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  • 1
    Electronic Resource
    Electronic Resource
    Springer
    Il nuovo cimento della Società Italiana di Fisica 4 (1984), S. 161-171 
    ISSN: 0392-6737
    Keywords: Impurity and defect absorption in solids ; Optical properties of thin films
    Source: Springer Online Journal Archives 1860-2000
    Topics: Physics
    Description / Table of Contents: Riassunto Sono stati misurati gli spettri infrarossi di film di silicio amorfo idrogenato drogati con fosforo e boro. È stato studiato l'andamento delle bande di assorbimento dei modi «stretching», «wagging» (o «rocking») in funzione del drogaggio il cui valore è stato determinato con misure Auger. All'aumentare del drogaggio col fosforo ha corrisposto una diminuzione del contenuto d'idrogeno ed un incremento dell'area della banda di «stretching» di Si-H a spese di quella relativa a Si-H2. Analoghi risultati sono stati ottenuti per i campioni drogati con boro. Poiché nessuno spostamento delle bande di «stretching» verso frequenze piú alte è stato osservato, i cambiamenti d'intensità delle bande sono stati attribuiti a modifiche strutturali piú che a variazioni dell'elettro-negatività dell'ambiente circostante il silicio. In particolare, la tecnica di crescita usata sembra aver favorito rispetto alle altre la configurazione di monoidruro, con un conseguente minor numero di difetti.
    Abstract: Реуме Измеряются инфракрасные спектры гидрогенизированных аморфныш пленок кремния, легированных фосфором и бором, выращенных с помощяы метода выпаривания. Исследуется изменение полосы поглощения (типа растяжения и покачивания) при изменении содержания легрующих примесей, которые анализируются методом Оже. При уменьшении легирования, отмечается уменьшение содержания водорода и увеличение момента нулевого порядка для растяжения SI−H за счет SI−H2. Для пленок, легированных бором, наблюдаются аналогичные результаты. Так как не наблюдается сдвиг по частоте в сторону больших частот для растянутых зон, то наблюденные изменения интенсивности зон приписываются изменениям структуры, а не изменениям электроотрицательности окружения атома кремния. В частности, использованная техника выращивания, повндимому, благоприятствует образованию моногидридной конфигурации с наименьшим числом дефектов.
    Notes: Summary The infra-red spectra of P- and B-doped hydrogenated amorphous silicon films grown by means of an evaporation method have been measured. The SiH n stretching and wagging (or rocking) absorption bands have been examined by varying the dopant content measured by Auger analysis. On increasing the doping, a reduction of hydrogen content has been noticed with an enhancing of zeroth-order moment of Si-H stretching at the expense of the Si-H2 one. Analogous results for B-doped films have been observed. Since no frequency shift towards higher frequencies of the stretching bands has been measured, the observed changes of the intensity of the bands have been attributed to structure modifications rather than to variations in the electronegativity in the neighbours of the silicon atom. In particular, the monohidride configuration with an overall decrease in the number of defects seems to be favoured by the deposition technique adopted.
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  • 2
    Electronic Resource
    Electronic Resource
    Springer
    Il nuovo cimento della Società Italiana di Fisica 4 (1984), S. 444-452 
    ISSN: 0392-6737
    Keywords: Nonlocalized single-particle electronic states
    Source: Springer Online Journal Archives 1860-2000
    Topics: Physics
    Description / Table of Contents: Riassunto Le bande di valenza dei tiofosfati FePS3 e NiPS3 sono state studiate utilizzando la tecnica della fotoemissione risonante. Brusche variazioni dell'intensità di alcune strutture degli spettri di distribuzione dell'energia dei fotoelettroni sono state osservate quando l'energia dei fotoni era variata intorno alle soglie di assorbimento 3p del Fe e del Ni. Invece altre strutture mostravano degli spettri di eccitazione lisci. Le prime sono state associate agli stati 3d del metallo di transizione (fotoemissione diretta e satelliti), le seconde agli stati dei gruppi (P2S6)4−. Infine, i risultati ottenuti confermano il modello fortemente ionico di questi composti.
    Abstract: Резюме Мы исследовали валентные зоны тифосфатов FePS3 и NiPS3 с помощью техники резонансной фотоэмиссии. Некоторые структуры кривых энергетичеких распределений обнаруживают быстрые изменения интенсивности, когда энергия фотона проходит через пороги 3p поглощения Fe или Ni. Напротив, другие структуры обнаруживают плавные спектры возбуждения. Первые структуры связаны с переходом ионов металла в состоянии 3d (прямая фотоэмиссии и сателлиты), вторые структуры связаны с (P2S6)4− состояниями. Полученные результаты подтверждают сильно ионную модель этих соединений.
    Notes: Summary We have investigated the valence bands of the tiophosphates FEPS3 and NiPS3 with the resonant-photoemission technique. Some structures of the energy distribution curves show rapid intensity changes when the photon energy is scanned across the Fe or Ni 3p absorption thresholds. Instead, other structures show smooth excitation spectra. We have related the former to the transition metal ion 3d states (direct photoemission and satellites) and the latter to the (P2S6)4− states. These results support also a strongly ionic picture of these compounds.
