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Polymerization of Methylthiirane initiated by platinum(II)- and palladium(II)-complexes

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Summary

Some complexes derived from platinum(II) and palladium(II) initiate stereospecific polymerization of methylthiirane in homogeneous phase.

When the metal environment is chiral no stereoelective polymerization occurs. The mechanism of polymerization initiated by platinum complexes seems to be similar to those proposed for zinc or cadmium derivatives whereas analogies are apparent between palladium and some aluminum derivatives, especially in the formation of great amounts of disulfide bonds during the polymerization.

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Authors and Affiliations

  1. Laboratoire de Chimie Macromoléculaire associé au CNRS, Université Pierre et Marie Curie, 4, Place Jussieu, 75230, Paris Cédex 05, France

    Philippe Dumas

  2. Laboratoire de Chimie de Coordination Organique et Biologique, Ecole Normale Supérieure, 24, rue Lhomond, 75231, Paris Cédex 05, France

    Jean-Pierre Girault & Philippe Guerin

Authors
  1. Philippe Dumas
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  2. Jean-Pierre Girault
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  3. Philippe Guerin
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Dumas, P., Girault, JP. & Guerin, P. Polymerization of Methylthiirane initiated by platinum(II)- and palladium(II)-complexes. Polymer Bulletin 2, 257–261 (1980). https://doi.org/10.1007/BF00282283

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  • DOI: https://doi.org/10.1007/BF00282283

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