ALBERT

Description / Table of Contents: Fluids rich in water, carbon and sulfur species and a variety of dissolved salts are a ubiquitous transport medium for heat and matter in the Earth’s interior. Fluid transport through the upper mantle and crust controls the origin of magmatism above subduction zones and results in natural risks of explosive volcanism. Fluids passing through rocks affect the chemical and heat budget of the global oceans, and can be utilized as a source of geothermal energy on land. Fluid transport is a key to the formation and the practical utilization of natural resources, from the origin of hydrothermal mineral deposits, through the exploitation of gaseous and liquid hydrocarbons as sources of energy and essential raw materials, to the subsurface storage of waste materials such as CO2. Different sources of fluids and variable paths of recycling volatile components from the hydrosphere and atmosphere through the solid interior of the Earth lead to a broad range of fluid compositions, from aqueous liquids and gases through water-rich silicate or salt melts to carbon-rich endmember compositions. Different rock regimes in the crust and mantle generate characteristic ranges of fluid composition, which depending on pressure, temperature and composition are miscible to greatly variable degrees. For example, aqueous liquids and vapors are increasingly miscible at elevated pressure and temperature. The degree of this miscibility is, however, greatly influenced by the presence of additional carbonic or salt components. A wide range of fluid–fluid interactions results from this partial miscibility of crustal fluids. Vastly different chemical and physical properties of variably miscible fluids, combined with fluid flow from one pressure – temperature regime to another, therefore have major consequences for the chemical and physical evolution of the crust and mantle. Several recent textbooks and review articles have addressed the role and diverse aspects of fluids in crustal processes. However, immiscibility of fluids and the associated phenomena of m ultiphase fluid flow are generally dealt with only in subsections with respect to specific environments and aspects of fluid mediated processes. This volume of Reviews in Mineralogy and Geochemistry attempts to fill this gap and to explicitly focus on the role that co-existing fluids play in the diverse geologic environments. It brings together the previously somewhat detached literature on fluid–fluid interactions in continental, volcanic, submarine and subduction zone environments. It emphasizes that fluid mixing and unmixing are widespread processes that may occur in all geologic environments of the entire crust and upper mantle. Despite different P-T conditions, the fundamental processes are analogous in the different settings.

