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  • Articles  (121)
  • air pollution  (74)
  • acid deposition  (49)
  • Energy, Environment Protection, Nuclear Power Engineering  (121)
  • Ethnic Sciences  (1)
  • 1
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    Amsterdam : Elsevier
    Radiation Physics and Chemistry 42 (1993), S. 525-529 
    ISSN: 0969-806X
    Keywords: Electron accelerators ; air pollution ; curing ; radiation processing ; trichloroethylene
    Source: Elsevier Journal Backfiles on ScienceDirect 1907 - 2002
    Topics: Chemistry and Pharmacology , Energy, Environment Protection, Nuclear Power Engineering , Physics
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  • 2
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    Amsterdam : Elsevier
    Environmental Pollution 86 (1994), S. 233-238 
    ISSN: 0269-7491
    Keywords: Alps ; Norway spruce ; air pollution ; ozone
    Source: Elsevier Journal Backfiles on ScienceDirect 1907 - 2002
    Topics: Energy, Environment Protection, Nuclear Power Engineering
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  • 3
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    Amsterdam : Elsevier
    Environmental Pollution 84 (1994), S. 131-138 
    ISSN: 0269-7491
    Keywords: air pollution ; bioindicators ; element ratios ; geochemical relations ; heavy metals
    Source: Elsevier Journal Backfiles on ScienceDirect 1907 - 2002
    Topics: Energy, Environment Protection, Nuclear Power Engineering
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  • 4
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    Amsterdam : Elsevier
    Environmental Pollution 86 (1994), S. 109-114 
    ISSN: 0269-7491
    Keywords: air pollution ; canker ; disease ; ozone ; plant
    Source: Elsevier Journal Backfiles on ScienceDirect 1907 - 2002
    Topics: Energy, Environment Protection, Nuclear Power Engineering
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  • 5
    ISSN: 1539-6924
    Keywords: Threshold ; measurement error ; mortality ; air pollution
    Source: Springer Online Journal Archives 1860-2000
    Topics: Energy, Environment Protection, Nuclear Power Engineering
    Notes: Abstract The association between daily fluctuations in ambient particulate matter and daily variations in nonaccidental mortality have been extensively investigated. Although it is now widely recognized that such an association exists, the form of the concentration–response model is still in question. Linear, no threshold and linear threshold models have been most commonly examined. In this paper we considered methods to detect and estimate threshold concentrations using time series data of daily mortality rates and air pollution concentrations. Because exposure is measured with error, we also considered the influence of measurement error in distinguishing between these two completing model specifications. The methods were illustrated on a 15-year daily time series of nonaccidental mortality and particulate air pollution data in Toronto, Canada. Nonparametric smoothed representations of the association between mortality and air pollution were adequate to graphically distinguish between these two forms. Weighted nonlinear regression methods for relative risk models were adequate to give nearly unbiased estimates of threshold concentrations even under conditions of extreme exposure measurement error. The uncertainty in the threshold estimates increased with the degree of exposure error. Regression models incorporating threshold concentrations could be clearly distinguished from linear relative risk models in the presence of exposure measurement error. The assumption of a linear model given that a threshold model was the correct form usually resulted in overestimates in the number of averted premature deaths, except for low threshold concentrations and large measurement error.
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  • 6
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    Biodegradation 4 (1993), S. 283-301 
    ISSN: 1572-9729
    Keywords: air pollution ; biofiltration ; bioremediation ; bioscrubbing ; off-gas treatment
    Source: Springer Online Journal Archives 1860-2000
    Topics: Biology , Energy, Environment Protection, Nuclear Power Engineering , Agriculture, Forestry, Horticulture, Fishery, Domestic Science, Nutrition
    Notes: Abstract This paper gives an overview of present biological techniques for the treatment of off-gases and the techniques that are being developed at the moment. The characteristics, advantages, disadvantages, costs and application area are discussed and compared. Biological off-gas treatment is based on the absorption of volatile contaminants in an aqueous phase or biofilm followed by oxidation by the action of microorganisms. Biofilters, bioscrubbers and biotrickling filters are used for elimination of odour and bioconvertable volatile organic and inorganic compounds and are enjoying increasing popularity. This popularity is a result of the low investment and operational costs involved compared to physico-chemical techniques and the elimination efficiencies that can be obtained. The operational envelop is still extending to higher concentrations and gas flow rates (exceeding 200,000 m3 h−1) and a broader spectrum of degradable compounds. Research and development on the use of membranes and the addition of activated carbon or a second liquid phase to the biological systems may lead to a more efficient elimination of hydrophobic compounds and buffering of fluctuating loads. Shorter adaptation periods can be obtained by inoculation with specialized microorganisms. Improved design and operation are made possible by the growing insights in the kinetics and microbiology and supported by the development of models describing biological off-gas treatment. In conclusion, biotechniques are efficient and cost effective in treating off-gases with concentrations of biodegradable contaminants up to 1–5 g/m3. They could play a justified and important role in air pollution control in the coming years.
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  • 7
    ISSN: 1572-9729
    Keywords: Picea rubens ; Abies fraseri ; acid deposition ; forest decline
    Source: Springer Online Journal Archives 1860-2000
    Topics: Biology , Energy, Environment Protection, Nuclear Power Engineering , Agriculture, Forestry, Horticulture, Fishery, Domestic Science, Nutrition
    Notes: Abstract Annual and seasonal rates of net nitrogen mineralization were determined for 19 sites in the spruce-fir forests of the Southern Appalachian Mountains. These sites included high and low elevation stands of red spruce (Picea rubens Sarg.) and Fraser fir (Abies fraseri (Pursh.) Poir.) on east and west exposures on Whitetop Mountain, Virginia; Mt. Mitchell, North Carolina; and Clingman's Dome in the Great Smoky Mountains National Park. Mineralization rates were determined using in situ soil incubations in PVC tubes with ion exchange resin bags placed in the bottom of the tubes to collect leachate. Throughfall was collected in resin bags placed in the top of the tubes. Average initial NH4-N + NO3-N ranged from 0.6 to 4.8 kg N/ha across all plots, and average mineralization rates ranged from 26 to 180 kg-N ha−1 yr−1. Throughfall ranged from 18 to 32 kg-N ha−1 yr−1 with NH4-N accounting for about two-thirds of the throughfall N across all sites. Throughfall and mineralization rates were not related to elevation or exposure. The high rates of N mineralization and relatively high nitrate concentrations indicate that leaching losses of nitrogen and associated cations could be substantial.
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  • 8
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    Water, air & soil pollution 85 (1995), S. 2205-2210 
    ISSN: 1573-2932
    Keywords: Trend ; gas ; aerosol ; bulk precipitation ; throughfall ; acid deposition
    Source: Springer Online Journal Archives 1860-2000
    Topics: Energy, Environment Protection, Nuclear Power Engineering
    Notes: Abstract Since 1985 measurements of gasses, aerosols, precipitation and throughfall have been carried out at three forest sites in Denmark with equal aged Norway Spruce plantations. The times series show a downward trend in the concentration of sulphur dioxide. Particulate sulphate, ammonia and particulate ammonium and the total nitrate seem to have a more constant concentration level. The wet deposition measurements show a decreasing trend in the content of acid (protons), sulphate, ammonium and nitrate, though for the nitrogen compounds it is only a slight fall. A decrease in concentrations of protons and sulphate is also seen in the throughfall measurements, in throughfall the nitrogen compounds hardly seem to decrease.
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  • 9
    ISSN: 1573-2932
    Keywords: air pollution ; sulphur ; nitrogen ; base cations ; throughfall ; Scots pine ; needle elements ; soil leachate ; N.-W. Russia
    Source: Springer Online Journal Archives 1860-2000
    Topics: Energy, Environment Protection, Nuclear Power Engineering
    Notes: Abstract Bulk precipitation and throughfall analyses in 50–100-year-old Scots pine stands revealed decreasing sulphur, nitrogen, calcium and magnesium deposition gradients, which extend from the St. Petersburg-Leningrad region and N.-E. Estonia to S.-E. Finland. The Ca and Mg deposition alleviate the acidifying effect of sulphur and nitrogen. The Scots pine canopies acted as a sink for ammonium and nitrate, while the canopy interactions increased sulphur, calcium and magnesium content in throughfall. Foliar S, N and Ca concentrations correlated positively with the corresponding deposition loads. In contrast, low foliar magnesium concentrations were detected in the vicinity of St. Petersburg. The results indicate that the sulphur and calcium deposition may have increased soil leachate S and Ca concentrations in the most polluted Scots pine stands.
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  • 10
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    Environmental and resource economics 16 (2000), S. 31-50 
    ISSN: 1573-1502
    Keywords: air pollution ; logit specification ; PM10 ; work loss days
    Source: Springer Online Journal Archives 1860-2000
    Topics: Energy, Environment Protection, Nuclear Power Engineering , Economics
    Notes: Abstract During the last decade an increasing amount of studies have investigatedthe relationship between air pollution and human health effects. In thisstudy we investigate how these effects in turn induce reduced labourproductivity in terms of sick-leaves, which is an important factor inassessment of air pollution costs in urban areas. For this purpose weemploy a logit model along with data on sick-leaves from a large office inOslo and different air pollutants. Our results indicate that sick-leaves aresignificantly associated with particulate matter (PM10), while theassociations with SO2 and NO2, are more ambiguous. We also tryto estimate the induced social costs in terms of lost labour productivity andincreased governmental expenditures, although these estimates are moreuncertain.
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  • 11
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    Environmental and resource economics 3 (1993), S. 381-394 
    ISSN: 1573-1502
    Keywords: Hedonic models ; air pollution ; meta analysis
    Source: Springer Online Journal Archives 1860-2000
    Topics: Energy, Environment Protection, Nuclear Power Engineering , Economics
    Notes: Abstract This paper reports a meta analysis of how effectively hedonic property models have detected the influence of air pollution on housing prices. Probit estimates are reported describing how data, model specification, and local property market conditions in cities represented in thirty-seven studies influence the ability of hedonic models to uncover negative, statistically significant relationships between housing prices and air pollution measures.
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  • 12
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    Environmental and resource economics 5 (1995), S. 115-129 
    ISSN: 1573-1502
    Keywords: Emission trading ; United States ; sulfur dioxide ; air pollution ; costs ; cost-effectiveness
    Source: Springer Online Journal Archives 1860-2000
    Topics: Energy, Environment Protection, Nuclear Power Engineering , Economics
    Notes: Abstract In 1990, the U.S. Congress passed legislation that amended the Clean Air Act to create a new program to mitigate the effects of acid deposition in the U.S. through emission reductions of sulfur dioxide (SO2) and nitrogen oxides (NOx) at electric utility plants across the country. The SO2 reductions, totalling a 40% reduction nationally from 1980 levels or a 10 million ton reduction annually, are achieved largely through an emission trading system, the largest program of its kind designed to date. This trading system has the potential to save up to half of the compliance costs associated with more traditional source-by-source emission limit programs. This paper briefly discusses background on the acid rain issue in the United States, and the principal features of the program, including: a permanent cap on utility emissions of SO2 beginning in 2010, decision to grant up-front allocation of emission credits to reduce individual approvals of trades, the use of continuous emission monitors and automatic penalties to ensure compliance, and integration of the Acid Rain program requirements with other Clean Air Act programs. The paper also discusses the development of the allowance trading market to date, including the types of compliance options chosen and quantity and type of emissions trading being conducted.
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  • 13
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    Environmental and resource economics 4 (1994), S. 305-330 
    ISSN: 1573-1502
    Keywords: Emission trading ; air pollution ; economic instruments ; costs ; europe ; sulfur
    Source: Springer Online Journal Archives 1860-2000
    Topics: Energy, Environment Protection, Nuclear Power Engineering , Economics
    Notes: Abstract This paper explores the analytical and empirical properties of a new method for emission trading according to a fixed exchange rate. The exchange rate is based on the ratios of the marginal costs of abatement in the optimal solution in order to account for the impact of the location of emission sources on the deposition. It is shown that, generally, this system will not achieve the optimal solution and does not guarantee that environmental deposition constraints are not violated, although total abatement costs are always reduced. A routine was developed to mimic trading as a bilateral, sequential process, subject to an exchange rate. In the example used, results for SO2 emissions in Europe show that, starting from a uniform reduction, exchange-rate trading achieves higher cost savings than one-to-one trading, without achieving the cost minimum. Sulfur deposition targets are not violated since the initial emission allocation overfulfilled targets at many places. The results are sensitive to: pre-trade emission levels, the transaction costs, the availability of information on potential cost savings and assumptions made on the behavior of trading partners.
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  • 14
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    Environmental and resource economics 8 (1996), S. 485-499 
    ISSN: 1573-1502
    Keywords: contingent valuation ; ordering effects ; air pollution ; health damage
    Source: Springer Online Journal Archives 1860-2000
    Topics: Energy, Environment Protection, Nuclear Power Engineering , Economics
    Notes: Abstract This paper focuses on ordering effects in CVM surveys; how the expressed value of a particular good valued in a sequence of several goods depends on where in the sequence the good is valued. We use data from a Norwegian CVM survey focusing on WTP for a 50% reduction in air pollution from car traffic to test for the existence of ordering effects and to apply a test for internal consistency. We found considerable and significant ordering effects in our data, but were not able to reject the hypothesis of internal consistency. Based on our survey, we argue that ordering effects may be a result of rational choice. These effects are problematic if a sequential valuation procedure is applied to a simultaneous problem, and/or the respondents are given imperfect information about the decision problem.
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  • 15
    ISSN: 1573-2932
    Keywords: acid deposition ; heavy metals ; cadmium ; soil contamination
    Source: Springer Online Journal Archives 1860-2000
    Topics: Energy, Environment Protection, Nuclear Power Engineering
    Notes: Abstract Simultaneous soil acidification and deposition of heavy metals is a major concern for forest and agricultural soils of the Black Triangle region of East Central Europe including southern former East Germany, northern Bohemia of the Czech Republic, and southern Poland. The objective of this project was to develop historical and future projections of acid and heavy metal deposition to soils (As, Cd, Pb, Zn) and to produce a preliminary map of soil sensitivity to cadmium pollution and uptake by crops. Ultimately, we wish to assess the relative hazard and recovery times of soils to metals deposition in the region. Emission and deposition data bases obtained from several models developed at IIASA were linked using the Geographical Information System ARC/INFO to produce soil maps of sensitivity to cadmium mobility based on metals deposition, soil type, soil texture, organic matter content, and acid deposition. RAINS 6.1 (Alcamo et al., 1990) was utilized to produce maps of acid deposition for EMEP grids (150 km x 150 km). The largest amount of acid load is deposited in southern East Germany. Sulfur deposition in that area was 10–12 gS/m2/yr in 1990, and S+N deposition exceeded 8000 eq/ha/yr. But the “hot spot” for metals deposition is further to the east, in the Silesia area of southern Poland. The TRACE2 trajectory model of Alcamo, Bartnicki, and Olendrzynski (1992) was used to estimate cumulative metals deposition since 1955 with scenarios to 2010. Pb has improved over Europe since 1970 when depositions in the Ruhr River Valley of West Germany exceeded 60 mg/m2/yr. But cadmium deposition in southern Poland (Katowice and Krakow) has now accumulated to 60–70 mg/m2 by atmospheric deposition alone. During base case simulations from 1955–87, approximately 1.8 mg/kg Pb and 0.12 mg/kg Cd have been added to the mixed plow-layer of ∼30 cm. If these emissions continue indefinitely, the accumulation of metals will become problematic for agriculture and the food chain.
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  • 16
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    Water, air & soil pollution 85 (1995), S. 499-504 
    ISSN: 1573-2932
    Keywords: Surface water ; water chemistry ; DOC ; liming ; acid deposition
    Source: Springer Online Journal Archives 1860-2000
    Topics: Energy, Environment Protection, Nuclear Power Engineering
    Notes: Abstract Northern Sweden has been regarded as unaffected by acid deposition, but many surface waters in the region fall within the definition of acid surface water (pH 〈 6.0, alkalinity 〈 50 mmolc m−3) permanently or during episodes. Approximatly 100 MSEK in spent annually on liming in northern Sweden. This paper summarizes our conclusions from a workshop on natural versus anthopogenic acidification held in February 1995. It was shown that organic substances have a key role in determining the acidity of surface waters in the region, although anthropogenic effects are documented in some coastal systems and in the southern mountain range. Sulfide oxidation occurs by the coast. It appears clear that many surface waters that were naturally acidic have been limed to unnatural pH levels. New criteria to screen liming candidates should be developed, and one such model based on water chemistry data is proposed.
