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Über Salze und Doppelsalze der Seltenen Erden, 3. Mitt. (1977)

Bukovec, Nataša ; Bukovec, Peter ; Golič, Ljubo ; [et al.]

Springer

Monatshefte für Chemie 108 (1977), S. 997-1003

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ISSN: 1434-4475

Source: Springer Online Journal Archives 1860-2000

Topics: Chemistry and Pharmacology

Notes: Abstract Complexes of the type Cs[Ln(SO4)2(H2O)3]H2O, (Ln=La, Ce, Pr, Nd, Sm, Eu, Gd, Tb, Dy, Ho, Er, Tm, Yb, Lu) were prepared from aqueous solution. The compounds are all isomorphous and crystallise monoclinic, space group P21/c,Z=4. Unit cell parameters were determined by the single crystal technique and correlated to the ionic radii of Ln3+. IR spectra were recorded in the range 4000-250 cm−1 and tentatively assigned. The number of observed bands exceeds the predicted number by site symmetry selection rules, indicating coupling in the layer structure.

Type of Medium: Electronic Resource

URL: http://dx.doi.org/10.1007/BF00897679

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