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  • 1
    Call number: AWI G5-95-0259
    Type of Medium: Monograph available for loan
    Pages: 34 S. : graph. Darst.
    Language: English
    Branch Library: AWI Library
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  • 2
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    PANGAEA
    In:  EPIC3Bremerhaven, PANGAEA
    Publication Date: 2016-11-21
    Repository Name: EPIC Alfred Wegener Institut
    Type: PANGAEA Documentation , notRev
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  • 3
    Publication Date: 2019-07-16
    Description: AbstractWe conducted an intercomparison of methods for the determination of 234Th in seawater. Samples were collected either from a shore-based 600 m water source, or from standard bottle casts collected in deep waters off Hawaii and in the Southern Ocean. We compared large volume techniques which rely upon Mn cartridges for the collection of dissolved 234Th and its detection via gamma counting (〉200 liter samples) with small volume methods that employed either direct beta counting, or beta counting after radiochemical purification (2-20-Liter samples). Unique to this study are the presentation of a novel 2 and 5 liter 234Th methods. This new method is an adaptation of 20-liter methods which are based on a coprecipitation of thorium with Mn oxides and the direct beta counting of the precipitate. These Mn coprecipitation methods were found to be superior to other methods due to ease of sample collection and processing and low overall analytical uncertainties.
    Repository Name: EPIC Alfred Wegener Institut
    Type: Article , isiRev
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  • 4
    Publication Date: 2019-07-16
    Repository Name: EPIC Alfred Wegener Institut
    Type: Article , isiRev
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  • 5
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    In:  EPIC3Journal of radioanalytical and nuclear chemistry, 248(3), pp. 795-799, ISSN: 0236-5731
    Publication Date: 2019-07-16
    Description: Thorium-234 is a naturally occurring radionuclide that has been widely studied in ocean sciences. These studies use the disequilibrium between the soluble parent uranium-238 (half-life = 4.5 x 109 years), and its particle reactive daughter, 234Th (half-life = 24.1 days), to quantify the in-situ removal rates of 234Th on sinking particles. Here, we present additional experiments that test a new 2-L procedure in which 234Th is co-scavenged with a MnO2 precipitate. Unlike other techniques, this method can be easily applied at-sea with an overall precision and accuracy of £ 5 %. Our experiments have sought to elucidate the effects of delaying reagent addition and precipitate filtration, differences in sample bottle types, and issues related to sample backgrounds and 234Th particulate sampling. Most of these experiments were conducted using water collected on repeated occupations of station ALOHA (22°45.0’N, 158°00.0’W), 100 km North of Oahu, Hawaii.
    Repository Name: EPIC Alfred Wegener Institut
    Type: Article , isiRev
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  • 6
    Publication Date: 2017-01-04
    Description: Author Posting. © The Authors, 2004. This is the author's version of the work. It is posted here by permission of American Society of Limnology and Oceanography for personal use, not for redistribution. The definitive version was published in Limnology and Oceanography 50 (2005): 311-327, doi:10.4319/lo.2005.50.1.0311.
    Description: We studied the effect of iron addition on particle export in the Southern Ocean by measuring changes in the distribution of thorium-234 during a 4 week Fe enrichment experiment conducted in the high-silicate high-nitrate waters just south of the Southern Antarctic Circumpolar Current Front at 172.5°W. Decreases in 234Th activity with time in the fertilized mixed layer (0-50m) exceeded those in unfertilized waters, indicating enhanced export of 234Th on sinking particles after Fe enrichment. The addition of Fe also affected export below the fertilized patch by increasing the efficiency of particle export through the 100 m depth horizon. Extensive temporal and vertical Lagrangian sampling allowed us to make a detailed examination of the 234Th flux model, which was used to quantify the fluxes of particulate organic carbon (POC) and biogenic silica (bSiO2). Iron addition increased the flux of both POC and bSiO2 out of the mixed layer by about 300%. The flux at 100 m increased by more than 700% and 600% for POC and bSiO2, respectively. The absolute magnitude of the POC and bSiO2 fluxes were not large relative to natural blooms at these latitudes, or to those found in association with the termination of blooms in other ocean regions. Our results support the hypothesis that Fe addition leads directly to significant particle export and sequestration of C in the deep ocean. This is a key link between ocean Fe inputs and past changes in atmospheric CO2 and climate.
    Description: This work was supported by the Division of Ocean Sciences at the U.S. National Science Foundation, the Biological and Environmental Research Office, Office of Science, U.S. Department of Energy, and for RIB Polar Star logistical support, Polar Programs at the U.S. National Science Foundation.
    Repository Name: Woods Hole Open Access Server
    Type: Preprint
    Format: 1612288 bytes
    Format: 1558016 bytes
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  • 7
    Publication Date: 2022-05-25
    Description: Author Posting. © Akadémiai Kiadó, 2008. This is the author's version of the work. It is posted here by permission of Springer for personal use, not for redistribution. The definitive version was published in Journal of Radioanalytical and Nuclear Chemistry 277 (2008): 253-259, doi:10.1007/s10967-008-0739-y.
    Description: 7Be is a cosmogenic isotope produced in the stratosphere and troposphere. 7Be has a half-life of 53.4 days and decays to 7Li emitting a 477 keV gamma line with a branching ratio of 0.104. It is predominantly washed out of the atmosphere through wet deposition. It is a tool for oceanographers to study air sea interaction and water mass mixing. Beryllium’s largely non-reactive nature in the open ocean makes it an excellent conservative tracer. Its conservative nature and extreme dilution in seawater also makes it difficult to concentrate and analyze. Early experiments at WHOI with Fe(OH)3 cartridges to directly collect 7Be by insitu underwater pumps proved ineffective. Collection efficiencies of the cartridges were too low to be consistently useful. At sea chemistry of whole water samples became the method of choice. The use of stable 9Be as a yield monitor further improved the accuracy of the procedure. The method was optimized at WHOI in 2005 using a seawater line that enters WHOI’s coastal research lab. The procedure was then used on an oceanographic cruise on the R/V Oceanus out of Bermuda in the oligotrophic Sargasso Sea.