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  • 17
    ISSN: 1573-2932
    Keywords: forest decline ; SO2 ; sulfate ; tandem filter ; throughfall ; acid deposition
    Source: Springer Online Journal Archives 1860-2000
    Topics: Energy, Environment Protection, Nuclear Power Engineering
    Notes: Abstract During the period from 25 May 1991 to 30 May 1992 the atmospheric concentrations and depositions of oxides of sulfur were continuously measured in a suburban masson pine forest which is currently experiencing severe dieback, in Chongqing, China. The annual mean concentrations of SO2 and particulate SO4 2− were 220 μ g/m3 (77 ppbv) and 32 μ g/m3 respectively. The atmospheric concentrations of these sulfur compounds were high in late autumn and winter. The annual wet and dry depositions of sulfur to the forest as measured by throughfall and stemflow were 93.1 and 46.6 kgSha−1a−1 respectively. These depositions are among the highest level ever reported in the world. Althogh the cause of the dieback of the masson pine trees has not been unequivocally determined, it is probable that the direct impact of SO2 is more likely the cause than acid deposition.
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  • 18
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    Water, air & soil pollution 85 (1995), S. 1311-1316 
    ISSN: 1573-2932
    Keywords: Pakistan ; air pollution ; ozone ; nitrogen dioxide ; rice ; wheat ; filtration ; yield
    Source: Springer Online Journal Archives 1860-2000
    Topics: Energy, Environment Protection, Nuclear Power Engineering
    Notes: Abstract Open-top chambers ventilated with ambient or chiarcoal-filtered air were used to assess the impact of air pollution on the yield of local cultivars of wheat and rice, at a site on the outskirts of Lahore. At this location, 6-h mean O3 concentrations reach 60 ppb in certain months, and annual mean NO2 concentrations are 20–25 ppb. The experiments showed significant yield reduction in two successive seasons which ranged from 33% to 46% in wheat and from 37% to 51% in rice. The major yield parameter affected was the number of ears or panicles per plant, although there was also evidence of small effects on 1000 grain weight and on the number of grains per ear/panicle. These results have significance in terms of the maintenance of agricultural yields as pollution emissions rise in south and south-east Asia.
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  • 19
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    Water, air & soil pollution 85 (1995), S. 1569-1574 
    ISSN: 1573-2932
    Keywords: synoptic circulation ; principal components analysis ; air pollution ; climate change ; classification
    Source: Springer Online Journal Archives 1860-2000
    Topics: Energy, Environment Protection, Nuclear Power Engineering
    Notes: Abstract A classification of atmospheric circulation was derived using principal components analysis (PCA) of daily sea level pressure over a 10 year period. Correlation coefficients of up to 0.65 were obtained between the individual principal component loadings and monthly means of gas and precipitation ion concentrations for a Scottish and a Norwegian station from the European Monitoring and Evaluation Programme (EMEP) network. The mean synoptic patterns of months predicted to have high or low gas and ion concentrations from their component loadings agreed well with previous work. High concentrations occur frequently with southerly flow or anticyclonic conditions, and low concentrations with westerly and northwesterly flow. We conclude that the PCA classification is a sensible method to use to derive circulation pattern-pollutant relationships, and is an encouraging first step to use the general circulation model (GCM) projections of future climate to assess possible future air/precipitation composition patterns
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  • 20
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    Water, air & soil pollution 85 (1995), S. 1635-1640 
    ISSN: 1573-2932
    Keywords: forested catchment ; air pollution ; nutrients ; pollutants ; balance ; plant bioindicators ; forest damage
    Source: Springer Online Journal Archives 1860-2000
    Topics: Energy, Environment Protection, Nuclear Power Engineering
    Notes: Abstract This paper includes an overview of ecological studies conducted since 1986 in the Ratanica pine-beech forested catchment located in the polluted, high populated southern part of Poland. General characteristics of the catchment (including soil and vegetation, air pollution, input/output of nutrients and pollutants, element budget data and forest health assessment) are presented. Based on biogeochemical and bioindication results, the Ratanica catchment has been classified as a moderately to heavily deteriorated area. Predictions for this forested catchment for various deposition of anthropogenic pollutants, are also disscused.
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  • 21
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    Water, air & soil pollution 82 (1995), S. 77-85 
    ISSN: 1573-2932
    Keywords: boreal forests ; forest health ; air pollution ; detection
    Source: Springer Online Journal Archives 1860-2000
    Topics: Energy, Environment Protection, Nuclear Power Engineering
    Notes: Abstract The Canadian boreal forest covers 299.2 Mha which is two-thirds of Canada's forest and runs in a continuous belt from Newfoundland north and west to the Yukon. The major species are spruce, pines, balsam fir, white birch and trembling aspen often occurring in extensive monocultures. Wildfire is the driving successional force in the boreal forest and has remained so despite fire suppression activities and extensive harvesting. Insects and diseases also cause extensive damage. In order to ensure the sustainability of forests, it is necessary for the forest manager to know the condition of the health of these forests. The CFS established in 1984 the Acid Rain National Early Warning System in order to monitor the health of the forests. National results show that mortality is generally in the normal range of 1–3% and is caused by known stresses; insects, diseases and abiotic damage. No signs of pollution damage have been yet been detected in boreal forests by the system. An early warning system to detect and monitor conditions remains an essential part of our commitment to the sustainability of Canada's forests.
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  • 22
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    Water, air & soil pollution 85 (1995), S. 63-76 
    ISSN: 1573-2932
    Keywords: Forest damage ; soil acidity ; N-saturation ; acid deposition ; root growth ; drought
    Source: Springer Online Journal Archives 1860-2000
    Topics: Energy, Environment Protection, Nuclear Power Engineering
    Notes: Abstract A survey of leaf and needle losses of European forests in 1993 revealed that 23% of the total forested area had defoliation of more than 25%. The focus of this defoliation is in Central Europe, namely in Poland, Slowakia, Czech Republic, and Germany. The annual surveys of leaf losses and discoloration indicated only small changes during the last years for the coniferous forests in Germany. However, the increasing leaf losses of oak and beech during the last years were alarming. Evaluating the potential relation between air pollutant deposition, soil changes and forest damage, we focus here on the recent changes in deposition and soil conditions, and their implication on tree root development and drought susceptability of trees. While deposition of SO4 2−, H+ and Ca2+ in many Central European forests decreased in the last decade, input of NH4 + and NO3 − remained high or even increased. The H+ load of many forest soils today is thus still high compared to weathering rates, but the proportion of the H+ load resulting from turnover of deposited N has increased. Recent effects of changing depositions on acid forest soils were: depletion of soil Al-pools, release of formerly stored soil SO4 2−, accumulation of N in soil organic matter, increasing N availability to trees and decreasing concentration of Ca2+ in the soil solution. We hypothesise that soil acidification and increased N availability will decrease the fine root biomass of trees and shift the rooting zone to upper soil layers. Increased above ground growth, observed in many areas of Europe, will furthermore decrease the root/shoot ratio. This development will finally cause increased drought susceptability of trees and is thus of destabilizing nature. The proposed chain of events might be overlapped by other effects of air pollutants on forest ecosystems, namely direct effects of gases on leaves, nutritional inbalances, and interactions with pests.
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  • 23
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    Water, air & soil pollution 85 (1995), S. 167-176 
    ISSN: 1573-2932
    Keywords: air pollution ; health effects ; risk assessment
    Source: Springer Online Journal Archives 1860-2000
    Topics: Energy, Environment Protection, Nuclear Power Engineering
    Notes: Abstract Based on combined information available from air quality monitoring data and long-range transport models, European population exposure to SO2, NO2 and O3 has been estimated. This information has been combined with the results of epidemiological studies assessing strength of association between the exposure and health effects to estimate an impact of the pollution on health in Europe. The analysis indicates that a considerable number of health problems, ranging from mild irritation of the respiratory system to increased mortality, can be attributed to short-term peaks of pollution observed in Europe. Chronic impacts of prolonged elevated SO2 levels on lung function are estimated to occur in close to10 million people in Europe.
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  • 24
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    Water, air & soil pollution 85 (1995), S. 177-188 
    ISSN: 1573-2932
    Keywords: health ; air pollution ; acidity
    Source: Springer Online Journal Archives 1860-2000
    Topics: Energy, Environment Protection, Nuclear Power Engineering
    Notes: Abstract Earlier in this century, a number of severe episodes clearly demonstrated that air pollution can affect human health; these included documented increases in mortality and morbidity. Although health was clearly affected during these episodes and acidity is a candidate for the responsible agent, it has been difficult to ascertain which agents were involved. In the past several years extensive research was launched to learn the significance of acidic aerosols on human health. The question of a health threat from acid aerosols was first raised by epidemiology studies, but results of the body of epidemiological evidence collected to date have been mixed. Even when a study finds evidence of a response to exposures involving high ambient acidity levels, it is usually difficult to know which agent or agents are responsible for causing the effects noted. High levels of acidic aerosols are nearly always accompanied by high levels of other air pollutants which may have known or suspected effects on the respiratory tract. For this reason, an understanding of the potential mechanisms of acid aerosol health effects needs supporting evidence from the laboratory, where exposures to various agents can be controlled. To date, this supporting evidence includes demonstration of physiological responses at acidity levels greater than those that exist in the ambient environment. A limited number of studies have considered responses at levels more characteristic of ambient exposures; these studies demonstrate little physiological response, probably due to the airways' ability to buffer acidity at low concentration. Although there is some evidence of impaired mucociliary clearance and modest changes in lung function, there is no evidence of airway inflammation or altered non-specific bronchial responsiveness as a result of acid aerosol exposure. The possibility that acid aerosols may potentiate responses to other pollutants remains a subject of interest. The potential existence of a group of individuals who are exquisitely sensitive to low acid concentrations requires further investigation. Recent epidemiology results are broadening the perspective from a focus on acidity per se to a focus on fine particulate matter, of which particulate acidity is but a subset. These studies find a consistent statistical association between various health responses, including mortality, and ambient measures of particulates, even at locations where levels of acidity are very low and at locations where current U.S. air quality standards are satisfied. There is at present no biological explanation for these associations.
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  • 25
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    Water, air & soil pollution 85 (1995), S. 273-278 
    ISSN: 1573-2932
    Keywords: acid deposition ; expert meetings ; monitoring guidelines ; monitoring network ; East Asia ; Environment Agency of Japan
    Source: Springer Online Journal Archives 1860-2000
    Topics: Energy, Environment Protection, Nuclear Power Engineering
    Notes: Abstract Acid deposition is widely recognized as one of the most serious international atmospheric pollution problems. East Asian countries are currently experiencing acid deposition and have only recently begun expanding domestic research and monitoring activities. However, acid deposition is not only a domestic but also a transboundary problem. In addressing the transboundary aspect, cooperative and collaborative action will be essential. The Environment Agency of Japan is advocating the need to establish an acid deposition monitoring network in East Asia. Therefore, it is sponsoring three “Expert Meetings on Acid Precipitation Monitoring Network in East Asia” between 1993 and 1995. The meetings are attended by both scientific researchers and government officials from numerous East Asian countries. At the administrative and scientific discussions of the first two meetings a consensus on the desirability of establishing a monitoring network in East Asia was obtained and a preliminary technical guideline manual for monitoring acid deposition was adopted. By the end of the third meeting it is hoped that a basic consensus can be reached on a framework for an East Asian acid deposition monitoring network. It is essential to establish such a network in order to evaluate the present state of acid deposition in the region and to reach a common scientific understanding on the acid deposition problem. This is a vital step toward promoting international cooperation on the issue.
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  • 26
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    Water, air & soil pollution 85 (1995), S. 249-260 
    ISSN: 1573-2932
    Keywords: acid deposition ; integrated assessment ; modeling ; protocols
    Source: Springer Online Journal Archives 1860-2000
    Topics: Energy, Environment Protection, Nuclear Power Engineering
    Notes: Abstract During the last decade the issue of integrated assessment has received attention both in the scientific literature and in the negotiation of international air pollution agreements. More than often this literature does not differentiate between the integrated assessment as a process and the development and use of models as a tool for calculating the potentials of various scenarios. This paper describes the difference between the process and the tool, and illustrates this using the negotiations leading to the Second Sulfur Protocol (June 1994, Oslo). The situation in Europe (with a highly visible interaction between science and policy) will be compared with the United States (where new legislation was passed before the integrated assessment was finished). Further, the role of integrated assessment models in these negotiations will be discussed with special attention for the interaction between model builders and model users. Lessons from the recent European experience will be drawn. These include lessons for future protocols on acidification, and combined ozone/acidification/eutrophicationprotocols. These lessons will deal with the scale of the problem, the scope of the integrated assessment models, the development of models in parallel with scientific development and the various modes of interaction with the policy community.
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  • 27
    ISSN: 1573-2932
    Keywords: tropospheric ozone ; white clover ; air pollution ; biomonitor
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    Topics: Energy, Environment Protection, Nuclear Power Engineering
    Notes: Abstract A white clover (Trifolium repens L.) system using measured biomass to indicate effective concentrations of tropospheric ozone (O3) has been developed. The system utilizes the relative response of an O3-sensitive clone (NC-S) and an O3-resistant clone (NC-R) grown in 15-liter pots. Forage (leaves, stems and flowers) is cut, dried, and weighed at 28-day intervals. Forage dry weight ratios (NC-S/NC-R) for individual or multiple harvests indicate O3 concentrations during growth. In, 3 years of testing in open-top field chambers at Raleigh, North Carolina, O3 always decreased growth of NC-S more than that of NC-R and the NC-S/NC-R ratio routinely decreased as the O3 concentration increased. A national field test was performed in 1993 and 1994 to determine if the clover system can account for effects of climatic variables on clover growth per-se, and if climatic variables affect the relative response of the two clones to O3. Eight locations (Corvallis, Oregon; Kennedy Space Center, Florida; Delaware, Ohio; Amherst, Massachusetts; Blacksburg, Virginia; Raleigh, North Carolina; Riverside, California; San Bemardino mountains, California) provided large differences in O3 concentrations and climate. The NC-S/NC-R forage ratios for three consecutive 28-day growth periods for each year as related to the mean 12 hour per day O3 concentrations are presented in this manuscript. Ratios were generally highest where mean O3 concentrations were lowest (Oregon and Florida), lowest where mean O3 concentrations were highest (both California locations), and intermediate at other locations.
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  • 28
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    Water, air & soil pollution 85 (1995), S. 1855-1860 
    ISSN: 1573-2932
    Keywords: Acidification ; acid deposition ; liming ; forest soil ; surface waters ; aluminum ; alkalinity ; Sweden
    Source: Springer Online Journal Archives 1860-2000
    Topics: Energy, Environment Protection, Nuclear Power Engineering
    Notes: Abstract Acidification of surface waters and forest soils is severe in large parts of southern Sweden. The shallow groundwaters are also affected. Large scale liming of surface waters and streams is in operation, often combined with wetland liming to limit the effects of acid episodes, e.g. at snow melt. Acid episodes are perhaps the most severe problem in limed surface waters and in many as yet well buffered waters, because of temperature-layered acid inflow, often superficial. As a result of some investigations, a large scale forest liming programme covering 6.500–10.000 km2 was recently suggested. The main objectives of this forest liming programme are to retard cation depletion and to prevent nutrient imbalance and forest decline in acidified areas. This paper deals with the effects of forest soil liming on streams and surface waters. The response of water chemistry is very dependent on hydrological and soil properties. Although pH itself may be little affected by liming, the acidity (or negative ANC) decreases, inorganic Al-species decrease and the Al/BC-ratio increases in the runoff water. Especially interesting is that this is also true during acid episodes. This means that toxicity for acid sensitive biota decreases. These results indicate that large scale liming may have beneficial effects on surface water chemistry. Furthermore, as surface waters are expected to respond to smaller decreases in acid deposition than do forests soils, forest soil liming may allow less frequent liming of lakes. Consequently, forest soil liming in combination with the anticipated emission reductions may have very beneficial results on surface waters in certain areas of Sweden.
