ALBERT

Description: Iron oxides compounds constitute an important component of mineral dust aerosol. Several previous studies have shown that these minerals are strong absorbers at visible wavelengths and thus that they play a critical role in the overall climate forcing caused by dust aerosol. When compiling a database of complex refractive indices of possible mineral species of iron-oxides to study their optical properties, we found that uniformly continuous optical constants for a single type of iron-oxides in the wavelength range between 0.2 and 50 μm is very scarce and that the use of hematite to represent all molecular or mineral iron-oxides types is a popular hypothesis. However, the crucial problem is that three continuous datasets for complex refractive indices of hematite are employed in climate models, but there are significant differences between them. Thus, the real role of iron-oxides in the optical properties of dust aerosols becomes a key scientific question, and we address this problem by considering different refractive indices, size distributions, and more logical weight fractions and mixing states of hematite. Based on the microscopic observations, a semi-external mixture that employs an external mixture between Fe-aggregates and other minerals and partly internal mixing between iron-oxides and aluminosilicate particles is advised as the optimal approximation. The simulations demonstrate that hematite with a spectral refractive indices from Longtin et al. (1988) shows approximately equal absorbing capacity to the mineral illite over the whole wavelength region from 0.55 to 2.5 μm, and only enhances the optical absorption of aerosol mixture at λ 〈 0.55 μm. Using the dataset from Querry (1985) may overestimate the optical absorption of hematite at both visible and near-infrared wavelengths. More laboratory measurements of the refractive index of iron-oxides, especially for hematite and goethite in the visible spectrum, should therefore be taken into account when assessing the effect of mineral dust on climate forcing.

Description: Eddy covariance using infrared gas analyses has been a useful tool for gas exchange measurements between soil, vegetation and atmosphere. So far, comparisons between the open- and closed-path eddy covariance (CP) system have been extensively made on CO2 flux estimations, while lacking in the comparison of water vapor flux estimations. In this study, the specific performance of water vapor flux measurements of an open-path eddy covariance (OP) system was compared against a CP system over a tall temperate forest in Northeast China. The results show that the fluxes from the OP system (LEop) were generally greater than the (LEcp though the two systems shared one sonic anemometer. The tube delay of closed-path analyser depended on relative humidity, and the fixed median time lag contributed to a significant underestimation of (LEcp between the forest and atmosphere, while slight systematic overestimation was also found for covariance maximization method with single broad time lag search window. After the optimized time lag compensation was made, the average difference between the 30 min (LEop and (LEcp was generally within 6%. Integrated over the annual cycle, the CP system yielded a 5.1% underestimation of forest evapotranspiration as compared to the OP system measurements (493 vs. 469 mm yr−1). This study indicates the importance to estimate the sampling tube delay accurately for water vapor flux calculations with closed-path analysers, and it also suggests that when discuss the energy balance closure problem in flux sites with closed-path eddy covariance systems, it has to be aware that some of the imbalance is possibly caused by the systematic underestimation of water vapor fluxes.

Description: This study investigates the effects of the total solar eclipse of 22 July 2009 on surface ozone and other photo-oxidants over China. A box model was used to study the sensitivity of ozone to the limb darkening effect during an eclipse event, and to show that the impact on ozone is small (less than 0.5 %). In addition, the regional model WRF-Chem was applied to study the effects of the eclipse on meteorological and chemical parameters, focusing on different regions in China. Chemical and meteorological observations were used to validate the model and to show that it can capture the effects of the total solar eclipse well. Model calculations show distinct differences in the spatial distributions of meteorological and chemical parameters with and without the eclipse. The maximum impacts of the eclipse occur over the area of totality, where there is a decrease in surface temperature of 1.5 °C and decrease in wind speed of 1 m s−1. The maximum impacts on atmospheric pollutants occur over parts of north and east China where emissions are greater, with an increase of 5 ppbv in NO2 and 25 ppbv in CO and a decrease of 10 ppbv in O3 and 4 ppbv in NO. This study also demonstrates the effects of the solar eclipse on surface photo-oxidants in different parts of China. Although the sun was obscured to a smaller extent in polluted areas than in clean areas, the impacts of the eclipse in polluted areas are greater and last longer than they do in clean areas. In contrast, the change in radical concentrations (OH, HO2 and NO3) in clean areas is much larger than in polluted areas mainly because of the limited source of radicals in these areas. The change in radical concentrations during the eclipse reveals that nighttime chemistry dominates in both clean and polluted areas. As solar eclipses provide a natural opportunity to test more thoroughly our understanding of atmospheric chemistry, especially that governed by photolysis, a comprehensive experimental campaign during a future solar eclipse is highly desirable.

