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  • 1
    Electronic Resource
    Electronic Resource
    Stamford, Conn. [u.a.] : Wiley-Blackwell
    Polymer Engineering and Science 35 (1995), S. 190-194 
    ISSN: 0032-3888
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: The block copolyetheresters with hard segments of poly(butylene terephthalate) and soft segments of poly(tetramethylene ether) were prepared by a terephthalic acid (TPA) process in the presence of some salts. The preparations of a block copolyetherester under various conditions were first studied in a 1 L stainless steel reactor to find the best method. Then, the preparations of four block copolyetheresters were run in a pilot plant comprising a 200 L polyesterification reactor and a 200 L polymerization reactor under the suitable condition. The presence of some salts reduced the formation of tetrahydrofuran (THF), and also reduced the total reaction time in the pilot plant. The thermal properties and various mechanical properties of the block copolytheresters prepared by the pilot plant were investigated to evaluate the feasibility of this method.
    Additional Material: 4 Ill.
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  • 2
    Electronic Resource
    Electronic Resource
    Stamford, Conn. [u.a.] : Wiley-Blackwell
    Polymer Engineering and Science 32 (1992), S. 792-803 
    ISSN: 0032-3888
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: The J-integral method to determine the fracture toughness of tough and ductile polymeric materials previously developed has been applied to the elastomer-modified polycarbonates. This investigation compares three different methods to obtain Jc: the conventional crack growth length, the stress whitening zone, and the newly developed hysteresis method. Jc values obtained from these three comparative methods are fairly close. The hysteresis method has the advantage over the other two methods of obtaining Jc without requiring the measurement of the crack growth length or the stress whitening zone, therefore avoiding the controversy in defining crack blunting. Results also indicate that the effect of elastomer quantity in polycarbonate on Jc is insignificant as long as the crack is in a stable condition. Higher elastomer contents in polycarbonate result in higher dJ/dΔa, dJ/dΔl, and tearing modulus (Tm). This indicates that the elastomer toughening mechanism is due to the increase of the energy required for crack growth extension. The hysteresis loss energy is directly related to the size of the crack tip plastic zone, and the presence of more elastomer indeed increases the crack tip plastic zone, thus making the polycarbonate tougher. Besides, the presence of elastomer tends to increase the crack initiation displacement and shift the failure modes from an unstable fracture. Jc and the criterion for crack initiation based on rate change of hysteresis energy are discussed in detail.
    Additional Material: 19 Ill.
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  • 3
    Electronic Resource
    Electronic Resource
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 43 (1997), S. 1325-1330 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: The effectiveness of applying silent discharge plasmas (SDP) for destroying and removing volatile organic compounds (VOCs) from gas streams is experimentally evaluated with a laboratory-scale reactor. The VOCs selected for study include toluene and methyl ethyl ketone (MEK). Direct collision with energetic electrons and reaction with generated gas-phase radicals are two major mechanisms responsible for destruction and removal of VOCs from gas streams. Operating parameters investigated include applied voltage, gas residence time, and temperature and composition of the gas stream. Experimental results indicate that the removal efficiency of toluene and MEK achieved with SDP can be enhanced by operating the system at a higher gas temperature and applied voltage due to the generation of more energetic electrons and radicals. O2 is essential for removing VOCs from gas streams with SDP. More than 80% removal efficiencies were achieved with this system for both toluene and MEK. SDP can potentially serve as an alternative control technology for removing VOCs from gas streams.
    Additional Material: 9 Ill.