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  • 29
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    Water, air & soil pollution 89 (1996), S. 147-157 
    ISSN: 1573-2932
    Keywords: Neutralization ; acid deposition ; organic matter ; cation exchange
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    Topics: Energy, Environment Protection, Nuclear Power Engineering
    Notes: Abstract Batch acid addition experiments were carried out to determine the acid buffer capacities (amount of acid required to lower soil pH by one unit) of forest soils. Samples of O, E, B (or BC), and C horizons taken from 29 podzolic profiles in southern Finland were used in the experiments. Subsamples of soil were equilibrated for 24 h with NaCl solution containing additions of HCl acid. Cation exchange, mineral dissolution (weathering), and the protonation of organic matter all appeared to have been involved in the buffering of the acid additions. For the O horizon samples, most of the cations released in response to the acid additions were base cations. For the mineral soil samples, most of the cations released were Al3+ ions. With the exception of a few samples, the added acid was not fully neutralised and pH was lowered even with the lowest addition treatment. However, the acid addition treatments corresponded to many times the regional annual acid deposition load (1.6–2.0 cmol(c) m−2). Calculated acid buffer capacities (cmol(c) kg−1 pH−1) ranged from 9.8 to 40.8 for O horizon soil samples and from 0.1 (C horizon) to 5.2 (E horizon) for the mineral soil samples. Total acid buffer capacities for a profile (to a depth of 50 cm) ranged from 500 to 2349, with a mean value of 1091 cmol(c) m−2 pH−1. It is concluded that, in addition to CEC and base saturation, acid buffer capacity is a useful measure to describe the ecological effects of acid deposition on soil.
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    Water, air & soil pollution 93 (1997), S. 395-408 
    ISSN: 1573-2932
    Keywords: air pollution ; pine bark ; sulphur ; pH ; conductivity ; heavy metals
    Source: Springer Online Journal Archives 1860-2000
    Topics: Energy, Environment Protection, Nuclear Power Engineering
    Notes: Abstract Sulphur and heavy metal deposition in northern Finland (= in Lapland) and the Kola Peninsula were surveyed using Scots pine bark samples. Sulphur concentrations in bark close to the Kola smelters were on an average twice as high as on the Finnish side of the border. The Cu and Ni concentrations near the smelters were almost 100-fold the mean values in northern Finland. There was a marked decrease in the sulphur and heavy metal concentrations with increasing distance from the emission sources. The effects of emission from the Kola Peninsula were evident in Finland only close to the border, especially in the eastern parts of Inari (NE corner of Lapland) where the Cu and Ni concentrations were 2- to 6-fold those in western Lapland. The sulphur and heavy metal concentrations in most of northern Finland were low. However were the concentrations of Cr in bark in the SW corner of Lapland considerably high, due to the emissions from the Tornio refined steel plants.
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    Water, air & soil pollution 94 (1997), S. 163-180 
    ISSN: 1573-2932
    Keywords: acid deposition ; liming ; catchment ; lake ; water chemistry ; fish ; soil ; model
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    Topics: Energy, Environment Protection, Nuclear Power Engineering
    Notes: Abstract In June 1983 a whole-catchment liming experiment was conducted at Tjønnstrond, southernmost Norway, to test the utility of terrestrial liming as a technique to restore fish populations in remote lakes with short water-retention times. Tjønnstrond consists of 2 small ponds of 3.0 and 1.5 ha in area which drain a 25-ha catchment. The area is located at about 650–700 meters above sea-level in sparse and unproductive forests of spruce, pine and birch with abundant peatlands. A dose of 3 ton/ha of powdered limestone were spread by helicopter to the terrestrial area. No limestone was added to the ponds themselves. The ponds were subsequently stocked with brown and brook trout. Liming caused large and immediate changes in surface water chemistry; pH increased from 4.5 to 7.0, Ca increased from 40 to 200 μeq/L, ANC increased from –30 to +70 μeq/L, and reactive-Al decreased from about 10 to 3 μmol/L. During the subsequent 11 years the chemical composition of runoff has decreased gradually back towards the acidic pre-treatment situation. The major trends in concentrations of runoff Ca, ANC, pH, Al and NO3 in runoff are all well simulated by the acidification model MAGIC. Neither the measured data nor the MAGIC simulations indicate significant changes in any other major ion as a result of liming. The soils at Tjønnstrond in 1992 contained significantly higher amounts of exchangeable Ca relative to those at the untreated reference catchment Storgama. In 1992 about 75% of the added Ca remains in the soil as exchangeable Ca, 15% has been lost in runoff, and 10% is unaccounted for. The whole-catchment liming experiment at Tjønnstrond clearly demonstrates that this liming technique produces a long-term stable and favourable water quality for fish. Brown trout in both ponds in 1994 have good condition factors, which indicate that the fish are not stressed by marginal water quality due to re-acidification. The water quality is still adequate after 11 years and 〉20 water renewals. Concentrations of H+ and inorganic Al have gradually increased and approach levels toxic to trout, but the toxicity of these are offset by the continued elevated Ca concentrations. Reduced sulphate deposition during the last 4 years (1990–94) has also helped to slow and even reverse the rate of reacidification. The experiment at Tjønnstrond demonstrates that for this type of upland, remote terrain typical of large areas of southern Norway, terrestrial liming offers a suitable mitigation technique for treating acidified surface waters with short retention times.
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  • 32
    ISSN: 1573-2959
    Keywords: air pollution ; GIS ; lichens ; remote sensing ; SO2 ; terrestrial ecosystems
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    Topics: Energy, Environment Protection, Nuclear Power Engineering
    Notes: Abstract Transboundary air pollution from industries in Nikel and Zapolyarnij has caused severe damage to the environment in Southern-Varanger in Norway and in Pechenga municipality in Russia. The work presented in this paper focuses on the integration of in-situ air pollution data with remote sensing based land cover maps. Land cover maps have been utilised to detect changes in the major land cover types within the area. The major change in the environment was the decrease of the sensitive lichen-dominated land cover types, and the increase of bilberry-dominated land cover types and finally the increase of the land cover types with the greatest air pollution stress (industrial barren, barren, and partly damaged vegetation, defoliated forests, lichen removal). A GIS based method for assessing the relationship of the remotely sensed land cover maps with the environmental condition parameters was developed and applied. By comparing the results from this analysis we observed that the land cover types with the greatest stress had the largest concentrations of SO2 in the ground air layer, while the land cover types with minor damage (the remaining lichen-dominated vegetation) had rather low concentrations of sulphur dioxide in the ground air layer. The area of the land cover types with the greatest stress (industrial barren, barren and partly damaged vegetation) has increased in the period 1973–1988, and the degradation is carried out in a such manner that sensitive mountain and lichen vegetation formations have been transformed into a more barren-like environment. The increase in the emissions has also transferred the natural barrens which also consisted of some sparse vegetation into a complete barren with little vegetation left. Also the epilitic lichens and mosses on bare rocks and stones were also removed by the high concentrations of SO2. The land cover types with minor damage (with the remaining lichen-dominated vegetation) had rather low concentrations of the contaminants (SO2, Ni and S), while the partly damaged and damaged land cover types had the highest concentrations of the contaminants. An exception was the Ni and S concentrations found in class 11 Industrial barrens which were lower than expected. Associations between the degradation and the SO2 concentration in the air were also documented. The conclusion from this analysis is that the in-situ data support the observations of damaged vegetation and industrial barrens imaged by the Landsat satellites, especially in the surroundings of Nikel and Zapolyarnij.
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    Environmental monitoring and assessment 49 (1998), S. 271-280 
    ISSN: 1573-2959
    Keywords: air pollution ; atmospheric change ; atmospheric stressors ; biodiversity ; ecosystem risk
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    Topics: Energy, Environment Protection, Nuclear Power Engineering
    Notes: Abstract Overall, the greatest threats to Canadian and global biodiversity are associated with conversions of natural ecosystems to anthropogenic ones, and over-exploitation of biological resources. This circumstance does not, however, trivialize the importance of atmospheric influences. Although scientific understanding of the risks is incomplete, it is nevertheless clear that anthropogenic changes in atmospheric stressors are potentially damaging to biodiversity and other ecological values over medium- and longer-term scales. It is important that greater investments be made in support of longer-term monitoring and research designed to understand the effects of atmospheric and other environmental stressors on the biodiversity and structure and function of Canadian ecosystems.
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    Environmental and ecological statistics 2 (1995), S. 191-212 
    ISSN: 1573-3009
    Keywords: multivariate interpolation ; kriging ; respiratory morbidity ; air pollution ; sulphates ; nitrates ; ozone ; Ontario Health Study ; environmental monitoring
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    Topics: Energy, Environment Protection, Nuclear Power Engineering
    Notes: Abstract We demonstrate a recently developed spatial interpolation methodology in a study of the chronic effects of air pollution on respiratory morbidity. Our study uses data from the Ontario Health Study, a large survey of households in Ontario conducted for the province by Statistics Canada. The interpolation procedure imputes unobserved vectors of air pollution concentrations for individual Public Health Units, from those observed at a few fixed air pollution monitoring sites. We use logistic regression methods to assess the significance of air pollution levels based on the imputed values after modelling the relationship between binary health responses and assorted covariates such as measures of life style. Our findings prove negative; no significant relationship between chronic respiratory morbidity and air pollution is found. The imputation methodology is seen to be promising and might well be used in other such analyses.
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  • 35
    ISSN: 1573-1642
    Keywords: urban forests ; urban ecology ; urban climate ; hydroclimate ; air pollution ; energy conservation ; carbon removal ; benefit-cost analysis
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    Topics: Architecture, Civil Engineering, Surveying , Energy, Environment Protection, Nuclear Power Engineering
    Notes: Abstract This paper is a review of research in Chicago that linked analyses of vegetation structure with forest functions and values. During 1991, the regions trees removed an estimated 5575 metric tons of air pollutants, providing air cleansing worth 9.2 million. Each year they sequester an estimated 315 800 metric tons of carbon. Increasing tree cover 10% or planting about three trees per building lot saves annual heating and cooling costs by an estimated 50 to 90 per dwelling unit because of increased shade, lower summertime air temperatures, and reduced neighborhood wind speeds once the trees mature. The net present value of the services trees provide is estimated as 402 per planted tree. The present value of long-term benefits is more than twice the present value of costs.
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    Environmental and resource economics 17 (2000), S. 109-123 
    ISSN: 1573-1502
    Keywords: economic development ; industrial composition ; pollution havens ; air pollution
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    Topics: Energy, Environment Protection, Nuclear Power Engineering , Economics
    Notes: Abstract This paper examines the impact on air pollution ofchanges in the composition of manufacturing output indeveloped and developing countries. Pollutionemissions from manufacturing output are estimated ina manner which holds constant the effect of technologyand regulations allowing the impact of compositional changes alone on pollution to beestimated. The paper has three main findings; (1) theinverted-U estimated between per capita income and thepollution intensity of GDP arises due to both thecomposition of manufacturing becoming cleaner and theshare of manufacturing output in GDP falling.Compositional changes alone are not responsible forthe inverted-U between per capita income and percapita emissions; (2) changes to the composition ofmanufacturing output are consistent with the pollutionhaven hypothesis, however there is clear evidence thatrising per capita incomes are associated with afalling income elasticity of demand for `dirty'products. This fact may explain the compositionalchanges that occur with development; (3) in additionto the income elasticity effect, the analysis suggeststhat land prices and to a lesser extent the prices oflabour and capital, determine the proportion of dirtyindustry within a country's manufacturing sector.
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    Integrated assessment 1 (2000), S. 145-156 
    ISSN: 1573-1545
    Keywords: transport ; air pollution ; greenhouse gasses ; externalities ; fuel efficiency of cars ; cost-effectiveness
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    Topics: Energy, Environment Protection, Nuclear Power Engineering
    Notes: Abstract This paper surveys some recent studies on conventional air pollution and climate change in the transport sector in Europe. Fuel efficiency standards, car emission standards and transport pricing instruments are analysed from an economic perspective taking into account environmental and economic efficiency objectives.
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  • 38
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    Human ecology 23 (1995), S. 259-284 
    ISSN: 1572-9915
    Keywords: South Africa ; urbanization ; hazards ; flood ; air pollution ; health ; human rights
    Source: Springer Online Journal Archives 1860-2000
    Topics: Biology , Energy, Environment Protection, Nuclear Power Engineering , Ethnic Sciences
    Notes: Abstract Rapid and spatially concentrated urbanization in South Africa has brought with it significant health and safety hazards. These hazards are described and analyzed through two optics: environmental rights and community participation. The rights perspective suggests that the system of apartheid led to a collapse of rural livelihoods, driving people to the cities, while apartheid's tight control over African residential location and employment ensured that high density settlement and unemployment would follow. The resulting urban environmental degradation and health and safety hazards are a violation of the human rights of the African residents of townships and informal settlements. The community participation perspective suggests that reconstruction can be linked to development and that community-based hazard identification and mitigation can be a vehicle for kick-starting urban revitalization.
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  • 39
    ISSN: 1573-2932
    Keywords: stand transpiration ; hydraulic architecture ; Pinus sylvestris L. ; air pollution
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    Topics: Energy, Environment Protection, Nuclear Power Engineering
    Notes: Abstract As part of a project studying the effects of massive reductions in the output of air pollutants in eastern Germany we monitored stand transpiration rates and water stress and analyzed the hydraulic architecture of Scots pine in three stands with different air pollution histories. Sap flow densities were continuously measured in 15 trees per stand with a thermoelectric method. The sap flow densities were scaled up to the stand transpiration rate via the conductive xylem area, which was measured with computer-tomography in the same trees. Radiation (PAR), humidity and temperature were monitored at three levels in the stands, water stress is assessed by predawn water potentials. As a parameter of hydraulic architecture we studied leaf specific conductivity (LSC). The proportion of the heartwood area did not significantly vary along the gradient of air pollution. The variation of sap flow densities within the stands was large. The ratios of sap flow densities in the inner and outer xylem were site-specific and significantly different between the stands. In the stand with the highest rate of air pollution there was a sharp decline in the sap flow densities towards the heartwood. Stand transpiration in the site with the lowest pollution was significantly higher than in the two more polluted sites. LSC in 2 years old twigs was significantly higher in the low pollution stand. In the dry summer of 1994 predawn water potentials fell to extreme values of below 1.6 MPa. At that stage transpiration ceased until the next substantial rainfalls.
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  • 40
    ISSN: 1573-2932
    Keywords: air pollution ; deposition ; emission ; mine industry ; precipitation ; soil water ; sulphur dioxide
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    Topics: Energy, Environment Protection, Nuclear Power Engineering
    Notes: Abstract The Kostomuksha mining complex in Russian Karelia is a major emission point source surrounded by large forest areas near the Finnish border. The sulphur dioxide emissions of the complex are almost 60 000 tonnes and dust emissions about 5 000 tonnes a year. Research into the effects of emissions on the surrounding forests were started in a Finnish-Russian co-operation project in 1992. Deposition measurements during the two first years indicate that the effects of the emissions extend about 30 km to the west of the complex. The annual sulphur deposition near the mining complex has been about 300 mg/m2 in bulk precipitation and about 500 mg/m2 in throughfall. Sulphur emissions sometimes extend the eastern parts of Finland, but there the deposition is clearly smaller than near to the mining complex. The high calcium emissions neutralize the acidifying effect of sulphur near to the mine and smelter. The iron concentration in precipitation also increased near the complex. Sulphur and calcium decreased in percolation water on moving westwards.
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  • 41
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    Water, air & soil pollution 85 (1995), S. 2381-2388 
    ISSN: 1573-2932
    Keywords: critical loads ; acid deposition ; emission reductions ; air pollution impacts ; ecosystem sensitivity
    Source: Springer Online Journal Archives 1860-2000
    Topics: Energy, Environment Protection, Nuclear Power Engineering
    Notes: Abstract Critical loads have been used in the revision of the Sulphur Protocol of the Convention on Long Range Transboundary Air Pollution (LRTAP) of the United Nations Economic Commission for Europe (UN/ECE). Critical loads, i.e. maximum allowable depositions which do not increase the probability of damage to forest soils and surface waters, have been computed and mapped for Europe by means of the Steady-state Mass Balance Method, using national data and, if national data were unavailable, using a European database. Results show that areas with low critical loads are located mostly in northern and central Europe. The reduction of the excess of sulfur (S) deposition over critical loads was a starting point for negotiations leading to the Oslo Protocol on Further Reduction of Sulphur Emissions (the “Second Sulphur Protocol”). The new protocol protects about 81%, 86% and 90% of the ecosystems' area in 2000, 2005 and 2010, respectively. In addition, the total European area in which sulphur deposition exceeds critical loads by more than 500 eq ha−1 yr−1 will be reduced from about 19% in 1980 to practically zero in 2010. Besides these results, a methodology is presented which allows the combined assessment of the acidifying effects of S and N as well as the eutrophying effects of N deposition on ecosystems (so-called critical load functions and the protection isolines derived from them). This methodology is well suited to integrate ecosystem sensitivities into future negotiations on the reductions of nitrogen (N) compounds, taking into account present or anticipated S emissions.
