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  • Articles  (34)
  • Springer  (28)
  • Wiley  (6)
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  • Articles  (34)
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  • 1
    Electronic Resource
    Electronic Resource
    Springer
    Applied physics 54 (1992), S. 120-123 
    ISSN: 1432-0630
    Keywords: 72.70 ; 73.40
    Source: Springer Online Journal Archives 1860-2000
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: Abstract We report on temperature (77 to 300 K) and voltage dependent low frequency (100 Hz to 100 kHz) noise behavior of InGaAs/InP photodiodes in non-equilibrium steady state. In addition to common white, 1/f, and Lorentz noise we are able to observe for the first time minima and maxima in the photocurrent noise spectra. The recombination of a pair of free carriers through a recombination center at the heterointerface provides the correlation between the electron and hole ensembles necessary to explain the observed noise reduction.
    Type of Medium: Electronic Resource
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  • 2
    ISSN: 1432-1858
    Source: Springer Online Journal Archives 1860-2000
    Topics: Electrical Engineering, Measurement and Control Technology , Technology
    Notes: Abstract  Microsystems recently have been introduced as tools for screening in modern chemistry, biochemistry and biology. It has been shown that new microsystems can be implemented in the biomedical laboratory by using the microsystemic approach for the sample carrier – the miniaturized microtiter plate (“the nanotiter plate”) – or the production of nanodroplets with ink jetters and to integrate those systems in macrodevices like xyz tables and detection devices like CCD-cameras. We show in this paper that decisive problems of the approach – the evaporation problem and the problem of chemical/biochemical/biological compatibility of the assays and the used materials can be solved successfully. It is possible to realize chemical synthesis in miniaturized flow systems and to perform isothermal amplification of RNA in silicon wafers. Furthermore real high throughput screening with in vivo systems can be performed and all relevant parameters as evaporation, pipetting and detection can be controlled on reasonable time scales.
    Type of Medium: Electronic Resource
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  • 3
    Electronic Resource
    Electronic Resource
    Springer
    Journal of thermal analysis and calorimetry 50 (1997), S. 569-586 
    ISSN: 1572-8943
    Keywords: crystal structure ; metal(II) picolinate and quinaldinate ; thermal degradation of imidazole and pyrazole complexes
    Source: Springer Online Journal Archives 1860-2000
    Topics: Chemistry and Pharmacology
    Notes: Abstract Complexes of the type M(Pa)2(HAz)2 and M(QA)2(HAz)2 (M=cobalt(II) and nickel(II); HPa=picolinic acid, HQa=quinaldic acid; HAz=azoles like imidazole (Him), pyrazole (HPz), benzimidazole (HBzIm) etc.) show a similar thermal behaviour. In the first step of decomposition the corresponding azolinium picolinates or quinaldinates (H2AzPa, H2AzQa) are split off with formation of polymeric mixed ligand complexes M(Pa)(Az) or M(Qa)(Az). X-ray analysis of Co(Qa)2(HBzIm)2 XIIIa illustrates a proton transfer and a subsequent thermal removal of benzimidazolinium quinaldinate (H2BzImQa): Hydrogen bridges from pyrrole nitrogen of the benzimidazole to the non-coordinated oxygen of the quinaldinate predetermine the thermal initiated proton transfer. The high volatility of the heterocyclic acids and the nitrogen coordination are responsible for the formation of the mixed ligand complex Co(Qa)(BzIm) XIVa. Exceptions are the complexes M(Pa)2(HPz)2 XIa-b and M(Qa)2(HIm)2 XVIIa-b. Pyrazole is eliminated from the complexes XIa-b with formation of the solvent-free inner complex M(Pa)2 XIIa-b. From compounds XVIIIa-b quinaldic acid or their decomposition products are split off and a high temperature modification of M(Im)2 XVIIIa-b is formed at elevated temperature. XVIIIa-b are decomposed to the cyanides M(CN)2 similarly to the thermal behaviour of Cu(Im). In the first step the thermal degradation of imidazole and pyrazole adducts of copper(II) picolinates and quinaldinates is characterized by the elimination of azoles. The reason for this thermal behaviour is the weaker coordination of the azole heterocycles in copper chelate compounds.
