ALBERT

Note: Zugl.: Karlsruhe, Univ. Fridericiana, Diss, 2009

Note: San Diego, Univ. of California, Diss., 1992

Note: Zugl.: Diss.

Note: Table of Contents: Copyright; Additional copies. - Foreword and acknowledgements. - Chapter 1. Cosmochemistry of the Rare Earth Elements: Condensation and Evaporation Processes / by William V. Boynton. - Introduction. - Meteorites. - Astrophysical context for interpretation of cosmochemical data. - Solar nebula. - Solar abundances. - Cosmochemical properties of the REE. - REE condensation reactions. - Activity coefficients. - Partial pressures. - Solid / gas distribution coefficients. - Why are the REE volatilities so different?. - Calculated REE patterns. - Early condensates. - Removing REE in the gas. - Comparison with meteoritic data. - Ultra-refractory component. - Group II inclusions. - FUN inclusions. - REE condensation as a function of oxygen fugacity. - Rims on CAI. - What have we learned from the REE?. - High temperatures were achieved in the solar nebula. - A very efficient mechanism for gas/dust separation existed in the solar nebula. - The high nebular temperatures existed for a long time. - A very intense, very brief, heat source also existed. - The solar nebula was a chaotic environment. - Summary. - Acknowledgements. - References. - Chapter 2. Radiogenic Isotope Geochemistry of Rare Earth Elements / by P. Jonathan Patchett. - Introduction. - Long-lived radioactive isotopes of Rare Earth Elements. - 138La-138Ce decay. - 147Sm-143Nd decay. - 176Lu-176Hf decay. - Cemical variations of La/Ce, Sm/Nd and Lu/Hf ratios. - Geochronological studies. - La-Ce and Lu-Hf chronology. - Sm-Nd chronology. - Defining bulk planetary isotopic evolution. - Isotopic study of planetary interiors. - The Moon. - The Earth. - Nd isotopes in studies of terrestrial crustal evolution. - Model Nd ages of continental crust. - Growth curves for the continental crust. - Origin of granitoids. - Nd isotopes and the sedimentary system. - Characterization of whole crustal terranes. - Crustal Lu-Hf isotopic studies. - Major unsolved problems. - Continental crustal growth curve. - Abundance of Archean continental crust. - Origin of mantle isotopic variations. - References. - Chapter 3. Partitioning of Rare Earth Elements between Major Silicate Minerals and Basaltic Melts / by Gordon A. McKay. - Introduction. - Usefulness of the REE for petrogenetic modelling. - Scope of this chapter. - Caveat. - How partition coefficients are measured. - Phenocryst/matrix studies of natural samples. - Experimental measurement of partition coefficients. - Basic experimental approach. - Equilibrium. - Percent level doping technique. - Beta-track mapping technique. - Other experimental approaches. - Henry's law: The applicability of percent-level doping results. - Factors governing mineral/melt partitioning. - Ionic size and charge of trace element. - Crystal field effects. - Cristallographic versus defect sites: The Henry's law question. - Phase compositions. - Oxidation state. - Thermodynamic relationships: Dependence of partitioning on temperature and composition. - Other predictive approaches. - Special applications. - Eu as an oxygen fugacity indicator. - Origin of the Eu anomaly in lunar mare basalts. - REE partition coefficient patterns for the major minerals. - Plagioclase. - Olivine. - Pyroxene. - Low-Ca pyroxene. - High-Ca pyroxene. - Garnet. - Future directions. - Acknowledgements. - References. - Chapter 4. An Approach to Trace Element Modeling Using a Simple Igneous System as an Example / by Gilbert N. Hanson. - Introduction. - Review of trace element equations. - Melting. - Fractional crystallization. - Melting versus fractional crystallization. - Essential structural constituents. - Example of petrogenetic approach. - Discussion and summary. - Acknowledgements. - References. - Chapter 5. Rare Earth Elements in Upper Mantle Rocks / by W. F. McDonough and Fredrick A. Frey. - Introduction. - Massive peridotites. - Massive peridotites: dominantly lherzolite Western Alps - Lanzo. - Western Alps -Baldissero, Balmuccia. - Eastern Liguria, Italy. - Western Liguria, Italy. - Eastern Pyrenees - France. - Ronda, Spain Effects of late stage alteration on REE. - What can be inferred about the melting process and the segregated melts?. - Massive peridotites: pyroxenite layers and veins and their wall rocks. - Amphibole-bearing pyroxenite veins. - Anhydrous pyroxenite layers. - How were the pyroxenite layers created? Evidence for multistage processes. - Implications for mantle enrichment processes (metasomatism). - Massive peridotites: dominantly harzburgite. - Oceanic peridotites. - Ultramafic xenoliths. - Group I spinel peridotites. - Garnet peridotites. - Pyroxenite and related xenoliths. - Models for REE abundance trends in peridotite xenoliths. - Megacrysts, minerals in xenoliths and damong inclusions. - Megacrysts. - Minerals in peridotites and pyroxenites. - Inclusions in diamonds. - Summary: comparison of peridotites from massifs and xenoliths and implications of REE data for Upper Mantle composition. - Acknowledgements. - References. - Chapter 6. Rare Earth Elements in Metamorphic Rocks / by Richard I. Grauch. - Introduction. - REE residence in metamorphic rocks. - REE mobility during metamorphism. - REE content of metamorphic rocks. - Suggestions for future work. - Acknowledgements. - References. - Chapter 7. Rare Earth Elements in Sedimentary Rocks: Influence of Provenance and Sedimentary Processes / by Scott M. McLennan. - Introduction. - Rare earth element properties and sedimentary rocks. - Cosmochemical considerations. - Geochemical considerations. - Aqueous geochemistry. - Normalizing and notation. - Sedimentary processes. - Weathering. - Diagenesis. - Sedimentary sorting. - REE and provenance studies. - Sedimentary rocks and crustal abundances. - Sedimentation and plate tectonics. - Archean sedimentary rocks and the Archean crust. - Archean greenstone belts. - REE in sedimentary rocks and crustal evolution. - Acknowledgements. - References. - Chapter 8. Aqueous Geochemistry