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    Water, air & soil pollution 85 (1995), S. 2401-2406 
    ISSN: 1573-2932
    Keywords: critical load ; acid deposition ; acidification model ; sulfur deposition
    Source: Springer Online Journal Archives 1860-2000
    Topics: Energy, Environment Protection, Nuclear Power Engineering
    Notes: Abstract The project Comprehensive Control and Demonstration for Acid Deposition in Liuzbou area is a national key project in the 8th Five-year-plan, and the study on critical loads will provide scientific and quantitative accordance for formulating control strategy. In this paper, critical loads of acid deposition to soil in Lirzhou area, China, were calculated using the Steady State Mass Balance method (SMB and PROFILE) and dynamic modeling methods(MAGIC), based on data obtained from field investigations and physiochemical properties measured through experiments such as the organic content, cation exchange capacity, base saturation, sulfate adsorption capacity, gibbsite coefficient, biomass base cation uptake and selectivity coefficient for cations. Weathering rates necessary to calculate soil chemistry in applying SMB and MAGIC model were determined by computation with PROFILE using independent geophysical properties such as soil texture and mineralogy as the input data, or by the total soil base cation content correlation. The results have shown that the critical loads of acidity in this area are in the range of 0.7–6.0 keq ha−1 yr−1, indicating sulfur deposition should be cut down by 50–90 percent of the present level. The upper soil layer is the most sensitive. The maximum allowable deposition loading of this area is also presented in the paper.
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    Water, air & soil pollution 85 (1995), S. 2547-2552 
    ISSN: 1573-2932
    Keywords: critical loads ; acid deposition ; forest soils ; mapping ; mathematical modelling
    Source: Springer Online Journal Archives 1860-2000
    Topics: Energy, Environment Protection, Nuclear Power Engineering
    Notes: Abstract Since 1990 the Institute for Ecology of Industrial Areas, acting as National Focal Center, is actively involved in an international research programme aimed at the calculation and mapping of critical loads of acidifying compounds. Following the methodological guidelines elaborated under the leadership of UN/ECE Task Force on Mapping and Coordination Center for Effects, national maps of critical loads and their exceedances for acidity, sulphur and nitrogen have been produced. These maps have already been utilized in derivation of European maps of critical loads of acidity and sulphur submitted to the UN/ECE LRTAP Convention as scientific input to the negotiations on the Second Sulphur Protocol. The lessons learned from the critical loads mapping exercise can be summarized as follow: the majority of Polish territory is covered with forest soils sensitive to acidification at an average Central European level; the exceedances of critical loads, estimated on the basis of national deposition data reveal the tune changes of ecological risks on the territory of Poland as a reflection of economic transition. The significant difference in the scale of those risks (measured by the percentage of the country territory with the maximum exceedances of critical loads) that appear in the period between 1987, representing the period of central planned economy and 1990, representing the early transition phase to a market economy, is particularly notable.
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    Water, air & soil pollution 85 (1995), S. 2565-2570 
    ISSN: 1573-2932
    Keywords: acid deposition ; air pollution impacts ; critical loads ; integrated modeling ; ecosystem sensitivity
    Source: Springer Online Journal Archives 1860-2000
    Topics: Energy, Environment Protection, Nuclear Power Engineering
    Notes: Abstract Critical loads have been computed and mapped in Southeast Asia, comprising China, Korea, Japan, The Philippines, Indo-China, Indonesia and the Indian subcontinent. The methodology involved the Steady-State Mass Balance (SSMB) method, originally developed for Europe. In contrast to Europe, where critical loads were computed for forest soils and surface waters, in Asia critical loads for 31 different vegetation types have been computed. Critical chemical limits as well as soil stability criteria were derived for each of these vegetation types, which include both natural and managed ecosystems. Results show that low critical loads in Asia occur in Bangla-Desh, Indo-China, Indonesia and the southern part of China. Uncertainties of the results are mainly due to uncertainties in base cation deposition. The critical loads are part of the impact module of the Asian version of the Regional Air pollution INformation and Simulation model (RAINS-Asia), a model used to assess abatement strategies for sulfur emissions which are rapidly increasing in this part of the world. The difference in the level of detail between European and Asian critical load maps enables different applications. In Europe, critical loads for sulphur were used in comparison to actual sulphur deposition with the aim of decreasing the excess of sulphur deposition over critical loads through optimal emission abatement. In Asia in general and China in particular the geographical distribution of critical loads of sensitive ecosystems, with some emphasis on crops, is likely to be used as a basis for future emission (re-)allocation.
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  • 45
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    Water, air & soil pollution 85 (1995), S. 2607-2612 
    ISSN: 1573-2932
    Keywords: acidification ; model testing ; modeling ; acid deposition
    Source: Springer Online Journal Archives 1860-2000
    Topics: Energy, Environment Protection, Nuclear Power Engineering
    Notes: Abstract Strategies to control the emission of atmospheric pollutants such as sulfur and nitrogen, are generally based in large part on projections using models that simulate the influence of sulfur and/or nitrogen deposition on the acid-base chemistry of surface waters. One of the principal models used throughout Europe and North America for such assessment is the Model of Acidification of Groundwater in Catchments (MAGIC). All watershed models are simplified representations of reality, and as such require careful testing to establish their veracity prior to use for making policy projections. This is particularly true where the use of these model projections has the potential for serious environmental or economic consequences. During the past five years, we have tested the MAGIC model in a large variety of settings and under quite varying environmental conditions. This work has included comparing model hindcast simulations with diatom-inferences of historical acidification, sensitivity analyses to examine the response of the model to alternative assumptions and formulations, and detailed testing of model forecasts by comparing simulated chemistry with the results of catchment-scale and plot-scale experimental acidification and deacidification. Our analyses have elucidated a number of potentially-important deficiencies in model structure and method of application. These have resulted in changes to the model and its calibration procedures. Our work has included in-depth evaluation of issues related to regional aggregation of soils data, background sulfur deposition, natural organic acidity, and aluminum mobilization. The result has been an improved and more thoroughly-tested version of MAGIC. The process we have followed to improve and confirm the MAGIC model has been iterative and time consuming. It required the availability of large volumes of data from experimental manipulation and paleolimnological studies. We believe that such model testing and confirmation efforts should be a critical prerequisite for regional or national assessment activities that are based largely on the results of environmental models.
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    Water, air & soil pollution 85 (1995), S. 2631-2636 
    ISSN: 1573-2932
    Keywords: Public awareness ; public information ; acid deposition
    Source: Springer Online Journal Archives 1860-2000
    Topics: Energy, Environment Protection, Nuclear Power Engineering
    Notes: Abstract It is fundamental that the general public have access to usable environmental information on which they can base their decisions. Since 1984 the Atmospheric Research and Information Centre (ARIC) has operated a public information programme for the UK on the subject of acid deposition. The objective of the programme is to disseminate information on acid deposition without advocacy. ARIC provides enquirers with a broad range of authoritative and accurate facts and opinions from a wide range of parties from all sides of the debate. These sources include pressure groups, governmental bodies and industrialists from the UK and overseas. By deconstructing complex technical material and reassembling it for dissemination in a user friendly form, ARIC assists those receiving information to obtain a balanced perspective. This enables personal decision making within the context of the fullest information resource ARIC is able to provide.
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  • 47
    ISSN: 1573-2932
    Keywords: Decision support system ; optimization ; air pollution ; sulphur ; critical load
    Source: Springer Online Journal Archives 1860-2000
    Topics: Energy, Environment Protection, Nuclear Power Engineering
    Notes: Abstract A Spatial Decision Support System (SDSS) is being developed for Her Majesty's Inspectorate of Pollution (HMIP). It enables the investigation of the spatial implications of different operating procedures from large point sources of pollution. The environmental effect of emissions is assessed using the critical loads methodology developed at ITE and modelled deposition “footprints”. This approach allows an “effect per unit emission” or “pollution potential” to be determined for each source. Individual sources are modelled and included within the SDSS if their current emissions are above a given threshold. The SDSS provides a graphical user interface (GUI) which facilitates a fast, efficient and effective means to specify and to examine the effect of different operating policies. Mapping, statistical and optimization facilities are provided to help describe the effect of any specified strategy. Maps may be produced as deposition rates or exceedance values. Statistics may be visualised as histograms and scatter plots. The optimization facility uses linear programming to minimise the total environmental impact (estimated from emissions and critical loads) or maximise power produced within environmental limits. The SDSS has been written in the Arc/Info Macro Language (AML) and provides an invisible interface with standard GIS facilities and programmes written in “C”.
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  • 48
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    Water, air & soil pollution 85 (1995), S. 2655-2660 
    ISSN: 1573-2932
    Keywords: materials ; buildings ; stone ; metal ; pollution ; decay ; acid deposition
    Source: Springer Online Journal Archives 1860-2000
    Topics: Energy, Environment Protection, Nuclear Power Engineering
    Notes: Abstract In 1986, the National Materials Exposure Programme was set up within the United Kingdom to investigate the effects of acid deposition on buildings and building materials. Thirty sites were chosen, which represented a range of geographical and pollution climates. Each site met a minimum meteorological and pollution monitoring regime (including SO2, NO2). After four years, other sites were included (with less frequent data collection) and some sites removed. At each site, samples of 3 types of stone, mild steel, painted steel, Cu, Al and galvanised steel were exposed, with some of the stone sheltered from direct precipitation. Samples were removed periodically for analysis and dose-response relations derived for different materials. The empirical relationships derived are in the form of: decay rate=a [SO+] + b [H2] + c [rainfall] + d These dose response relations have been used to develop critical load maps for materials for the United Kingdom. Eight years of data have been collected, some for the UNECE task force programme. Laboratory tests using an Atmospheric Flow Chamber were also undertaken. Since the beginning of the programme addition materials have been exposed on some sites including mortars. A further set of eight sites has been used to assess the effects of ozone on a range of organic materials (for example polyvinyl chloride, polycarbonate, sealants). The paper presents up-to-date findings for the programme and confirms the dominance of dry deposition of sulphur dioxide as the main decay process for sensitive materials in areas of significant pollution.
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  • 49
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    Water, air & soil pollution 85 (1995), S. 2693-2699 
    ISSN: 1573-2932
    Keywords: Critical loads ; Sulphur ; dose-response functions ; Damage functions ; acid deposition
    Source: Springer Online Journal Archives 1860-2000
    Topics: Energy, Environment Protection, Nuclear Power Engineering
    Notes: Abstract The United Kingdom National Materials Exposure Programme was initiated in 1986 to study the effects of acid deposition on building materials. The output data in the form of empirical dose-response equations (described elsewhere) have been incorporated into a geographical information system (GIS). In addition, data for the stock at risk of building materials has also been used. The dose-response relations indicate a dominance of dry deposition of sulphur dioxide in the decay process. Critical level/load maps have been determined for a number of materials. General pollution and meteorological data sets are also included in the mapping process. Maps give ‘exceedence squares’ on a 20 km square grid basis, indicating the unprotected areas or those still at risk for a given scenario for SO2 reduction in the context of the UNECE protocol for sulphur. In order to derive maps of areas sensitive to pollutants in the future a model, HARM 7.2, is used for the prediction of distribution of emissions of pollutants in the UK. A series of maps has now been produced for different materials at 70% and 80% scenarios for the reduction of SO2. Studies of the sensitivity of the exceedence maps to the accuracy or variation of the components in the dose-response equations have been undertaken. Results from the mapping programme and the sensitivity analysis are presented together with discussion of the concept of critical loads of materials.
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  • 50
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    Water, air & soil pollution 85 (1995), S. 2707-2712 
    ISSN: 1573-2932
    Keywords: Stone deterioration ; dry deposition ; air pollution ; calcareous stones ; field test ; laboratory test
    Source: Springer Online Journal Archives 1860-2000
    Topics: Energy, Environment Protection, Nuclear Power Engineering
    Notes: Abstract Dry deposition of gases plays an important role for the deterioration of stone materials and a better understanding of the processes involved will improve our ability to maintain stone monuments and buildings. As a part of an EU-project an investigation with four calcareous stone types have been exposed outdoor at two test sites in Norway for two years. The exposure has been carried out in sheltered position and the amount of reaction products and the penetration depth of SO2 into the stones was determined as soluble sulphate after half a year and after one and two years. Even if most of the sulphate was found in the upper 0.3 mm of the stone, there was an increase in the sulphate content in stone even down to the center of the stone sample. In laboratory tests with SO2, NO2 and changing relative humidity the synergistic effect of NO2 and the importance of the relative humidity was investigated. The uptake rates were calculated from the laboratory studies by analyzing the gas concentrations before and after the exposure chamber. By calculating the deposition velocity from the field study by using the amount of sulphate found in the stones together with the average outdoor concentration of SO2 at the test sites, the values were a magnitude higher than in the laboratory test, highest at the industrial paper mill sites with high concentrations both of SO2 and some hypochlorite and lower in urban atmosphere with fairly low values of SO2 and high values of NO2.
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    Water, air & soil pollution 85 (1995), S. 2713-2718 
    ISSN: 1573-2932
    Keywords: building stones ; porous carbonate stones ; acid deposition ; urban environment ; stone reactivity ; porosity ; petrophysics ; physical properties
    Source: Springer Online Journal Archives 1860-2000
    Topics: Energy, Environment Protection, Nuclear Power Engineering
    Notes: Abstract This work investigates the response of porous carbonate building stones to acid deposition during a short-terra exposure period and the characteristics that influence their reactivity and/or durability. Several carbonate porous stones used in Spanish and English monuments were exposed to English urban and suburban environments. In each location they were both exposed to and sheltered from rainfall. Monthly analyses were carried out in order to investigate any possible sign of reaction. In addition, some physical properties of the stones relating to transfer of moisture were determined. Results indicate that the reactivity of these stones is relatively high, significant signs of reaction were detected within only a few months of exposure. Under the same environmental conditions, the response and reactivity of porous carbonate stones are determined by their petrophysical characteristics.
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  • 52
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    Water, air & soil pollution 85 (1995), S. 2719-2724 
    ISSN: 1573-2932
    Keywords: Air pollution ; acid deposition ; sandstone deterioration ; gypsum formation ; sulphur isotopes
    Source: Springer Online Journal Archives 1860-2000
    Topics: Energy, Environment Protection, Nuclear Power Engineering
    Notes: Abstract The deterioration of two kinds of sandstone is discussed for two 18:th century buildings in central Stockholm: the Royal Palace, and the Royal Carolean Burial Chapel (Karolinska gravkoret) annexed to the mediaeval Riddarholm church. The facades of calcitic Gotland sandstone show many signs of serious decay, such as gypsum formation, pulverized surface, exfoliation, discolouration, and salt efflorescence. The socles are built of the more resistant quartzitic Roslagen sandstone, displaying some discolouration, cracks, and slight exfoliation. In total about 300 samples have been analysed. The surface concentration of sulphur is highest at ground level and at rain-sheltered positions. Chemical and sulphur isotope data indicate that the stone decay to a large part may be attributed to anthropogenic sources like acid deposition and car traffic.