Description / Table of Contents: The importance of sulfide minerals in ores has long been, and continues to be, a major reason for the interest of mineralogists and geochemists in these materials. Determining the fundamental chemistry of sulfides is key to understanding their conditions of formation and, hence, the geological processes by which certain ore deposits have formed. This, in turn, may inform the strategies used in exploration for such deposits and their subsequent exploitation. In this context, knowledge of structures, stabilities, phase relations and transformations, together with the relevant thermodynamic and kinetic data, is critical. As with many geochemical systems, much can also be learned from isotopic studies. The practical contributions of mineralogists and geochemists to sulfide studies extend beyond areas related to geological applications. The mining of sulfide ores, to satisfy ever increasing world demand for metals, now involves extracting very large volumes of rock that contains a few percent at most (and commonly less than one percent) of the metal being mined. This is true of relatively low value metals such as copper; for the precious metals commonly occurring as sulfides, or associated with them, the mineable concentrations (grades) are very much lower. The "as-mined" ores therefore require extensive processing in order to produce a concentrate with a much higher percentage content of the metal being extracted. Such mineral processing (beneficiation) involves crushing and grinding of the ores to a very fine grain size in order to liberate the valuable metal-bearing (sulfide) minerals which can then be concentrated. In some cases, the metalliferous (sulfide) minerals may have specific electrical or magnetic properties that can be exploited to enable separation and, hence, concentration. More commonly, froth flotation is used, whereby the surfaces of particles of a particular mineral phase are rendered water repellent by the addition of chemical reagents and hence are attracted to air bubbles pulsed through a mineral particle-water-reagent pulp. An understanding of the surface chemistry and surface reactivity of sulfide minerals is central to this major industrial process and, of course, knowledge of electrical and magnetic properties is very important in cases where those particular properties can be utilized. In the years since the publication of the first ever Reviews in Mineralogy volume (1974, at that time called MSA "Short Course Notes") which was entitled Sulfide Mineralogy, sulfides have become a focus of research interest for reasons centering on at least two other areas in addition to their key role in ore deposit studies and mineral processing technology. It is in these two new areas that much of the research on sulfides has been concentrated in recent years. The first of these areas relates to the capacity of sulfides to react with natural waters and acidify them; the resulting Acid Rock Drainage (ARD), or Acid Mine Drainage (AMD) where the sulfides are the waste products of mining, has the capacity to damage or destroy vegetation, fish and other aquatic life forms. These acid waters may also accelerate the dissolution of associated minerals containing potentially toxic elements (e.g., As, Pb, Cd, Hg, etc.) and these may, in turn, cause environmental damage. The much greater public awareness of the need to prevent or control AMD and toxic metal pollution has led to regulation and legislation in many parts of the world, and to the funding of research programs aimed at a greater understanding of the factors controlling the breakdown of sulfide minerals. We begin with a review of analytical methods for measuring and calibrating water contents in nominally anhydrous minerals by George Rossman. While infrared spectroscopy is still the most sensitive and most convenient method for detecting water in minerals, it is not intrinsically quantitative but requires calibration by some other, independent analytical method, such as nuclear reaction analysis, hydrogen manometry, or SIMS. A particular advantage of infrared spectroscopy, however, is the fact that it does not only probe the concentration, but also the structure of hydrous species in a mineral and in many cases the precise location of a proton in a mineral structure can be worked out based on infrared spectra alone. The methods and principles behind this are reviewed by Eugen Libowitzky and Anton Beran, with many illustrative examples. Compared to infrared spectroscopy, NMR is much less used in studying hydrogen in minerals, mostly due to its lower sensitivity, the requirement of samples free of paramagnetic ions such as Fe2+ and because of the more complicated instrumentation required for NMR measurements. However, NMR could be very useful under some circumstances. It could detect any hydrogen species in a sample, including such species as H2 that would be invisible with infrared. Potential applications of NMR to the study of hydrogen in minerals are reviewed by Simon Kohn. While structural models of "water" in minerals have already been deduced from infrared spectra several decades ago, in recent years atomistic modeling has become a powerful tool for predicting potential sites for hydrogen in minerals. The review by Kate Wright gives an overview over both quantum mechanical methods and classical methods based on interatomic potentials. Joseph Smyth then summarizes the crystal chemistry of hydrogen in high-pressure silicate and oxide minerals. As a general rule, the incorporation of hydrogen is not controlled by the size of potential sites in the crystal lattice; rather, the protons will preferentially attach to oxygen atoms that are electrostatically underbonded, such as the non-silicate oxygen atoms in some high-pressure phases. Moreover, heterovalent substitutions, e.g., the substitution of Al3+ for Si4+, can have a major effect on the incorporation of hydrogen. The second reason for even greater research interest in sulfide minerals arose initially from the discoveries of active hydrothermal systems in the deep oceans. The presence of life forms that have chemical rather than photosynthetic metabolisms, and that occur in association with newly-forming sulfides, has encouraged research on the potential of sulfide surfaces in catalyzing the reactions leading to assembling of the complex molecules needed for life on Earth. These developments have been associated with a great upsurge of interest in the interactions between microbes and minerals, and in the role that minerals can play in biological systems. In the rapidly growing field of geomicrobiology, metal sulfides are of major interest. This interest is related to a variety of processes including, for example, those where bacteria interact with sulfides as part of their metabolic activity and cause chemical changes such as oxidation or reduction, or those in which biogenic sulfide minerals perform a specific function, such as that of navigation in magnetotactic bacteria. The development of research in areas such as geomicrobiology and environmental mineralogy and geochemistry, is also leading to a greater appreciation of the role of sulfides (particularly the iron sulfides) in the geochemical cycling of the elements at or near the surface of the Earth. For example, the iron sulfides precipitated in the reducing environments beneath the surface of modern sediments in many estuarine areas may play a key role in the trapping of toxic metals and other pollutants. In our understanding of "Earth Systems," geochemical processes involving metal sulfides are an important part of the story. The main objective of the present text is to provide an up-to-date review of sulfide mineralogy and geochemistry. The emphasis is, therefore, on such topics as crystal structure and classification, electrical and magnetic properties, spectroscopic studies, chemical bonding, high and low temperature phase relations, thermochemistry, and stable isotope systematics. In the context of this book, emphasis is on metal sulfides sensu stricto where only the compounds of sulfur with one or more metals are considered. Where it is appropriate for comparison, there is brief discussion of the selenide or telluride analogs of the metal sulfides. When discussing crystal structures and structural relationships, the sulfosalt minerals as well as the sulfides are considered in some detail (see Chapter 2; also for definition of the term "sulfosalt"). However, in other chapters there is only limited discussion of sulfosalts, in part because there is little information available beyond knowledge of chemical composition and crystal structure. Given the dramatic developments in areas of research that were virtually non-existent at the time of the earlier reviews, major sections have been added here on sulfide mineral surface chemistry and reactivity, formation and transformation of metal-sulfur clusters and nanoparticles, modeling of hydrothermal precipitation, and on sulfides in biosystems. However, it should be emphasized that the growth in the literature on certain aspects of sulfide mineralogy over the past 20 years or so has been such that comprehensive coverage is not possible in a single volume. Thus, the general area of "sulfides in biosystems" is probably worthy of a volume in itself, and "environmental sulfide geochemistry" (including topics such as oxidative breakdown of sulfides) is another area where far more could have been written. In selecting areas for detailed coverage in this volume, we have been mindful of the existence of other relatively recent review volumes, including those in the RiMG series. It has also been our intention not to cover any aspects of the natural occurrence, textural or paragenetic relationships involving sulfides. This is published information that, although it may be supplemented by new observations, is likely to remain useful for a long period and largely not be superceded by later work. In the following chapters, the crystal structures, electrical and magnetic properties, spectroscopic studies, chemical bonding, thermochemistry, phase relations, solution chemistry, surface structure and chemistry, hydrothermal precipitation processes, sulfur isotope geochemistry and geobiology of metal sulfides are reviewed. Makovicky (Chapter 2) discusses the crystal structures and structural classification of sulfides and other chalcogenides (including the sulfosalts) in terms of the relationships between structural units. This very comprehensive survey, using a rather different and complementary approach to that used in previous review volumes, shows the great diversity of sulfide structures and the wealth of materials that remain to be characterized in detail. These materials include rare minerals, and synthetic sulfides that may represent as yet undescribed minerals. Pearce, Pattrick and Vaughan (Chapter 3) review the electrical and magnetic properties of sulfides, discussing the importance of this aspect of the sulfides to any understanding of their electronic structures (chemical bonding) and to applications ranging from geophysical prospecting and mineral extraction to geomagnetic and palaeomagnetic studies. Rapidly developing new areas of interest discussed include studies of the distinctive properties of sulfide nanoparticles. Wincott and Vaughan (Chapter 4) then outline the spectroscopic methods employed to study the crystal chemistry and electronic structures of sulfides. These range from UV-visible through infrared and Raman spectroscopies, to X-ray emission, photoemission and absorption, and to nuclear spectroscopies. Chemical bonding (electronic structure) in sulfides is the subject of the following chapter by Vaughan and Rosso (Chapter 5), a topic which draws on knowledge of electrical and magnetic properties and spectroscopic data as experimental input, as well as on a range of rapidly developing computational methods. Attention then turns to the thermochemistry of sulfides in a chapter by Sack and Ebel (Chapter 6) which is followed by discussion of phase equilibria at high temperatures in the review by Fleet (Chapter 7). Sulfides in aqueous systems, with emphasis on solution complexes and clusters, forms the subject matter of the chapter written by Rickard and Luther (Chapter 8). Sulfide mineral surfaces are the focus of the next two chapters, both by Rosso and Vaughan. The first of these chapters (Chapter 9) addresses characterization of the pristine sulfide surface, its structure and chemistry; the second (Chapter 10) concerns surface reactivity, including redox reactions, sorption phenomena, and the catalytic activity of sulfide surfaces. Reed and Palandri (Chapter 11) show in the next chapter how much can now be achieved in attempting to predict processes of sulfide precipitation in hydrothermal systems. The final chapters deal with two distinctive areas of sulfide mineralogy and geochemistry. Seal (Chapter 12) presents a comprehensive account of the theory and applications of sulfur isotope geochemistry; sulfur isotope fractionation can provide the key to understanding the natural processes of formation of sulfide deposits. In the final chapter, Posfai and Dunin-Borkowski (Chapter 13) review the rapidly developing area of sulfides in biosystems, discussing aspects of both sulfide mineral-microbe interactions and biomineralization processes involving sulfides.

