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  • 1
    Publication Date: 2012-04-01
    Description: Garnierites represent significant Ni ore minerals in the many Ni-laterite deposits worldwide. The occurrence of a variety of garnierite minerals with variable Ni content poses questions about the conditions of their formation. From an aqueous-solution equilibrium thermodynamic point of view, the present study examines the conditions that favor the precipitation of a particular garnierite phase and the mechanism of Ni-enrichment, and gives an explanation to the temporal and spatial succession of different garnierite minerals in Ni-laterite deposits. The chemical and structural characterization of garnierite minerals from many nickel laterite deposits around the world show that this group of minerals is formed essentially by an intimate intermixing of three Mg-Ni phyllosilicate solid solutions: serpentine-népouite, kerolite-pimelite, and sepiolite-falcondoite, without or with very small amounts of Al in their composition. The present study deals with garnierites which are essentially Al-free. The published experimental dissolution constants for Mg end-members of the above solid solutions and the calculated constants for pure Ni end-members were used to calculate Lippmann diagrams for the three solid solutions, on the assumption that they are ideal. With the help of these diagrams, congruent dissolution of Ni-poor primary minerals, followed by equilibrium precipitation of Ni-rich secondary phyllosilicates, is proposed as an efficient mechanism for Ni supergene enrichment in the laterite profile. The stability fields of the solid solutions were constructed using [log aSiO2(aq), log ((aMg2+ + aNi2+)/(aH+)2)] (predominance) diagrams. These, combined with Lippmann diagrams, give an almost complete chemical characterization of the solution and the precipitating phase(s) in equilibrium. The temporal and spatial succession of hydrous Mg-Ni phyllosilicates encountered in Ni-laterite deposits is explained by the small mobility of silica and the increase in its activity.
    Print ISSN: 0009-8604
    Electronic ISSN: 1552-8367
    Topics: Geosciences
    Published by Clay Minerals Society
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  • 2
    Publication Date: 2016-03-24
    Description: The advancement of tissue and, ultimately, organ engineering requires the ability to pattern human tissues composed of cells, extracellular matrix, and vasculature with controlled microenvironments that can be sustained over prolonged time periods. To date, bioprinting methods have yielded thin tissues that only survive for short durations. To improve their...
    Print ISSN: 0027-8424
    Electronic ISSN: 1091-6490
    Topics: Biology , Medicine , Natural Sciences in General
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  • 3
    Publication Date: 2015-10-23
    Description: Most stars become white dwarfs after they have exhausted their nuclear fuel (the Sun will be one such). Between one-quarter and one-half of white dwarfs have elements heavier than helium in their atmospheres, even though these elements ought to sink rapidly into the stellar interiors (unless they are occasionally replenished). The abundance ratios of heavy elements in the atmospheres of white dwarfs are similar to the ratios in rocky bodies in the Solar System. This fact, together with the existence of warm, dusty debris disks surrounding about four per cent of white dwarfs, suggests that rocky debris from the planetary systems of white-dwarf progenitors occasionally pollutes the atmospheres of the stars. The total accreted mass of this debris is sometimes comparable to the mass of large asteroids in the Solar System. However, rocky, disintegrating bodies around a white dwarf have not yet been observed. Here we report observations of a white dwarf--WD 1145+017--being transited by at least one, and probably several, disintegrating planetesimals, with periods ranging from 4.5 hours to 4.9 hours. The strongest transit signals occur every 4.5 hours and exhibit varying depths (blocking up to 40 per cent of the star's brightness) and asymmetric profiles, indicative of a small object with a cometary tail of dusty effluent material. The star has a dusty debris disk, and the star's spectrum shows prominent lines from heavy elements such as magnesium, aluminium, silicon, calcium, iron, and nickel. This system provides further evidence that the pollution of white dwarfs by heavy elements might originate from disrupted rocky bodies such as asteroids and minor planets.