of Rare Earth Elements / by Douglas G. Brookins. - Introduction. - The trivalent lanthanides (Ln III). - Types of complexes in solution. - Hydrolysis products. - Phosphate complexes. - Carbonate complexes. - Halide complexes. - Complexes with total dissolved sulfur. - Gadolinium-Terbium fractionation?. - Scandium and Yttrium. - Europium (II). - Cerium (IV). - Eh-pH diagrams. - Cerium. - Europium. - Other lanthanides. - Lanthanides in ocean waters. - Lanthanides and actinides. - Concluding remarks. - Acknowledgements. - References. - Chapter 9. Rare Earth Elements in Lunar Materials / by Larry A. Haskin. - Introduction. - The nature of planet moon. - The magma ocean hypothesis and its presumed products. - Lunar REE patterns. - Highland plutonic rocks. - Anorthosites. - Durâtes, troctolites, norites, and gabbros. - Lunar felsite (granite). - Highland volcanic rocks: KREEP. - Mare basalts. - Mare basalt sources as magma ocean products. - Assimilation of crusted material during basalt petrogenesis. - Glassy spherules. - Soils and breccias. - Caveat. - Acknowledgements. - References. - Chapter 10. Compositional and Phase Relations among Rare Earth Element Minerals / by Donald M. Burt. - Introduction. - Geochemical background. - Minerals. - Coupled substitutions. - Vector treatment. - Application to selected mineral groups. - Fluorides. - Carbonates. - Fluorocarbonates. - Monazite, xenotime, zircon, and related phases. - Apatites. - Florencite and related phases. - A-B oxides (niobates, tantalates, titanates, ferrites). - Fergusonitelbetafergusonite, ABO4. - Perovskite, ABO3. - Aeschyniteleuxenite, AB2O6. - Pyrochlore, A1-2B2O6(O,F,OH). - Allanite. - Titanite. - Garnet. - Gadolinite. - Chevkinite/perrierite. - Element distributions: acid-base relations. - Summary. - Acknowledgemen

Note: Table of Contents: 1 The Solid Phase of Marine Sediments / DIETER K. FÜTTERER 1.1 Introduction 1.2 Sources and Components of Marine Sediments 1.2.1 Lithogenous Sediments 1.2.2 Biogenous Sediments 1.2.3 Hydrogenous Sediments 1.3 Classification of Marine Sediments 1.3.1 Terrigenous Sediments 1.3.2 Deep-Sea Sediments 1.4 Global Patterns of Sediment Distribution 1.4.1 Distribution Patterns of Shelf Sediments 1.4.2 Distribution Patterns of Deep-Sea Sediments 1.4.3 Distribution Patterns of Glay Minerals 1.4.4 Sedimentation Rates 2 Geophysical Perspectives in Marine Sediments 2.1 Physical Properties of Marine Sediments / MONIKA BREITZKE 2.1.1 Introduction 2.1.2 Porosity and Wet Bulk Density 2.1.2.1 Analysis by Weight and Volume 2.1.2.2 Gamma Ray Attenuation 2.1.2.3 Electrical Resistivity (Galvanic Method) 2.1.2.4 Electrical Resistivity (Inductive Method) 2.1.3 Permeability 2.1.4 Acoustic and Elastic Properties 2.1.4.1 Biot-Stoll Model 2.1.4.2 Full Waveform Ultrasonic Gore Logging 2.1.5 Sediment Classification 2.1.5.1 Full Waveform Gore Logs as Acoustic Images 2.1.5.2 P-and S-Wave Velocity, Attenuation, Elastic Moduli and Permeability 2.1.6 Sediment Echosounding 2.1.6.1 Synthetic Seismograms 2.1.6.2 Narrow-Beam Parasound Echosounder Recordings 2.2 Sedimentary Magnetism / ULRICH BLEIL 2.2.1 Introduction 2.2.2 Biogenie Magnetic Minerals in Marine Sediments 2.2.3 Reduction Diagenesis of Magnetic Minerals in Marine Environments 3 Quantification of Early Diagenesis: Dissolved Constituents in Marine Pore Water / HORST D. SCHULZ 3.1 Introduction: How to Read Pore Water Concentration Profiles 3.2 Calculation of Diffusive Fluxes and Diagenetic Reaction Rates 3.2.1 Steady State and Non-Steady State Situations 3.2.2 The Steady State Situation and Fick's First Law of Diffusion 3.2.3 Quantitative Evaluation of Steady State Concentration Profiles 3.2.4 The Non-Steady State Situation and Fick's Second Law of Diffusion 3.2.5 The Primary Redox-Reactions: Degradation of Organic Matter 3.3 Sampling of Pore Water for Ex-Situ Measurements 3.3.1 Obtaining Sampies of Sediment for the Analysis of Pore Water 3.3.2 Pore Water Extraction from the Sediment 3.3.3 Storage, Transport and Preservation of Pore Water 3.4 Analyzing Constituents in Pore Water, Typical Profiles 3.5 In-Situ Measurements 3.6 Influence of Bioturbation, Bioirrigation, and Advection 4 Organic Matter: The Driving Force for Early Diagenesis / JÜRGEN RULLKÖTTER 4.1 The Organic Carbon Cycle 4.2 Organic Matter Accumulation in Sediments 4.2.1 Productivity Versus Preservation 4.2.2 Primary Production of Organic Matter and Export to the Ocean Bottom 4.2.3 Transport of Organic Matter through the Water Column 4.2.4 The Influence of Sedimentation Rate on Organic Matter Burial 4.2.5 Allochthonous Organic Matter in Marine Sediments 4.3 Early Diagenesis 4.3.1 The Organic Carbon Content of Marine Sediments 4.3.2 Chemical Composition of Biomass 4.3.3 The Principle of Selective Preservation 4.3.4 The Formation of Fossil Organic Matter and its Bulk Composition 4.3.5 Early Diagenesis at the Molecular Level 4.3.6 Biological Markers (Molecular Fossils) 4.4 Organic Geochemical Proxies 4.4.1 Total Organic Carbon and Sulfur 4.4.2 Marine Versus Terrigenous Organic Matter 4.4.3 Molecular Paleo-Seawater Temperature and Climate Indicators 4.5 Analytical Techniques 4.5.1 Sam pie Requirements 4.5.2 Elemental and Bulk Isotope Analysis 4.5.3 Rock-Eval Pyrolysis and Pyrolysis Gas Chromatography 4.5.4 Organic Petrography 4.5.5 Bitumen Analysis 4.6 The Future of Marine Geochemistry of Organic Matter 5 Bacteria and Marine Biogeochemistry / Bo BARKER JORGENSEN 5.1 Role of Microorganisms 5.1.1 From Geochemistry to Microbiology - and back 5.1.2 Approaches in Marine Biogeochemistry 5.2 Life and Environments at Small Scale 5.2.1 Hydrodynamics of Low Reynolds Numbers 5.2.2 Diffusion at Small Scale 5.2.3 Diffusive Boundary Layers 5.3 Regulation and Limits of Microbial Processes 5.3.1 Substrate Uptake by Microorganisms 5.3.2 Temperature as a Regulating Factor 5.3.3 Other Regulating Factors 5.4 Energy Metabolism of Prokaryotes 5.4.1 Free Energy 5.4.2 Reduction-Oxidation Processes 5.4.3 Relations to Oxygen 5.4.4 Definitions of Energy Metabolism 5.4.5 Energy Metabolism of Microorganisms 5.4.6 Chemolithotrophs 5.4.7 