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  • 3
    Electronic Resource
    Electronic Resource
    Springer
    Il nuovo cimento della Società Italiana di Fisica 1 (1982), S. 841-848 
    ISSN: 0392-6737
    Keywords: Impurity and defect absorption in solids
    Source: Springer Online Journal Archives 1860-2000
    Topics: Physics
    Description / Table of Contents: Riassunto Mediante misure di assorbimento ottico e di fotoconducibilità si è trovato che la larghezza della coda di Urbach e il valore del gap ottico dipendono fortemente dal disordine presente nella matrice dei film di silicio amorfo idrogenato. Inoltre si è osservato che il disordine termico e quello strutturale influenzano allo stesso modo il coefficiente di assorbimento avvalorando l'ipotesi che il valore del gap ottico dipende solo indirettamente dalla concentrazione totale di idrogeno.
    Notes: Summary We have found, from optical transmission and photoconductivity measurements, that the width of the Urbach's tail and the optical-band gap value depend on the amount of disorder present in the network ofa-Si: H films. The nature of the disorder, being it thermal or structural, affects in the same way the behaviour of the absorption coefficient and supports the hypothesis that the value of the optical-band gap depends only indirectly on the overall hydrogen content.
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  • 4
    Electronic Resource
    Electronic Resource
    Springer
    Il nuovo cimento della Società Italiana di Fisica 17 (1995), S. 37-52 
    ISSN: 0392-6737
    Keywords: X-ray photoelectron spectra ; Electron states in low-dimensional structures (including quantum wells, superlattices, layer structures, and intercalation compounds) ; Ion-molecule, ion-ion and charge-transfer reactions
    Source: Springer Online Journal Archives 1860-2000
    Topics: Physics
    Notes: Summary A detailed XPS study of the lithium-intercalated NiPS3 specimens was performed at the 2p, 3p, 3s core levels of the nickel atoms and at the 2p core levels of the sulphur and phosphorous atoms for various lithium contents. Comparison of the Ni 2p, 3p and 3s XPS spectra corresponding to NiPS3 and Li x NiPS3 systems shows some evident trends. In particular, a shift of the Ni main line towards lower binding energies, a decrease in the intensity of the Ni 3p, 2p satellite structures and a change in the full width at half maximum of the Ni 3s band with lithium content are observed. All these findings suggest a change in the 3d electron configuration for high lithium concentrations. As regards the cluster (P2S6)4−, with the addition of lithium, a P 2p main line shift towards higher binding energies is noted, while the S 2p peak shifts towards lower binding energies. These results are discussed in comparison with previous physical measurements concerning the nickel reduction process and the related electronic modifications.
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  • 5
    Electronic Resource
    Electronic Resource
    Springer
    Il nuovo cimento della Società Italiana di Fisica 13 (1991), S. 787-793 
    ISSN: 0392-6737
    Keywords: Electronic properties of specific thin films ; Conductivity of specific semiconductors and insulators
    Source: Springer Online Journal Archives 1860-2000
    Topics: Physics
    Notes: Summary The electrical-conductivity frequency dependence of reactive-evaporation-depositeda-Si:H films has been measured in the temperature range (100÷450)K. The influence of the substrate temperature, of the hydrogen ions energy and of post-deposition thermal treatments has also been investigated. The results show that, depending on the material quality, three different conduction mechanisms associated with gap states, band or band tail states and to hopping processes near the Fermi level are observed.
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  • 6
    Electronic Resource
    Electronic Resource
    Springer
    Il nuovo cimento della Società Italiana di Fisica 15 (1993), S. 9-16 
    ISSN: 0392-6737
    Keywords: II-VI compounds and other chalcogenides
    Source: Springer Online Journal Archives 1860-2000
    Topics: Physics
    Notes: Summary The fluorescence spectra of MnPS3 single crystals have been investigated at various temperatures beginning from 300K down to 10K in the 1.5 eV to 3.0 eV range. Four structures are observed in all spectra. The strong similarity between these results and previous data concerning the MnPS3 room temperature fluorescence suggests an intra-Mn nature for the transitions responsible for the above features. All the subband gap structures exhibit a temperature shift which can be satisfactorily interpreted by means of the crystal field theory and the so-called «transition metal weakly interacting» model. The fine splitting in the originally degenerate {4 E g,4 A 1g} levels is enhanced as temperature decreases. These results confirm the Mn2+ 3ϕ excited-state energy distribution deduced from the transition metal weakly interacting model.
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  • 7
    Electronic Resource
    Electronic Resource
    Springer
    Il nuovo cimento della Società Italiana di Fisica 6 (1985), S. 93-104 
    ISSN: 0392-6737
    Keywords: Conductivity phenomena in semiconductors and insulators
    Source: Springer Online Journal Archives 1860-2000
    Topics: Physics
    Description / Table of Contents: Riassunto Si sono eseguite misure di conducibilità, fotoconducibilità e potere termoelettrico in funzione della temperatura su una serie di film di silicio amorfo idrogenato drogati con fosforo e boro. I risultati sono stati interpretati sulla base di un modello che prevede due distinti meccanismi di transporto: nella regione ad alta temperatura attraverso stati estesi di banda, in quella a bassa temperatura con conduzione di tipo «hopping» in una banda d'impurezze la cui densità degli stati aumenta al crescere del contenuto di drogante. Si è anche osservato uno spostamento del livello di Fermi fino a 0.4 eV, verso le soglie di mobilità e una forte dipendenza della fotoconducibilità al variare del tipo e della quantità di drogante.
