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Reduction of tri(hetero)arylcarbinols to tri(hetero)arylmethanes (1990)

Avendaño, Carmen ; Diego, Carmen de ; Elguero, José

Springer

Monatshefte für Chemie 121 (1990), S. 649-652

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ISSN: 1434-4475

Keywords: Tri(hetero)arylcarbinols ; Tri(hetero)arylmethanes

Source: Springer Online Journal Archives 1860-2000

Topics: Chemistry and Pharmacology

Description / Table of Contents: Zusammenfassung Durch die Reduktion der entsprechenden Carbinole mit Lithium-aluminiumhydrid/Aluminiumchlorid wurden sieben neue Tri(hetero)arylmethane in sehr guten Ausbeuten (77–98%) hergestellt. Eine Ausnahme bildet das Tri-(2-benzothienyl)-Derivat mit 41%. Die1H-NMR-Spektren werden diskutiert.

Notes: Summary A series of seven new tri(hetero)arylmethanes has been prepared by reduction of the corresponding carbinols using a mixture of lithium aluminium hydride/aluminium trichloride. The yields are excellent (77–98%) except in the case of the tri(2-benzothienyl)derivative (41%).1H NMR spectra are discussed.

Type of Medium: Electronic Resource

URL: http://dx.doi.org/10.1007/BF00809768

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