Respiration and Fermentation 5.5 Pathways of Organic Matter Degradation 5.5.1 Depolymerization of Macromolecules 5.5.2 Aerobic and Anaerobic Mineralization 5.5.3 Depth Zonation of Oxidants 5.6 Methods in Biogeochemistry 5.6.1 Incubation Experiments 5.6.2 Radioactive Tracers 5.6.3 Example: Sulfate Reduction 5.6.4 Specific Inhibitors 5.6.5 Other Methods 6 Early Diagenesis at the Benthic Boundary Layer: Oxygen and Nitrate in Marine Sediments / CHRISTIAN HENSEN AND MATTHIAS ZABEL 6.1 Introduction 6.2 Oxygen and Nitrate Distribution in Seawater 6.3 The Role of Oxygen and Nitrate in Marine Sediments 6.3.1 Respiration and Redox Processes 6.3.1.1 Nitrification and Denitrification 6.3.1.2 Coupling of Oxygen and Nitrate to other Redox Pathways 6.3.2 Determination of Consumption Rates and Senthic Fluxes 6.3.2.1 Fluxes and Concentration Profiles Determined by In-Situ Devices 6.3.2.2 Ex-Situ Pore Water Data from Deep-Sea Sediments 6.3.2.3 Determination of Denitrification Rates 6.3.3 Oxic Respiration, Nitrification and Denitrification in Different Marine Environments 6.3.3.1 Quantification of Rates and Fluxes 6.3.3.2 Variation in Different Marine Environments: Case Studies 6.4 Summary 7 The Reactivity of Iron / RALF R. HAESE 7.1 Introduction 7.2 Pathways of Iron Input to Marine Sediments 7.2.1 Fluvial Input 7.2.2 Aeolian Input 7.3 Iron as a Limiting Nutrient for Primary Productivity 7.4 The Early Diagenesis of Iron in Sediments 7.4.1 Dissimilatary Iran Reductian 7.4.2 Solid Phase Ferric Iron and its Bioavailability 7.4.2.1 Properties of Iron Oxides 7.4.2.2 Bioavailability of Iron Oxides 7.4.2.3 Bioavailability of Sheet Silicate Sound Ferric lron 7.4.3 Iron and Manganese Redax Cycles 7.4.4 Iron Reactivity towards S, O2, Mn, NO3, P, HCO3, and Si-AI 7.4.4.1 lron Reduction by HS and Ligands 7.4.4.2 Iron Oxidation by O2, NO3, and Mn4+ 7.4.4.3 Iron-Sound Phosphorus 7.4.4.4 The Formation of Siderite 7.4.4.5 The Formation of lron Searing Aluminosilicates 7.4.5 Discussion: The Importance of Fe-and Mn-Reactivity in Various Enyironments 7.5 The Assay for Ferric and Ferrous Iron 8 Sulfate Reduction in Marine Sediments / SABINE KASTEN AND BO BARKER JØRGENSEN 8.1 Introduction 8.2 Sulfate Reduction and the Degradation of Organic Matter 8.3 Biotic and Abiotic Processes Coupled to Sulfate Reduction 8.3.1 Pyrite Formation 8.3.2 Effects of Sulfate Reduction on Sedimentary Solid Phases 8.4 Determination of Sulfate Reduction Rates 9 Marine Carbonates: Their Formation and Destruction / RALPH R. SCHNEIDER, HORST D. SCHULZ AND CHRISTIAN HENSEN 9.1 Introduction 9.2 Marine Environments of Carbonate Production and Accumulation 9.2.1 Shallow-Water Carbonates 9.2.2 Pelagic Calcareous Sediments 9.3 The Calcite-Carbonate-Equilibrium in Marine Aquatic Systems 9.3.1 Primary Reactions of the Calcite-Carbonate-Equilibrium with Atmospheric Contact in Infinitely Diluted Solutions 9.3.2 Primary Reactions of the Calcite-Carbonate-Equilibrium without Atmospheric Contact 9.3.3 Secondary Reactions of the Calcite-Carbonate-Equilibrium in Seawater 9.3.4 Examples for Calculation of the Calcite-Carbonate-Equilibrium in Ocean Waters 9.4 Carbonate Reservoir Sizes and Fluxes between Particulate and Dissolved Reservoirs 9.4.1 Production Versus Dissolution of Pelagic Carbonates 9.4.2 Inorganic and Organic Carbon Release trom Deep-Sea Sediments 10 Influences of Geochemical Processes on Stable Isotope Distribution in Marine Sediments / TORSTEN SICKERT 10.1 Introduction 10.2 Fundamentals 10.2.1 Principles of Isotopic Fractionation 10.2.2 Analytical Procedures 10.3 Geochemicallnfluences on 18O/16O Ratios 10.3.1 δ18O of Seawater 10.3.2 δ18O in Marine Carbonates 10.4 Geochemical Influences on 13C/12C Ratios 10.4.1

Note: Contents 1 Scope / G. Matthess 2 Polar Organic Substances and Their Role in the Water-Saturated and -Unsaturated Zones 2.0 Introduction / F.H. Frimmel 2.1 Isolation Procedures and Characterization Methods 2.1.1 Isolation and General Characterization of Organic Acids from Pore Water / F.H. Frimmel 2.1.2 Isolation and Characterization of Soil Humic Matter / W. Finger, B. Post and H. Klamberg 2.1.3 Isolation and Characterization of Organic Substancesin Ground Water and Sediments / F. Selenka and A. Hack 2.1.4 Chromatographie Characterization of the Acid-Soluble Part of Humic Substances / F.H. Frimmel 2.1.5 Spectroscopic Characterization of Humic Substances in the Ultraviolet and Visible Region and by Infrared Spectroscopy / G. Abbt-Braun 2.1.6 Temperature-Programmed/Time-Resolved Pyrolysis Field lonization Mass Spectrometry - a New Method for the Characterization of Humic Substances / H.-R. Schulten 2.1.7 Interpretation of the Pyrolysis Products of Isolated Humic and Fulvic Acids / G. Abbt-Braun 2.1.8 Characterization of Isolated Humic Material by 13C Nuclear Magnetic Resonance Spectroscopy /J. Buddrus and P. Burba 2.1.9 Characterization of Humic Substances Extracted by Organic Solvents / B. Post and H. Klamberg 2.2 Interaction of Inorganics with Humic Substances 2.2.1 Investigation of Metal Complexation by Polarography and Fluorescence Spectroscopy / F.H. Frimmel 2.2.2 Determination of Complexation Equilibria by the Ion-Exchange Method / W. Finger and H. Klamberg 2.2.3 Sorption of Metals on Humic Material / R. Becker and H. Klamberg 2.2.4 Interactions of Humic Substances with Iodine / K. G. Heumann and C. Reifenhäuser 2.2.5 Experiments on the Influence of Organic Ligands upon Kinetics of Feldspar Weathering / A. Petersen, G. Matthess and D. Schenk 2.3 Characterization of Some Organic Acids in the Subsurface of the Sandhausen Ecosystem / T. Cordt and H. Kussmaul 2.3.4 Organic Acids 2.3.5 Conclusions 3 Carbonate Systems 3.0 Introduction / E. Usdowski 3.1 Dissolution Kinetics in the Generation of Carbonate Ground Waters 3.1.1 Theoretical and Experimental Results of the Kinetics of Calcite Dissolution and Precipitation / W. Dreybrodt 3.1.2 Field Measurements and Laboratory Experiments on Calcite Dissolution Kinetics of Natural Porous Media / J. Baumann and H.D. Schulz 3.2 Field Studies on Subsurface Water of Selected Sites / B. Merkel and J. Grossmann 