〈br /〉〈span class="detail_caption"〉Notes: 〈/span〉Vanderburg, Andrew -- Johnson, John Asher -- Rappaport, Saul -- Bieryla, Allyson -- Irwin, Jonathan -- Lewis, John Arban -- Kipping, David -- Brown, Warren R -- Dufour, Patrick -- Ciardi, David R -- Angus, Ruth -- Schaefer, Laura -- Latham, David W -- Charbonneau, David -- Beichman, Charles -- Eastman, Jason -- McCrady, Nate -- Wittenmyer, Robert A -- Wright, Jason T -- England -- Nature. 2015 Oct 22;526(7574):546-9. doi: 10.1038/nature15527.〈br /〉〈span class="detail_caption"〉Author address: 〈/span〉Harvard-Smithsonian Center for Astrophysics, Cambridge, Massachusetts 02138, USA. ; Department of Physics, and Kavli Institute for Astrophysics and Space Research, Massachusetts Institute of Technology, Cambridge, Massachusetts 02139, USA. ; Department of Astronomy, Columbia University, New York, New York 10027, USA. ; Institut de Recherche sur les Exoplanetes, Department de Physique, Universite de Montreal, Montreal, Quebec H3C 3J7, Canada. ; NASA Exoplanet Science Institute, California Institute of Technology, Pasadena, California 91125, USA. ; Department of Physics, University of Oxford, Oxford OX1 3RH, UK. ; Department of Physics and Astronomy, University of Montana, Missoula, Montana 59812, USA. ; School of Physics and Australian Centre for Astrobiology, University of New South Wales, Sydney, New South Wales 2052, Australia. ; Department of Astronomy and Astrophysics and Center for Exoplanets and Habitable Worlds, The Pennsylvania State University, University Park, Pennsylvania 16802, USA.〈br /〉〈span class="detail_caption"〉Record origin:〈/span〉 〈a href="http://www.ncbi.nlm.nih.gov/pubmed/26490620" target="_blank"〉PubMed〈/a〉
    Print ISSN: 0028-0836
    Electronic ISSN: 1476-4687
    Topics: Biology , Chemistry and Pharmacology , Medicine , Natural Sciences in General , Physics
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  • 4
    Publication Date: 1991-02-15
    Description: 〈br /〉〈span class="detail_caption"〉Notes: 〈/span〉LaRosa, G J -- Davide, J P -- Weinhold, K -- Waterbury, J A -- Profy, A T -- Lewis, J A -- Langlois, A J -- Dreesman, G R -- Boswell, R N -- Shadduck, P -- New York, N.Y. -- Science. 1991 Feb 15;251(4995):811.〈br /〉〈span class="detail_caption"〉Record origin:〈/span〉 〈a href="http://www.ncbi.nlm.nih.gov/pubmed/1990444" target="_blank"〉PubMed〈/a〉
    Keywords: Amino Acid Sequence ; Base Sequence ; HIV-1/*genetics ; Molecular Sequence Data
    Print ISSN: 0036-8075
    Electronic ISSN: 1095-9203
    Topics: Biology , Chemistry and Pharmacology , Computer Science , Medicine , Natural Sciences in General , Physics
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  • 5
    Publication Date: 1990-08-24
    Description: The principal neutralizing determinant (PND) of human immunodeficiency virus HIV-1 is part of a disulfide bridged loop in the third variable region of the external envelope protein, gp120. Analysis of the amino acid sequences of this domain from 245 different HIV-1 isolates revealed that the PND is less variable than thought originally. Conservation to better than 80 percent of the amino acids in 9 out of 14 positions in the central portion of the PND and the occurrence of particular oligopeptide sequences in a majority of the isolates suggest that there are constraints on PND variability. One constraining influence may be the structural motif (beta strand--type II beta turn--beta strand--alpha helix) predicted for the consensus PND sequence by a neural network approach. Isolates with a PND similar to the commonly investigated human T cell lymphoma virus IIIB (HTLV-IIIB) and LAV-1 (BRU) strains were rare, and only 14 percent of sera from 86 randomly selected HIV-1 seropositive donors contained antibodies that recognized the PND of these virus isolates. In contrast, over 65 percent of these sera reacted with peptides containing more common PND sequences. These results suggest that HIV vaccine immunogens chosen because of their similarity to the consensus PND sequence and structure are likely to induce antibodies that neutralize a majority of HIV-1 isolates.〈br /〉〈span class="detail_caption"〉Notes: 〈/span〉LaRosa, G J -- Davide, J P -- Weinhold, K -- Waterbury, J A -- Profy, A T -- Lewis, J A -- Langlois, A J -- Dreesman, G R -- Boswell, R N -- Shadduck, P -- New York, N.Y. -- Science. 1990 Aug 24;249(4971):932-5.〈br /〉〈span class="detail_caption"〉Author address: 〈/span〉Repligen Corporation, Cambridge, MA 02139.〈br /〉〈span class="detail_caption"〉Record origin:〈/span〉 〈a href="http://www.ncbi.nlm.nih.gov/pubmed/2392685" target="_blank"〉PubMed〈/a〉