Description / Table of Contents: The publication of this volume occurs at the one-hundredth anniversary of 1905, which has been called the annus mirabilus because it was the year of a number of enormous scientific advances. Among them are four papers by Albert Einstein explaining (among other things) Brownian motion, the photoelectric effect, the special theory of relativity, and the equation E = mc2. Also of significance in 1905 was the first application of another major advance in physics, which dramatically changed the fields of Earth and planetary science. In March of 1905 (and published the following year), Ernest Rutherford presented the following in the Silliman Lectures at Yale: "The helium observed in the radioactive minerals is almost certainly due to its production from the radium and other radioactive substances contained therein. If the rate of production of helium from known weights of the different radioelements were experimentally known, it should thus be possible to determine the interval required for the production of the amount of helium observed in radioactive minerals, or, in other words, to determine the age of the mineral." Rutherford E (1906) Radioactive Transformations. Charles Scriber's Sons, NY Thus radioisotopic geochronology was born, almost immediately shattering centuries of speculative conjectures and estimates and laying the foundation for establishment of the geologic timescale, the age of the Earth and meteorites, and a quantitative understanding of the rates of processes ranging from nebular condensation to Quaternary glaciations. There is an important subplot to the historical development of radioisotopic dating over the last hundred years, which, ironically, arises directly from the subsequent history of the U-He dating method Rutherford described in 1905. Almost as soon as radioisotopic dating was invented, it was recognized that the U-He [or later the (U-Th)/He method], provided ages that were often far younger than those allowed by stratigraphic correlations or other techniques such as U/Pb dating. Clearly, as R.J. Strutt noted in 1910, He ages only provided "minimum values, because helium leaks out from the mineral, to what extent it is impossible to say" (Strutt, 1910, Proc Roy Soc Lond, Ser A 84:379-388). For several decades most attention was diverted to U/Pb and other techniques better suited to measurement of crystallization ages and establishment of the geologic timescale. Gradually it became clear that other radioisotopic systems such as K/Ar and later fission-track also provided ages that were clearly younger than formation ages. In 1910 it may have been impossible to say the extent to which He (or most other elements) leaked out of minerals, but eventually a growing understanding of thermally-activated diffusion and annealing began to shed light on the significance of such ages. The recognition that some systems can provide cooling, rather than formation, ages, was gradual and diachronous across radioisotopic systems. Most of the heavy lifting in this regard was accomplished by researchers working on the interpretation of K/Ar and fission-track ages. Ironically, Rutherfordπs He-based radioisotopic system was one of the last to be quantitatively interpreted as a thermochronometer, and has been added to K/Ar (including 40Ar/39Ar) and fission-track methods as important for constraining the medium- to low-temperature thermal histories of rocks and minerals. Thermochronology has had a slow and sometimes fitful maturation from what were once troubling age discrepancies and poorly-understood open-system behaviors, into a powerful branch of geochronology applied by Earth scientists from diverse fields. Cooling ages, coupled with quantitative understanding of crystal-scale kinetic phenomena and crustal- or landscape-scale interpretational models now provide an enormous range of insights into tectonics, geomorphology, and subjects of other fields. At the same time, blossoming of lower temperature thermochronometric approaches has inspired new perspectives into the detailed behavior of higher temperature systems that previously may have been primarily used for establishing formation ages. Increased recognition of the importance of thermal histories, combined with improved analytical precision, has motivated progress in understanding the thermochronologic behavior of U/Pb, Sm/Nd, Lu/Hf, and other systems in a wide range of minerals, filling out the temperature range accessible by thermochronologic approaches. Thus the maturation of low- and medium-temperature thermochronology has led to a fuller understanding of the significance of radioisotopic ages in general, and to one degree or another has permeated most of geochronology. Except in rare cases, the goal of thermochronology is not thermal histories themselves, but rather the geologic processes responsible for them. Thermochronometers are now routinely used for quantifying exhumation histories (tectonic or erosional), magmatism, or landscape evolution. As thermochronology has matured, so have model and interpretational approaches used to convert thermal histories into these more useful geologic histories. Low-temperature thermochronology has been especially important in this regard, as knowledge of thermal processes in the uppermost few kilometers of the crust require consideration of coupled interactions of tectonic, geodynamic, and surface processes. Exciting new developments in these fields in turn drive improved thermochronologic methods and innovative sampling approaches. The chapters This volume presents 22 chapters covering many of the important modern aspects of thermochronology. The coverage of the chapters ranges widely, including historical perspective, analytical techniques, kinetics and calibrations, modeling approaches, and interpretational methods. In general, the chapters focus on intermediate- to low-temperature thermochronometry, though some chapters cover higher temperature methods such as monazite U/Pb closure profiles, and the same theory and approaches used in low-temperature thermochronometry are generally applicable to higher temperature systems. The widely used low- to medium-temperature thermochronometric systems are reviewed in detail in these chapters, but while there are numerous chapters reviewing various aspects of the apatite (U-Th)/He system, there is no chapter singularly devoted to it, partly because of several previous reviews recently published on this topic. Chapter 1 by Reiners, Ehlers, and Zeitler provides a perspective on the history of thermochronology, comments on modern work in this field and general lessons on the potential for noise to be turned into signal. This chapter also provides a summary of the current challenges, unresolved issues, and most exciting prospects in the field. Much of the modern understanding of kinetic controls on apparent ages, thermal histories, and sampling approaches comes from decades of progress in fission-track dating, a method that remains as essential as ever, partly because of the power of track-length measurements and the depth of (at least empirical) understanding of the kinetics of track annealing. Tagami, Donelick and OπSullivan review the fundamentals of modern fission-track dating (Chapter 2). Two of the most commonly dated, well-understood, and powerful minerals dated by fission-track methods are apatite and zircon, and the specifics of modern methods for these systems and their kinetics are reviewed by Donelick, OπSullivan, and Ketcham (Chapter 3), and Tagami (Chapter 4). Although 40Ar/39Ar and (U-Th)/He dating methods followed somewhat different paths to their modern thermochronologic incarnations, they have many features in common, especially in the kinetics of diffusion and closure. Zeitler and Harrison review the concepts underlying both 40Ar/39Ar and (U-Th)/He methods (Chapter 5). Zircon was one of the first minerals dated by the (U-Th)/He method, but has only just begun to be used for thermochronometry of both bedrock and detrital samples, as reviewed by Reiners (Chapter 6). Continuous time-temperature paths from intracrystalline variations of radiogenic Ar proven perhaps the most powerful of all thermochronologic approaches, and an innovative analogous approach in He dating (4He/3He thermochronometry) is revealing remarkably powerful constraints on the extreme low temperature end of thermal histories, as reviewed by Shuster and Farley (Chapter 7). Thermochronology of detrital minerals provides unique constraints on the long-term evolution of orogens, sediment provenance, and depositional age constraints, to name a few. Bernet and Garver (Chapter 8) review the essentials of detrital zircon fission-track dating, one of the most venerable and robust of detrital thermochronometers, and in Chapter 9, Hodges, Ruhl, Wobus, and Pringle review the use of 40Ar/39Ar dating of detrital minerals, demonstrating the power of detrital muscovite ages in illuminating variations in exhumation rates in catchments over broad landscapes. (U-Th)/He thermochronometry presents several unique interpretational challenges besides new kinetics and low temperature sensitivity. One of these is long-alpha stopping distances, and its coupling with diffusion and U-Th zonation in age corrections. Dunai reviews modeling approaches to deal with these issues in interpreting low-temperature thermal histories (Chapter 10). Ketcham (Chapter 11) reviews the theory and calibration of both forward and inverse models of thermal histories from fission-track and (U-Th)/He data, and makes some important points about the interpretations of such models. Translating thermal histories into exhumational histories and their tectonic or geomorphic significance across a landscape requires quantitative understanding of the thermal structure of the crust and how it is perturbed, a review of which is presented by Ehlers (Chapter 12). Braun (Chapter 13) illustrates the power of low-temperature thermochronometry to constrain topographic evolution of landscapes over time, using PECUBE. Gallagher, Stephenson, Brown, Holmes, and Ballester present a novel method of inverse modeling of fission-track and (U-Th)/He data for thermal histories over landscapes (Chapter 14). Continuous time-temperature paths from closure profiles or their step-heating-derived equivalents are, to some degree, the holy grail of thermochronology. Harrison, Zeitler, Grove, and Lovera (Chapter 15) provide a review of the theory, measurement, and interpretation of continuous thermal histories at both intermediate and high temperatures, derived from both K-feldspar 40Ar/39Ar and monazite U/Pb dating. Extensional orogens provide a special challenge and opportunity for thermochronometry because tectonic exhumation by footwall unroofing often outstrips erosional exhumation, and often occurs at high rates. As Stockli shows (Chapter 16) thermochronology in these setting provides opportunities to measure rates of a number of important processes, as well as obtain a snapshot of crustal thermal structure and its imprint on thermochronometers with varying closure temperatures. Spotila (Chapter 17) reviews the use of thermochronology applied to tectonic geomorphology in a wide range of orogenic settings, introducing the concept of denudational maturity. Thermochronology has found great utility in economic geology, and newly developed approaches pose great potential in this area, and shown by McInnes, Evans, Fu, and Garwin in their review of the use and modeling of thermochronology of hydrothermal ore deposits (Chapter 18). The thermal histories of sedimentary basins are also critical to understanding thermal maturation of hydrocarbons, but are also critical for understanding basin formation, erosional histories of source regions, fluid flow, and climate change and other temporal signals preserved in sedimentary rocks. Armstrong (Chapter 19) reviews these issues and the use of thermochronology in deducing the thermal histories of sedimentary basins. Drawing on large datasets of bedrock apatite fission-track dates, Kohn, Gleadow, Brown, Gallagher, Lorencak, and Noble demonstrate the power of modeling, and, importantly, effectively visualizing, integrated thermotectonic and denudational histories over large regions (Chapter 20). Thermal histories of meteorites provide constraints on a wide range of fundamentally important processes, including nebular condensation and early solar-system metamorphic histories, and the dynamics of interplanetary collisions and shock metamorphism. Min reviews thermochronologic approaches to understanding meteorite thermal histories (Chapter 21), including new methods and approaches. Finally, the importance of robust models with which to interpret thermochronologic data is underscored by the review of the Software for Interpretation and Analysis of Thermochronologic Data (Chapter 22), summarized and compiled by Ehlers, for programs associated with the work of authors in this volume and others.