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  • 53
    ISSN: 1573-2932
    Keywords: acid deposition ; Al cycling ; forest soil ; jurbanite ; leucogranite ; soil solution ; stream water
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    Topics: Energy, Environment Protection, Nuclear Power Engineering
    Notes: Abstract The Lysina catchment in the Czech Republic was studied to investigate the biogeochemical response of Al to high loadings of acidic deposition. The catchment supports Norway spruce plantations and is underlain by granite and podzolic soil. Atmospheric deposition to the site was characterized by high H+ and SO4 2− fluxes in throughfall. The volume-weighted average concentration of total Al (Alt) was 28 μmol L−1 in the O horizon soil solution. About 50% of Alt in the O horizon was in the form of potentially-toxic inorganic monomeric Al (Ali). In the E horizon, Alt increased to 71 μmol L−1, and Ali comprised 80% of Alt. The concentration of Alt (120 μmol L−1) and the fraction of Ali (85%) increased in the lower mineral soil due to increases in Ali and decreases in organic monomeric Al (Alo). Shallow ground water was less acidic and had lower Alt concentration (29 μmol L−1). The volume-weighted average concentration of Alt was extremely high in stream water (60 μmol L−1) with Ali accounting for about 60% of Alt. The major species of Ali in stream water were fluorocomplexes (Al-F) and aquo Al3+. Soil solutions in the root zone were undersaturated with respect to all Al-bearing mineral phases. However, stream water exhibited Ali concentrations close to solubility with jurbanite. Acidic waters and elevated Al concentrations reflected the limited supply of basic cations on the soil exchange complex and slow weathering, which was unable to neutralize atmospheric inputs of strong acids.
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  • 54
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    Water, air & soil pollution 85 (1995), S. 2051-2056 
    ISSN: 1573-2932
    Keywords: acidification ; air pollution ; air pollution modelling
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    Topics: Energy, Environment Protection, Nuclear Power Engineering
    Notes: Abstract A long-term modelling (1991–1994) of oxidised sulphur, bound nitrogen and some heavy metals has been carried out by MSC-E/EMEP for the Northern Hemisphere. The transport unit of the model is an Eulerian scheme which could be classified as Pseudo-Lagrangian one. Vertical distribution described by means of Gaussian approximation and the exchange with the free troposphere are taken into account. Vertical movement is calculated proceeding from local mixing conditions, state of the surface, its height (topography) etc. The chemical unit for acid compounds contains 25 reactions and 14 compounds including sulphur and nitrogen compounds peroxyacetylnitrate, tropospheric ozone, volatile hydrocarbons (but methane) are considered as a whole via ozone creation potential. The model time step is 1 hour, meteorological data (winds, temperature, precipitation etc.) cover 6-hour intervals. The model results show that very significant part of the Arctic and West Asian acid pollution is produced by European countries. On the whole the Arctic pollution by SOx, NOx and NHx comes from sources of Old World. The main source of sulphur pollution is located in Russia and of nitrogen compound — in Central and Northern Europe. About 50% SOx, 70% NOx and 40% NHx deposition in Central Asia and Kazakhstan is-imported from external sources. A similar situation is observed in European and Asian parts of Russia.
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  • 55
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    Keywords: air pollution ; industrial emissions ; sulphur dioxide ; heavy metal aerosols ; contamination of precipitation
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    Topics: Energy, Environment Protection, Nuclear Power Engineering
    Notes: Abstract The results of investigations carried out in the forests of Kola peninsula subject to long-term air pollution by the nickel industrial enterprises are presented. Samples of rainwater from the open sites, from under the coniferous (pine) trees crowns and of the stemflow were collected at various distances from the emission sources. The highest levels in pollution of rainwater are detected over the area adjacent to the smelters. Researches of contamination of the precipitation in the vicinity of the two nickel enterprises of Kola peninsula show that concentrations of pollutants vary significantly (up to an order of magnitude) depending upon the meteorological conditions. The area of impact on forests of Kola peninsula is restricted by the radius of 30–40 km from the emission sources.
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  • 56
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    Water, air & soil pollution 98 (1997), S. 297-316 
    ISSN: 1573-2932
    Keywords: acid deposition ; ecosystem ; GLUE ; PROFILE
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    Topics: Energy, Environment Protection, Nuclear Power Engineering
    Notes: Abstract Critical loads of acid deposition for forest soils, ground and surface water resources are calculated utilising a variety of mathematical models. The estimation of the predictive uncertainty inherent in these models is important since the model predictions constitute the cornerstone of the development of emissions abatement policy decisions in Europe and the United Kingdom. The Generalised Likelihood Uncertainty Estimation (GLUE) approach is presented here as a tool for estimating the predictive uncertainty of PROFILE, a steady-state geochemical model that is widely applied within the critical loads community. GLUE is based on Monte Carlo simulation and explicitly recognises the possible equifinality of parameter sets. With this methodology it is possible to make an assessment of the likelihood of a parameter set being an acceptable simulator of a system when model predictions are compared to observed field data. The methodology is applied to a small catchment at Plynlimon, Mid-Wales. The results highlight that there is a large amount of predictive uncertainty associated with the model at the site: three of the six chosen field characteristics lie within the predicted distribution. The study also demonstrates that a wide range of parameter sets exist that give acceptable simulations of site characteristics as well as a broad distribution of critical load values that are consistent with the site data. Additionally, a sensitivity analysis of model parameters is presented.
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  • 57
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    Water, air & soil pollution 98 (1997), S. 297-316 
    ISSN: 1573-2932
    Keywords: acid deposition ; ecosystem ; GLUE ; PROFILE
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    Topics: Energy, Environment Protection, Nuclear Power Engineering
    Notes: Abstract Critical loads of acid deposition for forest soils, ground and surface water resources are calculated utilising a variety of mathematical models. The estimation of the predictive uncertainty inherent in these models is important since the model predictions constitute the cornerstone of the development of emissions abatement policy decisions in Europe and the United Kingdom. The Generalised Likelihood Uncertainty Estimation (GLUE) approach is presented here as a tool for estimating the predictive uncertainty of PROFILE, a steady-state geochemical model that is widely applied within the critical loads community. GLUE is based on Monte Carlo simulation and explicitly recognises the possible equifinality of parameter sets. With this methodology it is possible to make an assessment of the likelihood of a parameter set being an acceptable simulator of a system when model predictions are compared to observed field data. The methodology is applied to a small catchment at Plynlimon, Mid-Wales. The results highlight that there is a large amount of predictive uncertainty associated with the model at the site: three of the six chosen field characteristics lie within the predicted distribution. The study also demonstrates that a wide range of parameter sets exist that give acceptable simulations of the site characteristics as well as a broad distribution of critical load values that are consistent with the site data. Additionally, a sensitivity analysis of model parameters is presented.
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  • 58
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    Water, air & soil pollution 98 (1997), S. 381-387 
    ISSN: 1573-2932
    Keywords: air pollution ; bioindicator ; biomonitoring ; tree bark
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    Topics: Energy, Environment Protection, Nuclear Power Engineering
    Notes: Abstract During a two year research period from 1992 to 1993, samples of different species of trees were taken in 17 forest stands located in Navarra, Spain. From these samples, bark extracts were prepared in which the pH and the conductivity were measured. The health of the sampling trees was also evaluated by determining the degree of defoliation and decoloration of the canopies. The bark tissue analysis revealed the presence of an environmental acidity gradient that decreased from NW to SE. This coincides with the location of important sources of pollution and their course of transport and dispersion. On the other hand, in the samples ofQuercus ilex a significant correlation between the pH and the defoliation levels (P≤0.01, r=0.62) was found. This fact reveals the potential usefulness of tree bark as a health bioindicator of trees.
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  • 59
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    Water, air & soil pollution 93 (1997), S. 395-408 
    ISSN: 1573-2932
    Keywords: air pollution ; pine bark ; sulphur ; pH ; conductivity ; heavy metals
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    Topics: Energy, Environment Protection, Nuclear Power Engineering
    Notes: Abstract Sulphur and heavy metal deposition in northern Finland (= in Lapland) and the Kola Peninsulawere surveyed using Scots pine bark samples. Sulphur concentrations in bark close to the Kolasmelters were on an average twice as high as on the Finnish side of the border. The Cu and Niconcentrations near the smelters were almost 100-fold the mean values in northern Finland. Therewas a marked decrease in the sulphur and heavy metal concentrations with increasing distancefrom the emission sources. The effects of emissions from the Kola Peninsula were evident inFinland only close to the border, especially in the eastern parts of Inari (NE corner of Lapland)where the Cu and Ni concentrations were 2- to 6-fold those in western Lapland. The sulphur andheavy metal concentrations in most of northern Finland were low. However were theconcentrations of Cr in bark in the SW corner of Lapland considerably high, due to the emissionsfrom the Tornio refined steel plants.
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  • 60
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    Keywords: acid rain ; acid deposition ; acid fraction ; precipitation pH and conductivity
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    Topics: Energy, Environment Protection, Nuclear Power Engineering
    Notes: Abstract A microprocessor-based acid rain monitor was used to make real-time measurements of conductivity and pH of rainwater within individual storms. The automated measurements were compared with laboratory analyses of a subset of the samples taken. The laboratory measurements tended to overestimate the pH because of temperature induced changes in dissociation and Henry's Law constants affecting ionic compounds in the rainwater. The measurement artefact due to these effects may result in average hydrogen ion concentrations being underestimated by approximately 10 to 15% at UK sites. The greatest systematic discrepancies would be anticipated at highly polluted sites and during low temperature acidic episodes. The concept of a rainwater acid fraction was investigated and found to be useful for quality control and interpretative purposes. The field measurement of conductivity of low ionic strength samples was slightly lower than the corresponding laboratory measurement, possibly caused by limited resolution of the conductivity probe or dissolution of fine particulate material.
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  • 61
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    Water, air & soil pollution 98 (1997), S. 381-387 
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    Keywords: air pollution ; bioindicator ; biomonitoring ; tree bark
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    Topics: Energy, Environment Protection, Nuclear Power Engineering
    Notes: Abstract During a two year research period from 1992 to 1993, samples of different species of trees were taken in 17 forest stands located in Navarra, Spain. From these samples, bark extracts were prepared in which the pH and the conductivity were measured. The health of the sampling trees was also evaluated by determining the degree of defoliation and decoloration of the canopies. The bark tissue analysis revealed the presence of an environmental acidity gradient that decreased from NW to SE. This coincides with the location of important sources of pollution and their course of transport and dispersion. On the other hand, in the samples of Quercus ilex a significant correlation between the pH and the defoliation levels (P≤0.01, r = 0.62) was found. This fact reveals the potential usefulness of tree bark as a health bioindicator of trees.
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  • 62
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    Environmental monitoring and assessment 62 (2000), S. 175-191 
    ISSN: 1573-2959
    Keywords: air pollution ; biomonitoring ; O3
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    Topics: Energy, Environment Protection, Nuclear Power Engineering
    Notes: Abstract A group of 50 inexperienced scorers were asked to estimate –using standard reference photos – foliar injury induced by the gas pollutant ozone on the supersensitive indicator planttobacco (Nicotiana tabacum L.) cv. Bel-W3. Theaverage accuracy level was 56.1% (95.9% when theclasses nearest to the reality were also consideredcorrect) and the average repeatability was 65.4%. Theextreme classes were easily scored. Central classesproved to be more difficult to be evaluated: this maydepend on the fact that two leaves may have similaractual total injured area, but substantially differentnumbers and spatial distribution of the lesions. Insome cases we observed a prevalence of overestimationerrors in the high classes and underestimation in thelow classes: this is in contradiction with theWeber-Fechner law. It is noteworthy the very shorttime required by operators to score, regardless of the results.
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  • 63
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    Environmental monitoring and assessment 64 (2000), S. 81-91 
    ISSN: 1573-2959
    Keywords: air pollution ; air quality ; monitoring network ; mountainous regions ; multi-scale assessment ; spatial and temporal scales ; tropospheric ozone
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    Topics: Energy, Environment Protection, Nuclear Power Engineering
    Notes: Abstract A quantitatively robust yet parsimonious air-quality monitoring network in mountainous regions requires special attention to relevant spatial and temporal scales of measurement and inference. The design of monitoring networks should focus on the objectives required by public agencies, namely: 1) determine if some threshold has been exceeded (e.g., for regulatory purposes), and 2) identify spatial patterns and temporal trends (e.g., to protect natural resources). A short-term, multi-scale assessment to quantify spatial variability in air quality is a valuable asset in designing a network, in conjunction with an evaluation of existing data and simulation-model output. A recent assessment in Washington state (USA) quantified spatial variability in tropospheric ozone distribution ranging from a single watershed to the western third of the state. Spatial and temporal coherence in ozone exposure modified by predictable elevational relationships (∼ 1.3 ppbv ozone per 100 m elevation gain) extends from urban areas to the crest of the Cascade Range. This suggests that a sparse network of permanent analyzers is sufficient at all spatial scales, with the option of periodic intensive measurements to validate network design. It is imperative that agencies cooperate in the design of monitoring networks in mountainous regions to optimize data collection and financial efficiencies.
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  • 64
    ISSN: 1573-2959
    Keywords: PM10 ; urban air quality ; background ; NAME ; ADMS ; long range transport ; air pollution ; particulates ; nitrogen dioxide ; sulphur dioxide
    Source: Springer Online Journal Archives 1860-2000
    Topics: Energy, Environment Protection, Nuclear Power Engineering
    Notes: Abstract Norwich is the eastern most city in the United Kingdom. Despite a population of only 100,000 and very little local industry, studies have shown that the city experiences levels of nitrogen dioxide, ozone, particulates and sulphur dioxide exceeding the UK Air Quality Standards. Because of Norwich's situation within a large, predominantly rural area a large non-resident workforce is one factor that contributes to large, often very congested traffic flows. The city's location close to the European mainland also exposes it to polluted airmasses transported from the continent, especially in the case of particulates and ozone. In order to assess the relative contributions of local and regional sources, data from rural and urban monitoring sites are to be used in conjunction with ADMS-Urban and the UK Meteorological Office's NAME model.
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  • 65
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    Environmental monitoring and assessment 65 (2000), S. 181-189 
    ISSN: 1573-2959
    Keywords: air pollution ; Computer Fluid Dynamics (CFD) methods ; environment modelling ; atmospheric boundary layer (ABL) ; turbulence ; stable-stratified atmosphere ; complex terrain
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    Topics: Energy, Environment Protection, Nuclear Power Engineering
    Notes: Abstract Different urban air pollution problems deal with complex structure of air flows and turbulence. For such problems the Computer Fluid Dynamics (CFD) methods become widely used. However, this approach despite a number of advantages has some problems. Experience of use of CFD tools for development of models and suggestions of their applications for a local scale air pollution over a complex terrain and stable stratification are discussed in this paper, including: • Topography and complex geometry: choose of the co-ordinate system and computer grid; • Turbulence closure for air pollution modelling: modified k-ε model for stable stratified ABL; • Boundary conditions for vertical profiles of velocity for stable-stratified atmosphere; • Effects of the radiation and thermal budget of inclined surfaces to dispersion of pollutants; • Artificial sources of air dynamics and circulation. Some examples of CFD applications for air pollution modelling for a flat terrain, mountainous area, mining open cast and indoor ventilation are discussed. Modified k-ε model for stably-stratified ABL is suggested. Due to the isotropic character of the k-ε model a combination of it in vertical with the sub-grid turbulence closure in horizontal can be more suitable for ABL. An effective scheme of boundary conditions for velocity profiles, based on the developed similarity theory for stable-stratified ABL, is suggested. Alongside with the common studies of atmospheric dispersion, the CFD methods have also demonstrated a good potential for studying anthropogenic and artificial-ventilation sources of air dynamic and circulation in local-scale processes of air pollution.
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  • 66
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    Environmental monitoring and assessment 65 (2000), S. 381-387 
    ISSN: 1573-2959
    Keywords: air pollution ; model ; guideline ; automobile ; concentrations ; MLuS ; STREET ; PROKAS ; MISKAM ; AIR-EIA
    Source: Springer Online Journal Archives 1860-2000
    Topics: Energy, Environment Protection, Nuclear Power Engineering
    Notes: Abstract The draft of the German guideline to calculate automobile exhaust dispersion is explained. It contains a two-stage-system: For first quick estimates the guideline contains the simple models MLuS and STREET. In case these models are not applicable or their results shows concentration levels close to the air quality standards, the more complex models PROKAS_V and MISKAM are recommended. PROKAS_V is a Gaussian plume model, MISKAM is a 3-dimensional microscale non hydrostatic flow model for built-up areas with an Eulerian dispersion model. The guideline comprises cases in rural areas without or with few adjacent buildings as well as urban areas with buildings near the roads. The contribution gives information about the models, typical results and some of the problems showing up presently.