3.2.1 Pore Water Sampling in Carbonate Terrains 3.2.2 Variation of Inorganic Carbon in the Unsaturated Zone of a Carbonate Gravel System / L. Eichinger and B. Merkel 3.2.3 Isotope Geochemistry of the Subsurface Carbonate System in Sandhausen and Bocholt / H. Dörr, W. Leuchs, P. Obermann, W. Regenberg and C. Sonntag 3.2.4 Application of Stable Carbon and Sulfur Isotope Models to the Development of Ground Water in a Limestone-Dolomite-Anhydrite-Gypsum Area / K.W. Schaefer and E. Usdowski 3.2.5 A dissolution Front at the Contact of Sandsto Marly Limestone Aquifers / H.R. Langguth and R. Schulz 3.2.6 Carbonate Rock Dissolution Under Intermediate System Conditions / J. Michaelis 3.3 Alteration in Karst Systems 3.3.1 Mineralogy and Hydrogeochemistry of the Gypsum Karst of Foum Tatahouine, South Tunisia / W. Smykatz-Kloss, H. Hötzl and H. Kössl 3.3.2 Dedolomitization and Salt Formationin a Semi-Arid Environment / W. Smykatz-Kloss, and J. Goebelbecker 3.3.3 Transformation Processes in Paleokarst Sediments and Chemistry of Modern Waters in the Aladag Region, Turkey / M. Cevrini and W. Echle 4 Silicate Systems 4.0 Introduction / G. Matthess 4.1 Redox Reactions in the Subsurface 4.1.1 Anoxic Reaction Zones in an Aquifer Influenced by Increasing Nitrate and Sulfate Contents / W. Leuchs and P. Obermann 4.1.2 Nitrogen and Oxygen Isotopes as Indicators for Nitrification and Denitrification / H.-L. Schmidt, S. Voerkelius and A. Amberger 4.1.3 Redox Conditions and Microbial Sulfur Reactions in the Fuhrberger Field Sandy Aquifer / J. Böttcher, O. Strebet and W. Kölle 4.1.4 Influence of Fine-Grained Cover Beds on the Chemistry of Shallow Ground Water / G. Ebhardt and P. Fritsch 4.1.5 Hydrogeochemical Processes During the Passage of Surface Water and Ground Water Through Genetically Different Organic Sediments / H. Brühl, A. Moschick and H. Verleger 4.1.6 Hydrochemical Phenomena in the Dorsten Leakage System / M. Hoffmann, H.R. Langguth and J. Larue 4.1.7 Hydrogeochemical Processes in the Hamburg Deep Aquifer System / E.P. Loehnert, W. Bauhus and C. Sonntag 4.2 Rock-Water Interaction 4.2.1 Aluminium Speciation in Acid Soil Water and Ground Water / G. Dietze and B. Ulrich 4.2.2 Mineral-Pore Water Interaction in Two Soil Types on Pleistocene Sediments at Hamburg / F. Sztuka and I. Valeton 4.2.3 Subsurface Hydrochemical Reactions in the Sandhausen Forest Ecosystem / H. Jacob, W. Regenberg and C. Sonntag 4.3 Reaction Kinetics 4.3.1 Experimental Methods for Determining Dissolution Rates of Silicates - a Comparison / D. Schenk, G. Matthess, A. Dahmke and A. Petersen 4.3.2 Field Studies on the Kinetics of Silicate Minerals/Water Interaction / G. Matthess, A. Petersen, D. Schenk and A. Dahmke 5 Microbiology 5.0 Introduction / P. Hirsch 5.1 Characterization of the Natural Subsurface Environment 5.1.1 Morphological and Taxonomic Diversity of Ground Water Microorganisms / P. Hirsch, E. Rades-Rohkohl, J. Kölbel-Boelke and A. Nehrkorn 5.1.2 Methods of Studying Ground Water Microbiology: Critical Evaluations and Method suggestions / P. Hirsch, E. Rades-Rohkohl, J. Kölbel-Boelke, A. Nehrkorn, R. Schweisfurth, F. Selenka and A. Hack 5.1.3 Organic Substances in Ground Water and Sediments and Their Relationships to Microorganisms in a Sandy Aquifer / E Selenka and A. Hack 5.2 Microbial Activities 5.2.1 Observations on the Physiology of Microorganisms from Pristine Ground Water Environments / P. Hirsch 5.2.2 Formation and Transformation of Manganese Oxidation States by Bacteria / J. Gottfreund and R. Schweisfurth 5.2.3 Interactions Between Humic Acids and Microorganisms / G.-J. Tuschewitzki, B. Langer and H. Otremba 5.3 Microbiology of Selected Locations 5.3.1 Subsurface Microbial Activities in the Sandhausen Forest Ecosystem / R. Weyandt and R. Schweisfurth 5.3.2 Heterotrophic Bacterial Communities in the Bocholt Aquifer System / J. Kölbel-Boelke and A. Nehrkorn 5.3.3 The Natural Microflora of the Segeberger Forest Aquifer System / P. Hirsch and E. Rades-Rohkohl 5.3.4 Microbiological Observations of the Unsaturated Zone of a Quaternary Gravel Profile / I. Alexander, G. Freitag, J. Grossmann, Β. Merkel, P. Udluft and I. Ullsperger 6 Hydrogeochemical and Geochemical-Hydraulic Models and Model Concepts 6.0 Introduction / H.-D. Schulz 6.1 Hydrogeochemical Models and Concepts 6.1.1 Development of Secondary Permeability of a Fracture Aquifer in Carbonate Rocks: a Model / W. Dreybrodt 6.1.2 Some Aspects of Modelling the Carbon System in the Unsaturated Zone / B. Merkel, L. Eichinger and P. Udluft 6.1.3 Methodical Concepts in Silicate-Water Interaction - a Comparison of Results / A. Dahmke, G. Matthess, A. Petersen and D. Schenk 6.2 Combination of Transport and Geochemical Reactions 6.2.1 Water Movement and Geochemical Reactions in the Unsaturated Zone of Sands with Low Calcite Contents / H.-D. Schulz 6.2.2 Physical and Biochemical Processes Affecting Mass Transport in the Bocholt Aquifer System / C. Bugner and R. Mull 6.2.3 Tritium and 3He Measurements as Calibration Data for Ground Water Transport Models / H. Dörr, P. Schlosser, M. Stute and C. Sonntag 6.2.4 39Ar-, 85Kr-, 3He- and 3H Isotope Dating of Ground Water in the Bocholt and Segeberger Forst Aquifer Systems / M. Forster, H. Loosli and S. Weise 6.2.5 Modelling of Mass Balance and of Microbial Transformations in the Fuhrberger Feld Sandy Aquifer / O. Strebet, J. Böttcher and W.H.M. Duynisveld 6.3 Description of Geochemical Environments with Thermodynamic Equilibrium Models / M. Rolling and H.-D. Schulz 6