    Type of Medium: Electronic Resource
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  • 4
    Electronic Resource
    Electronic Resource
    Springer
    Journal of thermal analysis and calorimetry 38 (1992), S. 239-253 
    ISSN: 1572-8943
    Keywords: complexes ; coordination chemistry
    Source: Springer Online Journal Archives 1860-2000
    Topics: Chemistry and Pharmacology
    Description / Table of Contents: Zusammenfassung Das Zersetzung Verhalten der Komplexverbindungen vom Typ C0D2I2 (P = acetylaceton, Benzoylaceton;I = Imidazol oder Derivate) erfolgt stufenweise. Im Falle vonD = Acetylaceton erfolgt zuerst eine Eliminierung von Acetylaceton wärend beiD = Benzoylaceton zuerst ein Heteroligand eine Abspaltung erfährt. Bei einer unsubstituiertenΒ-Position von Nickelacyclen des Typs (bipy)Ni(CH2CH2CH2COO) erfolgt eine thermisch induzierteΒ-Hydrideliminierung unter Ringspaltung und Freisetzung von CO2. Im Gegensatz zur hohen thermischen Stabilität des Trimesityl Aluminium erfahren die Zwischenverbindungen Almes2Cl und AlmesCl2 mit abnehmenden Mesityl- bzw. zunehmenden Chlorgehalt einen wessentlich früheren thermischen Zerfall. Bei zunehmenden Kovalenzgrad ist hier ein Einfluss der veränderten Polarisation anzunehmen. Der thermische Abbau der prinzipiell wasserhaltig kristallisierenden Nickelchelate von alkylsubstituierten Chinolin-8-ol beginnt jeweils mit der Dehydratisierung. In Abhängigkeit von der Kettenlänge und der Position der Substitution am Chinolin schliesst sich der thermische Abbau der Chelatliganden ein- bzw. mehrstufig an.
    Notes: Abstract The behaviour of complexes of the type MeD2I2 (Me=Co,D = acetylacetone or benzoylacetone,I = imidazole and derivatives in the course of the stepwise thermal degradation is different. In the case ofD = acetylacetone in the first step acetylacetone is split off. At D = benzoylacetone the decomposition starts with the partial elimination of the heterocyclic ligands. InΒ-position unsubstituted nickelacyclic complexes from type (bipy)Ni(CH2CH2CH2COO) decompose by a reductive elimination and separating of CO2 forming a ‘(bipy)Ni’-intermediate. A single reductive decoupling is hindered by blocking up theΒ-position. Opposite to the high thermal stability of the trimesityl aluminium the intermediates Almes2Cl and AlmesCl2 show with decreasing amounts of mesityl groups and increasing content of halogene, respectively, a significant decreasing thermal stability. The thermal degradation of nickelchelates of alkylsubstituted chinolin-8-ol starts with the dehydration followed by a different separation of the ligands as a function of the chain-length and the position of the substituents of the ligands.
