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catena-Poly[[(acetonitrile-N)dichlorocopper(II)]-μ-2,5-dimethylpyrazine-κ2N:N′] (2001)

Näther, Christian ; Greve, Jan

Oxford [u.a.] : International Union of Crystallography (IUCr)

Acta crystallographica 57 (2001), S. 1388-1390

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ISSN: 1600-5759

Source: Crystallography Journals Online : IUCR Backfile Archive 1948-2001

Topics: Chemistry and Pharmacology , Geosciences , Physics

Notes: In the structure of the title compound, [CuCl2(C2H3N)(C6H8N2)], each Cu2+ cation is surrounded by two 2,5-dimethylpyrazine ligands, one acetonitrile ligand and two Cl− anions within a distorted tetragonal pyramid. The acetonitrile ligand, which forms the apex of the pyramid, the Cu2+ cation and the Cl− anions are all located in general positions, whereas each of the 2,5-dimethylpyrazine ligands is located about a centre of inversion. The 2,5-dimethylpyrazine ligands connect the Cu2+ cations via μ-N:N′ coordination to form chains.

Type of Medium: Electronic Resource

URL: http://dx.doi.org/10.1107/S0108270101015384

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