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  • 1
    Electronic Resource
    Electronic Resource
    Thermodynamic behavior of mixtures of methane and ethane in the critical region (1993)
    Springer
    International journal of thermophysics 14 (1993), S. 1187-1200 
    Details
    ISSN: 1572-9567
    Keywords: binary mixtures ; critical phenomena ; equation of state ; ethane ; methane ; plait point ; specific heat
    Source: Springer Online Journal Archives 1860-2000
    Topics: Physics
    Notes: Abstract An isomorphic equation of state for near-critical binary mixtures is used to represent equation of state and specific heat data for mixtures of methane and ethane in a substantial range of densities and temperatures around the critical line.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1007/BF00503681
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  • 2
    Electronic Resource
    Electronic Resource
    An improved parametric crossover model for the thermodynamic properties of fluids in the critical region (1993)
    Springer
    International journal of thermophysics 14 (1993), S. 1-32 
    Details
    ISSN: 1572-9567
    Keywords: critical phenomena ; equation of state ; ethane ; methane ; sound velocity ; specific heat ; thermodynamic properties
    Source: Springer Online Journal Archives 1860-2000
    Topics: Physics
    Notes: Abstract An improved parametric equation for the thermodynamic properties of fluids is presented that incorporates the crossover from singular thermodynamic behavior in the immediate vicinity of the critical point to regular thermodynamic behavior far away from the critical point. Based on a comparison with experimental data for ethane and methane, it is demonstrated that the crossover model is capable of representing the thermodynamic properties of fluids in a large range of temperatures and densities around the critical point.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1007/BF00522658
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  • 3
    Electronic Resource
    Electronic Resource
    Scaled equation for the isochoric heat capacity of methane-ethane mixtures in the critical region (1988)
    Springer
    International journal of thermophysics 9 (1988), S. 453-464 
    Details
    ISSN: 1572-9567
    Keywords: critical phenomena ; ethane ; heat capacity ; methane ; mixtures
    Source: Springer Online Journal Archives 1860-2000
    Topics: Physics
    Notes: Abstract Results of an experimental study of the isochotic heat capacity of methaneethane mixtures in a wide region around the liquid-gas critical line are presented. The data are represented by a universal scaled equation for critical mixtures.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1007/BF00513083
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  • 4
    Electronic Resource
    Electronic Resource
    Thermodynamic behavior of mixtures of methane and ethane in the critical region (1993)
    Springer
    International journal of thermophysics 14 (1993), S. 1187-1200 
    Details
    ISSN: 1572-9567
    Keywords: binary mixtures ; critical phenomena ; equation of state ; ethane ; methane ; plait point ; specific heat
    Source: Springer Online Journal Archives 1860-2000
    Topics: Physics
    Notes: Abstract An isomorphic equation of state for near-critical binary mixtures is used to represent equation of state and specific heat data for mixtures of methane and ethane in a substantial range of densities and temperatures around the critical line.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1007/BF02431283
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  • 5
    Electronic Resource
    Electronic Resource
    Crossover equation of state for the thermodynamic properties of mixtures of methane and ethane in the critical region (1996)
    Springer
    International journal of thermophysics 17 (1996), S. 909-944 
    Details
    ISSN: 1572-9567
    Keywords: critical phenomena ; equation of state ; ethane ; methane ; plait point ; thermodynamic properties
    Source: Springer Online Journal Archives 1860-2000
    Topics: Physics
    Notes: Abstract We present an equation of state for the thermodynamic properties of mixtures of methane and ethane in the critical region that incorporates the crossover from singular thermodynamic behavior near the locus of vapor-liquid critical points to regular thermodynamic behavior outside the critical region. The equation of state yields a satisfactory representation of the thermodynamic-property data for the mixtures in a large range of temperatures and densities.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1007/BF01439196
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  • 6
    Electronic Resource
    Electronic Resource
    Gas chromatographic study of adsorption of nitrogen-containing organic compounds on graphitized thermal carbon black (1981)
    Springer
    Chromatographia 14 (1981), S. 478-483 
    Details
    ISSN: 1612-1112
    Keywords: Gas-solid chromatography ; Graphitized thermal carbon black ; Thermodynamics of adsorption ; Nitrogen compounds
    Source: Springer Online Journal Archives 1860-2000
    Topics: Chemistry and Pharmacology
    Notes: Summary To study the role of the nitrogen atom in various valence states in the adsorption of nitrogen-containing molecules on the surface of hydrogen-treated graphitized thermal carbon black (HGTCB) gas chromatography was applied to determine the thermodynamic characteristics of adsorption: Henry's constants and heats of adsorption at zero surface coverage of nitriles, amines and indols on HGTCB. Adsorption characteristics of nitrogen-containing organic compounds and corresponding hydrocarbons are compared. It is shown that the logarithm of the retention volume and the heat of adsorption of n-alkylamines and n-alkylnitriles linearly depend on the number of carbon atoms in the molecule and on the average polarisability of the molecule. Relationship has been established between the Henry's constant as well as the heat of adsorption and the geometry of the molecule's disposition on HGTCB surface. Examples are given for the separation of a number of amines on the basis of the geometry of their molecules.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1007/BF02263538