    Type of Medium: Electronic Resource
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  • 5
    ISSN: 1434-6052
    Source: Springer Online Journal Archives 1860-2000
    Topics: Physics
    Notes: Abstract. We analyze the dependence of heavy quark free energies on the baryon chemical potential μb in 2-flavor QCD by performing a 6th order Taylor expansion in the chemical potential which circumvents the sign problem. The bare quark mass at $\hat m / T = 0.4$ corresponds to a pion mass of about 770 MeV and is thus not in the range of physical quark masses but the quark mass dependence is known to be small above Tc. At Nτ = 4 the lattices are coarse, however, we are using improved (p4 staggered) fermions. The Taylor expansion coefficients of color singlet and color averaged free energies are calculated and from this the expansion coefficients for the corresponding screening masses are determined. We find that for small μb the free energies of a static quark-antiquark pair decrease in a medium with a net excess of quarks and that screening is well described by a screening mass which increases with increasing μb. The μb-dependent corrections to the screening masses are well described by perturbation theory for T ≳ 2Tc. In particular, we find for all temperatures above Tc that the expansion coefficients for singlet and color averaged screening masses differ by a factor 2.PACS. 11.15.Ha, 11.10.Wx, 12.38Gc, 12.38.Mh
    Type of Medium: Electronic Resource
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  • 6
    Publication Date: 2019
    Description: Abstract Natural floodplains are characterized by a complex habitat mosaic. However, damming, water storage, and hydropower production affect many floodplains by altering their natural habitat diversity. Field sampling data and imaging spectroscopy are used in combination with statistical models to assess resource allocation strategies of willow stands in perialpine floodplains. Three contrasting floodplain reaches located along two rivers in Switzerland serve as test beds: The Sarine River is partitioned into an upstream and downstream segment under the influence of a dam and a hydropower plant, while the Sense River represents an undisturbed, natural floodplain. Airborne imaging spectrometer data allow mapping of spatially distributed Competitor/Stress tolerator/Ruderal (CSR) strategies using a partial least square modeling approach. Using cross validation, we demonstrate that a statistical modeling approach can reveal variations in CSR scores based on the StrateFy model. Such intraspecific variation of CSR scores cannot be captured by a strategy categorization based solely on the species. Results reveal that willows shifted toward more competition and less stress tolerance along hydrologically altered reaches compared to the willows strategy along the natural control. Moreover, the overall distribution of strategies indicates that stress factors (i.e., limiting growth factors), rather than disturbance (i.e., events leading to partial or total destruction), shape the plant traits of alluvial willow trees. Detailed assessments of resource allocation strategies contribute to a more complete understanding of the continuous and reciprocal shaping between flow regimes, landforms, and alluvial vegetation.
    Print ISSN: 2169-8953
    Electronic ISSN: 2169-8961
    Topics: Biology , Geosciences
    Published by Wiley on behalf of American Geophysical Union (AGU).
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  • 7
    Publication Date: 2011-10-29
    Description: Natural floodplains are spatially heterogeneous and dynamic ecosystems, but at the same time, a highly endangered landscape feature due to climate change and human impacts such as water storage, flood control and hydropower production. Flow is considered a master variable that shapes channel morphology, and the heterogeneity, distribution, and turnover of floodplain habitats. Despite their highly dynamic nature, the relative abundance of different habitat elements (islands, gravel bars) in natural floodplains seems to remain relatively constant over ecological time periods, and is referred to as the “shifting mosaic steady state” concept. In this conceptual context, we analysed spatio-temporal changes in relative habitat abundance and channel complexity of an alpine floodplain from its near natural state in 1940 before water abstraction and levee construction till 2007 using historical aerial images. Within the first decades of impairment, the relative abundance of floodplain habitats that depend on flood and flow pulses such as parafluvial channels and islands shifted towards a greater abundance of terrestrial forest and grassland habitats. After 1986, the duration and frequencies of high precipitation events (〉60 mm 24 h -1 ) triggering major, channel-reworking floods increased substantially and caused a restructuring of the floodplain and decrease in the abundance of more terrestrial habitat types. These results are contrary to expectations of the “shifting mosaic steady state” concept, yet suggest its potential application as an indicator of landscape transformation and human impacts on floodplain ecosystems. Lastly, the results raise the applied question as to whether an increased frequency of high flow events induced by climate change can contribute to floodplain restoration. Copyright © 2011 John Wiley & Sons, Ltd.
    Print ISSN: 0885-6087
    Electronic ISSN: 1099-1085
    Topics: Architecture, Civil Engineering, Surveying , Geography
    Published by Wiley
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  • 8
    Publication Date: 2006-02-03
    Print ISSN: 1434-6044
    Electronic ISSN: 1434-6052
    Topics: Physics
    Published by Springer
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  • 9
  • 10
    Publication Date: 2015-06-01
    Print ISSN: 1434-6001
    Electronic ISSN: 1434-601X
    Topics: Physics
    Published by Springer
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