    Abstract: Резюме(*) Провенеды измерения проводимости фотопропроводимости и термоэлектрической силы в зависимости от температуры для ряда a-Si: Н пленок ри n-типа, приготовленных с помощью метода испарения. Результаты объясняются с помощью модели, включающей два механизма проводимости: в области высоких температур через растянутые зонные состонния, а в области низких температур через зону примеси, для которой плотность состояний увеличивается с увеличением содержания легирующей примеси. Обнаружен сдвиг уровня Ферми до 0.4 эВ для обоих типов легирующих примесей. Кроме того, легирование фосфором быстро увеличивает фотопроводимость на два порядка, тогда как легирование бором уменьшает фотопроводимость.
    Notes: Summary Conductivity, photoconductivity and thermopower measurements have been made as functions of temperature on a series of p- and n-type a-Si: H films prepared by a reactive, evaporation method. The results have been fitted with a model including two conduction paths: in the high-temperature range through extended band states and in the low-temperature range as hopping in an impurity band, whose density of states increases with increasing dopant content. A shift of the Fermi level up to 0.4 eV towards the mobility edges for both types of dopants has been found. Moreover, phosphorus doping radiply increases the photoconductivity values by about two orders of magnitude, while boron incorporation causes considerable reduction.
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  • 8
    Electronic Resource
    Electronic Resource
    Springer
    Il nuovo cimento della Società Italiana di Fisica 13 (1991), S. 633-645 
    ISSN: 0392-6737
    Keywords: Optical properties of bulk materials ; Refractive index ; reflectivity ; critical angle ; dispersive power ; Transition-metal compounds
    Source: Springer Online Journal Archives 1860-2000
    Topics: Physics
    Notes: Summary Room temperature optical-reflectivity measurements on some transition metal thiophosphates were carried out in the near infrared and visible regions. The resulting spectra, interpreted on the basis of the «transition metal weakly interacting» model, agree well with earlier optical transmission measurements. Below the fundamental absorption edge, the observed features have been assigned to 3d–3d transitions occurring on the transition metal ion, while those observed at photon energies greater than the absorption threshold have been attributed to transitions from the valence bands to discrete 3d orbital levels or to the conduction bands. A more detailed information on the metal ion 3d levels energy distribution with respect to the valence band states belonging to the (P2S6)4- cluster and a more precise determination of the MPS3 absorption edge energy position have been obtained.
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  • 9
    Electronic Resource
    Electronic Resource
    Springer
    Il nuovo cimento della Società Italiana di Fisica 8 (1986), S. 263-278 
    ISSN: 0392-6737
    Keywords: Other interactions of matter with particles and radiation
    Source: Springer Online Journal Archives 1860-2000
    Topics: Physics
    Description / Table of Contents: Riassunto Si sono studiate le bande di valenza di FePS3 e NiPS3 con la tecnica della fotoemissione risonante. I risultati sperimentali ottenuti sono in accordo con la nostra precedente identificazione delle strutture della banda di valenza e con un modello di tipo ionico per la descrizione del legame metallo-calcogeno. Le strutture spettrali d'intensità rapidamente variabili al variare dell'energia di eccitazione intorno alle soglie d'assorbimentoM 2,3 del Fe e del Ni sono associate agli stati 3d del metallo di transizione; le rimanenti strutture, non risonanti, sono ascritte invece agli stati del cluster (P2S6)4−. Utilizzando la tecnica yield ad alta risoluzione, si sono misurati gli spettri di assorbimento dei livelli di core di zolfo e fosforo nei tiofosfati di Mn, Fe e Ni. In tutti i composti si riscontrano notevoli somiglianze fra le soglieL 2,3(P) edL 2,3(S). Gli spettri sono pertanto interpretativi in termini di densità proiettata degli stati delle bande di conduzione derivate dagli orbitali del cluster (P2S6)4−.
    Notes: Summary With the resonant photomeission technique we investigated the valence bands of FePS3 and NiPS3. The experimental results, support the ionic picture of the compounds and our previous identification of the valence band structures. The structures rapidly varying in intensity when the excitation energy is scanned across the Fe and NiM 2,3 absorption edge are associated to the transition metal 3d states; the nonresonating features are ascribed to the (P2P6)4− cluster states. With the yield technique we measured the high-resolution absorption spectra of the phosphorus and sulphur inner-core levels in Mn, Fe and Ni thiophosphates. TheL 2,3(P) andL 2,3(S) spectra are similar to each other in all the compounds and are interpreted in terms of the projected density of states of the conduction bands derived from the (P2S6)4− cluster states.
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  • 10
    ISSN: 0378-4363
    Source: Elsevier Journal Backfiles on ScienceDirect 1907 - 2002
    Topics: Physics
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