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  • 4
    Electronic Resource
    Electronic Resource
    Stamford, Conn. [u.a.] : Wiley-Blackwell
    Polymer Engineering and Science 35 (1995), S. 1433-1439 
    ISSN: 0032-3888
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: The fracture toughness of acrylonitrile-butadiene-styrene (ABS) was determined by three J-integral methods, ASTM E813-81, E813-87, and by hysteresis. The critical J values (J1c) obtained are fairly independent of the specimen thickness, ranging from 10 to 15 mm. ASTM E813-81 and hysteresis methods result in comparable J1c values, whereas the ASTM E813-87 was ∼40% to 50% higher. The critical displacement determined from the plots of hysteresis (energy or ratio) and the true crack grow length vs. displacement are close. This indicates the critical displacement determined by the hysteresis method is indeed the displacement at onset of crack initiation, and the corresponding J1c represents a physical event of crack initiation. The elastic storage energy. The input energy minus the hysteresis energy, is the most important factor in determining the onset of crack initiation. The critical elastic storage energy (at the beginning of crack growth) was found close to the J1c obtained from the E813-81 or the hysteresis method.
    Additional Material: 9 Ill.
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  • 5
    Electronic Resource
    Electronic Resource
    Brookfield, Conn. : Wiley-Blackwell
    Polymer Composites 13 (1992), S. 448-453 
    ISSN: 0272-8397
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Notes: The hygrothermal behavior of carbon fiber-reinforced poly(ether ether ketone) (PEEK) and poly(phenylene sulfide) (PPS) composites subjected to moisture and temperature is investigated in this study. The properties of both composites exposed to temperature/humidity and immersed in water for extended periods are studied. Properties studied include moisture sorption, crystallinity, dynamic mechanical response, tensile strength, and flexural strength. Both the PEEK/C.F. and the PPS/C.F. composites exhibit good moisture/temperature resistance and property retention after hygrothermal exposure. The diffusivities and the equilibrium moisture absorption are measured at 60, 70, 80°C with 85% R.H. (relative humidity). A Fickian type diffusion is observed at all exposures. Crystallinity increase of the composites is found for the PPS/C.F. composites exposed to 80°C with 85% R.H. environment and is correlated with the damping properties in the dynamic mechanical study. However, the hygrothermal effect on the crystallinity and the glass transition temperature of the PEEK/C.F. composites is negligible. Mechanical properties of the PEEK/C.F. composites decrease slightly with the increase of temperature/moisture and exposure period. Mechanical property reductions of the PPS/C.F. composites decrease with the increase in exposure temperature when subjected to a similar environment; this is due to the relatively complete molecular relaxation and additional crystallization at higher temperatures.
    Additional Material: 9 Ill.
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  • 6
    ISSN: 0272-8397
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Notes: The effect of physical aging on the penetration impact toughness and Mode I interlaminar fracture toughness of continuous carbon fiber (C.F.) reinforced poly(ether ether ketone) (PEEK) and poly(phenylene sulfide) (PPS) composites has been investigated by using an instrumented falling weight impact (IFWI) technique and a double cantilever beam (DCB) test. Composite materials studied are aged below their glass transition temperature (Tg) at various periods. Initiation force and energy of damage, failure propagation energy, impact energy and ductility index (D.I.) are reported. The Mode I critical value of strain energy release rate (GIC) of the unidirectional carbon fiber-reinforced PEEK (APC-2) composites is obtained. Results show that aging has a significant effect on the toughness of both composite materials. Energy absorbed during impact decreases with the increase of aging temperature and period. The PEEK/C.F. composites exhibit a higher retention of impact toughness than that of the PPS/C.F. composites after aging; however, the PPS/C.F. composites show a much higher ductility index. The Mode I fracture mechanism of the APC-2 composite is a combination of stable and unstable failure and shows a “stick-slip” behavior. Owing to the formation of a relative rigid structure, the fracture toughness (GIC) of APC-2 decreased with the increase of aging temperature and period.
    Additional Material: 13 Ill.
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  • 7
    Electronic Resource
    Electronic Resource
    Stamford, Conn. [u.a.] : Wiley-Blackwell
    Polymer Engineering and Science 10 (1970), S. 364-368 
    ISSN: 0032-3888
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: A diffusional model was established to study the kinetics of thermally-induced solid state polycondensation of poly(ethylene terephthalate). Diffusion through solid polymer is the rate controlling step when temperature is higher than 210°C and particle size is no smaller than 100 mesh. The activation energy is 30 Kcal/g mole. In polymerizing powders (20-200 mesh), the crystallinity of prepolymer and its changes during the polymerization affect the diffusivity and thus the polymerization rate. The diffusivity was found to be linearly proportional to the mass fraction of the amorphous phase in PET polymer.