Description: No hurricane is detected in the tropics off the Brazilian coast due to the lack of initial conditions (e.g., the weak vertical shear of horizontal wind) despite that high sea surface temperature is available. According to previous studies, the initial conditions (as the ingredients of hurricane's embryo) are related so that the thick warm-and-moist layer (due to the updraft vapour) below a cold-and-dry layer frames the convective instability which enhances diabatic processes accompanied by tropical cyclones with the weak vertical shear. So the basic question is how, starting with an internal-disturbance-free balance-situation, external forces create the rapidly-upward acceleration of moist air at the warm sea surface. The answer is revealed by the vertical-momentum equation which shows that boosted by the external-force-induced significant lower-layer equatorial westerly wind (LLEWW), the upward (unit-mass) acceleration could be as significant as the midlatitude Coriolis force. Besides creating cyclonic vortices through the upward acceleration and diabatic processes, the external-force-induced significant-LLEWW could directly create cyclonic wind shears along with easterly jets for the low-level cyclonic vorticity through reducing the peak value of zonally-homogeneous trade easterlies (centered at the Equator between the Northern and Southern Hemisphere subtropical high-belts). We emphasize external forces to avoid the ''chicken-and-egg'' problem accompanying nonlinear interactions of internal-forcing processes. The external-force-induced significant-LLEWW could result from the deflection of the cross-equatorial flow characterized by the seasonal shift coincident with that of locations of most embryos. This significant cross-equatorial flow is driven by the significant differential heating between the largest continent with the highest plateau and the largest ocean with the warm pool located to the east and on the equatorward side of the continent on the rotating Earth. Unfortunately, in the tropics off the Brazilian coast, the differential heating is weak between the relatively-small ocean and land mostly covered by tropical rainforest. No significant-LLEWW means no hurricane's embryo. A warm spawning ground without the embryo means no hurricane. Our investigation suggests that the external-force-induced significant-LLEWW embedded in the significant trade easterlies over the warm ocean be necessary and sufficient for making the embryo originate in an internal-disturbance-free balance-situation.

Description: Seasonal and spatial variations in foliar nitrogen (N) parameters were investigated in three European forests with different tree species, viz. beech (Fagus sylvatica L.), Douglas fir (Pseudotsuga menziesii, Mirb., Franco) and Scots pine (Pinus sylvestris L.) in Denmark, The Netherlands and Finland, respectively. This was done in order to obtain information about functional acclimation, tree internal N conservation and its relevance for both ecosystem internal N cycling and foliar N exchange with the atmosphere. Leaf N pools generally showed much higher seasonal variability in beech trees than in the coniferous canopies. The concentrations of N and chlorophyll in the beech leaves were synchronized with the seasonal course of solar radiation implying close physiological acclimation, which was not observed in the coniferous needles. During phases of intensive N metabolism in the beech leaves, the NH4+ concentration rose considerably. This was compensated for by a strong pH decrease resulting in relatively low Γ values (ratio between tissue NH4+ and H+). The Γ values in the coniferous were even smaller than in beech, indicating low probability of NH3 emissions from the foliage to the atmosphere as an N conserving mechanism. The reduction in foliage N content during senescence was interpreted as N re-translocation from the senescing leaves into the rest of the trees. The N re-translocation efficiency (ηr) ranged from 37 to 70% and decreased with the time necessary for full renewal of the canopy foliage. Comparison with literature data from in total 23 tree species showed a general tendency for ηr to on average be reduced by 8% per year the canopy stays longer, i.e. with each additional year it takes for canopy renewal. The boreal pine site returned the lowest amount of N via foliage litter to the soil, while the temperate Douglas fir stand which had the largest peak canopy N content and the lowestηr returned the highest amount of N to the soil. These results support the hypothesis that a high N status, e.g. as a consequence of chronically high atmospheric N inputs, increases ecosystem internal over tree-bulk-tissue internal N cycling in conifer stands. The two evergreen tree species investigated in the present study behaved very differently in all relevant parameters, i.e. needle longevity, Nc and ηr, showing that generalisations on tree internal vs. ecosystem internal N cycling cannot be made on the basis of the leaf habit alone.

Description: The effects of naturally acidified seawater on a snail species, Anachis misera (Family: Columbellidae) were quantified in five shallow vent-based environments off Kueishan Islet, Taiwan. An absence of Anachis snails was observed in the most acidic North site (pH 7.22), and the size structure differed among the remaining East, South, Southwest and Northwest sites. If a positive correlation between shell length and shell width or total weight existed, the coefficient of determination (R2) of the equations was low, i.e., 0.207–0.444. Snails from the Northwest site (pH 7.33) exhibited a more globular shape than those of the South ones (pH 7.80). Standardized shell thickness T1 (thickness of body whorl : shell length) and T2 (thickness of penultimate whorl : shell length) from the Northwest site showed a decrease of 6.3 and 9.4%, respectively, compared to the South ones. In a similar vein, based on the 16 examined protein spots, protein expression profiles of snails in the South were distinct. With further characterization by principle component analysis, the separation was mainly contributed by the first (i.e., spots 8, 1, 15, and 12) and second (i.e., spots 15, 13, 12, 1, and 11) principal-components. As a whole, the shallow vent-based findings provide new information from subtropics on the effects of ocean acidification on gastropod snails in natural environments.

