ALBERT

Description: The causes of the seasonal cycle of vertical turbulent cooling at the base of the mixed layer are assessed using observations from moored buoys in the tropical Atlantic Intertropical Convergence Zone (ITCZ) (4°N, 23°W) and trade wind (15°N, 38°W) regions together with mixing parameterizations and a one-dimensional model. At 4°N the parameterized turbulent cooling rates during 2017–2018 and 2019 agree with indirect estimates from the climatological mooring heat budget residual: both show mean cooling of 25–30 W m (Formula presented.) during November–July, when winds are weakest and the mixed layer is thinnest, and 0–10 W m (Formula presented.) during August–October. Mixing during November–July is driven by variability on multiple time scales, including subdiurnal, near-inertial, and intraseasonal. Shear associated with tropical instability waves (TIWs) is found to generate mixing and monthly mean cooling of 15–30 W m (Formula presented.) during May–July in 2017 and 2019. At 15°N the seasonal cycle of turbulent cooling is out of phase compared to 4°N, with largest cooling of up to 60 W m (Formula presented.) during boreal fall. However, the relationships between wind speed, mixed layer depth, and turbulent mixing are similar: weaker mean winds and a thinner mixed layer in the fall are associated with stronger mixing and turbulent cooling of SST. These results emphasize the importance of seasonal modulations of mixed layer depth at both locations and shear from TIWs at 4°N.

Description: In the boreal summer of 2021, the equatorial Atlantic experienced the strongest warm event, that is, Atlantic Niño, since the beginning of satellite observations in the 1970s. Such events have far‐reaching impacts on large‐scale wind patterns and rainfall over the surrounding continents. Yet, developing a paradigm of how Atlantic Niño interacts with the upper‐ocean currents and intraseasonal waves remains elusive. Here we show that the equatorial Kelvin wave associated with the onset of the 2021 Atlantic Niño modulated both the background flow and the eddy flux of the equatorial upper‐ocean circulation, causing an extremely weak and delayed tropical instability wave (TIW) season. TIW‐induced variations of sea surface temperature (SST), sea surface salinity, sea surface height, and eddy temperature advection were exceptionally weak during May to July, the climatological peak of TIW activity, but rebounded in August when higher than normal variability was observed. Moored velocity data at 23°W show that during the peak of the 2021 Atlantic Niño from June to August, the Equatorial Undercurrent was deeper and stronger than usual. An anomalously weak eddy momentum flux strongly suppressed barotropic energy conversion north of the equator from May to July, likely contributing to low TIW activity. Reduced baroclinic energy conversion also might have played a role, as the meridional gradient of SST was sharply reduced during the Atlantic Niño. Despite extremely weak TIW velocities, modest intraseasonal variability of chlorophyll‐a (Chl‐ a ) was observed during the Atlantic Niño, due to pronounced meridional Chl‐ a gradients that partly compensated for the weak TIWs. Plain Language Summary Every few years the eastern equatorial Atlantic Ocean is significantly warmer than usual during boreal summer. Such warm events are referred to as Atlantic Niño events, and share similarities with El Niño events in the Pacific. In 2021, the strongest Atlantic Niño in at least four decades was observed in the equatorial Atlantic. This study is the first that investigates the complex interaction between Atlantic Niño, tropical Atlantic upper‐ocean currents, and equatorial waves based on various observational data sets. We show that the developing 2021 Atlantic Niño weakened both the background flow and the variability of near‐surface currents in May, which in turn largely reduced the strength of intraseasonal (20–50 days) waves that are usually generated by instability of the upper‐ocean zonal currents. As a consequence, the cooling effect that these waves usually have north of the equator and the warming effect along the equator vanished from May to July 2021. Interestingly, variability of chlorophyll concentration was enhanced, suggesting that enhanced meridional chlorophyll gradients compensated for reduced wave activity. Key Points The developing 2021 Atlantic Niño led to weaker equatorial surface currents and reduced vertical shear of upper‐ocean horizontal velocity Strong reduction of the surface flow, eddy flux, and meridional temperature gradient in May caused extremely weak and delayed tropical instability wave (TIW) season Reduced meridional TIW advection contributed to sharpen the north equatorial Chl‐ a front resulting in modest intraseasonal Chl‐ a variability