    Additional Material: 6 Ill.
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  • 8
    Electronic Resource
    Electronic Resource
    Stamford, Conn. [u.a.] : Wiley-Blackwell
    Polymer Engineering and Science 16 (1976), S. 697-705 
    ISSN: 0032-3888
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: Multilayer flat film coextrusion was studied, both experimentally and theoretically. For the experimental study, a sheet-forming die with a feedblock was designed, and plastic films of three and five layers were coextruded. The die was provided with three pressure transducers in the axial direction in order to determine the pressure gradient in the die, allowing the determination of the reduction in pressure drop when different combinations of two polymer melts were coextruded. Polymers used for coextrusion were: (1) low density polyethylene and ethylene-vinyl acetate; (2) low density-polyethylene and high density polyethylene; (3) low density polyethylene and polystyrene. For the theoretical study, the z-component of the equations of motion for steady fully-developed flow were solved using a power law non-Newtonian model, Comparisons were made between the experimental and the theoretically predicted volumetric flow rates. Predictions of the velocity distributions, shear rate profiles, and shear stress distributions were made as functions of the processing conditions and the rheological properties of the individual polymers concerned.
    Additional Material: 14 Ill.
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  • 9
    Electronic Resource
    Electronic Resource
    Stamford, Conn. [u.a.] : Wiley-Blackwell
    Polymer Engineering and Science 21 (1981), S. 69-75 
    ISSN: 0032-3888
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: An experimental and theoretical study was carried out to achieve a better understanding of bubble dynamics in foam extrusion through a converging die. For the experimental study, a number of converging channels were constructed of aluminum, with glass windows on both sides. Bubble dynamics in the flow channel were recorded on movie film as a gas-charged molten polymer was extruded. The dies had various converging angles (30, 45, 60, 90, and 150 degrees), and the polymer was polystyrene. As blowing agent, sodium bicarbonate (generating CO2) was used. It was found that the gas bubbles moving along the centerline of the channel grow initially at the upstream end of the die, and then start to collapse as the gas-charged molten polymer approaches the exit plane of the die. In order to help interpret the experimental results, a theoretical analysis was made of bubble dynamics in a converging channel, in which a thread-like bubble was assumed to flow along the centerline of the converging channel and the Coleman-Noll second-order fluid model was assumed to describe the rheological behavior of the polymer melt. Some mathematically convenient simplifying assumptions not-withstanding, the theoretical analysis corroborates the experimental observations. The practical significance of the present investigation is discussed in connection with controlling the cell structure in extruded foam products.
    Additional Material: 12 Ill.
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  • 10
    Electronic Resource
    Electronic Resource
    Stamford, Conn. [u.a.] : Wiley-Blackwell
    Polymer Engineering and Science 22 (1982), S. 234-240 
    ISSN: 0032-3888
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: An investigation was conducted to establish property-morphology relationships in polymethylmethacrylate/polyvinylidenefluoride (PMMA/PVDF) blends. All blends were compounded in a twin-screw extruder and then processed by injection molding Mechanical properties of blends of various compositions were studied by dynamic mechanical and impact strength measurements. The presence of crystalline regions in blends was determined by Differential Scanning Calorimetry (DSC). Morphology of fracture surfaces of blends was studied by Spinning Electron Microscopy (SEM). PMMA/PVDF blends were found to form compatible mixtures over a wide range of blend composition. Changes in dynamic mechanical properties upon annealing were found to be a direct function of blond morphology. Electron microscopic evidence showed no signs of phase separation. DSC measurements detected crystalline regions in all blends containing 40 percent or more (by weight) PVDF.
    Additional Material: 12 Ill.
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