Description: Tea fields emit large amounts of nitrous oxide (N2O) to the atmosphere. Obtaining accurate estimations of N2O emissions from tea-planted soils is challenging due to strong spatial variability. We examined the spatial variability of N2O emissions from a red-soil tea field in Hunan province, China, on 22 April 2012 (in a wet season) using 147 static mini chambers approximately regular gridded in a 4.0 ha tea field. The N2O fluxes for a 30 min snapshot (10–10.30 a.m.) ranged from −1.73 to 1659.11 g N ha−1 d−1 and were positively skewed with an average flux of 102.24 g N ha−1 d−1. The N2O flux data were transformed to a normal distribution by using a logit function. The geostatistical analyses of our data indicated that the logit-transformed N2O fluxes (FLUX30t) exhibited strong spatial autocorrelation, which was characterized by an exponential semivariogram model with an effective range of 25.2 m. As observed in the wet season, the logit-transformed soil ammonium-N (NH4Nt), soil nitrate-N (NO3Nt), soil organic carbon (SOCt), total soil nitrogen (TSNt) were all found to be significantly correlated with FLUX30t (r=0.57–0.71, p

Description: Excessive groundwater withdrawal can cause land subsidence and earth fissures. The initiation and propagation of earth fissures are related to tensile failure and crack propagation in soils. Based on fracture mechanics, the crack band model (CBM), one of the smear crack models which is relatively easy to construct and convenient to be integrated into standard finite element codes is used in this paper. The calculated results of CBM are less dependent on the sizes of finite elements. The model was applied to simulate the formation and propagation of earth fissures in the hydrostratigraphic units with a bedrock ridge. The simulated positions and patterns of earth fissures coincide with field observations, suggesting that the modeling approach is adept to simulate the initiation and propagation of earth fissures due to groundwater withdrawal.

Description: The Suzhou-Wuxi-Changzhou (known as "Su-Xi-Chang") area, located in the southern part of Jiangsu Province, China, experienced serious land subsidence caused by overly exploitation of groundwater. The largest cumulative land subsidence has reached 3 m. With the rapid progress of land subsidence since the late 1980s, more than 20 earth fissures developed in Su-Xi-Chang area, although no pre-existing faults have been detected in the surroundings. The mechanisms of earth fissure generation associated with excessive groundwater pumping are: (i) differential land subsidence, (ii) differences in the thickness of the aquifer system, and (iii) bedrock ridges and cliffs at relatively shallow depths. In this study, the Guangming Village Earth Fissures in Wuxi area are selected as a case study to discuss in details the mechanisms of fissure generation. Aquifer exploitation resulted in a drop of groundwater head at a rate of 5–6 m yr−1 in the 1990s, with a cumulative drawdown of 40 m. The first earth fissure at Guangming Village was observed in 1998. The earth fissures, which developed in a zone characterized by a cumulative land subsidence of approximately 800 mm, are located at the flank of a main subsidence bowl with differential subsidence ranging from 0 to 1600 mm in 2001. The maximum differential subsidence rate amounts to 5 mm yr−1 between the two sides of the fissures. The fissure openings range from 30 to 80 mm, with a cumulative length of 1000 m. Depth of bed rock changes from 60 to 140 m across the earth fissure. The causes of earth fissure generation at Guangming Village includes a decrease in groundwater levels, differences in the thickness of aquifer system, shallow depths of bedrock ridges and cliffs, and subsequent differential land subsidence.

Description: Disaster damages have negative effects on economy, whereas reconstruction investments have positive effects. The aim of this study is to model economic causes of disasters and recovery involving positive effects of reconstruction activities. Computable general equilibrium (CGE) model is a promising approach because it can incorporate these two kinds of shocks into a unified framework and further avoid double-counting problem. In order to factor both shocks in CGE model, direct loss is set as the amount of capital stock reduced on supply side of economy; A portion of investments restore the capital stock in existing period; An investment-driven dynamic model is formulated due to available reconstruction data, and the rest of a given country's saving is set as an endogenous variable. The 2008 Wenchuan Earthquake is selected as a case study to illustrate the model, and three scenarios are constructed: S0 (no disaster occurs), S1 (disaster occurs with reconstruction investment) and S2 (disaster occurs without reconstruction investment). S0 is taken as business as usual, and the differences between S1 and S0 and that between S2 and S0 can be interpreted as economic losses including reconstruction and excluding reconstruction respectively. The study showed that output from S1 is found to be closer to real data than that from S2. S2 overestimates economic loss by roughly two times that under S1. The gap in economic aggregate between S1 and S0 is reduced to 3% in 2011, a level that should take another four years to achieve under S2.