverable gas. Of this large resource, about 25 billion barrels of oil and 11 TCF of gas have been produced to date. Nearly all of the oil and gas occurs in fields located within the Mesopotamian foredeep, Gotnia Basin, and Zagros foldbelt. Minor discoveries and shows have been found on the Arabian platform along the western flank of the Mesopotamian foredeep. There is one gas discovery (Akkas field) on the Arabian platform in western Iraq.Ninety-eight percent of the oil and gas occurs in reservoirs of Cenozoic and Cretaceous age. The largest reserves occur in: 1) carbonate rocks of the Kirkuk Group (Lower Miocene–Oligocene), in fields within the Zagros foldbelt of northeastern Iraq, the largest being Kirkuk field; 2) carbonate rocks of the Mishrif Formation (Turonian–Cenomanian), in fields within the Mesopotamian fore-deep and Zagros foldbelt in southern and central Iraq, including Rumaila, West Qurna, Majnoon, Halfayah, Zubair, and Buzurgan fields; and 3) siliciclastic rocks of the Zubair Formation (Albian– Barremian), in fields within the Mesopotamian foredeep and Zagros foldbelt in southern and central Iraq, including East Baghdad, Rumaila, West Qurna, and Zubair fields. Large reserves also occur in carbonate rocks of the Upper Cretaceous above the Mishrif Formation and in the Lower Cretaceous below the Zubair Formation. Smaller reserves occur in other Neogene and Paleogene carbonates and siliciclastics, in Jurassic and Triassic carbonates, and in Ordovician siliciclastics.Most of the oil and gas that have been discovered were generated from organic-rich, oil-prone carbonates of the Jurassic Sargelu and Naokelekan Formations. These source rocks are widely distributed and mature for oil and gas generation across the Mesopotamian foredeep and Zagros foldbelt. Lesser amounts of oil and gas are derived from: 1) Upper and Lower Cretaceous oil-prone source rocks within the Zagros foldbelt; 2) Triassic oil-prone source rocks in northwestern Iraq; and 3) Silurian gas-prone source rocks in western Iraq. The oil generated from the Jurassic source rocks migrated vertically to fill stacked reservoir intervals in many fields. Lateral migration of oil occurred along the western margin of the Mesopotamian foredeep, as proven by small fields and large seeps that are located where source rocks are absent or immature for oil or gas generation. The tectonics and sedimentation during the Phanerozoic created the source-rich setting of Iraq. Sedimentation was widespread across Iraq during most of the Paleozoic, although intervals of strata are absent and interpreted either not to have been deposited or to have been eroded following deposition. A notable example is the absence of Early and Middle Devonian strata from Iraq. The distribution of Pre-Permian strata, including the gas-prone Silurian source rocks, and therefore the Paleozoic hydrocarbon system and plays, was controlled in large part by erosion at the unconformity that separates Late and Early Carboniferous. Following siliciclastic infill of the topography at this unconformity, Iraq was covered by platform-wide deposition of carbonate sediments on an east-dipping ramp in the Permian, Triassic, and Early Jurassic. Continental fragments rifted from the northern and eastern margins of Arabia during these times, after which a large portion of eastern Iraq subsided. This intra-shelf basin, named the Gotnia Basin, was the location of organic-rich “starved” sedimentation in the Middle to Late Jurassic that formed the important Sargelu and Naokelekan source rocks. The Gotnia Basin was rimmed by carbonate shelf margins.The Gotnia Basin filled with anhydrite and salt layers in the latest Jurassic and then continued to fill throughout the Cretaceous, primarily by prograding carbonate and siliciclastic sediments that entered the basin along the southern, western, and northern margins. These progradational deposits contain the major reservoir units of Iraq, whereas the basinal sediments include most of the sealing facies, predominantly marine shales, as well as some locally important source rocks. The basinal area continued to contract by sedimentary infill until the Turonian, when the Arabian plate was disturbed by a compressional event related to the initial closing of the Tethys Ocean. This event is marked by a hiatus in deposition and, at least locally, erosion at an unconformity. Faults were inverted and folding of anticlines in the Mesopotamian foredeep (and probably in the Zagros foldbelt) occurred at this event.Marine waters flooded across this unconformity in the Late Turonian and Coniacian, with renewed carbonate deposition. Ophiolites were obducted onto Arabia in the middle part of the Late Cretaceous and are present in far northeastern Iraq. At the same time, thick calcareous and muddy sediments filled rapidly subsiding extensional grabens present in western Iraq. A subsiding trough formed in the position of the existing Mesopotamian foredeep and Zagros foldbelt of Iraq, and siliciclastic sediments started to fill the deep-water trough from the north and northeast due to the encroaching Tethys closure. Basinal carbonate and shale were deposited in the center of the trough in the Paleocene and Eocene, while the basin was partly filled by prograding carbonate shelf margins located on the southwestern and north-eastern sides of the basin. This continued through the Oligocene and Early Miocene, until the remaining basins were filled with anhydrite of the Dhiban Formation and the overlying carbonates of the Jeribe Formation in the Early Miocene. Deposition throughout the Late Cretaceous and Cenozoic provided the burial for the Mesozoic source rocks to generate oil and gas. Closure of the Tethys Ocean continued, with local uplift and erosion of areas of Iraq in the Early Miocene. Thick evaporitic deposits of the Fatha Formation lap onto and over the older Cenozoic strata. The marine seaway along the Mesopotamian foredeep was closed by the Middle Miocene, with ensuing non-marine siliciclastic deposition and folding associated with west-verging shortening deformation in the Zagros foldbelt. Oil and gas plays are proven and their distribution is well known for the Cenozoic and most of the Cretaceous. The deeper plays of the Lower Cretaceous, Jurassic, and older reservoirs are less well explored in the Mesopotamian foredeep, Gotnia Basin, and Kirkuk embayment of the Zagros foldbelt. Exploration is occurring in the marginally drilled interior of the Kurdistan region of the Zagros foldbelt in northeastern Iraq. Paleozoic plays in western Iraq are also marginally explored.