Description: Ice loss in the Southern Hemisphere has been greatest over the past 30 years in West Antarctica. The high sensitivity of this region to climate change has motivated geologists to examine marine sedimentary records for evidence of past episodes of West Antarctic Ice Sheet (WAIS) instability. Sediments accumulating in the Scotia Sea are useful to examine for this purpose because they receive iceberg-rafted debris (IBRD) sourced from the Pacific- and Atlantic-facing sectors of West Antarctica. Here we report on the sedimentology and provenance of the oldest of three cm-scale coarse-grained layers recovered from this sea at International Ocean Discovery Program Site U1538. These layers are preserved in opal-rich sediments deposited ∼1.2 Ma during a relatively warm regional climate. Our microCT-based analysis of the layer's in-situ fabric confirms its ice-rafted origin. We further infer that it is the product of an intense but short-lived episode of IBRD deposition. Based on the petrography of its sand fraction and the Phanerozoic 40Ar/39Ar ages of hornblende and mica it contains, we conclude that the IBRD it contains was likely sourced from the Weddell Sea and/or Amundsen Sea embayment(s) of West Antarctica. We attribute the high concentrations of IBRD in these layers to “dirty” icebergs calved from the WAIS following its retreat inland from its modern grounding line. These layers also sit at the top of a ∼366-m thick Pliocene and early Pleistocene sequence that is much more dropstone-rich than its overlying sediments. We speculate this fact may reflect that WAIS mass-balance was highly dynamic during the ∼41-kyr (inter)glacial world. Key Points - We present the first provenance data generated for Pleistocene-aged iceberg-rafted debris deposited in Iceberg Alley - We conclude that prominent iceberg-rafted debris layers deposited at Pirie Basin Site U1538 ∼1.2 Ma were sourced from West Antarctica - They represent intense suborbitally-paced episodes of iceberg discharge from tidewater glaciers, most likely in the Weddell Embayment

Description: The oceanic uptake and resulting storage of the anthropogenic CO2 (Cant) that humans have emitted into the atmosphere moderates climate change. Yet our knowledge about how this uptake and storage has progressed in time remained limited. Here, we determine decadal trends in the storage of Cant by applying the eMLR(C*) regression method to ocean interior observations collected repeatedly since the 1990s. We find that the global ocean storage of Cant grew from 1994 to 2004 by 29 ± 3 Pg C dec−1 and from 2004 to 2014 by 27 ± 3 Pg C dec−1 (±1σ). The storage change in the second decade is about 15 ± 11% lower than one would expect from the first decade and assuming proportional increase with atmospheric CO2. We attribute this reduction in sensitivity to a decrease of the ocean buffer capacity and changes in ocean circulation. In the Atlantic Ocean, the maximum storage rate shifted from the Northern to the Southern Hemisphere, plausibly caused by a weaker formation rate of North Atlantic Deep Waters and an intensified ventilation of mode and intermediate waters in the Southern Hemisphere. Our estimates of the Cant accumulation differ from cumulative net air-sea flux estimates by several Pg C dec−1, suggesting a substantial and variable, but uncertain net loss of natural carbon from the ocean. Our findings indicate a considerable vulnerability of the ocean carbon sink to climate variability and change. Key Points: - The global ocean storage of anthropogenic carbon grew by 29 ± 3 and 27 ± 3 Pg C dec−1 from 1994 to 2004 and 2004 to 2014, respectively - The change in oceanic storage of anthropogenic carbon relative to the atmospheric CO2 growth decreased by 15 ± 11% from the first to the second decade - This reduction is attributed to a decrease of the ocean buffer capacity and changes in ocean circulation

Description: International Ocean Discovery Program (IODP) Expedition 382 in the Scotia Sea’s Iceberg Alley recovered among the most continuous and highest resolution stratigraphic records in the Southern Ocean near Antarctica spanning the last 3.3 Myr. Sites drilled in Dove Basin (U1536/U1537) have well‐resolved magnetostratigraphy and a strong imprint of orbital forcing in their lithostratigraphy. All magnetic reversals of the last 3.3 Myr are identified, providing a robust age model independent of orbital tuning. During the Pleistocene, alternation of terrigenous versus diatomaceous facies shows power in the eccentricity and obliquity frequencies comparable to the amplitude modulation of benthic δ18O records. This suggests that variations in Dove Basin lithostratigraphy during the Pleistocene reflect a similar history as globally integrated ice volume at these frequencies. However, power in the precession frequencies over the entire ∼3.3 Myr record does not match the amplitude modulation of benthic δ18O records, suggesting Dove Basin contains a unique record at these frequencies. Comparing the position of magnetic reversals relative to local facies changes in Dove Basin and the same magnetic reversals relative to benthic δ18O at North Atlantic IODP Site U1308, we demonstrate Dove Basin facies change at different times than benthic δ18O during intervals between ∼3 and 1 Ma. These differences are consistent with precession phase shifts and suggest climate signals with a Southern Hemisphere summer insolation phase were recorded around Antarctica. If Dove Basin lithology reflects local Antarctic ice volume changes, these signals could represent ice sheet precession‐paced variations not captured in benthic δ18O during the 41‐kyr world.