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    Water, air & soil pollution 95 (1997), S. 75-85 
    ISSN: 1573-2932
    Keywords: Pb ; Cu ; Zn ; trace metal pollution ; air pollution ; Ap horizon ; forest soils
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    Topics: Energy, Environment Protection, Nuclear Power Engineering
    Notes: Abstract In this study, we used once-plowed lands that have returned to forest for over 50 years to study the vertical distribution of meteorologically-deposited lead. These mineral soils were an essentially homogeneous 20 cm-thick layer when last plowed. As such, they were effectively a “clean slate” upon which pollutants deposited since the last plowing can be measured without the confounding aspects of well-developed natural soil horizons and the spatial heterogeneity of native forest soils. The concentration and amount of lead as well as copper and zinc, biologically active metals, were measured at five sites in New England. In the mineral soil, copper content ranged from 25 mg cm depth−1 m−2 at 0–2 cm depth to 37 mg cm depth−1 m−2 at 6–8 cm depth, but showed no consistent pattern with depth at all sites. Zinc concentrations and amounts increased with depth in the mineral soil to 14 μg g−1 and 167 mg cm depth−1 m−2, respectively. In contrast, lead showed a decrease with depth from 350 mg cm depth−1 m−2 at 0–2 cm depth to 102–108 mg cm depth−1 m−2 between 10 and 20 cm depth. At all five sites, decreases in lead concentration with depth were correlated with decreases in the amount of organic mater. Amounts of total lead deposited since the abandonment from plowing have been estimated at 1.4 g m-2 in rural sites. Thirty-five percent of this presumably anthropogenically-derived lead was in the forest floor; the remaining 65 % was in the upper mineral soil.
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    Water, air & soil pollution 95 (1997), S. 75-85 
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    Keywords: Pb ; Cu ; Zn ; trace metal pollution ; air pollution ; Ap horizon ; forest soils
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    Topics: Energy, Environment Protection, Nuclear Power Engineering
    Notes: Abstract In this study, we used once-plowed lands that have returned to forest for over 50 years to study the vertical distribution of meteorologically-deposited lead. These mineral soils were an essentially homogeneous 20 cm-thick layer when last plowed. As such, they were effectively a “clean slate” upon which pollutants deposited since the last plowing can be measured without the confounding aspects of well-developed natural soil horizons and the spatial heterogeneity of native forest soils. The concentration and amount of lead as well as copper and zinc, biologically active metals, were measured at five sites in New England. In the mineral soil, copper content ranged from 25 mg cm depth-1 m-2 at 0–2 cm depth to 37 mg cm depth-1 m-2 at 6–8 cm depth, but showed no consistent pattern with depth at all sites. Zinc concentrations and amounts increased with depth in the mineral soil to 14 μg g-1 and 167 mg cm depth-1 m-2, respectively. In contrast, lead showed a decrease with depth from 350 mg cm depth-1 m-2 at 0–2 cm depth to 102–108 mg cm depth-1 m-2 between 10 and 20 cm depth. At all five sites, decreases in lead concentration with depth were correlated with decreases in the amount of organic mater. Amounts of total lead deposited since the abandonment from plowing have been estimated at 1.4 g m-2 in rural sites. Thirty-five percent of this presumably anthropogenically-derived lead was in the forest floor; the remaining 65% was in the upper mineral soil.
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    Water, air & soil pollution 96 (1997), S. 93-106 
    ISSN: 1573-2932
    Keywords: acid deposition ; acid rain ; back trajectory analysis ; precipitation events ; precipitation scavenging ; sub-event chemistry ; sub-event sampling
    Source: Springer Online Journal Archives 1860-2000
    Topics: Energy, Environment Protection, Nuclear Power Engineering
    Notes: Abstract Analysis of the chemical composition of rain at high temporal resolution provides additional information on wet deposition processes. High resolution data was obtained using a microprocessor-based acid rain monitor at two sites in SW Scotland and SE England. Meteorological details of the transport and wet deposition processes during two frontal rain events were examined and related to rainfall composition. Rapid depletions of ion concentrations during heavy rainfall in the first event were interpreted using a rainfall scavenging model. The sub-event data for the second event showed the influence of frontal discontinuities. Increasing ionic concentrations during this second event were attributed both to the change in air mass, and to diminished upwind precipitation scavenging.
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  • 70
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    Water, air & soil pollution 96 (1997), S. 93-106 
    ISSN: 1573-2932
    Keywords: acid deposition ; acid rain ; back trajectory analysis ; precipitation events ; precipitation scavenging ; sub-event chemistry ; sub-event sampling
    Source: Springer Online Journal Archives 1860-2000
    Topics: Energy, Environment Protection, Nuclear Power Engineering
    Notes: Abstract Analysis of the chemical composition of rain at high temporal resolution provides additional information on wet deposition processes. High resolution data was obtained using a microprocessor-based acid rain monitor at two sites in SW Scotland and SE England. Meteorological details of the transport and wet deposition processes during two frontal rain events were examined and related to rainfall composition. Rapid depletions of ion concentrations during heavy rainfall in the first event were interpreted using a rainfall scavenging model. The sub-event data for the second event showed the influence of frontal discontinuities. Increasing ionic concentrations during this second event were attributed both to the change in air mass, and to diminished upwind precipitation scavenging.
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  • 71
    ISSN: 1573-2932
    Keywords: acid rain ; acid deposition ; acid fraction ; precipitation pH and conductivity
    Source: Springer Online Journal Archives 1860-2000
    Topics: Energy, Environment Protection, Nuclear Power Engineering
    Notes: Abstract A microprocessor-based acid rain monitor was used to make real-time measurements of conductivity and pH of rainwater within individual storms. The automated measurements were compared with laboratory analyses of a subset of the samples taken. The laboratory measurements tended to overestimate the pH because of temperature induced changes in dissociation and Henry's Law constants affecting ionic compounds in the rainwater. The measurement artefact due to these effects may result in average hydrogen ion concentrations being underestimated by approximately 10 to 15% at UK sites. The greatest systematic discrepancies would be anticipated at highly polluted sites and during low temperature acidic episodes. The concept of a rainwater acid fraction was investigated and found to be useful fro quality control and interpretative purposes. The field measurement of conductivity of low ionic strength samples was slightly lower than the corresponding laboratory measurement, possibly caused by limited resolutio nof the conductivity probe or dissolution of fine particulate material.
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  • 72
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    Environmental monitoring and assessment 48 (1997), S. 125-137 
    ISSN: 1573-2959
    Keywords: air pollution ; critical levels ; critical loads ; forestdamage assessment ; industrial emissions ; sulphur deposition
    Source: Springer Online Journal Archives 1860-2000
    Topics: Energy, Environment Protection, Nuclear Power Engineering
    Notes: Abstract A method of calculation of sulphur deposition values on forests subjectto long-term industrial influence is presented. Investigations wereconducted in the vicinities of nickel smelters of Kola peninsula. Sulphurdioxide (SO2) is the major phytotoxicant emitted by theseenterprises. Depositions of sulphur were calculated on the basis of ground air layer pollution. To determine it a mathematical model was applied.Field surveys of forest ecosystems response to air contamination werecarried out and areas of different forest damage degree were identified.More than 4300 km2 of the territory of Kola peninsula isunder the impact of nickel enterprises. Average SO2concentration over the area of slight damage to forests is about 20µg/m3. It corresponds to the critical level proposed for forest ecosystems (UN ECE, 1993). Sulphur deposition over thearea of slight damage varies from 0.6 to 1.0 g/m2yr-1 for coniferous forests. For deciduous forests it isabout 1.0 g/m2 yr-1. These values are close totarget loads for highly sensitive ecosystems (Nilsson et al., 1991), but they exceed critical loads for the northern regions of Europe (Downing etal., 1993).
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  • 73
    ISSN: 1573-2959
    Keywords: air pollution ; indirect and direct gradient analysis ; vegetation monitoring
    Source: Springer Online Journal Archives 1860-2000
    Topics: Energy, Environment Protection, Nuclear Power Engineering
    Notes: Abstract The area along the Norwegian-Russian border is threatened by air pollution from emission sources on the Kola Peninsula. A permanent network of 78 systematically chosen monitoring sites has been established in eastern Finnmark, Norway. Species abundance data from the ground vegetation have been recorded from 1320 systematically chosen permanent plots inside 66 of these sites, using frequency in subplots and visual estimates of percentage cover. Environmental variables were obtained for the whole site. Multivariate data analysis has been used to describe the variation in the species composition and to study its relation to environmental variables and pollution impact. The analyses show that much of the variation in the species composition, based on average species abundance at the sites, is well explained by different soil and climatic conditions. However, estimated SO2 deposition, Ni, and Cu in the soil, and Ni in Cladina tissue have also been found to be statistically significantly correlated with the variation in the species data, but they explain only a minor part of the variation. The pollution impact over several years may have lead to a reduced lichen cover in the bottom-layer vegetation. Further development in an either negative or positive direction can be detected by re-investigations of the monitoring sites.
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  • 74
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    Environmental monitoring and assessment 57 (1999), S. 301-329 
    ISSN: 1573-2959
    Keywords: acid deposition ; acid rain ; precipitation chemistry ; precision ; quality assurance
    Source: Springer Online Journal Archives 1860-2000
    Topics: Energy, Environment Protection, Nuclear Power Engineering
    Notes: Abstract Precision estimates are presented for precipitation chemistry and depth measurements made by the Canadian Air and Precipitation Monitoring Network (CAPMoN). The estimates were made for daily measurements of ion concentration and precipitation depth as well as for weekly, 28-day, seasonal and annual precipitation-weighted mean concentrations and depths. The data on which the estimates are based were collected from collocated samplers at five CAPMoN sites during the period 1985 to 1993. The data pairs from the collocated samplers were used to calculate the between-instrument error defined as 1/√2 times the difference between the paired sample concentrations (or depths). For all of the ion concentrations and depths, the between-sampler errors were found not to be normally distributed, but the normality of the distributions improved with the length of the (volume-weighting) time period considered. A set of quantitative measures of overall network precision were derived in absolute (mg L-1) and relative (%) units. These included the Modified Median Absolute Deviation (M.MAD), the P90% probability values and the Coefficient of Variation (CoV). The latter, defined as the percent ratio of the M.MAD to the median concentration (or depth), represents the relative precision at the center of the error and concentration (and depth) distributions. Based on the CoV values, the relative precision of the CAPMoN measurements was very high (better than 4%) for SO 4 2- , NO 3 - , pH, H+, NH 4 + , sample depth and standard gauge depth, and not as high (between 10 and 〈35%) for Cl-, Na+, Ca2+, Mg2+, and K+. The ions with the lowest median concentrations had the poorest relative precision since so many of the concentrations were at or near the analytical detection limit. Except for the sample and standard gauge depths, both the absolute and relative precision improved with the length of the precipitation-weighting period. Detailed statistical testing established that the precision of the daily measurements is dependent on a number of factors, the most dominant being sample depth and concentration, i.e., the absolute precision improves with increasing sample depth and decreasing concentration. The strength of these relationships diminished with the length of the precipitation-weighting period being considered. Laboratory-related sources of imprecision were found to account for less than 4% of the overall daily measurement imprecision for most species, while field-related sources of imprecision accounted for the balance. Specialized plots are shown which allow data users to estimate the absolute and relative precision at any concentration and depth value.
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  • 75
    ISSN: 1573-2959
    Keywords: air pollution ; personal exposure monitoring ; children ; particulate matter ; seasons ; Scanning Electron Microscopy
    Source: Springer Online Journal Archives 1860-2000
    Topics: Energy, Environment Protection, Nuclear Power Engineering
    Notes: Abstract The personal exposure of children aged 9 – 11 years to particulate matter (PM10 and PM2.5) was carried out between January and September 1997 in the London Borough of Barnet. Personal sampling along with home, garden and classroom microenvironmental monitoring was completed for all ten children. Each child was monitored for five days during winter, spring and summer. All children completed daily time activity diaries to provide information on any potential activities that could influence their exposure to particulate matter. Each evening a household activity questionnaire was also completed by the parents. Personal Environmental Monitors were used to sample personal exposure to PM10 and PM2.5. Harvard Impactors were used for the microenvironmental sampling of both size fractions. The children's mean personal exposure concentrations for PM10 during winter, spring and summer were 72, 54 and 35 µg/m3 respectively and for PM2.5 22, 17 and 18 µg/m3 respectively. In order to determine the potential sources of particulate matter, analysis of the Teflon filters has been undertaken. The physical characteristics of the particles have been identified using Scanning Electron Microscopy. The relationships between personal exposure concentrations and the different microenvironments will be discussed.
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  • 76
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    Environmental modeling and assessment 3 (1998), S. 47-61 
    ISSN: 1573-2967
    Keywords: air pollution ; health effects ; social costs ; externalities ; integrated approach
    Source: Springer Online Journal Archives 1860-2000
    Topics: Energy, Environment Protection, Nuclear Power Engineering
    Notes: Abstract This study analyses health damages from particulate pollution and the corresponding social costs. The analyses, which are based on transferring dose–response functions to Norway, is made within an integrated approach, where the economic impacts of the health damages are handled separately from the non‐economic welfare effects. We find that the social costs of health damages in Oslo are significant, and that the non‐economic welfare effects clearly dominate the cost figure.
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  • 77
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    Environmental modeling and assessment 5 (2000), S. 119-124 
    ISSN: 1573-2967
    Keywords: background air concentration ; point source ; diagnostic model ; air pollution
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    Topics: Energy, Environment Protection, Nuclear Power Engineering
    Notes: Abstract This paper presents two simple methods for the estimation of the instantaneous background air pollution level in a study area around an emitting point source. The methods allow estimation of concentrations non-inclusive of the contribution of the local emitting source. Hourly records of several monitoring stations located around the point source and results of the diagnostic Lagrangian particle dispersion model LADISMO are used in the calculations. A hypothetical case study is used to demonstrate the application of the two methods.
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  • 78
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    Environmental and ecological statistics 1 (1994), S. 325-332 
    ISSN: 1573-3009
    Keywords: Administrative health records ; air pollution ; estimating equations ; hospital admissions ; longitudinal count data ; overdispersion ; ozone ; serial correlation
    Source: Springer Online Journal Archives 1860-2000
    Topics: Energy, Environment Protection, Nuclear Power Engineering
    Notes: Abstract A statistical model for longitudinal count data is used to examine the potential adverse health effects of ambient air pollution. Daily respiratory admissions to 164 acute care hospitals in Ontario are obtained for the period 1983 to 1988. Estimates of ozone levels in the vicinity of each hospital are determined from air pollution monitoring stations maintained by the Ontario Ministry of the Environment. Generalized estimating equation methods are used to make inferences about the regression and overdispersion parameters. The admission data display little evidence of serial correlation and extra Poisson variation. However, admission rates vary considerably among hospitals. This latter source of variation needs to be taken into account in examining the effects of air pollution on respiratory health status.
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  • 79
    ISSN: 1573-3009
    Keywords: structural measurement error ; generalized estimating equations ; longitudinal data ; environmental epidemiology ; spatial prediction ; clustered data ; nonlinear mixed-effect models ; air pollution ; respiratory morbidity ; ozone ; sulphate
    Source: Springer Online Journal Archives 1860-2000
    Topics: Energy, Environment Protection, Nuclear Power Engineering
    Notes: Abstract This paper presents the results of a reconsideration of earlier work that finds an association between daily hospital admissions for respiratory distress and daily concentrations of sulphate (lag 1) as well as daily maximum concentrations of ozone (lags 1 and 3). These associations are found even after clustering the data by hospital of admission and accounting for the effects of temperature. We use an adaptation of their generalized estimating equation technique for clustered data, that daily data being for southern Ontario summers from 1983 to 1988. Like them, we adjust for daily maximum temperatures. However, unlike the earlier work returned to ours includes daily average humidity as a potential explanatory variable in our model. Our analysis also differs from theirs in that we cluster the data by census subdivision to reduce the risk of confounding pollutant levels with population size within regions. Moreover, we log-transform the explanatory variables and then high-pass filter the resulting data. We also deviate from the earlier analysis by taking account of measurement error incurred in using surrogate measures of the explanatory variables. To do so we use new methodology designed for our study but of potential value in other applications. That methodology requires a spatial predictive distribution for the unmeasured explanatory variables. Each day about 700 missing measurements for each of these variables can then be imputed over the geographical domain of the study. With these imputations we get a measure of imputation error through the covariance of the predictive distribution. Along with the predictive distribution we require an impact model to link-up with the predictive distribution. We describe that model and show how it uses the imputed measurements of the missing values of the explanatory variables. We also show how through that model, uncertainty about these values is reflected in our analysis and in commensurate uncertainties in the inferences made. Apart from its substantive objectives, our analysis serves to test the new methods with the earlier results serving as a foil. The reassuring qualitative agreement between our findings and the earlier results seems encouraging.