Description / Table of Contents: In Materials Science, investigations aiming to prepare new types of molecular sieves (porous materials) have opened a productive field of research inspired by the crystal structures of minerals. These new molecular sieves are distinct from zeolites in that they have different kinds of polyhedra that build up their structures. Of particular interest are the new molecular sieves characterized by a mixed "octahedral"-tetrahedral framework (heteropolyhedral frameworks), instead of a purely tetrahedral framework as in zeolites. Heteropolyhedral compounds have been extensively studied since the early 1990's, with particular attention having been focused on titanosilicates, such as ETS-4 (synthetic analog of the mineral zorite) and ETS-10. However, titanosilicates are not the only representatives of novel microporous mineral phases. The search for "octahedral"-tetrahedral silicates was extended to metals other than titanium, for instance, the zirconosilicates with the preparation of synthetic counterparts of the minerals gaidonnayite, petarasite and umbite. Many microporous heteropolyhedral compounds containing metals such as Nb, V, Sn, Ca and lanthanides, have been reported and a wide number of distinct structural types (e.g., rhodesite-delhayelite and tobermorite) have been synthesized and structurally characterized. Moreover, the potential applications of these novel materials have been evaluated, particularly in the areas of catalysis, separation of molecular species, ion exchange and optical and magnetic properties. A comprehensive review of the mineralogical, structural, chemical and crystal-chemical studies carried on natural phases may be extremely useful to inspire and favor investigations on analogs or related synthetic materials. A similar synergy between mineralogists and materials scientists already occurred in the "classical" case of zeolites, in which the wide and deep structural and crystal-chemical knowledge accumulated in the study of the natural phases was extraordinarily useful to the chemists who are active in the field of molecular sieves. In particular, the structural investigation of the natural phases may be extremely rewarding and helpful in orienting the work of synthesis and in understanding the nature of the synthetic products, for the following reasons: Whereas rarely the crystalline synthetic products are suitable for single-crystal structural investigations, the natural counterparts are often well crystallized. Crystallization in nature occurs from chemical systems characterized by a wide compositional range, thus producing compounds with a very rich and variable crystal chemistry, which may provide precious information, suggesting possible substituting elements and addressing the synthetic work in a very productive way. The present volume follows a meeting on "Micro- and mesoporous mineral phases" (Rome, December 6-7, 2004) that was jointly organized by the Accademia Nazionale dei Lincei (ANL) and the International Union of Crystallography (IUCr) via its Commission on Inorganic and Mineral Structures (CIMS). The meeting was convened by Fausto Calderazzo, Giovanni Ferraris, Stefano Merlino and Annibale Mottana and financially supported by several other organizations representing both Mineralogy (e.g., the International Mineralogical Association and the European Mineralogical Union) and Crystallography (e.g., the European Crystallographic Association and the Italian Association of Crystallography). To participants, ANL staff, organizations, and, in general, all involved persons, our sincere acknowledgments; in particular, we are grateful to Annibale Mottana who was able to convince the ANL Academicians to schedule and support the meeting. This volume of the RiMG series highlights the present knowledge on micro- and mesoporous mineral phases, with focus on their crystal-chemical aspects, occurrence and porous activity in nature and experiments. As zeolites are the matter of numerous ad hoc meetings and books - including two volumes in this series - they do not specifically appear in the present volume. The phases of the sodalite and cancrinite-davyne groups, which mineralogists consider distinct from zeolites, are instead considered (in the order, chapter 7 by W. Depmeier and part of chapter 8 by E. Bonaccorsi and S. Merlino, respectively). The first two chapters of the volume cover general aspects of porous materials. This includes the application of the IUPAC nomenclature developed for ordered porous materials to non-zeolite mineral phases (L.B. McCusker, chapter 1) and the extension to heteropolyhedral structures of a topological description by using nodes representing the coordination polyhedra (S.V. Krivovichev, chapter 2). Chapters from 3 to 7 are dedicated to various groups of heteropolyhedral porous structures for which the authors emphasize some of the more general aspects according to their research specialization. G. Ferraris and A. Gula (chapter 3) put the emphasis on the modular aspects of well-known porous phases (such as sepiolite, palygorskite and rhodesite-related structures) as well as on heterophyllosilicates that may be not strictly porous phases (according to the definition given in chapter 1) but could be the starting basis for pillared materials. The porous mineral phases typical of hyperalkaline rocks (such as eudialytes and labuntsovites) are discussed by N.V. Chukanov and I.V. Pekov under their crystal-chemical (chapter 4) and minerogenetic (chapter 5) aspects showing the role of ion exchange during the geological evolution from primary to later phases, with experimental cation exchange data also being reported. J. Rocha and Z. Lin (chapter 6) emphasize how research on the synthesis of octahedral-pentahedral-tetrahedral framework silicates has been inspired and motivated by the many examples of such materials provided by nature; synthesis, structure and possible technological applications of a wide number of these materials are also described. Following chapters 7 and 8 - which besides the cancrinite-davyne group, presents the crystallographic features of the minerals in the tobermorite and gyrolite groups - M. Pasero (chapter 9) illustrates the topological and polysomatic aspects of the "tunnel oxides," a historical name applied to porous oxides related to MnO2, and reviews their main technological applications. The next two chapters (10 and 11) draw attention to "unexpected" porous materials like apatite and sulfides. T.J. White and his team (chapter 10) convincingly show that the apatite structure type displays porous properties, some of which are already exploited. Chapter 10 also contains two appendices that report crystal and synthesis data for hundreds of synthetic apatites, a number that demonstrates how wide the interest is for this class of compounds. E. Makovicky (chapter 11) analyzes the structures of natural and synthetic sulfides and selenides showing that, even if experimental work proving porous activity is practically still missing, several structure types display promising channels. Chapter 12, by M. Mellini, is the only one dedicated to mesoporous mineral phases - which are crystalline compounds with pores wider than 2 nm. Examples discussed are carbon nanotubes, fullerenes - which occur also in nature - chrysotile, opal and, moving from channels to cages, clathrates.

