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  • 1
    Electronic Resource
    Electronic Resource
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 21 (1975), S. 449-465 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: A theoretical study was carried out for the analysis of the high pressure polyethylene tubular reactor with axial mixing (TRAM). In the study, the Contraction Mapping Theorem in the square-integrable function space L2[0, 1] was first used to derive a uniqueness criterion for the existence of the steady state solution of the polyethylene TRAM. Then, an algorithm was derived which enabled us to compute the profiles of reactor temperature and concentration. Details of reactor performance were investigated in terms of the reactor operating and design variables: heat transfer coefficient, feed temperature and concentration, axial mixing, the length of reactor, and the distribution of preheating and cooling zones of the reactor. Also investigated in this study was the product quality in terms of the number-average molecular weight and molecular weight distribution as affected by change in reactor operating conditions and by the chain transfer reactions.
    Additional Material: 8 Ill.
    Type of Medium: Electronic Resource
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  • 2
    Electronic Resource
    Electronic Resource
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 25 (1979), S. 87-100 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: The operation of two arrangements of multistage adsorption beds, parallel and series, was analyzed, and the optimal design problem of minimizing the capital and operating costs of the multistage adsorption bed systems was formulated. Solution of the optimization problem was obtained by using the Fibonacci search scheme. For the purpose of the study, data on the adsorption of liquid on activated carbon were taken from the literature for both single solute and multisolute adsorption systems and was used to derive the expressions for adsorption rate and the equilibrium relationship. Details of the performance of the optimally designed multistage adsorption bed systems are presented in terms of the physical and design parameters.
    Additional Material: 18 Ill.
    Type of Medium: Electronic Resource
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  • 3
    Electronic Resource
    Electronic Resource
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 23 (1977), S. 558-567 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: A general flow model is developed which is discrete both in time and space. The stirred-tank network model (continuous time compartmental model) is summarized and compared with the discrete flow model. Efficient methods for model fitting are given and demonstrated with numerical examples.
    Additional Material: 4 Ill.
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  • 4
    Electronic Resource
    Electronic Resource
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 24 (1978), S. 559-560 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Type of Medium: Electronic Resource
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  • 5
    Electronic Resource
    Electronic Resource
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 23 (1977), S. 958-958 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Type of Medium: Electronic Resource
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  • 6
    Electronic Resource
    Electronic Resource
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 24 (1978), S. 1046-1054 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: The influence of combined forced and free convection on the performance of a reverse osmosis system in a horizontal circular pipe is examined. The free convective motion, which is superimposed upon the main axial flow, is caused by buoyancy forces arising from the buildup of a dense solute boundary layer near the membrane surface. The three-dimensional convective diffusion problem is solved by dividing it into a perturbation part accounting for the buoyancy effects present for Ra ≠ 0 and a nonperturbation part for the intrinsic convective flow pattern present even when Ra = 0.An approximate solution to the nonperturbation equations is obtained from the literature, and the perturbation equations are solved using a stream function-vorticity scheme valid for high Schmidt numbers. The effects of rejection parameter, Rayleigh number, and pressure parameter on the Sherwood number and concentration polarization are studied. Correlations are developed for the asymptotic Sherwood number and the effective axial length at which free convection becomes significant. The numerical results are in reasonable agreement with limiting analytical solutions and with the experimental asymptotic Sherwood numbers measured by Derzansky and Gill (1974) and Hsieh et al. (1976).
    Additional Material: 9 Ill.
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  • 7
    Electronic Resource
    Electronic Resource
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 22 (1976), S. 252-259 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: The influence of combined forced and free convection on the surface reaction of a laminarly flowing species in a rectangular channel is studied. The free convective motion, which is superimposed upon the main axial flow, arises from a transverse density gradient produced by the release of a reaction product, or heat, at the channel wall. A numerical stream function-vorticity method is employed to solve the three-dimensional conservation equations in the case of large Schmidt number. Effects of aspect ratio, diffusivity ratio, surface reaction rate, and Rayleigh number upon the overall reactant conversion rate and local Sherwood number are examined. Reasonable agreement is obtained with experimental data for a hydrochloric acid-calcium carbonate surface reaction.
