Abstract
An isomorphic equation of state for near-critical binary mixtures is used to represent equation of state and specific heat data for mixtures of methane and ethane in a substantial range of densities and temperatures around the critical line.
This is a preview of subscription content, log in via an institution to check access.
Similar content being viewed by others
References
M. E. Fisher, inCritical Phenomena, Vol. 186, Lecture Notes in Physics, F. J. W. Hahne, ed. (Springer-Verlag, Berlin, 1982), p. 1.
J. V. Sengers and J. M. H. Levelt Sengers,Annu. Rev. Phys. Chem. 37:189 (1986).
M. A. Anisimov,Critical Phenomena in Liquids and Liquid Crystals (Gordon and Breach, Philadelphia, 1991).
R. B. Griffiths and J. C. Wheeler,Phys. Rev. A2:1047 (1970).
W. F. Saam,Phys. Rev. A2:1461 (1970).
M. A. Anisimov, A. V. Voronel, and E. E. Gorodetskii,Sov. Phys. JETP 33:605 (1971).
M. A. Anisimov, A. T. Berestov, and S. B. Kiselev,Sov. Phys. JETP (1982).
S. B. Kiselev,High Temp. 26:337 (1988).
M. A. Anisimov, S. B. Kiselev, and I. G. Kostukova,J. Heat Trans. ASME 110:986 (1988).
S. B. Kiselev, S.-E. Khalidov, and A. V. Yudin,J. Eng. Phys. 54:467 (1988).
M. A. Anisimov, S. B. Kiselev, and S.-E. Khalidov,Int. J. Thermophys. 9:454 (1988).
G. X. Jin, S. Tang, and J. V. Sengers,Phys. Rev. E47:338 (1993).
S. B. Kiselev,High Temp. 24:375 (1986).
M. A. Anisimov, S. B. Kiselev, and I. G. Kostukova,Int. J. Thermophys. 6:465 (1985).
A. J. Liu and M. E. Fisher,Physica A156:35 (1989).
M. A. Anisimov and S. B. Kiselev,Sov. Tech. Rev. B. Therm. Phys. 3(2):1 (1992).
S. S. Leung and R. B. Griffiths,Phys. Rev. A8:2670 (1973).
S. B. Kiselev and A. A. Povodyrev,Fluid Phase Equil. 79:33 (1992).
M. R. Moldover and J. S. Gallagher,AIChE J. 24:267 (1978).
J. C. Rainwater, inSupercritical Fluid Technology, T. J. Bruno and J. F. Ely, eds. (CRC Press, Boca Raton FL, 1991), p. 57.
M. A. Anisimov and J. V. Sengers,Phys. Lett. A172:114 (1992).
W. H. Haynes, R. D. McCarty, and B. E. Eaton,J. Chem. Thermodynam. 17:209 (1985).
M. D. Bespalov, V. B. Nagaev, V. A. Smirnov, and S.-E. Khalidov,Teplofiz. Svoistva Veshestv Mater. 27:32 (1989).
R. T. Ellington, B. E. Eakin, J. D. Parent, D. C. Gami, and O. T. Blommer, inThermodynamic and Transport Properties of Gases, Liquids and Solids, Y. S. Touloukian, ed. (McGraw-Hill, New York, 1959), p. 180.
V. B. Nagaev, V. A. Smirnov, and S.-E. Khalidov,Teplofiz. Svoistva Veshestv Mater. 27:20 (1989).
D. G. Friend and J. F. Ely,Fluid Phase Equil. 19:77 (1992).
M. A. Anisimov, S. B. Kiselev, J. V. Sengers, and S. Tang,Physica A188:487 (1992).
S. B. Kiselev and J. V. Sengers,Int. J. Thermophys. 14:830 (1993).
Author information
Authors and Affiliations
Rights and permissions
About this article
Cite this article
Povodyrev, A.A., Kiselev, S.B. & Anisimov, M.A. Thermodynamic behavior of mixtures of methane and ethane in the critical region. Int J Thermophys 14, 1187–1200 (1993). https://doi.org/10.1007/BF02431283
Received:
Issue Date:
DOI: https://doi.org/10.1007/BF02431283