Note: Table of Contents: Preface. - Acknowledgments. - SAMUEL EPSTEIN: Scientist, Teacher and Friend. - PART A. EXPERIMENTAL AND THEORETICAL ISOTOPIC FRACTIONATION STUDIES. - Oxygen isotopic thermometer calibrations / Robert N. Clayton and Susan W. Kieffer. - Temperature dependence of isotopic fractionation factors / Robert E. Criss. - Oxygen isotope fractionation studies of solute-water interactions / James R. O'Neil and Alfred H. Truesdell. - Oxygen diffusion in leucite: Structural controls / Karlis Muehlenbachs and Cathy Connolly. - An experimental study of oxygen isotope partitioning between silica glass and CO2 vapor / Edward Stolper and Samuel Epstein. - D/H analysis of minerals by ion probe / E. Deloule, C. France-Lanord and F. Albarède. - PART B. THE HYDROSPHERE AND ANCIENT OCEANS. - Oxygen isotope history of seawater revisited: Timescales for boundary event changes in the oxygen isotope composition of sea water / R. T. Gregory. - Oxygen and hydrogen isotope compositions of oceanic plutonic rocks: High-temperature deformation and metamorphism of oceanic layer 3 / Debra S. Stakes. - The hydrogen and oxygen isotope history of the Silurian-Permian hydrosphere as determined by direct measurement of fossil water / L. Paul Knauth and Sarah K. Roberts. - Oxygen isotopes in phosphates of fossil fish-Devonian to Recent / Yehoshua Kolodny and Boaz Luz. - Dolomitization of the Hope Gate Formation (north Jamaica) by seawater: Reassessment of mixing-zone dolomite / Lynton S. Land. - Fossil meteoric ground waters in the Delaware Basin of southeastern New Mexico / Steven J. Lambert. - PART C. CLIMATOLOGY AND GLACIOLOGY. - The heavy isotope enrichment of water in coupled evaporative systems / Joel R. Gat and Carl Bowser. - The elusive climate signal in the isotopic composition of precipitation / James R. Lawrence and James W. C. White. - Stable oxygen and hydrogen isotope ratios in shallow ground waters from India and a study of the role of evapotranspiration in the Indian monsoon / R. V. Krishnamurthy and S. K. Bhattacharya. - Stable isotopic composition of waters in a small Piedmont watershed / David B. Wenner, Peter D. Ketcham and John F. Dowd. - Isotopic changes during the formation of depth hoar in experimental snowpacks / Richard A. Sommerfeld, Clark Judy and Irving Friedman. - Isotopic changes during snow metamorphism / Irving Friedman, Carl Benson and Jim Gleason. - The glacial/interglacial temperature range of the surface water of the oceans at low latitudes / Cesare Emiliani and David B. Ericson. - Is the Postglacial artificial? / Cesare Emiliani, David A. Price and Joanne Seipp. - PART D. Paleoenvironment and Archaeology. - Osteocalcin as the recommended biopolymer for 14C age dating of bone and δ13C and δ15N paleodietary reconstruction / Henry O. Ajie and Isaac R. Kaplan. - The relationship between stable oxygen and hydrogen isotope ratios of water in astomatal plants / Lee W. Cooper, Michael J. Deniro and Jon E. Keeley. - 13C/2C ratios of the Fe(IIl) carbonate component in natural geothites / Crayton J. Yapp and Harald Poths. - Oxygen isotope studies of zeolites: Stilbite, analcime, heulandite, and clinoptilolite I. Analytical technique / Xiahong Feng and Samuel M. Savin. - Eolian inputs of lead to the South Pacific via rain and dry deposition from industrial and natural sources / Dorothy M. Settle and Clair C. Patterson. - Stable isotopes and the Roman marble trade-evidence from Scythopolis and Caesarea, Israel / Ze'ev Pearl and Mordeckai Mararitz. - Part E. IGNEOUS AND METAMORPHC GEOCHEMISTRY. - Comparisons of 18O/16O and 87Sr/86Sr in volcanic rocks from the Pontine Islands, M. Ernici, and Campania with other areas in Italy / B. Turi, H. P. Taylor, Jr. and G. Ferrara. - Hydrogen, sulphur and neodymium isotope variations in the mantle beneath the EPR at 12°50' N / Marc Chaussidon, Simon M. F. Sheppard and Annie Michard. - Degassing of Obsidian Dome rhyolite, lnyo volcanic chain, California / Bruce E. Taylor. - Application of stable isotopes in identifying a major Hercynian synplutonic rift zone and its associated meteoric-hydrothermal activity, southern Schwarzwald, Germany / Hugh P. Taylor, Jr., Mordeckai Magaritz and Stephen M. Wickham. - An oxygen and hydrogen isotope study of high-grade metamorphism and anatexis in the Ruby Mountains-East Humboldt Range core complex, Nevada / Stephen M. Wickham, Hugh P. Taylor, Jr., Arthur W. Snoke and James R. O'Neil. - Daughter-parent isotope systematics in U-Th-bearing igneous accessory mineral assemblages as potential indices of metamorphic history: A discussion of the concept / Leon T. Silver. - Retrograde exchange of hydrogen isotopes between hydrous minerals and water at low temperatures / T. Kurtis Kyser and Robert K. Errich. - PART F. ORE DEPOSITS AND HYDROTHERMAL ALTERATION. - Stable isotope studies of quartz-vein type tungsten deposits in Dajishan Mine, Jiangxi Province, Southeast China / Yuch-Ning Shieh and Guo-Xin Zhang. - Oxygen isotope study of the fossil hydrothermal system in the Comstock Lode mining district, Nevada / Robert E. Criss and Duane E. Champion. - Oxygen isotope studies of Jurassic fossil hydrothermal systems, Mojave Desert, southeastern California / G. Cleve Solomon and Hugh P. Taylor, Jr. - Variations in δ18O values, water/rock ratios, and water flux in the Rico paleothermal anomaly, Colorado / Peter B. Larson and Brian S. Zimmerman. - PART G. EXTRATERRESTRIAL GEOCHEMISTRY. - Initial Pb isotopic compositions of lunar granites as determined by ion microprobe / W. Compston, I. S. Williams and C. Meyer. - Silicon, carbon and nitrogen isotopic studies of silicon carbide in carbonaceous and enstatite chondrites / J. Stone, I. D. Hutcheon, S. Epstein and G. J. Wasserburg. - Subject Index.