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  • 80
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    Environmental and ecological statistics 7 (2000), S. 77-91 
    ISSN: 1573-3009
    Keywords: acid deposition ; Bayesian inference ; Dirichlet distribution ; fish response ; Gibbs sampler ; lake eutrophication ; PCB ; risk assessment ; salmonid
    Source: Springer Online Journal Archives 1860-2000
    Topics: Energy, Environment Protection, Nuclear Power Engineering
    Notes: Abstract In environmental management, we often have to deal with binary response variables whose outcome dictates the course of action. This paper introduces a nonparametric Bayesian binary regression model with a single predictor variable that is more flexible than the commonly used logistic or probit models. Due to the Bayesian feature, the model can be easily used to combine observed data with our knowledge of the subject to produce site-specific results. By using three examples, this paper shows the potential application of the model in the environmental management, and its advantages in terms of flexibility in model specification, robustness to outliers, and realistic interpretation of data.
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  • 81
    ISSN: 1573-2932
    Keywords: acid deposition ; ozone ; forests ; nitrogen deposition ; pollution climate
    Source: Springer Online Journal Archives 1860-2000
    Topics: Energy, Environment Protection, Nuclear Power Engineering
    Notes: Abstract The tall, aerodynamically rough surfaces of forests provide for the efficient exchange of heat and momentum between terrestrial surfaces and the atmosphere. The same properties of forests also provide for large potential rates of deposition of pollutant gases, aerosols and cloud droplets. For some reactive pollutant gases, including SO2, HNO3 and NH3, rates of deposition may be large and substantially larger than onto shorter vegetation and is the cause of the so called "filtering effect" of forest canopies. Pollutant inputs to moorland and forest have been compared using measured ambient concentrations from an unpolluted site in southern Scotland and a more polluted site in south eastern Germany. The inputs of S and N to forest at the Scottish site exceed moorland by 16% and 31% respectively with inputs of 7.3 kg S ha-1 y and 10.6 kg N ha-1 y-1. At the continental site inputs to the forest were 43% and 48% larger than over moorland for S and N deposition with totals of 53.6 kg S ha-1 y-1 and 69.5 kg N ha-1 y-1 respectively. The inputs of acidity to global forests show that in 1985 most of the areas receiving 〉 1 kg H+ ha-1 y-1 as S are in the temperate latitudes, with 8% of total global forest exceeding this threshold. By 2050, 17% of global forest will be receiving 〉 1 kg H-1 ha-1 as S and most of the increase is in tropical and sub-tropical countries. Forests throughout the world are also exposed to elevated concentrations of ozone. Taking 60 ppb O3 as a concentration likely to be phytotoxic to sensitive forest species, a global model has been used to simulate the global exposure of forests to potentially phytotoxic O3 concentrations for the years 1860, 1950, 1970, 1990 and 2100. The model shows no exposure to concentrations in excess of 60 ppb in 1860, and of the 6% of global forest exposed to concentrations 〉 60 ppb in 1950, 75% were in temperate latitudes and 25% in the tropics. By 1990 24% of global forest is exposed to O3 concentrates 〉 60 ppb, and this increases to almost 50% of global forest by 2100. While the uncertainty in the future pollution climate of global forest is considerable, the likely impact of O3 and acid deposition is even more difficult to assess because of interactions between these pollutants and substantial changes in ambient CO2 concentration, N deposition and climate over the same period, but the effects are unlikely to be beneficial overall.
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  • 82
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    Water, air & soil pollution 118 (2000), S. 231-244 
    ISSN: 1573-2932
    Keywords: acidification ; air pollution ; critical loads ; ecological factors
    Source: Springer Online Journal Archives 1860-2000
    Topics: Energy, Environment Protection, Nuclear Power Engineering
    Notes: Abstract Ecosystem sensitivity to acid deposition can be a basis for thederivation of cost-effective strategies to sulfur and nitrogenpollutant control, consequently is widely concerned around theworld. In the article, the relative sensitivity of terrestrialecosystem to acid deposition in South China is assessed andmapped using a new sensitivity classification system suitable tosubtropical ecosystem. The result shows that the distribution ofecosystem sensitivity to acid deposition in South China isalmost zonal, on the whole, sensitivity increases from the northand west to the south and east. The most sensitive areas are thenorthwest and southeast of Zhejiang province, the central partof Fujian province, and the northeast of Guangdong province andGuangxi Zhuang Autonomous Region, which are all in the old acidsoil areas with high precipitation and coniferous forests. Theresulting distribution of sensitive regions is different othermaps, including the sensitivity map which is implemented in theRAINS-Asia model.
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  • 83
    ISSN: 1573-2932
    Keywords: acid deposition ; air pollution ; correlative study ; critical load ; defoliation ; Fagus sylvatica ; forest vitality ; meteorological stress ; Picea abies ; Pinus sylvestris ; Quercus ilex ; Quercus petraea ; Quercus robur
    Source: Springer Online Journal Archives 1860-2000
    Topics: Energy, Environment Protection, Nuclear Power Engineering
    Notes: Abstract Site-specific estimates for various environmentalstress factors were related with measured crowncondition data at a systematic 16 ×: 16 km2 gridover Europe, according to previously statedhypotheses, using a multiple regression approach,including interactions, and lagged effects of stressfactors. Methodological differences among countriesaccounted for 〉30% of the variation in defoliation.Nevertheless, crown condition was found to varynaturally with tree age, altitude, drought stress and,most likely, also pathogenic fungi and insects.Significant impacts of air pollution (specificallyozone but also NOx, SOx and acid deposition)were found at regional levels in parts of centralEurope, particularly for deciduous species. Impactsseemed less significant for conifers, especially forspruce, but this might be affected by confoundingeffects or strong correlations between (a harsh)climate and (low) atmospheric deposition in the areawhere spruce predominates. National studies indicatethat ozone and acid deposition can have a significanteffect on the defoliation of spruce as well. Weconclude that while forest condition varies naturally,continued emissions will contribute further to forestdecline in the long term.
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  • 84
    ISSN: 1573-2932
    Keywords: acid deposition ; acidification ; air pollution ; critical load ; defoliation ; drought ; meteorological stress ; N deposition ; nitrogen oxides ; ozone ; sulphur
    Source: Springer Online Journal Archives 1860-2000
    Topics: Energy, Environment Protection, Nuclear Power Engineering
    Notes: Abstract This paper is the first in a series of four,describing the hypothesis and approach of acorrelative study between observed data on crowncondition in Europe, monitored since 1986 at asystematic 16 × 16 km grid, and site-specificestimations of various natural and anthropogenicstress factors. The study was based on the hypothesisthat forests respond to various natural andanthropogenic stress factors, whose contributiondepend on the geographic region considered. In view ofthis hypothesis, major stand and site characteristics,chemical soil composition, meteorological stressfactors (temperature and drought stress indices) andair pollution stress (concentrations and/ordepositions of SOx, NOy, NHx andO3) were included as predictor variables. Theresponse variables considered were actual defoliationand changes/trends in defoliation for five major treespecies. The spatial distribution of the averagedefoliation during the period 1986–1995 shows highdefoliation in Central Europe and in parts ofScandinavia and of Southern Europe. There are,however, sharp changes at country borders, which aredue to methodological differences between countries.The spatial distribution of the calculated trends showa distinct cluster of large deterioration in parts ofCentral and Eastern Europe and in Spain and a ratherscattered pattern of positive and negative trends for most of Europe, indicating that other factors than airpollution only have a strong impact on defoliation.The limitations of the study are discussed in view ofthe quality of the considered response and predictor variables.
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    Water, air & soil pollution 120 (2000), S. 217-228 
    ISSN: 1573-2932
    Keywords: acid-buffering reactions ; acid deposition ; aluminium ; element budget ; soil acidification
    Source: Springer Online Journal Archives 1860-2000
    Topics: Energy, Environment Protection, Nuclear Power Engineering
    Notes: Abstract The present study aimed to assess thebuffering reactions and identify the sources of ionreplenishment by carrying out a laboratory leachingexperiment using some soils from a humid, temperateregion of Northern Spain. The experiment consisted ofthe addition of a solution of H2SO4 to fivesoils developed on various types of parent materials(granulite, serpentinite, schist, granite and sandysediments) and differing markedly in their mineralogyand chemical properties. Although the treatmentconsiderably intensified the leaching of base cations,the exchangeable fraction increased or was notaffected, which indicated significant mobilization ofthese elements from non exchangeable fractions. Thesoils differed markedly in the amounts ofSO4 2- retained, however only a small part ofthe amount retained in the upper horizons wasadsorbed. Acid load was mainly produced by freedeposited H+ and nitrification of internalorganic N. Sulphate retention was the dominantbuffering mechanism in the soils developed onserpentinite and schist. Proton consumption linked toAl mobilization occurred in the surface horizons ofall soils, but especially in the most acidic soils,those on granite and schist. In the soil on sandysediments, the dissolution of CaCO3 constitutedthe only buffering mechanism.
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    Water, air & soil pollution 105 (1998), S. 643-659 
    ISSN: 1573-2932
    Keywords: acid deposition ; acidification ; aluminium ; modeling
    Source: Springer Online Journal Archives 1860-2000
    Topics: Energy, Environment Protection, Nuclear Power Engineering
    Notes: Abstract Although the increased mobilization of aluminum from soils to surface waters is widely recognized as one of the most important ecological effects of acidic deposition, lumped-parameter mathematical models of acidification response typically overestimate the change in Al concentration under changing deposition by a considerable margin. The assumption of equilibrium with gibbsite (Al(OH)3) in the MAGIC model and other models of acid-base chemistry is shown to be inconsistent with measured values for a large variety of lake and stream databases. A modified algorithm for predicting Al concentration, based on empirical relationships evident in field data, provided superior estimates of changes in Al concentration in three long-term monitoring data sets and under experimental conditions at two experimental watershed manipulation sites.
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  • 87
    ISSN: 1573-2932
    Keywords: air pollution ; global warming ; greenhouse gas ; methaneformation
    Source: Springer Online Journal Archives 1860-2000
    Topics: Energy, Environment Protection, Nuclear Power Engineering
    Notes: Abstract To determine effective means to reduce methane (CH4) production from flooded rice soil, laboratory measurements were made on methane (CH4) formation in a Crowley silt loam as affected by the addition of potassium nitrate (KNO3), manganese dioxide (MnO2), and air (O2) under flooded conditions. In the experiment, oxidants were added to the soil prior to flooding at the rate of 300 and 1000 ppm O2 equivalent. Methane production was measured over a 32 d incubation period. Potassium nitrate added at rates of 300 and 1000 ppm O2 equivalent reduced CH4 production by 100% and MnO_2, at 300 and 1000 ppm O2 equivalent, significantly decreased CH4 formation approximately 20% and 98-99% over the 32 d period, respectively compared to controls. Air addition did not significantly affect CH4 formation.
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    Water, air & soil pollution 94 (1997), S. 163-180 
    ISSN: 1573-2932
    Keywords: acid deposition ; liming ; catchment ; lake ; water chemistry ; fish ; soil ; model
    Source: Springer Online Journal Archives 1860-2000
    Topics: Energy, Environment Protection, Nuclear Power Engineering
    Notes: Abstract In June 1983 a whole-catchment liming experiment was conducted at Tjønnstrond, southernmost Norway, to test the utility of terrestrial liming as a technique to restore fish populations in remote lakes with short water-retention times. Tjønnstrond consists of 2 small ponds of 3.0 and 1.5 ha in area which drain a 25-ha catchment. The area is located at about 650–700 meters above sea-level in sparse and unproductive forests of spruce, pine and birch with abundant peatlands. A dose of 3 ton/ha of powdered limestone were spread by helicopter to the terrestrial area. No limestone was added to the ponds themselves. The ponds were subsequently stocked with brown and brook trout. Liming caused large and immediate changes in surface water chemistry; pH increased from 4.5 to 7.0, Ca increased from 40 to 200μeq/L, ANC increased from −30 to +70μeq/L, and reactive-Al decreased from about 10 to 3μmol/L. During the subsequent 11 years the chemical composition of runoff has decreased gradually back towards the acidic pre-treatment situation. The major trends in concentrations of runoff Ca, ANC, pH, Al and NO3 in runoff are all well simulated by the acidification model MAGIC. Neither the measured data nor the MAGIC simulations indicate significant changes in any other major ion as a result of liming. The soils at Tjønnstrond in 1992 contained significantly higher amounts of exchangeable Ca relative to those at the untreated reference catchment Storgama. In 1992 about 75% of the added Ca remains in the soil as exchangeable Ca, 15% has been lost in runoff, and 10% is unaccounted for. The whole-catchment liming experiment at Tjønnstrond clearly demonstrates that this liming technique produces a long-term stable and favourable water quality for fish. Brown trout in both ponds in 1994 have good condition factors, which indicate that the fish are not stressed by marginal water quality due to re-acidification. The water quality is still adequate after 11 years and 〉20 water renewals. Concentrations of H+ and inorganic Al have gradually increased and approach levels toxic to trout, but the toxicity of these are offset by the continued elevated Ca concentrations. Reduced sulphate deposition during the last 4 years (1990–94) has also helped to slow and even reverse the rate of reacidification. The experiment at Tjønnstrond demonstrates that for this type of upland, remote terrain typical of large areas of southern Norway, terrestrial liming offers a suitable mitigation technique for treating acidified surface waters with short retention times.
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  • 89
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    Environmental monitoring and assessment 49 (1998), S. 251-262 
    ISSN: 1573-2959
    Keywords: air issues ; air pollution ; Canada ; ecological integrity ; national parks
    Source: Springer Online Journal Archives 1860-2000
    Topics: Energy, Environment Protection, Nuclear Power Engineering
    Notes: Abstract Several case histories illustrate national park air issues and responses in Canada. These examples include: acidification studies and establishment of a multiparticipant monitoring programme at Kejimkujik; studies of smoke at campgrounds in Jasper, La Mauricie and Forillon, its effect on health, and the management of visitors and firewood supply to mitigate these risks; and estimates of emissions from through-traffic in Yoho. From these cases and from reviews of the secondary literature, we can identify air issues that affect the maintenance of ecological integrity in national parks. These issues are: forest fires and smoke management; defining goals for ecosystem restoration; representation of natural regional conditions; visitor health and amenity; acidification; pesticides; eutrophication from airborne nitrates; permafrost melting; and UV-B. In June 1995, an International Air Issues Workshop brought together representatives from Canadian and U.S. national parks and other selected agencies. They ranked the air issues affecting national parks, producing quite an eclectic list. From the most to least serious issue, they are: acidification, toxics, visibility impairment, UV-B, smoke management, oil and gas development, fugitive dust, global warming, overflights, light pollution, noise and odour. Note that atmospheric change is only one among a group of stresses affecting national parks. Of 28 stresses recognized as significant for national parks in 1992, acid precipitation ranked 8th and climate change 23rd. Petrochemicals, 17th, pesticides, 18th and heavy metals, 21st, may be partly airborne. The 1995 workshop made several recommendations applicable to Parks Canada, from which those related to research and monitoring needs have been extracted. The air monitoring needed most by national parks is of suspended particulate and visibility. This is in response to human health and amenity concerns and international treaty obligations. The long-term protection of natural sites in national parks provides opportunities for other agencies to monitor ambient air quality and ecosystem responses, for example through the installation of under-canopy monitoring towers. The air research most needed in national parks is the modelling of natural landscapes and vegetation complexes in response to climate change. This follows from the primary purpose of each national park, to maintain the ecological integrity of an area selected to represent a natural region. The principal air research opportunities for other agencies in national parks are probably intensive instrumentation and sampling over several years to examine the air-vegetation-soil transfers of nutrients, pollutants and radiation.