    Keywords: Amino Acid Sequence ; Genetic Variation ; HIV Envelope Protein gp120/*genetics ; *HIV Seropositivity ; HIV-1/*genetics/isolation & purification/pathogenicity ; Humans ; Military Personnel ; Molecular Sequence Data ; Protein Conformation ; United States
    Print ISSN: 0036-8075
    Electronic ISSN: 1095-9203
    Topics: Biology , Chemistry and Pharmacology , Computer Science , Medicine , Natural Sciences in General , Physics
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  • 6
    Publication Date: 2009-02-14
    Description: Flexible, stretchable, and spanning microelectrodes that carry signals from one circuit element to another are needed for many emerging forms of electronic and optoelectronic devices. We have patterned silver microelectrodes by omnidirectional printing of concentrated nanoparticle inks in both uniform and high-aspect ratio motifs with minimum widths of approximately 2 micrometers onto semiconductor, plastic, and glass substrates. The patterned microelectrodes can withstand repeated bending and stretching to large levels of strain with minimal degradation of their electrical properties. With this approach, wire bonding to fragile three-dimensional devices and spanning interconnects for solar cell and light-emitting diode arrays are demonstrated.〈br /〉〈span class="detail_caption"〉Notes: 〈/span〉Ahn, Bok Y -- Duoss, Eric B -- Motala, Michael J -- Guo, Xiaoying -- Park, Sang-Il -- Xiong, Yujie -- Yoon, Jongseung -- Nuzzo, Ralph G -- Rogers, John A -- Lewis, Jennifer A -- New York, N.Y. -- Science. 2009 Mar 20;323(5921):1590-3. doi: 10.1126/science.1168375. Epub 2009 Feb 12.〈br /〉〈span class="detail_caption"〉Author address: 〈/span〉Frederick Seitz Materials Research Laboratory, University of Illinois at Urbana-Champaign, Urbana, IL 61801, USA.〈br /〉〈span class="detail_caption"〉Record origin:〈/span〉 〈a href="http://www.ncbi.nlm.nih.gov/pubmed/19213878" target="_blank"〉PubMed〈/a〉
    Print ISSN: 0036-8075
    Electronic ISSN: 1095-9203
    Topics: Biology , Chemistry and Pharmacology , Computer Science , Medicine , Natural Sciences in General , Physics
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  • 7
    Publication Date: 2015-02-06
    Description: 〈br /〉〈span class="detail_caption"〉Notes: 〈/span〉Lewis, Jennifer A -- Ahn, Bok Y -- England -- Nature. 2015 Feb 5;518(7537):42-3. doi: 10.1038/518042a.〈br /〉〈span class="detail_caption"〉Author address: 〈/span〉School of Engineering and Applied Sciences and the Wyss Institute for Biologically Inspired Engineering, Harvard University, Cambridge, Massachusetts 02138, USA.〈br /〉〈span class="detail_caption"〉Record origin:〈/span〉 〈a href="http://www.ncbi.nlm.nih.gov/pubmed/25652992" target="_blank"〉PubMed〈/a〉
    Print ISSN: 0028-0836
    Electronic ISSN: 1476-4687
    Topics: Biology , Chemistry and Pharmacology , Medicine , Natural Sciences in General , Physics
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  • 8
    Electronic Resource
    Electronic Resource
    Woodbury, NY : American Institute of Physics (AIP)
    Applied Physics Letters 56 (1990), S. 1222-1224 
    ISSN: 1077-3118
    Source: AIP Digital Archive
    Topics: Physics
    Notes: We have examined static properties of step and continuously graded single and multiple quantum well InGaAs/InP lasers grown by atmospheric pressure metalorganic vapor phase epitaxy. Systematic changes in the band gap of InGaAsP waveguide layers have resulted in lasers with low threshold current (〈10 mA), high quantum efficiency (26% per facet) and power output (∼70 mW), and the effective loss of 2–5 cm−1. We show that the changes in threshold current in short lasers can be explained by a switch from the n=1 to n=2 level. The level switching results in a very flat and wide (〉1000 A(ring)) gain profile.
