Summary
A series of seven new tri(hetero)arylmethanes has been prepared by reduction of the corresponding carbinols using a mixture of lithium aluminium hydride/aluminium trichloride. The yields are excellent (77–98%) except in the case of the tri(2-benzothienyl)derivative (41%).1H NMR spectra are discussed.
Zusammenfassung
Durch die Reduktion der entsprechenden Carbinole mit Lithium-aluminiumhydrid/Aluminiumchlorid wurden sieben neue Tri(hetero)arylmethane in sehr guten Ausbeuten (77–98%) hergestellt. Eine Ausnahme bildet das Tri-(2-benzothienyl)-Derivat mit 41%. Die1H-NMR-Spektren werden diskutiert.
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Avendaño, C., Diego, C.d. & Elguero, J. Reduction of tri(hetero)arylcarbinols to tri(hetero)arylmethanes. Monatsh Chem 121, 649–652 (1990). https://doi.org/10.1007/BF00809768
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DOI: https://doi.org/10.1007/BF00809768