Description / Table of Contents: Oxygen and silicon are the two most common elements in the earth's crust, together constituting an estimated 74.32 weight % and 83.77 atom % of crustal rocks (Mason and Moore, 1982). Thus, it is not surprising that SiO2 or silica, is the most abundant oxide on the earth's surface. In his widely cited survey, Clarke (1904) calculated that quartz alone comprises 12.0% of the crust by volume, ranking behind the mineral groups that include feldspar (59.5%) and amphibole/pyroxene (16.8%). Consequently, research into the silica system is motivated foremost by the prevalence of silica in man's immediate environment. The ubiquity of silica in igneous, metamorphic, and sedimentary rocks has led earth scientists to seek its uses as an indicator of large-scale geological processes, ranging from mountain-building to meteorite impacts. In industry, quartz has long played a prosaic but essential role as an inexpensive and relatively inert constituent of concrete aggregates, and modern electronics technology still relies on quartz oscillators. Silica phases also have played a prominent role in our understanding of the solid state. Physicists first discovered optical activity in crystals and the existence of soft modes during their investigations of quartz. Many scientists have written substantial reviews documenting the importance of silica in the earth, materials, and physical sciences. Notable among these are Robert Sosman, who followed his Properties of Silica (1927) with The Phases of Silica (1965), and Clifford Frondel, who devoted the third volume of Dana's System of Mineralogy (1962) exclusively to the silica minerals. These treatises continue to serve as encyclopedic resources for those interested in silica, and their historical analyses and descriptions of mineral varieties, morphologies, and localities will remain forever useful. Nevertheless, the past three decades have witnessed a first-order expansion of our knowledge of the silica system, and it is time to provide an updated silica review. The present volume focuses on the most recent developments, and it is intended to supplement rather than replace the earlier works of Sosman and Frondel. The contributions to this volume cover silica chemistry in the following fashion: Chapters 1 through 3 describe the crystal structures and phase transitions of silica and its stuffed derivatives. Recent studies of the low-pressure polymorphs quartz, tridymite, and cristobalite have demonstrated unusual superperiodic phases and other anomalies associated with structural transformations (Chapter 1). Spectacular progress in multianvil and diamond cell technologies has made the high-pressure regime accessible, revealing new transitions in the coesite and stishovite systems as well as the phenomenon of pressureinduced amorphization (Chapter 2). Stoichiometric substitution of cations within the frameworks of both low- and high-pressure polymorphs produces a dizzying variety of derivative compounds that are of geological and industrial importance (Chapter 3). Chapters 4 through 9 bridge the relationship between the microstructural character of real silica minerals and the behavior of silica in the geological environment. Incorporation of small amounts of H dramatically weakens quartz exposed to stress (Chapter 4). Consequently, tectonic pressures may lead not to brittle fracture but to the production of high densities of dislocations and preferred orientation in polycrystalline quartz (Chapter 5). The low pressures and temperatures in sedimentary settings may promote the crystallization of highly defective silica phases that are frequently metastable (Chapter 6); through diagenetic processes, these minerals anneal to macrocrystalline quartz (Chapter 7). The nature of the surface structure of quartz strongly influences the mechanisms and kinetics of silica dissolution in aqueous fluids (Chapter 8). Chapters 9 through 13 treat the basic physical properties of the phases of silica. Recent calorimetric studies of some of the more unusual silica compounds have added insight into the stability of the silica framework (Chapter 9). Quantum mechanical considerations of the Si-O bond have yielded a fundamental understanding of the bond lengths and angles within the polymorphous silica system (Chapter 10). Calculations based upon first-principles theory have achieved significant success in explaining and predicting silica transitions at high temperatures and pressures (Chapter 11). Spectroscopic analyses of silica (Chapters 12 and 13) have revealed vibrational behaviors in response to variations in temperature, pressure, and composition that have deepened our understanding of the dynamic interactions within the silica structure. Chapters 14 through 16 detail the uses of silica for industrial purposes. For instance, doping silica with other cations produces ceramics with low expansion on heating (Chapter 14), and high-silica zeolites are being explored for their properties as catalysts and molecular sieves (Chapter 15). High concentrations of silica dust in the workplace long have been linked with the incidence of respiratory diseases, such as silicosis, and recent evidence suggests that crystalline silica may be carcinogenic (Chapter 16).

Description / Table of Contents: Volatile components, by which we mean those magma constituents which typically prefer to occur in the gaseous or super-critical fluid state, may influence virtually every aspect of igneous petrology. The study of volatile-bearing systems, both in nature and in the laboratory, has far exceeded the relative abundances of these components in igneous rocks, yet in many ways the words of Bowen (1928) are still broadly applicable: " ... to many petrologists a volatile component is exactly like a Maxwell demon; it does just what one may wish it to do." (Bowen, 1928, p. 282) What we hope to show in this volume are some areas of progress in understanding the behavior of magmatic volatiles and their influence on a wide variety of geological phenomena; in doing this it also becomes apparent that there remain many questions outstanding. The range of topics we have tried to cover is broad, going from atomisticscale aspects of volatile solubility mechanisms and attendant effects on melt physical properties, to the chemistry of volcanic gases and the concentrations of volatiles in magmas, to the global geochemical cycles of volatiles. The reader should quickly see that much progress has been made since Bowen voiced his concerns about Maxwell demons, but like much scientific progress, answers to old questions have prompted even greater numbers of new questions. The Voltiles in Magmas course was organized and transpired at the Napa Valley Sheraton Hotel in California, December 2-4, 1994, just prior to the Fall Meetings of the American Geophysical Union in San Francisco.