    Type of Medium: Electronic Resource
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  • 9
    Electronic Resource
    Electronic Resource
    [S.l.] : American Institute of Physics (AIP)
    Journal of Applied Physics 78 (1995), S. 4596-4607 
    ISSN: 1089-7550
    Source: AIP Digital Archive
    Topics: Physics
    Notes: Bi2Sr2Ca0.64Cu1.64Ox (nominally Bi2212) powders were fabricated into powder-in-tube Ag- and Ag(7 at. % Cu)-sheathed tapes by cold and hot rolling to investigate the effects of sheath composition and rolling conditions on their microstructural development and superconducting properties. Bi2212 tapes with Ag(Cu) sheaths exhibited improved grain alignment and interfacial uniformity, as well as enhanced formation of the Bi-free phase (≈Sr7.5Ca6.5Cu14Ox), relative to the Ag-sheathed specimens. The hot-rolled Ag(Cu)-sheathed tapes displayed superior critical current densities (Jc), where magnetization Jcm=1.5×106 (H(parallel)c) and 4.6×105 A/cm2 (H⊥c) at T=5 K, H=1 T. Correspondingly, these specimens had transport critical current densities (Jct) of 6.7×104 A/cm2 (H(parallel)c) and 5.4×104 A/cm2 (H⊥c) at T=4.2 K, H=0 T and 2.2×104 A/cm2 (H(parallel)c) and 3.0×104 A/cm2 (H⊥c) at T=4.2 K, H=14 T. The chemical stability of the Ag(Cu) sheath regions during the partial melting process was also studied. Rapid oxidation of copper produced Cu2O precipitates in the sheath at 885 °C, and subsequently a Cu2O-free zone developed near the core/sheath interface. A theoretical analysis of Cu2O precipitate formation and decomposition during thermal processing is presented. © 1995 American Institute of Physics.
    Type of Medium: Electronic Resource
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  • 10
    Electronic Resource
    Electronic Resource
    [S.l.] : American Institute of Physics (AIP)
    Journal of Applied Physics 75 (1994), S. 5218-5226 
    ISSN: 1089-7550
    Source: AIP Digital Archive
    Topics: Physics
    Notes: The effects of magnetic alignment, heat treatment, and substrate interactions on the microstructural development and properties of YBa2Cu3O7−x (Y123) thick films were studied. Aligned films were formed by vacuum filtrating a particulate suspension in a 7 T applied field. These films and nonaligned control films were fired on either platinum (Pt) foil or magnesium oxide (MgO) substrates to various maximum temperatures between 930 and 1040 °C. Optical microscopy revealed large differences in microstructural development between the various films. Aligned Y123 films fired on Pt foil exhibited the best microstructural properties. Via plasma emission spectroscopy and secondary ion mass spectroscopy, approximately 0.1 wt % Pt was found distributed throughout the films fired on platinum, while negligible amounts of Mg were detected in the films fired on MgO substrates. Differential thermal analysis revealed that, in the presence of Pt, the peritectic temperature (1030 °C for pure Y123 in O2) is reduced 70 °C, thereby opening a substantial thermal processing window for partial melt assisted growth of textured Y123. SQUID measurements of magnetic hysteresis and Tc provided quantitative evidence that, relative to the films fired on MgO, those fired on Pt exhibited enhanced texture development [ΔM(Happ(parallel)c axis)/ΔM(Happ⊥c axis)=2.6 at 5 K, 1 T] and properties (Bean model Jc,m=5×104 A/cm2 at 5 K, 4 T) without degradation of the Tc characteristics.
    Type of Medium: Electronic Resource
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