ALBERT

Description: This sensor unit is designed to determine the level of activation of lunar dust or simulant particles using a fluorescent technique. Activation of the surface of a lunar soil sample (for instance, through grinding) should produce a freshly fractured surface. When these reactive surfaces interact with oxygen and water, they produce hydroxyl radicals. These radicals will react with a terephthalate diluted in the aqueous medium to form 2-hydroxyterephthalate. The fluorescence produced by 2-hydroxyterephthalate provides qualitative proof of the activation of the sample. Using a calibration curve produced by synthesized 2-hydroxyterephthalate, the amount of hydroxyl radicals produced as a function of sample concentration can also be determined.

Description: No abstract available

Description: The decision to return humans to the moon by 2020 makes it imperative to understand the effects of lunar dust on human and mechanical systems.( Bush 2004; Gaier 2005; Mendell 2005) During the Apollo missions, dust was found to cause numerous problems for various instruments and systems. Additionally, the dust may have caused health issues for some of the astronauts.(Gaier 2005; Rowe 2007) It is necessary, therefore, for studies to be carried out in a variety of disciplines in order to mitigate the effects of the dust as completely as possible. Due to the lack of an atmosphere, there is nothing to protect the lunar soil from ultraviolet radiation, solar wind, and meteorite impacts. These processes could all serve to "activate" the soil, or produce reactive surface species. In order to understand the possible toxic effects of the reactive dust, it is necessary to "reactivate" the dust, as samples returned during the Apollo missions were exposed to the atmosphere of the Earth. We have used grinding and exposure to UV radiation in order to mimic some of the processes occurring on the lunar surface. To monitor the reactivity of the dust, we have measured the ability of the dust to produce hydroxyl radicals in solution. These radicals have been measured using a novel fluorescent technique developed in our laboratory,(Wallace et al. 2008) as well as using electron paramagnetic resonance (EPR).

Description: In the history of manned spaceflight, environmental monitoring has relied heavily on archival sampling. For short missions, this type of sample collection was sufficient; returned samples provided a snapshot of the presence of chemical and biological contaminants in the spacecraft air and water. However, with the construction of the International Space Station (ISS) and the subsequent extension of mission durations, soon to be up to one year, the need for enhanced, real-time environmental monitoring became more pressing. The past several years have seen the implementation of several real-time monitors aboard the ISS, complemented with reduced archival sampling. The station air is currently monitored for volatile organic compounds (VOCs) using gas chromatography-differential mobility spectrometry (Air Quality Monitor [AQM]). The water on ISS is analyzed to measure total organic carbon and biocide concentrations using the Total Organic Carbon Analyzer (TOCA) and the Colorimetric Water Quality Monitoring Kit (CWQMK), respectively. The current air and water monitors provide important data, but the number and size of the different instruments makes them impractical for future exploration missions. It is apparent that there is still a need for improvements in environmental monitoring capabilities. One such improvement could be realized by modifying a single instrument to analyze both air and water. As the AQM currently provides quantitative, compound-specific information for target compounds present in air samples, and many of the compounds are also targets for water quality monitoring, this instrument provides a logical starting point to evaluate the feasibility of this approach. In this presentation, we will discuss our recent studies aimed at determining an appropriate method for introducing VOCs from water samples into the gas phase and our current work, in which an electro-thermal vaporization unit has been interfaced with the AQM to analyze target analytes at the relevant concentrations at which they are routinely detected in archival water samples from the ISS.

Description: No abstract available

Description: No abstract available

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Description: This paper continues the annual tradition, at this conference, of summarizing the results of chemical analyses performed on archival potable water samples returned from the International Space Station (ISS). 2016 represented a banner year for life aboard the ISS, including the successful conclusion for 2 crewmembers of a record 1-year mission. Water reclaimed from urine and/or humidity condensate remained the primary source of potable water for the crewmembers of ISS Expeditions 46-50. The year was also marked by the end of a long-standing tradition of U.S. sampling and monitoring of Russian Segment potable water sources. Two water samples, taken during Expedition 46 and returned on Soyuz 44 in March 2016, represented the final Russian Segment samples to be collected and analyzed by the U.S. side. Although anticipated for 2016, a rise in the total organic carbon (TOC) concentration of the product water from the U.S. water processor assembly due to breakthrough of organic contaminants from the system did not materialize, as evidenced by the onboard TOC analyzer and archival sample results.

Description: The purpose of this project is to assess the potential toxicity of lunar dust to cause the release of pro-inflammatory cytokines by human lung cells. Some of this dust is on the scale of 1-2 micrometers and could enter the lungs when astronauts track dust into the habitat and inhale it. This could be a serious problem as NASA plans on going back to the moon for an extended period of time. Literature shows that quartz, which has a known cytoxicity, can cause acute cases of silicosis within 6 months, and in most cases cause silicosis after 3 years. The activation of lunar dust through impacts creates surface based radicals which, upon contact with water create hydroxl radicals and peroxyl radicals which are very reactive and potentially might even be as cytotoxic as quartz. These radicals could then react with lung cells to produce pro-inflammatory mediators such as interleukin-6 and interleukin-8, and TNF-alpha.

Description: During the early years of human spaceflight, short duration missions allowed for monitoring of the spacecraft environment to be performed via archival sampling, in which samples were returned to Earth for analysis. With the construction of the International Space Station (ISS) and the accompanying extended mission durations, the need for enhanced, real-time monitors became apparent. The Volatile Organic Analyzer (VOA) operated on ISS for 7 years, where it assessed trace volatile organic compounds in the cabin air. The large and fixed-position VOA was eventually replaced with the smaller Air Quality Monitor (AQM). Since March 2013, the atmosphere of the U.S. Operating Segment (USOS) has been monitored in near real-time by a pair of AQMs. These devices consist of a gas chromatograph (GC) coupled with a differential mobility spectrometer (DMS) and currently target detection list of 22 compounds. These targets are of importance to both crew health and the Environmental Control and Life Support Systems (ECLSS) on ISS. Data is collected autonomously every 73 hours, though the units can be controlled remotely from mission control to collect data more frequently during contingency or troubleshooting operations. Due to a nominal three-year lifetime on-orbit, the initial units were replaced in February 2016. This paper will focus on the preparation and use of the AQMs over the past several years. A description of the technical aspects of the AQM will be followed by lessons learned from the deployment and operation of the first set of AQMs. These lessons were used to improve the already-excellent performance of the instruments prior to deployment of the replacement units. Data trending over the past several years of operation on ISS will also be discussed, including data obtained during a survey of the USOS modules. Finally, a description of AQM use for contingency and investigative studies will be presented.