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  • 7
    Electronic Resource
    Electronic Resource
    Chromatographic measurements and molecular statistical calculations of thermodynamic characteristics of adsorption of aromatic and polycyclic hydrocarbons on graphitized thermal carbon black (1979)
    Springer
    Chromatographia 12 (1979), S. 799-802 
    Details
    ISSN: 1612-1112
    Keywords: Gas-solid chromatography ; Gas-adsorption chromatography ; Henry's constants measurements, calculations ; Aromatic, cyclic hydrocarbons ; Chromatoscopy of tetralin
    Source: Springer Online Journal Archives 1860-2000
    Topics: Chemistry and Pharmacology
    Notes: Summary Retention volumes at zero sample size (Henry's constants) on graphitized thermal carbon black have been measured at a number of temperatures for benzene, all its methyl-substituted and some of alkyl-substituted derivatives, naphthalene, diphenyl, phenanthrene, anthracene, tetralin, cis- and trans-decalin, cyclohexane, adamantane and diamantane. The earlier published thermodynamic characteristics of adsorption of the aromatic hydrocarbons have been revised. A molecular statistical calculation of thermodynamic characteristics of adsorption using the atom-atom approximation for the energy of intermolecular interaction between adsorbate and adsorbent has been carried out for polycyclic hydrocarbons: adamantane, diamantane, cis- and trans-decalin. The measured retention volumes of tetralin have been used for the calculation of some parameters of geometric structure of the molecule.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1007/BF02260661
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  • 8
    Electronic Resource
    Electronic Resource
    Separation of isomers of saturated polycyclic hydrocarbons in packed capillary columns with graphitized thermal carbon black (1981)
    Springer
    Chromatographia 14 (1981), S. 148-154 
    Details
    ISSN: 1612-1112
    Keywords: Geometric isomers ; Gas-solid chromatography ; Graphitized carbon black ; Packed capillaries ; Polycyclic hydrocarbons
    Source: Springer Online Journal Archives 1860-2000
    Topics: Chemistry and Pharmacology
    Notes: Summary Using the example of perhydrophenanthrene, perhydroanthracene and cyclopentanodecalin isomers a possibility is shown to use packed capillary columns containing graphitized thermal carbon black for a complete separation of high-boiling mixtures of polycyclic saturated hydrocarbon isomers in accordance with the geometric structure of their molecules.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1007/BF02314759
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  • 9
    Electronic Resource
    Electronic Resource
    Retention of diphenyls, terphenyls, phenylalkanes and fluorene on graphitized thermal carbon black (1981)
    Springer
    Chromatographia 14 (1981), S. 510-514 
    Details
    ISSN: 1612-1112
    Keywords: Gas-solid chromatography ; Graphitized carbon black ; Aromatic hydrocarbons
    Source: Springer Online Journal Archives 1860-2000
    Topics: Chemistry and Pharmacology
    Notes: Summary This paper defines values of retention volumes for zero surface coverage (Henry's constant) at different temperatures, retention indices and variations of the internal energy (differential heats of adsorption) of diphenyl and its alkyl derivatives, terphenyls, diphenylmethane, triphenylmethane, diphenylethanes and fluorene on graphitized thermal carbon black (GTCB). Adsorption on GTCB takes place in accordance with the geometry of these molecules, the strongest adsorption being observed for para-terphenyl with least inhibited internal rotation of the molecule, while the weakest adsorption occurs for 2,6,2′,6′-tetramethyldiphenyl with the most inhibited internal rotation of the molecules. The flat molecules of fluorene are adsorbed on GTCB more readily than the nonflat molecules of diphenylmethane.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1007/BF02265630
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  • 10
    Electronic Resource
    Electronic Resource
    Retention of some phenyl-substituted and bicyclic hydrocarbons on graphitized carbon black (1983)
    Springer
    Chromatographia 17 (1983), S. 521-525 
    Details
    ISSN: 1612-1112
    Keywords: Gas-solid chromatography ; Retention on graphitized carbon black ; Phenylcyclanes, phenyl- and biphenylalkenes and ; alkines, bicyclohexyl, bicyclohexylmethane
    Source: Springer Online Journal Archives 1860-2000
    Topics: Chemistry and Pharmacology
    Notes: Summary Retention volume values for zero cample size (Henry's constants) at different temperatures, retention indices and differential adsorption heats of phenylethylene, phenylacetylene, C9–C12 phenylcyclanes, biphenylethylenes, biphenylacetylene, bicyclohexyl and bicyclohexylmethane have been determined on graphitized thermal carbon black (GTCB). The molecules of all these hydrocarbons are capable of internal rotation. The values of the thermodynamic adsorption characteristics of phenylcyclanes increase with increasing number of carbon atoms in the cycle. Bicyclohexyl is retained on GTCB considerably weaker than biphenyl while bicyclohexylmethane is retained stronger than biphenylmethane. Symmetric and nonsymmetric biphenylethylenes are retained much stronger than the corresponding biphenylethanes. Phenylethylene (styrene) and trans-biphenylethylene (trans-stilbene) are stronger retained on GTCB than phenylacetylene and biphenylacetylene (tolane), respectively. The relationship between the structure of these molecules and their retention on GTCB is discussed.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1007/BF02261913
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