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Polymerization of Methylthiirane initiated by platinum(II)- and palladium(II)-complexes (1980)

Dumas, Philippe ; Girault, Jean-Pierre ; Guerin, Philippe

Springer

Polymer bulletin 2 (1980), S. 257-261

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ISSN: 1436-2449

Source: Springer Online Journal Archives 1860-2000

Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics

Notes: Summary Some complexes derived from platinum(II) and palladium(II) initiate stereospecific polymerization of methylthiirane in homogeneous phase. When the metal environment is chiral no stereoelective polymerization occurs. The mechanism of polymerization initiated by platinum complexes seems to be similar to those proposed for zinc or cadmium derivatives whereas analogies are apparent between palladium and some aluminum derivatives, especially in the formation of great amounts of disulfide bonds during the polymerization.

Type of Medium: Electronic Resource

URL: http://dx.doi.org/10.1007/BF00282283

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