    Description: The authors would like to thank DOE, ONR and NSF for funding of this research.
    Repository Name: Woods Hole Open Access Server
    Type: Preprint
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  • 8
    Publication Date: 2022-05-25
    Description: Author Posting. © American Geophysical Union, 2008. This article is posted here by permission of American Geophysical Union for personal use, not for redistribution. The definitive version was published in Geochemistry Geophysics Geosystems 9 (2008): Q04003, doi:10.1029/2007GC001651.
    Description: We report 238U-230Th-226Ra-210Pb-210Po, 232Th-228Ra and 235U-231Pa measurements for a suite of 14 geologically and geochemically well-characterized basaltic samples from the Samoan volcanoes Vailulu'u, Malumalu, and Savai'i. Maximum eruption ages based on the presence of parent-daughter disequilibria indicate that Vailulu'u is magmatically productive with young lavas (〈8 Ka) resurfacing both its summit crater and lower flanks. 210Pb and 210Po measurements indicate that several flows have erupted within its summit crater in the past 100 years, with the newest observed flow being erupted in November of 2004. For lavas which have eruption ages that are demonstrably young, relative to the half-lives of 230Th, 231Pa, and 226Ra, we interpret their 238U -230Th, 235U-231Pa and 230Th - 226Ra disequilibria in terms of the magmatic processes occurring beneath the Samoan Islands. (230Th/238U) 〉 1 indicates that garnet is required as a residual phase in the magma sources for all these lavas. The large range of (238U/232Th) and (230Th/232Th) is attributed to long-term source variation. The Samoan basalts are all alkaline basalts and show significant 230Th and 231Pa excesses but limited variability, indicating that they have been derived by small but similar extents of melting. Their (230Th/238U), (231Pa/235U) and Sm/Nd fractionation are consistent with correlations among other ocean island basalt suites (particularly Hawaii) which show that (230Th/238U) and (231Pa/235U) of many OIBS can be explained by simple time-independent models. Interpretation of the 226Ra data requires time-dependent melting models. Both chromatographic porous flow and dynamic melting of a garnet peridotite source can adequately explain the combined U-Th-Ra and U-Pa data for these Samoan basalts. Several young samples from the Vailulu'u summit crater also exhibit significant 210Pb deficits that reflect either shallow magmatic processes or continuous magma degassing. In both cases, decadal residence times are inferred from these 210Pb deficits. The young coeval volcanism on Malumalu and Vailulu'u suggests the Samoa hot spot is currently migrating to the northeast due to dynamic interaction with the Tonga slab.
    Description: Support for this research was provided by NSF grants EAR-9909473 (KWWS), EAR-0509891 (SRH), EAR- 0609670 (MKR) and EAR-0504362 (MKR).
    Keywords: U-series disequilibria ; Samoa ; Eruption ages
    Repository Name: Woods Hole Open Access Server
    Type: Article
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  • 9
    Publication Date: 2023-08-28
    Description: A manganese nodule was recovered from station No. 18 of cruise Mn-74-01 of the R/V Moana Wave as part of the field work of the NSF-IDOE Inter-University Ferromanganese Research progam in 1974. The whole sample was first treated by 5M hydrochloric acid anf later digested with hydrochloric, perchloric and hydrofluoric acids. The soluble part was analysed by Atomic Absorption for nickel, cobalt and copper content.
    Keywords: Atomic absorption spectrophotometry; Cobalt; Copper; Deposit type; FFGR; Free-fall grab; Geochemistry; Identification; manganese micronodule; manganese nodule; Mn-74-01 IODE; Moana Wave; MW7401; MW7401-04G18; Nickel; NOAA and MMS Marine Minerals Geochemical Database; NOAA-MMS; Nodules, size; ocean; Pacific Ocean; sediment
    Type: Dataset
    Format: text/tab-separated-values, 6 data points
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  • 10
    Publication Date: 2023-08-28
    Description: Manganese nodules and crusts from stations of the SO06 expedition (R/V Sonne) in the Aitutaki Passage have been selected for chemical analysis of Ti, Mo and Pb using atomic absorption spectrophotometry. Material has been dried before analysis at 105°C for 72 hrs and results are presented as averages over various size fractions.
    Keywords: Atomic absorption spectrophotometry; BCR; Box corer (Reineck); Deposit type; DEPTH, sediment/rock; Elevation of event; Event label; FFGR; Free-fall grab; Geochemistry; Identification; Latitude of event; Lead; Longitude of event; manganese micronodule; manganese nodule; Molybdenum; NOAA and MMS Marine Minerals Geochemical Database; NOAA-MMS; Nodules, size; ocean; Pacific Ocean; Sample type; sediment; Shape; SO06; SO06_155GB; SO06_165GB; SO06_192GB; SO06_202KG; SO06_208GB; SO06_229GB; SO06_240GB; SO6/2-K-Loc24-155; SO6/2-K-Loc25-165; SO6/2-K-Loc27-192; SO6/2-K-Loc30-202; SO6/2-K-Loc31-208; SO6/2-K-Loc34-229; SO6/2-K-Loc36-240; Sonne; Texture; Titanium
    Type: Dataset
    Format: text/tab-separated-values, 421 data points
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