Note: TABLE OF CONTENTS FOREWORD 1 INTRODUCTION AND SURVEY OF RADIOANALYSIS 1.1 Introduction 1.2 Principles of radioanalysis 1.2.1 General 1.2.2 Glossary of basic terms and concepts 1.3 Scope and contents References 2 SAMPLING AND PRECONCENTRATION 2.1 Survey and principles 2.1.1 Sampling 2.1.2 From sample to aliquot 2.1.2 .1 General 2.1.2.2 Granular material 2.1.2.3 Water 2.2 Sampling procedures 2.2.1 Rocks 2.2.2 Sediments and pore water 2.2.2.1 Sediments 2.2.2.2 Pore water 2.2.3 Fresh and ground water and related particulate matter 2.2.3.1 Fresh water 2.2.3.2 Ground water 2.2.4 Sea- and estuarine water and related particulate matter and sediments 2.2.4.1 Water 2.2.4.2 Particulate matter 2.2.4.3 Sediment cores 2.2.5 Rainwater and dry deposition 2.2.5.1 Rainwater 2.2.5.2 Dry deposition 2.3 Preconcentration 2.3.1 General 2.3.2 Fresh water and rainwater 2.3.3 Seawater 2.3.3.1 Survey 2.3.3.2 Scavenging procedures 2.3.3.3 Ion-exchange and solvent extraction procedures for Th, U and Pu 2.4 Reference materials 2.4.1 Principle 2.4.2 Survey of reference materials and SRM's 2.4.3 Use of reference materials and SRM's 2.4.3.1 Reference materials 2.4.3.2 SRM's 2.4.4 Reference materials for environmental radioactivity and isotopic ratio measurements References 3 INSTRUMENTAL RADIOANALYSIS OF GEOLOGICAL MATERIALS 3.1 Survey 3.1.1 Activation analysis 3.1.2 Photon activation analysis 3.1.3 Charged particle activation analysis (CPAA and HIAA) 3.1.4 Prompt techniques 3.1.4.1 Neutron induced prompt capture y-ray measurement (PGAA) 3.1.4.2 Proton induced X-ray emission (PIXE) 3.2 Principles 3.2.1 Principles of instrumental neutron activation analysis (INAA) 3.2.1.1 Activation 3.2.1.2 Standardization and flux monitoring 3.2.1.3 Count rate 3.2.1.4 Counting result 3.2.1.5 Sensitivity 3.2.1.6 Characteristic parameters of the three types of neutron activation 3.2.2 Delayed neutron counting 3.2.3 Activation analysis with high-energy photons 3.2.4 Principles of charged particle activation analysis (CPAA) 3.2.5 Principles of prompt techniques 3.2.5.1 Prompt capture gamma-ray measurements (PGAA) 3.2.5.2 Proton induced X-ray emission (PIXE) 3.3 Practical aspects of INAA, IPAA and PIXE 3.3.1 The radioanalytical laboratory 3.3.2 Irradiation facilities for NAA 3.3.2.1 Nuclear reactors 3.3.2.2 Rabbit systems 3.3.2.3 Epithermal activation 3.3.2.4 Neutron generators 3.3.2.5 Delayed neutron counting 3.3.3 Routing of INAA 3.3.4 Practical aspects of IPAA 3.3.5 Practical aspects of CPAA 3.3.6 Practical aspects of PGAA 3.3.7 Practical aspects of PIXE and PIGE 3.3.7.1 Proton induced X-ray emission (PIXE) 3.3.7.2 Proton induced prompt gamma emission (PIGE) 3.3.8 The error-budget 3.4 Multielement determination by INAA based on gamma-ray spectrometry 3.4.1 General 3.4.2 A practical procedure for INAA of silicates based on thermal neutrons 3.4.2.1 Preparation of sample and standards for irradiation 3.4.2.2 Irradiation and measurements 3.4.2.3 Conclusion 3.4.3 Rocks and ores 3.4.4 Meteorites 3.4.5 Sediments 3.4.6 Air-dust 3.4.7 Coal and ash 3.5 Instrumental neutron activation analysis of the lanthanides 3.6 Instrumental neutron activation analysis of uranium 3.7 Applications of instrumental neutron activation analysis with an isotopic neutron source and a 14.5 MeV neutron generator 3.7.1 Survey 3.7.2 INAA with isotopic neutron sources in the radiochemical laboratory 3.7.3 INAA with the neutron generator in the radiochemical laboratory 3.7.4. Conclusion 3.8 Applications of IPAA to silicates 3.9 Applications of IPAA to silicates 3.10 Applications of prompt techniques 3.10.1 Applications of PGAA and PIGE 3.10.2 Applications of PIXE References 4 NEUTRON ACTIVATION ANALYSIS INCLUDING CHEMICAL SEPARATION OF GEOLOGICAL SAMPLES 4.1 Introduction 4.2 Dissolution procedures and separation schemes 4.3 Lanthanides 4.3.1 General 4.3.2 Present procedures 4.4 Noble metals 4.4.1 General 4.4.2 Separation schemes 4.4.3 Single element determinations 4.5 Uranium and thorium 4.5.1 General 4.5.2 Procedures 4.5.2.1 Uranium 4.5.2.2 Thorium 4.6 Other elements 4.6.1 General 4.6.2 Alkali metals 4.6.3 Earth alkali metals 4.6.4 Copper and zinc 4.6.5 Mercury 4.6.6 Indium 4.6.7 Thallium 4.6.8 Tin 4.6.9 Elements with volatile halides and hydrides: Ga, Ge, As, Se, Sb, Te 4.6.9.1 Survey 4.6.9.2 Procedures 4.6.10 Vanadium and tantalum 4.6.11 Chromium 4.6.12 Molybdenum andtungsten 4.6.13 Halogens References 5 RADIOANALYSIS OF WATER 5.1 Survey 5.2 Elemental analysis of fresh water 5.2.1 Survey 5.2.2 Routine elemental analysis of rainwater 5.2.2.1 Sampling and sample treatment 5.2.2.2 Irradiation and processing of aliquots 5.2.2.3 Results 5.2.3 Special elemental analysis of rainwater 5.2.3.1 Bromine and iodine by isotopic exchange 5.2.3.2 Iodate by anion-exchange 5,2.3.3 Silver by cation-exchange and subsequent INAA 5.2.4 Routine elemental analysis of surface and ground water 5.2.4,1 General 5.2.4.2 Routine procedures 5.3 Elemental analysis of seawater 5.3.1 Survey 5.3.2 Routine elemental analysis of seawater by preconcentration on a "Chelex"-column and INAA 5.3.3 Routine elemental analysis of seawater by preconcentration on active carbon 5.3.3,1 General 5.3.3.2 Arsenic and antimony 5,3.3.3 Vanadium, iodine, tellurium and uranium 5.3.3.4 Total antimony, molybdenum and tungsten 5,3.3.5 Chromate, cobalt, nickel and tetravalent selenium 5.3.3,6 Mercury 5.3.4 Special elemental analysis of seawater 5.3.4.1 General 5.3.4.2 Rubidium and cesium 5.3.4.3 Strontium 5.3.4.4 Manganese and zinc 5,3,4.5 Tin 5.3.4.6 Nickel 5.3.4.7 Noble metals 5.3.4.8 Mercury References 6 RADIOTRACER EXPERIMENTS IN THE LABORATORY 6.1 Survey 6.2 Basic equations of radiotracer experiments in closed systems 6.3 Isotopic exchange in solution 6.4 Isotopic exchange between a solution and a solid 6.5 Reactions in solution 6.6 Reaction between a solution and a solid 6.6.1 Dissolution 6.6. 2 Leaching 6.6.3 Diffusion from solids 6.6.4 Sorption 6.7 Migration studies in solid-liquid systems 6.7.1 General 6.7.2 The determina tion of distribution coefficients in seawater 6.7.3 Radioecological column experiments in the laboratory 6.7.4 Laboratory experiments on very slow migration; the case of the actinides References 7 RADIOTRACER EXPERIMENTS IN THE FIELD 7.1 Survey 7.2 Principles of (radio)tracer experiments in open systems with flow in one direction 7.2.1 Basic concepts 7.2.2 Measurement of linear velocity and flow rate 7.2.3 Measurement of axial dispersion 7.2.4 Measurement of sedimentation rates 7.2.4.1 General 7.2.4.2 Lead-210 7.2.4.3 Cesium-137 7.2.5 Measurement of the degree of sediment mixing 7.2.6 Measurement of filtration velocity in case of horizontal groundwater flow 7.2.7 Measurement of groundwater flow in the unsaturated zone by radiocarbon 7.3 Principles of (radio)tracer experiments in open systems with flow in various directions 7.3.1 Survey 7.3.2 Measurement of sand or silt flow rates on the sea floor 7.3.3 Radiotracer measurements in water movement in the saturated zone 7.3.4 Radiotracer measurement