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Über Salze und Doppelsalze der Seltenen Erden, 3. Mitt.

The salts and double salts of rare earths, III: Cesium bissulfato-triaquo-metallates(III) monohydrates

Cäsium-bis-sulfato-triaquo-metallate(III)-monohydrate

  • Anorganische, Struktur- und Physikalische Chemie
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Monatshefte für Chemie / Chemical Monthly Aims and scope Submit manuscript

Abstract

Complexes of the type Cs[Ln(SO4)2(H2O)3]H2O, (Ln=La, Ce, Pr, Nd, Sm, Eu, Gd, Tb, Dy, Ho, Er, Tm, Yb, Lu) were prepared from aqueous solution. The compounds are all isomorphous and crystallise monoclinic, space group P21/c,Z=4. Unit cell parameters were determined by the single crystal technique and correlated to the ionic radii of Ln3+.

IR spectra were recorded in the range 4000-250 cm−1 and tentatively assigned. The number of observed bands exceeds the predicted number by site symmetry selection rules, indicating coupling in the layer structure.

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Authors and Affiliations

  1. Laboratorium für anorganische Chemie, Universität Ljubljana, Murnikova 6, YU-61001, Ljubljana, Jugoslawien

    Nataša Bukovec, Peter Bukovec, Ljubo Golič &  Jože Šiftar

Authors
  1. Nataša Bukovec
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  2. Peter Bukovec
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  3. Ljubo Golič
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  4. Jože Šiftar
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Bukovec, N., Bukovec, P., Golič, L. et al. Über Salze und Doppelsalze der Seltenen Erden, 3. Mitt.. Monatshefte für Chemie 108, 997–1003 (1977). https://doi.org/10.1007/BF00897679

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  • DOI: https://doi.org/10.1007/BF00897679

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