Description / Table of Contents: This volume represents the proceedings of a course by the same title held at Harbor House Resort and Conference Center on Nantucket Island off the coast of Massachusetts, October 22-24, 1993. Numerous minerals are known to induce pulmonary diseases. The asbestos minerals (chrysotile and asbestiform amphiboles) are by far the most infamous. However, a number of silica polymorphs, clays, and zeolites have also been studied in great detail, as have several titania polymorphs, hematite, and magnetite (which are often used as negative controls in biological experiments). In fact, the relatively recent attention received by erionite (a fibrous zeolite) has arguably made it the most notorious of the minerals studied thus far. The processes that lead to the development of disease (or pathogenesis) by minerals very likely occur at or near the mineral-fluid interface (as do many geochemical processes!). Thus the field of "mineral-induced pathogenesis" is a prime candidate for interdisciplinary research, involving mineral scientists, health scientists, petrologists, pathologists, geochemists, biochemists, and surface scientists, to name a few. The success of such an interdisciplinary approach rests on the ability of scientists in very different fields to communicate, and this is hampered by vocabulary barriers and an unfamiliarity with concepts, approaches, and problems. It can be difficult enough for a geoscientist or bioscientist to maintain fluency in the many fields tangential to his or her own field, and this problem is only exacerbated when one investigates problems that are crossdisciplinary. Nevertheless, important advances can be facilitated if these barriers are overcome. This review volume and the short course upon which it was based are intended to provide some of the necessary tools for the researcher interested in this area of interdisciplinary research. The chapters present several of the important problems, concepts, and approaches from both the geological and biological ends of the spectrum. These two extremes are partially integrated throughout the book by cross-referencing between chapters. Chapter 1 also presents a general introduction into the ways in which these two areas overlap. However, many of the areas ripe for the interdisciplinarian will become obvious after reading the various chapters. The final chapter of this book discusses some of the regulatory aspects of minerals. Ultimately, the regulatory arena is where this type of interdisciplinary approach can make an impact, and hopefully better communication between all parties will accomplish this goal. A glossary is included at the end of this book, because the complexity of scientific terms in the two fields can thwart even the most enthusiastic of individuals.

Description / Table of Contents: Volume 13 of Reviews in Mineralogy presented much of our present-day knowledge of micas. At the time of that volume (1984), I mentioned that there was too much material available to attempt to cover all of the hydrous phyllosilicates in one volume. The micas were treated first because of their abundance in nature and the fact that more detailed studies had been carried out on them than on the rest of the phyllosilicates. The serpentines, kaolins, smectites, chlorites, etc. would have to wait their turn. Now, four years later, that tum has come. Hence the peculiar nature of the title of this volume. We know less about the rest of the phyllosilicates than we do about the micas, primarily because many of them are of finer grain sizes and lower crystallinities than most of the micas. As a result, we have been unable to determine as much detail regarding their structures, crystal chemistries, and origins. Nevertheless, there is a considerable body of literature about them, and this volume will attempt to collate and evaluate that literature. One compensating factor that has helped greatly in the accumulation of knowledge about these minerals is that some of them occur in large deposits that are of great economic value and thus stimulate interest. For this reason considerable emphasis in this volume will be related to the occurrence, origin, and petrology of the minerals. S. W. Bailey, Madison, Wisconsin, USA September 1,1988 The authors of this volume presented a short course by the same title to about 120 participants in Denver, Colorado, October 29-30,1988, just prior to the 100th anniversary meeting of the Geological Society of America. S. W. ("Bull") Bailey convened the course and edited this volume, his second for Reviews in Mineralogy. Because he is retiring at the end of this academic year after 38 years' teaching at the University of Wisconsin (Madison), his colleagues, friends and I (a diligent student of "Bull" thirty years ago) agreed that it would be appropriate to dedicate this volume to him, odd though it seems to have him editing a book honoring himself. He had no advance knowledge of this dedication.

Description / Table of Contents: This volume was published to be used as the textbook for the Short Course on Fe-Ti Oxides: Their Petrologic and Magnetic Significance, held May 24-27, 1991, organized by B.R. Frost, D.H. Lindsley, and SK Banerjee and jointly sponsored by the Mineralogical Society of America and the American Geophysical Union. It has been fourteen and a half years since the last MSA Short Course on Oxide Minerals and the appearance of Volume 3 of Reviews in Mineralogy. Much progress has been made in the interim. This is particularly evident in the coverage of the thermodynamic properties of oxide minerals: nothing in Volume 3, while in contrast, Volume 25 has three chapters (6, 7, and 8) presenting various aspects of the thermodynamics of oxide minerals; and other chapters (9, 11, 12) build extensively on thermodynamic models. The coverage of magnetic properties has also been considerably expanded (Chapters 4, 8, and 14). Finally, the interaction of oxides and silicates is emphasized in Chapters 9, 11, 12, 13, and 14. One of the prime benefits of Reviews in Mineralogy has been that any scientist can afford to have it at his or her fingertips. Because Volume 3 is out of print and will not be readily available to newcomers to our science, as much as possible we have tried to make Volume 25 a replacement for, rather than a supplement to, the earlier volume. Chapters on crystal chemistry, phase equilibria, and oxide minerals in both igneous and metamorphic rocks have been rewritten or extensively revised. The well received photographs of oxide textures in Volume 3 have been collected and expanded into a "Mini-Atlas" In Volume 25. Topics that receive less attention than in the earlier volume are oxides in lunar rocks and meteorites, and the manganese minerals. We hope that the new volume will tum out to be as useful as the previous one was.

Description / Table of Contents: The Mineralogical Society of America sponsored a short course on Contact Metamorphism, October 17-19, 1991, at the Pala Mesa Resort, Fallbrook, California, prior to its annual meeting with the Geological Society of America. As reviewed in Chapter 1, contact aureoles have unique attributes for elucidating the processes and controls of metamorphism. Within the last two decades there has been considerable evolution in our knowledge of metamorphism. This evolution spans a wide range of scales from submicroscopic analysis of grain boundaries through to regional scale analysis of contact metamorphism associated with batholith terrains. Geological sciences is becoming increasingly multidisciplinary in nature. Traditionally, contact aureoles were primarily studied by metamorphic petrologists. Their mapping of isograds and mineral zones in aureoles, coupled with microscopic analysis of the prograde metamorphic evolution of textures, structures and mineralogy, has provided an excellent framework for our understanding of contact metamorphism. However, complete understanding of the processes and controls of contact metamorphism requires a multidisciplinary analysis from a wide range of geological subdisciplines. This volume provides a multidisciplinary review of our current knowledge of contact metamorphism. As in any field of endeavor, we are provided with new questions, thereby dictating future directions of study. Hopefully, this volume will provide inspiration and direction for future research on contact metamorphism.

Description / Table of Contents: This book is written with two goals in mind. The first is to derive the 32 crystallographic point groups, the 14 Bravais lattice types and the 230 crystallographic space group types. The second is to develop the mathematical tools necessary for these derivations in such a manner as to lay the mathematical foundation needed to solve numerous basic problems in crystallography and to avoid extraneous discourses. To demonstrate how these tools can be employed, a large number of examples are solved and problems are given. The book is, by and large, self-contained. In particular, topics usually omitted from the traditional courses in mathematics that are essential to the study of crystallography are discussed. For example, the techniques needed to work in vector spaces with noncartesian bases are developed. Unlike the traditional group-theoretical approach, isomorphism is not the essential ingredient in crystallographic classification schemes. Because alternative classification schemes must be used, the notions of equivalence relations and classes which are fundamental to such schemes are defined, discussed and illustrated. For example, we will find that the classification of the crystallographic space groups into the traditional 230 types is defined in terms of their matrix representations. Therefore, the derivation of these groups from the point groups will be conducted using the 37 distinct matrix groups rather than the 32 point groups they represent. We have been greatly influenced by two beautiful books. Hermann Heyl's book entitled Symmetry based on his lectures at Princeton University gives a wonderful development of the point groups as well as an elegant exposition of symmetry in art and nature. Fredrik W. H. Zachariasen's book entitled Theory of X-ray Diffraction in Crystals presents important insights on the derivation of the Bravais lattice types and the crystallographic space groups. These two books provided the basis for many of the ideas developed in this book. The theorems, examples, definitions and corollaries are labelled sequentially as a group whereas the problems are labelled separately as a group as are the equations. The manner in which these are labelled is self-explanatory. For example, T4.15 refers to Theorem (T) 15 in Chapter 4 while DAl.l refers to Definition (D) 1 in Appendix (A) 1. We have strived to write this book so that it is self-teaching. The reader is encouraged to attempt to solve the examples before appealing to the solution presented and to work all of the problems. Preface to the Revised Edition of Mathematical Crystallography In the Revised Edition we have corrected the errors, misprints and omissions that we have found and our students and other users have kindly pointed out to us. The Revised Edition also includes a more comprehensive index and a set of solutions for all of the problems presented in the book.