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  • 90
    ISSN: 1573-2959
    Keywords: air pollution ; dispersion ; street canyon ; OSPM ; nitrogen oxides ; model validation
    Source: Springer Online Journal Archives 1860-2000
    Topics: Energy, Environment Protection, Nuclear Power Engineering
    Notes: Abstract A measuring campaign was conducted in the street canyon 'Runeberg street' in Helsinki in 1997. Hourly concentrations of carbon monoxide (CO), nitrogen oxides (NOX), nitrogen dioxide (NO2) and ozone (O3) were measured at the street and roof levels, and the relevant hourly meteorological parameters were measured at the roof level. The hourly street level measurements and on-site electronic traffic counts were conducted during the whole year 1997, and roof level measurements were conducted during approximately two months, from 3 March to 30 April in 1997. The Operational Street Pollution Model (OSPM) was used to calculate the street concentrations and the results were compared with the measurements. The overall agreement between measured and predicted concentrations was good for CO and NOx, but the model slightly overestimated the measured concentrations of NO2. The database, which contains all measured and predicted data, is available for a further testing of other street canyon dispersion models.
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  • 91
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    Water, air & soil pollution 103 (1998), S. 263-276 
    ISSN: 1573-2932
    Keywords: air pollution ; acid rain ; forest decline ; morphotypes ; Picea rubens
    Source: Springer Online Journal Archives 1860-2000
    Topics: Energy, Environment Protection, Nuclear Power Engineering
    Notes: Abstract The effects of acid precipitation and ozone on the composition of the ectomycorrhizal community of red spruce saplings were evaluated. In 1986, saplings were excavated from a site in Maine that had been clear-cut in 1979. Saplings were then potted in native soil and transported to Ithaca, New York. With the exception of an ambient control treatment, trees were grown in open-top chambers. Saplings were exposed to five levels of ozone and three levels of acid precipitation beginning in July 1987. Ectomycorrhizae were sampled in 1988 and 1991 after one and four years of treatment, respectively. Although the percentage of root tips infected by ectomycorrhizal fungi was not affected by treatments, a shift in the composition of the ectomycorrhizal community occurred in response to acid precipitation treatments for both sampling years. Among the seven ectomycorrhizal morphotypes identified, the percent composition of one morphotype increased and another decreased in response to higher rain acidity. Alone, ozone treatments did not influence ectomycorrhizal composition; however, a significant interactive response to ozone and acid precipitation was observed in the organic soil horizon in 1988. Such shifts in the composition of the ectomycorrhizal community may indicate that the experimental trees were stressed by pollution treatments.
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  • 92
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    Water, air & soil pollution 104 (1998), S. 269-283 
    ISSN: 1573-2932
    Keywords: acidification ; air pollution ; modelling
    Source: Springer Online Journal Archives 1860-2000
    Topics: Energy, Environment Protection, Nuclear Power Engineering
    Notes: Abstract A model, MAKEDEP, was developed for reconstructing historic atmospheric deposition and nutrient uptake for forests using present day values. Deposition is reconstructed by separation of wet deposition and throughfall into five different categories. Dry deposition is assumed to depend linearly on needle biomass. Non-marine deposition is scaled using general European emission and deposition trends for sulphur, nitrate and ammonia. Historic nutrient uptake is reconstructed using current biomass and nutrient content, a logistic forest growth curve and information on historic land use.
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  • 93
    ISSN: 1573-2932
    Keywords: acid deposition ; Adirondacks ; integrated assessment ; lake acidification ; mathematical model ; reduced-form modelling ; soil acidification
    Source: Springer Online Journal Archives 1860-2000
    Topics: Energy, Environment Protection, Nuclear Power Engineering
    Notes: Abstract A reduced-from modelling approach is used to predict soil and lake acidification as part of an integrated assessment of acid deposition effects and control strategies. The reduced-form model is based upon the mechanistic, lumped parameter watershed chemistry model, MAGIC (Model of Acidification of Groundwater in Catchments). Recent improvements to MAGIC are described, and its reduced-form representation in the Tracking and Analysis Framework (TAF), an integrated assessment model for decision and uncertainty analysis, is presented. Reduced-form models are developed for lake acid neutralising capacity (ANC), calcium, pH, and aluminium; and for soil base saturation. The model for lake ANC incorporates long-term depletion of the watershed acid neutralisation fraction, as is predicted to occur with MAGIC. In test calibrations for 33 representative watersheds in the Adirondacks, the resulting reduced-form model provides a close approximation to MAGIC, with average root mean square errors of 0.79 μeq l-1 for ANC, 1.09 μeq l-1 for calcium, 0.16 for pH, 2.52 μeq l-1 for aluminium, and 0.09% for soil base saturation. In addition, improved fish viability models are incorporated in the integrated assessment model, and predictions are demonstrated for a future deposition reduction scenario for the Adirondack region.
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  • 94
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    Water, air & soil pollution 104 (1998), S. 353-388 
    ISSN: 1573-2932
    Keywords: acid deposition ; acidification history ; aluminum adsorption ; base cation exchange ; biologic acidification ; podsols ; sulphate adsorption ; swedish forest soils
    Source: Springer Online Journal Archives 1860-2000
    Topics: Energy, Environment Protection, Nuclear Power Engineering
    Notes: Abstract Two submodels for simulating the leaching of forest soils are described. SOILORG is used for O, E, and top B layers where Al(OH)3 is absent and organic matter is the major base cation storage. SOILMIN cares for the rest of the profile where Al(OH)3 control of Al is assumed and goethite provides most of the sulphate storage, clay mineral surfaces providing base cation storage. Results are presented from a test run for the period 1911 to 2030, based on data from a 260 cm deep soil profile in the SW of Sweden investigated 1990 and on a likely deposition scenario. Considering that the deposition of base cations exceeded the removal by stemwood in 1911 when the simulation started, the biologic acidification of the soil profile had reached a steady state before 1911 so that no additional acidification took place before 1930 and very little before 1950. After 1950 it was strongly enhanced by the increased acid deposition. In the mineral soil a considerable resistance against acidification is offered both by base cation exchange and sulphate adsorption, creating an acidification front which moved slowly down the B-horizon then accelerated, reaching the bottom of the profile in 1990. A deposition reduction by 2/3 during 1990–2010 will cause a partial recovery of pH, particularly in the deeper parts of the profile.
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  • 95
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    Water, air & soil pollution 105 (1998), S. 409-415 
    ISSN: 1573-2932
    Keywords: acid deposition ; beryllium ; catchment ; groundwater ; soil solution ; stream water
    Source: Springer Online Journal Archives 1860-2000
    Topics: Energy, Environment Protection, Nuclear Power Engineering
    Notes: Abstract The environmental chemistry of beryllium (Be) was investigated at the Lysina catchment in western Bohemia, Czech Republic, a forest ecosystem with high loadings of acidic atmospheric deposition. The catchment supports Norway spruce plantations; it is underlain by leucogranite and the soils are Spodosols. Average concentrations of Be were high in groundwater (3.3 µg L-1) and in stream water (1.5 µg L-1), in comparison to the drinking water standard of the Czech Republic (0.2 µg L-1). Chemical equilibrium calculations suggest that aquoberyllium Be2+ was the prevailing inorganic species in drainage waters at the site. Atmospheric deposition of Be (45 µg m-2 yr-1) was small in comparison to drainage outflow (586 µg m-2 yr-1) at Lysina. Elevated Be concentrations in drainage water appear to be the result of the mobilization of Be from soils and weathered bedrock due to acidic atmospheric deposition. Increased mobility of Be due to acidification may have serious ecological consequences in acid-sensitive areas with terrestrial pools of available Be.
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  • 96
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    Water, air & soil pollution 118 (2000), S. 35-51 
    ISSN: 1573-2932
    Keywords: acid deposition ; China ; critical load ; soil sensitivity
    Source: Springer Online Journal Archives 1860-2000
    Topics: Energy, Environment Protection, Nuclear Power Engineering
    Notes: Abstract Critical loads of acid deposition havebeen mapped for Chinese soils using a modifiedsemi-quantitative method, which is based on theminerals controlling weathering and soil development,and corrected by introducing an Arrhenius relationshipto describe the effect of temperature and a weightedaveraging approach to evaluate the effect of soiltexture, land use and precipitation. As a consequenceof these modifications, the method has been quantifiedand can be more widely used. Results from this studyshow that the lowest critical loads of acid depositionin China, i.e., those areas most sensitive to aciddeposition, occur in the Podzolic soils in theNortheast, followed by Latosol, Dark brown forest soiland Black soil areas. The Ferralsol areas in SouthChina are intermediate, tolerating about 0.8–1.6 g m-2 yr-1 sulfur deposition. The highestcritical loads of acid deposition are mainly locatedin the Alpine soil areas on the Plateau of Tibet andareas of Xerosol and Podocal soil in Northwest China.The reason for lower critical loads in the Northeastrelative to South China can be attributed to thedifference of temperature, soil moisture and soiltexture. Comparison of critical loads with the sulfurdeposition in 1995 identifies almost one fourth of theland area in southeast China to be subject to risk of acidification.
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  • 97
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    Water, air & soil pollution 103 (1998), S. 423-439 
    ISSN: 1573-2932
    Keywords: airborne particles ; air pollution ; arsenic ; cadmium ; chromium ; copper ; lead ; manganese ; nickel ; precipitation ; selenium ; vanadium ; zinc
    Source: Springer Online Journal Archives 1860-2000
    Topics: Energy, Environment Protection, Nuclear Power Engineering
    Notes: Abstract The concentrations of vanadium (V), chromium (Cr), manganese (Mn), nickel (Ni), copper (Cu), zinc (Zn), arsenic (As), selenium (Se), cadmium (Cd), and lead (Pb) in precipitation and on airborne particles were measured at three Integrated Atmospheric Deposition Network (IADN) monitoring stations on Lakes Superior, Michigan and Erie during 1993 and 1994. These data were used to estimate annual wet and dry deposition fluxes at these sites. In most cases, both wet and dry deposition make an important contribution to the total atmospheric flux of trace metals. Total (wet + dry) annual loadings of Zn and Cr are higher at the Lake Erie site than at the Lake Michigan and Lake Superior sites. Atmospheric loadings of the other metals are similar at all three sites. Wet deposition of metals is more closely related to precipitation amount than to the concentration of metals in the precipitation. Dry deposition fluxes are controlled by the concentration of trace metals on large particles. Total particle mass concentrations are higher during the summer and fall at the Lake Erie site, however no seasonal trends in total particle mass at the other sites or trace metals at any of the sites were detected. The total atmospheric loadings calculated in this work are in agreement with other estimates of metals deposition to the Great Lakes.
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  • 98
    ISSN: 1573-2932
    Keywords: acidification ; air pollution ; atmospheric deposition ; Brazil ; Cubatão ; element fluxes ; element budgets ; Serra do Mar ; tropical rain forest
    Source: Springer Online Journal Archives 1860-2000
    Topics: Energy, Environment Protection, Nuclear Power Engineering
    Notes: Abstract Three rain forest ecosystems in the Serra do Mar, theatlantic coastal mountain range of Brazil, have beeninvestigated in the frame of an interdisciplinaryGerman-Brazilian research project on dispersion,transformation and deposition of air pollutants in andaround the industrial area of Cubatão. Part I ofthis paper gives a description of the overall goals ofthe project, the area of investigation, and thematerials and methods used. It reports on the resultsof the field measurements conducted from 1991 to 1995,covering concentrations of chemicals in precipitation,soil water, surface water and litter fluxes. In thepresent paper, part II, the element fluxes arepresented with calculated concentrations in thetransport media (precipitation, seepage water,litterfall) and their respective flow rates. Elementbudgets for the ecosystem and for the soil compartmentare interpreted with respect to turnover of chemicals,including nutrients, in forest vegetation, and toprocesses of soil acidification.The forests under investigation are characterized bya very high input from the atmosphere. Between 100 and200 kg S ha-1 are annually carried into soil byprecipitation in the form of sulfate, 20 to 70 kg ofnitrogen mainly in the form of ammonium, 3 to 24 kg offluoride. Input of ammonium and organic bound nitrogenis followed by nitrification in the top soil. At themost polluted site, nitrate output with seepageamounts to 300 kg N ha-1 yr-1, sulfate output tomore than 400 kg S. Soil acidification associated withturnover of sulfur and nitrogen is followed by therelease of aluminum from soil minerals, and leachingof ionic forms of Al (up to 280 kg Al ha-1annually). Transfer of aluminum ions to groundwaterand surface water can have serious ecologicaleffects. Alkalinity is consumed, and the water issubject to acidification.
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  • 99
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    Water, air & soil pollution 108 (1998), S. 107-127 
    ISSN: 1573-2932
    Keywords: acid deposition ; acidification ; base cations ; Bohemian lakes ; chloride ; Czech Republic ; lake water ; nitrate ; pH ; reversibility ; sulphate ; temporal changes
    Source: Springer Online Journal Archives 1860-2000
    Topics: Energy, Environment Protection, Nuclear Power Engineering
    Notes: Abstract Temporal changes in major solute concentrations in six Czech Republic lakes were monitored during the period 1984–1995. Four chronically-acidic lakes had decreasing concentrations of strong-acid anions (CSA = SO4 2- + NO3 - + Cl-), at rates of 3.0 to 9.0 μeq L-1 yr-1. Decreases in SO4 2-, NO3 -, and Cl- (at rates up to 5.1 μeq L-1 yr-1, 3.2 μeq L-1 yr-1, and 0.6 μeq L-1 yr-1, respectively) occurred. The response to the decrease in deposition of S was rapid and annual decline of SO4 2- in lake water was directly proportional to SO4 2- concentrations in the acidified lakes. Changes in NO3 - concentrations were modified by biological consumption within the lakes. The decline in CSA was accompanied in the four most acidic lakes by decreases in AlT, increases in pH at rates of 0.011 to 0.016 pH yr- 1, and decreases of Ca2+ and Mg2+ (but not Na+) in three lakes. The acid neutralizing capacity (ANC) increased significantly in all six lakes. Increases in base cation concentrations (CB = Ca2+ + Na+ + Mg2+ + K+) were the principal contributing factor to ANC increases in the two lakes with positive ANC, whereas decrease in CSA was the major factor in ANC increases in the four chronically-acidic lakes. The continued chemical recovery of these lakes depends on the uncertain trends in N deposition, the cycling of N in the lakes and their catchments, and the magnitude of the future decrease in S deposition.
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  • 100
    ISSN: 1573-2932
    Keywords: acid brown earth ; acid deposition ; aluminium chemistry ; alunite ; podzols ; soil solution ; surface water
    Source: Springer Online Journal Archives 1860-2000
    Topics: Energy, Environment Protection, Nuclear Power Engineering
    Notes: Abstract Al chemistry was studied in two acidic watersheds, one with a podzol, the other with an acid brown soil, in the Vosges mountains (N.E. France), by analysing both leaching and centrifugation soil solutions and spring waters over 3 yr. In the podzol, Al was mobilized in the eluvial horizons under the predominant influence of organic acidity, then leached down the profile as organic and F-bound Al. Strong undersaturation with respect to proto-imogolite and imogolite showed that the proto-imogolite theory of podzolization could not apply. Al was transferred from the soil to spring water mostly as Al3+ and Al-F. Al3+, as well as additional minor species (AlOH2+, AlSO4 +), originated from the redissolution of the top of the spodic horizons under the influence of both soil solution acidity and the occurrence of mobile anions derived from atmospheric deposition. Conversely, in the acid brown soil, Al mobilization was regulated by nitrate and occurred mainly as Al3+. Most of Al was retained in the deep soil and only traces of monomeric Al reached spring water. In the podzol eluvial horizons, soil solutions were undersaturated with respect to all relevant mineral phases and their chemical composition agree with the concept of a mobilization of Al from the solid soil organic Al and a control of Al3+ activity by complexation reaction with the solid and soluble soil organic matter and F. In the acid brown soil, soil solutions were found to be in equilibrium with natural alunite, and the formation of this mineral, if confirmed, would account for the occurrence of 'open' vermiculites instead of the expected hydroxy-Al interlayered vermiculites. Al solubility control in surface water of both watersheds remains unclear. The Al-F species in both watersheds and the likely control of Al solubility by alunite in the acid brown soil emphasize the influence of acid deposition on Al chemistry in acid watersheds.
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