    Additional Material: 9 Ill.
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  • 8
    Electronic Resource
    Electronic Resource
    Stamford, Conn. [u.a.] : Wiley-Blackwell
    Polymer Engineering and Science 16 (1976), S. 697-705 
    ISSN: 0032-3888
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: Multilayer flat film coextrusion was studied, both experimentally and theoretically. For the experimental study, a sheet-forming die with a feedblock was designed, and plastic films of three and five layers were coextruded. The die was provided with three pressure transducers in the axial direction in order to determine the pressure gradient in the die, allowing the determination of the reduction in pressure drop when different combinations of two polymer melts were coextruded. Polymers used for coextrusion were: (1) low density polyethylene and ethylene-vinyl acetate; (2) low density-polyethylene and high density polyethylene; (3) low density polyethylene and polystyrene. For the theoretical study, the z-component of the equations of motion for steady fully-developed flow were solved using a power law non-Newtonian model, Comparisons were made between the experimental and the theoretically predicted volumetric flow rates. Predictions of the velocity distributions, shear rate profiles, and shear stress distributions were made as functions of the processing conditions and the rheological properties of the individual polymers concerned.
    Additional Material: 14 Ill.
    Type of Medium: Electronic Resource
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  • 9
    Electronic Resource
    Electronic Resource
    Stamford, Conn. [u.a.] : Wiley-Blackwell
    Polymer Engineering and Science 18 (1978), S. 180-186 
    ISSN: 0032-3888
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: An experimental study was carried out to investigate the phenomenon of interfacial instability in multilayer flat-film coextrusion. For the study, a sheet-forming die with a feed block was used to coextrude three-and five-layer flat films. Polymers coextruded were: (a) low-density polyethylene with polystyrene, and (b) high-density polyethylene with polystyrene. It was observed that, for a given polymer system, there is a critical value of wall shear stress at which an irregular (i.e., unstable) interface between the layers sets in, giving rise to a pattern similar to that usually found in a wood panel. Once the instability sets in, the severity of interfacial instability is found to depend on both the total volumetric flow rate (hence wall shear stress) of the combined streams and the ratio of the individual layer thicknesses. An attempt is made to correlate the critical conditions for the onset of interfacial instability in terms of the layer thickness ratio, and the viscosity and elasticity ratios of the two polymers being coextruded.
    Additional Material: 17 Ill.
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  • 10
    Electronic Resource
    Electronic Resource
    Stamford, Conn. [u.a.] : Wiley-Blackwell
    Polymer Engineering and Science 18 (1978), S. 187-199 
    ISSN: 0032-3888
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: Multilayer blown film coextrusion was studied, both experimentally and theoretically. For the experimental study, an annular die with a feed-port system was designed and multilayer blown films were produced by rotating the inner mandrel with a one horsepower variable-speed drive at speeds from nearly 2 to 6 rpm, and by inflating the tubular molten film with air. The die has 16 feed slots and melt pressure transducers are mounted along the axial direction of the outer wall of the annular flow channel. The transducers were used to determine the pressure gradient in the annular flow channel, which then permitted determination of the reduction in pressure drop when different combinations of two polymer systems were coextruded. Polymers used for b own film coextrusion were: (1) low-density polyethylene with ethylene-vinyl acetate; (2) low-density polyethylene with high-density polyethylene; (3) low-density polyethylene with polypropylene; (4) high-density polyethylene with ethylene-vinyl acetate. For the theoretical study, stratified helical flow was analyzed using a power-law non-Newtonian model. A computational procedure was developed to predict the number of layers, layer thickness, and the volumetric flow rate as functions of certain processing variables (namely, the pressure drop in the die, and the angular speed of rotation of the inner mandrel of the die) and the rheological parameters of the individual polymers concerned. Comparison was made of the theoretical prediction of volumetric flow rate with experimental ones. Some representative results are presented of the theoretically predicted axial and angular velocity distributions, shear stress profiles, and shear rate profiles.
    Additional Material: 26 Ill.
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