Description / Table of Contents: The Mineralogical Society of America (MSA) sponsored a short course by this title December 1990 at the Cathedral Hill Hotel in San Francisco, California. It was organized by the editors, Jim Nicholls and Kelly Russell, and presented by the authors of this volume to about 80 participants in conjunction with the Fall Meeting of the American Geophysical Union. Igneous petrology, in its broadest applications, treats the transfer of matter and energy from planetary interiors to their exteriors. Over the past several decades igneous petrology has gained sophistication in three areas that deal with such transfers: the properties of silicate melts and solids can be estimated as functions of pressure, temperature and composition; some results of experimental and theoretical studies of the physics of multiphase flow are available; and many of the algorithms for realistically modeling magmatic processes are in place. Each of these fields of study, to some extent, have to be pursued independently. In our opinion, now is an ideal time to collect some features of these studies as preparation for more integrated future work and to show some consequences of applying current ideas to the study of igneous processes. We have attempted to bring together the basic data and fundamental theoretical constraints on magmatic processes with applications to specific problems in igneous petrology.

Description / Table of Contents: This is a book exclusively devoted to three minerals: the Al2SiO5 polymorphs - andalusite, sillimanite, and kyanite. This may seem to be narrowly focused and esoteric. However, as discussed in Chapter 1, the aluminum silicate polymorphs are perhaps the most important mineral group to metamorphic petrologists. Because these minerals occur in anatectic migmatites and peraluminous granitoids, they are also important in igneous petrology. In spite of their geologic significance, there are a variety of experimental, theoretical, and field problems involving the aluminum silicates. Theoretical problems include the nature and energetics of lattice defects, order/disorder, crystalline (solid) solution, and interfacial energy. The aluminum silicates epitomize the importance of understanding the mechanisms and kinetics of heterogeneous metamorphic reactions. The difficulties in calibration of the pressure-temperature (P- T) phase equilibrium diagram illustrate the pitfalls of hydrothermal experimentation and the need to understand the methodology and uncertainties of calorimetric measurements of thermodynamic data of minerals. Thus, this book covers a wide variety of topics that must be considered in the analysis of metamorphic systems. In so doing, this volume illustrates the fact that modern metamorphic petrology demands an awareness of a wide spectrum of geologic variables and processes. In concert with the tenor of the Mineralogical Society of America Reviews in Mineralogy series, this volume is intended to provide a comprehensive review, summarizing the methods, theories and pitfalls of the various contributions on the aluminum silicates. Hopefully, this book will provide readers with a reasonably in-depth overview, and thus avoid the need for extensive, independent literature reviews. Although a concerted effort was made to give a balanced coverage of divergent theories regarding various problems involving the aluminum silicates, this critique nevertheless includes some of the author's biases. Several sections of this book present the chronological development of research on various topics, giving readers historical perspectives on the development of theories, models and biases on various problems regarding the aluminum silicates. As in all fields, several landmark studies have set the tone for the strategy of approach to problems. Although such studies have provided important steps forward in our understanding of natural phenomena, they have had the undesirable effect of entrenching biases and methodology. In this volume I have attempted to point out the deleterious effects of certain parochial approaches, an example being the aluminum immobility concept discussed in Chapter 10. In addition to their primary importance in metamorphic petrology, the aluminum silicates illustrate a wide variety of experimental, theoretical, and experimental problems. Because the Al2SiO5 polymorphs alone offer a pedagogic illustration of many important principles of modern metamorphic petrology.

Description / Table of Contents: This book and accompanying MSA short course was first considered in 1987 in response to what seemed to be a growing interest in the chemical reactions that take place at mineral-water interfaces. Now, in 1990, this area of work is firmly established as one of the major directions in mineralogical and geochemical research (see Chapter 1). We believe that there are two major reasons for this. The first is that there is a growing awareness within various earth science disciplines that interface chemistry is very important in many natural processes, i.e., these processes cannot be adequately described, much less understood, unless the role of interface chemistry is carefully considered. Perhaps the best illustration of this increase in awareness is the diverse backgrounds of the scientists who will be attending the short course. Participants have research interests in aqueous and environmental geochemistry, mineralogy, petrology, and crystallography. In the final list of participants, one-quarter are from outside the United States, and include scientists from Australia, Canada, England, France, Israel, The Netherlands, Sweden, and Switzerland. The second reason that this field is one of the major new research directions in the earth sciences is because many methods, both experimental and theoretical, have relatively recently become available to study mineral surfaces and mineral-water interfaces. Many important spectroscopic techniques now used routinely to characterize surfaces and interfaces were not available twenty years ago, and some were not available just five years ago. To emphasize the importance of these methods, two Nobel prizes were awarded in the 1980's to the developers of x-ray photoelectron spectroscopy (XPS) and scanning tunneling microscopy (STM). We have directed ourselves and the other authors of this book to follow the general guidelines of writing for "Reviews in Mineralogy". However, for the subject of mineral-water interface geochemistry, this is not easy because the field is far from mature. Several chapters are not reviews in the traditional sense in that they cover research that is relatively recent for which a considerable amount of work remains. In any case, we believe that this book describes most of the important concepts and contributions that have driven mineral-water interface geochemistry to its present state. We begin in Chapter 1 with examples of the global importance of mineral-water interface reactions and a brief review of the contents of the entire book. Thereafter, we have divided the book into four sections, including atomistic approaches (Chapters 2- 3), adsorption (Chapters 4-8), precipitation and dissolution (Chapters 9-11), and oxidation-reduction reactions (Chapters 11-14).