Description: The climactic Los Chocoyos (LCY) eruption from Atitlán caldera (Guatemala) is a key chronostratigraphic marker for the Quaternary period given the extensive distribution of its deposits that reached both the Pacific and Atlantic Oceans. Despite LCY tephra being an important marker horizon, a radioisotopic age for this eruption has remained elusive. Using zircon (U–Th)/He geochronology, we present the first radioisotopically determined eruption age for the LCY of 75 ± 2 ka. Additionally, the youngest zircon crystallization 238U–230Th rim ages in their respective samples constrain eruption age maxima for two other tephra units that erupted from Atitlán caldera, W-Fall (130 +16/−14 ka) and I-Fall eruptions (56 +8.2/−7.7 ka), which under- and overlie LCY tephra, respectively. Moreover, rim and interior zircon dating and glass chemistry suggest that before eruption silicic magma was stored for 〉80 kyr, with magma accumulation peaking within ca. 35 kyr before the LCY eruption during which the system may have developed into a vertically zoned magma chamber. Based on an updated distribution of LCY pyroclastic deposits, a new conservatively estimated volume of ~1220 ± 150 km3 is obtained (volcanic explosivity index VEI 〉 8), which confirms the LCY eruption as the first-ever recognized supereruption in Central America.

Description: Tropical Instability Waves (TIWs) are the dominant source of intraseasonal variability in the central equatorial Atlantic and play an important role in the redistribution of heat in the upper ocean. Here we use multidecadal records of sea surface temperature, sea level anomaly, sea surface salinity, and near-surface currents constructed from in situ and satellite observations to reveal a long-term intensification of the intraseasonal variability of these variables due to an increase of TIW activity. Enhanced barotropic energy conversion from increased covariance of horizontal current fluctuations, rather than low-frequency changes of the mean zonal currents, drives the TIW intensification. As a consequence, boreal summer cooling of tropical North Atlantic surface waters through horizontal eddy temperature advection increased by 0.03°C month−1 decade−1 during 1993–2021, a change of 74% ± 53% relative to the long-term mean. The presented multidecadal TIW trends are strongly modulated by interannual variations like the 2021 Atlantic Niño. Key Points: - In situ and satellite observations show a long-term intensification of Tropical Instability Waves (TIWs) in the tropical North Atlantic - Enhanced TIW activity is mainly due to increased barotropic instability associated with increased covariance of velocity fluctuations - As a result, TIW-driven sea surface cooling north of the equator due to eddy temperature advection has increased by 74% from 1993 to 2021

Description: This contribution to the RECCAP2 (REgional Carbon Cycle Assessment and Processes) assessment analyzes the processes that determine the global ocean carbon sink, and its trends and variability over the period 1985-2018, using a combination of models and observation-based products. The mean sea-air CO2 flux from 1985 to 2018 is -1.6 +/- 0.2 PgC yr(-1) based on an ensemble of reconstructions of the history of sea surface pCO(2) (pCO(2) products). Models indicate that the dominant component of this flux is the net oceanic uptake of anthropogenic CO2, which is estimated at -2.1 +/- 0.3 PgC yr(-1) by an ensemble of ocean biogeochemical models, and -2.4 +/- 0.1 PgC yr(-1) by two ocean circulation inverse models. The ocean also degasses about 0.65 +/- 0.3 PgC yr(-1) of terrestrially derived CO2, but this process is not fully resolved by any of the models used here. From 2001 to 2018, the pCO2 products reconstruct a trend in the ocean carbon sink of -0.61 +/- 0.12 PgC yr(-1) decade(-1), while biogeochemical models and inverse models diagnose an anthropogenic CO2-driven trend of -0.34 +/- 0.06 and -0.41 +/- 0.03 PgC yr(-1) decade(-1), respectively. This implies a climate-forced acceleration of the ocean carbon sink in recent decades, but there are still large uncertainties on the magnitude and cause of this trend. The interannual to decadal variability of the global carbon sink is mainly driven by climate variability, with the climate-driven variability exceeding the CO2-forced variability by 2-3 times. These results suggest that anthropogenic CO2 dominates the ocean CO2 sink, while climate-driven variability is potentially large but highly uncertain and not consistently captured across different methods.

Description: The excess heat absorbed from the atmosphere has increased the temperature in the upper layers of the ocean (〈2,000 m). In the abyss, infrequently repeated ship sections, deep Argo float measurements, and sparse moored observations have found signs of warming in the Southwest Atlantic, possibly linked to changes in the Weddell Sea. We present a new moored temperature time series sampled near the bottom in the Vema Channel, from February 2019 to August 2020. Together with historical data, the combined record confirms the warming of the abyssal waters, with an increase of 0.059°C in potential temperature between January 1991 and August 2020, embedded within intense high-frequency variability. Moreover, the data suggest the possibility of an accelerated warming, with a change in the temperature trend from 0.0016°C yr−1, between the early 1990s and 2005, to 0.0026°C yr−1 afterwards.