Publication Date:
2017-01-13
Description:
The crystal structure of the title compound, [Rb(C18H36N2O6)]3RbSn9, consists of deltahedral [Sn9]4–cluster anions, Rb+cations and cryptand molecules, which partially sequester the cations. Those cations, which are not coordinated by cryptand molecules, are neighboured directly to the [Sn9]4–clusters and interconnect them to form∞1[RbSn9]3–chains. These chains extend parallel to [001] and are arranged in a pseudo-hexagonal rod packing, separated by the Rb-cryptand complex cations.
Electronic ISSN:
2056-9890
Topics:
Chemistry and Pharmacology
,
Geosciences
Permalink