Description / Table of Contents: This volume of Reviews in Mineralogy attempts to synthesize our present understanding of certain aspects of the mineralogy and chemistry of the rock-forming carbonates. Hopefully, it reflects the presently more active areas of research. This review follows, by ten years, a major assessment of (sedimentary) carbonate minerals by Lippmann (1973). There is only minor overlap of subject material, and I hope that this difference reflects fairly how this field has developed. In some respects carbonates are unique, for they are one of the few mineral groups providing an abundant record of biological, physical, and chemical processes throughout much of geologic time. Because of their relative importance in sedimentary rocks, lowtemperature examples are given more emphasis here. Moreover, the obvious correlation with energy resources has been a significant factor contributing to the current resurgence of interest in this area. However, the broader interest in carbonates is also a reflection of their widespread occurrence in vastly different geologic environments, including metamorphic and igneous settings, as well as an appreciation of their role in both atmospheric and oceanic chemistry, both past and present. In this volume, some of the papers are general (i.e., those addressing crystal chemistry and phase relations), and they provide overviews of a fundamental nature and are of interest to many. Others are more specialized in coverage and generally reflect the different approaches used in carbonate geochemistry. The final chapter introduces transmission electron microscopy, a relatively new and powerful technique for mineralogical research that has great potential in carbonate research. Owing to the short time interval between the completion of manuscripts and publication, much of the newer material in this volume is still "fresh." The various reviewers, all gratefully acknowledged, were expeditious in their efforts. A hurried schedule, however, allows for unnoticed errors to persist; these should be brought to my attention. PREFACE TO THE SECOND PRINTING Interest in carbonate research has continued at an ever-hurried pace since this book was first printed. While the individual chapters could not be revised in this second printing to include the many new findings, a partial listing of noteworthy papers that have since appeared are given in an Appendix at the end of the volume (p. 395-399). These papers are arranged by chapters corresponding roughly to the subject area discussed. In addition, incomplete references from the first printing are listed in this appendix. The assistance of the authors and especially of Paul Ribbe is greatly appreciated.

Description / Table of Contents: Inhalt: 1 Tone und Tongesteine. - 2 Aufbau und Strukturprinzipien der silicatischen Tonminerale. - 3 Systematik der Tonmineralstrukturen. - 4 Tonmineralneubildung und ihre Voraussetzungen. - 5 Spezielle Tonmineralogie. - 6 Spezielle Eigenschaften der silicatischen Tonkomponenten. - 7 Tonminerale in einer anthropogen veränderten Umwelt. - 8 Hinweise zur mineralogischen Untersuchung von Tongesteinen. - Anhang: Zusammensetzung und Eigenschaften wichtiger Tonminerale. - Anmerkungen. - Literatur. - Sachregister

Description / Table of Contents: Die Tonminerale gehören u. a. wegen ihrer hohen Reaktionsempfindlichkeit gegenüber Milieuveränderungen zu den eigentümlichsten Erscheinungen unserer anorganischen Welt. Sie nehmen in einigen Bereichen der gegenwärtigen Umweltproblematik geradezu (nicht immer klar erkannte) Schlüsselpositionen ein - so z. B. bei den Waldschäden. So wurde in diesem Buch versucht, nach einleitenden Betrachtungen zur Verbreitung und Genese von Tongesteinen und neben einer zusammenfassenden Darstellung der heutigen Tonmineralogie, vor allem das Verhalten der Tone und Tonminerale durch Ableitung von ihren Struktureigenschaften auch einem breiteren Interessentenkreis verständlich zu machen.

Description / Table of Contents: Geochemistry is a science that is based on an understanding of chemical processes in the earth. One of the principal tools available to the chemist for understanding systems at equilibrium is thermodynamics. The awareness and application of thermodynamic techniques has increased at a very fast pace in geosciences; in fact, one may be so bold as to say that thermodynamics in geology has reached the "mature" stage, although much future thermodynamic research is certainly needed. However, the natural processes in the earth are often sluggish enough that a particular system may not reach equilibrium. This observation is being supported constantly by new experimental and field data available to the geochemist e.g. the non-applicability of the phase rule in some assemblages, the compositional inhomogeneities of mineral grains, the partial reaction rims surrounding original minerals, the lack of isotopic equilibration or the absence of minerals (e.g. dolomite), which should be present according to thermodynamics. The need to apply kinetics has produced a large number of papers dealing with kinetics in geochemistry. As an initial response to this growing field, a conference on geochemical transport and kinetics was conducted at Airlie House, VA, in 1973, sponsored by the Carnegie Institution of Washington. The papers there dealt with several kinetic topics including diffusion, exsolution, metasomatism and metamorphic layering. Since 1973 the number of kinetic papers has continued to increase greatly. Therefore, the time is ripe for a Short Course in Kinetics, which brings together the fundamentals needed to explain field observations using kinetic data. It is hoped that this book may serve, not only as a reference for researchers dealing with the rates of geochemical processes, but also as a text in courses on geochemical kinetics. One of us has found this need of a text in teaching a graduate course on geochemical kinetics at Harvard and at Penn State during the past several years. Finally, it is our hope that the book may itself further even more research into the rates of geochemical processes and into the quantification of geochemical observations. The book is organized with a rough temperature gradient in mind, i.e. low temperature kinetics at the beginning and igneous kinetics at the end (no prejudices are intended with this scheme!). However, the topics in each chapter are general enough that they can be applied often to any geochemical domain: sedimentary, metamorphic or igneous. The theory of kinetics operates at two complementary levels: the phenomenological and the atomistic. The former relies on macroscopic variables (e.g. temperature or concentrations) to describe the rates of reactions or the rates of transport; the latter relates the rates to the basic forces operating between the particular atomic or molecular species of any system. This book deals with both descriptions of the kinetics of geochemical processes. Chapter one sets the framework for the phenomenological theory of reaction rates. If any geochemical reaction is to be described quantitatively, the rate law must be experimentally obtained in a kinetically sound manner and the reaction mechanism must be understood. This applies to heterogeneous fluid-rock reactions such as those occurring during metamorphism, hydrothermal alteration or weathering as well as to homogeneous reactions. Chapter 2 extends the theory to the global kinetics of geochemical cycles. This enables the kinetic concepts of stability and feedback to be applied to the cycling of elements in the many reservoirs of the earth. Chapter 3 applies the phenomenological treatment of chapter 1 to diagenesis and weathering. The rate of dissolution of minerals as well as the chemical evolution of pore waters are discussed. The atomistic basis of rates of reaction, transition state theory, is introduced in Chapter 4. Transition state theory can be applied to relate the rate constants of geochemical reactions to the atomic processes taking place. This includes not only homogeneous reactions but also reactions that occur at the surface of minerals. Chapter 5 discusses the theory of irreversible thermodynamics and its application to petrology. The use of the second law of thermodynamics along with the expressions for the rate of entropy production in a system have been used successfully since 1935 to describe kinetic phenomena. The chapter applies the concepts to the growth of minerals during metamorphism as well as to the formation of differentiated layers (banding) in petrology. Chapter 6 describes the phenomenological theory of diffusion both in aqueous solutions and in minerals. In particular, the multicomponent nature of diffusion and its consequence in natural systems is elaborated. Chapter 7 provides the atomistic basis for the rates of reactions in minerals. Understanding of the rates of diffusion, conduction, order-disorder reactions or exsolution in minerals depends on proper description of the defects in the various mineral structures. Chapter 8 provides the kinetic theory of crystal nucleation and growth. While many of the concepts in the chapter can be applied to aqueous systems, the emphasis is on igneous processes occurring during crystallization of a melt. To fully understand both the mineral composition as well as the texture of igneous rocks, the processes whereby new crystals form and grow must be quantified by using kinetic theory. Due to space and time limitations (kinetics!) some topics have not been covered in detail. In particular, the mathematical solution of diffusion or conduction equations is discussed very well by Crank in his book, Mathematics of Diffusion, and so is not covered to a great extent here. The treatment of fluid flow (e.g. convection) is also not covered in the text.