on water movement in the unsaturated zone 7.4 Practical aspects of radiotracer experiments in the field 7.4.1 Preparation 7.4.2 Performance 7.4.3 Calculations References 8 MEASUREMENT OF NATURAL RADIOACTIVITY 8.1 General 8.1.1 Survey 8.1.2 Concentrations 8.1.3 Detection by direct measurement ofradiation 8.1.3.1 In situ measurements of uranium and thorium 8.1.3.2 Laboratory measurements 8.1.4 Detection by secundary effects 8.2 Measurement of low-level gamma-activities 8.2.1 General 8.2.2 A low background system (LBS) 8.2.2.1 Set-up 8.2.2.2 Limits of detection and determination 8.2.2.3 Processing of data 8.2.3. Anti-coincidence (AC)-counting 8.3 Measurements in rocks and sediments 8.3.1 General 8.3.2 Radon measurements (emanometry) 8.3.3 Age dating by measurement of disequilibrium in the natural decay-series 8.3.3.1 General 8.3.3.2 234U-230Th 8.3.3.3 235U-231Pa 8.3.3.4 232Th-230Th 8.3.3.5 230Th-231Pa 8.3.4 Environmental laboratory measurements on naturally occurring radionucl

Note: Chapter 1. Introduction to U-series Geochemistry by Bernard Bourdon, Simon Turner, Gideon M. Henderson and Craig C. Lundstrom, p. 1 - 22 Chapter 2. Techniques for Measuring Uranium-series Nuclides: 1992-2002 by Steven J. Goldstein and Claudine H. Stirling, p. 23 - 58 Chapter 3. Mineral-Melt Partitioning of Uranium, Thorium and Their Daughters by Jonathan Blundy and Bernard Wood, p. 59 - 124 Chapter 4. Timescales of Magma Chamber Processes and Dating of Young Volcanic Rocks by Michel Condomines, Pierre-Jean Gauthier, and Olgeir Sigmarsson, p. 125 - 174 Chapter 5. Uranium-series Disequilibria in Mid-ocean Ridge Basalts: Observations and Models of Basalt Genesis by Craig C. Lundstrom, p. 175 - 214 Chapter 6. U-series Constraints on Intraplate Basaltic Magmatism by Bernard Bourdon and Kenneth W. W. Sims, p. 215 - 254 Chapter 7. Insights into Magma Genesis at Convergent Margins from U-series Isotopes by Simon Turner, Bernard Bourdon and Jim Gill, p. 255 - 316 Chapter 8. The Behavior of U- and Th-series Nuclides in Groundwater by Donald Porcelli and Peter W. Swarzenski, p. 317 - 362 Chapter 9. Uranium-series Dating of Marine and Lacustrine Carbonates by R. L. Edwards, C. D. Gallup, and H. Cheng, p. 363 - 406 Chapter 10. Uranium-series Chronology and Environmental Applications of Speleothems by David A. Richards and Jeffrey A. Dorale, p. 407 - 460 Chapter 11. Short-lived U/Th Series Radionuclides in the Ocean: Tracers for Scavenging Rates, Export Fluxes and Particle Dynamics by J. K. Cochran and P. Masquè, p. 461 - 492 Chapter 12. The U-series Toolbox for Paleoceanography by Gideon M. Henderson and Robert F. Anderson, p. 493 - 532 Chapter 13. U-Th-Ra Fractionation During Weathering and River Transport by F. Chabaux, J. Riotte and O. Dequincey, p. 533 - 576 Chapter 14. The Behavior of U- and Th-series Nuclides in the Estuarine Environment by Peter W. Swarzenski, Donald Porcelli, Per S. Andersson and Joseph M. Smoakv, p. 577 - 606 Chapter 15. U-series Dating and Human Evolution by A. W. G. Pike and P. B. Pettitt, p. 607 - 630 Chapter 16. Mathematical-Statistical Treatment of Data and Errors for 230Th/U Geochronology by K. R. Ludwig, p. 631 - 656

Note: Chapter 1. New Developments in Deformation Studies: High-Strain Deformation by Stephen J. Mackwell and Mervyn S. Paterson, p. 1 - 20 Chapter 2. New Developments in Deformation Experiments at High Pressure by William B. Durham, Donald J. Weidner, Shun-ichiro Karato, and Yanbin Wang, p. 21 - 50 Chapter 3. Deformation of Granitic Rocks: Experimental Studies and Natural Examples by Jan Tullis, p. 51 - 96 Chapter 4. Laboratory Constraints on the Rheology of the Upper Mantle by Greg Hirth, p. 97 - 120 Chapter 5. Partial Melting and Deformation by David L. Kohlstedt, p. 121 - 136 Chapter 6. Dislocations and Slip Systems of Mantle Minerals by Patrick Cordier, p. 137 - 180 Chapter 7. Instability of Deformation by Harry W. Green II and Chris Marone, p. 181 - 200 Chapter 8. Brittle Failure of Ice by Erland M. Schulson, p. 201 - 525 Chapter 9. Seismic Wave Attenuation: Energy Dissipation in Viscoelastic Crystalline Solids by Reid F. Cooper, p. 253 - 290 Chapter 10. Texture and Anisotropy by Hans-Rudolf Wenk, p. 291 - 330 Chapter 11. Modeling Deformation of Polycrystalline Rocks by Paul R. Dawson, p. 331 - 352 Chapter 12. Seismic Anisotropy and Global Geodynamics by Jean-Paul Montagner and Laurent Guillot, p. 353 - 386 Chapter 13. Theoretical Analysis of Shear Localization in the Lithosphere by David Bercovici and Shun-ichiro Karato, p. 387 - 420

Note: Chapter 1. Preface: Noble Gases – Noble Science by Alex N. Halliday, p. 1 - 20 Chapter 2. An Overview of Noble Gas Geochemistry and Cosmochemistry by Donald Porcelli, Chris J. Ballentine, Rainer Wieler, p. 21 - 70 Chapter 3. Noble Gases in the Solar System by Rainer Wieler, p. 71 - 100 Chapter 4. Noble Gases in the Moon and Meteorites: Radiogenic Components and Early Volatile Chronologies by Timothy D. Swindle, p. 101 - 124 Chapter 5. Cosmic-Ray-Produced Noble Gases in Meteorites by Rainer Wieler, p. 125 - 170 Chapter 6. Martian Noble Gases by Timothy D. Swindle, p. 171 - 190 Chapter 7. Origin of Noble Gases in the Terrestrial Planets by Robert O. Pepin, Donald Porcelli, p. 191 - 246 Chapter 8. Noble Gas Isotope Geochemistry of Mid-Ocean Ridge and Ocean Island Basalts: Characterization of Mantle Source Reservoirs by David W. Graham, p. 247 - 318 Chapter 9. Noble Gases and Volatile Recycling at Subduction Zones by David R. Hilton, Tobias P. Fischer, Bernard Marty, p. 319 - 370 Chapter 10. The Storage and Transport of Noble Gases in the Subcontinental Lithosphere by Tibor J. Dunai, Donald Porcelli, p. 371 - 410 Chapter 11. Models for the Distribution of Terrestrial Noble Gases and the Evolution of the Atmosphere by Donald Porcelli, Chris J. Ballentine, p. 411 - 480 Chapter 12. Production, Release and Transport of Noble Gases in the Continental Crust by Chris J. Ballentine, Pete G. Burnard, p. 481 - 538 Chapter 13. Tracing Fluid Origin, Transport and Interaction in the Crust by Chris J. Ballentine, Ray Burgess, Bernard Marty, p. 539 - 614 Chapter 14. Noble Gases in Lakes and Ground Waters by Rolf. Kipfer, Werner. Aeschbach-Hertig, Frank. Peeters, Martin. Stute, p. 615 - 700 Chapter 15. Noble Gases in Ocean Waters and Sediments by Peter Schlosser, Gisela Winckler, p. 701 - 730 Chapter 16. Cosmic-Ray-Produced Noble Gases in Terrestrial Rocks: Dating Tools for Surface Processes by Samuel Niedermann, p. 731 - 784 Chapter 17. K-Ar and Ar-Ar Dating by Simon P. Kelley, p. 785 - 818 Chapter 18. (U-Th)/He Dating: Techniques, Calibrations, and Applications by Kenneth A. Farley, p. 819 - 844

Note: Chapter 1. Mineralogy, Petrology and Geochemistry of Beryllium: An Introduction and List of Beryllium Minerals by Edward S. Grew, p. 1 - 76 Chapter 2. Behavior of Beryllium During Solar System and Planetary Evolution: Evidence from Planetary Materials by Charles K. Shearer, p. 77 - 120 Chapter 3. Trace-Element Systematics of Beryllium in Terrestrial Materials by Jeffrey G. Ryan, p. 121 - 146 Chapter 4. Rates and Timing of Earth Surface Processes From In Situ-Produced Cosmogenic Be-10 by Paul R. Bierman, Marc W. Caffee, P. Thompson Davis, Kim Marsella, Milan Pavich, Patrick Colgan, and David Mickelson, p. 147 - 206 Chapter 5. Cosmogenic Be-10 and the Solid Earth: Studies in Geomagnetism, Subduction Zone Processes, and Active Tectonics by Julie D. Morris, John Gosse, Stefanie Brachfeld, and Fouad Tera, p. 207 - 270 Chapter 6. Environmental Chemistry of Beryllium-7 by James M. Kaste, Stephen A. Norton, and Charles T. Hess, p. 271 - 290 Chapter 7. Environmental Chemistry of Beryllium by J. Vesely, S. A. Norton, P. Skrivan, V. Majer, P. Kram, T. Navr·til, and J. M. Kaste, p. 291 - 318 Chapter 8. Beryllium Analyses by Secondary Ion Mass Spectrometry by Richard L. Hervig, p. 319 - 332 Chapter 9. The Crystal Chemistry of Beryllium by Frank C. Hawthorne and Danielle M. C. Huminicki, p. 333 - 404 Chapter 10. Mineralogy of Beryllium in Granitic Pegmatites by Petr Cerny, p. 405 - 444 Chapter 11. Beryllium in Silicic Magmas and the Origin of Beryl-Bearing Pegmatites by David London and Joseph M. Evensen, p. 445 - 486 Chapter 12. Beryllium in Metamorphic Environments (Emphasis on Aluminous Compositions) by Edward S. Grew, p. 487 - 550 Chapter 13. Be-Minerals: Synthesis, Stability, and Occurrence in Metamorphic Rocks by Gerhard Franz and Giulio Morteani, p. 551 - 590 Chapter 14. Non-pegmatitic Deposits of Beryllium: Mineralogy, Geology, Phase Equilibria and Origin by Mark D. Barton and Steven Young, p. 591 - 691

Note: Chapter 1. The Crystal Structure of Apatite, Ca5(PO4)3(F,OH,Cl) by John M. Hughes and John Rakovan, p. 1 - 12 Chapter 2. Compositions of the Apatite-Group Minerals: Substitution Mechanisms and Controlling Factors by Yuanming Pana and Michael E. Fleet, p. 13 - 50 Chapter 3. Growth and Surface Properties of Apatite by John Rakovan, p. 51 - 86 Chapter 4. Synthesis, Structure and Properties of Monazite, Pretulite, and Xenotime by Lynn A. Boatner, p. 87 - 122 Chapter 5. The Crystal Chemistry of the Phosphate Minerals by Danielle M.C. Huminicki and Frank C. Hawthorne, p. 123 - 254 Chapter 6. Apatite in Igneous Systems by Philip M. Piccoli and Philip A. Candela, p. 255 - 292 Chapter 7. Apatite, Monazite, and Xenotine in Metamorphic Rocks by Frank S. Spear and Joseph M. Pyle, p. 293 - 336 Chapter 8. Electron Microprobe Analysis of REE in Apatite, Monazite and Xenotime: Protocols and Pitfalls by Joseph M. Pyle, Frank S. Spear, and David A. Wark, p. 337 - 362 Chapter 9. Sedimentary Phosphorites - An Example: Phosphoria Formation, Southeastern Idaho, U.S.A by Andrew C. Knudsen and Mickey E. Gunter, p. 363 - 390 Chapter 10. The Global Phosphorus Cycle by Gabriel M. Filippelli, p. 391 - 426 Chapter 11. Calcium Phosphate Biominerals by James C. Elliott, p. 427 - 454 Chapter 12. Stable Isotope Composition of Biological Apatite by Matthew J. Kohn and Thure E. Cerling, p. 455 - 488 Chapter 13. Trace Elements in Recent and Fossil Bone Apatite by Clive N. Trueman and Noreen Tuross, p. 489 - 522 Chapter 14. U-TH-Pb Dating of Phosphate Minerals by T. Mark Harrison, Elizabeth J. Catlos, and Jean-Marc Montel, p. 523 - 558 Chapter 15. (U-Th)/He Dating of Phosphates: Apatite, Monazite, and Xenotime by Kenneth A. Farley and Daniel F. Stockli, p. 559 - 578 Chapter 16. Fission Track Dating of Phosphate Minerals and the Thermochronology of Apatite by Andrew J.W. Gleadow, David X. Belton, Barry P. Kohn, and Roderick W. Brown, p. 579 - 630 Chapter 17. Biomedical Application of Apatites by Karlis A. Gross and Christopher C. Berndt, p. 631 - 672 Chapter 18. Phosphates as Nuclear Waste Forms by Rodney C. Ewing and LuMin Wang, p. 673 - 700 Chapter 19. Apatite Luminescence by Glenn A. Waychuna, p. 701 - 742

Note: Chapter 1. An Overview of Synchrotron Radiation Applications to Low Temperature Geochemistry and Environmental Science by Gordon E. Brown, Jr. and Neil C. Sturchio, p. 1 - 116 Chapter 2. A Brief Overview of Synchrotron Radiation by T. K. Sham and Mark L. Rivers, p. 117 - 148 Chapter 3. X-ray Reflectivity as a Probe of Mineral-Fluid Interfaces: A User Guide by Paul A. Fenter, p. 149 - 220 Chapter 4. X-ray Standing Wave Studies of Minerals and Mineral Surfaces: Principles and Applications by Michael J. Bedzyk and Likwan Cheng, p. 221 - 266 Chapter 5. Grazing-incidence X-ray Absorption and Emission Spectroscopy by Glenn A. Waychunas, p. 267 - 316 Chapter 6. Applications of Storage Ring Infrared Spectromicroscopy and Reflection-Absorption Spectroscopy to Geochemistry and Environmental Science by Carol J. Hirschmugl, p. 317 - 340 Chapter 7. Quantitative Speciation of Heavy Metals in Soils and Sediments by Synchrotron X-ray Techniques by Alain Manceau, Matthew A. Marcus, and Nobumichi Tamura, p. 341 - 428 Chapter 8. Microfluorescence and MicrotomographyAnalyses of Heterogeneous Earth and Environmental Materials by Stephen R. Sutton, Paul M. Bertsch, Matthew Newville, Mark Rivers, Antonio Lanzirotti and Peter Eng, p. 429 - 484 Chapter 9. Soft X-ray Spectroscopy and Spectromicroscopy Studies of Organic Molecules in the Environment by Satish C. B. Myneni, p. 485 - 579